Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

GII TON ESTE

Dng 1: Gii ton l thuyt este
Cu 1: S ng phn este ng vi cng thc phn t C3H6O2 l
A. 5.
B. 4.
C. 2.
D. 3.
Cu 2: S ng phn este ng vi cng thc phn t C4H8O2 l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 3: S ng phn n chc ng vi cng thc phn t C3H6O2 l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 4: S ng phn n chc ng vi cng thc phn t C4H8O2 l
A. 6.
B. 3.
C. 4.
D. 5.
Cu 5: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C 2H4O2 ln lt tc dng vi:
Na, NaOH, NaHCO3. S phn ng xy ra l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 6: Cht X c cng thc phn t C3H6O2, l este ca axit axetic. Cng thc cu to thu gn ca X l
A. C2H5COOH.
B. HO-C2H4-CHO.
C. CH3COOCH3.
D. HCOOC2H5.
Cu 7: Hp cht X c cng thc cu to: CH3CH2COOCH3. Tn gi ca X l:
A. etyl axetat.
B. metyl propionat.
C. metyl axetat.
D. propyl axetat.
Cu 8: Thy phn este E c cng thc phn t C 4H8O2 (c mt H2SO4 long) thu c 2 sn phm hu c X v
Y. T X c th iu ch trc tip ra Y bng mt phn ng duy nht. Tn gi ca E l:
A. metyl propionat.
B. propyl fomat.
C. ancol etylic.
D. etyl axetat.
Cu 9: Este etyl axetat c cng thc l
A. CH3CH2OH.
B. CH3COOH.
C. CH3COOC2H5.
D. CH3CHO.
Cu 10: un nng este HCOOCH3 vi mt lng va dung dch NaOH, sn phm thu c l
A. CH3COONa v C2H5OH.
B. HCOONa v CH3OH.
C. HCOONa v C2H5OH.
D. CH3COONa v CH3OH.
Cu 11: Este etyl fomiat c cng thc l
A. CH3COOCH3.
B. HCOOC2H5.
C. HCOOCH=CH2.
D. HCOOCH3.
Cu 12: un nng este CH3COOC2H5 vi mt lng va dung dch NaOH, sn phm thu c l
A. CH3COONa v CH3OH.
B. CH3COONa v C2H5OH.
C. HCOONa v C2H5OH.
D. C2H5COONa v CH3OH.
Cu 13: Thy phn este X trong mi trng kim, thu c natri axetat v ancol etylic. Cng thc ca X l
A. C2H3COOC2H5.
B. CH3COOCH3.
C. C2H5COOCH3.
D. CH3COOC2H5.
Cu 14: Este metyl acrilat c cng thc l
A. CH3COOCH3.
B. CH3COOCH=CH2.
C. CH2=CHCOOCH3.
D. HCOOCH3.
Cu 15: Este vinyl axetat c cng thc l
A. CH3COOCH3.
B. CH3COOCH=CH2.
C. CH2=CHCOOCH3.
D. HCOOCH3.
Cu 16: un nng este CH3COOCH=CH2 vi mt lng va dung dch NaOH, sn phm thu c l
A. CH2=CHCOONa v CH3OH.
B. CH3COONa v CH3CHO.
C. CH3COONa v CH2=CHOH.
D. C2H5COONa v CH3OH.
Cu 17: un nng este CH2=CHCOOCH3 vi mt lng va dung dch NaOH, sn phm thu c l
A. CH2=CHCOONa v CH3OH.
B. CH3COONa v CH3CHO.
C. CH3COONa v CH2=CHOH.
D. C2H5COONa v CH3OH.
Cu 18: Khi t chy hon ton mt este no, n chc th s mol CO 2 sinh ra bng s mol O 2 phn ng. Tn
gi ca este l
A. n-propyl axetat.
B. metyl axetat.
C. etyl axetat.
D. metyl fomiat.
Cu 19: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X 1 c kh nng phn ng vi: Na,
NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X 1, X2
ln lt l:
A. CH3-COOH, CH3-COO-CH3.
B. (CH3)2CH-OH, H-COO-CH3.
C. H-COO-CH3, CH3-COOH.
D. CH3-COOH, H-COO-CH3.

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

Cu 20: Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng):

Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l:
A. C2H5OH, CH3COOH.
B. CH3COOH, CH3OH.
C. CH3COOH, C2H5OH.
D. C2H4, CH3COOH.
Cu 21: Mt este c cng thc phn t l C 4H6O2, khi thu phn trong mi trng axit thu c axetanehit.
Cng thc cu to thu gn ca este l
A. HCOO-C(CH3)=CH2.
B. HCOO-CH=CH-CH3.
C. CH3COO-CH=CH2.
D. CH2=CH-COO-CH3.
Cu 22: Cho glixerol phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to
ra ti a l
A. 6.
B. 3.
C. 5.
D. 4.
Cu 23: Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni clorua, ancol benzylic,
p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l
A. 4.
B. 6.
C. 5.
D. 3.
Cu 24: Cho dy cc cht: HCHO, CH 3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong
dy tham gia phn ng trng gng l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 25: Cht X c cng thc phn t C 2H4O2, cho cht X tc dng vi dung dch NaOH to ra mui v nc.
Cht X thuc loi
A. ancol no a chc.
B. axit khng no n chc.
C. este no n chc.
D. axit no n chc.
Cu 26: Propyl fomat c iu ch t
A. axit fomic v ancol metylic.
B. axit fomic v ancol propylic.
C. axit axetic v ancol propylic.
D. axit propionic v ancol metylic.
Cu 27: Thu phn este X c CTPT C 4H8O2 trong dung dch NaOH thu c hn hp hai cht hu c Y v Z
trong Y c t khi hi so vi H2 l 16. X c cng thc l
A. HCOOC3H7
B. CH3COOC2H5
C. HCOOC3H5
D. C2H5COOCH3
Cu 28: Hp cht Y c cng thc phn t C 4H8O2. Khi cho Y tc dng vi dung dch NaOH sinh ra cht Z c
cng thc C3H5O2Na. Cng thc cu to ca Y l
A. C2H5COOC2H5.
B. CH3COOC2H5.
C. C2H5COOCH3.
D. HCOOC3H7.
+
Cu 29: Thu phn este c cng thc phn t C4H8O2 (xc tc H , thu c 2 sn phm hu c X v Y. T X c
th iu ch trc tip ra Y. Vy cht X l
A. metanol.
B. etyl axetat
C. axit axetic.
D. etanol.
Cu 30: Cho cc cht: etyl axetat, etanol, axit acrylic, phenol, phenylamoni clorua, phenyl axetat. S cht
tc dng c vi dung dch NaOH l
A. 3.
B. 4.
C. 5.
D. 6.
Cu 31: Cho cc cht: axit propionic (X); axit axetic (Y); ancol etylic (Z) v metyl axetat (T). Dy gm cc cht
c sp xp theo chiu tng dn nhit si l
A. T, Z, Y,X.
B. Z, T, Y, X.
C. T, X, Y, Z.
D. Y, T, X, Z.
Cu 32: Cho tt c cc ng phn n chc, mch h, c cng thc phn t C2H4O2 ln lt tc dng vi: Na,
NaOH, NaHCO3. S phn ng xy ra l
A. 2.
B. 3.
C. 4.
D. 5
Cu 33: Pht biu no di y ng ?
A. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ancol.
B. Khi thy phn cht bo lun thu c C2H4(OH)2.
C. Phn ng gia axit v ancol khi c H2SO4 c l phn ng mt chiu.
D. Phn ng thy phn este trong mi trng axit l phn ng thun nghch
Cu 34: Este X c cc c im sau:
- t chy hon ton X to thnh CO2 v H2O c s mol bng nhau;
- Thu phn X trong mi trng axit c cht Y (tham gi phn ng trng bc) v cht Z (c s nguyn t

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

cacbon bng mt na s nguyn t cacbon trong X).

Pht biu no di y khng ng ?
A. Cht X thuc loi este no, n chc.
B. Cht Y tan v hn trong nc.
C. un Z vi dung dch H2SO4 c 170C thu c anken.
D. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O.
Cu 35: C cc cht mt nhn ring bit sau: etyl axetat, fomandehit, axit axetic v etanol. phn bit
chng dng b thuc th no sau y ?
A. AgNO3/NH3, dung dch Br2, NaOH.
B. Qu tm, AgNO3/NH3, Na.
C. Qu tm, AgNO3/NH3, NaOH.
D. Phenolphtalein, AgNO3/NH3, NaOH.
Cu 36: Hp cht X c cng thc phn t CnH2nO2 khng tc dng vi Na, khi un nng X vi axit v c
c 2 cht Y1 v Y2. Bit Y2 b oxi ho cho metanal cn Y1 tham gia phn ng trng bc. Vy gi tr ca n l
A. 1.
B. 2.
C. 3.
D. 4.
Cu 37: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na,
NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X 1, X2
ln lt l
A. CH3-COOH, CH3-COO-CH3.
B. (CH3)2CH-OH, HCOO-CH3.
C. HCOO-CH3, CH3-COOH.
D. CH3-COOH, HCOO-CH3.
Cu 38: Cht hu c X c cng thc phn t C4H6O4 tc dng vi dung dch NaOH (un nng) theo phng
trnh phn ng: C4H6O4 + 2NaOH 2Z + Y.
oxi ha ht a mol Y th cn va 2a mol CuO (un nng), sau phn ng to thnh a mol cht T (bit Y,
Z, T l cc hp cht hu c). Khi lng phn t ca T l
A. 44 vC.
B. 58 vC.
C. 82 vC.
D. 118 vC.
Cu 39: Este X khng no, mch h, c t khi hi so vi oxy bng 3,125 v khi tham gia phn ng x phng
ha to ra mt anehit v mt mui ca mt axit hu c. C bao nhiu cng thc cu to ph hp vi X?
A. 2.
B. 5.
C. 3.
D. 4.
Dng 2: Gii ton este da vo phn ng x phng ha
Cu 40: Cho 6 gam mt este ca axit cacboxylic no n chc v ancol no n chc phn ng va ht vi 100
ml dung dch NaOH 1M. Tn gi ca este l
A. etyl axetat.
B. propyl fomiat.
C. metyl axetat.
D. metyl fomiat.
Cu 41: X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC 2H5 vCH3COOCH3 bng dung dch
NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l
A. 400 ml.
B. 300 ml.
C. 150 ml.
D. 200 ml.
Cu 42: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon
ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23)
A. 3,28 gam.
B. 8,56 gam.
C. 8,2 gam.
D. 10,4 gam.
Cu 43: X phng ho hon ton 37,0 gam hn hp 2 este l HCOOC 2H5 v CH3COOCH3 bng dung dch
NaOH, un nng. Khi lng NaOH cn dng l
A. 8,0g
B. 20,0g
C. 16,0g
D. 12,0g
Cu 44: X phng ho hon ton 17,6 gam hn hp 2 este l etyl axetat v metyl propionat bng lng va
V (ml) dung dch NaOH 0,5M. Gi tr V dng l
A. 200 ml.
B. 500 ml.
C. 400 ml.
D. 600 ml.
Cu 45: Thu phn hon ton 11,44 gam este no, n chc, mch h X vi 100ml dung dch NaOH 1,3M (va
) thu c 5,98 gam mt ancol Y. Tn gi ca X l
A. Etyl fomat
B. Etyl axetat
C. Etyl propionat
D. Propyl axetat
Cu 46: Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH
1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l
A. CH2=CH-CH2-COO-CH3.
B. CH2=CH-COO-CH2-CH3.
C. CH3-COO-CH=CH-CH3.
D. CH3-CH2-COO-CH=CH2.

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

Cu 47: X l mt este no, n chc, c t khi hi i vi CH 4 l 5,5. Nu em un 2,2 gam este X vi dung
dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l
A. HCOOCH2CH2CH3. B. C2H5COOCH3.
C. CH3COOC2H5.
D. HCOOCH(CH3)2.
Cu 48: X phng ha hon ton 22,3 gam hn hp gm hai este HCOOC 2H5 v CH3COOCH3 bng dung dch
NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l
A. 400 ml.
B. 300 ml.
C. 150 ml.
D. 200 ml.
Cu 49: Thy phn 1 este X c t khi hi i vi hiro l 44 th c mt mui natri c khi lng bng
41/44 khi lng este. CTCT ca este l
A. HCOOC2H5
B. HCOOCH3
C. CH3COOC2H5
D. CH3COOCH3
Cu 50: Thy phn 4,4 gam este n chc A bng 200 ml dung dch NaOH 0,25M (va ) th thu c 3,4
gam mui hu c B. CTCT thu gn ca A l:
A. HCOOC3H7
B. HCOOC2H5
C. CH3COOC2H5
D. C2H5COOCH3
Cu 51: Cho 0,1 mol este A vo 50 gam dung dch NaOH 10% un nng n khi este phn ng hon ton (cc
cht bay hi khng ng k). Dung dch thu c c khi lng 58,6 gam. C cn dung dch thu c 10,4
gam cht rn khan. CTCT ca A l
A. HCOOCH=CH2
B. CH2=CHCOOCH3
C. HCOOCH2CH=CH2 D. C2H5COOCH3
Cu 52: Thy phn este A no, n chc mch h bng dung dch NaOH thu c 1 mui hu c c khi
lng bng 41/37 khi lng ca
A. CTCT thu gn ca A l
A. HCOOCH3
B. HCOOCH=CH2
C. CH3COOC2H5
D. CH3COOCH3
Cu 53: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht
rn Y v cht hu c Z. Cho Z tc dng vi AgNO3/NH3 c cht hu c T. Cht T tc dng vi NaOH li
thu c cht Y. Cht X c th l
A. HCOOCH=CH2.
B. HCOOCH3.
C. CH3COOCH=CHCH3. D. CH3COOCH=CH2.
Cu 54: Thu phn este C4H6O2 trong mi trng axit thu c hn hp 2 cht u tham gia phn ng trng
bc. Cng thc cu to ca este l
A. HCOOCH2CH=CH2. B. HCOOC(CH3)=CH2. C. CH2CHCOOCH3.
D. HCOOCHCHCH3.
Cu 55: Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi 500 ml dung dch KOH
1M. Sau phn ng, thu c hn hp Y gm hai mui ca hai axit cacboxylic v mt ancol. Cho ton b lng
ancol thu c trn tc dng vi Na (d), sinh ra 3,36 lt H2 ( ktc). Hn hp X gm:
A. mt axit v mt este. B. mt este v mt ancol.C. hai este.
D. mt axit v mt ancol.
Cu 56: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon
ton, c cn dung dch thu c cht rn khan c khi lng l
A. 8,56 gam.
B. 3,28 gam.
C. 10,4 gam.
D. 8,2 gam.
Cu 57: un 0,1 mol X vi lng va dung dch NaOH, thu c 14,8 gam mui ca axit hu c Y v 0,2
mol ancol n chc c khi lng 9,2 gam. X c cng thc cu to l
A. (COOCH3)2.
B. CH2(COOC2H5)2.
C. (COOC2H5)2.
D. CH2(COOCH3)2.
Cu 58: Este X n chc c t khi hi so vi O 2 l 2,75. Khi un nng X vi dung dch NaOH to ra mui c
khi lng ln hn lng este phn ng. Cng thc cu to thu gn ca este ny l
A. C2H5COOCH3.
B. CH3COOC2H5.
C. HCOOC3H7.
D. CH3COOCH3.
Cu 59: Thy phn 0,2 mol este X cn 0,6 mol NaOH thu c 0,4 mol CHO 2Na; 0,2 mol C2H3O2Na v 18,4
gam ancol Y. Cng thc phn t ca X l
A. C6H12O6.
B. C7H10O6.
C. C8H10O6.
D. C8H14O6.
Cu 60: un nng 2,04 gam phenyl axetat vi 50 ml dung dch KOH 1M. C cn dung dch sau phn ng thu
c m gam cht rn. Bit hiu sut phn ng l 100%. Gi tr ca m l
A. 2,64 gam.
B. 3,87 gam.
C. 4,99 gam.
D. 3,43 gam.
Dng 3: Gii ton este da vo phn ng t chy
Cu 61: t chy hon ton 7,8 gam este X thu c 11,44 gam CO 2 v 4,68 gam H2O. Cng thc phn t ca
este l
A. C4H8O4
B. C4H8O2
C. C2H4O2
D. C3H6O2

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

Cu 62: Trong phn t este (X) no, n chc, mch h c thnh phn oxi chim 36,36 % khi lng. S ng
phn cu to ca X l
A. 4.
B. 2.
C. 3.
D. 5.
Cu 63: t chy hon ton 1,48 gam este A thu c 2,64 gam CO2 v 1,08 gam H2O. CTPT ca A l:
A. C2H4O2
B. C3H6O2
C. C3H4O2
D. C4H8O2
Cu 64: t chy hon ton 0,1 mol mt cht hu c X cn 4,48 lt kh oxi (ktc) thu c n CO2 : n H2O 1 : 1 . Bit
rng X tc dng vi dung dch NaOH to ra hai cht hu c. CTCT ca X l:
A. HCOOC3H7
B. HCOOCH3
C. CH3COOC2H5
D. C2H5COOCH3
Cu 65: t chy hon ton 7,4 gam mt este X thu c 13,2 gam CO 2 v 5,4 gam H2O. Bit rng X trng
gng c. CTCT ca X l:
A. HCOOC2H5
B. HCOOCH3
C. CH3COOC2H5
D. CH3COOCH3
Cu 66: Khi t chy hon ton mt este no, n chc th s mol CO 2 sinh ra bng s mol O 2 phn ng. Tn
gi ca este l
A. metyl fomiat.
B. etyl axetat.
C. n-propyl axetat.
D. metyl axetat.
Cu 67: t chy hon ton 1 mol este X thu c 3 mol kh CO 2. Mt khc khi x phng ha 0,1 mol este trn
thu c 8,2 gam mui cha natri. CTCT ca X l
A. HCOOC2H5
B. HCOOCH3
C. CH3COOC2H5
D. CH3COOCH3
Cu 68: Hp cht hu c X n chc cha (C, H, O) khng tc dng vi Na nhng tc dng vi dung dch
NaOH theo ti l mol 1 :1 hoc 1 : 2. Khi t chy 1 mol X thu c 7 mol CO 2. Cng thc ca X l
A. C2H5COOC4H9.
B. HCOOC6H5
C. C6H5COOH.
D. C3H7COOC3H7.
Cu 69: t chy hon ton m gam hn hp cc este no, n chc, mch h. Sn phm chy c dn vo
bnh ng dung dch nc vi trong thy khi lng bnh tng 6,2 gam. S mol CO2 v H2O sinh ra ln lt l
A. 0,1 v 0,01.
B. 0,01 v 0,1.
C. 0,1 v 0,1.
D. 0,01 v 0,01.
Cu 70: Hai este n chc X v Y l ng phn ca nhau. Khi ha hi 1,85 gam X, thu c th tch hi ng
bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l
A. HCOOC2H5 v CH3COOCH3.
B. C2H3COOC2H5 v C2H5COOC2H3.
C. C2H5COOCH3 v HCOOCH(CH3)2.
D. HCOOCH2CH2CH3 v CH3COOC2H5.
Cu 71: Khi t chy hon ton 4,4 gam hp cht hu c X n chc thu c sn phm chy ch gm 4,48 lt
CO2 ( ktc) v 3,6 gam H2O. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn
ng hon ton, thu c 4,8 gam mi ca axit hu c Y v cht hu c Z. Tn ca X l
A. etyl propionat.
B. metyl propionat.
C. isopropyl axetat.
D. etyl axetat.
Cu 72: t chy hon ton 5,6 lt (ktc) hn hp 2 este no, n chc l ng ng k tip thu c 19,712 lt
CO2 (ktc). X phng ha cng lng este trn bng dung dch NaOH to ra 17 gam mt mui duy nht. Cng
thc cu to ca 2 este l
A. CH3COOCH3 v CH3COOC2H5.
B. HCOOCH3 v HCOOC2H5.
C. HCOOC2H5 v HCOOC3H7.
D. CH3COOC2H5 v CH3COOC3H7.
Cu 73: X l hn hp 2 este to bi cng mt axit n chc vi 2 ancol n chc k tiesp nhau trong dy ng
ng. t chy 16,4 gam X thu c 37,4 gam CO2 v 12,6 gam H2O. Cng thc phn t ca 2 este l
A. C3H4O2 v C4H6O2.
B. C4H8O2 v C5H10O2. C. C3H6O2 v C4H8O2.
D. C5H8O2 v C6H10O2.
Dng 4: Hiu sut phn ng este ha hng s cn bng
Cu 74: 29: un 12 gam axit axetic vi 13,8 gam etanol (c H 2SO4 c lm xc tc) n khi phn ng t ti
trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ha l
A. 50%
B. 62,5%
C. 55%
D. 75%
Cu 75: un 12 gam axit axetic vi 13,8 gam etanol (c H 2SO4 c lm xc tc) n khi phn ng t trng thi
cn bng, thu c 11 gam este. Hiu sut ca phn ng este ha l
A. 55%.
B. 50%.
C. 62,5%.
D. 75%.
Cu 76: Cho 3 gam axit axetic phn ng vi 2,5 gam ancol etylic (xc tc H 2SO4 c, un nng) th thu c 3,3
gam este. Hiu sut phn ng este ha l
A. 70,2%
B. 77,27%
C. 75%
D. 80%

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

Cu 77: Cho 6,6 gam axit axetic phn ng vi hn hp gm 4,04 gam ancol metylic v ancol etylic t l 2:3 v
s mol, (xt H2SO4 c, un nng) th thu c a gam hn hp este. Hiu sut chung l 60%. Gi tr ca a l
A. 4,944
B. 5,103
C. 4,44
D. 8,8
Cu 78: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ha
bng 50%). Khi lng este to thnh l
A. 6,0 gam.
B. 4,4 gam.
C. 8,8 gam.
D. 5,2 gam.
ESTE TRONG THI TT NGHIP THPT
Cu 79: (GDTX-2010)-Cu 40: Cht no sau y l este?
A. HCOOH.
B. CH3CHO.
C. CH3OH.
D. CH3COOC2H5.
Cu 80: (KPB-2007)-Cu 36: S ng phn este ng vi cng thc phn t C3H6O2 l
A. 4.
B. 3.
C. 2.
D. 5.
Cu 81: (BT2-08)-Cu 26:Cht X c cng thc phn t C3H6O2. X l este ca axit axetic (CH3COOH). Cng thc
cu to thu gn ca X l
A. C2H5COOH.
B. HO-C2H4-CHO.
C. CH3COOCH3.
D. HCOOC2H5.
Cu 82: (GDTX-2009)-Cu 37: Metyl acrylat c cng thc cu to thu gn l
A. CH3COOC2H5.
B. CH3COOCH3.
C. C2H5COOCH3.
D. CH2=CHCOOCH3.
Cu 83: (BT-2007)-Cu 40: Etyl axetat c cng thc l
A. CH3COOH.
B. CH3CH2OH.
C. CH3COOC2H5.
D. CH3CHO.
Cu 84: (KPB-2008)-Cu 26: Etyl fomat c cng thc l
A. CH3COOCH3.
B. HCOOC2H5.
C. HCOOCH=CH2.
D. HCOOCH3.
Cu 85: (2010)-Cu 5: Cht khng phi axit bo l
A. axit axetic.
B. axit panmitic.
C. axit stearic.
D. axit oleic.
Cu 86: (GDTX-2010)-Cu 16: Axit no sau y l axit bo?
A. Axit fomic.
B. Axit oleic.
C. Axit acrylic.
D. Axit axetic.
Cu 87: (2010)-Cu 14: Vinyl axetat c cng thc l
A. C2H5COOCH3.
B. HCOOC2H5.
C. CH3COOCH=CH2.
D. CH3COOCH3.
Cu 88: (KPB-2007)-Cu 21: Thy phn este X trong mi trng kim, thu c natri axetat v ancol etylic.
Cng thc ca X l
A. CH3COOC2H5.
B. C2H5COOCH3.
C. C2H3COOC2H5.
D. CH3COOCH3.
Cu 89: (NC-2010)-Cu 44: Phn ng gia C2H5OH vi CH3COOH (xc tc H2SO4 c, un nng) l phn ng
A. x phng ha.
B. este ha.
C. trng hp.
D. trng ngng.
Cu 90: (CB-2010)-Cu 36: Cho CH3COOCH3 vo dung dch NaOH (un nng), sinh ra cc sn phm l
A. CH3OH v CH3COOH.
B. CH3COONa v CH3COOH.
C. CH3COOH v CH3ONa.
D. CH3COONa v CH3OH.
Cu 91: (BT-2008)-Cu 37: un nng este CH3COOC2H5 vi mt lng va dung dch NaOH, sn phm thu
c l
A. CH3COONa v CH3OH.
B. CH3COONa v C2H5OH.
C. HCOONa v C2H5OH.
D. C2H5COONa v CH3OH.
Cu 92: (KPB-2008)-Cu 3: un nng este HCOOCH3 vi mt lng va dung dch NaOH, sn phm thu
c l
A. CH3COONa v C2H5OH.
B. HCOONa v CH3OH.
C. HCOONa v C2H5OH.
D. CH3COONa v CH3OH.
Cu 93: (GDTX-2009)-Cu 1: Cht bo l trieste ca axit bo vi
A. etylen glicol.
B. glixerol.
C. etanol.
D. phenol.
Cu 94: (BKHXH&NV-2008)Cu 46: Khi thu phn cht bo trong mi trng kim th thu c mui ca axit
bo v
A. phenol.
B. glixerol.
C. ancol n chc.
D. este n chc.
Cu 95: (GDTX-2009)-Cu 4: Cho 8,8 gam CH3COOC2H5 phn ng ht vi dung dch NaOH (d), un nng.
Khi lng mui CH3COONa thu c l
A. 12,3 gam.
B. 16,4 gam.
C. 4,1 gam.
D. 8,2 gam.

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

Cu 96: (2010)-Cu 6: X phng ho hon ton 17,6 gam CH3COOC2H5 trong dung dch NaOH (va ), thu
c dung dch cha m gam mui. Gi tr ca m l
A. 19,2.
B. 9,6.
C. 8,2.
D. 16,4.
Cu 97: (GDTX-2010)-Cu 28: Cho 6,0 gam HCOOCH 3 phn ng ht vi dung dch NaOH (d), un nng.
Khi lng mui HCOONa thu c l
A. 4,1 gam.
B. 6,8 gam.
C. 3,4 gam.
D. 8,2 gam.
ESTE TRONG THI CAO NG, I HC
Cu 98: (C-08). Cho dy cc cht: HCHO, CH 3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht
trong dy tham gia phn ng trng gng l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 99: (KB-07). Thy phn este c cng thc phn t C 4H8O2 (vi xc tc axit), thu c 2 sn phm hu c
X v Y. T X c th iu ch trc tip ra Y. Vy cht X l
A. ancol metylic.
B. etyl axetat.
C. ancol etylic.
D. axit fomic.
Cu 100: (KB-2010). Thu phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng
mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l
A. metyl propionat
B. metyl axetat
C. etyl axetat
D. vinyl axetat
Cu 101: (KA-08). Este X c cc c im sau:
- t chy hon ton X to thnh CO2 v H2O c s mol bng nhau;
- Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn
t cacbon bng mt na s nguyn t cacbon trong X).
Pht biu khng ng l:
A. Cht X thuc loi este no, n chc.
B. Cht Y tan v hn trong nc.
C. un Z vi dung dch H2SO4 c 170oC thu c anken.
D. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O.
Cu 102: (KA-08). Pht biu ng l:
A. Phn ng thy phn este trong mi trng axit l phn ng thun nghch.
B. Khi thy phn cht bo lun thu c C2H4(OH)2.
C. Phn ng gia axit v ancol (ru) khi c H2SO4 c l phn ng mt chiu.
D. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v
ancol (ru).
Cu 103: (C-2010). Thu phn cht hu c X trong dung dch NaOH (d), un nng, thu c sn phm
gm 2 mui v ancol etylic. Cht X l
A. CH3COOCH2CH3
B. CH3COOCH2CH2Cl
C. ClCH2COOC2H5
D. CH3COOCH(Cl)CH3
Cu 104: (KA-07). Mt este c cng thc phn t l C 4H6O2, khi thu phn trong mi trng axit thu c
axetanehit. Cng thc cu to thu gn ca este l
A. CH2=CH-COO-CH3.
B. HCOO-C(CH3)=CH2.
C. HCOO-CH=CH-CH3.
D. CH3COO-CH=CH2.
Cu 105: (KA-07). Mnh khng ng l:
A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3.
B. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui.
C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2.
D. CH3CH2COOCH=CH2 c th trng hp to polime.
Cu 106: (KA-08). Cho s chuyn ho sau: C3H4O2 + NaOH X + Y
X + H2SO4 long Z + T
Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l:
A. HCOONa, CH3CHO.
B. HCHO, CH3CHO.
C. HCHO, HCOOH.
D. CH3CHO, HCOOH.

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

Cu 107: (KB-2010). Hp cht hu c mch h X c cng thc phn t C 6H10O4. Thy phn X to ra hai ancol
n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l
A. CH3OCO-CH2-COOC2H5.
B. C2H5OCO-COOCH3.
C. CH3OCO-COOC3H7.
D. CH3OCO-CH2-CH2-COOC2H5.
Cu 108: (KB-2010). Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi
CH COOH
H2

Y H SO3 ,ac Este c mi mui chn. Tn ca X l

Na, tha mn s chuyn ha sau: X
Ni,t 0
2

A. pentanal
B. 2 metylbutanal
C. 2,2 imetylpropanal
D. 3 metylbutanal
Cu 109: (C-07). Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu
c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO 3 (hoc Ag2O) trong dung dch NH3 thu c
cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l
A. HCOOCH=CH2.
B. CH3COOCH=CH2.
C. HCOOCH3.
D. CH3COOCH=CH-CH3.
Cu 110: (C-08). Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn
ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu
to ca X1, X2 ln lt l:
A. CH3-COOH, CH3-COO-CH3.
B. (CH3)2CH-OH, H-COO-CH3.
C. H-COO-CH3, CH3-COOH.
D. CH3-COOH, H-COO-CH3.
Cu 111: (KA-09). X phng ha mt hp cht c cng thc phn t C 10H14O6 trong dung dch NaOH (d), thu
c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l:
A. CH2=CH-COONa, HCOONa v CHC-COONa.
B. CH3-COONa, HCOONa v CH3-CH=CH-COONa.
C. HCOONa, CHC-COONa v CH3-CH2-COONa.
D. CH2=CH-COONa, CH3-CH2-COONa v HCOONa.
Cu 112: (C-2010). Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H 2SO4 c), un nng,
thu c 41,25 gam etyl axetat. Hiu sut ca phn ng este ho l
A. 62,50%
B. 50,00%
C. 40,00%
D. 31,25%
Cu 113: (KB-07). X l mt este no n chc, c t khi hi i vi CH 4 l 5,5. Nu em un 2,2 gam este X vi
dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l
A. CH3COOC2H5.
B. HCOOCH2CH2CH3. C. C2H5COOCH3.
D. HCOOCH(CH3)2.
Cu 114: (C-2010). Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau
trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O 2 (ktc), thu c 5,6 lt
kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l
A. CH3COOCH3 v 6,7
B. HCOOC2H5 v 9,5
C. HCOOCH3 v 6,7
D. (HCOO)2C2H4 v 6,6
Cu 115: (KB-07). Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch
hi ng bng th tch ca 0,7 gam N 2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l (cho H
= 1, C = 12, N = 14, O = 16)
A. C2H5COOCH3 v HCOOCH(CH3)2.
B. HCOOCH2CH2CH3 v CH3COOC2H5.
C. C2H3COOC2H5 v C2H5COOC2H3.
D. HCOOC2H5 v CH3COOCH3.
Cu 116: (C-2010). t chy hon ton 2,76 gam hn hp X gm CxHyCOOH, CxHyCOOCH 3, CH3OH thu
c 2,688 lt CO2 (ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam X phn ng va vi 30 ml dung dch
NaOH 1M, thu c 0,96 gam CH3OH. Cng thc ca CxHyCOOH l
A. C2H5COOH
B. CH3COOH
C. C2H3COOH
D. C3H5COOH
Cu 117: (KA-07). X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy
ra hon ton, c cn dung dch thu c cht rn khan c khi lng l
A. 8,56 gam.
B. 3,28 gam.
C. 10,4 gam.
D. 8,2 gam.

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

Cu 118: (KB-2010). Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y)

v este Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra
16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l
A. HCOOH v CH3OH
B. CH3COOH v CH3OH
C. HCOOH v C3H7OH
D. CH3COOH v C2H5OH
Cu 119: (C-07). Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm
4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n
khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l (Cho H = 1;
C = 12; O =16; Na = 23)
A. etyl propionat.
B. metyl propionat.
C. isopropyl axetat.
D. etyl axetat.
Cu 120: (C-07). Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x
phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X ?
(Cho H = 1; C = 12; O =16)
A. 2.
B. 5.
C. 3.
D. 4.
Cu 121: (C-08). Este n chc X c t khi hi so vi CH 4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung
dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to
ca X l
A. CH2=CH-CH2-COO-CH3.
B. CH2=CH-COO-CH2-CH3.
C. CH3 -COO-CH=CH-CH3.
D. CH3-CH2-COO-CH=CH2.
Cu 122: (C-08). X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC 2H5 v CH3COOCH3 bng
dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l
A. 400 ml.
B. 300 ml.
C. 150 ml.
D. 200 ml.
Cu 123: (KA-09). X phng ha hon ton 66,6 gam hn hp hai este HCOOC 2H5 v CH3COOCH3 bng dung
dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 1400C, sau khi phn ng
xy ra hon ton thu c m gam nc. Gi tr ca m l
A. 18,00.
B. 8,10.
C. 16,20.
D. 4,05.
Cu 124: (KA-09). Cht hu c X c cng thc phn t C 5H8O2. Cho 5 gam X tc dng va ht vi dung dch
NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X
l
A. CH3COOC(CH3)=CH2.
B. HCOOC(CH3)=CHCH3.
C. HCOOCH2CH=CHCH3
D. HCOOCH=CHCH2CH3.
Cu 125: (KB-09). Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng
va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c
mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l
A. C2H4O2 v C3H6O2
B. C3H4O2 v C4H6O2
C. C3H6O2 v C4H8O2
D. C2H4O2 v C5H10O2
Cu 126: (KB-09). Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch
KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X
trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 (d) th khi lng bnh tng 6,82
gam. Cng thc ca hai hp cht hu c trong X l
A. HCOOH v HCOOC2H5
B. CH3COOH v CH3COOC2H5
C. C2H5COOH v C2H5COOCH3
D. HCOOH v HCOOC3H7
Cu 127: (KB-09). Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3
trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O 2 (cng iu kin v nhit v p
sut). Khi t chy hon ton 1 gam X th th tch kh CO 2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to
ca X l
A. CH3COOCH3
B. O=CH-CH2-CH2OH C. HOOC-CHO
D. HCOOC2H5
Cu 128: (KB-09). Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t
khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH
1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l
A. 29,75
B. 27,75
C. 26,25
D. 24,25

Mt s chuyn Ha hc THPT GV: L Kim Hu (0979577657)

Cu 129: (C-09). Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH
1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l
A. CH3COOCH=CHCH3
B. CH2=CHCH2COOCH3
C. CH2=CHCOOC2H5
D. C2H5COOCH=CH2
Cu 130: (C-09). Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung
dch cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht
vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht hu c l
A. mt este v mt axit
B. mt este v mt ancol
C. hai axit
D. hai este
Cu 131: (KA-10). Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%,
thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l
A. HCOOH v CH3COOH
B. CH3COOH v C2H5COOH
C. C2H5COOH v C3H7COOH
D. HCOOH v C2H5COOH
Cu 132: (C-11). Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau
khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc ca X l
A. CH2=CHCOOCH3. B. CH3COOC2H5.
C. CH3COOCH=CH2.
D. C2H5COOCH3.
Cu 133: (C-11). x phng ha hon ton 52,8 gam hn hp hai este no, n chc, mch h l ng phn
ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc.
Cng thc ca hai este l
A. C2H5COOC2H5 v C3H7COOCH3.
B. CH3COOC2H5 v HCOOC3H7.
C. C2H5COOCH3 v CH3COOC2H5.
D. HCOOC4H9 v CH3COOC3H7.
Cu 134: (C-11). phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y (M x < My) cn
va 300 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton thu c 24,6 gam mui ca mt axit
hu c v m gam mt ancol. t chy hon ton lng ancol trn thu c 4,48 lt CO 2 (ktc) v 5,4 gam H2O.
Cng thc ca Y l
A. CH3COOCH3.
B. CH3COOC2H5.
C. CH2=CHCOOCH3.
D. C2H5COOC2H5.
Cu 135: (C-11). Hp cht hu c X c cng thc phn t l C 4H8O3. X c kh nng tham gia phn ng vi
Na, vi dung dch NaOH v phn ng trng bc. Sn phm thy phn ca X trong mi trng kim c kh
nng ha tan Cu(OH)2 to thnh dung dch mu xanh lam. Cng thc cu to ca X c th l
A. CH3COOCH2CH2OH.
B. HCOOCH2CH(OH)CH3.
C. CH3CH(OH)CH(OH)CHO.
D. HCOOCH2CH2CH2OH.
Cu 136: (KA-11). Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este,
s nguyn t Cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th
lng NaOH phn ng l 10 gam. Gi tr ca m l
A. 14,5.
B. 17,5.
C. 15,5.
D. 16,5.
Cu 137: (KA-11). t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit
oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH) 2 (d). Sau phn ng thu c 18 gam kt ta
v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban du thay i nh th no?
A. gim 7,74 gam.
B. gim 7,38 gam.
C. tng 2,70 gam.
D. tng 7,92 gam.
Cu 138: (KB-11). Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt
thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c 29,7 gam. S ng
phn cu to ca X tha mn cc tnh cht trn l
A. 2.
B. 6.
C. 4.
D. 5.
Cu 139: (KB-11). Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X thu
c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l
A. 72,08%.
B. 27,92%.
C. 25%.
D. 75%.