Phn ng nhit Nhm

Kim tra u gi
Vd1, Trng hp no sau y khng thu c Al(OH)3
A, Sc kh CO2 ti d vo dd Na[Al(OH)4]
B, Cho dd HCl ti d vo dd Ba[Al(OH)4]
C, Cho dd Na2CO3 tc dng vi dd Al2(SO4)3
D, Sc kh NH3 ti d vo dd AlCl3
Vd2, Cho V lt dd NaOH 1M vo 200 ml dd Al2(SO4)3 0,25M th thu c kt ta X v dd Y, Sc kh CO2 ti d
vo dd Y li thu c 2,34 gam kt ta. Gi tr ca V l
A, 0,06
B, 0,32
C, 0,34
D,0, 33
Vd3, Ha tan m gam Al2(SO4)3 vo nc c dd X.
-Nu cho t t 150 ml dd KOH 1M vo dd X th thu c a gam kt ta
-Nu cho t t 500 ml dd KOH 1M vo dd X th thu c 2a gam kt ta
Gi tr ca m l
A, 17,10
B, 34,20 gam
C,25,65
D,51,30
Vd4, Hn hp m gam Ba, Al2O3 tan ht vo nc th thu c dd X ch cha mt cht tan duy nht, nu sc kh
CO2 ti d vo dd X th thu c 15,6 gam kt ta. Gi tr ca m l
A, 23,9
B, 11,95
C,18,8
D,17,15
A, L thuyt
Al + MxOy M + Al2O3 ( M hay gp l Fe, Cr, Cu,...)
Vd1, phn ng no sau y khng phi phn ng nhit nhm
to
to Al2O3 + 2Fe
A, 2Al + Fe2O
B, 2Al + 3CuO
3Cu + Al2O3
3
to
C, 2Al + Cr2O3
Al2O3 + 2Cr
D, 2Al + 6H2SO4nng Al2(SO4)3+ 3SO2 + 6H2O
B, Bi tp
-Mi quan h khi lng mt = ms = mO+ mM+mAl
-nAl(t) = nAl(s) = tng s mol nOH-nO(t) = nO(s)
Dng 1: Phn ng hon ton + Al d hoc MxOy d ( thng ch xt p to ra kim loi, khng to ra cc
oxit trung gian)
Vd2, Cho Al d tc dng vi hn hp Fe2O3, Fe3O4 nung nng, sau khi phn ng xy ra hon ton hn hp rn
gm
A, Al, Fe, Fe2O3, Fe3O4
B, Al, Fe, Al2O3
C, Fe, Al2O3, Fe2O3, Fe3O4
D, Al2O3, Fe2O3, Fe3O4
-Thng nhm d: hn hp rn gm Al, M, Al2O3
+ cho tc dng vi kim nAld = 2/3.nH2 v nOH- = nAl(b)
vd3, hn hp X gm 41,4 gam Fe2O3, Cr2O3 v Al2O3 tc dng vi dd NaOH d, sau phn ng thu c cht rn c
khi lng l 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh
phn phn trm theo khi lng ca Cr2O3 trong hn hp X l
A, 20,33%
B,50,67%
C,36,71%
D,66,67%
Vd4, t nng mt hn hp gm Al v 16 gam Fe2O3( trong iu kin khng c khng kh) n khi phn ng xy
ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dd NaOH 1M sinh ra 3,36 lt H2(ktc). Gi
tr ca V l
A, 100
B, 150
C,200
D, 300
Vd5, Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau phn ng xy ra hon
ton, thu c hn hp rn X. Cho X tc dng vi dd NaOH d thu c dd Y, cht rn Z v 3,36 lt kh H2(ktc).
Sc kh CO2 d vo dd Y, thu c 39 gam kt ta. Gi tr ca m l?
A, 45,6
B,48,3
C, 36,7
D, 46,7
+ Cho hn hp tc dng vi kim v axit HCl ( H2SO4 long)
Vd6, Nung hn hp gm Al v Fe2O3 trong iu kin khng c oxi), thu c hn hp X. Chia X thnh hai phn
bng nhau.
-Cho phn 1 tc dng vi dd HCl d th thu c 7,84 lit H2(ktc)
-Cho phn 2 tc dng vi dd NaOH d thu c 3,36 lt kh H2(ktc).

Bit rng cc phn ng u xy ra hon ton. Phn trm khi lng ca Fe trong X l
A, 42,32%
B,46,47%
C, 66, 39%
D,33,61%
+ Cho hn hp tc dng vi dd HNO3 hay H2SO4
-Bo ton electron( u ui)
Vd7, Hn hp 24,1 gam Al, Fe2O3 nung nng phn ng nhit nhm xy ra hon ton th thu c hn hp X,
cho hn hp X tc dng vi dd HNO3 c nng d th thu c 20,16 lt NO2(ktc). Phn trm khi lng ca Fe
trong hn hp X l
A, 23,24%
B,46,47%
C,34,85%
D, 11,62%
Vd8, Hn hp 29,7 gam Al, FeO nung nng phn ng nhit nhm xy ra hon ton th thu c hn hp X, cho
hn hp X tc dng vi dd HNO3 c nng d th thu c 26,88 lt NO2(ktc). Nu cho hn hp X tc dng vi
dd HCl d th th tch kh H2 (ktc) l
A, 26,88
B,13,44
C, 8,96
D, 10,08
Vd9, Hn hp 59,9 gam Al, Fe3O4 nung nng phn ng nhit nhm xy ra hon ton th thu c hn hp X,
cho hn hp X tc dng vi dd HNO3 c nng d th thu c 38,08 lt NO2(ktc). Nu cho hn hp X tc dng
vi dd NaOH th thu c bao nhiu lt H2(ktc)
A, 5,6
B,3,36
C, 1,12
D, 0
Dng 2: Phn ng khng hon ton
Ch xt phn ng
2yAl + 3MxOy yAl2O3 +
3xM
u
P
2ya
3a
ya
xa
Rn...
Vd10, iu ch 78 gam Cr t Cr2O3 d bng phn ng nhit nhm vi hiu sut phn ng l 90% th khi lng
bt nhm cn dng ti thiu l
A, 81 gam
B, 54 gam
C,40,5 gam
D, 45 gam
Vd11, Trn 10,8 gam bt Al vi 34,8 gam Fe3O4 ri tin hnh phn ng nhit nhm trong iu kin khng c
khng kh. Ha tan ton b sn phm bng dd H2SO4 long(d) thu c 10,752 lt kh H2(ktc). Hiu sut ca
phn ng nhit nhm l
A, 80%
B, 90%
C, 70%
D, 60%
Vd12, Hn hp X gm Al v Fe3O4. Nung hn hp X nhit cao thu c hn hp Y. Chia Y lm 2 phn bng
nhau
Phn 1: Cho vo dd NaOH d thu c 1,344 lt H2(ktc)
Phn 2: Ha tan ht trong 310 ml dd H2SO4 1M (long) thu c 3,36 lt H2(ktc).
Hiu sut ca phn ng nhit nhm l
A, 60%
B,66,67%
C,75%
D, 80%
Dng 3: Chia hn hp thnh 2 phn khng bng nhau
Vd13, m gam hn hp Al, Fe2O3 un nng trong iu kin khng c khng kh thu c hn hp X, chia hn hp
X thnh 2 phn
Phn 1 cho tc dng vi dd NaOH d th thu c 0,336 lt H2(ktc) v 1,12 gam mt cht rn khng tan
Phn 2 cho tc dng vi dd HNO3 long d th thu c 2,016 lt NO(ktc) l sn phm kh duy nht ca N+5. Gi
tr ca m l
A, 9,64 gam
B, 7,23 gam
C, 14,46 gam
D, 2,41 gam
Vd14, m gam hn hp Al, FexOy un nng trong iu kin khng c khng kh thu c hn hp X, chia hn hp
X thnh 2 phn
Phn 1: cho tc dng vi dd NaOH d thu c 1,008 lt H2(ktc) v cn li 5,04 gam mt cht rn khng tan.
Phn 2: c khi lng l 29,79 gam, cho tc dng vi dd HNO3 long d thu c 8,064 lt NO(ktc) l sn phm
kh duy nht ca N+5. Gi tr ca m v cng thc ca oxit l
A, 39,72 gam v FeO
B, 39,72 gam v Fe3O4
C, 38,91 gam v FeO
D, 36,48 gam v Fe3O4
Dng 4: Tm cng thc ca oxit
Al, MxOy thng da vo t l s mol M v O
Vd15, m gam hn hp Al, FexOy un nng thu c hn hp X. Nu cho hn hp X tc dng vi dd KOH 1M th
th tch dd cn l 300 ml v thu c 0,15 mol H2. Nu cho hn hp X tc dng vi dd HCl d th thu 0,35 mol H2.
Bit cc phn ng xy ra hon ton, Gi tr ca m v cng thc ca oxit l

A, 21,4 v Fe3O4
B,24,1 v Fe2O3
C, 24,1 v FeO
D, 19,7 v Fe3O4
Vd16, 29,7 gam Al v FexOy un nng phn ng nhit nhm xy ra hon ton th thu c hn hp X, cho X
tc dng vi lng va 300 ml dd NaOH 1M th thu c 3,36 lt kh H2(ktc), dd Y v cht rn Z. Cng thc
ca oxit l
A, Fe2O3
B, FeO
C, Fe3O4
D, Fe2O3 hoc FeO
T luyn
Dng 1: Phn ng xy ra hon ton
Cu 1: Hn hp 8,1 gam Al v 16 gam Fe2O3 un nng thc hi n phn ng nhi t nhm hon ton, hn hp sau
phn ng cho tc dng vi dd HCl thu c V lt H2 iu ki n chun. V l
A. 8,96
C. 6,72
D. 7,84
B. Tt c sai
Cu 2: 24,1 gam hn hp Al, Fe2O3 nung nng cho phn ng nhit nhm xy ra hon ton th thu c hn hp X.
Cho hn hp X tc dng vi dd NaOH 1M th th tch NaOH phn ng l 0,3 lt, thu c 3,36 lt H2(ktc). Tnh
% khi lng ca Al trong hn hp ban u
A,11,20%
B,22,40%
C,33,61%
D,78,60%
Cu 3: Hn hp Al, Fe3O4 nung nng cho phn ng nhit nhm xy ra hon ton( trong iu kin khng c oxi)
thu c hn hp X. Cho hn hp X tc dng vi dd HCl 1M th th tch HCl dng l 450 ml v thu c 2,352
lt H2(ktc). Tnh % khi lng ca Al trong hn hp ban u.
A, 25,88%
B,8,62%
C,91,38%
D,23,00%
Cu 4: Hn hp m gam Al, FeO nung nng cho phn ng nhit nhm xy ra hon ton th thu c hn hp X,
nu cho hn hp X tc dng vi dd NaOH 1M th th tch dd NaOH cn l 0,3 lt. Nu cho hn hp X tc dng vi
dd HNO3c nng d th thu c 26,88 lt NO2(ktc) l sn phm duy nht ca N+5. Tnh m
A, 22,5
B,29,7
C,25,2
D,51,3
Cu 5: Cho 5,4 gam Al v 16 gam Fe2O3 vo ng s un nng(gi s ch xy ra phn ng kh oxit thnh st), hn
hp sau phn ng cho tc dng vi dd NaOH d thu c 3,36 lt kh H2(kc). Xc nh hi u sut Phn ng nhi t
nhm.
A. 50%
B.60%
C. 70%
D.80%
Cu 6: Hn hp 8,1 gam Al v 16 gam Fe2O3 un nng thc hi n phn ng nhi t nhm (gi s ch xy ra phn
ng kh oxit thnh st) , hn hp sau phn ng cho tc dng vi dd HCl d th thu c 7,84 lt kh H2 (kc). Xc
nh hi u sut phn ng nhi t nhm?
A. 80%
C. 90%
D.100%
B. 50%
Cu 7: Cho 8,1 gam Al v 16 gam Fe2O3 vo ng s un nng(gi s ch xy ra phn ng kh oxit thnh st).
Hi u sut phn ng l 50%, hn hp sau phn ng cho tc dng vi dd NaOH d thu c V lt kh H2(kc).V l
A. 2,24
B. 3,36
C. 6,72
D. 7,84
Cu 8: Hn hp 8,1 gam Al v 16 gam Fe2O3 un nng thc hi n phn ng nhi t nhm H=80%, hn hp sau
phn ng cho tc dng vi dd HCl thu c V lt H2 iu ki n chun. V l
A. 8,96
B. 6,72
C. 7,84
B. 8,288
Cu 9: Hn hp X gm Al v Fe3O4. Nung hn hp X nhit cao thu c hn hp Y. Chia Y lm 2 phn bng
nhau
Phn 1: Cho vo dd NaOH d thu c 0,672 lt H2(ktc)
Phn 2: Ha tan ht trong 320 ml dd H2SO4 1M (long) thu c 2,688 lt H2(ktc).
Hiu sut ca phn ng nhit nhm l
A, 60%
B,66,67%
C,75%
D, 80%
Cu 10: Hn hp A gm Al v FexOy. Thc hin phn ng nhit nhm hon ton thu c 78,75 g cht rn B. Ho
tan B trong dung dch NaOH d thy c 8,4 lt kh bay ra ( ktc) v cn li 44,8g cht rn khng tan. Cng thc
ca oxit st l:
A.FeO
B. Fe3O4
C. Fe2O3
D. FeO hoc Fe3O4
Cu 11: Hn hp m gam Al, Fe2O3 nung nng phn ng nhit nhm xy ra hon ton thu c hn hp X. Chia
hn hp X thnh 2 phn.
Phn 1 cho tc dng vi dd NaOH d thu c 0,336 lt H2(ktc)
Phn 2 c khi lng l 4,02 gam cho tc dng vi dd HCl d th thu c 1,68 lt H2(ktc)
Gi tr ca m l
A, 6,03
B,5,36
C, 8,04
D,12,06

Cu 12: Hn hp X gm Al v Fe3O4. Nung hn hp X nhit cao thu c hn hp Y. Chia Y lm 2 phn

Phn 1: Cho vo dd NaOH 1M thu c 0,336 lt H2(ktc), th tch NaOH cn l 50 ml
Phn 2: Ha tan ht trong 320 ml dd H2SO4 1M (long) thu c 2,688 lt H2(ktc).
Hiu sut ca phn ng nhit nhm l
A, 60%
B,66,67%
C,75%
D, 80%