TNG HP 4

Cu 1: Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu
c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung
dch X l
A. 13,32 gam.
B. 6,52 gam.
C. 8,88 gam.
D. 13,92 gam.
Cu 2: Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc
phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3.
Gi tr ca m l
A. 8,75.
B. 7,80.
C. 9,75.
D. 6,50.
Cu 3: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va
vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc
cu to thu gn ca X l
A. CH3COO(CH2)2COOC2H5.
B. CH3OOC(CH2)2COOC2H5.
C. CH3OOCCH2COOC3H7.
D. CH3COO(CH2)2OOCC2H5.
Cu 4: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm
X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3)
trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l
A. 76,6%.
B. 80,0%.
C. 70,4%.
D. 65,5%.
Cu 5: Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra 8,96 lt kh
CO2 ( ktc). Thnh phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung nu trn l
A. 92%.
B. 40%.
C. 84%.
D. 50%.
Cu 6: Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a
(mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l (bit trong mi dung dch [H+][OH-] = 10-14)
A. 0,30.
B. 0,15.
C. 0,12.
D. 0,03.
Cu 7: Cho 0,1 mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht:
A. H3PO4, KH2PO4.
B. K3PO4, KOH.
C. K3PO4, K2HPO4.
D. K2HPO4, KH2PO4.
Cu 8: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau
khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon
ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch
kh u o ktc)
A. CH4 v C3H6.
B. C2H6 v C3H6.
C. CH4 v C3H4.
D. CH4 v C2H4.
Cu 9: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t
ca X l
A. C12H16O12.
B. C6H8O6.
C. C3H4O3.
D. C9H12O9.
Cu 10: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch
sau phn ng thu c khi lng x phng l
A. 16,68 gam.
B. 18,24 gam.
C. 18,38 gam.
D. 17,80 gam.
Cu 11: un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu kin nhit
thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l
A. C3H8O.
B. C4H8O.
C. C2H6O.
D. CH4O.

Cu 12: Tin hnh hai th nghim sau:

- Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M;
- Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M.
Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng
nhau. Gi tr ca V1 so vi V2 l
A. V1 = V2.
B. V1 = 2V2.
C. V1 = 5V2.
D. V1 = 10V2.
Cu 13: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml
dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht
rn. Cng thc cu to thu gn ca X l
B. CH2=CHCOONH4.
A. H2NCH2COOCH3.
C. HCOOH3NCH=CH2.
D. H2NCH2CH2COOH.
Cu 14: Cho s chuyn ho sau:
+ Br (1:1mol),Fe,to

+ NaOH (d),t , p
+ HCl (d)
2
Toluen
X Y
Z.
Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm
A. m-metylphenol v o-metylphenol.
B. o-metylphenol v p-metylphenol.
C. benzyl bromua v o-bromtoluen.
D. o-bromtoluen v p-bromtoluen.
Cu 15: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba
trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit ,
p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l
A. 4.
B. 2.
C. 3.
D. 5.
Cu 16: Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong oxit m R
c ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l
A. S.
B. As.
C. N.
D. P.
Cu 17: Thnh phn chnh ca qung photphorit l
A. Ca(H2PO4)2.
B. Ca3(PO4)2.
C. NH4H2PO4.
D. CaHPO4.
Cu 18: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol)
etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l
0,8 g/ml)
A. 4,5 kg.
B. 5,4 kg.
C. 6,0 kg.
D. 5,0 kg.
Cu 19: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi
xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %)
A. 81 lt.
B. 49 lt.
C. 70 lt.
D. 55 lt.
Cu 20: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh
ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau
khi kt thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 15,6.
B. 11,5.
C. 10,5.
D. 12,3.
Cu 21: Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh (d).
Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l
Fe2O3 v hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia
a v b l (bit sau cc phn ng, lu hunh mc oxi ho +4, th tch cc cht rn l khng ng k)
A. a = 4b.
B. a = 0,5b.
C. a = 2b.
D. a = b.
Cu 22: Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi
dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l
A. K.
B. Li.
C. Na.
D. Rb.

Cu 23: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng

ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v
1,8 gam nc. Cng thc phn t ca hai ru trn l
B. C2H5OH v C3H7OH.
A. CH3OH v C2H5OH.
C. C3H7OH v C4H9OH.
D. C3H5OH v C4H7OH.
Cu 24: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm
KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng
thc phn t ca X l
B. CH3COOH.
C. HCOOH.
D. C3H7COOH.
A. C2H5COOH.
Cu 25: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp
gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO)
A. 0,6 lt.
B. 1,2 lt.
C. 0,8 lt.
D. 1,0 lt.
Cu 26: Cho cc phn ng:
(1) O3 + dung dch KI
o

t
(2) F2 + H2O

t
(3) MnO2 + HCl c
(4) Cl2 + dung dch H2S
Cc phn ng to ra n cht l:
A. (1), (2), (4).
B. (2), (3), (4).
C. (1), (2), (3).
D. (1), (3), (4).
Cu 27: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2
lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l
B. CH4.
C. C2H6.
D. C3H8.
A. C2H4.
Cu 28: Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng
vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl(vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l
A. 0,1 mol v 0,1 mol. B. 0,1 mol v 0,4 mol. C. 0,1 mol v 0,2 mol. D. 0,1 mol v 0,3 mol.
Cu 29: Cho sut in ng chun Eo ca cc pin in ho: Eo(Cu-X) = 0,46V; Eo(Y-Cu) = 1,1V;
Eo(Z-Cu) = 0,47V (X, Y, Z l ba kim loi). Dy cc kim loi xp theo chiu tng dn tnh kh t tri
sang phi l
A. Y, Z, Cu, X.
B. X, Cu, Z, Y.
C. Z, Y, Cu, X.
D. X, Cu, Y, Z.
Cu 30: Cho mt lng bt Zn vo dung dch X gm FeCl2 v CuCl2. Khi lng cht rn sau khi
cc phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dung dch
sau phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l
A. 13,1 gam.
B. 17,0 gam.
C. 19,5 gam.
D. 14,1 gam.
Cu 31: Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2
l
A. 3.
B. 1.
C. 2.
D. 4.
Cu 32: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z
u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm
chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l:
A. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. B. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO.
C. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH. D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO.