thi hc sinh gii c gii

Bi 1:
1. Vit cc phng trnh phn ng hn thnh s sau:
H2S
S
SO2
KHSO3 K2SO3 K2SO4 KOH KClO3 Cl2 CaOCl2.
2. Trnh by phng php h hc nhn bit cc kh cha trong cc l mt nhn sau:
CO2, SO2, H2S, N2
Bi 2: Cc kh A, B, C ln lt c iu ch bng cch cho dung dch axit clohidric tc dng vi cc cht rn:
Natri sunfit, st (II) sunfua, kalipemanganat.
1. Vit cc phng trnh phn ng iu ch A, B, C?
2. Tin hnh cc th nghim sau:
a) Sc kh A vo dung dch kh B.
b) Sc kh C ln lt vo cc dung dch kh A, B.
c) Cho ln lt cc kh A, B tc dng vi kh O2 d.
d) Cho ln lt cc kh A, B, C tc dng vi dung dch KOH d.
Vit cc phng trnh phn ng trong cc th nghim trn v ghi r iu kin nu c.
Bi 3: Cho 31,84 gam hn hp NaX, NaY (X, Y l hai Halogen 2 chu k lin tip) vo dung dch AgNO3 d thu
c 57,34 gam kt ta.
Tm cng thc ca NaX, NaY v tnh khi lng mi mui.
Bi 4: Cho 3,16 gam KMnO4 tc dng ht vi axit clohidric c. Kh thu c sau phn ng c dn vo 200ml
dung dch NaOH 1M.
Tnh nng mol/l ca cc cht thu c sau phn ng (bit cc phn ng xy ra hn tn, th tch dung dch thay
i khng ng k).
Bi 5: H tan ht 5,1 gam hn hp gm Mg v Al bng mt lng va 250 ml dung dch HCl thu c dung dch
A. C cn dung dch A c 22,85 gam mui khan.
1.Tnh nng mol/l ca dung dch HCl.
2.Cho 500 ml dung dch NaOH 2 M vo dung dch A thu c dung dch B v kt ta C. Khi lng kt ta C.
Bi 6: Dung dch A cha NaOH 1M v Ca(OH)2 0,1M. Sc V lt kh CO2 (ktc) vo 400ml dung dch A, ta thu c
mt lng kt ta c khi lng l 3 (gam). Tnh V?
Bi 7: Ha tan 0,88g hn hp A gm mt kim loi M thuc nhm II.A v oxit ca M vo dung dch HCl va , thu
c 200ml dung dch B cha 2,22g mui.
Xc nh kim loi M, bit rng tng s ht c bn trong nguyn t M ln hn 40.
Bi 8: Cho Fe phn ng va ht vi H2SO4 thu c kh A v 8,28 gam mui.
a) Tnh khi lng ca st phn ng bit rng s mol Fe bng 37,5% s mol H2SO4.
b) Cho lng kh A thu c trn tc dng vi 100ml dung dch NaOH 1M thu c dung dch B. Tnh nng mol/l cc
cht trong B (bit th tch dung dch B l 100ml).
...................................Ht.....................................
(Cn b coi thi khng gii thch g thm)

S GD & T VNH PHC

HNG DN CHM

Bi
Bi 1
(1,5)

Ni Dung
1. vit ng v cc phng trnh 1 im
2. (0,5 )
- Dng t giy tm dung dch Pb(NO3)2 nhn ra kh H2S
- Dng dung dch Br2 nhn ra kh SO2
- Dng nc vi trong nhn ra kh CO2
- Kh cn li l N2

Bi 2
(1,5)

1. kh A l SO2, kh B l H2S, kh C l Cl2 (Vit cc ptpt)

2. a) Sc kh A vo dung dch kh B
SO2 + 2H2S 3S + 2H2O
b) Sc kh C vo dung dch kh A v B
SO2 + Cl2 + 2H2O H2SO4 + 2HCl
H2S + 4Cl2 + 4H2O H2SO4 + 8HCl
c) Cho A v B tc dng vi O2 d
2SO2 + O2 2SO3
2H2S + O2 2SO2 + 2H2O
d) Cho cc kh A, B, C tc dng vi dung dch KOH d
SO2+2KOH K2SO3 + H2O
H2S + 2KOH K2S + 2H2O
Cl2 + 2KOH KCl + KClO + H2O

Bi 3
(1)

t nNaX = x (mol), nNaY = y (mol)

Trng hp 1: X l F, Y l Cl

im

0.5
0,25
0,25
0,25
0,25

0,5

Khi ch c phn ng : NaCl + AgNO3 NaNO3+ AgCl

42.x 58,5. y 31,84
x 0, 2549

tha mn
y 0,3613
y 0,3613

Theo bi ra ta c :

Trng hp 2: t cng thc chung ca 2 mui l NaR

Ta c phn ng: NaR + AgNO3 NaNO3+ AgR
Theo bi ra ta c:

31,84
57,34

M R 83,13 vy X l Br v Y l I
23 M R 108 M R

Vy cng thc ca hai mui l NaBr v NaI, t tm khi lng ca mi mui

Bi 4
(1)

Ptp: 2KMnO4 + 16HCl 2KCl + 2MnCl2+ 5Cl2 + 8H2O

S mol Cl2: 0,02.5/2 = 0,05 (mol).
Cl2
+ 2NaOH NaCl
+ NaClO
+ H2O
0,05
0,1
0,05
0,05
Dung dch sau phn ng: NaCl: 0,025M
NaClO: 0,025M
NaOH: 0,5M

Bi 5
(1)

t s mol ca Mg v Al ln lt l x v y.
Cc phng trnh phn ng:
Mg + 2HCl MgCl2 + H2
Al + 3HCl AlCl3 + 3/2 H2

0,5

 24.x 27. y 5,1

x 0,1( mol )

95.x 133,5. y 22,85 y 0,1(mol )

0, 2 0,3
CMHCl
2M
0, 25
b) Khi cho dung dch NaOH vo dung dch A c cc phn ng
AlCl3 + 3NaOH Al(OH)3 + 3NaCl
MgCl2 + 2NaOH Mg(OH)2 + 2NaCl
Al(OH)3 + NaOH NaAlO2 + 2H2O
D thy NaOH d nn kt ta thu c l Mg(OH)2 mMg (OH )2 0,1.58 5,8( g )
Theo bi ra:

Bi 6
(1)

Th t cc phn ng:
Ca(OH)2 + CO2 CaCO3 + H2O (1)
2NaOH + CO2 Na2CO3 + H2O (2)
Na2CO3 + CO2 + H2O 2NaHCO3 (3)
CaCO3 + CO2 + H2O Ca(HCO3)2 (4)
n
V CaCO3 0, 03mol nCa (OH )2 0, 04mol Xy ra 2 trng hp:
TH1 : Ca(OH)2d khi ch c phn ng 1 V = 0,672 (lt)
TH2: d CO2 mt phn kt ta b ha tan, khi xy ra 4 phn ng
V = (0,4 + 0,03 +0,020).22,4 = 10,08 (lt)

Bi 7
(1)

Dng phng php khi lng mol trung bnh

M + 2HCl MCl2 + H2
MO + 2HCl MCl2 + H2O
0,88
2, 22
0,88

Ta c : nhh nM nMO nMCl2

20,12 <M < 46,6
M 16 M 71 M
V M thuc nhm IIA v c tng s ht ln hn 40 nn M l Ca

Bi 8
(2)

a) Nu A l kh H2: Fe + H2SO4 FeSO4 + H2 (loi v khng tha mn u bi).

Vy A l kh SO2 (khng th l H2S v Fe l kim loi trung bnh)
Cc phng trnh phn ng:
2Fe + 6H2SO4 Fe2(SO4)3 + 3SO2 + 6H2O(1)
C th: Fe + Fe2(SO4)3 3FeSO4
(2)
Gi s mol Fe tham gia phn ng (1) v (2) ln lt l x v y
x y
.100 37,5
x 0, 04

Theo bi ra ta c: 3 x
(0,5 x y ).400 3 y.152 8, 28 y 0, 005
mFe = 0,045.56 =2,52 (gam)
b) nSO2 0,06 mol
Phn ng to hn hp hai mui

* Ch : khi chm nu hc sinh gii theo cc phng php khc, nu ng vn cho s im.

dnh cho hc sinh kh gii

(1 )

(1 )

Cu 1: Dy gm cc cht u tc dng c vi dung dch HCl lng l:

A. Mg(HCO3)2, HCOONa, PbS.
B. AgNO3, (NH4)2CO3, CuS.
C. KNO3, CaCO3, Fe(OH)3.
D. FeS, Sn, KOH.
Cu 2: H tan hn tn m gam FexOy bng dung dch H2SO4 c, nng sinh ra kh A v dung dch B. Cho kh A hp
th hn tn bi dung dch NaOH d to ra 12,6 g mui. Mt khc, c cn dung dch B thu c 120 g mui khan. CT
ca oxit st FexOy l
A. Fe2O3
B. FeO
C. Fe3O4
D. FeO2
Cu 3: H tan ht 12,00 gam hn hp kim loi A gm Fe v kim loi R h tr (II) khng i vo 200,00 ml dung
dch HCl 3,50 M thu c 6,72 lt kh (ktc) v dung dch B. Mt khc nu cho 3,6 gam kim loi R tan ht vo 400
ml dung dch H2SO4 1,00M th axit cn d. Kim loi R l
A. Ca
B. Be
C. Mg
D. Zn
Cu 4: Trong phn ng tng hp amoniac: N 2 (k) + 3H2 (k) 2NH3 (k) H < 0. tng hiu sut phn ng tng hp
phi:
A. Gim nhit v p sut
B. Tng nhit v gim p sut
C. Gim nhit va phi v tng p sut
D. Tng nhit v p sut
Cu 5: Cho phn ng sau:
(1)

N2O4
(kho
ng ma
u)

(2)

2NO2
(ma
u na
u o
)

Phn ng s bin i th no khi tng p sut?

A. chuyn dch theo chiu (2)
B. Kh t khng mu sang mu nu
C. khng chuyn dch
D. chuyn dch theo chiu (1)
Cu 6: Cho cc mui sau : natri florua (1), natri clorua (2), natri bromua (3), natri iotua(4). Mun iu ch cc
hiro halogenua ta c th dung mui no trong cc mui trn cho tc dng vi H2SO4 c
A. (1) v (3)
B. (3) v (4)
C. (1) v (2)
D. (2) v (3)
Cu 7: Ngi ta s dng nhit ca phn ng t chy than nung vi:
CaCO3

t0C

CaO + CO2

H>0.
Bin php k thut no sau y khng c s dng tng tc phn ng nung vi?
A. Thi khng kh nn vo l nung vi
B. p nh vi vi kch thc thch hp
C. Tng nhit phn ng cng cao cng tt D. Duy tr nhit phn ng thch hp
Cu 8: Cho phn ng sau trng thi cn bng: 2HI (k) H2 (k) + I2 (k). Hng s cn bng nhit ang xt l K=
15,625.10-3. Phn trm HI b phn hy nhit trn l
A. 18%
B. 15%
C. 10%
D. 20%
Cu 9: Hp th hn tn 6,72 l kh H2S (ktc) vo dung dch cha 16g NaOH. Tin hnh c cn dung dch thu c
lng mui khan l
A. 18,9 gam
B. 20,8 gam
C. 21,2 gam
D. 12,1 gam
Cu 10: Cho 1,26 gam hn hp (Mg, Al) c t l s mol tng ng l 3:2 tc dng vi dung dch axit sunfuric c,
va to ra 0,015 mol sn phm kh c lu hunh duy nht.Sn phm kh l
A. H2S
B. S
C. SO2
D. SO3
Cu 11: Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng (d), tht ra 0,112 lt ( ktc ) kh
SO2 ( l cht kh duy nht ng thi l sn phm kh duy nht). Cng thc ca hp cht st l
A. FeS2.
B. FeO
C. FeS.
D. FeCO3.
Cu 12: Nn 2 mol N2 v 8 mol H2 vo mt bnh kn c dung tch 2 lit ( c cha sn xc tc vi th tch khng ng
k) c gi nhit khng i. Khi phn ng trong bnh t trng thi cn bng, p sut kh trong bnh bng 0,8
p sut ban u.Hng s cn bng ca phn ng nhit trn l
A. 0,136
B. 0,216
C. 0,128
D. 0,218
Cu 13: H tan 3,38g oleum X vo nc ngi ta phi dng 800ml dd KOH 0,1M trung h dd X. Cng thc phn
t oleum X l
A. H2SO4.nSO3
B. H2SO4.2SO3
C. H2SO4.4SO3
D. H2SO4.3SO3

Cu 14: H tan hn tn 3,22 g hn hp X ( Fe, Mg v Zn ) bng mt lng va dung dch H 2SO4 to ra 1,344 lit
H2 ( ktc) v dung dch Y cha m (g) mui. Gi tr ca m l
A. 8,98
B.7,25
C.3,55
D. 5,67
Cu 15: Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hn tn vi oxi thu c hn
hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn ng ht vi Y l
A. 90 ml.
B. 75 ml.
C. 50 ml.
D. 57ml.
Cu 16: Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl
c, cht to ra lng kh Cl2 nhiu nht l
A. MnO2.
B. CaOCl2.
C. KMnO4.
D. K2Cr2O7.
Cu 17: H tan cht X bng dung dch H 2SO4 c nng, va gii phng SO 2. Nu t l mol ca axit v SO 2 l 2: 3
th X l cht no sau y
A. FeS2
B. H2S
C. S
D. FeS
Cu 18: Xt phn ng thun nghch sau: 2 SO2(k) + O2(k) 2 SO3 (k)
Tc phn ng thun thay i nh th no nu th tch bnh cha tng gp i ?
A. khng i
B. Gim 1/2
C. gim 1/8
D. gim 1/4
Cu 19: Cho 12,8g Cu tc dng vi H2SO4 c nng d, kh sinh ra cho vo 200ml dung dch NaOH 2M. Cng thc
mui c to thnh v khi lng l
A. Na2SO3 ; 24,2g
B. NaHSO3 ;15g v Na2SO3 ; 26,2g
C. NaHSO3 ; 23,2g
D. Na2SO3 ; 25,2g
Cu 20: C 4 l kh khng mu mt nhn gm: O 2, CO2, O3, HCl. Phng php ha hc no sau y nhn bit
c cc kh
A. dd KI c h tinh bt v dd KOH
B. Giy qu tm m, dd nc vi trong, dd KI c h tinh bt
C. dd nc vi trong v qu tm m
D. Giy qu tm m v dd AgNO3
Cu 21: Th tch dung dch NaOH 2M ti thiu hp th ht 5,6 lit kh SO2 (ktc) l
A. 125ml
B. 215ml
C. 500ml
D. 250 ml
Cu 22: Cng mt lng R khi ln lt h tan ht bng dung dch HCl v H 2SO4 c nng th khi lng SO 2 sinh
ra gp 48 ln H2. Mt khc khi lng mui clorua bng 63,5% khi lng mui sunfat. Kim loi R l
A. Mg
B. Al
C. Zn
D. Fe
Cu 23: Dn 2,688 lit hn hp gm O2 v O3 (ktc) vo dung dch KI d thu c 20,32 gam mt cht mu tm
en.Thnh phn phn trm theo th tch ca mi kh trong hn u ln lt l
A. 30% v 70%
B. 33,33% v 66,67% C. 46,33% v 53,67% D. 40% v 60%
Cu 24: t chy hn tn 125,6g hn hp FeS2 v ZnS thu c 102,4g SO2. Khi lng ca 2 cht trn ln lt l:
A. 78,6g v 47g
B. 10g v 115,6g
C. 76,6g v 47g
D. 77,6g v 48g
Cu 25: Bc tip xc vi khng kh c ln H2S b ha en do phn ng
4Ag + 2H2S + O2 2Ag2S + 2H2O
Ch ra pht biu ng
A. Ag l cht oxi ha; H2S l cht kh
B.Ag l cht kh; O2 l cht oxi ha
C.O2 l cht oxi ha; H2S l cht kh
D.O2 l cht kh; Ag l cht oxi ha
Cu 26: Nhi t phn 31,6g KMnO4 c V lt O2 ktc v 29,2 gam rn. Ch ra gi tr V l hi u sut ca phn ng
nhi t phn
A. 3,2 lt, 85%
B. 1,68 lt, 92,4%
C. 3,36 lt, 50%
D. 1,68 lt, 75%
Cu 27: Cho a gam MCO3 tc dng va vi dung dch H2SO4 4,9%(lng) thu c dung dch mui MSO4 7,336%.
Cho bay hi 207,2 gam dung dch mui trn thu c 27,8 gam tinh th. Cng thc ca phn t tinh th l
A. ZnSO4.7H2O
B. FeSO4.7H2O
C. FeSO4.5H2O
D. CuSO4.5H2O
Cu 28: Mt hp cht to bi mangan v oxi, trong t l v khi lng gia mangan v oxi la 55: 24. Cng thc
ha hc ca oxit l
A. Mn2O3
B. MnO3
C. MnO
D. Mn3O4

Cu 29: Cho 6,72g Fe tc dng vi 0,3 mol dung dch H 2SO4 c nng sinh ra kh SO 2. Sau khi phn ng xy ra hn
tn thu c
A. 0,03 mol FeSO4
B. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4
C. 0,12mol Fe2(SO4)3
D. 0,06 mol Fe2(SO4)3
Cu 30: Ha tan 33 gam hn hp X gm Fe v Al vo 600ml dung dch HCl 1,5 M. Nhn nh ng l
A. dung dch HCl d
B. hn hp X khng tan ht
C. khng th bit hn hp X c tan ht hay khng
D. dung dch HCl ha tan va hn hp X
Cu 31: H s ca phn ng:
FeCO3 + H2SO4 Fe2(SO4)3 +SO2 + CO2 +H2O
A. 2, 4, 1, 1, 2, 4
B. 4, 8, 2, 4, 4, 4
C. 8, 12, 4, 5, 8, 4
D. 2, 8, 1, 3, 2, 4
Cu 32: C mt loi qung pirit cha 96% FeS 2. Nu mi ngy nh my sn xut 100 tn axit sunfuric 98% th
lng qung pirit trn cn dng l bao nhiu ? Bit hiu sut iu ch H2SO4 l 90%
A. 67,44 tn
B. 69,44 tn
C. 68,44tn
D. 70,44tn
(Cho bit: H = 1; Cl = 35,5; O = 16; S = 32; Zn = 65; Al = 27; Fe = 56; Mg = 24; Cu = 64; Mn = 55; K = 39; Na
= 23; Ca = 40; Be = 9; C = 12; N = 14; Ag = 108; Br = 80)
----------- HT ----------

n thi hc sinh gii 2010

A. TRC NGHIM
1. Hy ch ra cu khng chnh xc:
A. Trong tt c cc hp cht, flo ch c s oxi h l -1 B. T flo n iot, nhit nng chy ca chng
gim dn
C. Bn knh nguyn t tng dn t flo n iot.
D. Tt c cc hp cht ca halogen vi hiro iu l
nhng cht kh t0 thng.
2. iu ch HBr ngi ta dng phn ng no?
A. HCl + NaBr NaCl + HBr
B. Br2 + H2O HBr + HBrO
C. PBr3 + 3H2O H3PO3 + 3HBr
D. H2 + Br2 2HBr
0
0
3. Sc kh clo vo dung dch KOH d, t 70 - 75 C thu c dung dch cha cc cht sau:
A. KCl, KClO3, KOH, H2O
B. KCl, KClO, Cl2, H2O
C. KCl, KClO, H2O
D. KClO3, KClO, KOH, H2O
4. Axit HCl th hin tnh oxi h trong phn ng no:
A. 2KMnO4 + 16HCl 2MnCl2 + 2KCl + 5Cl2 + 8H2O B. 2HCl + Fe FeCl2 + H2
C. 2HCl + Fe(OH)2 FeCl2 + 2H2O
D. 6HCl + Al2O3 2AlCl3 + 3H2O
5. Trong cc phn ng sau y phn ng dng iu ch oxi trong cng nghip l:
A. 2KMnO4 K2MnO4 + MnO2 + O2
B. 2H2O dp 2H2 + O2
C. 2Ag + O3 Ag2O + O2
D. 2KNO3 2KNO2 + O2
t0

t0

6. Cho cc kh gm: Cl 2, O2, CO, CH4, CO2 i chm qua bnh ng dd Ca(OH) 2 d. Hn hp kh c gi
li trong bnh l:
A. O2, CO, CH4
B. Cl2, CO2
C. Cl2, O2, CH4
D. O2, CO2
7. Cho dung dch H2SO4 cho ti d vo BaCO3, thy hin tng:
A. si bt kh khng mu
B. C kt ta trng
C. C trng v c kh ko mu
D. c kh mi hc tht ra.
8. iu ch SO2 ngi ta khng dng phn ng no:
A. Na2SO3 + H2SO4 Na2SO4 + SO2 + H2O
B. 4FeS2 + 11O2 2Fe2O3 + 8SO2
C. S + O2 SO2
D. Na2SO3 Na2O + SO2
9. Thuc th phn bit CO2 v SO2 l:
A. dd nc brom
B. dd Bari hidroxit
C. dd nc vi trong
D. dd natri hirosunfit
10. Dung dch di y khng phn ng vi dung dich AgNO3 l.
A. NaF
B. NaCl
C. HCl
D. CaCl2
11. Phn ng chng t H2S l cht kh:
A. H2S + 2NaOH Na2S + 2H2O
B. 2H2S + CuSO4 3S + 2H2O
C. H2S + CuSO4 CuS + H2SO4
D. H2S + NaOH NaHS + H2O
12. Cho s phn ng: Mg + H2S04 (c) MgSO4 + H2S + H2O
H s phn t H2SO4 tham gia l cht oxi h l
A. 1.
B. 4.
C. 5.
D. 6.
13. Pht biu no sao y khng chnh xc?
A. Tnh axit ca HX tng dn theo th t sau: HI, HBr, HCl, HF, o phn cc ca lin kt gia cc
halogen vi hiro tng dn t I n F.
B. T F2 n I2 nhit nng chy tng n.
C. Trong cc halogen F2 c tnh phi kim mnh nht.
D. Nguyn t halogen c 7e lp ngi cng d dng thu thm 1e to thnh ion m X - cu hnh e ca kh
him lin k trong bng tun hn.
14. Sc kh ozon vo dung dch KI d, nhit thng thu c dung dch cha cc cht
A. KOH, KI, I2, O2.
B. KOH, I2.
C. KOH, KI, I2.
D. KOH, I2, O2
15. Phn bit O2 v O3 bng.
A. tn m
B. giy tm dung dch KI v h tinh bt.
C. kim loi Ag
D. mu.
16. Xt phn ng : 2SO2(k) + O2(k) 2SO3 ( H < 0)
thu c nhiu SO3 ta cn:
A. Tng nhit .
B. Tng p sut.
B. thm xc tc.
D. gim nhit .
17. Pht biu no sau y ng?
A. Ni chung, cc phn ng h hc khc nhau xy ra nhanh chm vi tc khc nhau khng ng k.
B. Tc phn ng l bin thin nng ca mt trong cc cht phn ng hoc sn phm trong mt
n v thi gian.
C. Tc phn ng l bin thin nng ca cc cht phn ng trong mt n v thi gian.
D. Tc phn ng c xc nh theo l thuyt.
18. Khng nh no sau y khng ng?
A. Nhit ca ngn la axetilen chy trong oxi cao hn nhiu so vi chy trong khng kh.
B. Nu thc phm trong ni p sut nhanh chn hn so vi khi nu chng p sut thng.
C. Cc cht t rn (nh than, ci) c kch thc nh hn s chy nhanh hn.
D. Nu thc phm trn ni cao (p sut thp) thc phm nhanh chn hn.
19. Cn bng h hc l cn bng ng v:
A. trng thi cn bng phn ng khng dng li, m phn ng thun v phn ng nghch vn xy ra,
nhng tc bng nhau.
B. trng thi cn bng phn ng nghch vn xy ra.
C. trng thi cn bng phn ng thun vn xy ra.
D. trng thi cn bng phn ng vn xy ra.
t0

t0

t0

t0

20. Clo va l cht oxi h va l cht kh trong phn ng ca clo vi:

A. hidro
B. st
C. dd NaBr
D. dd NaOH
21. lm kh kh clo ngi ta dng:
A. dd H2SO4 c B. vi sng C. NaOH khan
D. vi khan
22. Sc kh O3 vo dd KI c nh sn vi git h tinh bt, hin tng quan st c l:
A. dd c mu vng nht
B. dd c mu xanh
C. dd trong sut
D. dd c mu tm
23. Trong cc nhng cht sau y, tnh cht no khng l tnh cht ca axit sunfuric c ngui:
A. ho nc
B. Phn ng h tan Al v Fe C. tan trong nc, to nhit
D. lm h than vi, giy,
ng
24. Cho cn bng: 2NO2 N2O4 H 58,04kJ Nhng bnh ng NO2 v N2O4 th:
A. hn hp vn gi nguyn mu nh ban u.
B. mu nu m dn
C. mu nu nht dn
D. hn hp c mu khc
25. Hiro sunfua l cht:
A. c tnh kh mnh
B. c tnh oxi h mnh
C. c tnh axit mnh
D. tan nhiu trong nc
- 26. Thuc th phn bit cc ion F , Cl , Br , I l:
A. qu tm
B. dd h tinh bt
C. dd Ba(NO3)2
D. dd AgNO3
27. Kh oxi c s dng nhiu trong lnh vc:
A. y t
B. luyn thp
C. cng nghip h cht
D. hn ct kim loi
B. T LUN
1. Thc hin nhng bin i ha hc sau bng cch vit nhng PTHH (ghi r iu kin phn ng nu c):
SO3 H2SO4.nSO3
FeS2
SO2
H2SO4
2. Hn thnh phng trnh phn ng: a. Na2S CuS SO2 H2SO4 Na2SO4 NaCl HCl Cl2.
b. FeS2 SO2 SO3 H2SO4 CuSO4 CuCl2 c) FeS H2S FeS Fe2O3 FeCl3
Fe2SO4 FeCl3
3. Thc hin chui phn ng sau (ghi r iu kin phn ng nu c):
a. Zn ZnS H2S S
SO2 BaSO3 BaCl2. b. SO2 S FeS H2S Na2S PbS
c. FeS2 SO2 S
H2S H2SO4 HCl Cl2 KClO3 O2
d. H2 H2S SO2 SO3 H2SO4 HCl Cl2
e. FeS2 SO2 HBr NaBr Br2 I2
SO3 H2SO4 KHSO4 K2SO4 KCl KNO3
FeSO 4 Fe(OH)2
FeS Fe2O3 Fe

Fe 2(SO4)3 Fe(OH)3
g) S SO2 SO3 NaHSO4 K2SO4 BaSO4
4. Ha cht v iu kin th nghim xem nh y . Vit 4 PTHH iu ch kh sunfur
5. Bng phng php ha hc phn bit cc kh ng trong mi l ring bit mt nhn sau: Lu hunh
ioxit, oxi v ozon.
6. Phn bit cc l mt nhn sau:
a. NaOH, H2SO4, HCl, BaCl2. b. H2SO4, HCl, NaCl, Na2SO4.
c. KCl, Na2CO3, NaI, CuSO4,
BaCl2.
d. Ca(NO3)2, K2SO4; K2CO3, NaBr.
e. NaCl, NaNO3, Na2CO3, Na2SO4.f. Na2SO3, Na2CO3, NaCl,
MgSO4, NaNO3.
g. I2, Na2SO4, KCl, KI, Na2S.
7. Phn bit cc kh mt nhn sau:
a. O2, SO2, Cl2, CO2.
b. Cl2, SO2, CO2, O2, O3.
c. O2, O3, H2S, SO2
8. Bng phng php h hc hy phn bit cc dung dch sau: NaCl, BaCl2, Na2CO3, Na2SO3

9. Bng phng php h hc hy phn bit cc dung dch sau: Na2S, Na2SO3, Na2SO4, BaCl2.
10. Ch dng thm mt thuc th (khng dng cht ch th mu), hy nhn bit cc dung dch sau: natri
sunfat, axit sunfuric, natri cacbonat, axit clohiric.
11. Bng pp ha hc hy phn bit cc dd sau:
a) KCl, K2CO3, MgSO4, Mg(NO3)2.
b) Na2SO4, NaNO3, Na2CO3, NaCl.
c) Na2SO3, Na2S,
NaCl, NaNO3.
d) HCl, H2SO4, BaCl2, Na2CO3.
e) AgNO3, Na2CO3, NaCl, K2SO4. f) HCl, H2SO4, BaCl2,
K2CO3.
g) HCl, HNO3, KCl, KNO3
h) HCl, Na2SO4, NaCl, Ba(OH)2.
12. Mui n b ln tp cht l: Na2SO4, MgCl2, BaCl2, CaSO4. Hy trnh bi phng php h hc loi b
tp cht, thu c NaCl tinh khit.Vit phng trnh h hc.
13. Mui NaCl c ln tp cht l NaI.
a. Lm th no chng minh rng trong mui NaCl ni trn c ln tp cht NaI.
b. Lm th no
c NaCl tinh khit.
14. Vit pt chng minh SO2 va c tnh oxi ha va c tnh kh.
15. Vit 2 pt chng minh S l mt cht oxi ha, 2 pt chng minh S l cht kh.
16. Vit phng trnh phn ng khi H 2SO4 lng v H2SO4 c nng tc dng vi cc cht sau: Fe, Cu,
FeO, Na2CO3. T cc phn ng trn rt ra kt lun g vi axit sunfuric.
17. Trnh by hai phng php iu ch hiro sufua t cc cht sau: S, Fe, axit HCl.
18. T mui n, nc, H2SO4 c. Vit cc phng trnh phn ng (ghi k phn ng nu c) iu ch: Kh
Cl2, H2S, SO2 , nc Javen, Na2SO4
19. T qung pirit st, mui n, khng kh, nc, khng kh; hy vit phng trnh iu ch: Fe 2(SO4)3,
Na2SO4, nc Javen, Na2SO3, Fe(OH)3, Natri, Natriclorat, NaHSO4, NaHSO3.
20. Cho 78,3 gam mangan ioxit tc dng vi HCl c. Lng clo thu c dn qua 500ml dung dch
NaOH 4M ( iu kin thng) c dung dch A.
a. Vit phng trnh phn ng.
b. Tnh nng mol ca cc cht trong dung dch A (coi Vdd khng thay i).
21. Cho 4,8g Mg tc dng vi 250ml dung dch H2SO4 10% (D = 1,176g/ml) thu c kh H2 v dung dch
A.
a. Tnh th tch kh H2(kc) thu c.
b. Tnh nng % cc cht trong dung dch A.
22. Hp th hn tn 3,36lt kh hidrosunfua ( ktc) vo 90ml dung dch NaOH 2M (D =1,221g/ml)
a. Vit PTHH ca phn ng xy ra.
b. Tnh nng mol v nng phn trm ca cht c trong dung dch thu c. (Na=23, S =32, O=16,
H = 1)
23. Cho 5,12g kim loi R c ha tr II khng i tc dng va vi 16g dung dch H2SO4 98% thy tht ra
kh SO2.
a. Vit PTHH ca phn ng xy ra. b. Tm kim loi R. (Fe = 56, Zn = 64,Mg =
24,Cu=64,Ni=59,Pb= 207)
24. Mt hn hp A gm Fe v mt kim loi M h tr 2.
- Ha tan hn tn 12,1g hn hp A bng H2SO4 lng th thu c 4,48lt kh H2(kc).
- Ha tan hn tn 12,1g hn hp A bng H2SO4 c nng th thu c 5,6 lt kh SO2(kc).
a. Vit cc phng trnh phn ng c th xy ra.
b. Xc nh kim loi M.
25. H tan 24,8g hh X gm Fe, Mg, Cu trong dd H 2SO4 , nng d thu c dung dch A. Sau khi c cn
dd A thu c 132 g mui khan. 24,8 g X tc dng vi dd HCl d th thu c 11,2 lt kh (kc).
a. Vit phng trnh phn ng
b. Tnh % khi lng mi kim loi trong hh X.
26. Cho 5,6 lit kh SO2 (kc) vo:
a. 400 ml dung dch KOH 1,5 M. b. 250 ml dung dch NaOH 0,8 M. c. 200 ml dung dch KOH 2 M.
Tnh nng cc cht trong dung dch thu c .

27. t chy hn tn 12,8 g S. Kh sinh ra c hp th ht bi 150 ml dung dch NaOH 20% (D = 1,28
g/ml). Tm CM, C% ca cc cht trong dung dch thu c sau phn ng.
28. H tan 4,8 g mt kim loi M h tr II va tc dng vi 392 g dung dch H2SO4 10%. Xc nh M.
29. Cho 40 g hn hp A cha Cu v Al tc dng vi dung dch H 2SO4 d thu c 22,4 lit kh (kc). Tnh %
khi lng mi kim loi?
30. Cho 36 g hn hp X cha Fe2O3 v CuO tc dng va vi dung dch H 2SO4 20% thu c 80 g hn
hp mui.
a) Tnh % khi lng tng cht trong hn hp X.
b) Tnh khi lng dung dch H2SO4 dng.
31. Cho 6,8 g hn hp X gm Mg v Fe vo dung dch H2SO4 lng th thu c 3,36 lit kh bay ra (kc).
a) Tnh % khi lng mi kim loi trong X?
b) Nu cho hn hp trn tc dng vi H2SO4 , nng.Tnh VSO2 (kc)?
32. Cho 35,2 g hn hp X gm Fe v CuO tc dng va vi 800 g dd H 2SO4 lng th thu c 4,48 lit kh
(kc) v dd A.
a) Tnh % khi lng mi cht trong X.
b) Tnh C% dung dch H2SO4 dng.
c) Tnh khi lng cc mui trong dung dch A.
33. Cho 40 g hn hp Fe Cu tc dng va vi dung dch H2SO4 98% nng thu c 15,68 lit SO2 (kc).
a.Tnh % khi lng mi kim loi trong hn hp?
b.Tnh khi lng dung dch H2SO4 dng?
34. Cho 20,8 g hn hp Cu v CuO tc dng va dung dch H2SO4 , nng thu c 4,48 lit kh (kc).
a. Tnh % khi lng mi kim loi trong hn hp?
b.Tnh khi lng dung dch H2SO4 80% cn dng v khi lng mui sinh ra.
35. Cho 7,6 g hn hp gm Fe, Mg, Cu vo dung dch H2SO4 , ngui d th thu c 6,16 lit kh SO2 (kc).
Phn khng tan cho tc dng vi dung dch HCl d thu c 1,12 lit kh (kc).Tnh % khi lng hn hp
u.
36. Cho 10,38 g hn hp gm Fe, Al v Ag chia lm 2 phn bng nhau:
- Phn 1: Tc dng vi dung dch H2SO4 lng d thu c 2,352 lit khi (kc).
- Phn 2: Tc dng vi dung dch H2SO4 , nng d thu c 2,912lit kh SO2 (kc).
Tnh khi lng tng kim loi trong hn hp ban u.
37. Nung nng hn hp gm 11,2 g bt Fe v 3,2 g bt lu hunh. Cho sn phm to thnh vo 200 ml dung
dch H2SO4 th thu c hn hp kh A bay ra v dung dch B ( Hp = 100%).
a. Tm % th tch ca hn hp A.
b. trung ha dung dch B phi dng 200 ml dung dch KOH 2M.Tm C M ca dung dch H2SO4
dng.
38. Cho 12,6 gr hn hp A cha Mg v Al c trn theo t l mol 3:2 tc dng va vi dung dch H 2SO4
c, nng thu c kh SO2 (kc).
a. Tnh % khi lng mi kim loi trong hn hp A?
b. Tnh VSO2 ( 270 C; 5 atm).
c. Cho tn b kh SO2 trn vo 400 ml dung dch NaOH 2,5 M. Tnh CM cc cht trong dung dch
thu c.
39. Cho h2 (X) gm Fe v FeS tc dng vi dd HCl d, thu c 7,84 lt hn hp kh (kc). Cho hn hp
ny qua dd Pb(NO)3 thu c 47,8 g kt ta mu en.
a. Vit phong trnh h hc. b. Hn hp kh thu c gm nhng kh no? Th tch mi kh l bao
nhiu?
c. Tnh khi lng cc cht trong hn hp X.
40. Cho 32 g hn hp Fe v FeS tc dng va vi dd HCl 2M. Sau phn ng thu c V lt hn hp kh
A (ktc) v dung dch B. Cho hn hp kh A i qua dd Pb(NO3)2 d th thu c 71,7 g kt ta mu en.
a. Vit phong trnh h hc.
b. Hn hp kh thu c gm nhng kh no? Tnh V ?

c. Tnh khi lng cc cht trong hh ban u.

d. Tnh Vdd HCl dng.
e. Khi lng cc
cht trong dd B.
41. Cho 300 ml dd H2SO4 98% (D = 1,84 g/cm3). Vy mun pha lng th tch H2SO4 trn thnh dd H2SO4
15%.
a. Tnh th tch nc cn dng pha lng.
b. Khi pha lng phi tin hnh nh th no?
H 0
42. Cho pt h hc: 2SO2 (k) + O2 (k) V O ,t 2SO3 (k)
Cn bng h hc ca phn ng s chuyn dch v pha no khi:
a. Tng nhit ca bnh phn ng?
b. Tng p sut chung ca hn hp?
c. Tng nng kh oxi?
d. Gim nng kh sunfur?
43. Sn xut vi trong cng nghip v th cng nghip u da tn phn ng hh: CaCO 3 (r) CaO (r) +
CO2 (k) H 0
Hy phn tch cc c im ca phn ng h hc nng vi? T nhng c im , hy cho bit nhng
bin php k thut no c s dng nng cao hiu xut ca qu trnh nung vi?
44. Ngi ta ung nng mt lng PCl5 trong mt bnh kn th tch 12 lt 250 0C. PCl5(k)
PCl3 (k)
+ Cl2 (k)
Lc cn bng c 0,21 mol PCl5; 0,32 mol PCl3; 0,32 mol Cl2. Tnh hng s cn bng KC ca phn ng.
45. Cho phn ng sau: H2O (k) + CO (k) H2(k) + CO2 (k).
7000C hng s cn bng KC = 1.873. Bit rng hn hp ban u gm: 0,300 mol H2O v 0,300 mol CO
trong bnh 10 lt 7000C.
-------------------HT------------------2 5

t0

(Chc cc em hc tt thi t kt qu cao)

1. t chy hn tn 2,3 g kim loi Na trong kh clo.Th tch kh Clo cn dng ktc l(bit Na = 23 ; Cl = 35,5) :
A. 2,24 lt
B. 3,36 lt
C. 4,48 lt
D. 1.12 lt
2. Cc electron ca nguyn t nguyn t X phn b trn 3 lp . Lp ngi cng c 6 electron. S n v in tch ht
nhn nguyn t ca nguyn t X l :
A. 17
B. 16
C. 15
D. 14
3. Oxit cao nht ca mt nguyn t l R2O5. Hp cht kh ca n vi hiro cha 17,64 % hiro v khi lng,
nguyn t khi ca R l:
A. 32
B. 28
C. 14
D. 31
4. in h tr ca Fe, Cu, Cl, O trong cc hp cht FeCl3, CuO ln lt l:
A. 3+, 2+, 1-, 2B. 2+, 3+, 1-, 2C.
+2, +3, -1, -2
D. +3, +2, -1, -2
5. Chn pht biu ng :
A. Phn ng ha hp khng phi l phn oxy ha kh
B.
Phn ng phn hy lun l phn ng oxy ha kh.
C. Phn ng trao
i c th l phn ng oxy ha kh
D. Phn ng th lun l phn ng
oxy ha kh
6. Gia cc nguyn t O, S, K c kh nng to thnh nhng kiu lin kt g khi chng h hp vi nhau tng i mt
:
A. Lin kt phn t
B. Lin kt ion
C.
Lin kt cng h tr
D. Lin kt ion v cng h tr
7. Trong phn ng oxi ha kh : Fe2O3 + 3CO 2Fe + 3CO2 , cht kh l:
2
2
A. C (trong CO2)
B. C (trong CO)

C. Fe trong Fe2O3
D. O2
8. Cho cc phn ng sau, phn ng no khng l phn ng oxi ha - kh:
A. Cu(OH)2 CuO + H2O
B. Fe + 2HCl FeCl2 + H2
Cl2 + 2NaOH NaCl + NaClO + H2O
2H2O
9. S oxy h ca clo trong HCl, Cl2, HClO3, HClO2, ClO 4 ln lt l:
A. +1, 0, +2, +4, +5
B. +1, 0, +2, +3, +4
-1, 0, +7, +3, +5
D. -1, 0, +5, +3, +7
10. Trong phn ng oxi ha- kh: 3Pb + 8HNO3 3Pb(NO3)2 + 2NO + 4H2O , cht oxi ha l :

A. H (trong HNO3)
B. Pb
2

C.
D. 2H2 + O2

C.

C.

D. N (trong HNO3)
O (trong HNO3)
11. Trong cc qu trnh sau y qu trnh no sai :
+7

+2

A. Mn +5e Mn
+6

-2

S +4e S

B. N N 5e
0

C.

D Fe Fe 3e
12. Thnh phn cu to nn tinh th nguyn t, tinh th phn t, tinh th ion ln lt l :
A. Cc ion, nguyn t, phn t.
B. Cc nguyn t, ion, phn t.
C. Cc ion, phn t, nguyn t
D. Cc nguyn t, phn t, ion.

13. Trong cc phn ng sau, phn ng no l phn ng oxi ha kh :

A. 2H2 + O2 2H2O
B. HCl + NaOH NaCl + H2O
C.
NH3 + HCl NH4Cl
D. Na2CO3 Na2O + CO2
14. Lin kt cng h tr l lin kt:
A. Gia cc phi kim ging nhau
B. c to nn gia hai nguyn t bng mt hay nhiu cp electron dng chung
C. c hnh thnh do s dng chung electron gia hai nguyn t khc nhau
D. Trong cp electron dng chung b lch v pha mt nguyn t.
+
15. S oxy h ca nit trong NH3, HNO3, HNO2, KNO3, NH 4 ln lt l:
A. -3, +5, +5, +3, +3
B. -3, +5, +3, +5, -3
C.
+3, -3, +3, +5, +5
D. +3, -5, -5, -3, +3
16. Du hiu nhn bit mt phn ng oxi ha - kh l:
A. C s to ra kt ta
B. C s thay i mu sc ca cc cht
C.
To ra cht kh.
D. C s thay i s oxi ha ca mt s nguyn t.
17. Cho 7,8g mt kim loi kali tc dng hn tn vi nc, th tch kh hiro thu c sau phn ng l (bit K = 39):
A. 1,12 lt
B. 2,24 lt
C. 3,36 lt
D. 4,48 lt
18. Cng h tr ca cacbon, lu hunh, clo trong CO2, H2S, HCl ln lt l:
A. 4, 2, 1
B. 4, 3,2
C. 2, 2, 1
D. 3, 4, 2
19. Cc nguyn t lin kt vi nhau :
A. chuyn sang trng thi c nng lng cao hn.
B.
t cu hnh lp ngi cng 8e hoc 2e.
C. To thnh mng
tinh th nguyn t.
D. To thnh mng tinh th ion.
20. Cho bit m in ca hidro l : 2,20 ; ca Si l: 1,90. Lin kt trong phn t SiH4 l lin kt :
A. Lin kt ion
B. Cng ha tr khng cc
C.
Cng ha tr c cc, cp electron dng chung lch v pha nguyn t clo
D. Cng ha tr c
cc, cp electron dng chung lch v pha nguyn t hidro
21. Bit pht pho thuc th 15, nhmVA, chu k 3, cng thc hp cht kh ca hidro vi l:
A. PH4
B. PH
C. PH3
D. PH2
22. in tch ca nguyn t l:

A. Mang in tch m
B. Mang in tch dng
C.
Trung ha v in
D. Ty theo mi nguyn t.
15
12
23. Cho bn nguyn t: : 7 X , 5Y , 126 Z , 147T . Cc nguyn t ng v ca nhau l:
A. X, Y
B. X, Y
C. X, T
D. Z, T
24. Ht nhn nguyn t liti c 3 proton v 4 ntron, s khi ca ht nhn nguyn t liti l:
A. 7
B. 4
C. 6
D. 3
25. Kim loi Na thuc nhm IA, phng trnh ng ca Na tc dng vi nc l:
A. 2Na + 2H2O 2NaOH + H2
B.
2Na + 2H2O NaOH + H2
C. Na + 2H2O
Na(OH)2 + H2
D. 2Na + 2H2O 2Na2O + H2
26. Mt nguyn t thuc chu k 2, nhm VIA trong bng tun hn, cu hnh electron ca nguyn t l:
A. 1s22s22p2
B. 1s22s22p5
C. 1s22s22p6
D. 1s22s22p4
27. Bit nguyn t Ar c s th t l 18, chu k 3, nhm VIIIA, chn p n ng:
A. Ar l kh him, trong nguyn t c 18 electron
B. Ar
l kim loi, nguyn t c 3 electron lp ngi cng
C. Ar l kh him,
nguyn t c 4 lp electron
D. Ar l phi kim, nguyn t c 3
electron lp ngi cng
28. Cu hnh electron ca nguyn t lu hunh (Z=16) l:
A. 1s22s22p53s23p4
B. 1s22s22p63s23p4
C.
1s22s22p53s23p5
D. 1s22s22p63s23p3
29. Cho nguyn t clo (Z=17), v tr ca clo trong bng tun hn cc nguyn t ha hc l:
A. th 17, chu k 3, nhm VIIB
B. th 3, chu k 3, nhm VIIA
C. th 8, chu k 3, nhm IIIA
D. th 17, chu k 3, nhm VIIA
30. Nguyn t ha hc l nhng nguyn t c cng:
A. S ntron
B. S khi
C. S proton
D. S ntron v s proton
31. Canxi nm th 20 trong bng tun hn cc nguyn t ha hc, canxi l:
A. Kim loi hoc phi kim
B. Kh him
C.
Phi kim
D. Kim loi
23
32. Nguyn t Na c k hiu nguyn t l 11 Na , s hiu nguyn t ca Na l:
A. 23
B. 34
C. 11
D. 12
33. Lp v nguyn t c cu to t:
A. Electron
B. Proton v ntron
C. Proton
D. Ntron
34. Chn cu pht biu sai:
A. Trong mt nhm, t trn xung di tnh phi kim gim dn
B.
Trong mt chu k, t tri qua phi tnh phi kim tng dn
C. Trong
mt chu k, t tri qua phi tnh kim loi tng dn
D. Trong mt nhm, t trn
xung di m in ca cc nguyn t gim dn
19
35. Nguyn t F c k hiu l 9 F , s ntrn trong nguyn t F l:
A. 10
B. 19
C. 28
D. 9
10
11
X
X
36. Nguyn t X c hai ng v bn: 5 chim 18,89% v 5 chim 81,11%. Nguyn t khi trung bnh ca
nguyn t X l:
A. 10,80
B. 10,81
C. 10,83
D. 10,82
+
37. Cu hnh electron ca K (Z=19) l :
A. 1s22s22p63s23p64s2
B. 1s22s22p63s23p44s2
C. 1s22s22p63s23p6
2
2
6
2
6
1
D. 1s 2s 2p 3s 3p 4s
38. Bit nit c Z = 7, cng thc oxit cao nht ca nguyn t nit l:
A. NO
B. N2O
C. NO2
D. N2O5
39. Hp cht kh ca R vi hiro l RH3, cng thc oxit cao nht ca R vi oxi l:
A. R2O3
B. RO5
C. R2O5
D. RO2
2
2
6
2
2
40. Cu hnh electron ca nguyn t Si l 1s 2s 2p 3s 3p , s hiu nguyn t ca silic l:
A. 10
B. 14
C. 16
D. 4