16 de Thi HSG Lop 9 Cac Tinh Co Dap An

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vn/leviethung76/
1
S GIO DC V O TO
BC GIANG
THI CHN HC SINH
GII
CPTHC
TNH
CHNH
NM HC 2011-2012
MN THI: HA HC- LP 9
THCS
Ngy thi: 01/4/2012 Thi gian
lm bi:150 pht
(Khng k thi gian giao )
Cu 1: (4,0 im)
1. Cho hn hp X gm Mg, Fe2O3 v Al2O3 tc dng vi dung dch CuSO4 (d), sau phn ng thu
c dung dch Y v cht rn Z. Cho ton b Z tc dng vi dung dch HCl (d), sau phn ng thu c
dung dch A v phn khng tan B. Ho tan B trong dung dch H 2SO4 c, nng (d) thu c kh C. Hp
th kh C vo dung dch Ba(OH)2 thu c kt ta D v dung dch F. Cho dung dch KOH (d) vo dung
dch F li thy xut hin kt ta D. Cho t t dung dch KOH n d vo dung dch A, c kt ta G.
Hy vit cc phng trnh ho hc ca cc phn ng xy ra.
2. t chy hon ton 13,2 gam hn hp gm hai hp cht hu c: A (C nH2nO) v B (CnH2n+2O), thu
c 29,7 gam CO2. Tm cng thc phn t ca A, B v vit cng thc cu to mch h c th c ca
chng.
Cu 2: (4,0 im)
1. Vit phng trnh ho hc hon thnh s phn ng sau:
Ru etylic
(1) axit axetic
(2) natri axetat
(3) metan
(4) axetilen
(5) etilen
(6) PE
(7)
vinyl clorua
(8)
PVC
2. Ha tan ht 17,2 gam hn hp X gm Fe v mt oxit st vo 200 gam dung dch HCl 14,6% thu
c dung dch A v 2,24 lt kh H 2 (ktc). Thm 33,0 gam nc vo dung dch A c dung dch B.
Nng phn trm ca HCl trong dung dch B l 2,92%. Mt khc, cng ha tan ht 17,2 gam hn hp
X vo dung dch H2SO4 c, nng th thu c V lt kh SO2 duy nht (ktc).
a) Xc nh cng thc ha hc ca oxit st trong hn hp X.
b) Tnh khong gi tr ca V?
Cu 3: (4,0 im)
1. Ha tan 2,16 gam hn hp Y gm Na, Fe v Al vo nc (d), thu c 0,448 lt kh H 2 thot ra
(ktc) v mt lng cht rn khng tan. Tch lng cht rn ny cho phn ng ht vi 60 ml dung dch
CuSO4 1M thu c 3,2 gam ng kim loi v dung dch A. Tch ly dung dch A cho phn ng vi mt
lng va dung dch NaOH thu c kt ta ln nht. Lc kt ta em nung nhit cao trong
khng kh n khi lng khng i thu c cht rn B.
a) Xc nh % khi lng mi kim loi trong hn hp Y.
b) Tnh khi lng cht rn B.
2. t chy hon ton 44,4 gam hn hp X gm ba axit: CH 3COOH, CnHmCOOH v HOOCCOOH, thu c 21,6 gam H 2O v a gam CO2. Mt khc, cho 44,4 gam hn hp X phn ng hon ton
vi NaHCO3 (d) thu c 16,8 lt kh CO2 (ktc). Tnh gi tr ca a?
Cu 4: (4,0 im)
1. Cho 5,04 lt hn hp kh A (ktc) gm C2H2 v H2 qua xc tc Ni un nng, sau phn ng thu
c hn hp kh B ch gm 3 hirocacbon c t khi so vi H2 bng 14,25.
a) Xc nh khi lng trung bnh ca A.
b) Cho hn hp kh B phn ng hon ton vi dung dch Br 2 (d). Tnh s mol Br2 tham gia
phn ng.
2. Hp th hon ton V lt kh CO 2 (ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH 1,4M,
sau khi cc phn ng xy ra hon ton thu c dung dch X. Cho ton b X tc dng vi dung dch
BaCl2 (d), thu c 11,82 gam kt ta. Tnh gi tr ca V?
Cu 5: (4,0 im)
1. Trong phng th nghim c cc dung dch ng trong cc l ring bit b mt nhn: KCl, Al(NO 3)3,
NaOH, MgSO4, ZnCl2, AgNO3. Dng thm mt thuc th, hy nhn bit cc dung dch trn. Vit cc phng
TI LIU BD HSG HA
Trang 1
L Vit Hng
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trnh phn ng (nu c).
2. Ha tan 2,56 gam kim loi ng vo 25,20 gam dung dch HNO 3 nng 60% thu c dung
dch A. Thm 210 ml dung dch NaOH 1M vo dung dch A. Sau khi cc phn ng kt thc, em c cn
hn hp thu c cht rn X. Nung X n khi lng khng i c 17,40 gam cht rn Y. Tnh nng
to
to
% ca cc cht trong dung dch A. Bit: 2NaNO
2NaNO2 + O2; 2Cu(NO3)
2CuO +
3
2
4NO2 + O2.
------------- Ht ----------------
HNG DN CHM
BI THI CHN HC SINH GII CP TNH
NM HC 2011-2012
NGY THI 01/4/2012
HDC CHNH THC
MN THI: HA HC LP 9 THCS
Bn hng dn chm c 06 .trang
S GIO DC V O TO
BC GIANG
Cu 1
(4,0
im)
(4 im)
1.1 (3,0 im)
X + dd CuSO4 d dd Y + cht rn Z:
Mg + CuSO4 MgSO4 + Cu
Dung dch Y gm MgSO4 v CuSO4 d.
Cht rn Z gm Cu, Fe2O3 v Al2O3.
Cho Z tc dng vi dung dch HCl d:
Al2O3 + 6HCl 2AlCl3 + 3H2O;
Fe2O3 + 6HCl 2FeCl3 + 3 H2O
Cu + 2FeCl3 2FeCl2 + CuCl2
Do HCl d nn Al2O3, Fe2O3 tan ht, cht rn B l Cu d.
B + H2SO4 c, nng, d kh B l SO2
o
Cu + 2H2SO4 t
CuSO4 + SO2 + 2 H2O
Sc SO2 vo dd Ba(OH)2:
Ba(OH)2 + SO2 BaSO3 + H2O; BaSO3 + SO2 + H2O Ba(HSO3)2
Kt ta D l BaSO3, dd F cha Ba(HSO3)2
dd F + dd KOH d:
Ba(HSO3)2 + 2KOH BaSO3 + K2SO3 + 2H2O
dd A + dd KOH d:
HCl + KOH KCl + H2O;
CuCl2 + 2KOH Cu(OH)2 + 2KCl
FeCl2 + 2KOH Fe(OH)2 + 2KCl; AlCl3 + 3KOH Al(OH)3 + 3KCl
Al(OH)3 +KOH KAlO2 + 2H2O
Kt ta G gm: Cu(OH)2, Fe(OH)2
TI LIU BD HSG HA
Trang 2
L Vit Hng
Mi
PTHH
ng cho
0,25.
(tr phn
ng HCl
vi
KOH)
1.2
Gi s mol ca A, B ln lt l x, y mol.
(14n+16)x + (14n + 18)y = 13,2
14nx+16x + 14ny + 18y = 13,2 (*)
29, 7
0, 675 mol (**)
44
T (*) v (**) 16x + 18y = 13,2 - 14 x 0,675 = 3,75
16(x+y) <16x+18y < 18(x+y)
3, 75
3, 75
x y
18
16
0, 675.16
0, 675.18
n
T (**)
3, 75
3, 75
2,88 n 3, 24 n = 3
Bo ton nguyn t cacbon: n CO2 = nx ny
0,25
0,25
Vy cng thc phn t v cng thc cu to ca:

- A l C3H6O: CH3CH2CH=O; CH3COCH3; CH2=CH-CH2-OH; CH2=CH-O-CH3
- B l C3H8O: CH3-CH2-CH2-OH; CH3CHOHCH3; CH3CH2-O-CH3
Cu 2
(4,0
im)
0,25
0,25
(4 im)
2.1
(1)
(2)
(3)
C2H5OH + O2
CH3COOH + H2O
mengim
CH3COOH + NaOH
CH3COONa + H2O
o
CH3COONa + NaOH
CH4 + Na2CO3
CaO, t
(4)
C
1500
2CH4
LLN
(5)
C2H2 + H2
(6)
nC2H
4
(7)
C2H2 + HCl
C2H2 + 3H2
Pd
to
xt , p
to
Mi
PTHH
ng cho
0,25.
C2H4
(-CH2-CH2-)n
HgCl2
150o 200o C
xt , p
to
(PE)
CH2=CH-Cl

(8)
nCH2=CH-Cl
(-CH2-CHCl-)n (nha PVC)
2.2
a) Gi cng thc ca oxit st l FexOy.
Cc PTHH khi X vo dung dch HCl:
Fe + 2HCl FeCl2 + H2
(1)
FexOy + 2yHCl FeCl2y/x + yH2O
(2)
200.14,6
nHCl ban u = 100.36,5 = 0,8 (mol)
n H2 =
2,24
=0,1(mol) m H2 =0,1.2=0,2(g)
22,4
T (1): nFe = nH 2 = 0,1(mol) => mFe = 0,1 . 56 = 5,6(g)

mFex Oy 17, 2 5, 6 11, 6( g )
nFe x O y
11,6
(mol ) (*)
56 x 16 y
0,25
T (1): nHCl = 2 nH 2 = 2.0,1= 0,2 (mol)

mddA = 200 + 17, 2 0, 2 217( g )
mddB = 217 + 33 = 250 (g)
250.2,92
nHCl d = 100.36,5 0,2(mol )
nHCl (2) = 0,8 - 0,2 - 0,2 = 0,4(mol)
1
1
0,2
nFe x O y
.nHCl
.0,4
(mol )
2
y
2
y
y
T (2):
(**)
T (*) v (**) ta c phng trnh

11,6
0,2
x
3
= y y 4
56 x 16 y
Vy cng thc Oxit st l: Fe3O4

b)Cc PTHH khi cho X vo dung dch H2SO4 c nng:
TI LIU BD HSG HA
Trang 3
L Vit Hng
0,25
t
2Fe + 6H2SO4 c Fe2(SO4)3
+ 3SO2 + 6H2O
2Fe3O4
+ SO2 + 10H2O
C th:
Fe + Fe2(SO4)3 3FeSO4
Nu H2SO4 d (5) khng xy ra:
o
t
+ 10H2SO4 c 3Fe2(SO4)3
nSO
max
(3)
0,25
(4)
(5)
3
1
3
1
n Fe + nFe3O4 .0,1 .0,05 = 0,175(mol) VSO2
2
2
2
2
max
= 3,92 (lt)
Nu H2SO4 khng d: (5) xy ra:

n Fe ( SO ) 3
nSO2
(3) v (4)
min nFe (5) =
t nFe (5) = x(mol) => nFe (3) = 0,1 - x
1
3
n
Fe ( SO ) 3 (3) v (4) = 2 (0,1 x ) + 2 .0,05
2
0,25
0,25
1
3
0,25
(0,1 x ) + .0,05 = x => x =
2
2
3
0,25 0,05
nFe (3) = 0,1 =
3
3
3 0,05 1
.0,05 = 0,05 (mol)
Khi nSO2 min = .
2 3
2
c pt:
0,25
=> VSO min = 0,05 . 22,4 = 1,12 (lt)

Vy khong gi tr c th nhn gi tr ca V l: 1,12 V 3,92
2
Cu 3
(4,0
im)
0,5
(4 im)
3.1
- Gi trong 2,16 gam hn hp c x mol Na, y mol Al.
n H2 0, 448 : 22, 4 0, 02 mol
nCuSO4 0,06.1= 0,06mol; nCuSO4 pu nCu=3,2:64 = 0,05 mol
nCuSO4 du 0,06 - 0,05 = 0,01mol
PTHH:
2Na + 2H2O 2NaOH + H2
(1)
x
x
0,5x
(mol)
2Al + 2H2O + 2NaOH 2NaAlO2 + 3H2
(2)
x
x
x
1,5x (mol)
2Al
+ 3CuSO4 2Al2(SO4)3 + 3Cu
(3)
(y-x)
1,5(y-x)
(y-x)
1,5(y-x)
(mol)
Fe
+ CuSO4 FeSO4 + Cu
(4)
a) Gi s khng xy ra phn ng (3) cht rn ch l Fe
Theo (4) nFe= nCu = 0,05 mol mFe= 0,05.56 = 2,8 gam > 2,16 (khng ph hp bi)
Vy c xy ra phn ng (3) v v CuSO4 cn d nn Al v Fe phn ng ht theo (3) v (4)
Theo (1) v (2): n H2 0,5x 1,5x 0, 02 mol x = 0,01
Theo (3): nAl(3) = y - 0,01 mol
n CuSO4 1,5 y 0, 01 mol
Theo (4): n Fe n CuSO4 (4) 0, 05 1,5 y 0, 01 mol
Ta c : mNa + mAl + mFe = 23.0,01 + 27y + 56[0,05-1,5(y - 0,01)] = 2,16 y = 0,03
trong hn hp ban u:
mNa = 23.0,01 = 0,23 gam
mAl = 27.0,03 = 0,81 gam
mFe = 2,16 - 0,23 -0,81 = 1,12 gam
TI LIU BD HSG HA
Trang 4
L Vit Hng
0,5
0,25
0,25
0,25
Vy:
0,23
0,81
.100%=10,65%; %m Al =
.100%=37,5%
2,16
2,16
1,12
%m Na =
.100%=51,85%
2,16
%m Na =
0,25
b) Trong dung dch A c:

n Al2 (SO4 )3 = 0,03- 0,01= 0,02 mol
n CuSO4 du = 0,01mol
n FeSO4 = n Fe =1,12:56 = 0,02 mol
Ta c s
CuSO4 Cu(OH)2 CuO
mCuO = 0,01.80 = 0,8 gam

0, 02
.160 1, 6 gam
2FeSO4 2Fe(OH)2 2Fe(OH)3 Fe2O3 m Fe2O3
2
0, 02
m Al 2 O3
.102 1, 02 gam
Al2(SO4)3 2Al(OH)3 Al2O3
2
Vy mB = 0,8 + 1,6 + 1,02 = 3,24 gam
3.2
Gi trong 44,4 gam X c x mol CH3COOH, y mol CnHmCOOH v z mol HOOC-COOH
PTHH
CH3COOH + NaHCO3 CH3COONa + CO2 + H2O
(1)
mol:
x
x
CnHmCOOH + NaHCO3 CnHmCOONa + CO2 + H2O (2)
mol:
y
y
HOOC-COOH + 2NaHCO3 NaOOC-COONa + 2CO2 + 2H2O (3)

mol:
z
2z
Theo (1), (2) v (3): nCO2 x y 2 z
- n H2O =
1,0
0,25
16,8
0, 75 mol
22, 4
21,6
=1,2 mol n H = 2n H2O = 2,4 mol
18
0,25
- Bo ton nguyn t oxi:

n O =2n CH3COOH +2n Cn H mCOOH +4n HOOC-COOH
=2x+2y+4z
=2.0,75=1,5 mol
0,25
- LBT khi lng:

mX mC mH mO 44, 4 gam
nC
nCO2
44, 4 2, 4 1,5.16
1,5 mol
12
nC 1,5 mol
0,5
Vy a = 1,5.44= 66 gam
Cu 4
(4,0
im)
0,25
(4 im)
4.1
a) Hn hp B gm C2H2; C2H4; C2H6
Gi cng thc chung ca B l C2 H x
d B/H 2 = 14,25 => MB = 14,25 x 2 = 28,5
Gi s c 1 mol B => mB = 28,5 gam
PTHH:
C2H2 + 1,25H2
1
1,25
TI LIU BD HSG HA
Ni
t0
Trang 5
=> 24 + x = 28,5 => x = 4,5

C2H4,5 (1)
1
L Vit Hng
28,5 38
= 12,67
LBT khi lng: mA = mB = 28,5 gam m nA = 2,25 mol => M A =
1,0
2,25 3
5,04
=0,225(mol)
22,4
T (1) => nB = 0,1 (mol)
3
PTHH
C2H4,5 +
Br2
4
theo (2): nBr2 0,1.0, 75 0, 075 mol.
b) Theo bi ra: n A =
C2H4,5Br1,5
(2)
1,0
4.2
Ta c: n K 2CO3 =0,1.0,2=0,02 (mol); n KOH = 0,1.1,4 = 0,14 (mol)
PTHH
CO2 + 2KOH K2CO3 + H2O
(1)
C th c:
CO2 + K2CO3 + H2O 2KHCO3
(2)
BaCl2 + K2CO3 BaCO3 + 2KCl (3)
0,25
11,82
= 0,06 mol> n K 2CO3 ban u = 0,02 mol
Theo (3): n K 2CO3 (3) = n BaCO3 =
197
C hai trng hp xy ra.
0,25
- TH1: khng xy ra phn ng (2)

Theo (1): n CO2 = n K 2CO3 (3) - n K 2CO3 b = 0,06 -0,02 = 0,04mol
V=0,04.22,4=0,896 lit
- TH2: c xy ra phn ng (2)
1
0,14
0, 07 mol
Theo (1): nCO2 (1) nK 2CO3 (1) nKOH
2
2
nK 2CO3 p (2) nK 2CO3 (1) nK 2CO3 b nK2CO3 (3) 0, 07 0, 02 0, 06 0, 03 mol
0,5
Theo (2): nCO2 (2) nK2CO3 (2) 0, 03mol

V = (0,07 + 0,03).22,4 = 2,24 lit
Cu 5
(4,0
im)
0,5
0,5
(4 im)
1. Dng phenolphtalein nhn bit cc dung dch: KCl, Al(NO3)3, NaOH, MgSO4, ZnCl2,
AgNO3.
Nhn bit
Ln lt nh vi git phenolphtalein vo tng dung dch mu th.
ng mi
- Nhn ra dung dch NaOH do xut hin mu hng.
cht cho
0,5
Ln lt cho dung dch NaOH vo mi dung dch mu th cn li:
- Dung dch AgNO3 c kt ta mu nu:
AgNO3 + NaOH
AgOH + NaNO3
hoc 2 AgNO3 + 2NaOH
Ag2O + H2O + 2NaNO3
- Dung dch MgSO4 c kt ta trng:

MgSO4 + 2NaOH
Mg(OH)2 + Na2SO4
- Cc dung dch Al(NO3)3, ZnCl2 u c chung hin tng to ra kt ta trng, tan trong
dung dch NaOH (d).
AlCl3 + 3NaOH
Al(OH)3 + 3NaCl
Al(OH)3 + NaOH
NaAlO2 + 2H2O
Zn(NO3)2 + 2NaOH
Zn(OH)2 + 2NaOH
TI LIU BD HSG HA
Zn(OH)2 + 2NaNO3
Na2ZnO2 + 2H2O
Trang 6
L Vit Hng
- Dung dch KCl khng c hin tng.
- Dng dung dch AgNO3 nhn ra dung dch ZnCl2 do to ra kt ta trng
3AgNO3 + ZnCl2
3AgCl + Zn(NO3)2
- Cn li l dung dch Al(NO3)3.

5.2
nCu = 0,04 mol; nNaOH = 0,21 mol; n HNO3 0, 24 mol.
Dung dch A c Cu(NO3)2, c th c HNO3.
Cu(OH) 2
ddcNaOH
Ta c: ddA
NaNO3
can
c th c NaOH hoac Cu(NO )
3 2
PTHH:
NaOH + HNO3 NaNO3 + H2O
2NaOH + Cu(NO3)2 Cu(OH)2 + 2NaNO3
0,08
0,04
0,04
0,08
mol
to
2NaNO3
2NaNO2 + O2
Cu(OH)
2
to
CuO
NaNO 2
c th c NaOH du
0,25
CuO + H2O
Gi s mol NaNO2 trong cht rn sau khi nung l x. Theo bo ton nguyn t ta c:
nCuO 0, 04 mol; nNaOH d = 0,21-x mol mY = 80. 0,04 + 69x + 40(0,21 - x) = 17,4 gam
x = 0,2 n NaNO2 0, 2 mol
nHNO3
d = 0,2 0,08 = 0,12mol
nHNO3
phn ng = 0,240,12 = 0,12mol
n H2O
1
n HNO
m
=2
=0,06 mol
3
=> mkh= mCu +
H 2O
0,25
= 1,08g
m HNO - mCu(NO ) - m H O = 2,56+7,56-7,52-1,08 = 1,52g

3
3 2
Trong dung dch A c:

n Cu NO3 n Cu 0, 04 mol
0,25
n HNO3 du 0, 24 0,12 0,12 mol.

mdd A = 2,56 + 25,2 mkh = 26,24 gam.
Vy trong dung dch A c:
0,12.63
C% HNO3 du
.100%= 28,81%
26, 24
0, 04.188
C% Cu NO3
.100%=28, 66%
2
26, 24
0,25
im ton bi
TI LIU BD HSG HA
Trang 7
L Vit Hng
(20
im)
2
UBND TNH BC NINH
S GIO DC V O TO
CHNH THC
( thi c 01 trang)
THI CHN HC SINH GII CP TNH

NM HC 2011 2012
MN THI : HA HC-LP 9
Thi gian lm bi: 150 pht (khng k thi gian giao )
Ngy thi: 20 thng 3 nm 2012
===========
Cu I (2 im): Mt hn hp cha Fe, FeO, Fe2O3. Nu ho tan a gam hn hp trn bng dung dch HCl
d th khi lng H2 thot ra bng 1,00% khi lng hn hp em th nghim. Nu kh a gam hn hp
trn bng H2 d th thu c khi lng nc bng 21,15% khi lng hn hp em th nghim. Xc
nh phn trm v khi lng mi cht c trong a gam hn hp trn.
Cu II (2 im): Cho 1 anken A kt hp vi H2 (Ni lm xc tc) ta c ankan B.
a/ Xc nh cng thc phn t ca A, B bit rng t chy ht B bng mt lng O 2 va th
th tch kh CO2 thu c bng 1/2 tng th tch ca B v O2.
b/ Mt hn hp X gm A, B v H2 c th tch l 22,4 lt. Cho X i qua Ni nung nng xc tc thu
c hn hp Y, bit t khi ca X so vi Y bng 0,70. Tnh th tch hn hp Y, s mol H 2 v A phn
ng vi nhau.
c/ Bit rng hn hp Y khng lm phai mu nc Br 2 v t khi dY/H2= 16. Xc nh thnh phn
trm th tch ca cc kh trong hn hp X.
Cc th tch kh u o iu kin tiu chun.
Cu III (2 im): Cho 316,0 gam dung dch mt mui hirocacbonat (A) 6,25% vo dung dch H 2SO4
long va , sau khi phn ng xy ra hon ton thu c 16,5 gam mui sunfat trung ho. Mt khc
cng cho lng dung dch mui hirocacbonat (A) nh trn vo dung dch HNO 3 va , ri c cn t t
dung dch sau phn ng th thu c 47,0 gam mui B. Xc nh A, B.
Cu IV (2 im): Cho cc ha cht CaCO3, NaCl, H2O v cc dng c cn thit lm th nghim, trnh
by phng php iu ch dung dch gm 2 mui Na2CO3 v NaHCO3 c t l s mol l 1:1.
Cu V (2 im): Ba cht kh X, Y, Z u gm 2 nguyn t, phn t cht Y v Z u c 3 nguyn t. C 3
cht u c t khi so vi hiro bng 22. Y tc dng c vi dung dch kim, X v Z khng c phn ng
vi dung dch kim. X tc dng vi oxi khi t nng sinh ra Y v mt cht khc. Z khng chy trong oxi.
a/ Lp lun tm cng thc phn t cc cht X, Y, Z.
b/ Trnh by cch phn bit ba bnh ng ring bit ba kh trn b mt nhn.
Cu VI (2 im): Vit phng trnh phn ng trong 0,75 mol H2SO4 tham gia phn ng sinh ra
a/ 8,4 lt SO2 (ktc).
b/ 16,8 lt SO2 (ktc).
c/ 25,2 lt SO2 (ktc).
d/ 33,6 lt SO2 (ktc).
Cu VII (2 im): Dn lung kh CO qua ng s c cha m gam hn hp cht rn X gm CuO v Fe 2O3
nung nng, sau mt thi gian trong ng s cn li n gam hn hp cht rn Y. Kh thot ra c hp th
ht vo dung dch Ca(OH)2 d c p gam kt ta. Vit cc phng trnh ha hc ca phn ng v thit
lp biu thc lin h gia n, m, p.
Cu VIII (2 im): Hai cc thy tinh A, B ng dung dch HCl d t trn hai a cn, thy cn trng
thi thng bng. Cho 5,00 gam CaCO3 vo cc A v 4,79 gam M2CO3 (M l kim loi) vo cc B. Sau khi
cc mui ha tan hon ton thy cn tr li v tr thng bng. Hy xc nh M.
Cu IX (2 im): Trnh by cc th nghim xc nh thnh phn nh tnh v nh lng ca nc.
Cu X (2 im): Nu cch pha ch 500,0 ml dung dch NaCl 0,9% (nc mui sinh l) t mui n
nguyn cht v nc ct. Nu tn cc dng c th nghim cn thit v m phng cch tin hnh bng hnh
v.
============== Ht ==============
Cho bit s khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; Si = 28;
P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Ni = 58; Cu = 64; Zn = 65; Ag = 108; Ba = 137
Th sinh c s dng bng HTTH v my tnh cm tay thng thng.
TI LIU BD HSG HA
Trang 8
L Vit Hng
UBND TNH BC NINH
S GIO DC V O TO
HNG DN CHM
THI CHN HC SINH GII CP TNH
NM HC 2011 2012
MN THI : HA HC-LP 9
Ngy thi: 20 thng 3 nm 2012
===========
Cu I (2 im): Mt hn hp cha Fe, FeO, Fe2O3. Nu ho tan a gam hn hp trn bng dung dch HCl
d th khi lng H2 thot ra bng 1,00% khi lng hn hp em th nghim. Nu kh a gam hn hp
trn bng H2 d th thu c khi lng nc bng 21,15% lng hn hp em th nghim. Xc nh
phn trm v khi lng mi cht c trong a gam hn hp trn.
CU
NI DUNG
IM
I
Gi s a = 100 gam. Gi x, y, z ln lt l s mol Fe, FeO, Fe2O3 trong a gam
Ho tan a g hn hp trn bng dung dch HCl d
Fe + 2 HCl
FeCl2 + H2
0,50
x
2x
x
x
FeO + 2 HCl FeCl2 + H2O
y
2y
y
y
Fe2O3+ 6HCl
2FeCl3 + 3H2O
z
6z
2z
3z
Ta c 2x = 1(*)
Kh a g hn hp trn bng H2 d
FeO + H2 Fe + H2O
0,50
y
y
y
y
Fe2O3 + 3 H2 2Fe + 3 H2O
z
3z
2z
3z
Ta c 18y + 54z = 21,15(**)
Li c 56x + 72y + 160z = 100(***)
T (*), (**), (***) c h phng trnh:
2x = 1
0,50
18y + 54z = 21,15
56x + 72y + 160z = 100
Gii h PT ta c x = 0,5; y = 0,5; z = 0,225
0,50
%Fe = 28%; %FeO = 36%; %Fe2O3 = 36%
Cu II (2 im): Cho 1 anken A kt hp vi H2 (Ni lm xc tc) ta c ankan B.
a/ Xc nh cng thc phn t ca A, B bit rng t chy ht B bng mt lng O 2 va th
th tch kh CO2 thu c bng 1/2 tng th tch ca B v O2.
b/ Mt hn hp X gm A, B v H2 c th tch l 22,4 lt. Cho X i qua Ni nung nng xc tc thu
c hn hp Y, bit t khi ca X so vi Y bng 0,70. Tnh th tch hn hp Y, s mol H 2 v A phn
ng vi nhau.
c/ Bit rng hn hp Y khng lm phai mu nc Br 2 v t khi dY/H2= 16. Xc nh thnh phn
trm th tch ca hn hp X.
Cc th tch kh u o iu kin tiu chun.
CU
NI DUNG
IM
Ni
II
a CnH2n + H2 CnH2n+2
t chy B(CnH2n+2 )
0,25
3n 1
O2 t 0 nCO2 + (n+1) H2O
2
3n 1
Nu ly 1 mol B, nO2 =
, nCO2 = n.
2
1
1
3n 1
nCO2 =
(nB + nO2) n =
(1+
).
2
2
2
CnH2n+2 +
n = 3 , A l C3H6, B l C3H8
0,50
Ta s dng kt qu
TI LIU BD HSG HA
Trang 9
L Vit Hng
ny
=
nx
dx/y =
Mx
My
dx/y =
nY
MX mX nY
=
.
=
(do mX = mY)
nX mY
nX
MY
nY
= 0,7 nY = 0,7 mol
nX
VY = 0,7 . 22,4 = 15,68 lt.
nH2 v nA phn ng
Ta s dng: nX nY = nH2 p = nA p
nX nY = 1- 0,7 = 0,3.
Vy n H2 p = nA p = 0,3 mol
C3H6 + H2 Ni ,t 0 C3H8
0,3
0,3
0,3
V hn hp Y sau phn ng khng lm phai mu nc Br 2, chng t C3H6
phn ng ht.
Vy n C3H6 b = 0,3 mol = a.
(2)
Hn hp Y sau phn ng gm:
C3H8 (b + 0,3) v H2 d (c 0,3)
dx/y =
44(b 0,3) 2(c 0,3)

= 2.16 = 32 g
b 0,3 c 0,3
44b 13,2 2c 0,6
= 32
bc
0,50
0,25
MX =
Thay b + c = 1- 0,3 = 0,7 44b + 2c = 9,8

Hay: 22b + c = 4,9 (3)
b + c = 0,7 (4)
T (3) v (4) b = 0,2 mol ( C3H8 ), c = 0,5 mol H2
0,50
Vy thnh phn % th tch ca hn hp X l: 30% C3H6 ; 20% C3H8 v 50% H2
Cu III (2 im): Cho 316 gam dung dch mt mui hirocacbonat (A) 6,25% vo dung dch H 2SO4
long va , sau khi phn ng xy ra hon ton thu c 16,5 gam mui sunfat trung ho. Mt khc
cng cho lng dung dch mui hirocacbonat (A) nh trn vo dung dch HNO 3 va , ri c cn t t
dung dch sau phn ng th thu c 47 gam mui B. Xc nh A, B.
CU
NI DUNG
IM
III
Gi cng thc ca mui A: R(HCO3)n
0,25
C: mA = 316.6,25% = 19,75 gam
0,25
2R(HCO3)n + nH2SO4 R2(SO4)n + 2nCO2 + 2nH2O
19,75gam
16,5gam
=> 16,5.(2R + 2.61n) = 19,75.(2R + 96n)
suy ra: R= 18n
Ta c bng sau:
n
1
2
3
0,5
R
18
36
54
KL
NH4
Khng tho mn
Khng tho mn
mui A l: NH4HCO3
- Theo bi: nA = 19,75 : 79 = 0,25 mol
0,25
NH4HCO3 + HNO3 NH4NO3 + H2O + CO2
0,25 mol
0,25 mol
0,25
m(NH4NO3) = 80 0,25 = 20 gammui B l mui ngm nc.
- t CTPT ca B l: NH4NO3.xH2O
m(H2O) = 47 20 = 27 gam n(H2O) = 27/18= 1,5 mol
0,50
x=6
Cng thc ca B: NH4NO3.6H2O
Cu IV (2 im): Cho cc ha cht CaCO3, NaCl, H2O v cc dng c cn thit lm th nghim, trnh
by phng php iu ch dung dch gm 2 mui Na2CO3 v NaHCO3 c t l s mol l 1:1.
TI LIU BD HSG HA
Trang 10
L Vit Hng
CU
IV
IM
0,25
NI DUNG
To ra v thu ly kh CO2: Nhit phn CaCO3
o
CaCO3 t
CaO + CO2
To ra dung dch NaOH: in phn dd NaCl bo ha c mng ngn
pdd
2NaCl + 2H2O mnx
2NaOH + Cl2 + H2
Vit cc phng trnh to mui
1.
CO2(d) + NaOH NaHCO3
(1)
2a
2a
(mol)
2.
NaHCO3 + NaOH Na2CO3 + H2O
(2)
a
a
a
(mol)
- Trnh by cch tin hnh th nghim: ly 2 th tch dung dch NaOH cho vo
cc A v cc B sao cho VA = 2VB (dng cc chia )
Gi s mol NaOH cc A l 2a mol th s mol NaOH cc B l a mol
Sc CO2 d vo cc A, xy ra phn ng (1)
Sau cc A vo cc B: xy ra phng trnh (2)
Kt qu thu c dung dch c s mol NaHCO3 l a mol v s mol Na2CO3 l a
mol => t l 1:1
-
0,25
0,25
0,25
1,00
Cu V (2 im): Ba cht kh X,Y, Z u gm 2 nguyn t, phn t cht Y v Z u c 3 nguyn t. C 3

cht u c t khi so vi hiro bng 22. Y tc dng c vi dung dch kim, X v Z khng c phn ng
vi dung dch kim. X tc dng vi oxi khi t nng sinh ra Y v mt cht khc. Z khng chy trong oxi.
a/ Lp lun tm cng thc phn t cc cht X, Y, Z.
b/ Trnh by cch phn bit ba bnh ng ring bit ba kh trn b mt nhn.
CU
NI DUNG
IM
V
a M = 22.2 = 44
Y l hp cht gm hai nguyn t, tc dng c vi kim c th l oxit axit.
Ch c trng hp Y l CO2 tho mn v cht gm 2 nguyn t, phn t gm 3
0,50
nguyn t v M = 44. ( Cc oxit, axit, mui khc khng tho mn)
X chy sinh ra 2 sn phm trong c CO 2 vy X l CXRY, trong R l H tho
0,25
mn. X l C3H8 c M = 44.
Z l N2O tho mn v cht gm 2 nguyn t, phn t gm 3 nguyn t v M = 44.
0,50
b Cch phn bit:
Cho qua nc vi trong d, kh no lm dung dch vn c l CO 2, 2 kh cn li
0,25
l C3H8 v N2O.
Ca(OH)2 + CO2 CaCO3 + H2O
0,25
em t 2 kh cn li ri dn sn phm chy vo dung dch nc vi trong, sn
phm chy no lm c nc vi trong l sn phm chy ca C3H8, cn N2O
khng chy
C3H8 + 5O2 3CO2 + 4H2O
0,25
Kh cn li l N2O
Cu VI (2 im): Vit phng trnh phn ng trong 0,75 mol H2SO4 tham gia phn ng sinh ra
a/ 8,4 lt SO2 (ktc).
b/ 16,8 lt SO2 (ktc).
c/ 25,2 lt SO2 (ktc).
d/ 33,6 lt SO2 (ktc).
CU
NI DUNG
IM
VI
n SO2
0,375 1
Cu + 2H2SO4 c t CuSO4 + SO2 + 2H2O

a)
0,50
n H 2 SO4
0,75 2
0
b)
c)
n SO2
n H 2 SO4
n SO2
n H 2 SO4
0,75
1 Na2SO3 + H2SO4
0,75
1,125 3
S + 2H2SO4 c
0,75 2
TI LIU BD HSG HA
Trang 11
Na2SO4 + SO2 + H2O
0,50
0,50
3SO2 + 2H2O
L Vit Hng
d)
n SO2
n H 2 SO4
1,5
2 2NaHSO3 + H2SO4
0,75
0,50
Na2SO4 + 2SO2 + H2O
Ch : Hc sinh chn cht khc v vit phng trnh ha hc ng, cho im ti

a tng ng.
Cu VII (2 im): Dn lung kh CO qua ng s c cha m gam hn hp cht rn X gm CuO v Fe 2O3
nung nng, sau mt thi gian trong ng s cn li n gam hn hp cht rn Y. Kh thot ra c hp th
ht vo dung dch Ca(OH)2 d c p gam kt ta. Vit cc phng trnh ha hc ca phn ng v thit
lp biu thc lin h gia n, m, p.
CU
NI DUNG
IM
VII
PTHH:
(1) 3Fe2O3 + CO 2Fe3O4 + CO2
(2) Fe2O3 + CO t 2FeO + CO2
1,00
(3) Fe2O3 + 3 CO 2Fe + 3 CO2
(4) CuO + CO Cu + CO2
(5) Ca(OH)2 + CO2 CaCO3 + H2O
p dng nh lut bo ton khi lng:
mx + mco = my + mCO2
m n = mCO2 mCO
m n = 44.n CO2 28.nCO
0,50
p
M nCO = nCO2 = nCaCO3 =
100
0
(44 28) p 16.p
100
100
m = n + 0,16p
0,50
Cu VIII (2 im): Hai cc thy tinh A, B ng dung dch HCl d t trn hai a cn, thy cn trng
thi thng bng. Cho 5 gam CaCO3 vo cc A v 4,79 gam M2CO3 (M l kim loi) vo cc B. Sau khi cc
mui ha tan hon ton thy cn tr li v tr thng bng. Hy xc nh M.
CU
NI DUNG
IM
VIII
CaCO3 + 2HCl CaCl2 + H2O + CO2
(1)
0,50
M2CO3 + 2HCl 2 MCl + H2O + CO2
(2)
0,50
(100 44).5
2,8
T(1) ta c: Khi lng cc A tng
100
T (2) Ta c: Khi lng cc B tng
0,50
(2M 60 44).4,79 (2M 16).4,79
2,8
2M 60
2M 60
0,50
M = 23 vy M l Na
mn =
TI LIU BD HSG HA
Trang 12
L Vit Hng
Cu IX (2 im): Trnh by cc th nghim xc nh thnh phn nh tnh v nh lng ca nc.
CU
NI DUNG
IM
IX
0,75
(1)
(2)
(3)
S phn hy nc.
Lp thit b phn hy nc nh hnh (1). Khi cho dng in mt chiu i qua
nc ( c pha thm mt t dung dch axit sunfuric lm tng dn in ca
nc), trn b mt hai in cc (Pt) xut hin bt kh. Cc kh ny tch t trong
hai u ng nghim thu A v B. t kh trong A, n chy km theo ting n nh,
l H2. Kh trong B lm cho tn m bng chy, l kh oxi.
S tng hp nc:
Cho nc vo y ng thy tinh hnh tr. Cho vo ng ln lt 2 th tch kh
hiro v 2 th tch kh oxi. Mc nc trong ng vch s 4 (hnh (2)). t bng
0,75
tia la in hn hp hi ro v oxi s n. Mc nc trong ng dng ln. Khi nhit
trong ng bng nhit bn ngoi th mc nc dng li vch chia s 1
(Hnh (3)), kh cn li lm tn m bng chy l oxi.
Xc nh thnh phn nh lng ca H2O
T cc d kin th nghim trn ta c phng trnh ha hc to thnh H2O
2H2 + O2 2H2O
Do t l v th tch bng t l v s mol nn ta c
0,50
nH2:nO2 = 2:1 mH2:mO2 = 4:32 = 1:8. Vy phn trm khi lng mi nguyn t
trong nc l
1*100%
11,1% %O = 100%-%H = 88,9%
%H =
1 8
Cu X (2 im): Nu cch pha ch 500 ml dung dch NaCl 0,9% (d = 1,009g/cm 3) (nc mui sinh l) t
mui n nguyn cht v nc ct. Nu tn cc dng c th nghim cn thit v m phng cch tin hnh
bng hnh v.
CU
NI DUNG
IM
X
Khi lng NaCl cn dng: 500.1,009.0,9% = 4,54 gam
- (1) Cn ly 4,54g NaCl ri cho vo cc thy tinh.
- (2) Cho t t nc ct (lng nh hn 500 ml) vo v lc u
1,00
- (3) Dng a thy tinh khuy u cho mui tan ht
- (4) dung dch va pha vo bnh nh mc 500 ml.
- (5) Cho tip nc ct va n vch 500ml.
- (6) y nt nhp kn, lc k ta c 500 ml dung dch nc mui sinh l nh
yu cu.
Cc dng c th nghim: cn in t, cc thy tinh, a thy tinh, bnh nh
mc 500 ml c nt nhm,
TI LIU BD HSG HA
Trang 13
L Vit Hng
athytinh
1,00
(3)
500 ml
H2O
(2)
NaCl
(4,54 gam)
(1)
(4), (5), (6)
Ch : Hc sinh c th m phng bng hnh v khc nhng vn m bo cc ni
dung ny.
Ch : Hc sinh lm cch khc ng cho im ti a tng ng.
TI LIU BD HSG HA
Trang 14
L Vit Hng
3
THI HSG MN HA 9 BNH PHC 2011-2012: (150 PHT).(28/3/2012)
Cu I: (2 ):
1. Nc clo va mi iu ch lm mt mu giy qu tm, nhng nc clo lu ngoi nh sng lm
cho qu tm ha . Ti sao?
2. Hy chn mt ha cht thch hp phn bit cc dung dch mui sau: NH4Cl, (NH4)2SO4, NaNO3,
MgCl2, FeCl3. Vit cc PTHH xy ra.
Cu II: ( 2 ):
1. Cho mt kim loi A tc dng vi mt dung dch mui B. Kim loi mi sinh ra bm trn kim loi A. Ly
hn hp kim loi ny ha tan trong dung dch HNO3 c nng thu c kh D duy nht v dung dch G
cha 3 mui. Hy xc nh A,B,D,G? Vit PTHH xy ra.
2. Bng png php ha hc, hy tch kh SO2 ra khi hn hp kh: SO2,SO3,O2.
Cu III: ( 4 )
1. T dung dch A cha a mol CuSO4 v b mol FeSO4, thc hin cc th nghim sau:
Th nghim 1: thm c mol Mg vo dd A, sau p thu c dd c 3 mui.
Th nghim 2: thm 2c mol Mg vo dd A, sau p thu c dd c 2 mui.
Th nghim 3: thm 3c mol Mg vo dd A, sau p thu c dd c 1 mui.
Hy tm mi quan h gia a,b,c trong tng th nghim trn?
2. Thm 100 gam nc vo dung dch cha 20 gam CuSO4 th thy nng ca dd gim i 10%. Xc
nh nng % ca dd ban u.
Cu IV: (4 )
Chia 26,88 gam MX2 thnh 2 phn bng nhau:
Phn I: cho vo 500 ml dd NaOH d thu c 5,88 gam M(OH)2 kt ta v dd D.
Phn II: cho vo 360 ml dd AgNO3 1M thu c dd B v 22,56 gam AgX kt ta. Cho thanh Al
vo dd B thu c dd E, khi lng thanh Al sau khi ly ra cn li tng ln m gam so vi ban u(
ton b kim loi thot ra bm vo thanh Al). Cho dd D vo dd E thu c 6,24 gam kt ta.( p
xy ra hon ton).
a. Xc nh cng thc phn t MX2 v gi tr m?
b. Tnh nng mol/lt ca dung dch NaOH dng.
Cu V: (4 )
Ha tan hon ton m gam hn hp X gm Fe v Zn trong m1 gam dd H2SO4 98% (ly d) thu c dd Y
( bit rng khi lng dd trc v sau p khng i) v V lt SO2 (ktc).
a. Vit PTHH cc p xy ra.
b. Xc nh thnh phn % theo khi lng mi kim loi trong hn hp X.
c. Cho dd Y ha tan va m2 gam MgCO3 thu c 4,48 lt kh (ktc) v dd Z. Cho tip BaCl2 d vo
dd Z thu c 239,99 gam kt ta. Xc nh m,m1,m2, V?
Cu VI: (4 )
1. Vit CTCT c th c ca cc cht c CTPT C4H6.
2. Dn 6,72 lt hn hp kh gm 2 hirocacbon mch h qua dd brom d, sau khi p xy ra hon ton
thy khi lng bnh ng dd brom tng thm 5,6 gam ng thi thot ra 2,24 lt mt cht kh. Mt khc
t chy hon ton 2,24 lt kh cn li trn thy to ra 8,96 lt CO2. (th tch cc kh o ktc).
a. Xc nh CTPT ca 2 H-C.
b. Tnh thnh phn % theo th tch ca mi kh trong hn hp.
- HT-
TI LIU BD HSG HA
Trang 15
L Vit Hng
S GIO DC & O TO
C MAU
CHNH THC
( thi gm c 2 trang)
4
THI HC SINH GII VNG TNH LP 9 THCS
NM HC 2011-2012
Mn thi: Ho hc
Ngy thi: 22 4 2012
Thi gian: 150 pht (Khng k thi gian giao )
Cu I (3,5 im)
1. Vit phng trnh ha hc ca cc phn ng thc hin s chuyn i trc tip sau:
a. FeS H2S SO2 H2SO4 E
b. vi CaO X Y Z T
Cho bit E l mui sunfat ca kim loi R c phn t khi l 152 ; X, Y, Z, T u l mui
ca canxi vi cc gc axit khc nhau.
2. Vit phng trnh ha hc ca 5 phn ng khc nhau trc tip iu ch FeCl3.
Cu II (3,0 im)
1. Tnh cht ca hp cht hu c ph thuc vo trt t sp xp cc nguyn t trong phn t .
Hy ly th d chng minh.
2. Axit lactic c cng thc cu to : CH3 CHOH COOH. Da vo tnh cht cc cht hu c
hc, hy vit phng trnh ha hc ca phn ng gia axit lactic vi:
a. Mg
b. C2H5OH
c. Na
3. Cht hu c c cng thc phn t: C3H9N. Hy vit cc cng thc cu to ng vi cng thc
phn t trn.
Cu III (3,5 im)
1. C hn hp gm cc cht rn: SiO 2, CuO, BaO. Nu phng php tch ring tng cht ra
khi hn hp vi iu kin khng lm thay i khi lng cc cht. Vit phng trnh phn ng
xy ra (nu c).
2. C 4 dung dch khng mu b mt nhn: MgSO 4, NaOH, BaCl2, NaCl. Hy nu phng php
ha hc nhn ra tng dung dch khi ch c dng thm axit HCl lm thuc th, vit phng
trnh ha hc. Du hiu ta nhit trong phn ng trung ha khng c coi l du hiu nhn bit.
Cu IV (3,5 im)
1. Nhng cht no sau y c dng lm kh v khng lm kh kh CO 2. Ti sao ? Vit
phng trnh phn ng (nu c): P2O5, Fe3O4, H2SO4 (c), Na, CaO.
2. C 2 vt bn trn qun o: vt du nhn v vt du n. Hy chn trong s cc cht sau
lm sch vt bn, gii thch: nc, nc x phng, gim n, t-xng, cn 90o.
3. Dn hn hp kh gm: Hidro v CO ly d qua bnh ng cc oxit: Fe 2O3, Al2O3 v CuO
nung nng. Kt thc phn ng thu c cht rn B v hn hp kh C. Ha tan cht rn B vo
dung dch HCl thu c dung dch D, kh v rn khng tan. Dn kh C qua dung dch nc vi
trong ly d thu c cht kt ta. Cho dung dch NaOH ly d vo dung dch D thu c kt
ta c thnh phn mt cht duy nht. Vit cc phng trnh phn ng xy ra.
Cu V (2,0 im)
Trn a cn 2 cc ng dung dch HCl v H 2SO4, cn v tr thng bng. Cho vo cc ng
dung dch HCl 25 gam CaCO 3. Cho vo cc ng dung dch H 2SO4 a gam Al cn vn v tr
thng bng. Tnh a ?
Cu VI (2,5 im)
Ly m gam hn hp E gm Al v Cu chia lm 2 phn:
- Phn 1 cho vo dung dch H2SO4 long, d thu c 2,688 lt kh.
- Phn 2 (nhiu hn phn 1 l 14,16 gam) cho tc dng ht vi H 2SO4 c, nng, ly d thu
c 14,336 lt kh. Tnh m v thnh phn phn trm khi lng mi kim loi c trong E. Bit
cc phn ng xy ra hon ton v th tch cc kh u o iu kin tiu chun.
Cu VII (2,0 im)
t chy hon ton cht hu c Y ngi ta thu c 14,336 lt kh CO 2 (ktc) v 5,76
gam H2O. cng iu kin nhit v p sut th tng th tch CO 2 v hi nc thu c bng
tng th tch ca Y v O2 tham gia phn ng.
TI LIU BD HSG HA
Trang 16
L Vit Hng
1. Xc nh cng thc phn t ca Y. Bit Y mch h, vit cng thc cu to ca Y.
2. Khi Y tc dng vi dung dch nc Brom theo t l s mol 1:2 thu c cht hu c Z.
Vit cng thc cu to c th c ca Z.
Cho C = 12; O = 16; H = 1; Ca = 40; S = 32;
Al = 27; Cu = 64; Fe = 56; Cl = 35,5.
---------- HT ----------
CHNH THC
GIO DC V O TO
TNH K NNG
5
K THI CHN HC SINH GII CP TNH LP 9 THCS NM
HC 2011-2012
Kha thi ngy: 17/3/2012
Mn thi: HA HC
Thi gian: 150 pht (khng k thi gian giao )
Cu 1. (3.0im)
1. mt hn hp gm Al, Fe, Cu, va Ag. Bng phng php ha hc hy tch ri hon ton cc
kim loi ra khi hn hp trn.
2. c 5 l mt nhn ng dung dch: NaOH, KCl, MgCl2, CuCl2, AlCl3.Hy nhn bit tng dung
dch trn m khng dng thm ha cht khc.vit c phng trnh phn ng xy ra.
Cu 2 (3.0 im)
Hon thnh cc phng trnh phn ng theo dy chuyn ha sau:
H2S + O2 (A)(rn) +(B)(lng)
(A)+ O2 (C)
MnO2 +HCl
(D)+(E)+(B)
(B)+(C)+(D)
(F)+(G)
(G)+ Ba
(H)+(I)
Cu 3(5.0 im)
Ly V1 lt HCl 0.6M trn V2 lt NaOH 0,4M. Tng V1+V2= 0,6 lt thu c dung dch A.bit rng 0,6 lt
dung dung dch A tc dng va vi 0,02 mol Al2O3.
Cu 4 (4.0 im):
Chia hn hp kim loi Cu, Al thnh 2 phn bng nhau :
Phn th nht nung nng trong khng kh ti phn ng hon ton thu c 18.2 g hn hp 2 Oxit. Ha
tna phn th hai va dung dch H2SO4 c nng thy bay ra 8,96 lit kh SO2 ktc
1. tnh % khi lng mi kim loi trong hn hp.
2. nu ha tan hon ton 14,93 gam kim loi X bng dung dch H2SO4 c nng v thu c mt
lng SO2 nh trn th X l kim loi g?
Cu 5(5.0 im)
Ha tan hn hp A thu c t s nung bt Al v S bng dung dch HCl ly d thy cn li 0.04 gam cht
rn v c 1,344 lt kh bay ra ktc.Cho ton b kh i qua dung dch Pb(NO3) ly d, sau phn ng
thu c 7,17 gam kt ta mu en.
Xc nh % Al v S trc khi nung
------HT-----(Hc sinh c s dng my tnh b ti v bng h thng tun hon cc nguyn t ha hc)
H v tn th sinh .....................................................S bo danh.........................................
TI LIU BD HSG HA
Trang 17
L Vit Hng
S GIO DC V O TO
IN BIN
CHNH THC
( thi c 02 trang)
6
K THI CHN HC SINH GII
NM HC 2011 -2012
Mn: Ha hc Lp 9
Thi gian lm bi: 150 pht (khng k thi gian giao )
Ngy thi: 18/4/2012
Cu 1. (3 im)
1. Vit phng trnh ha hc cho dy chuyn ha sau (ghi r iu kin phn ng, nu c)
Cu (1) CuCl2 (2) Cu(OH)2 (3) CuO (4) CuSO4 (5) Cu(NO3)2
(6)
Cu
2. A, B, C l 3 cht hu c mch h c cc tnh cht sau: B lm mt mu dung dch brom, C tc

dng c vi Na, A tc dng c vi Na v NaOH. A, B, C l nhng cht no trong s cc cht sau:
C4H8, C2H4O2, C2H6O. Hy vit cng thc cu to ca cc cht trn.
Cu 2. (4,5 im)
1. Nu hin tng v vit cc phng trnh ha hc c th xy ra khi tin hnh cc th nghim sau:
a) t dy st trong trong bnh ng kh clo, ngui, sau nc vo bnh lc nh, ri nh t
t dung dch natri hidroxit vo bnh.
b) Cho mu vi vo dung dch axit axetic.
c) Sc lng d kh axetilen vo bnh ng dung dch nc brom.
d) Nh vi git dung dch phenolphtalein vo cc ng dung dch Ca(OH)2 long, sau nh t t
dung dch axit clohiric ti d vo cc.
2. Ch dng thm qu tm hy nhn bit cc dung dch sau ng trong cc l ring bit b mt nhn:
Na2SO4, KOH, BaCl 2, H2SO4, MgCl2. Vit cc phng trnh ha hc dng.
Cu 3. (3,5 im)
1. T etilen, cc ha cht v dng c cn thit c y , hy vit cc phng trnh ha hc (ghi
r iu kin) iu ch cc cht sau : axit axetic, etylaxetat.
2. t chy hon ton m gam hp cht hu c A cn va 8,96 lt O 2 thu c 8,96 lt CO2 (cc
kh o ktc) v 7,2 gam nc. Xc nh cng thc phn t ca A, bit trong cng iu kin nhit v
p sut m gam A c th tch hi ng bng th tch ca 6,4 gam O2.
Cu 4. (4,5 im)
1. Ha tan 23,2 gam mui RCO 3 bng dung dch axit H2SO4 long va , sau phn ng thu c
30,4 gam mui v V lt CO2 ( ktc).
a) Tnh V v tm R.
b) Nhng mt thanh kim loi Zn nng 20 gam vo dung dch mui sunfat thu c trn, sau khi
phn ng xy ra hon ton ly thanh kim loi Zn ra ra sch, sy kh, cn nng bao nhiu gam? Gi s
kim loi sinh ra bm ht vo thanh Zn.
2. t chy hon ton V lt etilen ( ktc), cho tt c sn phm chy hp th hon ton vo bnh
ng 500 ml dung dch Ca(OH)2 0,2M thy to thnh 8 gam kt ta .
a) Tnh V.
b) Sau th nghim khi lng bnh ng dung dch Ca(OH)2 tng hay gim bao nhiu gam?
Cu 5. (4,5 im)
1. Cho 30,4 gam hn hp X gm Fe, Fe2O3, FeCO3 tc dng va vi 1,8 lt dung dch HCl, thy
thot ra mt hn hp kh c t khi i vi H2 l 15 v to thnh 51,55 gam mui clorua.
a) Tnh thnh phn % khi lng ca mi cht trong hn hp X.
b) Tnh nng mol ca dung dch HCl dng.
2. Cho 0,92 gam Na vo 400 gam dung dch CuSO4 3,2%, thu c kh A, kt ta B v dung dch C.
a) Tnh th tch kh A ( ktc) v khi lng kt ta B.
b) Tnh nng % cht tan trong dung dch C.
Cho nguyn t khi: H =1; C = 12; O = 16; Na = 23; Mg = 24; Al =27; S = 32; Cl = 35,5; Ca =
40; Fe = 56; Cu = 64; Zn= 65; Ba = 137.
....................... Ht ......................
Ghi ch: Th sinh khng c php s dng bng tun hon cc nguyn t ho hc
TI LIU BD HSG HA
Trang 18
L Vit Hng
7
K THI CHN HC SINH GII LP 9 CP TNH
S GIO DC V O TO GIA LAI
Nm hc 2011-2012
CHNH THC
MN: HO HC
Thi gian: 150 pht (khng k thi gian pht )
Cu 1. (3,0 im)
a. Hon thnh chui chuyn ho:
G
+B S
(lu hunh)
+ NaOH, , t
(1)
(2)
A
F
+ HCl
(3)
+ HCl
(7)
B
G
+NaOH
(4)
+NaOH
(8)
+NaOH
(5)
+Ba(OH)2
H +NaOH
+AgNO3
(9)
(6)
(10)
E kt ta trng
J kt ta en
b. Ch dng thm nc v kh cacbonic hy trnh by phng php nhn bit cc cht rn: Na 2CO3,
Na2SO4, NaCl, BaCO3 v BaSO4.
Cu 2. (3,0 im) a. Nu hin tng, gii thch, vit phng trnh phn ng xy
Hn hp kh
ra khi p ng nghim cha y hn hp kh C 2H2 v C2H4 vo chu thu tinh cha
C2H2 v C2H4
dung dch nc brom (nh hnh bn).
Dung dch
nc brom
b. T nhm cacbua v cc cht v c cn thit hy vit phng trnh phn ng
iu ch vinyl axetat v hexacloxiclohexan.
Cu 3. (2,0 im) t chy hon ton cht hu c Z (cha C, H v O) thu c CO 2 v H2O c t l khi
lng l 88:45.
- Tm cng thc phn t ca Z, bit trong phn t Z c mt nguyn t oxi.
- Vit cng thc cu to c th c ca Z, bit Z c mt s tnh cht ho hc ging ru etylic.
Cu 4. (2,0 im) Y l cht hu c cha cc nguyn t C, H, O v N. t chy hon ton 0,75 gam Y thu
c hn hp sn phm gm CO2, H2O v N2, cho hon ton sn phm chy vo dung dch Ca(OH)2 d
thu c 2 gam kt ta v khi lng bnh tng 1,33 gam. Tm cng thc phn t ca Y (bit MY = 75).
Cu 5. (3,0 im) Cho 3,07 gam hn hp bt kim loi X gm Al v Fe vo 150 ml dung dch hn hp
gm Fe(NO3)3 1,0 M v AgNO3 0,5 M, khuy u, sau phn ng thu c m gam kim loi v dung dch Y
(cha ba mui). Cho t t dung dch NaOH d, ly kt ta nung n khi lng khng i c 16,0
gam cht rn khan. Bit cc phn ng xy ra hon ton.
a. Vit phng trnh phn ng c th xy ra.
b. Tnh m v phn trm khi lng ca Al v Fe trong X.
Cu 6. (3,0 im)
a. Cho 14,4 gam hn hp Z gm mui cacbonat v hidrocacbonat ca cng mt kim loi kim (M) phn
ng vi dung dch HCl d, phn ng hon ton thu c 2,8 lt kh CO 2 (ktc). Tm M, tnh phn trm
khi lng cc mui trong Z.
b. X l dung dch HCl 0,3 M, Y l dung dch hn hp Na 2CO3 0,15 M v NaHCO3 0,1 M. Tnh th tch
CO2 sinh ra (ktc) khi:
- Cho t t 100 ml dung dch X vo 100 ml dung dch Y v khuy u.
- Cho t t 100 ml dung dch Y vo 100 ml dung dch X v khuy u.
Cu 7. (2,0 im) Trn 0,2 lt dung dch H2SO4 x M vi 0,3 lt dung dch NaOH 1,0 M thu c dung
dch A. phn ng vi A cn ti a 0,5 lt dung dch Ba(HCO 3)2 0,4 M, sau phn ng thu c m gam
kt ta. Tnh gi tr ca x v m.
Cu 8. (2,0 im) Ho tan hon ton 5,28 gam hn hp X gm Cu v mt oxit st (Fe xOy) trong H2SO4
c nng (d). Sau khi phn ng xy ra hon ton thu c 448 ml kh SO 2 (ktc) v dung dch. C cn
dung dch thu c 13,6 gam hn hp mui khan Y.
a. Vit phng trnh phn ng xy ra.
TI LIU BD HSG HA
Trang 19
L Vit Hng
b. Tm cng thc phn t ca oxit st, tnh phn trm khi lng cc cht trong Y.
Ht
Hc sinh c s dng bng h thng tun hon v my tnh b ti.
Kt qu:
Cu 1:
a. G: H2S; B: SO2 ; A; Na2SO3; C: NaHSO3; E; BaSO3; F: Na2S; G; H2S; H; NaHS; Na2S; J: Ag2S
b. T nghin cu
Cu 2:a. Dung dch nhc mu, nc dng ln trong ng nghim.. T vit spTHH
. b:C6H6Cl6 (Thuc su 666, hin nay cm s dng v phn hy trong mi trng chm);
CH3COOCH=CH2 Vynyl etat
Cu 3: C4H10O, tm h s bt bo ha k =
4 x 2 10 2
= 0 => Khng c lin kt pi, ru n chc
2
no,Vit 4 ng phn
Cu 4: C2H5O2N (HS nhm v c N2 trong bnh nn lm d sai). y cho sn phm chy l c c N 2 vo
nhng khi lng bnh tng l ta ch tnh khi lng hp th vo nc vi, cn nito khng tnh. SP chy
khng phi l CO2 v H2O
Cu 5: a. Vit 10 PTHH
b. %mFe = 91,2%; %mAl = 8,8%
Cu 6: a. M l K; %m K2CO3 = 47,92%; mui cn li ly 100% tr
Cu 7: TH1: NaOH ht => H2SO4 d => m = 46,6g
TH2: NaOH d, H2SO4 ht => m= 43g
Cu 8: Fe3O4; %mCuSO4 = 11,76% cn li tr ra
Cu 4 nn sa li "cho hon ton sn phm chy vo dung dch Ca(OH)2 d thu" nn thay bng t
cho hon ton sn phm chy qua dung dch Ca(OH)2 d thu
TI LIU BD HSG HA
Trang 20
L Vit Hng
8
K THI CHN HC SINH GII TNH
LP 9 THCS NM HC 2011-2012
Mn: Ha hc
Thi gian: 150 pht (khng k giao )
Ngy thi: 23/3/2012
S GIO DC V O TO
HAI DNG
THI CHNH THC
Cu I. ( 2,0 im)
1. Nung nng hn hp Cu, Ag trong O2 d, sau phn ng thu c cht rn A. Cho A vo dung
dch H2SO4 c nng d thu c dung dch B v kh C. Kh C tc dng vi dung dch KOH thu c
dung dch D. Dung dch D va tc dng vi BaCl2, va tc dng vi NaOH.
Xc nh thnh phn cc cht c trong A, B, C, D. Vit phng trnh cc phn ng xy ra trong th
nghi m trn.
2. Ch dng mt thuc th, trnh by cch nh n bit cc cht b t mu trng ng trong cc l
ring bi t mt nhn sau: BaCO3, BaSO4, Na2SO4, Na2CO3, MgCO3, CuSO4 (khan).
Vit cc phng trnh phn ng xy ra (nu c).
Cu II. ( 1,75 im)
1. Cho hn hp gm ru etylic, axit axetic, nc. Trnh by phng php tch ring ru etylic
nguyn cht v axit axetic (c th ln nc) t hn hp trn? Vit phng trnh phn ng minh ha (nu
c).
2. Khi thc hi n phn ng chuyn ha metan thnh axetilen thu c hn hp kh X gm metan,
axetilen v hidro. t chy hon ton X cn 6,72 lt O 2 (ktc). Sn phm chy c hp th ht vo dung
dch cha 0,1 mol Ca(OH)2.
a. Tnh khi lng ca hn hp X?
b. Hy cho bit dung dch thu c sau khi hp th sn phm chy c khi lng thay i nh th
no so vi dung dch Ca(OH)2 ban u?
Cu III. ( 2,0 im)
Cho 37,2 gam hn hp X gm: R, FeO, CuO (R l kim loi ch c ha tr II, hidroxit ca R khng
c tnh lng tnh) vo 500 gam dung dch HCl 14,6 % (HCl dng d), sau phn ng thu c dung dch
A, cht rn B n ng 9,6 gam (ch cha m t kim loi) v 6,72 lt H2 (ktc). Cho dung dch A tc dng vi
dung dch KOH d, thu c kt ta D. Nung kt ta D trong khng kh n khi lng khng i thu
c 34 gam cht rn E gm hai oxit.
1. Tm R v % khi lng ca mi cht trong hn hp X .
2. Tnh nng phn trm ca cc cht trong dung dch A.
Cu IV. ( 2,0 im)
Hn hp X gm (Al v oxit Fe xOy). Nung m gam X trong iu ki n khng c khng kh, khi
0
xy ra phn ng: Al + FexOy t
Al2O3 + Fe (phn ng cha c cn bng). Sau phn ng thu c
hn hp cht rn Y. Chia Y thnh hai phn:
Phn 1: cho tc dng vi dung dch NaOH d, sau phn ng thu c 1,68 lit kh v 12,6 gam cht rn.
Phn 2: cho tc dng vi dung dch H2SO4 c nng d, sau phn ng thu c 27,72 lt SO2 v dung
dch Z c cha 263,25 gam mui sunfat. Bit cc phn ng xy ra hon ton, cc kh o ktc.
1. Vit phng trnh cc phn ng xy ra.
2. Tm m v cng thc phn t ca oxit FexOy
Cu V. ( 2,25 im)
t chy hon 6,72 lt hn hp kh gm hai hidrocacbon mch h c cng thc C nH2n+2 (A) v
CmH2m (B) thu c 13,44 lit CO2 v 14,4 gam nc. Cc th tch kh o ktc.
1. Tm cng thc phn t ca hai hidrocacbon.
2. T B (mch khng nhnh) vit cc phng trnh phn ng iu ch CH 3COONa khng qu 3
giai on (khng qu 3 phn ng), cc cht v c v iu ki n phn ng xy ra c .
3. Tm cng thc cu to c th c ca B tha mn: khi cho B tc dng vi H 2O, xc tc H2SO4
th thu c hn hp hai sn phm hu c. Vit cc phng trnh phn ng.
Cho: Ag = 108; Al = 27; Ba = 137; C=12; Ca = 40; Cl =35,5; Cu = 64; Fe = 56;H = 1;
Mg = 24; Mn = 55; Na = 23; O = 16; Pb= 207; S = 32; Zn = 65.
Ht
TI LIU BD HSG HA
Trang 21
L Vit Hng
Hng dn chm v biu im
Mn: ha hc
Ngy thi 23/3/2012
S gio dc & o to
Hi Dng
Cu
I
Ni dung
im
2,0
- Cht rn A gm CuO, Ag
0
2Cu + O2 t
2CuO
(Ag khng phn ng vi kh oxi)
- Cho A vo dd H2SO4 c nng:
0
CuO + H2SO4() t
CuSO4 + H2O
0
2Ag + 2H2SO4() t
Ag2SO4 + SO2 + 2H2O
- Dung dch B gm CuSO4, Ag2SO4, H2SO4 d.
- Kh C l SO2. Cho C tc dng vi dd KOH.
SO2 + 2KOH K2SO3 + H2O
SO2 + KOH KHSO3
- Dung dch D gm 2 cht tan K2SO3, KHSO3.
K2SO3 + BaCl2 BaSO3 + 2KCl
KHSO3 + NaOH Na2SO3 + K2SO3
0,25
0,25
0,25
0,25
- Dng dung dch H2SO4 long nhn bit.

- Ly mu th ra cc ng nghim khc nhau, nh du tng ng. Nh dung dch
H2SO4 long, d vo cc ng nghim.
+ Cht rn phn ng to kt ta trng, gii phng kh l BaCO3
+ Cht rn khng tan trong dung dch H2SO4 l BaSO4.
+ Cht rn tan tan to dung dch khng mu, khng gii phng kh l Na2SO4
+ Cht rn tan tan to dung dch mu xanh, khng gii phng kh l CuSO4.
+ 2 cht rn tan, gii phng kh l MgCO3 v Na2CO3.
- Cho tip t t n d 2 cht rn cha nhn bit c (MgCO3 v Na2CO3) vo 2
dung dch ca chng va to thnh.
+ Cht rn no khi ngng thot kh m vn tan l Na2CO3
+ Cht rn no khi ngng thot kh m khng tan thm l MgCO3.
BaCO3 + H2SO4 BaSO4 + CO2 + H2O
MgCO3 + H2SO4 MgSO4 + CO2 + H2O
Na2CO3 + H2SO4 Na2SO4 + CO2 + H2O
II
0,75
0,25
1,75
- Cho hn hp tc dng vi dung dch NaOH d, chng ct thu ly ru etylic ln

nc v cht rn khan cha CH3COONa, NaOH d.
CH3COOH + NaOH CH3COONa + H2O
- Cho CuSO4 khan, d vo hn hp ru v nc, lc b cht rn thu c ru
1
etylic nguyn cht.
- Cho hn hp cht rn tc dng vi dung dch H2SO4 d. Chng ct thu ly
CH3COOH (ln nc).
2CH3COONa + H2SO4 CH3COOH + Na2SO4
- V khi lng ca nguyn t C, H c bo ton trong cc phn ng ho hc nn
khi lng ca kh metan ban u bng vi khi lng ca hn hp X.
2a - Khi t chy lng kh CH4 ban u v t chy X s cho cng lng CO2, H2O
v cng cn lng kh oxi phn ng nh nhau nn ta coi t chy X chnh l t
lng kh CH4 ban u.
TI LIU BD HSG HA
Trang 22
L Vit Hng
0,25
0,25
0,25
0,25
6, 72
nO 2 = 22, 4 0,3 mol
0
CH4 + 2O2 t
CO2 + H2O
0,15
0,3
0,15
0,3
Vy khi lng ca hn hp X l: mX = 0,15.16 = 2,4 gam.
- Khi lng ca CO2 v nc c hp th vo dung dch Ca(OH)2 l:
0,15.44 + 0,3.18 = 12 gam.
- Cc phng trnh phn ng:
CO2 + Ca(OH)2 CaCO3 + H2O
0,1
0,1
2b 0,1
CO2 + H2O + CaCO3 Ca(HCO3)2
0,05
0,05
0,05
- Khi lng dung dch sau phn ng tng ln so vi dung dch Ca(OH)2 ban u
l: 12 (0,1- 0,05).100 = 7 gam.
III
0,25
0,25
0,25
2,0
Tm R v % khi lng cc cht trong X

nHCl = (500.14,6)/(100.36,5) = 2 mol;
nH 2 = 6,72/22,4= 0,3 mol
-Cho X + dd HCl d:
V sn phm c H2, nn R l kim loi ng trc H trong dy hot ng ho hc,
nn R ng trc c Cu.
V axit d nn sau phn ng khng th c R d, m 9,6 gam cht rn B ch cha
m t kim loi, suy ra phi c phn ng ca R vi mui CuCl2 to ra Cu kim loi v
hiroxit ca R s khng tan trong nc ( y FeCl2 cha phn ng vi R do mc
phn ng ca CuCl2 vi R cao hn so vi FeCl2). Do B l Cu.
Dung dch A c RCl2, FeCl2 v HCl d. V dung dch A tc dng vi KOH d thu
kt ta D, sau nung D n hon ton thu c 34 gam cht rn E gm 2 oxit,
suy ra 2 oxit ny l RO v Fe2O3. Nh v y trong dung dch A khng c CuCl2.
R + 2HCl RCl2 + H2
(1)
FeO + 2HCl FeCl2 + H2O (2)
CuO + 2HCl CuCl2 + H2O (3)
R + CuCl2 RCl2 + Cu
(4)
- Cho dung dch A tc dng dung dch KOH d:
1
HCl + KOH KCl + H2O
(5)
RCl2 + 2KOH R(OH)2 + 2KCl (6)
FeCl2 + 2KOH Fe(OH)2 + 2KCl (7)
Nung kt ta ngoi khng kh:
0
R(OH)2 t
RO + H2O
(8)
t0
2Fe(OH)2 + O2
Fe2O3 + 2H2O (9)
E gm hai oxit: RO v Fe2O3
nCu = 9,6/64 = 0,15 mol
Theo p (3),(4): nCuO = nCuCl2 = nCu = 0,15 mol
Theo p (1), (4): nRCl2 = nR = nH2 + nCuCl2 = 0,3 + 0,15 = 0,45 mol
Theo p (6)(8): nRO = nR(OH)2 = nRCl2 = 0,45 mol
t nFeO ban u = x mol
Theo cc phn ng (2),(7),(9): nFe2O3 = .nFeO = 0,5x (mol)
Ta c: mE = mRO + mFe2O3 = 0,45.(MR + 16) + 0,5x.160 = 34 gam (*)
mX = mR + mFeO + mCuO = 0,45.MR + 72x + 80.0,15 = 37,2 gam
(**)
Gii h (*), (**) ta c: MR = 24;
x = 0,2
V y R l Mg
T tnh c % khi lng cc cht trong hn hp X:
TI LIU BD HSG HA
Trang 23
L Vit Hng
0,25
0,5
0,5
%mMg = mMg.100/mX = (0,45.24.100)/37,2 = 29,0%
%mFeO = 0,2.72.100/37,2 = 38,7%
%mCuO = 32,3%
0,25
Tnh nng phn trm cc cht trong dung dch A:

A c : MgCl2, FeCl2, HCl d
mMgCl2 = 0,45. 95 = 42,75 gam
mFeCl2 = 0,2.127 =25,4 gam
Ta c: nHCl p = nCl trong mui = 2.nMgCl2 + 2.nFeCl2 = 1,3 mol
=> mHCl d = 500.0,146- 1,3.36,5 =25,55 gam
2 p dng nh lu t BTKL:
mddA = mX + mdd HCl ban u mB mH2 = 527 gam
T tnh c nng phn trm ca cc cht trong dung dch A:
C%(MgCl2) = 8,11%
C%(FeCl2) = 4,82%
C%(HCl) = 4,85%
IV
0,25
0,25
2,0
Cc phng trnh phn ng:

0
3FexOy + 2yAl t
3xFe + yAl2O3
(1)
Cho phn 1 vo dung dch NaOH d c kh, suy ra trong cht rn c Al d. V Al
cn d, m phn ng xy ra hon ton nn FexOy ht. V y thnh phn ca Y c:
Al2O3, Fe v Al d.
Phn 1 tc dng vi dung dch NaOH d:
Al2O3 + 2NaOH 2NaAlO2 + H2O
(2)
1
2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2 (3)
12,6 gam cht rn khng tan l Fe
Phn 2 tc dng vi H2SO4 c nng d:
0
Al2O3 + 3H2SO4() t
Al2(SO4)3 + 3H2O (4)
0
2Al + 6H2SO4() t
Al2(SO4)3 + 3SO2 + 6H2O (5)
t0
2Fe + 6H2SO4()
Fe2(SO4)3 + 3SO2 + 6H2O (6)
T p(3) c nAl = 2/3.nH 2 = 0,05 mol
Li c: nFe = 12,6/56 = 0,225 mol
V y trong phn 1 c ( Al2O3, Fe (0,225 mol), Al(0,05 mol))
- Gi s phn 2 c khi lng gp a ln phn 1. T suy ra trong phn 2 c:
( Al2O3, Fe(0,225a mol) v Al (0,05a mol)
T p (5) v (6) suy ra:
0,5
0,5
nSO 2 = 3/2.(nAl + nFe) = 3/2.(0,05a + 0,225a) = 27,72/22,4= 1,2375 .

T tnh c a = 3.
Suy ra trong phn 2 c: 0,675 mol Fe v 0,15 mol Al
M t khc, tng khi lng mui sunfat = mAl2 ( SO4 )3 + m Fe2 ( SO4 )3 = 263,25 gam (7)
2 Theo p (4), (5): n Al2 ( SO4 )3 = n Al2O3 + . nAl = n Al2O3 + 0,075
Theo p (6): n Fe2 ( SO4 )3 = .nFe = 0,3375 mol
Thay cc s mol vo pt(7) s tnh c n Al2O3 = 0,3 mol
0,5
V y khi lng ca phn 2 l: mphn 2 = m Al2O3 + mFe + mAl = 0,3.102 + 0,675.56 +

0,15.27 = 72,45 gam
=> khi lng ca phn 1 l: mphn 1 = 72,45/3 =24,15 gam
T tnh c m = mphn 1 + m phn 2 = 96,6 gam
* Tm oxit:
Xt phn 2: t pt (1) c:
3x : y = nFe : n Al2O3 = 0,675 : 0,3 => x : y = 3: 4 V y oxit l Fe3O4
TI LIU BD HSG HA
Trang 24
L Vit Hng
0,5
2,25
V
nhh = 0,3 mol; n(CO2) = 0,6 mol; n(H2O) = 0,8 mol
t s mol hai cht CnH2n+2 v CmH2m ln lt l x v y mol
=> nhh = x + y = 0,3 mol (*)
t hn hp:
0
CnH2n+2 + O2 t
n CO2 + (n+1) H2O (1)
Mol
x
nx
(n+1)x
3m
0
CmH2m +
O2 t
m CO2 + m H2O
(2)
2
Mol
y
my
my
1
0,25
T cc p (1) v (2) ta c:
nCO2 = nx + my = 0,6
(**)
nH2O = (n+1)x + my = 0,8 (***)
Ly (***)-(**) ta c x = 0,2;
Thay x vo (*) suy ra y = 0,1
Thay x, y vo (**) ta c: 0,2n + 0,1m = 0,6 hay 2n + m = 6
Th cc gi tr ca m, ta c n:
n
1
2
3
m
4
2
0
CTPT A (CH4); B(C4H8) A(C2H6); B(C2H4)
Loi
T B vit phng trnh iu ch CH3COONa (khng qu 3 giai on):
- Nu B l C4H8:
C4H8 + H2 C4H10
xt , t 0
2 C4H10 + 5 O
4 CH3COOH + 2 H2O
2
- Nu B l C2H4:
C2H4 + H2O
axit C2H5OH
men
C2H5OH + O
CH3COOH + H2O
2
0,25
0,5
0,25
0,25
V B tc dng H2O c H2SO4 lm xc tc thu c hn hp 2 sn phm hu c, cho

nn B khng th l C2H4. V y B phi l C4H8.
V c hai sn phm c to ra nn CTCT ca B tha mn l:
CH2 =CH-CH2-CH3 v CH2=C(CH3)2
Ptp:
3
CH2 =CH-CH2-CH3 + H2O
CH3-CHOH-CH2-CH3
axit
axit
CH2 =CH-CH2-CH3 + H2O
HO-CH2-CH2-CH2-CH3
CH2=C(CH3)2 + H2O
axit (CH3)3C-OH
CH2=C(CH3)2 + H2O
axit HO-CH2-CH(CH3)2
0,25
0,25
0,25
Ch :
-
Nu phng trnh khng cn bng th tr na s im ca phng trnh . Hc

sinh c cch gii khc tng ng ng vn cho im ti a.
im ton bi lm trn n 0,25
TI LIU BD HSG HA
Trang 25
L Vit Hng
9
K THI CHN HC SINH GII CP TNH
S GIO DC V O TO
LNG SN
LP 9 THCS NM HC 2011 2012
CHNH THC
Mn thi: HA HC
Ngy thi: 22/03/2012
( thi gm 2 trang v c 6 cu)
Cu 1. (3,5 im)
1. Trong cng nghip, kh NH3 mi iu ch thng ln hi nc. lm kh kh NH3 ngi ta
c th dng ha cht no sau y: H2SO4 c, dung dch HCl c, P2O5, CaO, KOH khan? Gii thch, vit
phng trnh ha hc ca phn ng xy ra ( nu c).
2. C mt hn hp kh gm: CO2, CH4, C2H4. Hy trnh by phng php ha hc :
a. Thu c kh CH4 tinh khit t hn hp trn.
b. Thu c CO2 tinh khit t hn hp trn.
Cu 2. ( 3,5 im)
Nhng mt thanh st v mt thanh km vo cng mt cc cha 500ml dung dch CuSO4. Sau mt
thi gian ly ng thi hai thanh kim loi ra khi cc th mi thanh u c kim loi ng bm vo, khi
lng dung dch gim i 0,22 gam so vi ban u. Trong dung dch sau phn ng, nng mol ca
ZnSO4 ln gp 2,5 ln nng mol ca FeSO4 ( th tch dung dch coi nh khng i so vi trc phn
ng). Thm dung dch NaOH d vo cc, lc ly kt ta ri nung trong khng kh ti khi lng khng
i, thu c 14,5 gam cht rn.
a. Vit phng trnh ha hc ca phn ng c th xy ra.
b. Tnh s gam Cu bm ln mi thanh kim loi v nng mol ca dung dch CuSO4 ban u.
Cu 3. (3,5 im)
1. Vit cc phng trnh ha hc hon thnh s phn ng sau (Bit A1, A2, A3, A4, A5 l cc cht
v c):
A3 ti l1:1 ( t o , Pd )
A2
A1
C 2 H 2
(1)
C2 H 4
A3 til1:1(t o , Ni )
(2)
+ A4 d
(4)
C2 H 6
(3)
+A2
H2SO4 long
(5)
+ A5
C2H2Br4
C2H5OH
A3
(6)
2. t chy hon ton 224 ml (ktc) mt hidrocacbon th kh c cng thc tng qut l CnH2n + 2,
sn phm chy hp th vo 2 lt dung dch Ba(OH)2 0,01M, sau phn ng hon ton thu c 1,97 gam
kt ta. Xc nh cng thc phn t ca hidrocacbon.
Cu 4. ( 3 im)
90oC c 540 gam dung dch CuSO4 bo ha. Lm lnh dung dch xung cn 15oC. Hi c bao
nhiu gam tinh th CuSO4.5H2O tch ra khi dung dch trong qu trnh lm lnh. Bit tan SCuSO4 (90oC)
= 80 gam v SCuSO4 (15oC) = 25 gam.
Cu 5 ( 3,5 im)
Dung dch A cha hn hp Na2CO3 0,75M v NaHCO3 0,5M. Dung dch B cha H2SO4 1M. Tnh
th tch kh CO2 (ktc) thot ra khi:
a. rt t t 100 ml dung dch A vo 150 ml dung dch B.
b. rt t t 200 ml dung dch A vo 150 ml dung dch B.
c. rt t t 150 ml dung dch B vo 200 ml dung dch A.
TI LIU BD HSG HA
Trang 26
L Vit Hng
Cu 6. ( 3 im)
C 7 l ng 7 dung dch mt nhn c nh s t (1) n (7) gm: (NH4)2CO3, BaCl2, MgCl2,
H2SO4, Ba(OH)2, NaOH, Na2CO3. Thc hin cc th nghim c kt qu nh sau:
- Cht (1) tc dng vi cht (4) hoc (5) u to ra kt ta; tc dng vi cht (2) hoc (7) u to
ra kh.
- Cht (2) tc dng vi cht (4) hoc (5) u to ra kt ta; tc dng vi cht (3) to ra kh; tc
dng vi cht 6 th to ra c kt ta ln kh.
- Cht (5) tc dng vi cht (3), (6) hoc (7) u to ra kt ta.
- Cht (7) tc dng vi cht (4) hoc (6) u to ra kt ta.
Hy bin lun xc nh cc cht t (1) n (7). ( Hc sinh khng cn vit phng trnh ha hc ca
cc phn ng xy ra cu ny).
HT
Hc sinh c s dng bng tun hon
TI LIU BD HSG HA
Trang 27
L Vit Hng
S GIO DC V O TO
LONG AN
CHNH THC
10
MN THI: HA HC
NGY THI: 11/ 4/ 2012
THI GIAN:150 PHT (khng k thi gian pht )
Cu 1: (2 im) Hp cht A c cng thc R2X, trong R chim 74,19% v khi lng. Trong ht nhn
ca nguyn t R c s ht khng mang in nhiu hn s ht mang in l 1 ht. Trong ht nhn nguyn
t X c s ht mang in bng s ht khng mang in. Tng s proton trong phn t R 2X l 30. Tm
cng thc phn t ca R2X.
Cu 2: (6 im)
2.1/ (3 im) Hn hp A gm cc dung dch: NaCl, Ca(HCO 3)2, CaCl2, MgSO4, Na2SO4. Lm th
no thu c mui n tinh khit t hn hp trn?
2.2/ (3 im) Ha tan hon ton 13,45g hn hp 2 mui hidro cacbonat v cacbonat trung ca 1 kim
loi kim bng 300ml dung dch HCl 1M. Sau phn ng phi trung ha HCl d bng 75ml dung dch
Ca(OH)2 1M.
a. Tm cng thc 2 mui.
b. Tnh khi lng mi mui c trong hn hp ban u.
Cu 3: (5 im)
3.1/ (2 im) Xc nh B, C, D, E, G, M. Bit A l hn hp gm Mg v Cu. Hy vit phng trnh
ha hc thc hin s chuyn ha sau:
Dung dch D
+
Na
+O2 d
+ dd HCl
A
B
C
Kh E
Nung
+ E, t0
Kt ta G
B
M
3.2/ (3 im) Cho M l kim loi to ra hai mui MClx, MCly v to ra 2 oxit MO0,5x, M2Oy c thnh
phn v khi lng ca Clo trong 2 mui c t l 1 : 1,173 v ca oxi trong 2 oxit c t l
1 : 1,352.
a. Xc nh tn kim loi M v cng thc ha hc cc mui, cc oxit ca kim loi M.
b. Vit cc phng trnh phn ng khi cho M tc dng ln lt vi MCly; H2SO4 c, nng.
Cu 4: ( 3 im) t chy hon ton 2,24 l (ktc) mt hirocacbon A th kh. Sau dn ton b sn
phm chy qua bnh ng dung dch Ca(OH)2 c cha 0,2 mol Ca(OH)2 th c 10g kt ta to nn, ng
thi thy khi lng bnh tng thm 18,6g.
a. Xc nh cng thc phn t ca A.
b. Vit cng thc cu to c th c ca A.
Cu 5: (4 im) Cho 13,6g hn hp gm Fe v Fe2O3 tc dng hon ton vi 91,25g dung dch HCl
20% va .
a. Tnh thnh phn phn trm v khi lng ca mi cht c trong hn hp ban u.
b. Tnh nng phn trm ca cht tan c trong dung dch sau phn ng.
c. Nu ha tan hon ton 13,6g hn hp ni trn vo H 2SO4 c, nng, khi phn ng kt thc dn
ton b kh sinh ra vo 64 ml dung dch NaOH 10% (D = 1,25g/ml) th thu c dung dch A. Tnh nng
mol ca cht tan c trong dung dch A.( Bit rng th tch dung dch thay i khng ng k)
---HT--Ch : Hc sinh c php s dng bng tun hon cc nguyn t ha hc.
TI LIU BD HSG HA
Trang 28
L Vit Hng
S GIO DC V O TO
LONG AN
CHNH THC
TI LIU BD HSG HA

MN THI: HA HC
NGY THI: 11/ 4/ 2012
THI GIAN: 150 PHT (khng k thi gian pht )
HNG DN CHM
Trang 29
L Vit Hng
Cu
Cu 1
2
Cu 2
2.1
3
2.2
3
p n
t s proton, notron l P, N
2 M R x100
74,19
Ta c:
(1)
2M R M X
NR - PR = 1 => NR = PR + 1
(2)
PX = N X
(3)
2PR + PX = 30 => PX = 30 - 2PR (4)
M M = P + N
(5)
Th (2),(3),(4), (5)vo (1) ta c:
PR N R
0, 7419
PR N R PX
2 PR 1
0, 7419
2 PR 1 30 2 PR
2P 1
R
0,7419
31
PR = 11 (Na)
Th PR vo (4) => PX = 30 22 = 8 ( Oxi)
Vy CTHH: Na2O
im
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
Cho dung dch BaCl2 d vo dung dch A, lc b kt ta, dung dch cn

li: NaCl, MgCl2, BaCl2 d, CaCl2, Ca(HCO3)2.
BaCl2 + MgSO4 BaSO4 + MgCl2
Na2SO4 + BaCl2 BaSO4 + 2NaCl
Cho dung dch Na2CO3 d vo dung dch cn li, lc b kt ta, dung
dch cn li: NaCl, NaHCO3, Na2CO3 d.
MgCl2 + Na2CO3 MgCO3 + 2NaCl
BaCl2 + Na2CO3 BaCO3 + 2NaCl
CaCl2 + Na2CO3 CaCO3 + 2NaCl
Ca(HCO3)2 + Na2CO3 CaCO3 + 2NaHCO3
Cho dung dch HCl d vo dung dch cn li.
c cn dung dch thu c NaCl tinh khit.
NaHCO3 + HCl NaCl + CO2 + H2O
Na2CO3 + 2HCl 2NaCl + CO2 + H2O
-
a. nHCl = 0,3 x 1 = 0,3 mol

nCa ( OH )2 = 0,075 x 1 = 0,075 mol
AHCO3 + HCl ACl + CO2 + H2O
x
x
(mol)
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
A2CO3 + 2HCl 2ACl + CO2 + H2O

y
2y
(mol)
Ca(OH)2 + 2HCl CaCl2 + 2H2O
0,075
0,15
(mol)
Ta c: x + 2y = 0,15
Vi 0 < y < 0,075
Mt khc: Ax + 61x + 2Ay +60y = 13,45
A ( 0,15 2y) + 61 ( 0,15 2y ) + 2Ay +60y = 13,45
0,15A - 2Ay + 9,15 - 122y + 2Ay + 60y = 13,45
0,15A - 4,3 = 62y
0,15 A 4,3
y=
62
0,15 A 4,3
Vi y > 0 =>
>0
62
A > 28,7 (1)
0,15 A 4,3
TI LIU BD HSG
Vi yHA
< 0,075
=>0 0 Trang 30< 0,075
00 0
tt t t t 62
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
L Vit Hng
0,25
Ch :
Hc sinh c th gii cch khc, ng vn hng trn s im.

Ht
TI LIU BD HSG HA
Trang 31
L Vit Hng
S GD&T NGH
AN
11
K THI CHN HC SINH GII TNH LP 9 CP THCS
NM HC 2011 2012
Mn thi: HA HC - BANG A
Thi gian lm bi: 120 pht
chnh thc
Bi 1: (4,5 im)
1. Vit bn phng trnh ha hc trc tip to ra HCl t Cl2 bng bn cch khc nhau (cc cch
khc nhau nu cht tc dng vi Cl2 khc loi).
2. Chn 7 cht rn khc nhau m khi cho mi cht tc dng vi dung dch H 2SO4 c, nng, d
u cho sn phm l Fe2(SO4)3, SO2 v H2O. Vit cc phng trnh ha hc.
Bi 2: (4,0 im)
Mt hn hp rn A gm 0,2 mol Na2CO3; 0,1 mol BaCl2 v 0,1 mol MgCl2. Ch c dng thm
nc hy trnh by cch tch mi cht trn ra khi hn hp. Yu cu mi cht sau khi tch ra
khng thay i khi lng so vi ban u (Cc dng c, thit b cn thit k c ngun nhit, ngun
in cho y ).
Bi 3: (2,5 im)
T Metan, mui n, (cc cht xc tc, dng c cn thit cho y ) vit cc phng trnh ha hc
iu ch ra: iclometan, nha P.V.C, nha P.E, icloetilen, etan, etylclorua. Ghi r iu kin ca
phn ng nu c.
Bi 4: (4,5 im)
Trn u 30,96 gam hn hp bt X gm MgCO3 v kim loi R c ha tr khng i ri chia
lm hai phn bng nhau.
- t nng phn I trong khng kh, sau khi cc phn ng xy ra hon ton thu c 15 gam hn
hp cc oxit kim loi.
- ha tan va ht phn II cn 500ml dung dch cha hn hp HCl 1,2M v H 2SO4 0,24M
c dung dch A v c V lt kh B bay ra.
1. Vit cc phng trnh ha hc.
2. Xc nh kim loi R v t khi ca B so vi H2.
3. Cho 61,65 gam Ba kim loi vo dung dch A. Sau khi cc phn ng kt thc, lc c m
gam rn F khng tan v 500 ml dung dch E. Tnh gi tr ca m v nng C M ca mi cht tan c
trong dung dch E.
Bi 5: (4,5 im)
Chia 9,84 gam hn hp kh X gm Etilen v 1 hirocacbon mch h A thnh hai phn bng
nhau.
- Dn phn I qua dung dch Brom d, sau khi phn ng kt thc c V lt kh A thot ra, khi
lng Brom tham gia phn ng l 8 gam.
- t chy hon ton phn II ri cho ton b sn phm chy vo bnh c cha 500 ml dung dch
Ba(OH)2 0,66M. Sau khi phn ng kt thc thu c 63,04 gam kt ta. Dung dch sau khi lc b
kt ta b gim i m gam so vi khi lng ca dung dch Ba(OH)2 ban u.
1. Vit cc phng trnh ha hc.
2. Xc nh cng thc phn t ca A.
3. Tnh gi tr ca m v gi tr ca V KTC.
Cho H:1; C:12; O:16; Mg:24; Al:27; S:32; Cl:35,5; Ca:40; Fe:56; Cu:64; Zn: 65;
Ba:137.
.......... Ht ..........
TI LIU BD HSG HA
Trang 32
L Vit Hng
S GD&T NGH AN
K THI CHN HC SINH GII TNH LP 9 CP THCS

NM HC 2011 2012
HNG DN CHM THI CHNH THC
Mn: HA HC BANG A
(Hng dn chm gm c 04 trang)
Bi
Ni dung
im
Cl2 + H2
as
2 HCl
Cl2 + H2O
HCl + HClO
Cl2 + CH4
askt
CH3Cl + HCl
Cl2 + SO2 + 2H2O
2HCl + H2SO4
Mi
pt
ng
cho
0,25
Hc sinh c th chn mt s cht khc nh: NH3, H2S

Cc cht rn c th chn: Fe;FeO;Fe3O4;Fe(OH)2;FeS;FeS2;FeSO4
Cc pthh :
Bi 1
4.5
2Fe + 6H2SO4(c)
t0
2FeO + 4H2SO4(c)
Fe2(SO4)3 + 3SO2 + 6H2O

t0
Fe2(SO4)3+SO2+ 4H2O
t0
2Fe3O4 + 10H2SO4(c)
2Fe(OH)2 + 4H2SO4(c)
2FeS + 10H2SO4(c)
2FeS2 + 14H2SO4(c)
2FeSO4 + 2H2SO4(c)
Bi 2
4
t0
3 Fe2(SO4)3 + SO2 + 10H2O

t0
Fe2(SO4)3 + SO2 + 6H2O

Fe2(SO4)3 + 9SO2 + 10H2O
t0
Fe2(SO4)3 + 15SO2 + 14H2O
t0
Fe2(SO4)3 + SO2+ 2H2O
Mi
pt
ng
cho
0,5
mi
pt
khng
cn
bng
hoc
cn
bng
sai
u
tr
0,25
Cho hn hp ha tan vo nc c dung dch B ( cha 0,4 mol NaCl )

Lc ly rn C gm 0,1 mol BaCO3 v 0,1 mol MgCO3
Na2CO3 + BaCl2
BaCO3 + 2NaCl
0,75
Na2CO3 + MgCl2 MgCO3 + 2NaCl

in phn dung dch B c mng ngn n khi ht kh Cl2 th dng li thu c
dung dch D (cha 0,4 mol NaOH) v thu ly hn hp kh Cl2 v H2vaof bnh kn
to iu kin phn ng xy ra hon ton c kh HCl. Cho nc vo thu
c dung dch E c 0,4 mol HCl.
2NaCl + 2H2O
H2 + Cl2 2HCl
dpddcomangngan
2NaOH + H2 + Cl2
Chia dd E thnh 2 phn bng nhau E1 v E2 . Nhit phn hon ton rn C trong
bnh kn ri thu ly kh ta c 0,2 mol CO2. Cht rn F cn li trong bnh gm
0,1 mol BaO v 0,1mol MgO
t0
BaO
+ CO2
MgCO3
t0
MgO
+ CO2
BaCO3
0,75
Cho CO2 sc vo dd D phn ng xy ra hon ton ri un cn dd sau phn

ng ta thu c 0,2 mol Na2CO3
TI LIU BD HSG HA
Trang 33
L Vit Hng
0,75
2NaOH + CO2
Na2CO3 + H2O
Ha tan rn F vo nc d, lc ly phn khng tan l 0,1 mol MgO v dd sau khi

lc b MgO cha 0,1 mol Ba(OH)2
Cho MgO tan hon ton vo E1 ri un cn dd sau phn ng ta thu c 0,1 mol
MgCl2
MgO + 2HCl MgCl2 + H2O
Cho dd Ba(OH)2 tc dng vi E2 ri un cn dd sau phn ng c 0,1 mol
BaCl2
BaO + H2O Ba(OH)2
0,75
Ba(OH)2 + 2HCl BaCl2 + 2H2O

Cc pthh:
2CH4
2NaCl
15000 c
Lamlanhnhanh
dienphanNC
CH4 + Cl2
2Na + Cl2
as
CH2Cl2 + 2HCl
Bi 3
C2H2 + HCl C2H3Cl
2.5
n(C2H3Cl)
n(C2H4)
C2 H 3Cl n
trunghop
Pd ,t 0
C2H2 + H2
Vit
ng
mi
pt cho
0,25
C2H2+3H2
thiu
t hn
3 k
tr
0,25
; t
3 k
tr
ln
tr
0,5
(P.V.C)
C2H4
C2 H 4 n
trunghop
C2H2 + Cl2 C2H2Cl2

C2H4 + H
2
Ni,t o
C2H6
C2H4 + HCl C2H5Cl

Bi 4
Cc pthh :
4.5
4R + xO2
MgCO3
t0
2R 2Ox
(1)
MgO + CO2
(2)
2 R + 2xHCl 2 R Clx + xH2
(3)
MgCO3 + 2HCl MgCl2 + CO2 + H2O
(4)
2 R + xH2SO4 R 2(SO4)x + xH2
0,5
(5)
MgCO3 + H2SO4 MgSO4 + CO2 + H2O

(6)
61, 65
nHCl = 0,5.1,2 = 0,6 (mol) ; nBa
0, 45( mol )
137
30,96
nH 2 SO4 = 0,5.0,24 = 0,12(mol) ; m mi phn =
15, 48( g )
2
Gi M l khi lng mol ca kim loi R
0,25
1
t nR mi phn l a (mol); nMgCO3 mi phn l b (mol)

mX mi phn = Ma +84b = 15,48
1
1
T (1): nR2Ox =
nR = a mR2Ox = ( M+ 8x).a
2
2
(2): nMgO = nMgCO3 = b mMgO = 40b
M.a+ 8ax+40b = 15
T (3) v (5): nH = x. nR = ax
(4) v (6): nH = 2 nMgCO3 = 2b
ax+ 2b = 0,84
TI LIU BD HSG HA
Trang 34
L Vit Hng
44b 8ax 0, 48
axb0,84
8t 0, 48
2b 44
t ax= t c h
2b t 0,84
Gii h ny ta c: b = 0,12; t = 0,6
0, 6
Vi t = 0,6 a =
x
b = 0,12 mMgCO3 = 0,12.84 = 10,08 (g) mR = 15,48 10,08 =5,4 (g)
0, 6
Ma = 5,4 hay M .
= 5,4 M = 9x.
x
0,5
Chn: x= 1 M=9 (loi)
Ta c hpt:
x=2 M=18 (loi)

x=3 M=27 R l Al
3
T (3) v (5) c nH2 = nAl = 0,3 mol
2
T (4) v (6) c nCO2 = nMgCO3 = 0,12 mol
0,3.2 0,12.44
T khi ca B so vi H2 =
7
(0,3 0,12).2
Ba + 2H2O Ba(OH)2 + H2
0,25
(7)
3Ba(OH)2 + Al2(SO4)3 3BaSO4 + 2Al(OH)3

Ba(OH)2 + MgSO4 BaSO4 + Mg(OH)2
(8)
(9)
3Ba(OH)2 + 2AlCl3 3BaCl2 + 2Al(OH)3
(10)
Ba(OH)2 + MgCl2 BaCl2 + Mg(OH)2
(11)
C th Ba(OH)2 + 2Al(OH)3 Ba(AlO2)2 + 4H2O
(12)
0,5
Trong dd A c cha 4 cht tan: MgCl2; MgSO4; AlCl3; Al2(SO4)3, trong :

Tng nMg = 0,12; nAl = 0,2
nCl = 0,6; nSO4 = 0,12
Theo pt(7) nBa (OH )2 = nBa = 0,45; nOH trong Ba(OH)2 = 2.0,45 = 0,9 mol
T (8) v (9): nBa (OH )2 = nSO4 = nBaSO4 = 0,12 mol < 0,45 mol
nBa (OH )2 d: Cc phn ng (10 v (11) xy ra cng (8); (9)
3
3
T (8) v (10) nBa (OH )2 = nAl (OH )3 = nAl = 0,3
2
2
T (9) v (11) nBa (OH )2 = nMg ( OH )2 = nMg = 0,12
Sau (8); (9); (10); (11) nBa (OH )2 cn d = 0,45 - 0,3 - 0,12 = 0,03 (mol)
phn ng (12) xy ra
T (12) nAl (OH )3 b tan = 2 nBa (OH )2 = 2.0,03 = 0,06 (mol) < 0,2 (mol)
Sau khi cc phn ng kt thc nAl (OH )3 cn li = 0,2 - 0,06 = 0,14 (mol)
Vy khi lng kt ta F chnh l gi tr ca m v
m = 0,12.233 + 0,12.58 + 0,14.78 = 45,84(g)
1
1
T (10) v (11) nBaCl2 = nCl = .0,6 = 0,3 (mol)
2
2
Vy nng CM ca cc cht tan trong dd E ln lt l:
CM BaCl = 0,3:0,5 = 0,6 M
0,5
T (12) nBa ( AlO2 )2 = nBa (OH )2 d =0,03

CM Ba ( AlO ) = 0,03:0,5 = 0,06 M
2 2
Cu ny gii v l lun bng nhiu phng php khc nhau. Nu bi lm da

vo nh lut bo ton nguyn t , nhm nguyn t v lp lun, tnh ton chnh
TI LIU BD HSG HA
Trang 35
L Vit Hng
xc cho cng kt qu vn cho im ti a

Bi 5
Khi lng mi phn = 9,84: 2= 4,92(g); nBr2 = 8:160 = 0,05 ( mol)
4.5
V cho phn I qua dd Brom vn c kh bay ra nn A khng tc dng vi brom

trong dung dch
t cng thc tng qut ca A l CxHy ta c cc pthh
C2H4 + Br2 C2H4Br2 (1)
C2H4 + 3O2
t0
2CO2 + 2H2O (2)
4x y
CxHy +
O2
4
t0
y
xCO2 + H2O
2
0,5
(3)
CO2 + Ba(OH)2 BaCO3 + 2H2O (4)
c th 2CO2 + Ba(OH)2 Ba(HCO3)2 (5)

nBa (OH )2 = 0,5.0,66 = 0,33 (mol); nBaCO3 = 63,04:197 = 0,32(mol)
V nBaCO3 < nBa (OH )2 phi xt hai trng hp
TH 1: Ba(OH)2 d khng c phn ng (5)
T (1): nC2 H 4 mi phn = nBr2 = 0,05 (mol ) 1,4(g)
T (2) nCO2 = 2 nC2 H 4 = 2.0,05 = 0,1 (mol)
T (4) nCO2 = nBaCO3 = 0,32 (mol)
nCO2 (3) = 0,32-0,1 = 0,22 (mol) nC trong CxHy = 0,22 (mol) 2,64 (g)
mt khc mCx H y = 4,92-1,4 = 3,52 (g) mHtrong CxHy = 3,52-2,64 = 0,88 (g)
0,88 (mol)
x 0, 22 1
vy cng thc phn t ca A l CH4;
T CT ca CxHy
y 0,88 4
TH2: CO2 d c phn ng (5)
1,25
T (4): nCO2 = nBa (OH )2 = nBaCO3 = 0,32 (mol)

nBa (OH )2 (5) = 0,33-0,32 =0,01 (mol)
T (5): nCO2 = 2 nBa (OH )2 = 2.0,01 = 0,02 (mol)
1,25
Tng nCO2 = 0,32 + 0,02 = 0,34 (mol)

nCO2 (3) = 0,34 - 0,1 = 0,24 (mol) nCtrong CxHy = 0,24 (mol) 2,88(g)
mH trong CxHy = 3,52 - 2,88 = 0,64 (g) 0,64 (mol)
x 0, 24 3
T CT ca CxHy
y 0, 64 8
vy cng thc phn t ca A l C3H8;
C 2 trng hp A u l an kan khng tc dng vi Br2 trong dd nn u tha
mn, ph hp bi
Nu A l CH4 th nCH 4 = nCO2 = 0,22 (mol) V = 4,928 lt
0,75
T (2) v (3) n H 2O = 0,1 + 0,44 =0,54 mol

Tng m sn phm chy = 0,32.44 + 0,54.18 = 23,8 (g)
khi lng dung dch b gim = 63,04 23,8 = 39,24 (g)
Nu A l C3H8
1
1
nC3 H8 = . nCO2 = .0,24 = 0,08 (mol) V = 1,792 lt
3
3
T (2) v (3) n H 2O = 0,1 + 0,32=0,42 mol
0,75
Tng m n phm chy = 0,34.44 + 0,42 .18 = 22,52 (g)

TI LIU BD HSG HA
Trang 36
L Vit Hng
khi lng dung dch b gim = 63,04 22,52 = 40,52 (g)
cu ny nu bi lm l lun: v A mch h v khng cng brom trong dd nn

suy ra A l an kan nn cng thc tng qut l CnH2n+2 ri gii ra 2 trng hp
n =1; n=3 vn cho im ti a
---------- Ht --------* Lu : Bi lm cch khc ng vn cho im ti a.
TI LIU BD HSG HA
Trang 37
L Vit Hng
S GIO DC V O
TO PH TH
12
THI CHN HC SINH GII CP TNH LP 9 THCS NM
HC 2011 2012
chnh thc
Mn: Ha hc
Thi gian: 150 pht khng k thi gian giao
( thi c: 01 trang)
Cu I: (2,0 im)
Cho ln lt tng cht: Fe, BaO, Al 2O3, v KOH vo ln lt cc dung dch: NaHSO 4, CuSO4. Hy
vit PTHH ca cc phn ng xy ra.
Cu II: (3,0 im)
1) C 1 hh gm 5 kim loi: Al, Mg; Fe, Cu, Ag. Hy dng PPHH tch ring tng kim loi vi khi
lng khng i. Vit PTHH xy ra trong qu trnh tch.
2) Vit PTP trong mi trng hp sau
a. Oxit + Axit 2 mui + oxit
b. Mui + kim loi 2 mui
c. Mui + baz 2 mui + 1oxit
d. Mui + kim loi 1 mui
Cu III: (3,0 im)
1) Trn V1 lit dd HCl 0,6M vi V2 lt dd NaOH 0,4M thu c 0,6 lit dd A. Tnh V1, V2 bit 0,6 lt dd
A c th ho tan ht 1,02 gam Al2O3 (coi s pha trn khng lm thay i th tch)
2) Sc t t a mol kh CO2 vo 800 ml dd X gm KOH 0,5M v Ca(OH)2 0,2M. Tm gi tr ca a
thu c khi lng kt ta ln nht.
Cu IV: (10,0 im)
1) Ho tan cc cht gm Na2O, NaHCO3, BaCl2, NH4Cl c cng s mol vo nc d c dd A v
kt ta B. Hi dd A v kt ta B cha nhng cht g? Vit PTHH ca cc phn ng minh ho.
2) Ho tan ht 3,2 gam oxit M2On trong lng va dd H 2SO4 10%, thu c dd mui c nng
12,903%. Sau phn ng em c bt dd v lm lnh thu c 7,868 gam tinh th mui vi hiu
sut 70%. Xc nh cng thc ca tinh th mui .
3) Cho x gam mt mui halogenua ca mt kim loi kim tc dng vi 200ml dd H 2SO4 c, nng
va . Sau khi phn ng xy ra hon ton, thu c hn hp sn phm A trong c mt kh B
(mi trng thi). Cho kh B tc dng vi dd Pb(NO 3)2 (d) thu c 47,8 gam kt ta mu en.
Phn sn phm cn li, lm kh thu c 342,4 gam cht rn T. Nung T n khi lng khng i
thu c 139,2 gam mui duy nht.
a) Tnh nng mol/lit ca dd H2SO4 ban u.
b) Xc nh cng thc phn t ca mui halogenua.
c) Tnh x.
Cu V: (2,0 im)
C hn hp kh A gm metan, etilen v axetilen.
- Cho 5,6 lt hn hp kh a li qua dd nc brm d th c 52 gam brm tham gia phn ng.
- t chy hon ton 2,6 gam hn hp kh A th cn va 30,24 lt khng kh.
Xc nh thnh phn trm theo th tch cc kh trong hn hp A, bit cc kh o iu kin tiu
chun, trong khng kh oxi chim 20% v th tch cn li l ni t.
(Cho NTK: H = 1 ; Li=7; C = 12 ; O = 16 ; F=19; Ca=40; Br=80; I=127; Ba=137; Pb=207; N=14; Na =
23 ; Al = 27 ; S = 32 ; K = 39 ; Cl = 35,5 ; Fe = 56 ; Cu = 64)
Ht
Cn b coi thi khng gii thch g thm.
TI LIU BD HSG HA
Trang 38
L Vit Hng
S GIO DC V O
TO PH TH
THI CHN HC SINH GII CP TNH LP 9 THCS NM

HC 2011 2012
p n chnh thc
Mn: Ha hc
Thi gian: 150 pht khng k thi gian giao
( thi c: 01 trang)
Cu I: (2,0 im)
Cho ln lt tng cht: Fe, BaO, Al 2O3, v KOH vo ln lt cc dung dch: NaHSO 4, CuSO4. Hy
vit PTHH ca cc phn ng xy ra.
CU
NI DUNG
IM
2,0
* Vi NaHSO4:
Fe + 2NaHSO4 FeSO4 + Na2SO4 + 2H2
Ba(OH)2 + 2NaHSO4 BaSO4 + Na2SO4 + 2H2O
0,5
Ba(OH)2 + NaHSO4 BaSO4 + NaOH + H2O
BaO + H2O Ba(OH)2
Al2O3+ 6NaHSO4 Al2(SO4)3 + 3Na2SO4 + 3H2O
2KOH + 2NaHSO4 K2SO4 + Na2SO4 + 2H2O
0,5
* Vi CuSO4:
Fe + CuSO4 FeSO4 + Cu
BaO + H2O Ba(OH)2
0,5
Ba(OH)2 + CuSO4 BaSO4 + Cu(OH)2
2KOH + CuSO4 Cu(OH)2 + K2SO4
0,5
Cu II: (3,0 im)
1) C 1 hh gm 5 kim loi: Al, Mg; Fe, Cu, Ag. Hy dng PPHH tch ring tng kim loi vi khi
lng khng i. Vit PTHH xy ra trong qu trnh tch.
2) Vit PTP trong mi trng hp sau
a. Oxit + Axit 2 mui + oxit
b. Mui + kim loi 2 mui
c. Mui + baz 2 mui + 1oxit
d. Mui + kim loi 1 mui
TI LIU BD HSG HA
Trang 39
L Vit Hng
CU
2. 1,0
NI DUNG
a. Fe3O4 + 8HCl FeCl2 + 2FeCl3 + 4H2O
b. FeCl3 + 2Cu FeCl2 + 2CuCl2
c. 2NaHCO3 + Ca(OH)2 CaCO3 + Na2CO3 + 2H2O
d. 2FeCl3 + Fe 3FeCl2
IM
Cu III: (3,0 im)

1) Trn V1 lit dd HCl 0,6M vi V2 lt dd NaOH 0,4M thu c 0,6 lit dd A. Tnh V1, V2 bit 0,6 lt dd
A c th ho tan ht 1,02 gam Al2O3 (coi s pha trn khng lm thay i th tch)
2) Sc t t a mol kh CO2 vo 800 ml dd X gm KOH 0,5M v Ca(OH)2 0,2M. Tm gi tr ca a
thu c khi lng kt ta ln nht.
CU
NI DUNG
IM
1. (2,0) nHCl=0,6V1 (mol)
nNaOH=0,4V2 (mol)
nAl2O3=0,1 (mol)
- Theo bi ta c: V1+V2=0,6 lt
- PTHH: HCl + NaOH NaCl + H2O
(1)
* Trng hp 1: Trong dd A cn d axit HCl
6HCl + Al2O3 2AlCl3 + 3H2O
(2)
- Theo (1) v (2) ta c V1 + V2 = 0,3 lt (*)
1,0
* Trng hp 2: Trong dd A cn d axit NaOH
2NaOH + Al2O3 2NaAlO2 + H2O
(3)
- Theo (1) v (3) ta c nNaOH = nHCl + 2nAl2O3
=> 0,4V2 = 0,6V1 + 0,02 (**)
1,0
- T (*) v (**) ta c: V1 = 0,22 lit, V2 = 0,38 lt
2(1)
nKOH = 0,8.0,5 = 0,4 mol
nCa(OH)2 = 0,8.0,2 = 0,16 mol
Sc t t a mol kh CO2 vo 800 ml dd X c cc phng trnh phn ng
CO2
+
Ca(OH)2
CaCO3 + H2O
(1)
Mol
0,16
0,16
0,16
CO2
+
2KOH
K2CO3 + H2O
(2)
Mol
0,2
0,4
0,2
CO2
+
K2CO3 + H2O 2KHCO3
(3)
Mol
0,2
0,2
0,5
- Theo (1) ta c: Nu 0 a 0,16 th s mol CaCO3 tng t 0 n 0,16 mol
- Theo (2) v (3) ta c: Nu 0,16 a 0,56 th s mol CaCO3 = 0,16 mol
Vy thu c khi lng kt ta ln nht l 0,16.100 = 16 gam th 0,16 a
0.56
0,5
Cu IV: (10,0 im)
3) Ho tan cc cht gm Na2O, NaHCO3, BaCl2, NH4Cl c cng s mol vo nc d c dd A v
kt ta B. Hi dd A v kt ta B cha nhng cht g? Vit PTHH ca cc phn ng minh ho.
4) Ho tan ht 3,2 gam oxit M2On trong lng va dd H2SO4 10%, thu c dd mui c nng
12,903%. Sau phn ng em c bt dd v lm lnh thu c 7,868 gam tinh th mui vi hiu
sut 70%. Xc nh cng thc ca tinh th mui .
5) Cho x gam mt mui halogenua ca mt kim loi kim tc dng vi 200ml dd H 2SO4 c, nng
va . Sau khi phn ng xy ra hon ton, thu c hn hp sn phm A trong c mt kh B
(mi trng thi). Cho kh B tc dng vi dd Pb(NO 3)2 (d) thu c 47,8 gam kt ta mu en.
Phn sn phm cn li, lm kh thu c 342,4 gam cht rn T. Nung T n khi lng khng i
thu c 139,2 gam mui duy nht.
a) Tnh nng mol/lit ca dd H2SO4 ban u.
b) Xc nh cng thc phn t ca mui halogenua.
c) Tnh x.
CU
NI DUNG
IM
TI LIU BD HSG HA
Trang 40
L Vit Hng
1. (2,0)
2(3)
3(5)
Phng trnh ho hc
Na2O + H2O 2NaOH
Mol
a
2a
NaHCO3 + NaOH -> Na2CO3 + H2O
Mol
a
a
a
NH4Cl + NaOH NaCl + NH3 + H2O
Mol
a
a
a
a
BaCl2 + Na2CO3 BaCO3 + 2NaCl
Mol
a
a
a
2a
=> Dung dch A ch c NaCl
Kt ta B ch c BaCO3
- PTHH:
M2On
+
n H2SO4
M2(SO4)n + nH2O
Nu c 1 mol M2On th s gam dd H2SO4 10% l 980n gam
S gam dd mui l 2M+996n (gam)
(2M + 96n).100
56n
= 12,903 M =
Ta c: C% =
2M + 996n
3
Vy n = 3, M = 56 => oxits l Fe2O3
PTHH: Fe2O3 + 3H2SO4 Fe2(SO4)3 + 3H2O
a. nPb(NO3)2 =0,2 mol
- V kh B c mi trng thi khi tc dng vi dd Pb(NO 3)2 to kt ta en => B l
H2S
- Gi CTTQ ca mui halogenua kim loi kim l RX
- PTHH 8RX + 5H2SO4 c 4R2SO4 + H2S + 4X2 + 4H2O (1)
1,6
1,0
0,8
0,2
0,8
(c th HS vit 2 phng trnh lin tip cng c)
- Khi B tc dng vi dd Pb(NO3)2
H2S + Pb(NO3)2 PbS + 2HNO3
(2)
0,2
0,2
1, 0
= 5, 0M
- Theo (1) ta c: CM H2SO4 =
0, 2
b. Sn phm gm c: R2SO4, X2, H2S => cht rn T c R2SO4 v X2, nung T n
khi lng khng i => m R 2SO 4 = 139, 2g
m X 2 = 342, 4 - 139, 2 = 203, 2(g)
203, 2
= 254 M X = 127 . Vy X l it(I)
0,8
139, 2
= 174 R = 39 R l kali (K)
- Ta c: M R 2SO4 = 2R + 96 =
0,8
- Vy CTPT mui halogenua l KI
c. Tm x:
- Theo (1) n RX = 1, 6(mol) x = (39 +127).1, 6 = 265, 6(g)
- Theo (1) n X2 = 0,8(mol)
0,5
0,5
0,5
0,5
1,0
1,0
1.0
0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5
1,0
Cu V: (2,0 im)
C hn hp kh A gm metan, etilen v axetilen.
- Cho 5,6 lt hn hp kh a li qua dd nc brm d th c 52 gam brm tham gia phn ng.
- t chy hon ton 2,6 gam hn hp kh A th cn va 30,24 lt khng kh.
Xc nh thnh phn trm theo th tch cc kh trong hn hp A, bit cc kh o iu kin tiu
chun, trong khng kh oxi chim 20% v th tch cn li l ni t.
CU
NI DUNG
IM
(2,0)
- Gi a, b, c ln lt l s mol ca CH4, C2H4, C2H2 trong 5,6 lt hn hp A
5, 6
= 0, 25
- Ta c: a + b + c =
(1)
22, 4
TI LIU BD HSG HA
Trang 41
L Vit Hng
(2)
(3)
0,5
(4)
- PTHH
C2H4 + Br2 C2H4Br2

C2H2 + 2Br2 C2H2Br4
52
n Br2 = b + 2c =
= 0,325
160
- gi ka, kb, kc ln lt l s mol ca CH4, C2H4, C2H2 trong 2,6 gam hn hp A.
- Ta c
16ka + 28kb + 26kc = 2,6
(5)
2CH4 + 4O2 2CO2 + 4H2O
(6)
C2H4 + 3O2 2CO2 + 2H2O
(7)
2C2H2 + 5O2 4CO2 + 2H2O
(8)
n O2 = 2ka + 3kb + 2,5kc = 0, 27
(9)
- Gii h PT (1), (4), (5), v (9) ta c
a = 0,025 mol %VCH 4 = 10%
0,5
0,5
b = 0,125 mol %VC2H 4 = 50%

c = 0,1 mol %VC2 H2 = 40%
0,5
Ch : Th sinh lm bi theo phng php khc: Cho kt qu ng, lp lun cht ch gim kho
cn c thang im ca hng dn chm cho im sao cho hp l.
TI LIU BD HSG HA
Trang 42
L Vit Hng
13
TI LIU BD HSG HA
Trang 43
L Vit Hng
14
K THI CHN HC SINH GII LP 9 THCS
NM HC 2011-2012
Mn thi : HO HC
Thi gian : 150 pht (khng k thi gian giao )
Ngy thi : 03/4/2012
S GIO DC V O TO
QUANG NAM
CHNH THC
Cu I.(3 im)
1.Cho cc kim loi Mg, Al, Fe ln lt tc dng vi cc dung dch HCl, NaOH, CuSO4, AgNO3.Vit cc
phng trnh phn ng xy ra (nu c).
2.C bn cht sau: KCl, H2O, MnO2, H2SO4 c .T nhng cht trn lm th no c th iu ch :HCl ;
Cl2 ; KClO3. Vit phng trnh phn ng dng.
Cu II.(3 im)
1.Hon thnh cc phng trnh phn ng ca s sau. Ghi r iu kin ( nu c):
Saccaroz (1) glucoz (2) ancol etylic (3) axit axetic (4) natriaxetat (5) metan (6) axetilen (7)
benzen (8) nitrobenzen.
2.Mt trong nhng cch lm sch tp cht c ln trong nc ma dng sn xut ng phn theo
phng php th cng trc y c thc hin bng cch cho bt than xng v mu b vo nc p
ma. Sau khuy k un nh ri lc ly phn nc trong. Phn nc trong ny mt hn mu xm v mi
ma. C cn nc lc th thu c ng phn. Hy gii thch vic s dng than xng v mu b trong
cch lm ny?
3.Butan c ln tp cht l cc kh etilen, cacbonic, axetilen. Nu cch tin hnh v vit cc phng trnh
phn ng xy ra trong qu trnh lm sch kh.
Cu III.(4 im)
1.Cho 0,1g canxi tc dng vi 25,0cm 3 nc lnh nhit phng. Th tch kh hyro o c trong
thi gian 4 pht, mi ln o cch nhau 30 giy. Kt qu thu c nh sau:
Thi
0
30
60
90
120
150
180
210
240
gian(gy)
Th
tch(cm3)
20
32
42
50
56
59
60
60
a.Da vo bng s liu cho bit: tc phn ng thay i th no v sau bao nhiu giy phn ng kt
thc.
b.Tm th tch kh hyro thu c nhit phng v nng phn trm ca dung dch sau khi phn ng
kt thc. Bit iu kin nhit phng 1,0 mol kh c th tch 24000cm 3 v khi lng ring ca nc
l 1,0g/cm3.
2.Cho 400 ml dung dch E gm AlCl 3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch
NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc
dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. Tm x,y.
Cu IV.(3 im)
1.C cc cht lng A, B, C, D, E. Cht no l benzen, ancol etylic, axit axetic, dung dch glucoz, nc.
Bit kt qu ca nhng th nghim nh sau:
-Cho tc dng vi Na th A, B, C, D c kh bay ra; E khng phn ng
- Cho tc dng vi CaCO3 th A, B, C, E khng phn ng; D c kh bay ra
-Cho tc dng vi dung dch AgNO3/NH3 th A, C, D, E bc khng xut hin; B c bc xut hin
-t trong khng kh th A, E chy d dng; D c chy ; B,C khng chy
Xc nh A, B, C, D, E v vit cc phng trnh phn ng ho hc theo cc kt qu th nghim trn.
2.t chy hon ton m(g) cht hu c A ch thu c a(g) CO 2 v b(g) H2O. Bit 3a = 11b v 7m = 3(a
+ b). Xc nh cng thc phn t (A), bit t khi hi ca (A) i vi khng kh : dA/KK < 3 .
Cu V.(4 im)
Cho V lt(ktc) kh CO i qua ng s ng 5,8g st oxit nung , mt thi gian thu c hn hp kh A
v cht rn B. Cho B tc dng ht vi axit HNO3 long d thu c dung dch C v 0,784 lit (ktc) kh
NO l sn phm kh duy nht. C cn dung dch C thu c 18,15g mui st III khan. Nu ho tan hon
ton B bng axit HCl d thu c 0,672 lit kh (ktc)(xem qu trnh st tc dng vi mui st III v mui
st II khng ng k).
1.Tm cng thc st oxit v phn trm khi lng cc cht trong B.
2.Tm V v phn trm th tch cc kh trong hn hp A, bit t khi ca A i vi hyro l 17,2.
TI LIU BD HSG HA
Trang 44
L Vit Hng
Cu VI.( 3 im)
Mt hn hp kh (A) gm mt hirocacbon (X) mch h v H2. Cho 17,6g hn hp (A) vo dung dch
nc brom , sau khi phn ng hon ton thy dung dch brom nht mu v khi lng brom tham gia
phn ng l 96,0g. Khi t chy hon ton 17,6g hn hp (A), dn sn phm chy vo nc vi trong th
ton b sn phm chy b hp th ht v to c 20,0g kt ta. Lc b kt ta thy khi lng dung dch
nc vi tng thm m(gam) so vi ban u. un si dung dch cn li to thm 50,0g kt ta na.
1.Tm cng thc phn t ca (X) v tnh thnh phn phn trm s mol hn hp (A).
2. Tnh m.
Ghi ch : Th sinh c php dng bng tun hon v my tnh b ti.
S GIO DC V O TO
QUNG NAM
K THI HC SINH GII LP 9 NM HC : 2011-2012
HNG DN CHM V BIU IM MN HA HC
CHNH THC
(Hng dn chm c 4 trang)
STT
Cu I
3
im
p n
1.Cc phn ng:
Mg + 2HCl
MgCl2 + H2
Mg + CuSO4
MgSO4 +Cu
Mg + 2AgNO3
Mg(NO3)2 +2Ag
2Al + 6HCl
2AlCl3 + 3H2
2Al + 2NaOH +2H2O 2NaAlO2 + 3H2
2Al + 3CuSO4
Al2(SO4)3 + 3Cu
Al+ 3AgNO3
Al(NO3)3 +3Ag
Fe+ 2HCl
FeCl2 + H2
Fe + CuSO4
FeSO4 +Cu
Fe+ 2AgNO3
Fe(NO3)2 +2Ag
Nu AgNO3 d th : Fe(NO3)2 + AgNO3 Fe(NO3)3 + Ag
2.
2KCl + H2SO4 c nng
(0,25.4)
MnO2 + 4HCl
toC
MnCl2 +Cl2 + 2H2O
pmangngan
2KCl + 2H2O 2KOH +H2+Cl2
3Cl2 + 6KOH
100
oC 5KCl+ KClO3 + 3H2O
im
2,0
(0,2.10)
1,0
K2SO4
Cu II 1.
3
im
2HCl
C12H22O11 + H2O H 2 SO
(0,125.8)
4;toC 2C6H12O6
enzim ; 30 35 oC
C6H12O6
2C2H5OH + 2CO2
C2H5OH + O2
enzim
CH3COOH + H2O
CH3COOH + NaOH
CH3COONa + H2O
CH3COONa + NaOH CaO;
toC
CH4 + Na2CO3
1500 oC ; l ln
2CH4
C2H2 +3H2
600 oC; btthan
C6H6
3C2H2
C6H6 +HNO3 c
H 2SO
4 C6H5NO2 +H2O
2.Than xng (C v nh hnh) c c tnh hp ph cc cht mu v mi.Mu b(protein) khi
tan trong nc ma to thnh dung dch keo, c kh nng gi cc tp cht nh l lng, khng
lng ng.Khi un nng protein b ng t,ko nhng ht tp cht ny lng xung, nh khi
lc b phn khng tan, thu c nc ma trong, khng c mu ,mi v cc tp cht.
3.Cho hn hp kh C4H10,C2H4 ,C2H2 ,CO2 i qua dung dch brom d. Kh i ra l C4H10 v
CO2, cho hn hp thu c vo dung dch nc vi d. Kh i ra l C4H10 nguyn cht.
C2H4 + Br2
C2H4Br2
TI LIU BD HSG HA
Trang 45
L Vit Hng
1,0
1,0
1,0
C2H2 + 2Br2
C2H2Br4
Cu
III
4
im
1.a.-Tc phn ng gim dn theo thi gian.

(0,25)
-Phn ng kt thc sau 210 giy
(0,25)
b.Phng trnh phn ng:
Ca + 2H2O Ca(OH)2 +H2
S mol H2 = s mol Ca(OH)2 = s mol Ca = 0,1:40 =0,0025mol
Th tch kh H2 = 0,0025.24000 =60cm3
( hoc nhn vo bng s liu th tch kh H2 =60cm3)
(0,25)
Khi lng Ca(OH)2 =74.0,0025=0,185g
(0,25)
Khi lng dung dch sau phn ng = 25.1 + 0,1 0,0025.2 = 25,095g
(0,25)
Nng % dung dch = (0,185:25,095).100 = 0,737%
(0,25)
2. Phng trnh in li
AlCl3
(1)
Al3+ + 3Cl(0,20.5)
0,4x
0,4x
: (mol)
3+
2Al2(SO4)3 2Al +3SO4 (2)
0,4y
: (mol)
0,8y 1,2 y
Khi tc dng vi NaOH:
Al3+ + 3OH- Al(OH)3
(3)
Nu NaOH d th c phn ng:
Al3+ + 4OH- AlO2- + 2H2O (4)
Khi cho BaCl2 d vo :
Ba2+ + SO42- BaSO4
(5)
: (mol)
1,2 y
1,2 y
S mol Al3+ = 0,4x +0,8y;
S mol BaSO4 =33,552 :233 = 0,144 mol nSO42- =1,2y = 0,144 y= 0,12(mol)
(0,5)
nOH = nNaOH = 0,612 mol;
nAl(OH)3 =8,424:78= 0,108 mol nOH to kt ta (3) = 0,108.3 =0,324 < 0,612
c phn ng (3) &(4)
(0,5)
s mol OH- to AlO2- = 0,612- 0,324 = 0,288 mol
0,4x +0,8y=0,108 + (0,288:4) x= 0,21mol
5)
Cu
IV
1.T cc kt qu xc nh c A:C2H5OH; B: dung dch glucoz(C6H12O6 ); C:H2O

;D:CH3COOH ; E : C6H6(benzen)
(0,5)
3im
2C2H5OH + 2Na
(0,125.8)
2C2H5ONa + H2
2H2O + 2Na
2NaOH + H2
2CH3COOH + 2Na
2CH3COONa + H2
2CH3COOH + CaCO3 (CH3COO)2Ca + H2O + CO2
C6H12O6 + Ag2O NH
3 ,toC
C6H12O7 + 2Ag
TI LIU BD HSG HA
Trang 46
L Vit Hng
0,5
1,0
1,0
1,5
( 0,
1,5
C2H5OH + 3O2
2CO2 + 3H2O
CH3COOH + 2O2
2CO2 + 2H2O
2C6H6 + 15O2
12CO2 + 6H2O
2. mC =12a/44 =3a/11 =b(g)
mH = 2b/18 =b/9(g)
(0,25)
mO = m-( b + b/9 ) = m -10b/9
theo : 7m =3a +3b =11a +3b = 14b m=2b(g)
mO =2b 10b/9 = 8b/9(g)
(0,25)
Gi cng thc phn t ca A l CxHyOz
Ta c t l : x:y:z = b/12 :b/9:8b/9.16
= 3:4:2
(0,5)
cng thc phn t A : (C3H4O2)n; vi n nguyn dng
theo : 72n < 29.3 n < 1,208 ch c n = 1 ng iu kin
Vy cng thc phn t ca A l: C3H4O2
(0,5)
Cu V 1. Gi cng thc phn t st oxit l FexOy
HNO 3
CO
Ta c s FexOy FexOy;Fe;FexOy d Fe(NO3)3;NO
4im p dng s bo ton vi nguyn t Fe: s mol Fe(Fe O ) = s mol Fe trong Fe(NO )
x y
3 3
= 18,15:242=0,075mol
(0,5)
S mol O = (5,8-56.0,075):16 = 0,1mol
(0,25)
Ta c x:y = 0,075:0,1 = 3:4
Vy cng thc cn tm Fe3O4
(0,25)
Cht rn B c th gm:Fe,FeO,Fe3O4 d
Phng trnh phn ng:
Fe + 4HNO3 Fe(NO3)3 + NO + 2H2O
(1)
3FeO + 10HNO3 3Fe(NO3)3 + NO + 5H2O
(2)
3Fe3O4 + 28HNO3 9Fe(NO3)3 + NO + 14H2O
(3)
Fe + 2 HCl
(4)
FeCl2 + H2
FeO + 2 HCl
(5)
FeCl2 + H2O
Fe3O4 + 8HCl
(6)
2FeCl3 + FeCl2 + 4H2O
(0,5)
Gi a,b,c ln lt l s mol Fe,FeO,Fe3O4 d trong B
T (4) s mol H2 = a = 0,03
T (1),(2),(3) s mol NO = a + b/3+ c/3 = 0,035
S mol Fe = a + b + 3c = 0,075
Gii h phng trnh ta c: a=0,03 ; b = 0 ; c= 0,015
Khi lng B = 56.0,03 + 232.0,015 = 5,16g
(0,75)
% khi lng hn hp : %Fe = 32,56% ; %Fe3O4 = 67,44%
(0,25)
2.Phng trnh phn ng:
Fe3O4 + 4CO toC
(7)
3Fe + 4CO2
Theo phn ng: s mol CO phn ng = s mol CO2
Gi d l % th tch CO2 ; % th tch CO = 1-d
Ta c : 44d + 28(1-d) = 17,2.2
d= 0,4 . %VCO2=40% ; %VCO =60%
(0,75)
Theo (7) s mol CO phn ng = (4/3).s mol Fe =(4/3).0,03=0,04mol
TI LIU BD HSG HA
Trang 47
L Vit Hng
1,5
1,0
1,5
1,5
Do s mol CO ban u = (0,04.100):40=0,1mol
V=0,1.22,4= 2,24lit
(0,75)
Cu
VI
3
im
1.Gi cng thc phn t tng qut ca (X) l :CnH2n+2-2k ; vi: 2n4; 1 k n
CnH2n+2-2k + kBr2
(1)
CnH2n+2-2kBr2k
x
kx
: mol
2CnH2n+2-2k +(3n+1-k)O2 2nCO2 + 2(n+1-k)H2O
(2)
x
nx
: mol
2H2 + O2 2 H2O
(3)
(4)
2CO2 + Ca(OH)2 Ca(HCO3)2
(5)
toC
Ca(HCO3)2 CaCO3 + H2O +CO2 (6)
Gi x l s mol (X) trong hn hp
S mol CO2 =nx = 0,2 + 2.0,5 =1,2 (a)
S mol Br2 =kx = 0,6 (b)
T (a) & (b) n =2k
+ khi k=1 n =2 CTPT C2H4
x = 0,6 s mol H2 =(17,6 28.0,6):2 = 0,4 mol
% C2H4 = 60% ; %H2 = 40%
+ khi k=2 n = 4 CTPT C4H6
x = 0,3 s mol H2 =(17,6 54.0,3):2 = 0,7 mol
% C4H6 = 30% ; %H2 = 70%
2.S mol nguyn t H trong 2 trng hp: 4.0,6+2.0,4= 6.0,3+2.0,7=3,2mol
s mol H2O= 1,6mol
S mol CO2 = nx =1,2mol
m = mCO2 + mH2O mCaCO3 =44.1,2 +18.1,6 -20 =61,6gam
Ghi ch: Cc bi ton cu III,IV,V ,VI : Hc sinh c th gii theo cch khc nhng lp lun ng v
cho kt qu ng vn t im ti a nh trn.
- Phng trnh ho hc khng cn bng hoc cn bng sai th tr na s im ca phng trnh .
Trong mt phng trnh vit sai 1 cng thc ha hc th khng tnh im phng trnh.
TI LIU BD HSG HA
Trang 48
L Vit Hng
0,5
0,5
0,5
0,5
0,5
0,25
0,25
S GIO DC V OTO
QUNG NINH
-------------------- THI CHNH THC
15
K THI CHN HC SINH GII CP TNH
MN HA HC 9
(BANG B)
Ngy thi: 23/03/2012
Thi gian lm bi: 150 pht
(Khng k thi gian giao )
( thi ny c 01 trang)
H v tn, ch k
ca gim th s 1
Cu 1 : (3,5 im)
Cho s phn ng sau :
A (2) FeCl2 (3) B
(1)
(4)
Fe
Fe2O3
(5)
D (6) C
Bit A,B,C,D l cc hp cht khc nhau ca st v khng phi l FeCl 2, Fe2O3. Xc nh cng thc ha
hc ca cc hp cht v vit cc phng trnh phn ng minh ha.
(7)
Cu 2: (5,0 im)
1/ Nhit phn hn hp gm BaCO 3, MgCO3, Al2O3 c cht rn A v kh B. Ha tan A vo nc d
c dung dch D v cht rn khng tan C. Cho t t n d dung dch HCl vo dung dch HCl vo dung
dch D th xut hin kt ta, sau kt ta tan dn. Cht rn C tan mt phn trong dung dch NaOH d,
phn cn li tan ht trong dung dch HCl d . Xc nh cc cht trong A,B,C,D v vit phng trnh ha
hc xy ra. Bit cc phn ng xu ra hon ton.
2/ Bng phng php ha hc, hy phn bit 4 cht kh ng trong 4 bnh mt nhn sau: CO, CO 2, N2,
SO2.
Cu 3 (3,5 im)
Hn hp X gm Fe, FeO, Fe 3O4 , Fe2O3 c s mol bng nhau. Ly 52 gam hn hp X cho vo dung
dch HCl d thu c dung dch A. Cho dung dch NaOH n d vo dung dch A thu c kt ta B.
Lc ly kt ta B nung ngoi khng kh n khi lng khng i c m gam cht rn C. Tm gi tr ca
m. Bit cc phn ng xy ra hon ton.
Cu 4: (3,5 im)
Ha tan hon ton a gam oxit ca mt kim loi ha tr (II) trong 48 gam dung dch H 2SO4 long, nng
6,125% thu c dung dch A cha 2 cht tan trong H 2SO4 c nng 0,98%. Mt khc, dng 2,8
lt cacbon (II) oxit kh hon ton a gam oxit trn thnh kim loi thu c kh B duy nht. Nu ly
0,896 lt kh B cho vo dung dch Ca(OH)2 d thu c 0,8 gam kt ta. Tm gi tr ca a v xc nh
cng thc ca oxit kim loi . Bit cc th tch kh u o iu kin tiu chun.
Cu 5: (4,5 im)
t chy hon ton 5,6 lt hn hp gm 2 hidrocacbon (t l th tch l 2:3) c cng s nguyn t
cacbon trong phn t thu c 11,2 lt kh cacbonic v 11,2 gam nc. Xc nh cng thc phn t ca 2
hidrocacbon bit cc th tch kh u o iu kin tiu chun.
TI LIU BD HSG HA
Trang 49
L Vit Hng
S GIO DC & O TO
QUANG TR
CHNH THC
16
NM HC 2011 - 2012
MN: HA HC LP 9 THCS
Kho ngy: 12/4/2012
thi c 01 trang, gm 05 cu
Cu 1. (4,0 im)
1. Hn hp A gm CaCO3, Cu, FeO, Al. Nung nng A (trong iu kin khng c khng kh) mt
thi gian thu ly cht rn B. Cho B vo nc d c dung dch C v cht rn D (khng thay i khi
lng khi cho vo dung dch NaOH). Cho D tc dng vi dung dch H 2SO4 c nng, d. Xc nh B, D
v vit cc phng trnh phn ng xy ra.
2. Ho tan hon ton 4 gam FexOy cn 52,14 ml dung dch HCl 10% (D = 1,05g/ml). Xc nh
cng thc FexOy.
3. Mt hn hp gm Al2(SO4)3 v K2SO4, trong s nguyn t oxi chim 20/31 tng s nguyn
t c trong hn hp. Tnh % theo khi lng mi mui trong hn hp.
Cu 2. (4,0 im)
1. Vit cc phng trnh phn ng xy ra khi cho ln lt cc cht kh sau: SO 2, Cl2, NO2, H2S,
CO2 tc dng vi dung dch Ca(OH)2 d.
2. Hn hp kh A gm a mol SO 2 v 5a mol khng kh. Nung nng hn hp A vi V 2O5 xc tc
thu c hn hp kh B. Bit rng t khi hi ca A so vi B bng 0,93. Hy tnh hiu sut phn ng gia
SO2 v O2. Cho khng kh c cha 80% N2 v 20% O2 theo th tch.
3. Nh t t 3V1 lt dung dch Ba(OH)2 xM (dung dch X) vo V1 lt dung dch Al2(SO4)3 yM
(dung dch Y) th phn ng va v thu c kt ta ln nht l m gam.
a) Tnh gi tr x/y.
b) Nu trn V2 lt dung dch X vo V1 lt dung dch Y ( trn ) th kt ta thu c c khi lng
bng 0,9m gam. Xc nh gi tr V2/V1.
Cu 3. (4,0 im)
1. Kh hon ton 24 gam hn hp Fe2O3 v CuO nung nng bng lng CO d, ton b CO2 sinh
ra cho hp th hon ton vo dung dch Ca(OH)2 d th thu c 40 gam kt ta.
Vit cc phng trnh phn ng xy ra v tnh s mol mi oxit trong hn hp ban u.
2. Vit cc phng trnh phn ng chng minh:
a) Tnh axit ca dung dch HCl mnh hn CH3COOH b) hot ng ca O3 mnh hn O2
c) Tnh baz ca dung dch Ba(OH)2 mnh hn NH3 d) hot ng ca Fe mnh hn Cu
3. Cho hn hp A gm 3 kim loi X, Y, Z c ha tr ln lt l III, II, I v t l s mol tng ng l
1:2:3, trong s mol ca X bng x mol. Ha tan hon ton A bng dung dch c cha y (gam) HNO 3 (ly
d 25%). Sau phn ng thu c V lt kh NO 2 v NO (ktc, khng c sn phm kh khc). Da vo s
phn ng chng minh rng: y = 1,25(10x + V/22,4)63.
Cu 4. (4,0 im)
1. Ha tan hon ton 8,7 gam mt hn hp gm kali v mt kim loi M (thuc nhm IIA) trong
dung dch HCl d, th thu c 5,6 dm 3 H2 (ktc). Nu ha tan hon ton 9 gam kim loi M trong dung
dch HCl d, th th tch kh H2 sinh ra cha n 11 lt (ktc).Hy xc nh kim loi M.
(Cho cc kim loi nhm IIA: Be=9, Mg=24, Ca=40, Sr=88, Ba=137)
2. T tinh bt, cc cht v c cn thit v cc iu kin c , hy vit cc phng trnh phn ng
iu ch cc cht sau: etyl axetat, etilen, PVC.
Cu 5. (4,0 im)
Cho 76,2 gam hn hp A gm 1 ancol n chc (ROH) v 1 axit cacboxylic n chc (R /COOH).
Chia A thnh 3 phn bng nhau. em phn 1 tc dng ht vi Na, thu c 5,6 lt H 2 (ktc). t chy ht
phn 2 th thu c 39,6 gam CO2. em phn 3 thc hin phn ng este ha vi hiu sut 60%, sau phn
ng thy c 2,16 gam nc sinh ra. Vit cc phng trnh phn ng xy ra, xc nh cng thc phn t,
cng thc cu to ca cc cht trong A.
Cho: H=1, O=16, C=12, N=14, Na=23, Mg=24, Al=27, S=32, Cl=35,5; Ca=40, Fe=56, Cu=64.
(Th sinh khng c dng bng HTTH v bng Tnh tan)
TI LIU BD HSG HA
Trang 50
L Vit Hng
HNG DN CHM THI CHN HSG TNH THCS
NM HC: 2011-2012
Kho
ngy
12 thng 4 nm 2012
CHNH THC
Mn: HO HC Lp 9
(Hng dn chm c 05 trang)
Cu
Ni dung
im
Cu 1
4,0 im
to
1
2,5
Phn ng: CaCO3
CaO + CO2
to
2Al + 3FeO
Al2O3 + 3Fe
(B: CaO, Al2O3, Cu, FeO, CaCO3 d, Fe, Al)
CaO + H2O Ca(OH)2
2Al + Ca(OH)2 + 2H2O Ca(AlO2)2 + 3H2
Al2O3 + Ca(OH)2 Ca(AlO2)2 + H2O
Do D khng thay i khi lng khi cho vo dung dch NaOH, nn
D khng cn Al v Al2O3. Suy ra: D gm Cu, FeO, CaCO3, Fe.
to
CaCO3 + H2SO4 c
CaSO4 + CO2 + H2O
S GD&T QUANG TR
Cu + 2H2SO4 c
to
2FeO + 4H2SO4 c
to
2Fe + 6H2SO4 c
2
Cu 2
1
Fe2(SO4)3 + SO2 +4 H2O

Fe2(SO4)3 + 3SO2 +6H2O
0,25
1, 05.52,14.10
0,15 mol
100.36,5
Phn ng: Fe x O y + 2yHCl x FeCl2y x + yH2O (1)
Ta c: nHCl =
Theo (1) v bi ra:

3
CuSO4 +2H2O + SO2

to
0,25
56x 16y
2y
x 2
. Vy cng thc Fe2O3

4
0,15
y 3
Gi x, y ln lt l s mol ca Al2(SO4)3 v K2SO4 trong hn hp.

12x 4y 20
x 1

Ta c:
17x 7y 31
y 2
342.1
.100% 49,57%
Vy: %(m) Al2(SO4)3 =
342.1 174.2
%(m)K2SO4 = 50,43%
0,25
0,25
Gi s mol SO2 phn ng l x

Theo (1): S mol gim = s mol O2 phn ng = 0,5x (mol)
nB= 6a-0,5x (mol)
Theo LBTKL: mA= mB = m
m
m
x
0,93 0,84 .
dA/B = :
6a 6a 0,5x
a
a a
V , nn H% ca phn ng tnh theo SO2. Vy H%= 84%
2 1
Trang 51
0,5
4,0 im
1,5
Ca(OH)2 + SO2 CaSO3 + H2O

2Ca(OH)2 + 2Cl2 CaCl2 + Ca(ClO)2 + H2O
0
6Ca(OH)2 + 6Cl2 t
5CaCl2 + Ca(ClO3)2 + 6H2O
Ca(OH)2 + H2S
CaS
+ 2H2O
2Ca(OH)2 + 4NO2 Ca(NO2 )2 + Ca(NO3)2 + 2H2O
ng mi pt 0,25 0,25x6= 1,5 im
2)Hn hp A ban u c SO2: amol, N2 : 4a mol v O2: a mol.
Phn ng : 2SO2 + O2 2SO3 (1) (C th chn a=1 mol)
TI LIU BD HSG HA
0,25
L Vit Hng
0,25
0,25
0,25
0,5
Phn ng: 3Ba(OH)2 + Al2(SO4)3 3BaSO4 + 2Al(OH)3 (1)
3V1x
V1y
3
1
x
x=y 1
Ta c:
3V1x V1 y
y
Chn x = y =1, khi m=3V1.233+ 2.V1.78=855V1gam (I)
Do 0,9m<m(gam) nn c 2 trng hp xy ra
Trng hp 1: Al2(SO4)3 d, Ba(OH)2 ht
2
Theo(1): 0,9m=V2.233+ V2 .78 285V2 gam(II)
3
V2
2, 7
T (I, II) :
V1
Trng hp 2: Kt ta tan mt phn
Sau (1) xy ra tip phn ng: 2Al(OH)3+Ba(OH)2 Ba(AlO2)2+4H2O(2)
Theo(1,2): Khi lng kt ta tan l 0,1m= (V2 3V1 ).2.78 0,1m (III)
V2
3,548 (=3,55)
T (I, III) :
V1
Cu 3
1
40
=0,4 mol
100
Gi x, y ln lt l s mol ca Fe2O3 v CuO trong 24 gam hn hp
Ta c: nCO2 = nCaCO3 =
Phn ng : Fe2O3 + 3CO

x
to
0,5
0,5
4,0 im
1,0
2Fe + 3CO2 (1)

3x
to
CuO + CO
Cu + CO2 (2)
y
y
Ca(OH)2 + CO2 CaCO3 + H2O (3)
Theo bi ra ta c h phng trnh:
y=0,1
160x+80y=24

3x+y=0,4
x=0,1
2
1,0
Phn ng : a) HCl + CH3COONa NaCl + CH3 COOH

b) O3 + 2KI + H2O 2KOH + I2 + O2
c) Ba(OH)2 + 2NH4Cl BaCl2 + 2NH3 + 2H2O
d) Fe + CuSO4 Cu + FeSO4
y.100
y
Ta c: nHNO3 (phn ng) =

63.125 63.1,25
1,0
S : X+Y+Z + HNO3 X(NO3)3 + Y(NO3)2 + ZNO3 + NO2 + NO (1)

y
V
V
).63
y =1,25.(10x+
p dng LBT:
=3x+4x + 3x +
22,4
63.1,25
22,4
0,5
0,5
Cu 4
1
2K + 2HCl 2KCl + H2 (1)

M + 2HCl MCl2 + H2 (2)
Theo (1,2) v bi ra:
a+2b=0,5
11
9
18,3 < M < 34,8 (do 0 < b < 0,25)
M 22, 4
39a+b.M =8,7
4,0 im
0,5
Phn ng:
TI LIU BD HSG HA
Trang 52
1,0
Vy M l Mg
L Vit Hng
- iu ch etyl axetat: CH3COOC2H5

o
axit, t
(-C6H10O5-)n + nH2O
nC6H12O6
2,5
men 2C2H5OH + 2CO2

C6H12O6
mengia
m
C2H5OH + O2
CH3COOH + H2O
o
H2SO4 , t
CH3COOH + C2H5OH
CH3COOC2H5 + H2O
- iu ch etilen
H SO ,1700 C
C2H5OH
CH2=CH2 + H2O
2 4d
- iu ch PVC: (-CH2-CHCl-)n
t0
CaO
CH3COONa + NaOH(rn)
CH4 + Na2CO3
15000 C
LLN
CH CH + 3H
2CH4
2
xt , t o
CH CH + HCl
CH2=CHCl
o
xt , p , t
nCH2=CHCl
(-CH2-CHCl-)n
C th theo cch khc cng cho im ti a:
C2H4 C2H4Cl2 C2H3Cl PVC
Mi phng trnh 0,25 im 0,25x10= 2,5 im
Cu 5
t ancol ROH l: CxHyO, axit RCOOH: CaHbO2
Phn 1: 2ROH + 2Na 2RONa + H2 (1)
2 RCOOH + 2Na 2RCOONa + H2 (2)
Phn 2: CxHyO + (x+y/4 -1/2)O2 xCO2 + y/2H2O (3)
CaHbO2 + (a+b/4 - 1)O2 aCO2 +b/2H2O (4)
H 2SO4 , t o
Phn 3: ROH + RCOOH
RCOOR + H2O (5)

ng mi phng trnh phn ng 0,25 im 5x0,25=1,25 im
Theo (1, 2): n(1/3A)= 2nH2=2.5,6/22,4= 0,5 mol
Nu H%(5)=100% th n(ROH p)=n(R/COOH p)=0,12.100/60=0,2 mol
C hai trng hp:
Trng hp 1: nROH 0, 2mol nR 'COOH 0,3mol
Theo(3, 4): 0,2x + 0,3a = 39,6/44 = 0,9 (= nCO2 khi t phn 2)
2x + 3a = 9 x = 3 , a = 1
Trong A: C3HyO : 0,2 mol v HCOOH : 0,3 mol
mA= 3[(12.3+y+16)0,2 + 46.0,3]=76,2 y=6
4,0 im
1,25
0,5
0,5
0,5
Vy CTPT, CTCT cc cht trong A: C3H6O (CH2=CH-CH2-OH)

HCOOH
0,25
Trng hp 2: nR 'COOH 0, 2mol nROH 0,3mol

Theo(3, 4): 3x + 2a = 9 x = 1, a= 3
Trong A: CH4O : 0,3 mol v C3HbO2 : 0,2 mol
mA= 3[32.0,3 + (68+b)0,2]=76,2 b=11 (loi v b l)
0,5
0,5
Ghi ch: Th sinh c th lm cch khc, nu ng vn t im ti a trong mi cu. Nu PTHH

thiu iu kin hoc thiu cn bng hoc thiu c hai th tr mt na s im ca PTHH .
. HT .
TI LIU BD HSG HA
Trang 53
L Vit Hng
TI LIU BD HSG HA
Trang 54
L Vit Hng

16 de Thi HSG Lop 9 Cac Tinh Co Dap An

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16 de Thi HSG Lop 9 Cac Tinh Co Dap An

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Vy cng thc phn t v cng thc cu to ca:

nHCl ban u = 100.36,5 = 0,8 (mol)

T (1): nFe = nH 2 = 0,1(mol) => mFe = 0,1 . 56 = 5,6(g)

T (1): nHCl = 2 nH 2 = 2.0,1= 0,2 (mol)

mddB = 217 + 33 = 250 (g)

T (*) v (**) ta c phng trnh

Vy cng thc Oxit st l: Fe3O4

Nu H2SO4 khng d: (5) xy ra:

=> VSO min = 0,05 . 22,4 = 1,12 (lt)

b) Trong dung dch A c:

mCuO = 0,01.80 = 0,8 gam

HOOC-COOH + 2NaHCO3 NaOOC-COONa + 2CO2 + 2H2O (3)

- Bo ton nguyn t oxi:

- LBT khi lng:

=> 24 + x = 28,5 => x = 4,5

- TH1: khng xy ra phn ng (2)

Theo (2): nCO2 (2) nK2CO3 (2) 0, 03mol

hoc 2 AgNO3 + 2NaOH

Ag2O + H2O + 2NaNO3

- Dung dch MgSO4 c kt ta trng:

- Cn li l dung dch Al(NO3)3.

d = 0,2 0,08 = 0,12mol

phn ng = 0,240,12 = 0,12mol

=> mkh= mCu +

m HNO - mCu(NO ) - m H O = 2,56+7,56-7,52-1,08 = 1,52g

Trong dung dch A c:

n HNO3 du 0, 24 0,12 0,12 mol.

THI CHN HC SINH GII CP TNH

44(b 0,3) 2(c 0,3)

Thay b + c = 1- 0,3 = 0,7 44b + 2c = 9,8

Cu V (2 im): Ba cht kh X,Y, Z u gm 2 nguyn t, phn t cht Y v Z u c 3 nguyn t. C 3

Cu + 2H2SO4 c t CuSO4 + SO2 + 2H2O

Na2SO4 + SO2 + H2O

Ch : Hc sinh chn cht khc v vit phng trnh ha hc ng, cho im ti

(44 28) p 16.p

2. A, B, C l 3 cht hu c mch h c cc tnh cht sau: B lm mt mu dung dch brom, C tc

S GIO DC V O TO GIA LAI

- Dng dung dch H2SO4 long nhn bit.

- Cho hn hp tc dng vi dung dch NaOH d, chng ct thu ly ru etylic ln

Tm R v % khi lng cc cht trong X

Tnh nng phn trm cc cht trong dung dch A:

Cc phng trnh phn ng:

nSO 2 = 3/2.(nAl + nFe) = 3/2.(0,05a + 0,225a) = 27,72/22,4= 1,2375 .

V y khi lng ca phn 2 l: mphn 2 = m Al2O3 + mFe + mAl = 0,3.102 + 0,675.56 +

V B tc dng H2O c H2SO4 lm xc tc thu c hn hp 2 sn phm hu c, cho

Nu phng trnh khng cn bng th tr na s im ca phng trnh . Hc

LP 9 THCS NM HC 2011 2012

K THI CHN HC SINH GII LP 9 CP TNH

Cho dung dch BaCl2 d vo dung dch A, lc b kt ta, dung dch cn

a. nHCl = 0,3 x 1 = 0,3 mol

A2CO3 + 2HCl 2ACl + CO2 + H2O

Hc sinh c th gii cch khc, ng vn hng trn s im.

K THI CHN HC SINH GII TNH LP 9 CP THCS

Cl2 + SO2 + 2H2O

Hc sinh c th chn mt s cht khc nh: NH3, H2S

Fe2(SO4)3 + 3SO2 + 6H2O

3 Fe2(SO4)3 + SO2 + 10H2O

Fe2(SO4)3 + SO2 + 6H2O

Fe2(SO4)3 + 15SO2 + 14H2O

Fe2(SO4)3 + SO2+ 2H2O

Cho hn hp ha tan vo nc c dung dch B ( cha 0,4 mol NaCl )

Na2CO3 + MgCl2 MgCO3 + 2NaCl