Ti liu n tp lp 11

THPT CMgar

on Phc

B. ANKAIEN
Cu 1. Vit cng thc cu to ca ankaien c cng thc phn t
C4H6; C5H8
a.
Gi tn, cho bit ankaien no l ankaien lin hp
b.
Cu 2. Vit phng trnh phn ng gia cc cht sau y theo t l s mol 1 : 1
a. Buta-1,3-ien v clo
b. Buta-1,3-ien v HBr
c. iso-pren v brom
Cu 3. Vit cng thc cu to ca ankaien sau:
Hexa-1,3-ien
Octa-1,4-ien/
Cu 4. Tnh lng brom ti a c th phn ng vi 1,68 lt (ktc) buta-1,3-ien
Cu 5. Tnh lng buta-1,3-ien thu c khi cho 240 lt ancol etylic 96O (khi lng ring ancol etylic nguyn cht l
0,8g/ml)i qua xc tc (ZnO+Al2O3) 500OC. Hiu sut phn ng l 80%
Cu 6. Cho 43,2g buta-1,3-ien phn ng vi dung dch brom thu c 53,5g hp cht A v 32,1g hp cht B. Phn t
hp cht A v B u cha74,77% Br
Vit cng thc cu to ca A, B v tnh hiu sut chung ca phn ng (theo khi lng), bit B c ng phn hnh
hc
Cu 7. t chy hon ton mt lng hirocacbon mch h A cn va ng 550cm3 oxi (ktc). Lm lnh hn hp sn
phm chy ngng t hi nc, sau dn phn sn phm cn li qua bnh ng dd KOH d thy khi lng bnh tng
thm 0,786g
a. Lp cng thc phn t ca A
b. Hirocacbon A c trng hp thnh cao su. Vit ctct ca A v phng trnh phn ng trng hp c th c
xy ra ca A
c. Tnh lng brom ti a c th phn ng vi 16,2g A
Cu 8. Ly hai lng bng nhau ca ankaien A, phn th nht cho phn ng vi brom d c cht B, phn th hai cho
phn ng vi clo d c hp cht C. Khi lng ca B v C khc nhau 7,2g
a. Lp ctpt ca A, B, C . Vit cng thc cu to thu gn ca A, bit rng khi lng ca sn phm cng brom thu
c l 155,2g
b. Tnh khi lng ca ankaien dng, gi s hiu sut phn ng vi clo v brom u bng 80%
Cu 9. hn hp kh A cha nit v hai hirocacbon k tip nhau trong mt dy ng ng. Khi lng hn hp A l
18,30g v th tch ca n l 11,20 lt. Trn A vi vi 1 lng d oxi ri t chy, thu c 11,70g H 2O v 21,28 lt CO2.
Cc th tch o ktc
Xc nh ctpt v % v khi lng ca mi hirocacbon trong hn hp A
Cu 10. Mt hirocacbon A c t l khilng mC : mH = 8 : 1
a. Tm cng thc phn t ca A , A l cht kh
b. vit phng trnh phn ng trng hp A, bit A l ankaien lin hp
Cu 11. Cho hn hp hai hirocacbon A v B vi MB MA = 24. Cho bit dB/A = 1,8. t chy hon ton V lt hn hp
trn thu c 11,2 lt CO2 v 8,1g H2O
a. Tnh V (ktc)
b. Cn bao nhiu gam ancol etylic iu ch lng hn hp hirocacbon u, bit A l ankaien lin hp
Cu 12. Mt hn hp X gm 1 anken v 1 ankaien c cng s nguyn t cacbon
a. t chy hon ton 1,0752 lt hn hp X (ktc) thu c 8,448g CO2. Xc nh ctpt ca hirocacbon, vit ctct
b. Nu khi lng brom cn dng phn ng ht vi hn hp trn l 13,44g. Hy tnh dX/H2
Cu 13. Dn 4,032 lt (ktc) mt ankaien lin hp qua bnh brom d thy khi lng bnh tng 9,72g
a. Xc nh ctpt ca ankaien. Vit ctct , gi tn
b. Vit phng trnh phn ng ca ankaien ny (ankaien lin hp) vi HCl (t l mol 1 : 1)
Cu 14. Trn ln 1 ankaen lin hp A v oxi d vo 1 kh nhin k to p sut ban u l 2atm (oxi chim 9/10 th tch
hn hp). bt tia la in t hn hp ri a v nhit ban u, cho hi nc ngng t ht th p sut gim so vi
ban u.
a. Xc nh ctpt ca A
b. Vit ctct ca A
c. Ho tan 3,36 lt A (ktc) trong 1,5 lt dd Br2 0,1M thu c 1 hn hp sn phm B
Vit phng trnh phn ng xy ra
-

Ti liu n tp lp 11

THPT CMgar

on Phc

Dung dch brom nh th no

Cu 15. t chy hon ton hirocacbon A (kh k thng), hn hp sn phm thu c CO 2 chim 76,52% khi lng
a. Xc nh ctpt ca A
b. Xc nh ctct ca A v hon thnh cc phn ng theo s :
A +Cl2, 1:1 B +dd NaOH C + H2, Ni,toc D + H2SO4, 180 A
cao su
-

C. ANKIN
Cu 1. Vit ctct thu gn v gi tn cc ankin c ctpt: C3H4, C4H6, C5H8
Cu 2. Vit phng trnh phn ng xy ra gia propin v cc cht sau: H 2 (xt:Pd/CaCO3); Br2 (dd), HCl, AgNO3/NH3
Cu 3. Vit cc phng trnh phn ng thc hin cc chuyn ho theo s
CH4
axetilen
vinyl axetilen
2-clo buta 1,3- ien
sn phm trng hp 1,4
Bezen
Cu 4. Vit phng trnh phn ng thc hin dy chuyn ho sau (ghi r iu kin nu c)
(4)
? (5) C2H6
(1)
(2)
(3)
CaCO3
?
CaC2
C2H2
(6)
? (7) CH2 CH
n
Cl
Cu 5. Hon thnh chui phn ng
(1)
a. Metan
axetilen (2)
etilen (3)
ancol etylic (4)
buta-1,3-ien (5)
(6)
(8)
Vinyl axetilen
b. Propan
metan
axetilen
vinyl axetilen
buta-1,3-ien

cao su buna

etilen
PE
c. . Natri axetat Metan axetilen vinyl axetilen buta1,3-ien cao subuna

Vinylclorua poli vinylclorua (PVC)

d. CaC2 C2H2 C4H4 C4H10 C2H4 C2H5OH

Poli etilen (P.E)

e. CH3COONa CH4 C2H2 C4H4 C4H6 cao su buna

C2Ag2 C2H2 C2H3Cl PVC

Cu 5a . Vit ctct cc ankin c tn sau: iso-butylaxetilen, metyl iso-propylaxetilen, 3-metylpen-1-in, 2,2,5,5tetrametylhex-3-in, xiclopropylaxetilen
Cu 6. So snh ngn la ca metan, etilen, axetilen khi t trong khng kh iu kin thng. Gii thch
Cu 6a. Phn bit cc kh sau bng phng php ha hc:
a. CH4, C2H4, C2H2, NH3, HCl
b. n-butan, but-1-en, buta-1,3-ien, but-1-in
c. metan, etilen, axetilen ch dng 1 ho cht
d. Butan, but-2-en, but-2-in, vinyl axetilen ch dng 1 ho cht
e. Axetilen, etilen, metan
f. But-1-in, but-2-in
g. Etan, propen, propin, kh cacbonic
h. Buta-1,3-ien , axetilen, etan
Cu 7. Tch ri hn hp sau:
a. Metan, etilen, axetilen
b. Metan, etilen, axetilen, amoniac, kh cacbonic
Cu 8. Tch ri metan ra khi hn hp: CH4, CO2, NH3, O2
Cu . C6H10 c bao nhiu ng phn phn ng c vi dd AgNO 3/NH3? Vit ctct v gi tn cc ng phn .
Cu 9. T than , vi v cc cht v c cn thit vit phng trnh phn ng iu ch: cc ng phn icloetan,
polietilen (PE), poli(vinyl clorua) (PVC), cao su buna, cao su cloropren, benzen.

Ti liu n tp lp 11

THPT CMgar

on Phc

Cu 10. Mt hn hp kh gm C2H2 v H2 c t khi so vi H2 l 5. nu un nng hn hp trn c xc tc thch hp, vi

hiu sut 100%. Tm % th tch cc kh thu c sau phn ng
Cu 11. Cho 2,24 lt hn hp X (ktc) gm C2H2 v C2H4 i qua dung dch Br2 (d) thy khi lng bnh ng dung dch
tng 2,7g
a. Vit ptp
b. Tnh % th tch v % khi lng mi kh trong hn hp u
Cu 12. Cho 3,36 lt hn hp A (ktc) gm C2H2 v CH4 qua dung dch AgNO3/NH3 d thy c 24,0g kt ta. Tnh khi
lng sn phm thu c khi t chy hon ton 6,72 lt hn hp trn
Cu 13. Trong bnh kn dung tch 35,84 lt cha hn hp kh axetilen v hiro (ktc) v 1 t bt Ni (th tch khng ng
k). Nung nng bnh 1 thi gian, sau lm lnh bnh n 0OC, ri chia hn hp kh trong bnh thnh 2 phn bng nhau
a. Dn bnh th nht qua dung dch AgNO3/NH3 (d) thy to ra 2,4g kt ta mu vng nht. Tnh th tch
axetilen (ktc) c to thnh trong bnh
b. Dn phn th 2 qua bnh dung dch brom d thy khi lng bng tng thm 0,82g. Tnh th tch etilen (ktc)
to ra
c. Tnh th tch etan sinh ra v th tch hiro cn li trong bnh sau phn ng (ktc). Bit t khi ca hn hp u
(axetilen v hiro trc phn ng) so vi hiro bng 4
Cu 14. Hn hp A gm 0,15 mol axetilen v 0,3 mol H2. Dn hn hp qua ng ng Ni, tOC, thu c hn hp kh B
gm etan, etilen, axetilen v H2 c LKPT trung bnh l 18. Tm hiu sar1 ca phn ng cng H2
Cu 15. Ngi ta thc hin phn ng trng hp 3 phn t (tam hp) axetilen to benzen bng cch un nng bnh kn
ng kh axetilen, c bt than, 600OC. Sau khi a nhit bnh v nh lc ban u. Coi th tch bnh khng i, xc tc
v bezen lng to ra chim th tch khng ng k, ngi ta nhn thy p sut trong bnh gim 2,5 ln so vi trc khi
phn ng. Tm hiu sut ca phn ng iu ch bezen t axetilen
Cu 16. Hn hp X gm C2H2 v H2 ly cng s mol. Ly mt lng hn hp X cho i qua cht xc tc thch hp, nung
nng thu c hn hp Y gm 4 cht. Dn hn hp Y qua bnh nc brom d thy khi lng bnh br 2 tng 10,8g v thot
ra 4,48 lt kh Z (ktc) c t khi so vi H2 bng 8. Tm th tch O2 (ktc) cn t chy ht hn hp kh Y
Cu 17. Cho hn hp gm axetilen v hiro vo ng A cha cht xc tc cho xy ra phn ng cng (khng xy ra phn
ng trng hp). Kh i ra khi ng A c dn vo bnh B cha dung dch AgNO 3/NH3 (d), ri vo bnh C cha dd brom
(d) ri vo mt kh k D.
Sau th nghim bnh B thu c 2,4g kt ta vng (kh), khi lng bnh C tng thm 1,96g, cn kh kt D cha
2624 cm3 kh
Cho oxi (d) v 100 cm3 kh D vo 1 kh nhin k ri t, sau cho tip xc vi dung dch KOH th thy th tch
hn hp sn phm trong kh nhin k gim 25cm3. Tnh:
a. Th tch axetilen cn li khng b oxi ho
b. Th tch etilen v th tch etan sinh ra
c. Th tch axetilen v th tch hiro trong hn hp u. Cc th tch o ktc
Cu 18. Cho 40,8g hn hp A gm canxi cacbua v nhm cacbua tc dng vi nc thu c 16,8 lt (ktc) hn hp kh
B. Gi s cancxi cacbua v nhm cacbua u tinh khit, cc phn ng xy ra hon ton
a. Tnh % khi lng ca hn hp A, B
b. Tnh nhit lng to ra khi t` chy hon ton hn hp kh B. Bit rng nhit to ra khi t chy metan v
axetilen tng ng l 880kj/mol v 1320kj/mol
Cu 19. Hn hp X gm hiro v axetilen c t khi so vi hiro bng 5,8
Tnh % th tch mi kh trong X
a.
Dn 1,792 lt X (ktc) qua bt Ni un nng cho n khi phn ng xy ra hon ton thu c hn hp Y (ktc).
b.
Tnh t khi ca Y so vi H2
Cu 20. Hn hp kh A cha C2H2 v H2. T khi ca A so vi H2 l 5,00. Dn 20,16 lt kh A i qua nhanh cht xc tc Ni
nung nng th bin thnh 10,08 lt kh B. Dn hn hp kh B i t t qua bnh ng nc brom (d) cho phn ng xy ra
hon ton th cn li 7,39 lt hn hp kh C. Cc th tch c o ktc
a. Tnh % th tch tng cht trong mi hn hp A, B, C
b. Khi lng bnh nc brom tng bao nhiu gam ?
Cu 21. Khi cho 800g t n tc dng ht vi nc c 224 lt C 2H2 (ktc)
a. Tm hm lng (% khi lng) ca CaC2 trong t n
b. Lng C2H2 trn iu ch c bao nhiu kg PVC. Cho hiu sut ton b qu trnh iu ch l 80%

Ti liu n tp lp 11

THPT CMgar

on Phc

Cu 22. Thc hin phn ng chuyn ho metan thnh axetilen thu c hn hp kh A gm metan, axetilen v hiro.
Ly 5,6g hn hp A cho t t vo dd AgNO3/NH3 (d) thy c 36,0g kt ta. Tnh hiu sut ca qu trnh chuyn ho
metan thnh axetiken
Cu 23. Hn hp kh X (k thng) gm hai ankin ng ng lin tip. Ly 14,7g. Ly 14,7g hn hp X chia lm hai
phn bng nhau
Phn 1: Tc dng ht vi 48g brom
Phn 2: Dn qua dung dch AgNO3/NH3 thu c kt ta, ly kt ta cho vo dd HCl d thu c mt
kt ta khc c khi lng 7,175g
Xc nh ctct ng v gi tn A, B
Cu 24. Hn hp A gm hai ankin hn km nhau 14 vc (u). Cho bit 3,82g hn hp A lm mt mu va dd c ha tan
16g brom (sn phm thu c ch c lin kt n)
a. Xc nh ctpt ca hai hirocacbon
b. Tnh % s mol mi cht trong hn hn hp A
c. Xc nh ctct ca hai ankin, gi tn. Bit hai ankin c cu to mch thng
Cu 25. Khi cho 1 hirocacbon X tc dng vi dung dch brom d sinh ra 1 hp cht Y cha 4 nguyn t brom trong phn
t. Trong phn t Y, % khi lng ca cacbon bng 10%. Tm cng thc phn t ca X v Y
Cu 26. Cho 10 lt hn hp kh CH4 v C2H2 tc dng vi 10 lt H2. Sau phn ng xy ra hon ton thu c 16 lt hn
hp kh ( cc kh o cng k nhit v p sut). Th tch CH 4 v C2H2 trc phn ng l bao nhiu?
Cu 26a. Mt hn hp X nng 4,8g gm mt ankin A v H2 (trong H2 c th tch bng 8,96 lt ktc). Cho hn hp i
qua Ni, tOC, phn ng hon ton ta thu c hn hp kh Y c dY/X = 2,5
a. Tm ctpt v khi lng ca A
b. Tnh s mol H2 phn ng
Cu 27. Hn hp X gm 1 ankin th kh v H2 c t khi so vi CH4 l 0,425. Nung nng hn hp X vi Ni phn
ng xy ra hon ton thu c hn hp kh Y c t khi so vi CH4 l 0,8. Cho Y i qua bnh Br2 d, khi lng bnh Br2
tng bao nhiu gam?
Cu 28. X l mt hirocacbon. Mt th tch hi X vi 4,875 th tch CH4 c cng khi lng (cc th tch kh, hi o
cng iu kin nhit , p sut). Cho 7,8g X tc dng ht vi dd AgNO 3/NH3, thu c 29,2g cht rn khng tan, mu
vng. Xc nh ctct ca X. Bit X c cu to mch h khng phn nhnh
Cu 29. Hn hp A gm hai ankin hn km nhau 1 nhm metylen trong phn t. Cho 6,6g hn hp A hp th vo lng
d dd AgNO3/NH3, thu c 38,7g cht rn khng tan, c mu vng nht. Khng cn hirocacbon bay ra sau phn ng
a. Tm ctpt hai ankin
b. Tnh % khi lng mi cht trong hn hp A
. Nu un nng hn hp A trong bnh kn vi xc tc thch hp, thu c hai hirocacbon tng ng, c cu to
cn xng. Xc nh hai hirocacbon ny
Cu 30. Hn hp A gm hai ankin u mch lin tip (khng c axetilen). Cho 3,22g hn hp tc dng hon ton vi
lng d dd AgNO3/NH3, thu c 10,71g cht rn mu vng
a. Xc nh ctct, ctpt v tn hai ankinh
b. Tnh khi lng mi cht trong 3,22g hn hp
Cu 31. Nn hp X gm 3 kh; CH4, C2H4, C2H2. Nu t chy ht 3,36 lt hn hp X (ktc) ri cho sn phm chy hp
th vo dd nc vi trong d th thu c 24g kt ta. Cn nu ly 13,6g hn hp X cho tc dng vi lng d dd
AgNO3/NH3 th thu c 38,4g kt ta. Xc nh % khi lng mi cht trong X. Cc phn ng xy ra hon ton
Cu 32. (TSH-2001). Hn hp Z gm 0,15 mol CH4,; 0,09 mol C2H2; 0,2 mol H2. Nung nng hn hp Z thu c hn
hp kh Y. Cho Y i qua dd brom d thu c hn hp kh A c KLPT trung bnh l 16. tng khi lng bnh brom l
0,82g. Tnh s mol mi cht trong A
Cu 33. (TGH-2002) . X, Y l hai hirocacbon c ctpt C 5H8. X l monome dng trng hp thnh cao su iso-pren. Y
c mch cacbon phn nhnh v to kt ta vi dd AgNO 3/NH3. Hy cho bit ctct ca X, Y. Vit cc ptp
Cu 34. (TSH-2003) Cht A c ctpt C7H8. Cho A tc dng vi dd AgNO3/NH3 thu c kt ta B. MB > 214 vc (u).
Vit ctct c th c ca A
Cu 35. Cho hn hp A gm 0,3 mol C2H2 v 0,6 mol H2 iqua ng cha Ni, un nng, thu c hn hp kh B. Dn B
qua bnh nc brom d, khi lng bnh brom tng thm m gam, c 8,96 lt hn hp kh C thot ra (ktc) khi bnh brom
(trong C khng c hi nc). dC/He = 3,125. Tm m
Cu 36. Hn hp kh A cha metan, axetilen, v propilen. t chy hon ton 11,0g hn hp A, thu c 12,6g H 2O.
Mc khc, nu ly 11,2 lt A (ktc) dn qua nc brom (d) th khi lng brom tham gia phn ng ti a l 100,0g.

Ti liu n tp lp 11

THPT CMgar

on Phc

Xc nh % theo khi lng v theo th tch ca tng cht trong hn hp A

Cu 37. t chy hon ton 13,9g hn hp A gm etan, axetilen, propilen cn va ng 165,2 lt khng kh. Mc khc khi
trn 40,32 lt hn hp A vi H2 (d) trong bnh c xc tc Ni nung nng, sau khi p xy ra hon ton th tch kh trong
bnh gim 44,8 lt
Tnh % theo khi lng ca hn hp kh ban u. Bit cc kh o ktc, oxi chim 1/5 th tch khng kh
Cu 38. t chy hon ton 1 ankin X th kh thu nc H2 v CO2 c tng khi lng 25,5g. Nu cho sn phm chy
i qua dd Ca(OH)2 d, thu c 45g kt ta. Tm ctpt ca X
Cu 39. Trong bnh kn cha hirocacbon X v H2. Nung nng bnh n khi phn ng hon ton thu c kh Y duy nht.
cng iu kin nhit , p sut trong bnh trc khi nung nng gp 3 ln p sut trong bnh sau khi nung nng. t
chy mt lng Y thu c 8,8g CO2 va2 5,4g H2O. Tm ctpt ca X v tnh % th tch ca hn hp u
Cu 40. Hn hp B gm axetilen, etilen v hirocacbon X. t chy hon ton mt lng hn hp B thu c hn hp
CO2 v hi nc c t l th tch 1 : 1. Nu dn V lt B (ktc) qua dung dch brom d, thy khi lng bnh ng dung
dch tng 0,82g. kh cn li em t chy hon ton, thu c 1,32g CO2 v 0,72g H2O
a. X thuc loi hirocacbon no
b. Tm cng thc phn t, tnh V v % th tch cc kh trong B
Cu 41. t chy hon ton 5,3g hn hp hai ankin hn km nhau 2 nguyn t cacbon thu c 17,6g hn hp
a. Tm ctpt ca 2 ankin
b. Cng lng hn hp trn nu cho tc dng vi lng d dd AgNO3.NH3 th sau 1 thi gian nhn thy lng
kt ta vt qu 25g. Xc nh ctpt ca chng
Cu 42. t chy hon ton hn hp hai ankin ng ng lin tip thu c 220 cm3 CO2 (ktc)
a. Tm ctpt v tnh % theo th tch mi ankin trong hn hp
b. Ly 1,68 lt (ktc) hn hp trn li qua lng d dung dch AgNO 3/NH3 thu c 3,675g kt ta. Tm ctct ca
2 ankin
Cu 43. t chy hon ton mt hn hp gm 20 cm3 mt hirocacbon A v 160 cm3 oxi (d) trong mt kh nhin k. Sau
khi lm lnh hn hp cn li 130 cm3 trong c 80 cm3 b hp th bi KOH v cn li l oxi d
Xc nh ctpt v ctct ca A, bit rng a tc dng vi dd AgNO 3/NH3 to ra kt ta
a.
Tnh lng kt ta thu c khi cho 10,8g A tc dng vi lng d dd AgNO 3/NH3
b.
Cu 44. C 1 hirocacbon A, bit 5,4g A c cng th tch vi 1,6g CH4 25OC v 74 cmHg
Tm ctpt ca A, vit ctct c th c ca A
a.
Xc nh ctct ng ca A, bit A l ng ng ca C2H2 v khng tc dng vi AgNO3/NH3
b.
Cu 45. t chy 3,4g mt hp cht hu c A thu c 11g CO2 v 3,6g H2O
a. Tm cng thc n gin nht ca A
b. Tm ctpt ca A, bit dA/H2 = 34
c. Vit ctct cc ng phn mch h c th c ca A, gi tn
Cu 46. X l hn hp gm 1 ankan v 1 ankin. T khi ca X so vi hiro l 17,5. t chy hon ton mt lng bt k
hn hp hp X u thu c kh cacbonic v hi nc c s mol bng nhau. Bit hn hp X khng tc dng vi dung
dch AgNO3/NH3. Tm ctct ca ankan v ankin
Cu 47. Hn hp kh A gm hiro, mt anken, mt ankin. t chy hon ton 90 ml A thu c 120 ml CO 2. un nng
90 ml A c mt cht xc Ni th sau phn ng ch cn li 40 ml mt ankan duy nht. Cc th tch o ktc
a. Xc nh ctpt v % th tch hn hp A
b. Tnh th tch O2 va t chy hon ton 90 ml A
Cu 48. Hn hp X gm hai hirocacbon mch h, c s cc bon lin tip (khng cung dy ng ng). Chia 13,44 lt
hn hp X (ktc) lm hai nphn bng nhau
Phn 1: t chy hon ton thu c 30,8g CO2
Phn 2: Cho li qua bnh brom d thu c 32g brom phn ng
a. Tm ctpt, vit ctct 2 hirocacbon trn
b. Tnh % khi lng mi hirocacbon trong X
Cu 49.Mt bnh kn dung tch 8,40 lt cha 4,96g O2 v 1,30g hn hp kh A gm 2 hirocacbon. Nhit trong bnh t1 =
0OC v p sut trong bnh p1 = 0,50 atm.
Bt tia la in trong bnh kn th hn hp A chy hon ton. Sau phn ng, nhit trong bnh l t 2 = 136,5OC v p
sut l P2 atm. Dn cc kh trong bnh sau phn ng i qua bnh th nht ng H 2SO4 c, sau qua bnh 2 ng dung
dch NaOH (d) th khi lng bnh th hai tng 4,18g.
a. Tnh P2, bit th tch bnh khng i
b. Xc nh cng thc phn t v % theo th tch ca tng cht trong hn hp A, nu bit thm rng trong hn
hp c mt cht l anken v 1 cht l ankin

Ti liu n tp lp 11

THPT CMgar

on Phc

Cu 50. t chy hon ton mt s mol nh nhau ca 3 hirocacbon K, L, M thu c lng CO 2 nh nhau v t l s
mol H2 v CO2 i vi K; L; M tng ng bng 0,5; 1; 1,5
Cu 51. Mt hn hp X gm 1 ankan, 1 anken v 1 ankin c th tch 1,792 lt (ktc) c chia thnh hai phn bng nhau
Phn : Cho qua dung dch AgNO3/NH3 d thu c 0,735g kt ta v th tih hn hp gim 12,25%
Phn 2: t chy hon ton ri hp th ton b sn phm vo 9,2 lt dung dch Ca(OH) 2 0,0125M
thy c 11g kt ta
Xc nh ctpt ca hirocacbon
Cu 52. t chy hon ton mt lng hirocacbon X thu c 8,8g CO 2 v 1,8g H2O
a. Xc nh ctpt ca X, bit MX khng ln hn 80
b. Nu X lm mt mu brom iu kin thng v to ra sn phm cha 18,09% cacbon v khi lng. Xc
nh ctpt ca X
Cu 353 Cho 1 hirocacbon A, bit rng 5,4g A c cng th tch vi 1,6g CH 4 25OC v 74cmHg.
Tm ctpt ca A, vit ctct c th c
a.
Xc nh ctct ng ca A. Bit A l ng ng ca C2H2 v khng tc dng vi dd AgNO3/NH3
b.
Cu 54. C 1 hn hp X gm hai ankin ng mol. Cho 5 lt hn hp X (54,6OC v 0,8094 atm) qua dung dch brom d
khi lng dung dch brom tng thm 8,1g
a. nu t chy hon ton lng hn hp X trn th thu c bao nhiu lt CO 2 (ktc) v bao nhiu gam H2O ?
b. Nu cho lng hn hp X trn qua dung dch AgNO3/NH3 d th thu c bao nhiu gam kt ta
Cu 55. t chy hon ton 0,1 mol cht hu c A cn 12,8g O2 sn phm thu c 16,8 lt hn hp hi v kh (
136,5OC, 1 atm) gm CO2 v H2O, hn hp ny c t khi so vi metan l 2,1
a. Tm ctpt t ca A. Vit ctct c th c ca A. Bit hn hp hi (CO 2 + H2O) c t khi so vi CH4 l 2,1
b. Xc nh ctct ng v gi tn A, bit rng A to kt ta vng nht khi tc dng vi dd AgNO 3/NH3. Tnh
lng kt ta thu c khi dng 0,1mol A vi hiu sut 90%
Cu 56. t chy hon ton hn hp hai ankin kh iu kin thng thu c 26,4g CO 2
a. Tm ctpt 2 ankin
b. Cho 8g hn hp trn tc dng vi dung dch AgNO3/NH3 sau mt thi gian thy khi lng kt ta vt qu
25g. Tm cu to 2 ankin trn
Cu 57. A l mt hirocacbon. t chy A thu c s mol kh CO2 nhiu gp i s mol H2O.
Cho 0,05 mol A phn ng ht vi dung dch AgNO3/NH3 thu c 7,95g kt ta
a. Xc nh ctpt v ctct ca A
b. Hon thnh s chuyn ho
C Al2O3 X H2O Y 15OO0C Z
A HCl, 1 : 1 B
Cao su c clo (cao su cloropren)
Cu 58. t chy hon ton 6,72 lt (ktc) hn hp hai hirocacbon A, B kh cng dy ng ng, thu c 20,16 lt CO 2
(ktc) v 10,8g H2O
Xc nh dy ng ng ca A v B
a.
Tm ctpt ca A v B
b.
Vit ctct A, B v gi tn
c.
Xc nh ctct ng ca A, B, bit c A v B u tc dng vi dd AgNO 3/NH3
d.
Cu 59. t chy 2 hirocacbon mch h cng dy ng ng thu c khi` lng sn phm l 22,1g. Khi cho ton b
lng sn phm ny vo 400g dd NaOH th thu c dung dch gm hai mui c nng 9,0026%. T l mol hai mui l
1:1
a. Xc nh cng thc chung dy ng ng, bit s lin kt khng qu 2
b. Tm ctpt ca 2 hirocacbon, cho bit t l mol ca chng trong hn hp l 1 : 2 (theo chiu tng khi lng
phn t)
Cu 60. a. Vinyl clorua c th trng hp theo 2 kiu: (u ui) v (u - u). Vit ctct ca polime thu
c theo 2 kiu trn v kiu no l sn phm chnh, ti sao?
c. khi clo ho PVC thu c mt loi t clorin cha 66,77% clo. Hi trung bnh c bao nhiu mc xch PVC tc
dng vi 1 phn t Cl2.