You are on page 1of 1

Fb: Cng Hin / 0983564815

1 CCH GII CHO BI TON PEPTIT TRONG MINH HA CA BGD


Cu 43. un nng 0,16 mol hn hp E gm hai peptit X (C xHyOzN6) v Y (CnHmO6Nt) cn dng 600 ml dung
dch NaOH 1,5M ch thu c dung dch cha a mol mui ca glyxin v b mol mui ca alanin. Mt khc t
chy 30,73 gam E trong O2 va thu c hn hp CO2, H2O v N2, trong tng khi lng ca CO2 v
nc l 69,31 gam. Gi tr a : b gn nht vi
A. 0,730.
B. 0,810.
C. 0,756.
D. 0,962.

- X v Y u to t Gly v Ala nn z = 7 v t =5.


- Gi c, d l mol ca X, Y ta c: c + d = 0,16.
- Khi cho E tc dng vi NaOH th
X + 6NaOH Mui Gly (C2H4O2NNa) + H2O
Y + 5NaOH Mui Ala (C3H6O2NNa) + H2O
nNaOH = 6c + 5d = 0,9
c = 0,1 v d = 0,06.
* Khi CHT 30,73 gam E CO2 + H2O.
Gi mol ca X v Y tng ng l 10x v 6x, mol CO2 v H2O l y v z.
V X = 6+6.(-0,5) = 3 (X: hexapeptit nn c 6 nhm CO (6) v 6 nguyn t N, mi N c -0,5)
V Y = 5+5.(-0,5) = 2,5 (Y: pentapeptit, c 5 nhm CO (5) v 5 nguyn t N, mi N c -0,5)
- Khi t X: CO2 - H2O = (X - 1).10x = 20x
- Khi t Y: CO2 - H2O = (Y - 1).6x = 9x
y - z = 20x + 9x = 29x (1)
- Ngoi ra: 44y + 18z = 69,31 (2)
- Lng E em t:
mE = mO + mN + mC + mH = (16.7 + 14.6).10x + (16.6 + 14.5).6x + 12y + 2z = 30,73 (3)
Gii h (1), (2), (3) ta c: x = 0,005; y = 1,16 v z = 1,015.
* Trong 30,73 gam E c nX = 0,05 v nY = 0,03 nE = 0,08
Khi nE = 0,16 mE = 61,46 gam.
BTKL kl mui = 61,46 + 0,9.40 - 0,16.18 = 94,58 gam.
97a + 111b = 94,58 v a + b = 0,9 a = 0,38 v b = 0,52 t l a:b = 0,73

You might also like