UBND TNH THI NGUYN K THI CHC HSG TNH LP 12 NM HC 2013-2014

S GIO DC V O TO
MN THI : HA HC{ VNG 1}
CHNH THC
( Thi gian lm bi 180 khng k thi gian giao )

Cu 1: ( 3 im)
1. C 6 l b mt nhn, mi l ng 1 dung dch mui nitrat ca mt kim loi: Ba(NO3)2 , Al(NO3)3,
Pb(NO3)2, Zn(NO3)2, AgNO3 v Cd(NO3)2. Ch c dng ba ha cht lm thuc th, hy nhn bit
tng dung dch mui. Trnh by cch tin hnh th nghim nhn bit mi dung dch mui ng
trong mi l v vit phng trnh ha hc sy ra( dng phng trnh ion).
2. Cho s cc phng trnh ha hc:
(1) X + HCl ---> X1 + X2 +H2O
(2) X1 + NaOH ---> X3 + X4
(3) X1 + Cl2 ---> X5
(4) X3 +H2O +O2 ---X6
(5) X2 + Ba(OH)2 ----> X7
(6) X7 + NaOH ---> X8 + X9 + ...
(7) X8 + HCl ---> X2 + ...
(8) X5 + X9 + H2O ---> X4 +...
Bit cht X3 , X6 v X8 l cc cht kt ta
Hon thnh cc phng trnh ha hc v cho bit cht X,...,X9.
Cu 2: (4 im)
1. Cho ba nguyn t A,R,X ( ZA<ZR<ZX) u nhm A v khng cng chu k trong bng tun hon.
Tng s lng t chnh ca electron cui cng ca ba nguyn t nguyn t A, R, X ( k hiu ln lt
l nA, nR, nX) bng 6; tng s lng t ph ca chng bng2; tng s lng t t l -2, v tng s
lng t spin bng -1/2 trong s lng t spin eA l +1/2.
a, xc nh A, R, X. Cho bit dng hnh hc ca phn t A2R v A2X. So snh gc ha tr trong hai
phn t v gii thch.
b, i vi phn t A2XR3 v ion XR42-, hy vit cng thc kiu Lewis, cho bit dng hnh hc v
trng thi lai ha ca nguyn t trung tm.
2. Hp cht v c X thnh phn c hai nguyn t, c 120<MX< 145. Cho X phn ng vi O2 thu
c cht duy nht Y. Cho Y phn ng vi H2O thu c hai axit c c l A v B. A phn ng vi
dung dch bc nitorat thu c kt ta trng C, kt ta ny tan trong dung dch NH3. B phn ng vi
dung dch NaOH d thu c mui D. D phn ng vi dung dch AgNO3 thu c kt ta mu vng
E. Cht X khi phn ng vi nc thu c hai axit G v A, khi un nng G thu c axit B v kh H.
Xc nh cng thc phn t ca cc cht A, B,C,D,X,Y,G,H.
Cu 3: 3 im
1. Hirocacbon A c cng thc phn t l C9H10. A c kh nng tc dng vi Br2 khan, xc tc bt
Fe,to. Cho A tc dng vi H2 xc tc Ni/to. Thu c cht B c CTPT l C9H12/. Oxi ha B bng O2
trong H2SO4 thu c Axeton. Xc nh cng thc phn t v gi tnA,B. Vit phng trnh ha hc
sy ra. Trnh by c ch phn ng khi B tc dng vi Br2 khan, xc tc bt Fe, to.
2. Vit phng trnh ha hc thc hin cc phn ng sau:
Cu 4:
1. a, tnh PH ca dung dch A gm KCN 0,12M; NH4Cl 0,15M v KOH 0,155 M.
b, tnh th tch dung dch HCl 0,21 M cn cho vo 50 ml dung dch A pH ca hn hp thu c
bng 9,24.
Cho pKa ca HCN l 10-9,35; ca NH4+ l 10-9,24.
2. Cho 37,2 g hn hp X gm: R, FeO, CuO ( R l kim loi ha tr II v hidroxit ca R khng c tnh
lng tnh) vo 500 dung dch HCl 14,6%(HCl dng d), sau phn ng thu c dung dch A v
cht rn B c khi lg 9,6 g(ch cha mt kim loi) v 6,72 lit H2 .(ktc).cho dung dch A phn ng
KOH d, thu c kt ta D. Nung kt ta D trong khng kh n khi lng khng i thu uc
34g cht rn E gm hai oxit.
a, tm R v phn trm cc cht c trong hn hp X.
b, Tnh nng phn trm cc cht c trong dung dch A.
Cu 5: 5 im
1.hn hp X gm hai cht A, B l ng phn ca nhau cha C,H,O, mi cht ch cha mt nhm
chc, u c phn ng vi NaOH theo t l 1:1. Ly 12,9 g hn hp X cho tc dng va vi 75 ml

dung dch NaOH 2M thu c hn hp Y.

a, xc nh cng thc phn t ca A v B.
b, Chia hn hp Y thnh hai phn bng nhau. Mt phn cho tc dng ht vi dung dch AgNO3 trong
NH3 d thu c 21,6 g kt ta Ag. Mt phn em c cn thu c 6,55 g hn hp mui khan. Xc
nh cng thc cu to ph hp ca A,B v tnh khi lng mi cht trong 12,9 g hn hp X.
2.Thy phn khng hon ton peptit A c khi lng mol l 293 vC v cha 14,3% N theo khi
lng. Thu c 2 peptit B v C. Mu cha 0,472 g peptit B khi un nng, phn ng hon ton vi
18ml d2 HCl 0,222M. Mu cha 0,666g peptit C khi un nng, phn ng hon ton vi 14,7 ml dung
dch NaOH 1,6% c khi lng ring 1,022g/ml. Xc nh cng thc cu to ca peptit A.
.................................... Ht ............................
Gim th coi thi khng gii thch g thm.
H v tn th sinh:...................
S bo danh:..............................
MNH T NH LI CHC CHN C NHIU SAI ST.
p n mt s cu:
Cu 1: 2. X :FeCO3
Cu 2:1. O< H> S l ba nguyn t cn tm.
2. X l PCl
Cu 3: 1. X l cumen
2? Phn ny khng c phn mn... Xl mn.
Cu 4; 1a. 11.77
b. 35,13ml
2. a, Mg l M. %Mg=29%......... FeO =38,7%.............% CuO= 32,3%
b, FeCl2=4,82%............ HCl=4,85%
MgCl=8,11%
Cu 5:a, C4H6O2
,b, HCOOC3H5. B l este mch vng.
2. A.: GLY-PHE-ALA
-ALA-PHE-GLY