Dap An Thong Ke 007-2014 - Du Doan de Thi - H 2015

Thng k H 2007-2014
[D ON THI THPT QUC GIA NM 2015 MN HA HC]
LI NI U
Cu chuyn
Mt ln, Anhxtanh c mt phng vin hi: Nu ngi c 60 pht gii quyt mt vn ,
ngi s lm nh th no? Anhxtanh p: Ti s dnh 55 pht TM CU HI NG, cn 5
pht cn li vn s c gii quyt!
Sau y mi cc bn c cc CU HI NG!
Ti sao bn chn cun sch ny?
Cc C c dy Bit mnh bit ta trm trn trm thng. Bit mnh l th no? Bn bit
im mnh , im yu ca bn thn v mn Ha. Nhng ni dung no d, ni dung no kh?
Mc tiu ca bn l bao nhiu im cho mn Ha?
Ta y l cu trc thi, cc dng bi thi, ni dung kin thc c bn cn hc. Bn lm
cc thi ca cc nm trc hay cha? Bn tng thi th tri nghim khng kh ca cuc
thi cha?
Nu cu tr li l cha hoc cha ch ng th ti chc mng bn chn ng cha kha ri!
Kinh nghim ca ti khi hc l lun xem cc cc nm thi v lm li n nh mnh i thi
xem i phng ca mnh nh th no c cch i ph ph hp!
Ti sao cun sch ny c ta l D ON thi THPT Quc Gia nm 2015
Khi ti nghin cu cc thi ca cc nm trc theo dng chuyn th ti nhn thy mt
iu v cng th v v hp l l thi c s lp li tng, kiu ra , kiu t cu hi
cng nh cc kin thc. Cc nm gn y thi LP LI khong 50% tng ca cc nm
trc do cc nguyn nhn sau:
1. Kin thc khng thay i v sch gio khoa khng thay i.
2. Kin thc ph thng th phi phn ln mi ngi hiu v lm bi c. Nguyn tc ra
l xut pht t cc phn ng trong sch gio khoa v thm cc cng thc tnh ton,
giu mt yu t no i v cho bit mt s d kin tm ra. Cc cng thc th cng
rt t v khng thay i.
3. Cc k nng, cc phng php t duy t thay i.
4. Hc sinh mi nm l khc nhau (c mt lng nh thi li nhng khng nh hng).
iu ny c ngha l hc sinh gn nh mi v kim tra nhng kin thc c nn cn
c s lp li.
5. Kh nhiu kin thc kh, nhy cm khng c a vo k thi do yu cu gim ti ca
chng trnh. iu ny lm cho vic thi c tr nn n gin hn v do kin thc t
i nn buc phi lp li.
Cc cu d on l vo thi THPT Quc Gia nm 2015 c bi mu xanh
Mt s v d minh ha:
Cu 1. (B-07) 6: Trong cc dd: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u
t/d c vi dd Ba(HCO3)2 l:
ledangkhuong@gmail.com| T: 0985.131.193 1
Thng k H 2007-2014
A. HNO3, NaCl, Na2SO4.

B. HNO3, Ca(OH) 2, KHSO4, Na2SO4.
C. NaCl, Na2SO4, Ca(OH)2.
D. HNO3, Ca(OH) 2, KHSO4, Mg(NO3)2.
Cu 2. (A-13) 37: Dy cc cht u tc dng c vi dung dch Ba(HCO3)2 l:
A. HNO3, NaCl v Na2SO4.
B. HNO3, Ca(OH)2 v KNO3.
C. NaCl, Na2SO4 v Ca(OH)2.
D. HNO3, Ca(OH)2 v Na2SO4.
Cu 1. C-07) 3: SO2 lun th hin tnh kh trong cc p vi
A. H2S, O2, nc Br2.
B. dd NaOH, O2, dd KMnO4.
C. dd KOH, CaO, nc Br2.
D. O2, nc Br2, dd KMnO4.
Cu 2. (A-12) 34: Dy cht no sau y u th hin tnh oxi ha khi phn ng vi SO2?
A. Dung dch BaCl2, CaO, nc brom.
B. Dung dch NaOH, O2, dung dch KMnO4.
C. O2, nc brom, dung dch KMnO4.
D. H2S, O2, nc brom.
Cu 1. (B-08) 41: Cho 0,1 mol P2O5 vo dd cha 0,35 mol KOH. Dd thu c c cc cht:
A. K3PO4, K2HPO4.
B. K2HPO4, KH2PO4.
C. K3PO4, KOH.
D. H3PO4, KH2PO4.
Cu 2. (C-12) 49: Cho 1,42 gam P2O5 tc dng hon ton vi 50 ml dung dch KOH 1M, thu c
dung dch X. C cn dung dch X thu c cht rn khan gm
A. K3PO4 v KOH.
B. K2HPO4 v K3PO4.
C. KH2PO4 v K2HPO4.
D. H3PO4 v KH2PO4.
Cu 1. (A-08) 48: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l
A. 2.
B. 3.
C. 1.
D. 4.
Cu 2. (C-09) 54: Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2;
CH3CH=CH2; CH3CH=CHCOOH. S cht c ng phn hnh hc l
A. 4.
B. 3
C. 2.
D. 1.
Cu 1. (C-09) 12: Hh kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu
c hh kh Y c t khi so vi He l 5. Hiu sut ca p hiro ho l
A. 20%.
B. 25%.
C. 50%.
D. 40%.
Cu 2. (A-12) 49: Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng,
thu c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ho l
A. 70%.
B. 80%.
C. 60%.
D. 50%.
Cu 1. (A-09) 37: Cho 0,25 mol mt anehit mch h X p vi lng d dd AgNO3 trong NH3, thu c
54g Ag. Mt khc, khi cho X p vi H2 d (xc tc Ni, to) th 0,125 mol X p ht vi 0,25 mol H2. Cht X c
cng thc ng vi CT chung l
A. CnH2n(CHO)2 (n 0). B. CnH2n+1CHO (n 0). C. CnH2n-1CHO (n 2). D. CnH2n-3CHO (n 2).
Cu 2. (B-12) 31: Cho 0,125 mol anehit mch h X phn ng vi lng d dung dch AgNO3
trong NH3 thu c 27 gam Ag. Mt khc, hiro ho hon ton 0,25 mol X cn va 0,5 mol H2.
Dy ng ng ca X c cng thc chung l
A. CnH2n(CHO)2 (n 0).
B. CnH2n-3CHO (n 2).
C. CnH2n+1CHO (n 0).
D. CnH2n-1CHO (n 2).
Cu 1. (B-09) 14: Cho 0,02 mol amino axit X t/d va vi 200 ml dd HCl 0,1M thu c 3,67 gam
mui khan. Mt khc 0,02 mol X t/d va vi 40 gam dd NaOH 4%. Cng thc ca X l
A. H2NC2H3(COOH)2.
B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH.
Cu 2. (C-13) 40: Cho 100 ml dung dch amino axit X nng 0,2M phn ng va vi 80 ml
dung dch NaOH 0,25M, thu c dung dch Y. Bit Y phn ng ti a vi 120 ml dung dch HCl
0,5M, thu c dung dch cha 4,71 gam hn hp mui. Cng thc ca X l
A. H2NC3H5(COOH)2.
B. (H2N)2C2H3COOH.
C. (H2N)2C3H5COOH.
D. H2NC3H6COOH.
Cu 1. (B-08) 25: Th tch dd HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng t/d vi
xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %)
A. 55 lt.
B. 81 lt.
C. 49 lt.
D. 70 lt.
Cu 2. (B-12) 44: iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt
axit nitric 94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l
A. 60.
B. 24.
C. 36.
D. 40.
Cu 1. (A-08) 8: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l:
Thng k H 2007-2014
A. CH3CHO, C2H5OH, C2H6, CH3COOH.

B. CH3COOH, C2H6, CH3CHO, C2H5OH.
C. C2H6, C2H5OH, CH3CHO, CH3COOH.
D. C2H6, CH3CHO, C2H5OH, CH3COOH
Cu 2. (B-09) 32: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi
l:
A. CH3COOH, C2H5OH, HCOOH, CH3CHO.
B. CH3CHO, C2H5OH, HCOOH, CH3COOH.
C. CH3COOH, HCOOH, C2H5OH, CH3CHO.
D. HCOOH, CH3COOH, C2H5OH, CH3CHO
Cn v s kiu bi tng t na trong cun sch ny, hy cho mnh c c hi khm ph

no!
Li ch m bn thu c t cun sch ny l g?
1. Nu bn l hc sinh
a. Bn c mt h thng kin thc m bn cn phi hc v hiu su sc cng nh
cc cch t duy, cch lm bi m bn cn luyn tp trc khi vo phng thi.
b. Bn hiu c thi cng khng qu kh nh bn ngh v nu bn lm c
hoc lp li nhng bi t MU n mc nhn vo bn c th cm my tnh bm
hoc ni ngay th bn hon ton c th yn tm v im s ca mnh.
2. Nu bn l gio vin
i.
Bn c mt h thng cu hi tha h m i dy v bn cng nhn ra rng h
thng bi tp y l qu . Bn ch cn cho hc sinh nm chc kin thc
trong y l bn qu gii ri. Vi vic u t ch 50.000 thay v ngi copy,
chnh sa ti liu hng tun.
ii.
Bn hiu c cch ra mt thi v cc ni dung trng tm cn dy cho hc
sinh. iu ny s gip bn nhanh chng ng vng trn bc ging vi kin
thc v k nng y mnh. Hc sinh ca bn s t nhiu hn l iu chc
chn. C hnh phc no hn ca mt gio vin khi thy hc sinh ca mnh
t phi khng bn?
3. Nu bn l sinh vin s phm
a. Bn c ti liu v cng quan trng c th i gia s cho hc sinh ca bn. Bn
c mt h thng y v v cng hiu qu tp lm gio vin m nhng
gio vin nhiu kinh nghim mi c c.
b. Bn hiu c mt cng vic ca gio vin l phi ra thi. V bn tha sc
sng to ra mt tng t ng khng no? Bn mau chng c mt k nng
ca mt gio vin gii. Khi bn i thc tp hay khi xin vic cng d dng hn
hn do chuyn mn ca bn rt cng.
Ai nn mua cun sch ny?
1. Hc sinh (ng nhin ri!)
2. Gio vin (V cng hp l!)
3. Sinh vin (Khng cn nghi ng g na!)
4. Bn b, ngi thn ca hc sinh (Mua lm qu, qu tuyt vi!)
Ti sao bn lm nhiu im vn km?
n gin l bn cha hiu SU v cha to c LIN KT gia cc kin thc cng
nh bn cha LP s ln ln nn cha c k nng, k so. V iu cng khin cho bn
nh km hn m trong thi i hc th vic nh nhiu kin thc l mt li th rt ln.
Thng k H 2007-2014
Ti sao cc Thy khng lm tt c cc bi nhng c th lm bt c bi no trong

chng trnh ph thng?
n gin l cc Thy nm chc kin thc ct li v cch t duy ch khng phi lm tt
c cc bi tp. Mt li th l cc Thy LP LI kin thc qua nhiu nm nn hiu SU SC
nn vic sng to ra cn n gin ni chi n lm bi.
Mt l do na l cc Thy c mt tm th ch ng khi lm bi tp ch khng b ng nh
hc sinh. iu ny lm cho cch t duy mch lc v sng sut hn.
Lm th no hc tt vi b kp ny?
1. Hy c k l thuyt lin quan. Nn s dng mindmap vit cho n
gin, d hiu v d nh.
2. Lm cc bi tp i km. p n cc em c th lin h qua gmail/face:
ledangkhuong@gmail.com v nu khng bit cch gii th ln google.com
l c y , chi tit.
3. Tp trung lm nhng bi c MU XANH, l nhng bi cha kha. Lm
c nhng bi ny ngha l cc bi khc bn c th lm c.
4. Lp li cho n khi hiu su sc, bm nhanh khong 30 giy/ cu. L
thuyt ni nhanh khong 30 giy/ cu l t.
5. Lun bnh tnh, ht th su khi lm bi.
6. Trao i vi bn b, thy c hiu su v nh, lin kt cc kin thc.
Hc t bn b rt hiu qu, hy copy t nhng ngi gii
7. Lm thm b Luyn 10 thi th i hc t trn 8 im
8. Lun c mt cun s ghi ch nhng li ca mnh v lun xem li n mi
khi lm bi tp
9. c phn ph lc pha sau sch. N v cng hu ch!
10. Lun nhn v mc tiu, c m ca bn thn.
V mt ln na ti chc mng bn s hu B kp tuyt vi ny!

Chc bn thnh cng!
Thn i!
ThS. L ng Khng
ThS. Trn Trng Tuyn
Thng k H 2007-2014
MC LC
Phn 1: V C .............................................................................................................................. 8
1. Nguyn t, bng tun hon cc nguyn t ho hc, lin kt ho hc ..................................... 8
1.1. Bi ton v ht c bn, cu hnh electron ......................................................................... 8
1.2. V tr nguyn t trong bng tun hon, nh lut tun hon ............................................. 8
1.3. Bi ton oxit, hp cht vi Hiro, ng v .................................................................. 10
1.4. Lin kt ha hc, cu trc mng tinh th ....................................................................... 10
2. PHN NG OXI HA KH,.............................................................................................. 12
TC PHN NG V CN BNG HA HC ............................................................... 12
2.1. Phn ng oxi ha kh, cht oxi ha, cht kh ............................................................ 12
2.2. Cn bng phn ng oxi ha kh .................................................................................. 14
2.3. Tc phn ng ............................................................................................................. 15
2.4. Chuyn dch cn bng ha hc ....................................................................................... 16
3. S IN LY- pH DUNG DCH .......................................................................................... 18
3.1. Cht in ly, axit, ba z, lng tnh ............................................................................... 18
3.2. Phn ng ion trong dung dch ........................................................................................ 18
3.3. Bi ton pH ..................................................................................................................... 20
3.4. Tnh theo phng trnh ion, nh lut bo ton in tch ............................................... 20
4. PHI KIM ................................................................................................................................ 23
4.1. OXI LU HUNH ..................................................................................................... 23
4.2. HALOGEN ..................................................................................................................... 24
4.3. NIT PHOTPHO ........................................................................................................ 26
4.4. CACBON - SILIC ......................................................................................................... 28
5. I CNG V KIM LOI ............................................................................................... 30
5. 1. Dy in ha ca kim loi ............................................................................................. 30
5.2. PHN NG C TRNG CA KIM LOI .............................................................. 31
5.3. iu ch kim loi ........................................................................................................... 32
5.4. Bi ton kh cc oxit kim loi bng kh CO, H2 ........................................................... 33
5.5. Bi ton kim loi tc dng vi phi kim .......................................................................... 33
5.6. in phn ....................................................................................................................... 34
5.7. n mn kim loi ............................................................................................................. 36
5.8. Bi ton kim loi tc dng vi dd mui ......................................................................... 37
5.9. Bi ton kim loi tc dng vi dd axit ........................................................................... 39
5.10. Mg, Al, Zn tc dng vi HNO3 to mui NH4NO3 .................................................... 40
6. KIM LOI KIM, KIM TH ............................................................................................ 41
6.1 L THUYT ................................................................................................................... 41
6.2. KIM LOI KIM, KIM TH tc dng vi AXIT, tm kim loi ............................... 42
Thng k H 2007-2014
6.3. KIM LOI KIM tc dng vi H2O ................................................................................ 43

6.4. BI TON CO2 tc dng vi DUNG DCH KIM ...................................................... 43
6.5. DUNG DCH AXIT tc dng vi MUI CACBONAT............................................... 44
7. NHM V HP CHT ....................................................................................................... 46
7.1. Nhm, nhm oxit tc dng vi dung dch kim, axit ..................................................... 46
7.2. Bi ton Al3+, Zn2+ tc dng vi dung dch kim .......................................................... 47
8. ST V HP CHT ............................................................................................................ 49
8.1. St tc dng vi axit ....................................................................................................... 49
8.2. Oxit st tc dng vi axit .............................................................................................. 50
8.3. Phn ng NHIT NHM............................................................................................... 51
8.4. Hp cht cha S ca Fe .................................................................................................. 52
8.5. GANG THP ................................................................................................................. 53
9. Crom, ng, niken, ch, km, bc, vng, thic ...................................................................... 54
10. TNG HP KIN THC .................................................................................................. 57
10.1. L thuyt..................................................................................................................... 57
10.2. OXIT TC DNG VI AXIT .................................................................................. 63
10.3. Bi ton 3 Cu + 8H+ +2NO3- 3Cu2+ +2NO + 4H2O ............................................... 63
10.4. Fe2+ tc dng vi Ag+ .................................................................................................. 64
10.5. Fe tc dng vi axit HNO3 v H2SO4 c nng m cn d kim loi .......................... 65
10.6. Bi ton lin quan n KMnO4 ................................................................................... 65
10.7. Cc dng khc ............................................................................................................. 66
Phn 2: HU C......................................................................................................................... 67
11. I CNG HU C V HIDROCACBON ................................................................. 67
11.1. ng phn, danh php .................................................................................................. 67
11.2. ANKAN........................................................................................................................ 68
11.3. ANKEN ........................................................................................................................ 69
11.4. ANKIN, ANKAIEN, TECPEN ................................................................................. 70
11.5. HN HP HIROCACBON ...................................................................................... 70
11.6. Hn hp hidrocacbon vi H2 ........................................................................................ 72
12. DN XUT HALOGEN, ANCOL, PHENOL .................................................................. 73
12.1. Dn xut halogen ......................................................................................................... 73
12.2. PHENOL ..................................................................................................................... 74
12.3. ANCOL ........................................................................................................................ 75
13. AN HIT, XETON, AXIT CACBONXYLIC ................................................................. 79
13.1. ANHIT ................................................................................................................... 79
13.2. XETON ........................................................................................................................ 82
13.3. AXIT CACBOXYLIC ................................................................................................. 82
Thng k H 2007-2014
14. ESTE, LIPIT ........................................................................................................................ 86

14.1. ng phn, danh php ................................................................................................. 86
14.2. Phn ng thy phn trong mi trng kim (x phng ha) ....................................... 87
14.3. Phn ng t chy ........................................................................................................ 89
14.4. CHT BO .................................................................................................................. 90
14.7. Hn hp este vi axit, ancol ......................................................................................... 91
15. AMIN, AMINOAXIT, PEPTIT, PROTEIN ....................................................................... 93
15.1. AMIN .......................................................................................................................... 93
15.2. AMINOAXIT ............................................................................................................... 94
15.3. PEPTIT, protein............................................................................................................ 97
15.5. CC DNG HP CHT KHC CHA NIT ................................................................ 99
16. CACBOHIRAT .............................................................................................................. 100
16.1. L THUYT ............................................................................................................. 100
16.2. S phn ng ........................................................................................................... 102
16.3. PHN NG thy phn, TRNG BC ..................................................................... 102
16.4. Phn ng ln men tinh bt .......................................................................................... 103
16.5. Phn ng iu ch Xenluloz trinitrat ................................................................... 104
17. Polime v vt liu polime .................................................................................................. 105
18. TNG HP HU C ...................................................................................................... 107
18.1. Phn ng trng bc .................................................................................................... 107
18.2. Tc dng vi dung dch Cu(OH)2 ............................................................................. 107
18.3. Tc dng vi dung dch Br2 ....................................................................................... 107
18.4. Tc dng vi H2......................................................................................................... 108
18.5. Tc dng vi dung dch NaOH .................................................................................. 108
18.6. linh ng ca H, lc axit, nhit si, nhit nng chy, tan ..................... 109
18.7. iu ch ...................................................................................................................... 110
18.8. Nhn bit .................................................................................................................... 110
18.9. S phn ng .......................................................................................................... 111
18.10. Cc dng cu hi l thuyt tng hp ....................................................................... 114
18.11. Tnh ton tng hp ................................................................................................... 115
D B I HC NM 2009 ......................................................................................... 118
MT S CNG THC S DNG TRONG GII TON HA HC ......................... 122
TNH TAN CA MUI V BAZ .................................................................................... 122
KHI LNG MOL NGUYN T V PHN T ........................................................ 123
DANH PHP THNG THNG ...................................................................................... 124
NHN BIT CC CHT .................................................................................................... 125
Thng k H 2007-2014
Phn 1: V c
1. Nguyn t, bng tun hon cc nguyn t ho hc,
lin kt ho hc
1.1. Bi ton v ht c bn, cu hnh electron
Cu 1. (A-10) 32: Nhn nh no sau y ng khi ni v 3 nguyn t: 13 X, 26Y, 12 Z ?

A. X v Z c cng s khi.
B. X, Z l 2 ng v ca cng mt nguyn t ho hc.
C. X, Y thuc cng mt nguyn t ho hc.
D. X v Y c cng s ntron.
Cu 2. (A-07): Dy gm cc ion X+, Y- v nguyn t Z u c cu hnh electron 1s22s22p6 l:
A. Li+, F-, Ne.
B. K+,, Cl-, Ar.
C. Na+, Cl-, Ar.
D. Na+, F-, Ne.
Cu 3. (B-10) 12: Mt ion M3+ c tng s ht proton, ntron, electron l 79, trong s ht mang
in nhiu hn s ht khng mang in l 19. Cu hnh electron ca nguyn t M l
A. [Ar]3d54s1.
B. [Ar]3d64s2.
C. [Ar]3d64s1.
D. [Ar]3d34s2.
26
55
26
Cu 4. (A-11) 42: Cu hnh electron ca ion Cu2+ v Cr3+ ln lt l

A. [Ar]3d9 v [Ar]3d14s2.
B. [Ar]3d74s2 v [Ar]3d3.
9
3
C. [Ar]3d v [Ar]3d .
D. [Ar]3d74s2 v [Ar] 3d14s2.
Cu 5. (A-12) 11: Nguyn t R to c cation R+. Cu hnh electron phn lp ngoi cng ca R+
( trng thi c bn) l 2p6. Tng s ht mang in trong nguyn t R l
A. 10.
B. 11.
C. 22.
D. 23.
Cu 6. (A-13) 11: trng thi c bn, cu hnh electron ca nguyn t Na (Z = 11) l
A. 1s22s22p63s2.
B. 1s22s22p53s2.
C. 1s22s22p43s1.
D. 1s22s22p63s1.
Cu 7. (B-14): Ion X2+ c cu hnh electron trng thi c bn 1s 2 2s 2 2p6 . Nguyn t X l
A. Ne (Z = 10)
B. Mg (Z = 12)
C. Na (Z = 11)
D. O (Z = 8)
Cu 8. (B-13) 32: S proton v s ntron c trong mt nguyn t nhm ( 27Al13 ) ln lt l
A. 13 v 14.
B. 13 v 15.
C. 12 v 14.
D. 13 v 13.
Cu 9. (A-14) 9: Cu hnh electron trng thi c bn ca nguyn t nguyn t X c tng s
electron trong cc phn lp p l 8. Nguyn t X l
A. O (Z=8)
B. Cl (Z=17)
C. Al (Z=13)
D. Si (Z=14)
Cu 10. (C-13) 25: trng thi c bn, nguyn t ca nguyn t X c 4 electron lp L (lp
th hai). S proton c trong nguyn t X l
A. 7.
B. 6.
C. 8.
D. 5.
1.2. V tr nguyn t trong bng tun hon, nh lut tun hon

Cu 11. (A-07) : Anion X- v cation Y2+ u c cu hnh electron lp ngoi cng l 3s23p6. V tr ca
cc nguyn t trong bng tun hon cc nguyn t ha hc l:
A. X c s th t 17, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4,
nhm IIA (phn nhm chnh nhm II).
B. X c s th t 17, chu k 4, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4,
C. X c s th t 18, chu k 3, nhm VIA (phn nhm chnh nhm VI); Y c s th t 20, chu k 4, nhm
IIA (phn nhm chnh nhm II).
D. X c s th t 18, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 3,
Cu 12. (A-09) 36: Cu hnh electron ca ion X3+ l 1s22s22p63s23p63d6. Trong bng tun hon cc
nguyn t ho hc, nguyn t X thuc
A. chu k 4, nhm VIIIA.
B. chu k 4, nhm IIA.
C. chu k 3, nhm VIB.
D. chu k 4,
nhm VIIIB.
Thng k H 2007-2014
Cu 13. (C -14): 26 Cation R+ c cu hnh electron 1s22s22p63s23p6. V tr ca nguyn t R trong

bng tun hon cc nguyn t ha hc l
A. chu k 3, nhm VIIIA
B. chu k 4, nhm IIA
C. chu k 3, nhm VIIA
D. chu k 4, nhm IA
Cu 14. (C-12) 14: Nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52.
Trong ht nhn nguyn t X c s ht khng mang in nhiu hn s ht mang in l 1. V tr (chu
k, nhm) ca X trong bng tun hon cc nguyn t ha hc l
A. chu k 3, nhm VA.
B. chu k 3, nhm VIIA.
C. chu k 2, nhm VIIA.
D. chu k 2, nhm VA.
Cu 15. (C-09) 15: Cc kim loi X, Y, Z c cu hnh electron nguyn t ln lt l: 1s22s22p6 3s1;
1s22s22p63s2; 1s22s22p63s23p1. Dy gm cc kim loi xp theo chiu tng dn tnh kh t tri sang
phi l:
A. Z, Y, X.
B. X, Y, Z.
C. Y, Z, X.
D. Z, X, Y.
Cu 16. (C-09) 11: Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn
t c a nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng.
Nguyn t X v Y c s electron hn km nhau l 2. Nguyn t X, Y ln lt l
A. kim loi v kim loi. B. phi kim v kim loi. C. kim loi v kh him.
D. kh him v kim loi
Cu 17. (A-12) 19: X v Y l hai nguyn t thuc cng mt chu k, hai nhm A lin tip. S proton ca
nguyn t Y nhiu hn s proton ca nguyn t X. Tng s ht proton trong nguyn t X v Y l 33.
Nhn xt no sau y v X, Y l ng?
A. n cht X l cht kh iu kin thng.
B. m in ca X ln hn m in ca Y.
C. Lp ngoi cng ca nguyn t Y ( trng thi c bn) c 5 electron.
D. Phn lp ngoi cng ca nguyn t X ( trng thi c bn) c 4 electron.
Cu 18. (C-07) 16: Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca
cc nguyn t tng dn theo th t
A. M < X < Y < R.
B. R < M < X < Y.
C. Y < M < X < R.
D. M < X < R < Y.
Cu 19. (B-07): Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII),
theo chiu tng ca in tch ht nhn nguyn t th
A. tnh phi kim gim dn, bn knh nguyn t tng dn.
B. tnh kim loi tng dn, m in tng dn.
C. m in gim dn, tnh phi kim tng dn.
D. tnh kim loi tng dn, bn knh nguyn t gim dn
Cu 20. (B-09) 3: Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy gm cc
nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l:
A. N, Si, Mg, K.
B. K, Mg, Si, N.
C. K, Mg, N, Si.
D. Mg, K, Si, N.
Cu 21. (A-08) 35:Bn knh nguyn t ca cc nguyn t: 3Li, 8O, 9F, 11Na c xp theo th t tng
dn t tri sang phi l
A. F, O, Li, Na.
B. F, Na, O, Li.
C. F, Li, O, Na.
D. Li, Na, O, F.
Cu 22. (B-08)2: Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l:
A. P, N, F, O.
B. N, P, F, O.
C. P, N, O, F.
D. N, P, O, F.
Cu 23. (A-10) 35: Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th
A. bn knh nguyn t tng, m in gim. B. bn knh nguyn t v m in u tng.
C. bn knh nguyn t gim, m in tng. D. bn knh nguyn t v m in u gim.
Cu 24. (B-14): Hai nguyn t X v Y cng mt chu k trong bng tun hon cc nguyn t ha hc, X
thuc nhm IIA, Y thuc nhm IIIA ( ZX ZY 51 ). Pht biu no sau y ng?
A. Kim loi X khng kh c ion Cu 2 trong dung dch
B. Hp cht vi oxi ca X c dng X 2 O7
C. Trong nguyn t nguyn t X c 25 proton
D. nhit thng X khng kh c H 2 O
Cu 25. (B-12) 14: Pht biu no sau y l sai?
A. Nguyn t kim loi thng c 1, 2 hoc 3 electron lp ngoi cng.
B. Cc nhm A bao gm cc nguyn t s v nguyn t p.
C. Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim.
D. Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c.
Thng k H 2007-2014
1.3. Bi ton oxit, hp cht vi Hiro, ng v

Cu 26. (B-08) 36: Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong
oxit m R c ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l
A. S.
B. As.
C. N.
D. P.
Cu 27. (A-09) 12: Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns2np4. Trong
hp cht kh ca nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm khi lng ca
nguyn t X trong oxit cao nht l
A. 50,00%.
B. 27,27%.
C. 60,00%.
D. 40,00%.
Cu 28. (A-12) 18: Phn trm khi lng ca nguyn t R trong hp cht kh vi hiro (R c s oxi
ha thp nht) v trong oxit cao nht tng ng l a% v b%, vi a : b = 11 : 4. Pht biu no sau y
l ng?
A. Phn t oxit cao nht ca R khng c cc.
B. Oxit cao nht ca R iu kin thng l cht rn.
C. Trong bng tun hon cc nguyn t ha hc, R thuc chu k 3.
D. Nguyn t R ( trng thi c bn) c 6 electron s.
Cu 29. (B-12) 20: Nguyn t Y l phi kim thuc chu k 3, c cng thc oxit cao nht l YO3. Nguyn
t Y to vi kim loi M hp cht c cng thc MY, trong M chim 63,64% v khi lng. Kim loi M
l
A. Zn.
B. Cu.
C. Mg.
D. Fe.
Cu 30. (C-07) 24: Trong t nhin, nguyn t ng c hai ng v l 6329 Cu v 2965 Cu. Nguyn t
khi trung bnh ca ng l 63,54. Thnh phn phn trm tng s nguyn t ca ng v 6329 Cu l
A. 27%.
B. 50%.
C. 54%.
D. 73%.
Cu 31. (B-11) 1: Trong t nhin clo c hai ng v bn: 3717 Cl chim 24,23% s nguyn t, cn li
l 3517 Cl. Thnh phn % theo khi lng ca 3717 Cl trong HClO4 l
A. 8,43%.
B. 8,79%.
C. 8,92%.
D. 8,56%.
1.4. Lin kt ha hc, cu trc mng tinh th

Cu 32. (B-07): Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s
electron ca anion v tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi
ha duy nht. Cng thc XY l
A. AlN.
B. MgO.
C. LiF.
D. NaF.
Cu 33. (C -14) 32: Cht no sau y l hp cht ion?
A. SO2
B. K2O
C. CO2
D. HCl
Cu 34. (A-08) 31: Hp cht trong phn t c lin kt ion l
A. NH4Cl.
B. NH3.
C. HCl.
D. H2O.
Cu 35. (A-11) 12: Khi so snh NH3 vi NH4+, pht biu khng ng l:
A. Phn t NH3 v ion NH4+u cha lin kt cng ha tr.
B. Trong NH3 v NH4+, nit u c s oxi ha 3.
C. NH3 c tnh baz, NH4+ c tnh axit.
D. Trong NH3 v NH4+, nit u c cng ha tr 3.
Cu 36. (B-10) 11: Cc cht m phn t khng phn cc l:
A. HBr, CO2, CH4.
B. Cl2, CO2, C2H2.
C. NH3, Br2, C2H4.
D. HCl, C2H2, Br2.
Cu 37. (A-13) 32: Lin kt ha hc gia cc nguyn t trong phn t HCl thuc loi lin kt
A. hiro.
B. cng ha tr khng cc.
C. cng ha tr c cc.
D. ion.
Cu 38. (C-08) 26: Nguyn t ca nguyn t X c cu hnh electron 1s22s22p63s23p64s1, nguyn t
ca nguyn t Y c cu hnh electron 1s22s22p5. Lin kt ho hc gia nguyn t X v nguyn t Y
thuc loi lin kt
A. kim loi.
B. cng ho tr.
C. ion.
D. cho nhn.
Cu 39. (C-09) 13: Dy gm cc cht trong phn t ch c lin kt cng ho tr phn cc l:
A. O2, H2O, NH3.
B. H2O, HF, H2S. C. HCl, O3, H2S.
D. HF, Cl2, H2O.
Thng k H 2007-2014
Cu 40. (C-12) 20: Cho dy cc cht: N2, H2, NH3, NaCl, HCl, H2O. S cht trong dy m phn t ch
cha lin kt cng ha tr khng cc l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 41. (A-14) 2: Lin kt ha hc gia cc nguyn t trong phn t NH3 l lin kt
A. cng ha tr khng cc
B. Hiro
C. ion
D. cng ha tr phn cc
Cu 42. (C-10) 26: Lin kt ho hc gia cc nguyn t trong phn t H2O l lin kt
A. ion.
B. cng ho tr phn cc.
C. hiro.
D. cng ho tr khng phn
cc.
Cu 43. (C-13) 21: Lin kt ha hc trong phn t Br2 thuc loi lin kt
A. ion.
B. hiro.
C. cng ha tr khng cc.
D. cng ha tr c cc.
Cu 44. (B-13) 13: Cho gi tr m in ca cc nguyn t: F (3,98); O (3,44); C (2,55); H (2,20);
Na (0,93). Hp cht no sau y l hp cht ion?
A. NaF.
B. CO2.
C. CH4.
D. H2O.
Cu 45. (C-10) 36: Dy gm cc kim loi c cu to mng tinh th lp phng tm khi l:
A. Be, Mg, Ca.
B. Li, Na, K.
C. Na, K, Mg.
D. Li, Na, Ca.
Cu 46. (C-11) 29: Dy gm cc kim loi u c cu to mng tinh th lp phng tm khi l:
A. Na, K, Ca, Ba.
B. Na, K, Ca, Be.
C. Li, Na, K, Mg.
D. Li, Na, K, Rb.
Cu 47. (B-11) 7: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l:
A. Na, K, Ca.
B. Na, K, Ba.
C. Li, Na, Mg.
D. Mg, Ca, Ba.
Cu 48. (B-09) 33: Pht biu no sau y l ng?
A. Photpho trng c cu trc tinh th nguyn t. B. th rn, NaCl tn ti di dng tinh th phn t.
C. Nc thuc loi tinh th phn t.
D. Kim cng c cu trc tinh th phn t.
Cu 49. (C-11) 27: Trong bng tun hon cc nguyn t ho hc, nguyn t X nhm IIA,
nguyn t Y nhm VA. Cng thc ca hp cht to thnh t 2 nguyn t trn c dng l
A. X2Y3.
B. X2Y5.
C. X3Y2.
D. X5Y2.
3
Cu 50. (A-11) 36:Khi lng ring ca canxi kim loi l 1,55 g/cm . Gi thit rng, trong tinh th
canxi cc nguyn t l nhng hnh cu chim 74% th tch tinh th, phn cn li l khe rng. Bn
knh nguyn t canxi tnh theo l thuyt l
A. 0,185 nm.
B. 0,196 nm.
C. 0,155 nm.
D. 0,168 nm.
A. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht.
B. Tt c cc tinh th phn t u kh nng chy v kh bay hi.
C. Tinh th nc , tinh th iot u thuc loi tinh th phn t.
D. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ho tr.
Thng k H 2007-2014
2. PHN NG OXI HA KH,

TC PHN NG V CN BNG HA HC
2.1. Phn ng oxi ha kh, cht oxi ha, cht kh
Cu 1. (A-07): Cho cc p sau:

a) FeO + HNO3 (c, nng)
b) FeS + H2SO4 (c nng)
c) Al2O3 + HNO3 (c, nng)
d) Cu + dd FeCl3
e) CH3CHO + H2 (Ni, to)
f) glucoz + AgNO3 trong dd NH3
g) C2H4 + Br2
h) glixerol + Cu(OH)2
Dy gm cc p u thuc loi p oxi ho - kh l
A. a, b, c, d, e, h.
B. a, b, d, e, f, g.
C. a, b, d, e, f, h.
D. a, b, c, d, e, g.
Cu 2. (A-14) 16: Phn ng no di y thuc loi phn ng oxi ha - kh ?
A.
2NO2 2NaOH
NaNO3 NaNO2 H2O
B.
NaOH HCl
NaCl H2O
C. CaO CO2
D. AgNO3 HCl
AgCl HNO3
CaCO3
Cu 3. (A-13) 27: Tin hnh cc th nghim sau:
(a) Sc kh etilen vo dung dch KMnO4 long.
(b) Cho hi ancol etylic i qua bt CuO nung nng.
(c) Sc kh etilen vo dung dch Br2 trong CCl4.
(d) Cho dung dch glucoz vo dung dch AgNO3 trong NH3 d, un nng.
(e) Cho Fe2O3 vo dung dch H2SO4 c, nng.
Trong cc th nghim trn, s th nghim c xy ra phn ng oxi ha - kh l
A. 5.
B. 2.
C. 4.
D. 3.
Cu 4. (B-14) Anehit axetic th hin tnh oxi ha trong phn ng no sau y?
Ni ,t
A. CH3CHO H2
CH3CH 2OH
0
t
B. 2CH3CHO 5O2
4CO2 4H2O
0
C. CH3CHO Br2 H 2O
CH3COOH 2HBr
D. CH3CHO 2AgNO3 3NH3 H 2O
CH3COONH 4 2NH 4 NO3 2Ag
Cu 5. (B-08) 19: Cho cc p:
Ca(OH)2+ Cl2 CaOCl2 + H2O
2H2S + SO2 3S + 2H2O
to
2NO2 + 2NaOH NaNO3 + NaNO2+ H2O
4KClO3
KCl + 3 KClO4
O3 O2 + O
A. 5.
B. 2.
C. 3.
S p oxi ho kh l
Cu 6. (C-13) 46: Cho cc phng trnh phn ng:
(a) 2Fe + 3Cl2 2FeCl3.
(b) NaOH + HCl NaCl + H2O.
D. 4.
(c) Fe3O4 + 4CO 3Fe + 4CO2.

(d) AgNO3 + NaCl AgCl + NaNO3.
Trong cc phn ng trn, s phn ng oxi ha - kh l
A. 2.
B. 1.
C. 3.
D. 4.
Cu 7. (A-07): Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3) 3, FeSO4, Fe2(SO4)
3, FeCO3 ln lt p vi HNO3 c, nng. S p thuc loi p oxi ho - kh l
A. 5.
B. 7.
C. 6.
D. 8.
Cu 8. (A-10) 2: Thc hin cc th nghim sau:
(I) Sc kh SO2 vo dd KMnO4.
(II) Sc kh SO2 vo dd H2S.
(III) Sc hh kh NO2 v O2 vo nc.
(IV) Cho MnO2 vo dd HCl c, nng.
(V) Cho Fe2O3 vo dd H2SO4 c, nng.
(VI) Cho SiO2 vo dd HF.
Thng k H 2007-2014
S th nghim c p oxi ho - kh xy ra l
A. 6.
B. 5.
C. 4.
D. 3.
Cu 9. (A-10) 15: Nung nng tng cp cht sau trong bnh kn: (1) Fe + S (r), (2) Fe 2O3 + CO (k), (3)
Au + O2(k), (4) Cu + Cu(NO3)2 (r), (5) Cu + KNO3 (r), (6) Al + NaCl (r). Cc trng hp xy ra p oxi ho
kim loi l:
A. (1), (3), (6).
B. (2), (5), (6).
C. (2), (3), (4).
D. (1), (4), (5).
Cu 10. (B-10) 25: Cho dd X cha KMnO4 v H2SO4 (long) ln lt vo cc dd: FeCl2, FeSO4, CuSO4,
MgSO4, H2S, HCl (c). S trng hp c xy ra p oxi ho - kh l
A. 3.
B. 5.
C. 4.
D. 6.
Cu 11. (C-08) 24: Cho dy cc cht: FeO, Fe(OH)2, FeSO4, Fe3O4, Fe2(SO4)3, Fe2O3. S cht trong dy
b oxi ha khi t/d vi dd HNO3 c, nng l
A. 3.
B. 5.
C. 4
D. 6.
Cu 12. (B-11) 30: Thc hin cc th nghim vi hn hp bt gm Ag v Cu (hn hp X):
(a) Cho X vo bnh cha mt lng d kh O3 ( iu kin thng).
(b) Cho X vo mt lng d dung dch HNO3 (c).
(c) Cho X vo mt lng d dung dch HCl (khng c mt O2).
(d) Cho X vo mt lng d dung dch FeCl3.
Th nghim m Cu b oxi ho cn Ag khng b oxi ho l
A. (d).
B. (a).
C. (b).
D. (c).
Cu 13. (B-07) 23: Khi cho Cu t/d vi dd cha H2SO4 long v NaNO3, vai tr ca NaNO3 trong p l
A. cht xc tc.
B. cht oxi ho.
C. mi trng.
D. cht kh.
Cu 14. (A-08) 20: Cho cc p sau:
2HCl + Fe FeCl2 + H2.
4HCl + MnO2 MnCl2 + Cl2 + 2H2O.
14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O.
6HCl + 2Al 2AlCl3 + 3H2.
16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O.
S p trong HCl th hin tnh oxi ha l
A. 2.
B. 1.
C. 4.
D. 3
Cu 15. (B-11) 5: Cho cc phn ng:
(a) Sn + HCl (long)
(b) FeS + H2SO4 (long)
(c) MnO2 + HCl (c)
(e) Al + H2SO4 (long)
(d) Cu + H2SO4 (c)
(g) FeSO4 + KMnO4 + H2SO4
to
to
S phn ng m H+ ca axit ng vai tr cht oxi ho l

A. 3.
B. 5.
C. 2.
Cu 16. (C-13) 28: Cho cc phng trnh phn ng sau:
(a) Fe + 2HCl FeCl2 + H2.
(b) Fe3O4 + 4H2SO4 Fe2(SO4)3 + FeSO4 + 4H2O.
D. 6.
(c) 2KMnO4 + 16HCl 2KCl + 2MnCl2 + 5Cl2 + 8H2O.

(d) FeS + H2SO4 FeSO4 + H2S.
(e) 2Al + 3H2SO4 Al2(SO4)3 + 3H2.
Trong cc phn ng trn, s phn ng m ion H+ ng vai tr cht oxi ha l
A. 2.
B. 1.
C. 4.
D. 3.
Cu 17. (B-09) 16: Cho cc p sau:
(b) HCl + NH4HCO3 NH4Cl + CO2 + H2O.
(a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O.
(c) 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O.
(d) 2HCl + Zn ZnCl2 + H2.
S p trong HCl th hin tnh kh l A. 2.
B. 3.
C. 1.
D. 4.
Cu 18. (B-08) 13: Cho dy cc cht v ion: Cl2, F2, SO2, Na+, Ca2+, Fe2+, Al3+, Mn2+, S2-, Cl-. S cht v
ion trong dy u c tnh oxi ho v tnh kh l
A. 3.
B. 4.
C. 6.
D. 5.
Cu 19. (A-09) 26:Cho dy cc cht v ion:Zn, S, FeO, SO2, N2, HCl,Cu2+,Cl-. S cht v ion c c tnh oxi
ha v tnh kh l
A. 7.
B. 5.
C. 4.
D. 6.
Cu 20. (C-09)Trong cc cht: FeCl2, FeCl3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3. S cht c c tnh oxi
ho v tnh kh l
A. 2.
B. 3.
C. 5.
D. 4.
Thng k H 2007-2014
Cu 21. (A-11) 15: Cho dy cc cht v ion: Fe, Cl2, SO2, NO2, C, Al, Mg2+, Na+, Fe2+, Fe3+. S cht v
ion va c tnh oxi ho, va c tnh kh l
A. 8.
B. 5.
C. 4.
D. 6.
Cu 22. (C-12) 36: Cho dy gm cc phn t v ion: Zn, S, FeO, SO2, Fe2+, Cu2+, HCl. Tng s phn t
v ion trong dy va c tnh oxi ha, va c tnh kh l
A. 5.
B. 6.
C. 7.
D. 4.
Cu 23. (C-08) 35: Cho p ha hc: Fe + CuSO4 FeSO4 + Cu.
Trong p trn xy ra
A. s kh Fe2+ v s oxi ha Cu.
C. s oxi ha Fe v s oxi ha Cu.
B. s kh Fe2+ v s kh Cu2+.
D. s oxi ha Fe v s kh Cu2+.
Cu 24. (B-10) 19: Cho p: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH
P ny chng t C6H5-CHO
A. va th hin tnh oxi ho, va th hin tnh kh.
B.ch th hin tnh oxi ho.
C. ch th hin tnh kh.
D. khng th hin tnh kh v tnh oxi
ho.
Cu 25. (B-12) 29: Cho cc cht ring bit sau: FeSO4, AgNO3, Na2SO3, H2S, HI, Fe3O4, Fe2O3 tc
dng vi dung dch H2SO4 c, nng. S trng hp xy ra phn ng oxi ho - kh l
A. 6.
B. 3.
C. 4.
D. 5.
2.2. Cn bng phn ng oxi ha kh

Cu 26. (A-07): Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong PT p gia Cu vi dd
HNO3 c, nng l
A. 10.
B. 8.
C. 9.
D. 11.
Cu 27. 17 (C -14): Cho phng trnh ha hc : a Al + b H2SO4 Al2(SO4)3 + dSO2 + eH2O.
T l a : b l
A. 1 : 2
B. 1 : 3
C. 1 : 1
D.2:3
Cu 28. (B-14) : Cho phn ng: SO2 + 2KMnO4 + H2O K2SO4 + MnSO4 + H2SO4.
Trong phng trnh ha hc ca phn ng trn, khi h s ca KMnO4 l 2 th h s ca SO2 l
A. 5.
B. 6.
C. 4.
D. 7.
Cu 29. (B-07) 4: Trong p t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s
A. nhn 13 electron.
B. nhn 12 electron.
C. nhng 13 electron.
D. nhng 12
electron.
Cu 30. (A-09) 15: Cho PT ho hc: Fe3O4 + HNO3 Fe(NO3) 3 + NxOy + H2O
Sau khi cn bng PT ho hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca
HNO3 l
A. 13x - 9y.
B. 46x - 18y.
C. 45x - 18y.
D. 23x - 9y.
Cu 31. (A-10) 49: Trong p: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O
S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia p. Gi tr ca k l
A. 3/14.
B. 4/7.
C. 1/7.
D. 3/7.
t
Cu 32. (C-12) 29: Cho phn ng ha hc: Cl2 +KOH
KCl + KClO3 + H2O
T l gia s nguyn t clo ng vai tr cht oxi ha v s nguyn t clo ng vai tr cht kh
trong phng trnh ha hc ca phn ng cho tng ng l
A. 1 : 5.
B. 5 : 1.
C. 3 : 1.
D. 1 : 3.
Cu 33. (C-11) 2: Cho 3,16 gam KMnO4 tc dng vi dung dch HCl c (d), sau khi phn ng
xy ra hon ton th s mol HCl b oxi ha l
A. 0,10.
B. 0,05.
C. 0,02.
D. 0,16
Cu 34. (B-11) 19: Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH +
H2O.Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l
A. 27.
B. 24.
C. 34.
D. 31.
Cu 35. (C-10) 5: Cho p: Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O.
Tng h s ca cc cht (l nhng s nguyn, ti gin) trong PT p l
A. 23.
B. 27.
C. 47.
D. 31.
Cu 36. (B-12) 42: Cho phng trnh ha hc (vi a, b, c, d l cc h s):
aFeSO4 + bCl2 cFe2(SO4)3 + dFeCl3
o
Thng k H 2007-2014
T l a : c l
A. 4 : 1.
B. 3 : 2.
C. 2 : 1.
D. 3 : 1.
Cu 37. (A-13) 50: Cho phng trnh phn ng aAl + bHNO3 cAl(NO3)3 + dNO + eH2O.T l a : b l
A. 1 : 3.
B. 1 : 4.
C. 2 : 3.
D. 2 : 5.
Cu 38. (A-13) 56: Cho phng trnh phn ng
aFeSO4 + bK2Cr2O7 + cH2SO4
dFe2(SO4)3 + eK2SO4 + fCr2(SO4)3 + gH2O.
T l a : b l
A. 6 : 1.
B. 2 : 3.
C. 1 : 6.
D. 3 : 2.
Cu 39. (B-13) 36: Cho phn ng: FeO + HNO3 Fe(NO3)3 + NO + H2O.Trong phng trnh ca phn
ng trn, khi h s ca FeO l 3 th h s ca HNO3 l
A. 6.
B. 8.
C. 4.
D. 10.
2.3. Tc phn ng
Cu 40. 40 (A-14): Cho ba mu v (100% CaCO3) c cng khi lng: mu 1 dng khi, mu 2 dng
vin nh, mu 3 dng bt mn vo ba cc ng cng th tch dung dch HCl (d, cng nng , iu
kin thng) . Thi gian vi tan ht trong ba cc tng ng l t1, t2, t3 giy. So snh no sau y
ng?
A. t 3 t 2 t1
B.
t 2 t1 t 3
C.
t1 t 2 t 3
D.
t1 t 2 t 3
Cu 41. (B-09) 8: Cho cht xc tc MnO2 vo 100 ml dd H2O2, sau 60 giy thu c 33,6 ml kh O2 (
ktc). Tc trung bnh ca p (tnh theo H2O2) trong 60 giy trn l
A. 5, 0.10 -4 mol/(l.s). B. 5, 0.10 -5 mol/(l.s). C. 1, 0.10 -3 mol/(l.s). D. 2, 5.10 -4 mol/(l.s).
2HBr k
Cu 42. (B-14) Thc hin phn ng sau trong bnh kn: H 2 k Br2 k
Lc u nng hi Br2 l 0,072 mol/l. Sau 2 pht, nng hi Br2 cn li l 0,048 mol/l. Tc
trung bnh ca phn ng tnh theo Br2 trong khong thi gian trn l
A. 8.104 mol/(l.s)
B. 6.104 mol/(l.s)
C. 4.104 mol/(l.s)
D. 2.104 mol/(l.s)
Cu 43. (B-13) 19: Cho phng trnh ha hc ca phn ng: X + 2Y Z + T. thi im ban u,
nng ca cht X l 0,01 mol/l. Sau 20 giy, nng ca cht X l 0,008 mol/l. Tc trung bnh ca
phn ng tnh theo cht X trong khong thi gian trn l
A. 4,0.104 mol/(l.s).
B. 1,0.104 mol/(l.s).
C. 7,5.104 mol/(l.s).
D. 5,0.104 mol/(l.s).
Cu 44. (C-10) 41: Cho phn ng: Br2 + HCOOH 2HBr + CO2.
Nng ban u ca Br2 l a mol/lt, sau 50 giy nng Br2 cn li l 0,01 mol/lt. Tc trung bnh
ca phn ng trn tnh theo Br2 l 4.10-5 mol/(l.s). Gi tr ca a l
A. 0,012.
B. 0,016.
C. 0,014.
D. 0,018.
Cu 45. (C-12) 42: Cho phn ng ha hc: Br2 + HCOOH 2HBr + CO2
Lc u nng ca HCOOH l 0,010 mol/l, sau 40 giy nng ca HCOOH l 0,008 mol/l.
Tc trung bnh ca phn ng trong khong thi gian 40 giy tnh theo HCOOH l
A. 5,0.10-5 mol/(l.s).
B. 2,5.10-5 mol/(l.s).
C. 2,5.10-4 mol/(l.s).
D. 2,0.10-4 mol/(l.s).
Cu 46. (A-12) 26: Xt phn ng phn hy N2O5 trong dung mi CCl4 45oC:
N2O5 N2O4 + O2
Ban u nng ca N2O5 l 2,33M, sau 184 giy nng ca N2O5 l 2,08M. Tc trung bnh
ca phn ng tnh theo N2O5 l
A. 2, 72.10 -3 mol/(l.s).
B. 1, 36.10-3 mol/(l.s).
-3
C. 6,80.10 mol/(l.s).
D. 6,80.10-4 mol/(l.s).
Thng k H 2007-2014
2.4. Chuyn dch cn bng ha hc

Cu 47. 37 (A-14): H cn bng sau c thc hin trong bnh kn:
CO 2 k H 2
CO k H 2O k
k ;
H 0
Cn bng trn chuyn dch theo chiu thun khi

A. cho cht xc tc vo h
B. thm kh H2 vo h
C. gim nhit ca h
D. tng p sut chung ca h.
Cu 48. (C-09) 41: Cho cn bng (trong bnh kn) sau: CO (k) + H2O (k) CO2 (k) + H2 (k)
H < 0
Trong cc yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H 2; (4) tng p
sut chung ca h; (5) dng cht xc tc. Dy gm cc yu t u lm thay i cn bng ca h l:
A. (1), (4), (5).
B. (1), (2), (3).
C. (2), (3), (4).
D. (1), (2), (4).
Cu 49. (B-08) 23: Cho cn bng ho hc: N2 (k) + 3H2 (k) 2NH3 (k); p thun l p to nhit. Cn
bng ho hc khng b chuyn dch khi
A. thay i p sut ca h.
B. thay i nng N2. C. thay i nhit .
D. thm cht xc tc Fe.
NO (k) ; 0
Cu 50. (C-14) Cho h cn bng trong mt bnh kn : N2 (k) + O2
A. tng nhit ca h
B. Gim p sut ca h C. Thm kh NO vo h D. Thm cht xc tc vo h
Cu 51. (A-08) 32: Cho cn bng ho hc: 2SO2 + O2 2SO3 p thun l p ta nhit, pht biu ng
l:
A. Cn bng chuyn dch theo chiu thun khi tng nhit .
B. Cn bng chuyn dch theo chiu nghch khi gim nng O2.
C. Cn bng chuyn dch theo chiu thun khi gim p sut h p.
D. Cn bng chuyn dch theo chiu nghch khi gim nng SO3
Cu 52. (A-10) 16: Cho cn bng: 2SO2 (k) + O2 (k) 2SO3 (k). Khi tng nhit th t khi ca hh kh so
vi H2 gim i. Pht biu ng khi ni v cn bng ny l:
A. P thun thu nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
B. P nghch to nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
C. P nghch thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
D. P thun to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
Cu 53.
(B-10) 34: Cho cc cn bng sau:
(I) 2HI (k) H2 (k) + I2 (k);
(II) CaCO3 (r) CaO (r) + CO2 (k);
(III) FeO (r) + CO (k) Fe (r) + CO2 (k);
(IV) 2SO2 (k) + O2 (k) 2SO3 (k).
Khi gim p sut ca h, s cn bng b chuyn dch theo chiu nghch l
A. 4.
B. 3.
C. 2.
D. 1.
Cu 54. (A-09) 50: Cho cn bng sau trong bnh kn:
2NO2 (k) N2O4 (k)
(mu nu )
(khng mu)
Bit khi h nhit ca bnh th mu nu nht dn. P thun c
A. H > 0, p ta nhit.
B. H < 0, p ta nhit.
C. H > 0, p thu nhit. D. H < 0, p
thu nhit.
Cu 55. (C-08) 21: Cho cc cn bng ho hc:
N2 (k) + 3H2 (k) 2NH3 (k) (1)
H2 (k) + I2 (k) 2HI (k)
(2)
2NO2 (k) N2O4 (k)
(4)
2SO2 (k) + O2 (k) 2SO3 (k) (3)
Khi thay i p sut nhng cn bng ha hc b chuyn dch l:
A. (1), (2), (3).
B. (2), (3), (4).
C. (1), (3), (4).
D. (1), (2), (4).
Cu 56. (A-11) 26: Cho cn bng ho hc: H2 (k) + I2 (k) 2HI (k); H > 0.Cn bng khng b chuyn
dch khi
A. tng nhit ca h.
B. gim nng HI.
C. tng nng H2.
D. gim p sut chung ca h.
Cho
cn
bng
ha
hc
sau:
Cu 57. (C-11)
N2 (k) + 3H2 (k) 2NH3 (k) H < 0
A. tng nhit ca h phn ng.
B. gim p sut ca h phn ng.
C. tng p sut ca h phn ng.
D. thm cht xc tc vo h phn ng.
Cu 58. (C-09) 7: Cho cc cn bng sau:
(1) 2SO2 (k) + O2 (k) SO3 (k)
(2) N2 (k) + 3H2 (k) 2NH3 (k)
(3) CO2 (k) + H2 (k) CO (k) + H2O (k)
(4) 2HI (k) H2 (k)+ I2 (k)
Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l
A. (1) v (2).
B. (1) v (3).
C. (3) v (4).
D. (2) v (4).
Cu 59. (C-10) 29: Cho cn bng ho hc: PCl5 (k) PCl3 (k) + Cl2 (k); H > 0.
Cn bng chuyn dch theo chiu thun khi
t0
Thng k H 2007-2014
A. thm PCl3 vo h p.
B. tng nhit ca h p.
C. tng p sut ca h p.
D. thm Cl2 vo h p
Cu 60. (B-11) 27: Cho cn bng ho hc sau: 2SO2 (k) + O2 (k) 2SO3 (k); H < 0.
Cho cc bin php: (1) tng nhit , (2) tng p sut chung ca h phn ng, (3) h nhit , (4)
dng thm cht xc tc V2O5, (5) gim nng SO3, (6) gim p sut chung ca h phn ng. Nhng
bin php no lm cn bng trn chuyn dch theo chiu thun?
A. (1), (2), (4), (5).
B. (2), (3), (5).
C. (2), (3), (4), (6).
D. (1), (2), (4).
Cu 61. (B-12) 23: Cho phn ng: N2 (k) + 3H2 (k) 2NH3 (k); H = 92 kJ. Hai bin php u
lm cn bng chuyn dch theo chiu thun l
A. gim nhit v gim p sut.
B. tng nhit v tng p sut.
C. gim nhit v tng p sut.
D. tng nhit v gim p sut.
Cu 62. (C-12) 23: Cho cn bng ha hc: CaCO 3(rn) CaO (rn) + CO 2 (kh)
Bit phn ng thun l phn ng thu nhit. Tc ng no sau y vo h cn bng cn bng
cho chuyn dch theo chiu thun?
A. Tng nng kh CO2.
B. Tng p sut.
C. Gim nhit .
D. Tng nhit .
Cu 63. (A-13) 19: Cho cc cn bng ha hc sau:
(a) H2 (k) + I2 (k) 2HI (k).
(b) 2NO2 (k) N2O4 (k).
(c) 3H2 (k) + N2 (k) 2NH3 (k).
(d) 2SO2 (k) + O2 (k) 2SO3 (k).
nhit khng i, khi thay i p sut chung ca mi h cn bng, cn bng ha hc no trn khng
b chuyn dch?
A. (c).
B. (b).
C. (a).
D. (d).
Cu 64. (B-13) 54: Trong mt bnh kn c cn bng ha hc sau: 2NO2 (k) N2O4 (k). T khi hi ca
hn hp kh trong bnh so vi H2 nhit T1 bng 27,6 v nhit T2 bng 34,5.
Bit T1 > T2. Pht biu no sau y v cn bng trn l ng?
A. Khi tng nhit , p sut chung ca h cn bng gim.
B. Khi gim nhit , p sut chung ca h cn bng tng.
C. Phn ng thun l phn ng ta nhit.
D. Phn ng nghch l phn ng ta nhit.
Cu 65. (C-13) 9: Trong bnh kn c h cn bng ha hc sau:
CO2 (k) + H2 (k) CO (k) + H2O (k); H > 0.
Xt cc tc ng sau n h cn bng:
(a) tng nhit ;
(b) thm mt lng hi nc;
(c) gim p sut chung ca h;
(d) dng cht xc tc;
(e) thm mt lng CO2.
Trong nhng tc ng trn, cc tc ng lm cn bng chuyn dch theo chiu thun l:
A. (a) v (e).
B. (b), (c) v (d).
C. (d) v (e).
D. (a), (c) v (e).
Thng k H 2007-2014
3. S IN LY- pH DUNG DCH

3.1. Cht in ly, axit, ba z, lng tnh
Cu 1. (B-08) 15: Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11 (saccaroz),
CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 2. (B-10) 53: Dd axit fomic 0,007M c pH = 3. Kt lun no sau y khng ng?
A. Khi pha long 10 ln dd trn th thu c dd c pH = 4.
B. in li ca axit fomic s gim khi thm dd HCl.
C. Khi pha long dd trn th in li ca axit fomic tng.
D. in li ca axit fomic trong dd trn l 14,29%.
Cu 3. (C-09) 29: Dy gm cc cht va tan trong dd HCl, va tan trong dd NaOH l:
A. NaHCO3, MgO, Ca(HCO3)2.
B. NaHCO3, ZnO, Mg(OH)2.
C. NaHCO3, Ca(HCO3)2, Al2O3.
D. Mg(OH)2, Al2O3, Ca(HCO3)2
Cu 4. (A-08) 17: Cho cc cht: Al, Al2O3, Al2(SO4) 3, Zn(OH)2, NaHS, K2SO3, (NH4) 2CO3. S cht u
p c vi dd HCl, dd NaOH l
A. 4.
B. 5.
C. 7.
D. 6.
Cu 5. (B-11) 45: Cho dy cc cht sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3, K2SO4. C
bao nhiu cht trong dy va tc dng c vi dung dch HCl, va tc dng c vi dung dch NaOH?
A. 3.
B. 5.
C. 4.
D. 2.
Cu 6. (A-12) 33: Cho dy cc cht: Al, Al(OH)3, Zn(OH)2, NaHCO3, Na2SO4. S cht trong dy va
phn ng c vi dung dch HCl, va phn ng c vi dung dch NaOH l
A. 5.
B. 4.
C. 3.
D. 2.
Cu 7. (A-07)Cho dy Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2.S cht c tnh cht lng
tnh l
A. 4.
B. 5.
C. 2.
D. 3.
Cu 8. (A-11) 22: Cho cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht c tnh cht
lng tnh l
A. 3.
B. 4.
C. 2.
D. 1.
Cu 9. (C-07) 5: Trong s cc dd: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dd c pH
> 7 l
A. Na2CO3, C6H5ONa, CH3COONa.
B. Na2CO3, NH4Cl, KCl.
C. KCl, C6H5ONa, CH3COONa.
D. NH4Cl, CH3COONa, NaHSO4.
Cu 10. (C-08) 27: Cho cc dd c cng nng : Na2CO3 (1), H2SO4 (2), HCl (3), KNO3 (4). Gi tr pH ca
cc dd c sp xp theo chiu tng t tri sang phi l:
A. (3), (2), (4), (1).
B. (4), (1), (2), (3).
C. (1), (2), (3), (4).
D. (2), (3), (4), (1).
Cu 11. (C-13) 52: Dung dch cht no di y c mi trng kim?
A. NH4Cl.
B. Al(NO3)3.
C. CH3COONa.
D. HCl.
3.2. Phn ng ion trong dung dch

Cu 12. (B-07) 6: Trong cc dd: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u
t/d c vi dd Ba(HCO3)2 l:
A. HNO3, NaCl, Na2SO4.
B. HNO3, Ca(OH) 2, KHSO4, Na2SO4.
C. NaCl, Na2SO4, Ca(OH)2.
D. HNO3, Ca(OH) 2, KHSO4, Mg(NO3) 2.
Cu 13. (A-13) 37: Dy cc cht u tc dng c vi dung dch Ba(HCO3)2 l:
A. HNO3, NaCl v Na2SO4.
B. HNO3, Ca(OH)2 v KNO3.
C. NaCl, Na2SO4 v Ca(OH)2.
D. HNO3, Ca(OH)2 v Na2SO4.
Cu 14. (C -14) 44: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch sau: HNO3,
Na2SO4, Ba(OH)2, NaHSO4. S trng hp c phn ng xy ra l
A. 3.
B. 2.
C. 1.
D. 4.
Cu 15. (B-10) 8: Cho dung dch Ba(HCO3)2 ln lt vo cc dd: CaCl2, Ca(NO3)2, NaOH, Na2CO3,
KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l
Thng k H 2007-2014
A. 4.
B. 7.
C. 5.
D. 6.
Cu 16. (A-09) 5: Cho bn hh, mi hh gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl3;
BaCl2 v CuSO4; Ba v NaHCO3. S hh c th tan hon ton trong nc (d) ch to ra dd l
A. 3.
B. 2.
C. 1.
D. 4.
Cu 17. (B-07) 25: Hh X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho
hh X vo H2O (d), un nng, dd thu c cha
A. NaCl, NaOH, BaCl2.
B. NaCl, NaOH.
C. NaCl, NaHCO3, NH4Cl, BaCl2.
D.
NaCl.
Cu 18. (C-09) 33: Dy gm cc ion (khng k n s phn li ca nc) cng tn ti trong mt dd l:
A. Al3+, NH4+, Br-, OHB. Mg2+, K+, SO42-, PO43C. H+, Fe3+, NO3-, SO42D. Ag+, Na+, NO3-, ClCu 19. (C-10) 7: Dy gm cc ion cng tn ti trong mt dd l:
A. Al3+, PO43, Cl, Ba2+.
B. Ca2+, Cl, Na+, CO32.
C. K+, Ba2+, OH, Cl. D. Na+, K+, OH, HCO3.
Cu 20. (C-13) 4: Dy gm cc ion cng tn ti trong mt dung dch l:
A. K+; Ba2+; Cl v NO3- .
B. Cl; Na+; NO3- v Ag+.
C. K+; Mg2+; OH v NO3- .

D. Cu2+; Mg2+; H+ v OH.
Cu 21. (A-13) 30: Cht no sau y khng to kt ta khi cho vo dung dch AgNO3?
A. HNO3.
B. HCl.
C. K3PO4.
D. KBr.
Cu 22. (C-08) 10: Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong
dy t/d vi lng d dd Ba(OH)2 to thnh kt ta l
A. 5.
B. 4.
C. 1.
D. 3.
Cu 23. (A-09)41:C nm dd ng ring bit trong nm ng nghim:(NH4)2SO4, FeCl2,
Cr(NO3)3, K2CO3, Al(NO3)3. Cho dd Ba(OH)2 n d vo nm dd trn. Sau khi p kt thc, s
ng nghim c kt ta l
A. 4.
B. 2.
C. 5.
D. 3.
Cu 24. (C-08) 30: Cho dy cc cht: KOH, Ca(NO3)2, SO3, NaHSO4, Na2SO3, K2SO4. S cht trong
dy to thnh kt ta khi p vi dd BaCl2 l
A. 4.
B. 6.
C. 3.
D. 2.
Cu 25. (A-09) 8: Dy gm cc cht u t/d c vi dd HCl long l:
A. KNO3, CaCO3, Fe(OH)3.
B. FeS, BaSO4, KOH.
C. AgNO3, (NH4)2CO3, CuS.
D. Mg(HCO3) 2, HCOONa, CuO.
Cu 26. (A-14): Nh t t n d dung dch NaOH long vo mi dung dch sau: FeCl3, CuCl2,
AlCl3, FeSO4. Sau khi cc phn ng xy ra hon ton, s trng hp thu c kt ta l
A. 4
B. 2
C. 3
D. 1
Cu 27. (B-10) 14: Pht biu no sau y khng ng?
A. Trong cc dd: HCl, H2SO4, H2S c cng nng 0,01M, dd H2S c pH ln nht.
B. Nh dd NH3 t t ti d vo dd CuSO4, thu c kt ta xanh.
C. Dd Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng.
D. Nh dd NH3 t t ti d vo dd AlCl3, thu c kt ta trng.
Cu 28. (B-14) : Cho phn ng ha hc : NaOH HCl
NaCl H2O
Phn ng ha hc no sau y c cng phng trnh ion thu gn vi phn ng trn?
Fe OH 2 2KCl
A. 2KOH FeCl2
B. NaOHNaHCO3
Na 2CO3 H2O
C. NaOH NH4Cl
NaCl NH3 H2O D. KOH HNO 3
KNO3 H2O
Cu 29. (A-10) 31: Cho cc cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht t/d c
vi dd NaOH long nhit thng l
A. 4.
B. 5.
C. 3.
D. 6.
Cu 30. (B-09) 28: Cho cc p ha hc sau:
(1) (NH4)2SO4 + BaCl2
(2) CuSO4 + Ba(NO3) 2
(3) Na2SO4 + BaCl2
(4) H2SO4 + BaSO3
(5) (NH4) 2SO4 + Ba(OH) 2

(6) Fe2 (SO4)3 + Ba(NO3) 2
Cc p u c cng mt PT ion rt gn l:
A. (1), (2), (3), (6).
B. (1), (3), (5), (6).
C. (2), (3), (4), (6).
D. (3), (4), (5), (6).
Cu 31. (A-12) 45: Cho cc phn ng sau:
(a) FeS + 2HCl FeCl2 + H2S
(b) Na2S + 2HCl 2NaCl + H2S
(c) 2AlCl3 + 3Na2S + 6H2O 2Al(OH)3 + 3H2S + 6NaCl
Thng k H 2007-2014
(d) KHSO4 + KHS K2SO4 + H2S

(e) BaS + H2SO4 (long) BaSO4 + H2S
S phn ng c phng trnh ion rt gn S2- + 2H+ H2S l
A. 1.
B. 3.
C. 2.
D. 4.
Cu 32. (B-12) 57: Dung dch cht X khng lm i mu qu tm; dung dch cht Y lm qu tm
ha xanh. Trn ln hai dung dch trn thu c kt ta. Hai cht X v Y tng ng l
A. KNO3 v Na2CO3.
B. Ba(NO3)2 v Na2CO3.
C. Na2SO4 v BaCl2.
D. Ba(NO3)2 v K2SO4.
Cu 33. (A-14): trung ha 20 ml dung dch HCl 0,1 M cn 10 ml dung dch NaOH nng x
mol/l. Gi tr ca x l
A. 0,1
B. 0,3
C. 0,2
D. 0,4
Cu 34. (C-09) 20: Cho dd cha 0,1 mol (NH4)2CO3 t/d vi dd cha 34,2 gam Ba(OH)2. Sau p
thu c m gam kt ta. Gi tr ca m l
A. 19,7.
B. 39,4.
C. 17,1.
D. 15,5.
3.3. Bi ton pH
Cu 35. (A-08) 28: Trn ln V ml dd NaOH 0,01M vi V ml dd HCl 0,03 M c 2V ml dd Y. Dd Y

c pH l
A. 4.
B. 3.
C. 2.
D. 1.
Cu 36. (B-07) 33: Trn 100 ml dd (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dd (gm
H2SO4 0,0375M v HCl 0,0125M), thu c dd X. Gi tr pH ca dd X l
A. 7.
B. 2.
C. 1.
D. 6.
Cu 37. (B-09) 6: Trn 100 ml dd hh gm H2SO4 0,05M v HCl 0,1M vi 100 ml dd hh gm
NaOH 0,2M v Ba(OH) 2 0,1M, thu c dd X. Dd X c pH l
A. 13,0.
B. 1,2.
C. 1,0.
D. 12,8.
Cu 38. (B-08) 28: Trn 100 ml dd c pH = 1 gm HCl v HNO3 vi 100 ml dd NaOH nng a
+
-14
(mol/l) thu c 200 ml dd c pH = 12. Gi tr ca a l (bit trong mi dd [H ][OH ] = 10 )
A. 0,15.
B. 0,30.
C. 0,03.
D. 0,12.
Cu 39. (C-11) 20: Cho a lt dung dch KOH c pH = 12,0 vo 8,00 lt dung dch HCl c pH =
3,0 thu c dung dch Y c pH =11,0. Gi tr ca a l
A. 1,60.
B. 0,80.
C. 1,78.
D. 0,12.
Cu 40. (A-07) 21: Dd HCl v dd CH3COOH c cng nng mol/l, pH ca hai dd tng ng l x
v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li)
A. y = x - 2.
B. y = 2x.
C. y = 100x.
D. y = x + 2.
Cu 41. (A-07) 25: Cho m gam hh Mg, Al vo 250 ml dd X cha hh axit HCl 1M v axit H2SO4
0,5M, thu c 5,32 lt H2 ( ktc) v dd Y (coi th tch dd khng i). Dd Y c pH l
A. 7.
B. 1.
C. 2.
D. 6.
Cu 42. (B-13) 49: Trong s cc dung dch c cng nng 0,1M di y, dung dch cht no
c gi tr pH nh nht?
A. NaOH.
B. HCl.
C. H2SO4.
D. Ba(OH)2.
3.4. Tnh theo phng trnh ion, nh lut bo ton in tch

Cu 43. (A-10) 36: Dd X c cha: 0,07 mol Na+; 0,02 mol SO42- v x mol OH- . Dd Y c cha ClO4-,
NO3- , v y mol H+; tng s mol ClO4-v NO3- l 0,04. Trn X v Y c 100 ml dd Z. Dd Z c pH (b
qua s in li ca H2O) l
A. 1.
B. 12.
C. 13.
D. 2.
Cu 44. (B-14): Cho mui X tc dng vi dung dch NaOH d, thu c dung dch cha hai cht
tan. Mt khc, cho a gam dung dch mui X tc dng vi a gam dung dch Ba(OH) 2, thu c 2a
gam dung dch Y. Cng thc ca X l
A. KHS.
B. NaHSO4.
C. NaHS.
D. KHSO3
Cu 45. (A-10) 30: Cho dd X gm: 0,007 mol Na+; 0,003 mol Ca2+; 0,006 mol Cl; 0,006 mol HCO3
v 0,001 mol NO3-. loi b ht Ca2+ trong X cn mt lng va dd cha a gam Ca(OH)2. Gi
tr ca a l
Thng k H 2007-2014
A. 0,180.
B. 0,120.
C. 0,444.
D. 0,222.
Cu 46. (C-12) 22: Dung dch E gm x mol Ca2+ , y mol Ba2+, z mol HCO3- . Cho t t dung dch
Ca(OH)2 nng a mol/l vo dung dch E n khi thu c lng kt ta ln nht th va ht V lt
dung dch Ca(OH)2. Biu thc lin h gia cc gi tr V, a, x, y l
A. V = 2a(x+y).
B. V = a(2x+y) C. V= (x+2y)/2
D. V= (x+y)/a
Cu 47. (B-10) 45: Dd X cha cc ion: Ca2+, Na+, HCO3 v Cl, trong s mol ca ion Cl l 0,1.
Cho 1/2 dd X p vi dd NaOH (d), thu c 2 gam kt ta. Cho 1/2 dd X cn li p vi dd
Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dd X th thu c m gam cht
rn khan. Gi tr ca m l
A. 9,21.
B. 9,26.
C. 8,79.
D. 7,47.
Cu 48. (A-10) 24: Cho m gam NaOH vo 2 lt dd NaHCO3 nng a mol/l, thu c 2 lt dd X. Ly
1 lt dd X t/d vi dd BaCl2 (d) thu c 11,82 gam kt ta. Mt khc, cho 1 lt dd X vo dd CaCl2
(d) ri un nng, sau khi kt thc cc p thu c 7,0 gam kt ta. Gi tr ca a, m tng ng l
A. 0,08 v 4,8.
B. 0,04 v 4,8.
C. 0,14 v 2,4.
D. 0,07 v 3
+
3+
Cu 49. (B-11) 11: Dung dch X gm 0,1 mol H , z mol Al , t NO3 mol v 0,02 mol SO42- Cho 120
ml dung dch Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn ng kt thc, thu c
3,732 gam kt ta. Gi tr ca z, t ln lt l
A. 0,020 v 0,012.
B. 0,012 v 0,096. C. 0,020 v 0,120.
D. 0,120 v 0,020.
Cu 50. (C-07) 31: Mt dd cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl v y mol SO42. Tng khi
lng cc mui tan c trong dd l 5,435 gam. Gi tr ca x v y ln lt l
A. 0,03 v 0,02.
B. 0,05 v 0,01.
C. 0,01 v 0,03.
D. 0,02 v 0,05.
Cu 51. (C-09) 1: Nh t t 0,25 lt dd NaOH 1,04M vo dd gm 0,024 mol FeCl3; 0,016
molAl2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l
A. 2,568.
B. 1,560.
C. 4,128.
D. 5,064.
Cu 52. (C-07) 6: Khi cho 100ml dd KOH 1M vo 100ml dd HCl thu c dd c cha 6,525 gam
cht tan. Nng mol (hoc mol/l) ca HCl trong dd dng l
A. 0,75M.
B. 1M.
C. 0,25M.
D. 0,5M.
Cu 53. (C-08) 12: Dd X cha cc ion: Fe3+, SO42-, NH4+, Cl-. Chia dd X thnh hai phn bng nhau:
- Phn mt t/d vi lng d dd NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt
ta;
- Phn hai t/d vi lng d dd BaCl2, thu c 4,66 gam kt ta.
Tng khi lng cc mui khan thu c khi c cn dd X l (qu trnh c cn ch c nc bay
hi)
A. 3,73 gam.
B. 7,04 gam.
C. 7,46 gam.
D. 3,52 gam.
Cu 54. (B-14): Hn hp X gm hai mui R2CO3 v RHCO3. Chia 44,7 gam X thnh ba phn
bng nhau:
- Phn mt tc dng hon ton vi dung dch Ba(OH)2 d thu c 35,46 gam kt ta.
- Phn hai tc dng hon ton vi dung dch BaCl2 d, thu c 7,88 gam kt ta.
- Phn ba tc dng ti a vi V ml dung dch KOH 2M.
Gi tr ca V l
A. 180
B.200.
C.110.
D. 70.
Cu 55. (B-12) 22: Mt dung dch gm: 0,01 mol Na+; 0,02 mol Ca2+; 0,02 mol HCO3- v a mol ion
X (b qua s in li ca nc). Ion X v gi tr ca a l
A. NO3- v 0,03
B. Cl- v 0,01
C. CO32- v 0,03
D. OH- v 0,03
Cu 56. (A-13) 12: Cho 1,37 gam Ba vo 1 lt dung dch CuSO4 0,01M. Sau khi cc phn ng xy
ra hon ton, khi lng kt ta thu c l
A. 2,33 gam.
B. 1,71 gam.
C. 3,31 gam.
D. 0,98 gam.
Cu 57. (B-13) 40: Dung dch X cha 0,12 mol Na+; x mol SO42- ; 0,12 mol Cl v 0,05 mol NH4+ .
Cho 300 ml dung dch Ba(OH)2 0,1M vo X n khi cc phn ng xy ra hon ton, lc b kt ta,
thu c dung dch Y. C cn Y, thu c m gam cht rn khan. Gi tr ca m l
A. 7,190.
B. 7,705.
C. 7,875.
D. 7,020.
Cu 58. (B-14): Dung dch X gm 0,1 mol K+; 0,2 mol Mg2+; 0,1 mol Na+; 0,2 mol Cl- v a mol Y2. C cn dung dch X, thu c m gam mui khan. Ion Y2- v gi tr ca m l
A. SO24 v 56,5.
B. CO32 v 30,1.
C. SO24 v 37,3.
D. CO32 v 42,1.
Cu 59. (A-14) 29: Dung dch X cha 0,1 mol ; 0,3 mol ; 0,4 mol v a mol . un dung dch X n
cn thu c mui khan c khi lng l
Thng k H 2007-2014
A. 49,4 gam
B. 28,6 gam
C. 37,4 gam
D. 23,2 gam
Cu 60. (C-13) 32: Cho 50 ml dung dch HNO3 1M vo 100 ml dung dch KOH nng x mol/l, sau
phn ng thu
c dung dch ch cha mt cht tan duy nht. Gi tr ca x l
A. 0,5.
B. 0,3.
C. 0,8.
D. l,0.
Thng k H 2007-2014
4. PHI KIM
4.1. OXI LU HUNH
Cu 1. (A-08) 12: Trong phng th nghim, ngi ta iu ch oxi bng cch
A. in phn nc.
B. nhit phn Cu(NO3) 2.
C. nhit phn KClO3 c xc tc MnO2.
D. chng ct phn on khng kh lng.
Cu 2. (B-09) 7: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2),
KMnO4, KNO3 v AgNO3. Cht to ra lng O2 ln nht l
A. KClO3.
B. KMnO4.
C. KNO3.
D. AgNO3.
Cu 3. (B-11) 34: Nhit phn 4,385 gam hn hp X gm KClO3 v KMnO4, thu c O2 v m
gam cht rn gm K2MnO4, MnO2 v KCl. Ton b lng O2 tc dng ht vi cacbon nng ,
thu c 0,896 lt hn hp kh Y (ktc) c t khi so vi H2 l 16. Thnh phn % theo khi
lng ca KMnO4 trong X l
A. 74,92%.
B. 72,06%.
C. 27,94%.
D. 62,76%.
Cu 4. ((B-09) 46: ng dng no sau y khng phi ca ozon?
A. Ty trng tinh bt, du n.
B. Cha su rng.
C. iu ch oxi trong phng th nghim.
D. St trng nc sinh hot
Cu 5. (B-14): Tri cy c bo qun lu hn trong mi trng v trng. Trong thc t, ngi ta
s dng nc ozon bo qun tri cy. ng dng trn da vo tnh cht no sau y?
A. Ozon tr v mt ha hc.
B. Ozon l cht kh c mi c trng.
C. Ozon l cht c tnh oxi ha mnh.
D. Ozon khng tc dng c vi nc.
Cu 6. (C-10) 19: Nguyn t S ng vai tr va l cht kh, va l cht oxi ho trong p no
sau y?
to
A. S + 2Na
Na2S.
to
B. C. S + 6HNO3 (c)
H2SO4 + 6NO2 + 2H2O
C. 4S + 6NaOH(c)
2Na2S + Na2S2O3 + 3H2O.

o
t
D. D. S + 3F2
SF6.
Cu 7. (C-14): Cho cc phn ng ha hc sau :
o
(a) S + O2
SO2
t
(b) S + 3F2
SF6
t
(c) S + Hg HgS
(d) S + HNO3 (c)
H2SO4 + 6NO2 + 2H2O
S phn ng trong S th hin tnh kh l :
A. 2
B. 3
C. 1
D. 4
Cu 8. (C-08) 5: Trng hp khng xy ra p ha hc l
A. 3O2 + 2H2S to 2H2O + 2SO2.
B. FeCl2 + H2S FeS + 2HCl.
C. O3 + 2KI + H2O 2KOH + I2 + O2.
D. Cl2 + 2NaOH NaCl + NaClO + H2O.
Cu 9. (C-13) Thuc th no di y phn bit c kh O2 vi kh O3 bng phng php
ha hc?
A. Dung dch KI + h tinh bt.
B. Dung dch NaOH.
C. Dung dch H2SO4.
D. Dung dch CuSO4.
Cu 10. (A-10) 46: Cht c dng ty trng giy v bt giy trong cng nghip l
A.N2O.
B. CO2.
C. SO2.
D. NO2.
Cu 11. (A-14): Kh X lm c nc vi trong v c dng lm cht ty trng bt g trong cng
nghip giy. Cht X l
A. CO2
B. O3
C. NH3
D. SO2
Cu 12. C-07) 3: SO2 lun th hin tnh kh trong cc p vi
A. H2S, O2, nc Br2.
B. dd NaOH, O2, dd KMnO4.
C. dd KOH, CaO, nc Br2.
D. O2, nc Br2, dd KMnO4.
Cu 13. (C -14): Kh no sau y c kh nng lm mt mu nc brom?
A. N2.
B. SO2.
C. CO2.
D. H2.
0
Cu 14. (A-12) 34: Dy cht no sau y u th hin tnh oxi ha khi phn ng vi SO2?
A. Dung dch BaCl2, CaO, nc brom.
B. Dung dch NaOH, O2, dung dch
KMnO4.
Thng k H 2007-2014
C. O2, nc brom, dung dch KMnO4.

D. H2S, O2, nc brom.
Cu 15. (B-14): Nung nng hn hp bt X gm a mol Fe v b mol S trong kh tr, hiu sut phn
ng bng 50%, thu c hn hp rn Y. Cho Y vo dung dch HCl d, sau khi cc phn ng xy ra
hon ton, thu c hn hp kh Z c t khi so vi H2 bng 5. T l a : b bng
A. 2 : 1.
B. 1 : 1.
C. 3 : 1.
D. 3 : 2.
Cu 16. (C-09) 26: Cht kh X tan trong nc to ra mt dd lm chuyn mu qu tm thnh
v c th c dng lm cht ty mu. Kh X l
A. NH3.
B. CO2.
C. SO2.
D. O3.
Cu 17. (C-11) 59: Dn mu kh thi ca mt nh my qua dung dch Pb(NO3)2 d th thy
xut hin kt ta mu en. Hin tng chng t trong kh thi nh my c kh no sau y?
A. NH3.
B. CO2.
C. SO2.
D. H2S.
Cu 18. (C-08) 38: Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu
kin khng c khng kh), thu c hh rn M. Cho M t/d vi lng d dd HCl, gii phng hh kh X
v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 ( ktc). Gi
tr ca V l
A. 2,80.
B. 3,36.
C. 3,08.
D. 4,48.
Cu 19. (C-10) 27: Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch
X. trung ho 100ml dd X cn dng 200 ml dd NaOH 0,15M. Phn trm v khi lng ca nguyn
t lu hunh trong oleum trn l
A. 32,65%.
B. 35,95%.
C. 37,86%.
D. 23,97%.
Cu 20. (A-14): Ha tan ht 1,69 gam oleum c cng thc H2SO4.3SO3 vo nc d. Trung ha
dung dch thu c cn V ml dung dch KOH 1M . Gi tr ca V l
A. 10
B. 40
C. 20
D. 30
Cu 21. (C-13) 16: Dung dch H2SO4 long phn ng c vi tt c cc cht trong dy no
sau y?
A. Al2O3, Ba(OH)2, Ag.
B. CuO, NaCl, CuS.
C. FeCl3, MgO, Cu.
D. BaCl2, Na2CO3, FeS.
Cu 22. (A-13) 4: Trong iu kin thch hp, xy ra cc phn ng sau:
(a) 2H2SO4 + C
2SO2 + CO2 + 2H2O.
(b) H2SO4 + Fe(OH)2
FeSO4 + 2H2O.
(c) 4H2SO4 + 2FeO
Fe2(SO4)3 + SO2 + 4H2O.
(d) 6H2SO4 + 2Fe
Fe2(SO4)3 + 3SO2 + 6H2O.
Trong cc phn ng trn, phn ng xy ra vi dung dch H2SO4 long l
A. (b).
B. (a).
C. (d).
D. (c).
4.2. HALOGEN
Cu 23. (A-11) 2: Pht biu no sau y l sai?
A. Bn knh nguyn t ca clo ln hn bn knh nguyn t ca flo.
B. m in ca brom ln hn m in ca iot.
C. Tnh kh ca ion Br ln hn tnh kh ca ion Cl .

D. Tnh axit ca HF mnh hn tnh axit ca HCl.
Cu 24. (A-10) 28: Pht biu khng ng l:
A. Tt c cc nguyn t halogen u c cc s oxi ho: -1, +1, +3, +5 v +7 trong cc hp cht.
B. Trong cng nghip, photpho c sn xut bng cch nung hh qung photphorit, ct v than cc
1200oC trong l in.
C. Kim cng, than ch, fuleren l cc dng th hnh ca cacbon.
D. Hiro sunfua b oxi ho bi nc clo nhit thng.
Cu 25. (C-11) 26: Pht biu no sau y khng ng?
A. Trong cc hp cht, ngoi s oxi ho -1, flo v clo cn c cc s oxi ho +1, +3, +5, +7.
B. Mui AgI khng tan trong nc, mui AgF tan trong nc.
C. Flo c tnh oxi ha mnh hn clo.
D. Dung dch HF ha tan c SiO2.
Thng k H 2007-2014

0
t
Cu 26. (A-14) : Cho phn ng : NaX (rn) + H2SO4 (c)
NaHSO4 + HX (kh) .
Cc hiro halogenua (HX) c th iu ch theo phn ng trn l :
A. HCl, HBr v HI.
B. HF v HCl
C. HBr v HI
D. HF, HCl, HBr v HI
Cu 27. (B-13) 5: Cho cc pht biu sau:
(a) Trong cc phn ng ha hc, flo ch th hin tnh oxi ha.
(b) Axit flohiric l axit yu.
(c) Dung dch NaF long c dng lm thuc chng su rng.
(d) Trong hp cht, cc halogen (F, Cl, Br, I) u c s oxi ha: -1, +1, +3, +5 v +7.

(e) Tnh kh ca cc ion halogenua tng dn theo th t: F , Cl , Br , I .
Trong cc pht biu trn, s pht biu ng l
A. 3.
B. 5.
C. 2.
D. 4.
Cu 28. (C-10) 33: Pht biu no sau y ng?
A. Iot c bn knh nguyn t ln hn brom.
C. Dd NaF p vi dd AgNO3 sinh ra AgF kt
ta.
B. Flo c tnh oxi ho yu hn clo.
D. Axit HBr c tnh axit yu hn axit HCl.
Cu 29. (C-11) 40: Mc phn cc ca lin kt ha hc trong cc phn t c sp xp theo th
t gim dn t tri sang phi l:
A. HI, HCl, HBr.
B. HCl, HBr, HI.
C. HI, HBr, HCl.
D. HBr, HI, HCl
Cu 30. (A-07) 16: Trong phng th nghim, ngi ta thng iu ch clo bng cch
A. in phn nng chy NaCl.
B. cho dd HCl c t/d vi MnO2, un nng.
C. cho F2 y Cl2 ra khi dd NaCl.
D. in phn dd NaCl c mng ngn.
Cu 31. (B-14): Cho hnh v m t th nghim iu ch kh Cl2 t MnO2 v dung dch HCl:
Kh Cl2 sinh ra thng ln hi nc v hiro clorua. thu c kh Cl2 kh th bnh (1) v bnh (2)
ln lt ng
A. dung dch NaOH v dung dch H2SO4 c.
B. dung dch H2SO4 c v dung dch NaCl.
C. dung dch H2SO4 c v dung dch AgNO3 .
D. dung dch NaCl v dung dch H2SO4 c.
Cu 32. (C-07) 38: Cc kh c th cng tn ti trong mt hh l
A. NH3 v HCl.
B. H2S v Cl2.
C. Cl2 v O2.
D. HI v O3.
Cu 33. (C -14): Cho 23,7 gam KMNO4 phn ng ht vi dung dch HCl c (d), thu c V
lt kh Cl2 (ktc). Gi tr ca V l
A. 3,36.
B. 6,72.
C. 8,40.
D. 5,60.
Cu 34. (A-10) 34: Hh kh no sau y khng tn ti nhit thng?
A. CO v O2.
B. Cl2 v O2.
C. H2S v N2.
D. H2 v F2.
Cu 35. (C-09) 8: Cht dng lm kh kh Cl2 m l
A. Na2SO3 khan.
B. dd NaOH c
C. dd H2SO4 m c.
D. CaO.
Cu 36. (C-11) 48: Kh no sau y khng b oxi ho bi nc Gia-ven?
A. SO2.
B. CO2.
C. HCHO.
D. H2S
Cu 37. (C-09) 9: phn bit CO2 v SO2 ch cn dng thuc th l
A. nc brom.
B. CaO.
C. dd Ba(OH)2.
D. dd NaOH
Cu 38. (C -14): Dn 4,48 lt hn hp kh gm N2 v Cl2 vo dung dch Ca(OH)2 d. Sau khi phn
ng xy ra hon ton, cn li 1,12 lt kh thot ra. Bit th tch cc kh o iu kin tiu chun. Phn
trm th tch ca Cl2 trong hn hp trn l
A. 25,00%.
B. 88,38%.
C. 11,62%
D. 75,00%.
Cu 39. (B-07) 14: Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dd KOH 100oC. Sau khi p xy ra
Thng k H 2007-2014
hon ton, thu c 37,25 gam KCl. Dd KOH trn c nng l (cho Cl = 35,5; K = 39)
A. 0,24M.
B. 0,48M.
C. 0,4M.
D. 0,2M
Cu 40. (B-09) 24: Cho dd cha 6,03 gam hh gm hai mui NaX v NaY (X, Y l hai nguyn t c trong
t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dd AgNO3 (d), thu c
8,61 gam kt ta. Phn trm khi lng ca NaX trong hh ban u l
A. 58,2%.
B. 41,8%.
C. 52,8%.
D. 47,2%.
Cu 41. (A-09) 7: Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt p vi lng d
dd HCl c, cht to ra lng kh Cl2 nhiu nht l
A. KMnO4.
B. MnO2
C. CaOCl2.
D. K2Cr2O7.
Cu 42. (A-09) 38: Trng hp no sau y khng xy ra p ho hc?
A. Sc kh Cl2 vo dd FeCl2.
B. Sc kh H2S vo dd CuCl2.
C. Sc kh H2S vo dd FeCl2.
D. Cho Fe vo dd H2SO4 long, ngui.
Cu 43. (B-08) 47: Cho cc p: (1) O3+ dd KI
(3) MnO2 + HCl c

Cc p to ra n cht l:
A. (1), (2), (3).
B. (1), (3), (4).
(2) F2+ H2O

o
(4) Cl2+ dd H2S
C. (2), (3), (4).
D. (1), (2), (4).
Cu 44. (A-12) 23: Hn hp X c khi lng 82,3 gam gm KClO3, Ca(ClO3)2, CaCl2 v KCl. Nhit
phn hon ton X thu c 13,44 lt O2 (ktc), cht rn Y gm CaCl2 v KCl. Ton b Y tc dng
va vi 0,3 lt dung dch K2CO3 1M thu c dung dch Z. Lng KCl trong Z nhiu gp 5 ln
lng KCl trong X. Phn trm khi lng KCl trong X l
A. 12,67%.
B. 18,10%.
C. 25,62%.
D. 29,77%.
4.3. NIT PHOTPHO

Cu 45. (A-08) 40: Cho cc p sau:
to
(1) Cu(NO3 ) 2
(3) NH3 + O2
t ,Pt
to
(5) NH4Cl
Cc p u to kh N2 l:
A. (2), (4), (6).
B. (3), (5), (6).
Cu 46. (B-08) 31: Cho cc p sau:
to
( 4 ) N H 3 + C l 2
to
(6) N H 3 + C u O
(2) NH4NO2
C. (1), (3), (4).

to
D. (1), (2), (5).
Kh X + H2O
NH3 + O2 kh Y + H2O
H2S + O2 (d)
850o ,Pt
NH4HCO3 + HCl long Kh Z + NH4Cl + H2O

Cc kh X, Y, Z thu c ln lt l:
A. SO3, NO, NH3.
B. SO2, N2, NH3.
C. SO2, NO, CO2.
D. SO3, N2, CO2.
Cu 47. (C-10) 44: Sn phm ca phn ng nhit phn hon ton AgNO3 l:
A. Ag2O, NO, O2.
B. Ag2O, NO2, O2.
C. Ag, NO, O2.
D. Ag, NO2, O2.
Cu 48. (C-08) 9: Nhit phn hon ton 34,65 gam hh gm KNO3 v Cu(NO3)2, thu c hh kh X (t
khi ca X so vi kh hiro bng 18,8). Khi lng Cu(NO3)2 trong hh ban u l
A. 8,60 gam.
B. 20,50 gam.
C. 11,28 gam.
D. 9,40 gam.
Cu 49. (B-13) 7: Ha tan hon ton 1,28 gam Cu vo 12,6 gam dung dch HNO3 60% thu c
dung dch X (khng c ion NH4+ ). Cho X tc dng hon ton vi 105 ml dung dch KOH 1M, sau lc
b kt ta c dung dch Y. C cn Y c cht rn Z. Nung Z n khi lng khng i, thu c
8,78 gam cht rn. Nng phn trm ca Cu(NO3)2 trong X l
A. 28,66%.
B. 29,89%.
C. 30,08%.
D. 27,09%.
Cu 50. (A-09) 17: Nung 6,58g Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian
thu c 4,96g cht rn v hh kh X. Hp th hon ton X vo nc c 300 ml dd Y. Dd Y c
pH bng
A. 4.
B. 2.
C. 1.
D. 3.
Cu 51. (B-07) 29: Trong phng th nghim, ngi ta thng iu ch HNO3 t
A. NaNO2 v H2SO4 c.
B. NaNO3 v H2SO4 c.
C. NH3 v O2.
D. NaNO3 v HCl c.
Thng k H 2007-2014
Cu 52. (A-07) 44: Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta
un nng dd amoni nitrit bo ho. Kh X l
A. NO.
B. NO2.
C. N2O.
D. N2.
Cu 53. (A-11) 59: Khng kh trong phng th nghim b nhim bi kh clo. kh c, c th xt
vo khng kh dung dch no sau y?
A. Dung dch NaOH.
B. Dung dch NaCl.
C. Dung dch NH3.
D. Dung dch H2SO4 long.
Cu 54. (B-13) 51: Ha tan mt kh X vo nc, thu c dung dch Y. Cho t t dung dch Y n d
vo dung dch ZnSO4, ban u thy c kt ta trng, sau kt ta tan ra. Kh X l
A. NO2.
B. HCl.
C. SO2.
D. NH3.
Cu 55. (A-13) 42: Th nghim vi dung dch HNO3 thng sinh ra kh c NO2. hn ch kh
NO2 thot ra t ng nghim, ngi ta nt ng nghim bng:
(a) bng kh.
(b) bng c tm nc.
(c) bng c tm nc vi.
(d) bng c tm gim n.
Trong 4 bin php trn, bin php c hiu qu nht l
A. (b).
B. (d).
C. (c).
D. (a).
- trong dung dch Ba(NO3)2, ngi ta un nng nh dd vi:
(C-11)
nhn
ra
ion
NO
3
Cu 56.
A. kim loi Cu.
B. dung dch H2SO4 long.
C. kim loi Cu v dung dch Na2SO4.
D. kim loi Cu v dung dch H2SO4 long.
Cu 57. (A-10) 22: Hh kh X gm N2 v H2 c t khi so vi He bng 1,8. un nng X mt thi gian
trong bnh kn (c bt Fe lm xc tc), thu c hh kh Y c t khi so vi He bng 2. Hiu sut ca p
tng hp NH3 l
A. 25%.
B. 50%.
C. 36%.
D. 40%.
Cu 58. (A-10) 60: Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng, thu c
cht rn X (gi s p xy ra hon ton). Phn trm khi lng ca Cu trong X l
A. 85,88%.
B. 14,12%.
C. 87,63%.
D. 12,37%.
Cu 59. (B-14): Nung nng bnh kn cha a mol hn hp NH3 v O2 (c xc tc Pt) chuyn ton b
NH3 thnh NO. Lm ngui v thm nc vo bnh, lc u thu c 1 lt dung dch HNO3 c pH = 1,
cn li 0,25 mol kh O2. Bit cc phn ng xy ra hon ton. Gi tr ca a l
A. 0,1
B. 0,4
C. 0,3
D. 0,2
Cu 60. (B-14): Trong cng nghip, sn xut axit H3PO4 c tinh khit v nng cao, ngi ta
lm cch no sau y?
A. Cho dung dch H2SO4 c, nng tc dng vi qung apatit.
B. t chy photpho trong oxi d, cho sn phm tc dng vi nc.
C. Cho photpho tc dng vi dung dch HNO3 c, nng.
D. Cho dung dch axit H2SO4 c, nng tc dng vi qung photphorit
Cu 61. (A-14): T 6,2 kg photpho iu ch c bao nhiu lt dung dch H3PO4 2M (hiu sut ton
b qu trnh iu ch l 80%)
A. 100 lt
B. 80 lt
C. 40 lt
D. 64 lt
Cu 62. (B-14): Cho m gam P2O5 tc dng vi 253,5 ml dung dch NaOH 2M, sau khi cc phn ng
xy ra hon ton thu c dung dch X. C cn dung dch X, thu c 3m gam cht rn khan. Gi tr
ca m l
A. 21,30
B. 8,52
C. 12,78
D. 7,81
Phn bn ha hc
Cu 63. (C-09) 44: Phn bn nitrophotka (NPK) l hn hp ca
A. (NH4)2HPO4 v KNO3.
B. NH4H2PO4 v KNO3.
C. (NH4)3PO4 v KNO3.
D. (NH4)2HPO4 v NaNO3p.
Cu 64. (B-08) 17: Thnh phn chnh ca qung photphorit l
A. Ca3(PO4) 2.
B. NH4H2PO4.
C. Ca(H2PO4) 2.
Cu 65. (B-09) 57: Phn bn no sau y lm tng chua ca t?
A. KCl.
B. NH4NO3.
C. NaNO3.
D. CaHPO4.
D. K2CO3.
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Cu 66. (A-09) 49: Pht biu no sau y l ng?

+
A. Phn ln cung cp nit ho hp cho cy di dng ion nitrat (NO3 ) v ion amoni (NH4 ).
B. Amophot l hh cc mui (NH4) 2HPO4 v KNO3.
C. Phn hh cha nit, photpho, kali c gi chung l phn NPK.
D. Phn ur c cng thc l (NH4)2CO3. .

A. Thnh phn chnh ca supephotphat kp gm hai mui Ca(H2PO4)2 v CaSO4.
B. Ur c cng thc l (NH2)2CO.
C. Supephotphat n ch c Ca(H2PO4)2.
D. Phn ln cung cp nit cho cy trng.
Cu 68. (C-12) 12: Thnh phn chnh ca phn bn phc hp amophot l
A. Ca3(PO4)2 v (NH4)2HPO4.
B. NH4NO3 v Ca(H2PO4)2.
C. NH4H2PO4 v (NH4)2HPO4.
D. NH4H2PO4 v Ca(H2PO4)2.
Cu 69. (B-10) 16: Mt loi phn supephotphat kp c cha 69,62% mui canxi ihirophotphat,
cn li gm cc cht khng cha photpho. dinh dng ca loi phn ln ny l
A. 48,52%.
B. 42,25%.
C. 39,76%.
D. 45,75%.
Cu 70. (A-12) 5: Mt loi phn kali c thnh phn chnh l KCl (cn li l cc tp cht khng cha
kali) c sn xut t qung xinvinit c dinh dng 55%. Phn trm khi lng ca KCl trong loi
phn kali l
A. 95,51%.
B. 65,75%.
C. 87,18%.
D. 88,52%.
Cu 71. (A-08) 39: Cho Cu v dd H2SO4 long t/d vi cht X (mt loi phn bn ha hc), thy
thot ra kh khng mu ha nu trong khng kh. Mt khc, khi X t/d vi dd NaOH th c kh mi
khai thot ra. Cht X l
A. amophot.
B. ure.
C. natri nitrat.
D. amoni nitrat.
Cu 72. (B-08) 41: Cho 0,1 mol P2O5 vo dd cha 0,35 mol KOH. Dd thu c c cc cht:
A. K3PO4, K2HPO4.
B. K2HPO4, KH2PO4.
C. K3PO4, KOH.
D. H3PO4, KH2PO4.
Cu 73. (C-12) 49: Cho 1,42 gam P2O5 tc dng hon ton vi 50 ml dung dch KOH 1M, thu c
dung dch X. C cn dung dch X thu c cht rn khan gm
A. K3PO4 v KOH.
B. K2HPO4 v K3PO4.
C. KH2PO4 v K2HPO4.
D. H3PO4 v KH2PO4.
Cu 74. (B-09) 49: Cho 100 ml dd KOH 1,5M vo 200 ml dd H3PO4 0,5M, thu c dd X. C cn dd
X, thu c hh gm cc cht l
C. KH2PO4 v H3PO4.
D. K3PO4 v
A. KH2PO4 v K3PO4. B. KH2PO4 v K2HPO4.
KOH.
H3 PO 4
KOH
KOH
Y
Z
Cu 75. (B-10) 35: Cho s chuyn ho:
P2O5 X
Cc cht X, Y, Z ln lt l:
A. K3PO4, K2HPO4, KH2PO4.
C. K3PO4, KH2PO4, K2HPO4.
B. KH2PO4, K2HPO4, K3PO4.
D. KH2PO4, K3PO4, K2HPO4.
Cu 76. (A-13) 6: Oxi ha hon ton 3,1 gam photpho trong kh oxi d. Cho ton b sn phm vo
200 ml dung dch NaOH 1M n khi phn ng xy ra hon ton, thu c dung dch X. Khi lng mui
trong X l
A. 12,0 gam.
B. 14,2 gam.
C. 11,1 gam.
D. 16,4 gam.
4.4. CACBON - SILIC

Cu 77. (A-11) 8: Trong cc th nghim sau:
(1) Cho SiO2 tc dng vi axit HF.
(2) Cho kh SO2 tc dng vi kh H2S.
(3) Cho kh NH3 tc dng vi CuO un nng.
(4) Cho CaOCl2 tc dng vi dung dch HCl c.
(5) Cho Si n cht tc dng vi dung dch NaOH.
Thng k H 2007-2014
(6) Cho kh O3 tc dng vi Ag.

(7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng.
S th nghim to ra n cht l
A. 7.
B. 6.
C. 5.
D. 4.

A. Dd m c ca Na2SiO3 v K2SiO3 c gi l thy tinh lng.
B. m chy magie c th c dp tt bng ct kh.
C. CF2Cl2 b cm s dng do khi thi ra kh quyn th ph hy tng ozon.
D. Trong phng th nghim, N2 c iu ch bng cch un nng dd NH4NO2 bo ho.
Cu 79. (A-11) 49: Nhm nhng cht kh (hoc hi) no di y u gy hiu ng nh knh khi
nng ca chng trong kh quyn vt qu tiu chun cho php?
A. CH4 v H2O.
B. CO2 v CH4.
C. N2 v CO.
D. CO2 v O2.
Cu 80. (A-14): Cht kh no sau y c to ra t bnh cha chy v dng sn xut thuc gim
au d dy?
A. N2
B. CO
C. CH4
D. CO2
A. Clo c dng dit trng nc trong h thng cung cp nc sch.
B. Amoniac c dng iu ch nhin liu cho tn la.
C. Lu hunh ioxit c dng lm cht chng nm mc.
D. Ozon trong khng kh l nguyn nhn chnh gy ra s bin i kh hu.
Cu 82. (B-12) 52: Mt mu kh thi c sc vo dung dch CuSO4, thy xut hin kt ta mu
en. Hin tng ny do cht no c trong kh thi gy ra?
A. H2S.
B. NO2.
C. SO2.
D. CO2.
Cu 83. (C -14): loi b cc kh HCl, CO2 v SO2 c ln trong kh N2, ngi ta s dng lng d
dung dch
A. NaCl
B. CuCl2
C. Ca(OH)2
D. H2SO4
Cu 84. (A-13) 10: iu kin thch hp xy ra cc phn ng sau:
(a) 2C + Ca CaC2
(b) C + 2H2 CH4
(c) C+ CO2 2CO
(d) 3C + 4Al Al4C3
Trong cc phn ng trn, tnh kh ca cacbon th hin phn ng
A. (c).
B. (b).
C. (d).
D. (a).
Cu 85. (B-14): Cho dy chuyn ha sau:
CO2 H2O
NaOH
X
Y
X . Cng thc ca X l
A. NaOH
B. Na2CO3
C.NaHCO3
D. Na2O.
Cu 86. (C-13) 35: Pht biu no di y khng ng?
A. SiO2 l oxit axit.
B. t chy hon ton CH4 bng oxi, thu c CO2 v H2O.
C. Sc kh CO2 vo dung dch Ca(OH)2 d, dung dch b vn c.
D. SiO2 tan tt trong dung dch HCl.
Thng k H 2007-2014
5. I CNG V KIM LOI

5. 1. Dy in ha ca kim loi
Cu 1. (C-07) 51: Cho cc ion kim loi: Zn2+, Sn2+, Ni2+, Fe2+, Pb2+. Th t tnh oxi ho gim dn l
A. Pb2+ > Sn2+ > Fe2+ > Ni2+ > Zn2+.
B. Sn2+ > Ni2+ > Zn2+ > Pb2+ > Fe2+.
C. Zn2+ > Sn2+ > Ni2+ > Fe2+ > Pb2+.
D. Pb2+ > Sn2+ > Ni2+ > Fe2+ > Zn2+.
Cu 2. (C-07) 8: Th t mt s cp oxi ho - kh trong dy in ho nh sau: Fe2+/Fe; Cu2+/Cu;
Fe3+/Fe2+.
Cp cht khng p vi nhau l
A. Fe v dd CuCl2.
B. Fe v dd FeCl3.
C. dd FeCl2 v dd CuCl2. D. Cu v dd FeCl3.
Cu 3. (C-10) 18: Cho bit th t t tri sang phi ca cc cp oxi ho - kh trong dy in ho
(dy th in cc chun) nh sau: Zn2+/Zn; Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Cc kim loi v ion
u p c vi ion Fe2+ trong dd l:
A. Zn, Ag+.
B. Ag, Cu2+.
C. Ag, Fe3+.
D. Zn, Cu2+.
Cu 4. (A-07) 46: Mnh khng ng l:
2+ + 2+ +
2+
A. Tnh oxi ha ca cc ion tng theo th t: Fe , H , Cu , Ag .
B. Fe kh c Cu
trong
dd.
3+
D. Fe c tnh oxi ha mnh
oxi ho c Cu.
2+
hn Cu .
Cu 5. (C-08) 52: Hai kim loi X, Y v cc dung dch mui clorua ca chng c cc phn ng ha
hc sau:
X + 2YCl3 XCl2 + 2YCl2;
Y + XCl2 YCl2 + X.
Pht biu ng l:
A. Ion Y2+ c tnh oxi ha mnh hn ion X2+.
B. Kim loi X kh c ion Y2+.
E. Kim loi X c tnh kh mnh hn kim loi Y.
D. Ion Y3+ c tnh oxi ha mnh hn ion X2 +.
Cu 6. (B-07) 26: Cho cc p xy ra sau y:
(2)
Mn + 2HCl MnCl2 + H2
(1) AgNO3 + Fe(NO3) 2 Fe(NO3)3 + Ag
Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l
2+ + 3+ +
+ 3+ +
2+
A. Mn , H , Fe , Ag .
B. Ag , Fe , H , Mn .
+
2+ + 3+
2+ + + 3+
C. Ag , Mn , H , Fe .
D. Mn , H , Ag , Fe .
Cu 7. (A-07) 18: Dy cc ion xp theo chiu gim dn tnh oxi ho l (bit trong dy in ha, cp
3+
2+
+
Fe /Fe ng trc cp Ag /Ag):
3+ 2+ + 2+
+ 2+ 3+ 2+
A. Fe , Cu , Ag , Fe .
B. Ag , Cu , Fe , Fe .
3+ + 2+ 2+
+ 3+ 2+ 2+
C. Fe , Ag , Cu , Fe .
D. Ag , Fe , Cu , Fe .
Cu 8. (C-11) 44: Dy gm cc ion u oxi ha c kim loi Fe l
A. Fe 3+ , Cu 2+ , Ag + .
B. Zn 2+ , Cu 2+ , Ag + . C. Cr 2+ , Au 3+ , Fe 3+ . D. Cr 2+ , Cu 2+ , Ag + .
C. Fe
2+
Cu 9. (C-12) 35: Cho dy cc ion: Fe2+ , Ni2+, Cu2+, Sn2+. Trong cng iu kin, ion c tnh oxi
ha mnh nht trong dy l
A. Sn2+.
B. Cu2+.
C. Fe2+.
D. Ni2+.
Cu 10. (A-08) 36: X l kim loi p c vi dd H2SO4 long, Y l kim loi t/d c vi dd
3+
2+
Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe /Fe
ng trc
+
Ag /Ag)
A. Fe, Cu.
B. Cu, Fe.
C. Ag, Mg.
D. Mg, Ag.
Cu 11. (C-09) 52: Th t mt s cp oxi ho - kh trong dy in ho nh sau: Mg2+/Mg; Fe2+/Fe;
Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Dy ch gm cc cht, ion tc dng c vi ion Fe3+ trong dung dch l:
A. Fe, Cu, Ag+.
B. Mg, Fe2+, Ag.
C. Mg, Cu, Cu2+.
D. Mg, Fe, Cu.
Cu 12. (B-08)1: Cho bit cc p xy ra sau:
2NaBr + Cl2 2NaCl + Br2
2FeBr2 + Br2 2FeBr3
Pht biu ng l:
A. Tnh kh ca Cl mnh hn ca Br .
B. Tnh oxi ha ca Br2 mnh hn ca Cl2.
Thng k H 2007-2014
2+
3+
C. Tnh kh ca Br mnh hn ca Fe .
D. Tnh oxi ha ca Cl2 mnh hn ca Fe .
Fe + 2Fe(NO3)3 3Fe(NO3)2
AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag
Dy sp xp theo th t tng dn tnh oxi ho ca cc ion kim loi l:
A. Fe2+, Ag+, Fe3+. B. Ag+, Fe2+, Fe3+.
C. Fe2+, Fe3+, Ag+.
D. Ag+, Fe3+, Fe2+.
Cu 14. (A-12) 32: Cho cc cp oxi ho - kh c sp xp theo chiu tng dn tnh oxi ho ca dng
oxi ha nh sau: Fe2+/Fe, Cu2+/Cu, Fe3+/Fe2+. Pht biu no sau y l ng?
A. Fe2+ oxi ha c Cu thnh Cu2+.
B. Cu2+ oxi ho c Fe2+ thnh Fe3+.
C. Fe3+ oxi ha c Cu thnh Cu2+.
D. Cu kh c Fe2+ thnh Fe.
Cu 15. (B-13) 45: Cho phng trnh ha hc ca phn ng: 2Cr + 3Sn2+ 2Cr3+ + 3Sn.
Nhn xt no sau y v phn ng trn l ng?
A. Sn2+ l cht kh, Cr3+ l cht oxi ha.
B. Cr l cht oxi ha, Sn2+ l cht kh.
C. Cr l cht kh, Sn2+ l cht oxi ha.
D. Cr3+ l cht kh, Sn2+ l cht oxi ha.
Cu 16. (A-13) 44: Cho cc cp oxi ha - kh c sp xp theo th t tng dn tnh oxi ha ca
cc ion kim loi: Al3+/Al; Fe2+/Fe; Sn2+/Sn; Cu2+/Cu. Tin hnh cc th nghim sau:
(a) Cho st vo dung dch ng(II) sunfat.
(b) Cho ng vo dung dch nhm sunfat.
(c) Cho thic vo dung dch ng(II) sunfat.
(d) Cho thic vo dung dch st(II) sunfat.
Trong cc th nghim trn, nhng th nghim c xy ra phn ng l:
A. (b) v (c).
B. (b) v (d).
C. (a) v (c).
D. (a) v (b).
5.2. PHN NG C TRNG CA KIM LOI

Cu 17. (C-07) 33: Cho kim loi M t/d vi Cl2 c mui X; cho kim loi M t/d vi dd HCl c mui
Y. Nu cho kim loi M t/d vi dd mui X ta cng c mui Y. Kim loi M c th l
A. Mg.
B. Zn.
C. Al.
D. Fe.
Cu 18. (C-11) 3: Dy gm cc kim loi u tc dng c vi dung dch HCl nhng khng tc
dng vi dung dch HNO3 c, ngui l:
A. Cu, Fe, Al.
B. Fe, Al, Cr.
C. Cu, Pb, Ag.
D. Fe, Mg, Al.
Cu 19. (A-14): Kim loi no sau y khng tc dng vi dung dch H2SO4 long?
A. Cu
B. Na
C. Mg
D. Al
Cu 20. (C-08) 47: Cp cht khng xy ra phn ng ho hc l
A. Cu + dung dch FeCl3.
B. Fe + dung dch HCl. C. Fe + dung dch FeCl3.
D. Cu + dung dch
FeCl2.
Cu 21. (A-10) 47: Cc cht va t/d c vi dd HCl va t/d c vi dd AgNO3 l:
A. MgO, Na, Ba.
B. Zn, Ni, Sn.
C. Zn, Cu, Fe.
D. CuO, Al, Mg.
Cu 22. (C-08) 29: Kim loi M p c vi: dd HCl, dd Cu(NO3)2, dd HNO3 (c, ngui). Kim loi M
l
A. Al.
B. Zn.
C. Fe.
D. Ag.
Cu 23. (C-08) 39: Cho hh bt Al, Fe vo dd cha Cu(NO3)2 v AgNO3. Sau khi cc p xy ra hon
ton, thu c hh rn gm ba kim loi l:
A. Fe, Cu, Ag.
B. Al, Cu, Ag.
C. Al, Fe, Cu.
D. Al, Fe, Ag.
Cu 24. (A-09) 31: Cho hh gm Fe v Zn vo dd AgNO3 n khi cc p xy ra hon ton, thu c
dd X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l
A. Fe(NO3)3 v Zn(NO3) 2.
B. Zn(NO3)2 v Fe(NO3) 2.
C. AgNO3 v Zn(NO3) 2.
D. Fe(NO3)2 v AgNO3
Cu 25. (A-12) 46: Cho hn hp gm Fe v Mg vo dung dch AgNO3, khi cc phn ng xy ra hon
ton thu c dung dch X (gm hai mui) v cht rn Y (gm hai kim loi). Hai mui trong X l
A. Mg(NO3)2 v Fe(NO3)2.
B. Fe(NO3)3 v Mg(NO3)2.
C. AgNO3 v Mg(NO3)2.
D. Fe(NO3)2 v AgNO3.
Thng k H 2007-2014
Cu 26. (B-14): Cho bt Fe vo dung dch AgNO3 d, sau khi phn ng xy ra hon ton, thu c
dung dch gm cc cht tan:
A. Fe(NO3)2, AgNO3, Fe(NO3)3.
B. Fe(NO3)2, AgNO3.
C. Fe(NO3)3, AgNO3.
D. Fe(NO3)2, Fe(NO3)3.
Cu 27. (A-13) 7: Cho bt Fe vo dung dch gm AgNO3 v Cu(NO3)2. Sau khi cc phn ng xy ra
hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X v
hai kim loi trong Y ln lt l:
A. Fe(NO3)2; Fe(NO3)3 v Cu; Ag.
B. Cu(NO3)2; Fe(NO3)2 v Cu; Fe.
C. Cu(NO3)2; Fe(NO3)2 v Ag; Cu.
D. Cu(NO3)2; AgNO3 v Cu; Ag.
Cu 28. (C-09) 35: Dy no sau y ch gm cc cht va t/d c vi dd HCl, va t/d c vi dd
AgNO3?
A. Fe, Ni, Sn.
B. Al, Fe, CuO.
C. Zn, Cu, Mg.
D. Hg, Na, Ca.
Cu 29. (C-13) 60: Kim loi Ni u phn ng c vi cc dung dch no sau y?
A. MgSO4, CuSO4.
B. NaCl, AlCl3.
C. CuSO4, AgNO3.
D. AgNO3, NaCl.
5.3. iu ch kim loi
Cu 30. (C-09) 37: Nguyn tc chung c dng iu ch kim loi l

A. cho hp cht cha ion kim loi t/d vi cht kh.
B.oxi ho ion kim loi trong hp cht thnh nguyn t kim loi.
C. kh ion kim loi trong hp cht thnh nguyn t kim loi.
D. cho hp cht cha ion kim loi t/d vi cht oxi ho.
Cu 31. (C-07) 23: kh ion Cu2+ trong dd CuSO4 c th dng kim loi
A. Fe.
B. Na.
C. K.
D. Ba.
Cu 32. (C-14): Phn ng no sau y l phn ng iu ch kim loi bng phng php nhit luyn
t0
A. Mg + FeSO4 MgSO4 + Fe
B. CO + CuO
Cu + CO2
C. CuCl2
D. 2Al2O3
Cu + Cl2
4Al + 3O2
Cu 33. (C-07) 4: kh ion Fe3+ trong dd thnh ion Fe2+ c th dng mt lng d
A. kim loi Mg.
B. kim loi Cu.
C. kim loi Ba.
D. kim loi Ag.
Cu 34. (A-07)Cho lung kh H2 (d) qua hh cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao.
Sau p hh rn cn li l:
A. Cu, FeO, ZnO, MgO.
B. Cu, Fe, Zn, Mg.
C. Cu, Fe, Zn, MgO.
D. Cu, Fe, ZnO, MgO.
Cu 35. (C-07) 13: Cho kh CO (d) i vo ng s nung nng ng hh X gm Al2O3, MgO, Fe3O4, CuO thu
c cht rn Y. Cho Y vo dd NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc p xy ra
hon ton. Phn khng tan Z gm
A. MgO, Fe, Cu.
B. Mg, Fe, Cu.
C. MgO, Fe3O4, Cu. D. Mg, Al, Fe, Cu.
Cu 36. (B-07) 36: thu c Al2O3 t hh Al2O3 v Fe2O3, ngi ta ln lt:
A. dng kh H2 nhit cao, dd NaOH (d).
B. dng kh CO nhit cao, dd HCl (d).
C. dng dd NaOH (d), dd HCl (d), ri nung nng.
D. dng dd NaOH (d), kh CO2 (d), ri nung
nng.
Cu 37. (C-08) 48: Hai kim loi c th c iu ch bng phng php in phn dung dch l
A. Al v Mg.
B. Na v Fe.
C. Cu v Ag.
D. Mg v Zn.
Cu 38. (A-07) Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn
hp cht nng chy ca chng l:
A. Fe, Ca, Al.
B. Na, Ca, Al.
C. Na, Cu, Al.
D. Na, Ca, Zn.
Cu 39. (A-09) Dy cc kim loi u c th c iu ch bng phng php in phn dd mui
ca chng l:
A. Fe, Cu, Ag.
B. Mg, Zn, Cu.
C. Al, Fe, Cr.
D. Ba, Ag, Au.
Cu 40. (A-12) 8: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch
mui (vi in cc tr) l:
A. Ni, Cu, Ag.
B. Ca, Zn, Cu.
C. Li, Ag, Sn.
D. Al, Fe, Cr.
Cu 41. (C-11) 36: Dy gm cc oxit u b Al kh nhit cao l:
A. FeO, MgO, CuO.
B. PbO, K2O, SnO.
C. Fe3O4, SnO, BaO.
D. FeO, CuO, Cr2O3
Cu 42. (C-10) 48: Kim loi M c th c iu ch bng cch kh ion ca n trong oxit bi kh H 2
nhit cao. Mt khc, kim loi M kh c ion H+ trong dung dch axit long thnh H2. Kim loi M l
A. Cu.
B. Mg.
C. Fe.
D. Al.
Cu 43. (B-12) 58: Trng hp no sau y to ra kim loi?
dpdd
dpnc
Thng k H 2007-2014
A. t FeS2 trong oxi d.

B. Nung hn hp qung apatit, x vn v than cc trong l ng.
C. t Ag2S trong oxi d.
D. Nung hn hp qung photphorit, ct v than cc trong l in.
Cu 44. (C-12) 32: Kim loi no sau y iu ch c bng phng php thy luyn?
A. Mg.
B. Ca.
C. Cu.
D. K.
Cu 45. (B-13) 8: Cho s phn ng: Al2(SO4)3 X Y Al.

Trong s trn, mi mi tn l mt phn ng, cc cht X, Y ln lt l nhng cht no sau y?
A. NaAlO2 v Al(OH)3.
B. Al(OH)3 v NaAlO2.
C. Al2O3 v Al(OH)3.
D. Al(OH)3 v Al2O3.
5.4. Bi ton kh cc oxit kim loi bng kh CO, H2
Cu 46. (A-09) 16: Cho lung kh CO (d) i qua 9,1 gam hh gm CuO v Al2O3 nung nng n khi
p hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hh ban u l
A. 0,8 gam.
B. 8,3 gam.
C. 2,0 gam.
D. 4,0 gam.
Cu 47. (A-08) 22: Cho V lt hh kh ( ktc) gm CO v H2 p vi mt lng d hh rn gm CuO v
Fe3O4 nung nng. Sau khi cc p xy ra hon ton, khi lng hh rn gim 0,32 gam. Gi tr ca V l
A. 0,448.
B. 0,112.
C. 0,224.
D. 0,560.
Cu 48. (C-07) 46: Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit
st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20.
Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l
A. FeO; 75%.
B. Fe2O3; 75%.
C. Fe2O3; 65%.
D. Fe3O4; 75%.
Cu 49. (C-08) 17: Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hh rn gm CuO,
Fe2O3 ( nhit cao). Sau khi cc p xy ra hon ton, thu c kh X. Dn ton b kh X trn vo
lng d dd Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l
A. 1,120.
B. 0,896.
C. 0,448.
D. 0,224.
Cu 50. (B-10) 46: Hh X gm CuO v Fe2O3. Ho tan hon ton 44 gam X bng dd HCl (d), sau p thu
c dd cha 85,25 gam mui. Mt khc, nu kh hon ton 22 gam X bng CO (d), cho hh kh thu
c sau p li t t qua dd Ba(OH)2 (d) th thu c m gam kt ta. Gi tr ca m l
A. 76,755.
B. 73,875.
C. 147,750.
D. 78,875.
Cu 51. (C-09) 38: Kh hon ton mt oxit st X nhit cao cn va V lt kh CO ( ktc), sau
p thu c 0,84 gam Fe v 0,02 mol kh CO2. Cng thc ca X v gi tr V ln lt l
A. Fe3O4 v 0,224.
B. Fe3O4 v 0,448.
C. FeO v 0,224.
D. Fe2O3 v
0,448.
Cu 52. (B-10) 7: Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc), thu c a gam
kim loi M. Ho tan ht a gam M bng dd H2SO4 c nng (d), thu c 20,16 lt kh SO2 (sn phm
kh duy nht, ktc). Oxit MxOy l
A. Cr2O3.
B. FeO.
C. Fe3O4.
D. CrO.
Cu 53. (B-11) 33: Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm
CO, CO2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y.
Ho tan ton b Y bng dung dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht,
ktc). Phn trm th tch kh CO trong X l
A. 57,15%.
B. 14,28%.
C. 28,57%.
D. 18,42%.
Cu 54. (B-12) 40: Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt
thi gian thu c cht rn X v kh Y. Cho Y hp th hon ton vo dung dch Ba(OH)2 d, thu
c 29,55 gam kt ta. Cht rn X phn ng vi dung dch HNO3 d thu c V lt kh NO (sn
phm kh duy nht, ktc). Gi tr ca V l
A. 2,24.
B. 4,48.
C. 6,72.
D. 3,36.
5.5. Bi ton kim loi tc dng vi phi kim

Cu 55. (C-11) 28: t chy hon ton 17,4 gam hn hp Mg v Al trong kh oxi (d) thu c
30,2 gam hn hp oxit. Th tch kh oxi (ktc) tham gia phn ng l
Thng k H 2007-2014
A. 4,48 lt.
B. 8,96 lt.
C. 17,92 lt.
D. 11,20 lt.
Cu 56. (C-09) 32: t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht)
trong hh kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hh kh p l 5,6 lt (
ktc). Kim loi M l
A. Mg.
B. Ca.
C. Be.
D. Cu.
Cu 57. (C-14): Cho kim loi M phn n g vi Cl2, thu c mui X. Cho M tc dng vi dung dch
HCl, thu c mui Y. Cho Cl2 tc dng vi dung dch mui Y, thu c mui X. Kim loi M l
A. Fe
B. Al
C. Zn
D. Mg
Cu 58. (C-13) 3: Cho 7,84 lt hn hp kh X (ktc) gm Cl2 v O2 phn ng va vi 11,1 gam
hn hp Y gm Mg v Al, thu c 30,1 gam hn hp Z. Phn trm khi lng ca Al trong Y l
A. 75,68%.
B. 24,32%.
C. 51,35%.
D. 48,65%.
Cu 59. (C -14): t chy 11,9 gam hn hp gm Zn, Al trong kh Cl2 d. Sau khi cc phn ng xy
ra hon ton, thu c 40,3 gam hn hp mui. Th tch kh Cl2 (ktc) phn ng l
A. 8,96 lt
B. 6,72 lt
C. 17,92 lt
D. 11,2 lt
Cu 60. (C-12) 55: Oxi ho hon ton m gam kim loi X cn va 0,25m gam kh O2. X l kim loi no
sau y?
A. Cu.
B. Ca.
C. Al.
D. Fe.
5.6. in phn
Cu 61. (A-08) 5: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra
A. s kh ion Cl-.
B. s oxi ho ion Cl-.
C. s oxi ho ion Na+. D. s kh ion Na+.
Cu 62. (C-07) 17: Trong cng nghip, natri hiroxit c sn xut bng phng php
A. in phn dd NaCl, khng c mng ngn in cc.
C. in phn dd NaCl, c mng ngn
in cc.
B. in phn dd NaNO3, khng c mng ngn in cc.
D. in phn NaCl nng chy.
Cu 63. (A-10) 37: P in phn dd CuCl2 (vi in cc tr) v p n mn in ho xy ra khi nhng
hp kim Zn-Cu vo dd HCl c c im l:
A. P cc m c s tham gia ca kim loi hoc ion kim loi. B. P cc dng u l s oxi ho Cl-.
C. u sinh ra Cu cc m.
D. P xy ra lun km theo s pht sinh dng in
Cu 64. (A-11) 50:Khi in phn dd NaCl (cc m bng st, cc dng bng than ch, c mng
ngn xp) th
A. cc m xy ra qu trnh oxi ho H2O v cc dng xy ra qu trnh kh ion Cl .

B. cc dng xy ra qu trnh oxi ho ion Na+ v cc m xy ra qu trnh kh ion Cl .
C. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ho ion Cl .

+
D. cc m xy ra qu trnh kh ion Na v cc dng xy ra qu trnh oxi ho ion Cl
Cu 65. (C-10) 59: in phn dung dch CuSO4 vi anot bng ng (anot tan) v in phn dung
dch CuSO4 vi anot bng graphit (in cc tr) u c c im chung l
A. catot xy ra s kh: Cu2+ + 2e Cu.
B. catot xy ra s oxi ho: 2H2O + 2e
2OH + H2.
C. anot xy ra s kh: 2H 2O O2 + 4H+ + 4e.
D. anot xy ra s oxi ho: Cu Cu2+ + 2e.
Cu 66. (A-10) 42: in phn (vi in cc tr) mt dd gm NaCl v CuSO4 c cng s mol, n khi
catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c
anot l
A. kh Cl2 v H2.
B. kh Cl2 v O2.
C. ch c kh Cl2.
D. kh H2 v O2
Cu 67. Cho cc phn ng xy ra theo s sau:
X1 + H2O
Dien phan
X2 + X3 + H2
Co mang ngan
BaCO3 + K2CO3 + H2O

X2 + X4
Hai cht X2, X4 ln lt l:
A. KOH, Ba(HCO3)2
B. NaOH, Ba(HCO3)2
C. KHCO3, Ba(OH)2
D. NaHCO3, Ba(OH)2
Cu 68. (A-11) 1: in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr,
Thng k H 2007-2014
mng ngn xp) n khi khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit
lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l
A. KNO3, HNO3 v Cu(NO3)2.
B. KNO3, KCl v KOH.
C. KNO3 v Cu(NO3)2.
D. KNO3 v KOH.
(A-07)
40:
in
phn
dd
CuCl
vi
in
cc
tr,
sau mt thi gian thu c 0,32 gam Cu
Cu 69.
2
catt v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dd NaOH ( nhit
thng). Sau p, nng NaOH cn li l 0,05M (gi thit th tch dd khng thay i). Nng ban
u ca dd NaOH l (cho Cu = 64)
A. 0,2M.
B. 0,1M.
C. 0,05M.
D. 0,15M
Cu 70. (B-07) 32in phn dd cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn xp).
dd sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l (bit ion SO 42khng b in phn trong dd)
A. b > 2a.
B. b = 2a.
C. b < 2a.
D. 2b = a.
Cu 71. (B-09) 2: in phn c mng ngn 500 ml dd cha hh gm CuCl2 0,1M v NaCl 0,5M
(in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dd thu c
sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05.
B. 2,70.
C. 1,35.
D. 5,40
Cu 72. (C -14): in phn dung dch hn hp CuSO4 (0.05 mol) v NaCl bng dng in c
cng khng i 2A (in cc tr, mng ngn xp). Sau thi gian t giy th ngng in phn, thu
c dung dch Y v kh hai in cc c tng th tch l 2,24 lt (ktc). Dung dch Y ha tan ti a
0,8 gam MgO. Bit hiu sut in phn 100%, cc kh sinh ra khng tan trong dung dch. Gi tr ca t
l
A. 6755
B. 772
C. 8685
D. 4825
Cu 73. (A-14): in phn dung dch X cha a mol CuSO4 v 0,2 mol KCl (in cc tr, mng ngn
xp, cng dng in khng i) trong thi gian t giy, thu c 2,464 lt kh anot (ktc). Nu
thi gian in phn l 2t giy th tng th tch kh thu c c hai in cc l 5,824 lt (ktc). Bit
hiu sut in phn 100%, cc kh sinh ra khng tan trong dung dch. Gi tr ca a l
A. 0,26
B. 0,24
C. 0,18
D. 0,15
Cu 74. (A-13) 9: Tin hnh in phn dung dch cha m gam hn hp CuSO4 v NaCl (hiu sut
100%, in cc tr, mng ngn xp), n khi nc bt u b in phn c hai in cc th
ngng in phn, thu c dung dch X v 6,72 lt kh (ktc) anot. Dung dch X ha tan ti a
20,4 gam Al2O3. Gi tr ca m l
A. 25,6.
B. 50,4.
C. 51,1.
D. 23,5.
Cu 75. (A-10) 54: in phn (in cc tr) dd X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng
in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l
A. 1,344 lt.
B. 2,240 lt.
C. 1,792 lt.
D.
2,912 lt.
Cu 76. (B-10) 21: in phn (vi in cc tr) 200 ml dd CuSO4 nng x mol/l, sau mt th i gian
thu c dd Y vn cn mu xanh, c khi lng gim 8 gam so vi dd ban u. Cho 16,8 gam bt st
vo Y, sau khi cc p xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l
A. 2,25.
B. 1,50.
C. 1,25.
D. 3,25.
Cu 77. (C-11) 13: in phn 500 ml dung dch CuSO4 0,2M (in cc tr) cho n khi catot
thu c 3,2 gam kim loi th th tch kh (ktc) thu c anot l
A. 2,24 lt.
B. 3,36 lt.
C. 0,56 lt.
D. 1,12 lt.
Cu 78. (A-11) 16: Ho tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi
in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy
nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu
c c hai in cc l 0,1245 mol. Gi tr ca y l
A. 4,788.
B. 4,480.
C. 1,680.
D. 3,920.
Cu 79. (B-09) 9: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c
m kg Al catot v 67,2 m3 ( ktc) hh kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hh kh
X sc vo dd nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l
A. 108,0.
B. 75,6.
C. 54,0.
D. 67,5.
Cu 80. (B-13) 18: in phn nng chy Al2O3 vi cc in cc bng than ch, thu c m kilogam
Thng k H 2007-2014
Al catot v 89,6 m3 (ktc) hn hp kh X anot. T khi ca X so vi H2 bng 16,7. Cho 1,12 lt

X (ktc) phn ng vi dung dch Ca(OH)2 d, thu c 1,5 gam kt ta. Bit cc phn ng xy ra
hon ton. Gi tr ca m l
A. 144,0.
B. 104,4.
C. 82,8.
D. 115,2.
Cu 81. (A-12) 20: in phn 150 ml dung dch AgNO3 1M vi in cc tr trong t gi, cng
dng in khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht rn X, dung dch Y
v kh Z. Cho 12,6 gam Fe vo Y, sau khi cc phn ng kt thc thu c 14,5 gam hn hp kim loi
v kh NO (sn phm kh duy nht ca N+5 ). Gi tr ca t l
A. 0,8.
B. 1,2.
C. 1,0.
D. 0,3.
Cu 82. (B-12) 8: in phn dung dch hn hp gm 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl
(in cc tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca
qu trnh in phn l 100%. Gi tr ca V l
A. 5,60.
B. 11,20.
C. 22,40.
D. 4,48.
Cu 83. (B-12) 55: Ngi ta iu ch H2 v O2 bng phng php in phn dung dch NaOH vi
in cc tr, cng dng in 0,67A trong thi gian 40 gi. Dung dch thu c sau in phn
c khi lng 100 gam v nng NaOH l 6%. Nng dung dch NaOH trc in phn l (gi thit
lng nc bay hi khng ng k)
A. 5,08%.
B. 6,00%.
C. 5,50%.
D. 3,16%.
Cu 84. (C-12) 8: Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng
in phn thu c dung dch X v 1,68 lt kh Cl2 (ktc) duy nht anot. Ton b dung dch X tc
dng va vi 12,6 gam Fe. Gi tr ca V l
A. 0,15.
B. 0,60.
C. 0,45.
D. 0,80.
Cu 85. (C-13) 48: in phn dung dch gm NaCl v HCl (in cc tr, mng ngn xp). Trong qu
trnh in phn, so vi dung dch ban u, gi tr pH ca dung dch thu c
A. khng thay i.
B. gim xung.
C. tng ln sau gim xung.
D. tng ln.
5.7. n mn kim loi

Cu 86. (A-14): Cho l Al vo dung dch HCl, c kh thot ra. Thm vi git dung dch CuSO4 vo th
A.phn ng ngng li
B. tc thot kh khng i
C. tc thot kh gim
D. tc thot kh tng
Cu 87. (B-07) 31: C 4 dd ring bit: a) HCl, b) CuCl2, c) FeCl3, d) HCl c ln CuCl2. Nhng vo mi
dd mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l
A. 0.
B. 1.
C. 2.
D. 3.
Cu 88. (A-09) 24: Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc
vi dd cht in li th cc hp kim m trong Fe u b n mn trc l:
A. I, II v IV.
B. I, II v III.
C. I, III v IV.
D. II, III v IV.
Cu 89. (B-10) 30: C 4 dd ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi dd mt thanh Ni. S
trng hp xut hin n mn in ho l
A. 1.
B. 4.
C. 3.
D. 2.
Cu 90. (C-07) 7: Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Pb; Fe v Zn;
Fe v Sn; Fe v Ni. Khi nhng cc cp kim loi trn vo dd axit, s cp kim loi trong Fe b ph hu
trc l
A. 4.
B. 1.
C. 2.
D. 3.
Cu 91. (A-08) 50: Bit rng ion Pb2+ trong dd oxi ha c Sn. Khi nhng hai thanh kim loi Pb v
Sn c ni vi nhau bng dy dn in vo mt dd cht in li th
A. c Pb v Sn u b n mn in ho.
B. c Pb v Sn u khng b n mn in ho.
C. ch c Pb b n mn in ho.
D. ch c Sn b n mn in ho.
Cu 92. (B-08) 50: Tin hnh bn th nghim sau:
- Th nghim 1: Nhng thanh Fe vo dd FeCl3;
- Th nghim 2: Nhng thanh Fe vo dd CuSO4;
- Th nghim 3: Nhng thanh Cu vo dd FeCl3;
- Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dd HCl. S trng hp xut hin n
Thng k H 2007-2014
mn in ho l
A. 1.
B. 2.
C. 4.
D. 3.
Cu 93. (C-11) 30: Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n mn
A. km ng vai tr catot v b oxi ha.
B. st ng vai tr anot v b oxi ho.
+
C. st ng vai tr catot v ion H b oxi ha.
D. km ng vai tr anot v b oxi ho.
Cu 94. (B-12) 26: Trng hp no sau y xy ra n mn in ho?
A. Si dy bc nhng trong dung dch HNO3.
B. t l st trong kh Cl2.
C. Thanh nhm nhng trong dung dch H2SO4 long.
D. Thanh km nhng trong dung dch CuSO4.
Cu 95. (C-12) 26: Tin hnh cc th nghim sau:
(a) Cho l Fe vo dung dch gm CuSO4 v H2SO4 long;
(b) t dy Fe trong bnh ng kh O2;
(c) Cho l Cu vo dung dch gm Fe(NO3)3 v HNO3;
(d) Cho l Zn vo dung dch HCl.
S th nghim c xy ra n mn in ha l
A. 1.
B. 4.
C. 2.
D. 3.
Cu 96. (A-13) 55: Trng hp no sau y, kim loi b n mn in ha hc?

A. Thp cacbon trong khng kh m.
B. t dy st trong kh oxi kh.
C. Kim loi km trong dung dch HCl.
D. Kim loi st trong dung dch HNO3 long.
Cu 97. (C-13) 44: Pht biu no di y khng ng?
A. Tnh cht ha hc c trng ca kim loi l tnh kh.
B. Bn cht ca n mn kim loi l qu trnh oxi ha - kh.
C. n mn ha hc pht sinh dng in.
D. Nguyn tc chung iu ch kim loi l kh ion kim loi thnh nguyn t kim loi.
.8. Bi ton kim loi tc dng vi dd mui
Cu 98. (A-10) 10: Cho 19,3 gam hh bt gm Zn v Cu c t l mol tng ng l 1 : 2 vo dd cha 0,2
mol Fe2(SO4)3. Sau khi cc p xy ra hon ton, thu c m gam kim loi. Gi tr ca m l
A. 12,80.
B. 12,00.
C. 6,40.
D. 16,53
Cu 99. (C-10) 13: Cho 29,8 gam hh bt gm Zn v Fe vo 600 ml dd CuSO 4 0,5M. Sau khi cc p xy
ra hon ton, thu c dd X v 30,4 gam hh kim loi. Phn trm v khi lng ca Fe trong hh ban u
l
A. 56,37%.
B. 64,42%.
C. 43,62%.
D. 37,58%.
Cu 100. (B-09) 5: Cho 2,24 gam bt st vo 200 ml dd cha hh gm AgNO3 0,1M v Cu(NO3)2
0,5M. Sau khi cc p xy ra hon ton, thu c dd X v m gam cht rn Y. Gi tr ca m l
A. 2,80.
B. 2,16.
C. 4,08.
D. 0,64.
Cu 101. (C -14): Nhng thanh Fe vo dung dch CuSO4. Sau mt thi gian, khi lng dung dch
gim 0,8 gam so vi khi lng dung dch ban u. Khi lng Fe phn ng l
A. 6,4 gam
B. 8,4 gam.
C. 11,2 gam.
D. 5,6 gam.
Cu 102. (C -14): Cho hn hp gm Al v Zn vo dung dch AgNO3. Sau khi phn ng xy ra hon ton,
thu c dung dch X ch cha mt mui v phn khng tan Y gm hai kim loi. Hai kim loi trong Y v
mui trong X l
A. Al, Ag v Zn(NO3)2
B. Al, Ag v Al(NO3)3
C. Zn, Ag v Al(NO3)3
D. Zn, Ag v Zn(NO3)2
Cu 103. (A-12) 15: Cho 2,8 gam bt st vo 200 ml dung dch gm AgNO3 0,1M v Cu(NO3)2
0,5M; khi cc phn ng xy ra hon ton thu c m gam cht rn X. Gi tr ca m l
A. 4,72.
B. 4,48.
C. 3,20.
D. 4,08.
Cu 104. (B-09) 45: Nhng mt thanh st nng 100 gam vo 100 ml dd hh gm Cu(NO3)2 0,2M v
AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi
thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st p l
A. 1,40 gam.
B. 2,16 gam.
C. 0,84 gam.
D. 1,72 gam.
Cu 105. (B-13) 52: Nhng mt thanh st vo dung dch hn hp cha 0,02 mol AgNO3 v 0,05 mol
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Cu(NO3)2. Sau khi cc phn ng xy ra hon ton, khi lng thanh st tng m gam (coi ton b kim
loi sinh ra bm vo thanh st). Gi tr ca m l
A. 2,00.
B. 3,60.
C. 1,44.
D. 5,36.
Cu 106. (B-08) 56: Cho mt lng bt Zn vo dd X gm FeCl2 v CuCl2. Khi lng cht rn sau khi
cc p xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dd sau p thu
c 13,6 gam mui khan. Tng khi lng cc mui trong X l
A. 13,1 gam.
B. 17,0 gam.
C. 19,5 gam.
D. 14,1 gam.
Cu 107. (C-09) 24: Cho m gam Mg vo dd cha 0,12 mol FeCl3. Sau khi p xy ra hon ton thu c
3,36 gam cht rn. Gi tr ca m l
A. 2,16.
B. 5,04.
C. 4,32.
D. 2,88.
Cu 108. (B-11) 46: Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn
ng xy ra hon ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u.
Gi tr ca m l
A. 20,80.
B. 29,25.
C. 48,75.
D. 32,50.(A-09) 47: Cho hh gm 1
A. 1,8.
B. 1,5.
C. 1,2.
D. 2,0.
Cu 109. (C-09) 42: Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50 gam
vo 200 ml dung dch AgNO3 1M cho n khi phn ng xy ra hon ton. Lc dd, em c cn thu c
18,8 gam mui khan. Kim loi M l
A. Fe.
B. Cu.
C. Mg.
D. Zn.
Cu 110. (A-08) 44: Cho hh bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dd AgNO3 1M. Sau khi cc
p xy ra hon ton, thu c m gam cht rn. Gi tr ca m l (bit th t trong dy th in ho:
Fe3+/Fe2+ ng trc Ag+/Ag)
A. 59,4.
B. 64,8.
C. 32,4.
D. 54,0.
Cu 111. (B-07) 47: Cho m gam hh bt Zn v Fe vo lng d dd CuSO4. Sau khi kt thc cc p, lc
b phn dd thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hh bt
ban u l
A. 90,27%.
B. 85,30%.
C. 82,20%.
D. 12,67%.
Cu 112. (B-12) 43: Cho m gam bt st vo dung dch hn hp gm 0,15 mol CuSO4 v 0,2 mol HCl.
Sau khi cc phn ng xy ra hon ton, thu c 0,725m gam hn hp kim loi. Gi tr ca m l
A. 16,0.
B. 18,0.
C. 16,8.
D. 11,2.
Cu 113. (B-14): Cho hn hp X gm Al v Mg tc dng vi 1 lt dung dch gm AgNO3 a mol/l v
Cu(NO3)2 2a mol/l, thu c 45,2 gam cht rn Y. Cho Y tc dng vi dung dch H2SO4 c, nng
(d), thu c 7,84 lt kh SO2 ( ktc, l sn phm kh duy nht). Bit cc phn ng xy ra hon ton.
Gi tr ca a l
A. 0,25.
B. 0,30.
C. 0,15.
D. 0,20.
Cu 114. (A-11) 47: Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO4. Sau
mt thi gian, thu c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo dung dch H2SO4
(long, d), sau khi cc phn ng kt thc th khi lng cht rn gim 0,28 gam v dung dch thu
c ch cha mt mui duy nht. Phn trm khi lng ca Fe trong X l
A. 48,15%.
B. 51,85%.
C. 58,52%.
D. 41,48%.
Cu 115. (B-08) 34: Tin hnh hai th nghim sau:
- Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dd Cu(NO3)2 1M;
- Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dd AgNO3 0,1M.
Sau khi cc p xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr ca
V1 so vi V2 l
A. V1 = V2.
B. V1 = 10V2
C. V1 = 5V2.
D. V1 = 2V2.
Cu 116. (C-09) 4: Cho m1 gam Al vo 100 ml dd gm Cu(NO3)2 0,3M v AgNO3 0,3M. Sau khi cc p
xy ra hon ton th thu c m2 gam cht rn X. Nu cho m2 gam X t/d vi lng d dd HCl th thu
c 0,336 lt kh ( ktc). Gi tr ca m1 v m2 ln lt l
A. 8,10 v 5,43.
B. 1,08 v 5,43.
C. 0,54 v 5,16.
D. 1,08 v 5,16.
Cu 117. (B-11) 51: Cho m gam bt Cu vo 400 ml dung dch AgNO3 0,2M, sau mt thi gian phn
ng thu c 7,76 gam hn hp cht rn X v dung dch Y. Lc tch X, ri thm 5,85 gam bt Zn vo
Y, sau khi phn ng xy ra hon ton thu c 10,53 gam cht rn Z. Gi tr ca m l
A. 5,12.
B. 3,84.
C. 5,76.
D. 6,40.
Thng k H 2007-2014
Cu 118. (B-12) 30: Cho 0,42 gam hn hp bt Fe v Al vo 250 ml dung dch AgNO3 0,12M. Sau khi
cc phn ng xy ra hon ton, thu c dung dch X v 3,333 gam cht rn. Khi lng Fe trong hn
hp ban u l
A. 0,168 gam.
B. 0,123 gam.
C. 0,177 gam.
D. 0,150 gam.
Cu 119. (A-13) 35: Cho hn hp X gm 0,01 mol Al v a mol Fe vo dung dch AgNO3 n khi phn
ng hon ton, thu c m gam cht rn Y v dung dch Z cha 3 cation kim loi. Cho Z phn ng
vi dung dch NaOH d trong iu kin khng c khng kh, thu c 1,97 gam kt ta T. Nung T
trong khng kh n khi lng khng i, thu c 1,6 gam cht rn ch cha mt cht duy nht.
Gi tr ca m l
A. 9,72.
B. 3,24.
C. 6,48.
D. 8,64.
5.9. Bi ton kim loi tc dng vi dd axit

Cu 120. (A-08) 7: Cho 2,13 gam hh X gm ba kim loi Mg, Cu v Al dng bt t/d hon ton vi oxi
thu c hh Y gm cc oxit c khi lng 3,33 gam. Th tch dd HCl 2M va p ht vi Y l
A. 57 ml.
B. 50 ml.
C. 75 ml.
D. 90 ml.(C-08)
44: Ho tan ht 7,74 gam hh bt Mg, Al bng 500 ml dd hh HCl 1M v H2SO4 0,28M thu c dd X v
8,736 lt kh H2 ( ktc). C cn dd X thu c lng mui khan l
A. 38,93 gam.
B. 103,85 gam.
C. 25,95 gam.
D. 77,86 gam.
Cu 121. (C-07) 27: Ha tan hon ton 3,22 gam hh X gm Fe, Mg v Zn bng mt lng va dd
H2SO4 long, thu c 1,344 lt hiro ( ktc) v dd cha m gam mui. Gi tr ca m l
A. 9,52.
B. 10,27.
C. 8,98.
D. 7,25.
Cu 122. (A-12) 27: Ha tan hon ton 2,43 gam hn hp gm Mg v Zn vo mt lng va dung
dch H2SO4 long, sau phn ng thu c 1,12 lt H2 (ktc) v dung dch X. Khi lng mui trong dung
dch X l
A. 4,83 gam.
B. 5,83 gam.
C. 7,33 gam.
D. 7,23 gam.
Cu 123. (B-08) 26: Cho m gam hh X gm Al, Cu vo dd HCl (d), sau khi kt thc p sinh ra 3,36 lt
kh ( ktc). Nu cho m gam hh X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc p
sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 11,5.
B. 10,5.
C. 12,3.
D. 15,6.
Cu 124. (A-09) 9: Cho 3,024 gam mt kim loi M tan ht trong dd HNO3 long, thu c 940,8 ml
kh NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l
A. NO v Mg.
B. NO2 v Al.
C. N2O v Al.
D. N2O v Fe.
Cu 125. (C-13) 8: Cho m gam Al phn ng hon ton vi dung dch HNO3 long (d), thu c 4,48
lt kh NO (ktc, sn phm kh duy nht). Gi tr ca m l
A. 4,05.
B. 2,70.
C. 8,10.
D. 5,40.
Cu 126. (A-09) 21: Cho 3,68 gam hh gm Al v Zn t/d vi mt lng va dd H2SO4 10%, thu
c 2,24 lt kh H2 ( ktc). Khi lng dd thu c sau p l
A. 101,68 gam.
B. 88,20 gam.
C. 101,48 gam.
D. 97,80 gam.
Cu 127. (A-09) 42: Ho tan hon ton 14,6 gam hh X gm Al v Sn bng dd HCl (d), thu c 5,6 lt kh
H2 ( ktc). Th tch kh O2 ( ktc) cn p hon ton vi 14,6 gam hh X l
A. 2,80 lt.
B. 1,68 lt.
C. 4,48 lt.
D. 3,92 lt.
Cu 128. (C-07) 42: Ho tan hon ton hh X gm Fe v Mg bng mt lng va dd HCl 20%, thu
c dd Y. Nng ca FeCl2 trong dd Y l 15,76%. Nng phn trm ca MgCl2 trong dd Y l
A. 24,24%.
B. 11,79%.
C. 28,21%.
D. 15,76%.
Cu 129. (C-09) 28: Ho tan hon ton 8,862 gam hh gm Al v Mg vo dd HNO 3 long, thu c dd X
v 3,136 lt ( ktc) hh Y gm hai kh khng mu, trong c mt kh ha nu trong khng kh. Khi
lng ca Y l 5,18 gam. Cho dd NaOH (d) vo X v un nng, khng c kh mi khai thot ra. Phn
trm khi lng ca Al trong hh ban u l
A. 19,53%.
B. 12,80%.
C. 10,52%.
D. 15,25%.
Cu 130. (B-13) : Ha tan hn hp X gm 11,2 gam Fe v 2,4 gam Mg bng dung dch H2SO4 long
(d), thu c dung dch Y. Cho dung dch NaOH d vo Y thu c kt ta Z. Nung Z trong khng
kh n khi lng khng i, thu c m gam cht rn. Bit cc phn ng u xy ra hon ton. Gi tr
ca m l
Thng k H 2007-2014
A. 36.

B. 20.
C. 18.
D. 24.
Cu 131. (C-13) : Cho 2,8 gam hn hp X gm Cu v Ag phn ng hon ton vi dung dch HNO3 d,
thu c
0,04 mol NO2 (sn phm kh duy nht ca N+5 ) v dung dch cha m gam mui. Gi tr ca m l
A. 4,08.
B. 3,62.
C. 3,42.
D. 5,28.
Cu 132. (C -14): Cho 2.19g hn hp gm Cu, Al tc dng hon ton vi dung dch HNO3 d, thu
c dung dch Y v 0,672 lt kh NO ( ktc, l sn phm kh duy nht). Khi lng mui trong Y l
A. 6,39 gam
B. 8,27 gam
C. 4,05 gam
D. 7,77 gam
Cu 133. (A-13) 53: Cho 12 gam hp kim ca bc vo dung dch HNO3 long (d), un nng n phn
ng hon ton, thu c dung dch c 8,5 gam AgNO3. Phn trm khi lng ca bc trong mu hp kim
l
A. 65%.
B. 30%.
C. 55%.
D. 45%.
Cu 134. (A-07) 14: Ha tan hon ton 12 gam hh Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt
( ktc) hh kh X (gm NO v NO2) v dd Y (ch cha hai mui v axit d). T khi ca X i vi H2
bng 19. Gi tr ca V l
A. 4,48.
B. 5,60.
C. 3,36.
D. 2,24.
5.10. Mg, Al, Zn tc dng vi HNO3 to mui NH4NO3

Cu 135. (B-08) 16: Cho 2,16 gam Mg t/d vi dd HNO3 (d). Sau khi p xy ra hon ton thu c
0,896 lt kh NO ( ktc) v dd X. Khi lng mui khan thu c khi lm bay hi dd X l
A. 8,88 gam.
B. 13,92 gam.
C. 6,52 gam.
D. 13,32 gam.
Cu 136. (A-09) Ho tan hon ton 12,42g Al bng dd HNO3 long (d), thu c dd X v 1,344 lt ( ktc)
hh kh Y gm 2 kh l N2O v N2. T khi ca hh kh Y so vi kh H2 l 18. C cn dd X, thu c m gam cht
rn khan. Gi tr ca m l
A. 38,34.
B. 34,08.
C. 106,38.
D. 97,98.
Cu 137. (A-13) 34: Ha tan hon ton m gam Al bng dung dch HNO3 long, thu c 5,376 lt
(ktc) hn hp kh X gm N2, N2O v dung dch cha 8m gam mui. T khi ca X so vi H2 bng 18. Gi
tr ca m l
A. 17,28.
B. 21,60.
C. 19,44.
D. 18,90.
Cu 138. (C-10) 3: Cho hh gm 6,72g Mg v 0,8 gam MgO t/d ht vi lng d dd HNO3. Sau khi cc
p xy ra hon ton, thu c 0,896 lt mt kh X (ktc) v dd Y. Lm bay hi dd Y thu c 46 gam
mui khan. Kh X l
A. N2O.
B. NO2.
C. N2.
D. NO.
Cu 139. (C-11) 55: Ho tan hon ton 13,00 gam Zn trong dung dch HNO3 long, d thu c
dung dch X v 0,448 lt kh N2 (ktc). Khi lng mui trong dung dch X l
A. 18,90 gam.
B. 37,80 gam.
C. 28,35 gam.
D. 39,80 gam.
Cu 140. (B-12) 27: Cho 29 gam hn hp gm Al, Cu v Ag tc dng va vi 950 ml dung dch
HNO3 1,5M, thu c dung dch cha m gam mui v 5,6 lt hn hp kh X (ktc) gm NO v N2O. T
khi ca X so vi H2 l 16,4. Gi tr ca m l
A. 98,20.
B. 97,20.
C. 98,75.
D. 91,00.
Cu 141. (C-12) 18: Ha tan hon ton 8,9 gam hn hp gm Mg v Zn bng lng va 500 ml
dung dch HNO3 1M. Sau khi cc phn ng kt thc, thu c 1,008 lt kh N2O (ktc) duy nht v
dung dch X cha m gam mui. Gi tr ca m l
A. 31,22.
B. 34,10.
C. 33,70.
D. 34,32.
Cu 142. (B-14): Cho 3,48 gam bt Mg tan ht trong dung dch hn hp gm HCl (d) v KNO3, thu
c dung dch X cha m gam mui v 0,56 lt (ktc) hn hp kh Y gm N2 v H2. Kh Y c t khi so
vi H2 bng 11,4. Gi tr ca m l
A. 16,085.
B. 14,485.
C. 18,300.
D. 18,035.
Thng k H 2007-2014
6. KIM LOI KIM, KIM TH

6.1 L THUYT
Cu 1. (B-14): Kim loi no sau y tan ht trong nc d nhit thng
A. Na
B. Fe
C. Mg
D. Al
Cu 2. (A-10) 6: Pht biu no sau y ng?
A. Theo chiu tng dn ca in tch ht nhn, cc kim loi kim th (t beri n bari) c nhit
nng chy gim dn.
B. Kim loi xesi c dng ch to t bo quang in.
C. Kim loi magie c kiu mng tinh th lp phng tm din.
D. Cc kim loi: natri, bari, beri u t/d vi nc nhit thng.
Cu 3. (A-14): Pht biu no sau y l sai?
A. Cc kim loi kim c nhit nng chy tng dn t Li n Cs.
B. Cc kim loi kim u l kim loi nh
C. Cc kim loi kim c bn knh nguyn t ln hn so vi cc kim loi cng chu k
D. Cc kim loi kim c mu trng bc v c nh kim
Cu 4. (C-12) 3: Pht biu no sau y l ng?
A. Trong hp cht, tt c cc kim loi kim u c s oxi ha +1.
B. Tt c cc kim loi nhm IIA u c mng tinh th lp phng tm khi.
C. Tt c cc hiroxit ca kim loi nhm IIA u d tan trong nc.
D. Trong nhm IA, tnh kh ca cc kim loi gim dn t Li n Cs.
Cu 5. (B-12) 3: Khi ni v kim loi kim, pht biu no sau y l sai?
A. Cc kim loi kim c mu trng bc v c nh kim.
B. Trong t nhin, cc kim loi kim ch tn ti dng hp cht.
C. T Li n Cs kh nng phn ng vi nc gim dn.
D. Kim loi kim c nhit nng chy v nhit si thp.
Cu 6. (B-08) 14: P nhit phn khng ng l
to
to
B. NH4NO2
2KNO2 + O2
N2 + 2H2O
A. 2KNO3
to
to
C. NH4Cl
D. NaHCO3
NH3 + HCl
NaOH + CO2
Cu 7. (A-08) 3: T hai mui X v Y thc hin cc p sau:
X1 + H2O X2
X X1+ CO 2
X2 + 2Y X + Y2 + H2O
X2 + Y X + Y1 + H2O
Hai mui X, Y tng ng l
A. CaCO3, NaHSO4.
B. BaCO3, Na2CO3. C. CaCO3, NaHCO3.
D.MgCO3, NaHCO3.
Cu 8. (C-13) 11: Dung dch no di y khi phn ng hon ton vi dung dch NaOH d, thu
c kt ta trng?
A. Ca(HCO3)2.
B. FeCl3.
C. AlCl3.
D. H2SO4.
Cu 9. (B-09) 26: Thc hin cc th nghim sau:
(I) Cho dd NaCl vo dd KOH.
(II) Cho dd Na2CO3 vo dd Ca(OH) 2.
(III) in phn dd NaCl vi in cc tr, c mng ngn.
(IV) Cho Cu(OH) 2 vo ddNaNO3.
(VI) Cho dd Na2SO4 vo dd Ba(OH) 2.
(V) Sc kh NH3 vo dd Na2CO3.
Cc th nghim u iu ch c NaOH l:
A. II, III v VI.
B. I, II v III.
C. I, IV v V.
D. II, V v VI.
Cu 10. (C-13) 29: Sn phm thu c khi in phn dung dch KCl (in cc tr, mng ngn xp) l
A. K v Cl2.
B. K, H2 v Cl2.
C. KOH, H2 v Cl2.
D. KOH, O2 v HCl.
Cu 11. (A-14): Dn hn hp kh gm CO2, O2, N2 v H2 qua dung dch NaOH. Kh b hp th l
A. H2
B. CO2
C. N2
D. O2
Cu 12. (C-07) 26: C th dng NaOH ( th rn) lm kh cc cht kh
A. NH3, SO2, CO, Cl2.
B. N2, NO2, CO2, CH4, H2.
C. NH3, O2, N2, CH4, H2.
D. N2, Cl2, O2 , CO2, H2.
Cu 13. (C-07) 36: Cho s p: NaCl (X) NaHCO3 (Y) NaNO3. X v Y c th l
A. NaOH v NaClO. B. Na2CO3 v NaClO.
C. NaClO3 v Na2CO3.
D. NaOH v Na2CO3.
Thng k H 2007-2014
Cu 14. (A-11) 9: Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l:

A. HCl, NaOH, Na2CO3.
B. NaOH, Na3PO4, Na2CO3.
C. KCl, Ca(OH)2, Na2CO3.
D. HCl, Ca(OH)2, Na2CO3
Cu 15. (A-11) 17: Hp cht no ca canxi c dng c tng, b bt khi gy xng?
A. Thch cao nung (CaSO4.H2O).
C. Vi sng (CaO).
D. Thch cao sng (CaSO4.2H2O).
B. vi (CaCO3).
Cu 16. (C-14): lm mm nc c tnh cng vnh cu c th dng dung dch no sau y?
A. CaCl2
B. Na2CO3
C. Ca(OH)2
D. KCl
Cu 17. (C-08) 3: Hai cht c dng lm mm nc cng vnh cu l
A. Na2CO3 v HCl.
B. Na2CO3 v Na3PO4. C. Na2CO3 v Ca(OH)2.
D. NaCl v Ca(OH)2.
Cu 18. (B-08)6: Mt mu nc cng cha cc ion: Ca2+, Mg2+, HCO3-, Cl-, SO42-. Cht c dng
lm mm mu nc cng trn l
A. Na2CO3.
B. HCl.
C. H2SO4.
D. NaHCO3.
Cu 19. (C-11) Mt cc nc c cha cc ion: Na+ (0,02 mol), Mg2+ (0,02 mol), Ca2+ (0,04 mol), Cl- (0,02
2
mol), HCO3- (0,10 mol) v SO4 (0,01 mol). un si cc nc trn cho n khi cc phn ng xy ra
hon ton th nc cn li trong cc
A. l nc mm.
B. c tnh cng vnh cu.
C. c tnh cng ton phn.
D. c tnh cng tm thi.
Cu 20. (B-13) 26: Mt loi nc cng khi un si th mt tnh cng. Trong loi nc cng ny c ha tan
nhng hp cht no sau y?
A. Ca(HCO3)2, Mg(HCO3)2.
B. Ca(HCO3)2, MgCl2.
C. CaSO4, MgCl2.
D. Mg(HCO3)2., CaCl2.
6.2. KIM LOI KIM, KIM TH tc dng vi AXIT, tm kim loi

Cu 21. (B-07) 17: Cho 1,67 gam hh gm hai kim loi 2 chu k lin tip thuc nhm IIA (phn nhm
chnh nhm II) t/d ht vi dd HCl (d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l (cho Be = 9,
Mg = 24, Ca = 40, Sr = 87, Ba = 137)
A. Be v Mg.
B. Mg v Ca.
C. Sr v Ba.
D. Ca v Sr.
Cu 22. (B-10) 33: Ha tan hon ton 2,45 gam hh X gm hai kim loi kim th vo 200 ml dd HCl
1,25M, thu c dd Y cha cc cht tan c nng mol bng nhau. Hai kim loi trong X l
A. Mg v Ca.
B. Be v Mg.
C. Mg v Sr.
D. Be v Ca.
Cu 23. (A-10) 3: Cho 7,1 gam hh gm mt kim loi kim X v mt kim loi kim th Y t/d ht vi
lng d dd HCl long, thu c 5,6 lt kh (ktc). Kim loi X, Y l
A. kali v bari.
B. liti v beri.
C. natri v magie.
D. kali v canxi.
Cu 24. (C-12) 40: Ho tan hon ton 1,1 gam hn hp gm mt kim loi kim X v mt kim loi
kim th Y (MX < MY) trong dung dch HCl d, thu c 1,12 lt kh H2 (ktc). Kim loi X l
A. Li.
B. Na.
C. Rb.
D. K.
Cu 25. (C-11) 16: ho tan hon ton 6,4 gam hn hp gm kim loi R (ch c ha tr II) v oxit
ca n cn va 400 ml dung dch HCl 1M. Kim loi R l
A. Ba.
B. Be.
C. Mg.
D. Ca.
Cu 26. (B-08) 24: Cho 1,9 gam hh mui cacbonat v hirocacbonat ca kim loi kim M t/d ht vi
dd HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l
A. Na.
B. K.
C. Rb.
D. Li.
Cu 27. (C-08) 34: X l kim loi thuc phn nhm chnh nhm II (hay nhm IIA). Cho 1,7 gam hh
gm kim loi X v Zn t/d vi lng d dd HCl, sinh ra 0,672 lt kh H2 (ktc). Mt khc, khi cho 1,9 gam
X t/d vi lng d dd H2SO4 long, th th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X
l: A. Ba.
B. Ca.
C. Sr.
D. Mg.
Cu 28. (C-08) 43: Cho 3,6 gam Mg t/d ht vi dd HNO3 (d), sinh ra 2,24 lt kh X (sn phm kh duy
nht, ktc). Kh X l
A. N2O.
B. NO2.
C. N2.
D. NO.
Cu 29. (C-11) 25: Ho tan hon ton 6,645 gam hn hp mui clorua ca hai kim loi kim thuc
hai chu k k tipnhau vo nc c dung dch X. Cho ton b dung dch X tc dng hon ton vi
Thng k H 2007-2014
dung dch AgNO3 (d), thu c 18,655 gam kt ta. Hai kim loi kim trn l
A. Rb v Cs.
B. Na v K.
C. Li v Na.
D. K v Rb.
6.3. KIM LOI KIM tc dng vi H2O

Cu 30. (C -14): Ha tan ht 4,68 gam kim loi kim M vo H2O d, thu c 1,344 lt kh H2
(ktc). Kim loi M l : A. Na
B. K
C. Li
D. Rb
Cu 31. (B-13) 35: Khi ha tan hon ton m gam mi kim loi vo nc d, t kim loi no sau y
thu c th tch kh H2 (cng iu kin nhit v p sut) l nh nht?
A. K.
B. Na.
C. Li.
D. Ca.
Cu 32. (A-10) 21: Ho tan hon ton 8,94 gam hh gm Na, K v Ba vo nc, thu c dd X v 2,688
lt kh H2 (ktc). Dd Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ho dd X bi dd Y, tng
khi lng cc mui c to ra l
A. 13,70 gam.
B. 12,78 gam.
C. 18,46 gam.
D. 14,62 gam.
Cu 33. (B-13) 38: Hn hp X gm hai kim loi kim v mt kim loi kim th. Ha tan hon ton
1,788 gam X vo nc, thu c dung dch Y v 537,6 ml kh H2 (ktc). Dung dch Z gm H2SO4 v
HCl, trong s mol ca HCl gp hai ln s mol ca H2SO4. Trung ha dung dch Y bng dung dch Z
to ra m gam hn hp mui. Gi tr ca m l
A. 4,460.
B. 4,656.
C. 3,792.
D. 2,790.
Cu 34. (C-07) 18: Cho mt mu hp kim Na-Ba t/d vi nc (d), thu c dd X v 3,36 lt H2 (
ktc). Th tch dd axit H2SO4 2M cn dng trung ho dd X l
A. 150ml.
B. 75ml.
C. 60ml.
D. 30ml.
Cu 35. (C-13) 39: Ha tan ht mt lng hn hp gm K v Na vo H2O d, thu c dung dch X
v 0,672 lt kh H2 (ktc). Cho X vo dung dch FeCl3 d, n khi phn ng xy ra hon ton, thu
c m gam kt ta. Gi tr ca m l
A. 2,14.
B. 6,42.
C. 1,07.
D. 3,21.
Cu 36. (B-09) 21: Ho tan hon ton 2,9 gam hh gm kim loi M v oxit ca n vo nc, thu c
500 ml dd cha mt cht tan c nng 0,04M v 0,224 lt kh H2 ( ktc). Kim loi M l
A. Na.
B. Ca.
C. Ba.
D. K.
6.4. BI TON CO2 tc dng vi DUNG DCH KIM

Cu 37. (C -14): Hp th hon ton 6,72 lt kh CO2 (ktc) vo dung dch cha a mol KOH, thu
c dung dch cha 33,8 gam hn hp mui. Gi tr ca a l
A. 0,5.
B. 0,6.
C. 0,4.
D. 0,3.
Cu 38. (C-10) 12: Hp th hon ton 3,36 lt kh CO2 (ktc) vo 125 ml dd Ba(OH)2 1M, thu c
dd X. Coi th tch dd khng thay i, nng mol ca cht tan trong dd X l
A. 0,6M.
B. 0,2M.
C. 0,1M.
D. 0,4M.
Cu 39. (A-07) 32: Hp th hon ton 2,688 lt kh CO2 ( ktc) vo 2,5 lt dd Ba(OH)2 nng a
mol/l, thu c 15,76 gam kt ta. Gi tr ca a l (cho C = 12, O = 16, Ba = 137)
A. 0,032.
B. 0,04.
C. 0,048.
D. 0,06
Cu 40. (A-08) 27: Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 500 ml dd hh gm NaOH 0,1M v
Ba(OH)2 0,2M, sinh ra m gam kt ta. Gi tr ca m l
A. 19,70.
B. 17,73.
C. 9,85.
D. 11,82.
Cu 41. (A-11) 7: Hp th hon ton 0,672 lt kh CO2 (ktc) vo 1 lt dung dch gm NaOH
0,025M v Ca(OH)2 0,0125M, thu c x gam kt ta. Gi tr ca x l
A. 2,00.
B. 1,00.
C. 1,25.
D. 0,75.
Cu 42. (A-09) 4: Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dd cha hh NaOH 0,06M v
Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l
A. 1,182.
B. 3,940.
C. 1,970.
D. 2,364.
Cu 43. (B-11) 29: Hp th hon ton 2,24 lt CO2 (ktc) vo 100 ml dung dch gm K2CO3
Thng k H 2007-2014
0,2M v KOH x mol/lt, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton
b Y tc dng vi dung dch BaCl2 (d), thu c 11,82 gam kt ta. Gi tr ca x l
A. 1,6.
B. 1,2.
C. 1,0.
D. 1,4.
Cu 44. (B-12) 25: Sc 4,48 lt kh CO2 (ktc) vo 1 lt dung dch hn hp Ba(OH)2 0,12M v
NaOH 0,06M. Sau khi cc phn ng xy ra hon ton thu c m gam kt ta. Gi tr ca m l
A. 19,70.
B. 23,64.
C. 7,88.
D. 13,79.
Cu 45. (B-14) : Hp th hon ton 3,36 lt kh CO2 (ktc) vo dung dch cha 0,15 mol NaOH v 0,1
mol Ba(OH)2, thu c m gam kt ta. Gi tr ca m l
A. 14,775.
B. 9,850.
C. 29,550.
D. 19,700.
Cu 46. (C-12) 11: Hp th hon ton 0,336 lt kh CO2 (ktc) vo 200 ml dung dch gm NaOH
0,1M v KOH 0,1M thu c dung dch X. C cn ton b dung dch X thu c bao nhiu gam cht rn
khan?
A. 2,58 gam.
B. 2,22 gam.
C. 2,31 gam.
D. 2,44 gam.
Cu 47. (A-13) 23: Hn hp X gm Na, Ba, Na2O v BaO. Ha tan hon ton 21,9 gam X vo nc,
thu c 1,12 lt kh H2 (ktc) v dung dch Y, trong c 20,52 gam Ba(OH)2. Hp th hon ton
6,72 lt kh CO2 (ktc) vo Y, thu c m gam kt ta. Gi tr ca m l
A. 21,92.
B. 23,64.
C. 39,40.
D. 15,76.
Cu 48. (B-13) 33: Hp th hon ton 2,24 lt kh CO2 (ktc) vo 750 ml dung dch Ba(OH)2 0,2M, thu
A. 29,55.
B. 19,70.
C. 9,85.
D. 39,40.
Cu 49. (C-13) 20: Hp th hon ton 2,24 lt kh CO2 (ktc) vo dung dch Ca(OH)2 d, thu
A. 19,70.
B. 10,00.
C. 1,97.
D. 5,00.
6.5. DUNG DCH AXIT tc dng vi MUI CACBONAT

Cu 50. (A-07) 28: Cho t t dd cha a mol HCl vo dd cha b mol Na2CO3 ng thi khuy u,
thu c V lt kh ( ktc) v dd X. Khi cho d nc vi trong vo dd X thy c xut hin kt ta. Biu
thc lin h gia V vi a, b l:
A. V = 22,4(a - b).
B. V = 22,4(a + b).
C. V = 11,2(a - b).
D. V = 11,2(a + b).
Cu 51. (A-09) 22: Dd X cha hh gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht
200 ml dd HCl 1M vo 100 ml dd X, sinh ra V lt kh ( ktc). Gi tr ca V l
A. 4,48.
B. 3,36.
C. 2,24.
D. 1,12.
Cu 52. (A-12) 39: Cho hn hp K2CO3 v NaHCO3 (t l mol 1 : 1) vo bnh dung dch Ba(HCO3)2
thu c kt ta X v dung dch Y. Thm t t dung dch HCl 0,5M vo bnh n khi khng cn kh
thot ra th ht 560 ml. Bit ton b Y phn ng va vi 200 ml dung dch NaOH 1M. Khi lng kt
ta X l
A. 3,94 gam.
B. 7,88 gam.
C. 11,28 gam.
D. 9,85 gam.
Cu 53. (A-10) 45: Nh t t tng git n ht 30 ml dd HCl 1M vo 100 ml dd cha Na2CO3 0,2M v
NaHCO3 0,2M, sau p thu c s mol CO2 l
A. 0,020.
B. 0,030.
C. 0,015.
D. 0,010.
Cu 54. (B-13) 14: Cho 200 ml dung dch Ba(OH)2 0,1M vo 300 ml dung dch NaHCO3 0,1M, thu
c dung dch X v kt ta Y. Cho t t dung dch HCl 0,25M vo X n khi bt u c kh sinh ra th
ht V ml. Bit cc phn ng u xy ra hon ton. Gi tr ca V l
A. 80.
B. 40.
C. 160.
D. 60.
Cu 55. (C-10) 34: Cho 9,125 gam mui hirocacbonat p ht vi dd H2SO4 (d), thu c dd cha
7,5 gam mui sunfat trung ho. Cng thc ca mui hirocacbonat l
A. NaHCO3.
B. Ca(HCO3)2.
C. Ba(HCO3)2.
D. Mg(HCO3)2.
Cu 56. (B-08) 32: Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra
8,96 lt kh CO2 ( ktc). Thnh phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung
nu trn l: A. 40%.
B. 50%.
C. 84%.
D.
92%.
Thng k H 2007-2014
Cu 57. (C-13) 1: Ha tan hon ton 20,6 gam hn hp gm Na2CO3 v CaCO3 bng dung dch
HCl d, thu c V lt kh CO2 (ktc) v dung dch cha 22,8 gam hn hp mui. Gi tr ca V l
A. 4,48.
B. 1,79.
C. 5,60.
D. 2,24.
Thng k H 2007-2014
7. NHM V HP CHT
7.1. Nhm, nhm oxit tc dng vi dung dch kim, axit
A. Trong cng nghip, kim loi Al c iu ch bng phng php in phn Al2O3 nng chy.
B. Al(OH)3 phn ng c vi dung dch HCl v dung dch KOH.
C. Kim loi Al tan c trong dung dch HNO3 c, ngui.
D. Trong cc phn ng ha hc, kim loi Al ch ng vai tr cht kh.
Cu 2. (B-14): Cc dung dch no sau y u c tc dng vi Al2O3?
A. NaSO4, HNO3
B. HNO3, KNO3
C. HCl, NaOH
D. NaCl, NaOH
(C-14)
Cu 3.
: kh chua cho t ngi ta thng s dng cht no sau y?
A. Mui n
B. Thch cao
C. Phn chua
D. Vi sng
Cu 4. (C-08) 14: Chia m gam Al thnh hai phn bng nhau:
- Phn 1 t/d vi lng d dd NaOH, sinh ra x mol kh H2;
- Phn 2 t/dng vi lng d dd HNO3 long, sinh ra y mol kh N2O (sn phm kh duy nht).
Quan h gia x v y l A. x = 2y.
B. y = 2x.
C. x = 4y.
D. x = y.
Cu 5. (B-07) 21: Hh X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh.
Nu cng cho m gam X vo dd NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi
lng ca Na trong X l (bit cc th tch kh o trong cng iu kin, cho Na = 23, Al = 27)
A. 39,87%.
B. 77,31%.
C. 49,87%.
D. 29,87%.
Cu 6. (A-08) 30: Cho hh gm Na v Al c t l s mol tng ng l 1 : 2 vo nc (d). Sau khi
cc p xy ra hon ton, thu c 8,96 lt kh H2 ( ktc) v m gam cht rn khng tan. Gi tr ca m l
A. 10,8.
B. 5,4.
C. 7,8.
D. 43,2.
Cu 7. (A-14): Cho m gam hn hp Al v Na vo nc d, sau khi cc phn ng xy ra hon ton ,
thu c 2,24 lt kh H2 (ktc) v 2,35 gam cht rn khng tan. Gi tr ca m l
A. 4,35
B. 4,85
C. 6,95
D. 3,70
Cu 8. (A-13) 39: Hn hp X gm Ba v Al. Cho m gam X vo nc d, sau khi cc phn ng xy
ra hon ton, thu c 8,96 lt kh H2 (ktc). Mt khc, ha tan hon ton m gam X bng dung dch
NaOH, thu c 15,68 lt kh H2 (ktc). Gi tr ca m l
A. 19,1.
B. 24,5.
C. 16,4.
D. 29,9.
Cu 9. (C-13) 12: Hn hp X gm Ba, Na v Al, trong s mol ca Al bng 6 ln s mol ca Ba. Cho
m gam X vo nc d n phn ng hon ton, thu c 1,792 lt kh H2 (ktc) v 0,54 gam cht rn.
Gi tr ca m l
A. 3,90.
B. 5,27.
C. 3,45.
D. 3,81.
Cu 10. (A-11) 21: Chia hn hp X gm K, Al v Fe thnh hai phn bng nhau.
- Cho phn 1 vo dung dch KOH (d) thu c 0,784 lt kh H2 (ktc).
- Cho phn 2 vo mt lng d H2O, thu c 0,448 lt kh H2 (ktc) v m gam hn hp kim
loi
Y. Ho tan hon ton Y vo dung dch HCl (d) thu c 0,56 lt kh H2 (ktc).
Khi lng (tnh theo gam) ca K, Al, Fe trong mi phn hn hp X ln lt l:
A. 0,39; 0,54; 1,40.
B. 0,78; 1,08; 0,56.
C. 0,39; 0,54; 0,56.
D. 0,78; 0,54; 1,12.
Cu 11. (C-12) 25: Hn hp X gm Na, Al v Fe (vi t l s mol gia Na v Al tng ng l 2 : 1).
Cho X tc dng vi H2O (d) thu c cht rn Y v V lt kh. Cho ton b Y tc dng vi dung dch
H2SO4 long (d) thu c 0,25V lt kh. Bit cc kh o cng iu kin, cc phn ng u xy ra
hon ton. T l s mol ca Fe v Al trong X tng ng l A. 16 : 5.
B. 5 : 16.
C. 1 : 2.
D. 5 : 8.
Cu 12. (C-09) 14: Ho tan hon ton m gam hh X gm Na2O v Al2O3 vo H2O thu c 200 ml dd
Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO 2 (d) vo Y thu c a gam kt ta. Gi tr
ca m v a ln lt l
A. 8,3 v 7,2.
B. 11,3 v 7,8.
C. 13,3 v 3,9.
D. 8,2 v 7,8.
Cu 13. (A-12) 28: Ha tan hon ton m gam hn hp gm Na2O v Al2O3 vo nc thu c
Thng k H 2007-2014
dung dch X trong sut. Thm t t dung dch HCl 1M vo X, khi ht 100 ml th bt u xut hin kt
ta; khi ht 300 ml hoc 700 ml th u thu c a gam kt ta. Gi tr ca a v m ln lt l
A. 15,6 v 27,7.
B. 23,4 v 35,9.
C. 23,4 v 56,3.
D. 15,6 v 55,4.
Cu 14. (C-10) 1: Cho 1,56 gam hh gm Al v Al2O3 p ht vi dd HCl (d), thu c V lt kh H2
(ktc) v dd X. Nh t t dd NH3 n d vo dd X thu c kt ta, lc ht lng kt ta, nung n
khi lng khng i thu c 2,04 gam cht rn. Gi tr ca V l
A. 0,448.
B. 0,224.
C. 1,344.
D. 0,672.
7.2. Bi ton Al3+, Zn2+ tc dng vi dung dch kim

Cu 15. (A-07) 37: Nh t t cho n d dd NaOH vo dd AlCl3. Hin tng xy ra l
A. c kt ta keo trng v c kh bay ln.
B. c kt ta keo trng, sau kt ta tan.
C. ch c kt ta keo trng.
D. khng c kt ta, c kh bay ln.
Cu 16. (A-07) 24: Trn dd cha a mol AlCl3 vi dd cha b mol NaOH. thu c kt ta th cn
c t l
A. a : b = 1 : 5.
B. a : b = 1 : 4.
C. a : b > 1 : 4.
D. a : b < 1 : 4.
Cu 17. (A-14): Khi nh t t n d dung dch NaOH vo dung dch hn hp gm a mol HCl v b
mol AlCl3, kt qu th nghim c biu din trn th sau:
s mol Al(OH)3
0.4
s mol NaOH
0
0,8
2,0
2,8
T l a : b l
A. 2 : 1
B. 2 : 3
C. 4 : 3
D. 1 : 1
Cu 18. (A-08) 14: Cho V lt dd NaOH 2M vo dd cha 0,1 mol Al2(SO4)3 v 0,1 mol H2SO4 n khi
p hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l
A. 0,45.
B. 0,35.
C. 0,25.
D. 0,05.
Cu 19. (C -14): Cho 300 ml dung dch NaOH 0,1M phn ng vi 100ml dung dch Al 2(SO4)3
0,1M. Sau khi phn ng xy ra hon ton, thu c a gam kt ta. Gi tr ca a l
A. 1,17.
B. 2,34.
C. 1,56.
D. 0,78.
Cu 20. (B-07) 7: Cho 200 ml dd AlCl3 1,5M t/d vi V lt dd NaOH 0,5M, lng kt ta thu c l
15,6 gam. Gi tr ln nht ca V l (cho H = 1, O = 16, Al = 27)
A. 1,2.
B. 1,8.
C. 2,4.
D. 2.
Cu 21. (B-11) 24: Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng
vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt
khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y
l
A. 3 : 4.
B. 3 : 2.
C. 4 : 3.
D. 7 : 4.
Cu 22. (B-10) 28: Cho 150 ml dd KOH 1,2M tc dng vi 100 ml dd AlCl3 nng x mol/l, thu c
dd Y v 4,68 gam kt ta. Loi b kt ta, thm tip 175 ml dd KOH 1,2M vo Y, thu c 2,34 gam kt
ta. Gi tr ca x l
A. 1,2.
B. 0,8.
C. 0,9.
D. 1,0.
Cu 23. (C-07) 21: Thm m gam kali vo 300ml dd cha Ba(OH) 2 0,1M v NaOH 0,1M thu c dd
X. Cho t t dd X vo 200ml dd Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln
nht th gi tr ca m l
A. 1,59.
B. 1,17.
C. 1,71.
D. 1,95.
Cu 24. (A-09) 2: Ho tan ht m gam ZnSO4 vo nc c dd X. Cho 110 ml dd KOH 2M vo X, thu
c a gam kt ta. Mt khc, nu cho 140 ml dd KOH 2M vo X th cng thu c a gam kt ta. Gi tr
ca m l
A. 20,125.
B. 22,540.
C. 12,375.
D. 17,710
Cu 25. (A-10) 26: Ho tan hon ton m gam ZnSO4 vo nc c dd X. Nu cho 110 ml dd KOH 2M
vo X th thu c 3a gam kt ta. Mt khc, nu cho 140 ml dd KOH 2M vo X th thu c 2a gam kt
ta. Gi tr ca m l
A. 17,71.
B. 16,10.
C. 32,20.
D. 24,15.
Thng k H 2007-2014
Cu 26. (C-09) 39: Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dd
X. Cho ton b X t/d vi 200 ml dd Ba(OH)2 1M, sau p thu c m gam kt ta. Gi tr ca m l
A. 7,8.
B. 46,6.
C. 54,4.
D. 62,2.
Cu 27. (A-12) 13: Cho 500 ml dung dch Ba(OH)2 0,1M vo V ml dung dch Al2(SO4)3 0,1M; sau khi
cc phn ng kt thc thu c 12,045 gam kt ta. Gi tr ca V l
A. 300.
B. 75.
C. 200.
D. 150.
Cu 28. (B-13) 22: Th tch dung dch NaOH 0,25M cn cho vo 15 ml dung dch Al2(SO4)3 0,5M
thu c lng kt ta ln nht l
A. 210 ml.
B. 60 ml.
C. 90 ml.
D. 180 ml.
Thng k H 2007-2014
8. ST V HP CHT
8.1. St tc dng vi axit
Cu 1. (C-12) 27: Dung dch long (d) no sau y tc dng c vi kim loi st to thnh mui
st(III)?
A. H2SO4.
B. HNO3.
C. FeCl3.
D. HCl.
A. Kim loi Fe phn ng vi dung dch HCl to ra mui st(II).
B. Dung dch FeCl3 phn ng c vi kim loi Fe.
C. Kim loi Fe khng tan trong dung dch H2SO4 c, ngui.
D. Trong cc phn ng ha hc, ion Fe2+ ch th hin tnh kh.
Cu 3. (A-13) 22: Kim loi st tc dng vi dung dch no sau y to ra mui st(II)?
A. HNO3 c, nng, d.
B. MgSO4.
C. CuSO4.
D. H2SO4 c, nng, d.
Cu 4. (A-14): Cho hn hp gm 1 mol cht X v 1 mol cht Y tc dng ht vi dung dch H2SO4 c,
nng (d), to ra 1 mol kh SO2 (sn phm kh duy nht). Hai cht X, Y l
A. FeO, Fe3O4
B. Fe3O4, Fe2O3
C. Fe, Fe2O3
D. Fe, FeO
Cu 5. (C-12) : Cho dy cc kim loi: Cu, Ni, Zn, Mg, Ba, Ag. S kim loi trong dy phn ng
c vi dung dch FeCl3 l
A. 6.
B. 4.
C. 3.
D. 5.
Cu 6. (B-13) 4: Ha tan hon ton Fe3O4 trong dung dch H2SO4 long (d), thu c dung dch X.
Trong cc cht: NaOH, Cu, Fe(NO3)2, KMnO4, BaCl2, Cl2 v Al, s cht c kh nng phn ng c
vi dung dch X l
A. 4.
B. 6.
C. 5.
D. 7.
Cu 7. (B-13) 15: Ha tan hon ton x mol Fe vo dung dch cha y mol FeCl3 v z mol HCl, thu
c dung dch ch cha mt cht tan duy nht. Biu thc lin h gia x, y v z l
A. 2x = y + 2z.
B. 2x = y + z.
C. x = y 2z.
D. y = 2x.
Cu 8. (B-09) Ho tan m gam hh gm Al, Fe vo dd H2SO4 long (d). Sau khi cc p xy ra hon ton,
thu c dd X. Cho dd Ba(OH)2 (d) vo dd X, thu c kt ta Y. Nung Y trong khng kh n khi lng
khng i, thu c cht rn Z l
A. hh gm BaSO4 v FeO.
B. hh gm Al2O3 v Fe2O3.
C. hh gm BaSO4 v Fe2O3.
D. Fe2O3.
Cu 9. (C-07) 48: Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n khi cc
phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung
dch Y l
A. MgSO4 v FeSO4.
B. MgSO4. C. MgSO4 v Fe2(SO4)3. D. MgSO4, Fe2(SO4)3 v FeSO4.
Cu 10. (B-07) 10: Cho 6,72 gam Fe vo dd cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn
phm kh duy nht). Sau khi p xy ra hon ton, thu c
A. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.
B. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.
C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.
D. 0,12 mol FeSO4.
Cu 11. (A-10) 39: Cho x mol Fe tan hon ton trong dd cha y mol H2SO4 (t l x : y = 2 : 5), thu c
mt sn phm kh duy nht v dd ch cha mui sunfat. S mol electron do lng Fe trn nhng khi
b ho tan l
A. 2x.
B. 3x.
C. 2y.
D. y.
Cu 12. (B-08) 46: Th tch dd HNO3 1M (long) t nht cn dng ho tan hon ton mt hh
gm 0,15 mol Fe v 0,15 mol Cu l (bit p to cht kh duy nht l NO)
A. 1,0 lt.
B. 0,6 lt.
C. 0,8 lt.
D. 1,2 lt.
Cu 13. (A-13) 33: Ha tan hon ton 1,805 gam hn hp gm Fe v kim loi X bng dung dch HCl,
thu c1,064 lt kh H2. Mt khc, ha tan hon ton 1,805 gam hn hp trn bng dung dch
HNO3 long (d), thu c 0,896 lt kh NO (sn phm kh duy nht). Bit cc th tch kh u o
iu kin tiu chun. Kim loi X l
Thng k H 2007-2014
A. Zn.

B. Al.
C. Cr.
D. Mg.
8.2. Oxit st tc dng vi axit

Cu 14. (C-08) 41: Ha tan hon ton Fe3O4 trong dd H2SO4 long (d) c dd X1. Cho lng d
bt Fe vo dd X1 (trong iu kin khng c khng kh) n khi p xy ra hon ton, thu c dd X 2
cha cht tan l
A. Fe2(SO4)3 v H2SO4.
B. FeSO4.
C. Fe2(SO4)3.
D. FeSO4 v
H2SO4.
Cu 15. (B-08) 12: Cho 9,12 gam hh gm FeO, Fe2O3, Fe3O4 t/d vi dd HCl (d). Sau khi cc p
xy ra hon ton, c dd Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l
A. 9,75.
B. 8,75.
C. 7,80.
D. 6,50.
Cu 16. (A-08) 4: ho tan hon ton 2,32 gam hh gm FeO, Fe3O4 v Fe2O3 (trong s mol
FeO bng s mol Fe2O3), cn dng va V lt dd HCl 1M. Gi tr ca V l
A. 0,23.
B. 0,18.
C. 0,08.
D. 0,16.
Cu 17. (C-09) 22: Cho m gam hh X gm FeO, Fe2O3 , Fe3O4 vo mt lng va dd HCl 2M, thu
c dd Y c t l s mol Fe2+ v Fe3+ l 1 : 2. Chia Y thnh 2 phn bng nhau. C cn phn mt thu
c m1 gam mui khan. Sc kh clo (d) vo phn hai, c cn dd sau p thu c m2 gam mui khan.
Bit m2 m1 = 0,71. Th tch dd HCl dng l
A. 240 ml.
B. 80 ml.
C. 320 ml.
D. 160 ml.
Cu 18. (C-11) 10: Ho tan hon ton hn hp X gm 0,2 mol Fe v 0,2 mol Fe2O3 vo dung dch
axit H2SO4 long (d), thu c 2,24 lt kh (ktc) v dung dch Y. Cho lng d dung dch NaOH
vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Gi tr nh nht ca m l
A. 57,4.
B. 59,1.
C. 60,8.
D. 54,0.
Cu 19. (C-12) 1: Cho 42,4 gam hn hp gm Cu v Fe3O4 (c t l s mol tng ng l 3 : 1)
tc dng vi dung dch HCl d, sau khi cc phn ng xy ra hon ton cn li m gam cht rn. Gi tr
ca m l
A. 19,2.
B. 9,6.
C. 12,8.
D. 6,4.
Cu 20. (B-07) 12: Nung m gam bt st trong oxi, thu c 3 gam hh cht rn X. Ha tan ht hh X
trong dd HNO3 (d), thot ra 0,56 lt ( ktc) NO (l sn phm kh duy nht). Gi tr ca m l:
A. 2,52.
B. 2,22.
C. 2,62.
D. 2,32.
Cu 21. (A-08) 29: Cho 11,36 gam hh gm Fe, FeO, Fe2O3 v Fe3O4 p ht vi dd HNO3 long (d),
thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dd X. C cn dd X thu c m gam
mui khan. Gi tr ca m l
A. 38,72.
B. 35,50.
C. 49,09.
D. 34,36.
Cu 22. (B-12) 2: t 5,6 gam Fe trong khng kh, thu c hn hp cht rn X. Cho ton b X tc
dng vi dung dch HNO3 long (d), thu c kh NO (sn phm kh duy nht) v dung dch
cha m gam mui. Gi tr ca m l
A. 18,0.
B. 22,4.
C. 15,6.
D. 24,2.
Cu 23. (B-13) 29: Hn hp X gm FeO, Fe2O3 v Fe3O4. Cho kh CO qua m gam X nung nng, sau
mt thi gian thu c hn hp cht rn Y v hn hp kh Z. Cho ton b Z vo dung dch Ca(OH)2
d, n phn ng hon ton, thu c 4 gam kt ta. Mt khc, ha tan hon ton Y trong dung dch
H2SO4 c, nng (d), thu c 1,008 lt kh SO2 (ktc, sn phm kh duy nht) v dung dch cha
18 gam mui. Gi tr ca m l
A. 6,80.
B. 7,12.
C. 13,52.
D. 5,68.
Cu 24.
(A-14): Hn hp X gm Al, Fe3O4 v CuO, trong oxi chim 25% khi lng hn hp.
Cho 1,344 lt kh CO (ktc) i qua m gam X nung nng, sau mt thi gian thu c cht rn Y v hn
hp kh Z c t khi so vi H2 bng 18. Ha tan hon ton Y trong dung dch HNO3 long (d), thu
c dung dch cha 3,08m gam mui v 0,896 lt kh NO ( ktc, l sn phm kh duy nht). Gi tr
m gn gi tr no nht sau y?
A. 8,0
B. 9,5
C. 8,5
D. 9,0
Cu 25. (C -14): Nung nng 8,96 gam bt Fe trong kh O2 mt thi gian, thu c 11,2 gam hn
hp cht rn X gm Fe, FeO, Fe2O3 v Fe3O4. Ha tan ht X trong dung dch hn hp gm a mol
HNO3 v 0,06 mol H2SO4 thu c dung dch Y ( khng cha NH4+ ) v 0,896 lt kh NO duy nht
ktc. Gi tr ca a l :
Thng k H 2007-2014
A. 0,32.

B. 0,16.
C. 0,04.
D. 0,44.
Cu 26. (B-13) 34: Cho m gam mt oxit st phn ng va vi 0,75 mol H2SO4, thu c dung
dch ch cha mt mui duy nht v 1,68 lt kh SO2 (ktc, sn phm kh duy nht ca S+6). Gi tr ca
m l
A. 24,0.
B. 34,8.
C. 10,8.
D. 46,4.
Cu 27. (C-13) 15: Ha tan ht 0,2 mol FeO bng dung dch H2SO4 c, nng (d), thu c kh SO2
(sn phm kh duy nht). Hp th hon ton kh SO2 sinh ra trn vo dung dch cha 0,07 mol KOH v
0,06 mol NaOH, thu c dung dch cha m gam mui. Gi tr ca m l
A. 15,32.
B. 12,18.
C. 19,71.
D. 22,34.
Cu 52. (B-10) 20: Ho tan hon ton 2,44g hh bt X gm FexOy v Cu bng dd H2SO4 c nng (d). Sau p
thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dd cha 6,6 gam hh mui sunfat. Phn trm khi
lng ca Cu trong X l
A. 39,34%.
B. 65,57%.
C. 26,23%.
D. 13,11%.
8.3. Phn ng NHIT NHM

Cu 28. (C-07) 9: P ho hc xy ra trong trng hp no di y khng thuc loi p nhit
nhm?
A. Al t/d vi Fe3O4 nung nng.
B. Al t/d vi CuO nung nng.
C. Al t/d vi Fe2O3 nung nng.
D. Al t/d vi axit H2SO4 c, nng.
Cu 29. (C-11) 19: Nung hn hp gm 10,8 gam Al v 16,0 gam Fe2O3 (trong iu kin khng c
khng kh), sau khi phn ng xy ra hon ton thu c cht rn Y. Khi lng kim loi trong Y l
A. 16,6 gam.
B. 11,2 gam.
C. 5,6 gam.
D. 22,4 gam.
Cu 30. (B-09) 20: Nung nng m gam hh gm Al v Fe3O4 trong iu kin khng c khng kh. Sau
khi p xy ra hon ton, thu c hh rn X. Cho X t/d vi dd NaOH (d) thu c dd Y, cht rn Z
v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dd Y, thu c 39 gam kt ta. Gi tr ca m l
A. 45,6.
B. 48,3.
C. 36,7.
D. 57,0.
Cu 31. (C-08) 45: t nng mt hh gm Al v 16 gam Fe2O3 (trong iu kin khng c khng kh)
n khi phn ng xy ra hon ton, thu c hh rn X. Cho X t/d va vi V ml dd NaOH 1M sinh ra
3,36 lt H2 ( ktc). Gi tr ca V l
A. 150.
B. 100.
C. 200.
D. 300.
Cu 32. (A-08) 45: Nung nng m gam hh Al v Fe2O3 (trong mi trng khng c khng kh) n
khi p xy ra hon ton, thu c hh rn Y. Chia Y thnh hai phn bng nhau:
- Phn 1 t/d vi dd H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc);
- Phn 2 t/d vi dd NaOH (d), sinh ra 0,84 lt kh H2 ( ktc).
Gi tr ca m l
A. 22,75
B. 21,40.
C. 29,40.
D. 29,43.
Cu 33. (C-12) 30: Nung hn hp bt gm Al v Fe2O3 (trong iu kin khng c oxi), thu c
hn hp cht rn X. Chia X thnh 2 phn bng nhau:
- Cho phn 1 vo dung dch HCl (d) thu c 7,84 lt kh H2 (ktc);
- Cho phn 2 vo dung dch NaOH (d) thu c 3,36 lt kh H2 (ktc).
Bit rng cc phn ng u xy ra hon ton. Phn trm khi lng ca Fe trong X l
A. 33,61%.
B. 42,32%.
C. 66,39%.
D. 46,47%.
Cu 34. (B-10) 22: Trn 10,8g bt Al vi 34,8g bt Fe3O4 ri tin hnh p nhit nhm trong iu kin
khng c khng kh. Ho tan hon ton hh rn sau p b ng dd H2SO4 long (d), thu c 10,752 lt
kh H2 (ktc). Hiu sut ca p nhit nhm l
A. 80%.
B. 90%.
C. 70%.
D. 60%.
Cu 35. (B-11) 8: Thc hin phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr2O3
(trong iu kin khng c O2), sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt
lng d dung dch HCl (long, nng), sau khi cc phn ng xy ra hon ton, thu c 2,016 lt H2
(ktc). Cn nu cho ton b X vo mt lng d dung dch NaOH (c, nng), sau khi cc phn ng
kt thc th s mol NaOH phn ng l
A. 0,14 mol.
B. 0,08 mol.
C. 0,16 mol.
D. 0,06 mol.
Thng k H 2007-2014
Cu 36. (B-12) 50: Nung nng 46,6 gam hn hp gm Al v Cr2O3 (trong iu kin khng c
khng kh) n khi phn ng xy ra hon ton. Chia hn hp thu c sau phn ng thnh hai phn
bng nhau. Phn mt phn ng va vi 300 ml dung dch NaOH 1M (long). ha tan ht phn
hai cn va dung dch cha a mol HCl. Gi tr ca a l
A. 0,9.
B. 1,3.
C. 0,5.
D. 1,5.
Cu 37. (A-14): Thc hin phn ng nhit nhm hn hp gm Al v m gam hai oxit st trong kh tr,
thu c hn hp rn X. Cho X vo dung dch NaOH d, thu c dung dch Y, cht khng tan Z v
0,672 lt kh H2 (ktc). Sc kh CO2 d vo Y, thu c 7,8 gam kt ta. Cho Z tan ht vo dung dch
H2SO4 , thu c dung dch cha 15,6 gam mui sunfat v 2,464 lt kh SO 2 ( ktc, l sn phm kh
duy nht ca H2SO4). Bit cc phn ng xy ra hon ton. Gi tr ca m l
A. 5,04
B. 6,29
C. 6,48
D. 6,96
Cu 38. (A-12) 9: Hn hp X gm Fe3O4 v Al c t l mol tng ng 1 : 3. Thc hin phn ng

nhit nhm X (khng c khng kh) n khi phn ng xy ra hon ton thu c hn hp gm
A. Al, Fe, Fe3O4 v Al2O3.
B. Al2O3, Fe v Fe3O4.
C. Al2O3 v Fe.
D. Al, Fe v Al2O3.
Cu 39. (B-14): Nung hn hp gm 0,12 mol Al v 0,04 mol Fe2O4 mt thi gian, thu c hn hp
rn X. Ha tan hon ton X trong dung dch HCl d thu c 0,15 mol kh H2 v m gam mui. Gi tr
ca m l :A. 34,10.
B. 32,58.
C. 31,97. D. 33,39.
Cu 40. (A-13) 24: Hn hp X gm 3,92 gam Fe, 16 gam Fe2O3 v m gam Al. Nung X nhit cao
trong iu kin khng c khng kh, thu c hn hp cht rn Y. Chia Y thnh hai phn bng nhau.
Phn mt tc dng vi dung dch H2SO4 long (d), thu c 4a mol kh H2. Phn hai phn ng vi
dung dch NaOH d, thu c a mol kh H2. Bit cc phn ng u xy ra hon ton. Gi tr ca m l
A. 5,40.
B. 7,02.
C. 3,51.
D. 4,05.
8.4. Hp cht cha S ca Fe

Cu 41. (B-08) 11: Nung mt hh rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh
(d). Sau khi cc p xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l
Fe2O3 v hh kh. Bit p sut kh trong bnh trc v sau p bng nhau, mi lin h gia a v b l
(bit sau cc p, lu hunh mc oxi ho +4, th tch cc cht rn l khng ng k)
A. a = 0,5b.
B. a = b.
C. a = 4b.
D. a = 2b.
Cu 42. (A-11) 31: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh
(gm 20% th tch O2 v 80% th tch N2) n khi cc phn ng xy ra hon ton, thu c mt cht
rn duy nht v hn hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li l O2. Phn trm
khi lng ca FeS trong hn hp X l
A. 59,46%.
B. 42,31%.
C. 26,83%.
D. 19,64%.
Cu 43. (B-10) 36: t chy hon ton m gam FeS2 b ng mt lng O2 va , thu c kh X. Hp
th ht X vo 1 lt dd cha Ba(OH)2 0,15M v KOH 0,1M, thu c dd Y v 21,7 gam kt ta. Cho Y vo
dd NaOH, thy xut hin thm kt ta. Gi tr ca m l
A. 23,2
B. 12,6.
C. 18,0.
D. 24,0.
Cu 44. (A-07) 5: Ho tan hon ton hh gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ),
thu c dd X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l
A. 0,075.
B. 0,12.
C. 0,06.
D. 0,04.
Cu 45. (A-12) : Cho 18,4 gam hn hp X gm Cu2S, CuS, FeS2 v FeS tc dng ht vi HNO3 (c
nng, d) thu c V lt kh ch c NO2 ( ktc, sn phm kh duy nht) v dung dch Y. Cho ton
b Y vo mt lng d dung dch BaCl2, thu c 46,6 gam kt ta; cn khi cho ton b Y tc dng
vi dung dch NH3 d thu c 10,7 gam kt ta. Gi tr ca V l
A. 38,08.
B. 24,64.
C. 16,8.
D. 11,2.
Cu 46. (B-07) 48: Cho 0,01 mol mt hp cht ca st t/d ht vi H2SO4 c nng (d), thot ra
0,112 lt ( ktc) kh SO2 (l sn phm kh duy nht). Cng thc ca hp cht st l
A. FeS.
B. FeS2.
C. FeO
D. FeCO3.
Thng k H 2007-2014
8.5. GANG THP

Cu 47. (A-08) 47: Trong cc loi qung st, qung c hm lng st cao nht l
A. hematit nu.
B. manhetit.
C. xierit.
D. hematit .
Cu 48. (A-12) 6: Qung no sau y giu st nht?
A. Xierit.
B. Manhetit.
C. Hematit .
D. Pirit st.
Cu 49. (A-11) 4: Qung st manhetit c thnh phn chnh l
A. FeCO3.
B. Fe2O3.
C. Fe3O4.
D. FeS2.
Cu 50. (B-08)3: Nguyn tc luyn thp t gang l:
A. Dng O2 oxi ho cc tp cht Si, P, S, Mn, trong gang thu c thp.
B. Dng cht kh CO kh oxit st thnh st nhit cao.
C. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, trong gang thu c thp.
D. Tng thm hm lng cacbon trong gang thu c thp.
Cu 51. (B-11)2 luyn c 800 tn gang c hm lng st 95%, cn dng x tn qung
manhetit cha 80% Fe3O4 (cn li l tp cht khng cha st). Bit rng lng st b hao ht
trong qu trnh sn xut l 1%. Gi tr ca x l
A. 1394,90.
B. 1325,16.
C. 1311,90.
D. 959,59.
Thng k H 2007-2014
9. Crom, ng, niken, ch, km, bc, vng, thic
Cu 1. (A-07): Pht biu khng ng l:

A. Cc hp cht CrO, Cr(OH)2 t/d c vi dd HCl cn CrO3 t/d c vi dd NaOH.
B. Thm dd kim vo mui icromat, mui ny chuyn thnh mui cromat.
C. Cc hp cht Cr2O3, Cr(OH)3, CrO, Cr(OH)2 u c tnh cht lng tnh.
D. Hp cht Cr(II) c tnh kh c trng cn hp cht Cr(VI) c tnh oxi ho mnh.
Cu 2. (C-08) 53: Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong
dy c tnh cht lng tnh l
A. 5.
B. 2.
C. 3.
D. 4
Cu 3. (C -14) : Cht no sau y va phn ng vi dung dch NaOH long, va phn ng vi
dung dch HCl? A. NaCrO2
B. Cr(OH)3
C. Na2CrO4
D. CrCl3
Cu 4. (B-14) : Cho s phn ng sau:
o
RCl2 + H2
R + 2HCl(long)
o
t
2R + 3Cl2
2RCl3
R(OH)3 + NaOH(long) NaRO2 + 2H2O
Kim loi R l
A. Cr.
B. Al.
C. Mg.
D. Fe.
A. CrO3 l mt oxit axit
B. Cr(OH)3 tan c trong dung dch NaOH
C. Cr phn ng vi axit H2SO4 long to thnh Cr3+
D. Trong mi trng kim, Br2 oxi ha CrO2 thnh CrO24
A. Crom(III) oxit v crom(III) hiroxit u l cht c tnh lng tnh.
C. Ancol etylic bc chy khi tip xc vi CrO3.
B. Khi phn ng vi dung dch HCl, kim loi Cr b oxi ho thnh ion Cr2+.
D. Crom(VI) oxit l oxit baz.
Cu 7. (C-07) 55: Cc hp cht trong dy cht no di y u c tnh lng tnh?
A. Cr(OH)3, Fe(OH)2, Mg(OH)2.
B. Cr(OH)3, Zn(OH)2, Pb(OH)2.
C. Cr(OH)3, Zn(OH)2, Mg(OH)2.
D. Cr(OH)3, Pb(OH)2, Mg(OH)2.
Cu 8. (B-07) : Nung hh bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi p hon
ton, thu c 23,3 gam hh rn X. Cho ton b hh X p vi axit HCl (d) thot ra V lt kh H2 (
ktc). Gi tr ca V l
A. 7,84.
B. 4,48.
C. 3,36.
D. 10,08.
Cu 9. (C-09) 47: iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm vi
hiu sut ca phn ng l 90% th khi lng bt nhm cn dng ti thiu l
A. 81,0 gam.
B. 54,0 gam.
C. 40,5 gam.
D. 45,0 gam.
Cu 10. (C-11) 43: Ho tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d thu
c dung dch Y. C cn dung dch Y thu c (m + 31,95) gam hn hp cht rn khan. Ho tan
hon ton 2m gam hn hp X vo nc thu c dung dch Z. Cho t t n ht dung dch Z vo
0,5 lt dung dch CrCl3 1M n phn ng hon ton thu c kt ta c khi lng l
A. 54,0 gam.
B. 20,6 gam.
C. 30,9 gam.
D. 51,5 gam.
Cu 11. (A-08) : oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH,
lng ti thiu Cl2 v KOH tng ng l
A. 0,015 mol v 0,04 mol.
B. 0,015 mol v 0,08 mol.
C. 0,03 mol v 0,08 mol.
D. 0,03 mol v 0,04 mol.
Cu 12. (B-08) 52: Cho cc dd: HCl, NaOH c, NH3, KCl. S dd p c vi Cu(OH)2 l
A. 1.
B. 3.
C. 2.
D. 4.
Cu 13. (A-09) : Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hh rn (c
cha mt oxit) nng 0,95m gam. Phn trm khi lng PbS b t chy l
A. 95,00%.
B. 25,31%.
C. 74,69%.
D. 64,68%
Cu 14. (A-09) 60: Trng hp xy ra p l
A. Cu + Pb(NO3)2 (long)
B. Cu + HCl (long)
Thng k H 2007-2014
C. Cu + H2SO4 (long)
D. Cu + HCl (long) + O2
Cu 15. (B-09) 47: Cho s chuyn ho gia cc hp cht ca crom:
(Cl 2 KOH)
H 2 SO4
(FeSO 4 H 2SO 4 )
KOH
Y
Z
T
Cr(OH)3 X
Cc cht X, Y, Z, T theo th t l:
A. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3.
B. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3.
C. KCrO2; K2Cr2O7; K2CrO4; CrSO4.
D. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3.
Cl
KOH ( dac , du ),Cl2

2
X
Cu 16. (C-12) : Cho s phn ng: Cr
Y
to
Bit Y l hp cht ca crom. Hai cht X v Y ln lt l

A. CrCl2 v Cr(OH)3.
B. CrCl3 v K2Cr2O7.
C. CrCl3 v K2CrO4.
K2CrO4.
D.
CrCl2
t
dd NaOH,du
Cl2 , du , t
Cu 17. (A-13) 57: Cho s phn ng Cr
Y
X
o
Cht Y trong s trn l

A. Na2Cr2O7.
B. NaCrO2 .
C. Cr(OH)3.
D. Cr(OH)2.
Cu 18. (C-11) 60: Khi cho lng d dung dch KOH vo ng nghim ng dung dch kali icromat,
dung dch
trong ng nghim
A. chuyn t mu da cam sang mu vng.
B. chuyn t mu vng sang mu .
C. chuyn t mu da cam sang mu xanh lc.
D. chuyn t mu vng sang mu da cam.
Cu 19. (A-11) 51: Hin tng xy ra khi nh vi git dung dch H2SO4 vo dung dch Na2CrO4 l:
A. Dung dch chuyn t mu vng sang khng mu.
B. Dung dch chuyn t mu da cam sang mu vng.
C. Dung dch chuyn t mu vng sang mu da cam.
D. Dung dch chuyn t khng mu sang mu da cam.
Cu 20. (C-11) 45: Cho phn ng:
6FeSO4 +K2Cr2O7 +7H2SO4 3Fe2(SO4)3 + Cr2(SO4)3 + K2SO4 + 7H2O
Trong phn ng trn, cht oxi ha v cht kh ln lt l
A. K2Cr2O7 v FeSO4.
B. K2Cr2O7 v H2SO4. C. H2SO4 v FeSO4.
D.
FeSO4
v
K2Cr2O7
Cu 21. (B-09) 55: Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl p v
s mol NO (sn phm kh duy nht) to thnh ln lt l
A. 0,03 v 0,02.
B. 0,06 v 0,01.
C. 0,03 v 0,01.
D. 0,06 v 0,02.
Cu 22. (B-09) 59: Ha tan hon ton 1,23 gam hh X gm Cu v Al vo dd HNO3 c, nng thu
c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dd Y. Sc t t kh NH3 (d) vo dd Y,
sau khi p xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hh X v
gi tr ca m ln lt l
A. 21,95% v 2,25.
B. 78,05% v 2,25.
C. 21,95% v 0,78.
D. 78,05% v 0,78.
Cu 23. (C-08) 54: Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch
H2SO4 long nng (trong iu kin khng c khng kh), thu c dung dch X v 7,84 lt kh H2 (
ktc). C cn dung dch X (trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m
l
A. 42,6.
B. 45,5.
C. 48,8.
D. 47,1.
Cu 24. (A-10) : Cho m gam hh bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau t/d ht vi lng
d dd HCl long, nng thu c dd Y v kh H2. C cn dd Y thu c 8,98 gam mui khan. Nu cho m
gam hh X t/d hon ton vi O2 (d) to hh 3 oxit th th tch kh O2 (ktc) p l
A. 2,016 lt.
B. 1,008 lt.
C. 0,672 lt.
D. 1,344 lt.
A. Trong mi trng kim, mui Cr(III) c tnh kh v b cc cht oxi ho mnh chuyn thnh mui
Cr(VI).
B. Do Pb2+/Pb ng trc 2H+/H2 trong dy in ho nn Pb d dng p vi dd HCl long ngui,
gii phng kh H2
C. CuO nung nng khi t/d vi NH3 hoc CO, u thu c Cu.
D. Ag khng p vi dd H2SO4 long nhng p vi dd H2SO4 c, nng.
Cu 26. (C-10) 52: Cho m gam bt crom phn ng hon ton vi dung dch HCl (d), thu c V lt
Thng k H 2007-2014
kh H2 (ktc). Mt khc, cng m gam bt crom trn phn ng hon ton vi kh O2 (d), thu c 15,2
gam oxit duy nht. Gi tr ca V l
A. 2,24
B. 4,48.
C. 3,36.
D. 6,72.
Cu 27. (C-07) 53: Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch
NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X
bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3
trong hn hp X l (hiu sut ca cc phn ng l 100%)
A. 50,67%.
B. 20,33%.
C. 66,67%.
D. 36,71%.
Cu 28. (C-12) 50: Ha tan hon ton 2,7 gam hn hp X gm Fe, Cr, Al bng dung dch HCl d,
thu c 1,568 lt kh H2 (ktc). Mt khc, cho 2,7 gam X phn ng hon ton vi kh Cl2 d, thu c
9,09 gam mui. Khi lng Al trong 2,7 gam X l bao nhiu?
A. 1,08 gam.
B. 0,54 gam.
C. 0,81 gam.
D. 0,27 gam.
Cu 29. (A-12) 43: Nhn xt no sau y khng ng?
A. Vt dng lm bng nhm v crom u bn trong khng kh v nc v c mng oxit bo v.
B. Crom l kim loi cng nht trong tt c cc kim loi.
C. Nhm v crom u b th ng ha bi HNO3 c, ngui.
D. Nhm v crom u phn ng vi dung dch HCl theo cng t l s mol.
Cu 30. (A-13) 49: Cho cc pht biu sau:
(a) Trong bng tun hon cc nguyn t ha hc, crom thuc chu k 4, nhm VIB.
(b) Cc oxit ca crom u l oxit baz.
(c) Trong cc hp cht, s oxi ha cao nht ca crom l +6.
(d) Trong cc phn ng ha hc, hp cht crom(III) ch ng vai tr cht oxi ha.
(e) Khi phn ng vi kh Cl2 d, crom to ra hp cht crom(III).
Trong cc pht biu trn, nhng pht biu ng l:
A. (a), (c) v (e).
B. (b), (c) v (e).
C. (a), (b) v (e).
Cu 31. (B-13) 59: Trng hp no sau y khng xy ra phn ng?
A. Au + HNO3 c
B. Ag + O3
C. Sn + HNO3 long
D. Ag + HNO3 c
D. (b), (d) v (e).
Cu 32. (C-13) 49: Cho 1,56 gam Cr phn ng ht vi dung dch H2SO4 long (d), un nng, thu
c V ml kh H2 (ktc). Gi tr ca V l
A. 896.
B. 336.
C. 224.
D. 672.
A. Cu(OH)2 tan c trong dung dch NH3.
B. Cr(OH)2 l hiroxit lng tnh.
C. Kim loi Cu phn ng c vi dung dch hn hp KNO3 v HCl.
D. Kh NH3 kh c CuO nung nng.
Thng k H 2007-2014
10. TNG HP KIN THC

10.1. L thuyt
Cu 143. (C-09) 40: Ch dng dd KOH phn bit c cc cht ring bit trong nhm no sau y?
A. Mg, Al2O3, Al.
B. Mg, K, Na.
C. Zn, Al2O3, Al.
D. Fe, Al 2O3, Mg.
Cu 144. (C-10) 43: Thuc th dng phn bit dung dch NH4NO3 vi dung dch (NH4)2SO4 l
A. ng(II) oxit v dung dch NaOH.
B . ng(II) oxit v dung dch HCl.
C. dung dch NaOH v dung dch HCl
. D. kim loi Cu v dung dch HCl.
Cu 145. (B-10) 4: Phng php loi b tp cht HCl c ln trong kh H2S l: Cho hh kh li t t qua
mt lng d dd
A. Pb(NO3)2.
B. NaHS.
C. AgNO3.
D. NaOH.
Cu 146. (A-07) 2: nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l b
mt nhn, ta dng thuc th l
A. Al.
B. Fe.
C. CuO.
D. Cu.
Cu 147. (C -14): Cc cht kh iu ch trong phng th nghim thng c thu theo phng php
y khng kh (cch 1, cch 2) hoc y nc (cch 3) nh cc hnh v di y:
C th dng cch no trong 3 cch trn thu kh NH3 ?

A. Cch 1
B. Cch 2
C. Cch 3
D. Cch 2 hoc Cch 3
Cu 148. (B-07) 30: C th phn bit 3 dd: KOH, HCl, H2SO4 (long) bng mt thuc th l
A. giy qu tm.
B. Zn.
C. Al.
D. BaCO3.
Cu 149. (C-10) 60: Thuc th dng phn bit 3 dung dch ring bit: NaCl, NaHSO4, HCl l
A. NH4Cl.
B. (NH4)2CO3.
C. BaCO3.
D. BaCl2.
Cu 150. (C-13) 45: Thuc th no sau y dng phn bit kh H2S vi kh CO2?
A. Dung dch HCl.
B. Dung dch Pb(NO3)2.
C. Dung dch K2SO4.
D. Dung dch NaCl.
Cu 151. (A-08) 56: Tc nhn ch yu gy ma axit l
A. CO v CH4.
B. CH4 v NH3.
C. SO2 v NO2.
D. CO v CO2.
Cu 152. (B-08) 53: Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c
dng rc ln thu ngn ri gom li l
A. vi sng.
B. ct.
C. mui n.
D. lu hunh.
Cu 153. (B-10) 47: Cho mt s nhn nh v nguyn nhn gy nhim mi trng khng kh nh sau:
(1) Do hot ng ca ni la.
(2) Do kh thi cng nghip, kh thi sinh hot.
(3) Do kh thi t cc phng tin giao thng.
(4) Do kh sinh ra t qu trnh quang hp ca cy xanh.
(5) Do nng cao ca cc ion kim loi: Pb2+, Hg2+, Mn2+, Cu2+ trong cc ngun nc.
Nhng nhn nh ng l:
A. (1), (2), (3).
B. (2), (3), (5).
C. (1), (2), (4).
D. (2), (3), (4).
Cu 154. (C -14): Trng hp no sau y khng xy ra phn ng iu kin thng?
A. Dn kh Cl2 vo dung dch H2S
B. Cho dung dch Ca(HCO3)2 vo dung dch NaOH
C. Cho dung dch Na3PO4 vo dung dch AgNO3
D. Cho CuS vo dung dch HCl
Cu 155. (B-10) 5: Pht biu no sau y khng ng khi so snh tnh cht ha hc ca nhm v
crom?
A. Nhm v crom u b th ng ha trong dd H2SO4 c ngui.
Thng k H 2007-2014
B. Nhm c tnh kh mnh hn crom.

C. Nhm v crom u p vi dd HCl theo cng t l v s mol.
D. Nhm v crom u bn trong khng kh v trong nc.
Cu 156. (C-10) 17: Ho tan hh gm: K2O, BaO, Al2O3, Fe3O4 vo nc (d), thu c dd X v cht rn
Y. Sc kh CO2 n d vo dd X, sau khi cc p xy ra hon ton thu c kt ta l
A. Fe(OH)3.
B. K2CO3.
C. Al(OH)3.
D. BaCO3.
Cu 157. (B-09) 11: Khi nhit phn hon ton tng mui X, Y th u to ra s mol kh nh hn s
mol mui tng ng. t mt lng nh tinh th Y trn n kh khng mu, thy ngn la c mu
vng. Hai mui X, Y ln lt l:
A. KMnO4, NaNO3.
B. Cu(NO3)2, NaNO3.
C. CaCO3, NaNO3.
D. NaNO3, KNO3.
Cu 158. (A-07) 51: C 4 dd mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dd KOH (d) ri
thm tip dd NH3 (d) vo 4 dd trn th s cht kt ta thu c l
A. 2.
B. 1.
C. 3.
D. 4.
Cu 159. (C-10) 28: Cht rn X p vi dd HCl c dd Y. Cho t t dd NH3 n d vo dd Y, ban u
xut hin kt ta xanh, sau kt ta tan, thu c dd mu xanh thm. Cht X l
A. FeO.
B. Cu.
C. CuO.
D. Fe.
Cu 160. (C-09) 45: Ho tan hon ton mt lng bt Zn vo mt dung dch axit X. Sau phn ng thu
c dung dch Y v kh Z. Nh t t dung dch NaOH (d) vo Y, un nng thu c kh khng mu T.
Axit X l
A. H2 SO4 c.
B. HNO3.
C. H3PO4.
D. H2SO4 long.
Cu 161. (C-10) 37: Nh t t dd NaOH n d vo dd X. Sau khi cc p xy ra hon ton ch thu
c dd trong sut. Cht tan trong dd X l
A. AlCl3.
B. CuSO4.
C. Ca(HCO3)2.
D. Fe(NO3)3.
Cu 162. (A-11) 24: Phn chua c dng trong ngnh cng nghip thuc da, cng nghip giy, cht
cm mu trong ngnh nhum vi, cht lm trong nc. Cng thc ho hc ca phn chua l
A. Na2SO4.Al2(SO4)3.24H2O.
B. K2SO4.Al2(SO4)3.24H2O.
C. (NH4)2SO4.Al2(SO4)3.24H2O.
D. Li2SO4.Al2(SO4)3.24H2O.
Cu 163. (B-14): Phng trnh ha hc no sau y khng ng?
A. Ca + 2H2O Ca(OH)2 + H2.
t
B. 2Al + Fe2O3
Al2O3 + 2Fe.
t
C. 4Cr + 3O2
D. 2Fe + 3H2SO4(long) Fe2(SO4)3 + 3H2.
2Cr2O3.
Cu 164. (C-10) 40: Cho s chuyn ho sau:
X
Y
Z
CaO CaCl2 Ca(NO3)2 CaCO3
Cng thc ca X, Y, Z ln lt l:
A. HCl, HNO3, Na2CO3.
B. Cl2, HNO3, CO2
C. HCl, AgNO3, (NH4)2CO3.
D.
Cl2,
AgNO3, MgCO3.
Cu 165. (C-10) 6: Cho cc dd long: (1) FeCl3, (2) FeCl2, (3) H2SO4, (4) HNO3, (5) hh gm HCl v
NaNO3. Nhng dd p c vi kim loi Cu l:
A. (1), (3), (5).
B. (1), (2), (3).
C. (1), (3), (4).
D. (1), (4), (5).
A. Cr(OH)3 tan trong dung dch NaOH.
B. Trong mi trng axit, Zn kh Cr3+ thnh Cr.
C. Photpho bc chy khi tip xc vi CrO3.
D. Trong mi trng kim, Br2 oxi ha C rO 2 - t h nh C rO 4 2 Cu 167. (C-11) 35: C 4 ng nghim c nh s theo th t 1, 2, 3, 4. Mi ng nghim cha mt
trong cc dung dch AgNO3, ZnCl2, HI, Na2CO3. Bit rng:
- Dung dch trong ng nghim 2 v 3 tc dng c vi nhau sinh ra cht kh;
- Dung dch trong ng nghim 2 v 4 khng phn ng c vi nhau.
Dung dch trong cc ng nghim 1, 2, 3, 4 ln lt l:
A. ZnCl2, HI, Na2CO3, AgNO3.
B. ZnCl2, Na2CO3, HI, AgNO3.
C. AgNO3, HI, Na2CO3, ZnCl2.
D. AgNO3, Na2CO3, HI, ZnCl2.
Cu 168. (A-07) 39: Khi nung hh cc cht Fe(NO3)2, Fe(OH)3 v FeCO3 trong khng kh n khi
lng khng i, thu c mt cht rn l
A. Fe.
B. FeO.
C. Fe3O4.
D. Fe2O3.
Cu 169. (B-11) 28: Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng ca
nit trong X l 11,864%. C th iu ch c ti a bao nhiu gam hn hp ba kim loi t 14,16 gam
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X?
A. 10,56 gam.
B. 3,36 gam.
C. 7,68 gam.
D. 6,72 gam.
Cu 170. (B-08) 44: Hh rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hh X tan hon ton trong dd
A. NaOH (d).
B. HCl (d).
C. AgNO3 (d).
D. NH3(d).
Cu 171. (C-12) 43: loi b Al, Fe, CuO ra khi hn hp gm Ag, Al, Fe v CuO, c th dng lng
d dung dch no sau y?
A. Dung dch NaOH.
B. Dung dch Fe(NO3)3.
C. Dung dch HNO3.
D. Dung dch HCl.
Cu 172. (B-10) 42: Cho cc cp cht vi t l s mol tng ng nh sau:
(a) Fe3O4 v Cu (1:1);
(b) Sn v Zn (2:1);
(c) Zn v Cu (1:1);
(d) Fe2(SO4)3 v Cu (1:1);
(e) FeCl2 v Cu (2:1);
(g) FeCl3 v Cu (1:1).
S cp cht tan hon ton trong mt lng d dd HCl long nng l
A. 4.
B. 2.
C. 3.
D. 5.
(1) t dy st trong kh clo.
(2) t nng hn hp bt Fe v S (trong iu kin khng c oxi).
(3) Cho FeO vo dung dch HNO3 (long, d).
(4) Cho Fe vo dung dch Fe2(SO4)3.
(5) Cho Fe vo dung dch H2SO4 (long, d).
C bao nhiu th nghim to ra mui st(II)?
A. 2.
B. 1.
C. 4.
D. 3.
Cu 174. (B-11) 2: Dy gm cc cht (hoc dung dch) u phn ng c vi dung dch FeCl2 l:
A. Bt Mg, dung dch BaCl2, dung dch HNO3. B. Kh Cl2, dung dch Na2CO3, dung dch HCl.
C. Bt Mg, dung dch NaNO3, dung dch HCl. D. Kh Cl2, dung dch Na2S, dung dch HNO3.
(1) Sc kh H2S vo dung dch FeSO4;
(2) Sc kh H2S vo dung dch CuSO4;
(3) Sc kh CO2 (d) vo dung dch Na2SiO3;
(4) Sc kh CO2 (d) vo dung dch Ca(OH)2;
(5) Nh t t dung dch NH3 n d vo dung dch Al2(SO4)3;
(6) Nh t t dung dch Ba(OH)2 n d vo dung dch Al2(SO4)3.
Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l
A. 5.
B. 6.
C. 3.
D. 4.
A. Hn hp FeS v CuS tan c ht trong dung dch HCl d.
B. Thi khng kh qua than nung , thu c kh than t.
C. Photpho d bc chy trong khng kh iu kin thng.
D. Dung dch hn hp HCl v KNO3 ho tan c bt ng.
Cu 177. (B-09) 12: C cc th nghim sau:
(I) Nhng thanh st vo dd H2SO4 long, ngui.
(II)Sc kh SO2 vo nc brom.
(III) Sc kh CO2 vo nc Gia-ven.
(IV) Nhng l nhm vo dd H2SO4 c,
ngui.
S th nghim xy ra p ho hc l
A. 2.
B. 1.
C. 3.
D. 4.
Cu 178. (B-09) 40: Th nghim no sau y c kt ta sau p?
B. Cho dd NH3 n d vo dd AlCl3.
A. Cho dd NaOH n d vo dd Cr(NO3)3.
D. Thi CO2 n d vo dd Ca(OH) 2.
C. Cho dd HCl n d vo dd NaAlO2 (hoc Na[Al(OH)4]).
Cu 179. (B-14): Tin hnh cc th nghim sau
(a) Cho dung dch NH3 vo dung dch BaCl2
(b) Sc kh SO2 vo dung dch H2S
(c) Cho dung dch AgNO3 vo dung dch H3PO4
(d) Cho dung dch AgNO3 vo dung dch HCl
Thng k H 2007-2014
(e) Cho dung dch AgNO3 vo dung dch HF

Sau khi kt thc th nghim, s trng hp thu c kt ta l
A. 2
B.3
C. 5
D. 4
(a) Cho Al vo dung dch HCl.
(b) Cho Al vo dung dch AgNO3.
(c) Cho Na vo H2O.
(d) Cho Ag vo dung dch H2SO4 long.
Trong cc th nghim trn, s th nghim xy ra phn ng l
A. 1.
B. 2.
C. 4.
D. 3.
Cu 181. (C-13) 26: Thc hin cc th nghim sau:
(a) Sc kh Cl2 vo dung dch NaOH nhit thng.
(b) Cho Fe3O4 vo dung dch HCl long (d).
(c) Cho Fe3O4 vo dung dch H2SO4 c, nng (d).
(d) Ha tan ht hn hp Cu v Fe2O3 (c s mol bng nhau) vo dung dch H2SO4 long (d).
Trong cc th nghim trn, sau phn ng, s th nghim to ra hai mui l
A. 2.
B. 4.
C. 1.
D. 3.
Cu 182. (A-10) 11: Cho 4 dd: H2SO4 long, AgNO3, CuSO4, AgF. Cht khng t/d c vi c 4 dd trn
l
A. NH3.
B. KOH.
C. NaNO3.
D. BaCl2.
Cu 183. (C-11) 50: Cho hn hp X gm Cu, Ag, Fe, Al tc dng vi oxi d khi un nng c cht
rn Y. Cho Y vo dung dch HCl d, khuy k, sau ly dung dch thu c cho tc dng vi dung
dch NaOH long, d. Lc ly kt ta to thnh em nung trong khng kh n khi lng khng i
thu c cht rn Z. Bit cc phn ng xy ra hon ton. Thnh phn ca Z gm:
A. Fe2O3, CuO.
B. Fe2O3, CuO, Ag.
C. Fe2O3, Al2O3. D. Fe2O3, CuO, Ag2O.
Cu 184. (C-12) 17: Cho Fe tc dng vi dung dch H2SO4 long to thnh kh X; nhit phn tinh th
KNO3 to thnh kh Y; cho tinh th KMnO4 tc dng vi dung dch HCl c to thnh kh Z. Cc kh X, Y v Z
ln lt l
A. SO2, O2 v Cl2.
B. H2, NO2 v Cl2.
C. H2, O2 v Cl2.
D. Cl2, O2 v H2S.
Cu 185. (A-10) 17: C cc pht biu sau:
(1) Lu hunh, photpho u bc chy khi tip xc vi CrO3.
(2) Ion Fe3+ c cu hnh electron vit gn l [Ar]3d5.
(3) Bt nhm t bc chy khi tip xc vi kh clo.
(4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O.
Cc pht biu ng l:
A. (1), (2), (3).
B. (1), (3), (4).
C. (2), (3), (4).
D. (1), (2), (4).
Cu 186. (B-14): Cho cc phn ng sau:
t
(a) C H 2 O(hoi)
(b) Si + dung dch NaOH
t
(c) FeO CO
(d) O3 + Ag
t
t
(e) Cu(NO3 )2
(f) KMnO4
S phn ng sinh ra n cht l

A. 4.
B. 3.
C. 5.
D. 6.
Cu 187. (B-12) 32: Cho cc cht sau: FeCO3, Fe3O4, FeS, Fe(OH)2. Nu ho tan cng s mol mi cht
vo dung dch H2SO4 c, nng (d) th cht to ra s mol kh ln nht l
A. Fe3O4.
B. Fe(OH)2.
C. FeS.
D. FeCO3.
0
Cu 188. (B-11) 14: Cho dy cc cht: SiO2, Cr(OH)3, CrO3, Zn(OH)2, NaHCO3, Al2O3. S cht trong
dy tc dng c vi dung dch NaOH (c, nng) l
A. 4.
B. 6.
C. 3.
D. 5.
Cu 189. (C-11) 15: Cho cc cht: KBr, S, SiO2, P, Na3PO4, FeO, Cu v Fe2O3. Trong cc cht trn, s
cht c th b oxi ha bi dung dch axit H2SO4 c, nng l
A. 4.
B. 5.
C. 7.
D. 6.
Thng k H 2007-2014
Cu 190. (B-11) 39: Cho dy cc oxit sau: SO2, NO2, NO, SO3, CrO3, P2O5, CO, N2O5, N2O. S oxit trong
dy tc dng c vi H2O iu kin thng l
A. 7.
B. 5.
C. 6.
D. 8.
Cu 191. (A-12) 22: Cho dy cc oxit: NO2, Cr2O3, SO2, CrO3, CO2, P2O5, Cl2O7, SiO2, CuO. C bao
nhiu oxit trong dy tc dng c vi dung dch NaOH long?
A. 7.
B. 8.
C. 6.
D. 5.
Cu 192. (B-13) 48: Mt mu kh thi c cha CO2, NO2, N2 v SO2 c sc vo dung dch Ca(OH)2
d. Trong bn kh , s kh b hp th l
A. 3.
B. 4.
C. 1.
D. 2.
Cu 193. (A-11) 38: Tin hnh cc th nghim sau:
(1) Cho dung dch NaOH vo dung dch Ca(HCO3)2.
(2) Cho dung dch HCl ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
(3) Sc kh H2S vo dung dch FeCl2.
(4) Sc kh NH3 ti d vo dung dch AlCl3.
(5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
(6) Sc kh etilen vo dung dch KMnO4.
Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta?
A. 6.
B. 3.
C. 5.
D. 4.
(a) Nung NH4NO3 rn.
(b) un nng NaCl tinh th vi dung dch H2SO4
(c).
(c) Sc kh Cl2 vo dung dch NaHCO3.
(d) Sc kh CO2 vo dung dch Ca(OH)2 (d).
(e) Sc kh SO2 vo dung dch KMnO4.
(g) Cho dung dch KHSO4 vo dung dch NaHCO3.
(h) Cho PbS vo dung dch HCl (long).
(i) Cho Na2SO3 vo dung dch H2SO4 (d), un
nng.
S th nghim sinh ra cht kh l
A. 4.
B. 6.
C. 5.
D. 2.
Cu 195. (B-12) 12: Cho cc th nghim sau:
(a) t kh H2S trong O2 d;
(b) Nhit phn KClO3 (xc tc MnO2);
(c) Dn kh F2 vo nc nng;
(d) t P trong O2 d;
(e) Kh NH3 chy trong O2;
(g) Dn kh CO2 vo dung dch Na2SiO3.
S th nghim to ra cht kh l
A. 5.
B. 4.
C. 2.
D. 3.
A. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn.
B. nhit thng, tt c cc kim loi kim th u tc dng c vi nc.
C. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thu tinh.
D. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v.

A. Ch (Pb) c ng dng ch to thit b ngn cn tia phng x.
B. Thic c th dng ph ln b mt ca st chng g.
C. Trong y hc, ZnO c dng lm thuc gim au dy thn kinh, cha bnh eczema, bnh nga.
D. Nhm l kim loi dn in tt hn vng.
(a) Nhit phn AgNO3.
(c) Nhit phn KNO3.
(d).
(e) Cho Fe vo dung dch CuSO4.
(b) Nung FeS2 trong khng kh.

(d) Cho dung dch CuSO4 vo dung dch NH3
(g) Cho Zn vo dung dch FeCl3 (d).
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(h) Nung Ag2S trong khng kh.

(i) Cho Ba vo dung dch CuSO4 (d).
S th nghim thu c kim loi sau khi cc phn ng kt thc l
A. 3.
B. 5.
C. 2.
D. 4.
(1) Cho Zn vo dung dch AgNO3;
(2) Cho Fe vo dung dch Fe2(SO4)3;
(3) Cho Na vo dung dch CuSO4;
(4) Dn kh CO (d) qua bt CuO nng.
Cc th nghim c to thnh kim loi l
A. (1) v (2).
B. (1) v (4).
C. (2) v (3).
D. (3) v (4).
(a) H2S + SO2
(b) Na2S2O3 + dung dch H2SO4 (long)
to
(c) SiO2 + Mg
tilemol 1:2
(d) Al2O3 + dung dch NaOH
(e) Ag + O3
(g) SiO2 + dung dch HF
S phn ng to ra n cht l
A. 3.
B. 6.
C. 5.
Cu 201. (A-12) 29: Thc hin cc th nghim sau ( iu kin thng):
(a) Cho ng kim loi vo dung dch st(III) clorua.
(b) Sc kh hiro sunfua vo dung dch ng(II) sunfat.
(c) Cho dung dch bc nitrat vo dung dch st(III) clorua.
(d) Cho bt lu hunh vo thy ngn.
D. 4.
S th nghim xy ra phn ng l
A. 3.
B. 1.
C. 4.
D. 2.
Cu 202. (C-08) 36: Cho s chuyn ho (mi mi tn l mt p/t p):
dd X
dd Y
dd Z
NaOH
Fe(OH)2
Fe2(SO4)3
BaSO4
Cc dd (dd) X, Y, Z ln lt l:
A. FeCl3, H2SO4(c, nng), Ba(NO3)2.
B. FeCl3, H2SO4 (c, nng), BaCl2
C. FeCl2, H2SO4 (c, nng), BaCl2.
D. FeCl2, H2SO4 (long), Ba(NO3)2.
Cu 203. (B-12) 11: Cho s o chuyn ho: o
FeCl3
T
CO du , t
t
Fe(NO3)3
Z
Fe(NO3)3
Y
X
Cc cht X v T ln lt l
A. FeO v NaNO3.
B. FeO v AgNO3.
C. Fe2O3 v Cu(NO3)2.
D. Fe2O3 v AgNO3.
Cu 204. (B-10) 58: Cho s chuyn ho: Fe3O4 + dd HI (d) X + Y + H2O.
Bit X v Y l sn phm cui cng ca qu trnh chuyn ho. Cc cht X v Y l
A. Fe v I2.
B. FeI3 v FeI2.
C. FeI2 v I2.
D. FeI3 v I2.
Cu 205. (A-12) 56: Nhn xt no sau y khng ng?
A. BaSO4 v BaCrO4 hu nh khng tan trong nc.
B. Al(OH)3 v Cr(OH)3 u l hiroxit lng tnh v c tnh kh.
C. SO3 v CrO3 u l oxit axit.
D. Fe(OH)2 v Cr(OH)2 u l baz v c tnh kh.
Cu 206. (B-12) : Pht biu no sau y l ng?

A. Tt c cc phn ng ca lu hunh vi kim loi u cn un nng.
B. Trong cng nghip, nhm c sn xut t qung olomit.
C. Ca(OH)2 c dng lm mt tnh cng vnh cu ca nc.
D. CrO3 tc dng vi nc to ra hn hp axit.
(a) Cho dung dch HCl vo dung dch Fe(NO3)2.
Thng k H 2007-2014
(b) Cho FeS vo dung dch HCl.

(c) Cho Si vo dung dch NaOH c.
(d) Cho dung dch AgNO3 vo dung dch NaF.
(e) Cho Si vo bnh cha kh F2.
(f) Sc kh SO2 vo dung dch H2S.
Trong cc th nghim trn, s th nghim c xy ra phn ng l
A. 6.
B. 5.
C. 3.
D. 4.
10.2. OXIT TC DNG VI AXIT

Cu 208. (A-07) 56: thu ly Ag tinh khit t hh X (gm a mol Al2O3, b mol CuO, c mol Ag2O), ngi
ta ho tan X bi dd cha (6a + 2b + 2c) mol HNO3 c dd Y, sau thm (gi thit hiu sut cc
p u l 100%)
A. 2c mol bt Cu vo Y. B. c mol bt Al vo Y.
C. c mol bt Cu vo Y.
D. 2c mol bt
Al vo Y.
Cu 209. (B-07) 22: Nung 13,4 gam hh 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht
rn v kh X. Lng kh X sinh ra cho hp th vo 75 ml dd NaOH 1M, khi lng mui khan thu c
sau p l
A. 5,8 gam.
B. 6,5 gam.
C. 4,2 gam.
D. 6,3 gam
Cu 210. (A-07) 49: Ho tan hon ton 2,81 gam hh gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4
0,1M (va ). Sau p, hh mui sunfat khan thu c khi c cn dd c khi lng l
A. 3,81 gam.
B. 4,81 gam.
C. 5,81 gam.
D. 6,81 gam.
Cu 211. (B-10) 2: Nung 2,23g hh X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu
c 2,71g hh Y. Ho tan hon ton Y vo dd HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy
nht, ktc). S mol HNO3 p l
A. 0,12.
B. 0,14.
C. 0,16.
D. 0,18.
Cu 212. (C-09) 51: Nung nng 16,8 gam hn hp gm Au, Ag, Cu, Fe, Zn vi mt lng d kh O2, n
khi cc phn ng xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M va
phn ng vi cht rn X l
A. 400 ml.
B. 200 ml.
C. 800 ml.
D. 600 ml.
Cu 213. (B-12) 18: t chy hn hp gm 1,92 gam Mg v 4,48 gam Fe vi hn hp kh X gm clo v
oxi, sau phn ng ch thu c hn hp Y gm cc oxit v mui clorua (khng cn kh d). Ha tan Y
bng mt lng va 120 ml dung dch HCl 2M, thu c dung dch Z. Cho AgNO3 d vo dung dch
Z, thu c 56,69 gam kt ta. Phn trm th tch ca clo trong hn hp X l
A. 51,72%.
B. 76,70%.
C. 53,85%.
D. 56,36%.
Cu 214. (A-13) 46: Cho 25,5 gam hn hp X gm CuO v Al2O3 tan hon ton trong dung dch
H2SO4 long, thu c dung dch cha 57,9 gam mui. Phn trm khi lng ca Al2O3 trong X l
A. 80%.
B. 60%.
C. 20%.
D. 40%.
10.3. Bi ton 3 Cu + 8H+ +2NO3- 3Cu2+ +2NO + 4H2O

Cu 215. (A-09) 25: Cho 6,72 gam Fe vo 400 ml dd HNO3 1M, n khi p xy ra hon ton, thu
c kh NO (sn phm kh duy nht) v dd X. Dd X c th ho tan ti a m gam Cu. Gi tr ca m l
A. 1,92.
B. 3,20.
C. 0,64.
D. 3,84.
Cu 216. (A-13) 5: Cho m gam Fe vo bnh cha dung dch gm H2SO4 v HNO3, thu c dung dch X
v 1,12 lt kh NO. Thm tip dung dch H2SO4 d vo bnh thu c 0,448 lt kh NO v dung
dch Y. Bit trong c hai trng hp NO l sn phm kh duy nht, o iu kin tiu chun. Dung
dch Y ha tan va ht 2,08 gam Cu (khng to thnh sn phm kh ca N+5). Bit cc phn ng u
xy ra hon ton. Gi tr ca m l
A. 4,06.
B. 2,40.
C. 4,20.
D. 3,92.
Cu 217. (B-07) 40: Thc hin hai th nghim:
1) Cho 3,84 gam Cu p vi 80 ml dd HNO3 1M thot ra V1 lt NO.
Thng k H 2007-2014
2) Cho 3,84 gam Cu p vi 80 ml dd cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO.

Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l
A. V2 = V1.
B. V2 = 2V1.
C. V2 = 2,5V1.
D. V2 = 1,5V1.
Cu 218. (A-08) 41: Cho 3,2 gam bt Cu t/d vi 100 ml dd hh gm HNO3 0,8M v H2SO4 0,2M. Sau
khi cc p xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 0,746.
B. 0,448.
C. 1,792.
D. 0,672
Cu 219. (B-10) 51: Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dd cha 0,9 mol H2SO4 (long). Sau khi
cc p xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 6,72.
B. 8,96.
C. 4,48.
D. 10,08.
Cu 220. (A-11) 32: Cho 7,68 gam Cu vo 200 ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi
cc phn ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dung dch
sau phn ng th khi lng mui khan thu c l
A. 19,76 gam.
B. 22,56 gam.
C. 20,16 gam.
D. 19,20 gam.
Cu 221. (A-09) 35: Cho hh gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dd cha hh gm H2SO4
0,5M v NaNO3 0,2M. Sau khi cc p xy ra hon ton, thu c dd X v kh NO (sn phm kh duy
nht). Cho V ml dd NaOH 1M vo dd X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l
A. 360.
B. 240.
C. 400.
D. 120.
Cu 222. (A-11) 35: Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4
0,1M. Sau khi cc phn ng xy ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc)
thot ra. Thm tip vo bnh 0,425 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc,
sn phm kh duy nht) to thnh v khi lng mui trong dung dch l
A. 0,224 lt v 3,750 gam.
B. 0,112 lt v 3,750 gam.
C. 0,224 lt v 3,865 gam.
D. 0,112 lt v 3,865 gam.
Cu 223. (B-11) 22: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30
ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol
kh NO (sn phm kh duy nht ca N+5 ). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh
Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l
A. 2.
B. 4.
C. 3.
D. 1.
Cu 224. (A-14): C ba dung dch ring bit : H2SO4 1M; KNO3 1M; HNO3 1M c nh s ngu nhin
l (1), (2), (3).
Trn 5 ml dung dch (1) vi 5 ml dung dch (2), thm bt Cu d, thu c V1 lt kh NO.
Trn 5 ml dung dch (1) vi 5 ml dung dch (3), thm bt Cu d, thu c 2V1 lt kh NO.
Trn 5 ml dung dch (2) vi 5 ml dung dch (3), thm bt Cu d, thu c V2 lt kh NO.
Bit cc phn ng xy ra hon ton, NO l sn phm kh duy nht, cc th tch kh o cng
iu kin. So snh no sau y ng?
A. V2 2V1
B. 2V2 V1
C. V2 3V1
D. V2 V1
Cu 225. (B-14): Ha tan ht 10,24 gam hn hp X gm Fe v Fe3O4 bng dung dch cha 0,1 mol
H2SO4 v 0,5 mol HNO3, thu c dung dch Y v hn hp gm 0,1 mol NO v a mol NO2 (khng cn
sn phm kh no khc). Chia dung dch Y thnh hai phn bng nhau:
- Phn mt tc dng vi 500 ml dung dch KOH 0,4M, thu c 5,35 gam mt cht kt ta
- Phn hai tc dng vi dung dch Ba(OH)2 d, thu c m gam kt ta.
Bit cc phn ng xy ra hon ton. Gi tr ca m l
A. 20,62
B. 41,24
C. 20,21
D. 31,86
Cu 226. (B-13) 23: Ha tan hon ton hn hp gm 2,8 gam Fe v 1,6 gam Cu trong 500 ml dung dch
hn hp HNO3 0,1M v HCl 0,4M, thu c kh NO (kh duy nht) v dung dch X. Cho X vo dung
dch AgNO3 d, thu c m gam cht rn. Bit cc phn ng u xy ra hon ton, NO l sn phm
kh duy nht ca N+5 trong cc phn ng. Gi tr ca m l
A. 29,24.
B. 30,05.
C. 34,10.
D. 28,70.
10.4. Fe2+ tc dng vi Ag+

Cu 227. (B-09) 50: Ho tan hon ton 24,4 gam hh gm FeCl2 v NaCl (c t l s mol tng ng l
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1:2) vo mt lng nc (d), thu c dd X. Cho dd AgNO3 (d) vo dd X, sau khi p xy ra hon
ton sinh ra m gam cht rn. Gi tr ca m l
A. 57,4.
B. 28,7.
C. 10,8.
D. 68,2.
Cu 228. (C-13) 36: Hn hp X gm FeCl2 v NaCl c t l mol tng ng l 1 : 2. Ha tan hon ton
2,44 gam X vo nc, thu c dung dch Y. Cho Y phn ng hon ton vi dung dch AgNO3 d, thu
c m gam cht rn. Gi tr ca m l
A. 5,74.
B. 2,87.
C. 6,82.
D. 10,80.
Cu 229. (C-09) 59: Cho 100 ml dd FeCl2 1,2M tc dng vi 200 ml dd AgNO3 2M, thu c m gam kt
ta. Gi tr ca m l
A. 34,44.
B. 47,4.
C. 30,18.
D. 12,96
Cu 230. (A-12) 44: Cho 100 ml dung dch AgNO3 2a mol/l vo 100 ml dung dch Fe(NO3)2 a mol/l.
Sau khi phn ng kt thc thu c 8,64 gam cht rn v dung dch X. Cho dung dch HCl d vo X thu
A. 22,96.
B. 11,48.
C. 17,22.
D. 14,35.
10.5. Fe tc dng vi axit HNO3 v H2SO4 c nng m cn d kim loi

Cu 231. (C-10) 30: Cho a gam Fe vo 100 ml dd hh gm HNO3 0,8M v Cu(NO3 )2 1M. Sau khi cc p
xy ra hon ton, thu c 0,92a gam hh kim loi v kh NO (sn phm kh duy nht ca N +5). Gi tr
ca a l
A. 5,6.
B. 11,2.
C. 8,4.
D. 11,0.
Cu 232. (B-09) 30: Cho m gam bt Fe vo 800 ml dd hh gm Cu(NO3) 2 0,2M v H2SO4 0,25M. Sau khi cc
p xy ra hon ton, thu c 0,6m gam hh bt kim loi v V lt kh NO (sn phm kh duy nht, ktc).
Gi tr ca m v V ln lt l
A. 10,8 v 4,48.
B. 10,8 v 2,24.
C. 17,8 v 2,24.
D. 17,8 v 4,48.
Cu 233. (B-07) 38: Cho hh Fe, Cu p vi dd HNO3 long. Sau khi p hon ton, thu c dd ch cha
mt cht tan v kim loi d. Cht tan l
A. Cu(NO3)2.
B. HNO3.
C. Fe(NO3)2.
D. Fe(NO3)3.
Cu 234. (A-11) 5: un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt
lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v 5,6
lt hn hp kh (ktc) gm NO v NO2 (khng c sn phm kh khc ca N+5 ). Bit lng HNO3
phn ng l
44,1 gam. Gi tr ca m l
A. 50,4.
B. 40,5.
C. 44,8.
D. 33,6.
10.6. Bi ton lin quan n KMnO4

Cu 235. (A-07) 29: Ho tan 5,6 gam Fe bng dd H2SO4 long (d), thu c dd X. Dd X p va vi
V ml dd KMnO4 0,5M. Gi tr ca V l
A. 40.
B. 80.
C. 60.
D. 20.
Cu 236. (A-11) 60: Ho tan hh bt gm m gam Cu v 4,64 gam Fe3O4 vo dd H2SO4 (long, rt
d), sau khi cc phn ng kt thc ch thu c dd X. Dung dch X lm mt mu va 100 ml dd
KMnO4 0,1M. Gi tr ca m l
A. 0,96.
B. 1,24.
C. 3,2.
D. 0,64.
Thng k H 2007-2014
10.7. Cc dng khc

Cu 237. (CD-07) 1: Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dd H2SO4 20% thu
c dd mui trung ho c nng 27,21%. Kim loi M l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56;
Cu = 64; Zn = 65)
A. Cu.
B. Zn.
C. Fe.
D. Mg.
Cu 238. (A-08) 24: Ho tan hon ton 0,3 mol hh gm Al v Al4C3 vo dd KOH (d), thu c a
mol hh kh v dd X. Sc kh CO2 (d) vo dd X, lng kt ta thu c l 46,8 gam. Gi tr ca a l
A. 0,55.
B. 0,60.
C. 0,40.
D. 0,45.
Cu 239. (B-09) 25: Cho 61,2 gam hh X gm Cu v Fe3O4 t/d vi dd HNO3 long, un nng v khuy
u. Sau khi cc p xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dd
Y v cn li 2,4 gam kim loi. C cn dd Y, thu c m gam mui khan. Gi tr ca m l
A. 151,5.
B. 137,1.
C. 97,5.
D. 108,9.
Cu 240. (B-10) 49: Hh bt X gm Cu, Zn. t chy hon ton m gam X trong oxi (d), thu c 40,3
gam hh gm CuO v ZnO. Mt khc, nu cho 0,25 mol X p vi mt lng d dd KOH long nng, th
thu c 3,36 lt kh H2 (ktc). Phn trm khi lng ca Cu trong X l
A. 19,81%.
B. 29,72%.
C. 39,63%.
D. 59,44%.
Cu 241. (B-11) 42: Nhit phn mt lng AgNO3 c cht rn X v hn hp kh Y. Dn ton b Y
vo mt lng d H2O, thu c dung dch Z. Cho ton b X vo Z, X ch tan mt phn v thot ra
kh NO (sn phm kh duy nht). Bit cc phn ng xy ra hon ton. Phn trm khi lng ca X
phn ng l
A. 70%.
B. 25%.
C. 60%.
D. 75%.
Cu 242. (A-14): t chy 4,16 gam hn hp gm Mg v Fe trong kh O2, thu c 5,92 gam hn hp X
ch gm cc oxit. Ha tan hon ton X trong dung dch HCl va , thu c dung dch Y. Cho dung
dch NaOH d vo Y, thu c kt ta Z. Nung Z trong khng kh n khi lng khng i, thu c
6 gam cht rn. Mt khc cho Y tc dng vi dung dch AgNO3 d, thu c m gam kt ta. Gi tr ca
m l
A. 10,80
B. 32,11
C. 32,65
D. 31,57
Cu 243. (B-12) 35: t 16,2 gam hn hp X gm Al v Fe trong kh Cl2 thu c hn hp cht rn Y.
Cho Y vo nc d, thu c dung dch Z v 2,4 gam kim loi. Dung dch Z tc dng c vi ti a
0,21 mol KMnO4 trong dung dch H2SO4 (khng to ra SO2). Phn trm khi lng ca Fe trong hn
hp X l
A. 72,91%.
B. 64,00%.
C. 66,67%.
D. 37,33%.
Cu 244. (B-12) 36: Ho tan hon ton 0,1 mol FeS2 trong 200 ml dung dch HNO3 4M, sn phm thu
c gm dung dch X v mt cht kh thot ra. Dung dch X c th ha tan ti a m gam Cu. Bit
trong cc qu trnh trn, sn phm kh duy nht ca N+5 u l NO. Gi tr ca m l
A. 12,8.
B. 6,4.
C. 9,6.
D. 3,2
Cu 245. (B-13) 50: Ha tan hon ton 24 gam hn hp X gm MO, M(OH)2 v MCO3 (M l kim loi c
ha tr khng i) trong 100 gam dung dch H2SO4 39,2%, thu c 1,12 lt kh (ktc) v dung dch
Y ch cha mt cht tan duy nht c nng 39,41%. Kim loi M l
A. Zn.
B. Ca.
C. Mg.
D. Cu.
Thng k H 2007-2014
Phn 2: Hu c
11. I CNG HU C V HIDROCACBON
11.1. ng phn, danh php
Cu 3. (A-10) 14: Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to
nht l
A. C3H9N.
B. C3H7Cl.
C. C3H8O.
D. C3H8.
Cu 4. (A-10) 18: Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l
A. 1.
B. 2.
C. 4.
D. 3.
Cu 5. (A-08) 33: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l
A. 2.
B. 4.
C. 3.
D. 5.
Cu 6. (B-11) 41: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l
A. 8.
B. 7.
C. 9.
D. 5.
Cu 7. (A-09) 13: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 :
4. Hp cht X c cng thc n gin nht trng vi CTPT. S ng phn cu to thuc loi hp cht thm
ng vi CTPT ca X l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 8. (B-13) 37: Cht no sau y trong phn t ch c lin kt n?
A. Metyl fomat.
B. Axit axetic.
C. Anehit axetic.
D. Ancol etylic.
Cu 9. (C-10) 39: S lin kt (xich ma) c trong mi phn t: etilen; axetilen; buta-1,3-ien ln
lt l:
A. 5; 3; 9.
B. 4; 3; 6.
C. 3; 5; 9.
D. 4; 2; 6.
Cu 10. (C-09) 31: Cho cc cht: xiclobutan, 2- metylpropen, but-1 -en, cis-but-2-en, 2-metylbut-2en. Dy gm cc cht sau khi p vi H2 (d, xc tc Ni, to), cho cng mt sn phm l:
A. xiclobutan, cis-but-2-en v but-1-en.
B. but-1-en, 2-metylpropen v cis-but-2-en.
C. xiclobutan, 2-metylbut-2-en v but-1-en.
D. 2-metylpropen, cis-but-2-en v xiclobutan.
Cu 11. (A-08) 48: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l
A. 2.
B. 3.
C. 1.
D. 4.
Cu 12. (C-09) : Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2;
CH3CH=CH2; CH3CH=CHCOOH. S cht c ng phn hnh hc l
A. 4.
B. 3
C. 2.
D. 1.
Cu 13. (C-10) : Cht no sau y c ng phn hnh hc?
A. 2-clopropen.
B. But-2-en.
C. 1,2-icloetan.
D. But-2-in.
Cu 14. (C-11) 34: Cht no sau y c ng phn hnh hc?
A. CH2=CH-CH=CH2.
B. CH3-CH=C(CH3)2.
C. CH3-CH=CH-CH=CH2.
D. CH2=CH-CH2-CH3.
(a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O
th X l anken.
(b) Trong thnh phn hp cht hu c nht thit phi c cacbon.
(c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr.
(d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau.
(e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh.
(g) Hp cht C9H14BrCl c vng benzen trong phn t.
S pht biu ng l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 16. (B-07) 8: Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s
o
mol O2 gp i s mol cn cho p chy) 139,9 C, p sut trong bnh l 0,8 atm. t chy hon
ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t
l
A. C2H4 O2.
B. CH2O2.
C. C4H8O2.
D. C3H6O2
Cu 17. (A-12) 12: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri
Thng k H 2007-2014
em ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c
39,4 gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l
A. CH4.
B. C3H4.
C. C4H10.
D. C2H4.
Cu 18. (B-12) 21: t chy hon ton 20 ml hi hp cht hu c X (ch gm C, H, O) cn va 110 ml
kh O2, thu c 160 ml hn hp Y gm kh v hi. Dn Y qua dung dch H2SO4 c (d), cn li 80 ml
kh Z. Bit cc th tch kh v hi o cng iu kin. Cng thc phn t ca X l
A. C4H8O2.
B. C4H10O.
C. C3H8O.
D. C4H8O.
11.2. ANKAN
Cu 19. (A-13) 8: Tn thay th (theo IUPAC) ca (CH3)3CCH2CH(CH3)2 l
A. 2,2,4,4-tetrametylbutan.
B. 2,4,4-trimetylpentan.
C. 2,2,4-trimetylpentan.
D. 2,4,4,4-tetrametylbutan.
Cu 20. (C-08) 7: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc
dy ng ng ca
A. ankan.
B. ankin.
C. ankaien.
D. anken.
Cu 21. (C-07) 2: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi
khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam
nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn
l (Cho H = 1; C = 12; O = 16)
A. 70,0 lt.
B. 78,4 lt.
C. 84,0 lt.
D. 56,0 lt.
Cu 22. (A-10) 50: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo
dd Ba(OH)2 (d) to ra 29,55 gam kt ta, dd sau p c khi lng gim 19,35 gam so vi dd Ba(OH)2
ban u. Cng thc phn t ca X l
A. C3H8.
B. C2H6.
C. C3H4.
D. C3H6.
Cu 23. (A-08) 46: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hh Y (cc th
tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t
ca X l
A. C6H14.
B. C3H8.
C. C4H10.
D. C5H12.
Cu 24. (B-11) 50: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8,
C4H6 v H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol
brom ti a phn ng l
A. 0,24 mol.
B. 0,36 mol.
C. 0,60 mol.
D. 0,48 mol.
Cu 25. (C-12) 39: Nung mt lng butan trong bnh kn (c xc tc thch hp) thu c hn hp
kh X gm ankan v anken. T khi ca X so vi kh hiro l 21,75. Phn trm th tch ca butan trong X
l
A. 66,67%.
B. 25,00%.
C. 50,00%.
D. 33,33%.
Cu 26. (A-08) 49: Cho iso-pentan t/d vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu
c l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 27. (A-13) 1: Khi c chiu sng, hirocacbon no sau y tham gia phn ng th vi clo theo
t l mol 1 : 1, thu c ba dn xut monoclo l ng phn cu to ca nhau?
A. isopentan.
B. neopentan.
C. butan.
D. pentan.
Cu 28. (B-07) 50: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t
khi hi i vi hiro l 75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80)
A. 3,3-imetylhecxan.
B. 2,2-imetylpropan.
C. isopentan.
D.
2,2,3trimetylpentan.
Cu 29. (A-09) 6: Hirocacbon X khng lm mt mu dd brom nhit thng. Tn gi ca X l
A. xiclohexan.
B. xiclopropan.
C. stiren.
D. etilen.
Cu 30. (B-08) 38: Hirocacbon mch h X trong phn t ch cha lin kt (xich ma) v c hai
nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 (
cng iu kin nhit , p sut). Khi cho X t/d vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti
a sinh ra l
A. 3.
B. 4.
C. 2.
D. 5.
Cu 31. (C-14): Hirocacbon X tc dng vi brom, thu c dn xut monobrom duy nht c t khi
hi so
vi H2 bng 75,5. Cht X l
A. 2,2-imetylpropan
B. pentan
C. 2-metylbutan
D. but-1-en
Thng k H 2007-2014
Cu 32. (C-08) 46: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O.
Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X
l
A. 2-Metylbutan.
B. etan.
C. 2,2-imetylpropan. D. 2-Metylpropan.
Cu 33. (C-07) 39: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%)
t/d vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng
phn ca nhau. Tn ca X l
A. 2-metylpropan.
B. 2,3-imetylbutan.
C. butan.
D. 3-metylpentan.
Cu 34. (C-12) : t chy hon ton hn hp X gm hai hirocacbon k tip nhau trong dy ng
ng, thu
c 2,24 lt kh CO2 (ktc) v 3,24 gam H2O. Hai hirocacbon trong X l
A. C2H6 v C3H8.
B. CH4 v C2H6.
C. C2H2 v C3H4.
D. C2H4 v C3H6.
11.3. ANKEN
Cu 35.
(A-14): Cht X c cng thc : CH3 CH CH3 CH CH 2 . Tn thay th ca X l
A. 2-metylbut-3-in
B. 2-metylbut-3-en
C. 3-metylbut-1-in
D.3-metylbut-1en
Cu 36. (B-14): Trong phn t propen c s lin kt xich ma () l
A. 7.
B. 6.
C. 8.
D. 9.
Cu 37. (A-07) Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn
t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dd
Ca(OH)2 d, thu c s gam kt ta l
A. 10.
B. 20.
C. 30.
D. 40.
Cu 38. (B-08) 49: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln
khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng
A. ankan.
B. ankaien.
C. anken.
D. Ankin.
Cu 39. (A-07) 3: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh
phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5)
A. C4H8.
B. C3H4.
C. C2H4.
D. C3H6.
Cu 40. (B-09) 43: Cho hirocacbon X p vi brom (trong dd) theo t l mol 1 : 1, thu c cht hu
c Y (cha 74,08% Br v khi lng). Khi X p vi HBr th thu c hai sn phm hu c khc
nhau. Tn gi ca X l
A. but-1-en.
B. xiclopropan.
C. but-2-en.
D. propilen.
Cu 41. (C-13) 55: Cht no di y khi phn ng vi HCl thu c sn phm chnh l 2-clobutan?
A. But-1-en.
B. Buta-1,3-ien.
C. But-2-in.
D. But-1-in.
Cu 42. (A-07) 9: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l
A. eten v but-2-en (hoc buten-2).
B. eten v but-1-en (hoc buten-1).
C. propen v but-2-en (hoc buten-2).
D. 2-metylpropen v but-1-en (hoc buten-1).
Cu 43. (A-10) 33: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l
A. 3-etylpent-3-en.
B. 2-etylpent-2-en.
C. 3-etylpent-2-en.
D. 3-etylpent-1-en.
Cu 44. (B-12) 56: Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn
phm chnh l
A. 2-metylbutan-2-ol.
B. 3-metylbutan-2-ol.
C. 3-metylbutan-1-ol.
D. 2-metylbutan-3ol.
Cu 45. (B-13) 46: Hirocacbon no sau y khi phn ng vi dung dch brom thu c 1,2ibrombutan?
A. But-1-en.
B. Butan.
C. Buta-1,3-ien.
D. But-1-in.
Cu 46. (C-09) 17: kh hon ton 200 ml dd KMnO4 0,2M to thnh cht rn mu nu en cn V
lt kh C2H4 ( ktc). Gi tr ti thiu ca V l
A. 2,240.
B. 2,688.
C. 4,480.
D. 1,344.
Cu 47. (B-09) 19: Hh kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy
nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi p xy ra hon ton, thu
c hh kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. CTCT ca anken l
C. CH2=CH-CH2-CH3. D.CH3-CH=CH-CH3.
A. CH2=C(CH3)2.
B. CH2=CH2.
Cu 48. (C-11) 56: Cht X tc dng vi benzen (xt, t) to thnh etylbenzen. Cht X l
A. C2H4.
B. C2H2.
C. CH4.
D. C2H6.
Cu 49. (C-09) 12: Hh kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu
Thng k H 2007-2014
c hh kh Y c t khi so vi He l 5. Hiu sut ca p hiro ho l

A. 20%.
B. 25%.
C. 50%.
D. 40%.
Cu 50. (A-12) 49: Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng,
thu c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ho l
A. 70%.
B. 80%.
C. 60%.
D. 50%.
Cu 51. (A-13) 48: Hn hp X gm H2, C2H4 v C3H6 c t khi so vi H2 l 9,25. Cho 22,4 lt X (ktc)
vo bnh kn c sn mt t bt Ni. un nng bnh mt thi gian, thu c hn hp kh Y c t khi so
vi H2 bng 10. Tng s mol H2 phn ng l
A. 0,075 mol.
B. 0,070 mol.
C. 0,050 mol.
D. 0,015 mol.
Cu 52. (A-12) 4: t chy hon ton 3 lt hn hp X gm 2 anken k tip nhau trong dy ng
ng cn va 10,5 lt O2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha
hon ton X trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai
bng 6/13 ln tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s
nguyn t cacbon ln hn) trong Y l
A. 46,43%.
B. 10,88%.
C. 31,58%.
D. 7,89%.
11.4. ANKIN, ANKAIEN, TECPEN
Cu 53. (C-10) 49: Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3, to), thu c
hn hp Y ch c hai hirocacbon. Cng thc phn t ca X l
A. C2H2.
B. C4H6.
C. C5H8.
D. C3H4.
Cu 54. (A-11) 13: Cho 13,8 gam cht hu c X c cng thc phn t C7H8 tc dng vi mt
lng d dung dch AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to
tha mn tnh cht trn?
A. 2.
B. 5.
C. 4.
D. 6.
Cu 55. (A-12) 1: Hirat ha 5,2 gam axetilen vi xc tc HgSO4 trong mi trng axit, un nng.
Cho ton b cc cht hu c sau phn ng vo mt lng d dung dch AgNO3 trong NH3 thu c
44,16 gam kt ta. Hiu sut phn ng hirat ha axetilen l
A. 60%.
B. 80%.
C. 92%.
D. 70%.
Cu 56. (A-11) 43: Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom
(ng phn cu to v ng phn hnh hc) thu c l
A. 2.
B. 3.
C. 4.
D. 1.
Cu 57. (A-12) 35: Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc
cu to c th c ca X l
A. 6.
B. 7.
C. 4.
D. 5.
Cu 58. (C -14): Cht no sau y lm mt mu dung dch KMnO4 iu kin thng?
A. Benzen
B. Axetilen
C. Metan
D. Toluen
Cu 59. (B-11) 47: Trong qu gc chn rt giu hm lng

A. vitamin A.
B. ete ca vitamin A.
C. -caroten.
D. este ca
vitamin A.
Cu 60. (C -14): S hirocacbon l ng phn cu to ca nhau, cha vng benzen, c cng cng
thc phn t C8H10 l
A. 4
B. 2
C. 5
D. 3
Cu 61. (C-13) 33: S ng phn cu to, mch h ng vi cng thc phn t C4H6 l
A. 2.
B. 5.
C. 4.
D. 3.
11.5. HN HP HIROCACBON
Cu 62. (C-10) 16: t chy hon ton 6,72 lt (ktc) hh gm hai hirocacbon X v Y (M Y > MX), thu
c 11,2 lt kh CO2 (ktc) v 10,8 gam H2O. Cng thc ca X l
A. C2H4.
B. CH4.
C. C2H6.
D. C2H2.
Cu 63. (B-10) 13: Hh kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t
chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v
Thng k H 2007-2014
anken ln lt l
A. CH4 v C2H4.
B. C2H6 v C2H4.
C. CH4 v C3H6.
D. CH4 v C4H8.
Cu 64. (C-08) 42: t chy hon ton hh M gm mt ankan X v mt ankin Y, thu c s mol CO2
bng s mol H2O. Thnh phn phn tr m v s mol ca X v Y trong hh M ln lt l
A. 75% v 25%.
B. 20% v 80%.
C. 35% v 65%.
D.
50% v 50%.
Cu 65. (B-14): t chy hon ton 0,2 mol hn hp X gm mt ankan v mt anken, thu c 0,35
mol CO2 v 0,4 mol H2O. Phn trm s mol ca anken trong X l
A. 40%.
B. 50%.
C. 25%.
D. 75%.
Cu 66. (B-08) 48: t chy hon ton 1 lt hh kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2
v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X
l
A. C2H6.
B. C2H4.
C. CH4.
D. C3H8.
Cu 67. (B-08) 21: Dn 1,68 lt hh kh X gm hai hirocacbon vo bnh ng dd brom (d). Sau khi
p xy ra hon ton, c 4 gam brom p v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th
sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc)
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6.
Cu 68. (A-07) 8: Cho 4,48 lt hh X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha
1,4 lt dd Br2 0,5M. Sau khi p hon ton, s mol Br2 gim i mt na v khi lng bnh tng
thm 6,7 gam. CTPT ca 2 hirocacbon l
A. C2H2 v C4H8.
B. C2H2 v C3H8.
C. C3H4 v C4H8.
D. C2H2 v C4H6.
Cu 69. (A-07) 47: Hh gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton
hh trn thu c hh kh Y. Cho Y qua dd H2SO4 c, thu c hh kh Z c t khi i vi hiro bng 19.
Cng thc phn t ca X l
A. C4H8.
B. C3H4.
C. C3H6.
D. C3H8.
Cu 70. (A-08) 34: Hh X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy
hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l
A. 20,40 gam.
B. 18,60 gam.
C. 18,96 gam.
D. 16,80 gam.
Cu 71. (B-11) 35: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2

l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch
Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l
A. 7,3.
B. 6,6.
C. 3,39.
D. 5,85.
Cu 72. (C-13) 10: Hn hp kh X gm C2H6, C3H6 v C4H6. T khi ca X so vi H2 bng 24. t
chy hon ton 0,96 gam X trong oxi d ri cho ton b sn phm chy vo 1 lt dung dch Ba(OH)2
0,05M. Sau khi cc phn ng xy ra hon ton, thu c m gam kt ta. Gi tr ca m l
A. 9,85.
B. 5,91.
C. 13,79.
D. 7,88.
Cu 73. (B-13) 28: Cho 3,36 lt kh hirocacbon X (ktc) phn ng hon ton vi lng d dung
dch AgNO3 trong NH3, thu c 36 gam kt ta. Cng thc phn t ca X l
A. C4H4.
B. C3H4.
C. C4H6.
D. C2H2.
Cu 74. (A-11) 23: t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht
bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt
lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc
cu to ca C3H4 v C4H4 trong X ln lt l:
A. CHC-CH3, CH2=C=C=CH2.
B. CH2=C=CH2, CH2=CH-CCH.
C. CHC-CH3, CH2=CH-CCH.
D. CH2=C=CH2, CH2=C=C=CH2.
Cu 75. (A-09) 30: Hh kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t.
Hh X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln
lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.
B. 0,2 mol C2H4 v 0,1 mol C2H2.
C. 0,1 mol C3H6 v 0,2 mol C3H4.
D. 0,2 mol C3H6 v 0,1 mol C3H4.
Cu 76. (B-09) 35: Cho hh X gm CH4, C2H4 v C2H2. Ly 8,6 gam X t/d ht vi dd brom (d) th
khi lng brom p l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hh kh X t/d vi lng d dd
AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l
A. 20%.
B. 50%.
C. 25%.
D. 40%.
Cu 77. (C-08) 28: t chy hon ton 20,0 ml hh X gm C3H6, CH4, CO (th tch CO gp hai ln th
tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X
Thng k H 2007-2014
so vi kh hiro l
A. 12,9.
B. 25,8.
C. 22,2.
D. 11,1.
Cu 78. (B-12) 46: t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng
thc n gin nht khc nhau, thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht trong X l
A. mt ankan v mt ankin.
B. hai ankaien.
C. hai anken.
D. mt anken v mt ankin.
11.6. Hn hp hidrocacbon vi H2
Cu 79. (C-09) 25: Hh kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni
thu c hh kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dd brom (d) th c m
gam brom tham gia p. Gi tr ca m l
A. 16,0.
B. 3,2.
C. 8,0.
D. 32,0.
Cu 80. (A-14): Hn hp kh X gm etilen v propin. Cho a mol X tc dng vi lng d dung dch
AgNO3 trong NH3, thu c 17,64 gam kt ta. Mt khc a mol X phn ng ti a vi 0,34 mol H2. Gi
tr ca a l:
A. 0,32
B. 0,22
C. 0,34
D. 0,46
Cu 81. (C-07) 25: Dn V lt ( ktc) hh X gm axetilen v hiro i qua ng s ng bt niken nung
nng, thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong dd NH3 thu c 12 gam kt ta.
Kh i ra khi dd p va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24
lt kh CO2 ( ktc) v 4,5g nc. Gi tr ca V bng
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96.
Cu 82. (A-08) 25: un nng hh kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi
gian thu c hh kh Y. Dn ton b hh Y li t t qua bnh ng dd brom (d) th cn li 0,448 lt hh
kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dd brom tng l
A. 1,04 gam.
B. 1,32 gam.
C. 1,64 gam.
D. 1,20 gam.
Cu 83. (A-10) 9: un nng hh kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc
Ni), thu c hh kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc p, khi lng
bnh tng m gam v c 280 ml hh kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l
A. 0,585.
B. 0,620.
C. 0,205.
D. 0,328.
Cu 84. (A-11) 6: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua
cht xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch
brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi
so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l
A. 22,4 lt.
B. 26,88 lt.
C. 44,8 lt.
D. 33,6 lt.
Cu 85. (B-12) 24: Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xc
tc Ni) mt thi gian, thu c hn hp Y c t khi so vi H2 bng 10. Dn hn hp Y qua dung dch
brom d, sau khi phn ng xy ra hon ton, khi lng brom tham gia phn ng l
A. 0 gam.
B. 24 gam.
C. 8 gam.
D. 16 gam.
Cu 86. (A-13) 15: Trong mt bnh kn cha 0,35 mol C2H2; 0,65 mol H2 v mt t bt Ni. Nung nng
bnh mt thi gian, thu c hn hp kh X c t khi so vi H2 bng 8. Sc X vo lng d dung dch
AgNO3 trong NH3 n phn ng hon ton, thu c hn hp kh Y v 24 gam kt ta. Hn hp kh
Y phn ng va vi bao nhiu mol Br2 trong dung dch?
A. 0,20 mol.
B. 0,25 mol.
C. 0,10 mol.
D. 0,15 mol.
Cu 87. (A-14): Hn hp kh X gm 0,1 mol C2H2; 0,2 mol C2H4 v 0,3 mol H2. un nng X vi xc
tc Ni, sau mt thi gian thu c hn hp kh Y c t khi so vi H2 bng 11. Hn hp Y phn ng ti
a vi a mol Br2 trong dung dch. Gi tr ca a l
A. 0,3
B. 0,2
C. 0,4
D. 0,1
Cu 88. (B-14): Mt bnh kn ch cha cc cht sau: axetilen (0,5 mol), vinylaxetilen (0,4 mol), hiro
(0,65 mol) v mt t bt niken. Nung nng bnh mt thi gian, thu c hn hp kh X c t khi so vi
H2 bng 19,5. Kh X phn ng va vi 0,7 mol AgNO3 trong dung dch NH3, thu c m gam kt
ta v 10,08 lt hn hp kh Y (ktc). Kh Y phn ng ti a vi 0,55 mol Br 2 trong dung dch. Gi tr
ca m l
A. 76,1.
B. 92,0.
C. 75,9.
D. 91,8.
Cu 89. (C-13) 50: Cho 27,2 gam ankin X tc dng vi 15,68 lt kh H2 (ktc) c xc tc thch
hp, thu c hn hp Y (khng cha H2). Bit Y phn ng ti a vi dung dch cha 16 gam Br2.
A. C4H6.
B. C3H4.
C. C2H2.
D. C5H8.
Thng k H 2007-2014
12. DN XUT HALOGEN, ANCOL, PHENOL

12.1. Dn xut halogen
Cu 1. (A-13) 51: Trng hp no sau y khng xy ra phn ng?
t
(a) CH2=CH-CH2Cl + H2O
(b) CH3CH2CH2Cl + H2O

o
t cao , p cao
(c) C6H5Cl + NaOH (c)
; Vi C6H5- l gc phenyl)
(d) C2H5Cl + NaOH
A. (a).
B. (b).
to
C. (c).
D. (d).
Cu 2. (B-13) 55: un si dung dch gm cht X v KOH c trong C2H5OH, thu c etilen. Cng
thc ca X l
A. CH3COOH.
B. CH3CHCl2.
C. CH3CH2Cl.
D.
CH3COOCH=CH2.
Cu 3. (B-10) 41: Pht biu no sau y ng?
A. Khi un C2H5Br vi dd KOH ch thu c etilen.
B. Dd phenol lm phenolphtalein khng mu chuyn thnh mu hng.
C. Dy cc cht: C2H5Cl, C2H5Br, C2H5I c nhit si tng dn t tri sang phi.
D. un ancol etylic 140oC (xc tc H2SO4 c) thu c imetyl ete.
Cl2 (1:1)
NaOH d
HCl
Z
X
Y
Cu 4. (A-07) 35: Cho s C6H6
Fe,t o
t o cao, P cao
Hai cht hu c Y, Z ln lt l:
A. C6H6(OH)6, C6H6Cl6.
B. C6H4(OH)2, C6H4Cl2.
Cu 5. (B-08) 33: Cho cc p:
to
HBr + C2H5OH
C2H4 + HBr
C. C6H5ONa, C6H5OH. D. C6H5OH, C6H5Cl.

C2H4 + Br2
askt(1:1mol)
C2H6 + Br2
S p to ra C2H5Br l
A. 4.
B. 3.
C. 2.
D. 1.
Cu 6. (C-11) 49: un si hn hp gm propyl bromua, kali hiroxit v etanol thu c sn phm
hu c l
A. propan-2-ol.
B. propin.
C. propen.
D. propan.
Br (1:1mol),Fe,t o
NaOH ( dac ),t , p

2
Cu 7. Cho s chuyn ho sau:
X
Y
Toluen
HCl ( du )
Z
Trong X, Y, Z u l hh ca cc cht hu c. Z c thnh phn chnh gm
A. m-metylphenol v o-metylphenol.
B. benzyl bromua v o-bromtoluen.
C. o-bromtoluen v p-bromtoluen.
D. o-metylphenol v p-metylphenol.
Cu 8. (C-11) 4: Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo
t l s mol 1:1 (c mt bt st) l
A. p-bromtoluen v m-bromtoluen.
B. benzyl bromua.
C. o-bromtoluen v p-bromtoluen.
D. o-bromtoluen v m-bromtoluen.
o
Thng k H 2007-2014
12.2. PHENOL
Cu 9. (A-13) 3: Phenol phn ng c vi dung dch no sau y?
A. NaHCO3.
B. NaCl.
C. HCl.
D. KOH.
Cu 10. (C-13) 6: Dung dch phenol (C6H5OH) khng phn ng c vi cht no sau y?
A. NaOH.
B. NaCl.
C. Br2.
D. Na.
Cu 11. (A-14): Phenol (C6H5OH) khng phn ng vi cht no sau y?
A. Na
B. NaOH
C. NaHCO3
D. Br2
Cu 12. (A-12) 17: Cho cc pht biu sau v phenol (C6H5OH):
(a) Phenol tan nhiu trong nc lnh.
(b) Phenol c tnh axit nhng dung dch phenol trong nc khng lm i mu qu tm.
(c) Phenol c dng sn xut phm nhum, cht dit nm mc.
(d) Nguyn t H ca vng benzen trong phenol d b thay th hn nguyn t H trong benzen.
(e) Cho nc brom vo dung dch phenol thy xut hin kt ta.
S pht biu ng l
A. 4.
B. 2.
C. 5.
D. 3
Cu 13. (C -14): Pht biu no sau y l sai khi ni v phenol (C6H5OH)?
A. Dung dch phenol khng lm i mu qu tm
B. Phenol tc dng vi nc brom to kt ta
C. Phenol thuc loi ancol thm, n chc
D. Phenol t tan trong nc lnh nhng tan nhiu trong nc nng
(a) Cc cht CH3NH2, C2H5OH, NaHCO3 u c kh nng phn ng vi HCOOH.
(b) Phn ng th brom vo vng benzen ca phenol (C6H5OH) d hn ca benzen.
(c) Oxi ha khng hon ton etilen l phng php hin i sn xut anehit axetic.
(d) Phenol (C6H5OH) tan t trong etanol.
A. 4.
B. 2.
C. 3.
D. 1.
Cu 15. (B-07) 11: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u t/d
c vi dd NaOH l
A. 2.
B. 4.
C. 3.
D. 1.
Cu 16. (B-11) 15: Ho tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch
cht Y th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l:
A. phenol, natri hiroxit, natri phenolat.
B. phenylamoni clorua, axit clohiric, anilin.
C. anilin, axit clohiric, phenylamoni clorua.
D. natri phenolat, axit clohiric, phenol.
Cu 17. (B-12) 45: C bao nhiu cht cha vng benzen c cng cng thc phn t C7H8O?
A. 3.
B. 5.
C. 6.
D. 4.
Cu 18. (B-10) 50: Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cc cht thuc loi phenol l:
A. (1), (3), (5), (6).
B. (1), (2), (4), (6).
C. (1), (2), (4), (5).
D. (1), (4), (5), (6).
Cu 19. (B-08) 37: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua p
gia phenol vi
A. dd NaOH.
B. Na kim loi.
C. nc Br2.
D. H2 (Ni, nung
nng).
Cu 20. (A-10) 4: Trong s cc pht biu sau v phenol (C6H5OH):
(1) Phenol tan t trong nc nhng tan nhiu trong dd HCl.
(2) Phenol c tnh axit, dd phenol khng lm i mu qu tm.
(3) Phenol dng sn xut keo dn, cht dit nm mc.
(4) Phenol tham gia p th brom v th nitro d hn benzen.
Cc pht biu ng l:
A. (1), (2), (4).
B. (2), (3), (4).
C. (1), (2), (3).
D. (1), (3), (4).
Cu 21. (A-11) 10: Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc
n gin nht. Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn
ng hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu
ng phn (cha vng benzen) tha mn cc tnh cht trn?
Thng k H 2007-2014
A. 7.
B. 9.
C. 3.
D. 10.
Cu 22. (C-11) 18: Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri
(d), thu c 2,24 lt kh H2 (ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml
dung dch NaOH 1M. Gi tr ca m l
A. 7,0.
B. 21,0.
C. 14,0.
D. 10,5.
Cu 23. (B-07) 34: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO 2 thu c nh
hn 35,2 gam. Bit rng, 1 mol X ch t/d c vi 1 mol NaOH. Cng thc cu to thu gn ca X l (cho
C =12, O = 16)
A. C2H5C6H4OH.
B. HOCH2C6H4COOH.
C. HOC6H4CH2OH.
D.
C6H4(OH)2.
Cu 24. (C-12) 16: Cho dung dch cha m gam hn hp gm phenol (C6H5OH) v axit axetic tc
dng va vi nc brom, thu c dung dch X v 33,1 gam kt ta 2,4,6-tribromphenol. Trung
ha hon ton X cn va 500 ml dung dch NaOH 1M. Gi tr ca m l
A. 33,4.
B. 21,4.
C. 24,8.
D. 39,4.
12.3. ANCOL
ng phn, danh php
Cu 25. (A-13) 36: ng vi cng thc phn t C4H10O c bao nhiu ancol l ng phn cu to ca
nhau?
A. 4.
B. 3.
C. 2.
D. 5.
Cu 26. (C-07) 43: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca
nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? (Cho H = 1; C = 12; O = 16)
A.2.
B.3.
C.4.
D.5.
Cu 27. (C-13) 37: S ng phn cha vng benzen, c cng thc phn t C7H8O, phn ng c vi
Na l
A. 3.
B. 5.
C. 4.
D. 2.
Cu 28. (B-07) 2: Cc ng phn ng vi CTPT C8H10O (u l dn xut ca benzen) c tnh cht: tch
nc thu c sn phm c th trng hp to polime, khng t/d c vi NaOH. S lng ng phn
ng vi CTPT C8H10O, tho mn tnh cht trn l
A. 1.
B. 4.
C. 3.
D. 2.
Cu 29. (C-11) 33: S ancol ng phn cu to ca nhau c cng thc phn t C5H12O, tc dng
vi CuO un nng sinh ra xeton l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 30. (C-12) 15: S ancol bc I l ng phn cu to ca nhau c cng thc phn t C5H12O l
A. 8.
B. 1.
C. 4.
D. 3.
Cu 31. (B-14): Ancol no sau y c s nguyn t cacbon bng s nhm -OH?
A. Propan-1,2-iol
B. Glixerol
C. Ancol benzylic
D. Ancol etylic
Cu 32. (C-09) 53: Dy gm cc cht u tc dng vi ancol etylic l:
A. HBr (to), Na, CuO (to), CH3COOH (xc tc).
C. Ca, CuO (to), C6H5OH (phenol),
HOCH2CH2OH.
B. NaOH, K, MgO, HCOOH (xc tc).
D. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O.
Phn ng tch nc to anken
Cu 33. (A-08) 42: Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm
chnh thu c l
A. 3-metylbuten-1 (hay 3-metylbut-1-en).
B. 2-metylbuten-2 (hay 2-metylbut-2-en).
C. 3-metylbuten-2 (hay 3-metylbut-2-en).
D. 2-metylbuten-3 (hay 2-metylbut-3-en).
Cu 34. (B-13) 16: Tn gi ca anken (sn phm chnh) thu c khi un nng ancol c
cng thc (CH3)2CHCH(OH)CH3 vi dung dch H2SO4 c l
A. 3-metylbut-2-en.
B. 2-metylbut-1-en.
C. 2-metylbut-2-en.
D. 3-metylbut-1-en.
Cu 35. (A-07) 34: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l
ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l
D.
A. (CH3)3COH.
B. CH3CH(CH3)CH2OH. C. CH3OCH2CH2CH3.
CH3CH(OH)CH2CH3.
Thng k H 2007-2014
Cu 36. (C-07) 47: Khi thc hin phn ng tch nc i vi ru (ancol) X, ch thu c mt anken
duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao
nhiu cng thc cu to ph hp vi X?
A. 5.
B. 4.
C. 3.
D. 2.
Cu 37. (A-10) 59: Tch nc hh gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol
mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l
A. CH3-CH2-CH(OH)-CH3.
B. CH3-CH2-CH2-OH. C. CH3-CH2-CH2-CH2-OH. D. CH3-CH(OH)-CH3.
Cu 38. (B-08) 18: un nng mt ru (ancol) n chc X vi dd H2SO4 c trong iu kin
nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y
l ( sai, phi hi l cng thc phn t ca X mi ng)
A. C3H8O.
B. C2H6O.
C. CH4O.
D. C4H8O.
Cu 39. (A-12) 38: Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H2SO4 c
thu c anken Y. Phn t khi ca Y l
A. 42.
B. 70.
C. 28.
D. 56.
Phn ng tch nc to ete
Cu 40. (C-08) 11: Khi un nng hh ru (ancol) gm CH3OH v C2H5OH (xc tc H2SO4 c,
140oC) th s ete thu c ti a l
A. 4.
B. 2.
C. 1.
D. 3.
Cu 41. (B-08) 7: un nng hh gm hai ru (ancol) n chc, mch h, k tip nhau trong dy
ng ng vi H2SO4 c 140oC. Sau khi cc p kt thc, thu c 6 gam hh gm ba ete v 1,8 gam
nc. CTPT ca hai ru trn l
A. CH3OH v C2H5OH.
B. C2H5OH v C3H7OH.
C. C3H5OH v C4H7OH.
D.C3H7OH v C4H9OH.
Cu 42. (C-13) 2: Hn hp X gm hai ancol n chc, ng ng k tip. un nng 16,6 gam X vi
H2SO4 c 140C, thu c 13,9 gam hn hp ete (khng c sn phm hu c no khc). Bit
cc phn ng xy ra hon ton. Cng thc ca hai ancol trong X l
A. C3H5OH v C4H7OH.
B. CH3OH v C2H5OH.
C. C3H7OH v C4H9OH.
D. C2H5OH v C3H7OH.
Cu 43. (A-09) un nng hh hai ancol n chc, mch h vi H2SO4 c, thu c hh gm cc ete.
Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2
gam H2O. Hai ancol l
A. C2H5OH v CH2=CH-CH2-OH.
B. C2H5OH v CH3OH.
C. CH3OH v C3H7OH.
D. CH3OH v CH2=CH-CH2-OH.
Cu 44. (B-11) 16: Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y)
l ng
ng k tip thnh hai phn bng nhau:
- t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O.
o
- un nng phn 2 vi H2SO4 c 140 C to thnh 1,25 gam hn hp ba ete. Ho hi hon
ton hn hp ba ete trn, thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu
kin nhit , p sut).
Hiu sut phn ng to ete ca X, Y ln lt l
A. 25% v 35%.
B. 20% v 40%.
C. 40% v 20%.
D. 30% v 30%.
Cu 45. (B-10) 59: t chy hon ton m gam hh X gm ba ancol (n chc, thuc cng dy ng ng),
thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H2SO4 c th tng
khi lng ete ti a thu c l
A. 7,85 gam.
B. 7,40 gam.
C. 6,50 gam.
D. 5,60 gam.
Cu 46. (C-11) 22: t chy hon ton mt lng hn hp X gm 3 ancol thuc cng dy ng
ng thu c 6,72 lt kh CO2 (ktc) v 9,90 gam H2O. Nu un nng cng lng hn hp X nh
trn vi H2SO4 c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l
A. 6,45 gam.
B. 5,46 gam.
C. 4,20 gam.
D. 7,40 gam.
Ancol tc dng vi Na
Cu 47. (C-10) 24: Cho 10 ml dd ancol etylic 46o p ht vi kim loi Na (d), thu c V lt kh H2
(ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. Gi tr ca V l
A. 4,256.
B. 2,128.
C. 3,360.
D. 0,896.
Cu 48. (A-07) 42: Cho 15,6 gam hh hai ancol (ru) n chc, k tip nhau trong dy ng ng t/d ht
Thng k H 2007-2014
vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l (cho H = 1, C = 12, O = 16, Na = 23)
A. CH3OH v C2H5OH.
B. C2H5OH v C3H7OH.
C. C3H5OH v C4H7OH.
D. C3H7OH v C4H9OH.
Cu 49. (C-08) 31: t chy hon ton hh M gm 2 ru X v Y l ng ng k tip ca nhau, thu
c 0,3 molCO2 v 0,425 mol H2O. Mt khc, cho 0,25mol hh M t/d vi Na (d), thu c cha n 0,15
mol H2. CTPT ca X, Y l:
A. C2H6O2, C3H8O2. B. C2H6O, CH4O.
C. C3H6O, C4H8O.
D. C2H6O, C3H8O.
t chy ancol
Cu 50. (B-07) 37: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6
gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l (cho C = 12, O = 16)
A. C2H4(OH)2.
B. C3H7OH.
C. C3H5(OH)3.
D. C3H6(OH)2.
Cu 51. (C-13) 43: t chy hon ton 1 mol ancol no, mch h X cn va 3,5 mol O2. Cng
thc phn t ca X l
A. C3H8O3.
B. C2H6O2.
C. C2H6O.
D. C3H8O2.
Cu 52. (A-10) 27: t chy hon ton m gam hh 3 ancol n chc, thuc cng dy ng ng, thu
c 3,808 lt kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l
A. 5,42.
B. 5,72.
C. 4,72.
D. 7,42.
Cu 53. (B-10) 38: t chy hon ton mt lng hh X gm 2 ancol ( u no, a chc, mch h, c
cng s nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh
o ktc). Gi tr ca V l
A. 14,56.
B. 15,68.
C. 11,20.
D. 4,48.
Cu 54. (B-14): t chy hon ton 0,1 mol mt ancol n chc trong 0,7 mol O2 (d), thu c tng
s mol cc kh v hi bng 1 mol. Khi lng ancol ban u em t chy l
A. 8,6 gam.
B. 6,0 gam.
C. 9,0 gam.
D. 7,4 gam.
Cu 55. (C -14): t chy hon ton m gam hn hp gm ba ancol cng dy ng ng, thu c
4,704 lt kh CO2 (ktc) v 6,12 gam H2O. Gi tr ca m l
A. 4,98.
B. 4,72.
C. 7,36.
D. 5,28.
Cu 56. (A-08) 21: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu:
tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng
vi cng thc phn t ca X l
A. 3.
B. 4.
C. 2.
D. 1.
Cu 57. (C-08) 37: t chy hon ton mt ru (ancol) a chc, mch h X, thu c H2O v CO2
vi t l s mol tng ng l 3:2. Cng thc phn t ca X l
A. C2H6O2.
B. C2H6O.
C. C3H8O2.
D. C4H10O2.
Cu 58. (A-09) 10: Cho hh X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy
hon ton hh X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l
A. C3H5(OH)3 v C4H7(OH)3.
B. C2H5OH v C4H9OH.
C. C2H4(OH)2 v C4H8(OH)2.
D. C2H4(OH)2 v C3H6(OH)2.
Cu 59. (A-09) 19: Khi t chy hon ton m gam hh hai ancol no, n chc, mch h thu c V lt
kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l:
V
V
V
V
A. m=a.
B. m 2a
.
C. m 2a
.
D. m a
.
22, 4
11, 2
5,6
5,6
Cu 60. (C-12) 44: t chy hon ton hn hp X gm hai ancol no, hai chc, mch h cn va
V1 lt kh O2, thu c V2 lt kh CO2 v a mol H2O. Cc kh u o iu kin tiu chun. Biu
thc lin h gia cc gi tr V1,V2, a l
A. V1 = 2V2 + 11,2a.
B. V1 = V2 22,4a.
C. V1 = V2 + 22,4a. D. V1 = 2V2 11,2a.
Cu 61. (B-12) 59: t chy hon ton m gam hn hp X gm hai ancol, thu c 13,44 lt kh CO2
(ktc) v 15,3 gam H2O. Mt khc, cho m gam X tc dng vi Na (d), thu c 4,48 lt kh H2 (ktc).
Gi tr ca m l
A. 12,9.
B. 15,3.
C. 12,3.
D. 16,9.
Cu 62. (B-12) 15: Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m
gam X thu c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt
kh H2 (ktc). Gi tr ca V l
A. 3,36.
B. 11,20.
C. 5,60.
D. 6,72.
Cu 63. (B-13) 25: Hn hp X gm ancol metylic, etylen glicol. Cho m gam X phn ng hon ton vi
Na d, thu c 2,24 lt kh H2 (ktc). t chy hon ton m gam X, thu c a gam CO2. Gi tr ca a
Thng k H 2007-2014
l
A. 2,2.
B. 4,4.
C. 8,8.
D. 6,6.
Cu 64. (A-13) 43: t chy hon ton hn hp X gm 0,07 mol mt ancol a chc v 0,03 mol
mt ancol khng no, c mt lin kt i, mch h, thu c 0,23 mol kh CO2 v m gam H2O. Gi tr
ca m l
A. 2,70.
B. 5,40.
C. 8,40.
D. 2,34.
Ancol a chc tc dng vi Cu(OH)2
Cu 65. (A-14): Ancol X no, mch h, c khng qu 3 nguyn t cacbon trong phn t. Bit X khng
tc dng vi Cu(OH)2 iu kin thng. S cng thc cu to bn ph hp vi X l
A. 5
B. 3
C. 4
D. 2
Cu 66. (C-07) 45: Cho cc cht c CTCT nh sau: HOCH2-CH2OH (X); HOCH2-CH2-CH2OH (Y); HOCH2CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi
Cu(OH)2 to thnh dd mu xanh lam l
A. X, Y, R, T.
B. X, Z, T.
C. Z, R, T.
D. X, Y, Z, T.
Cu 67. (A-09) t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 (
ktc). Mt khc, nu cho 0,1 mol X t/d va vi m gam Cu(OH)2 th to thnh dd c mu xanh lam.
Gi tr ca m v tn gi ca X tng ng l
A. 9,8 v propan-1,2-iol.
B. 4,9 v propan-1,2-iol.
C. 4,9 v propan-1,3-iol.
D. 4,9
v glixerol.
Cu 68. (A-12) 47: t chy hon ton mt lng ancol X to ra 0,4 mol CO2 v 0,5 mol H2O. X tc
dng vi Cu(OH)2 to dung dch mu xanh lam. Oxi ha X bng CuO to hp cht hu c a chc
Y. Nhn xt no sau y ng vi X?
A. Trong X c 3 nhm -CH3.
B. Hirat ha but-2-en thu c X.
C. Trong X c 2 nhm -OH lin kt vi hai nguyn t cacbon bc hai.
D. X lm mt mu nc brom.
Cu 69. (A-13) : Hn hp X gm ancol metylic, ancol etylic v glixerol. t chy hon ton m gam X,
thu c 15,68 lt kh CO2 (ktc) v 18 gam H2O. Mt khc, 80 gam X ha tan c ti a 29,4
gam Cu(OH)2. Phn trm khi lng ca ancol etylic trong X l
A. 23%.
B. 46%.
C. 16%.
D. 8%.
Cu 70. (C-13) 22: t chy hon ton mt lng ancol X cn va 8,96 lt kh O2 (ktc), thu
c 6,72 lt kh CO2 (ktc) v 7,2 gam H2O. Bit X c kh nng phn ng vi Cu(OH)2. Tn ca X l
A. propan-1,3-iol.
B. propan-1,2-iol.
C. glixerol.
D. etylen glicol.
Oxi ha khng hon ton ancol to anhit, xeton, axit cacbonxylic
Cu 71. (B-07) 1: Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung
nng. Sau khi p hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t
khi i vi hiro l 15,5. Gi tr ca m l
A. 0,92.
B. 0,32.
C. 0,64.
D. 0,46.
Cu 72. (B-08) 9: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hh sn
ph m X (gm HCHO, H2O v CH3OH d). Cho ton b X t/d vi lng d Ag2O (hoc AgNO3)
trong dd NH3, c 12,96 gam Ag. Hiu sut ca lng cht rn trong bnh gim 0,32 gam. Hh hi thu
c c t khi i vi hiro l 15,5. Gi tr ca m l p oxi ho CH3OH l
A. 76,6%.
B. 80,0%.
C. 65,5%.
D. 70,4%.
Cu 73. (A-10) 38: Oxi ho ht 2,2 gam hh hai ancol n chc thnh anehit cn va 4,8 gam CuO.
Cho ton b lng anehit trn t/d vi lng d dd AgNO 3 trong NH3, thu c 23,76 gam Ag. Hai
ancol l:
A. CH3OH, C2H5CH2OH.
B. CH3OH, C2H5OH. C. C2H5OH, C3H7CH2OH.
D.
C2H5OH,
C2H5CH2OH.
Cu 74. (C-10) 55: Cho 4,6 gam mt ancol no, n chc phn ng vi CuO nung nng, thu c 6,2
gam hn hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi
lng d dung dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l
A. 16,2.
B. 21,6.
C. 10,8.
D. 43,2.
Cu 75. (A-08) 2: Cho m gam hh X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng
ng t/d vi CuO (d) nung nng, thu c mt hh rn Z v mt hh hi Y (c t khi hi so vi H2 l
13,75). Cho ton b Y p vi mt lng d Ag2O (hoc AgNO3) trong dd NH3 un nng, sinh ra 64,8
Thng k H 2007-2014
gam Ag. Gi tr ca m l
A. 7,8.
B. 8,8.
C. 7,4.
D. 9,2.
Cu 76. (B-09) 51: Hh X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi
ho hon ton 0,2 mol hh X c khi lng m gam bng CuO nhit thch hp, thu c hh sn
phm hu c Y. Cho Y t/d vi mt lng d dd AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l
A. 15,3.
B. 13,5.
C. 8,1.
D. 8,5.
Cu 77. (C -14): Chia m gam ancol X thnh hai phn bng nhau:
- Phn mt phn ng ht vi 8,05 gam Na, thu c a gam cht rn v 1,68 lt kh H2 (ktc).
- Phn hai phn ng vi CuO d, un nng, thu c cht hu c Y. Cho Y phn ng vi
lng d dung dch AgNO3 trong NH3, thu c 64,8 gam Ag.
Bit cc phn ng xy ra hon ton. Gi tr ca a l
A. 8,25.
B. 18,90.
C. 8,10.
D. 12,70.
Cu 78. (C-12) 34: Cho m gam hn hp hi X gm hai ancol (n chc, bc I, l ng ng k tip)
phn ng vi CuO d, thu c hn hp hi Y gm nc v anehit. T khi hi ca Y so vi kh hiro
bng 14,5. Cho ton b Y phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 97,2
A. 14,0.
B. 10,1.
C. 18,9.
D. 14,7.
Cu 79. (B-10) 18: Hh X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi
hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc p xy ra hon ton,
thu c hh Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y t/d hon ton
vi lng d dd AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X
l
A. 65,2%.
B. 16,3%.
C. 48,9%.
D. 83,7%.
Cu 80. (C-10) 50: Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, c cht hu c
X. Tn gi ca X l
A. metyl vinyl xeton.
B. propanal. C. metyl phenyl xeton. D. imetyl xeton.
Cu 81. (C-08) 51: Oxi ho ancol n chc X bng CuO ( un nng), sinh ra mt sn phm hu c
duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l
A. CH3-CHOH-CH3.
B. CH3-CH2-CHOH-CH3.
C. CH3-CO-CH3. D. CH3-CH2-CH2-OH.
Cu 82. (C-09) 36: Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v
etanol d. Cho ton b X t/d vi dd NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol
b oxi ho to ra axit l
A. 1,15 gam.
B. 4,60 gam.
C. 2,30 gam.
D. 5,75 gam.
Cu 83. (B-12) 19: Oxi ha 0,08 mol mt ancol n chc, thu c hn hp X gm mt axit
cacboxylic, mt anehit, ancol d v nc. Ngng t ton b X ri chia lm hai phn bng nhau.
Phn mt cho tc dng ht vi Na d, thu c 0,504 lt kh H2 (ktc). Phn hai cho phn ng trng
bc hon ton thu c 9,72 gam Ag. Phn trm khi lng ancol b oxi ho l
A. 50,00%.
B. 62,50%.
C. 31,25%.
D. 40,00%.
Cu 84. (C-12) 34: Cho m gam hn hp hi X gm hai ancol (n chc, bc I, l ng ng k tip)
phn ng vi CuO d, thu c hn hp hi Y gm nc v anehit. T khi hi ca Y so vi kh hiro
bng 14,5. Cho ton b Y phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 97,2
A. 14,0.
B. 10,1.
C. 18,9.
D. 14,7.
Cu 85. (C-13) Oxi ha m gam ancol n chc X, thu c hn hp Y gm axit cacboxylic, nc v
ancol d. Chia Y lm hai phn bng nhau. Phn mt phn ng hon ton vi dung dch KHCO3 d, thu
c 2,24 lt kh CO2 (ktc). Phn hai phn ng vi Na va , thu c 3,36 lt kh H2 (ktc) v 19 gam
cht rn khan. Tn ca X l
A. metanol.
B. etanol.
C. propan-2-ol.
D. propan-1-ol.
13. AN HIT, XETON, AXIT CACBONXYLIC

13.1. ANHIT
Cng thc phn t, ng phn
Cu 3. (A-14): Cho anehit no, mch h, c cng thc CnHmO2. Mi quan h gia n vi m l
A. m = 2n
B. m = 2n +1
C. m = 2n + 2
D. m = 2n - 2
Cu 4. (C-10) 23: Anehit no mch h X c cng thc n gin nht C2H3O. Cng thc phn t ca
X l
Thng k H 2007-2014
A. C4H6O2.
B. C8H12O4.
C. C2H3O.
D. C6H9O3.
Cu 5. (B-08) 22: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng
thc phn t ca X l
A. C6H8O6.
B. C3H4O3.
C. C12H16O12.
D. C9H12O9.
(C-14):
Tn
thay
th
ca
CH
CH
O
l
Cu 6.
3
A. metanal
B. metanol
C. etanol
D. etanal
Cu 7. (C-08) 33: Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S
cht trong dy tham gia p trng gng l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 8. (A-09) 37: Cho 0,25 mol mt anehit mch h X p vi lng d dd AgNO3 trong NH3, thu c
54g Ag. Mt khc, khi cho X p vi H2 d (xc tc Ni, to) th 0,125 mol X p ht vi 0,25 mol H2. Cht X c
cng thc ng vi CT chung l
B. CnH2n+1CHO (n 0).
C. CnH2n-1CHO (n 2).
Cu 9. (B-12) 31: Cho 0,125 mol anehit mch h X phn ng vi lng d dung dch AgNO3
trong NH3 thu c 27 gam Ag. Mt khc, hiro ho hon ton 0,25 mol X cn va 0,5 mol H2.
Dy ng ng ca X c cng thc chung l
B. CnH2n-3CHO (n 2).
C. CnH2n+1CHO (n 0).
(B-07)
41:
t
chy
hon
ton
a
mol
mt
anehit
X (mch h) to ra b mol CO 2 v c mol H2O
Cu 10.
(bit b = a + c). Trong p trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng
anehit
A. no, n chc.
B. khng no c hai ni i, n chc.
C. khng no c mt ni i, n chc.
D. no, hai chc.
Cu 11. (A-08) 1: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi p xy ra
hon ton ch thu c mt hh kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit ,
p sut). Ngng t Y thu c cht Z; cho Z t/d vi Na sinh ra H2 c s mol bng s mol Z p. Cht
X l anehit
A. khng no (cha mt ni i C=C), hai chc.
B. no, hai chc.
C. no, n chc.
D. khng no (cha mt ni i C=C), n chc
PHN NG TRNG BC
Cu 12. (A-13) 2: Khi lng Ag thu c khi cho 0,1 mol CH3CHO phn ng hon ton vi lng
d dung dch AgNO3 trong NH3, un nng l
A. 16,2 gam.
B. 21,6 gam.
C. 10,8 gam.
D. 43,2 gam.
Cu 13. (C-13) 38: Cho 4,4 gam anehit n chc X phn ng hon ton vi lng d dung dch
AgNO3 trong NH3, un nng, thu c 21,6 gam Ag. Cng thc ca X l
A. C2H3CHO.
B. HCHO.
C. CH3CHO.
D. C2H5CHO.
Cu 14. (C-08) 32: t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu
cho X t/d vi lng d Ag2O (hoc AgNO3) trong dd NH3, sinh ra s mol Ag gp bn ln s mol X p.
CTPT ca X l
A. HCHO.
B. CH3CHO.
C. (CHO)2.
D. C2H5CHO.
Cu 15. (C-07) 34: Cho 2,9 gam mt anehit p hon ton vi lng d AgNO3 (hoc Ag2O) trong dd
NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l (Cho H = 1; C = 12; O = 16; Ag =
108)
A. HCHO.
B. CH2=CH-CHO.
C. OHC-CHO.
D. CH3CHO.
Cu 16. (C-09) 5: Cho 0,1 mol hh X gm hai anehit no, n chc, mch h, k tip nhau trong dy
ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag.
Hai anehit trong X l
A. HCHO v C2H5CHO.
B. HCHO v CH3CHO.
C. C2H3CHO v C3H5CHO.
D. CH3CHO v C2H5CHO.
Cu 17. (C-08) 16: Cho hh gm 0,1 mol HCHO v 0,1 mol HCOOH t/d vi lng d Ag2O (hoc
AgNO3) trong dd NH3, un nng. Sau khi cc p xy ra hon ton, khi lng Ag to thnh l
A. 43,2 gam.
B. 10,8 gam.
C. 64,8 gam.
D. 21,6 gam.
Cu 18. (A-07) 4: Cho 6,6 gam mt anehit X n chc, mch h p vi lng d AgNO3 (hoc Ag2O)
trong dd NH3, un nng. Lng Ag sinh ra cho p ht vi axit HNO 3 long, thot ra 2,24 lt kh NO (sn
phm kh duy nht, o ktc). CTCT thu gn ca X l
A. CH3CHO.
B. HCHO.
C. CH3CH2CHO.
D. CH2 = CHCHO.
Thng k H 2007-2014
Cu 19. (A-08) 10: Cho 3,6 gam anehit n chc X p hon ton vi mt lng d Ag2O (hoc
AgNO3) trong dd NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dd HNO3
c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l
A. C3H7CHO.
B. HCHO.
C. C4H9CHO.
D. C2H5CHO.
Cu 20. (A-11) 27: t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong
cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong
NH3 th thu c 0,04 mol Ag. X l
A. anehit no, mch h, hai chc.
B. anehit khng no, mch h, hai chc.
C. anehit axetic.
D. anehit fomic
Cu 21. (A-07) 15: Cho 0,1 mol anehit X t/d vi lng d AgNO3 (hoc Ag2O) trong dd NH3, un
nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y p va vi 4,6 gam Na. Cng
thc cu to thu gn ca X l
A. HCHO.
B. CH3CH(OH)CHO.
C. CH3CHO.
D. OHC-CHO
Cu 22. (B-11) 40: Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca
Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt
thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu
c 0,784 lt CO2 (ktc). Tn ca Z l
A. anehit acrylic.
B. anehit butiric.
C. anehit propionic. D. anehit axetic
Cu 23. (B-11) 43: X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t
u c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn
hp Y c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d),
c V lt H2 (ktc). Gi tr ln nht ca V l
A. 22,4.
B. 13,44.
C. 5,6.
D. 11,2.
Cu 24. (A-10) 43: Cho m gam hh etanal v propanal p hon ton vi lng d dd AgNO 3 trong NH3,
thu c 43,2 gam kt ta v dd cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l
A. 9,5.
B. 10,9.
C. 14,3.
D. 10,2.
Cu 25. (B-11) 13: hiro ho hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64
gam, cn 1,12 lt H2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch
AgNO3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l
A. CH2=C(CH3)-CHO v OHC-CHO.
B. OHC-CH2-CHO v OHC-CHO.
C. H-CHO v OHC-CH2-CHO.
D. CH2=CH-CHO v OHC-CH2-CHO.
Cu 26. (C-11) 41: Hn hp G gm hai anehit X v Y, trong MX < MY < 1,6MX. t chy hn
hp G thu c CO2 v H2O c s mol bng nhau. Cho 0,10 mol hn hp G vo dung dch AgNO3
trong NH3 thu c 0,25 mol Ag. Tng s cc nguyn t trong mt phn t Y l
A. 6.
B. 9.
C. 10.
D. 7.
Cu 27. (C-13) 53: Hn hp X gm hai anehit no, n chc, mch h (t l s mol 3 : 1). t chy
hon ton mt lng X cn va 1,75 mol kh O2, thu c 33,6 lt kh CO2 (ktc). Cng thc ca
hai anehit trong X l
A. HCHO v CH3CHO.
B. CH3CHO v C2H5CHO.
C. HCHO v C2H5CHO.
D. CH3CHO v C3H7CHO.
AN HIT tc dng vi H2
Cu 28. (A-09) 3: Cho hh kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi p xy
ra hon ton, thu c hh kh Y gm 2 cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84
lt kh CO2 ( ktc). % theo th tch ca H2 trong X l
A. 46,15%.
B. 35,00%.
C. 53,85%.
D. 65,00%.
Cu 29. (A-14): Cho 0,1 mol anehit X phn ng ti a vi 0,3 mol H2, thu c 9 gam ancol Y. Mt
khc 2,1 gam X tc dng ht vi lng d dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr
ca m l
A. 10,8
B. 21,6
C. 5,4
D. 16,2
Cu 30. (C-09) 57: Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h,
k tip nhau trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi
lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO 2. Cng thc v phn trm khi lng
ca X ln lt l
A. HCHO v 50,56%.
B. CH3CHO v 67,16%. C. HCHO v 32,44%.
D. CH3CHO v
Thng k H 2007-2014
49,44%.
Cu 31. (B-09) 42: Hiro ho hon ton m gam hh X gm hai anehit no, n chc, mch h, k tip
nhau trong dy ng ng thu c (m + 1) gam hh hai ancol. Mt khc, khi t chy hon ton cng
m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l
A. 17,8.
B. 24,8.
C. 10,5.
D. 8,8.
Cu 32. (B-07) 49: Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng.
CT ca anehit l
A. HCHO.
B. C2H3CHO.
C. C2H5CHO.
D. CH3CHO.
Cu 33. (B-14): Chia 20,8 gam hn hp gm hai anehit n chc l ng ng k tip thnh hai phn
bng nhau:
- Phn mt tc dng hon ton vi lng d dung dch AgNO3 trong NH3 un nng, thu c
108 gam Ag.
- Phn hai tc dng hon ton vi H2 d (xc tc Ni, t0), thu c hn hp X gm hai ancol Y v
Z (MY < MZ). un nng X vi H2SO4 c 1400C, thu c 4,52 gam hn hp ba ete. Bit hiu sut
phn ng to ete ca Y bng 50%.
Hiu sut phn ng to ete ca Z bng
A. 40%.
B. 60%.
C. 30%.
D. 50%.
13.2. XETON
Cu 34. (A-08) 54: S ng phn xeton ng vi cng thc phn t C5H10O l
A. 5.
B. 6.
C. 3.
D. 4.
Cu 35. (A-07) 54: Cho cc cht: HCN, H2, dd KMnO4, dd Br2. S cht p c vi (CH3)2CO l
A. 4.
B. 1.
C. 3.
D. 2.
Cu 36. (A-10) 58: Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l
A. 2-metylbutan-3-on.
B. metyl isopropyl xeton.
C. 3-metylbutan-2-ol.
D. 3-metylbutan-2-on.
Cu 37. (C-07) 52: Trong cng nghip, axeton c iu ch t
A. xiclopropan.
B. propan-1-ol.
C. propan-2-ol.
D. cumen.
Cu 38. (A-10) 1: Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu phn trong dd
H2SO4 long. thu c 145 gam axeton th lng cumen cn dng (gi s hiu sut qu trnh iu
ch t 75%) l
A. 300 gam.
B. 600 gam.
C. 500 gam.
D. 400 gam.
Cu 39. (A-11) 56: Pht biu no sau y v anehit v xeton l sai?
A. Axetanehit phn ng c vi nc brom.
B. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn.
C. Axeton khng phn ng c vi nc brom.
D. Anehit fomic tc dng vi H2O to thnh sn phm khng bn.
13.3. AXIT CACBOXYLIC

Phn ng t chy
Cu 40. (B-07) 15: t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 (
ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l
A. 8,96.
B. 11,2.
C. 6,72.
D. 4,48.
Cu 41. (A-11) 3: t chy h/ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u
c mt lin kt i C=C trong phn t, thu c V lt kh CO2 (ktc) v y mol H2O. Biu thc lin h
gia cc gi tr x, y v V l
28
(x 30y)
55
28
C. V
(x 62y)
95
A.
28
(x 30y)
55
28
D. V
(x 62y)
95
B. V
Cu 42. (B-10) 3: Hh X gm axit panmitic, axit stearic v axit linoleic. trung ho m gam X cn 40 ml
dd NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO 2 (ktc) v 11,7
gam H2O. S mol ca axit linoleic trong m gam hh X l
A. 0,015.
B. 0,010.
C. 0,020.
D. 0,005.
Thng k H 2007-2014
Cu 43. (A-11) 30: Trung ho 3,88 gam hn hp X gm hai axit cacboxylic no, n chc, mch h
bng dung dch NaOH, c cn ton b dung dch sau phn ng thu c 5,2 gam mui khan. Nu t
chy hon ton 3,88 gam X th th tch oxi (ktc) cn dng l
A. 2,24 lt.
B. 4,48 lt.
C. 1,12 lt.
D. 3,36 lt.
Cu 44. (A-11) 34: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc
dng vi NaHCO3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X
cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l
A. 0,2.
B. 0,3.
C. 0,6.
D. 0,8.
Cu 45. (A-12) 14: Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X
phn ng ht vi dung dch NaHCO3 thu c 1,344 lt CO2 (ktc). t chy hon ton m gam X cn
2,016 lt O2 (ktc), thu c 4,84 gam CO2 v a gam H2O. Gi tr ca a l
A. 1,62.
B. 1,44.
C. 3,60.
D. 1,80.
Cu 46. Mt hn hp X gm 2 axit no. t chy hon ton hn hp X thu c s mol H2O ng bng
s mol X t chy. Cho 0,1 mol hn hp X tc dng vi Ag2O/ NH3 thu c 12,96 gam Ag. Hy cho
bit khi cho 0,1 mol hn hp X tc dng vi NaHCO3 th thu c ti a bao nhiu lt CO2 (ktc) ?
A. 2,24 lt
B. 3,136 lt
C 3,36 lt
D. 3,584 lt
Cu 47. (B-12) 34: Hn hp X gm hai axit cacboxylic n chc. t chy hon ton 0,1 mol X cn 0,24
mol O2, thu c CO2 v 0,2 mol H2O. Cng thc hai axit l
A. HCOOH v C2H5COOH.
B. CH2=CHCOOH v CH2=C(CH3)COOH.
C. CH3COOH v C2H5COOH.
D. CH3COOH v CH2=CHCOOH.
Cu 48. (A-13) 29: Bit X l axit cacboxylic n chc, Y l ancol no, c hai cht u mch h, c
cng s nguyn t cacbon. t chy hon ton 0,4 mol hn hp gm X v Y (trong s mol ca X
ln hn s mol ca Y) cn va 30,24 lt kh O2, thu c 26,88 lt kh CO2 v 19,8 gam H2O. Bit
th tch cc kh o iu kin tiu chun. Khi lng ca Y trong 0,4 mol hn hp trn l
A. 11,4 gam.
B. 19,0 gam.
C. 17,7 gam.
D. 9,0 gam.
Phn ng axit- baz

Cu 49. (A-13) 28: Dung dch axit axetic phn ng c vi tt c cc cht trong dy no sau y?
A. Na, CuO, HCl.
B. NaOH, Cu, NaCl.
C. Na, NaCl, CuO.
D.
NaOH,
Na,
CaCO3.
Cu 50. (C -14): Axit axetic khng phn ng vi cht no sau y?
A. NaOH
B. MgCl2
C. ZnO
D. CaCO3
Cu 51. (B-14): Dung dch axit acrylic (CH2=CH-COOH) khng phn ng c vi cht no sau y?
A. Na2CO3
B. Mg(NO3)2
C. Br2
D. NaOH.
Cu 52. (B-07) 27 trung ha 6,72g mt axit cacboxylic Y (no, n chc), cn dng 200 gam dd NaOH
2,24%. CT ca Y l
A. CH3COOH.
B. HCOOH.
C. C2H5COOH.
D. C3H7COOH.
Cu 53. (C-14): Cho 13,8 gam hn hp gm axit fomic v etanol phn ng ht vi Na d, thu c
V lt kh H2 (ktc). Gi tr ca V l
A. 6,72
B. 4,48
C. 3,36
D. 7,84
Cu 54. (A-14): Hn hp X gm axit axetic, propan-2-ol. Cho mt lng X phn ng va vi Na,
thu c 0,448 lt kh H2 (ktc) v m gam cht rn Y. Gi tr ca m l
A.3,28
B. 2,40
C. 2,36
D. 3,32
Cu 55. (A-14): Trung ha 10,4 gam axit cacboxylic X bng dung dch NaOH, thu c 14,8 gam
mui. Cng thc ca X l
A. C2 H5COOH
B. HOOC CH 2 COOH
C. HOOC COOH
D. C3H7 COOH
Cu 56. (C-10) 14: Cho 16,4 gam hh X gm 2 axit cacboxylic l ng ng k tip nhau p hon ton
vi 200 ml dung dch NaOH 1M v KOH 1M, thu c dd Y. C cn dd Y, thu c 31,1 gam hh cht rn
khan. Cng thc ca 2 axit trong X l
A. C2H4O2 v C3H4O2.
B. C2H4O2 v C3H6O2.
C. C3H4O2 v C4H6O2.
D. C3H6O2
v C4H8O2.
Cu 57. (B-08) 29: Cho 3,6 gam axit cacboxylic no, n chc X t/d hon ton vi 500 ml dd gm KOH
Thng k H 2007-2014
0,12M v NaOH 0,12M. C cn dd thu c 8,28 gam hh cht rn khan. Cng thc phn t ca X l
A. C2H5COOH.
B. CH3COOH.
C. HCOOH.
D. C3H7COOH.
Cu 58. (C-09) 16: Trung ho 8,2 gam hh gm axit fomic v mt axit n chc X cn 100 ml dd
NaOH 1,5M. Nu cho 8,2 gam hh trn t/d vi mt lng d dd AgNO3 trong NH3, un nng th thu c
21,6 gam Ag. Tn gi ca X l
A. axit acrylic.
B. axit propanoic.
C. axit etanoic.
D. axit metacrylic.
Cu 59. (C-13) 5: Cho hn hp gm 0,05 mol HCHO v 0,02 mol HCOOH vo lng d dung dch
AgNO3 trong NH3, un nng. Sau khi cc phn ng xy ra hon ton, thu c m gam Ag. Gi tr ca m
l
A. 15,12.
B. 21,60.
C. 25,92.
D. 30,24.
Cu 60. (A-07) 31: t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha
a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l
C. C2H5-COOH.
D. CH3-COOH.
A. HOOC-CH2-CH2-COOH.
B. HOOC-COOH.
Cu 61. (B-09) 1: Khi cho a mol mt hp cht hu c X (cha C, H, O) p hon ton vi Na hoc
vi NaHCO3 th u sinh ra a mol kh. Cht X l
A. etylen glicol.
B. axit aipic.
C. ancol o-hiroxibenzylic.
D. axit 3hiroxipropanoic.
Cu 62. (A-11) 19: t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol
H2O (vi
z = y x ). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn ca E l
A. axit oxalic.
B. axit acrylic.
C. axit aipic.
D. axit fomic.
Cu 63. (C-12) 4: Trong phn t axit cacboxylic X c s nguyn t cacbon bng s nhm chc. t
chy hon ton mt lng X thu c s mol CO2 bng s mol H2O. Tn gi ca X l
A. axit axetic.
B. axit malonic.
C. axit oxalic.
D. axit fomic.
Cu 64. (C-13) 34: Hn hp X gm hai axit cacboxylic n chc, ng ng k tip. Cho 5,4 gam X
phn ng hon ton vi dung dch NaHCO3 d, thu c 2,24 lt kh CO2 (ktc). Cng thc ca hai
axit trong X l
A. C3H7COOH v C4H9COOH.
B. CH3COOH v C2H5COOH.
C. C2H5COOH v C3H7COOH.
D. HCOOH v CH3COOH.
Cu 65. (C-10) 47: Axit cacboxylic X c cng thc n gin nht l C3H5O2 . Khi cho 100 ml dung
dch axit X nng 0,1M phn ng ht vi dung dch NaHCO 3 (d), thu c V ml kh CO2 (ktc). Gi
tr ca V l
A. 448.
B. 224.
C. 112.
D. 336.
Cu 66. (B-11) 56: Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh
hn ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H2O. Mt khc, nu cho a mol
X tc dng vi lng d dung dch NaHCO3, th thu c 1,6a mol CO2. Thnh phn % theo khi
lng ca Y trong X l
A. 46,67%.
B. 40,00%.
C. 25,41%.
D. 74,59%.
Cu 67. (C -14): Axit malic l hp cht hu c tp chc, c mch cacbon khng phn nhnh, l
nguyn nhn
chnh gy nn v chua ca qu to. Bit rng 1 mol axit matic phn ng c vi ti a 2 mol
NaHCO3. Cng thc ca axit matic l
A.CH3OOC-CH(OH)-COOH
B.HOOC-CH(OH)-CH(OH)-CHO
C.HOOC-CH(OH)-CH2-COOH
D.HOOC-CH(CH3)-CH2-COOH
Cu 68. (C-07) 15: Cho 5,76 gam axit hu c X n chc, mch h t/d ht vi CaCO3 thu c 7,28
gam mui ca axit hu c. Cng thc cu to thu gn ca X l
A. CH2=CH-COOH
B. CH3COOH.
C. HCC-COOH.
D. CH3-CH2COOH.
Cu 69. (B-09) 36: Hh X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t
cacbon). Chia X thnh hai phn bng nhau. Cho phn mt t/d ht vi Na, sinh ra 4,48 lt kh H2 (
ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v
khi lng ca Z trong hh X ln lt l
A. HOOC-CH2-COOH v 70,87%.
B. HOOC-CH2-COOH v 54,88%.
C. HOOC-COOH v 60,00%.
D. HOOC-COOH v 42,86%.
Cu 70. (A-13) 47: Cho X v Y l hai axit cacboxylic mch h, c cng s nguyn t cacbon, trong
Thng k H 2007-2014
X n chc, Y hai chc. Chia hn hp gm X v Y thnh hai phn bng nhau. Phn mt tc dng ht vi
Na, thu c 4,48 lt kh H2 (ktc). t chy hon ton phn hai, thu c 13,44 lt kh CO2 (ktc).
Phn trm khi lng ca Y trong hn hp l
A. 57,14%.
B. 42,86 %.
C. 28,57%.
D. 85,71%.
Cu 71. (B-09) 52: Cho 0,04 mol mt hh X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO p va
vi dd cha 6,4g brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dd NaOH 0,75
M. Khi lng ca CH2=CH-COOH trong X l
A. 0,56 gam.
B. 1,44 gam.
C. 0,72 gam.
D. 2,88 gam.
Cu 72. (A-10) 48: Hh gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim
loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l
A. axit propanoic.
B. axit etanoic.
C. axit metanoic.
D. axit butanoic.
Cu 73. (B-10) 10: Hh Z gm hai axit cacboxylic n chc X v Y (MX > MY) c t ng khi l ng l 8,2
gam. Cho Z t/d va vi dd NaOH, thu c dd cha 11,5 gam mui. Mt khc, nu cho Z t/d vi mt
lng d dd AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X trong
Z l
A. C3H5COOH v 54,88%.
B. C2H3COOH v 43,90%.
C. C2H5COOH v 56,10%.
D. HCOOH v 45,12%.
Cu 74. (A-11) 44: Ho hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc

Y (s mol X ln hn s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o trong
cng iu kin nhit , p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752
lt CO2 (ktc). Cng thc cu to ca X, Y ln lt l
A. H-COOH v HOOC-COOH.
B. CH3-COOH v HOOC-CH2-CH2-COOH.
C. CH3-CH2-COOH v HOOC-COOH.
D. CH3 -COOH v HOOC-CH2 -COOH.
Cu 75. (A-13) 40: Hn hp X cha ba axit cacboxylic u n chc, mch h, gm mt axit no v
hai axit khng no u c mt lin kt i (C=C). Cho m gam X tc dng va vi 150 ml dung dch NaOH
2M, thu c 25,56 gam hn hp mui. t chy hon ton m gam X, hp th ton b sn phm
chy bng dung dch NaOH d, khi lng dung dch tng thm 40,08 gam. Tng khi lng ca hai
axit cacboxylic khng no trong m gam X l
A. 18,96 gam.
B. 9,96 gam.
C. 12,06 gam.
D. 15,36 gam.
Cu 76. (B-13) 3: Hn hp X gm hai axit cacboxylic n chc, mch h, k tip nhau trong cng
dy ng ng. t chy hon ton 4,02 gam X, thu c 2,34 gam H2O. Mt khc 10,05 gam X phn
ng va vi dung dch NaOH, thu c 12,8 gam mui. Cng thc ca hai axit l
A. CH3COOH v C2H5COOH.
B. C2H5COOH v C3H7COOH.
D. C2H3COOH v C3H5COOH.
Phn ng este ha
Cu 77. (C-08) 15: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu
sut p este ho bng 50%). Khi lng este to thnh l
A. 6,0 gam.
B. 4,4 gam.
C. 8,8 gam.
D. 5,2 gam.
Cu 78. (C-07) 41: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi
p t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca p este ho l
A. 55%.
B. 50%.
C. 62,5%.
D. 75%.
Cu 79. (C -14): un nng 24 gam axit axetic vi lng d ancol etylic (xc tc H2SO4 c), thu
c 26,4 gam este. Hiu sut ca phn ng este ha l
A. 75%
B. 44%
C. 55%
D. 60%
Cu 80. (C-09) 21: Cho 45 gam axit axetic p vi 69 gam ancol etylic (xc tc H2SO4 c), un nng,
thu c 41,25 gam etyl axetat. Hiu sut ca p este ho l
A. 31,25%.
B. 40,00%.
C. 62,50%.
D. 50,00%.
Cu 81. (A-07) 19: Hh X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hh X t/d vi
5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hh este (hiu sut ca cc p este ho u
bng 80%). Gi tr ca m l
A. 8,10.
B. 16,20.
C. 6,48.
D. 10,12.
Cu 82. (A-10) 53: Cho hh X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong
dy ng ng) t/d ht vi Na, gii phng ra 6,72 lt kh H2 (ktc). Nu un nng hh X (c H2SO4 c
lm xc tc) th cc cht trong hh p va vi nhau to thnh 25 gam hh este (gi thit p este ho
t hiu sut 100%). Hai axit trong hh X l
B. CH3COOH v C2H5COOH.
Thng k H 2007-2014

D. HCOOH v CH3COOH.
Cu 83. (A-12) 37: t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc,
mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3
mol CO2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu
c m gam este. Gi tr ca m l
A. 8,16.
B. 4,08.
C. 2,04.
D. 6,12.
Cu 84. (C-12) 31: t chy hon ton m gam hn hp X gm hai ancol n chc, cng dy ng
ng, thu c 15,68 lt kh CO2 (ktc) v 17,1 gam nc. Mt khc, thc hin phn ng este ha m
gam X vi 15,6 gam axit axetic, thu c a gam este. Bit hiu sut phn ng este ha ca hai ancol
u bng 60%. Gi tr ca a l
A. 25,79.
B. 15,48.
C. 24,80.
D. 14,88.
Cu 85. (B-13) 53: Hn hp X gm mt axit cacboxylic no, n chc, mch h v mt ancol n
chc, mch h. t chy hon ton 21,7 gam X, thu c 20,16 lt kh CO2 (ktc) v 18,9 gam H2O.
Thc hin phn ng este ha X vi hiu sut 60%, thu c m gam este. Gi tr ca m l
A. 9,18.
B. 15,30.
C. 12,24.
D. 10,80.
14. ESTE, LIPIT

14.1. ng phn, danh php
Cu 1. (A-08) 6: S ng phn este ng vi cng thc phn t C4H8O2 l
A. 5.
B. 2.
C. 4.
D. 6.
Cu 2. (B-14): S ng phn cu to c cng thc phn t C8H10O, cha vng benzen, tc dng c
vi Na, khng tc dng vi dung dch NaOH l
A. 3.
B. 5.
C. 6.
D. 4.
Cu 3. (B-11) 1: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn
ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l
29,7 gam. S ng phn cu to ca X tho mn cc tnh cht trn l
A. 5.
B. 2.
C. 4.
D. 6.
Cu 4. (B-13) 44: Este no sau y khi phn ng vi dung dch NaOH d, un nng khng to ra hai
mui?
A. C6H5COOC6H5 (phenyl benzoat).
B. CH3COO[CH2]2OOCCH2CH3.
C. CH3OOCCOOCH3.
D. CH3COOC6H5 (phenyl axetat).
Cu 5. (B-07) 43: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c
th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X
v Y l
A. HCOOC2H5 v CH3COOCH3.
B. C2H3COOC2H5 v C2H5COOC2H3.
C. C2H5COOCH3 v HCOOCH(CH3) 2.
D. HCOOCH2CH2CH3 v CH3COOC2H5.
Cu 6. (B-07) Cho glixerol p vi hh axit bo gm C17H35COOH v C15H31COOH, s loi trieste
c to ra ti a l
A. 6.
B. 3.
C. 5.
D. 4.
Cu 7. (C-07) 30: Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia p
x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp
vi X?
A. 2.
B. 5.
C. 3.
D. 4.
Cu 8. (C-13) 41: Hp cht X c cng thc phn t C5H8O2, khi tham gia phn ng x phng
ha thu c mt anehit v mt mui ca axit cacboxylic. S ng phn cu to tha mn tnh cht
trn ca X l: A. 3.
B. 2.
C. 5.
D. 4.
Cu 9. (A-08) 18: Pht biu ng l:
A. P gia axit v ru khi c H2SO4 c l p mt chiu.
B. Tt c cc este p vi dd kim lun thu c sn phm cui cng l mui v ru (ancol).
C. Khi thy phn cht bo lun thu c C2H4(OH)2.
D. P thy phn este trong mi trng axit l p thun nghch.
Thng k H 2007-2014
14.2. Phn ng thy phn trong mi trng kim (x phng ha)

Cu 10. (C-13) 30: Trng hp no di y to ra sn phm l ancol v mui natri ca axit
cacboxylic?
to
A. HCOOCH=CHCH3 + NaOH
t
B. CH3COOCH2CH=CH2 + NaOH
t
C. CH3COOCH=CH2 + NaOH
t
D. CH3COOC6H5 (phenyl axetat) + NaOH
Cu 11.
(A-14): Thy phn cht X bng dung dch NaOH, thu c hai cht Y v Z u c phn ng
trng bc, Z tc dng c vi Na sinh ra kh H2. Cht X l
A. HCOO CH 2CHO
B. CH3COO CH CH 2
o
C. HCOO CH CH 2
D. HCOO CH CHCH3
Cu 12. (B-14): Trng hp no sau y khng to ra CH3CHO?
A. Oxi ha CH3COOH.
B. Oxi ha khng hon ton C2H5OH bng CuO un nng.
C. Cho CH CH cng H2O (t0, xc tc HgSO4, H2SO4).
D. Thy phn CH3COOCH=CH2 bng dung dch KOH un nng.
Cu 13. (C-09) 8: Thu phn cht hu c X trong dd NaOH (d), un nng, thu c sn phm gm
2 mui v ancol etylic. Cht X l
A. CH3COOCH2CH2Cl.
B. CH3COOCH2CH3.
C. CH3COOCH(Cl)CH3.
D. ClCH2COOC2H5
Cu 14. (A-07) 55: Mt este c CTPT l C4H6O2, khi thu phn trong mi trng axit thu c
axetanehit. CTCT thu gn ca este l
A. HCOO-C(CH3)=CH2.
B. HCOO-CH=CH-CH3.
C. CH3COO-CH=CH2. D. CH2=CH-COO-CH3.
Cu 15. (A-13) 20: Cht no sau y khi un nng vi dung dch NaOH thu c sn phm c anehit?
A. CH2=CHCOOCH2CH3.
B. CH3COOC(CH3)=CH2.
C. CH3COOCH2CH=CH2.
D. CH3COOCH=CHCH3.
Cu 16. (B-07) 46: Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn
phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l
A. ru metylic.
B. etyl axetat.
C. axit fomic.
D. ru etylic.
Cu 17. (B-14): Cht X c cng thc phn t C6H8O4. Cho 1 mol X phn ng ht vi dung dch NaOH,
thu c cht Y v 2 mol cht Z. un Z vi dung dch H2SO4 c, thu c imetyl ete. Cht Y phn
ng vi dung dch H2SO4 long (d), thu c cht T. Cho T phn ng vi HBr, thu c hai sn phm
l ng phn cu to ca nhau. Pht biu no sau y ng?
A. Cht T khng c ng phn hnh hc.
B. Cht X phn ng vi H2 (Ni, t0) theo t l mol 1 : 3.
C. Cht Y c cng thc phn t C4H4O4Na2.
D. Cht Z lm mt mu nc brom.
Cu 18. (B-14): Hai este X, Y c cng cng thc phn t C8H8O2 v cha vng benzen trong phn t.
Cho 6,8 gam hn hp gm X v Y tc dng vi dung dch NaOH d, un nng, lng NaOH phn ng
ti a l 0,06 mol, thu c dung dch Z cha 4,7 gam ba mui. Khi lng mui ca axit cacboxylic
c phn t khi ln hn trong Z l
A. 0,82 gam.
B. 0,68 gam. C. 2,72 gam. D. 3,40 gam.
Cu 19. (B-12) 37: Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc dng vi
dung dch NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l
A. CH3COOCH2C6H5.
B. HCOOC6H4C2H5.
C. C6H5COOC2H5.
D. C2H5COOC6H5.
Cu 20. (A-07) 33: Mnh khng ng l:
A. CH3CH2COOCH=CH2 t/d vi dd NaOH thu c anehit v mui.
B. CH3CH2COOCH=CH2 t/d c vi dd Br2.
C. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3.
D. CH3CH2COOCH=CH2 c th trng hp to polime.
Cu 21. (B-11) 20: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat,
tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l
A. 2.
B. 4.
C. 5.
D. 3.
Thng k H 2007-2014
Cu 22. (C-12) 28: Cho cc este: etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4), phenyl
axetat (5). Dy gm cc este u phn ng c vi dung dch NaOH (un nng) sinh ra ancol l:
A. (1), (3), (4).
B. (3), (4), (5).
C. (1), (2), (3).
D. (2), (3), (5).
Cu 23. (B-10) 1: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai
ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l
A. CH3OCO-CH2-COOC2H5.
B. C2H5OCO-COOCH3.
C. CH3OCO-COOC3H7.
D. CH3OCO-CH2-CH2-COOC2H5
Cu 24. (B-10) 31: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY).
Bng mt p c th chuyn ho X thnh Y. Cht Z khng th l
A. metyl propionat.
B. metyl axetat.
C. etyl axetat.
D. vinyl axetat.
Cu 25. (A-09) 40: X phng ho mt hp cht c cng thc phn t C10H14O6 trong dd NaOH (d),
thu c glixerol v hh gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l:
B. HCOONa, CHC-COONa v CH3-CH2A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa.
COONa.
C. CH2=CH-COONa, HCOONa v CHC-COONa.
D. CH3-COONa, HCOONa v CH3-CH=CHCOONa.
Cu 26. (A-11) Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c
axit axetylsalixylic (o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton
vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l
A. 0,72.
B. 0,24.
C. 0,48.
D. 0,96.
Cu 27. (A-13) 13: Hp cht X c thnh phn gm C, H, O, cha vng benzen. Cho 6,9 gam X vo 360
ml dung dch NaOH 0,5M (d 20% so vi lng cn phn ng) n phn ng hon ton, thu c dung
dch Y. C cn Y thu c m gam cht rn khan. Mt khc, t chy hon ton 6,9 gam X cn va
7,84 lt O2 (ktc), thu c 15,4 gam CO2. Bit X c cng thc phn t trng vi cng thc n
gin nht. Gi tr ca m l
A. 12,3.
B. 11,1.
C. 11,4.
D. 13,2.
Cu 28. (C-14): Este X c t khi hi so vi He bng 21,5. Cho 17,2 gam X tc dng vi dung dch
NaOH d, thu c dung dch cha 16,4 gam mui. Cng thc ca X l
A. C2H3COOCH3
B. CH3COOC2H3
C. HCOOC3H5
D. CH3COOC2H5
Cu 29. (C-11) 5: x phng ho hon ton 52,8 gam hn hp hai este no, n chc, mch h l
ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia
phn ng trng bc. Cng thc ca hai este l
A. C2H5COOC2H5 v C3H7COOCH3.
B. C2H5COOCH3 v CH3COOC2H5.
C. HCOOC4H9 v CH3COOC3H7.
D. CH3COOC2H5 v HCOOC3H7.
Cu 30. (A-09) 11: X phng ho hon ton 1,99 gam hh hai este bng dd NaOH thu c 2,05 gam
mui ca mt axit cacboxylic v 0,94 gam hh hai ancol l ng ng k tip nhau. Cng thc ca hai este
l
A. CH3COOCH3 v CH3COOC2H5.
B. C2H5COOCH3 v C2H5COOC2H5.
C. CH3COOC2H5 v CH3COOC3H7.
D. HCOOCH3 v HCOOC2H5.
Cu 31. (A-09) 39:X phng ha hon ton 66,6 gam hh hai este HCOOC2H5 v CH3COOCH3 bng dd
NaOH, thu c hh X gm hai ancol. un nng hh X vi H2SO4 c 140 oC, sau khi p xy ra hon ton
thu c m gam nc. Gi tr ca m l
A. 4,05.
B. 8,10.
C. 18,00.
D. 16,20.
Cu 32. (C-08) 1: Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X t/d vi 300 ml dd
KOH 1M (un nng). C cn dd sau p thu c 28 gam cht rn khan. Cng thc cu to ca X l
A. CH2=CH-CH2-COO-CH3.
B. CH2=CH-COO-CH2-CH3.
C. CH3 -COO-CH=CH-CH3.
D. CH3-CH2-COO-CH=CH2.
Cu 33. (C-12) 45: Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng th tch
ca 1,6 gam kh oxi (o cng iu kin). Mt khc, thy phn hon ton 11 gam X bng dung dch
NaOH d, thu c 10,25 gam mui. Cng thc ca X l
A. C2H5COOCH3.
B. C2H5COOC2H5.
C. CH3COOC2H5.
D. HCOOC3H7.
Cu 34. (C -14): Cho 26,4 gam hn hp hai cht hu c c cng cng thc phn t C4H8O2 tc
dng vi dung dch NaOH va , thu c dung dch X cha 28,8 gam hn hp mui v m gam
ancol Y. un Y vi dung dch H2SO4 c nhit thch hp, thu c cht hu c Z, c t khi hi
so vi Y bng 0,7. Bit cc phn ng xy ra hon ton. Gi tr ca m l
A. 6,0
B. 6,4
C. 4,6
D. 9,6
Thng k H 2007-2014
Cu 35. (B-14): Thy phn hon ton 0,1 mol este X bng NaOH, thu c mt mui ca axit
cacboxylic Y v 7,6 gam ancol Z. Cht Y c phn ng trng bc, Z ha tan c Cu(OH) 2 cho dung
dch mu xanh lam. Cng thc cu to ca X l
A. HCOOCH2CH2CH2OOCH.
B. HCOOCH2CH2OOCCH3.
C. CH3COOCH2CH2OOCCH3.
D. HCOOCH2CH(CH3)OOCH.
Cu 36. (A-14): Thy phn 37 gam este cng cng thc phn t C3H6O2 bng dung dch NaOH d.
Chng ct dung dch sau phn ng thu c hn hp ancol Y v cht rn khan Z. un nng Y vi
H2SO4 c 1400C, thu c 14,3 gam hn hp cc este. Bit cc phn ng xy ra hon ton. Khi
lng mui trong Z l
A. 40,0 gam
B. 42,2 gam
C. 38,2 gam
D. 34,2 gam
Cu 37. (C-13) 17: Este X c cng thc phn t C4H8O2. Cho 2,2 gam X vo 20 gam dung dch NaOH
8%, un nng, sau khi phn ng xy ra hon ton, thu c dung dch Y. C cn Y thu c 3 gam
cht rn khan. Cng thc cu to ca X l
A. CH3COOCH2CH3.
B. HCOOCH(CH3)2.
C. HCOOCH2CH2CH3.
D. CH3CH2COOCH3
14.3. Phn ng t chy

Cu 38. (A-11) 57: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n
chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l
A. 4.
B. 6.
C. 2.
D. 5.
Cu 39. (B-11) 37: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08
gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l
A. 75%.
B. 72,08%.
C. 27,92%.
D. 25%.
Cu 40. (B-08) 4 Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2
p. Tn gi ca este l
A. metyl fomiat.
B. etyl axetat.
C. n-propyl axetat.
D. metyl axetat.
Cu 41. (A-08) 38: Este X c cc c im sau:
- t chy hon ton X to thnh CO2 v H2O c s mol bng nhau;
- Thu phn X trong mi trng axit c cht Y (tham gia p trng gng) v cht Z (c s nguyn
t cacbon bng mt na s nguyn t cacbon trong X).
Pht biu khng ng l:
A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O.
B. Cht Y tan v hn trong nc.
C. un Z vi dd H2SO4 c 170oC thu c anken.
D. Cht X thuc loi este no, n chc.
Cu 42. (B-12) 5: Thy phn este X mch h c cng thc phn t C4 H6O2 , sn phm thu
c c kh nng trng bc. S este X tha mn tnh cht trn l
A. 4.
B. 3.
C. 6.
D. 5.
Cu 43. (C-07) 19: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy
ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X t/d vi dd NaOH va n
khi p hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l
A. etyl propionat.
B. metyl propionat.
C. isopropyl axetat.
D. etyl axetat.
Cu 44. (C-09) 4: Hh Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau
trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 (ktc), thu c
5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l
A. (HCOO)2C2H4 v 6,6.
B. HCOOCH3 v 6,7.
C. CH3COOCH3 v 6,7.
D. HCOOC2H5 v 9,5.
Cu 45. (B-09) 10: Hh X gm 2 este no, n chc, mch h. t chy hon ton mt lng X cn
dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X t/d vi dd NaOH, thu c
mt mui v hai ancol l ng ng k tip. CTPT ca hai este trong X l
A. C2H4O2 v C5H10O2.
B. C2H4O2 v C3H6O2
C. C3H4O2 v C4H6O2. D. C3H6O2 v C4H8O2.
Cu 46. (B-12) 4: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt
kh O2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml
dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong
c a mol mui Y v b mol mui Z (MY < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l
A. 2 : 3.
B. 4 : 3.
C. 3 : 2.
D. 3 : 5.
Thng k H 2007-2014
Cu 47. (A-07) 36: X phng ha 8,8 gam etyl axetat bng 200 ml dd NaOH 0,2M. Sau khi p xy ra
hon ton, c cn dd thu c cht rn khan c khi lng l
A. 3,28 gam.
B. 8,56 gam.
C. 8,2 gam.
D. 10,4 gam.
Cu 48. (C-11) 11: Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol
X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol
Ca(OH)2 th vn thu c kt ta. Thu phn X bng dung dch NaOH thu c 2 cht hu c c s
nguyn t cacbon trong phn t bng nhau. Phn trm khi lng ca oxi trong X l
A. 37,21%.
B. 36,36%.
C. 43,24%.
D. 53,33%.
Cu 49. (A-11) 39: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong
phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi
dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l
A. 17,5.
B. 14,5.
C. 15,5.
D. 16,5.
Cu 50. (C-09) 2: Cho 20 gam mt este X (c phn t khi l 100 vC) t/d vi 300 ml dd NaOH 1M.
Sau p, c cn dd thu c 23,2 gam cht rn khan. Cng thc cu to ca X l
A. CH2=CHCH2COOCH3.
B. CH3COOCH=CHCH3.
C. C2H5COOCH=CH2.
D. CH2=CHCOOC2H5.
Cu 51. (A-09) 56: Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X t/d va ht vi dd
NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng
thc ca X l
A. HCOOC(CH3)=CHCH3.
B. CH3COOC(CH3)=CH2.
C. HCOOCH2CH=CHCH3.
D. HCOOCH=CHCH2CH3.
Cu 52. (B-08) 27: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X t/d
va vi 100 gam dd NaOH 8% thu c cht hu c Y v 17,8 gam hh mui. Cng thc cu to thu
gn ca X l
A. CH3OOC(CH2) 2COOC2H5.
B. CH3COO(CH2) 2COOC2H5.
C. CH3COO(CH2) 2OOCC2H5.
D. CH3OOCCH2COOC3H7.
Cu 53. (C-08) 2: X phng ho hon ton 22,2 gam hh gm hai este HCOOC2H5 v CH3COOCH3 bng
dd NaOH 1M (un nng). Th tch dd NaOH ti thiu cn dng l
A. 400 ml.
B. 300 ml.
C. 150 ml.
D. 200 ml.
Cu 54. (C-11) 8: Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch
NaOH 8%, sau khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt
ancol. Cng thc ca X l
A. CH3COOCH=CH2. B. CH3COOC2H5. C. C2H5COOCH3.
D. CH2=CHCOOCH3
Cu 55. (B-07) 24: X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2
gam este X vi dd NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l
A. HCOOCH2CH2CH3.
B. C2H5COOCH3.
C. CH3COOC2H5.
D.
HCOOCH(CH3) 2.
Cu 56. (B-13) 39: Thy phn hon ton m1 gam este X mch h bng dung dch NaOH d, thu
c m2 gam ancol Y (khng c kh nng phn ng vi Cu(OH)2) v 15 gam hn hp mui ca hai
axit cacboxylic n chc. t chy hon ton m2 gam Y bng oxi d, thu c 0,3 mol CO2 v 0,4
mol H2O. Gi tr ca m1 l
A. 14,6.
B. 11,6.
C. 10,6.
D. 16,2.
14.4. CHT BO
Cu 57.
(B-14): Axit no sau y l axit bo?
A. Axit axetic
B. Axit glutamic
C. Axit stearic
D. Axit aipic
Cu 58. (A-08) 19: Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring
bit: Na, Cu(OH)2, CH3OH, dd Br2, dd NaOH. Trong iu kin thch hp, s p xy ra l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 59. (B-11) 31: Triolein khng tc dng vi cht (hoc dung dch) no sau y?
A. H2O (xc tc H2SO4 long, un nng).
B. Cu(OH)2 ( iu kin thng).
C. Dung dch NaOH (un nng).
D. H2 (xc tc Ni, un nng).
Cu 60. (C-11) 24: Cng thc ca triolein l
A. (CH3[CH2]14COO)3C3H5.
B. (CH3[CH2]7CH=CH[CH2]5COO)3C3H5.
C. (CH3[CH2]16COO)3C3H5.
D. (CH3[CH2]7CH=CH[CH2]7COO)3C3H5.
Thng k H 2007-2014

(a) Cht bo c gi chung l triglixerit hay triaxylglixerol.
(b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c.
(c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch.
(d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5.
S pht biu ng l
A. 4.
B. 1.
C. 2.
D. 3.
A. Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni.
B. Cc cht bo thng khng tan trong nc v nh hn nc.
C. Cht bo b thy phn khi un nng trong dung dch kim.
D. Cht bo l trieste ca etylen glicol vi cc axit bo.
Cu 63. (A-07) 20: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v
hai loi axit bo. Hai loi axit bo l
B. C15H31COOH v C17H35COOH.
D. C17H33COOH v C15H31COOH
Cu 64. (B-08) 39: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn
dd sau p thu c khi lng x phng l
A. 17,80 gam.
B. 18,24 gam.
C. 16,68 gam.
D. 18,38 gam.
Cu 65. (C-07) 54: trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung
dch KOH 0,1M. Ch s axit ca mu cht bo trn l
A. 4,8.
B. 7,2.
C. 6,0.
D. 5,5.
Cu 66. (C-10)38: trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dd cha a gam
NaOH. Gi tr ca a l
A. 0,150.
B. 0,200.
C. 0,280.
D. 0,075.
Cu 67. (B-11) 26: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt
lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l
A. 31,45 gam.
B. 31 gam.
C. 32,36 gam.
D. 30 gam.
Cu 68. (A-13) 26: Cho 0,1 mol tristearin ((C17H35COO)3C3H5) tc dng hon ton vi dung dch
NaOH d, un nng, thu c m gam glixerol. Gi tr ca m l
A. 27,6.
B. 4,6.
C. 9,2.
D. 14,4.
Cu 69. (A-14): t chy hon ton 1 mol cht bo, thu c lng CO2 v H2O hn km nhau 6 mol.
Mt khc a mol cht bo trn tc dng ti a vi 600 ml dung dch Br2 1M. Gi tr ca a l
A. 0,20
B. 0,15
C. 0,30
D. 0,18
Cu 70. (C -14): t chy hon ton a gam triglixerit X cn va 3,26 mol O2, thu c 2,28 mol
CO2 v 39,6 gam H2O. Mt khc, thy phn hon ton a gam X trong dung dch NaOH, un nng,
thu c dung dch cha b gam mui. Gi tr ca b l
A. 40,40
B. 31,92
C. 36,72
D. 35,60
Cu 71. (C-13) 24: Khi x phng ha triglixerit X bng dung dch NaOH d, un nng, thu c sn
phm gm glixerol, natri oleat, natri stearat v natri panmitat. S ng phn cu to tha mn tnh cht trn
ca X l
A. 4.
B. 2.
C. 1.
D. 3.
14.7. Hn hp este vi axit, ancol

Cu 72. (C-08) 13: Mt hh X gm hai cht hu c n chc. Cho X p va vi 500 ml dd KOH 1M.
Sau p, thu c hh Y g m hai mui ca hai axit cacboxylic v mt ru (ancol). Cho ton b lng
ru thu c trn t/d vi Na (d), sinh ra 3,36 lt H2 ( ktc). Hh X gm
A. mt axit v mt este.
B. mt este v mt ru.
C. hai este. D. mt axit v mt ru.
Cu 73. (C-09) 43: Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi
dung dch cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X
tc dng ht vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht hu c l
A. mt este v mt axit.
B. hai axit.
C. hai este.
D. mt este v mt ancol.
Cu 74. (A-10) Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH
24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l
B. HCOOH v C2H5COOH.
Thng k H 2007-2014
C. HCOOH v CH3COOH.
D. CH3COOH v C2H5COOH.
Cu 75. (C-11) 7: phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y
(MX < MY) cn va 300 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton thu c 24,6
gam mui ca mt axit hu c v m gam mt ancol. t chy hon ton lng ancol trn thu c
4,48 lt CO2 (ktc) v 5,4 gam H2O. Cng thc ca Y l
A. CH3COOCH3.
B. C2H5COOC2H5.
C. CH2=CHCOOCH3.
D. CH3COOC2H5.
Cu 76. (B-09) 13: Cho hh X gm hai hp cht hu c no, n chc t/d va vi 100 ml dd
KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hh X
trn, sau hp th ht sn phm chy vo bnh ng dd Ca(OH)2 (d) th khi lng bnh tng
6,82 gam. Cng thc ca hai hp cht hu c trong X l
A. CH3COOH v CH3COOC2H5.
B. C2H5COOH v C2H5COOCH3.
C. HCOOH v HCOOC2H5.
D. HCOOH v HCOOC3H7.
Thng k H 2007-2014
15. AMIN, AMINOAXIT, PEPTIT, PROTEIN
15.1. AMIN
Cu 3. (C-12) 48: Cng thc chung ca amin no, n chc, mch h l
A. CnH2n-5N (n 6). B. CnH2n+1N (n 2). C. CnH2n-1N (n 2).
D. CnH2n+3N (n 1).
Cu 4. (C-09) 6: S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l
A. 4.
B. 2.
C. 5.
D. 3.
Cu 5. (A-12) 48: S amin bc mt c cng cng thc phn t C3H9N l
A. 3.
B. 1.
C. 2.
D. 4.
Cu 6. (A-14): C bao nhiu amin bc ba l ng phn cu to ca nhau ng vi cng thc phn t
C5H13N?
A. 3
B. 2
C. 5
D. 4
Cu 7. (C-10) 57: S amin thm bc mt ng vi cng thc phn t C7H9N l
A. 3.
B. 2
C. 5
D. 4
Cu 8. (B-13) 20: S ng phn amin bc mt, cha vng benzen, c cng cng thc phn t C7H9N
l
A. 3.
B. 2.
C. 5.
D. 4.
Cu 9. (A-11) 14: Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S
ng phn amin bc mt tha mn cc d kin trn l
A. 3.
B. 1.
C. 4.
D. 2.
Cu 10. (C-10) 22: Dd no sau y lm qu tm chuyn mu xanh?
A. Phenylamoni clorua.
B. Anilin.
C. Glyxin.
D. Etylamin
Cu 11. (A-13) 14: Dung dch no sau y lm phenolphtalein i mu?
A. axit axetic.
B. glyxin.
C. alanin.
D. metylamin.
Cu 12. (C -14): Phn trm khi lng nit trong phn t anilin bng
A. 18,67%
B. 12,96%
C. 15,05%
D. 15,73%
Cu 13. (B-08) 30: Cht p vi dd FeCl3 cho kt ta l
A. CH3NH2.
B. CH3COOCH3.
C. CH3OH.
D. CH3COOH.
Cu 14. (A-09) 18: Cho 10g amin n chc X p hon ton vi HCl (d), thu c 15g mui. S ng
phn cu to ca X l
A. 4.
B. 8.
C. 5.
D. 7.
Cu 15. (A-07) 7: Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2
(cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16)
A. C3H7N.
B. C3H9N.
C. C4H9N.
D. C2H7N.
Cu 16. (C-09) 11: Cho 2,1 gam hh X gm 2 amin no, n chc, k tip nhau trong dy ng ng p
ht vi dd HCl (d), thu c 3,925 gam hh mui. Cng thc ca 2 amin trong hh X l
A. C3H7NH2 v C4H9NH2. B. CH3NH2 v C2H5NH2.
C. CH3NH2 v (CH3)3N.
D. C2H5NH2
v C3H7NH2.
Cu 17. (B-10) 57: Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn
nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l
A. H2NCH2CH2CH2CH2NH2.
B. CH3CH2CH2NH2 .C. H2NCH2CH2NH2. D.
H2NCH2CH2CH2NH2.
Cu 18. (C-07) 37: trung ha 25 gam dd ca mt amin n chc X nng 12,4% cn dng
100ml dd HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14)
A. C3H5N.
B. C2H7N.
C. CH5N.
D. C3H7N.
Cu 19. (C-08) 6: Cho 5,9 gam amin n chc X t/d va vi dd HCl, sau khi p xy ra hon ton
thu c dd Y. Lm bay hi dd Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc
phn t ca X l
A. 5.
B. 4.
C. 2.
D. 3.
Cu 20. (B-10) 27: t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5
mol hh Y gm kh v hi. Cho 4,6 gam X t/d vi dd HCl (d), s mol HCl p l
A. 0,1.
B. 0,4.
C. 0,3.
D. 0,2.
Cu 21. (B-13) 31: Cho 0,76 gam hn hp X gm hai amin n chc, c s mol bng nhau, phn ng
hon ton vi dung dch HCl d, thu c 1,49 gam mui. Khi lng ca amin c phn t khi nh
hn trong 0,76 gam X l
A. 0,58 gam.
B. 0,31 gam.
C. 0,45 gam.
D. 0,38 gam.
Cu 22. (B-11) 9: Hn hp kh X gm O2 v O3 c t khi so vi H2 l 22. Hn hp kh Y gm
Thng k H 2007-2014
metylamin v etylamin c t khi so vi H2 l 17,833. t hon ton V1 lt Y cn va V2 lt X

(bit sn phm chy gm CO2, H2O v N2, cc cht kh o cng iu kin nhit , p sut). T l V1 :
V2 l
A. 2 : 1.
B. 1 : 2.
C. 3 : 5.
D. 5 : 3.
Cu 23. (A-12) 7: Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH
(4), NH3 (5) (C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l:
A. (3), (1), (5), (2), (4).
B. (4), (1), (5), (2), (3).
C. (4), (2), (3), (1), (5).
D. (4), (2), (5), (1), (3).
Cu 24.
(B-14) : Cho X, Y, Z, T l cc cht khc nhau trong s 4 cht: CH3NH2, NH3, C6H5OH
(phenol), C6H5NH2 (anilin) v cc tnh cht c ghi trong bng sau:
Cht
X
Y
Z
T
Nhiit si (oC)
182
184
-6,7
-33,4
pH (dung dch nng 6,48
7,82
10,81
10,12
0,001M)
Nhn xt no sau y ng?
A. Y l C6H5OH.
B. Z l CH3NH2
C. T l C6H5NH2
D. X l NH3
Cu 25. (C-13) 42: Dy gm cc cht c sp xp theo th t tng dn lc baz t tri sang phi l:
A. Phenylamin, amoniac, etylamin.
B. Etylamin, amoniac, phenylamin.
C. Etylamin, phenylamin, amoniac.
D. Phenylamin, etylamin, amoniac.
Cu 26. (B-12) 28: t chy hon ton 50 ml hn hp kh X gm trimetylamin v hai hirocacbon
ng ng k tip bng mt lng oxi va , thu c 375 ml hn hp Y gm kh v hi. Dn ton b
Y i qua dung dch H2SO4 c (d), th tch kh cn li l 175 ml. Cc th tch kh v hi o cng
iu kin. Hai hirocacbon l
A. C2H4 v C3H6.
B. C3H6 v C4H8.
C. C2H6 v C3H8.
D. C3H8 v C4H10.
Cu 27. (B-12) 38: Alanin c cng thc l
A. C6H5-NH2.
B. CH3-CH(NH2)-COOH.
C. H2N-CH2-COOH.
D. H2N-CH2-CH2-COOH.
Cu 28. (C-12) 10: Cho 20 gam hn hp gm hai amin no, n chc, mch h tc dng va vi
V ml dung dch HCl 1M, thu c dung dch cha 31,68 gam hn hp mui. Gi tr ca V l
A. 320.
B. 50.
C. 200.
D. 100.
Cu 29. (A-12)Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k
tip, bit
(MX < MY). t chy hon ton mt lng M cn dng 4,536 lt O2 (ktc) thu c H2O, N2 v 2,24 lt
CO2 (ktc). Cht Y l
A. etylamin.
B. propylamin.
C. butylamin.
D. etylmetylamin.
Cu 30. (C-13) 18: t chy hon ton mt amin n chc X trong kh oxi d, thu c kh N2;
13,44 lt kh CO2 (ktc) v 18,9 gam H2O. S cng thc cu to ca X l
A. 4.
B. 3.
C. 2.
D. 1.
15.2. AMINOAXIT
Cu 31. (B-13) 27: Amino axit X c phn t khi bng 75. Tn ca X l
A. alanin.
B. glyxin.
C. valin.
D. lysin.
Cu 32. (C-13) 19: Phn trm khi lng ca nguyn t nit trong alanin l
A. 15,73%.
B. 18,67%.
C. 15,05%.
D. 17,98%.
+
A. Trong dd, H2N-CH2-COOH cn tn ti dng ion lng cc H3N -CH2-COO .
B. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl.
C. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt.
D. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin).
Cu 34. (A-11) 46: Dung dch no sau y lm qu tm i thnh mu xanh?
A. Dung dch glyxin.
B. Dung dch alanin.
C. Dung dch lysin.
D. Dung dch valin.
Thng k H 2007-2014
Cu 35. (C -14): Dung dch cht no sau y lm xanh qu tm?

A. Glyxin
B. Phenylamin
C. Metylamin
D. Alanin
Cu 36. (A-08) 9: C cc dd ring bit sau: C6H5NH3Cl (phenylamoni clorua), H2NCH2CH2(NH2)COOH,
ClH3N-CH2COOH, HOOC-CH2CH2CH(NH2)-COOH, H2N-CH2COONa. S lng cc dd c pH < 7 l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 37. (B-11) 23: Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2)
CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l:
A. (2), (1), (3).
B. (3), (1), (2).
C. (1), (2), (3).
D. (2), (3), (1).
Cu 38. (A-13) 45: Trong cc dung dch: CH3CH2NH2, H2NCH2COOH, H2NCH2CH(NH2)
COOH, HOOCCH2CH2CH(NH2)COOH, s dung dch lm xanh qu tm l
A. 4.
B. 3.
C. 1.
D. 2.
Cu 39. (B-12) 38: Alanin c cng thc l
A. C6H5-NH2.
B. CH3-CH(NH2)-COOH.
C. H2N-CH2-COOH.
Cu 40. (C-11) 21: Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn
ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l
A. glyxin.
B. valin.
C. alanin.
D. phenylalanin.
Cu 41. (B-11) 48: Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon),
phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH,
ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho
thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c
12,96 gam Ag kt ta. Gi tr ca m l
A. 3,56.
B. 5,34.
C. 2,67.
D. 4,45.
Cu 42. (A-07) 12: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X t/d vi axit HCl (d), thu
c 13,95 gam mui khan. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5)
A. CH3CH2CH(NH2)COOH.
B. H2NCH2CH2COOH. C. CH3CH(NH2)COOH. D. H2NCH2COOH.
Cu 43. (A-11) 11: S ng phn amino axit c cng thc phn t C3H7O2N l
A. 1.
B. 2.
C. 3.
D. 4.
Cu 44. (C-08) 20: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0
gam X t/d va vi dd NaOH, c cn dd sau p thu c 19,4 gam mui khan. Cng thc ca X l
A. H2NC3H6COOH.
B. H2NCH2COOH.
C. H2NC2H4COOH.
D. H2NC4H8COOH.
Cu 45. (B-14): Amino axit X trong phn t ch cha hai loi nhm chc. Cho 0,1 mol X tc dng va
vi 0,2 mol NaOH, thu c 17,7 gam mui. S nguyn t hiro trong phn t X l
A. 9.
B. 6.
C. 7.
D. 8.
Cu 46. (B-09) 14: Cho 0,02 mol amino axit X t/d va vi 200 ml dd HCl 0,1M thu c 3,67 gam mui
khan. Mt khc 0,02 mol X t/d va vi 40 gam dd NaOH 4%. Cng thc ca X l
A. H2NC2H3(COOH)2.
B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH.
Cu 47. (A-14): Cho 0,02 mol -amino axit X tc dng va vi dung dch cha 0,04 mol NaOH.
Mt khc 0,02 mol X tc dng va vi dung dch cha 0,02 mol HCl, thu c 3,67 gam mui.
Cng thc ca X l
A. CH3CH NH 2 COOH
B. HOOC CH 2CH NH 2 COOH
C. HOOC CH 2CH 2CH NH 2 COOH
D. H 2 N CH 2CH NH 2 COOH
Cu 48. (C-13) 40: Cho 100 ml dung dch amino axit X nng 0,2M phn ng va vi 80 ml
dung dch NaOH 0,25M, thu c dung dch Y. Bit Y phn ng ti a vi 120 ml dung dch HCl
0,5M, thu c dung dch cha 4,71 gam hn hp mui. Cng thc ca X l
A. H2NC3H5(COOH)2.
B. (H2N)2C2H3COOH.
C. (H2N)2C3H5COOH.
D. H2NC3H6COOH.
Cu 49. (B-10) Hh X gm alanin v axit glutamic. Cho m gam X t/d hon ton vi dd NaOH (d), thu c
dd Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X t/d hon ton vi dd HCl, thu c dd Z cha
(m+36,5) gam mui. Gi tr ca m l
A. 112,2.
B. 165,6.
C. 123,8.
D. 171,0.
Cu 50. (A-10) 29: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dd HCl 2M, thu c dd
X. Cho NaOH d vo dd X. Sau khi cc p xy ra hon ton, s mol NaOH p l
A. 0,70.
B. 0,50.
C. 0,65.
D. 0,55.
(B-13)
41:
Amino
axit
X
c
cng
thc
H
NC
H
(COOH)
.
Cho
0,1
mol
X vo 0,2 lt dung dch H2SO4
Cu 51.
2
x y
2
Thng k H 2007-2014
0,5M, thu c dung dch Y. Cho Y phn ng va vi dung dch gm NaOH 1M v KOH 3M, thu
c dung dch cha 36,7 gam mui. Phn trm khi lng ca nit trong X l
A. 10,526%.
B. 10,687%.
C. 11,966%.
D. 9,524%.
Cu 52. (A-13) 25: Cho 100 ml dung dch amino axit X nng 0,4M tc dng va vi 80 ml
dung dch NaOH 0,5M, thu c dung dch cha 5 gam mui. Cng thc ca X l
A. NH2C3H5(COOH)2.
B. (NH2)2C4H7COOH.
C. NH2C3H6COOH.
D. NH2C2H4COOH.
Cu 53. (C-12) 60: Cho 14,55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl d,
thu c dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui khan?
A. 16,73 gam.
B. 8,78 gam.
C. 20,03 gam.
D. 25,50 gam.
Cu 54. (A-10) 41: Hh X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng
p ti a vi 2 mol HCl hoc 2 mol NaOH. t chy h/ton X thu c 6 mol CO2, x mol H2O v y mol
N2. Cc gi tr x, y tng ng l
A. 7 v 1,0.
B. 8 v 1,5.
C. 8 v 1,0.
D. 7 v 1,5.
Cu 55. (A-09) 14: Cho 1 mol amino axit X p vi dd HCl (d), thu c m1 gam mui Y. Cng 1 mol
amino axit X p vi dd NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l
A. C5H9O4N.
B. C4H10O2N2.
C. C5H11O2N.
D. C4H8O4N2.
Cu 56. (A-12) 10: Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH2 trong phn
t), trong t l mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch
HCl 1M. Mt khc, t chy hon ton 3,83 gam hn hp X cn 3,192 lt O2 (ktc). Dn ton b
sn phm chy (CO2, H2O v N2) vo nc vi trong d th khi lng kt ta thu c l
A. 13 gam.
B. 20 gam.
C. 15 gam.
D. 10 gam.
Cu 57. (B-12) 13: Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch
KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c
dung dch cha m gam mui. Gi tr ca m l
A. 44,65.
B. 50,65.
C. 22,35.
D. 33,50.
A. Tt c cc peptit u c phn ng mu biure.
B. H2N-CH2-CH2-CO-NH-CH2-COOH l mt ipeptit.
C. Mui phenylamoni clorua khng tan trong nc.
D. iu kin thng, metylamin v imetylamin l nhng cht kh c mi khai.
Cu 59. (A-12) 50: Dung dch cht no sau y lm qu tm chuyn thnh mu hng?
A. Axit aminoaxetic.
B. Axit -aminopropionic.
C. Axit -aminoglutaric.
D. Axit ,-iaminocaproic.
Cu 60. (C-13) 51: Cho X l axit cacboxylic, Y l amino axit (phn t c mt nhm NH2). t chy
hon ton 0,5 mol hn hp gm X v Y, thu c kh N2; 15,68 lt kh CO2 (ktc) v 14,4 gam H2O.
Mt khc, 0,35 mol hn hp trn phn ng va vi dung dch cha m gam HCl. Gi tr ca m l
A. 4,38.
B. 5,11.
C. 6,39.
D. 10,22.
Cu 61. (C-12) 38: S nhm amino v s nhm cacboxyl c trong mt phn t axit glutamic tng
ng l
A. 1 v 2.
B. 1 v 1.
C. 2 v 1.
D. 2 v 2.
Cu 62. (C-12) 47: Cho cc cht hu c: CH3CH(CH3)NH2 (X) v CH3CH(NH2)COOH (Y). Tn thay
th ca X v Y ln lt l
A. propan1amin v axit 2aminopropanoic.
B. propan1amin v axit aminoetanoic.
C. propan2amin v axit aminoetanoic.
D. propan2amin v axit 2aminopropanoic.
A. Axit glutamic l thnh phn chnh ca bt ngt.
B. Amino axit thuc loi hp cht hu c tp chc.
C. Cc amino axit thin nhin hu ht l cc -amino axit.
D. nhit thng, cc amino axit u l nhng cht lng.
Thng k H 2007-2014
15.3. PEPTIT, protein

Cu 64. (C-14): S lin kt peptit c trong mt phn t Ala-Gly-Val-Gly-Ala l
A. 2
B. 4
C. 5
D. 3
Cu 65. (A-09) 20: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l
A. dd NaOH.
B. dd NaCl.
C. Cu(OH)2 trong mi trng kim.
D. dd HCl.
Cu 66. (B-09) 18: S ipeptit ti a c th to ra t mt hh gm alanin v glyxin l
A. 3.
B. 1.
C. 2.
D. 4.
A. Anilin tc dng vi nc brom to thnh kt ta trng
B. Dung dch lysin lm xanh qu tm
C. Dung dch glyxin khng lm i mu qu tm
D. Cho Cu(OH)2 vo dung dch lng trng trng thy xut hin mu vng
Cu 68. (A-14): Cho cc cht : axit glutamic, saccaroz, metylamoni clorua, vinyl axetat, phenol,
glixerol, Gly-Gly. S cht tc dng vi dung dch NaOH long, nng l
A. 3
B. 4
C. 6
D. 5
Cu 69. (A-10) 25: Pht biu ng l:
A. Enzim amilaza xc tc cho p thy phn xenluloz thnh mantoz.
B. Khi thy phn n cng cc protein n gin s cho hh cc -aminoaxit.
C. Khi cho dd lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m.
D. Axit nucleic l polieste ca axit photphoric v glucoz.
Cu 70. (B-07) 16: Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l
A. protit lun cha chc hiroxyl.
B. protit lun cha nit.
C. protit lun l cht hu c no.
D. protit c khi lng phn t ln hn.
Cu 71. C-11) 9: Pht biu no sau y ng?
A. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit.
B. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH)2 cho hp cht mu tm.
C. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit.
D. Amino axit l hp cht c tnh lng tnh.
Cu 72. (B-08)4: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dd HCl (d),
sau khi cc p kt thc thu c sn phm l:
A. H2N-CH2-COOH, H2N-CH2-CH2-COOH.
C. H2N-CH2-COOH, H2N-CH(CH3)-COOH.
+
+
+
+
B.
H3N -CH2-COOHCl ,
H3N -CH2-CH2D.
H3N -CH2-COOHCl ,
H3N CH(CH3)COOHCl
COOHCl
Cu 73. (B-10)9: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch
h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng
khi lng CO2 v H2O bng 54,9g. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc
vi trong d, to ra m gam kt ta. Gi tr ca m l
A. 120.
B. 60.
C. 30.
D. 45.
Cu 74. (A-10) 40: C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu
c 3 aminoaxit: glyxin, alanin v phenylalanin?
A. 6.
B. 9.
C. 4.
D. 3.
Cu 75.
(B-14): C bao nhiu tripeptit (mch h) khi thy phn hon ton u thu c sn phm
gm alanin v glyxin?
A. 8.
B. 5.
C. 7.
D. 6.
Cu 76. (C-10) 45: Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti
a bao nhiu ipeptit khc nhau?
A. 1.
B. 4.
C. 2.
D. 3
Cu 77. (C-09) 50: Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X
bng 100.000 vC th s mt xch alanin c trong phn t X l
A. 453.
B. 382.
C. 328.
D. 479.
Cu 78. (A-11) 20: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp
gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l
A. 81,54.
B. 66,44.
C. 111,74.
D. 90,6.
Cu 79. (A-13) 21: Cho X l hexapeptit AlaGlyAlaValGlyVal v Y l tetrapeptit GlyAlaGly
Glu. Thy phn hon ton m gam hn hp gm X v Y thu c 4 amino axit, trong c 30 gam
glyxin v 28,48 gam alanin. Gi tr ca m l
A. 77,6.
B. 73,4.
C. 83,2.
D. 87,4.
Cu 80. (B-10) 48: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol
Thng k H 2007-2014
alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c
ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l
A. Gly-Phe-Gly-Ala-Val.
B. Gly-Ala-Val-Val-Phe.
C. Gly-Ala-Val-Phe-Gly.
D. Val-Phe-Gly-Ala-Gly.
Cu 81. (A-11) 18: Khi ni v peptit v protein, pht biu no sau y l sai?
A. Protein c phn ng mu biure vi Cu(OH)2 .
B. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit.
C. Thy phn hon ton protein n gin thu c cc -amino axit.
D.Tt c cc protein u tan trong nc to thnh dung dch keo
Cu 82. (A-11): Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X
gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t).
Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui
khan thu c l
A. 8,15 gam.
B. 7,09 gam.
C. 7,82 gam.
D. 16,30 gam.
Cu 83. (B-12) 10: un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit
mch h Y vi 600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch
thu c 72,48 gam mui khan ca cc amino axit u c mt nhm COOH v mt nhm NH2
trong phn t. Gi tr ca m l
A. 51,72.
B. 54,30.
C. 66,00.
D. 44,48.
Cu 84. (B-11) 57: Pht biu khng ng l:

A. ipeptit glyxylalanin (mch h) c 2 lin kt peptit.
B. Etylamin tc dng vi axit nitr nhit thng to ra etanol.
C. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu.
D. Metylamin tan trong nc cho dung dch c mi trng baz.
Cu 85. (A-14): Thy phn hon ton 4,34 gam tripeptit mch h X (c to nn t hai -amino axit
c cng thc dng H2NCx H yCOOH ) bng dung dch NaOH d, thu c 6,38 gam mui. Mt khc
thy phn hon ton 4,34 gam X bng dung dch HCl d, thu c m gam mui. Gi tr ca m l
A. 6,53
B. 8,25
C. 5,06
D. 7,25
Cu 86. (B-13) 9: Tripeptit X v tetrapeptit Y u mch h. Khi thy phn hon ton hn hp gm X
v Y ch to ra mt amino axit duy nht c cng thc H2NCnH2nCOOH. t chy 0,05 mol Y trong oxi
d, thu c N2 v 36,3 gam hn hp gm CO2, H2O. t chy 0,01 mol X trong oxi d, cho sn phm
chy vo dung dch Ba(OH)2 d, thu c m gam kt ta. Bit cc phn ng u xy ra hon ton.
Gi tr ca m l
A. 11,82.
B. 17,73.
C. 23,64.
D. 29,55.
Cu 87. (C-12) 13: Pht biu no sau y l sai?
A. Protein n gin c to thnh t cc gc -amino axit.
B. Tt c cc peptit u c kh nng tham gia phn ng thy phn.
C. Trong phn t ipeptit mch h c hai lin kt peptit.
D. Tripeptit GlyAlaGly c phn ng mu biure vi Cu(OH)2.
Cu 88. (C-12) 33: Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch KOH
va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l
A. 1,46.
B. 1,36.
C. 1,64.
D. 1,22.
Cu 89. (B-14): Hn hp X gm ba peptit u mch h c t l mol tng ng l 1 : 1 : 3. Thy phn
hon ton m gam X, thu c hn hp sn phm gm 14,24 gam alanin v 8,19 gam valin. Bit tng s
lin kt peptit trong phn t ca ba peptit trong X nh hn 13. Gi tr ca m l
A. 18,83
B. 18,29
C. 19,19
D. 18,47
Cu 90. (A-13) 58: Peptit X b thy phn theo phng trnh phn ng X + 2H2O 2Y + Z (trong Y
v Z l cc amino axit). Thy phn hon ton 4,06 gam X thu c m gam Z. t chy hon ton m gam
Z cn va 1,68 lt kh O2 (ktc), thu c 2,64 gam CO2; 1,26 gam H2O v 224 ml kh N2
(ktc). Bit Z c cng thc phn t trng vi cng thc n gin nht. Tn gi ca Y l
A. glyxin.
B. alanin.
C. axit glutamic.
D. lysin.
Thng k H 2007-2014
15.5. CC DNG HP CHT KHC CHA NIT

Cu 91. (B-08) 43: Cho cht hu c X c cng thc phn t C2H8O3N2 t/d vi dd NaOH, thu c
cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l
A. 85.
B. 68.
C. 45.
D. 46.
Cu 92. (A-07) 23: Cho hh X gm hai cht hu c c cng cng thc phn t C2H7NO2 t/d va
vi dd NaOH v un nng, thu c dd Y v 4,48 lt hh Z ( ktc) gm hai kh (u lm xanh giy
qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dd Y thu c khi lng mui khan l (cho
H = 1, C = 12, N = 14, O = 16, Na = 23)
A. 16,5 gam.
B. 15,7 gam.
C. 14,3 gam.
D. 8,9 gam.
Cu 93. (B-08) 20: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N p vi 100
ml dd NaOH 1,5M. Sau khi p xy ra hon ton, c cn dd thu c 11,7 gam cht rn. Cng thc cu
to thu gn ca X l
A. HCOOH3NCH=CH2.
B. H2NCH2CH2COOH.
C. CH2=CHCOONH4.
D.
H2NCH2COOCH3.
Cu 94. (A-09) 48: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X p va
vi dd NaOH sinh ra mt cht kh Y v dd Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn
mu xanh. Dd Z c kh nng lm mt mu nc brom. C cn dd Z thu c m gam mui khan. Gi tr
ca m l
A. 10,8.
B. 9,4.
C. 8,2.
D. 9,6.
Cu 95. (C-09) 55: Cho 1,82 gam hp cht hu c n chc, mch h X c CTPT C3H9O2N tc dng
va vi dd NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan.
CTCT thu gn ca X l
A. HCOONH3CH2CH3.
B. CH3COONH3CH3.
C. CH3CH2COONH4.
D. HCOONH2(CH3)2.
Cu 96. (B-10) 6: Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn
iu kin thng. Cht X p vi dd NaOH, gii phng kh. Cht Y c p trng ngng. Cc cht X v Y ln
lt l
A.vinylamoni fomat v amoni acrylat.
B. amoni acrylat v axit 2-aminopropionic.
C. axit 2-aminopropionic v amoni acrylat.
D. axit 2-aminopropionic v axit 3aminopropionic.
Cu 97. (A-07) 48: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2
(cc kh o ktc) v 3,15 gam H2O. Khi X t/d vi dd NaOH thu c sn phm c mui H2N-CH2COONa. CTCT thu gn ca X l
A. H2N-CH2-COO-C3H7.
B. H2N-CH2-COO-CH3.
C. H2N-CH2-COO-C2H5.
Cu 98. (C-09) 18: Cht X c cng thc phn t C3H7O2N v lm mt mu dd brom. Tn gi ca X l
A. metyl aminoaxetat. B. axit -aminopropionic.
C. axit -aminopropionic. D. amoni acrylat.
Cu 99. (B-09) 15: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi p
vi dd NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc
cht Z v T ln lt l
A. CH3OH v NH3.
B. CH3OH v CH3NH2.
C. CH3NH2 v NH3.
D. C2H5OH
v N2.
Cu 100. (B-09) 41: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n
chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X p ht vi 300 ml dd
NaOH 1M, thu c dd Y. C cn Y thu c m gam cht rn. Gi tr m l
A. 27,75.
B. 24,25.
C. 26,25.
D. 29,75.
Cu 101. (B-12) 47: Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc
phn t
C3H9O2N (sn phm duy nht). S cp cht X v Y tha mn iu kin trn l
A. 3.
B. 2.
C. 4.
D. 1.
Cu 102. (B-14): Hn hp X gm cht Y (C2H8N2O4) v cht Z (C4H8N2O3); trong , Y l mui ca
axit a chc, Z l ipeptit mch h. Cho 25,6 gam X tc dng vi dung dch NaOH d, un nng, thu
c 0,2 mol kh. Mt khc 25,6 gam X tc dng vi dung dch HCl d, thu c m gam cht hu c.
Gi tr ca m l
A. 20,15.
B. 31,30.
C. 23,80.
D. 16,95.
Thng k H 2007-2014
16. CACBOHIRAT
16.1. L THUYT
Cu 3. (A-09) 46: Cacbohirat nht thit phi cha nhm chc ca

A. ancol.
B. xeton.
C. amin.
D. anehit.
Cu 4. (A-08) 16: Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l
A. saccaroz.
B. tinh bt.
C. mantoz.
D. xenluloz.
Cu 5. (B-14) : Glucoz v fructoz u
A. c cng thc phn t C6H10O5.
B. c phn ng trng bc.
C. thuc loi isaccarit.
D. c nhm CH=O trong phn t.
Cu 6. (C-08) 22: Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, mantoz. S cht trong
dy tham gia p trng gng l
A. 3.
B. 4.
C. 2.
D. 5.
Cu 7. (A-09) 55: Dy gm cc dd u tham gia p trng bc l:
A. Glucoz, mantoz, axit fomic, anehit axetic.
B. Fructoz, mantoz, glixerol, anehit axetic.
C. Glucoz, glixerol, mantoz, axit fomic.
D. Glucoz, fructoz, mantoz, saccaroz.
Cu 8. (A-08) 37: Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia p
A. ho tan Cu(OH) 2.
B. trng ngng.
C. trng gng.
D. thy phn.
Cu 9. (B-07) 42: Pht biu khng ng l
A. Dd fructoz ho tan c Cu(OH) 2.
B. Thy phn (xc tc H+, to) saccaroz cng nh mantoz u cho cng mt monosaccarit.
C. Sn phm thy phn xenluloz (xc tc H+, to) c th tham gia p trng gng.
D. Dd mantoz t/d vi Cu(OH) 2 khi un nng cho kt ta Cu2O.
A. Saccaroz lm mt mu nc brom.
B. Xenluloz c cu trc mch phn nhnh.
C. Amilopectin c cu trc mch phn nhnh. D. Glucoz b kh bi dd AgNO3 trong NH3.
Cu 11. (A-07) 30: chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho
dd glucoz p vi
B. AgNO3 (hoc Ag2O) trong dd NH3, un nng.
A. Cu(OH)2 trong NaOH, un nng.
C. Cu(OH) 2 nhit thng.
D. kim loi Na.
A. Glucoz t/d c vi nc brom.
B. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH.
C. Glucoz tn ti dng mch h v dng mch vng.
D. dng mch h, glucoz c 5 nhm OH k nhau.
Cu 13. (A-14): Cht tc dng vi H2 to thnh sobitol l
A. saccaroz
B. glucoz
C. xenluloz
D. tinh bt
Cu 14. (A-10) 19: Mt phn t saccaroz c
A. mt gc -glucoz v mt gc -fructoz.
B. mt gc -glucoz v mt gc -fructoz.
C. hai gc -glucoz.
D. mt gc -glucoz v mt gc -fructoz.
Cu 15. (B-10) 60: Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ho tan
Cu(OH)2 nhit thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l
A. xenluloz.
B. mantoz.
C. glucoz.
D. saccaroz.
Cu 16. (C-11)C mt s nhn xt v cacbohirat nh sau:
(1) Saccaroz, tinh bt v xenluloz u c th b thu phn.
(2) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH)2 v c kh nng tham gia
phn ng trng bc.
(3) Tinh bt v xenluloz l ng phn cu to ca nhau.
(4) Phn t xenluloz c cu to bi nhiu gc -glucoz.
(5) Thu phn tinh bt trong mi trng axit sinh ra fructoz
Trong cc nhn xt trn, s nhn xt ng l
A. 2.
B. 4.
C. 3.
D. 5.
Cu 17. (B-11) 12: Cho cc pht biu sau v cacbohirat:
(a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc.
(b) Tinh bt v xenluloz u l polisaccarit.
(c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam.
(d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch
thu c mt loi monosaccarit duy nht.
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag.
Thng k H 2007-2014
(g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.

S pht biu ng l
A. 5.
B. 6.
C. 4.
D. 3.
(a) C th dng nc brom phn bit glucoz v fructoz.
(b) Trong mi trng axit, glucoz v fructoz c th chuyn ho ln nhau.
(c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO3 trong NH3.
(d) Trong dung dch, glucoz v fructoz u ho tan Cu(OH)2 nhit thng cho dung
dch mu xanh lam.
(e) Trong dung dch, fructoz tn ti ch yu dng mch h.
(g) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ).
S pht biu ng l
A. 4.
B. 5.
C. 3.
D. 2.
Cu 19. (C-12) 6: Cho cc pht biu sau:

(1) Fructoz v glucoz u c kh nng tham gia phn ng trng bc;
(2) Saccaroz v tinh bt u khng b thy phn khi c axit H2SO4 (long) lm xc tc;
(3) Tinh bt c to thnh trong cy xanh nh qu trnh quang hp;
(4) Xenluloz v saccaroz u thuc loi isaccarit.
Pht biu ng l
A. (1) v (2).
B. (3) v (4).
C. (2) v (4).
D. (1) v (3).
Cu 20. (B-12) 6: Th nghim no sau y chng t trong phn t glucoz c 5 nhm hiroxyl?
A. Kh hon ton glucoz thnh hexan.
B. Cho glucoz tc dng vi Cu(OH)2.
C. Tin hnh phn ng to este ca glucoz vi anhirit axetic.
D. Thc hin phn ng trng bc.
Cu 21. (A-12) 55: Cho cc pht biu sau v cacbohirat:
(a) Tt c cc cacbohirat u c phn ng thy phn.
(b) Thy phn hon ton tinh bt thu c glucoz.
(c) Glucoz, fructoz v mantoz u c phn ng trng bc.
(d) Glucoz lm mt mu nc brom.
S pht biu ng l
A. 1.
B. 2.
C. 3.
D. 4.
(a) t chy hon ton este no, n chc, mch h lun thu c s mol CO2 bng s mol H2O.
(b) Trong hp cht hu c nht thit phi c cacbon v hiro.
(c) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn t hn
km nhau mt hay nhiu nhm CH2 l ng ng ca nhau.
(d) Dung dch glucoz b kh bi AgNO3 trong NH3 to ra Ag.
(e) Saccaroz ch c cu to mch vng.
S pht biu ng l
A. 5.
B. 3.
C. 4.
D. 2.
Cu 23. (A-13) 41: Dy cc cht u c kh nng tham gia phn ng thy phn trong dung dch
H2SO4 un nng l:
A. glucoz, tinh bt v xenluloz.
B. glucoz, saccaroz v fructoz.
C. fructoz, saccaroz v tinh bt.
D. saccaroz, tinh bt v xenluloz.
(a) Glucoz c kh nng tham gia phn ng trng bc.
(b) S chuyn ha tinh bt trong c th ngi c sinh ra mantoz.
(c) Mantoz c kh nng tham gia phn ng trng bc.
(d) Saccaroz c cu to t hai gc -glucoz v -fructoz.
A. 1.
B. 2.
C. 4.
D. 3.
Cu 25. (B-13) 30: Cacbohirat no sau y thuc loi isaccarit?
Thng k H 2007-2014
A. Amiloz.
B. Saccaroz.
C. Glucoz.
D. Xenluloz.
(a) Hiro ha hon ton glucoz to ra axit gluconic.
(b) iu kin thng, glucoz v saccaroz u l nhng cht rn, d tan trong nc.
(c) Xenluloz trinitrat l nguyn liu sn xut t nhn to v ch to thuc sng khng khi.
(d) Amilopectin trong tinh bt ch c cc lin kt -1,4-glicozit.
(e) Sacaroz b ha en trong H2SO4 c.
(f) Trong cng nghip dc phm, saccaroz c dng pha ch thuc. Trong cc pht biu
trn, s pht biu ng l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 27. (B-13) 56: Cht no di y khi cho vo dung dch AgNO3 trong NH3 d, un nng,
khng xy ra phn ng trng bc?
A. Mantoz.
B. Fructoz.
C. Saccaroz.
D. Glucoz.
Cu 28. (C-13) 13: Dy cc cht no di y u phn ng c vi Cu(OH)2 iu kin thng?
A. Etylen glicol, glixerol v ancol etylic.
B. Glucoz, glixerol v saccaroz.
C. Glucoz, glixerol v metyl axetat.
D. Glixerol, glucoz v etyl axetat.
A. Hiro ha hon ton glucoz (xc tc Ni, un nng) to ra sobitol.
B. Xenluloz tan tt trong nc v etanol.
C. Thy phn hon ton tinh bt trong dung dch H2SO4, un nng, to ra fructoz.
D. Saccaroz c kh nng tham gia phn ng trng bc.
16.2. S phn ng
Cu 30.
(C-09) 46: Cho cc chuyn ho sau:
X + H2O
Y + H2
xt ,t
Y
Ni ,t o
Sobitol
o
t
Y + 2AgNO3 + 3NH3 + H2O
Amoni gluconat + 2Ag + 2NH4NO3
xt
Y
E+Z
a's'
Z + H2O
X+G
chat diepluc
o
X, Y v Z ln lt l:
A. xenluloz, fructoz v kh cacbonic.
B. tinh bt, glucoz v ancol etylic.
C. xenluloz, glucoz v kh cacbon oxit.

D. tinh bt, glucoz v kh cacbonic.
Cu 31. (A-12) 30: Cho s phn ng:

xt ,t o
(a) X + H2O
Y
to
(b) Y + AgNO3 + NH3 + H2O
Amoni gluconat + Ag + NH4NO3
xt
E+Z
(c) Y
a's'
(d) Z + H2O
X+G
chat diepluc
X, Y, Z ln lt l:
A. Xenluloz, fructoz, cacbon ioxit.
C. Tinh bt, glucoz, etanol.
B. Xenluloz, saccaroz, cacbon ioxit.

D. Tinh bt, glucoz, cacbon ioxit.
16.3. PHN NG thy phn, TRNG BC

Cu 32. (C -14): Cho hn hp gm 27 gam glucoz v 9 gam fructoz phn ng hon ton vi lng
d dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr ca m l
A. 32,4
B. 16,2
C. 21,6
D. 43,2
Cu 33. (C-07) 20: Cho 50ml dd glucoz cha r nng t/d vi mt lng d AgNO3 (hoc Ag2O)
trong dd NH3 thu c 2,16 gam bc kt ta. Nng mol (hoc mol/l) ca dd glucoz dng l
A. 0,20M.
B. 0,10M.
C. 0,01M.
D. 0,02M.
Cu 34. (C-10) 9: Thu phn hon ton 3,42 gam saccaroz trong mi trng axit, thu c dd X.
Cho ton b dd X p ht vi lng d dd AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca
Thng k H 2007-2014
m l
A. 21,60.
B. 2,16.
C. 4,32.
D. 43,20.
Cu 35. (B-11) 59: Thu phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian
thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc
dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l
A. 0,090 mol.
B. 0,12 mol.
C. 0,095 mol.
D. 0,06 mol.
Cu 36. (C-10) 25: Thu phn hon ton tinh bt trong dd axit v c long, thu c cht hu c X.
Cho X p vi kh H2 (xc tc Ni, to), thu c cht hu c Y. Cc cht X, Y ln lt l:
A. glucoz, sobitol. B. glucoz, saccaroz.
C. glucoz, etanol.
D. glucoz, fructoz.
Cu 37. (A-08) 53: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l
A. 2,25 gam.
B. 1,80 gam.
C. 1,82 gam.
D. 1,44 gam.
Cu 38. (B-12) 51: Thy phn hn hp gm 0,01 mol saccaroz v 0,02 mol mantoz trong
mi trng axit, vi hiu sut u l 60% theo mi cht, thu c dung dch X. Trung ha
dung dch X, thu c dung dch Y, sau cho ton b Y tc dng vi lng d dung dch
AgNO3 trong NH3, thu c m gam Ag. Gi tr ca m l
A. 6,480.
B. 9,504.
C. 8,208.
D. 7,776.
16.4. Phn ng ln men tinh bt

Cu 39. (A-07) 41: Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b
lng CO2 sinh ra c hp th hon ton vo dd Ca(OH)2, thu c 550g kt ta v dd X. un k dd X thu
thm c 100g kt ta. Gi tr ca m l:
A. 650.
B. 550.
C. 810.
D. 750.
Cu 40. (A-09) 2Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo
dd nc vi trong, thu c 10g kt ta. Khi lng dd sau p gim 3,4g so vi khi lng dd nc
vi trong ban u. Gi tr ca m l
A. 20,0.
B. 30,0.
C. 13,5.
D. 15,0.
Cu 41. (C-11) 32: Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu
sut qu trnh ln men to thnh ancol etylic l
A. 54%.
B. 40%.
C. 80%.
D. 60%.
Cu 42. (A-11) 48: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut
ton b qu trnh l 90%. Hp th ton b lng CO2 sinh ra khi ln men m gam tinh bt vo nc
vi trong, thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng
nc vi trong ban u l 132 gam. Gi tr ca m l
A. 486.
B. 297.
C. 405.
D. 324.
Cu 43. (B-08) 10: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt
ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic
nguyn cht l 0,8 g/ml)
A. 5,4 kg.
B. 5,0 kg.
C. 6,0 kg.
D. 4,5 kg.
Cu 44. (C-09) 48: Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong
qu trnh ny c hp th ht vo dung dch Ca(OH)2 (d) to ra 40g kt ta. Nu hiu sut ca qu trnh
ln men l 75% th gi tr ca m l
A. 60.
B. 58
C. 30
D. 48.
Cu 45. (A-10) 44: T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic
(hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hh X.
trung ho hh X cn 720 ml dd NaOH 0,2M. Hiu sut qu trnh ln men gim l
A. 90%.
B. 10%.
C. 80%.
D. 20%.
Cu 46. (C-12) 7: Ln men 90 kg glucoz thu c V lt ancol etylic (D = 0,8 g/ml) vi hiu sut ca
qu trnh ln men l 80%. Gi tr ca V l
A. 46,0.
B. 57,5.
C. 23,0.
D. 71,9.
Cu 47. (A-13) 18: Ln men m gam glucoz to thnh ancol etylic (hiu sut phn ng bng
90%). Hp th hon ton lng kh CO2 sinh ra vo dung dch Ca(OH)2 d, thu c 15 gam kt ta.
Gi tr ca m l
A. 18,5.
B. 7,5.
C. 45,0.
D. 15,0.
Cu 48. (B-13) 47: Tin hnh ln men gim 460 ml ancol etylic 8o vi hiu sut bng 30%. Bit
khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml v ca nc bng 1 g/ml. Nng
phn trm ca axit axetic trong dung dch thu c l
A. 2,51%.
B. 2,47%.
C. 3,76%.
D. 7,99%.
Thng k H 2007-2014
Cu 49. (C-13) 47: Tin hnh sn xut ancol etylic t xenluloz vi hiu sut ca ton b qu trnh
l 70%.
sn xut 2 tn ancol etylic, khi lng xenluloz cn dng l
A. 5,031 tn.
B. 10,062 tn.
C. 3,521 tn.
D. 2,515 tn.
16.5. Phn ng iu ch Xenluloz trinitrat

Cu 50. (B-07) 13: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit
sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng dd cha m kg axit nitric (hiu sut p
t 90%). Gi tr ca m l
A. 42 kg.
B. 10 kg.
C. 30 kg.
D. 21 kg.
Cu 51. (A-11) 28: Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu
sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz
trinitrat iu ch c l
A. 2,20 tn.
B. 1,10 tn.
C. 2,97 tn.
D. 3,67 tn.
Cu 52. (C-08) 19: T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit
hiu sut p tnh theo xenluloz l 90%). Gi tr ca m l
A. 26,73.
B. 33,00.
C. 25,46.
D. 29,70.
Cu 53. (C-09) 27: Th tch ca dd axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4
kg xenluloz trinitrat (hiu sut 80%) l
A. 42,34 lt.
B. 42,86 lt.
C. 34,29 lt.
D. 53,57 lt.
Cu 54. (B-08) 25: Th tch dd HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng t/d vi
xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %)
A. 55 lt.
B. 81 lt.
C. 49 lt.
D. 70 lt.
Cu 55. (B-12) 44: iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt
axit nitric 94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l
A. 60.
B. 24.
C. 36.
D. 40.
Thng k H 2007-2014
17. Polime v vt liu polime
Cu 1. (C-08) 25: T nilon - 6,6 c iu ch bng p trng ngng

A. HOOC-(CH2)2-CH(NH2)-COOH.
B. HOOC-(CH2)4-COOH v HO-(CH2)2-OH.
C. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2.
D. H2N-(CH2)5-COOH.
Cu 2. (A-07) 10: Nilon6,6 l mt loi
A. t poliamit.
B. t visco.
C. polieste.
D. t axetat.
Cu 3. 46 (A-14): Polime no sau y trong thnh phn cha nguyn t nit?
A. Nilon-6,6
B. Polietilen
C. Poli(vinyl clorua)
D. Polibutaien
Cu 4. (A-09) 29: Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l
B. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH.
A. CH2=CH-COOCH3 v H2N-[CH2]6-COOH.
C. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH.
D. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH.
Cu 5. (C-14): T nitron dai, bn vi nhit, gi nhit tt, thng c dng dt vi v may qun
o m.
Trng hp cht no sau y to thnh polime dng sn xut t nitron?
A. CH2=CH-CN
B. CH2=CH-CH3
C. H2N [CH2]5 COOH
D. H2N
[CH2]6 COOH
Cu 6.
(B-14): Trng hp hirocacbon no sau y to ra polime dung sn xut cao su buna?
A. 2-metylbuta-1,3-ien.
B. Penta-1,3-ien.
C. But-2-en.
D. Buta-1,3-ien.
Cu 7.
(B-14): Poli(etylen terephtalat) c iu ch bng phn ng vi axit teraphtalic vi cht
no sau y?
A. Etylen glicol
B. Etilen
C. Glixerol
D. Ancol etylic
Cu 8. (C-07) 22: Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng p trng
hp
A. C2H5COO-CH=CH2.B. CH2=CH-COO-C2H5.
C. CH3COO-CH=CH2. D. CH2=CH-COO-CH3.
Cu 9. (B-07) 18: Dy gm cc cht c dng tng hp cao su Buna-S l:
A. CH2=C(CH3)-CH=CH2, C6H5CH=CH2.
B. CH2=CH-CH=CH2, C6H5CH=CH2.
C. CH2=CH-CH=CH2, lu hunh.
D. CH2=CH-CH=CH2, CH3-CH=CH2.
Cu 10. (B-09) 23: Dy gm cc cht u c kh nng tham gia p trng hp l:
A. stiren; clobenzen; isopren; but-1-en.
B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen.
C. buta-1,3-ien; cumen; etilen; trans-but-2-en.
D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua.
Cu 11. (C-10) 35: Polime no sau y c tng hp bng p trng ngng?
A. poli(metyl metacrylat).
B. poli(etylen terephtalat).
C. polistiren.
D.
poliacrilonitrin.
Cu 12. (A-10) 52: Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7; (4)
poli(etylen-terephtalat); (5) nilon-6,6; (6) poli(vinyl axetat), cc polime l sn phm ca p trng
ngng l:
A. (1), (3), (6).
B. (1), (2), (3).
C. (1), (3), (5).
D. (3), (4), (5).
Cu 13. (A-10) 23: Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S
t tng hp l
A. 5.
B. 2.
C. 3.
D. 4.
A. T visco l t tng hp.
B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N.
C. Trng hp stiren thu c poli(phenol-fomanehit).
D. Poli(etylen terephtalat) c iu ch bng p trng ngng cc monome tng ng
Cu 15. (B-08) 35: Polime c cu trc mng khng gian (mng li) l
A. PE.
B. amilopectin.
C. PVC.
D. nha bakelit.
Cu 16. (B-10) 26: Cc cht u khng b thu phn trong dd H2SO4 long nng l:
A. t capron; nilon-6,6; polietilen.
C. poli(vinyl axetat); polietilen; cao su
buna.
B. nilon-6,6; poli(etylen-terephtalat); polistiren.
D. polietilen; cao su buna; polistiren.
Cu 17. (A-07) 43: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1
phn t clo p vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5)
A. 5.
B. 6.
C. 4.
D. 3.
Cu 18. (A-08) 13: Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch
t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l
A. 113 v 152.
B. 121 v 114.
C. 121 v 152.
D. 113 v 114
Cu 19. (C-07) 49: Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn
ng trng hp
A. CH2=C(CH3)COOCH3.
B. CH2 =CHCOOCH3.
C. C6H5CH=CH2. D. CH3COOCH=CH2.
Thng k H 2007-2014
Cu 20. (C-07) 50: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t
enang, nhng loi t no thuc loi t nhn to?
A. T tm v t enang.
B. T visco v t nilon-6,6.
C. T nilon-6,6 v t capron.
D. T visco v t axetat.
Cu 21. (C-09) 34: Trong thc t, phenol c dng sn xut
A. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D. C. nha rezol, nha rezit v thuc tr
su 666.
B. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric.
D. nha rezit, cht dit c 2,4-D v
thuc n TNT.
Cu 22. (C-11) 1: Cho cc polime: (1) polietilen, (2) poli(metyl metacrylat), (3) polibutaien, (4)
polistiren, (5) poli(vinyl axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime c th b thu
phn trong dung dch axit v dung dch kim l:
A. (1), (4), (5).
B. (1), (2), (5).
C. (2), (5), (6).
D. (2), (3), (6).
Cu 23. (A-11) 29: Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp?
A. Trng hp metyl metacrylat.
C. Trng ngng hexametyleniamin vi axit aipic.
B. Trng hp vinyl xianua.
D. Trng ngng axit -aminocaproic
Cu 24. (A-11) Cho s phn ng:
HCN
X; X
polime Y; X + CH2=CH-CH=CH2
polime Z
C2H2
Y v Z ln lt dng ch to vt liu polime no sau y?
A. T olon v cao su buna-N.
B. T nilon-6,6 v cao su cloropren.
C. T nitron v cao su buna-S.
D. T capron v cao su buna.
trung hop
dong trung hop
Cu 25. (B-11) 36: Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C
bao nhiu t thuc loi t poliamit?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 26. (A-12) 25: Loi t no sau y c iu ch bng phn ng trng hp?
A. T nitron.
B. T visco.
C. T xenluloz axetat.
D. T nilon-6,6.
Cu 27. (A-12) 59: C cc cht sau: keo dn ure-fomanehit; t lapsan; t nilon-6,6; protein; si
bng; amoni axetat; nha novolac. Trong cc cht trn, c bao nhiu cht m trong phn t ca
chng c cha nhm -NH-CO-?
A. 6.
B. 4.
C. 3.
D. 5.
Cu 28. (B-12) 9: Cc polime thuc loi t nhn to l
A. t visco v t nilon-6,6.
B. t tm v t vinilon.
C. t nilon-6,6 v t capron.
D. t visco v t xenluloz axetat.
Cu 29. (B-12) 60: Cho cc cht: caprolactam (1), isopropylbenzen (2), acrilonitrin (3), glyxin (4), vinyl
axetat (5). Cc cht c kh nng tham gia phn ng trng hp to polime l
A. (1), (2) v (3).
B. (1), (2) v (5).
C. (1), (3) v (5).
D. (3), (4) v (5).
A. Si bng, t tm thuc loi polime thin nhin.
B. T visco, t xenluloz axetat u thuc loi t tng hp.
C. Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng ngng.
D. T nilon6,6 c iu ch t hexametyleniamin v axit axetic.
Cu 31. (A-13) 38: T nilon-6,6 l sn phm trng ngng ca
A. axit aipic v etylen glicol.
B. axit aipic v hexametyleniamin.
C. etylen glicol v hexametyleniamin.
D. axit aipic v glixerol.
Cu 32. (B-13) 1: Trong cc polime: t tm, si bng, t visco, t nilon-6, t nitron, nhng polime
c ngun gc t xenluloz l
A. si bng, t visco v t nilon-6.
B. t tm, si bng v t nitron.
C. si bng v t visco.
D. t visco v t nilon-6.
Cu 33. (B-13) 60: T nitron (olon) l sn phm trng hp ca monome no sau y?
A. CH2=CHCN. B. CH3COOCH=CH2. C. CH2=C(CH3)COOCH3. D. CH2=CHCH=CH2.
Cu 34. (C-13) 56: T no di y thuc loi t nhn to?
A. T nilon-6,6.
B. T axetat.
C. T tm.
D. T capron.
Cu 35. (C-13) 27: Trng hp m tn etilen thu c 1 tn polietilen (PE) vi hiu sut phn ng
bng 80%. Gi tr ca m l
A. 1,80.
B. 2,00.
C. 0,80.
D. 1,25.
Thng k H 2007-2014
18. TNG HP HU C
18.1. Phn ng trng bc
Cu 86. (C-14): Cho cc cht :HCHO, CH3CHO , HCOOH, C2H2 . S cht c phn ng trng bc l
A. 1
B. 3
C. 2
D. 4
Cu 87. (A-07) 50: Dy gm cc cht u t/d vi AgNO3 (hoc Ag2O) trong dd NH3 l:
A. axit fomic, vinylaxetilen, propin.
B. anehit fomic, axetilen, etilen.
C. anehit axetic, butin-1, etilen.
D. anehit axetic, axetilen, butin-2.
Cu 88. (B-08) 40: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz).
S cht trong dy tham gia c p trng gng l
A. 3.
B. 6.
C. 5.
D. 4.
Cu 89. (A-09) 45: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2
(mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht t/d c vi dd
AgNO3 trong NH3 to ra kt ta l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 90. (C-12) 41: Cho dy cc cht: anehit axetic, axetilen, glucoz, axit axetic, metyl axetat. S
cht trong dy c kh nng tham gia phn ng trng bc l
A. 3.
B. 2.
C. 5.
D. 4.
Cu 91. (A-13) 16: Cc cht trong dy no sau y u to kt ta khi cho tc dng vi dung dch
AgNO3 trong NH3 d, un nng?
A. vinylaxetilen, glucoz, imetylaxetilen.
B. vinylaxetilen, glucoz, anehit axetic.
C. glucoz, imetylaxetilen, anehit axetic.
D. vinylaxetilen, glucoz, axit propionic.
18.2. Tc dng vi dung dch Cu(OH)2

Cu 92. (B-08) 8: Cho cc cht: ru (ancol) etylic, glixerin (glixerol), glucoz, imetyl ete v axit
fomic. S cht t/d c vi Cu(OH)2 l
A. 1.
B. 3.
C. 4.
D. 2.
Cu 93. C-11) 39: Cho cc cht: saccaroz, glucoz, fructoz, etyl fomat, axit fomic v anehit
axetic. Trong cc cht trn, s cht va c kh nng tham gia phn ng trng bc va c kh nng
p vi Cu(OH)2 iu kin thng l
A. 3.
B. 5.
C. 4.
D. 2.
Cu 94. (B-09) 38: Cho cc hp cht sau:
(a) HOCH2-CH2OH.
(c) HOCH2-CH(OH)-CH2OH.
(e) CH3-CH2OH.
(b) HOCH2-CH2-CH2OH.
(d) CH3-CH(OH)-CH2OH.
(f) CH3-O-CH2CH3.
Cc cht u t/d c vi Na, Cu(OH)2 l:
A. (a), (b), (c).
B. (c), (d), (f).
C. (a), (c), (d).
D. (c), (d), (e).
Cu 95. (B-10) 24: Cc dd p c vi Cu(OH)2 nhit thng l:
A. glixerol, axit axetic, glucoz.
C. anehit axetic, saccaroz, axit axetic
B. lng trng trng, fructoz, axeton.
D. fructoz, axit acrylic, ancol etylic.
Cu 96. (C-07) 44: Ch dng Cu(OH)2 c th phn bit c tt c cc dd ring bit sau:
A. glucoz, mantoz, glixerin (glixerol), anehit axetic.
B. lng trng trng, glucoz, fructoz, glixerin (glixerol).
C. saccaroz, glixerin (glixerol), anehit axetic, ru (ancol) etylic.
D. glucoz, lng trng trng, glixerin (glixerol), ru (ancol) etylic.
18.3. Tc dng vi dung dch Br2

Cu 97. (B-14): Cho cc cht sau : etilen, axetilen, phenol (C6H5OH) , buta-1,3-ien, toluen, anilin. S
cht lm mt mu nc brom iu kin thng l
A. 4
B. 2
C. 5
D. 3
Cu 98. (B-08) 45: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin),
C6H5OH (phenol), C6H6 (benzen). S cht trong dy p c vi nc brom l
A. 6.
B. 8.
C. 7.
D. 5.
Cu 99. (C-11) 46: Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan v
Thng k H 2007-2014
xiclopentan. Trong cc cht trn, s cht phn ng c vi dung dch brom l

A. 6.
B. 4.
C. 5.
D. 3.
Cu 100. (A-14): Axit cacboxylic no di y c mch cacbon phn nhnh, lm mt mu dung dch
brom?
A. Axit metacrylic
B. Axit 2-metylpropanoic
C. Axit propanoic
D. Axit acrylic
Cu 101. (B-10) 40: Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete,
s cht c kh nng lm mt mu nc brom l
A. 5.
B. 4.
C. 6.
D. 3.
Cu 102. (A-12) 16: Cho dy cc cht: stiren, ancol benzylic, anilin, toluen, phenol (C6H5OH). S cht
trong dy c kh nng lm mt mu nc brom l
A. 5.
B. 4.
C. 3.
D. 2.
Cu 103. (A-12) 52: Cho dy cc cht: cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht
trong dy lm mt mu dung dch brom l
A. 5.
B. 4.
C. 2.
D. 3.
Cu 104. (B-13) 58: Cho dy cht sau: isopren, anilin, anehit axetic, toluen, pentan, axit metacrylic v
stiren. S cht trong dy phn ng c vi nc brom l
A. 6.
B. 4.
C. 7.
D. 5.
18.4. Tc dng vi H2
Cu 105. (C-10) 20: ng vi cng thc phn t C3H6O c bao nhiu hp cht mch h bn khi t/d vi
kh H2 (xc tc Ni, to) sinh ra ancol?
A. 3.
B. 4.
C. 2.
D. 1.
Cu 106. (C-08) 18:
Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3),
CH2=CH-CH2-OH (4). Nhng cht p hon ton vi lng d H2 (Ni, to) cng to ra mt sn phm l:
A. (2), (3), (4).
B. (1), (2), (4).
C. (1), (2), (3).
D. (1), (3), (4).
Cu 107. (B-10) 43: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng
p cng H2 (xc tc Ni, to)?
A. 3.
B. 5.
C. 2.
D. 4.
Cu 108. (B-10) 15: Dy gm cc cht u t/d vi H2 (xc tc Ni, to), to ra sn phm c kh nng p
vi Na l:
A. C2H3CH2OH, CH3COCH3, C2H3COOH.
B. C2H3CHO, CH3COOC2H3, C6H5COOH.
C. C2H3CH2OH, CH3CHO, CH3COOH.
D. CH3OC2H5, CH3CHO, C2H3COOH.
Cu 109. (B-13) 12: Trong cc cht: stiren, axit acrylic, axit axetic, vinylaxetilen v butan, s cht c
kh nng tham gia phn ng cng hiro (xc tc Ni, un nng) l
A. 4.
B. 2.
C. 5.
D. 3.
Cu 110. (C-13) 59: Cho cc cht: but-1-en, but-1-in, buta-1,3-ien, vinylaxetilen, isobutilen,
anlen. C bao nhiu cht trong s cc cht trn khi phn ng hon ton vi kh H2 d (xc tc Ni,
un nng) to ra butan?
A. 6.
B. 5.
C. 4.
D. 3.
18.5. Tc dng vi dung dch NaOH

Cu 111. (A-09) 23: Hp cht hu c X t/d c vi dd NaOH v dd brom nhng khng t/d vi dd
NaHCO3. Tn gi ca X l
A. anilin.
B. phenol.
C. axit acrylic.
D. metyl axetat.
Cu 112. (C-11) 47: S hp cht ng phn cu to ca nhau c cng thc phn t C8H10O, trong
phn t c vng benzen, tc dng c vi Na, khng tc dng c vi NaOH l
A. 7.
B. 6.
C. 4.
D. 5.
Cu 113. (B-07) 9: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2
ln lt t/d vi: Na, NaOH, NaHCO3. S p xy ra l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 114. (B-07) 39: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol,
phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht t/d c vi dd
NaOH l
A. 4.
B. 6.
C. 5.
D. 3.
Cu 115. (C-07) 29: S hp cht n chc, ng phn cu to ca nhau c cng CTPT C4H8O2, u t/d
c vi dd NaOH l
A. 5.
B. 3.
C. 6.
D. 4.
Thng k H 2007-2014
Cu 116. (B-10) 32: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t
C5H10O2, p c vi dd NaOH nhng khng c p trng bc l
A. 4.
B. 5.
C. 8.
D. 9.
Cu 117. (C-08) 23: Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S
cht trong dy p c vi NaOH (trong dd) l
A. 3.
B. 2.
C. 1.
D. 4.
Cu 118. (C-12) 5: Cho dy cc dung dch: axit axetic, phenylamoni clorua, natri axetat,
metylamin, glyxin, phenol (C6H5OH). S dung dch trong dy tc dng c vi dung dch NaOH l
A. 4.
B. 3.
C. 6.
D. 5.
Cu 119. (C-11) 42: Hai cht no sau y u tc dng c vi dung dch NaOH long?
B. CH3NH3Cl v H2NCH2COONa.
A. CH3NH3Cl v CH3NH2.
C. CH3NH2 v H2NCH2COOH.
D. ClH3NCH2COOC2H5 v H2NCH2COOC2H5.
Cu 120. (A-11) 33: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, mcrezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch
NaOH long, un nng l
A. 5.
B. 3.
C. 4.
D. 6.
Cu 121. (B-07) 19: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin
(Z), este ca aminoaxit (T). Dy gm cc loi hp cht u t/d c vi dd NaOH v u t/d c
vi dd HCl l
A. X, Y, Z, T.
B. X, Y, T.
C. X, Y, Z.
D. Y, Z, T.
Cu 122. (C-12) 46: Cht no sau y va tc dng c vi dung dch NaOH, va tc dng c vi
nc Br2?
A. CH3CH2COOH.
B. CH3COOCH3.
C. CH2=CHCOOH.
D. CH3CH2CH2OH.
Cu 123. (C-07) 11: Cho cc cht: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht
t/d c vi nhau l
A. 4.
B. 3.
C. 2.
D. 1.
Cu 124. (C-10) 31: ng vi CTPT C2H7O2N c bao nhiu cht va p c vi dd NaOH, va p
c vi dd HCl?
A. 4.
B. 2.
C. 1.
D. 3.
Cu 125. (C-08) 49: Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH,
CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l
A. 4.
B. 2.
C. 3.
D. 5.
Cu 126. (C-09) 58: Cho tng cht H2NCH2COOH, CH3COOH, CH3 COOCH3 ln lt tc dng vi
dd NaOH (to) v vi dung dch HCl (to). S phn ng xy ra l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 127. (C-09) 30: S hp cht l ng phn cu to, c cng CTPT C4H8O2, t/d c vi dd NaOH
nhng khng t/d c vi Na l
A. 3.
B. 2.
C. 4.
D. 1.
Cu 128. (A-12) 40: Cho dy cc hp cht thm: p-HO-CH2-C6H4-OH, p-HO-C6H4-COOC2H5, p-HO-C6H4COOH, p-HCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong dy tha mn ng thi 2 iu kin
sau?
(a) Ch tc dng vi NaOH theo t l mol 1 : 1.
(b) Tc dng c vi Na (d) to ra s mol H2 bng s mol cht phn ng.
A. 3.
B. 4.
C. 1.
D. 2.
Cu 129. (B-12) 41: Cho dy cc cht sau: toluen, phenyl fomat, fructoz, glyxylvalin (Gly-Val),
etylen glicol, triolein. S cht b thu phn trong mi trng axit l
A. 6.
B. 3.
C. 4.
D. 5.
18.6. linh ng ca H, lc axit, nhit si, nhit nng chy,

tan
Cu 130. (B-07) 20: Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic (Z) v imetyl
ete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l
A. T, Z, Y, X.
B. Z, T, Y, X.
C. T, X, Y, Z.
D. Y, T, X, Z.
Cu 131. (C-14): Trong s cc cht di y, cht c nhit si cao nht l
A. CH3COOH B. C2H5OH
C. HCOOCH3
D. CH3CHO
Cu 132. (A-08) 8: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l:
A. CH3CHO, C2H5OH, C2H6, CH3COOH.
B. CH3COOH, C2H6, CH3CHO, C2H5OH.
Thng k H 2007-2014
C. C2H6, C2H5OH, CH3CHO, CH3COOH.

D. C2H6, CH3CHO, C2H5OH, CH3COOH
Cu 133. (B-09) 32: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi
l:
A. CH3COOH, C2H5OH, HCOOH, CH3CHO.
B. CH3CHO, C2H5OH, HCOOH, CH3COOH.
C. CH3COOH, HCOOH, C2H5OH, CH3CHO.
D. HCOOH, CH3COOH, C2H5OH, CH3CHO
Cu 134. (C-12) 21: Cho dy cc cht: etan, etanol, etanal, axit etanoic. Cht c nhit si cao nht
trong dy l
A. axit etanoic.
B. etanol.
C. etanal.
D. etan.
Cu 135. (C-09) 23: Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm
cc cht c sp xp theo tnh axit tng dn (t tri sang phi) l:
A. (T), (Y), (X), (Z). B. (X), (Z), (T), (Y).
C. (Y), (T), (Z), (X).
D. (Y), (T), (X), (Z).
Cu 136. (C-11) 57: Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l:
A. HCOOH, CH3COOH, CH3CH2COOH.
B. CH3COOH, CH2ClCOOH, CHCl2COOH.
C. CH3COOH, HCOOH, (CH3)2CHCOOH.
D. C6H5OH, CH3COOH, CH3CH2OH.
Cu 137. (C-10) 58: Dung dch no sau y c pH > 7?
A. Dung dch CH3COONa.
B. Dung dch NaCl.
C. Dung dch NH4Cl.
D. Dung dch
Al2(SO4)3.
Cu 138. (C-11) 31: Cho cc dung dch: C6H5NH2 (anilin), CH3NH2, NaOH, C2H5OH v
H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l
A. 3.
B. 4.
C. 2.
D. 5.
Cu 139. (B-07) 3: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l:
A. anilin, metyl amin, amoniac.
B. amoni clorua, metyl amin, natri hiroxit.
C. anilin, amoniac, natri hiroxit.
D. metyl amin, amoniac, natri axetat.
18.7. iu ch
Cu 140. (A-09) 27: Dy gm cc cht u iu ch trc tip (bng mt p) to ra anehit axetic l:
A. CH3COOH, C2H2, C2H4.
B. C2H5OH, C2H4, C2H2.
C. C2H5OH, C2H2, CH3COOC2H5.
D. HCOOC2H3, C2H2, CH3COOH.
Cu 141. (C-09) 49: Qu trnh no sau y khng to ra anehit axetic?
A. CH2=CH2 + H2O (to, xc tc HgSO4).
B. CH2=CH2 + O2 (to, xc tc).
C. CH3COOCH=CH2 + dung dch NaOH (to).
D. CH3CH2OH + CuO (to).
Cu 142. (C-09) 21: Dy gm cc cht c th iu ch trc tip (bng mt p) to ra axit axetic l:
A. CH3CHO, C2H5OH, C2H5COOCH3.
B. CH3CHO, C6H12O6 (glucoz), CH3OH.
C. CH3OH, C2H5OH, CH3CHO.
D. C2H4(OH)2, CH3OH, CH3CHO.
Cu 143. (C-10) 51: iu kin thch hp: cht X phn ng vi ch t Y to ra anehit axetic; cht X
phn ng vi cht Z to ra ancol etylic. Cc cht X, Y, Z ln lt l:
A. C2H2, H2O, H2.
B. C2H4, O2, H2O.
C. C2H2, O2, H2O.
D. C2H4, H2O, CO.
18.8. Nhn bit
Cu 144. (B-07) 44: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc
th phn bit 3 cht lng trn l
A. dd phenolphtalein.
B. nc brom.
C. dd NaOH.
D. giy qu tm.
Cu 145. (A-09) 34: C ba dd: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol
etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dd HCl
th nhn bit c ti a bao nhiu ng nghim?
A. 5.
B. 6.
C. 3.
D. 4.
Cu 146. (B-08) 54: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh
cht: X, Z u p vi nc brom; X, Y, Z u p vi H2 nhng ch c Z khng b thay i nhm chc;
cht Y ch t/d vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l:
A. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO.
B. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH.
C. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH.
D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO.
Cu 147. (C-09) 56: Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc
dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. CTCT ca X
v Y ln lt l
A. C2H5COOH v HCOOC2H5.
B. HCOOC2H5 v HOCH2COCH3.
C. HCOOC2H5 v HOCH2CH2CHO.
D. C2H5COOH v CH3CH(OH)CHO.
Cu 148. (C-10) 32: Hai cht X v Y c cng cng thc phn t C2H4O2. Cht X p c vi kim loi Na
v tham gia p trng bc. Cht Y p c vi kim loi Na v ho tan c CaCO 3. Cng thc ca X, Y
Thng k H 2007-2014
ln lt l:
A. CH3COOH, HOCH2CHO.
B. HCOOCH3, HOCH2CHO
C. HCOOCH3, CH3COOH.
D. HOCH2CHO, CH3COOH
Cu 149. (C-08) 4: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng p
vi: Na, NaOH, Na2CO3. X2 p vi NaOH (un nng) nhng khng p Na. Cng thc cu to ca X1, X2
ln lt l:
A. CH3-COOH, CH3-COO-CH3.
B. (CH3)2CH-OH, H-COO-CH3.
C. H-COO-CH3, CH3-COOH.
D. CH3-COOH, H-COO-CH3.
Cu 150. (C-07) 28: Cho cht X t/d vi mt lng va dd NaOH, sau c cn dd thu c cht
rn Y v cht hu c Z. Cho Z t/d vi AgNO3 (hoc Ag2O) trong dd NH3 thu c cht hu c T. Cho
cht T t/d vi dd NaOH li thu c cht Y. Cht X c th l
A. HCOOCH=CH2.
B. CH3COOCH=CH2.
C. HCOOCH3. D. CH3COOCH=CH-CH3.
Cu 151. (C-07) 32: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, t/d
c vi Na v vi NaOH. Bit r ng khi cho X t/d vi Na d, s mol H2 thu c bng s mol X tham
gia p v X ch t/d c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l
A. C6H5CH(OH)2.
B. HOC6H4CH2OH.
C. CH3C6H3(OH)2.
D. CH3OC6H4OH.
Cu 152. (A-11) 45: X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C3H6O. X tc
dng c vi Na v khng c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng
trng bc. Z khng tc dng c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l:
A. CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH.
B. CH2=CH-CH2-OH, CH3-CO-CH3, CH3-CH2-CHO.
C. CH2=CH-CH2-OH, CH3-CH2-CHO, CH3-CO-CH3.

D. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH
Cu 153. (C-11) 12: Hp cht hu c X c cng thc phn t l C4H8O3. X c kh nng tham gia
phn ng vi Na, vi dung dch NaOH v phn ng trng bc. Sn phm thy phn ca X trong mi
trng kim c kh nng ho tan Cu(OH)2 to thnh dung dch mu xanh lam. Cng thc cu to ca
X c th l
A. CH3COOCH2CH2OH.
B. HCOOCH2CH(OH)CH3.
C. HCOOCH2CH2CH2OH.
D. CH3CH(OH)CH(OH)CHO.
Cu 154. B-09) 48: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X t/d c
vi Na, tham gia p trng bc v p cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l
A. HO-CH2-CH2-CH=CH-CHO. B. HOOC-CH=CH-COOH. C. HO-CH2-CH=CH-CHO. D. HO-CH2-CH2-CH2CHO.
18.9. S phn ng
Cu 155. (C-07) 12: Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l
A. CH3CH2OH v CH2=CH2.
B. CH3CHO v CH3CH2OH.
C. CH3CH2OH v CH3CHO.
D. CH3CH(OH)COOH v CH3CHO.
.
Cu 156. (A-10) 7: Cho s chuyn ho:
( Este a chc)
Tn gi ca Y l
A. propan-1,2-iol.
B. propan-1,3-iol.
C. glixerol.
D. propan-2ol.
X + H2SO4 long
Cu 157. (A-08) 23: Cho s chuyn ho sau: C3H4O2 + NaOH X + Y
Z+T
Bit Y v Z u c p trng gng. Hai cht Y, Z tng ng l:
C. CH3CHO, HCOOH. D. HCOONa, CH3CHO.
A. HCHO, CH3CHO.
B. HCHO, HCOOH.
Cu 158. (B-10) 54: Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng p vi Na,
tho mn s chuyn ho sau:
3
2
Y
Este c mi chui chn
X
H SO dac
Ni,t o
CH COOH
2
Tn ca X l
A. pentanal.
B. 2-metylbutanal.
C. 2,2-imetylpropanal.
Cu 159. (B-10) 37: Cho s chuyn ho sau:
o
D. 3-metylbutanal.
H2 ,t
xt,t
Z
C2 H2
X
Y
Caosu Buna N
Pd,PbCO3
t o ,xt,p
Cc cht X, Y, Z ln lt l:
A. benzen; xiclohexan; amoniac.
B. axetanehit; ancol etylic; buta-1,3-ien.
C. vinylaxetilen; buta-1,3-ien; stiren.
D. vinylaxetilen; buta-1,3-ien; acrilonitrin.
Cu 160. (C-08) 50: Cho s chuyn ha sau (mi mi tn l mt PTP): Tinh bt X Y Z
Thng k H 2007-2014
metyl axetat.
Cc cht Y, Z trong s trn ln lt l:
A. C2H5OH, CH3COOH.
B. CH3COOH, CH3OH.
C. CH3COOH, C2H5OH.
D. C2H4, CH3COOH.
Cu 161. (C-09) 15: Cht X c cng thc phn t C4H9O2N. Bit:
X + NaOH Y + CH4O
Y + HCl (d) Z + NaCl
Cng thc cu to ca X v Z ln lt l
A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH.
B.CH3CH(NH2)COOCH3
v
CH3CH(NH3Cl)COOH.
C. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH.
D. H2NCH2COOC2H5 v ClH3NCH2COOH.
Cu 162. (C-11)Cho s p/:

(X, Z, M l cc cht v c, mi mi tn ng vi mt phng trnh p/). Cht T trong s trn l
A. C2H5OH.
B. CH3CHO.
C. CH3OH.
D. CH3COONa.
Cu 163. (B-13) 6: Cho s phn ng: C2H2

X CH3COOH.
Trong s trn mi mi tn l mt phn ng, X l cht no sau y?
A. CH3COONa.
B. HCOOCH3.
C. CH3CHO.
D. C2H5OH
Cu 164. (B-11) 3: Cho s phn ng:
(1) X + O2
xt,t
axit cacbonxylic Y1
(3) Y1 + Y2
xt,t
Y3 + H2O
(2) X + H2
xt,t
ancol Y2
o
Bit Y3 c cng thc phn t C6H10O2. Tn gi ca X l

A. anehit acrylic.
B. anehit propionic.
C. anehit metacrylic. D. anehit axetic.
Cu 165. (A-12) 31: Hp cht X c cng thc C8H14O4. T X thc hin cc phn ng (theo ng t l
mol):
(a) X + 2NaOH X1 + X2 + H2O
(b) X1 + H2SO4 X3 + Na2SO4
(c) nX3 + nX4 nilon-6,6 + 2nH2O
(d) 2X2 + X3 X5 + 2H2O
Phn t khi ca X5 l
A. 174.
B. 216.
C. 202.
D. 198.
Cu 166. (C-12) 24: Cho s phn ng:
NaOH
AgNO / NH
NaOH
3
3
Z
Este X C4HnO2
Y
C2H3O2Na
to
to
to
Cng thc cu to ca X tha mn s cho l

A. CH3COOCH2CH3.
C. CH3COOCH=CH2.
Cu 167. (A-12) 42: Cho s chuyn ha sau:
B. CH2=CHCOOCH3.
D. HCOOCH2CH2CH3.
(a) C3H4O2 + NaOH X + Y

(b) X + H2SO4 (long) Z + T
(c) Z + dung dch AgNO3/NH3 (d) E + Ag + NH4NO3
(d) Y + dung dch AgNO3/NH3 (d) F + Ag + NH4NO3
Cht E v cht F theo th t l
A. HCOONH4 v CH3CHO.
B. (NH4)2CO3 v CH3COONH4.
C. HCOONH4 v CH3COONH4.
D. (NH4)2CO3 v CH3COOH.
Cu 168. (B-12) 7: Cho dy chuyn ha sau:
H 2O
H2
H 2O
X
Y
Z
CaC2
Pd / PbCO , t o
H SO , t o
3
Tn gi ca X v Z ln lt l
A. axetilen v ancol etylic.
B. axetilen v etylen glicol.
C. etan v etanal.
D. etilen v ancol etylic.
CaO , t o
Cu 169. (B-12) 39: Cho phng trnh ha hc:2X + NaOH
2CH4 + K2CO3 + Na2CO3
Cht X l
A. CH2(COOK)2.
B. CH2(COONa)2.
C. CH3COOK.
D. CH3COONa.
Thng k H 2007-2014
Cu 170. (C-12) 51: Cho cc phn ng sau:

t
X + 2NaOH
2Y + H2O
(1)
Y + HCl (long) Z + NaCl
(2)
Bit X l cht hu c c cng thc phn t C6H10O5. Khi cho 0,1 mol Z tc dng ht vi Na (d)
th s mol H2 thu c l
A. 0,15.
B. 0,20.
C. 0,10.
D. 0,05.
Cu 171. (A-14): Cho hnh v m t th nghim iu ch kh Y t dung dch X:
Hnh v trn minh ha phn ng no sau y?

t
A. NH4Cl NaOH
NaCl NH3 H2O
0
H2SO4
,t
B. C2 H5OH
C2 H4 H2O
t
C. NaCl(rn) + H2SO4(c)
NaHSO4 HCl
0
CaO ,t
D. CH3COONa(rn) + NaOH(rn)
Na 2CO3 CH4
0
Cu 172. (A-13) 17: Cho s cc phn ng:

t
X + NaOH (dung dch)
Y+Z
CaO , t
Y + NaOH (rn)
T+P
1500 C
T
Q + H2
Trong s trn, X v Z ln lt l:
A. CH3COOCH=CH2 v CH3CHO.
C. HCOOCH=CH2 v HCHO.
t , xt
Q + H2O
Z
B. CH3COOCH=CH2 v HCHO.
D. CH3COOC2H5 v CH3CHO.
Thng k H 2007-2014
18.10. Cc dng cu hi l thuyt tng hp

Cu 173. (C-10) 46: Cp cht no sau y khng phi l ng phn ca nhau?
A. Ancol etylic v imetyl ete
B. Glucoz v fructoz
C. Saccaroz v xenluloz
D. 2-metylpropan-1-ol v butan-2-ol
Cu 174. (B-11) 17: Pht biu no sau y ng?
A. Trong phn ng este ho gia CH3COOH vi CH3OH, H2O to nn t OH trong nhm
COOH ca axit v H trong nhm OH ca ancol.
B. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c
mi thm ca chui chn.
C. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ho hc, ch cn
dng thuc th l nc brom.
D. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng
nghip thc phm, m phm
A. Dd natri phenolat p vi kh CO2, ly kt ta va to ra cho t/d vi dd NaOH li thu c natri
phenolat.
B. Anilin p vi dd HCl, ly mui va to ra cho t/d vi dd NaOH li thu c anilin.
C. Phenol p vi dd NaOH, ly mui va to ra cho t/d vi dd HCl li thu c phenol.
D. Axit axetic p vi dd NaOH, ly dd mui va to ra cho t/d vi kh CO2 li thu c axit axetic.
(a) Anehit va c tnh oxi ho va c tnh kh.
(b) Phenol tham gia phn ng th brom kh hn benzen.
(c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt.
(d) Dung dch axit axetic tc dng c vi Cu(OH)2.
(e) Dung dch phenol trong nc lm qu tm ho .
(g) Trong cng nghip, axeton c sn xut t cumen.
S pht biu ng l
A. 4.
B. 2.
C. 5.
D. 3.
Cu 177. (B-11) 38: Ancol v amin no sau y cng bc?
A. (CH3)3COH v (CH3)3CNH2.
B. (C6H5)2NH v C6H5CH2OH.
C. (CH3)2CHOH v (CH3)2CHNH2.
D. C6H5NHCH3 v C6H5CH(OH)CH3.
Cu 178. (C-09) 19: Pht biu no sau y sai?
A. Nhit si ca este thp hn hn so vi ancol c cng phn t khi.
B. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn.
C. S nguyn t hiro trong phn t este n v a chc lun l mt s chn.
D. Sn phm ca p x phng ho cht bo l axit bo v glixerol.
Cu 179. Pht biu ng l:
A. Vinyl axetat p vi dd NaOH sinh ra ancol etylic.
C. Thu phn benzyl clorua thu c
phenol.
B. Phenol p c vi nc brom.
D. Phenol p c vi dd NaHCO3.
Cu 180. (A-08) 11: Pht biu ng l:
A. Tnh axit ca phenol yu hn ca ru (ancol).
B. Cao su thin nhin l sn phm
trng hp ca isopren.
C. Cc cht etilen, toluen v stiren u tham gia p trng hp. D. Tnh baz ca anilin mnh hn ca
amoniac.
A. Cc ancol a chc u p vi Cu(OH)2 to dd mu xanh lam.
B. Etylamin p vi axit nitr nhit thng, sinh ra bt kh.
C. Benzen lm mt mu nc brom nhit thng.
D. Anilin t/d vi axit nitr khi un nng, thu c mui iazoni.
Cu 182. (B-09) 22: Cho cc hp cht hu c: (1) ankan;(2) ancol no, n chc, mch h; (3)
xicloankan; (4) ete no, n chc, mch h; (5) anken;(6) ancol khng no (c mt lin kt i C=C),
mch h; (7) ankin;(8) anehit no, n chc, mch h;(9) axit no, n chc, mch h;(10) axit khng
no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2
bng s mol H2O l:
A. (1), (3), (5), (6), (8).
B. (3), (4), (6), (7), (10).
C. (3), (5), (6), (8), (9).
D.
(2),
(3), (5), (7), (9).
A. Este isoamyl axetat c mi chui chn.
Thng k H 2007-2014
B. Etylen glicol l ancol no, n chc, mch h.

C. Axit bo l nhng axit cacboxylic a chc.
D. Ancol etylic tc dng c vi dung dch NaOH.
Cu 184. (C-12) 37: Pht biu no sau y l sai?
A. Poli(metyl metacrylat) c dng ch to thy tinh hu c.
B. Cao su bunaN thuc loi cao su thin nhin.
C. Lc baz ca anilin yu hn lc baz ca metylamin.
D. Cht bo cn c gi l triglixerit hoc triaxylglixerol.
Cu 185. (C-12) 59: Cho cc pht biu:
(1) Tt c cc anehit u c c tnh oxi ho v tnh kh;
(2) Tt c cc axit cacboxylic u khng tham gia phn ng trng bc;
(3) Phn ng thy phn este trong mi trng axit l phn ng thun nghch;
(4) Tt c cc ancol no, a chc u ha tan c Cu(OH)2.
Pht biu ng l
A. (2) v (4).
B. (1) v (3).
C. (3) v (4).
D. (1) v (2).
18.11. Tnh ton tng hp

Cu 186. (A-08) 26: Trung ho 5,48 gam hh gm axit axetic, phenol v axit benzoic, cn dng 600 ml dd
NaOH 0,1M. C cn dd sau p, thu c hh cht rn khan c khi lng l
A. 8,64 gam.
B. 6,84 gam.
C. 4,90 gam.
D. 6,80 gam.
Cu 187. (A-08) 43: Cho s chuyn ha: CH4 C2H2 C2H3ClPVC. tng hp 250 kg PVC theo s
trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v
hiu sut ca c qu trnh l 50%)
A. 358,4.
B. 448,0.
C. 286,7.
D. 224,0.
Cu 188. (B-09) 17: Hp cht hu c X t/d c vi dd NaOH un nng v vi dd AgNO3 trong NH3.
Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p
sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng
thc cu to ca X l
A. O=CH-CH2-CH2OH.
B. HOOC-CHO.
C. CH3COOCH3.
D. HCOOC2H5.
Cu 189. (B-09) 29: Cho X l hp cht thm; a mol X p va ht vi a lt dd NaOH 1M. Mt khc, nu
cho a mol X p vi Na (d) th sau p thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn
ca X l
A. HO-C6H4-COOCH3 B. CH3-C6H3(OH)2
C. HO-CH2-C6H4-OH.
D. HO-C6H4-COOH.
Cu 190. (B-09) 39: Hai hp cht hu c X v Y l ng ng k tip, u t/d vi Na v c p trng
bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. CTCT ca X v Y tng
ng l
A. HOCH2CHO v HOCH2CH2CHO.
C. HOCH(CH3)CHO v HOOCCH2CHO.
B. HOCH2CH2CHO v HOCH2CH2CH2CHO.
D. HCOOCH3 v HCOOCH2CH3.
Cu 191. (B-09) 27: t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt
kh CO2( ktc). Bit X c p vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l
A. O=CH-CH=O.
B. CH2=CH-CH2-OH.
C. CH3COCH3.
D. C2H5CHO.
Cu 192. (A-10) 12: Hh kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon
ton 100 ml hh X bng mt lng oxi va , thu c 550 ml hh Y gm kh v hi nc. Nu cho Y i
qua dd axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng
thc phn t ca hai hirocacbon l
A. CH4 v C2H6.
B. C2H4 v C3H6.
C. C2H6 v C3H8.
D. C3H6 v C4H8
Cu 193. (A-10) 20: Hh M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c
cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t
chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi
H2SO4 c thc hin p este ho (hiu sut l 80%) th s gam este thu c l
A. 22,80.
B. 34,20.
C. 27,36.
D. 18,24
Cu 194. (B-10) 17: Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau
khi phn ng xy ra hon ton, thu c x mol hh kh gm: CO2, CO, N2 v H2. Gi tr ca x l
A. 0,60.
B. 0,36.
C. 0,54.
D. 0,45.
Cu 195. (B-10) 44:Hh M gm axit cacboxylic X, ancol Y (u n chc, s mol X g p hai ln s mol Y) v
este Z c to ra t X v Y. Cho mt lng M t/d va vi dd cha 0,2 mol NaOH, to ra 16,4 gam mui
v 8,05 gam ancol. Cng thc X, Y l
A. HCOOH v CH3OH. B. CH3COOH v CH3OH.
C. HCOOH v C3H7OH.
D.
CH3COOH
v
Thng k H 2007-2014
C2H5OH.
Cu 196. (C-07) 10: Hp cht X c CTPT trng CTG nht, va t/d c vi axit va t/d c vi
kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t
C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X p hon ton vi
mt lng va dd NaOH (un nng) thu c 4,85 gam mui khan. CTCT thu gn ca X l
A. CH2=CHCOONH4.
B. H2NCOO-CH2CH3.
C. H2NCH2COO-CH3.
D. H2NC2H4COOH.
Cu 197. (C-07) 40: Cho hh hai anken ng ng k tip nhau t/d vi nc (c H2SO4 lm xc tc)
thu c hh Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hh Z sau hp th ton b
sn phm chy vo 2 lt dd NaOH 0,1M thu c dd T trong nng ca NaOH bng 0,05M. Cng
thc cu to thu gn ca X v Y l (Cho: H = 1; C = 12; O = 16; th tch dd thay i khng ng k)
A. C2H5OH v C3H7OH
B. C3H7OH v C4H9OH C. C2H5OH v C4H9OH
D. C4H9OH v
C5H11OH
Cu 198. (C-08) 8: Cht hu c X c CTPT C4H6O4 t/d vi dd NaOH (un nng) theo p/t p:
C4H6O4 + 2NaOH 2Z + Y. oxi ho ht a mol Y th cn va 2a mol CuO (un nng), sau p to
thnh a mol cht T (bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l
A. 44 vC.
B. 58 vC.
C. 82 vC.
D. 118 vC.
Cu 199. (C-10) 2: t chy hon ton 2,76 gam hh X gm CxHyCOOH, CxHyCOOCH3, CH3OH thu c
2,688lt CO2 (ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam X p va vi 30 ml dd NaOH 1M, thu
c 0,96 gam CH3OH. Cng thc ca CxHyCOOH l
A. C3H5COOH.
B. CH3COOH.
C. C2H3COOH.
D. C2H5COOH.
Cu 200. (C-11) 37: Hai cht hu c X, Y c thnh phn phn t gm C, H, O (MX < MY < 82). C X
v Y u
c kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KHCO3 sinh ra
kh CO2. T khi hi ca Y so vi X c gi tr l
A. 1,47.
B. 1,91.
C. 1,57.
D. 1,61.
Cu 201. (A-11) 37: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl
acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng
thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u
thay i nh th no?
A. Gim 7,38 gam.
B. Tng 2,70 gam.
C. Tng 7,92 gam.
D. Gim 7,74 gam.
Cu 202. (B-10) 23: Cho hh M gm anehit X (no, n chc, mch h ) v hirocacbon Y, c tng s mol
l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO 2 (ktc) v 7,2 gam
H2O. Hirocacbon Y l
A. CH4.
B. C2H2.
C. C3H6.
D. C2H4.
Cu 203. (B-11) 6: Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t
chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca
anehit trong hn hp M l
A. 30%.
B. 40%.
C. 50%.
D. 20%.
Cu 204. (A-12) 41: Ha hi 8,64 gam hn hp gm mt axit no, n chc, mch h X v mt axit no,
a chc Y (c mch cacbon h, khng phn nhnh) thu c mt th tch hi bng th tch ca 2,8
gam N2 (o trong cng iu kin nhit , p sut). t chy hon ton 8,64 gam hn hp hai axit
trn thu c 11,44 gam CO2. Phn trm khi lng ca X trong hn hp ban u l
A. 72,22%.
B. 27,78%.
C. 35,25%.
D. 65,15%.
Cu 205. (B-12) 28: t chy hon ton 50 ml hn hp kh X gm trimetylamin v hai hirocacbon
ng ng k tip bng mt lng oxi va , thu c 375 ml hn hp Y gm kh v hi. Dn ton b
Y i qua dung dch H2SO4 c (d), th tch kh cn li l 175 ml. Cc th tch kh v hi o cng
iu kin. Hai hirocacbon l
A. C2H4 v C3H6.
B. C3H6 v C4H8.
C. C2H6 v C3H8.
D. C3H8 v C4H10.
Cu 206. (B-12) 33: un nng m gam hn hp X gm cc cht c cng mt loi nhm chc vi 600
ml dung dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit cacboxylic n chc v
15,4 gam hi Z gm cc ancol. Cho ton b Z tc dng vi Na d, thu c 5,04 lt kh H2 (ktc). C
cn dung dch Y, nung nng cht rn thu c vi CaO cho n khi phn ng xy ra hon ton,
thu c 7,2 gam mt cht kh. Gi tr ca m l
A. 40,60.
B. 22,60.
C. 34,30.
D. 34,51.
Cu 207. (A-13) 60: Cho 13,6 gam mt cht hu c X (c thnh phn nguyn t C, H, O) tc dng
va vi dung dch cha 0,6 mol AgNO3 trong NH3, un nng, thu c 43,2 gam Ag. Cng thc cu to
ca X l
A. CH CCH2CHO.
B. CH3C CCHO.
Thng k H 2007-2014
C. CH C[CH2]2CHO.
D. CH2=C=CHCHO.
Cu 208. (B-13) 10: Hn hp X gm hiro, propen, axit acrylic, ancol anlylic (C3H5OH). t chy
hon ton 0,75 mol X, thu c 30,24 lt kh CO2 (ktc). un nng X vi bt Ni mt thi gian, thu
c hn hp Y. T khi hi ca Y so vi X bng 1,25. Cho 0,1 mol Y phn ng va vi V lt dung
dch Br2 0,1M. Gi tr ca V l
A. 0,3.
B. 0,6.
C. 0,4.
D. 0,5.
Cu 209. (B-13) 17: Hai cht hu c X v Y, thnh phn nguyn t u gm C, H, O, c cng s
nguyn t cacbon (MX < MY). Khi t chy hon ton mi cht trong oxi d u thu c s mol
H2O bng s mol CO2. Cho 0,1 mol hn hp gm X v Y phn ng hon ton vi lng d dung
dch AgNO3 trong NH3, thu c 28,08 gam Ag. Phn trm khi lng ca X trong hn hp ban u l
A. 39,66%.
B. 60,34%.
C. 21,84%.
D. 78,16%.
Cu 210. (A-14): t chy hon ton 13,36 gam hn hp X gm axit metacrylic, axit aipic, axit axetic
v glixerol (trong s mol axit metacrylic bng s mol axit axetic) bng O2 d, thu c hn hp Y
gm kh v hi. Dn Y vo dung dch cha 0,38 mol Ba(OH) 2 , thu c 49,25 gam kt ta v dung
dch Z. un nng Z li xut hin kt ta. Cho 13,36 gam hn hp X tc dng vi 140 ml dung dch
KOH 1M, sau khi cc phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi
lng l
A. 19,04 gam
B. 18,68 gam
C. 14,44 gam
D. 13,32 gam
Cu 211.
(A-14): Cho X, Y l hai cht thuc dy ng ng ca axit acrylic v M X < MY; Z l ancol
c cng s nguyn t cacbon vi X; T l este hai chc to bi X, Y v Z. t chy hon ton 11,16 gam
hn hp E gm X, Y, Z, T cn va 13,216 lt kh O2 (ktc), thu c kh CO2 v 9,36 gam nc.
Mt khc 11,16 gam E tc dng ti a vi dung dch cha 0,04 mol Br2. Khi lng mui thu c khi
cho cng lng E trn tc dng ht vi dung dch KOH d l
A. 4,68 gam
B. 5,44 gam
C. 5,04 gam
D. 5,80 gam
Cu 212. (B-13) 21: Axit cacboxylic X hai chc (c phn trm khi lng ca oxi nh hn 70%), Y v
Z l hai ancol ng ng k tip (MY < MZ). t chy hon ton 0,2 mol hn hp gm X, Y, Z cn
va 8,96 lt kh O2 (ktc), thu c 7,84 lt kh CO2 (ktc) v 8,1 gam H2O. Phn trm khi lng
ca Y trong hn hp trn l
A. 15,9%.
B. 29,9%.
C. 29,6%.
D. 12,6%
Thng k H 2007-2014
B GIO DC V O TO
D B I HC NM 2009
MN: HA HC- KHI A
D B
Thi gian lm bi: 90 pht, khng k

thi gian pht .
( thi c 04 trang)
(60 cu trc nghim)
M thi 860
H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
H = 1; He= 4 ; C = 12; N = 14; O = 16; F=19; Ne=20; Na = 23; Mg = 24; Al = 27;
S = 32; Cl = 35.5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Br = 80; Ag = 108;Ba =137.
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40):
Cu 1: Cho mt lung kh CO i qua ng s ng m gam Fe2O3 nung nng. Sau mt thi gian thu c
10.44 gam cht rn X gm Fe, FeO, Fe2O3 v Fe3O4 . Ha tan ht X trong dung dch HNO3 c, nng thu
c 4.368 lt NO2 (sn phm kh duy nht iu kin tiu chun). Gi tr ca m l
A. 12
B. 24
C. 10.8
D. 16
Cu 2: t chy hon ton mt hn hp A (glucz, anehit fomic, axit axetic) cn 2.24 lt O 2 (iu
kin tiu chun). Dn sn phm chy qua bnh ng dung dch Ca(OH) 2, thy khi lng bnh tng m
gam. Gi tr ca m l
A. 6.2
B. 4.4
C. 3.1
D. 12.4
Cu 3: Tng s ht ca mt nguyn t X l 28. X l
A. O
B. N
C. F
D. Ne
Cu 4: Bit Cu c s hiu nguyn t l 29. Cu hnh electron ca ion Cu+ l
A. [Ar]3d104s1
B. [Ar]3d94s1
C. [Ar]3d9
D.[Ar]3d10
Cu 5: Cho phng trnh ho hc:
Al + HNO3 Al(NO3)3 + NO + N2O + H2O (Bit t l th tch N2O: NO = 1 : 3) Sau khi cn bng
phng trnh ho hc trn vi h s cc cht l nhng s nguyn, ti gin th h s ca HNO3 l
A. 66
B. 60
C. 64
D. 62
Cu 6: a mt hn hp kh N2 v H2 c t l 1: 3 vo thp tng hp, sau phn ng thy th tch kh i
ra gim 1/10 so vi ban u. Tnh thnh phn phn trm v th tch ca hn hp kh sau phn ng.
A. 20%, 60%, 20%
B. 22.22%, 66.67%, 11.11%
C. 30%, 60%, 10%
D. 33.33%, 50%, 16.67%
Cu 7: Dy gm cc cht no sau y u c tnh lng tnh ?
A. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2
B. H2O, Zn(OH)2, CH3COONH4, H2NCH2COOH, NaHCO3
C. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO
D. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH
Cu 8: C 4 dung dch trong sut , mi dung dch ch cha mt cation v mt loi anion. Cc loi ion
trong c 4 dung dch gm: Ba2+, Mg2+, Pb2+, Na+, SO42-, Cl-, CO32-, NO3-. l 4 dung dch g?
A. BaCl2, MgSO4, Na2CO3, Pb(NO3)2
B. BaCO3, MgSO4, NaCl, Pb(NO3)2
C. BaCl2, PbSO4, MgCl2, Na2CO3
D. Mg(NO3)2, BaCl2, Na2CO3, PbSO4
Cu 9: Khi nhit phn hon ton 100 gam mi cht sau: KClO 3 (xc tc MnO2), KMnO4, KNO3 v AgNO3.
Cht to ra lng O2 t nht l
A. KClO3
B. KMnO4
C. KNO3
D. AgNO3
Cu 10: Pht biu no sau y l ng:
A. Photpho trng c cu trc mng tinh th nguyn t, photpho c cu trc polime
B. Nitrophotka l hn hp ca NH4H2PO4 v KNO3
C. Thy tinh lng l dung dch m c ca Na2SiO3 v K2SiO3
D. Cacbon monooxit v silic ioxit l oxit axit
Cu 11: Cho cc kim loi: Cr, W , Fe , Cu , Cs . Sp xp theo chiu tng dn cng t tri sang phi l
A. Cu < Cs < Fe < W < Cr
B. Cs < Cu < Fe < W < Cr
Thng k H 2007-2014
C. Cu < Cs < Fe < Cr < W

D. Cs < Cu < Fe < Cr < W
Cu 12: Ho tan 5.4 gam bt Al vo 150 ml dung dch A cha Fe(NO3)3 1M v Cu(NO3)2 1M. Kt thc
phn ng thu c m gam rn. Gi tr ca m l
A. 10.95
B. 13.20
C. 13.80
D. 15.20
Cu 13: A l hn hp kh gm SO2 v CO2 c t khi hi so vi H2 l 27. Dn a mol hn hp kh A qua
bnh ng 1 lt dung dch NaOH 1.5a M, sau phn ng c cn dung dch thu c m gam mui. Biu
thc lin h gia m v a l
A. m=105a
B. m=103.5a
C. m=116a
D. m=141a
Cu 14: Sc V lt CO2 ( iu kin tiu chun) vo 200 ml dung dch X gm Ba(OH) 2 1M v NaOH 1M .
Sau phn ng thu c 19.7 gam kt ta, gi tr ca V l
A. 2.24 v 4.48
B. 2.24 v 11.2
C. 6.72 v 4.48
D. 5.6 v 11.2
Cu 15: Ho tan ht m gam Al2(SO4)3 vo nc c dd A. Cho 300 ml dung dch NaOH 1M vo A, thu
c a gam kt ta. Mc khc, nu cho 400 ml dung dch NaOH 1M vo A, cng thu c a gam kt
ta. Gi tr ca m l
A. 21.375
B. 42.75
C. 17.1
D. 22.8
Cu 16: A l hn hp cc mui Cu(NO3)2, Fe(NO3)2, Fe(NO3)3, Mg(NO3)2. Trong O chim 9.6% v
khi lng. Cho dung dch KOH d vo dung dch cha 50 gam mui A. Lc kt ta thu c em nung
trong chn khng n khi lng khng i thu c m gam oxit. Gi tr ca m l
A. 47.3
B. 44.6
C. 17.6
D. 39.2
Cu 17: Cho a mol bt km vo dung dch c ha tan b mol Fe(NO 3)3. Tm iu kin lin h gia a v b
sau khi kt thc phn ng khng c kim loi.
A. a 2b
B. b > 3a
C. b 2a
D. b = 2a/3
Cu 18: t chy hon ton 4.872 gam mt Hirocacbon X, dn sn phm chy qua bnh ng dung
dch nc vi trong. Sau phn ng thu c 27.93 gam kt ta v thy khi lng dd gim 5.586 gam.
A. CH4
B. C3H6
C. C4H10
D. C4H8
Cu 19: in phn 2 lt dung dch hn hp gm NaCl v CuSO4 n khi H2O b in phn hai cc th
dng li, ti catt thu 1.28 gam kim loi v ant thu 0.336 lt kh ( iu kin tiu chun). Coi th tch
dung dch khng i th pH ca dung dch thu c bng
A. 12
B. 13
C. 2
D. 3
Cu 20: Cho t t 150 ml dd HCl 1M vo 500 ml dung dch A gm Na2CO3 v NaHCO3 th thu c 1.008 lt kh
(iu kin tiu chun) v dung dch B. Cho dung dch B tc dng vi dung dch Ba(OH)2 d th thu c 29.55
gam kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dung dch A ln lt l:
A. 0.18M v 0.26M
B. 0.21M v 0.18M
C. 0.21M v 0.32M
D. 0.2M v 0.4M
Cu 21: Cho 3.2 gam Cu tc dng vi 100ml dung dch hn hp HNO3 0.8M v H2SO4 0.2M, sn phm kh duy
nht l kh NO. S gam mui khan thu c l
A. 7.90
B. 8.84
C. 5.64
D. 10.08
Cu 22: Hy cho bit, phn ng no sau y HCl ng vai tr l cht oxi ha?
A. Fe + KNO3 + 4HCl FeCl3 + KCl + NO + 2H2O
B. MnO2 + 4HCl MnCl2 + Cl2 + 2H2O
C. Fe + 2HCl FeCl2 + H2
D. NaOH + HCl NaCl + H2O
Cu 23 : Cho hn hp kim loi Mg, Zn, Fe vo dung dch cha AgNO3 v Cu(NO3)2.. Sau khi phn ng xy ra hon
ton thu c dung dch X gm 3 mui v cht rn Y gm ba kim loi. Ba mui trong X l
A. Mg(NO3)2, Fe(NO3)3, AgNO3
B. Mg(NO3)2, Zn(NO3)2, Cu(NO3)2
C. Mg(NO3)2, Zn(NO3)2, Fe(NO3)3
D. Mg(NO3)2, Zn(NO3)2, Fe(NO3)2
Cu 24: Cho 6.4 gam dung dch ru A c nng 71.875% tc dng vi lng d Na thu c 2.8 lt H2 iu
kin tiu chun. S nguyn t H c trong cng thc phn t ru A l
A. 4
B. 6
C. 8
D. 10
Cu 25: Cho cc cng thc phn t sau : C3H7Cl , C3H8O v C3H9N. Hy cho bit s sp xp no sau y theo chiu
tng dn s lng ng phn ng vi cc cng thc phn t ?
A. C3H7Cl < C3H8O < C3H9N
B. C3H8O < C3H9N < C3H7Cl
C. C3H8O < C3H7Cl < C3H9N
D. C3H7Cl < C3H9N < C3H8O
Cu 26: Cho 2.46 gam hn hp gm HCOOH, CH3COOH, C6H5OH, H2NCH2COOH tc dng va vi 40 ml
dung dch NaOH 1M. Tng khi lng mui khan thu c sau khi phn ng l
A. 3.52 gam
B. 6.45 gam
C. 8.42 gam
D. 3.34 gam
Thng k H 2007-2014
Cu 27: Dy cc cht u lm mt mu dung dch thuc tm l

A. Etilen, axetilen, anehit fomic, toluen B. Axeton, etilen, anehit axetic, cumen
C. Benzen, but-1-en, axit fomic, p-xilen D. Xiclobutan, but-1-in, m-xilen, axit axetic
Cu 28: t chy 1.6 gam mt este E n chc c 3.52 gam CO2 v 1.152 gam H2O. Nu cho 10 gam
E tc dng vi 150ml dung dch NaOH 1M , c cn dung dch sau phn ng thu c 16 gam cht rn
khan . Vy cng thc ca axit to nn este trn c th l
A. CH2=CH-COOH
B. CH2=C(CH3)-COOH
C. HOOC(CH2)3CH2OH
D. HOOC-CH2-CH(OH)-CH3
Cu 29: Cht bo A c ch s axit l 7. x phng ho 10 kg A, ngi ta un nng n vi dung dch
cha 1.420 kg NaOH. Sau khi phn ng xy ra hon ton trung ho hn hp, cn dng 500ml dung
dch HCl 1M. Khi lng x phng (kg) thu c l
A. 10.3425
B. 10.3435
C. 10.3445
D. 10.3455
Cu 30: Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l
A. Gly, Ala, Glu, Tyr
B. Gly, Val, Tyr, Ala
C. Gly, Val , Lys, Ala
D. Gly, Ala, Glu, Lys
Cu 31: Cho 29.8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung
dch thu c 51.7 gam mui khan. Cng thc phn t 2 amin l
A. CH5N v C2H7N
B. C2H7N v C3H9N
C. C3H9N v C4H11N
D. C3H7N v C4H9N
Cu 32: Cho cc cht : amoniac (1) ; anilin (2) ; p-nitroanilin (3) ; p-metylanilin (4) ; metylamin
(5) ; imetylamin (6) . Hy chn s sp xp cc cht trn theo th t lc baz tng dn .
A . (3) < (2) < (4) < (1) < (5) < (6)
B . (2) > (3) > (4) > (1) > (5) > (6)
C . (2) < (3) < (4) < (1) < (5) < (6)
D . (3) < (1) < (4) <(2) < (5) < (6)
Cu 33: Thy phn 34.2 gam mantz vi hiu sut 50%. Sau tin hnh phn ng trng bc vi
dung dch thu c. Khi lng Ag kt ta l
A. 43.2 gam
B. 32.4 gam
C. 21.6 gam
D. 10.8 gam
Cu 34: C 45.75 gam cao su buna-S phn ng va ht vi 20 gam brom trong CCl4. T l mt xch butaien v
stiren trong cao su buna-S l
A. 1 : 3
B. 1 : 2
C. 2 : 3
D. 3 : 5
Cu 35: Cho cc cht sau : axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic,
metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l
A. 8
B. 7
C. 5
D. 6
Cu 36: nhn bit ba l mt nhn: phenol, stiren, ancol benzylic, ta dng mt thuc th duy nht l
A. Nc brom
B. Dung dch NaOH
C. Na
D. Ca(OH)2
Cu 37: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3.75. Dn X qua Ni nung nng, thu c hn hp
kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l
A. 40%
B. 50%
C. 25%
D. 20%
Cu 38: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l:
A. CH3CHO, C2H5OH, C2H5COOCH3.
B. C2H4(OH)2, CH3OH, CH3CHO.
C. CH3CHO, C6H12O6 (glucoz), CH3OH.
D. CH3OH, C2H5OH, CH3CHO.
Cu 39: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol),
C6H6(benzen), CH3CHO. S cht trong dy phn ng c vi nc brom l
A. 5
B. 6
C. 7
D. 8
Cu 40: Ru X, anehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t, thuc cc dy ng ng no
n chc mch h. t hon ton hn hp 3 cht ny (c s mol bng nhau) thu c t l mol
CO2:H2O=11:12 . Vy cng thc phn t ca X, Y, Z l:
A. CH4O, C2H4O, C2H4O2
B. C2H6O, C3H6O, C3H6O2
C. C3H8O, C4H8O, C4H8O2
D. C4H10O, C5H10O, C5H10O2
II. PHN RING [10 cu] :Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Cho cc dung dch sau: Na2CO3, NaOH v CH3COONa c cng nng mol/l v c cc gi tr pH tng
ng l pH1, pH2 v pH3. S sp xp no ng vi trnh t tng dn pH.
A. pH3 < pH1 < pH2
B. pH3< pH2 < pH1
C. pH1 < pH3 < pH2 D. pH1 < pH2 < pH3
Cu 42: Cho 13.8 gam axit A tc dng vi 16.8 gam KOH , c cn dung dch sau phn ng thu c 26.46 gam
cht rn. cng thc cu to thu gn ca A l
A. C3H6COOH
B. C2H5COOH
C. CH3COOH
D. HCOOH
Cu 43: Chn pht biu ng:
A. Tnh oxi ha ca Ag+ > Cu2+ > Fe3+ > Ni2+ > Fe2+
B. Tnh kh ca K > Mg > Zn > Ni > Fe > Hg
C. Tnh Kh ca K > Fe > Cu > I- > Fe2+ > Ag
D. Tnh oxi ha ca Ag+ > I2 > Fe3+ > Cu2+ > S
Thng k H 2007-2014
Cu 44: Cn ti thiu bao nhiu gam NaOH (m1) v Cl2 (m2) phn ng hon ton vi 0.01 mol CrCl3. Gi tr
ca m1 v m2 ln lt l
A. 3.2 v 1.065
B. 3.2 v 0.5325
C. 6.4 v 0.5325
D. 6.4 v 1.065
Cu 45: Ch dng mt thuc th phn bit cc kim loi sau: Mg, Zn, Fe, Ba?
A. Dung dch NaOH
B. Dung dch H2SO4 long
C. Dung dch HCl D. Nc
Cu 46: t chy hon ton 1 mol ancol no A cn 3.5 mol O2. Cng thc phn t ca A l
A. C2H6O
B. C2H6O2
C. C3H8O3
D. C3H6O2
Cu 47: Cho 0.1 mol cht X ( CH6O3N2) tc dng vi dung dch cha 0.2 mol NaOH un nng thu c cht kh
lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m l
A. 8.5
B. 12.5
C. 15
D. 21.8
Cu 48: Ho tan 19.2 gam Cu vo 500 ml dung dch NaNO3 1M, sau thm vo 500ml dung dch HCl 2M . Kt
thc phn ng thu c dung dch X v kh NO duy nht, phi thm bao nhiu ml dung dch NaOH 1M vo X
kt ta ht ion Cu2+
A. 600
B. 800
C. 400
D. 120
Cu 49: Thy phn hon ton mt lng mantoz, sau cho ton b lng glucoz thu c ln men thnh
ancol etylic th thu c 100 ml ancol 460. Khi lng ring ca ancol l 0,8gam/ml. Hp th ton b kh CO2vo
dung dch NaOH d thu c mui c khi lng l
A. 106 gam
B. 84.8 gam
C. 212 gam
D. 169.6 gam
Cu 50: Hirat ho 3.36 lt C2H2 ( iu kin tiu chun) thu c hn hp A ( hiu sut phn ng 60%) . Cho hn
hp sn phm A tc dng vi dung dch Ag2O/NH3 d thu c m gam cht rn. Gi tr ca m l
A. 19.44
B. 33.84
C. 14.4
D. 48.24
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Xt phn ng thun nghch sau:
SO2(k) + NO2(k) SO3(k) + NO(k).
Cho 0.11(mol) SO2, 0.1(mol) NO2, 0.07(mol) SO3 vo bnh kn 1 lt. Khi t cn bng ha hc th cn li 0.02(mol)
NO2. Vy hng s cn bng KC l
A. 18
B. 20
C. 23
D. 0.05
Cu 52: Cho Na d tc dng vi a gam dung dch CH3COOH. Kt thc phn ng, thy khi lng H2 sinh ra l
11a
. Vy nng C% dung dch axit l
240
A. 10%
B. 25%
C. 4.58%
D. 36%
Cu 53: Cho 0.1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc
dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32.4 gam Ag. Hai anehit trong X l
A. CH3CHO v C2H5CHO.
B. CH3CHO v C3H5CHO.
C. HCHO v CH3CHO.
D. HCHO v C2H5CHO.
Cu 54: Dy gm cc kim loi u tc dng c vi dung dch FeCl3 l:
A. Fe, Mg, Cu, Ag, Al
B. Fe, Zn, Cu, Al, Mg
C. Cu, Ag, Au, Mg, Fe
D. Au, Cu, Al, Mg, Zn
Cu 55: Cn bao nhiu a mol K2Cr2O7 v b mol HCl iu ch c 3.36 lit Cl2 iu kin tiu chun. Gi tr a v
b ln lt l:
A. 0.05 v 0.7
B. 0.05 v 0.35
C. 0.1 v 0.7
D. 0.1 v 0.35
Cu 56: Ha tan hon ton hn hp gm FeS2 0.24 mol v Cu2S vo dung dch HNO3 va thu c dung dch
X (ch cha hai mui sunfat) v V lt kh NO duy nht . Gi tr ca V l
A. 34.048
B. 35.84
C. 31.36
D. 25.088
Cu 57: nhn bit cc kh: CO2, SO2, H2S, N2 cn dng cc dung dch:
A. Nc brom v NaOH
B. NaOH v Ca(OH)2
C. Nc brom v Ca(OH)2
D. KMnO4 v NaOH
Cu 58: t chy hon ton 1 mol ancol no A cn 2.5 mol O2. Cng thc phn t cu A l
A. C2H6O
B. C2H6O2
C. C3H8O3
D. C3H6O2
Cu 59: Cho 20 gam hn hp 3 amin no n chc l ng ng k tip c t l mol tng ng l 1: 10 : 5, tc
dng va vi dung dch HCl thu c 31.68 gam hn hp mui. Tng s ng phn ca 3 amin trn l
A. 7
B. 14
C. 28
D. 16
Cu 60: Ln men m gam glucz vi hiu sut 90%, lng CO2 sinh ra hp th ht vo nc vi trong thu c
15 gam kt ta v khi lng dung dch gim 5.1 gam. Gi tr m l
A. 20.25
B. 22.5
C. 30
D. 45
----------- HT ----------
Thng k H 2007-2014
MT S CNG THC S DNG TRONG GII TON HA HC

I. Cng thc tnh s mol
1. Mi cht
2. Cht kh
3. Cht tan trong dd
II. Nng dung dch
1. Nng mol
2. Nng %
m
M
P.V
V
v n=
n=
R.T
22,4
n = CM.V
n=
n
V
m
C%= ct .100%
mdd
CM =
m
V
10.C%.d
CM =
M
3. Khi lng ring
d=
4. Quan h gia CM v C%
5. Quan h gia tan v C%
100.C%
T
T=
.100
v C%=
100-C%
100+T
III. T khi hi ca kh A so vi kh B
d A/B =
MA
MB
IV. Cng thc Faraday

A.I.t
I.t
I.t
m=
hoc n=
hoc n e trao oi =
N.F
N.F
F
V. Hng s cn bng ca phn ng thun nghch mA + n B pC + qD
[C]p .[D]q
KC =
[A]m .[B]n
VI. Tc tc thi ca phn ng ha hc mA + n B pC + qD
v=k.[A]m.[B]n
VII. Khi lng mol trung bnh ca hn hp
m
M .n +M1 .n 2 +...+Mn .n n
M= hh = 1 1
n hh
n1 +n2 +...+n n
VIII. ru
V
D0 = ruou .100 o
Vdd ruou
TNH TAN CA MUI V BAZ

- Cc baz u khng tan, tr NaOH, KOH, Ca(OH)2, Ba(OH)2 (ngoi ra cn LiOH, RbOH,...)
- Mui ca kim loi kim nh Na, K v NH4 u tan
- Mui nitrat v axetat u tan
- Mui cacbonat, photphat, sunfit u khng tan
- Mui clorua (hoc bromua, iotua) u tan tr AgCl, PbCl2
- Mui sunfat u tan tr BaSO4, CaSO4, PbSO4 v Ag2SO4
Thng k H 2007-2014
KHI LNG MOL NGUYN T V PHN T

I. Khi lng mol nguyn t v phn t hp cht v c
Phi kim
Kim loi
Oxit
M
Hidroxit, M
Gc
mui
axit
Nguyn
M
Nguyn t M
t
H
1
Na (I)
23
NO
30
HCl
36,5
NO3
C
12
Mg (II)
24
NO2
46
HNO3
63
CO3
N
14
Al (III)
27
CO2
44
H2SO4
98
PO4
O
16
K (I)
39
SO2
64
H3PO4
98
SO4
F
19
Ca (II)
40
MgO
40
NaOH
40
P
31
Fe (II, III)
56
CaO
56
KOH
56
S
32
Cu (II)
64
Al2O3 102 Al(OH)3
78
Cl
35,5 Zn (II)
65
FeO
72
Zn(OH)2 99
Br
80
Ag (I)
108 Fe2O3 160 CaCO3
100
I
127 Ba (II)
137 Fe3O4 232 BaSO4
233
II. Khi lng mol phn t hp cht hu c
CH4
16
C6H6
78
CH4O
32
CH2O2
46
C2H6
30
C2H4
28
C2H6O
46
C2H4O2 60
C6H10O5
C3H8
44
C3H6
42
C3H8O
60
C3H6O2 64
C6H12O6
C4H10
58
C4H8
56
C4H10O 74
C4H8O2 88
C12H22O11
62
60
95
96
162
180
342
GC HIDROCACBON, NHM CHC

MT S POLIME V VT LIU POLIME THNG DNG
Polime
Cng
thc iu ch
polime
Polietiten
PE
TH
Poli(vinyl clorua)
PVC
TH
Polistiren
PS
TH
T nitron (t olon)
TH
Poli(metyl
PMMA
TH
metacrylat)
Cao su isopren
TH
Cao su cloropren
TH
Cao su Buna
TH
Cao su Buna-S
TH
Cao su Buna-N
TH
Poli(phenolTN
fomandehit)
Poli(ure-fomandehit)
TN
T nilon-6,6
TN
T capron (t nilonTH
6)
T enang (t nilon-7)
TN
T lapsan
TN
Monome
u
ban
Thng k H 2007-2014
DANH PHP THNG THNG

Cng thc
HCOOH
CH3COOH
C2H5COOH
C3H7COOH
C4H9COOH
C15H31COOH
C17H31COOH
C17H33COOH
C17H35COOH
C6H5COOH
CH2=CHCOOH
CH2=C(CH3)COOH
HOOC-COOH
HOOC-CH2-COOH
HOOC-[CH2]4-COOH
o,p-(NO2)3C6H3OH
Tn gi
axit fomic
axit axetic
axit propionic
axit butiric
axit valeric
axit panmitic
axit linoleic
axit oleic
axit stearic
axit bezoic
axit acrylic
axit metacrylic
axit oxalic
Axit malonic
Axit aipic
Axit picric
Cng thc
C2H4
C2H2
C6H6
C6H5CH3
HOCH2-CH2OH
HOCH2-CH(OH)-CH2OH
CH3COCH3
C6H5NH2
H2NCH2COOH
CH3CH(NH2)COOH
(CH3)2CH(NH2)COOH
HOOC-[CH2]2CH(NH2)COOH
H2N[CH2]4CH(NH2)COOH
Tn gi
etilen
axetilen
benzen
Toluen
Etilen glicol
Glixerol
Axeton
Anilin
Glyxin
Alanin
Valin
Axit glutamic
Lysin
Thng k H 2007-2014
NHN BIT CC CHT

A. TRNG THI, MU SC CC N CHT, HP CHT
Cr(OH)2 : vng
HgI2
Cr(OH) 3 : xanh
CuS, NiS, FeS, PbS, : en
K2Cr2O7 : da cam
: rn, en
KMnO4
: tm
: rn, vng
CrO3
: rn, thm
: rn, trng, , en
Zn
: trng xanh
Fe
: trng xm
Zn(OH)2 : trng
FeO
: rn, en
Hg
: lng, trng bc
Fe3O4
: rn, en
HgO
: mu vng hoc
Fe2O3
: mu nu
Mn
: trng bc
Fe(OH)2 : rn, mu trng xanh
MnO
: xm lc nht
Fe(OH)3 : rn, nu
MnS
: hng nht
Al(OH)3 : mu trng, dng keo tan trong
MnO2
: en
NaOH
H2S
: kh khng mu
Zn(OH)2 : mu trng, tan trong NaOH
SO2
: kh khng mu
Mg(OH)2 : mu trng.
SO3
: lng, khong mu, si 450C
Cu:
: rn,
Cu2O:
: rn,
: rn, en
Br2
: lng, nu
CuO
I2
: rn, tm
Cu(OH)2 : xanh lam
Cl2
: kh, vng
CuCl2, Cu(NO3) 2, CuSO4.5H2O : xanh
CdS
: vng
CuSO4
: khan, mu trng
HgS
FeCl3
: vng
AgF
: tan
CrO
: rn, en
AgCl
: mu trng
Cr2O3
: rn, xanh thm
AgBr
: vng nht
BaSO4
: trng, khng tan trong axit.
AgI
: vng m
BaCO3, CaCO3: trng
Thng k H 2007-2014
B. NHN BIT CHT KH

Kh
SO2
Thuc th
Hin tng
- Qu tm m
- H2S, CO, Mg,
Ha hng
Kt ta vng
- dd Br2,
ddI2,
dd KMnO4
Mt mu
- nc vi trong
Lm c
SO2 + Ca(OH)2 CaSO3 + H2O
- Qu tm m
Lc u lm mt
mu, sau xut
hin mu
Cl2 + H2O HCl + HClO
- dd KI+h tinh bt
Khng mu xm
- h tinh bt
Mu xanh tm
- Qu tm m
Ha xanh
- kh HCl
To khi trng
NH3 + HCl NH4Cl
- Oxi khng kh
Khng mu nu
2NH + O2 2NO2
- dd FeSO4 20%
Mu thm
NO + ddFeSO4 20% Fe(NO)(SO4)
Cl2
I2
NH3
NO
NO2
CO2
Phn ng
SO2 + H2S 2S + 2H2O
SO2 + Br2 + 2H2O 2HBr + H2SO4
SO2 + I2 + 2H2O 2HI + H2SO4
SO2 + 2KMnO4 + 2H2O 2H2SO4 + 2MnSO4 + K2SO4
as
[O] O2
HClO HCl + [O] ;
Cl2 + 2KI 2KCl + I2

H tinh bt + I2 dd mu xanh tm
- Kh mu nu, lm qu tm ha
3NO2 + H2O 2HNO3 + NO
- nc vi trong
Lm c
CO2 + Ca(OH)2 CaCO3 + H2O
- qu tm m
Ha hng
- khng duy tr s chy

CO
H2
O2
HCl
- dd PdCl2
, bt kh CO2
CO + PdCl2 + H2O Pd + 2HCl + CO2
- CuO (t0)
Mu en
t
CO + CuO (en)
Cu () + CO2
- t c ting n. Cho sn phm vo CuSO4

khan khng mu to thnh mu xanh
- CuO (t0)
CuO (en) Cu
()
- Que dim
Bng chy
- Cu (t0)
Cu() CuO (en)
- Qu tm m
Ha
- AgCl
Kt ta trng
- Qu tm m
- O2
Cl2
SO2
FeCl3
Ha hng
CuSO4 + 5H2O CuSO4.5H2O

0
t
H2 + CuO(en)
Cu() + H2O
t
Cu + O2
CuO
HCl + AgNO3 AgCl+ HNO3
- PbCl2
Kt ta en
2H2S + O2 2S + 2H2O
H2S + Cl2 S + 2HCl
2H2S + SO2 3S + 2H2O
H2S + 2FeCl3 2FeCl2 + S + 2HCl
3H2S+2KMnO42MnO2+3S+2KOH+2H2O
5H2S+2KMnO4+3H2SO42MnSO4+5S+K2SO4+8H2O
H2S + Pb(NO3)2 PbS+ 2HNO3
H2O(Hi)
CuSO4 khan
Trng ha xanh
CuSO4 + 5H2O CuSO4.5H2O
O3
dd KI
Kt ta tm
KI + O3 + H2O I2 + 2KOH + O2
H2S
Kt ta vng
KMnO4
Thng k H 2007-2014
C. NHN BIT ION DNG (CATION)

Ion
Thuc th
Hin tng
Li+
Na+
K+
Ca2+
Ba2+
t
trn ngn la
v sc
Ngn la mu thm
Ngn la mu vng ti
Ngn la mu tm hng
Ngn la mu da cam
Ngn la mu lc (hi vng)
Ca2+
dd SO24 , dd CO32
trng
Ba2+
dd SO24 , dd CO32
trng
Ag+
Pb2+
dd KI
Ca2+ + SO24 CaSO4 ;Ca2+ + CO32 CaCO3

Ba2+ + SO24 BaSO4 ;Ba2+ + CO32 BaCO3
Ba2+
CrO24
BaCrO4
AgCl trng
AgBr vng nht
AgI vng m
Ag+
Ag+
Ag+
+
+
+
Cl
Br
I
AgCl
AgBr
AgI
PbI2 vng
Pb2+
2I
PbI2
2I
HgI2
S2
PbS
S2
HgS
FeS
S2
CuS
Na2CrO4
HCl, HBr, HI
NaCl, NaBr,
NaI
Phn ng
HgI2
Hg2+
Pb2+
PbS en
Pb2+
Hg2+
HgS
Hg2+
Hg2+
FeS en
Fe2+
CuS en
Cu2+
Ni2+
+
+
S2
Ni2+
CdS vng
NiS en
Cd2+
S2
CdS
NiS
Mn2+
MnS hng nht
Mn2+
S2
MnS
Zn2+
xanh, tan trong dd NH3 d
Cu(OH)2
+ 4NH3 [Cu(NH3)4](OH)2
Fe2+
Cu2+
Na2S, H2S
Cd2+
trng, tan trong dd NH3 d
Zn(OH)2
+ 4NH3 [Cu(NH3)4](OH)2
Ag+
trng, tan trong dd NH3 d
AgOH
+ 2NH3 [Ag(NH3)2]OH
Mg2+
trng
Mg2+
Fe2+
trng,
ha nu ngoi khng kh
Fe2+
+
2OH Fe(OH)2
4Fe(OH)2 + O2 + 2H2O 4Fe(OH)3
Fe3+
nu
Fe3+
3OH
Fe(OH)3
Al3+
keo trng
tan trong kim d
Al3+
3OH
Al(OH)3
Cu2+
Zn2+
Be2+
dd NH3
2OH
Al(OH)3 + OH
Zn2+
AlO2
Zn(OH)2 + 2OH
dd Kim
trng
tan trong kim d
Be2+
Be(OH)2 + 2OH
Pb(OH)2 + 2OH
xm, tan trong kim d
Cu2+
xanh
Cr3+
BeO22
2OH
Cr3+
ZnO22
2OH
Pb2+
Pb2+
+ 2H2O
2OH
PbO22
3OH
Mn(OH)2
Zn(OH)2
+ 2H2O
Be(OH)2
+ 2H2O
Pb(OH)2
+ 2H2O
Cr(OH)3
3
Cr(OH)3 + 3OH [ Cr(OH)6 ]
Cu2+
2OH
Cu(OH)2
Thng k H 2007-2014
NH 4
NH3
NH4 + OH
NH3 + H2O
Thng k H 2007-2014
D. NHN BIT ION M (ANION)

Ion
Thuc th
Hin tng
OH
Qu tm
Ha xanh
Phn ng
Cl
trng
Cl + Ag+
AgCl (ha en ngoi nh sng)
Br
vng nht
Br + Ag+
AgBr (ha en ngoi nh sng)
vng m
I + Ag+
AgI (ha en ngoi nh sng)
PO 34
vng
PO34 + 3Ag+ Ag3PO4
en
S2 + 2Ag+
CO23
trng
CO32 + Ba2+ BaCO3 (tan trong HCl)
SO 23
trng
SO32 + Ba2+
BaSO3 (tan trong HCl)
trng
SO24 + Ba2+
BaSO4 (khng tan trong HCl)
vng
CrO24 + Ba2+ BaCrO4
en
S2 + Pb2+
PbS
CO23
Si bt kh
CO32 + 2H+
CO2 + H2O (khng mi)
SO 23
Si bt kh
SO32 + 2H+
SO2 + H2O (mi hc)
Si bt kh
S2 + 2H+
H2S (mi trng thi)
SiO 23
keo
SiO32 + 2H+
H2SiO3
HCO 23
Si bt kh
2 HCO3
CO2 + CO3 + H2O
Si bt kh
t
2 HSO3
SO2 + SO3 + H2O
AgNO3
BaCl2
SO 4
CrO 24
S
Ag2S
Pb(NO3)2
HCl
HSO 3
un nng
NO 3
Cu, H2SO4
Kh mu nu
H2SO4
Kh mu nu do
HNO2 phn tch
NO 2
NO3 + H+
HNO3
3Cu + 8HNO3
2NO + O2
2Cu(NO3)2 + 2NO+4H2O
2NO2
2 NO2 + H+
HNO2
3HNO2
2NO + O2
2NO + HNO3 + H2O

2NO2

Dap An Thong Ke 007-2014 - Du Doan de Thi - H 2015

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Dap An Thong Ke 007-2014 - Du Doan de Thi - H 2015

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Thng k H 2007-2014

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

A. HNO3, NaCl, Na2SO4.

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

A. CH3CHO, C2H5OH, C2H6, CH3COOH.

Cn v s kiu bi tng t na trong cun sch ny, hy cho mnh c c hi khm ph

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

Ti sao cc Thy khng lm tt c cc bi nhng c th lm bt c bi no trong

V mt ln na ti chc mng bn s hu B kp tuyt vi ny!

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

6.3. KIM LOI KIM tc dng vi H2O ................................................................................ 43

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

14. ESTE, LIPIT ........................................................................................................................ 86

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

Cu 1. (A-10) 32: Nhn nh no sau y ng khi ni v 3 nguyn t: 13 X, 26Y, 12 Z ?

Cu 4. (A-11) 42: Cu hnh electron ca ion Cu2+ v Cr3+ ln lt l

1.2. V tr nguyn t trong bng tun hon, nh lut tun hon

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

Cu 13. (C -14): 26 Cation R+ c cu hnh electron 1s22s22p63s23p6. V tr ca nguyn t R trong

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

1.3. Bi ton oxit, hp cht vi Hiro, ng v

1.4. Lin kt ha hc, cu trc mng tinh th

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

2. PHN NG OXI HA KH,

Cu 1. (A-07): Cho cc p sau:

(c) Fe3O4 + 4CO 3Fe + 4CO2.

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

(e) Al + H2SO4 (long)

(d) Cu + H2SO4 (c)

(g) FeSO4 + KMnO4 + H2SO4

S phn ng m H+ ca axit ng vai tr cht oxi ho l

(c) 2KMnO4 + 16HCl 2KCl + 2MnCl2 + 5Cl2 + 8H2O.

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

2.2. Cn bng phn ng oxi ha kh

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

dFe2(SO4)3 + eK2SO4 + fCr2(SO4)3 + gH2O.

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

2.4. Chuyn dch cn bng ha hc

Cn bng trn chuyn dch theo chiu thun khi

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

3. S IN LY- pH DUNG DCH

3.2. Phn ng ion trong dung dch

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

B. Cl; Na+; NO3- v Ag+.

C. K+; Mg2+; OH v NO3- .

(2) CuSO4 + Ba(NO3) 2

(3) Na2SO4 + BaCl2

(4) H2SO4 + BaSO3

(5) (NH4) 2SO4 + Ba(OH) 2

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

(d) KHSO4 + KHS K2SO4 + H2S

Cu 35. (A-08) 28: Trn ln V ml dd NaOH 0,01M vi V ml dd HCl 0,03 M c 2V ml dd Y. Dd Y

3.4. Tnh theo phng trnh ion, nh lut bo ton in tch

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

2Na2S + Na2S2O3 + 3H2O.

[D ON THI THPT QUC GIA NM 2015 MN HA HC]

C. O2, nc brom, dung dch KMnO4.