BI TP TRC NGHIM V ST

Cu 1 : Oxi ha chm m gam Fe ngoi khng kh sau mt thi gian thu c 12 gam hn hp X ( Fe , FeO , Fe 2O3 ,Fe3O4
). ha tan ht X , cn va 300 ml dung dch HCl 1M , ng thi gii phng 0,672 lt kh ( ktc ). Tnh m ?
A.10,08
B.8,96
C.9,84
D.10,64
Cu 2: Ha tan hon ton 2,8 gam hn hp FeO , Fe 2O3 v Fe3O4 cn va V ml dung dch HCl 1M , thu c dung
dch X. Cho t t dung dch NaOH d vo dung dch X thu c kt ta Y. Nung Y trong khng kh n khi lng
khng i thu c 3 gam cht rn. Tnh V ?
A.87,5
B.125
C.62,5
D.175
Cu 3 : Trn bt Al vi bt Fe 2O3 ( t l mol 1 : 1 ) thu c m gam hn hp X. Thc hin phn ng nhit nhm hn hp
X trong iu kin khng c khng kh sau mt thi gian thu c hn hp rn Y. Ha tan ht Y bng acid nitric long d ,
thy gii phng 0,448 lt kh NO ( ktc sn phm kh duy nht ). m =?
A.7,48
B.11,22
C.5,61
D.3,74
Cu 4: Ha tan ht 7,68 gam hn hp FeO , Fe 2O3 v Fe3O4 cn va 260 ml dung dch HCl 1M. Dung dch thu c
cho tc dng vi dd NaOH d ri lc kt ta nung trong khng kh n khi lng khng i thu c m gam rn.. tnh m
?
A.20
B.8
C.16
D.12
Cu 5: X l hn hp gm Fe v 2 oxit ca st. Ha tan ht 15,12 gam X trong dung dch HCl d , sau phn ng thu c
16,51 gam mui Fe (II) v m gam mui Fe (III ) . Mt khc , khi cho 15,12 gam X phn ng hon ton vi dung dch acid
nitric long d th gii phng 1,568 lt NO ( sn phm kh duy nht - ktc ). Thnh phn % v khi lng ca Fe trong
X l ?
A.11,11%
B.29,63%
C.14,81%
D.33,33%
Cu 6 :Ha tan ht m gam hn hp X gm Cu v 2 oxit st cn va 500ml dung dch HCl 1,2M. C cn dung dch
sau phn ng thu c 38,74 gam hn hp hai mui khan . m nhn gi tr ?
A.22,24
B.20,72
C.23,36
D.27,04
Cu 7: Ha tan ht a gam hn hp 2 oxit st bng dung dch HCl d sau phn ng thu c dung dch cha 9,75 gam
FeCl3 v 8,89 gam FeCl2 . a nhn gi tr no ?
A.10,08
B.10,16
C.9,68
D.9,84
Cu 8 : Ha tan ht 4 gam hn hp A gm Fe v 1 oxit st trong dung dch acid HCl d thu c dung dch X. Sc kh
Cl2 cho n d vo X thu c dung dch Y cha 9,75 gam mui tan. Nu cho 4 gam A tc dng vi dung dch HNO3
long d th thu c V lt NO ( sn phm kh duy nht - ktc)/ V= ?
A.0,896
B.0,747
C.1,120
D.0,672
Cu 9: Ha tan ht a gam hn hp X gm Fe v mt oxit st trong b gam dung dch H 2SO4 9,8% ( lng va ), sau
phn ng thu c dung dch cha 51,76 gam hn hp hai mui khan. Mt khc nu ha tan ht a gam X bng dung dch
H2SO4 c nng th thu c duy nht 58 gam mui Fe (III). Xc nh b ?
A.370
B.220
C.500
D.420
Cu 10 : Ha tan ht m gam hn hp A gm Cu v 1 oxit st bng 320 ml dung dch HCl 1M ( va ). Dung dch thu
c sau phn ng ch cha hai mui l FeCl 2 ( c khi lng 15,24 gam ) v CuCl 2. Xc nh cng thc ca oxit st v
gi tr m ?
A. Fe3O4 v 14,40 gam
B. Fe2O3 v 11,84 gam
C. Fe3O4 v 11,84 gam
D. Fe2O3 v 14,40 gam
Cu 11: Ha tan ht m gam hn hp Y( gm Cu v 2 oxit ca st ) bng 260 ml dung dch HCl 1M - lng va , thu
c dung dch Z cha 2 mui vi tng khi lng l 16,67 gam. Xc nh m ?
A.11,60
B.9,26
C.11,34
D.9,52
Cu 12 :Y l mt hn hp gm st v 2 oxit ca n. Chia Y lm hai phn bng nhau :
Phn 1 : em ha tan ht trong dung dch HCl d thu c dung dch Z cha a gam FeCl 2 v 13 gam FeCl3
Phn 2 : Cho tc dng ht vi 875 ml dung dch HNO 3 0,8M ( va ) thu c 1,568 lt kh NO ( ktc - sn phm kh
duy nht ). Tnh a. ?
A.10,16
B.16,51
C.11,43
D.15,24
Cu 13 : Ha tan hon ton 13,92 gam hn hp X gm MgO, FeO v Fe 2O3 phi dng va ht 520 ml dung dch HCl
1M. Mt khc , khi ly 0,27 mol hn hp X t nng trong ng s khng c khng kh ri thi mt lung H 2 d i qua
phn ng xy ra hon ton th thu c m gam cht rn v 4,86 gam nc. Xc nh m?
A.16,56
B.20,88
C.25,06
D.16,02
Cu 14: Hn hp A gm CuSO4 , FeSO4 v Fe2(SO4)3 , trong % khi lng ca S l 22% . Ly 50 gam hn hp A ho
tan vo trong nc. Thm dung dch NaOH d , ly kt ta thu c em nung ngoi khng kh n khi lng khng i
. Lng oxit sinh ra em kh hon ton bng CO th lng Fe v Cu thu c bng :
A.17 gam
B.18 gam
C.19 gam
D.20 gam
Cu 15 : A l hn hp cc mui Cu(NO 3)2 , Fe(NO3)2 v Fe(NO3)3. Trong N chim 16,03% v khi lng. Cho dung
dch KOH d vo dung dch cha 65,5 gam mui A . Lc kt ta thu c em nung trong khng kh n khi lng
khng i thu c bao nhiu gam oxit ?
A.27
B.34
C.25
D.31
Cu 16: Ha tan ht mt hn hp X gm 0,02 mol Fe : 0,04 mol Fe 3O4 v 0,03 mol CuO bng dung dch HCl d.Cho t
t dung dch NH3 n d vo dung dch sau phn ng, lc kt ta em nung trong khng kh n khi lng khng i
thu c a gam cht rn. a nhn gi tr ?
A.12,8
B.11,2
C.10,4
D.13,6

Cu 17.Ha tan hn hp gm st v 1 oxit ca st cn va 0,1 mol H 2SO4 c ; thot ra 0,224 lt SO 2 ( ktc). C cn

dung dch sau phn ng thu c bao nhiu gam mui khan ?
A.8
B.12
C.16
D.20
Cu 18: Cho m gam Fe tan va trong dung dch hn hp HCl v FeCl 3 thu c dung dch X ch cha mt mui duy
nht v 5,6 lt H2 ( ktc ). C cn dung dch X thu c 85,09 gam mui khan. m nhn gi tr no ?
A.14
B.20,16
C.21,84
D.23,52
Cu 19: Cho dung dch acid nitric long vo mt cc thy tinh c ng 5,6 gam Fe v 9,6 gam Cu. Khuy u phn
ng xy ra hon ton ; c 3,136 lt NO thot ra ( ktc ) v cn li m gam cht rn khng tan. Gi tr ca m bng :
A.2,56
B.1,92
C.4,48
D.5,76
Cu 20: Ha tan hon ton 5,4 gam mt oxit st vo dung dch HNO 3 d thu c 1,456 lt hn hp NO v NO2 ( ktc ngoi ra khng cn sn phm kh no khc ). Sau phn ng khi lng dung dch tng ln 2,49 gam so vi ban u. Cng
thc ca oxit st v s mol HNO3 phn ng l :
A.FeO v 0,74 mol
B.Fe3O4 v 0,29 mol
C.FeO v 0,29 mol
D.Fe3O4 v 0,75 mol
Cu 21: Ha tan 10 gam hn hp gm Fe v Fe xOy bng HCl thu c 1,12 lt H 2 ( ktc ). Cng lng hn hp ny nu
ha tan ht bng dung dch HNO3 c nng thu c 5,6 lt NO2 ( ktc ). Xc nh FexOy ?
A.FeO
B.Fe2O3
C.Fe3O4
D.Khng xc nh c
Cu 22: Cho m gam hn hp X gm Al ,Fe3O4 , FeO, Fe2O3 tc dng vi dung dch HCl d thu c dung dch Y, trong
khi lng ca FeCl2 l 31,75 gam v 8,064 lt H 2 ( ktc ).C cn dung dch Y thu c 151,54 gam cht rn khan.
Nu cho m gam hn hp X tc dng vi dung dch HNO 3 long d thu c dung dch Z v kh NO ( sn phm kh duy
nht ). C cn dung dch Z thu c bao nhiu gam mui khan ?
A.242,3
B.268,4
C.189,6
D.254,9
Cu 23: Nung 23,2 gam hn hp X ( FeCO3 v FexOy ) ti phn ng hon ton thu c kh A v 22,4 gam Fe2O3 duy
nht. Cho kh A hp th hon ton vo dung dch Ba(OH) 2 d thu c 7,88 gam kt ta. Mt khc , ha tan ht 23,2
gam X cn va V ml dung dch HCl 2M. CT FexOy v gi tr ca V l :
A.FeO v 200
B.Fe3O4 v 250
C.FeO v 250
D.Fe3O4 v 360
Cu 24: Ha tan hon ton mt hn hp gm FeO, Fe 2O3 v Fe3O4 ( trong t l khi lng ca FeO v Fe 2O3 bng 9:20
) bng dung dch HCl , thu c 16,25 gam FeCl3. Khi lng mui FeCl2 thu c sau phn ng bng :
A.5,08 gam
B.6,35 gam
C.7,62 gam
D.12,7 gam
Cu 25: Cho ln lt 23,2 gam Fe 3O4 v 8,4 gam Fe vo dung dch HCl 1M. Th tch dung dch HCl ti thiu ha tan
cc cht rn trn l :
A.0,9 lt
B.1,1 lt
C.0,8 lt
D.1,5 lt
Cu 26: Cho lung kh CO i qua mt lng qung hematit ( cha Fe 2O3 ) th thu c 300,8 gam hn hp cc cht rn X
v thot ra hn hp kh Y. Cho hp th ton b kh Y bng dung dch NaOH d thy khi lng bnh NaOH tng thm
52,8 gam. em cht rn X ha tan trong dung dch HNO 3 d thu c 387,2 gam mui. Thnh phn % khi lng ca
Fe2O3 trong qung l :
A.80%
B.60%
C.50%
D.40%
Cu 27: Cho 0,24 mol FeO v 0,03 mol Fe3O4 vo dung dch HNO3 long , kt thc phn ng thu c dung dch X v
3,36 gam kim loi d. Khi lng mui c trong dung dch X l :
A.48,6 gam
B.58,08 gam
C.56,97 gam
D.65,34 gam
Cu 28: em nhhit phn hon ton a mol Fe(NO 3)2 thu c hn hp kh X c t khi so vi H 2 bng T1. Nhit phn
hon ton a mol Fe(NO3)3 thu c hn hp kh Y c t khi so vi H2 bng T2. Biu thc no di y l ng :
A.T1 = 0,972T2
B.T1 = T2
C.T2 = 0,972T1
D.T2 = 1,08T1
Cu 29: Hn hp A gm st v 2 oxit ca n. Cho m gam A tc dng vi dung dch H 2SO4 c nng d n phn ng
hon ton thu c dung dch Y v thot ra 2,24 lt SO 2 ( ktc ). Cho dung dch NaOH d vo Y thu c kt ta Z. Nung
Z ti khi lng khng i th thy khi lng gim 7,02 gam. Gi tr ca m gam l :
A.11,2
B.19,2
C.14,4
D.16,0
Cu 30: Ha tan hon ton a gam hn hp X gm Fe , FeS , FeS 2 v S vo dung dch HNO3 long d , gii phng 8,064
lt NO ( l sn phm kh duy nht tkc ) v dung dch Y. Cho dung dch Ba(OH)2 d vo dung dch Y thu c kt ta
Z. Ha tan ht lng kt ta Z bng dung dch HCl d , sau phn ng cn li 30,29 gam cht rn khng tan . Gi tr ca a
gam l :
A.7,92
B.9,76
C.8,64
D.9,52
Cu 31:Ha tan ht m gam hn hp gm x mol FeO , x mol Fe 2O3 v y mol Fe3O4 bng dung dch HNO3 c nng thu
c 6,72 lt NO2 ( ktc ). Gi tr ca m gam l :
A.46,4
B.48,0
C.35,7
D.69.6
Cu 32: Ha tan ht 7,52 gam hn hp A gm Cu v 1 oxit ca st bng dung dch HNO 3 long d , sau phn ng gii
phng 0,1493 lt NO ( ktc - l sn phm kh duy nht ) v cn li 0,96 gam kim loi khng tan. C cn dung dch sau
phn ng thu c 16,44 gam cht rn khan. Cng thc ca oxit st l :
A.FeO
B.Fe2O3
C.Fe3O4
D.FeOv Fe2O3
Cu 33: Thi hn hp kh CO v H2 i qua a gam hn hp gm CuO v Fe3O4 c t l mol 1:2 , sau phn ng thu c b
gam cht rn A. Ha tan hon ton b gam A bng dung dch HNO 3 long d , thu c dung dch X ( khng cha ion
Fe2+ ). C cn dung dch X thu c 41 gam mui khan. a gam nhn gi tr no ?
A.9,8
B.10,6
C.12,8
D.13,6

p n bi tp TN v st :
1A - 2A - 3D - 4B - 5C - 6A - 7D - 8B - 9A - 10C - 11D - 12B - 13A - 14A - 15C - 16B - 17B - 18C - 19A
20C - 21A - 22A - 23D - 24B - 25A - 26D - 27A - 28C - 29B - 30B - 31D - 32C - 33D
P N CHI TIT :
Cu 1: nkh = nH2 = 0,672/22,4= 0,03 mol .
Ta c : nH+(HCl)= nH+(ho tan oxit ) + nH+(kh ) => 0,3 = nH+(ho tan oxit ) + 2.0,03 => nH+(ho tan oxit ) = 0,24 mol
nO(oxit) = nH+(ho tan oxit ) = 0,12 mol => m = mX mO(oxit) = 12 0,12.16 = 10,08 gam
Cu 2: Quy i hn hp thnh 2,8 gam ( FeO : x mol v Fe2O3 : y mol ) -------> 3 gam Fe2O3
Thit lp h : 72x + 160y = 2,8 v x + 2y = 3.2/160 ( BTNT Fe trong Fe2O3 )
= > x = 0,025 mol v y = 6,25.10-3 mol
FeO + 2HCl FeCl2 + H2O
Fe2O3 + 6HCl 2FeCl3 + 3 H2O
0,025 0,05
6,25.10-3 0,0375
=> Tng s mol HCl p/ = 0,0875 mol => V = 0,0875 l = 87,5 ml
Cch kh c : ( Cch gii ca bn Hunh Anh T )Quy i thnh 2,8 gam ( Fe : x mol v O : y mol )
S hp thc : 2Fe Fe2O3
Ta c : nFe = 2nFe2O3 = 2.3/160 = 0,0375 mol
=> nO (oxit) = ( 2,8 0,0375.56 ) / 16 = 0,04375 mol => nHCl p/u = 2 nO (oxit) = 0,0875 mol =>V = 87,5 ml
Cu 3: Phn ng nhit nhm khng hon ton nn ta khng th xc nh c r sn phm Y gm nhng cht
quy i hn hp Y thnh X ( theo nguyn BTKL )
Ta c : Al Al3+ +3e
N+5 +3e NO
=> m = 0,02( 27 + 160) = 3,74 gam
0,02 0,06
0,06 0,02
Cu 4: Ta c : nCl- = 0,26 mol => nO2- (oxit ) = nCl- = 0,13 mol ( BT T ) => mFe = 7,68 0,13.16 = 5,6 gam
S hp thc : 2Fe Fe2O3
=> mFe2O3 = 160.5,6/112 = 8 gam.
Cu 5: Quy i 15,12 gam X thnh : Fe ;
FeO v Fe2O3
( x mol ) ( y mol )
Ho tan vo dd HCl ta c pt : x + y = 16,51/127 = 0,13 mol.
Cho X vo HNO3 d :
Fe Fe3+ + 3e
N+5 + 3e NO
x
3x
0,21 0,07
3+
FeO Fe + 1e
y
y
=> Bo ton electron: 3x + y = 0,21
Gii h = > x = 0,04 mol v y = 0,09 mol = > % m Fe = 0,04.56/15,12 . 100% = 14,81%
Cu 6: 2 mui khan y l CuCl2 v FeCl2 . Ta c : nO2- (oxit ) = nCl- = .0,6 = 0,3 mol ( BT T )
BTKL : mCu & Fe = mmuoi mCl- = 38,74 0,6.35,5 = 17,44 gam
mX = mCu & Fe + mO2- (oxit ) = 17,44 +0,3.16 = 22,24 gam
Cu 7: Quy i thnh a gam FeO v Fe2O3
S hp thc : Fe2O3 2FeCl3 ( 0,06 mol ) v FeO FeCl2 ( 0,07 mol )
=> a = 0,03.160 + 0,07.72 = 9,84 gam
Cu 8: nFe = nFeCl3 = 0,06 mol => nO (oxit ) = ( 4 0,06.56)/16 = 0,04 mol
Quy i 4 gam A thnh Fe v O. Cho tc dng vi HNO 3 :
Fe Fe3+ + 3e
O + 2e O20,06
0,18
0,08 0,04
+5
N + 3e NO
=> V = 0,1/3.22,4 = 0,747 lit
0,1 0,1/3
Cu 9: 51,76 gam gm 2 mui F eSO4 : x mol v Fe2(SO4)3 : y mol.
Lp h : 152x + 400y = 51,76 v x + 2y = 58.2/400 (BTNT Fe trong Fe2(SO4)3 )
=> x = 0,13 mol v y = 0,08 mol => S mol H2SO4 p/ = x +3y = 0,37 mol
=> mdung dich = ( 0,37.98.100) / 9,8 gam = 370 gam = b
Cu 10: nFe = nFeCl2 = 0,12 mol v nO (oxit ) = nH+ = 0,16 mol => nFe : nO = 0,12 : 0,16 = 3:4 => Fe3O4
BTNT Cl: nHCl = 2nFeCl2 + 2nCuCl2 => 0,32 = 2.0,12 + 2nCuCl2 => nCuCl2 = 0,04 mol = nCu

no. Ta

 m = mCu + mFe + mO = 0,04.64 + 0,12.56 + 0,16.16 = 11,84 gam

Cu 11: nCl- = 0,26 mol => mCu&Fe = mmuoi - mCl- = 16,67 0,26.35,5 = 7,44 gam
nO2- (oxit ) = nCl- = 0,13 mol => mY = mCu&Fe + mO2- (oxit ) = 7,44 +0,13.16 = 9,52 gam
Cu 12: Phn II : BTNT N : nNO3- ( muoi ) = nHNO3 p/u nNO = 0,875.0,8 1,568/22,4 = 0,63 mol
Fe Fe(NO3)3 3NO3Phn I : BTNT Fe : nFe = nFeCl2 + nFeCl3
0,21
0,63
=> nFeCl2 = 0,21 13/162,5 = 0,13 mol => a = 0,13.127 = 16,51 gam
Cu 13: 13,92 gam X ( MgO x mol ; FeO y mol v Fe2O3 z mol ). Ta c : nO (oxit ) = nH+ = .0,52 = 0,26 mol
=> x + y +3z = 0,26 ( 1 ) v 40x + 72y + 160z = 13,92 ( 2 )
Trong 0,27 mol X s mol MgO , FeO v Fe2O3 ln lt l kx , ky v kz mol => kx + ky + kz = 0,27 ( 3 )
V : nH2O = nH2 = nO(FeO) + nO(Fe2O3) = ky +3kz = 0,27 ( 4 ). Bi n i ( 3 ) & ( 4 ) => x = 2z ( 5 )
Gii ( 1) , (2) v ( 5) => x = 0,08 mol ; y = 0,06 mol v z = 0,04 mol => k = 0,27/0,18 = 1,5
BTKL : m = 1,5.13,92 0,27.16 = 16,56 gam
Cu 14: mS = 50.22/100 = 11 gam => nSO4 (2-) = nS = 11/32 = 0,34375 mol (BTNT S )
mCu&Fe = mmuoi mSO4(2-) = 50 96.0,34375 = 17 gam
Cu 15: mN = 65,5.16,03/100 = 10,5 gam => nNO3- = nN = 10,5/14 = 0,75 mol ( BTNT N )
S : 2NO3 ( mui ) < = > O2- (oxit )
2 mol NO3 to 1 mol O2- khi lng gim 2.62 16 = 108 gam
0,75 mol NO3 to 0,375 mol O2- khi lng gim 108.0,375 = 40,5 gam
=> moxit = mmuoi - mgiam = 65,5 40,5 = 25 gam
Cu 16: Cu2+ to phc trong dd amoniac d => cht rn sau cng l Fe 2O3 .
BTNT Fe : nFe = nFe + 3nFe3O4 = 0,02 + 0,04.3 = 0,14 mol
=> nFe2O3 = nFe = 0,07 mol => a = 0,07.160 = 11,2 gam
Cu 17: BTNT S : nH2SO4 p/u = nSO4 (2-) muoi + nSO2 => nSO4 (2-) muoi = 0,1 0,01 = 0,09 mol
Fe2(SO4)3 3SO42- => mmuoi = 0,03.400 = 12 gam
0,03
0,09
Cu 18: C ch 1 : Vit PTHH : nFeCl2 = 0,67 mol
Fe + 2HCl FeCl2 + H2 (1)
Fe + 2FeCl3 3FeCl2 ( 2 )
0,25
0,25 0,25
0,14
( 0,67 0,25 = 0,42 )
=> nFe = 0,25 + 0,14 = 0,39 mol => m = 0,39.56 = 21,84 gam
Cch 2: Bo ton electron
Fe Fe2+ + 2e
2H+ + 2e H2
x
x 2x
0,5 0,25
Fe 3+ + 1e Fe2+
0,67 - x 0,67 - x
=> Bo ton electron: 2x = 0,5 + 0,67 x
=> x = 0,39 mol => m = 21,84 gam
Cu 19: Sau phn ng , Cu cn d ( Fe Fe2+ )
Fe Fe2+ + 2e
N+5 + 3e NO
0,1
0,2
0,42 0,14
Cu Cu2+ + 2e
0,11
0,22
=> m = 9,6 0,11.64 = 2,56 gam
Cu 20: mkh = 5,4 2,49 = 2,91 gam ( NO x mol v NO2 y mol ).
Lp h : x + y = 1,456/22,4 = 0,065 mol v 30x + 46y = 2,91 => x = 5.10-3 mol v y = 0,06 mol
Quy i oxit st thnh Fe ( a mol ) v O ( b mol ) .Ta c : 56a + 16b = 5,4
Fe Fe3+ + 3e
O + 2e O2N+5 + 3e NO
N+5 + 1e NO2
-3
a
3a
b 2b
0,015 5.10
0,06 0,06
Bo ton e: 3a 2b = 0,06 + 0,015. Gii h 2 pt trn : a = b = 0,075 mol = > FeO
BTNT N : nHNO3 p/u = nNO3- muoi + nNO + nNO2 = 3nFeO + nNO + nNO2 = 0,29 mol
Cu 21: nFe = nH2 = 0,05 mol ( Fe n cht - khng phi Fe trong oxit ).
Cho vo HNO3 , quy i 10 gam ( Fe a mol v O b mol ). => 56a + 16b = 10. Bo ton electron :

Fe Fe3+ + 3e
O + 2e O2N+5 + 1e NO2
=> 3a 2b = 0,25
a
3a
b 2b
0,25 0,25
Gii h => a = 0,15 mol = nFe v b = 0,1 mol = nO(oxit) => nFe(oxit) = nFe - nFe = 0,15 0,05 = 0,1 mol => FeO
Cu 22: nAl = 2/3 nH2 = 0,24 mol = nAl(NO3)3 = > mAlCl3 = 0,24.133,5 = 32,04 gam
=> mFeCl3 = mrn han mFeCl2 mAlCl3 = 151,54 31,75 32,04 = 87,75 gam => nFeCl3 = 0,54 mol
Cho hn hp vo HNO3 long d to 2 mui Fe(NO3)3 v Al(NO3)3 . BTNT Al v Fe ta c :
nAl(NO3)3 = nAl = 0,24 mol v nFe(NO3)3 = nFeCl2 + nFeCl3 = 31,75/127 + 0,54 = 0,79 mol
=> mmui = 0,24.213 + 0,79.242 = 242,3 gam
Cu 23: nFeCO3 = nCO2 = nBaCO3 = 7,88/197 = 0,04 mol. BTNT Fe : nFe = 2nFe2O3 = 0,28 mol
=> nFe(oxit) = 0,28 0,04 = 0,24 mol => moxit = mX mFeCO3 = 23,2 0,04.16 = 18,56 gam
=> nO (oxit ) = ( 18,56 0,24.56 ) / 16 = 0,32 mol => Fe3O4 .
BTT : nHCl = nH+ = 2nCO3(2-) + 2 nO (oxit ) = 2.0,04 + 2.0,32 = 0,72 mol => V = 0,72/2 = 0,36 lit = 36O ml
Cu 24: mFeO / mFe2O3 = 9/20 => nFeO = nFe2O3 => nFeCl2 = nFeCl3 = 0,05 mol => mFeCl2 = 0,05.127 = 6,35 gam
Cu 25: PTHH: Fe3O4 + 8HCl FeCl2 + 2FeCl3 + 4H2O
Fe + 2FeCl3 3FeCl2 Fe + 2HCl FeCl2 + H2
0,1 0,8
0,2
0,1 0,2
0,05 0,1
=> nHCl = 0,8 + 0,1 = 0,9 mol => V = 0,9 lit
Cu 26: mtng = mCO2 = 52,8 gam => nO ( b kh ) = nCO2 = 1,2 mol
=> Khi lng ca qung = mX + mO = 300,8 +1,2.16 = 320 gam .BTNT Fe : nFe2O3 = nFe(NO3)3 = 0,8 mol
=> % mFe2O3 = 0,8.160/320.100% = 40%
Cu 27: BTNT Fe : nFeO + 3nFe3O4 = nFe(NO3)2 + nFe d => nFe(NO3)2 = 0,27.180 = 48,6 gam
Cu 28: Fe(NO3)2 Fe2O3 + 4NO2 + O2
2Fe(NO3)3 Fe2O3 + 6NO2 + 3/2 O2
a
2a
0,25a
a
3a
0,75a
T1 = ( 46.2a + 32.0,25a ) / ( 2a + 0,25a ) = 400/9
T2 = ( 46.3a + 32.0,75a ) / ( 3a + 0,75a ) = 43,2
=> T2 / T1 = 0,972 = > T2 = 0,972T1
Cu 29: Fe(OH)3 Fe2O3
107
80

=> nFe2O3 = 7,02/ ( 107 80 ) = 0,26 mol = nFe

=> mFe = 0,7mA + 5,6ne = 0,7mA + 5,6.2nSO2 => mA = 19,2 gam

Cu 30: mrn = mBaSO4 = 30,29 gam => nS(X) = nBaSO4 = 0,13 mol. Quy i hn hp thnh Fe v S
Fe Fe3+ + 3e
S S+6 + 6e
N+5 + 3e NO
0,1
0,3
0,13
0,78
1,08 0,36
=> a = mFe + mS = 9,76 gam
Cu 31: FeO v Fe2O3 c cng s mol => quy i thnh Fe3O4 .Nhm : nFe3O4 = nNO2 = 0,3 mol
=> m = 0,3.232 = 69,6 gam
Cu 32: Cn li kim loi Cu khng tan => ion Fe tn ti trong dung dch sau phn ng l Fe 2+.
Quy i hn hp A thnh Cu, Fe v O
Cu Cu2+ + 2e
Fe Fe2+ + 2e
O + 2e O2N+5 + 3e NO
x
2x
y
2y
z 2z
0,02
Bo ton e : 2x + 2y 2z = 0,02 .Ta c : 64x + 56y +16z = 7,52 0,96 v 188x + 180y = 16,44 (cht rn khan )
Gii h ta c : x = 0,03 ; y = 0,06 v z = 0,08 => nFe : nO = y : z = => Fe3O4
Cu 33: CuO Cu(NO3)2
Fe3O4 3Fe(NO3)3
x
2x
2x
6x
Ta c : mmuoi = 188x + 6x.242 = 41 = > x = 0,025 mol => a = 80.0,025 + 23.0,05 = 13,6 gam