1.

Sc kh CO2 vo dung dch Ba(OH)2 hoc Ca(OH)2

Bn cht phn ng :
CO2 + Ba(OH)2 BaCO3 + H2 O
mol

BaCO3 + CO2 + H2O Ba(HCO3)2

mol

(1)
(2)

Suy ra : Lng kt ta tng dn n cc i a mol ng vi phn ng (1), phn ng ny cn a mol CO2.

Sau lng kt ta tan dn n ht ng vi phn ng (2), phn ng ny cng cn a mol CO2. Vy s
bin thin lng kt ta BaCO3 hoc CaCO3 theo lng CO2 c biu din bng th sau:

Nhn xt :Da vo dng hnh hc ca th, ta thy ng bin thin lng kt ta hp vi trc honh to
thnh mt tam gic vung cn. Suy ra : Nu phn ng to ra mt lng kt ta x mol (nh th di
y) th ta d dng tnh c smol CO2 tham gia phn ng l x mol hoc y = (2a x) mol .
0

2. Sc kh CO2 vo dung dch cha hn hp cc baz NaOH (hoc KOH) v Ba(OH)2 (hoc
Ca(OH)2 )
Bn cht phn ng :
Ca(OH)2 + CO2 = CaCO3 + H2O
BI TP V NHM S DNG TH
1.
Cho 1 mol KOH vo dung dch cha a mol HNO3 v c mol Al(NO3)3. thu c d mol kt
ta.Kt qu th nghim c biu din trn th sau .
1

gi tr ln nht ca a tha mn l:
A. 0,75 mol.
B. 0,5 mol.
C. 0,7 mol.
D. 0,3 mol
2.
Cho 200 ml dung dch NaOH 2M vo V ml dung dch AlCl3 1,2M. Kt qu th nghim c biu din
trn th sau

Tnh khi lng kt ta thu c sau phn ng.

A. 7,8 gam
B. 9,36 gam
C. 6,24 gam
D. 4,68 gam
3.
Cho V1 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M. Kt qu th nghim c biu
din trn th .

Gi tr ln nht ca V l
A. 1,2.
B. 1,8.
C. 2,4.
D. 2
4.
( A-2014): Khi nh t t n d dung dch NaOH vo dung dch hn hp gm a mol HCl v b
mol AlCl3, kt qu th nghim c biu din trn th sau

1.

T l a : b l
A. 4 : 3
B. 2 : 3
C. 1 : 1
D.2 : 1
5.
Khi nh t t n d dung dch KOH vo dung dch hn hp cha AlCl 3 v HCl,kt qu th
nghim c biu din trn th sau (s liu tnh theo n v mol)

nAl(OH)

T l x : a l :
A.4,8
B.5,0
C.5,2
D.5,4
6.
Khi nh t t n d dung dch KOH vo dung dch AlCl 3,kt qu th nghim c biu
din trn th sau (s liu tnh theo n v mol).

Gi tr ca x l :
A.0,12

B.0,14

C.0,15

D. 0,2

7.
Khi nh t t n d dung dch NaOH vo dung dch AlCl 3,kt qu th nghim c biu
din trn th sau (s liu tnh theo n v mol).

Gi tr ca x l : A.0,412

B.0,456

C. 0,515

D.0,546

8.
Khi nh t t n d dung dch NaOH vo dung dch AlCl 3,kt qu th nghim c biu
din trn th sau (s liu tnh theo n v mol).

Gi tr ca x l : A.0,412
B.0,426 C. 0,415
D. 0,405
9.
Khi nh t t n d dung dch NaOH vo dung dch AlCl 3,kt qu th nghim c biu din
trn th sau (s liu tnh theo n v mol).

Gi tr ca x l : A.0,80

B.0,84

C.0,86

D.0,82

10.
Khi nh t t n d dung dch NaOH vo dung dch AlCl 3,kt qu th nghim c biu din
trn th sau (s liu tnh theo n v mol).Biu thc lin h gia x v y l :
A. 3y - x = 1,44
B. 3y - x = 1,24
C. 3y + x = 1,44
D. 3y + x =
1,24

11.

Khi nh t t n d dung dch NaOH vo dung dch AlCl 3,kt qu th nghim c biu din
trn th sau (s liu tnh theo n v mol).

T l x : y l : A. 7: 8B. 6:7

C.5:4

D.4:5
4

12.
Cho hn hp X gm x mol NaOH v y mol Ba(OH) 2 t t vo dung dch cha z mol AlCl 3
thy kt ta xut hin, kt ta tng dn v tan i mt phn. Lc thu c m gam kt ta. Gi trca
m l :
A.78(4z x 2y). B.78(2z x y). C.78(4z x y). D.78(2z x 2y).
13.
X l dung dch NaOH C%. Ly 18 gam X hoc 74 gam X tc dng vi 400 ml AlCl30,1M
th lng k ta vn nhnhau. Gi trca C l :
A.4.

B.8.

C.7,2.

D.3,6.

14.
Trong mt cc ng 200 ml dung dch AlCl 3 2M. Rt vo cc V ml dung dch NaOH c
nng a mol/lt ta c mt kt ta; em sy kh v nung n khi lng khng i c 5,1
gam cht rn. Nu V = 200 ml th a c gi tr no?
A.2M.
B.1,5M hay 3M.
C.1M hay 1,5M.
D.1,5M hay 7,5M.
15.
*Ha tan hon ton m gam hn hp NaOH v KOH vo nc, thu c dung dch
Z, trong OH 0,1 n 0,14 . Cho dung dch Z phn ng vi dung dch cha 0,04 mol AlCl 3,
khi lng kt ta thu c l m gam. Gi tr ca m l :
A. 1,56 m 2,6. B. m = 2,6.
C. 1,56 m 3,12. D. m = 3,12.
( thi th H ln 1 THPT chuyn Nguyn Hu H Ni, nm hc 2013 2014)
16.
X l dung dch Al(NO3)3 aM. Thm 6,21 gam Na vo 100 ml dung dch X (TN1) thu c m gam
kt ta. Mt khc, nu thm 6,44 gam Na vo 100 ml dung dch X (TN2) th thu c 0,8m gam kt ta.
Cc phn ng xy ra hon ton. Gi tr ca a l
A. 1,2M.
B. 0,9M.
C. 0,8M.
D. 1,24M.
( thi th i hc ln 2 Trng THPT chuyn L Hng Phong Nam nh, 2012 2013)
17.
Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3v 0,1 mol H2SO4 n khi
phn ng hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l :
A.0,35.
B.0,25.
C.0,45.
D.0,05.