T chn Ha 12

Ngy son: 04/8/2013

TC 2: LUYN TP V ESTE
I. MC TIU :
K nng :
- Vit c cng thc cu to ca este c ti a 4 nguyn t cacbon.
- Vit cc phng trnh ho hc minh ho tnh cht ho hc ca este no, n chc.
- Phn bit c este vi cc cht khc nh ancol, axit,... bng phng php ho hc.
II. PHNG PHP :
m thoi gi m, s dng bi tp ha hc.
III. T CHC HOT NG DY HC :
1. n nh t chc
2. Bi mi :
Hot ng ca gv
Cu hi v bi tp nh tnh:
Cu 1: Chn cu tr li chnh xc nht:
A. Este l sn phm ca phn ng este ha gia cc cht hu c v ru.
B. Este l sn phm ca phn ng gia axit v c vi ru.
C. Este l sn phm ca phn ng cng gia axit hu c vi ru.
D. Este l sn phm ca phn ng este ha gia axit v c hoc hu c vi
ru.
Cu 2: Cng thc tng qut ca este no n chc l:
A. CnH2nO2(n 2).
D. CnH2nO(n 1).
B. CnH2n-2O2(n 1).
C. CnH2n+2O2(n 1).
Cu 3: Mt hp cht A c cng thc C3H4O2. A tc dng c vi dung
dch Br2, NaOH, AgNO3/NH3, nhng khng tc dng c vi Na. Cng
thc cu to ca A phi l:
A. HCOOCH=CH2.
B. CH3COOCH3.
C. CH2=CHCOOH.
D. HCOOCH2CH3.
Cu 4: Etilenglicol tc dng vi hn hp 2 axit CH 3COOH v HCOOH th
s thu c bao nhiu este ch cha chc este:
A. 1.
B. 2.
C. 3.
D. 4.
Cu 5: Este metyl metacrylat c iu ch t:
A. Axit acrylic v ru metylic.
B. Axit acrylic v ru etylic.
C. Axit metacrylic v ru etylic.
D. Axit metacrylic v ru metylic.
Cu 6: Este metyl metacrylat c dng sn xut:
A. Thuc tr su.
C. Cao su.
B. Thy tinh hu c.
D. T tng hp.
Cu 7: tinh ch CH3COOH c ln C2H5OH ngi ta lm nh sau:
1

hs
Cu 1: C

Cu 2: A
Cu 3: a

Cu 4: C
Cu 5: D

Cu 6: B
Cu 7: D

T chn Ha 12
A. Cho hn hp tc dng vi NaOH d, c cn ly sn phm cho tc dng
vi H2SO4 ta thu c axit axetic.
B. Cho hn hp tc dng vi Na d, c cn ly sn phm cho tc dng vi
H2SO4 ta thu c axit axetic
C. Cho hn hp tc dng vi K 2CO3 d, c cn ly sn phm cho tc dng
vi H2SO4 ta thu c axit axetic
D. C A,C.
Cu 8: Trong phn ng este ha giu ru v axit hu c th cn bng s
chuyn dch theo chiu to ra este khi ta:
A. Chng ct ngay tch este.
B. Cho ru d hay axit d.
C. Dng cht ht nc tch nc.
D. C ba bin php A ,B,C.
Cu 9: Dng ha cht g phn bit cc mu th mt nhn cha: Metyl
fomiat v etyl axetat.
A. AgNO3/NH3.
C. Na2CO3.
B. Cu(OH)2/NaOH.
D. A v B.
Cu 10: Dng ha cht g phn bit vinyl fomiat v metyl fomiat?
A. AgNO3/NH3.
B. Cu(OH)2/NaOH.
C. Dung dch Br2.
D. A v C.
Cu 11: Este C4H8O2 c gc ru l metyl th cng thc cu to ca este
l :
A. CH3COOC2H5.
C. HCOOC3H7.
B. C2H5COOCH3.
D. C2H3COOCH3.
Cu 12: Cho este c cng thc phn t l C 4H6O2 c gc ru l metyl th
tn gi ca axit tng ng ca n l:
A. Axit acrylic.
D. Axit oxalic.
B. Axit axetic.
C. Axit propionic.
Cu 13: Hp cht no sau y khng phi l este?
A. C2H5COOC2H5
C. HCOOCH3.
B. CH3CH2CH2COOCH3.
D. C2H5COCH3.
Cu 14: Vinyl axetat phn ng c vi cht no trong s cc cht sau
y:
A. Dung dch Br2.
B. NaOH.
C. Na.
D. C A v B ng.
Cu 15: Vinyl fomiat phn ng c vi cht no trong s cc cht sau
y:
A. AgNO3/NH3.
C. NaOH.
B. Cu(OH)2/NaOH.
D. C 3 cu trn.
Cu 16: Mt hp cht B c cng thc C4H8O2. B tc dng c vi
NaOH, AgNO3/NH3, nhng khng tc dng c vi Na. Cng thc cu
to ca B phi l:
2

Cu 8: D

Cu 9: D
Cu 10: C
Cu 11: B
Cu 12: A

Cu 13: D
Cu 14: D
Cu 15: D

Cu 16: A

Cu 17: D

T chn Ha 12
A. HCOOCH(CH3)2.
C. C2H5COOCH3.
B.CH3 COOCH2CH3.
D.CH3CH2 COOCH3.
Cu 17: Cho cc phn ng sau:
Askt
CH3COOH + Cl2 ClCH2COOH + HCl(1)
HCOOH + 1/2O2 CO2 + H2O
(2)
H2SO4 c
CH3COOH+C2H5OH CH3COOC2H5+H2O (3)
C2H5Cl + H2O
C2H5OH+HCl
(4)
Hy cho bit phn ng no l phn ng este ha?
A. (1) v (4).
C. (2) v (3).
B. (2) v (4).
D. (3).

Hot ng 2.
GV giao bi tp HS lm
1/Vit cc CTCT cc este ng phn ca C4H8O2 v gi tn.Nhng este no c kh nng
tham gia phn ng trng gng
2/ bi tp t tn gi vit CTCT
Metyl fomat,vinyl axetat
Etyl propionat ,metyl acrylat
Bi 1.
HCOOCH(CH3)2 isopropyl fomat
HCOOCH2CH2CH3 propyl fomat
CH3COOC2H5 etyl axetat
C2H5COOCH3 metyl propionate
Bi 2
HCOOCH3,CH3COOCH=CH2
C2H5COOC2H5,CH2=CH-COOCH3
Rt kinh nghim:

T chn Ha 12
Ngy son 10/8/2013 TC 3: BI TP V ESTE-CHT BO
A.Mc tiu:
1.Kin thc :
-n tp v cng c cc kin thc v este cht bo
2.K nng:
-Rn luyn k nng vit PTHH ,bi tp v cht bo
B.Phng php: m thoi bi tp
C.Chun b :
-Hc sinh n lai cc kin thc v este cht bo
D.T chc cc hot ng dy hc
Hot ng ca thy v tr
Ni dung c bn
Hot ng 1
Gv giao bi tp hn hp 2 este
Bi 1. x phng ho hon ton
19,4g hn hp 2 este n chc
A,B cn 200ml dung dch NaOH
1M .Sau khi phn ng xy ra hon
ton ,c cn dung dch thu c
hn hp 2 ancol l ng ng k
tip nhau v 1 mui khan duy nht
.Xc nh CTCT,gi tn ,% mi
este

Bi 2 .Thu phn hon ton hn

hp gm 2 este n chc X,Y l
ng ng cu to ca nhau cn
100ml dung dch NaOH 1M ,thu
c 7,85ghn hp 2 mui ca 2
axit l ng ng k tipv 4,95g
2 ancol bc 1.Xc nh CTCT ,%
mi este trong hn hp
Hot ng 2 Gv giao bi tp v
cht bo
Hs lm gv cha b xung
Bi 3
un nng 4,45kg cht bo
(tristearin)c cha 20% tp cht
vi dung dch NaOH.

I.Bi tp hn hp este
Bi 1
Hai este c cng gc axit v cng to ra 1 mui sau
khi x phng ho .t CT chung ca 2 este l
RCOOR
RCOOR + NaOH RCOONa + ROH
Ta c MRCOOR =19,4/0,3=64,67g/mol
Hay MR+MR=20,67.Vy 2 ancol l CH3OH,C2H5OH
CTCT ca 2 este l HCOOCH3v HCOOC2H5
%HCOOCH3=61,85%
%HCOOC2H5=38,15%
Bi 2 .Theo nh lut
BTKL :meste=8,8g,neste=0,1mol,CTPT l C4H8O2
RCOOR + NaOH RCOONa +ROH
MRCOONa =78,5g/mol ,vy 2 axit l
HCOOH,CH3COOH ,m 2 ancol l bc 1 nn CTCT
ca 2 este l HCOOCH2CH2CH3v CH3COOC2H5
II. Bi tp v cht bo

Bi 3
(C17H35COO)3C3H5+ 3NaOH C3H5(OH)3
+C17H35COOH
Khi lng glixerol thu c
l:3,56.92.85%/890=0,3128kg
4

T chn Ha 12
Tnh khi lng glixerol thu
c ,bit h=85%

Bi 4
(C17H33COO)3C3H5+ 3H2 (C17H35COO)3C3H5
Bi 4. Tnh th tch H2 thu c Th tch H2 cn : 1 tn .3.22,4/884=76018lit
ktc cn hirhoa 1 tn
glixerol trioleat nh cht xc tc
l Ni,gi s H =100%
Bi 5
nKOH =0,1.0,09=0,009mol
mKOH =0,009.56=0,504g=504mg
Bi 5. Khi x phng ho hon
Ch s x phng ho : 504/2,52=200
ton 2,52g cht bo A cn 90ml
Khi lng glixerol thu c khi xphng ho 2,52g
dung dch KOH 0,1M.Mt khc
cht bo l 0,53.2,52/5,04=0,265g
,khi x phng ho hon ton 5,04g (RCOO)3C3H5+3KOHC3H5(OH)3+3RCOOH
cht bo A thu c 0,53g
3.56(g) 92(g)
glixerol.Tnh ch s axit v ch ss
m (g)
0,265(g)
x phng ho
m=0,484g=484mg
ch s axit : 504-484/2,52=8

Hot ng 3: Cng c kin thc

Rt kinh nghim:

T chn Ha 12
Ngy son : 8/9/2012
TC 4: GLUCOZO
A.Mc tiu:
1.Kin thc:
-cng c v khc su kin thc v glucozo,tnh cht ho hc ca glucozo
2.k nng:
-lm bi tp v glucozo,saccarozo nhn bit.
B.Phng php : m thoi bi tp
C.Chun b : hc sinh n tp cc kin thc v glucozo
D.T chc cc hot ng dy hc
Hot ng ca thy v tr
Ni dung
Hot ng 1
Hc sinh n li khi nim
I. Glucozo : C6H12O6(M=180g/mol)
cacbohirat,tnh cht ca glucozo
CTCT: CH2OH-(CHOH)4-CHO
Fructozo CH2OH-(CHOH)3-CO-CH2OH
* T/c: tnh cht ca ancol a chc v t/c ca
anehit
Hot ng 2
Trong mi trng bazo : G F
Gv yu cu hs lm bi tp v glucozo
II Bi tp v glucozo
Bi 1 .un nng dung dch cha 18g
Bi 1
glucozo vi dung dch AgNO3/NH3 va Ta c s mol Ag = s mol AgNO3=2 s mol
,bit rng cc phn ng xy ra hon glucozo=0,2 mol
ton .Tnh khi lng Ag v AgNO3
Vy :
-Hs ln bng lm
mAg=0,2.108=21,6g,mAgNO3=0,2.170=34g
_Gv cha b xung
Bi 2 .Ln men m(g) glucozo thnh
ancol etylic vi H=80%.Hp th hon
ton kh sinh ra vo dung dch Ca(OH)2
d thu c 20g kt ta .Tnh m

Bi 3. Kh glucozo bng H2 to
sobitol . to ra 1,82g sobitol vi
H=80%.Tnh khi lng glucozo cn
dng

Hot ng 3 .Cng c

Bi 2
C6H12O6 2 C2H5OH + 2CO2
CO2+ Ca(OH)2 CaCO3 + H2O
S mol glucozo =1/2 s mol
CaCO3=0,1mol.vy s g glucozo
=0,1.180.100/80=22,5g
Bi 3
C6H12O6 +H2 C6H12O6
180
182
x
1,82
khi lng glucozo l
1,82.180.100/182.80=2,24g

HS tr li cc cu hi trc nghim sau

6

T chn Ha 12
Cu1 .Trng hp no sau y c hm lng glucozo ln nht?
A.mu ngi
B .Mt ong
C.dung dch huyt thanh
D. qu nho chn
Cu2. Thuc th no sau y dng nhn bit cc dung dch :
glixerol,fomanehit,glucozo,ancol etylic
A.AgNO3/NH3
B.Na
C.nc brom D.Cu(OH)2/NaOH
Rt kinh nghim:

T chn Ha 12
Ngy son 12/9/2012
TC 5:
BI TP V SACCAROZ-TINH BT-XENLULOZO
A.Mc tiu
1.kin thc:
-Cng c v khc su kin thc v saccaroz tinh bt ,xenlulozo
2.k nng:
-k nng lm bi tp v tinh bt v xenlulozo
B.Phng php: m thoi bi tp
C.T chc cc hot ng dy hc
Hot ng ca thy v tr

Ni dung

Hot ng1
Gv giao bi tp v saccarozo
Hs lm gv cha b xung
Bi 1. Thu phn hon ton 1 kg
saccarozo thu c m(g)
glucozo.Tnh m

IV.Bi tp v saccarozo
Bi 1
C12H22O11+H2O C6H12O6+C6H12O6
342
180(g)
1kg
x(kg)
m =1.180/342=0,526kg

Bi 2. Nc ma cha khong
13% saccarozo.Bit H ca qu
trnh tinh ch l 75%.Tnh khi
lng saccarozo thu c khi tinh
ch 1 tn nc ma trn.GV yu
cu HS n tp cc kin thc v
tinh bt v xenloluzo
HS trao i nhm thy r s
ging v khc nhau v cu to v
tnh cht ca tinh bt v xenloluzo

Bi 2
Lng saccarozo trong 1 tn nc ma
l:1000.13/100=130g
Lng saccarozo thu c sau khi tinh ch l:
130.75/100=97,5g
I.So snh s ging v khc nhau v cu trc phn
t ,tnh cht ca tinh bt v xenloluzo

Hot ng 2
GV giao bi tp v tinh bt
Bi 1. Thu phn 1kg sn cha
20% tinh bt trong mi trng
axit vi hiu sut 85%.Tnh khi
lng glucozo thu c
_HS nhn bi tp v lm
-GV cha b xung

II Bi tp v tinh bt
Bi 1
Khi lng tinh bt trong 1kg sn l:
1000.20/100=200g
(C6H10O5)n +n H2O nC6H12O6
162n
180n
200g
Khi lng glucozo thu c l
180.200.85/162.100=188.89g
8

T chn Ha 12
Bi 2. Cho m(g) tinhbt sn
xut ancol etylic,ton b lng
kh sinh ra uc dn vo dung
dch Ca(OH)2 d thu c 500g
kt ta .Bit hiu sut ca mi
giai on l 75%.Tnh m
Hot ng 3 .GV giao bi tp v
xenlulozo
-HS nhn bi tp v lm

Bi 2 . S bin i cc cht
(C6H10O5)nC6H12O62nCO22nCaCO3
162n
200g(h=100 )
V H =75% nn khi lng CaCO3 thc t thu
c l 200.0,75.0,75.0,75=84,375g
thu c 500g CaCO3 th khi lng tinh bt
cn dng l: 500.162/84,375=960g
III.Bi tp v xenlulozo

Bi 1 .Dng 324kg xenlulozo v

420kg HNO3 nguyn ch c th
thu c ? tn xenlulozo
trinirat,bit s hao ht trong qu
trnh sn sut l 20%

Bi 1 .
[C6H7O2(OH)3]n3nHNO3[C6H7O2(ONO2)3]n
+3nH2O
Theo PT khi lng HNO3 d ,nn khi lng sn
phm tnh theo xenlulozo
324.297.80/162.100=475,2kg=0,4752tn

Bi 2. Khi lng phn t trung

bnh ca xenlulozo trong si bng
l 4860000.Tnh ss gc glucozo
c trong si bng trn

Bi 2. S gc glucozo l: 48600000/162=300000

Hot ng 4 .Cng c
Rt kinh nghim:

T chn Ha 12
Ngy son 16/9/2012
TC 6:
LUYN TP CHNG I-II
A.Mc tiu
1.kin thc :
- cng c v khc su kin thc v este-lipit-cacbohirat
-tnh cht ho hc c trng ca cc hp cht trn
2.k nng : rn lun k nng lm bi tp t lun v trc nghim
B.Phng php: m thoi bi tp
C.T chc cc hot ng dy hc
Hot ng ca thy v tr
Ni dung
Hot ng 1
GV yu cu HS trao i nhm cc kin thc
I.Kin thc
v este,lipit,cacbohirat : CTCT,tnh cht ,iu
ch
Hot ng 2
GV yu cu HS lm cc bi tp v este,lipit

II. Bi tp

-HS nhn bi tp v lm
-GV nhn xt v b xung

Bi 1.
RCOOR+NaOHRCOONa+ROH
Bi 1.Khi x phng ha hon ton 6g mt este S mol RCOOK=s mol
n chc cn 100ml dung dch KOH 1M ,c
KOH=0,1mol.Vy
cn sn phm thu c 8,4g mui khan.Xc
MRCOOK=8,4/0,1=84,vy R l H
nh CTCT v gi tn
MRCOOR=6/0,1=60,R l CH3
Este l: HCOOCH3 metyl axetat
Bi 2
-Hs lm bi tp 2 gv cha b xung
RCOOR+NaOHRCOONa+ROH
HCl + NaOH NaCl + H2O
Bi 2.
S mol NaOH d =s mol
Thu phn hon ton 2,2g mt este n chc HCl=0,075mol,khi lng
bng 100ml NaOH 1M.Sau phi thm vo RCOONa=6,4375-0,075.58,5=2,05g
75ml dung dch HCl1M trung ho NaOH
MRCOONa=2,05/0,025=82,vy R l CH3.
d,sau cn cn thn thu c 6,43 75ghn Ta c : MRCOOR=2,2/0,025=88,R l C2H5
hp 2 mui khan ,x c nh cng thc cu
.CTCT l CH3COOC2H5 etyl axetat.
to,gi tn este trn

Bi 3
C6H12O62CO2 + 2C2H5OH
CO2 + Ca(CO3)2CaCO3+H2O
S mol glucozo=1/2 s mol CaCO3 =0,2
mol.Khi lng glucozo cn dng l:
10

T chn Ha 12
Bi 3
0,2 .180.100/70=51,4g
Cho glucozo ln men thnh ancol etylic,ton
Th tch dung dch
b lngkh sinh ra c hp th ht vo dung Ca(OH)2=0,4/1=0,4lit
dch Ca(OH)2
ly d thu c 40g kt ta.Tnh khi lng
glucozo cn dng ,bit hiu sut phn ng t
70%
-Tnh th tch dung dch Ca(OH)21M dng

Hot ng 3: HS lm bi tp trc nghim

.
Cu 1:
nhn bit glucozo v glierol dng thuc th no sau y:
A.Cu(OH)2
B.AgNO3(NH3,t0) C.Na
D.H2SO4
Cu 2: C3H6O2c bao nhiu CTCT cng tc dng vi dung dch NaOH?
A.2
B.3
C.4
D.5
Cu 3: Khi t chy hon ton 1este thu c s mol CO2bng s mol H2O th o l :
A.este n chc
B.este no n chc
C.este khng no
D.trieste.
Cu 4: Khi thu phn vinyl axetat trong mi trng axit s thu c:
A.axit axetic v ancol ety lic
B.axit axetic v ancol vinylic
C. axaxetic v andehit axetic
D.axit foocmic v ancol etylic
Cu 5;Phn ng no sau y dng sn xut x phng:
A.un nng dung dch axit vi dung dch kim.
B.un nng cht bo vi dung dch kim
C.un nng glixerol vi axit
D.A,C u ng
Cu 6.un nng 9g axit axetic vi 9g ancol etylic (H2SO4 c) thu c m(g) este vi hiu
sut phn ng t 80%.Gi tr ca m l:
A.13,2g
B.16,5g
C.10,56g
D.21,53g.
Cu 7. trng 1 ci gng ht 5,4g Ag ,ngi ta dng mg glucozo .gi tr ca m l:
A.4,5g
B.18g
C..9g
D.8,55g
Cu 8. phn ng thu phn tinh bt xy ra trong mi trng:
A.axit
B.bazo
C.trung tnh
D.kim nh
Rt kinh nghim:

11

T chn Ha 12
Ngy son 20/9/2012
TC 7: LUYN TP TP V AMIN
A.Mc tiu:
1.kin thc:
-cng c v khc su kin thc v amin,tnh cht ho hc ca amin
2.k nng :
-rn luyn k nng lm bi tpt lun v trc nghim
B.Phng php: m thoi-bi tp
C.T chc cc hot ng dy hc
Hoat ng ca thy v tr
Ni dung
Hot ng 1
GV cho HS trao i nhm v
I.Bi tp v amin
CTCT,tnh cht ho hc ca amin
Hot ng 2
GV giao bi tp v amin ,HS lm
Bi 1.Trung ho 50ml dung dch
metyl amin cn 30ml dung dch
HCl 0,1M.Gi s th tch khng
thay i,tnh nng mol/l ca
metyl amin
-GV cha b sung
Bi 2.Cho nc brom d vo
aniline thu c 16,5g kt
ta.Tnh khi lng aniline trong
dung dch.
-HS nhn bi tp v lm ,GV
cha
Bi 3
.Cho 1,395g anilin tc dng hon
ton vi 0,2l dung dch HCl
1M .Tnh khi lng mui thu
c

Bi 1
nHCl=0,1.0,03=0,003mol
CH3NH2 + HCl CH3NH3Cl
0,003
0,003
CM=0,003/0,05=0,06M
Bi 2
C6H5NH2+Br2 C6H2Br3NH2
S mol 2,4,6-tribromanilin=16,5/330=0,05mol
Khi lng aniline thu c l: 93.0,05=4,65g

Bi 3
S mol anilin=1,395/93=0,015mol
S mol HCl=0,2mol
C6H5NH2+HCl C6H5NH3Cl
0,015
0,015
Khi lng mui thu c l:0,015.129,5=1,9425g

Hot ng 3
HS lm bi tp trc nghim
Cu 1.Cht no sau y c lc bazo ln nht ?
12

T chn Ha 12
A.NH3
B.C6H5NH2
C .(CH3)3N
D,(CH3)2NH
Cu2.Dy cc amin c xp theo chiu tng dn lc bazo l:
A.C6H5NH2,CH3NH2,(CH3)2NH
B.CH3NH2,(CH3)2NH,C6H5NH2
C.C6H5NH2,(CH3)2NH,CH3NH2
D.CH3NH2,C6H5NH2,(CH3)2NH
Cu 3.Phn ng ca aniline vi dung dch brom chng t
A.nhm chc v gc hirocacbon c nh hng qua lai ln nhau
B.Nhm chc v gc hiroccbon khng c nh hng qua li ln nhau
C.nhm chc nh hng n t/c ca gc hirocacbon
D.gc hirocacbon nh hng n nhm chc
Cu4.Ho cht c th dng nhn bit phenol v aniline l:
A.dung dch brom.
B .H2O
C.Na
D.dung dch HCl
Cu5 . Amin n chc c 19,178% nito v khi lng .CTPT ca amin l:
A.C4H5N
B.C4H7N
C.C4H11N
D.C4H9N
Rt kinh nghim:

13

T chn Ha 12
Ngy 22/9/2012
TC 8
LUYN TP V AMINO AXIT
I.Mc tiu
1.Kin thc :
- cng c v khc su kin thc v amino axit,tnh cht ca amino axit
2.K nng:
-rn luyn k nng lm bi tp
II.Phng php: m thoi-bi tp
III.Chun b: HS n tp li cc kin thc v amino axit
IV.T chc cc hot ng dy hc
Hot ng ca thy v tr
Ni dung
Hot ng 1
I.
Kin thc c bn
GV yu cu HS trao i nhm v
II.Bi tp v amin
amin,tnh cht ca amin
Bi 1
Gi CTG ca A l CxHyOzNt
Hot ng 2
Ta c
GV giao bi tp v amin HS nhn
x:y:z:t=40,4/12:7,9/1:36/16:15,7/14=3:7:2:1
bi tp v lm
Cng thc phn t ca A l ( C3H7O2N)n
Bi 1. Mt amino axit A c 40,4%
=89.Vy n=1
C,7,9%H,15,7%N,36%O v khi
Cng thc phn t l C3H7O2N
lng v M=89g/mol.Xc nh
CTPT ca A
-GV nhn xt v b sung
Bi 2.Cho 0,1molamino axit A phn
ng va vi 100ml dung dch
HCl 2M .Mt khc 18g A cng phn
ng va vi 200ml dung dch
HCl trn.Xc nh khi lng phn
t ca A
Bi 3.X l 1 amino axit,khi cho
0,01mol X tc dng vi HCl th
dng ht 80ml dung dch HCl
0,125M v thu c 1,835g mui
khan,Khi cho 0,01mol X tc dng
vi dung dch NaOH th cn dng
25g dung dch NaOH 3,2% .Xc
nh CTPT v CTCT ca X

Bi 2
Ta c 0,1 mol A phn ng va vi 0,2mol
HCl.Mt khc 18g A cng phn ng va
0,4mol HCl trn.Vy A c khi lng phn t
l; 18/0,2= 90g/mol
Bi 3
S mol HCl=s mol X=0,01mol.X c 1 nhm
NH2
RNH2 + HCl RNH3Cl
0,01
0,01
m X=m m-m HCl=1,835-36,5.0,02=1,47g
MX=147g/mol
n NaOH=2nX=0,01mol,vy X c 2 nhm COOH
v X c dng R(NH2)(COOH)2,do R l C3H5

Hot ng 3
HS lm bi tp trc nghim
14

T chn Ha 12
Cu1. chng minh amino axit l hp cht lng tnh,ta c th dng phn ng ca cht
ny vi
A.dung dch KOH v CuO
B.dung dch KOH v HCl
C.dung dch NaOH v NH3
D.dung dch HCl v Na2SO4
Cu 2.Phn bit 3 dung dch : H2N-CH2-COOH,CH3COOH v C2H5NH2, ch cn dng
thuc th l:
A.dung dch HCl
B.Na
C.qu tm
C.dung dch NaOH Cau Cu
3.Pht biu no sau y l ng
A.Amino axit l hp cht a chc c 2 nhm chc
B.Amino axit l hp cht tp chc c 1nhom COOH v 1 nhm NH2
C.Amino axit l hp cht tp chc c 2nhm COOH v 1 nhm NH2
D.Amino axit l hp cht tp chc cha ng thi 2 nhm chc NH2v COOH
Cu 4.Cho m (g) anilin tc dung vi dung dch HCl d .C cn dung dch sau phn ng
thu c 15,54g mui khan .Hiu sut phn ng 80% th gi tr ca m l
A.11,16g
B.12,5g
C.8,928g
D.13,95g
Cu 5. tch ring hn hp benzene,phenol,aniline ta dng cc ho cht no (cc dng
c y )
A.dung dch bom,NaOH,kh CO2
B.dung dch NaOH,NaCl,kh CO2
C.dung dch brom,HCl,kh CO2
D.dung dch NaOH,HCl,kh CO2
Rt kinh nghim:

15

T chn Ha 12
Ngy son 26/9/2012 TC 9: BI TP V PEPTIT-PROTEIN
I.Mc tiu
1.Kin thc:
Cng c v khc su kin thc v peptit-protein,tnh cht ca chng
2.K nng: Rn luyn k nng lm bi tp v peptit-protein
II.Phng php: m thoi-bi tp
III.Chun b : HS n tp cc kin thc v peptit-protein
IV.T chc cc hot ng dy hc
Hot ng ca thy v tr
Ni dung
Hot ng 1
I.Kin thc
GV yu cu HS trao i nhm v cu
to ,tnh cht ca peptit-protein
Hot ng 2
GV giao bi tp v peptit-HS lm
Bi 1.Thc hin phn ng trng ngng
2 amino axit glyxin v alanin thu c
ti a ? i peptit.Vit CTCT v gi tn

II.Bi tp v peptit
Bi 1
H2N-CH2-CO-NH-CH(CH3)-COOH
H2N-CH2-CO-NH-CH2-COOH
H2N-CH(CH3)-CO-NH-CH(CH3)-COOH
Ala-Ala
H2N-CH(CH3)-CO-NH-CH2-COOH
Ala-Gly

-HS lm bi tp 2
Bi 2. Vit cc CTCT v gi tn cc
tripeptit c th hnh thnh t
glyxin,alanin,phenylalanine(C6H5CH2CH(NH2)-COOH)

Bi 2
H2N-CH2-CO-NH-CH(CH3)-CO-NHCH(C6H5CH2)-COOH Gly-Ala-Phe
Gly-Phe-Ala,Ala-Gly-Phe,Ala-Phe-Gly
Phe-Ala-Gly,Phe-Gly-Ala
Ala-Ala-Ala
Bi 3.Thu phn 1kg protein X thu
Bi 3
c 286,5g glyxin.Nu phn t khi
n X1000:50 000=0,02mol
ca X l 50 000 th s mt xch glyxin
n Gly=286,5:75=3,82mol;s mt xch l
trong phn t X l?
3,82:0,02=191
Hot ng 3 HS tr li cu hi trc nghim
Cu 1.Chn cu sai trong cc cu sau
A.phn t cc protit gm cc mch di polipeptit to nn
B.protit rt t tan trong nc v d tan khi un nng
C.khi cho Cu(OH)2 vo lng trng trng thy xut hin mu tm
D.khi nh axit HNO3 vo lng trng trng thy xut hin mu vng
Cu 3.Thu phn hpn ton protit s thu c sn phm
A. amin
B.aminoaxit
C.axit
D.polipeptit
Cu 4 phn bit glixerol,glucozo,lng trng trng ta ch dng
16

T chn Ha 12
A.Cu(OH)2
BAgNO3
C.dung dch brom
D.tt c u sai
Cu 5.mi tanh ca c l hn hp cc amin v 1 s tp cht khc, kh mi tanh ca c
trc khi nu nn:
A.ngm c tht lu trong nc cc amin tan i
B.ra c bng dung dch thuc tm c tnh st trng
C.ra c bng dung dch Na2CO3
D.ra c bng gim n
Cu 6.S ng phn cu to ca peptit c 4 mt xch c to thnh t 4 amino axit khc
nhau l
A.4
B .16
C.24
D.12
Cu 7. Chn pht biu ng trong cc pht biu sau
A.enzim l nhng cht hu ht c bn cht protein,c kh nng xc tc cho cc qu trnh
ho hc,c bit l trong c th sinh vt
B.enzim l nhng protein c kh nng xc tc cho cc qu trnh ho hc,c bit l trong
c th sinh vt
C.enzim l nhng cht khng c bn cht protein, c kh nng xc tc cho cc qu trnh
ho hc,c bit l trong c th sinh vt
D.enzim l nhng cht hu ht khng c bn cht protein.
Rt kinh nghim:

17

T chn Ha 12
Ngy son : 28/9/2012

TC 10: BI TP TNG HP CHNG III

I . Mc tiu :
1. Kin thc : Cng c v khc su kin thc v amin, amino axit, peptit, polime
2. K nng : Rn luyn k nng lm bi tp , k nng lm bi tp nhn bit
II. Phng php : m thoi trao i nhm
III. Chun b : HS n tp cc kin thc v amin,amino axit, polime
IV. T chc cc hot ng dy v hc
Hot ng ca thy v tr
Hot ng 1
HS trao i nhm cc kin thc v
amin, amino axit, peptit, polime
Hot ng 2
GV yu cu HS lm bi tp v amin
- HS lm vic theo nhm v theo yu
cu ca GV
Bi 1 . Cho 1,395g anilin tc dng hon
ton vi 0,2 lit HCl 1M.Tnh khi lng
mui thu c

Ni dung
I. Kin thc

II. Bi tp
Bi tp v amin
Bi 1
S mol C6H5NH2= 1,395: 93=0,15mol
S mol HCl=0,2mol
C6H5NH2 + HCl C6H5NH3Cl
Khi lng mui thu c l :
0,15.129,5=1,9425g

Hot ng 3
Bi 2 .Cho 0,02mol amino axit A tc
dng va vi 80ml dung dch HCl
0,25 M.C cn hn hp sau phn ng
thu c 3,67g mui khan.Xc nh
phn t khi ca A

Bi tp v amino axit
Bi 2
S mol HCl = 0,08.0,25=0,02mol
S mol A= s mol HCl nn A c 1 nhm
NH2
H2NR(COOH)n + HCl
H3NClR(COOH)n
M (mui ) =3.67:0,02=147g/mol

Bi 3.
Este A c iu ch t aminoaxit Y v
ancol etylic. T khi hi ca X so vi
H2 bng 51,5. t chy hon ton 10,3g
X thu c 17,6 g CO2 , 8,1 g H2O ,
1,12lit N2 (ktc) .Xc nh CTCT thu
gn ca A

Bi 3
M X =51,5.2=103
Cng thc ca este c dng :
NH2-R-COOC2H5 m M =103, vy R l
CH2. CTCT l: H2N-CH2-COOC2H5

18

T chn Ha 12
Hot ng 4
GV yu cu HS lm bi tp v polime
HS lm theo yu cu

Bi tp v polimme
Bi 4

Bi 4.
Tin hnh trng hp 41,6g stiren vi
nhit xc tc thch hp . Hn hp sau
phn ng tc dng va vi dung dch
cha 16g brom.Khi lng polime thu
c l ?

S mol stiren : 41,6:104=0,4mol

S mol brom: 16:160=0,1mol.
Hn hp sau phn ng tc dng vi
dung dch brom , vy stiren cn d
C6H5CH=CH2 + Br2 C6H5CHBr-CH2Br
0,1
0,1
S mol stiren trng hp =0,4-0,1=0,3
Khi lng polime=0,3.104=31,2g

Hot ng 5: Cng c kin thc hc

Rt kinh nghim:

19

T chn Ha 12
Ngy son 1/10/2012 TC 11: LUYN TP V POLIME-VT LIU POLIME
1.Kin thc
I.Mc tiu:
- cng c v khc su kin thc v polime, cc phng php iu ch polime
2.K nng -rn luyn k nng lm bi tp v polime
II.Phng php : m thoi- trao i nhm
III.Chun b : HS n tp cc kin thc v polime
IV. T chc cc hot ng dy hc
Hot ng ca thy v tr
Ni dung
Hot ng 1
I.Kin thc c bn
GV yu cu HS trao i nhm v cu
to ,tnh cht ,cch iu ch polime
-HS lm vic theo nhm
-i din cc nhm bo co GV nhn
xt v b sung
Hot ng 2
II.Bi tp
-GV giao bi tp v polime
Bi 1.
Bi 1. T 13kg axetilen c th iu ch nC2H2 nCH2=CHCl(- CH2-CHCl -)n
c ? kg PVC(h=100%)
26n
62,5n
13kg
31,25 kg
Bi 2.H s trng hp ca polietilen
M=984g/mol v ca polisaccarit
M=162000g/mol l ?

Bi 2.ta c (-CH2-CH2-)n =984, n=178

(C6H10O5) =162n=162000, n=1000

Bi 3. Tin hnh trng hp 5,2g stiren.

Hn hp sau phn ng cho tc dng vi
100ml dung dch brom 0,15M, cho tip
dung dch KI d vo th c 0,635g
iot.Tnh khi lng polime to thnh

Bi 3.PTP
:nC6H5CH=CH2(-CH2-CH(C6H5)-)
C6H5CH=CH2 + Br2 C6H5CHBrCH2Br
Br2 + 2KI I2 +2KBr
S mol I2=0,635:254=0,0025mol
S mol brom cn d sau khi phn ng vi
stiren d = 0,0025mol
S mol brom phn ng vi stiten d =0,0150,0025=0,0125mol
Khi lng stiren d =1,3g
Khi lng stiren trng hp = khi lng
polime=5,2-1,3=3.9g

Hot ng 3 HS lm bi tp trc nghim

Cu 1.Cht khng c kh nng tham gia phn ng trng hp l
A.stiren
B.toluen
C.propen
D.isopren
20

T chn Ha 12
Cu 2. Trong cc nhn xt di y ,nhn xt no khng ng
A.cc polime khng bay hi
B.a s cc polime kh ha tan trong dung mi thng thng
C.cc polime khng c nhit nng chy xc nh
D.cc polime u bn vng di tc dng ca axit
Cu 3.T nilon-6,6 thuc loi
A.t nhn to
B .t bn tng hp
C.t thin nhin
D.t tng hp
Cu 4. iu ch polime ngi ta thc hin
A.phn ng cng
B.phn ng trng hp
C.phn ng trng ngng
D.phn ng trng hp hoc trng ngng
Cu 5.c im ca cc monome tham gia phn ng trng hp l
A.phn t phi c lin kt i mch nhnh
B.phn t phi c lin kt i mch chnh
C.phn t phi c cu to mch khng nhnh
D.phn t phi c cu to mch nhnh
Hot ng 4: Cng c kin thc hc
Rt kinh nghim:

21

T chn Ha 12
Ngy son : 15/10/2012
TC 12: N TP CHNG III IV
I . Mc tiu :
1. Kin thc : Cng c v khc su kin thc v amin, amino axit, peptit, polime
2. K nng : Rn luyn k nng lm bi tp , k nng lm bi tp nhn bit
II. Phng php : m thoi trao i nhm
III. Chun b : HS n tp cc kin thc v amin,amino axit, polime
IV. T chc cc hot ng dy v hc
Hot ng ca thy v tr
Hot ng 1
HS trao i nhm cc kin thc v
amin, amino axit, peptit, polime

Ni dung
I. Kin thc

II. Bi tp
Hot ng 2
Bi tp v amin
GV yu cu HS lm bi tp v amin
Bi 1 .4n CnH2n+3 N + (6n +3) O24n
- HS lm vic theo nhm v theo yu
4 (14n + 17)
6n +3
cu ca GV
6,2g
0,45
Bi 1 t chy hon ton 6,2 g amin
CO2 + 2(2n +3) H2O
no , n chc mch h cn 10,08 lit oxi Gii ra ta c n=1. CTCT : CH3NH2
(ktc) . CTCT ca amin l?
Hot ng 3
GV giao bi tp v amino axit- HS lm
vic theo nhm
Bi 2 . Cho 15,1 g amino axit n chc
tc dng vi HCl d thu c 18,75 g
mui . Xc nh CTCT ca amin trn

Hot ng 4
GV yu cu HS lm bi tp v polime
HS lm theo yu cu
Bi 3.
Polime X c phn t khi M=280000
g/mol v h s trng hp l 10000

Hot ng 5

Bi tp v amino axit
Bi 2.
NH2RCOOH + HCl NH3ClRCOOH
Khi lng HCl = 18,75-15,1=3,65g ,
s mol HCl = 0,01mol
Phn t khi ca amino axit=151
M R=151-45-16= 80. Vy R l :C6H5CHCTCT : C6H5 CH(NH2) COOH
Bi tp v polimme
Bi 3
M monome:280000:10000=28
Vy M=28 l C2H4

HS lm bi tp trc nghim
22

T chn Ha 12
1.Anilin khng tc dng vi cht no ?
a. C2H5OH
b.H2SO4
c.HNO2
d.NaCl
2. tch ring tng cht trong hn hp gm benzen , nilin, phenol, ta ch cn dng ho
cht (dng c , k th nghim y )
a.Br2, NaOH ,kh CO2 b.NaOH, NaCl, kh CO2
c. Br2, HCl, kh CO2 d . NaOH, HCl, kh CO2
3. Amin n chc c 19,178% nit v khi lng .CTPT ca amin l
a. C4H5N
b.C4H7N
c.C4H11N
d.C4H9N
4. Cho lng d anilin tc dng hon ton vi dung dch cha 0,1mol H2SO4 long
.Lng mui thu c l:
a.19,1g
b.18,7g
c. 27,6g
d. 28,4g
5. Cho m (g) anilin tc dng vi dung dch HCl d .C cn dung dch sau phn ng thu
c 15,54g mui khan .Hiu sut ca phn ng l 80% th gi tr ca m l:
a.11,16g
b. 12,5g
c.8,928g
d.13,95g
6. Phn bit 3 dung dch : H2NCH2COOH, CH3COOH, C2H5NH2 ch cn dng 1 thuc th
no ?
a. HCl
b.Na
c. qu tm
d. NaOH
7. Cho 0,01mol amino axit X phn ng va vi 0,02mol HCl hoc 0,01mol NaOH
.Cng thc ca X c dng
a. H2NRCOOH b. H2N R (COOH)2 c. (H2N)2R COOH d.(H2N)2R (COOH)2
8. Nha phenol fomanehit c iu ch t phenol v fomanehit bng loi phn ng no
?
a. trao i
b. axit-bazo
c. trng hp
d. trng ngng
9. Khi cho H2N(CH2)6NH2 tc dng vi axit no sau y th to ra nilon-6,6.
a. axit oxalic
b. axit aipic
c. axit malonic
d.axit glutamic
10. Poli(vinyl clorua) c iu ch theo s :
X Y Z PVC
X l cht no trong cc cht sau?
a. metan
b .etan
c. butan
d. propan
Hot ng 6: Cng c kin thc ton bi
Rt kinh nghim:

23