CNG HA I CNG-V C

Made by Phng Khanh Nguyn

I. Cu to nguyn t
Phn ny c phng trnh Schrodinger kh kh hiu. Nn ko cn c hiu lm g. Bi tp nu ra s dng
cho hm sng g . V bt tm 1 ci g . Ch cn ch th t vit s lng t
xc nh c cc s lng t n,l,m v lm tip theo yu cu ca

(n,l,m) nh vy s

1. Bn s lng t v ngha. Bi tp s dng cho 4 s lng t ca e cui cng, xc nh cu hnh e.

2. Nng lng cc e vi h 1 ht nhn 1 e
h nhiu e (tnh gn ng theo phng php Slater) cng thc quan trng
3. Biu din e di dng cc my e ca AO s, p (3 loi), d (5 loi) ch cc trc
4. Vit c cu hnh e v gin orbital (l my ci vung c 2 mi tn ngc chiu y)
II. Bng tun hon cc nguyn t ha hc
1. Cu to bng tun hon
2. nh lut tun hon
3. Mt s tnh cht tun hon cc nguyn t
III.Cu to phn t
1. Tnh cht ca phn t (i lng c trng Momen lng cc)
Phn cc lin kt
Phn cc phn t
T tnh ca phn t: Thun t v nghch t
2. Lin kt ha hc theo thuyt VB
Nguyn l xen ph cc i
Thuyt VB v ha lp th
Gii thch cu to da trn cc m my thun khit
Gii thch cu to trn c s AO lai ha (thuyt lai ha ca Pauling)
Lai ha thng gp sp3, sp2, sp, sp3d, sp3d2
Thuyt VSEPR- s y nhau gia cc cp e ha tr (quan trng) hc hiu ht (hc thuc bng 3.2)
3. Lin kt ha hc theo thuyt MO: (phn ny quan trng nht l v c gin MO)
Lun im c bn
i vi phn t ng hch A2 thuc chu k 2 (2 loi gin )
i vi phn t d hch AB
IV. Phc cht
1.nh ngha phc cht, Phn loi, Danh php phc cht
2.Thuyt VB
Lai ha trong i vi trng phi t mnh (CO,CN--, NO2-, NH3, NSCN-, OH2
Lai ha ngoi i vi trng phi t yu (I-, Br-, Cl-, F-, OH-)
Phn bit phc nghch t (phc spin thp) v phc thun t (phc spin cao)
3.Thuyt trng tinh th: khi nim quan trng thng s tch v nng lng ghp
Trng t din
Trng bt din
Trng vung phng
T chng ny tr i slide ca thy c y , d hiu. Mi ngi nn hc ht trong slide.
Bn di t ghi mt vi phn trng tm thi
Bi tp th trong slide ca thy c c nhiu cc cu c lm ht trong y. Bi no ko lm c th nhn t, t
s gi li gii cho

V. Nhit ng ha hc
1.Cho s liu tnh H, S, G
2. Entropy: cc yu t nh hng n entropy ca mt cht
VI. ng ha hc
A. Tc v c ch phn ng
1. Phng trnh vn tc phn ng dng vi phn v tch phn i vi phn ng bc 0,1,2 (bc 2 ch xt p
c 1 cht u hoc 2 cht u c nng ging nhau).
2. Ch cng thc lin h gia t1/2 v k, ngha ca t1/2.
3. Tm bc cu phn ng da vo th hoc tc u
4. nh hng ca nhit n tc phn ng v Phng trnh Arrhenius
5. Gii thch nh hng ca nn v nhit n tc phn ng. Thuyt va chm hot ng
6. C ch phn ng: cc khi nim: C ch phn ng, phn t s, bc gii hn tc ...
2 loi c ch p l c ch bc u chm v c ch bc u nhanh
7. Cht xc tc: khi nim, c ch xc tc
B. Cn bng ha hc
1. Quy tc vit Q,K mi lin h vi nhau v vi G, Kp, Kc, Kn (ch cn nh cng thc)
2. T t l Q/K => chiu ca phn ng
3. Nguyn l chuyn dch cn bng (nguyn l Le Chatelier): Cc yu t nh hng n CBHH: Nng
, p sut, Nhit
VII. Dung dch
A. Vn chung
1.L thuyt chung hc thuc cc bng 8.1, 8.2, 8.3
2.Cn bng pha
3.Gin pha:
Cu to: 3 ng (ng si, ng nng chy, ng thng hoa),
3 vng (rn lng kh),
2 im c bit (im ti hn v im ba)
Trng thi cc cht thay i ntn
H s gc ca 3 ng ny
4.Nguyn nhn hnh thnh dung dch:
Nguyn nhn v mt lin kt
Nguyn nhn v mt nhit ng
5. tan v nh hng ca nhit v p sut n tan
B. DD cha cht tan ko phli, ko bay hi
1.nh lut Raoult 1,2,3 nh cng thc thi
2.p sut thm thu v nh lut Vant Hoff
Phn ny quan trng
S thm thu
p sut thm thu
Hc k ch vai tr ca p sut thm thu: tnh cht ng trng, Nhc trng, u trng
VIII. Dung dch cht in ly (phn ny trong slide ca thy, hc ht)
1. in ly
Cng thc
Cc yu t nh hng: Bn cht cht tan, Bn cht dung mi, Nng , Nhit
Cch xc inh in ly
2. Hng s in ly K
3. Thuyt acid, base
Lu

cch tnh pH ca cc dung dch axid mnh, base mnh, n acid yu, n base yu, dd m.
Dung lng m, cc yu t nh hng
Tch s tan. Cn bng ha tan kt ta. Cc yu t nh hng n tan,
IX. Phn ng oxi ha kh v dng in
Phn ny c slide
Ch 1 s phn trng tm
Cch vit s pin Galvanic,
Phng trnh nesrt
Biu thc lin h gia in th chun ca pin Ep v G, K t xc nh c chiu ca phn ng
~The end~
Chc cc bn thi tt
P/s: mi ngi thy phn no quan trng m t li ghi thiu th bo li cho t ngay nh!