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1. ATOMIC STRUCTURE-II
THREE MARKS
1.
What do you understand by the dual character of matter? (Text book page no:3)
2.
3.
4.
Define an orbital?(15)
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6.
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8.
Define hybridization?(23)
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Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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2. PERIODIC CLASSIFICATION-II
THREE MARKS
1.
2.
3.
4.
5.
Calculate the effective nuclear charge experienced by the 4s electron in potassium atom.(36)
6.
Calculate the effective nuclear charge of the last electron in an atom whose configuration
1s22s22p63s23p5.(36)
7.
Second ionization potential is greater than first ionization energy. Why? (38)
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20.
Calculate the electro negativity values of fluorine and chlorine on mullikens scale given that
(I.E)F=17 ev/atom,(E.A)F=3.62ev/atom (IP)Cl=13ev/atom and (EA)Cl =4ev/atom.(45)
FIVE MARKS
1.
2.
3.
Explain the paulings scale for the determination of electro negativity? Mention disadvantage.(43)
4.
5.
How are electro negativity values useful in finding out the percentage of ionic character of polar
covalent bond?(45)
6.
How are electro negativity values useful in finding out the nature of bonding between the
atoms?(45)
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8.
9.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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3. P-BLOCK ELEMENTS
THREE MARKS
1.
2.
H3PO3 is diprotic.Prove.(60)
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8.
Why do noble gases form compounds with fluorine and oxygen only?
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11.
12.
13.
Holmes signal.(64)
14.
Prepare phosphine.(63)
15.
16.
H3PO4 is triprotic.Prove.(61)
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5.
Explain the anomalous nature of fluorine? (or) How fluorine differs from other halogens?(67)
6.
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8.
9.
Explain the chemical method for isolation of noble gases from air?(or) Ramsay-Raleighs
method.(74)
10.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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4. D-BLOCK ELEMENTS
THREE MARKS- WHY QUESTIONS
1.
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5.
1.
Why Zn2+ salts are white while Ni2+ salts are coloured?
2.
3.
A substance is found to have a magnetic moment of 3.9 BM. How many unpaired electrons does it
contains?
4.
Explain why the melting and boiling points of Zn,Cd,Hg are low?
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18.
Prepare-Calamine.(Zinc Carbonate)(103)
19.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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FIVE MARKS
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6. F-BLOCK ELEMENTS
FIVE MARKS ONLY
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6.
2.
Mention the type of hybridization and magnetic property of the following complexes using VB
theory a) [FeF6]4-
3.
For the complexes K4[Fe(CN)6], [Cu(NH3)4]SO4 Mention a) Name b) Central metal ion
c) Ligands
4.
b)[Fe(CN)6]4- (129)
d) Coordination number
e) Geometry
How is the paramagnetic moment related to the number of unpaired electrons in?
a) K4[Fe(CN)6]
b) K3[Fe(CN)6]
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Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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10.
Taking [FeF6]4- as an example discuss geometry, nature of d-orbital splitting and magnetic
property using VB theory.
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16.
Explain the following terms a) ligand b) chelates c) central metal atom d) coordination number
17.
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2.
3.
4.
What are the types of nuclear reaction? Give example for each type?(139-140)
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8.
9.
Write any three difference between chemical reactions and nuclear reactions?(137)
10.
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Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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8. SOLID STATE
THREE MARKS
1.
2.
3.
Determine the number of CsCl units per unitcell. CsCl has BCC arrangement?(155)
4.
5.
6.
Sketch the following lattices a) simple cubic b) Face centered cubic c) Body centered
cubic.(154)
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6.
Explain AB and AB2 type of crystals with example.(or)Discuss the structure of CsCl
and TiO2.(159)
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9.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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9. THERMODYNAMICS II
THREE MARKS
1.
2.
Predict the feasibility of the reaction when i) both H and S increase ii) both H and S
decrease H decreases but S increases.
3.
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11.
1.
2.
What are spontaneous reactions? What are the conditions for the spontaneity of a
process?(169,176)
3.
4.
5.
2.
H2O(g) + O2(g)
3.
4.
5.
6.
What happens when n(g) =0, n(g) =+ve , n(g) =-ve in a gaseous reaction?(185-186)
7.
2HI(g)
2 NO2(g)
4HCl(g) + O2(g)
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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8.
9.
What are the relations between formation and dissociation equilibrium constant? give an
example.(186)
FIVE MARKS
1.
Derive the relation Kp= Kc(RT)n(g) for a general chemical equilibrium reaction?(184-186)
2.
State Le chateliers principle. Discuss the effect of pressure, concentration and temperature on
the following reaction N2(g) + O2(g)
2NO(g)
3.
4.
5.
6.
7.
2.
Derive the relation ship between half life period and rate constant for a first order reaction?(7)
3.
4.
What is meant by zero order reaction? What is the rate constant of such a reaction?[creative]
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Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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FIVE MARKS
1.
Explain the experimental determination of rate constant of acid hydrolysis of methyl acetate.(12-13)
Define adsorption.(24)
2.
3.
What is electrophoresis?(39)
4.
What is catalysis?(26)
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6.
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11.
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13.
What is tanning?(42)
14.
15.
What is electrodialysis?(36-37)
16.
What is peptisation?(35)
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21.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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2.
Write any three methods for the preparation of colloids by dispersion methods?(34)
3.
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10.
11.
12.
Define Faraday.(53)
2.
3.
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11.
12.
What is PH of solution?(65)
13.
14.
Why phenolphthalein is not suitable indicator in the titration of strong acid against weak base?(76)
15.
Why Methyl orange is not suitable indicator in the titration of strong base against weak acid?(76)
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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FIVE MARKS
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4.
Write a brief account on the relation between EMF and Free energy. (or) Show that the electrical
energy supplied by a cell is equal to the free energy?(91-92)
5.
6.
7.
8.
How will you predict whether a metal will displace another metal from its salt or not?(90)
[ Note: Problems-see example(92), example1(94),example4(96), exercise 5th one]
2.
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5.
6.
7.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
www.kalvisolai.com
8.
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10.
11.
Meso tartaric acid is optically inactive with chiral carbon atoms-reason out.(113)
[ Note: see E/Z conventions given in the book]
FIVE MARKS
1.
2.
3.
4.
5.
6.
7.
2.
How will you convert phenol into phenolphthalein? (or) (166)How is phenolphthalein prepared?
3.
4.
Give a brief account on coupling reaction of phenol with benzene diazonium chloride? (or) Write
the dye test for phenol?(165)
5.
6.
What happens when glycerol reacts with KHSO4? (or) Prepare Acrolein?(149)
7.
Phenol is insoluble in NaHCO3 solution bit acetic acid is soluble. Give reason?(159)
8.
9.
10.
11.
12.
13.
14.
15.
16.
How will you convert 2-methyl-2-propanol into 2-methyl propene. (or) How is tertiary butyl alcol
converted into isobutylene?(136)
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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17.
What happens when ethylene reacts with cold dilute alkaline KMnO4?(139)
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27.
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29.
30.
31.
1.
Esterification(131)
2.
Lucas test(131)
3.
Oxidation(134)
4.
Iodoform test(135)
5.
Catalytic dehydrogenation(135-136)
6.
Victor-Meyers test(136-137)
7.
Bouveault-Blanc Reduction.(140)
8.
9.
10.
Saponification reaction(146)
11.
12.
How Glycerol reacts with Oxalic acid at i) 383K ii) 533K. (149,150)
13.
Cannizzaro reaction.(152)
14.
15.
Schotten-Baumann reaction.(162)
16.
Etherification.(162)
17.
Halogenation-Bromination.(163)
18.
Dye test.(165)
19.
Kolbes reaction.(165)
20.
Riemer-Tiemann reaction.(165)
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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21.
22.
Lederer-Manasse reaction.(166)
17. ETHERS
FIVE MARKS ONLY
1.
Write all possible isomers with the molecular formula C4H10O and name them.(183)
2.
3.
4.
d) dilute H2SO4
5.
Differentiate anisole and diethyl ether.(or) Differentiate aromatic and aliphatic ether.(192)
6.
7.
Explain the formation of CH3I and phenol when anisole is heated with HI?(191)
8.
Diethyl ether forms peroxide easily while anisole does not form peroxide easily-Explain.
(186 and creative)
9.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
Prepare benzhydrol.(231)
12.
Uses of benzaldehyde.(224)
13.
14.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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NAMING REACTIONS USED FOR PROBLEMS
1.
Rosenmund Reduction.(201-202)
2.
Stephens reaction.(204)
3.
4.
5.
6.
Clemmenson Reduction(214)
7.
Wolff-Kishner Reduction(215)
8.
Tollens test(216)
9.
Fehlings test(216)
10.
Cannizaro reaction.(mechanism)(220-221)
11.
12.
Benzoin condensation.(221-222)
13.
Perkins reaction.(222)
14.
Knovenagal reaction.(222)
15.
Haloform reaction.(226)
16.
17.
Prepare the following alcohols from Grignard reagent i)primary ii)secondary iii)tertiary(210)
2.
Prepare the following compounds from ammonia? i)aldimine ii)hydrobenzamide iii) Diacetone
amine.(211-212)
3.
4.
5.
Prepare the following compounds from acetone? i) Chloritone ii) Mesityl oxide iii) Phorone iv)
Mesitylene.(227)
19. CARBOXYLIC ACIDS
THREE MARKS
1.
2.
Formic acid reduces Tollens reagent but acetic acid does not-Give reasons.(250)
3.
4.
5.
What happens when calcium salt of aceticacid is distilled?(250)(repeated in carbonyl compounds Q.no3)
6.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
www.kalvisolai.com
7.
8.
9.
10.
11.
12.
13.
14.
15.
1.
Esterification reaction.(mechanism)(246-247)
2.
HVZ- reaction.(249)
3.
4.
Kolbes reaction.(mechanism)(262)
5.
6.
7.
Hoffmanns reaction.(270)
FIVE MARKS AND SOME IMPORTANT CONVERSIONS.
1.
2.
3.
What happens when lactic acid is i) dil.H2SO4 ii) heated alone iii) alkaline KMnO4 iv)PCl5 (253)
2.
1.
2.
Diazotization (300)
3.
Nitration of benzene.(mechanism)(282-283)
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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4.
5.
Carbylamine reaction.(294)
6.
7.
Schotten-Baumann reaction.(300)
8.
9.
Gattermann reaction.(307)
10.
11.
Coupling reaction.(308)
12.
1.
2.
3.
4.
5.
How are i) Phenol ii) Chlorobenzene iii) Biphenyl prepared by using C6H5N2Cl.(306,307,308)
6.
How does Nitrous acid react with primary, secondary, tertiary amines?(294)
7.
21. BIO-MOLECULES
FIVE MARKS ONLY
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5.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.
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22. CHEMISTRY IN ACTION
THREE MARKS
1.
Define chemotherapy.(332)
2.
3.
4.
5.
Give short note on anti malarials? give two examples. (or) antiprotozoals.(334)
6.
7.
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10.
11.
12.
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15.
16.
Prepare polystyrene.(338)
FIVE MARKS
1.
2.
3.
Write briefly on Buna rubbers? (or) Explain Buna-S and Buna-N rubbers.(339)
4.
Explain briefly on colour and structure of dyes?(or) Explain Chromophores and Oxochromes?(336)
5.
6.
Prepared by
Mr. V. KARTHIKEYAN M.Sc.,B.Ed.,M.Phil.,
[P.G. Assistant in Chemistry]
Kongu Matric Higher Secondary School,
Uthukuli, Tirupur Dt.
Mr. V.KARTHIKEYAN M.Sc.,B.Ed., M.Phil., (P.G. Assistant in Chemistry), Kongu Matric. Hr. Sec. School , Uthukuli Tirupur Dt.