Bi tp este lipit

Cu 1 . Mt este c cng thc phn t l C4H6O2 , khi thu phn trong mi trng axit thu c axit acrylic .
Cng thc cu to thu gn ca C4H6O4 l
A. HCOOCH2CH = CH2
B. CH3COOCH = CH2
C. CH2 = CH - COOCH3
D. HCOOC(CH3) = CH2
Cu 2. X phng ho hon ton 1 mol este X thu c 1 mol mui v x ( x 2 ) mol ru . Vy este X c to
thnh t
A. axit n chc v ru n chc
B. axit a chc v ru n chc
C. axit a chc v ru a chc
D. axit n chc v ru a chc
Cu 3. Cc ng phn ng vi cng thc phn t C8H8O2 ( u l dn xut ca benzen ) tc dng vi NaOH
to ra mui v ru l
A. 3
B. 2
C. 7
D. 4
Cu 4. Cho cc cht sau : Axit propionic (1); axeton (2) ; metyl axetat (3) ; propan - 1 - ol (4)
Dy no sau y c sp xp theo chiu tng dn nhit si?
A. 2,3,4,1
B. 2,3,1,4
C. 3,2,4,1
D. 3,2,1,4
Cu 5. Cc ng phn ng vi cng thc phn t C9H8O2 ( u l dn xut ca benzen) tc dng vi NaOH
d cho 2 mui v cng hp vi Br2 theo t l 1 : 1 l
A. 1
B. 3
C.5
D. 6
Cu 6. Mt este c CTPT l C3H6O2 , c phn ng trng gng vi dung dch AgNO3/ NH3 . CTCT ca este l
A. HCOOC2H5
B. CH3COOCH3
C. HCOOC3H7
D. C2H5COOH
Cu 7. Cu no sau y khng ng ?
A. M ng vt ch yu cu thnh t cc axit bo , no, tn ti trng thi rn
B. Du thc vt ch yu cha cc axit bo khng no, tn ti trng thi lng
C. Hiro ho du thc vt lng s to thnh cc m ng vt rn
D. Cht bo nh hn nc v khng tan trong nc
Cu 8. Cho cht hu c A ch cha mt loi nhm chc tc dng vi 1 lit dung dch NaOH 0,75M thu c
0,45 mol mui v 0,15 mol ru . Lng NaOH d c th trung ho ht 0,75 lt dung dch HCl 0,4M . Cng thc
tng qut ca A l
A. RCOOR'
B. (RCOO)2R'
C. (RCOO)3 R'
D. R(COOR')3
Cu 9. Cho 32,7g cht hu c X ch cha mt loi nhm chc tc dng vi 1,5 lit dung dch NaOH 0,5M thu
c 36,9g mui v 0,15 mol ru . Lng NaOH d c th trung ho ht 0,5 lit dung dch HCl 0,6M . Cng thc
cu to thu gn ca X l
A. CH3COOC2H5
B. (CH3COO)2C2H4
C. (CH3COO)3C3H5
D. C3H5(COOCH3)3
Cu 10. un nng axit axetic vi ancol isoamylic (CH3)2CH- CH2- CH2OH c H2SO4 c xc tc thu c
isoamyl axetat ( du chui ) . Lng du chui thu c t 198,525g axit axetic un nng vi 300g ancol
isoamylic l ( Bit H = 68%)
A. 146,25g
B. 292,49g
C. 438,75g
D. 238,50
Cu 11. un mt lng d axit axetic 20,7g ancol etylic ( c H2SO4 c lm xc tc ) . n khi phn ng dng
li thu c 16,5g este . Hiu sut ca phn ng este ho l
A. 75%
B. 62,5%
C. 60%
D. 41,67%
Cu 12. X phng ho hon ton 14,55g hn hp hai este n chc X,Y cn 150 ml dung dch NaOH 1,5M .
Sau phn ng c dung dch thu c hn hp hai ancol ng ng k tip v mt mui duy nht . Cng
thc cu to thu gn ca hai este l
A. HCOOCH3 v HCOOC2H5
B. CH3COOCH3 v CH3COOC2H5
B. C2H5COOCH3 v C2H5COOC2H5
D. C3H7COOCH3 v C4H9COOC2H5
Cu 13. Mt este to bi axit n chc v ru n chc c t khi hi so vi kh CO2 bng 2 . Khi un
nng este vi dung dch NaOH to ra mui c khi lng ln hn lng este phn ng . Cng thc cu to thu
gn ca este l
A. CH3COOCH3
B. HCOOC3H7
C. CH3COOC2H5
D. C2H5COOCH3
Cu 14. Thc hin phn ng este ho hn hp gm 322,5g axit metacrylic v 150g ancol metylic vi hiu
sut t 60% . Khi lng metyl metacrylat thu c l
A. 187,5g
B. 225g
C. 262,5g
D. 300g
Cu 15. Cho 52,8g hn hp gm hai este no, n chc l ng phn ca nhau c t khi hi so vi H 2
bng 44, tc dng vi 2 lit dung dch NaOH 0,6M ,ri c cn dung dch va thu c cn li 66,9g cht rn B.
Cng thc phn t ca hai este l
A. HCOOC2H5 v CH3COOCH3
B. C2H5COOCH3 v CH3COOC2H5
C. HCOOC3H7 v CH3COOC2H5
D. HCOOC3H7 v CH3COOCH3
Cu 16. Este X c cng thc phn t C7H12O4 , khi cho 51,9g X tc dng vi 300g dung dch NaOH 4% th
thu c mt ancol hai chc Y v 26,7g hn hp hai mui . Cng thc cu to thu gn ca X l

A. HCOO - (CH2)4- OOCCH3

B. CH3COO- (CH2)3-OOCCH3
C. C2H5COO- (CH2)3- OOCH
D. CH3COO-(CH2)2- OOCC2H5
Cu 17. Cho 2,64g mt este ca ca axit cacboxylic n chc v ru n chc phn ng va ht vi 60ml
dung dch NaOH 0,5M thu c cht X v cht Y . t chy hon ton m gam cht Y cho 3,96g CO 2 v 2,16g
H2O . Cng thc cu to ca este l
A. CH3COOCH2CH2CH3
B. CH2= CHCOOCH3
C. CH3COOCH= CH3
D. HCOOCH2CH2CH3
Cu 18.X phng ho hon ton mt tri este X bng dung dch NaOH thu c 9,2g glixerol v 83,4g mui
ca mt axit bo no B . Cht B l
A. axit axetic
B. axit panmitic
C. axit oleic
D. axit stearic
Cu 19. Cu no sau y khng ng?
CH3COOCH=CH2 cng dy ng ng vi CH2= CHCOOCH3
A.
CH3CH2COOCH= CH2 tc dng c vi dung dch NaOH thu c anehit v mui
B.
CH3COOCH= CH2 tc dng c vi dung dch Br2
C.
CH3COOCH= CH2 c th trng hp to polime
D.
Cu 20. X phng ho 4,4g etyl axetat bng 100 ml dung dch NaOH 1M . Sau phn ng xy ra hon ton ,
c cn dung dch thu c thu c cht rn khan c khi lng l
A. 6,1g
B. 61g
C. 4,1g
D.41g
Cu 21. Mt este cng thc phn t l C4H6O2 , khi thu phn trong mi trng axit thu c anehit axetic .
Cng thc cu to thu gn ca este l
A. CH2 = CHCOOCH3
B. HCOOC(CH3) = CH2
C. HCOOCH = CHCH3
D. CH3COOCH = CH2
Cu 22. X l mt este n chc , c t khi hi i vi CH 4 l 5,5 . Nu em un 4,4g este X vi dung
dch NaOH d ,thu c 4,1g mui . Cng thc cu to thu gn ca X l
A. HCOOCH2CH2CH3
B. HCOOCH(CH3)2
C. C2H5COOCH3
D. CH3COOC2H5
Cu 23. Hai este n chc X v Y l ng phn ca nhau .Khi ho hi 3,7g X thu c th tch hi ng
bng th tch ca 1,4 gam N2 ( o cng iu kin nhit ) . Cng thc cu to thu gn ca X v Y l
A. C2H5COOCH3 v HCOOCH(CH3)2
B. HCOOC2H5 v CH3COOCH3
C. C2H3COOC2H5 v C2H5COOC2H3
D. HCOOCH2CH2CH3 v CH3COOC2H5
Cu 24. Thu phn este c cng thc phn t C4H8O2 ( vi xc tc axit) , thu c 2 sn phm hu c X v Y
. T X c th iu ch trc tip ra Y . Vy cht X l
A. ancol metylic
B. etyl axetat
C. axit fomic
D. ancol etylic
Cu 25. Hp cht hu c X cha mt loi nhm chc c CTPT C8H14O4 . Khi thu phn X trong dung dch
NaOH thu c mt mui v hn hp hai ru A, B . Phn t ru B c s nguyn t cacbon gp i phn t ru
A . Khi un nng vi H2SO4 c iu kin thch hp A cho mt olefin v B cho 3 olefin ng phn . CTCT
thu gn ca X l
A. CH3OOCCH2CH2COOCH2CH3
B. C2H5OCO- COOCH2CH2CH2CH3
C. HOCOCH2CH2CH2CH2COOCH3
D. C2H5OCO - COOC(CH3)3
Cu 26. Thu phn cht X c CTPT C8H14O5 thu c ru etylic v cht hu c Y .Cho bit nX = nC2H5OH =
1/2nY . Y c iu ch trc tip t glucoz bng phn ng ln men , trng ngng Y thu c mt loi
polime.CTCT thu gn ca X l .
A. C2H5OCOCH(OH)CH2COOC2H5
B. CH2(OH)CH2COOCH2CH2COOC2H5
C. C2H5OCOCH- COOC2H5
D. CH3CH(OH)COOCH(CH3)COOC2H5
Cu 27. Hp cht hu c X n chc cha C,H,O . t chy hon ton X thu c nCO2 = nO2=1,5 nH2O . Bit
X tc dng c vi NaOH v tham gia phn ng trng gng . CTCT thu gn ca X l
A. HCOOCH2CH3
B. HCOOCH= CH2
C. HCOOCH3
D. HCOOCH2CH=CH2
Cu 28. Trn 13,6 gam phenyl axetat vi 250 ml dung dch NaOH 1M .Sau khi phn ng xy ra hon ton c
cn dung dch sau phn ng thu c m gam cht rn khan . Gi tr ca m l
A. 8,2
B. 10,2
C. 19,8
D. 21,8
Cu 29. Thu phn este X trong mi trng axit thu c hai cht hu c A, B. Oxi ho A to ra sn phm l
cht B . Cht X khng th l
A. etyl axetat
B. etilen glicol oxalat
C. vinyl axetat
D. isopropyl propionat
Cu 30. X phng ho 13,2 gam hn hp hai este HCOOCH 2CH2CH3 v CH3COOC2H5 cn dng 150 ml dung
dch NaOH x ( mol/l) .Gi tr ca x l
A. 0,5
B. 1
C. 1,5
D. 2
Cu 31. X phng ho hon ton 0,1 mt cht hu c X ( cha C, H,O ) cn va 300 ml dung dch
NaOH 1M , c cn dung dch sau phn ng thu c 24,6 gam mui khan . CTPT ca X l
A. (HCOO)3C3H5
B. (CH3COO)3C3H5
C. C3H5(COOCH3)3
D. (CH3COO)C2H4

Cu 32. Hn hp X gm 2 este n chc mch h , l ng phn ca nhau . Cho m gam X tc dng va

vi 100 ml NaOH 1M thu c mt mui ca axit cacboxylic v hn hp 2 ancol . Mt khc nu t chy hon
ton m gam X th thu c 8,96 lt CO2(ktc) v 7,2 gam H2O . CTCT thu gn ca 2 este l
CH3COOCH2CH2CH3 v CH3COOCH(CH3)2
A.
HCOOCH(CH3)2 v HCOOCH2CH2CH3
B.
CH3COOCH2CH2CH2CH3 v CH3COOCH(CH3)CH2CH3
C.
CH3COOCH(CH3)C2H5 v CH3COOCH(C2H5)2
D.
Cu 33. Dy thuc th thch hp phn bit 4 cht lng ring bit : ancol etylic, anehit axetic, axit
axetic, metyl fomiat ng trong 4 l mt nhn l
A. Na, dd AgNO3/NH3
B. giy qu tm , NaOH
C. giy qu tm , dd AgNO3/NH3
D.Cu(OH)2, NaOH
Cu 34. Hn hp X gm 2 cht hu c A, B ch cha mt loi nhm chc . Cho m gam X tc dng ht vi
NaOH thu c mt mui ca axit hu c n chc v hn hp 2 ancol , tch nc hon ton hai ancol ny
iu kin thch hp ch thu c mt anken lm mt mu 24g Br2 . Bit A, B cha khng qu 4 nguyn t
cacbon trong phn t . Gi tr ca m l
A. 11,1
B. 22,2
C. 13,2
D. 26,4
?Cu 35. Trn 100 ml CH3COOH 1M nguyn cht vi 10ml ancol etylic 460 ( D = 0,8g/ml) . un nng hn hp
ny sau mt thi gian ri cho tc dng vi Na d th thy c c 3,584 lt H2 (ktc) . Khi lng este sinh ra l
A. 14,08
B. 28,16
C. 9,48
D. 1,76
Cu 37.
Cu 38. Mt loi m cha 40% olein , 20% panmitin v 40% stearin. X phng ho hon ton m gam m trn
thu c 138g glixerol. Gi tr ca m l
A. 1209
B. 1304,7
C. 1326
D. 1335
Cu 39. X phng ho 1kg lipit c ch s axit l 2,8 ngi ta cn dng 350ml KOH 1M . Khi lng glixerol thu
c l
A. 9,2g
B. 18,4g
C. 32,2g
D. 16,1g
Cu 40.
Cu 41.
Cu 42. Hp cht hu c mch h X l este n chc , khng no, c mt ni i gia cacbon vi cacbon .
Trong phn t X c s nguyn t cacbon ng vi s nguyn t cacbon ca hirocacbon iu kin thng
th kh . un X vi dung dch NaOH c mui X1 v cht hu c X2 , em X2 tc dng vi nc clo c cht
hu c X3 c kh nng ho tan Cu(OH)2 . X c tn gi l
A. metyl acrylat
B. metyl metacrylat
C. anlyl fomiat
D. vinyl axetat
Cu 43. X l hn hp 2 este ca cng mt ancol no , n chc v hai axit no, n chc ng ng k
tip . t chy hon ton 0,1 mol X cn 6,16 lt O 2 ( ktc). un nng 0,1 mol X vi 50g dung dch NaOH
20% n phn ng hon ton , ri c cn dung dch sau phn ng c m gam cht rn . Gi tr ca m l
A. 13,5g
B. 7,5g
C. 15g
D. 37,5g
Cu 44. X l este to c gia glixerol v hai axit ( fomic v axetic) . X tc dng c vi Na gii phng H2 .
Tng s cng thc cu to tho mn iu kin ca X l .
A. 1
B. 2
C. 3
D. 4
Cu 45. Mt loi m cha 70% olein ( glixeryl trioleat) v 30% stearin ( glixeryl tristearat) v khi lng . Khi
lng x phng Na thu c khi x phng ho hon ton 100 kg m l
A. 90,8 kg
B. 68 kg
C. 103,16 kg
D. 110,5 kg
Cu 46. t chy hon ton x gam este E cn 0,2 mol O2 . Cho sn phm chy c hp th ht vo dung
dch KOH thy khi lng dung dch tng 12,4 gam . Cng thc phn t ca E l
A. C4H6O4
B. C4H8O2
C. C3H6O2
D. C2H4O2
Cu 47. Khi thu phn 0,1 mol este X ca 1 ancol a chc v 1 axit n chc cn dng 100 ml dung dch
NaOH 3M . Mt khc khi thu phn 6,35g este cn 3g NaOH . X l
A. glixerol triaxetat
B. glixerol triacrylat
C. etylen glicol iacrylat
D. etylen glicol iaxetat
Cu 48. Khi x phng ho hon ton 40,3g tripanmitin th khi lng glixerol thu c l
A. 3,45g
B. 9,2g
C. 4,6g
D. 2,3g
Cu 49. Thu phn hon ton 88,8g mt triglixerit thu c 9,2g glixerol(glixerin) v hai loi axit bo . Hai
loi axit bo l .
A. C15H31COOH v C17H35COOH
B.C17H33COOH v C17H35COOH
C. C17H31COOH v C17H33COOH
D. C17H33COOH v C15H31COOH
Cu 50. x phng ho hon ton 3,28g hn hp hai este c to ra t hai axit n chc , mch h v mt
ancol n chc , mch h cn dng 500 ml dung dch NaOH 0,1M . Khi lng mui thu c sau phn ng x
phng ho l

A. 6,38g
B. 3,68g
C. 5,28g
D. 2,98g
Cu 51. Thc hin phn ng x phng ho gia 0,1 mol mt este n chc X vi 200 ml dung dch NaOH
1M thu c 8,8g ancol v dung dch cha 12,2g cht tan . Este X c tn gi l
A. vinyl fomat
B. benzyl benzoat
C. isoamyl axetat
D. isopropyl axetat
Cu 52.
Cu 53. Cho phenol tc dng vi anhirit axetic thu c m gam phenyl axetat , trung ho axit axetic to
ra sau phn ng cn 2 lt dung dch NaOH 1M . Gi tr ca m l
A. 136
B. 300
C. 27,2
D. 272
Cu 55. Cho 10,28g hn hp hai este n chc tc dng va vi dung dch NaOH thu c 8,48g mui
ca hai axit hu c k tip nhau trong dy ng ng v mt ancol . Mt khc t chy hon ton
20,56g hn hp hai este ny cn 1,26 mol oxi , thu c kh CO2 v 15,12g nc . CTCT ca hai este l
HCOOC(CH3) = CH2 v CH3COOC(CH3) = CH2
A.
HCOOCH2CH = CH2 v CH3COOCH2CH = CH2
B.
CH3COOCH2CH = CH2 v C2H5COOCH2CH = CH2
C.
CH3COOCH = CHCH3 v C2H5COOCH=CHCH3
D.
Cu 56. X phng ho hon ton 20,4g cht rn hu c X n chc bng dd NaOH thu c mui Y v hp
cht hu c Z . Cho Z tc dng vi Na d thu c 2,24 lt H2 ( ktc) . Nung Y vi NaOH rn thu c kh R ,
dR/O2 = 0,5 . Z tc dng vi CuO nung nng cho sn phm tham gia phn ng trng bc .Tn gi ca X l .
A. propyl axetat
B. etyl axetat
C. isopropyl fomat
D. propyl propionat

p n
1A
13D
25D
37C
49B

2B
14B
26B
38B
50B

3B
15C
27B
39D
51C

4A
16D
28D
40B
52C

5A
17D
29D
41A
53D

6A
18B
30B
42D
54D

7C
19A
31C
43A
55C

8C
20A
32B
44C
56C

9C
21D
33C
45C

10B
22D
34C
46C

11D
23B
35C
47C

12A
24D
36C
48C