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CHUYN 3 :

HIROCACBON KHNG NO

I. BI TP V ANKEN
Cu 1: Anken X c cng thc cu to: CH3CH2C(CH3)=CHCH3. Tn ca X l
A. isohexan.
B. 3-metylpent-3-en.
C. 3-metylpent-2-en.
D. 2-etylbut-2-en.
Cu 2: S ng phn ca C4H8 l
A. 7.
B. 4.
C. 6.
D. 5.
Cu 3: Hp cht C5H10 mch h c bao nhiu ng phn cu to ?
A. 4.
B. 5.
C. 6.
D. 10.
Cu 4: Hp cht C5H10 c bao nhiu ng phn anken ?
A. 4.
B. 5.
C. 6.
D. 7.
Cu 5: Hp cht C5H10 c bao nhiu ng phn cu to ?
A. 4.
B. 5.
C. 6.
D. 10.
Cu 6: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t
ca X. Cc cht X, Y, Z thuc dy ng ng
A. ankin.
B. ankan.
C. ankaien.
D. anken.
Cu 7: Anken X c c im: Trong phn t c 8 lin kt xch ma. CTPT ca X l
A. C2H4.
B. C4H8.
C. C3H6.
D. C5H10.
Cu 8: Vitamin A cng thc phn t C20H30O, c cha 1 vong 6 cnh v khng c cha lin kt ba. S lin kt
i trong phn t vitamin A l
A. 7.
B. 6.
C. 5.
D. 4.
Cu 9: Licopen, cng thc phn t C40H56 l cht mu o trong qua c chua, chi cha lin kt i v lin kt
n trong phn t. Hiro ha hon ton licopen c hirocacbon C40H82. V y licopen c
A. 1 vong; 12 ni i.
B. 1 vong; 5 ni i.
C. 4 vong; 5 ni i.
D. mch h; 13 ni i.
Cu 10: Cho cc cht sau: 2-metylbut-1-en (1); 3,3-imetylbut-1-en (2); 3-metylpent-1-en (3);
3-metylpent-2-en (4); Nhng cht no l ng phn ca nhau ?
A. (3) v (4).
B. (1), (2) v (3).
C. (1) v (2).
D. (2), (3) v (4).
Cu 11: Hp cht no sau y c ng phn hnh hc ?
A. 2-metylbut-2-en.
B. 2-clo-but-1-en.
C. 2,3- iclobut-2-en.
D. 2,3- imetylpent-2-en.
Cu 12: Nhng hp cht no sau y c ng phn hnh hc (cis-trans) ? CH3CH=CH2 (I); CH3CH=CHCl (II);
CH3CH=C(CH3)2 (III); C2H5C(CH3)=C(CH3)C2H5 (IV); C2H5C(CH3)=CClCH3 (V).
A. (I), (IV), (V).
B. (II), (IV), (V).
C. (III), (IV).
D. (II), III, (IV), (V).
CH2=CHCH=CHCH2CH3;
Cu 13: Cho cc cht sau: CH2=CHCH2CH2CH=CH2;
CH3C(CH3)=CHCH2; CH2=CHCH2CH=CH2;
CH3CH2CH=CHCH2CH3;
CH3C(CH3)=CHCH2CH3;
CH3CH2C(CH3)=C(C2H5)CH(CH3)2; CH3CH=CHCH3. S cht c ng phn hnh hc l:
A. 4.
B. 1.
C. 2.
D. 3.
Cu 14: p dng quy tc Maccopnhicop vo trng hp no sau y ?
A. Phan ng cng ca Br2 vi anken i xng.
C. Phan ng cng ca HX vo anken i xng.
B. Phan ng trng hp ca anken.
D. Phan ng cng ca HX vo anken bt i xng.
Cu 15: Khi cho but-1-en tc dng vi dung dch HBr, theo qui tc Maccopnhicop san phm no sau y l san
phm chnh ?
A. CH3-CH2-CHBr-CH2Br.
C. CH3-CH2-CHBr-CH3.
B. CH2Br-CH2-CH2-CH2Br .
D. CH3-CH2-CH2-CH2Br.
Cu 16: Anken C4H8 c bao nhiu ng phn khi tc dng vi dung dch HCl chi cho mt san phm hu c
duy nht ?
A. 2.
B. 1.
C. 3.
D. 4.
Cu 17: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht
sau khi phan ng vi H2 (d, xc tc Ni, to), cho cng mt san phm l:
A. xiclobutan, cis-but-2-en v but-1-en.
B. but-1-en, 2-metylpropen v cis-but-2-en.
C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis -but-2-en v xiclobutan.
Cu 18: Cho hn hp tt ca cc ng phn mch h ca C4H8 tc dng vi H2O (H+,to) thu c ti a bao
nhiu san phm cng ?
A. 2.
B. 4.
C. 6.
D. 5
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Cu 19: C bao nhiu anken th kh (kt) m khi cho mi anken tc dng vi dung dch HCl chi cho mt
san phm hu c duy nht ?
A. 2.
B. 1.
C. 3.
D. 4.
Cu 20: Hirat ha 2 anken chi to thnh 2 ancol (ru). Hai anken l
A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2).
C. eten v but-2-en (hoc buten-2).
D. eten v but-1-en (hoc buten-1).
Cu 21: Anken thch hp iu ch ancol sau y (CH3 CH2)3C-OH l
A. 3-etylpent-2-en.
B. 3-etylpent-3-en.
C. 3-etylpent-1-en.
D. 3,3- imetylpent-1-en.
Cu 22: Hirat ha hn hp X gm 2 anken thu c chi thu c 2 ancol. X gm
A. CH2=CH2 v CH2=CHCH3.
B. CH2=CH2 v CH3CH=CHCH3.
C. B hoc D.
D. CH3CH=CHCH3 v CH2=CHCH2CH3.
Cu 23: S cp ng phn cu to anken th kh (kt) thoa mn iu kin: Khi hirat ho to thnh hn hp
gm ba ancol l
A. 6.
B. 3.
C. 5.
D. 4.
Cu 24: S cp ng phn anken th kh (kt) thoa mn iu kin: Khi hirat ho to thnh hn hp gm ba
ancol l:
A. 6.
B. 7.
C. 5.
D. 8.
Cu 25: Hp cht X c CTPT C3H6, X tc dng vi dung dch HBr thu c mt san phm hu c duy nht.
Vy X l:
A. propen.
B. propan.
C. ispropen.
D. xicloropan.
Cu 26: Hai cht X, Y c CTPT C3H6 v C4H8 v u tc dng c vi nc brom. X, Y l
A. Hai anken hoc xicloankan vong 3 cnh.
C. Hai anken hoc xicloankan vong 4 cnh.
B. Hai anken hoc hai ankan.
D. Hai anken ng ng ca nhau.
Cu 27: C hai ng nghim, mi ng cha 1 ml dung dch brom trong nc c mu vng nht. Thm vo ng
th nht 1 ml hexan v ng th hai 1 ml hex-1-en. Lc u ca hai ng nghim, sau yn hai ng nghim
trong vi pht. Hin tng quan st c l:
A. C s tch lp cc cht long ca hai ng nghim.
B. Mu vng nht vn khng i ng nghim th nht
C. ng nghim th hai ca hai lp cht long u khng mu.
D. A, B, C u ng.
Cu 28: Trng hp eten, san phm thu c c cu to l:
A. (-CH2=CH2-)n .
B. (-CH2-CH2-)n .
C. (-CH=CH-)n.
D. (-CH3-CH3-)n .
Cu 29: Oxi ho etilen bng dung dch KMnO4 thu c san phm l:
A. MnO2, C2H4(OH)2, KOH.
C. K2CO3, H2O, MnO2.
B. C2H5OH, MnO2, KOH.
D. C2H4(OH)2, K2CO3, MnO2.
Cu 30: X l hn hp gm 2 hirocacbon. t chy X c nCO 2 = nH2O. X c th gm
A. 1xicloankan + anken.
B. 1ankan + 1ankin.
C. 2 anken.
D. A hoc B hoc C.
o
Cu 31: iu ch etilen trong phong th nghim t C2H5OH, (H2SO4 c, 170 C) thng ln cc oxit nh SO2,
CO2. Cht dng lm sch etilen l:
A. dd brom d.
B. dd NaOH d.
C. dd Na2CO3 d.
D. dd KMnO4 long d.
Cu 32: San phm chnh ca s ehirat ha 2-metylbutan-2-ol l cht no ?
A. 3-metylbut-1-en.
B. 2-metylbut-1en. C. 3-metylbut-2-en.
D. 2-metylbut-2-en.
Cu 33: Khi tch nc t ru (ancol) 3-metylbutanol-1 (hay 3-metylbutan-1-ol), san phm chnh
thu c l:
A. 2-metylbuten-3 (hay 2-metylbut-3-en).
B. 3-metylbuten-2 (hay 3-metylbut-2-en).
C. 3-metylbuten-1 (hay 3-metylbut-1-en).
D. 2-metylbuten-2 (hay 2-metylbut-2-en).
Cu 34: Hp cht 2-metylbut-2-en l san phm chnh ca phan ng tch t cht no ?
A. 2-brom-2-metylbutan.
B. 2-metylbutan -2- ol.
C. 3-metylbutan-2- ol.
D. Tt ca u ng.
Cu 35: Khi lng etilen thu c khi un nng 230 gam ru etylic vi H2SO4 m c, hiu sut phan ng
t 40% l:
A. 56 gam.
B. 84 gam.
C. 196 gam.
D. 350 gam.
Cu 36: Cho 3,36 lt hn hp etan v etilen (ktc) i chm qua qua dung dch brom d. Sau phan ng khi
lng bnh brom tng thm 2,8 gam. S mol etan v etilen trong hn hp ln lt l:
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A. 0,05 v 0,1.
B. 0,1 v 0,05.
C. 0,12 v 0,03.
D. 0,03 v 0,12.
Cu 37: 2,8 gam anken A lm mt mu va dung dch cha 8 gam Br 2. Hirat ha A chi thu c m t ancol
duy nht. A c tn l:
A. etilen.
B. but - 2-en.
C. hex- 2-en.
D. 2,3-dimetylbut-2-en.
Cu 38: 0,05 mol hirocacbon X lm mt mu va dung dch cha 8 gam brom cho ra san phm c hm
lng brom t 69,56%. Cng thc phn t ca X l:
A. C3H6.
B. C4H8.
C. C5H10.
D. C5H8.
Cu 39: Dn t t 8,4 gam hn hp X gm but-1-en v but-2-en li chm qua bnh ng dung dch Br 2, khi kt
thc phan ng thy c m gam brom phan ng. m c gi tr l:
A. 12 gam.
B. 24 gam.
C. 36 gam.
D. 48 gam.
Cu 40: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d, thy khi
lng bnh tng thm 7,7 gam. Thnh phn phn % v th tch ca hai anken l:
A. 25% v 75%.
B. 33,33% v 66,67%.
C. 40% v 60%.
D. 35% v 65%.
Cu 41: Hn hp X gm 2 anken l ng ng lin tip c th tch 4,48 lt ( ktc). Nu cho hn hp X i qua
bnh ng nc brom d, khi lng bnh tng ln 9,8 gam. % th tch ca mt trong 2 anken l:
A. 50%.
B. 40%.
C. 70%.
D. 80%.
Cu 42: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d, thy khi
lng bnh tng thm 7,7 gam. CTPT ca 2 anken l:
A. C2H4 v C3H6.
B. C3H6 v C4H8.
C. C4H8 v C5H10.
D. C5H10 v C6H12.
Cu 43: Mt hn hp X c th tch 11,2 lt (ktc), X gm 2 anken ng ng k tip nhau. Khi cho X qua nc
Br2 d thy khi lng bnh Br2 tng 15,4 gam. Xc nh CTPT v s mol mi anken trong hn hp X.
A. 0,2 mol C2H4 v 0,3 mol C3H6.
B. 0,2 mol C3H6 v 0,2 mol C4H8.
C. 0,4 mol C2H4 v 0,1 mol C3H6.
D. 0,3 mol C2H4 v 0,2 mol C3H6.
Cu 44: Mt hn hp X gm ankan A v anken B, A c nhiu hn B mt nguyn t cacbon, A v B u th
kh ( ktc). Khi cho 6,72 lt kh X (ktc) i qua nc brom d, khi lng bnh brom tng ln 2,8 gam; th
tch kh con li chi bng 2/3 th tch hn hp X ban u. CTPT ca A, B v khi lng ca hn hp X l:
A. C4H10, C3H6 ; 5,8 gam.
B. C3H8, C2H4 ; 5,8 gam.
C. C4H10, C3H6 ; 12,8 gam.
D. C3H8, C2H4 ; 11,6 gam.
Cu 45: Mt hn hp X gm ankan A v mt anken B c cng s nguyn t C v u th kh ktc. Cho
hn hp X i qua nc Br2 d th th tch kh Y con li bng na th tch X, con khi lng Y bng 15/29 khi
lng X. CTPT A, B v thnh phn % theo th tch ca hn hp X l
A. 40% C2H6 v 60% C2H4.
B. 50% C3H8v 50% C3H6
C. 50% C4H10 v 50% C4H8.
D. 50% C2H6 v 50% C2H4
Cu 46 : Hn hp X gm metan v 1 olefin. Cho 10,8 lt hn hp X qua dung dch brom d thy c 1 cht kh
bay ra, t chy hon ton kh ny thu c 5,544 gam CO 2. Thnh phn % v th tch metan v olefin trong
hn hp X l:
A. 26,13% v 73,87%.
B. 36,5% v 63,5%.
C. 20% v 80%.
D. 73,9% v 26,1%.
Cu 47: Cho 8960 ml (ktc) anken X qua dung dch brom d. Sau phan ng thy khi lng bnh brom tng
22,4 gam. Bit X c ng phn hnh hc. CTCT ca X l:
A. CH2=CHCH2CH3.
B. CH3CH=CHCH3.
C. CH3CH=CHCH2CH3.
D. (CH3)2C=CH2.
Cu 48: a) Cho hirocacbon X phan ng vi brom (trong dung dch) theo ti l mol 1 : 1, thu c cht hu c
Y (cha 74,08% Br v khi lng). Khi X phan ng vi HBr th thu c hai san phm hu c khc nhau. Tn
gi ca X l:
A. but-1-en.
B. but-2-en.
C. Propilen.
D. Xiclopropan.
b) Hirocacbon X c ng HCl theo ti l mol 1:1 to san phm c hm lng clo l 55,04%. X c cng thc
phn t l:
A. C4H8.
B. C2H4.
C. C5H10.
D. C3H6.
Cu 49: Hn hp X gm metan v anken, cho 5,6 lt X qua dung dch brom d thy khi lng bnh brom tng
7,28 gam v c 2,688 lt kh bay ra (ktc). CTPT ca anken l:
A. C4H8.
B. C5H10.
C. C3H6.
D. C2H4
Cu 50: Dn 3,36 lt (ktc) hn hp X gm 2 anken l vo bnh nc brom d, thy khi lng bnh tng thm
7,7 gam. CTPT ca 2 anken l:
A. C2H4 v C4H8.
B. C3H6 v C4H8.
C. C4H8 v C5H10.
D. A hoc B.
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Cu 51: Cho 10 lt hn hp kh (54,6oC; 0,8064 atm) gm 2 olefin li qua bnh dung dch brom d thy khi
lng bnh brom tng 16,8 gam. CTPT ca 2 anken l (Bit s C trong cc anken khng vt qu 5)
A. C2H4 v C5H10.
B. C3H6 v C5H10.
C. C4H8 v C5H10.
D. A hoc B.
Cu 52: Mt hirocacbon X cng hp vi axit HCl theo ti l mol 1:1 to san phm c thnh phn khi lng clo
l 45,223%. Cng thc phn t ca X l:
A. C3H6.
B. C4H8.
C. C2H4.
D. C5H10.
Cu 53: Cho hn hp X gm etilen v H2 c ti khi so vi H2 bng 4,25. Dn X qua bt niken nung nng (hiu
sut phan ng 75%) thu c hn hp Y. Ti khi ca Y so vi H2 (cc th tch o cng iu kin) l:
A. 5,23.
B. 3,25.
C. 5,35.
D. 10,46.
Cu 54: Cho H2 v 1 olefin c th tch bng nhau qua Niken un nng ta c hn hp A. Bit ti khi hi
ca A i vi H2 l 23,2. Hiu sut phan ng hiro ho l 75%. Cng thc phn t olefin l
A. C2H4.
B. C3H6.
C. C 4 H 8 .
D. C5H10.
Cu 55: Hn hp kh X gm H2 v mt anken c kha nng cng HBr cho san phm hu c duy nht. Ti khi
ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phan ng xay ra hon ton, thu c hn hp kh
Y khng lm mt mu nc brom; ti khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l:
A. CH3CH=CHCH3.
B. CH2=CHCH2CH3.
C. CH2=C(CH3)2.
D. CH2=CH2.
Cu 56: Cho hn hp X gm anken v hiro c ti khi so vi heli bng 3,33. Cho X i qua bt niken nung
nng n khi phan ng xay ra hon ton, thu c hn hp Y c ti khi so vi heli l 4. CTPT ca X l:
A. C2H4.
B. C3H6.
C. C4H8.
D. C5H10.
Cu 57: Hn hp kh X gm H2 v C2H4 c ti khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn
hp kh Y c ti khi so vi He l 5. Hiu sut ca phan ng hiro ho l:
A. 20%.
B. 25%.
C. 50%.
D. 40%.
Cu 58: t chy hon ton a gam hn hp eten, propen, but-2-en cn dng va b lt oxi ( ktc) thu c
2,4 mol CO2 v 2,4 mol nc. Gi tr ca b l:
A. 92,4 lt.
B. 94,2 lt.
C. 80,64 lt.
D. 24,9 lt.
Cu 59: t chy hon ton V lt (ktc) hn hp X gm CH 4, C2H4 thu c 0,15 mol CO 2 v 0,2 mol H2O.
Gi tr ca V l:
A. 2,24.
B. 3,36.
C. 4,48.
D. 1,68.
Cu 60: t chy hon ton 0,1 mol hm hp gm CH4, C4H10 v C2H4 thu c 0,14 mol CO2 v 0,23mol
H2O. S mol ca ankan v anken trong hn hp ln lt l:
A. 0,09 v 0,01.
B. 0,01 v 0,09.
C. 0,08 v 0,02.
D. 0,02 v 0,08.
Cu 61: Mt hn hp kh gm 1 ankan v 1 anken c cng s nguyn t C trong phn t v c cng s mol.
Ly m gam hn hp ny th lm mt mu va 80 gam dung dch 20% Br2 trong dung mi CCl4. t chy
hon ton m gam hn hp thu c 0,6 mol CO2. Ankan v anken c cng thc phn t l:
A. C2H6 v C2H4.
B. C4H10 v C4H8.
C. C3H8 v C3H6.
D. C5H12 v C5H10.
Cu 62: t chy hon ton 10ml hirocacbon X cn va 60 ml kh oxi, sau phan ng thu c 40 ml kh
cacbonic. Bit X lm mt mu dung dch brom v c mch cacbon phn nhnh. CTCT ca X
A. CH2=CHCH2CH3.
B. CH2=C(CH3)2.
C. CH2=C(CH2)2CH3.
D. (CH3)2C=CHCH3.
Cu 63: Cho 0,2 mol hn hp X gm etan, propan v propen qua dung dch brom d, thy khi lng bnh
brom tng 4,2 gam. Lng kh con li em t chy hon ton thu c 6,48 gam nc. Vy % th tch etan,
propan v propen ln lt l:
A. 30%, 20%, 50%.
B. 20%, 50%, 30%.
C. 50%, 20%, 30%.
D. 20%, 30%, 50%.
Cu 64: Mt hn hp X gm 2 hirocacbon A, B c cng s nguyn t cacbon. A, B chi c th l ankan hay
anken. t chy 4,48 lt (kc) hn hp X thu c 26,4 gam CO 2 v 12,6 gam H2O. Xc nh CTPT v s mol
ca A, B trong hn hp X.
A. 0,1 mol C3H8 v 0,1 mol C3H6.
B. 0,2 mol C2H6 v 0,2 mol C2H4.
C. 0,08 mol C3H8 v 0,12 mol C3H6.
D. 0,1 mol C2H6 v 0,2 mol C2H4.
Cu 65: Mt hn hp X gm 1 anken A v 1 ankin B, A v B c cng s nguyn t cacbon. X c khi lng l
12,4 gam, c th tch l 6,72 lt. Cc th tch kh o ktc. CTPT v s mol A, B trong hn hp X l:
A. 0,2 mol C2H4 v 0,1 mol C2H2.
B. 0,1 mol C3H6 v 0,1 mol C3H4.
C. 0,2 mol C3H6 v 0,1 mol C3H4.
D. 0,1 mol C2H4 v 0,2 mol C2H2.
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Cu 66: Mt hn hp A gm 2 hirocacbon X, Y lin tip nhau trong cng dy ng ng. t chy 11,2 lt
hn hp X thu c 57,2 gam CO2 v 23,4 gam CO2. CTPT X, Y v khi lng ca X, Y l:
A. 12,6 gam C3H6 v 11,2 gam C4H8.
B. 8,6 gam C3H6v 11,2 gam C4H8.
C. 5,6 gam C2H4 v 12,6 gam C3H6.
D. 2,8 gam C2H4 v 16,8 gam C3H6.
Cu 67: t chy hon ton 0,05 mol mt anken A thu c 4,48 lt CO 2 (ktc). Cho A tc dng vi dung dch
HBr chi cho mt san phm duy nht. CTCT ca A l:
A. CH2=CH2.
B. (CH3)2C=C(CH3)2.
C. CH2=C(CH3)2.
D. CH3CH=CHCH3.
Cu 68: Hn hp X gm propen l ng ng theo ti l th tch 1:1. t 1 th tch hn hp X cn 3,75 th tch
oxi (cng k). Vy B l:
A. eten.
B. propan.
C. buten.
D. penten.
Cu 69: em t chy hon ton 0,1 mol hn hp X gm 2 anken l ng ng k tip nhau thu c CO2 v
nc c khi lng hn km nhau 6,76 gam. CTPT ca 2 anken l:
A. C2H4 v C3H6. B. C3H6 v C4H8.
C. C4H8 v C5H10.
D. C5H10 v C6H12.
Cu 70: X, Y, Z l 3 hirocacbon k tip trong dy ng ng, trong M Z = 2MX. t chy hon ton 0,1 mol
Y ri hp th ton b san phm chy vo 2 lt dung dch Ba(OH)2 0,1M c m t lng kt ta l:
A. 19,7 gam.
B. 39,4 gam.
C. 59,1 gam.
D. 9,85 gam.
Cu 71: Chia hn hp gm C3H6, C2H4, C2H2 thnh hai phn u nhau.
Phn 1: t chy hon ton thu c 2,24 lt CO2 (ktc).
Phn 2: Hiro ho ri t chy ht th th tch CO2 thu c (ktc) l bao nhiu ?
A. 1,12 lt.
B. 2,24 lt.
C. 4,48 lt.
D. 3,36 lt.
Cu 72: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu
c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). Ti khi ca X so vi kh H2 l:
A. 12,9.
B. 25,8.
C. 22,2.
D. 11,1
Cu 73: t chy hon ton 0,1 mol anken X thu c CO 2 v hi nc. Hp th hon ton san phm bng
100 gam dung dch NaOH 21,62% thu c dung dch mi trong nng ca NaOH chi con 5%. Cng thc
phn t ng ca X l:
A. C2H4.
B. C3H6.
C. C4H8.
D. C5H10.
Cu 74: X l hn hp gm hirocacbon A v O 2 (ti l mol tng ng 1:10). t chy hon ton X c hn
hp Y. Dn Y qua bnh H2SO4 c d c hn Z c ti khi so vi hiro l 19. A c cng thc phn t l:
A. C2H6.
B. C4H8.
C C4H6.
D. C3H6.
Cu 75: m gam hn hp gm C3H6, C2H4 v C2H2 chy hon ton thu c 4,48 lt kh CO 2 (ktc). Nu hiro
ho hon ton m gam hn hp trn ri t chy ht hn hp thu c V lt CO2 (ktc). Gi tr ca V l:
A. 3,36.
B. 2,24.
C. 4,48.
D. 1,12.
Cu 76: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phan
ng xay ra hon ton, c 4 gam brom phan ng v con li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th
sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc)
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6.
Cu 77: Hn hp X gm C3H8 v C3H6 c ti khi so vi hiro l 21,8. t chy ht 5,6 lt X (ktc) th thu c
bao nhiu gam CO2 v bao nhiu gam H2O ?
A. 33 gam v 17,1 gam.
B. 22 gam v 9,9 gam.
C. 13,2 gam v 7,2 gam.
D. 33 gam v 21,6 gam.
Cu 78: Hin nay PVC c iu ch theo s sau:
C2H4 CH2ClCH2Cl C2H3Cl PVC.
Nu hiu sut ton b qu trnh t 80% th lng C2H4 cn dng san xut 5000 kg PVC l:
A. 280 kg.
B. 1792 kg.
C. 2800 kg.
D. 179,2 kg.
Cu 79: Thi 0,25 mol kh etilen qua 125 ml dung dch KMnO4 1M trong mi trng trung tnh (hiu sut
100%) khi lng etylen glicol thu c bng
A. 11,625 gam.
B. 23,25 gam.
C. 15,5 gam.
D. 31 gam.
Cu 80: kh hon ton 200 ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh C 2H4 (
ktc). Gi tr ti thiu ca V l:
A. 2,240.
B. 2,688.
C. 4,480.
D. 1,344.
Cu 81: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i
khi lng phn t X. t chy 0,1 mol cht Z, san phm kh hp th hon ton vo dung dch Ca(OH) 2 (d),
thu c s gam kt ta l:
A. 20.
B. 40.
C. 30.
D. 10.
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Cu 82: Hn hp X c ti khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol
X, tng khi lng ca CO2 v H2O thu c l:
A. 18,60 gam.
B. 18,96 gam.
C. 20,40 gam.
D. 16,80 gam.
Cu 83: X l hn hp C4H8 v O2 (ti l mol tng ng 1:10). t chy hon ton X c hn hp Y. Dn Y
qua bnh H2SO4 c d c hn Z. Ti khi ca Z so vi hiro l
A.18.
B. 19.
C. 20.
D. 21.
Cu 84: Hn hp X gm 2 anken kh phan ng va vi dung dch cha 48 gam brom. Mt khc t chy
hon ton hn hp X dng ht 24,64 lt O2 (ktc). Cng thc phn t ca 2 anken l:
A. C2H4 v C3H6.
B. C2H4 v C4H8.
C. C3H6 v C4H8.
D. A v B u ng.
Cu 85: t chy mt s mol nh nhau ca 3 hirocacbon K, L, M ta thu c lng CO2 nh nhau v ti l s
mol nc v CO2 i vi s mol ca K, L, M tng ng l 0,5 ; 1 ; 1,5. CTPT ca K, L, M (vit theo th t
tng ng) l:
A. C2H4, C2H6, C3H4.
B. C3H8, C3H4, C2H4.
C. C3H4, C3H6, C3H8.
D. C2H2, C2H4, C2H6.
II. BI TP V ANKAIEN -TECPEN - ANKIN
Cu 1: S ng phn thuc loi ankaien ng vi cng thc phn t C5H8 l
A. 4.
B. 5.
C. 6.
D. 7.
Cu 2: C5H8 c bao nhiu ng phn ankaien lin hp ?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 3: Trong cc hirocacbon sau: propen, but-1-en, but-2-en, penta-1,4- ien, penta-1,3- ien hirocacbon
cho c hin tng ng phn cis - trans ?
A. propen, but-1-en.
B. penta-1,4-dien, but-1-en.
C. propen, but-2-en.
D. but-2-en, penta-1,3- ien.
Cu 4: Cng thc phn t ca buta-1,3-ien (ivinyl) v isopren (2-metylbuta-1,3-ien) ln lt l
A. C4H6 v C5H10.
B. C4H4 v C5H8.
C. C4H6 v C5H8.
D. C4H8 v C5H10.
Cu 5: Hp cht no trong s cc cht sau c 9 lin kt xch ma v 2 lin kt ?
A. Buta-1,3-ien.
B. Penta-1,3- ien.
C. Stiren.
D. Vinyl axetilen.
Cu 6: Hp cht no trong s cc cht sau c 7 lin kt xch ma v 3 lin kt ?
A. Buta-1,3-ien.
B. Tuloen.
C. Stiren.
D. Vinyl axetilen.
o
Cu 7: Cho phan ng gia buta-1,3-ien v HBr -80 C (ti l mol 1:1), san phm chnh ca phan ng l
A. CH3CHBrCH=CH2.
B. CH3CH=CHCH2Br.
C. CH2BrCH2CH=CH2.
D. CH3CH=CBrCH3.
Cu 8: Cho phan ng gia buta-1,3-ien v HBr 40oC (ti l mol 1:1), san phm chnh ca phan ng l
A. CH3CHBrCH=CH2.
B. CH3CH=CHCH2Br.
C. CH2BrCH2CH=CH2.
D. CH3CH=CBrCH3.
Cu 9: 1 mol buta-1,3-ien c th phan ng ti a vi bao nhiu mol brom ?
A. 1 mol.
B. 1,5 mol.
C. 2 mol.
D. 0,5 mol.
Cu 10: Isopren tham gia phan ng vi dung dch Br2 theo ti l mol 1:1 to ra ti a bao nhiu san phm ?
A. 4.
B. 1.
C. 3.
D. 2.
Cu 11: Isopren tham gia phan ng vi dung dch HBr theo ti l mol 1:1 to ra ti a bao nhiu san phm
cng ?
A. 8.
B. 5.
C. 7.
D. 6.
Cu 12: Cht no sau y khng phai l san phm cng gia dung dch brom v isopren (theo ti l mol 1:1) ?
A. CH2BrC(CH3)BrCH=CH2.
B. CH2BrC(CH3)=CHCH2Br.
C. CH2BrCH=CHCH2CH2Br.
D. CH2=C(CH3)CHBrCH2Br.

Cu 13: Ankaien A + brom (dd)

CH3C(CH3)BrCH=CHCH2Br. Vy A l
A. 2-metylpenta-1,3-ien.
B. 2-metylpenta-2,4-ien.
C. 4-metylpenta-1,3-ien.
D. 2-metylbuta-1,3-ien.
Cu 14: Ankaien B + Cl2 CH2ClC(CH3)=CH-CH2Cl-CH3. Vy A l
A. 2-metylpenta-1,3-ien.
B. 4-metylpenta-2,4-ien.
C. 2-metylpenta-1,4-ien.
D. 4-metylpenta-2,3-ien.

Cu 15: Cho 1 Ankaien A + brom(dd)

1,4-ibrom-2-metylbut-2-en. Vy A l
A. 2-metylbuta-1,3-ien.
C. 3-metylbuta-1,3-ien.
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B. 2-metylpenta-1,3-ien.
D. 3-metylpenta-1,3-ien.
Cu 16: Trng hp ivinyl to ra cao su Buna c cu to l ?
A. (-C2H-CH-CH-CH2-)n.
B. (-CH2-CH=CH-CH2-)n.
C. (-CH2-CH-CH=CH2-)n.
D. (-CH2-CH2-CH2-CH2-)n.
Cu 17: ng trng hp ivinyl v stiren thu c cao su buna-S c cng thc cu to l
A. (-CH2-CH=CH-CH2-CH(C6H5)-CH2-)n.
B. (-C2H-CH-CH-CH2-CH(C6H5)-CH2-)n.
C. (-CH2-CH-CH=CH2- CH(C6H5)-CH2-)n.
D. (-CH2-CH2-CH2-CH2- CH(C6H5)-CH2-)n .
Cu 18: ng trng hp ivinyl v acrylonitrin (vinyl xianua) thu c cao su buna-N c cng thc cu to l
A. (-C2H-CH-CH-CH2-CH(CN)-CH2-)n.
B. (-CH2-CH2-CH2-CH2- CH(CN)-CH2-)n.
C. (-CH2-CH-CH=CH2- CH(CN)-CH2-)n.
D. (-CH2-CH=CH-CH2-CH(CN)-CH2-)n .
Cu 19: Trng hp isopren to ra cao su isopren c cu to l
A. (-C2H-C(CH3)-CH-CH2-)n .
C. (-CH2-C(CH3)-CH=CH2-)n .
B. (-CH2-C(CH3)=CH-CH2-)n.
D. (-CH2-CH(CH3)-CH2-CH2-)n .
Cu 20: Tn gi ca nhm hirocacbon khng no c cng thc chung l (C5H8)n (n 2) l
A. ankaien.
B. cao su.
C. anlen.
D. tecpen.
Cu 21: Caroten (licopen) l sc t mu o ca c rt v c chua chn, cng thc phn t ca caroten l
A. C15H25.
B. C40H56.
C. C10H16.
D. C30H50.
Cu 22: Oximen c trong tinh du l hng qu, limonen c trong tinh du chanh. Chng c cng cng thc
phn t l
A. C15H25.
B. C40H56.
C. C10H16.
D. C30H50.
Cu 23: C4H6 c bao nhiu ng phn mch h ?
A. 5.
B. 2.
C. 3.
D. 4.
Cu 24: C bao nhiu ankin ng vi cng thc phn t C5H8 ?
A. 1.
B. 2.
C. 3.
D. 4
Cu 25: Ankin C4H6 c bao nhiu ng phn cho phan ng th kim loi (phan ng vi dung dch cha
AgNO3/NH3)
A. 4.
B. 2.
C. 1.
D. 3.
Cu 26: C bao nhiu ng phn ankin C5H8 tc dng c vi dung dch AgNO3/NH3 to kt ta
A. 3.
B. 2.
C. 4.
D. 1.
Cu 27: Ankin C6H10 c bao nhiu ng phn phan ng vi dung dch AgNO3/NH3 ?
A. 3.
B. 4.
C. 5.
D. 6.
Cu 28: Trong phn t ankin X, hiro chim 11,111% khi lng. C bao nhiu ankin ph hp
A. 1.
B. 2.
C. 3.
D. 4
Cu 29: Cho ankin X c cng thc cu to sau :
CH3C C CH CH3
Tn ca X l
CH3
A. 4-metylpent-2-in. B. 2-metylpent-3-in. C. 4-metylpent-3-in. D. 2-metylpent-4-in.

Cu 30: Cho phan ng : C2H2 + H2O

A . A l cht no di y
A. CH2=CHOH.
B. CH3CHO.
C. CH3COOH.
D. C2H5OH.
Cu 31: Cho s phan ng sau: CH3-CCH + AgNO3/ NH3 X + NH4NO3 X c cng thc cu to l?
A. CH3-CAgCAg.
B. CH3-CCAg.
C. AgCH2-CCAg.
D. A, B, C u c th ng.
Cu 32: Trong s cc hirocacbon mch h sau: C4H10, C4H6, C4H8, C3H4, nhng hirocacbon no c th to
kt ta vi dung dch AgNO3/NH3 ?
A. C4H10 ,C4H8.
B. C4H6, C3H4. C. Chi c C4H6.
D. Chi c C3H4.
Cu 33: Hn hp A gm hiro v cc hirocacbon no, cha no. Cho A vo bnh c niken xc tc, un nng
bnh mt thi gian ta thu c hn hp B. Pht biu no sau y sai ?
A. t chy hon ton hn hp A cho s mol CO2 v s mol nc lun bng s mol CO2 v s mol nc
khi t chy hon ton hn hp B.
B. S mol oxi tiu tn t hon ton hn hp A lun bng s mol oxi tiu tn khi t hon ton hn
hp B.
C. S mol A - S mol B = S mol H2 tham gia phan ng.
D. Khi lng phn t trung bnh ca hn hp A bng khi lng phn t trung bnh ca hn hp B.
Cu 34: Cht no trong 4 cht di y c th tham gia ca 4 phan ng: Phan ng chy trong oxi, phan ng
cng brom, phan ng cng hiro (xc tc Ni, to), phan ng th vi dd AgNO3 /NH3
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A. etan.
B. etilen.
C. axetilen.
D. xiclopropan.
Cu 35: Cu no sau y sai ?
A. Ankin c s ng phn t hn anken tng ng.
B. Ankin tng t anken u c ng phn hnh hc.
C. Hai ankin u dy khng c ng phn.
D. Butin c 2 ng phn v tr nhm chc.
Cu 36: Cho cc phan ng sau: (1) CH4 + Cl2
(2) C2H4 + H2
(3) 2 CHCH
Cl2

(4) 3 CHCH
(5) C2H2 + Ag2O (6) Propin + H2O
S phan ng l phan ng oxi ho kh l:
A. 2.
B. 3.
C. 4.
D. 5.
Cu 37: Cho dy chuyn ho sau: CH4 A B C Cao su buna. Cng thc phn t ca B l
A. C4H6.
B. C2H5OH.
C. C4H4.
D. C4H10.
Cu 38: C chui phan ng sau:
KOH
N + H2 B D HCl E (spc) D
Xc nh N, B, D, E bit rng D l mt hidrocacbon mch h, D chi c 1 ng phn.
A. N : C2H2 ; B : Pd ; D : C2H4 ; E : CH3CH2Cl.
B. N : C4H6 ; B : Pd ; D : C4H8 ; E : CH2ClCH2CH2CH3.
C. N : C3H4 ; B : Pd ; D : C3H6 ; E : CH3CHClCH3.
D. N : C3H4 ; B : Pd ; D : C3H6 ; E : CHCH2CH2Cl.
Cu 39: Cht no sau y khng iu ch trc tip c axetilen ?
A. Ag2C2.
B. CH4.
C. Al4C3.
D. CaC2.
Cu 40: lm sch etilen c ln axetilen ta cho hn hp i qua dd no sau y ?
A. dd brom d.
B. dd KMnO4 d.
C. dd AgNO3 /NH3 d.
D. cc cch trn u ng.
Cu 41: nhn bit cc bnh ring bit ng cc kh khng mu sau y: SO2, C2H2, NH3 ta c th dng ho
cht no sau y ?
A. Dung dch AgNO3/NH3.
B. Dung dch Ca(OH)2
C. Qu tm m.
D. Dung dch NaOH
Cu 42: X l mt hirocacbon kh ( ktc), mch h. Hiro ho hon ton X thu c hirocacbon no Y c
khi lng phn t gp 1,074 ln khi lng phn t X. Cng thc phn t X l
A. C2H2.
B. C3H4.
C. C4H6.
D. C3H6.
Cu 43: Cht hu c X c cng thc phn t C6H6 mch thng. Bit 1 mol X tc dng vi AgNO3 d trong
NH3 to ra 292 gam kt ta. CTCT ca X c th l
A. CH CCCCH2CH3.
C. CHCCH2CH=C=CH2.
B. CHCCH2CCCH3.
D. CHCCH2CH2CCH.
Cu 44: Mt hirocacbon A mch thng c CTPT C6H6. Khi cho A tc dng vi dung dch AgNO3/NH3 d thu
c hp cht hu c B c MB - MA=214 vC. Xc nh CTCT ca A ?
A. CHCCH2CH2CCH.
B. CH3C CCH2CCH.
C. CHCCH(CH3)CCH.
D. CH3CH2CCCCH.
Cu 45: A l hirocacbon mch h, th kh (kt), bit A 1 mol A tc dng c ti a 2 mol Br 2 trong dung
dch to ra hp cht B (trong B brom chim 88,88% v khi lng. V y A c cng thc phn t l
A. C5H8.
B. C2H2.
C. C4H6.
D. C3H4.
Cu 46: 4 gam mt ankin X c th lm mt mu ti a 100 ml dung dch Br2 2M. CTPT X l
A. C5H8 .
B. C2H2.
C. C3H4.
D. C4H6.
Cu 47: X l mt hirocacbon khng no mch h, 1 mol X c th lm mt mu ti a 2 mol brom trong nc.
X c % khi lng H trong phn t l 10%. CTPT X l
A. C2H2.
B. C3H4.
C. C2H4.
D. C4H6.
Cu 48: X l hn hp gm 2 hirocacbon mch h (thuc dy ng ng ankin, anken, ankan). Cho 0,3 mol X
lm mt mu va 0,5 mol brom. Pht biu no di y ng
A. X c th gm 2 ankan.
B. X c th gm2 anken.
C. X c th gm1 ankan v 1 anken.
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Cu 49: Hn hp X gm 1 ankin th kh v hiro c ti khi hi so vi CH 4 l 0,425. Nung nng hn hp X

vi xc tc Ni phan ng hon ton thu c hn hp kh Y c ti khi hi so vi CH 4 l 0,8. Cho Y i qua
bnh ng dung dch brom d, khi lng bnh tng ln bao nhiu gam ?
A. 8.
B. 16.
C. 0.
D. Khng tnh c.
Cu 50: Hn hp A gm C2H2 v H2 c dA/H2 = 5,8. Dn A (ktc) qua bt Ni nung nng cho n khi cc phan
ng xay ra hon ton ta c hn hp B. Phn trm th tch mi kh trong hn hp A v dB/H2 l
A. 40% H2; 60% C2H2; 29.
B. 40% H2; 60% C2H2 ; 14,5.
C. 60% H2; 40% C2H2 ; 29.
D. 60% H2; 40% C2H2 ; 14,5.
Cu 51: Mt hn hp gm etilen v axetilen c th tch 6,72 lt (ktc). Cho hn hp qua dung dch brom d
phan ng xay ra hon ton, lng brom phan ng l 64 gam. Phn % v th tch etilen v axetilen ln lt l
A. 66% v 34%.
B. 65,66% v 34,34%.
C. 66,67% v 33,33%.
D. Kt qua khc.
Cu 52: Cho 10 lt hn hp kh CH4 v C2H2 tc dng vi 10 lt H2 (Ni, to). Sau khi phan ng xay ra hon ton
thu c 16 lt hn hp kh (cc kh u o cng iu kin nhit p sut). Th tch ca CH 4 v C2H2 trc
phan ng l
A. 2 lt v 8 lt.
B. 3 lt v 7 lt.
C. 8 lt v 2 lt.
D. 2,5 lt v
7,5 lt.
Cu 53: Cho 28,2 gam hn hp X gm 3 ankin ng ng k tip qua mt lng d H 2 (to, Ni) phan ng
xay ra hon ton. Sau phan ng th tch th tch kh H2 giam 26,88 lt (ktc). CTPT ca 3 ankin l
A. C2H2, C3H4, C4H6.
B. C3H4, C4H6, C5H8.
C. C4H6, C5H8, C6H10.
D. Ca A, B u ng.
Cu 54: Hn hp X gm propin v mt ankin A c ti l mol 1:1. Ly 0,3 mol X tc dng vi dung dch
AgNO3/NH3 d thu c 46,2 gam kt ta. A l
A. But-1-in.
B. But-2-in.
C. Axetilen.
D. Pent-1-in.
Cu 55: Trong bnh kn cha hirocacbon X v hiro. Nung nng bnh n khi phan ng hon ton thu c
kh Y duy nht. cng nhit , p sut trong bnh trc khi nung nng gp 3 ln p sut trong bnh sau khi
nung. t chy mt lng Y thu c 8,8 gam CO2 v 5,4 gam nc. Cng thc phn t ca X l
A. C2H2.
B. C2H4.
C. C4H6.
D. C3H4.
Cu 56: t chy hon ton mt ankin X th kh thu c H 2O v CO2 c tng khi lng l 23 gam. Nu
cho san phm chy i qua dung dich Ca(OH)2 d, c 40 gam kt ta. Cng thc phn t ca X l
A. C3H4.
B. C2H2.
C. C4H6.
D. C5H8.
Cu 57: t chy hon ton 5,4 gam mt hirocacbon A ri cho san phm chy i qua bnh 1 ng dd H2SO4
c, d; bnh 2 ng dung dch Ba(OH)2 d thy khi lng bnh 1 tng 5,4 gam; bnh 2 tng 17,6 gam. A l
cht no trong nhng cht sau ? (A khng tc dng vi dd AgNO3/NH3)
A. But-1-in.
B. But-2-in.
C. Buta-1,3-ien.
D. B hoc C.
Cu 58: Hn hp X gm C2H2 v H2 ly cng s mol. Ly mt lng hn hp X cho i qua cht xc tc thch
hp, un nng c hn hp Y gm 4 cht. Dn Y qua bnh ng nc brom thy khi lung bnh tng 10,8
gam v thot ra 4,48 lt kh Z (ktc) c ti khi so vi H 2 l 8. Th tch O 2 (ktc) cn t chy hon ton hn
hp Y l
A. 33,6 lt.
B. 22,4 lt.
C. 16,8 lt.
D. 44,8 lt.
Cu 59: Cho 17,92 lt hn hp X gm 3 hirocacbon kh l ankan, anken v ankin ly theo ti l mol 1:1:2 li
qua bnh ng dd AgNO3/NH3 ly d thu c 96 gam kt ta v hn hp kh Y con li. t chy hon ton
hn hp Y thu c 13,44 lt CO2. Bit th tch o ktc. Khi lng ca X l
A. 19,2 gam.
B. 1,92 gam.
C. 3,84 gam.
D. 38,4 gam.
Cu 60: Mt hn hp gm 2 ankin khi t chy cho ra 13,2 gam CO2 v 3,6 gam H2O. Tnh khi lng brom
c th cng vo hn hp trn
A. 16 gam.
B. 24 gam.
C. 32 gam.
D. 4 gam.
Cu 61: Cho canxi cacbua k thut (chi cha 80% CaC2 nguyn cht) vo nc d, th thu c 3,36 lt kh
(ktc). Khi lng canxi cacbua k thut dng l
A. 9,6 gam.
B. 4,8 gam
C. 4,6 gam.
D. 12 gam
Cu 62: C 20 gam mt mu CaC2 (c ln tp cht tr) tc dng vi nc thu c 7,4 lt kh axetilen (20 oC,
740mmHg). Cho rng phan ng xay ra hon ton. tinh khit ca mu CaC2 l
A. 64%.
B. 96%.
C. 84%.
D. 48%.
9

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Cu 63: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi
lng brom phan ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d
dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l
A. 40%.
B. 20%.
C. 25%.
D. 50%.
Cu 64: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c
khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.
B. 0,1 mol C3H6 v 0,2 mol C3H4.
C. 0,2 mol C2H4 v 0,1 mol C2H2.
D. 0,2 mol C3H6 v 0,1 mol C3H4.
Cu 65: Trong m t bnh kn cha hirocacbon A th kh (kt) v O2 (d). B t tia la i n t chy ht A a
hn hp v iu kin ban u trong % th tch ca CO 2 v hi nc ln lt l 30% v 20%. Cng thc
phn t ca A v % th tch ca hirocacbon A trong hn hp l
A. C3H4 v 10%.
B. C3H4 v 90%.
C. C3H8 v 20%.
D. C4H6 v 30%.
Cu 66: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO 2 v 2 lt hi H2O
(cc th tch kh v hi o trong cng iu kin nhit v p sut). Cng thc phn t ca X l
A. C2H4.
B. CH4.
C. C2H6.
D. C3H8.
Cu 67: Hn hp X c ti khi so vi H 2 l 21 gm propan, propen v propin. Khi t chy hon ton 0,1 mol
X, tng khi lng ca CO2 v H2O thu c l
A. 18,60 gam.
B. 18,96 gam.
C. 20,40 gam.
D. 16,80 gam.
Cu 68: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn
th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut
ca ca qu trnh l 50%)
A. 224,0.
B. 448,0.
C. 286,7.
D. 358,4.
Cu 69: un nng hn hp kh gm 0,06 mol C 2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c
hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th con li 0,448 lt hn hp
kh Z ( ktc) c ti khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l
A. 1,20 gam.
B. 1,04 gam.
C. 1,64 gam.
D. 1,32 gam.
Cu 70: t chy hon ton m gam hirocacbon th kh, mch h, nng hn khng kh thu c 7,04 gam
CO2. Sc m gam hirocacbon ny vo nc brom d n khi phan ng hon ton, thy c 25,6 gam brom phan
ng. Gi tr ca m l
A. 2 gam.
B. 4 gam.
C. 10 gam
D. 2,08 gam
Cu 71: t chy hon ton m gam hirocacbon th kh, mch h thu c 7,04 gam CO 2. Sc m gam
hirocacbon ny vo nc brom d n khi phan ng hon ton, thy c 25,6 gam brom phan ng. Gi tr ca
m l
A. 2 gam.
B. 4 gam.
C. 2,08 gam.
D. A hoc C.
Cu 72: Dn V lt ( ktc) hh X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh
Y. Dn Y vo lng d AgNO3 trong dd NH3 thu c 12 gam kt ta. Kh i ra khoi dung dch phan ng va
vi 16 gam brom v con li kh Z. t chy hon ton kh Z c 2,24 lt kh CO 2 (ktc) v 4,5 gam H2O.
Gi tr ca V bng
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96.
Cu 73: Cho 4,48 lt hn hp X (ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br 2
0,5M. Sau khi p hon ton, s mol Br2 giam i mt na v m bnh tng thm 6,7 gam. CTPT ca 2
hirocacbon l
A. C3H4 v C4H8.
B. C2H2 v C3H8.
C. C2H2 v C4H8.
D. C2H2 v C4H6.
Cu 74: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dd brom (d). Sau khi phan ng hon
ton, c 4 gam brom phan ng v con li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh
CO2 (ktc). CTPT ca hai hirocacbon l
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6.
Cu 75: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO 2 bng s mol
H2O. Thnh phn % v s mol ca X v Y trong hn hp M ln lt l
A. 35% v 65%.
B. 75% v 25%.
C. 20% v 80%.
D. 50% v 50%.
Cu 76: t chy hon ton 20,0 ml hn hp X gm C 3H6, CH4, CO (th tch CO gp hai ln th tch CH 4), thu
c 24,0 ml CO2 (cc kh o cng iu kin to, p). Ti khi ca X so vi kh hiro l
A. 25,8.
B. 12,9.
C. 22,2.
D. 11,1.
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Cu 77: Mt hn hp X gm 1 ankan A v 1 ankin B c cng s nguyn t cacbon. Trn X vi H 2 c

hn hp Y. Khi cho Y qua Pt nung nng th thu c kh Z c ti khi i vi CO 2 bng 1 (phan ng cng H 2
hon ton). Bit rng VX = 6,72 lt v VH = 4,48 lt. CTPT v s mol A, B trong hn hp X l (Cc th tch
kh o kc)
A. 0,1 mol C2H6 v 0,2 mol C2H2.
B. 0,1 mol C3H8 v 0,2 mol C3H4.
C. 0,2 mol C2H6 v 0,1 mol C2H2.
D. 0,2 mol C3H8 v 0,1 mol C3H4.
Cu 78: Mt hn hp X gm C2H2, C3H6, CH4. t chy hon ton 11t hn hp X thu c 12,6 gam H2O.
Nu cho 11,2 lt hn hp X (ktc) qua dung dch brom d thy c 100 gam brom phan ng. Thnh phn % th
tch ca X ln lt l
A. 50%; 25% ; 25%.
B. 25% ; 25; 50%.
C.16% ; 32; 52%.
D. 33,33%; 33,33; 33,33%.
Cu 79: Dn 4,032 lt (ktc) hn hp kh A gm C 2H2, C2H4, CH4 ln lt qua bnh 1 cha dung dc AgNO 3
trong NH3 ri qua bnh 2 cha dung dch Br2 d trong CCl4. bnh 1 c 7,2 gam kt ta. Khi lng bnh 2
tng thm 1,68 gam. Th tch (ktc) hn hp A ln lt l:
A. 0,672 lt; 1,344 lt; 2,016 lt.
B. 0,672 lt; 0,672 lt; 2,688 lt.
C. 2,016; 0,896 lt; 1,12 lt.
D. 1,344 lt; 2,016 lt; 0,672 lt.
Cu 80: X, Y, Z l 3 hirocacbon th kh trong iu kin thng, khi phn hu mi cht X, Y, Z u to ra C
v H2, th tch H2 lun gp 3 ln th tch hirocacbon b phn hu v X, Y, Z khng phai l dng phn. CTPT
ca 3 cht l
A. C2H6 ,C3H6 C4H6.
B. C2H2 ,C3H4 C4H6.
C. CH4 ,C2H4 C3H4.
D. CH4 ,C2H6 C3H8.
Cu 81: Hn hp X gm 0,1 mol C2H2; 0,15 mol C2H4 ; 0,2 mol C2H6 v 0,3 mol H2. un nng X vi bt Ni
xc tc 1 thi gian c hn hp Y. t chy hon ton hn hp Y c s gam CO2 v H2O ln lt l
A. 39,6 v 23,4.
B. 3,96 v 3,35.
C. 39,6 v 46,8.
D. 39,6 v 11,6.
Cu 82: Hn hp ban u gm 1 ankin, 1 anken, 1 ankan v H 2 vi p sut 4 atm. un nng bnh vi Ni xc
tc thc hin phan ng cng sau a bnh v nhit ban u c hn hp Y, p sut hn hp Y l 3
atm. Ti khi hn hp X v Y so vi H2 ln lt l 24 v x. Gi tr ca x l
A. 18.
B. 34.
C. 24.
D. 32.
Cu 83: Hn hp A gm H2, C3H8, C3H4. Cho t t 12 lt A qua bt Ni xc tc. Sau phan ng c 6 lt kh duy
nht (cc kh o cng iu kin). Ti khi hi ca A so vi H2 l
A. 11.
B. 22.
C. 26.
D. 13.
Cu 84: un nng hn hp X gm 0,1 mol C3H4 ; 0,2 mol C2H4 ; 0,35 mol H2 vi bt Ni xc tc c hn hp
Y. Dn ton b Y qua bnh ng dung dch KMnO4 d, thy thot ra 6,72 l hn hp kh Z (ktc) c ti khi so
vi H2 l 12. Bnh ng dung dch KMnO4 tng s gam l:
A. 17,2.
B. 9,6.
C. 7,2.
D. 3,1.
Cu 85: t chy m gam hn hp C2H6, C3H4, C3H8, C4H10 c 35,2 gam CO2 v 21,6 gam H2O. Gi tr ca m
l
A. 14,4.
B. 10,8.
C. 12.
D. 56,8.
Cu 86: t chy 1 hirocacbon A c 22,4 lt kh CO2 (ktc) v 27 gam H2O. Th tch O2 (ktc) (l) tham gia
phan ng l:
A. 24,8.
B. 45,3.
C. 39,2.
D. 51,2.
Cu 87: Mt hn hp X gm 1 ankin v H2 c V = 8,96 lt (kc) v mX = 4,6 gam. Cho hn hp X i qua Ni
nung nng, phan ng hon ton cho ra hn hp kh Y, c ti khi d Y X = 2. S mol H2 phan ng; khi lng;
CTPT ca ankin l
A. 0,16 mol; 3,6 gam; C2H2.
B. 0,2 mol; 4 gam; C3H4.
C. 0,2 mol; 4 gam; C2H2.
D. 0,3 mol; 2 gam; C3H4.
Cu 88: t chy mt hirocacbon M thu c s mol nc bng s mol CO 2 v s mol CO2 nho hn hoc
bng 5 ln s mol M. Xc nh CTPT v CTCT ca M bit rng M cho kt ta vi dung dch AgNO3/NH3.
A. C4H6 v CH3CH2C CH.
B. C4H6 v CH2=C=CHCH3.
C. C3H4 v CH3C CH.
D. C4H6 v CH3C CCH3.
2

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