BI TP N TP PHN HIROCACBON

I/ L thuyt
1 nh ngha hirocacbon l hp cht hu c cu to bi 2 nguyn t nguyn t H v C
2 Cng thc tng qut ca hirocacbon lun c dng CnH2n+2-2k trong n 1 v k l s
lin kt pi +vng v k=( 2sntC+2 sntH)/2
3 Trong phn ny chng ta s nghin cu v hp cht c tn gi l ankan, anken, ankin,
ankadddien, xicloankan,..
4 ANKAN
a) nh ngha: ankan l hirocacbon c cng thc tng qut l CnH2n+2 vi n1 v
k=0
b) Cu to ha hc :trong phn t ankan ch cha cc lin kt n c c im bn
trong cc p ha hc, tnh cht ha hc c trng l p th
c) Tnh cht ha hc : - nkan c p th vi Cl2: CnH2n+2n + Cl2 CnH2n+1Cl + HCl
- ankan c p cracking to hir hoc to ankan v anken mi
VD CnH2n+2 CmH2m+2 +CkH2k vi n3 v m+k =n
-ankan c p t chy CnH2n+2 + O2 n CO2 + (n+1) H2O
5 ANKEN
a nh ngha : anken l hirocacbon c cng thc phn t CnH2n vi k n 2
b Cu to phn t : trong phn t hp cht anken c mt lin kt i v cn li l
lin kt n. Lin kt n ny km bn, d b t ra trong cc phn ng ha hc,
phn ng c trng l phn ng cng
c Tnh cht ha hc c p cng vi H2; Br2; H2O; HCl. VD; CnH2n + H2 CnH2n+2
c p trng hp to polime, VD: CH2=CH2 -(-CH2-CH2-)nc p oxi ha khng hon ton: anken lm mt mu dd thuc
tm KMnO4
c p t chy CnH2n + O2 n CO2 + n H2O
(Lu khi t chy anken s mol CO2 thu c lun bng s mol nc)
6 ANKIN
a nh ngha: ankin l hirocacbon c cng thc pt l CnH2n-2 vi n 2
b Cu to phn t : trong phn t ankin c 1 lin kt 3 cn li l lin kt n, lin
kt 3 ny km bn, d b t ra trong cc ha hc, p c trng l p cng
c Tnh cht ha hc ankin c p cng H2, HCl, H2O, Br2(dd)
- ankin c p nh hp v tam hp ca axetilen
- ankin lm mt mau dd KMnO4
- ankin c p oxi ha hon ton bi oxi v s mol nc tr s
mol CO2 bng s mol ankin
7. B sung quy tc cng maccopnhicop : khi cng anken hoc ankin vi H2O; HX ta cng
phn cha hiro vo phn cacsbon cha nhiu hio hn

B/ Bi tp
I/ Bi tp tng hp: ANKAN
Dng I: Phn bi tp xc nh cng thc pt hp cht hu c
Cu 1. Xc nh CTPT ca ankan trong cc trng hp sau:
a) Ankan cha 16% hydro. p s: C7H16
b) Ankan cha 83,33% cacbon. p s: C5H12
c) t chy hon ton 2 lt ankan A c 8 lt H2O (cc kh o cng iu kin nhit , p
sut). p s: C3H8
d) t chy hon ton 8,7 gam ankan A c 26,4 gam CO2. p s: C4H10
Cu 2. Hn hp A gm mt ankan v 1 xicloankan, sau phn ng thu c 11,2 lit CO2
(ktc) v 9,9 gam H2O. Thnh phn % th tch ca xicloankan trong A l:
Cu 2. Mt ankan to c dn xut monoclo trong clo chim 33,33% v khi lng.
Xc nh CTPT ca ankan. p s: C5H12
Cu 3. Mt ankan to c dn xut monobrom trong brom chim 73,39% v khi lng.
Xc nh CTPT ca ankan. p s: C2H6
Cu 4. Ankan X c cacbon chim 83,33% khi lng phn t. X tc dng vi brom un nng
c chiu sng c th to 4 dn xut ng phn cha mt nguyn t brom trong phn t. Xc
nh CTCT v tn X. p s: C5H12
Cu 5. Cho ankan A tc dng brom thu c mt dn xut cha brom c t khi i vi
khng kh bng 5,207. Xc nh CTCT v gi tn ca ankan A. p s: C5H12
Cu 6. Mt ankan phn ng vi clo theo t l mol 1 : 2 thu c sn phm cha 83,53% clo
v khi lng. CTPT ca ankan l g? p s: CH4
Cu 7. Cho 5,6 lt ankan kh (27,3 oC v 2,2 atm) tc dng vi clo ngoi nh sng ch to mt
dn xut clo duy nht c khi lng l 49,5 gam.
A) Xc nh CTCT c th c ca ankan. p s: C2H6
B) Xc nh % th tch ca ankan v clo trong hn hp u. Bit t khi hi ca hn hp so
vi H2 bng 30,375
.
Dng II: PP Trung bnh
Cu 1. t chy hon ton hn hp A gm hai ankan thu c 3,36 lt CO2 (ktc) v 3,96
gam H2O. Tnh th tch oxi tham gia phn ng ( ktc) l
Cu 2. Cho hn hp X gm 2 ankan ng ng lin tip c khi lng l 20,6 gam v c th
tch bng th tch ca 14 gam kh nit ( cng iu kin nhit , p sut). Tm CTPT v %
th tch ca mi ankan.
Cu 3. t chy hon ton V lt (kc) hn hp 2 hydrocacbon l ng ng lin tip nhau,
sn phm chy t t cho qua bnh 1 ng CaCl2 khan v bnh 2 ng KOH d th thy khi
lng bnh 1 tng 14,4 gam, bnh 2 tng 22 gam. Tm CTPT v % th tch ca mi
hydrocacbon
Cu 4. Cho hn hp X gm 2 ankan ng ng lin tip. t chy hon ton 4,12 gam hn
hp X to ra 12,32 gam CO2. Tm CTPT v % th tch ca mi ankan.
Cu 5. t chy hon ton hn hp 2 hydrocacbon l ng ng lin tip cn 1,35 mol O2
to thnh 0,8 mol CO2. CTPT ca 2 hydrocacbon? p s: C2H6 ; C3H8
Cu 6. t chy hon ton V lt (kc) hn hp 2 hydrocacbon l ng ng lin tip nhau,
sn phm chy thu c c t l th tch CO2 v H2O l 12 : 23. Tm CTPT v % th tch ca
mi hydrocacbon
Cu 7. Hn hp A gm etan v propan. t chy m gam A thu c 8,96 lit CO2 (ktc) v
9,9 gam nc. Thnh phn % khi lng etan trong hn hp l:
Cu 8. Hn hp X gm 2 ankan, phn t khi hn km nhau 28 vC. t chy hon ton
1,76 gam hn hp X cn 2,24 lt O2 ( 0oC ; 2 atm). Tm CTPT v % th tch ca mi ankan
Cu 9. t chy hon ton hn hp 2 hydrocacbon l ng ng nhau to thnh 22 gam CO2
v 12,6 gam H2O . Xc nh CTPT ca 2 hydrocacbon bit s nguyn t Cacbon trong hai
phn t gp i nhau.

Cu 10. Hn hp B gm hai ankan c trn theo t l mol 1:2. t chy ht hn hp B thu

c 8,96 lit CO2 (ktc) v 9,9 gam H2O. Cng thc phn t ca hai Hidrocacbon l:
Dng III: P cracking ankan
Cu 1:(H - A- 08) Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn
hp Y(cc th tch o cng iu kin nhit v p sut), t khi ca Y so vi H2 bng 12.
Cng thc ca X l:
A. C6H14
B. C3H8
C. C4H10
D. C5H12
Cu 2:(H - B- 08) Ba hiocacbon X,Y,Z l ng ng k tip, khi lng phn t ca Z
bng 2 ln khi lng phn t ca X. Cc cht X,Y,Z thuc dy ng ng:
A. Ankan
B. ankadien
C. Anken
D. Ankin.
Cu 3:(H - B- 07) Nhit phn metan thu c hn hp X gm C2H2, CH4 v H2. T khi
hi ca X so vi H2 bng 5. Hiu sut qu trnh nhit phn l:
A. 50%
B. 60%
C. 70%
D.80%.
Cu 4: Thc hin phn ng crackinh hon ton m gam isobutan, thu c hn hp A gm hai
hircacbon. Cho hn hp A qua dung dch nc brom c ha tan 11,2 gam brom. Brom b
mt mu hon ton. C 2,912 lt kh KTC thot ra khi bnh brom, kh ny c t khi so vi
CO2 bng 0,5. Gi tr ca m l:
A. 5,22 gam
B. 6,96 gam
C. 5,80 gam D.4,64 gam.
Cu 5: Thc hin phn ng hi ha hn hp M gm etan v propan thu c hn hp N
gm bn hicacbon v hir. Gi d l t khi ca M so vi N. Nhn xt no sau y ng?
A. 0 < d < 1
B. d > 1
C. d = 1
D.1<d<2.
Cu 6: Crackinh 5,8 gam C4H10 c hn hp kh X. Khi lng nc thu c khi t chy
hon ton X l:
A. 9 gam
B. 4,5 gam
C. 18 gam
D.36 gam
Cu 7: Crackinh 0,1 mol n- pentan c hn hp X. t chy ht X ri hp th sn phm
chy bi nc vi trong d. Hi khi lng cui cng thu c tng hay gim bao nhiu?
A. gim 17,2 gam
B. tng 32,8 gam
C. tng 10,8 gam
D.tng 22 gam.
Cu 8: Crackinh V lt butan thu c 35 lt hn hp A gm H 2,CH4, C2H4, C3H6, C4H8 v mt
phn butan cha b crakinh. Cho hn hp A li rt t t qua bnh ng nc brom d, thy
th tch cn li 20 lt. % butan phn ng l?
A. 25%
B. 60%
C. 75%
D.85%.
Cu 9: Nhit phn 8,8 gam C3H8 ta thu c hn hp A gm CH4, C2H4, C3H6, H2 v C3H8 d
cha b nhit phn. T khi ca hn hp A so vi H2 l?
A. 11,58
B. 15,58
C. 11,85
D.18,55.
Cu 10: Khi crackinh mt ankan kh iu kin thng thu c mt hn hp gm ankan v
anken trong c hai cht X v Y c t khi so vi Y l 1,5. Cng thc ca X v Y l?
A. C2H6 v C3H8
B. C2H4 V C3H6
C. C4H8V C6H12
D. C3H8 v C5H6.
Cu 11: Hn hp kh gm etan v propan c t khi so vi hidro l 20,25 c nung trong
bnh kn vi cht xc tc thc hin phn ng hidro ha. Sau mt thi gian thu c hn
hp kh c t khi hi so vi H2 l 16,2 gm ankan, anken v hidro. Tnh hiu sut phn ng
hidro bit rng tc phn ng ca etan v propan l nh nhau.
A. 30%
B. 50%
C. 25%
D.40%.
Cu 12: Thc hin phn ng crackinh 11,2 lt hi isopentan KTC, thu c hn hp A ch
gm ankan v anken. Trong hn hp A c cha 7,2 gam mt cht X m t chy th thu c
11,2 lt CO2 v 10,8 gam nc. Hiu sut phn ng l:
A. 30%
B. 50%
C. 80%
D.40%.
Cu 13: Thc hin phn ng crackinh m gam isobutan, thu c hn hp A gm cc
hidrocacbon. Dn hn hp A qua bnh nc brom c ha tan 6,4 gam brom. Nc brom mt
mu ht, c 4,704 lt hn hp kh B KTC gm cc hidrocacbon thot ra. T khi ca B so
vi hidro bng 117/7. Gi tr ca m l:
A. 8,7 gam
B. 5,8 gam
C. 6,96 gam D.10,44 gam.

Dng IV: phn ng chy ankan

Phn ng t chy c dng:
3n 1
2 O2
CnH2n+2 +
nCO2 + n+1H2O
Suy ra: Phng php cn nh
n nH 2O
ankan khi chy cho CO2
nO2(pu)= nCO2 1/ 2nH 2 O
nankan nH 2O nCO 2
mtan g mCO2 mH 2 O mkt

mgiam mkt mCO2 mH 2O

Cu 1. Oxi ha hon ton hydrocacbon X c 11,2 lt CO2 (kc) v 10,8 gam H2O. Xc
nh CTCT v tn ca X bit clo ha X ch thu c mt dn xut monoclo duy nht. p s:
C5H12
Cu 2. Oxi ha hon ton hydrocacbon X c 2,24 lt CO2 (kc) v 2,16 gam H2O. Xc
nh CTCT v tn ca X bit clo ha X theo t l mol 1:1 to 4 sn phm th. p s: C5H12
Cu 3. t chy hon ton mt Hidrocacbon A thu c 2,24 lit CO2 (ktc) v 3,6g H2O.
xc nh CTPT A
p s: CH4
Cu 4. t chy hon ton mt Hidrocacbon X phi cn 11,2 lit Oxi (ktc), sau phn ng dn
sn phm qua bnh nc vi trong d thu c 30 gam kt ta. Cng thc phn t ca X l
p s C3H8
Cu 5. t chy hon ton mt Hidrocacbon X phi cn 1,456 lit Oxi (ktc), sau phn ng
dn sn phm qua bnh ng H2SO4 c d th khi lng bnh tng 0,9 gam. Cng thc
phn t ca X l p s C4H10
Cu 6. t chy hon ton mt Hidrocacbon X phi cn 1,792 lit Oxi (ktc), sau phn ng
dn sn phm qua bnh nc vi trong d khi lng bnh tng 3,28 gam. Cng thc phn t
ca X l p s C5H12
Cu 7. t chy Hidrocacbon A thu c 3 lit CO2 v 4 lit hi nc, o cng iu kin v
nhit p sut.
Xc nh CTPT A. p s C3H8
Cu 8. t chy hon ton 0,05 mol ankan A ri dn sn phm chy qua bnh cha nc vi
trong d thu c 20 gam kt ta. sau th nghim khi lng bnh tng l. p s 13,3g
Cu 9. t chy ht V lt (ktc) hidrocacbon X ri dn sn phm qua bnh cha dung dch
Ba(OH)2 d. Sau th nghim thu c 7,88g kt ta, ng thi khi lng dung dch gim
5,22g. Gi tr ca V.p s: 0,224 lit
Cu 10.t chy ht V lt (ktc) hidrocacbon X ri dn sn phm qua bnh cha nc vi
trong d. Sau th nghim thu c 15 g kt ta, ng thi khi lng dung dch tng 10,2 g.
Gi tr ca V.p s: 1,12 lit

II. Bi tp anken
1.Hon thnh dy chuyn ha sau . C2H2 -> C2H4 -> C2H5OH -> C2H4 -> C2H4(OH)2
2.C3H7OH -> C3H6 -> C3H8 -> C2H4 -> C2H5OH.
3.t chy hon ton 2,24 l kh ktc ri hp thu ton b vo dd cha 11,1 g Ca(OH)2 .Hi sau
khi hp th khi lng dd tng hoc gim bao nhiu gam ?
4. Hn hp X gm ankan v anken c t l s mol 3:2 .t chy hon ton X , dn hi chy
qua dd Ca(OH)2 bnh tng 7,08 g v c 8 g kt ta . Phn dd nc lc tc dng vi Ca(OH)2
d xut hin thm 4 g kt ta na . Tm cng thc phn t mi cht .
5.A l ankan , B l anken u th kh
t chy 0,1 mol hn hp ( cha a mol A v b mol B ) thu c khi lng CO2 ln hn
nc l 7,6 g
t chy 0,1 mol hn hp ( cha a mol A v b mol B ) thu c khi lng CO2 ln hn
nc l 6,2 g
Tm ctpt A, B .bit s nguyn t trong B ln hn A

6. Hn hp A gm hidro v 1 olefin c t l s mol 1:1 . un nng hn hp A vi niken xc

tc thu c hn hp B c t khi so vi hidro l 12,5 . Hiu sut phn ng l h
a. Lp biu thc tnh h theo n
b.bit h > 70% xc nh cng thc phn t ca olefin v tnh h
7.Ly hai th tch bng nhau ca 1 anken th kh cho p ring r vi dd clo , brom . Khi
lng ca hai sn phm cng khc nhau 44 ,5 g
a. Tnh th tch anken dng 27,3 0 C v 1 at . Gi s hiu sut p u t 80 %
b. Vit cng tha cu to c th c ca anken bit rng khi lng sn phm cng brom thu
c l 108 g v nu cho p vi HCl ch thu c 1 sn phm duy nht
8.Hn hp kh A cha 1 ankan v 1 anken .Khi lng hn hp a l 9 g v th tch l 8,96 l .
t chy hon ton A thu 13,44 l CO2 . Cc kh u o ktc .
Xc nh cng thc v tnh % mi anken
10.cn bao nhiu ml etilen ktc iu ch 1 tn PE . Gi s hiu sut p trng hp t 80
%.
11. Hn hp A gm anken v hidro c t khi so vi hidro bng 9 ,dn hn hp i qua bt
niken nung nng n khi p hon ton thu c kh B x t khi so vi H2 bng 15 . Tm
ctpt ca X v tnh % th tch ca kh trong A v B .
12.Cho mt lng anken X tc dng vi nc c cht hu c Y , thy khi lng bnh
ng nc ban u tng 4,2 g .nu cho lng X nh trn tc dng vi HBr thu c cht Z thy
khi lng Y , Z khc nhau 9,45 g .Tm cng thc phn t v gi tn X , gi s cc p xy ra hon
ton
13.t chy hon ton 2,24 l ktc mt hidrocacbon X mch h , sau dn sn phm chy
ln lt i qua H2SO4 c v dd Ca(OH)2 d .Sau th nghim thy khi lng bnh ng axit tng
5,4 g v bnh Ca(OH)2 c 30 g kt ta .Tm cng thc phn t ca X
14.Cho hn hp 2 anken qua bnh nc brom d . thy khi lng bnh brom tng 16 g .
Tng s mol 2 anken l
A. 0,1
B .0,2
C.0,05
D. 0,15
15.Hn hp A gm 1 ankan v 1 anken c cng s nguyn t C trong phn t v c cng s
mol . Hn hp ny lm mt mu va 80 g dd brom 20 % . Cn t chy hn hp cho 13,44 l CO2
ktc.Ctpt l
A.C4H6, C2H4
B.C4H10 ,C4H8
C.C3H8 , C3H6
D. KT QU
KHC
16.Mt hn hp gm 3 anken C3H6,C4H8 , C5H10 . Nu t chy hn hp cho 6,72 l hi nc
ktc . Nu cho hn hp p vi hidro d c xc tc ,t chy sn phm ri dn sn phm chy vo
nc vi trng d , th khi lng kt ta sinh ra l
A.30 g
B .31g
C. 32 g
D . 29 g
17.t chy anken X thu 2,24 l CO2 ktc , nu dn ton b sn phm chy vo nc vi
trong d th khi lng bnh tng A.6,2 g
B.5,2
C.4,2
D. 10
18.Cho 6,72 l hn hp gm 2 anken li qua dd brom d ,thy khi lng bnh tng 16,8 g .
Tm cng thc pt ca anken , bit s C mi anken khng qu 5 . A. C2H4 , C4H8 B. C3H6 , C4H8 C
. C4H8 , C5 H10 D. kt qu khc
19. Khi t chy mt HC A mch h cn 30 th tch khng kh , sinh ra 4 th tch CO2 . A tc
dng vi hidro c xc tc Ni to mt hidrocacbon no mch nhnh .Xc nh ctct ca A bit khng
kh chim 20 % th tch
20.dn 3,584 l hn hp X gm 2 anken lin tip nhau trong dy ng ng vo nc brom
d thy khi lng bnh ng nc brom tng 10,50 g
a. Tm ctpt ca A , B . Bit th tochs kh o 00 C vaf 1,25 at
b. Tnh t khi ca hn hp so vi hidro
21. Vit phng trnh cho dy chuyn ha sau

Bi 22 : Hn hp A v B l hai anken c khi lng 12,6g trn theo t l ng mol tc dng

va vi 32g brom. Nu trn hn hp trn ng lng th 16,8g hn hp tc dng va
vi 0,6g H2. Tm cng thc phn t ca A v B, bit MA < MB.
S : C3H6 v C6H12
Bi 23 : C 1,12 lt hn hp X gm H2, ankan, anken (ankan v anken cng s nguyn t
cacbon), t khi hi ca X i vi oxi l 0,575. Khi cho 560ml hn hp X i qua bnh brom
thy 16g dung dch Br2 5% mt mu ng thi lng bnh tng thm 0,14 gam.
1 Xc nh cng thc phn t ankan, anken.
2 Xc nh thnh phn % ca hn hp ban u theo th tch.
3 Tnh th tch oxi cn t 1,12 lt hn hp X.
S : C2H6 v C2H4; %H2=%C2H6=40; %C2H4=20
Bi 24 : hiro ha hon ton 0,7g mt anken cn dng 246,4cm3 hiro ( 27,3oC v 1
atm). Xc nh cng thc phn t. Vit cng thc cu to, bit rng anken c cu to mch
thng.
S : C5H10
Bi 25 : Cho hn hp A gm C2H4 v H2 qua Ni, c hn hp B c d B/H 2 = 4,5. Nu cho A
qua dung dch Br2 d th khi lng bnh brom tng 0,14g. Cc phn ng xy ra hon ton.

1 Tnh khi lng cc cht trong A.

2 Tnh th tch dung dch brom 0,5M ti thiu cn dng.
S : 0,14; 0,04; 10ml
Bi 26 : Cho hn hp hiro v etilen c t khi hi so vi hiro l 7,5.
1 Tnh thnh phn % th tch kh trong hn hp.
2 Cho hn hp trn vo bnh kn c bt niken nung nng lm xc tc th sau phn ng
thu c mt hn hp kh c t khi so vi H2 l 9. Xc nh thnh phn % hn hp
kh sau phn ng.
S : 50% v 50%; 20%, 40%, 40%
Bi 27 : Cho hn hp X gm anken v hiro c t khi so vi heli bng 3,33. Cho X i qua
bt niken nung nng th ton b anken b hiro ha c hn hp Y c t khi so vi heli l
4.
1 Tm cng thc phn t ca anken.
2 Suy ra thnh phn ca hn hp.
S : C5H10, X (16%, 84%), Y (20%, 80%)
Bi 28 : Cho H2 v 1 olefin c th tch bng nhau qua Ni nung nng thu c hn hp A. Bit
rng t khi hi ca A i vi H2 l 23,2. Hiu sut phn ng hiro ha l 75%.
1 Tm cng thc v gi tn olefin.
2 t V (lt) hn hp A ni trn ri cho ton b sn phm chy qua 128g dung dch
H2SO4 98% sau th nghim nng dung dch H2SO4 l 62,72%. Tnh V (lt) (ktc).
S : C4H8; 22,4 lt
Bi 29 : Cho hn hp A gm 2 olefin l ng ng k tip nhau tham gia phn ng hp nc
c xc tc th c hn hp ancol B. Cho B tc dng vi Na thu c 5,6 lt kh (ktc).
Mt khc nu t chy hon ton hn hp A ri cho ton b sn phm chy hp th ht vo
nc vi trong th thu c 75g mui trung tnh v 40,5g mui axit.
1 xc nh cng thc 2 olefin.
2 Tm % khi lng v th tch tng olefin trong A.
S : C2H4 v C3H6, 50%
Bi 30 : t chy hon ton 0,672 lt hn hp gm hirocacbon v nit th thu c 0,88g
CO2 v 0,36g H2O. Bit khi lng hn hp l 0,84g v th tch o (ktc).
1 Tm cng thc phn t ca hirocacbon.
2 Suy ra thnh phn hn hp.
S : C2H4, 33,33% v 66,67%
Bi 31: Cho hn hp kh A (ktc) gm 2 olefin. t chy hon ton 7 th tch A cn 31
th tch oxi (ktc).
1 Xc nh cng thc phn t 2 olefin. Bit rng olefin nhiu cacbon chim t l trong
40 50% th tch ca A.
2 Tm % khi lng cc olefin trong A.
S : C2H4 v C4H8; 35,5% v 64,5%
Bi 32 : Khi t chy mt th tch hirocacbon A cn 6 th tch oxi v sinh ra 4 th tch CO2.
A c th lm mt mu dung dch brom c ni i v c th kt hp vi hiro to thnh mt
hirocacbon no mch nhnh.
Xc nh cng thc cu to ca A v vit cc phng trnh phn ng.
S : C4H8

Bi 33 : Cho 2,24 lt mt hn hp kh A (ktc) gm etan, propan, propilen sc qua dung dch

brom d, thy khi lng bnh tng thm 2,1g. Nu t chy kh cn li thu c mt lng
CO2 v 3,24g H2O.
1 Tnh thnh phn % th tch mi kh.
2 Dn lng CO2 ni trn vo bnh ng 200ml dung dch KOH 2,6M. Hy xc nh
nng M cc cht trong dung dch sau phn ng.
S : 50%, 20%, 30%, 0,65M. 1,3M
Bi 34 : Mt hn hp X gm ankan A v anken B, s nguyn t hiro trong phn t A bng
s nguyn t cacbon trong B. Khi t chy 3g hn hp X th thu c 5,4g nc. Xc nh
cng thc phn t A, B v tnh % th tch cc kh trong hn hp A.
S : CH4 v C4H8; 80% v 20%
Bi 35 : Mt hn hp gm H2, mt ankan v mt anken ( c cng s nguyn t cacbon vi
ankan). Khi t 100ml hn hp thu c 210ml kh CO2. Mt khc khi nung nng 100ml hn
hp vi Ni th sau phn ng cn li 70ml mt hirocacbon duy nht.
1 Tm cng thc phn t ca ankan v anken.
2 nh % th tch ca ankan v anken.
3 Tnh th tch O2 cn t chy 10ml hn hp (cc kh o cng iu kin)
S : C3H6 v C3H8; 30%, 40%, 350ml
Bi 36 : Mt hn hp kh gm nit v mt hirocacbon; 0,42g hn hp chim th tch
336cm3 (ktc). t chy lng hn hp ngi ta c 0,44g CO2 v 0,18g H2O.
1 Xc nh thnh phn nguyn t ca hirocacbon v cng thc nguyn ca n.
2 Xc nh khi lng phn t v cng thc cu to.
S : 85,72%, 14,28%, C2H4
Bi 37 : t chy hon ton 0,25 mol kh A thu c 33g CO2 v 13,5g hi nc.
1 Tm cng thc phn t v cng th cu to ca A, bit rng (ktc) khi lng ring
ca A l 1,875g/l.
2 Tnh khi lng sn phm to thnh khi cho lng cht A trn qua dung dch brom
d.
S : C3H6 ; 50g
Bi 38 : Hai hirocacbon A v B u th kh, A c cng thc C2xHy; B c cng thc CxH2x
(tr s x trong c 2 cng thc l bng nhau).
1 Lp cng thc phn t A v B. Bit rng t khi ca A i vi metan bng 3,625 v t
khi ca B i vi He l 7. Vit cng thc cu to ca A v B.
2 Tnh lng sn phm thu c khi cho hn hp trn tc dng va vi 16g dung
dch brom.
S : x=2, y=10, 18,8g
Bi 39 : t chy hon ton 0,03696 lt anken X 27,3oC v 1 atm, thu ton b kh CO2 vo
dung dch KOH ta c 0,3g mui axit v 0,207g mui trung tnh. Xc nh cng thc phn
t v cng thc cu to ca X.
S : C3H6
Bi 40 : Cho 3,5g mt anken tc dng vi dung dch KMnO4 long th c 5,2g sn phm
hu c.
1 Tm cng thc phn t ca anken.
2 Tnh th tch oxi (ktc) cn thit t chy ht lng anken trn.
S : C5H10 v 8,4ml

Bi 41 : Mt hn hp hai olefin ng ng k tip nhau c th tch 17,92 lt (o 0oC v 2,5

atm) dn qua bnh cha dung dch KMnO4 d, thy khi lng bnh cha dung dch KMnO4
tng 70g.
1 Xc nh cng thc phn t, vit cng thc cu to hai olefin.
2 Tnh % khi lng 2 olefin trong hn hp.
3 t chy hon ton th tch trn ca hn hp ri cho sn phm vo 5 lt dung dch
NaOH 1,8M s thu c mui g? Bao nhiu gam?
S : C3H6 v C2H4; 40% v 60%; 424g v 84g
Bi 42 : Mt hn hp X gm CO v mt hirocacbon A mch h. t chy hon ton 1,96g
hn hp X c 4,84g CO2 v 1,44g H2O.
1 Tm dy ng ng ca A.
2 Tm cng thc phn t ca A, bit d X/H 2 = 19,6. S : CnH2n; C4H8
Bi 43 : Dn 2,24 lt mt anken A (ktc) qua bt CuO nung nng, khi lng bt CuO gim
14,4g. Phn ng hon ton.
1 Tm cng thc phn t ca A.
2 Vit phng trnh phn ng trng hp, phn ng ca A vi dung dch KMnO4.
3 Hn hp A vi mt ng ng B trn theo t l mol 1:1. t chy hon ton mt th
tch hn hp cn 3,75 th tch oxi trong cng iu kin. Hy gi tn B.
S : C3H6, C2H4
Bi 44 : t chy hon ton a gam cht hu c A cn dng 6,72 lt O2 (ktc). Sn phm chy
ln lt qua bnh P2O5 thy bnh tng 3,6g ri qua bnh nc vi trong thy xut hin 20g kt
ta trng.
1 Tnh s gam a?
2 Lp cng thc thc nghim ri suy ra cng thc phn t ca A, bit t khi hi ca A
so vi nit l 2.
3 Vit cng thc cu to c th c, suy ra cng thc ng ca A, bit A cng vi H2O
cho 1 sn phm duy nht.
S : 2,8;
C4H8
Bi 45 : Hn hp X gm 2 hirocacbon A v B (B c s cacbon ln hn A, A v B u phn
ng vi dung dch Br2). 8,96 lit hn hp X tc dng ht vi nc brom cn ti thiu 64g
brom. Mt khc, em t 8,96 lit hn hp X tng s CO2 thu c l 48,4g. Hiu s hi nc
sinh ra ca B so vi A l 12,6g.
Xc nh cng thc phn t ca A, B.
S : C3H6; C2H4

III. Bi tp v ankin
Cu 01. Vit phng trnh minh ha cho dy chuyn ha

Cu 2: Khi t chy mt hirocacbon X ta thu c CO2, H2O vi t l s mol CO2:H2O l 2. X l

hirocacbon no sau y?
A. C2H4
B. C2H2
C. C3H6
D. C4H8
Cu 3: t chy hon ton 1 ankin (kc) thu c 22g CO2 v 7,2g H2O. CTPT ca ankin l:
A. C4H6
B. C3H4
C. C5H8
D. C2H2
Cu 4: t chy mt ankin mch h X thu c lng nc c khi lng ng bng khi lng X
em t. Bit X c kh nng tc dng vi dung dch AgNO 3 trong NH3 to kt ta. CTCT ca X l
g?
A. CH CH
B. CH C - CH3
C. CH C - CH2 - CH3 D. CH C - (CH2)2 - CH3

Cu 5: Cho 0,3 mol hn hp gm propin v ankin X phn ng va vi dung dch cha 0,2 mol
AgNO3 /NH3 . Cht X l:
A. Axetylen
B. But-1-in
C. But-2-in
D. Pent-1-in
Cu 6: Mt hn hp X gm 2 ankin l ng ng k tip nhau. Ho hi hn hp X c 5,6 lt (o
iu kin tiu chun) ri dn qua bnh dung dch Br 2 (ly d) th thy khi lng bnh tng 8,6 gam.
Cng thc phn t 2 ankin l:
A. C2H2 v C3H4
B. C3H4 v C4H6
C. C4H6 v C5 H8
D. C5H8 v C6H10
Cu 7: t chy 6,72 lt kh ( ktc) 2 hidrocacbon cng dy ng ng to thnh 39,6 gam CO 2 v
10,8 gam H2O. Cng thc phn t 2 hidrocacbon l:
A. C2H6; C3H8
B. C2H2; C3H4
C. C3H8; C5H12
D. C2H2; C4H6
Cu 8: t chy hon ton V lt (kc) mt ankin thu c 10,8g H O. Tt c sn phm chy cho hp
2

th ht vo bnh nc vi trong thy khi lng bnh tng 50,4g. V c gi tr l:

A. 6,72 lt
B. 4,48 lt
C. 13,44 lt
D. 12 lt
Cu 9: t chy hon ton Vlt (ktc) mt ankin thu c 5,4g H 2O. Tt c sn phm chy cho hp
th vo ht dung dch nc vi trong thy khi lng bnh tng 25,2g. V c gi tr l bao nhiu?
A. 3,36 lt
B. 2,24 lt
C. 6,72 lt
D. 6 lt
Cu 10: Hn hp X gm propin v but-2-in li tht chm qua bnh dd AgNO 3/NH3 d thy c 44,1 g
kt ta. %V mi kh trong hn hp X l:
A. 80%; 20%
B. 25%; 75%
C. 68,96%; 31,04%
D. Kt qu khc
Cu 11: t chy hon ton 0,1 mol ankin c 0,2 mol nc. Nu hiro ho hon ton 0,1 mol
ankin ny ri t chy th s mol nc thu c l:
A. 0.3mol
B. 0.4mol
C. 0.5mol
D. 0.6mol
Cu 12: Hn hp X gm 0,2 mol C 2H2 v 0,3 mol H2 c dn qua ng ng bt Ni nung nng thu
c hn hp Y gm C2H6, C2H4, C2H2 v H2. S mol xi cn dng t chy hn hp Y l:
A. 0,65mol
B. 0,75 mol
C. 0,55mol
D. 0,45 mol
Cu 13: Cho 13,44 lt kh hn hp gm mt ankin v 1 ankan kc i qua bnh ng nc Brm d,
thy c 8,96 lt kh thot ra kc. Khi lng brm tham gia p l:
A.64g
B. 70g
C. 65g
D. 74g
Cu 14: t chy hon ton 4,48 lit ankin(kc) thu c 7,2g H 2O . Nu hiro ho hon ton 4,48 lit
ankin ny ri t chy th lng nc thu c l:
A. 9g
B. 14,4g
C. 7,2g
D. 21,6g
Cu 15: Chia hn hp ankin C3H4 v C4H6 thnh 2 phn u nhau. Phn 1 em t chy han tan thu
c 3,08 gam CO2 v 0,9 gam H2O. Phn 2 dn qua dung dch Br 2 d th lng Brm phn ng l
bao nhiu?
A. 3,8 gam
B. 6,4 gam
C. 3,2 gam
D. 6,8 gam
Cu 16: iu ch 5,1617 lt axetilen(ktc) vi hiu sut 95% cn lng CaC 2 cha 10% tp cht
l:
A. 17,6g
B. 15g
C. 16,54g
D. Kt qu khc.
Cu 17: A l mt hirocacbon, th tch metylaxetilen bng 1,75 th tch hi A c cng khi lng
trong cng iu kin. S ng phn mch h ca A l:
A. 6
B. 5
C. 4
D. 3
Cu 18: Hn hp X gm 2 Hyr cacbon k tip nhau trong dy ng ng. t chy hon ton X th
th tch kh CO2 sinh ra bng th tch O2 cn dng t chy ht X. CTPT ca 2 Hyr cacbon trong
X l:
A- C2H6 v C3H6
B- C2H2 v C3H4.
C- C4H8 v C5H10
D- C A, B, C
Cu 19: Mt hirocacbon A mch h, th kh. Khi lng ca V lt kh ny bng 2 ln khi lng ca V
lt kh N2 cng iu kin nhit , p sut. Cng thc phn t ca hirocacbon l g?
A. C2H6
B. C2H4
C. C4H10
D. C4H8
Cu 20: t chy hon ton 0,25 mol hn hp khi gm ankin A v anken B thu c sn phm ln
lt qua bnh 1 ng P2O5 d v bnh 2 ng KOH d m c th thy bnh 1 tng 11,7 gam; bnh 02
tng 30,8 gam
Xc nh cng thc phn t ca A,B bit rng A km B mt nguyn t C
Cu 21: mt hn hp axetilen ,propen, metan

- t chy hon ton 11gam hn hp th thu c 12,6 gam nc

- mt khc 5,6 l (ktc) phn ng va vi dd cha 50 g Br 2
Xc nh thnh phn th tch hn hp u
Cu 22: mt hn hp kh X gm mt ankan, mt anken, mt ankin c th tch 1,792 l (ktc) c
chia thnh 2 phn bng nhau
- phn 01 cho qua dd AgNO3 trong NH3 d to ra 0,735 g kt ta v th tch hn hp gim 12,5%
- phn 2 em t chy hon ton ri hp th ton b sn phm vo 9,2 l dd Ca(OH) 2 0,0125M thy c
11 g kt ta
Xc nh cng thc phn t ca cc hirocacbon
Cu 23: t chy hon ton hn hp X gm 2 hirocacbon thuc cng dy ng ng thu c
19,712 lit CO2(ktc) v 10,08 g nc
a) Xc nh ng ng ca A,B bit rng chng c th l ankan, anken, ankin
b) Xc nh CTPT, CTCT c th c ca A,B bit chng th kh k thng
c) Chn cng thc ng ca A,B bit rng khi cho lng hn hp X tc dng vi AgNO3

trong NH3 d th ta c 4,8 g kt ta

Cu 24: dn ton b 6,72 l hn hp gm 2 ankin cho qua dd AgNO3 th thy c 2,24 l kh
thot ra c khi lng ng bng khi lng ca 7,56 l khi CH4 ng thi thu c 29,4 g
kt ta, xc nh cng thc cu to ca ankin
Cu 25: A l hn hp gm 2 hirocacbon th kh cng dy ng ng ankan, anken, ankin.
t chy hon ton A sau dn qua ng ng P2O5 d ri ng ng NaOH d th thy ng
1 tng 9 g cn ng 2 tng 30,8 g
a) Xc nh cng thc phn t ca hn hp A
b) Xc nh cng thc cu to ng cc cht trong A bit rng khi chng tc dng vi
AgNO3/NH3 d th thu c 14,7 g kt ta

BI TP B SUNG
Cu 1: Cho cc cht sau: CH - CH = CH
3

CH CH =C(CH )
3

CH3

(3) ;
2

CH3

C=C

C2H5

(1) ; CH - CH = CHCl (2) ;

CH3
(4)

Cl
C=C

C2H5

C2H5

(5)

Cht c ng cis-trans l:
A.(1), (2) v (3)
B.(2), (4) v (5)
C.(1), (4) v (5)
D.(2), (3) v (4)
Cu 2: Hirocacbon c cng thc phn t C H v c tnh i xng phn t cao nht trong s cc
4

ng phn mch h c tn gi no sau y?

A. Cis but 2 en
B. Trans but 2 en
C. 2-metyl but-2-en
D. But-2-en
Cu 3: S ng phn mch h c cng thc C5H10 l:
A. 3
B. 5
C. 8
D. Kt qu khc
Cu 4: C5H10 c bao nhiu /phn anken khi cng vi HCl to sp trong clo lin kt vi cacbon
bc 3?
A. 1
B. 2
C. 3
D. 4
Cu 5: c tn hp cht sau theo danh php IUPAC

CH3

CH3
C=C

Cl

Br

A. 2- Brom-3- clobut-2-en
B. 2,3-brom clo-2- buten
C. cis-2-brom-3-clobut-2-en
D. Cis-3-clo-2-brombut-2-en
Cu 6: Khi cng HBr vo 2-metylbut-2-en theo t l 1 : 1, s lng sn phm thu c l bao
nhiu?
A. 1
B. 2
C. 3
D. 4
Cu 7: iu ch etilen trong phng th nghim t
cc oxit nh

c,

) thng ln

. Chn mt trong s cc cht sau loi b

A. Dd brom d
B. Dd NaOH d
C. Dd Na2CO3 d
D. Dd KMnO4 long, d
Cu 8: Mt hiro cacbon (X) th kh c cng thc phn t dng C H
x 1

A. CH

B. C H
4

C.C H
4

. CTPT ng ca (X) l:
3x

D.C H
6

Cu 9: i vi Ankin, nguyn t cacbon lin kt ba trng thi lai ho no?

A. sp
B. sp2
C. sp3
D. sp4
Cu 10: C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (Ni,
) thu c sn phm l isopentan?
A. 3
B. 4
C. 5
D. 6
Cu 11: Thc hin th nghim sau : thu vo bnh nn th tch kh C 2H2 v th tch kh Cl2 .y
bnh bng nt bc. Ly tay m ming bnh v a ngn la que m vo gn ming bnh. Tip tc
a vo ming bnh giy qu tm t. Cho bit hin tng g xy ra?

Cl2

C2H2

A. Qu tm khng i mu, v sn phm ca phn ng l ClCH=ChCl khng phi l axit hoc

baz .
B. Thnh bnh c nhiu mui than, qu tm chuyn sang mu v xy ra phn ng :
CHCH + Cl2 2C + 2HCl
C. Khng c hin tng g xy ra, qu tm khng i mu .
D. Qu tm khng i mu v xy ra phn ng: CHCH + Cl2 Cl2CH-CHCl2
Cu 12: Hn hp gm C2H4, C2H6, C2H2 , tinh ch C2H6 ngi ta cho hn hp li chm qua :
A. dd KMnO4.
B. Dd Br2.
C. dd AgNO3/NH3; dd Br2.
D. A,B,C.
Cu 13 : t chy hon ton mt hirocacbon X ri dn ton b sn phm chy qua bnh cha CaCl 2
khan v d2 NaOH th thy khi lng cc bnh tng ln lt l 0,72g v 2,2g. Dy ng ng ca X:
A. Ankan
B. Anken
C. Ankin
D. Xyclo ankan
Cu 14: Cng thc tng qut ca hydrocacbon c dng CnH2n + 2 2a . Gi tr a = 2 ng vi :
A. xiclopentan
B. 2-metyl butadien-1,3
C. vinylaxetylen
D. xiclohexan
Cu 15: Isopren c th cng hp brm theo t l s mol 1:1 to thnh cc ng phn v tr. S ng
phn v tr l :
A. 1
B. 2
C. 3
D. 4
Cu 16: Cao su isopren v cao su buna khc nhau ch:
A.Cu trc lp th
B. Thnh phn monome
C.Cng thc cu to ca cc mt xch
D. Ch c tn thng mi
Cu 17: Mt hn hp X gm anken v H2. Khi t chy hon ton 2,24lt kh X(dktc) vi lng d
oxi ri cho sn phm chy i qua dung dch Ba(OH) 2 d th c 31,52g kt ta. Sau khi lc kt ta,
khi lng dung dch cn li nh hn khi lng dung dch ban u l 20,52g. Vy, CTPT ca A l:
A. C2H4
B. C3H6
C. C4H8
D. C5H10

Cu 18: Cho 5,6 lt hn hp 2 olefin l ng ng lin tip hp nc (c xc tc) c hn hp 2

ru. Thu hn hp 2 ru ny dng khan ri chia lm 2 phn bng nhau. Phn 1 phn ng ht vi
Na d thu c 840 ml kh. t chy ht phn 2 ri cho ton b sn phm chy hp th vo bnh
ng NaOH d th khi lng bnh NaOH tng 13,75 gam. Cng thc phn t ca 2 olefin l:
A. C2H4; C3H6
B. C3H6; C4H8
C. C4H8; C5H10
D. C5H10; C6H12
Cu 19: t chy hon ton a gam hn hp C2H4, C3H6, C4H8, C5H10 cn 24,99 lt O2(ktc) thu c
16,8 lt CO2( ktc). Hi a c gi tr bao nhiu?
A. 7,5g
B. 10,5g
C. 4g
D. 12g
Cu 20: t chy hon ton hn hp 2 anken thu c 7,2 gam nc. Dn ton b kh CO 2 va thu
c vo dung dch Ca(OH)2 d th thu c bao nhiu gam kt ta?
A. 40 gam

B. 20 gam

C. 100 gam

D. 200 gam

Cu 21: t chy hon ton V lt C3H6 ( ktc) ri cho ton b sn phm chy hp th ht vo dung
dch c cha 102,6 gam Ba(OH)2 th thu c lng kt ta cc i. V c gi tr no sau y?
A. 2,24 lt
B. 4,48 lt
C. 5,6 lt
D. 8,96 lt
Cu 22: Hn hp A gm Buten-2 v Propen. Sau khi hirat ha hon ton hn hp A, thu c h 2 B
gm ba cht hu c. t chy hon ton h 2 B, ch thu c x mol CO 2 v y mol H2O. Chn kt lun
ng:
A. x = y
B. x > y
C. A, B u sai
D. x c th bng, ln hn hoc nh hn y l cn ph thuc vo s mol mi cht trong hn
hp B
Cu 23: Cho polivinyl clorua ( - CH -CHCl-)
2

tc dng vi kh Clo ngi ta c mt polime c

n

cha 66,77% Clo trong phn t. Tnh xem trung bnh mt phn t Clo tc dng vi my mc xch CH -CHCl-. Gi thuyt rng h s trng hp n khng thay i trong phn ng.
2

A. 2
B. 3
C. 4
D. 5
Cu 24: Bit 1 mol kh etilen chy hon ton to ra 1 nhit lng l 1423kj. Nhit lng to ra khi
t chy 1 kg etilen l :
A. 50821,4kj
B. 50281,4kj
C. 50128,4kj
D. 50812,4kj
Cu 25: t chy hon ton Vlt (kc) mt ankin th kh thu c H
O v CO
c tng
khi lng l 92g. Nu cho sn phm chy i qua dung dch Ca(OH) 2 d, thu c 160g kt ta.
CTPT ca ankin l:
A. C
H
B. C
H
C. C
H
D. C

Cu 26: Oxi ha hon ton 0,1344 lt mt ankin A ( 273 0c v 1 atm) ri dn tt c kh CO 2 sinh ra

vo dung dch Ca(OH)2 th thu c 0,729g mui trung ha v 0,3g mui axit. Cng thc phn t
ca A:
A. C3H4
B. C3H6
C. C5H10
D. C4H6
Cu 27: Cht A c cng thc phn t C 6H6. 1 mol A tc dng vi AgNO3 d trong dung dch NH3 to
ra 292 gam kt ta. Cht A l :
A. Hexadiin-1,5
B. Hexadiin-1,4
C. Hexadiin-1,3
D. Mt cht khc
Cu 28: Trong mt bnh kn cha hn hp A gm hirocacbon X v H2 vi Ni. Nung nng bnh 1 thi
gian ta thu c 1 kh B duy nht. t chy B, thu c 8,8 gam CO 2 v 5,4 gam nc. Bit VA =
3VB. Cng thc ca X l:
A. C3H4
B. C3H8
C. C2H2
D. C2H4

Cu 29: Cho135ml hn hp kh A gm H2, mt olefin v mt ankin i qua ng c Ni nung nng, sau

phn ng ch cn 60ml mt hirocacbon duy nht. Mt khc, nu t chy hon ton 60ml hn hp A
th thu c 80ml CO2. Cc th tch o cng iu kin. Vy, CTPT ca hai hirocacbon:
A. C2H2 ; C2H4
B. C3H4 ; C3H6
C. C2H2 ; C6H6
D. kin khc
Cu 30: Chia hn hp gm C2H2, C2H4 v C2H6 thnh hai phn u nhau. Phn 1, em t chy hon
ton thu c 22,4 lt CO2(ktc). Phn 2, em hiro ho hon ton, sau t chy ht th thu c
th tch CO2(ktc) l:
A. 22,4lt
B. 11,2lt
C. 33,6lt
D. 44,8lt
Cu 31: Hn hp X gm 3 kh C3H4, C2H2, H2 cho vo bnh kn dung tch 9,7744 lit 25 0C p sut 1
atm cha 1 t Ni nung nng bnh mt thi gian thu c h 2 kh Y, bit dX/Y=0,75. S mol H2 tham gia
p l :
A. 0,75mol
B. 0,3mol
C. 0,15mol
D. Kt qu khc.
Cu 32: Hn hp A gm Etan, Etilen, Axetilen v Butaien-1,3. t chy ht m gam hn hp A. Cho
sn phm chy hp th vo dung dch nc vi d, thu c 100 gam kt ta v khi lng dung dch
nc vi sau phn ng gim 39,8 gam. Tr s ca m l:
A. 58,75g
B. 13,8g
C. 60,2g
D. 37,4g
Cu 33: Trong mt bnh kn dung tch khng i cha hn hp xi d v mt ankadien lin hp A
theo t l th tch 9:1 nhit to C v p sut p atm. Bt tia la in t chy ht A ri a nhit
bnh v toC th p sut trong bnh lc ny bng 21p:20 atm. Cc cht u th kh. Tn cht A l:
A. propanien.
B. ivinyl
C. penta-1,3-ien.
D. buta-1,2-ien.
Cu 34: Cho V lt ( iu kin tiu chun) hn hp kh gm 2 olefin lin tip nhau trong dy ng
ng hp nc (c H2SO4 long xc tc) thu c 6,45 gam hn hp A gm 3 ru. em un hn
hp A trong H2SO4 c 1400C th thu c 5,325 gam B gm 6 ete khan. Gi thit hiu sut ca tt
c cc loi phn ng u t 100%. Cho bit cng thc cu to ca cc ru?
A. CH3OH v CH3-CH2-CH2-CH2-OH
B. C2H5OH; CH2=CH-CH2-OH v C4H9OH
C. CH2=CH-OH; CH3OH v C2H5OH
D. Kt qu khc
Cu 35: Hn hp X gm 2 hidrocacbon A, B c cng s nguyn t cacbon v c s lin kt pi hm
km nhau 1 n v . t 8.96 lit hh X cn 36,08 lt O 2 v sn phm chy khi cho qua P2O5 th khi
lng tng 18 g.(cc kh o ktc)
a. CTPT ca A & B l :
A. C3H4 & C3H6 B. C2H2 & C2H4
C. C4H6 & C4H8
D. Tt c u sai
b. Nu thm 1 hidrocacbon D vo 8.96 lit hh X th thu c hh Y. t Y thu c 66 g CO 2 & 35.2 g
H2O. CTPT ca D l :
A.C2H10
B.C3H8
C.C2H6
D. Tt c u sai
c. Thnh phn % V hh Y (A, B ,D) ln lt l :
A.40/40/20
B.30/40/30
C.10/60/30
D. Tt c u sai