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H ni, ngy 25 thng 6 nm 2015

Khai thc bi tp PEPTIT: X l dng ton t chy hn hp mui.

Dng 1: gi thit lin quan n sn phm t chy: Na2CO3; CO2. H2O v N2.
|| x l: vit CTPT + bin i: nhn ra tng quan CO2 v H2O gii quyt.!
Cu 1. [198168]: Thy phn m gam hn hp X gm mt tetrapeptit Y v mt pentapeptit Z bng dung dch
NaOH va ri c cn thu c (m + 23,7) gam hn hp mui ca Gly v Ala. t chy ton b lng mui
sinh ra bng mt lng oxi va thu c Na2CO3 v hn hp hi T gm CO2, H2O v N2. Dn ton b hn
hp hi T i rt chm qua bnh ng dung dch NaOH c d thy khi lng bnh tng 84,06 gam v c 7,392
lt mt kh duy nht (ktc) thot ra khi bnh. Thnh phn phn trm khi lng ca Y trong hn hp X c gi
tr gn nht vi (bit thy phn Y hay Z u thu c Gly v Ala)
A. 53%.
B. 54%.
C. 55%.
D. 56%.
HD: mui dng CnH2nNO2Na = .C2n-1H4n.N2.O.Na2CO3.
|| t C2n-1H4n.N2.O.Na2CO3 cho 0,33 mol N2 v (CO2 + H2O) = 84,06 gam.
|| c h s mol CO2 v H2O
|| c h s mol Gly v Ala

y x 0,33
44 x 18 y 84, 06
2 x 3 y 1,59
x y 0,33 2

x
y
x
y

1, 26
.
1,59

0,39
0, 27

Thy phn: BTKL nH2O = nX = (0,66 40 23,7) 18 = 0,15 mol.

|| c h s mol tetrapeptit Y4 v pentapeptit Z5

x y 0,15
4 x 5 y 0, 66

x
y

0, 09
0, 06

|| mmui = m + 23,7 = 0,39 (75 + 22) + 0,27 (89 + 22) || m = 44,1 gam.
Gi s c 0,09 mol Y4 l (Gly)a-(Ala)4a v 0,06 mol Z5 l (Gly) b(Ala)5b
|| c 0,09a + 0,06b = Gly = 0,39 mol 3a + 2b = 13. Ch c cp nghim a = 3; b = 2
(do thy phn Y, Z u cho Gly, Ala nn 1 a 3 v 1 b 4).
|| Y l (Gly)3(Ala)1 %Y trong X = 0,09 (75 3 + 89 1 18 3) 44,1 53,06%. Chn A. .
Cu 2. [192049]: X v Y l hai peptit c to t cc -amino axit no, mch h cha 1 nhm NH2 v 1 nhm
COOH. un nng 0,1 mol hn hp E cha X, Y bng dung dch NaOH (va ). C cn dung dch sau phn
ng thu c m gam mui khan. t chy ton b lng mui ny thu c 0,2 mol Na2CO3 v hn hp gm
CO2, H2O, N2 trong tng khi lng ca CO2 v H2O l 65,6 gam. Mt khc t chy 1,51m gam hn hp E
cn dng a mol O2, thu c CO2, H2O v N2. Gi tr ca a gn nht vi
A. 2,5.
B. 1,5.
C. 3,5.
D. 3,0.
HD: Mui dng CnH2nNO2Na C2n 1H4n.N2O.Na2CO3; m Na2CO3 c 0,2 mol
|| T CTPT ny cho ta cc thng tin: s mol 0,2; t l H2O CO2 = 0,2 mol.
kt hp khi lng = 65,6 gam gii ra 1 mol CO2 v 1,2 mol H2O.
s Ctb = 3, gi tr ca m = 0,4 (89 + 22) = 44,4 gam.
Bo ton O2 cn t 0,1 mol E = t 0,4 mol C3H7NO2 = t 0,2 mol C6H12N2O3
im lng O2 cn t u bng (0,2 6 3 0,2 3) 3 = 1,5 mol.
Vic cn li l xem xt t l gia 2 phn: c 0,1 mol E mE = 44,4 + 0,1 18 0,2 2 40 = 30,2 gam
c 1,51 44,4 30,2 = 2,22 || dng gp 2,22 ln O2 cn t c gi tr 1,5 2,22 = 3,33.
Vy gi tr ca a gn nht vi 3,5. Ta chn p n C. .
Cu 3. [203538]: Thy phn hon ton m gam hn hp M gm tetrapeptit X v pentapeptit Y (u mch h)
bng dung dch KOH va , ri c cn cn thn th thu c (m + 11,42) gam hn hp mui khan ca Val v

Bin son: Phm Hng Vng.

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H ni, ngy 25 thng 6 nm 2015

Ala. t chy hon ton mui sinh ra bng mt lng oxi va thu c K2CO3 ; 2,464 lt N2 (ktc) v 50,96
gam hn hp gm CO2 v H2O. Phn trm khi lng ca Y trong hn hp M c th l
A. 55,24%.
B. 54,54%.
C. 45,98%.
D. 64,59%.
HD: t mui 2CnH2nNO2 K = K2CO3.N2.C2n1H4n + O2 K2CO3 + 0,11 mol N2 + 50,96 gam {CO2 + H2O}.
Theo c ngay h

44 x 18 y 50,96
y x 0,11

x
y

0, 79
x y 0,11 2
. Gii h Val, Ala
0,9
5 x 3 y 0,9

x
y

0,12
0,1

C x mol X4 + y mol Y5 + (4x + 5y) mol KOH 0,12 mol (Val-K) + 0,1 mol (Ala-K) + (x + y) mol H2O.
|| c h:

4x

5y

m tang

0,12
11, 42

0,1
0, 22 56 18 x

0, 03

0, 02

. BTKL m = 19,88 gam.

0,03 mol ValaAla4-a + 0,02 mol ValbAla5-b. || c 3a + 2b = 12.

cp a = 2, b = 3 tha mn || Y5 l Ala2Val3 || mY = 9,14 gam || %Y trong M 45,98 %. Chn C. .
Cp b = 0, a = 4 cng tha mn nhng ra p n khc.
Dng 2: Lin quan n O2 cn t.
|| X l: quan st phng trnh: cn v khng cn chuyn i cht t.
Cu 4. [204219]: Hn hp E gm peptit X (CnHmOzN4) v peptit Y (CxHyO7Nt) u mch h, cu to t cc
aminoaxit no cha 1 nhm NH2, 1 nhm COOH. Cho hn hp E phn ng vi 2 lt dung dch NaOH 0,65M
thu c dung dch Z. trung ha Z cn 100 ml dung dch HCl 2M. C cn dung dch sau phn ng thu c
m gam mui. t chy hon ton m gam mui trn cn 177,6 gam O2. Gi tr gn nht vi m l
A. 137.
B. 147.
C. 157.
D. 127.
HD: E phn ng va 1,1 mol NaOH || c 0,55 mol ipeptit E2 dng C2nH4nN2O3.
phng trnh thy phn: E2 + 2NaOH mui + H2O.
NaCl, NaOH, H2O u t chy khng cn O2 nn t mui v t E2 u cn cng 5,55 mol O2 nh nhau.
|| bo ton O t E2 cho CO2 = H2O = (0,55 3 + 5,55 2) 3 = 4,25 mol n = 85/22.
C 1,1 mol mui hu c dng CnH2nNO2Na mmui hu c = 1,1 (14n + 46 + 23) = 135,4 gam.
|| m = 135,4 + 0,2 58,5 = 147,1 gam (trnh qun mui v c NaCl) chn p n B. .
Cu 5. (TM): Hn hp E cha peptit X mch h (to bi glyxin v alanin) v este Y mch h (c to bi
etylen glicol v mt axit n chc, khng no cha mt lin kt C=C). un nng hn hp E vi dung dch
NaOH va thu c 23,08 gam hn hp mui F, trong c cha a gam mui glyxin v b gam mui alanin.
Ly ton b F em t chy thu c Na2CO3; N2; 23,76 gam CO2 v 7,56 gam H2O. Mt khc cng em t
cng lng E trn cn dng 0,89 mol O2. T l gn ng ca a : b l.
A. 2,5.
B. 2,8.
C. 2,4.
D. 2,6.
HD: Gi s mol mui axit l 2x mol etilen glicol l x mol; i din mui 2 amino axit l y mol.
t F c t l: nCO2 nH2O = 2x .y = 0,12 mol.
Ch : t E cn 0,89 mol O2; x mol etilen glicol cn 2,5x mol O2; cn li H2O; NaOH khng cn.
|| t F cn (0,89 2,5x) mol O2; N2 c .y mol; (x + .y) mol Na2CO3.
Bo ton khi lng || 23,08 + 32.(0,89 2,5x) = (x + .y).106 + 14y + 31,32.
Gii h c x = y = 0,08 mol. Bin lun: s Cmui axit (0,54 + 0,12 0,08 2) 0,16 = 3,125
M axit khng no, 1 ni i C=C || s C = 3. || mmui gly + ala = 8,04 gam.
Gii h c 0,06 mol Gly v 0,02 mol Ala a : b 2,62. Chn p n D. .!

Bin son: Phm Hng Vng.