CHAPTER I

1 . Purification of Lithium Carbonate . . . . . . . . . .

2

. Purification of Silver Residues . . . . . . . . . . . .

3 . Preparation of Amalgams . . . . . . . . . . . . . .
4 . Sodium Amalgam . . . . . . . . . . . . . . . . .
5 . Barium Amalgam . . . . . . . . . . . . . . . . .
A . By Electrolysis . . . . . . . . . . . . . . . . . . . . .
B . By Displacement . . . . . . . . . . . . . . . . . . . .

6 . Amalgams of Lanthanum, Neodymium, and Cerium . .

. Red Mercuric Sulfide

CHAPTER I1

.
.................
CHAPTER 111

8 . Boron Trifluoride . . . . . . . . . . . . . . . . .
9 . Potassium Fluoborate
I

10 . Gallium Trichloride . . . . . . . . . . . . . . . . .
11 . Anhydrous Rare-Earth Chlorides . . . . . . . . . . .
12 . Carbon Tetrafluoride . . . . . . . . . . . . . . . . .
13 . Trioxalato Salts . . . . . . . . . . . . . . . . . .
A Potassium Tri-oxalato-aluminiate
B Potassium Tri-oxalato-ferriate
C . Potassium Tri-oxalato-cobaltiate . . . . . . . . . . . . .

..............
CHAPTER IV

. ............
. ..............
D . Potassium Tri-oxalato-chromiFte . . . . . . . . . . . . .
14 . Silicobromoform (Tribromosllane) . . . . . . . . . .
15 . The Higher Chlorides of Silicon . . . . . . . . . . .
16 . Lead Dioxide . . . . . . . . . . . . . . . . . . .

17 . Lead Tetracetate . . . . . . . . . . . . . . . . .
18 . Anhydrous Zirconium Bromide . . . . . . . . . . .
19 . Anhydrous Thorium Bromide . . . . . . . . . . . .
20 . Nitrosyl Chloride

21

. Monochloramine. . . . . . . . . . . . . . . . . .

CHAPTER V

.................

VOLUME I1
CHAPTER I

1. Copper(1) Chloride. . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
2. Silver Chlorate.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
3. Recovery of Silver and Iodine from Silver Iodide
Residues. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . G
10
CHAPTER I1

1. Metal Derivatives of 1,3-Diketones. . . . . . . . . . .

5. Beryllium Acetylacetonate [Eis(2,4-pentanedion
lium] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
6. Barium Bromate. . . . . . . . . . . . . . . . . . . . . . 20
CHAPTER I11

7. Porous Boron Oxide.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

S. Ammonium Tetrafluoborate. . . . . . . . . . . . . . . . . . . . . . . . . 23
A. Reaction in Aqueous Solution.. . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
B. Fusion Reaction.. . . . . . . . . . . . . . . . .

9. Aluminum Acetylacetonate [Tris(

minum] . . . . . . . . . . . . . . . . . 25
10. Gallium(II1) Perchlorate 6-Hydrate . . . . .
. 2G
. . . . . 11. The Rare Earth Elements and Their s . . 29
12. The Extraction of Rare Earth Minerals. I. Monazite
and Xenotime.. . . . . . . . . . . . . . . . . . . . . . . . .
B. Removal of Thorium . . . . . . . . . . . . . . . . .
. . 41
E. Subsequent Treatm

Cerite, and Gadolinite (Separation of Cerium and

Yttrium Earths by the Double Sulfate Met,hod). . . . . 44
A. Extraction. . . . . . . . . . . . . . . . . . . . . . . . .
C. Separation of Cerium and Yttrium Earths.
B. Precipitation o arths. . . . . . . . . . . . . . . . . . . . . . . 46

14, The Separation of Cerium from Rare Earth Mixtures. .

A. Separation of Cerium. . . . . . . . . . . . . . . . . . . . . 4s
15. Fractional Crystallization; The Magnesium Rare Earth
Nitrates. ......................... . . . . . . . . . . 52
A. Preparation of a Series.. ................................. 52
B. Fractional Crystallization.. .............................. 53
C. Modifications ........................................... 57
48
B. Recovery of Cerium.. . . . . . . . . . . . . . . . . . . . . 51
Ix

16 . The Average Atomic Weight of Rare Earth Elements in

a Mixture; Method Based on the Ratios. Oxslate:
Oxide and Oxalate : Permanganate . . . . . . . . . . . . . . . . . 58
17 . Rare Earth Bromates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
A . Preparation of the Rare Earth Eulleate Solution . . . . . . . . . . . . . 63

B . Preparation of Rare Earth Bromates., .................... 64

18 . Europium Amalgam; Separation of Europium from Rare

Earth Mixtures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
A . Preparation of Europium Amalgam . . . . . . . . . . . . . . . . . . . . . . . 66
B . Separation of Europium from Other Rare Earths ............ 68
19 . Europium(I1) Salts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
A . Europiurn(I1) Sulfate .................................... 70
B . Europium(I1) Carbonate ................................. 71
C . Europium(1I) Chloride ................................... 71
PAGE

CHAPTER IV

20 . Sugar Charcoal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
21 . Mo\osodiurn Acetylide (Ethynylsodium) . . . . . . . . . . . . .
74
75
A . Purification of Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . 76
B . Sodium Acetylide from Sodium a
C

. Sodium Acetglide from So

22 . Carbon Monoxide .......

23 . Ammonium Carbamate ..
24 . Alkali Metal Cyanates . . .
A . Potassium Cyanate .......
B . Sodium Cyanate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
25 . Cyanogen Chloride . . . . . . . . . . . . . . . . . . . . . . 90
26 . Silica Gel . . . . . . . . . . . . . .
27 . Disilicon Rexabromide (Hexabromodisilane) . . . . . . . . . . 98
28 . Gerrnanium(I1) Sulfide (Precipitated) . . . . . . . . . . . . . . . . 102
A . Reduction of Germanium(1V) Oxide ....................... 103
B . Reduction of Germanium(1V) Sulfide ...... . . . . . . . . . . 104

29 . Germanium(I1) Iodide . . . . . . . . . . . . . . . . . . . . . . . . . . 106

30 . Gemaniurn(1V) Chloride . . . . . . . . . . . . . . . . . . . . . . . . 109
31 . Germanium(1V) Iodide ......... . . . . . . . . . . . . . . . . . 112
32 . Titanium(1V) Bromide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
33 . Titanium(II1) Bromide ............................. 116
34 . Bis[tris(2, 4-pentanediono)titanium(IV)] Hexachloroti-

35. Zirconium Acetylacetonate [Tetrakis(2,4-pentanediono) 36 . Thorium Acetylacetonate [Tetrakis(2,4-~entanedion)otanate(

1V) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
zirconium] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
thorium] ........................................ 123
CHAPTER V

38 . Sodium Amide .................................... 128

39 . Ammonium Aeide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136
40 . Potassium Azide (Sodium Azide) .................... 139

A . Butyl Nitrite ........................................... 139

B . Potassium Azide ........................................ 140

41 . Phosphonium Iodide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141

42 . Phosphorus(II1) Chloride ........................... 145
43 . Phosghorus(I1I) Bromide . . . . . . . . . . . . . . . . . . . . . . . . . . . 147
44 . Phosphorue(V) Oxybromide (Phogphoryl Tribromide) . . 151
45 . Phosphorus (V) Sulfobromide (Thiophosphoryl Tribre
mide) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
46 . Ammonium hlonofluophasphate ..................... 155
47 . Ammonium Difluophosphate ........................ 157
48 . Addition Compound of Sulfur Dioxide and Trimethylamine
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159
49 . SuIfites and Pyrosulfites of the Alkali Metals . . . . . . . . . . 162
A . Sodium Sulfite and Sodium Pyrosulfite ..................... 162
B . Potassium Sulfite and Potassium Pyrosulfite ................ 166

50 . Salts of Dithionic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167

A . Calcium Dithionate ..................................... 168
B . Barium Dithionate ........ ......................... 170
C . Sodium Dithionate . . . . . . . . ......................... 170

173
A . Pyridine-Sulfur Trioride . ......................... 173
B . Dimethylaniline-Sulfur T ......................... 174
C . DioxaneSulfur Trioxide ................................ 174

52

. Sulfamic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 176

A . Sulfamic Acid from Hydroxylammonium Sulfate

B . Sulfamic Acid from Acetoxime ............................. 177
C . Purification of Sulfamic Acid for Use as an Acidimetric
PAW

CHAPTER VI

51 . Addition Compounds of Sulfur Trioxide . . . . . . . . . . . . . .

................................
53 . Tria
A . Ammonium Sulfamate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180
B . Triammonium Imidodisulfate 1-Hydrate . . . . . . . . . . . . . . . . . . . 180

5-2 Potassium Nitridotrisulfate 182

55 . Aluminum Selenide and Hydrogen Selenide . . . . . . . . . . . 183
56 Potassium and Sodium Selenocyanates 186
57 Hexahalogenotellurates(1V) (Halotellurites) 188
A Ammonium Hexachlorotellurate(1V) 189
B . Potassium Hexabromotellurate(1V) . . . . . . . . . . . . . . . . . . 189
58 Chromium(II1) Oxide Gel 190
193
60 . Tris (ethylenediamine) chromium (111) Salts 19G
idodisulf ate 1-Hydrate . . . . . . . .

. .........................

................
............
. .......................
...........................
59 . Anhydrous Chromium(II1) Chloride . . . . . . . . . . . . . . . . .
............
A . Anhydrous Chromium(II1) Sulfate ........................ 197
B Anhydrous Ethylenediamine., 197 C . Tris(ethylenediamine)chromium(III)

Sulfate .

.........

. . . . . 198
D . Tris (ethylenediamine) chromium (111) Chloride . . . . . . . . . . . . . . 198
E . Tris (ethyl enediamine) chromium (111) Halides .

. . . . . . . . . . . . . . 199

6 1. cis-Dichlorobis(ethy1enediamine) chromium (I1 I) Chloride

and trans-Bis(thiocyanat0) bis(ethy1enediamine)Pffil

chromium(I11) Thiocyanate. . . . . . . . . . . . . . . . . . . . . . . 200

62. Potassium Hexacyanochromate(II1) . . . . . . . . . . . . . . . . . . 203
63. Chromyl Chloride (Chromium(V1) Dioxychloride) . . . . . 205
64. Potassium Monochlorochromate. . . . . . . . .
CHAPTER VII

65. Hydriodic Acid; Regeneration of Oxidized Solutions. .

66. -Trisodium Ortho eriodate . (Sodium Paraperiodate) :

210

$"

Sodium Iodideromine Met.hod . . . . . . . . . . . . . . . . . . . "212

67. Potassium Hexacyanomanganate(II1) _. . . . . . . . .
CHAPTER VIII

68. Beta-Iron(II1) Oxide 1-Hydrate. .................... 215

69. Hexamminecobalt(II1) Salts. . . . . . . . . . . . . . . . . . . . . . . . 216
B. Hexamminecobalt(II1) Nitrate. . . . . . . . . . . . . . . . . . . . 218
C. Hexamminecobalt(II1) Bromide . . . . . . . . . . . . . . . . . . . 219
A. Hexamminecobalt (1II)r Chloride. . . . . . .
D. Hexamminecobalt(II1) Oxalate

70. Tris (ethylenediamine) cobalt (I

71. cis- and trans-Dichlorobis(ethylenediamine)cobalt(IIT) Chloride and the
Resolution of the cis-Form. . . . . . . . 222
A. Preparation of the trans-Form . . . . . . . . . . . . . . . . . . . 223
B. Conversion to the cis-Form.. . . . . . . . . . . 223
C. Resolution of the &-Form.. ............................. 224
72. Potassium Hexacyanocobaltate(II1). . . . . . . . . . . . . .
73. Potassium Tetracyanonickelate (11) . . . . . . . . . . . . . . .
74. The Metal Carbonyls ..........................
7G. Dicobalt Octacarbonyl, Cobalt Nitrosyl Tricarbonyl,
and Cobalt Tetracarbonyl Hydride. . . . . . . . . . . . . . . . . 288
A. Potassium Salt of Cobalt Tetracarbonyl Hydride 238
B. Cobalt Nitrosyl Tricarbonyl.. ............................ 239
C. Cobalt Tetracarbonyl Hydride
D. Dicobalt Octacarbonyl .......

77. Iron Tetracarbonyl Dihydrid

78. Potassium Tetracyanopallad
79. Potassium Tetrachloroplatin

80. Tetrammineplatinum(I1) Chloride (Tetrammineplati-

81. Plahinum(1V) Chloride. . . . . . . . . . . . . . .

Appendix. The Nomenclature of Inorganic Compounds.. . 257
Index of Contributors. ................................ 269
Subject Index. ....................................... 270
Formula Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 287
75. Nickel Tetracarbonyl. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23-1
platinite) . . . . . . . . . . . . . . . . . . . . . .
nous Chloride). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

VOL- III
CHAPTER I
1 . Sodium Peroxide &Hydrate .
CHAPTER I1
2

...............1

. Basic Beryllium Derivatives of Organic Acids . . . . . . . . 4

9
11
12
16
17
21
24
3

. Basic Beryllium Acetate and Propionate . . . . . . . . . .

. Strontium Sulfide and Selenide Phosphors . . . . . . . . . .

A . Preparation and Purification of Reagents . . . . . . . .

B . Special Techniques . . . . . . . . . . . . . . . . . .

. Preparation of Strontium Compounds . . . . . . . . . .

D . Preparation of Infrared-sensitive Phosphors .

......
Barium Thiocyanate . . . . . . . . . . . . . . . . . . .

5
CHAPTER I11
6

. Boron Chloride and Bromide . . . . . . . . . . . . . . . 27

. Aluminum Bromide . . . . . . . . . . . . . . . . . . . 30

7
CHAPTER IV
8
9

. Carbon Tetraiodide . . . . . . . . . . . . . . . . . . .
. Cyanamide . . . . . . . . . . . . . . . . . . . . . . .

10

. Dicyanodiamide (Cyanoguanidine) . . . . . . . . . . . . .

11

. Aminoguanidonium Hydrogen Carbonate (Aminoguanidine Bicarbonate)

......................
12
13
14

. Ammonium Dithiocarbemate . . . . . . . . . . . . . . .

. Organosilicon Compounds . . . . . . . . . . . . . . . . . .
. Dimethyldichlorosilane (Dimethylsilicon Dichloride) . . . . .

. Diphenylsilanediol . . . . . . . . . . . . . . . . . . . .
17 . Germanium(I1) Iodide (Germanium Diiodide) . . . . . . . .
18 . Methylgermanium Triiodide (Methyltriiodogermane) . . . .
19 . The Extraction of Hafnium and Zirconium from Cyrtolite . .
16

. Extraction . . . . . . . . . . . . . . . . . . . . . .
B . Analytical Methods . . . . . . . . . . . . . . . . . .
A

. Precipitation of Zirconium-Hafnium Phosphates . . . . .

. Conversion of the Phosphates to Acid-soluble Compounds .

. Fractionation of Zirconium and Hafnium . . . . . . . .

F . The Preparation of Low-hafnium Zirconia . . . . . . . .
E

ix

. Vinylchlorosilanes . . . . . . . . . . . . . . . . . . . .

15

. Nitrogen(V) Oxide (Nitrogen Pentoxide. Dinitrogen Pentoxide.

21 . Hydroxybmmonium Salts . . . . . . . . . . . . . . . .
20

A . Hydroxylammonium Phosphate . . . . . . . . . . . .
Nitric Anhydride) . . . . . . . . . . . . . . . . . . . 78
81
82
83

83
22 . The Poly- and Mctaphosphates and the Strong Phosphoric Acids 85

. Pyrophosphoric Acid (Diphosphoric Acid)

23

. . . . . . . . . 96

98

A Disodium Dihydrogen Pyrophosphrttc 99

100
101

26 . Sodium Metaphosphates . . . . . . . . . . . . . . . . . 103

A . Sodium Trimetaphosphate . . . . . . . . . . . . . . . 104

27 . Sodium Monofluophosphate .
28 .

. . . . . . . . . . . . . . . 106
Silver Monofluophosphate . . . . . . . . . . . . . . . . 109

. Hexafluophosphates of Sodium, Ammonium. and Potassium . 111

30 . Ammonium Metavanadate . . . . . . . . . . . . . . . . 117
29

CHAPTER VI

. Hydroxylammoniurn Arsenate . . . . . . . . . . . . .
C . Hydroxylammonium Oxalate . . . . . . . . . . . . . .
24 . Sodium Pyrophosphates (Sodium Diphosphates) . . . . . . .
B

B . Tetrasodium Pyrophosphate . . . . . . . . . . . . . .
25

. Sodium Triphosphate (Sodium Tripolyphosphate) . . . . . .

. ..........
B . Sodium Polymetaphosphate (Grahams Salt) . . . . . . 104
31 . Sulfur(V1) Fluoride (Sulfur Hexafluoride) . . . . . . . . . . 119
33 . Selenium(1V) Oxide (Selenium Dioxide) . . . . . . . . . . 127
34 . Selenium(1V) Oxychloride . . . . . . . . . . . . . . . . 130
35

. Crystalline Selenic Acid . . . . . . . . . . . . . . . . . 137

. Tellurium(1V) Chloride (Tellurium Tetrachloride) . . . . . . 140

37 . Tellurium(1V) Oxide (Tellurium Dioxide) . . . . . . . . . . 143
36

38 . Telluric Acid . . . . . . . . . . . . . . . . . . . . . . 145

39 . Chromium(I1) Acetate (Chromous Acetate) .

. . . . . . . . 148
40 . Anhydrous Chromium(I1) Chloride (Chromous Chloride) . . 150
41 . Hexamminechromium(II1) Nitrate . . . . . . . . . . . . . 153
42 . Chromium Hexacarbonyl . . . . . . . . . . . . . . . . . 156
43 . Potassium Octacyanomolybdate(1V) 2-Hydrate (Potassium
Molybdocyanide Dihydrate) . . . . . . . . . . . . . . 160
45 . Uranium(1V) Oxalate .
46

. . . . . . . . . . . . . . . . . 166

. Potassium Tetraoxalatouranate(1V) . . . . . . . . . . . . 109

32 . Disulfur Pentoxydichloride (Pyrosulfuryl Chloride) .

. . . . . 124
44 . Tungsten(VI) Chloride (Tungsten Hexachloride) . . . . . . 163
CHAPTER VII
47 . Anhydrous Metal Fluorides .

A . Nickel(I1) Fluoride .

.................

B . Cobalt(II1) Fluoride .

. . . . . . . . . . . . . . . 171
173

................

. Silver(I1) Fluoride . . . . . . . . . . . . . . . . . . 176

D . Carbon Tetrafluoride . . . . . . . . . . . . . . . . . 178

E Tantalum(Niobium) (V) Fluoride [Tantalum (Niobium)

Pentafluoride] . . . . . . . . . . . . . . . . . . . 179

. Tungsten(V1) Fluoride (Tungsten Hexafluoride) . . . . . 181

48 . Bromine(II1) Fluoride (Bromine Trifluoride) . . . . . . . 184
F

49 . Rhenium(V1) Oxide (Rhenium Trioxide) . . . . . . . . . . 186

50 . Rhenium(VI1) Oxide (Dirhenium Heptoxide) . . . . . . . . 188

CHAPTER VIII
51 . Anhydrous Iron(II1) Chloride (Ferric Chloride) .

. . . . . . 191

52 . Hexamminenickel(I1) Bromide and Hexamminenickel(I1)

Iodide . . . . . . . . . . . . . . . . . . . . . . . . 194

53 . Bis(N,N'-Disalicylalethylenediamine). ~.Aquodicobalt(II)
(Bis[ N . N'-bis (0- h ydroxy ben z y1idine)ethylenediaminel-paquodicobalt(
I1)) . . . . . . . . . . . . . . . . . . . 196

VOLUME IV

CHAPTER IA
1 . Lithium Nitride . . . . . . . . . . .
2 . Extraction of Cesium from Pollucite

. Cesium Antimony(II1) Chloride Method and

Preparation of Cesium Nitrate . . . . . .
B . Cesium Alum Method . . . . . . . .
h

C . Cesium Iododichloride Method . . . . .

CHAPTER IB
.....
3 . Silver(I1) Oxide . . . . . . . . . . .
4 . Gold Powder and Potassium Tetrabromoaurate(II1) .
CHAPTER IIA
5 . Calcium Dihydrogen Orthophosphate l-Hydrate . .
6 . Calcium Hydrogen Orthophosphate 2-Hydrate and Calcium
Hydrogen Orthophosphate . . . . . .

CHAPTER 111,4
7 . Aluminum Phosphide . . . . . . . . . .
CHAPTER IV
8 . Biurea . . . . . . . . . . . . . .
A . Preparation from Hydrazine Sulfate

B . Preparation from Hydrazine Hydrate . . . .

A . Preparation from Carbohydrazide

....
9 . Urazine . . . . . . . . . . . . .
B . Preparation from Carbohydrazide-N-carboxamide
.............
10 . Carbohydrazide . . . . . . . . . . . .
11 . Cyanate Condensation Products of Carbohydrazide .
A . Carbohydrazide-N-carboxamide . . . . .

B . Carbohydrazide-N,N',- dicarboxamide . . . .
ix

....
12 . Thiosemicarbazide . . . . . . . . . . .
13 . Iodotrichlorosilane and Diiododichlorosilane . . .
14 . Cyclohexyltrichlorosilane . . . . . . . . .
15 . Silicon Tetraacetate . . . . . . . . . .
CHAPTER V
16 . Nitrosyl Chloride . . . . . . . . . . .
17 . Nitryl Chloride . . . . . . . . . . .

18 . Phosphorous Acid . . . . . . . . . . .
19 . Diethyl Yhosphite .

..........

20 . Dioctyl Phosphite . . . . . . . . . . .
21 . Alkyl Dichlorophosphites . . . . . . . . .
22 . 2-Chloroethyl Dichlorophosphite . . . . . .
23~TfisodiumD ihydrogen Hypophosphate . . . . .
24 . Phosphorus(V) Sulfochloride . . . . . . . .

A . Preparation from Phosphorus(II1) Chloride, Aluminum

Trichloride, and Elcrnental Sulfur . .
B . Preparation from Phosphorus(V) Sulfide and
25 . 0-Ethyl Dichlorothiophosphate . . . . . . .
26 . Diethyl Monoamidophosphate . . . . . . .
27 . Diethyl Monochlorophosphate . . . . . . .
28 . Vanadium (111) Oxide and Vanadium(V) Oxytrichloride
(Correction) . . . . . . . . . . . .
Phosphorus(V) Chloride . . . . . . .
CHAPTER VI-4
29 . Sodium Superoxide . . . . . . . . . .
trichlorosilane . .
30 . 2-Chloroethyl Chlorosulfonate and (2-Ch1oroethoxy)#

31 . Sodium Selenopentathionate 3-Hydrate and Sodium

Telluropentathionate 2-Hydrate . . . . .
32 . Xanthates and Dithiocarbamates of Selenium(I1) and
Tellurium(I1) . . . . . . . . . . .

.........
CHAPTER VIB
33 . Addition Compounds of Chromium(V1) Oxide .
A . Pyridine-Chromium(V1) Oxide . . . . . .

3 . 3-Picoline-Chromium(VI) Oxide .

....

C . 4-Picoline-Chromium(VI) Oxide .

....

34 . Potassium Pentachloroaquomolybdate(II1) and Potassium

Hexachloromolybdate(II1) . . . . . .
35 . Bis(8-quinolinolo)dioxouranium(VI) and Its Addition
Compound with 8-Quinolinol . . . . . . .
CHAPTER VIIA
36 . Anhydrous Metal Halides . . . . . . . .
37 . Gallium(I1) Chloride . . . . . . . . . .
38 . Bismuth(II1) Iodide . . . . . . . . . .
39 . Aluminum Iodide . . . . . . . . . . .
40 . Tin(1V) Iodide . . . . . . . . . . . .
41 . Zirconium and Hafnium Tetrachlorides
42 . Vanadium(I1) Chloride . . . . . . . . .

43 . Vanadium(II1) Chloride
44 . Tantalum (V) Bromide
....

.........
.........
45 . Fluorination of Volatile Inorgarlic Compounds . .
46 . Methyl Chlorofluorophosphite and Methyl Difluorophosphite
.............
$7 . Silicon Tetrafluoride . . . . . . . . . .
48 . Germanium(1V) Fluoride . . . . . . . . .
49 . Phosphorus(II1) Fluoride . . . . . . . . .
50 . Arsenic(II1) Fluoride . . . . . . . . . .
51 . Chlorine(1V) Oxide . . . . . . . . . .
A . Small-scale Preparation of Chlorine (IV) Oxide
Admixed with Inert Gas and Chlorine
B . Preparation of Chlorine(1V) Oxide Free from
Chlorine . . . . . . . . . . . .
...

CHAPTER VIII
52 . Iron(I1) Formate . . . . . . . . . . .
53 . Iron(I1) Bromide 6-Ammoniate
54 . Potassium Ferrate(V1) . . . . . . . . .
56 . Acidopentamminecobalt(II1) Salts . . . . . .

B . Fluoropentamminecobalt(1II) Nitrate . . .

D . Nitropentamminecobalt(II1) Nitrate . . . .
E . Nitratopentamminecohalt(II1) Nitrate . . .
.......
55 . Nitrosylpentamminecobalt (11) Chloride, Black and
Nitrosylpentamminecobalt (111) Chloride. Pink . .

A . Carbonatopentamminecobalt(II1) Nitrate . .
C . Iodopentamminecobalt(II1) Nitrate . . . .
F . Acetatopentamminecobalt(II1) Nitrate . . . 175
57 . cis- and trans-Dinitrobis(ethylenediamine)cobalt(III)
Nitrate . . . . . . . . . . . . . 176
58 . trans-Dinitrodiamminepalladium(I1) . . . . . . 179