TNG HP S 6

Cu 1: in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M
(in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu
c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05.
B. 2,70.
C. 1,35.
D. 5,40.
Cu 2: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2
0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca
m l
A. 2,80.
B. 2,16.
C. 4,08.
D. 0,64.
Cu 3: Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn
hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l
A. 13,0.
B. 1,2.
C. 1,0.
D. 12,8.
Cu 4: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v
AgNO3. Cht to ra lng O2 ln nht l
A. KClO3.
B. KMnO4.
C. KNO3.
D. AgNO3.
Cu 5: Cho cht xc tc MnO2 vo 100 ml dung dch H2O2, sau 60 giy thu c 33,6 ml kh O2 (
ktc). Tc trung bnh ca phn ng (tnh theo H2O2) trong 60 giy trn l
A. 5, 0.104 mol/(l.s). B. 5, 0.10 5 mol/(l.s). C. 1, 0.103 mol/(l.s). D. 2,5.10 4 mol/(l.s).
Cu 6: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al
catot v 67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp
kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l
A. 108,0.
B. 75,6.
C. 54,0.
D. 67,5.
Cu 7: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng
va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH,
thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l
A. C2H4O2 v C5H10O2.
B. C2H4O2 v C3H6O2.
C. C3H4O2 v C4H6O2.
D. C3H6O2 v C4H8O2.
Cu 8: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung
dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng
hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi
lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l
B. C2H5COOH v C2H5COOCH3.
A. CH3COOH v CH3COOC2H5.
C. HCOOH v HCOOC2H5.
D. HCOOH v HCOOC3H7.
Cu 9: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam
mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X
l
A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH.
Cu 10: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi
dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh
T. Cc cht Z v T ln lt l
A. CH3OH v NH3.
B. CH3OH v CH3NH2.
C. CH3NH2 v NH3.
D. C2H5OH v N2.
Cu 11: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3
trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit
v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt (
ktc). Cng thc cu to ca X l
A. O=CH-CH2-CH2OH.
B. HOOC-CHO.
C. CH3COOCH3.
D. HCOOC2H5.
Cu 12: S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l
A. 3.
B. 1.
C. 2.
D. 4.
Cu 13: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht.
T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu
c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu
to ca anken l
A. CH2=C(CH3)2.
B. CH2=CH2.
D. CH3-CH=CH-CH3.
C. CH2=CH-CH2-CH3.

Cu 14: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi
phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu
c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c
39 gam kt ta. Gi tr ca m l
A. 45,6.
B. 48,3.
C. 36,7.
D. 57,0.
Cu 15: Ho tan hon ton 2,9 gam hn hp gm kim loi M v oxit ca n vo nc, thu c 500 ml
dung dch cha mt cht tan c nng 0,04M v 0,224 lt kh H2 ( ktc). Kim loi M l
A. Na.
B. Ca.
C. Ba.
D. K.
Cu 16: Cho cc hp cht hu c:
(1) ankan;
(2) ancol no, n chc, mch h;
(3) xicloankan;
(4) ete no, n chc, mch h;
(5) anken;
(6) ancol khng no (c mt lin kt i C=C), mch h;
(7) ankin;
(8) anehit no, n chc, mch h;
(9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc.
Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l:
A. (1), (3), (5), (6), (8).
B. (3), (4), (6), (7), (10).
C. (3), (5), (6), (8), (9).
D. (2), (3), (5), (7), (9).
Cu 17: Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c
trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3
(d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l
A. 58,2%.
B. 41,8%.
C. 52,8%.
D. 47,2%.
Cu 18: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng
v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy
nht, ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui
khan. Gi tr ca m l
A. 151,5.
B. 137,1.
C. 97,5.
D. 108,9.
Cu 19: Thc hin cc th nghim sau:
(I) Cho dung dch NaCl vo dung dch KOH.
(II) Cho dung dch Na2CO3 vo dung dch Ca(OH)2.
(III) in phn dung dch NaCl vi in cc tr, c mng ngn.
(IV) Cho Cu(OH)2 vo dung dch NaNO3.
(V) Sc kh NH3 vo dung dch Na2CO3.
(VI) Cho dung dch Na2SO4 vo dung dch Ba(OH)2.
Cc th nghim u iu ch c NaOH l:
A. II, III v VI.
B. I, II v III.
C. I, IV v V.
D. II, V v VI.
Cu 20: t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2
( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l
A. O=CH-CH=O.
B. CH2=CH-CH2-OH. C. CH3COCH3.
D. C2H5CHO.
Cu 21: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc,
nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc
cu to thu gn ca X l
A. HO-C6H4-COOCH3.
B. CH3-C6H3(OH)2.
C. HO-CH2-C6H4-OH.
D. HO-C6H4-COOH.
Cu 22: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M.
Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn
phm kh duy nht, ktc). Gi tr ca m v V ln lt l
A. 10,8 v 4,48.
B. 10,8 v 2,24.
C. 17,8 v 2,24.
D. 17,8 v 4,48.
Cu 23: Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung
dch X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam
mui sunfat khan. Gi tr ca m l
A. 52,2.
B. 54,0.
C. 58,0.
D. 48,4.
Cu 24: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom
(d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc
dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4
c trong X l
A. 20%.
B. 50%.
C. 25%.
D. 40%.

Cu 25: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon).
Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc).
t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi
lng ca Z trong hn hp X ln lt l
A. HOOC-CH2-COOH v 70,87%.
B. HOOC-CH2-COOH v 54,88%.
C. HOOC-COOH v 60,00%.
D. HOOC-COOH v 42,86%.
Cu 26: Pht biu no sau y l ng?
A. T visco l t tng hp.
B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N.
C. Trng hp stiren thu c poli(phenol-fomanehit).
D. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng.
Cu 27: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng
bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca
X v Y tng ng l
A. HOCH2CHO v HOCH2CH2CHO.
B. HOCH2CH2CHO v HOCH2CH2CH2CHO.
C. HOCH(CH3)CHO v HOOCCH2CHO.
D. HCOOCH3 v HCOOCH2CH3.
Cu 28: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t
khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung
dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l
A. 27,75.
B. 24,25.
C. 26,25.
D. 29,75.
Cu 29: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau
trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng
m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l
A. 17,8.
B. 24,8.
C. 10,5.
D. 8,8.
Cu 30: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht
hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu
c khc nhau. Tn gi ca X l
A. but-1-en.
B. xiclopropan.
C. but-2-en.
D. propilen.
Cu 31: Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v
AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi
thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l
A. 1,40 gam.
B. 2,16 gam.
C. 0,84 gam.
D. 1,72 gam.
Cu 32: ng dng no sau y khng phi ca ozon?
A. Ty trng tinh bt, du n.
B. Cha su rng.
C. iu ch oxi trong phng th nghim.
D. St trng nc sinh hot.
Cu 33: Cho s chuyn ho gia cc hp cht ca crom:
+ (Cl2 + KOH)
+ H2SO4
+ (FeSO4 + H2 SO4 )
+ KOH
X
Cr(OH)3
Y
Z
T
Cc cht X, Y, Z, T theo th t l:
A. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3.
B. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3.
C. KCrO2; K2Cr2O7; K2CrO4; CrSO4.
D. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3.
Cu 34: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi
Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l
A. HO-CH2-CH2-CH=CH-CHO.
B. HOOC-CH=CH-COOH.
C. HO-CH2-CH=CH-CHO.
D. HO-CH2-CH2-CH2-CHO.
Cu 35: Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H3PO4 0,5M, thu c dung dch
X. C cn dung dch X, thu c hn hp gm cc cht l
A. KH2PO4 v K3PO4.
B. KH2PO4 v K2HPO4.
C. KH2PO4 v H3PO4.
D. K3PO4 v KOH.
Cu 36: Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2)
vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau
khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l
A. 57,4.
B. 28,7.
C. 10,8.
D. 68,2.

Cu 37: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho
hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp
sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam
Ag. Gi tr ca m l
A. 15,3.
B. 13,5.
C. 8,1.
D. 8,5.
Cu 38: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn
ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va
40 ml dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l
A. 0,56 gam.
B. 1,44 gam.
C. 0,72 gam.
D. 2,88 gam.
Cu 39: Cho cc th in cc chun: E oAl3+ /Al = 1, 66V; E oZn 2+ /Zn = 0, 76V; E oPb2+ /Pb = 0,13V;
`

E oCu 2+ /Cu = +0,34V. Trong cc pin sau y, pin no c sut in ng chun ln nht?

A. Pin Zn Cu.
B. Pin Zn Pb.
C. Pin Al Zn.
D. Pin Pb Cu.
Cu 40: Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s
mol NO (sn phm kh duy nht) to thnh ln lt l
A. 0,03 v 0,02.
B. 0,06 v 0,01.
C. 0,03 v 0,01.
D. 0,06 v 0,02.
Cu 41: Ngi ta iu ch anilin bng s sau:
+ HNO3 c
Fe + HCl
Benzen
Anilin
H SO c Nitrobenzen
to
2

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t
50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l
A. 186,0 gam.
B. 55,8 gam.
C. 93,0 gam.
D. 111,6 gam.
Cu 42: Phn bn no sau y lm tng chua ca t?
A. KCl.
B. NH4NO3.
C. NaNO3.
D. K2CO3.
Cu 43: Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25 oC,
Ka ca CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25 oC l
A. 1,00.
B. 4,24.
C. 2,88.
D. 4,76.
Cu 44: Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu
c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo
dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng
ca Cu trong hn hp X v gi tr ca m ln lt l
A. 21,95% v 2,25.
B. 78,05% v 2,25.
C. 21,95% v 0,78.
D. 78,05% v 0,78.
Cu 45: Cho s chuyn ho:
H SO c, to

+ Mg, ete khan

+ HBr
2 4
Y

Z
X (anken)
Butan-2-ol
Trong X, Y, Z l sn phm chnh. Cng thc ca Z l
A. (CH3)3C-MgBr.
B. CH3-CH2-CH2 -CH2-MgBr.
C. CH3-CH(MgBr)-CH2-CH3.
D. (CH3)2CH-CH2-MgBr.