S GD & T VNH PHC

TRNG THPT CHUYN VNH PHC

THI KSCL LN 4 NM HC 2014 - 2015

MN HA HC 12

Thi gian lm bi: 90 pht;

(Khng k thi gian giao )
M thi 136
Cho nguyn t khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; S = 32; Cl = 35,5; Br = 80; P = 31; Na = 23; Mg = 24; Al = 27; K = 39; Ca
= 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba = 137; Pb = 207; Ni = 59.
Cu 1: Ha tan hon ton 2,43 gam hn hp gm Mg v Zn vo mt lng va dung dch H 2SO4 long, sau
phn ng thu c 1,12 lt H2 (ktc) v dung dch X. Khi lng mui trong dung dch X l
A. 5,83 gam.
B. 4,83 gam.
C. 7,33 gam.
D. 7,23 gam.
Cu 2: Cht hu c A ch cha C, H,O c CTPT trng cng thc n gin nht. Cho 2,76 gam A tc dng vi
mt lng va dd NaOH, chng kh th phn bay hi ch c H 2O, phn cht rn khan cha 2 mui c khi
lng 4,44 gam. t chy hon ton hai mui ny c 3,18 gam Na2CO3; 2,464 lt CO2(ktc) v 0,9 gam H2O.
Nu t chy 2,76 gam A th khi lng H2O thu c l
A. 1,2g
B. 0,36g
C. 0,9g
D. 1,08g
Cu 3: Ha tan ht 20,9 gam hn hp gm M v M2O (M l kim loi kim) vo nc, thu c dung dch X
cha 28 gam cht tan v 1,12 lt kh H2 (ktc). Kim loi M l
A. Rb.
B. Li.
C. K.
D. Na.
Cu 4: Cht X l anehit mch h. Mt th tch hi X cng hp ti a ba th tch kh H 2, thu c cht Y. Mt
th tch hi Y tc dng vi Na d, thu c mt th tch kh H 2 (cc th tch kh v hi o cng iu kin).
Cht x thuc loi
A. anehit no, ba chc, mch h.
B. an ehit n chc, mach h, phn t c hai lin kt C=C.
C. anehit hai chc, mch h, phn t c mt lin kt C=C.
D. an ehit n chc, mch h, phn t c ba lin kt C=C.
Cu 5: Pht biu no sau y l sai?
A. Tt c kim loi u dn in.
B. Nguyn tc iu ch kim loi l kh ion kim loi thnh nguyn t.
C. Tt c kim loi u tan c trong dung dch HCl.
D. Phng php thy luyn dng iu ch kim loi c tnh kh yu.
Cu 6: Cho cc nhn xt sau:
(a) Phenol (C6H5OH) v anilin u phn ng vi nc brom to kt ta.
(b) Anehit phn ng vi H2 (xc tc Ni, to) to ra ancol bc mt.
(c) Axit fomic tc dng vi dung dch KHCO3 to ra CO2.
(d) Etylen glicol, axit axetic v glucoz u ha tan c Cu(OH)2 iu kin thng.
(e) Anehit fomic v phenol c dng tng hp nha novolac.
S nhn xt ng l: A. 2. B. 3. C. 4. D. 5.
Cu 7: Ma axit ch yu l do nhng cht thi sinh ra trong qu trnh sn xut cng nghip nhng khng c
x l trit . l nhng cht no sau y ?
A. NH3, HCl
B. H2S, Cl2
C. SO2, NO2.
D. CO2, SO2
Cu 8: Dung dch no di y tc dng c vi NaHCO3?
A. Na2S.
B. NaOH.
C. CaCl2.
D. BaSO4.
Cu 9: Cho cc phn ng:
(a) Cl2 + NaOH
(b) Fe3O4 + HCl
(c) KMnO4 + HCl
(d) FeO + HCl
(e) CuO + HNO3
(f) KHS + KOH
S phn ng to ra hai mui l
A. 6.
B. 4.
C. 5.
D. 3.
Cu 10: Trong mt bnh kn cha hn hp X gm hidrocacbon A mch h( l cht kh iu kin thng) v
0,06 mol O2, bt tia la in t chy ton b hn hp X. Ton b sn phm chy sau phn ng cho qua 3,5
lt dung dch Ca(OH)2 0,01M th thu c 3 gam kt ta v c 0,224 lt kh duy nht thot ra khi bnh(ktc).
Bit cc phn ng xy ra hon ton, nc b ngng t khi cho qua dung dch. Cht A c s CTPT tho mn l
A. 4.
B. 6.
C. 7.
D. 5.
Cu 11: Hn hp X gm mt anehit v mt ankin c cng s nguyn t cacbon. t chy hon ton a (mol)
hn hp X thu c 3a (mol) CO 2 v 1,8a (mol) H2O. Hn hp X c s mol 0,1 tc dng c vi ti a 0,14
mol AgNO3 trong NH3 (iu kin thch hp). S mol ca anehit trong 0,1 mol hn hp X l

A. 0,03.
B. 0,04.
C. 0,02.
D. 0,01.
Cu 12: Ha tan 7,2 gam mt hn hp gm hai mui sunfat ca mt kim loi kim v mt kim loi kim th
vo nc d, thu c dung dch X. Cho dung dch BaCl 2 phn ng va vi X, thu c 11,65 gam, kt ta
v dung dch Y cha m gam mui. Gi tr ca m l: A. 6,50.
B. 7,00.
C. 8,20.
D. 5,95.
Cu 13: Sp xp cc ion theo chiu gim dn tnh oxi ha (t tri qua phi)
A. Ag+, Fe3+, Fe2+, Cu2+, H+
B. Fe3+, Ag+, Fe2+, Cu2+, H+
+
3+
2+
+
2+
C. Ag , Fe , Cu , H , Fe
D. Fe2+, H+, Cu2+, Fe3+, Ag+
Cu 14: Cc t u c ngun gc t xenluloz l
A. t visco v t axetat.
B. t tm v t visco.
C. t tm v t axetat.
D. t lapsan v t nilon-6,6.
Cu 15: Cho 250 ml dung dch X gm Na2CO3 v NaHCO3 phn ng vi dung dch H2SO4 d, thu c 2,24
lt kh CO2 (ktc). Cho 500 ml dung dch X phn ng vi dung dch BaCl2 d, thu c 15,76 gam kt ta.
Nng mol/l ca NaHCO3 trong X l: A. 0,16M. B. 0,40M.
C. 0,24M.
D. 0,08M.
Cu 16: Sc kh CO2 n d vo dung dch NaAlO2 th
A. thu c kt ta mu trng dng keo.
B. c kt ta mu trng dng keo, sau tan ht.
C. thu c kt ta mu nu.
D. khng c hin tng g.
Cu 17: Cho dy cht: Ca3(PO4)2, BaSO4, KNO3, CuO, Cr(OH)3, AgCl v BaCO3. S cht trong dy khng tan
trong dung dch HNO3 long l
A. 1.
B. 2. C. 4. D. 3.
Cu 18: Cht no sau y gy ra tnh cng tm thi ca nc?
A. HCl
B. Ca(HCO3)2
C. NaOH
D. CaCl2
Cu 19: Cho cn bng 2NO2 N2O4 (kh khng mu) H = -61,5 kJ. Nhng bnh ng hn hp NO 2 v N2O4
vo bnh ng nc th:
A. Mu nu m dn
B. Hn hp vn gi nguyn mu nh ban u
C. Chuyn sang mu xanh
D. Mu nu nht dn
Cu 20: Nung m gam hn hp X gm KClO3 v KMnO4 thu c cht rn Y (KCl, K2MnO4, MnO2, KMnO4)
v O2. Trong Y c 1,49 gam KCl chim 19,893% theo khi lng. Trn lng O2 trn vi khng kh theo t l
th tch tng ng l 1:4 thu c hn hp kh Z. t chy ht 0,528 gam cacbon bng hn hp Z thu c
hn hp kh T gm 3 kh O 2, N2, CO2, trong CO2 chim 22% v th tch. Bit trong khng kh c 80% N 2 v
20% O2 theo th tch. Gi tr ca m l
A. 8,70.
B. 8,77.
C. 8,91.
D. 8,53.
Cu 21: Khi thy phn mt triglixerit X, thu c cc axit bo gm axit oleic, axit panmitic, axit stearic. Th
tch kh O2 (ktc) cn t chy hon ton 8,6 gam X l
A. 15,680 lt.
B. 20,160 lt.
C. 17,472 lt.
D. 16,128 lt.
Cu 22: Ha tan ht hn hp gm 0,01 mol Cu 2S; 0,04 mol FeCO3 v x mol FeS2 bng dung dch HNO3 va
. Sau khi cc phn ng xy ra hon ton, thu c V lt (ktc) hn hp hai kh, trong c mt kh mu nu
v dung dch ch cha mui ca Cu2+, Fe3+ vi mt anion. Gi tr ca V l
A. 51,072.
B. 46,592.
C. 47,488.
D. 50,176.
Cu 23: Nhit nng chy, nhit si v tan trong nc ca ba cht hu c X, Y, Z c trnh by trong
bng sau:
Nhit si
Nhit nng chy
tan trong nc (g/100mL)
(OC)
(OC)
20OC
80OC
X
181,7
43
8,3

Y
Phn hy trc khi si
248
23
60
Z
78,37
-114

X, Y, Z tng ng l cht no sau y:

A. Phenol, ancol etylic, glyxin.
B. Phenol, glyxin, ancol etylic.
C. Glyxin, phenol, ancol etylic.
D. Ancol etylic, glyxin, phenol.
Cu 24: C bao nhiu nguyn t ha hc m nguyn t c electron cui cng in vo phn lp 2s ?
A. 4.
B. 3.
C. 2.
D. 1.
Cu 25: in phn 100 ml dung dch hn hp Cu(NO3)2 0,2M v AgNO3 0,1M (in cc tr, hiu sut in
phn 100%) vi cng dng in khng i 3,86A. Thi gian in phn n khi thu c 1,72 gam kim loi
catot l t giy. Gi tr ca t l
A. 250.
B. 750.
C. 1000.
D. 500.
Cu 26: Cht no sau y l hp cht ion:
A. H2CO3
B. Na2O
C. NO2
D. O3
Cu 27: Pht biu no sau y l sai?
A. Kh F2 tc dng vi H2O un nng, to ra O2 v HF.

B. Kh Cl2 phn ng vi dung dch KOH long, ngui to ra KClO3.

C. Kh Cl2 tc dng vi dung dch NaBr d to ra Br2 v NaCl.
D. Kh HI b nhit phn mt phn to ra H2 v I2.
Cu 28: Hirat ha anken (c xc tc) thu c mt ancol duy nht c cng thc C4H9OH. Anken l
A. but-1-en.
B. 2-metylpropen.
C. but-2-en.
D. 2-metylbut-2-en.
Cu 29: Cho 1 ming Fe vo cc ng dung dch H 2SO4 long. Bt kh H2 s bay ra nhanh hn khi ta thm vo
cc trn dung dch no trong cc dung dch sau?
A. Na2SO4
B. HgSO4
C. MgSO4
D. Al2(SO4)3
Cu 30: Cho kh H2S li chm cho n d qua hn hp gm FeCl 3, AlCl3, NH4Cl, CuCl2 thu c kt ta X.
Thnh phn ca X l:
A. FeS, Al2S3, CuS
B. CuS, S
C. CuS
D. FeS, CuS
Cu 31: A c cng thc phn t C7H8O. Khi phn ng vi dd Br2 d to thnh sn phm B c MB MA=237.S
cht A tha mn l:
A. 1
B. 4
C. 2
D. 5
Cu 32: Cho 5,04 gam hn hp Mg v Al c t l mol tng ng l 3:2 tc dng vi dung dch HNO 3 long, d
thu c dung dch X v 0,896 lt (ktc) hn hp hai kh khng mu, khng ha nu trong khng kh c t khi
hi so vi H2 bng 18. S mol HNO3 b kh trong qu trnh trn l
A. 0,095 mol.
B. 0,11mol.
C. 0,1 mol.
D. 0,08 mol.
Cu 33: Cho 1 (mol) axit T tc dng vi dung dch NaHCO3 d thu c 1 (mol) CO2. S nhm chc ca T l
A. 3.
B. 2.
C. 1.
D. 4.
Cu 34: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H4O2 v c cc tnh cht sau: X, Y u
c phn ng cng hp vi Br2, cho 1 mol X hoc 1 mol Z tc dng vi lng d dung dch AgNO3 trong NH3
un nng, thu c ti a 4 mol Ag. Cc cht X, Y, Z ln lt l
A. CH2=CH- COOH, HCOOCH=CH2, OHC-CH2- CHO.
B. OHC- CH2- CHO, CH2=CH- COOH, HCOOCH=CH2.
C. HCOOCH=CH2, CH3-CO-CHO, OHC-CH2-CHO.
D. HCOOCH=CH2, CH2=CH- COOH, OHC-CH2-CHO.
23
Cu 35: Mt nguyn t c k hiu 11 Na . Trong bng tun hon cc nguyn t ha hc nguyn t natri thuc
A. nhm IIIB, chu k 4.
B. nhm IA, chu k 3.
C. nhm IA, chu k 4.
D. nhm IA, chu k 2.
Cu 36: Este X c cng thc phn t l C 9H8O2 tc dng vi mt lng ti a dung dch NaOH un nng thu
c dung dch Y ch cha hai mui. Thm Br2 d vo dung dch Y (sau khi c axit ha bng HCl long
d) thu c 43,8 gam kt ta cha 4 nguyn t Br trong phn t. Tng khi lng mui trong Y l:
A. 21 gam
B. 20,6 gam
C. 33,1 gam
D. 28
Cu 37: Hn hp X gm mt ancol v mt axit cacboxylic u no, n chc, mch h, c cng s nguyn t
cacbon trong phn t. t chy hon ton 51,24 gam X, thu c 101,64 gam CO 2. un nng 51,24 gam X vi
xc tc H2SO4 c, thu c m gam este (hiu sut phn ng este ha bng 60%). Gi tr m gn gi tr no
nht sau y? A. 25,5.
B. 28,5.
C. 41,8.
D. 47,6.
Cu 38: im ging nhau ca glucoz v saccaroz l
A. u phn ng vi Cu(OH)2 to dung dch mu xanh lam.
B. u lm xanh h tinh bt.
C. u phn ng vi dung dch AgNO3 trong NH3 to Ag.
D. u b thu phn trong dung dch axit.
Cu 39: Thy phn khng hon ton pentapeptit Gly-Ala-Val-Ala-Gly, thu c ti a bao nhiu ipeptit mch
h cha Gly? A. 4. B. 3. C. 1. D. 2.
Cu 40: Cho a gam hn hp X gm glyxin, alanin v valin phn ng vi 200 ml dung dch HCl 0,1M, thu
c dung dch Y. phn ng ht vi cc cht trong dung dch Y cn 100 ml dung dch KOH 0,55M. t
chy hon ton a gam hn hp X, thu c hn hn hp Z gm CO 2, H2O v N2. Cho Z vo bnh ng dung
dch Ba(OH)2 d, thy khi lng bnh tng 7,445 gam. Bit cc phn ng xy ra hon ton. Gi tr ca a l
A. 3,255.
B. 2,135.
C. 2,695.
D. 2,765.
Cu 41: X l hn hp kim loi Ba v Al. Ha tan m gam X vo lng d nc thu c 8,96 lt H 2 (ktc).
Cng ha tan m gam X vo dung dch NaOH d th thu c 12,32 lt kh H2 (ktc). Gi tr ca m l:
A. 21,80.
B. 57,50.
C. 13,70.
D. 58,85.
Cu 42: Tn gi no sau y ng vi C2H5-NH2:
A. Etyl amin.
B. Anilin
C. Metyl amin
D. Alanin.
Cu 43: Cho hnh v m t qua trnh xc nh C v H trong
hp cht hu c.

Hy cho bit s vai tr ca CuSO4 (khan) v bin i ca n trong th nghim.

A. Xc nh H v mu CuSO4 t mu trng sang mu xanh
B. Xc nh H v mu CuSO4 t mu xanh sang mu trng
C. Xc nh C v mu CuSO4 t mu xanh sang mu trng.
D. Xc nh C v mu CuSO4 t mu trng sang mu xanh.
Cu 44: Cho s th nghim nh hnh v.

Bit cc kh c cng s mol. Nghing ng nghim nc nhnh A chy ht sang nhnh B. Xc nh

thnh phn ca cht kh sau phn ng.
A. CO2, O2
B. CO2
C. O2 , CO2, I2.
D. O2
Cu 45: Cht hu c X c cng thc phn t C 4H6O4, khng c kh nng tham gia phn ng trng bc. Cho a
mol X phn ng vi dung dch KOH d, thu c ancol Y v m gam mt mui. t chy hon ton mt lng
ancol Y, thu c 0,2 mol CO2 v 0,3 mol H2O. Gi tr ca a v m ln lt l
A. 0,1 v 16,6.
B. 0,12 v 24,4.
C. 0,1 v 13,4.
D. 0,2 v 12,8.
Cu 46: Oxi ha 25,6 gam CH3OH, thu c hn hp sn phm X gm HCHO, HCOOH, H 2O v CH3OH d,
bit rng c 75% lng CH3OH ban u b oxi ho. Chia X thnh hai phn bng nhau:
- Phn mt phn ng vi lng d dung dch AgNO3 trong NH3 un nng, thu c m gam Ag.
- Phn hai phn ng va vi 100 ml dung dch KOH 1M.
Gi tr ca m l A. 64,8. B. 108,0.
C. 129,6.
D. 32,4.
Cu 47: Phn ng no ng?
A. CH3OH + CuO t HCHO + H2O + Cu . B. CH3OH + NaOH CH3ONa + H2O .
C. C2H5OH + H2O C2H4(OH)2 + H2.
D. C2H5OH + NaCl C2H5Cl + NaOH.
Cu 48: Cho 18,3 gam hn hp gm Ba v Na vo 1 lt dung dch CuSO 4 0,5M, sau khi cc phn ng xy ra
hon ton, thu c m gam kt ta v 4,48 lt kh H2 (ktc). Gi tr ca m l
A. 45,5.
B. 40,5.
C. 50,8.
D. 42,9.
Cu 49: Hn hp kh no di y tn ti iu kin thng?
A. SO2 v H2S.
B. Cl2 v NH3.
C. HCl v NH3.
D. Cl2 v O2.
Cu 50: t chy hon ton 0,2 mol mt ancol n chc X trong 31,36 lt O2 (d) (ktc), thu c tng s
mol cc kh v hi bng 2 mol. Ancol X c s ng phn cu to l
A. 4.
B. 2.
C. 6.
D. 8.
O

-----------------------------------------------

P N
1D
11
21C
31C
41A

2D
12D
22A
32A
42A

3D
13C
23B
33C
43A

4C
14A
24C
34D
44D

5C
15C
25B
35B
45A

6D
16A
26B
36A
46B

7C
17B
27B
37A
47A

8B
18B
28C
38A
48D

9D
19D
29B
39D
49D

10C
20B
30B
40A
50A