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nOH
= 2. 5 x = 0,05 (mol)
nH
= nOH hay 0,4 V = 0,05 => V = 0,125 (lit) hay 125 (ml)
b. Tnh tng khi lng cc mui.
m Cc mui =
m cation +
m anion
= mNa
+ mBa
+ mCl
+ mSO 4
= 23.0,2.0,125 + 137.0,1.0,125 + 35,5.0,2.0,15 + 96.0,2.0,05 =
4,3125 (g)
V d 2: Cho 200 ml dung dch A cha HCl 1 (M) v HNO3 2(M) tc dng vi 300 ml
dung dch B cha NaOH 0,8 (M) v KOH (cha r nng ) thu c dung dch C.
Bit rng trung ho 100 ml dung dch C cn 60 ml dung dch HCl 1 M, tnh :
a/ Nng ban u ca KOH trong dung dch B.
b/ Khi lng cht rn thu c khi c cn ton b dung dch C.
Hng dn
Bnh thng i vi bi ny ta phi vit 4 phng trnh gia 2 axit vi 2 baz. Nhng
nu ta vit phng trnh dng ion ta ch phi vit 1 phng trnh ion thu gn
ca phn ng trung ho.
a. Phng trnh phn ng trung ho :
H+ + OH- H2O
Trong 200 (ml) ddA :
nH
= 0,2 . 1 + 0,2 . 2 = 0,6 (mol)
Trong 300 (ml) ddB :
nOH
KOH).
Trong dung dch C cn d OHTrong 100 (ml) dd C :
Nguyn Thanh Tuyn
nOH
= nH
Gii bi ton bng phng trnh ion thu gn. Nguyn Thanh Tuyn Trng THPT H Bc Thanh H
nOH
nOH
= (0,24 + 0,3.a) 0,6 = 0,3.a 0,36 (mol)
Ta c : 0,3.a 0,36 = 0,3 => a = 0,66/0,3 = 2,2 (M).
b. Khi lng cht rn khi c cn ton b dd C.
i vi bi ny nu gii vi phng php bnh thng s gp kh khn, v c th tnh
c khi lng cc mui nhng khng tnh c khi lng baz v ta khng bit baz
no d. Vy bi ny ta s s dng phng trnh ion, thay v tnh khi lng cc mui
v baz ta i tnh khi lng cc ion to ra cc cht .
Ta c :
m Cht rn = mNa
mNa
mK
mCl
+ mK
+ mCl
+ mNO 3
+ mOH
mNO
nOH
mOH
m Cht rn = mNa
+ mK
+ mCl
+ mNO 3
+ mOH d = 68,26 (g).
V d 3: a/ Cho dung dch NaOH c pH = 13 (dung dch A). trung ho 10 ml
dung dch A cn 10 ml dung dch B cha 2 axit HCl v H2SO4. Xc nh pH ca
dung dch B ?
b/ Trn 100 ml dd A vi 100 ml dung dch Ba(OH)2 x (M), thu c dung dch C.
trung ho dung dch 500 ml dung dch C cn 350 ml dung dch B. Xc nh x
Hng dn
y l nhng phn ng gia 1 Baz v 2 Axit v 2 Baz v 2 Axit (c km theo
theo to kt ta), v c lin quan n pH dung dch. Vy nn nu gii phng php
bnh thng s rt kh khn trong vic lp phng trnh gii h. Nn ta s dng
phng trnh ion thu gn.
a. Phng trnh phn ng trung ho ddA vi ddB
H+ + OH- H2O (1)
H = 10-13 (M) OH = 10-1 (M).
Dd NaOH (ddA) c pH = 13
Trong 10 ml = 10-2 (l) dung dch A c :
S mol OH- :
nOH
= 10-3 (mol)
H =
Trong 350 ml dd B c : nH
= 3,5. 10-2 (mol).
Theo pt (1) c : 2,5. 10-2 + 0,5x = 3,5 . 10-2 => x = 2.10-2 (M)
Nguyn Thanh Tuyn
Gii bi ton bng phng trnh ion thu gn. Nguyn Thanh Tuyn Trng THPT H Bc Thanh H
nCaCO 3 = nHCO 3
Hng dn gii
nHCl = nH
= 0,18 mol => VHCl 2M = 0,18/2 = 0,09(l)
b. Nu dng 0,12 lit dung dch HCl 2M hay 0,12.2 = 0,24 mol H+ > 0,18 mol. Nn s
c phng trnh :
HCO 3 + H+ CO2 + H2O
0,06
0,06
VCO 2 = 0,06.22,4 = 1,344 (l)
Nguyn Thanh Tuyn
Gii bi ton bng phng trnh ion thu gn. Nguyn Thanh Tuyn Trng THPT H Bc Thanh H
Bi tp tham kho
Cu 1: Mt dung dch A cha HCl v H2SO4 theo t l mol 3:1. 100ml dung dch A trung ha va bi
50ml dung dch NaOH 0,5M. Nng mol mi acid l?
A. [HCl]=0,15M;[H2SO4]=0,05M
B. [HCl]=0,5M;[H2SO4]=0,05M
C. [HCl]=0,05M;[H2SO4]=0,5M
D. [HCl]=0,15M;[H2SO4]=0,15M
Cu 2: 200ml dung dch A cha HCl 0,15M v H2SO4 0,05M phn ng va vi V lt dung dch B cha
NaOH 0,2M v Ba(OH)2 0,1M. Ga tr ca V l?
A. 0,25lt
B. 0,125lt
C. 1,25lt
D. 12,5lt
Cu 3: Tng khi lng mui thu c sau phn ng ca dung dch A v dung dch B trn(cu 22) l?
A. 43,125gam B. 0,43125gam
C. 4,3125gam D. 43,5gam
Cu 4: 200 ml dung dch A cha HNO3 v HCl theo t l mol 2:1 tc dng vi 100ml NaOH 1M th lng
acid d sau phn ng tc dng va vi 50 ml Ba(OH)2 0,2M. Nng mol cc acid trong dung dch A
l?
A. [HNO3]=0,04M;[HCl]=0,2M
B. [HNO3]=0,4M;[HCl]=0,02M
C. [HNO3]=0,04M;[HCl]=0,02M
D. [HNO3]=0,4M;[HCl]=0,2M
Cu 5: Trn 500 ml dung dch A cha HNO3 0,4M v HCl 0,2M vi 100 ml dung dch B cha NaOH 1M
v Ba(OH)2 0,5M th dung dch C thu c c tnh g?
A. Acid
B. Baz
C. Trung tnh D. khng xc nh c
Cu 6: Cho 84,6 g hn hp 2 mui CaCl2 v BaCl2 tc dng ht vi 1 lt dung dch cha Na2CO3 0,25M
v (NH4)2CO3 0,75M sinh ra 79,1 gam kt ta. Thm 600 ml Ba(OH)2 1M vo dung dch sau phn ng.
Khi lng kt ta v th tch kh bay ra l?
A. 9,85gam; 26,88 lt
B. 98,5gam; 26,88 lt
C. 98,5gam; 2,688 lt
D. 9,85gam; 2,688 lt
Cu 7: Cho 200 ml dung dch A cha HCl 1M v HNO3 2M tc dng vi 300 ml dung dch cha NaOH
0,8M v KOH (cha bit nng ) th thu c dung dch C. Bit rng trung ha dung dch C cn 60
ml HCl 1M. Nng KOH l?
A. 0,7M
B. 0,5M
C. 1,4M
D. 1,6M
Cu 8: 100 ml dung dch X cha H2SO4 2 M v HCl 2M trung ha va bi 100ml dung dch Y gm 2
baz NaOH v Ba(OH)2 to ra 23,3 gam kt ta. Nng mol mi baz trong Y l?
A. [NaOH]=0,4M;[Ba(OH)2]=1M
B. [NaOH]=4M;[Ba(OH)2]=0,1M
C. [NaOH]=0,4M;[Ba(OH)2]=0,1M
D. [NaOH]=4M;[Ba(OH)2]=1M
Cu 9: Dung dch HCl c pH=3. Cn pha long bng nc bao nhiu ln c dung dch c pH=4.
A. 10
B. 1
C. 12
D. 13
Cu 10: Dung dch NaOH c pH=12 cn pha long bao nhiu ln c dung dch c pH=11
A. 10
B. 1
C. 12
D. 13
Cu 11: Trn 100 ml dung dch gm Ba(OH)2 0,1M v NaOH 0,1M vi 400 ml dung dch gm H2SO4
0,0375M v HCl 0,0125M thu c dung dch X. Ga tr pH ca dung dch X l?
A. 2
B. 1
C. 6
D. 7
Cu 12: Cho 2,45g hn hp Al- Ba(t l mol tng ng l 4:1) tc dng vi 50ml dd
NaOH 1M, thu c dung dch X. Tnh th tch HCl 1M cn thm vo dd X sau
phn ng thu c:
a/ Kt ta ln nht
A. 0,07 l
B. 0,08 l
C. 0,09 l
D. 0,1 l
b/ 1,56 g kt ta
A. 0,05 l
B. 0,08 l
C. 0,13 l
D. C A v C ng
Cu 13: Cho m gam hn hp Mg v Al vo 250ml dung dch X cha hn hp acid HCl 1M v acid
H2SO4 0,5M thu c 5,32 lt H2 (ktc) v dung dch Y (coi th tch dung dch khng i). Dung dich Y
c pH l?
A. 7
B. 1
C. 2
D. 6
Nguyn Thanh Tuyn
Gii bi ton bng phng trnh ion thu gn. Nguyn Thanh Tuyn Trng THPT H Bc Thanh H
Cu 14: Cho mt mu hp kim Na-Ba tc dng vi nc d thu c dung dch X v 3,36lt H2 (ktc).
Th tch dung dch acid H2SO42 M cn dng trung ha dung dch X l?
A. 150ml
B. 75ml
C. 60ml
D. 30ml
Cu 15:200 ml dung dch A cha HNO3 1M v H2SO4 0,2M trung ha vi dung dch B cha NaOH 2M
v Ba(OH)2 1M. Th tch dung dch B cn dng l?
A. 0,05 lt
B. 0,06 lt
C. 0,04lt
D. 0,07 lt
Cu 16: Hn hp X gm Na v Ba. Ha tan m gam X vo nc c 3,36lt H2 ( ktc) v dung dch Y.
trung ha lng dung dch Y cn bao nhiu lt dung dch HCl 2M?
A. 0,15lt
B. 0,3 lt
C. 0,075lt
D. 0,1lt
Cu 17: Dung dch X cha NaOH 0,06M v Ba(OH)2 0,02M. pH ca dung dch X l?
A. 13
B. 12
C. 1
D.2
Cu 18:Trn dung dch X cha NaOH 0,1M; Ba(OH)2 0,2M vi dung dch Y (HCl 0,2M; H2SO4 0,1M)
theo t l no v th tch dung dch thu c c pH=13?
A. VX:VY=5:4
B. VX:VY=4:5
C. VX:VY=5:3
D. VX:VY=6:4
Cu 19: C 4 dd mi dung dch ch cha 1 ion (+) v 1 ion (-). Cc ion trong 4 dung dch gm: Ba2+,
Mg2+, Pb2+, Na+, SO42-, Cl-, NO3-, CO32-. l 4 dung dch no sau y?
A. BaSO4, NaCl, MgCO3, Pb(NO3)2
B. BaCl2, Na2CO3, MgSO4, Pb(NO3)2
C. Ba(NO3)2, Na2SO4, MgCO3, PbCl2
D. BaCO3, NaNO3, MgCl2, PbSO4
Cu 20: Trn 150 ml dd MgCl2 0,5M vi 50ml dd NaCl 1M th nng mol/l ion Cl- trong dung dch l?
A. 2 M
B. 1,5 M
C. 1,75 M
D. 1 Khi lng
Cu 21: Cho 8,8 gam hn hp 2 kim loi Mg v Ca tc dng va vi 500 ml dung dch HCl. Sau
c cn dung dch, thu c a gam hn hp 2 mui. Cho hn hp 2 mui trn vo 1 lng d dung dch
cha hn hp Na2CO3 v (NH4)CO3 . Kt thc phn ng thu c 26,8 g kt ta X
Nng mol ca dung dch HCl v khi lng ca Mg trong hn hp ban u ln lt l
A. 1,2 M - 4,8g
B. 1,5 M- 4,8g
C. 1,2 M - 2,4g
D. 1 M - 4,8g
p n: 1- A
12-A-D
2- B 3-C
13-B 14-B
4- D
15-D
5 -A
16-C
6-B
7-C
17-A 18-A
8-D
19- B
Nu
Nu
Ch :
Nu baz d ch thu c mui trung ho.
Nu CO2 d ch c mui axit.
Nu cng mt lc c 2 mui th c 2 cht CO2 v baz u ht.
- Khi lng chung ca cc mui :
nCO2
1<
nOH
nCO2
m Cc mui =
m cation +
m anion
Gii bi ton bng phng trnh ion thu gn. Nguyn Thanh Tuyn Trng THPT H Bc Thanh H
m = mK + mNa + mHCO 3
= 0,2.0,5. 39 + 0,2.1. 23 + 0,3. 61 = 26,6 (g)
TH3 : V3 = 4,48 lit CO2 ktc
4,48
2
1 < n
= 0,2 < 2 to ra 2 mui axit HCO 3 v CO 3
CO 2
Gii bi ton bng phng trnh ion thu gn. Nguyn Thanh Tuyn Trng THPT H Bc Thanh H
1-D
2-A
3-B
4-C
5- D
Do
>
nn trong phn ng trn NO 3 s ht, th tch kh NO sinh ra
3
8
2
s c tnh theo ion ny
nNO 3 =
H2
0,1 mol
nKNO 3 = 0,1
2
Gii bi ton bng phng trnh ion thu gn. Nguyn Thanh Tuyn Trng THPT H Bc Thanh H
8 H+ + 2 NO 3 3 Cu2+ + 2 NO + 4 H2O
0, 2
mol 0,1
3
2+
+
3 Fe
+ 4 H + NO 3 3 Fe3+ + NO + 2 H2O
0,1
mol
0,1
3 M + 8 H+ + 2 NO 3 3 M2+ + 2 NO + 4 H2O
mol
0,21 0,56
Do sau cc th nghim th
2 Fe Fe2O3 ;
Mg MgO ; Cu CuO
a
a/ 2
b
b
c
a
15,6 = 160
+ 40b + 80c
2
11,76= 56a + 24b + 64 c
Gii h (1), (2), (3) kt qu
c
(2)
(3)
Bi tp tham kho
Cu 1: Cho 19,2g Cu vo 500ml dung dch NaNO3 1M sau thm tip 500ml
dung dch HCl 2M vo. Phn ng kt thc thu c dung dch X v V lt kh
NO(ktc). Gi tr ca V v th tch dung dch NaOH 2M cn dng kt ta ht
ion Cu2+ trong dung dch X ln lt l
A. 4,48lt - 4lt
B. 4,48lt - 2lt
C. 2,24lt - 4lt
D. 4,48lt 0,5lt
Cu 2: Thc hin 2 th nghim
Nguyn Thanh Tuyn
Gii bi ton bng phng trnh ion thu gn. Nguyn Thanh Tuyn Trng THPT H Bc Thanh H
a.
b.
1-A
2-D
3-B
4-C