thi mn Phn Tch nh Lng

Lp Ha 2006, 06/01/2009, 9:15

Thi gian: 120 pht (khng tnh 5 pht c )
Cu 1. (4 im)
Acid oxalic, H2C2O4, l mt acid yu 2 chc c pKa1=1.25 v pKa2 = 4.27 c xem l mt cht
chun gc trong chun acid baz. Chun dung dch H2C2O4 0.1N bng NaOH 0.1N.
Hy:
9 Thit lp iu kin chun .
9 V ung cong chun .
9 La chn cht ch th ph hp.
9 Tnh cc sai s ch th m cc SV la chn.
Cu 2. (6 im)
Hm lng Fe trong mt mu thin thch uc xc nh bng chun oxyha kh vi KMnO4.
Phn tch vin thc hin phn tch lp 3 ln nh sau: ha tan mi -g mu trong acid v dng ct
Walden kh nh lng Fe3+ v Fe2+. Chun bng KMnO4 vi hn hp bo v Zymmerman, tn
Vi mL.
Ln lp i

Khi lng mu (mi)

Th tch KMnO4 tiu tn (Vi)

0.4185

41.3

0.3529

35.2

0.4046

40.2

Nng KMnO4 c xc nh bng dung dch chun gc H2C2O4 (0.1000 0.0004)N. Ht 10

mL dung dch H2C2O4 dung dch chun gc vo erlen, thm 1 mL H2SO4 c, un nng n
khong 70 oC. T buret cha KMnO4, chun chm H2C2O4 cho n khi dung dch trong erlen c
mu hng bn trong 30s. Ghi ly th tch KMnO4 tiu tn. Chun lp 4 ln c th tch KMnO4
tiu tn l: 8.00; 8.03; 7.99; 7.97 mL.
+
o
o
= 0.77V , E MnO
= 1.51V , [H ] = 2N, pipet = 0.02 mL, cn = 0.0002 g,
Cho E Fe
/ Fe
,8 H / Mn
3+

2+

2+

MFe2O3 = 159.69 (g/mol)

9 Hy nu cu to v cch s dng ct Walden
9 Vit cc phng trnh phn ng xy ra trong th nghim ny.
9 V ung cong chun gia Fe2+ v KMnO4
9 Vai tr ca hn hp Zymmerman. Gii thch
9 Vai tr ca H2SO4 v nhit trong phn ng chun gia H2C2O4 v KMnO4. Gii thch
9 Tnh % theo khi lng Fe2O3 trong mu thin thch c km theo sai s.
Ghi ch: Sinh vin uc php mang vo phng thi bng tm tt cc cng thc trong chng trnh phn
tch nh lng do PGS. TS. C Thnh Long.