Chng 7.

DN XUT HALOGEN - ANCOL, ETE, PHENOL, RU THM

L THUYT
A. ANCOL ETE
1. Cng thc chung
2. Tn gi v iu kin tn ti ca ancol
3. Tnh cht vt l (s nh hng ca lk Hidro n si, tan)
4. Tnh cht ha hc
(1) Phn ng vi kim loi mnh Na, K, Ca, Ba
(2) Phn ng c trng ca ancol a chc c nhiu nhm OH - k tip vi Cu(OH)2
(3) Phn ng tch H2O to ete (140oC/H2SO4 c)
(4) Phn ng tch H2O to anken (170oC/H2SO4 c)
(5) Phn ng este ha vi axit (H2SO4 c/t o)
(6) Phn ng oxi ha khng hon ton (CuO/to hoc O2/xt)
(7) Phn ng oxi ha hon ton (phn ng chy)
5. iu ch
(1) Ln men ru (phng php vi sinh)
(1) Thy phn dn xut halogen/OH-,to hoc este
(2) Hidrat ha (cng H2O) anken tng ng
B. PHENOL RU THM ETE THM
1. Cng thc chung
2. Mt s phenol, ancol thm v ete thm thng gp
3. Tnh cht vt l
3. Tnh cht ha hc (s nh hng qua li gia nhm OH- v vng benzen)
Phenol

Ancol Thm

Na, K,...
Br2,
HNO3/H2SO4
CuO/to
Tch H2O
to ni i
Tch H2O
to ete
Phn ng
chy
Trng hp

4. iu ch
(1) Phenol
(2) Ancol thm

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A. DN XUT HALOGEN - ANCOL ETE

1. Tm CTCT v gi tn
Cu 1. Vit CTCT v gi tn cc ancol c CTPT: C3H8O, C4H10O, C3H6O.
Cu 2. Vit CTCT v gi tn cc cht c CTPT: C2H6O, C3H8O, C4H10O.
Cu 3. Vit CTCT v gi tn cc ancol bc 1 c CTPT: C3H8O, C4H10O, C5H12O.
Cu 4. Vit CTCT v gi tn cc ancol bc 2 c CTPT: C3H8O, C4H10O, C5H12O.
Cu 5. Vit CTCT cc ancol khng b oxi bi CuO/t0 c CTPT: C4H10O, C5H12O.
Cu 6. Vit CTCT v gi tn cc cht khng tc dng vi Na c CTPT: C2H6O, C3H8O, C4H10O.
Cu 7. Vit CTCT cc ancol tc dng vi CuO/t0 c CTPT: C3H8O, C4H10O, C5H12O.
Cu 8. Vit CTCT v gi tn cc ancol tc dng vi Cu(OH) 2 nhit thng c CTPT: C2H6O2, C3H8O2,
C3H8O3, C4H10O2.
2. Hidrat ha (cng H2O) Hidrat ha (tch H2O)
Cu 1. Vit CTCT cc anken c CTPT: C4H8, C5H10, C6H12 khi hidrat ha to mt ancol duy nht.
Cu 2. Vit CTCT cc anken c CTPT: C3H6, C4H8, C5H10 khi hidrat ha to hai ancol.
Cu 3. Vit CTCT cc ancol c CTPT: C3H8O, C4H10O, C5H12O khi tc nc to mt ancken duy nht.
Cu 4. Vit CTCT cc ancol c CTPT: C4H10O, C5H12O khi tc nc to t nht hai ancken.
Cu 5. Vit CTCT cc ancol c CTPT: C5H12O, C6H14O khng tham gia tch nc to ancken.
Cu 6. Vit CTCT cc cht sau: etilen; but-2-en; propilen; 2-metyl but-1-en; 2,3-imetylbut-2-en. Cc cht
khi hp nc ch to mt ancol duy nht?
Cu 7. Vit CTCT cc cht sau: but-1-en; propilen; 3-metyl but-1-en; 2,3-imetylbut-2-en; but-2-en. Cc
cht khi hidrat ha to hai ancol?
Cu 8. Vit CTCT cc cht sau: pent-2-en; etilen; but-2-en; 2,3-imetylbut-2-en; but-1-en. Cc cht khi
hidrat ha to mt ancol duy nht?
Cu 9. Hidrat ha cc anken sau: propilen; pent-2-en; etilen; but-2-en; 2,3-imetylbut-2-en; but-1-en. Vit
phng trnh v gi tn sn phm chnh.
Cu 10. hidrat ha cc ancol sau: sec butylic; propylic; isobutylic; 3-metyl butan-1-ol; tert butylic;
pentan-2-ol; butan-2-ol; 2,3-imetylbutan-2-ol; butan-1-ol. Vit phng trnh v gi tn sn phm chnh.
Cu 12. Vit CTCT cc cht sau: etylic; butan-2-ol; propylic; 2-metyl butan-1-ol; 2,3-imetylbutan-2-ol.
Cc cht khi tch nc ch to mt anken duy nht?
Cu 12. Vit CTCT cc cht: butan-1-ol; propylic; 3-metyl butan-1-ol; 2,3-imetylbutan-2-ol; butan-2-ol.
Cc cht khi hidrat ha to hai anken?
Cu 13. Vit CTCT cc cht sau: pentan-2-ol; butan-2-ol; 3-metylbutan-2-ol; pentan-1-ol; butan-1-ol. Cc
cht khi un vi H2SO4 c /170o to mt anken duy nht?
3. Dn xut halogen/OH-,to
Cu 1. Vit phng trnh iu ch etilenglicol t C 2H4.
Cu 2. Vit phng trnh iu ch glixerol t propen C3H6.
Cu 3. Vit CTCT ca cc dn xut halogen C 2H4Cl2, C3H6Br2, C3H5Cl3, C4H8Br2. Khi thy phn trong
NaOH/to to sn phm tc dng vi Cu(OH)2 nhit thng.
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Cu 3. Vit CTCT v gi tn sn phm chnh ca cc phn ng sau:

a. Clo ha isopentan (1 : 1, as).
b. Brom ha benzen (1 : 1, Fe, to).
c. Clo ha toluen (1 : 1, as).
d. Brom ha toluen (1 : 1, Fe, to).
e. Clo ha propilen (1 : 1, as).
4. Tnh cht vt l (s nh hng ca lk Hidro n si, tan)
Cu 1. V sao ancol tan tt trong nc cn hidricacbon th khng?
Cu 2. V sao ancol c nhit si cao hn cc ete, hidricacbon tng ng?
Cu 3. Vit CTCT cc cht sau: etylic; butan-2-ol; propylic; 2-metyl butan-1-ol; tert butylic. Sp xp theo
nhit si tng dn.
Cu 4. Vit CTCT cc cht: butan-1-ol; propylic; isobutylic; 3-metyl butan-1-ol; butan-2-ol. Sp xp theo
nhit si tng dn.
Cu 5. Vit CTCT cc cht sau: pentan-2-ol; sec butylic; 3-metylbutan-2-ol; pentan-1-ol; n-butylic. Sp xp
theo nhit si gim dn.
Cu 6. Vit CTCT cc ancol sau: sec butylic; propylic; isobutylic; 3-metyl butan-1-ol; tert butylic; pentan-2ol; 2,3-imetylbutan-2-ol; etylic. Sp xp theo nhit si gim dn.
5. Phn ng vi kim loi mnh Na, K, Ca, Ba
a. Tnh th tch H2 lin quan n ru
Cu 1. Cho 10ml ancol 46o (d = 0,8 g/ml) tc dng ht vi Na d th c bao nhiu lit H2.
Cu 2. Cho 30ml ancol 92o (d = 0,78 g/ml) tc dng ht vi Na d th c bao nhiu lit H2.
Cu 3. Cho 92ml ancol 23o (d = 0,789 g/cm3) tc dng ht vi Kali d th c bao nhiu lit H2.
Cu 4. Cho 10ml ancol xo (d = 0,8 g/ml) tc dng ht vi Na d th c 2,29 lit H2. Tm x.
Cu 5. Cho 54ml ancol yo (d = 0,8 g/ cm3) tc dng ht vi Na d th c 28,2912 lit H2. Tm y.
Cu 6. Cho 45ml ancol ao (d = 0,8 g/cm3) tc dng ht vi Kali d th c 19,152 lit H2. Tm a.
b. Tm ancol v th tch H2 bng phng php bo ton khi lng
Cu 1. Cho 3,7 gam ancol n chc tc dng Na sau phn ng thu c 0,56 lit kh (ktc). Tm ancol.
Cu 2. Cho 6,2 gam ancol hai chc tc dng kali sau phn ng thu c 2,24 lit kh (ktc). Tm ancol.
Cu 3. Cho 9,2 gam ancol n chc tc dng Na sau phn ng thu c 13,6 gam mui v V lit kh (ktc).
Tm V v ancol.
Cu 4. Cho 4,6 gam ancol ba chc tc dng kali sau phn ng thu c 7,45 gam mui v V lit kh (ktc).
Tm V v ancol.
Cu 5. Cho 6,9 gam hai ancol n chc (hn nhau 2 nguyn t C trong phn t) tc dng Na sau phn ng
thu c 10,2 gam mui v V lit kh (ktc). Tm V v hai ancol.
Cu 6. Cho 2,3 gam hai ancol n chc (hn nhau 28 vC) tc dng 4,6 gam Na sau phn ng thu c
6,85 gam cht rn v V lit kh (ktc). Tm V v hai ancol.
Cu 7. Cho 4,6 gam hai ancol a chc c cng s nhm -OH (hn nhau 14 vC) tc dng 6 gam Na sau
phn ng thu c 10,45 gam cht rn v V lit kh (ktc). Tm V v hai ancol.
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6. Phn ng c trng ca ancol a chc c nhiu nhm OH- k tip vi Cu(OH)2

Cu 1. Cn bao nhiu gam glixerol ha tan ht 9,8g ng hidroxit. Nu thay glixerol bng elienglicol th
khi lng tng ng bao nhiu gam.
Cu 2. Cho 16,32 gam hn hp etilenglicol va glixerol tc dng va vi 10,29g Cu(OH) 2. Tnh phn
trm s mol mi cht trong hn hp.
Cu 3. Chia m gam hn hp ancol etylic v glixerol thnh hai phn bng nhau. Phn 1: tc dng ht vi Na
d thu c 4,48 lit H2 (ktc). Phn 2: c kh nng ha tan ti a 4,9 gam Cu(OH) 2. Tnh m v phn trm
khi lng mi cht trong hn hp.
Cu 4. Chia 26,2 gam hn hp hai ancol n chc k tip A, B v glixerol thnh hai phn bng nhau. Phn
1: tc dng ht vi Na d thu c 2,24 lit H 2 (ktc). Phn 2: c kh nng ha tan ti a 2,45 gam Cu(OH) 2.
Tnh tm hai ancol A, B v tnh phn trm khi lng mi cht trong hn hp.
7. Phn ng tch H2O to ete (140oC/H2SO4 c) - anken (170oC/H2SO4 c)
a. Bin lun tm nhit thch hp - Tm ancol, ete, anken
Cu 1. un nng hn hp ancol X vi H 2SO4 c nhit thch hp thu c cht hu c Y c t khi so
vi X bng 0,6086. Hy cho bit nhit thch hp, tm CTPT ca X v Y.
Cu 2. un nng hn hp ancol X vi H 2SO4 c nhit thch hp thu c cht hu c Y c t khi so
vi X bng 1,4375. Hy cho bit nhit thch hp, tm CTPT ca X v Y.
Cu 3. un nng hn hp ancol X vi H 2SO4 c nhit thch hp thu c cht hu c Y. T khi ca
X so vi Y bng 1,428. Hy cho bit nhit thch hp, tm CTPT ca X v Y.
Cu 4. un nng hn hp ancol X vi H 2SO4 c nhit thch hp thu c cht hu c Y. T khi ca
Y so vi X bng 1,608. Hy cho bit nhit thch hp, tm CTPT ca X v Y.
b. Tm s sn phm to thnh Tnh s mol mi ete
Cu 1. un hn hp 3 ancol vi H2SO4 c, 140oC thu c bao nhiu ete?
Cu 2. un hn hp 5 ancol vi H2SO4 c, 140oC thu c bao nhiu ete?
Cu 3. un hn hp cc ancol ca CH 3OH, CH3CH2CH2OH vi H2SO4 c, 140oC thu c bao nhiu
ete?
Cu 4. un hn hp cc ancol ca CH3OH, C3H7OH vi H2SO4 c, 140oC thu c bao nhiu ete?
Cu 5. un hn hp cc ancol ca CH 3OH, C3H7OH vi H2SO4 c, 180oC thu c ti a bao nhiu sn
phm?
Cu 6. un hn hp 3 ancol c khi lng 166 gam vi H2SO4 140oC thu c cc ete c khi lng 139
gam, s mol bng nhau. Tnh s mol ca mi ete.
Cu 7. un hn hp 2 ancol c khi lng 120 gam vi H2SO4 140oC thu c cc ete c khi lng 102
gam, s mol bng nhau. Tnh s mol ca mi ete.
Cu 8. un hn hp 2 ancol k tip c khi lng m gam vi H 2SO4 140oC thu c cc ete c khi
lng 102 gam v 18 gam nc. Tm cc ancol.
Cu 9. un hn hp 2 ancol k tip c khi lng 134 gam vi H 2SO4 140oC thu c cc ete c khi
lng 102 gam, s mol bng nhau. Tnh cc ancol.

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8. Phn ng este ha vi axit (H2SO4 c/t o)

Cu 1. un nng hn hp gm 4,6g ancol etylic v 6g axit axetic (CH 3COOH) vi H2SO4 c nhit
thch hp thu c este (hiu sut 80%). Tnh khi lng este thu c.
Cu 2. un nng hn hp gm 4,6g ancol etylic v 4,6g axit axetic (CH 3COOH) vi H2SO4 c nhit
thch hp thu c este (hiu sut 75%). Tnh khi lng este thu c.
Cu 3. un nng hn hp gm m gam ancol etylic v axit axetic (CH 3COOH) d vi H2SO4 c nhit
thch hp thu c 8,8g este (hiu sut 75%). Tnh khi gi tr m.
Cu 4. un nng hn hp gm m gam ancol metylic v axit axetic (CH 3COOH) d vi H2SO4 c nhit
thch hp thu c 7,4g este (hiu sut 80%). Tnh khi gi tr m.
9. Phn ng oxi ha khng hon ton (CuO/to hoc O2/xt)
Cu 1. Oxi ha bng CuO/to 4,6g mt ancol n chc mch h, sau phn ng thu c 6,2g hn hp gm
anehit, nc v ancol d. Tm ancol v tnh hiu sut phn ng oxi ha.
Cu 2. Oxi ha 6g mt ancol n chc mch h, sau phn ng thu c 8,08g hn hp gm anehit, nc
v ancol. Tm ancol v tnh hiu sut phn ng oxi ha.
Cu 3. Oxi ha 3g mt ancol n chc bng CuO/t o thu c 4,056g hn hp gm ancol, anehit, nc.
Tm ancol v tnh hiu sut phn ng oxi ha.
Cu 4. Oxi ha mt ancol n chc c khi lng 5,4 g sau phn ng thu c 7,32g hn hp gm ba cht.
Tm ancol v tnh hiu sut phn ng oxi ha.
10. Phn ng oxi ha hon ton (phn ng chy)
Cu 1. t chy hon ton hn hp hai ancol no n chc mch h k tip cn dng V lit oxi (ktc) thu
c 5,6 lit CO2 v 6,3g nc. Tnh m, V, tm hai ancol v phn trm khi lng mi ancol.
Cu 2. t chy hon ton m gam mt ancol no n chc mch h cn dng V lit oxi (ktc) thu c 4,48
lit CO2 v 5,4g nc. Tnh m, V, tm CTPT ancol. Nu un nng lng ancol trn vi H 2SO4 c/140o th
c bao nhiu gam ete.
Cu 3. t chy hon ton m gam hn hp hai ancol no hai chc mch h k tip cn dng V lit oxi (ktc)
thu c 5,6 lit CO2 v 6,3g nc. Tnh m, V v tm hai ancol. Nu em hn hp trn tc dng vi Na d th
c bao nhiu lt kh H2 (ktc).
Cu 4. t chy hon ton m gam hn hp ba ancol no n chc mch h cn dng V lit oxi (ktc), hp th
ton b sn phm chy vo bnh ng Ca(OH) 2 d th c 30 gam kt ta, khi lng bnh tng 20,76 gam.
Tnh m, V v tm hai ancol. Nu un nng lng ancol trn vi H2SO4 c/140o th c bao nhiu gam ete.
Cu 5. t chy hon ton m gam hn hp hai ancol no hai chc mch h k tip cn dng V lit oxi (ktc),
hp th ton b sn phm chy vo bnh ng nc vi trong d th c 20 gam kt ta, khi lng dung
dch sau phn ng gim 6,16 gam. Tnh m, V v tm hai ancol. Nu em hn hp trn tc dng vi Kali d
th c bao nhiu lt kh H2 (ktc).
Cu 6. t chy hon ton m gam hn hp hai ancol no a chc mch h (c cng s nhm chc v hn
nhau 2 nguyn t C trong phn t) cn dng V lit oxi (ktc), hp th ton b sn phm chy vo bnh ng
Ba(OH)2 d th c 59,1 gam kt ta, khi lng dung dch sau phn ng gim 38,34 gam. Tnh m, V v
tm hai ancol. Nu em hn hp trn tc dng vi Kali d th c bao nhiu lt kh H 2 (ktc).
11. Ln men ru (phng php vi sinh)
Cu 1. Tnh khi lng ancol etylic to thnh khi ln men 180g glucozo, hiu sut 75%.

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Cu 2. Tnh khi lng ancol etylic to thnh khi ln men 162g tinh bt, hiu sut qu trnh 81%.
Cu 3. Tnh khi lng ancol etylic to thnh khi ln men 3,24kg tinh bt, hiu sut mi giai on 81%.
Cu 4. Tnh th tch ancol etylic (d = 0,8 g/ml) to thnh khi ln men 540g glucozo, hiu sut 80%.
Cu 5. Tnh th tch ancol etylic (d = 0,78 g/cm 3) to thnh khi ln men 1,62kg tinh bt, hiu sut mi giai
on 81%.
Cu 6. Tnh khi lng glucozo c ln 5% tp cht tr cn dng ln men thu c 500ml ru etylic bit
ru nguyn cht c d = 0,8 g/ml hiu sut qu trnh 70%.
Cu 7. Tnh th tch ancol etylic (d = 0,78 g/cm 3) to thnh khi ln men 6,4kg tinh bt cos ln 4% tp cht
tr, hiu sut mi giai on 78%.
Cu 8. Tnh khi lng glucozo c ln 2% tp cht tr cn dng ln men thu c 6 lit ru etylic 46 o
bit ru nguyn cht c d = 0,8 g/ml hiu sut qu trnh 85%.
Cu 9. Tnh khi lng tinh bt c ln 3,5% tp cht tr cn dng ln men thu c 2,3 lit ru etylic
92o bit ru nguyn cht c d = 0,8 g/ml hiu sut qu trnh 81%.
Cu 10. Tnh khi lng tinh bt c ln 5% tp cht tr cn dng ln men thu c 3 lit ru etylic 23 o
bit ru nguyn cht c d = 0,8 g/ml hiu sut mi giai on 80%.
Cu 11. Ngi ta ln men 3 kg glucozo sau phn ng thu c 1,725 lit ru etylic (d = 0,78 g/cm 3) nguyn
cht. Tnh hiu sut qu trnh ln men.
Cu 12. Ngi ta ln men 1,62 kg tinh bt vi hiu sut mi giai on bng nhau sau phn ng thu c 0,6
lit ru etylic (d = 0,78 g/cm3) nguyn cht. Tnh hiu sut mi giai on ln men.
Cu 13. Ngi ta ln men 3,6 kg glucozo sau phn ng thu c 3,75 lit ru etylic 46 o, bit ru nguyn
cht c d = 0,78 g/cm3. Tnh hiu sut qu trnh ln men.
Cu 14. Ngi ta ln men 4,86 kg tinh bt c ln 2% tp cht tr vi hiu sut mi giai on bng nhau sau
phn ng thu c 3,26 lit ru etylic 46 ; bit ru nguyn cht c d = 0,78 g/cm 3. Tnh hiu sut mi giai
on ln men.
12. Vit phng trnh phn ng v thc hin chui phn ng
(gio vin ra sau)
B. PHENOL RU THM ETE THM
1. CTCT v tn gi phenol, ancol thm v ete thm
Cu 1. Hy cho bit s khc nhau gia Phenol v Ancol thm v c im cu to (v tr gn nhm -OH) v
tnh cht ha hc c trng (tc dng Na, NaOH, dung dch Br 2)?
Cu 2. Cho hp cht thm c CTPT C7H8O. Vit CTCT tha mn tnh cht sau:
a. Tc dng vi Na, khng tc dng vi NaOH.
b. Tc dng vi NaOH.
c. Khng tc dng vi Na v NaOH.
Cu 3. Cho hp cht thm c CTPT C8H10O. Vit CTCT tha mn tnh cht sau:
a. Tc dng vi Na, khng tc dng vi NaOH.
b. Tc dng vi Na v NaOH.
c. Khng tc dng vi Na v NaOH.
d. Tch H2O to sn phm phn ng trng hp to ra polime.
Cu 4. Cho hp cht thm X c CTPT C7H8O2. Vit CTCT tha mn tnh cht sau:
a. Tc dng vi Na to s mol kh bng vi s mol cht X v tc dng vi NaOH t l 1 : 1.
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b. X tc dng vi NaOH theo t l 1 : 2.

c. X khng tc dng vi NaOH v tc dng vi Na to s mol kh bng mt na s mol cht X.
d. X khng tc dng vi NaOH v tc dng vi Na to s mol kh bng vi s mol ca X.
Cu 5. Tm t l phn ng ca cc cht sau vi Na v NaOH
a. CH3-C6H4-OH.
b. HOCH2-C6H4-OH.
c. CH3-O-C6H3-(OH)2.
d. HO-C6H4-CH(OH)2.
e. CH3-O-C6H4-O-CH3.
f. CH2OH-C6H4-O-CH3.
2. Tnh cht vt l - ng dng
Cu 1. Tr li cc cu hi sau:
a. Phenol tan c trong nc nhit no?
b. Phenol v Ancol thm cht no tan c trong nc lnh?
c. Nu hin tng khi lu Phenol trong khng kh m.
d. V sao Phenol tc dng c vi NaOH cn Ancol th khng?
e. V sao Phenol tc dng c vi Br2 d hn Benzen?
f. V s tng tc gia nhm OH v vng benzen.
Cu 2. Tr li cc cu hi sau:
a. Phenol trong cng nghip c sn xut trc tip t hidrocacbon thm no? Vit phng trnh.
b. Trong cng nghip phenol dng lm nguyn liu sn xut cc cht no? Vit phng trnh.
3. Tnh cht ha hc (s tng tc qua li gia nhm OH- v vng benzen)
a. Tc dng vi Na, NaOH
Cu 1. Tr li cc cu hi sau:
a. V sao phenol c tnh axit cn ancol th khng?
b. Vit phng trnh chng minh phenol c tnh axit yu.
c. Phenol v Benzen cht no tham gia phn ng th vi Br2 d hn. V sao?
d. Phenol tc dng vi cht no trong cc cht sau: Na, NaOH, Na 2CO3, NaHCO3, Br2, HNO3,
HCHO, (CH3CO)2O (anhidric axetic), HCl.
e. Dung dch Natriphenolat (C6H5ONa) tc dng vi cc cht no sau y: NaOH, CO 2, Na2CO3, Br2,
HCl, HNO3.
f. Cc cht: phenol, imetyl ete, o-crezol, ancol benzylic, metyl phenyl ete. Cht tc dng vi Na?
g. Cc cht: phenol, imetyl ete, etyl phenyl ete, p-crezol, ancol benzylic. Cht tc dng vi NaOH?
h. Cc cht: phenol, metyl isopropyl ete, m-crezol, metyl phenyl ete, ancol benzylic, 1,4-ihidroxi
phenol. Cht tc dng vi dung dch brom? Vit phng trnh (ty chn t l phn ng 1 : 1 hoc 1 : 3).
i. Cc cht: phenol, metyl isopropyl ete, o-crezol, ancol benzylic, metyl phenyl ete, 1,3-ihidroxi
phenol. Cht tc dng vi NaOH? Phng trnh.
Cu 2. Cho 14g hn hp phenol v etanol tc dng va vi 200ml NaOH 0,5M. Tnh phn trm khi
lng mi cht trong hn hp.
Cu 3. Cho 18,6g hn hp phenol v etanol tc dng vi Na d thu c 3,36 lit kh (ktc). Tnh phn trm
khi lng mi cht trong hn hp. Hn hp trn tc dng vi Br2 d th c bao nhiu gam kt ta.

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Cu 4. Cho 20g hn hp phenol, ancol benzylic v crezol tc dng vi Na d thu c 2,24 lit kh (ktc).
Tnh phn trm khi lng mui thu c sau phn ng.
Cu 5. Cho m gam hn hp phenol, ancol benzylic, crezol tc dng vi kali d thu c 1,12 lit kh (ktc)
v 13,8 gam cht rn. Tnh gi tr m.
Cu 6. Cho 15 gam hn hp phenol, ancol etylic, crezol tc dng vi kali d thu c V lit kh (ktc) v
20,7 gam cht rn. Tnh gi tr m.
Cu 7. Cho 12,48 gam hn hp phenol, o-crezol, m-crezol tc dng va vi V ml KOH 1M ri c cn
thu c 17,04 gam cht rn. Tnh gi tr m.
Cu 8. Cho 11,88 gam hn hp phenol, o-crezol, m-crezol tc dng va vi 55g KOH 11,2% ri c cn
thu c 50,82 gam cht hi v m gam cht rn. Tnh gi tr m. Nu cho hn hp trn tc dng vi kali d
th bao nhiu lit kh (ktc)?
Cu 9. Cho 13,52 gam hn hp phenol, p-crezol, m-crezol tc dng va vi 50g KOH 7,84% v NaOH
4,8% ri c cn thu c 39,7 gam cht hi v m gam cht rn. Tnh gi tr m. Nu cho hn hp trn tc
dng vi natri d th bao nhiu lit kh (ktc)?
Cu 10. Chia m gam hn hp phenol v etanol thnh hai phn bng nhau. Phn 1: tc dng va vi
100ml NaOH 0,5M. Phn 2: tc dng vi kali d th c 2,24 lit kh (ktc). Tnh m v phn trm khi
lng mi cht trong hn hp.
b. Phn ng Brom ha Nitro ha
Cu 1. Vit CTCT cc cht v tr li cc cu hi sau:
a. Cc cht: phenol, imetyl ete, o-crezol, metyl phenyl ete. Cht tc dng vi Br 2?
b. Cc cht: o-crezol, etyl phenyl ete, p-crezol, ancol benzylic. Cht tc dng vi Br 2?
c. Cc cht: metyl isopropyl ete, m-crezol, metyl phenyl ete, 1,4-ihidroxi phenol. Cht tc dng vi
dung dch brom? Vit phng trnh (ty chn t l phn ng 1 : 1 hoc 1 : 3).
d. Cc cht: phenol, etyl n-propyl ete, o-crezol, ancol benzylic, metyl phenyl ete, 1,3-ihidroxi
phenol. Cht tc dng vi Br2?
Cu 2. Cho 9,3g hn hp phenol v etanol tc dng vi dung dch Brom d th c 16,55g kt ta. Tnh
phn trm khi lng mi cht trong hn hp.
Cu 3. Chia m gam hn hp phenol v etanol thnh hai phn bng nhau. Phn 1: tc dng vi dung dch
Brom d th c 33,1g kt ta. Phn 2: tc dng vi Na d th c 2,24 lit kh (ktc). Tnh m v phn
trm khi lng mi cht trong hn hp.
Cu 4. Cho m1 gam hn hp phenol v NaHCO 3 tc dng vi dung dch Brom d th c m 2 gam kt ta
v 3,36 lit kh (ktc), thm tip HCl n d th lng kh thot ra thm 2,24 lit. Vit phn ng. Tm m 1, m2.
Cu 5. Nitro ha 9,4 kg phenol hiu sut 80% th c bao nhiu kilogam thuc n TNT?
Cu 6. Tnh khi lng phenol cn sn xut 2,29 kg thuc n TNT bit hiu sut phn ng 75%?
Cu 7. Tnh khi lng axit nitric cn sn xut 6,87 kg thuc n TNT bit hiu sut phn ng 90%?
Cu 8. Tnh khi lng dung dch axit nitric 94% cn sn xut 4,58 kg thuc n TNT bit hiu sut qu
trnh phn ng 90%?
Cu 9. Tnh khi lng phenol v dung dch axit nitric 63% cn sn xut 9,16 kg thuc n TNT bit hiu
sut qu trnh phn ng 80%?
Cu 10. Tnh th tch dung dch axit nitric 97% (d = 1,8g/ml) cn sn xut 9,2 kg thuc n TNT bit hiu
sut qu trnh phn ng 78%?

Trn Quc on Chng 7. Ancol Phenol Ancol v Ete Thm Face: Quoc Doan Tran Tel 0979 654 736

4. iu ch Phenol - Ancol thm

Cu 1. Tnh khi lng phenol thu c t 7,8 kg benzen, bit hiu sut c qu trnh 80%.
Cu 2. Cho s phn ng Benzen Cumen Phenol. Tnh khi lng phenol thu c t 7,8 kg
benzen, bit hiu sut mi giai on 75%.
Cu 3. Cho s phn ng Benzen Cumen Phenol. Tnh khi lng benzen cn dng sn xut 9,4
kg phenol, bit hiu sut mi giai on 75%.
Cu 4. Cho s phn ng Benzen Cumen Phenol. Tnh khi lng cumen cn dng sn xut 4,7
kg phenol, bit hiu sut mi giai on 85%.
Cu 5. Cho s phn ng Benzen Cumen Phenol. sn xut 4,7 kg phenol ngi ta dng 4,1 kg
benzen. Tnh hiu sut ca qu trnh.
Cu 6. Cho s phn ng Benzen Cumen Phenol. Ngi ta phi dng 3,9 kg benzen sn xut 4,3
kg phenol. Hiu sut ca mi giai on nh nhau. Tnh hiu sut mi giai on.

Trn Quc on Chng 7. Ancol Phenol Ancol v Ete Thm Face: Quoc Doan Tran Tel 0979 654 736