Cu 43. un nng 0,16 mol hn hp E gm hai peptit X (C xHyOzN6) v Y (CnHmO6Nt) cn dng 600 ml dung dch NaOH 1,5M ch thu c dung dch cha a mol mui ca glyxin v b mol mui ca alanin. Mt khc t chy 30,73 gam E trong O2 va thu c hn hp CO2, H2O v N2, trong tng khi lng ca CO2 v nc l 69,31 gam. Gi tr a : b gn nht vi A. 0,730. B. 0,810. C. 0,756. D. 0,962.
- X v Y u to t Gly v Ala nn z = 7 v t =5.
- Gi c, d l mol ca X, Y ta c: c + d = 0,16. - Khi cho E tc dng vi NaOH th X + 6NaOH Mui Gly (C2H4O2NNa) + H2O Y + 5NaOH Mui Ala (C3H6O2NNa) + H2O nNaOH = 6c + 5d = 0,9 c = 0,1 v d = 0,06. * Khi CHT 30,73 gam E CO2 + H2O. Gi mol ca X v Y tng ng l 10x v 6x, mol CO2 v H2O l y v z. V X = 6+6.(-0,5) = 3 (X: hexapeptit nn c 6 nhm CO (6) v 6 nguyn t N, mi N c -0,5) V Y = 5+5.(-0,5) = 2,5 (Y: pentapeptit, c 5 nhm CO (5) v 5 nguyn t N, mi N c -0,5) - Khi t X: CO2 - H2O = (X - 1).10x = 20x - Khi t Y: CO2 - H2O = (Y - 1).6x = 9x y - z = 20x + 9x = 29x (1) - Ngoi ra: 44y + 18z = 69,31 (2) - Lng E em t: mE = mO + mN + mC + mH = (16.7 + 14.6).10x + (16.6 + 14.5).6x + 12y + 2z = 30,73 (3) Gii h (1), (2), (3) ta c: x = 0,005; y = 1,16 v z = 1,015. * Trong 30,73 gam E c nX = 0,05 v nY = 0,03 nE = 0,08 Khi nE = 0,16 mE = 61,46 gam. BTKL kl mui = 61,46 + 0,9.40 - 0,16.18 = 94,58 gam. 97a + 111b = 94,58 v a + b = 0,9 a = 0,38 v b = 0,52 t l a:b = 0,73