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    IIT JEE Advanced 2013 Question Paper II with Solutions pdf Download. Practice model test papers with answer keys. Maths,Physics,Chemistry solved previous papers.

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    286 views40 pages

    IIT JEE Advanced 2013 Question Paper II With Solutions

    Uploaded by

    gayathri
    IIT JEE Advanced 2013 Question Paper II with Solutions pdf Download. Practice model test papers with answer keys. Maths,Physics,Chemistry solved previous papers.

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    auR-2 CODE PAPER-2 w PART |: PHYSICS SECTION — 1 : (One or more options correct Ss 1: (WH a afte wel Awe This section contains 8 multiple choice questions. Each qui hgs four choices A), (B), (C) and (D) out of which ONE or MORE are correct. wa avs F 8 agtood wea & | vale vet ar famed (AB) Nc) silk (0) &, RA O Uw or siftres wet S| SCNT jes of d by measuring the corresponding angles 6 in the range 0 to 90S-FHé Wavelength 2 is exactly known O° 1. Using the expression 2d sin @= A, one calcul; and the error in @ is constant for all valueof, ane 4 afe, FA wart & | SS 0 AM 0° B aga & a (a) d& a @) aa PRpg el (c) aa 7 Rex ved & (0) d afe ued & | ww ANSWER : D PHYSICS 2. Two non-conducting spheres of radii R, and R, and carrying uniform volume charge densities +p and —p, respectively, are placed such that they partially overlap) shown in the figure. At all points in the overlapping region, Ro (A) the electrostatic field is zero. @ (B) the electrostatic potential is constant. (C) the electrostatic field is constant in magnitude. (0) the electrostatic field has same direction. a} sree R, aM Ry Pea ae Ae wT OL yp VORA ART STAT wa & orate fear rar & | gt thetf wears 8 ow 8 PHS) (A) fer aga da yee | (8) Rer aga fara arax & (c) fer tga aa aT (D) Rew aga aa at eo S The figure below shows the variation of specific heat capacity (C) of a solid as a function of temperature (7). The temperature is increased continuously from 0) to 500 K at a constant rate. Ignoring any volume change, the following statement) is (are) correct to a reasonable approximation. (A) the rate at which heat is absorbed in the range 0-100 K varies lin igh temperature 7. t (8) heat absorbed in increasing the temperature from 0-100 K is less required for increasing the temperature from 400-500 K. (C) there is no change in the rate of heat absorption in the range 40! (D) the rate of heat absorption increases in the range 200-300 K. ° Ta & | aa #0 8 500 K ae TH Rita afez arr 4 oRads steria 8, Pe Var A a Thera arc we Be 7 (A) 0-100K% aa, sraxhfta Ge (8) 0-100 K am aA Pag FEM FT GOT Gt Ger 3 (C) sraeitftar Ger at ax 4d0>5Q0 ar & aa aoRafea & | & da ag WHE | The radius oe ai Ky ron in a Hydroger-like atom is 4.5 ap, where ay is the . 3h Bohr radius. IfSO(bitSangular momentum is 5. It is given that 4 is Planck constant and Ris Siveg) instant. The possible wavelength(s), when the atom de-excites, is (are) Ww RAM RAY Eclaght He DH HTN 4S ay F FET ay Ae Poa F | aaa wtotta wan SA fear & fra ater Precio a R Resat Dear & option a4 oe seater fAfereor a eee a ree Oe ® ie os o# ANSWER : AC PHYSICS Two bodies, each of mass M, are kept fixed with a separation 21. A particle of mass ‘mis projected from the midpoint of the line joining their centres, perpendicular to t line. The gravitational constant is G. The correct statement(s) is (are) (A) The minimum initial velocity of the mass m to escape the gravitational "Z) the two bodies is 4~\ ae (8) The minimum initial velocity of the mass m to escape the gravitatiofiaNiel the two bodies is 2 ~\ ae Oo (C) The minimum initial velocity of the mass m to escape the grAvitZfiond| field of the two bodies is ~\ 2G. (0) The energy of the mass m remains constant. fist fori cele or samt Me, & dra fist & a} a ast are Yer & ey vafta fear crn & | yecaeter Fadia Ge (A) 2 fist & qecrato as 8 vara &, mor ETT oR TT 4 Me | 8) @ fil & qocrefo aa = Se m GI TT Ue at 2 Mey (C) @ fist & gered & fey Sar m BT PATH UNE aT 2GM » | (0) arm Bh eI ° ANSWER : BD oO Ss PHYSICS 6. Aparticle of mass m is attached to one end of a mass-less spring of force ceggtant A, lying on a frictionless horizontal plane. The other end of the spring is TR particle starts moving horizontally from its equilibrium position at time ¢ initial velocity up, When the speed of the particle is 0.5 u, it collides elastloflly with a rigid wall. After this collisien, (A) the speed of the particle when it returns to its equilibrium posifid is (8) the time at which the particle passes through the equilibrium posi the first time is im vf G io (C)_ the time at which the maximum compression of thé Spring Ovéurs is ¢ (0) the time at which the particle passes ZF ig p= on [tt second time is ¢ = 3 Ee rium position for the abet afta daw wl eek act xfta fier & ww RRS m SoA G1 GI YSt gan e | ga fri ag & | ae oo ot BRT S BAT 1 = OUR UPA SO mfr 8 wer S| wa wr aH mG 0.5 Bh &, TE VE FS Wag ora 8 | gu deg }& ae (A) sa aor oft i AAS uy BIAS (8) Fa em ah rT ae yore & ae ra = 2 BE (c) oa fier 4 en 8 aw aren 4 [Be 2. [ne \ PHYSICS A steady current / flows along an infinitely long hollow cylindrical conductor of ra R. This cylinder is placed coaxially inside an infinite solenoid of radius 2, solenoid has n turns per unit length and carries a steady current /. Consider int Pata distance r from the common axis. The correct statement(s) is (are) (A) Inthe region 0 22, the magnetic field is non-zero. Wer Fen & shia wea Ghai aerwy ort BH cas 18E THE | Be ter O) 2R Broa at aria oeaferara war wae | we uftaferar Fn we ute gos was FET A® \ we fg pe fag vt erat Or Bl we 8, Sl aT) FHT (A) O fi (8) If the wind blows from the source to the observer, f,> fi. oO (C) If the wind blows from observer to the source, fy < fj, & (D) If the wind blows from the source to the observer, f a ares, for velo at afta, va et Ut WU GR a sik aes | ay Use F fee Awe ar Owe aes f, waft Sitcom trem cere wa eN nm aaa Preaet ary 4 ea a afr & re ke (A) af& arg dere @ eta at fee >fi | & Ashi Wah & A M'. The masses of some neutral atoms are given in the below: we afte 4.x wT FO (4-2) AI Vd Zee & geri UG daz | semi Gt ot & wager Gul of det Gat wed F | ww ant fre m, Va m, FAA & A were aPrat A fratea et wear zy (mF m2) < M | Tat my Ti ms FAM & St ware PH wh worry Hes, or at afte war weed & WE (m; +m) >M" Ig weep renee 1H 1.007825 wu iH 2.014102 u fA 050-2 tHe 4.002603 u Sri [6015123 u [727 |7.016004u | MAN ROI ;Su [Bsc [81.916709u | Ga 151.9198030 Pb 205.974455 u [29 0388 wv BoPo 209.982876 u (Lu = 932 MeVic") aC 14. The correct statement is (A) The nucleus $Zi can emit an al; (B) The nucleus 3)°Po can (C) Deuteron and alpha pat (D) The nuclei j)Zn and $3Se wel weer & es rgo complete fusion. }0 complete fusion (A) “Pre Stiga tor & isa ox Gea e | (B) afar 3!°Po Yay fore a aX Wo & | (C) ser Wer BY wad S | (0) wa) Terr BX wad S | oO 412. The Kein ergy (in keV) of the alpha particle, when the nucleus ;;°Po at rest es alpha decay, is AT aiPre 2°Po torre ora @, da tet oo at aft Got Pe 19 (B) 5422 (C) 3707 (0) 5818 ANSWER: A PHYSICS Paragraph for Questions 13 and 14 Wet 13 sie 14% fag aq A small block of mass 1 kg is released from rest at the top of a rough track. The trachcis circular arc of radius 40 m. The block slides along the track without toppling and a fridfigfal force acts on it in the direction opposite to the instantaneous velocity. The work d ‘overcoming the friction up to the point 0, as shown in the figure below, is 150 J; acceleration due to gravity, g = 10 ms”), We we Th eas fy B WH 1 se Y Yew a frmraen o vist 1 ae 1 40 m Broa or Gia age | Yewr ory wer ue fen Gee eV ee Jem wy yw aie got arent a ot faetta feen Fara F | : fry Que am & fay ai ot afamr wet & fay i507 ei (Tees ANT g GT APT = 10 ms cfSTy), 13. (D) 20 ms" or :B 14, The magnitude of We nokyal reaction that acts on the block at the point Q is FZOW, TeH WR ret siftrcia ser ar UAT e (A) 7.54, Ov) 86N (C) 115N (D) 225N ws ANSWER: A PHYSICS Paragraph for Questions 15 and 16 Wed 15 sie 16 & fag aq A thermal power plant produces electric power of 600 kW at 4000 V, which is transported to a place 20 km away from the power plant for consumers’ usage. It transported either directly with a cable of large current carrying capacity or by combination of step-up and step-down transformers at the two ends. The dra direct transmission is the large energy dissipation. In the method using trai dissipation is much smaller. In this method, a step-up transformer is used al so that the current is reduced to a smaller value. At the consumers’ end, a reasonable to assume that the power cable is purely resistive and ideal with a power factor unity. All the currents and voltages ment we ante foes das 600 KW aT ef 4000 VO axa unten & soar & fey a ort ort & | gear a ay Ry FEAT ATCA ofa 8 Fo oT wea & a al fel we vert a Nal frm or wear S | yeaa Yor ar ale ae z fe geri iN BH FES aie ea & vate grote & soar & ate A aa aga Ha ah ate Foye seat graork waa a atk ema ora & fire Af Re a oral geawre er gett fear ora = dee ® faga afta A on wh | ae APT oT Ue a RRIGPR sree & a Grer adr Woe va, wera enisil ¢ deeansit Br A ms aT AS | 45. If the direct transmission meth: power dissipation (in %) during afe tS See wr ora Reerfer AY erfaeer ara (% A) (A) 20 (8) S or 46. In the methodusing\the Yansformers, assume that the ratio of the number of tums in the primary tothat it\the secondary in the step-up transformer is 1 : 10. If the power to the consumers K@s to be supplied at 200 V, the ratio of the number of turns in the primary tf/thatNa\the secondary in the step-down transformer is oi 4, ve an fe cert greet & mea Pl een wr aGUT 1: 108 | ale fea alsa, Sorte wt 3 dt apart gear 4 ete a fedae & adel Ht de 0.4 2 km S Ta wee TIT aT (c) 40 (0) 50 (B) 150:1 (C) 100:1 (0) 50:1 ANSWER: A SECTION - 3 : (Matching List Type) ws —3: (aor Eh wa) WN This section contains 4 multiple choice questions. Each question has matching }ists The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is we ws 4 4 agtwor wed & | cede oer A Gert Eee | fea faqer (A), (B), (C) ie (0) & ry S Sar vs WAT | 17. Match List I with List II and select the correct answer using soy below the lists : List 1 List II P. Boltzmann constant 1 (MPT) Q. Coefficient of viscosity 20 (ML T}) R. Planck constant 3 S. Thermal conductivity 4 Bast EAA Gata sire ate arat ar its ae yell ae wel oa GP: aa Pp. aecean Pradie Q Ma pie R s wie Frade BST Tera Codes : (A) (8) (c) (D) Hew RROD HE Rn-Ao NSWER : C SS 18. A right angled prism of refractive index :1, is placed in a rectangular block of refractive index 12), which is surrounded by a medium of refractive index 4, as iw in the figure. A ray of light ‘e’ enters the rectangular block at normal incidence. Depending upon the relationships between 4, 42, and 1, it takes one of tHe/our! possible paths ‘ef’, ‘eg’, ‘eh’ or ‘ei’. ERS) Wy woaig & wae fist Oy, soahie & sraarHRe ww a RET AG | el aren y, smacdtie & are & fers 4H caty ongene feet es TNE at PRT ‘e’ STATOR wit wx afreiaaa arate eel Fl yy, wy BR py BWA frie etch ef were a freer aE ws wei ef, ‘eg’, eh’ A 4 Patt & | Match the paths in List I with conditio Wve indices in List II and select the correct answer using the codes ¢ efists: ae fea wa wl uel G BAfera wiry she Etat & Hd fa wa als wr wah ay gra: List 1/ att n/a PB eof Q erg > My and py > py R. eoh , Ayo 8S. esi v4) My, Hy Codes : PQ Ss a) 2 3,1\4 ) 1 204 (c) 4 203 (0) 2 4 1 we 7 ANSWER : D PHYSICS 19. Match List I of the nuclear processes with List II containing parent nucleus and gne of the end products of each process and then select the correct answer usi codes given below the lists : Ea ge arate urns dt ag & | ey gr aware } we! we sift mPa ds fey mg S| yeah & Ae Ra ay ats wal GR gay List 1 / itt List 1/ att P. Alpha decay 1 POS ENE LL, Romar @. decay 2 hy Barr R. Fission frist S. Proton emission wer sant Codes : P QR a4 201 ®) 1 3 2 (2 1 4 (2) 4 3 2 20. One mole of a monatomic ideal gas is taken along two cyclic processes ESF>G-E and E-F—-H--E as shown in the PV diagram. The procks¢ involved are purely isochoric, isobaric, isothermal or adiabatic. we vera steel te & uw Ha aw, fra 4 cald pv ate & amt wT EF-GE F E>F-HE 4 & oar ore & | tafe errr, Gard, WATE a was S| ES P. GoE 160 PpVo In2 Q GH - 36 PoVo R. FoH 3. 24P Vo s. FoG 4. 31 PoVo Codes P QRS (A) 43 (8) 4 3 a () 3 10 2\4 (2) 1 204 ANSWER: A PART Il : CHEMISTRY SECTION - 1 : (One or more options correct Type) mY farered ware) Bs —1: (TH TT aftr Tet This section contains 8 multiple choice questions. Each question has four ch ( (B), (C) and (D) out of which ONE or MORE are correct. ga aus 4 8 aghtmcn wer & | uetw wer F are faarcn (A), (B), ORES a we ar sift wae | 21. The correct statement(s) about O, is(are) (A) 0-0 bond lengths are equal. (B) Thermal decomposition of O, is endothermic. (C)_ O,is diamagnetic in nature. 5° (D) O, has a bent structure. 0, of Fw aera & ® e (A) 0-0 are @ cag aeTae & | (8) 0, oT ade fete Gersih F | (C) 0, wfergaarra & | € y 0, H ean afr Vt F | & (D) ANSWER 22, In the nuclear transmutation : oe + x ——> ‘Be (X, Y) is(are) (A) (7) , D) (C) @, dD) (0) (wp) Prefer {Be + X \Be + F(X) se @ (B) (p,D) (C) (n, D) (D) (p) Oo KS ANSWER : AB CHEMISTRY 23. The carbon-based reduction method is NOT used for the extraction of (A) tin from SnO, (8) iron from Fe,0; (C) aluminium from ALO, (D) magnesium from MgCO, Sat & Premr aed cert ror FAR ar Fry eT 2 (A) Sn0, & fer (B) Fe,0, 8 SRA (C) 41,0, 8 Yaffe (D) Mgco, iC ANSWER : CD Ss 24, The thermal dissociation = QI of ) is studied under different conditions. CaCOx(3) == Ca0(s)+ CO%s) For this equilibrium, the correct stat Cs are) (A) AHis dependent on T (8) Kisindependent of the } of CaCO, (c) areca areal (0) Avis independent ore ca CO, at a given T st, ifany Caco,erA) & ARIE Br area AAT sraensit a frat 7a | CaCOx(s) wi re (A) kel fe (K) CaCO, & oP OAT OX Prk wet aT B | WR CO, & aa wz fre aa F | & GR a) & wa w Pie et oa z | ANSWER : ABD CHEMISTRY 25. The K,, of Ag,CrO, is 1.1 x 10-2 at 298 K. The solubilty (in mol/L) of 4g,CrQyin a 0.1 M AgNO, solution is (A) 1.1 10-1! (B) 1.1 10-10 (C) 1.1 x 10-2 (D) 1.1 9 K,, (Ag,CrO,) 1 APT 298 KW 1.1 x 10"? & 10.1 MAgNO, y @ facta Areieher Fz (A) 1.1 «107! (B) 11x10! = (C) Lax10-2 — (D) LD 10% is oY ANSWER: B 26. In the following reaction, the product(s) ne) Prefer aire 3 wearers C5 OH C acre SG OH” cH. He Hac! CHo!, CHs P Q R s (A) P (maior) (B) Q (minor) (C)_ R (minor) (D) 5 (major) ANSWER : BD x oct Rhy SC) 27. The major product(s) of the following reaction is(are) aqueous Br (2. equivalents) ©) z oe S SO3H Br Br Ss OH a) P ®) @ (©) (2) s Prefered oifiBrer ae) eT wn CS oH O Weta Bro (3.0 Tera) 5 er on Br AL Soy Ss (C) Rk (0) Ss ° ANSWER : B oO CHEMISTRY 28. After completion of the reactions (I and I), the organic compound(s) in the “AR mixtures is(are) rete sfifrnst (ik m1) & We & ae werafie fam A aire caifral) or ae | ° Bra (1.0 mol) Reaction I: yc S cry ——__— GMP; Oma!) #queous! sri NaOH c O° L Bra (1.0 mol) Reaction: 4,07 ScHy ——————> PRT TE: (4.0 mot) CH3COOH ° oO °O Oo yoo Sonyer Hc? Scers ayc7 Bry BrH,C” jr ‘ONa CHBrs P Q R s T u (A) Reaction I: P and Reaction II: P ZB ne (B) Reaction I: U, acetone and Reaction (C) Reaction I : T, U, acetone and React (D) Reaction I: R, acetone and Rea cetone (A) afifiear1: Psie Se (8) aiftfrar 1: u, wate aie 10, wa (C) afta i: 7, U, W:P T, (0) aftr 1: Rk, wher 1: S, we \ Ric S SECTION - 2 : (Paragraph Type) WS — 2: (PGE VSR) This section contains 4 paragraphs each describing theory, experiment, data etc. questions relate to four paragraphs with two questions on each paragraph. Each of a paragraph has only one correct answer among the four choices {Ay 8).(Q) H Rraidl, Wari shy sitesi ante wl eet act 4 lat ws Vata ano ney 2 ior 9 gv ares oy el oe FI af & ay famed (A), (B), (C) she (D) & fSrrt B dact yw wet S| Paragraph for Questions 29 and 30 Wea 29 Ud 30 & fed argewe A fixed mass ‘m' of a gas is subjected to transformation of state; 11 to M to Nand back to K as shown in the figure we te & fitted Serr ‘mat orn oRa KGL am KY faa art frag ag & Pressure ae N Volu 29. The succeeding operations that enablg thi formation of states are (A) Heating, cooling, heating, (C)_ Heating, cooling, cooling, uftarert Gi $7 sree (A) 74, dst, 14, Sst (Cc) 74, ds, oor, 7H li (8) Cooling, heating, cooling, heating (D) Cooling, heating, heating, cooling , Te (8) 331, 7, ds, TH ow (0) ds, 74, 7H, Sst RA 30. The pair of isochdys provesses among the transformation of states is (A) KtoL Sadie (B) LtoMandNtoK (C) Lto, SBN _ (D) MtoNandNtoK are py Rerferal 4 waaraatra wary Bre ( LaM (8) LUM@RNGK (CLad aN (0) MANSR NOK ANSWER :B 31. 32. CHEMISTRY Paragraph for Questions 31 and 32 WET 31 Ud 32 & ford ayer The reactions of C/, gas with cold-dilute and hot-concentrated NaOH in wat sodium salts of two (different) oxoacids of chlorine, P and Q, ees: th gas reacts with SO, gas, in presence of charcoal, to give a product R. R white phosphorus to give a compound S. On hydrolysis, S' gives (am id of phosphorus, 7. Cl, Te wy otk Bix NaOH & Tey fer ERT wa: SS sie q aftiivar ax of (Pie) IN & sitiara & afar P PAD WF I Cl, (g) aReIA BH Gakefa F so, (g) 8 sififrar |e & Rar DRERG Ent siftiren He ify Ss Sa F | SH Ter, WERE BT we srrdisra Tele | P and Q, respectively, are the sodium salts of (A) hypochlorus and chloric acids rus and chlorus acids (C)_chloric and perchloric acids ( lorieand hypochlorus acids Pax o mag: sth isan aa FAS R, Sand T, respectively, (A) SO,Cl;, PCl, and fy (8) SO,Cl,, PCl, and H,PO, (C) SOC, PCI, at 0. (0) SOCI, PCI, and H,PO, RST. (A) SO, 5 (B) SO,Cl,, PCI, 3 HyPO, (C) SOCl, I,PO> (0) SOCI, PCI, ait H,PO, Oo O- ANSWER: A Ss CHEMISTRY Paragraph for Questions 33 and 34 Wet 33 Wd 34 & RA ews ‘An aqueous solution of a mixture of two inorganic salts, when treated with " gave a precipitate (P) and a filtrate (Q). The precipitate P was found to disse in/jot water. The filtrate (Q) remained unchanged, when treated with HS in eral acid medium. However, it gave a precipitate (R) with ,S in an amrfagiagal ypedium. The precipitate R gave a coloured solution (S), when treated with 4j0, in an aqueous NaOH medium. O sorta cath & va fer or cele freer Ty RT BT Ww sae (P) aie ya fhege (Q) eM z | sree a geri & | Frege (Q) 7] Grr orcita aA A HS ERT snaRafiia wean 8, for wait ae 4 H,S & ey Saao RS aT wera NaOH FEM I H,0, Ot aia CAT 33. The precipitate P contains (A) Pb (8) Hg,?* Gp Ag™ (0) Hg* sada PH safterd & (A) Pb (B) ~ (C) Ag (0) He Ae) oa 34. The coloured Splut (A) Fe,($Qu); SO, (C) ZnSO, (D) Na,CrO, Or fer (A) Fe(89,)3 (8) CuSO, (C) ZnSO, (D) Na,CrO, oO ANSWER : D Ss 35. CHEMISTRY Paragraphs for Questions 35 and 36 Wei 35 Ud 36 & fra arqee P and Q are isomers of dicarboxylic acid C,H,O,. Both decolorize Br, /H,. heating, P forms the cyclic anhydride. ) Upon treatment with dilute alkaline KMnO,, P as well as Q could pro one-O) more than one from S, T’and U. PAR Ow seerdifraar ara C,H,0, & at wrraadl = | ae axa & | oe oy Pama Welegigs Fae | spar oa pa as Sonia ae aif §, Tarra U aT Wed E | COOH COOH COOH Ht+on = H+ OH HO H--OH = HO--H H COOH COOH cok Ss T Compounds formed from P and Q are, respectiv (A) Optically active S and optically active pai, (8) Optically inactive $ and optically inactive (C) Optically active pair (7, U) and opti ict (D) Optically inactive pair (7, U) and optig4lly i\active S Pak Qari wi afte wre, (A) gar he Syd yao (8) gam Fafa Sua ger F (Cc) gan ate ar (7, U) (bd) sar Fafa aH (7, CHEMISTRY 36. In the following reaction sequences V and W are, respectively IN Prafetad afitira ageat 4, vai ware & ©) Hint aN oy IN y ‘AICI (anhydrous) 1. Zn-Hg/HCI oer w 2. HPO, P 0 ban OO 7 we @ CH,0H (8) and/stte - Ss Oo Ww Y © Cp anaste vo Ww HOH,C. CHEMISTRY SECTION - 3 : (Matching List Type) ers — 3: (Gael a FoR) IW This section contains 4 multiple choice questions. Each question has matching fists The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is Yeffect, se us 4 4 agteor mer € | gee oer Y Gas eet & | fei faePea (A), (B), (C) site (0) & fort B act vw BETS | ig 37. Match the chemical conversions in List I with the appropriate reagents in UAT and select the correct answer using the code given below the lists : aati a fa 7a cerahte woes oT atu a fe wa are wafer Sisry ger Yee & A eg wa es aT wary List I AGH 1 P. a — = Q. one —— oe s. Oo — or ) ( (i) BH,, (ii) H)O,/NaOH Codes : P*Q RS (A) 2 3 01 4 (B)3 2 1 4 ()2 3 4 1 2.4 1 CHEMIST! 38. The unbalanced chemical reactions given in List I show missing reagent or ceagition ee ) (?) which are provided in List II. Match List I with List II and select the answer using the code given below the lists : Gait ee seg ais tot aorta Ca) S11 Gt 1s Waa Hy wn Eat & A fey Sarr a UE TAR OPT : List 1 Ait 1 Light ART P. pho, + H,S0, > PbSO, + 0, + other product neo No 2 2 Q Na,S,0, + HO —> NaHSO, + other ae) - 2 , R.NjH, —> Ny + other product31I Sern 2 S. XeF, —> Xe + other product/s S 4. Ch Codes : P QRS a4 2 3 1 O (®) 3 2 1 4 (1 4 2 3 (02) 34 7 S \ SWER: D O° Oo S CHEMISTRY, 39, The standard reduction potential data at 25 °C is given below. are orrarae fg 25 °C ux Praferttad & | Ko E°(Fe™, Fer, 0.77 ¥; E° (Fe, Fe) =-0.44V E°(Cu*, Cu) = + 0.34 V; E°(Cu", Cu) = + 0.52V E°[O,(@) + 4H* + 4e~ > 2HO] = +1.23 V; E°[0,(g)+2H,O+ 4e~ > 40H] = + 0.40 V Oo E° (Cr, Cr) = - 0.74 V; E°(CP*, Cr) =-0.91V Match E° of the redox pair in List I with the values give ind select the correct answer using the code given below the lists : wet 14 fed 7a tern FO Ee nF RA fra 8 qatar wifory den yfeet & =e fed 7a ars wT afr : List AGT 1 E°(Fe*, Fe) E°(4H,O === 4H* + 40H") Vv E°(Cu2* + Cu 9 2Cu") 0.044 E°(Cr*, Cr+) KG ER:D ype” Codes : P (A) 4 (B) 2 (Cc) 1 (0) 3 RNLH=O Hoannw Neon O° Oo Ss CHEMISTRY | 40. An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List !. The variation in conductivity of these reactions is given in List II. Match List 1 with WsCil and select the correct answer using the code given below the lists : List I List 1 P.(C;Hs)N + CHyCOOH 1. Conductivity decreases and 7 increases Q. KI(0.IM) + AgNO; (0.01M) 2. Conductivity decreases a1 en _ es does not change much R. CH;COOH + KOH 3. Conductivity incre: and) then e . does not change m| S.NaOH + HI 4. Conductivity do or ge much Se and then iner oN, X& oefe freer 4 wae: y oT oefe fara AR ( dren &, a 1m fearn ran S| aftrensii S ser aus Fase | Gai a Ein o eed Airy ae Ty ars or wae Hey wel SR gra ahi P. (C)Hs);N +CH;COOH 1 1 x Y Q KI.(@.1M) + AgNOs (0.01M} vedi & oe area afar ! Ss x Y et ete R. CHyCOOH + KOH aeft & oie aca afte x Y uRtafera we ett | S.NaOH + HI 4. area afte oRafia vet ett site x oY aera ash F | Codes : P QAR (a) 3 4 (8) 4 3 r C2 390 4 M1 4° 35 RS ANSWER : A NSS Ce es) SECTION — 1 : (One or more options correct Type) KR ews —1: (tH aT after wel framed aT) This section contains 8 multiple choice questions. Each question has four choi (8), (C) and (D) out of which ONE or MORE are correct. ge we 4 8 aged wer & | uel ves FY any fewer (A), (B), (C) ae > Ow or aftr uel S | 41, Letw= MEF ng p= tur: n=1,2,3, cram be Const Hy= free: Rez<> } where Cis the st of al complex nu POH, 2° 2, € POH, and O represents the origin, then Zz, 02) = x x 2n Sn A > (8) 6 ©) > (2) B+ oon 2 A,= free: meesfon n| {pec:Rez wy = Lat 2, € POH, 2,6 PA £2, 02,= 2n = art fi w= P= {w":n=1,2,3,...)> a) ® § ey = o = cD 42. 1f3*=4"", then x= 2 log, 2 1 2 log, 3 Fog, 2 (©) {Zj0g,3 = ©) 20g, 3-1 aft 3¢= 41, 2 log, 2. 2 1 2 log) 3 ) Fieg,2=1 O (8) y7H0g,3 (©) T=T08,3 () Jog, 3-1 ww ANSWER : ABC MATHEMATICS, 43. Let @be a complex cube root of unity with @ # 1 and P = [p,] be an x.n matrix wil p,= @), Then P? #0, when n= (A) 57 (B) 55 (C) 58 (D) 56 Eh mow awe a AR, att ca =n ww = Gs) SA, FET p= | aa, Pe 0, Fd n= (A) 37 (B) 55 (Cc) 58 ©) ANSWER : BCD Oo 44. The function f(x) =2|x|+|x+2|-||x+2|-2|x||hasa a fm or a local maximum at x = 2 2 @ 2 ® > © 2 or 5 E a WHA f(x) =2 |x| + [x +2|—|[x+2]-2 [0B q ye wari sifteds Rr x & A We, dee “2 e 2 eS @ 45. lim Lez i nd (n+ 1) [(na + 1) Then a= as o = aeR at nt (n+ Ola Wa= Oo (A) 5 (8) 7 (Cc) 2 (0) a SS ANSWER: B MATHEMATICS 48. Circle(s) touching x — axis at a distance 3 from the origin and having an intercept of length 21/7 on y — axis is (are) LG (A) 2 +y?~6x+8y+9=0 (B) P+y-6x+7y+9=0 (C) 2 +y-6x-8y+9=0 (D) 2 +y?-6r-7y+9 x ort OF yes V3 GA oe wel HA Te (TA) TM y— aT FAM TENA) TIF (A) x+y? 6x+ 8y+9=0 (B) e+y?-6x+ 7+ (C) + y?-6r-8y+9=0 (D) 2 +y?-6x—Jy+ oO ANSWER : AC ar déplanar. Then a can 47. Two lines L, take value(s) (A) 1 (B) 2 (0) 4 era S| a a Bl A A (0) 4 48. Ina triangle POR, P is tt Sa ingle and cos P = ae Further the incircle of the triangle touches the si Yon and RP at N, L and M respectively, such that the the side(s) of (A) 16 (C) 24 (D) 22 Arps POR, aan cos P= 4 | eae sfatad fryst oT sia-ga apait PY RP OT HH: N, LAM MW BA AE wal Ha & fe PN, OL wet RM. it part wT Deny & | ca ry a YT cyoMst) wt ) = @) (A) (B) 18 (C) 24 (D) 22 ANSWER : BD MATHEMATICS SECTION ~ 2 : (Paragraph Type) WS — 2: (HPOST VHT) This section contains 4 paragraphs each describing theory, experiment, data ‘ight questions relate to four paragraphs with two questions on each paragraph. Eact of a paragraph has only one correct answer among the four choices (A), (! ga avs 4 Rraial, vari sfx offal onfe wr ea are 4 U vaftta one wes @, firrt 8 ex orqede oy at oer & | fret & a fewer (A), (B), (C) sik (0) & for G dae ww A WA e | Paragraph for Questions 49 and 50 v wer 49 Ud 50 & fa awe Let = 8,9 5,0 Sy, where fz-1+3i j2[<4 = Cc: ~ j2l<4}, Sy fee Hm Bi > of an 49. Area of S Y So aaa = HO lox 32a as ®) © > (0) 5 50. O- ANSWER: ¢ MATHEMATICS Paragraph for Questions 51 and 52 wet 51 Ud 52 & feet qe A box B, contains 1 white ball, 3 red balls and 2 black balls. Another box Gece R Is 2 white balls, 3 red balls and 4 black balls. A third box B, contains 3 white and 5 black balls. we 8) B, 41 wba Fe, 3 ore He en 2 ref Fe S| ww Get AT We, 3 cre He cen 4 areft He S| vw del We B, 4 3 wee, 4 cee Soret Fe 1 51. If 1 ball is drawn from each of the boxes B,, B, and B, prepability that all 3 drawn balls are of the same colour is ufe dfeal 2, B, den B, A yee a1 &, aa Prove ag ei 3 tel & ww Go em Ht orem zs : 90 566 ) Gas ®) cas 8 ©) Cas, ANSWER : @) 52. If 2 balls are drawn (withouteefacement/ from a randomly selected box and one of the balls is white and the oth ig rel, the probability that these 2 balls are drawn from box B, is afe 248 we agen & fen sient & Proreft onl & ae yar jie abe a at ft, va gF 2 del a A B, a foal a wife & 116 65 55 A) ter (C) gr (0) igr ANSWER : D Ss MATHEMATICS Paragraph for Questions 53 and 54 Wo Wea 53 Wd 54 & ford ogee Z Let f: [0, 1] + R (the set of all real numbers) be a function, Suppose the functis twice differentiable, f (0) = f(1) = 0 and satisfies f"(x) - 2f'(x) + f(x) 2 e*, ard ff: (0, J oR ON aaa ensil or wpe ye word FT We fA AT saHHAS , £(0) =f (1) = 0 FM f"(w) - 2") + FQ) ze x YO, 1 Bl UGS Ga | & ° 53. Which of the following is true for 0s0), 00. Iie art fi PO Wace 3? =4ax H YH aie share | PROHO RW Raw Tt waet Tae vw fey ww fro g at far Tat y= 2x ars O)R fers F | Length of chord PQ is @) shar Po at orang & RS (a) Ta a Cs he (2) 3a (B) 5 ANS} aS If chord PQ subtends it the vertex of »? = dax, then tan 0= WOM o sata Gi S Ta tan o= 2 2 2 Zvi () 35 (>) Zv5 ANSWER : D MATHEMATICS | SECTION -— 3 : (Matching list Type) Brat welt WHR) W This section contains 4 multiple choice questions. Each question has matching ligfs The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is cork wa as 9 4 aghtwor wed & | rte oer A yo Ue e | afeal & fay faerer (A), (B), (C) atk (0) & fSrr4 B sact ye Tete | 57. A line L : y= mx + 3 meets y — axis at E(0, 3) and the arc of the parabolé ip 0 wor wetter AFT e fa 1 R Aft o(Z-] cos 2+ mQoseg x = cos x sin 2x sec x 325 eof +3) cos 2x WA sec.x ae lan S. a cot (sini jan" (x6)),x#0, 41 ANSWER : B MATHEMATICS 4 yt3 zt 59. Consider the lines L, : : va3 23 and the pla Pi: Tx+y+2z=3, Py: 3x + Sy 62=4. Let ax + by + cz =d be the equation plane passing through the point of intersection of lines Z, and L,, and perpenfigffar to planes P, and P,. Match List — I with List — II and select the correct answer using the code/Ylven the lists : y 243 Ret 2, Py 23x + Sy—62=4 CfA | APT fh ax + by +cz=d, fag 8 YoRA Ten Ta Waa P, a P, & aa, WATS, EUR kT Pie ame ae & (PA as a wi ar aha: are wet List It RE TT L 2B 3 Codes : P QRS a) 3 2 4 1 ®) 1 3 4 2 (3 2 1 4 ()2 4 1 3 Moder A O° Oo MATHEMATICS 60. Maich List ~I with List —II and select the correct answer using the code given below the lists : List - List P. Volume of parallelepiped determined by vectors @, B and ¢is2. 1. wR Then the volume of the parallelepiped determined by vectors 2(@ x b), 3 (B x @) and (é x ais Q Volume of parallelepiped determined by vectors d, b and @is 5. 2. Then the volume of the parallelepiped determined by vectors 3(@ +b), (b + 2) and A(é * d)is R. Area of a triangle with adjacent sides determined by vectors @ and B is 20. Then the area 9 of the triangle with adjacent sides determined by vectors (2d + 3B) and (d — 5) is ° re S. Area of a parallelogram with adjacent sides determin 60 vectors @ and 5 is 30. Then the area of the parallelog adjacent sides determined by vectors (@ + 5) and @ yet - 1a) eet 118 BAfera wif en fer y wart wey WE SAT BA: wa

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