Nguyn Anh Phong

THI TH THPT QUC GIA NM 2016

L Kiu Hng

LN 3 MN HA HC

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thi gm 50 cu trc nghim

p n, video li gii chi tit, cng b trao gii vo ngy 12/10/2015

Cu 1: Thu phn este X c CTPT C4H8O2 trong dung dch NaOH thu c hn hp hai cht hu c Y
v Z trong Y c t khi hi so vi H2 l 16. X c cng thc l
A. HCOOC3H7

B. CH3COOCH3

C. HCOOC3H5

D. C2H5COOCH3

Cu 2: Trong cc cu hnh electron ca nguyn t v ion crom sau y, cu hnh electron no khng
ng
A. 24Cr: (Ar)3d54s1.

B. 24Cr: (Ar)3d44s2.

C. 24Cr2+: (Ar)3d4.

D. 24Cr3+: (Ar)3d3.

Cu 3: Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, C2H2, HCOOH, C2H5OH, HCOOCH3. S

cht trong dy tham gia phn ng trng gng vi AgNO3 /NH3 d l :
A. 3.

B. 6.

C. 4.

D. 5.

Cu 4: Tng s ht (p, n, e) trong 2 nguyn t kim loi X v Y l 142, trong tng s ht mang in
nhiu hn tng s ht khng mang in l 42 ht. S ht mang in ca nguyn t Y nhiu hn X l 12
ht. X v Y ln lt l
A. Ca v Fe.

B. Fe v Cu.

C. Mg v Fe.

D. Al v Fe.

Cu 5: Cht X c cng thc phn t C3H6O2, l este ca axit axetic. Cng thc cu to thu gn ca X l
A. C2H5COOH.

B. HO-C2H4-CHO.

C. CH3COOCH3.

D. HCOOC2H5.

Cu 6: Sc kh CO2 n d vo dung dch NaAlO2. Hin tng xy ra l:

A. Dung dch vn trong sut.
B. C kt ta keo trng, sau kt ta li tan.
C. C kt ta keo trng.
D. C kt ta nu .
Cu 7: Khi thu phn cht bo trong mi trng kim th thu c mui ca axit bo v
A. ancol n chc.

B. phenol.

C. este n chc.

D. glixerol.

Cu 8: Cho Cu tc dng vi dung dch hn hp gm NaNO3 v H2SO4 long s gii phng kh no sau
y?
A. NO2.

B. NO.

C. N2O.

Cu 9: Dy cc cht sau c sp xp theo chiu nhit si tng dn :

A. CH3CH2COOH, CH3COOC2H5, CH3CH2CH2OH.
B. CH3COOH , CH3CH2OH, CH3COOC2H5.
C. CH3CH2CH2OH, CH3CH2COOH , CH3COOC2H5 .
D. HCOOC2H5 , CH3CH2CH2OH, CH3CH2COOH.

D. NH3.

Cu 10: Khng kh trong phng th nghim b nhim bn bi kh clo. kh c, c th xt vo khng

kh dung dch no sau y?
A. Dung dch HCl.

B. Dung dch NH3.

C. Dung dch H2SO4.

D. Dung dch NaCl.

Cu 11: Cho 11,1 gam metyl axetat tc dng vi 500ml dung dch KOH 0,4M un nng, sau phn ng
c cn thu c m gam cht rn khan. Gi tr m l.
A. 17,5

B. 18,5

C. 16,5

D. 15,5

Cu 12: Nng phn trm ca dung dch thu c khi cho 3,9 gam kali tc dng vi 108,2 gam H2O l
A. 4,996%.

B. 5,175%

C. 6,00%

D. 5,000%

Cu 13: Cho 0,15 mol phenyl axetat tc dng vi lng d dung dch KOH 1M (un nng). Th tch
KOH 1M phn ng l.
A. 400 ml
B. 150 ml
C. 300 ml
D. 100ml
Cu 14: Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M
(va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l :
A. 3,81 gam.

B. 5,81 gam.

C. 6,81 gam.

D. 4,81 gam.

Cu 15: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao. Sau
phn ng hn hp rn cn li l:
A. Cu, FeO, ZnO, MgO.

B. Cu, Fe, Zn, Mg.

C. Cu, Fe, Zn, MgO.

D. Cu, Fe, ZnO, MgO.

Cu 16: Cho K d vo 102 gam dung dch CH3COOH 40% thu c V lt kh H2 (ktc). Bit cc phn
ng hon ton. Gi tr ca V l:
A. 7,616

B. 45,696

C. 15,232

D. 25,296

Cu 17: Cho cc cn bng sau trong cc bnh ring bit:

H2 (k, khng mu) + I2 (k, tm)
2NO2 (k, nu )

2HI (k, khng mu)

N2O4 (k, khng mu)

(1)
(2)

Nu lm gim th tch bnh cha ca c 2 h trn, so vi ban u th mu ca

A. h (1) h (2) u m ln.

B. h (1) khng thay i; h (2) nht i.

C. h (1) v h (2) u nht i.

D. h (1) m ln; h (2) nht i.

Cu 18: Cht CH3CH(CH3)CH2COOH c tn gi l:

A. Axit 2 metylpropanoic

B. Axit 2 metylbutanoic

C. Axit 3 metylbutan1oic

D. Axit 3 metylbutanoic

Cu 19: Cho cn bng ha hc: 3H2(k) + N2(k)

2NH3(k). Gi nguyn nhit , nn th tch hn hp xung

cn mt na. Nhn xt no sau y v tc phn ng thun (vt) v tc phn ng nghch (vn) l chnh xc
A. vt gim, vn tng

B. vt tng, vn gim

C. vt v vn u gim

D. vt v vn u tng

Cu 20: Hn hp X gm: Fe(OH)2, Cu(OH)2, Ni(OH)2, Zn(OH)2, Al(OH)3, AgCl. Cho hn hp X vo

dung dch NH3 d th c t i a bao nhiu cht tan ?

A. 3.

B. 5.

C. 4.

D. 2.

Cu 21: Phn ng CH3CH2OH + CuO CH3CHO + Cu + H2O thuc loi phn ng:
A. Phn ng th

B. Phn ng cng

C. Phn ng tch

D. Khng thuc c 3 loi phn ng trn

Cu 22: Dy gm cc ion no sau y khng tn ti trong cng mt dung dch?

A. K+; NO3-; Mg2+; HSO4-

B. Ba2+; Cl- ;Mg2+; HCO3-

C. Cu2+ ; Cl-; Mg2+; SO42-

D. Ba2+; Cl- ;Mg2+; HSO4-

Cu 23: Trong cc cht di y, cht no c gi tn l ivinyl?

A. CH2 = C = CH CH3

B. CH2 = CH CH = CH2

C. CH2 = CH CH2 CH = CH2

D. CH2 = CH CH = CH CH3

Cu 24: Cho cc cht: NaHSO3; NaHCO3; KHS; NH4Cl; AlCl3; CH3COONH4, Al2O3, Zn, ZnO,
NaHSO4. S cht lng tnh l
A. 8.

B. 7.

C. 6.

D. 5.

Cu 25: Cho cc pht biu sau:

(1). Tt c cc anken u c cng thc l CnH2n.
(2). t chy hon ton mt ankan bt k th lun cho s mol H2O ln hn s mol CO2.
(3). Cc ankin u c kh nng to kt ta trong dung dch AgNO3/NH3.
(4). Cc ancol no n chc, mch h khi tch nc 1700C (H2SO4/c nng) u c kh nng sinh ra
anken.
S pht biu ng l:
A. 4

B. 3

C. 2

D. 1

Cu 26: Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc
dng vi lng d dung dch Ba(OH)2 to thnh kt ta l:
A. 5.
B. 4.
C. 1.
D. 3.
Cu 27: S ng phn ancol ca hp cht hu c c cng thc phn t C4H8O l:
A. 5

B. 6

C. 4

D. 3

Cu 28: bin mt s du m lng thnh m rn hoc b nhn to ngi ta thc hin qu trnh.
A. Lm lnh
B. Hidro ha (xc tc Ni)
C. C cn nhit cao
D. X phng ha
Cu 29: Cho m gam este n chc, no, mch h tc dng va vi 80 ml dung dch NaOH 1M thu
c hn hp hai cht hu c X v Y. Ly ton b lng Y trn ri t chy ht trong oxi d thu c
4,48 lt kh CO2 (ktc). Bit cc phn ng hon ton. S mol O2 tham gia phn ng t chy l:
A. 0,28
B. 0,26
C. 0,30
D. 0,33
Cu 30: Cho 3,68 gam hn hp cha Mg, Fe vo 100 ml dung dch hn hp cha Fe(NO3)3 0,3M,
Cu(NO3)2 0,4M v AgNO3 0,5M. Sau khi phn ng hon ton thu c dung dch X v 9,08 gam cht
rn. Lc b cht rn ri cho NaOH d vo X thy c m gam kt ta xut hin. Gi tr ca m l :
A. 7,98
B. 8,97
C. 7,89
D. 9,87

Cu 31: Cho 1 mol HCOOH v 1 mol CH3OH vo bnh kn nhit khng i ri thc hin phn ng
este ha. Ngi ta thy hiu sut ca phn ng este ha l 60%. hiu sut phn ng l 75% th ng i
ta phi cho thm vo bnh a mol HCOOH. Gi tr ca a l:
A. 0,80
B. 0,75
C. 0,85
D. 0,70
Cu 32: Khi sc t t n d CO2 vo dung dch hn hp c cha 0,3 mol NaOH, 0,1 mol KOH v
Ca(OH)2. Kt qu th nghim thu c biu din trn th sau :
S mol CaCO3

0,5
0,2

S mol CO2

Gi tr ca a :b l :
A. 4:5
B. 3:4
C. 2:3
D. 3:5
Cu 33: Hn hp X gm 0,15 mol pro pin, 0,1 mol axetilen, 0,2 mol etan v 0,6 mol H2. Nung nng hn
hp X (xc tc Ni) mt thi gian, thu c hn hp kh Y. Cho Y tc dng vi AgNO 3 d trong NH3 thu
c a mol kt ta v 15,68 lt hn hp kh Z (ktc). Sc kh Z qua dung dch Brom d thy c 8,0 gam
brom phn ng. Gi tr ca a l:
A. 0,12

B. 0,14

C. 0,10

D. 0,15

Cu 34: Dung dch A cha H2SO4 0,5M; B l dung dch cha NaOH 0,8M. Ngi ta V1 lt dung dch
A vo V2 lt dung dch B. Thu c dung dch C c PH = 2. T l ca V1 : V2 l :
A. 7:9
B. 9:7
C. 11:9
D. 9:11
Cu 35: X l hn hp cha 3 ancol no, mch h. t chy hon ton 0,06 mol X thu c 6,16 gam CO2.
Th tch (lt) kh O2 (ktc) ti thiu cn dng l:
A. 3,136

B. 4,704

C. 3,584

D. 3,808

Cu 36: Oxi ha hon ton 0,31 gam P thnh P2O5 ri cho ton b lng P2O5 trn vo 100ml dung dch
hn hp cha KOH 0,1M v NaOH 0,15M. Sau khi cc phn ng xy ra hon ton thu c dung dch X
cha m gam mui. Gi tr ca m l :
A. 1,72
B. 1, 59
C. 1, 69
D. 1,95
Cu 37: Xc nh cc cht (hoc hn hp) X v Y tng ng khng tha mn th nghim sau:

A. NaHCO3 , CO 2 .

B. Cu NO3 2 ; NO 2 , O 2 .

C. K 2 MnO 4 ;O 2 .

D. NH 4 NO3 ; N 2 O.

Cu 38: Cho mt lung kh CO d qua 18,56 gam Fe3O4 nung nng. Hn hp kh thu c sau phn ng
cho qua dung dch Ca(OH)2 d thy xut hin m gam kt ta trng. Bit cc phn ng hon ton. Gi tr
ca m l:
A. 8
B. 24
C. 16
D. 32

Cu 39: Ha tan ht 5,36 gam hn hp FeO, Fe2O3 v Fe3O4 trong dung dch cha 0,03 mol HNO3 v
0,12 mol H2SO4, kt thc phn ng thu c dung dch X v 0,01 mol kh NO (sn phm kh duy nht).
Cho 0,04 mol Cu vo X, sau phn ng c cn dung dch thu c m gam mui khan. Gi tr ca m l
A. 19,424.
B. 23,176.
C.18,465.
D. 16,924.
Cu 40: Ha tan ht 11,54 gam hn hp rn X gm Al, Mg, Al(NO3)3 v Mg(NO3)2 trong dung dch
cha H2SO4 v 0,1 mol NaNO3 (un nng nh), kt thc phn ng thu c dung dch Y ch cha cc
mui sunfat (khng cha mui amoni) v V lt (ktc) hn hp kh Z gm NO, N2O v N2. T khi ca Z
so vi He bng 99,5/11. Cho dung dch NaOH 1,5M vo dung dch Y n khi kt ta cc i th dng
480 ml. Ly kt ta nung ngoi khng kh n khi khi lng khng i thu c 12,96 gam rn. Gi tr
ca V gn nht vi
A. 2,2
B. 2,4
C. 3,2
D. 3,6
Cu 41: un nng 8,68 gam hn hp cc ancol no, n chc trong H2SO4 c thu c hn hp sn
phm X gm cc ancol d, anken, ete v H2O. Bit tng s mol cc ete trong X l 0,04 mol. Ngi ta t
chy hon ton lng ete v anken trong X th thu c 0,34 mol kh CO2. Mt khc, nu t chy ht
lng ancol d trong X th thu c 0,1 mol CO2 v 0,13 mol H2O. Nu t chy ht 8,68 gam cc ancol
trn bng O2 d th tng khi lng CO2 v H2O thu c s gn nht vi:
A. 29 gam
B. 30 gam
C. 31 gam
D. 32 gam
Cu 42: t chy hon ton m gam hn hp X gm etilen, axetilen v andehit axetic cn va V lt O2
ktc, thu c hn hp sn phm Y. Sc Y qua dung dch Ca(OH)2 d thu c 40 gam kt ta. Nu
cho 2m gam hn hp X vo dung dch nc Brom d th c 0,5 mol Br 2 phn ng. Cn nu cho 3m gam
hn hn hp X vo Br2 trong dung mi CCl4 d th c 0,6 mol Br 2 phn ng. Gi tr ca m v V ln lt
l:
A. 6,40 v 14,56
B. 7,80 v 11,2
C. 6,6 v 13,44
D. 6,3 v 12,32
Cu 43: Cho 29,2 gam hn hp X gm Al2O3, CuO, Al, Cu vo trong dung dch HCl d thu c 5,6 lt
kh H2 (ktc), dung dch sau phn ng ch cha HCl d v mt mui, lc ly phn cht rn khng tan cho
vo dung dch HNO3 d, thu c 8,96 lt kh NO2 (ktc,sn phm kh duy nht). Bit cc phn ng hon
ton. Phn trm khi lng ca oxi trong hn hp X gn nht vi gi tr no sau y :
A. 20%
B. 25%
C. 15%
D. 30 %
Cu 44: t chy hon ton mt hn hp X gm hai hirocacbon A, B ng ng lin tip (thuc mt
trong cc dy ng ng ankan, anken, ankin) ri cho ton b sn phm vo dung dch nc vi trong,
thy xut hin 20 gam kt ta v khi lng dung dch trong bnh tng thm 7,4 gam. Cho t t dung dch
NaOH 1M vo dung dch nc lc sau phn ng, thylng kt ta tng dn, khi kt ta cc i th lng
NaOH cn dng t nht l 150ml. Cho hn hp X phn ng vi Br2 vi t l 1:1 th s sn phm c th thu
c l:
A. 1
B. 2
C. 3
D. 4
Cu 45: Cho m gam hn hp X cha Fe, Fe3O4 v Fe(NO3)2 tan ht trong 320 ml dung dch KHSO4 1M.
Sau phn ng thu c dung dch Y cha v 0,896 lt kh NO (ktc, sn phm kh duy nht). C cn
dung dch Y thu c 59,04 gam mui trung ha. Mt khc, cho NaOH d vo Y th thy c 0,44 mol
NaOH phn ng. Phn trm khi lng ca Fe c trong X gn nht vi :
A. 2,5%
B. 2,8%
C. 4,2%
D. 6,3%
Cu 46: A, B, C, D c cng cng thc phn t C4H6O4 u phn ng vi NaOH theo t l mol 1:2. Trong
:
- A, B u to mt mui v mt ancol.
- C, D u to mt mui, mt ancol v nc.
Bit rng khi t chy mui do A, C to ra th trong sn phm chy khng c nc. Cng thc cu to
dng thu gn ca A, B, C, D ln lt l:

A.HCOOCH2 - CH2OOCH; H3COOC-COOCH3; HOOC - COOC2H5; HOOC - CH2 - COOCH3.

B.H3COOC-COOCH3; HCOOCH2 - CH2COOH; HOOC - COOC2H5; HOOC - CH2 - COOCH3.
C.H3COOC-COOCH3; HCOOCH2 - CH2OOCH; HOOC - COOC2H5; HOOC - CH2 - COOCH3.
D.H3COOC-COOCH3; HCOOCH2 - CH2OOCH; HOOC - CH2 - COOCH3; HOOC - COOC2H5.
Cu 47: Cho X,Y l 2 axit cacboxylic n chc, mch h, cha no ( c mt ni i C=C; M X M Y ); Z
l ancol c cng s nguyn t cacbon vi X; T l este 3 chc to bi X,Y v Z. Chia 40,38 gam hn hp
E gm X, Y, Z, T lm 3 phn nhau :
Phn 1 : t chy hon ton thu c 0,5 mol CO 2 v 0,53 mol H 2 O .
Phn 2 : Cho tc dng vi dung dch Brom d th thy s mol Brom phn ng l 0,05 mol.
Phn 3 : Cho tc dng vi lng va dung dch hn hp gm KOH 1M v NaOH 3M ri c
cn thu c m gam cht rn khan. Gi tr m l :
A. 6,66.
B. 5,04.
C. 6,8.
D. 5,18.
Cu 48: Cho 0,1 mol Fe; 0,15 mol Fe(NO3)2 v m gam Al tan ht trong dung dch HCl. Sau phn ng thu
c 2,352 lt (ktc) hn hp kh X gm NO v N2O c t khi so vi H2 l 16, dung dch Y ch cha
47,455 gam mui trung ha. Cho NaOH d vo Y th th y c 0,82 mol NaOH phn ng. Bit cc phn
ng hon ton. Gi tr ca m l :
A. 1,08
B. 1,35
C. 1,62
D. 0,81
Cu 49: A l hp cht hu c cha C, H, O. t chy hon ton 3,08 gam A, hp th ton b sn phm
thu c vo bnh ng 5000 ml dung dch Ca(OH)2 0,02M thy xut hin 6 gam kt ta, phn nc lc
c khi lng ln hn dung dch Ca(OH)2 ban u l 1,24 gam. Bit rng khi lng mol phn t ca A
nh hn khi lng mol phn t ca glucoz; A phn ng c vi NaOH theo t l mol A v NaOH l 1
: 4; A c phn ng trng gng. S ng phn ca A tha mn l:
A. 4
B. 5
C. 6
D. 7
Cu 50: Ha tan ht m gam hn hp rn A gm Mg, Cu(NO3)2, Fe, FeCO3 vo dung dch cha H2SO4
v 0,045 mol NaNO3, thu c dung dch B ch cha 62,605 gam cc mui (khng c ion Fe3+) v thy
thot ra 3,808 lt (ktc) hn hp kh C gm N2, NO2, N2O, NO, H2, CO2 c t khi so vi H2 bng 304/17
( trong C c cha 0,02 mol H2). Cho dung dch NaOH 1M vo dung dch B n khi thu c lng kt
ta ln nht l 31,72 gam th dng ht 865 ml. Mt khc, cho 94,64 gam BaCl2 vo B sau cho tip
AgNO3 d vo th thu c 256,04 gam kt ta. Bit cc phn ng hon ton. Gi tr ca m l :
A. 28,4
B. 27,2
C. 32,8
D. 34,6
..Ht..