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S GIO DC V O TO NGH AN
TRNG THPT QUNH LU 1

THI TH K THI THPT QUC GIA LN 1 NM 2016

MN HA HC
Thi gian lm bi: 90 pht

M thi 142
H v tn: .S BD
Cu 1: Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2. Dy xp theo
th t pH tng dn l:
A. (2), (3), (1).
B. (2), (1), (3).
C. (3), (1), (2).
D. (1), (2), (3).
Cu 2: Cc ancol (CH3)2CHOH ; CH3CH2OH ; (CH3)3COH c bc ancol ln lt l
A. 2, 3, 1.
B. 1, 3, 2.
C. 2, 1, 3.
D. 1, 2, 3.
Cu 3: Hy chn cu pht biu sai:
A. Phenol l cht rn kt tinh d b oxi ho trong khng kh thnh mu hng nht
B. Nhm OH v gc phenyl trong phn t phenol c nh hng qua li ln nhau.
C. Khc vi benzen, phenol phn ng d dng vi dung dch Br2 nhit thng to thnh kt ta trng.
D. Phenol c tnh axit yu nhng mnh hn H2CO3
Cu 4: Nhm cc kim loi no sau y u tc dng c vi nc lnh to dung dch kim
A. Ba, Na, K, Ca.
B. Na, K, Mg, Ca.
C. K, Na, Ca, Zn.
D. Be, Mg, Ca, Ba.
Cu 5: Este A iu ch t ancol metylic c t khi so vi oxi l 2,3125. Cng thc ca A l
A. C2H5COOCH3.
B. CH3COOCH3.
C. CH3COOC2H5.
D. C2H5COOC2H5.
Cu 6: Hn hp kh no sau y khng tn ti nhit thng ?
B. Cl2 v O2.
C. H2S v N2.
D. H2 v F2.
A. CO v O2.
Cu 7: Cht no sau y khng to c kt ta vi AgNO3
A. HNO3
B. Fe(NO3)2
C. NaOH
D. HCl
Cu 8: in tr c trng cho kh nng cn tr dng in. in tr cng ln th kh nng dn in ca kim loi cng
gim. Cho 4 kim loi X, Y, Z, T ngu nhin tng ng vi Ag, Al, Fe, Cu. Cho bng gi tr in tr ca cc kim loi
nh sau:
Kim loi
X
Y
Z
T
-8
-8
-7
in tr (m)
2,82.10
1,72.10
1,00.10
1,59.10-8
Y l kim loi
A. Fe.
B. Ag.
C. Cu.
D. Al.
Cu 9: Cho cc dung dch: HCl, NaOH, NH3, KCl. S dung dch phn ng c vi AlCl3 l
A. 3.
B. 4.
C. 1.
D. 2.
Cu 10: Cho 5,76 g mt axit hu c n chc mch h tc dng ht vi CaCO3 thu c 7,28 g mui ca axit hu
c. CTCT thu gn ca axit ny l:
A. C2H5COOH.
B. CH3COOH.
C. C2H3COOH.
D. HCOOH.
Cu 11: Trong nhng dy cht sau y, dy no c cc cht l ng phn ca nhau ?
A. CH3OCH3, CH3CHO.
B. C4H10, C6H6.
D. C2H5OH, CH3OCH3.
C. CH3CH2CH2OH, C2H5OH.
Cu 12: Trong thc t lm sch lp oxit trn b mt kim loi trc khi hn ngi ta thng dung 1 cht rn mu
trng. Cht rn l?
A. NH4Cl
B. Bt vi
C. NaCl
D. Nc
Cu 13: Gluxit l hp cht tp chc trong phn t c nhiu nhm -OH v c nhm :
A. cacboxyl
B. amin
C. anehit
D. cacbonyl
Cu 14: Cp ha cht c th phn ng oxi ha kh vi nhau l
A. Fe2O3 v HI.
B. Br2 v NaCl.
C. CaCO3 v H2SO4.
D. FeS v HCl.
Cu 15: trng thi c bn, s obitan s c cha e ca nguyn t c s hiu 20 l
A. 2.
B. 4.
C. 3.
D. 1.
Cu 16: Nhng mnh no sau y l sai?
A. Khi thay i trt t cc gc -amino axit trong phn t peptit s dn n c cc ng phn peptit.
B. Trong phn t peptit mch h nu c n gc -amino axit th s c (n-1) lin kt peptit.
C. Cc peptit thng th rn,d tan trong nc .
D. Nu phn t peptit c cha n gc -amino axit th s c s ng phn l n!
Cu 17: Mt hidrocacbon X mch thng c CTPT C6H6. Khi cho X tc dng vi dung dch AgNO3/NH3 d thu c
hp cht hu c Y c MY- MX=214 vc. Xc nh CTCT ca X?
A. CH C-CH(CH3 )-C CH
B. CH3 CH2 C C - C CH
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C. CH C- CH2- CH2-C CH
D. CH3 -C C CH2 - C CH
Cu 18: Cho cc cht sau:
1. NH2(CH2)5CONH(CH2)5COOH
2. NH2CH(CH3)CONHCH2COOH
3. NH2CH2CH2CONHCH2COOH
4. NH2(CH)6NHCO(CH2)4COOH.
Hp cht no c lin kt peptit?
C. 2
D. 2,3
A. 1,2,3,4.
B. 1,3,4
Cu 19: C 5 dung dch NH3, HCl, NH4Cl, Na2CO3, CH3COOH c nh ngu nhin l A, B, C, D, E. Ga tr pH v
kh nng dn in ca dung dch theo bng sau:
Dung dch
Ph
Kh nng dn in

A
5,15
Tt

B
10,35
Tt

C
4,95
Km

D
1,25
Tt

E
10,60
Km

Cc dung dch A, B, C, D, E ln lt l?
A. NH4Cl, NH3, CH3COOH, HCl, Na2CO3
B. NH4Cl, Na2CO3, CH3COOH, HCl, NH3
D. Na2CO3, HCl, NH3, NH4Cl, CH3COOH
C. CH3COOH, NH3, NH4Cl, HCl, Na2CO3
Cu 20: Hnh v di y m t th nghim iu ch kh X trong phng th nghim.

X l kh no trong cc kh sau:
A. N2
B. HCl
C. CO2
D. NH3
Cu 21: Ho tan 7,8 gam hn hp bt Al v Mg trong dung dch HCl d. Sau phn ng khi lng dung dch tng
thm 7,0 gam so vi dung dch HCl ban u. Khi lng Al v Mg trong hn hp u l
C. 5,4 gam v 2,4 gam.
D. 2,7 gam v 1,2 gam.
A. 5,8 gam v 3,6 gam.
B. 1,2 gam v 2,4 gam
Cu 22: Dung dch cha cht no sau y (nng khong 1 M) khng lm i mu qu tm?
A. NaOH.
B. HCl
C. KCl.
D. NH3.
Cu 23: nhn bit dung dch H2SO4, HCl, NaOH, K2SO4 phi dng 1 thuc th duy nht no?
B. Ba(HCO3)2
C. Dung dch NH3
D. BaCl2
A. Qy tm
+
2
6
Cu 24: Cation M c cu hnh electron lp ngoi cng l 2s 2p . Nguyn t M l:
A. Ne
B. Na
C. F
D. K
Cu 25: Cho cc phn ng:
H2NCH2COOH + HCl H3N+CH2COOHCl-.
H2NCH2COOH + NaOH H2NCH2COONa + H2O.
Hai phn ng trn chng t axit aminoaxetic
A. c tnh oxi ha v tnh kh.
B. ch c tnh baz.
C. ch c tnh axit.
D. c tnh cht lng tnh.
Cu 26: in phn vi in cc tr dung dch cha 0,3 mol AgNO3 bng cng dng in 2,68 ampe, trong thi
gian t (gi) thu c dung dch X. Cho 22,4 gam bt Fe vo dung dch X thy thot ra kh NO (sn phm kh duy
nht) thu c 34,28 gam cht rn. Cc phn ng xy ra hon ton. Gi tr ca t l
A. 1,40.
B. 1,20.
C. 1,25.
D. 1,00.
Cu 27: Oxi ha m gam ancol etylic mt thi gian thu c hn hp X. Chia X thnh 3 phn bng nhau:
- Phn 1 tc dng va vi dung dch NaHCO3 thot ra 4,48 lt kh.
- Phn 2 tc dng vi Na d thot ra 8,96 lt kh
- Phn 3 tc dng vi dung dch AgNO3/NH3 d to thnh 21,6 gam Ag. Cc phn ng ca hn hp X xy ra hon ton.
Th tch kh o ktc. Gi tr ca m v hiu sut phn ng oxi ha ancol etylic l
C. 82,8 v 50%
D. 96,8 v 42,86%
A. 124,2 v 33,33%
B. 96 v 60%
Cu 28: Ly hn hp X gm Zn v 0,3 mol Cu(NO3)2 nhit phn mt thi gian thu c hn hp rn Y v 10,08 lit
hn hp kh Z gm NO2 v O2. Y tc dng va vi dung dch cha 2,3 mol HCl thu dc dung dch A ch cha
cc mui clorua v 2,24 lt hn hp kh B gm 2 n cht khng mu. Bit cc kh o ktc, d B = 7,5 . Tnh tng
H2

khi lng mui trong dung dch A?

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A. 154,65 gam
B. 152,85 gam
C. 156,10 gam
D. 150,30 gam
Cu 29: Cho 12,96 gam hn hp Al v Mg tc dng va vi dung dch cha 1,8 mol HNO3 to ra sn phm kh X
duy nht. Lm bay hi dung dch sau phn ng thu c m gam mui khan, m l?
D. 96,66
A. 116,64
B. 105,96
C. 102,24
Cu 30: Cho m gam ancol no, mch h X tc dng hon ton vi CuO (d) nung nng, thu c hn hp hi Y (c t
khi hi so vi H2 l 47/3) c cht hu c Z v thy khi lng cht rn gim 9,6 gam. Mt khc t a mol Z, thu
c b mol CO2 v c mol nc; vi b = a+c. Gi tr ca m l:
C. 18,6.
D. 34,8.
A. 17,4.
B. 37,2.
+ NaOH

+ HCl du

X1
X2. Vy X2 l
Cu 31: Cho cc dy chuyn ha. Glyxin
A. ClH3NCH2COOH.
B. H2NCH2COONa.
C. H2NCH2COOH.
D. ClH3NCH2COONa
Cu 32: t chy hon ton 7,12 gam hn hp M gm ba cht hu c X; Y; Z (u c thnh phn C, H,O). Sau phn ng
thu c 6,72 lt kh CO2 v 5,76 gam nc. Mt khc nu cho 3,56 gam hn hp M phn ng vi Na d thu c 0,28 lt
kh hiro, cn nu cho 3,56 gam hn hp M phn ng vi dung dch NaOH th cn va 200 ml dung dch NaOH 0,2 M.
Sau phn ng vi NaOH thu c mt cht hu c v 3,28 gam mt mui. Bit mi cht ch cha mt nhm chc. Gi s
cc phn ng xy ra hon ton, th tch kh o iu kin tiu chun. Cng thc cu to ca X; Y; Z l:
A. HCOOH, C2H5OH, CH3COOC2H5
B. CH3COOH, C2H5OH, CH3COOC2H5.
C. CH3COOH, CH3OH, CH3COOCH3
D. CH3COOH, C2H5OH, CH3COOCH3
Cu 33: Cho 11,2 gam Fe vo 300 ml dung dch cha (HNO3 0,5M v HCl 2M) thu c kh NO duy nht v dung
dch X. Cho dung dch X tc dng vi lng d dung dch KMnO4/H2SO4 long. Bit cc phn ng xy ra hon ton.
Tnh khi lng KMnO4 b kh.
A. 4,71 gam.
B. 23,70 gam.
C. 18,96 gam.
D. 20,14 gam.
Cu 34: Nh t t dung dch Ba(OH)2 n d vo dung dch hn hp Na2SO4 v Al2(SO4)3 ta c th biu din s
ph thuc khi lng kt ta theo s mol Ba(OH)2 nh sau

Da vo th hy xc nh gi tr ca x l
A. 0,40 (mol)
B. 0,30 (mol)
C. 0,20 (mol)
D. 0,25 (mol)
Cu 35: Polime X c to ra do phn ng ng trng hp gia but-1,3-dien v stiren. Bit 6,234 g X phn ng va
ht vi 3,807 g Br2. T l s mt xch but-1,3-dien v stiren trong polime trn l:
A. 2:3
B. 2:1.
C. 1:2.
D. 1:1.
Cu 36: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn
hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm
chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu
to thu gn ca X v Y l
A. C3H7OH v C4H9OH.
B. C2H5OH v C3H7OH.
C. C2H5OH v C4H9OH.
D. C4H9OH v C5H11OH.
Cu 37: Cho H2 v 1 olefin c th tch bng nhau qua Niken un nng ta c hn hp X (o 136,50C, 1atm) . Bit
t khi hi ca X i vi H2 l 23,2. Hiu sut phn ng hiro ho no sau y tha mn:
A. 44,83%.
B. 73,53%.
C. 80%
D. 50,25%.
Cu 38: Mt bnh kn ch cha cc cht sau: axetilen (0,5 mol), vinylacetilen (0,4 mol), hidro (0,65 mol), v mt t
bt Niken. Nung nng bnh mt thi gian thu c hn hp kh X c t khi so vi H2 bng 19,5. Kh X phn ng va
vi 0,7 mol AgNO3 trong NH3 thu c m gam kt ta v 10,08 lt hn hp kh Y (iu kin tiu chun). Kh Y
phn ng ti a vi 0,55 mol brom trong dung dch. Gi tr ca m l:
A. 91,8.
B. 75,9.
C. 76,1.
D. 92,0.
Cu 39: Ly m gam Mg tc dng vi 500ml dung dch AgNO3 0,2M v Fe(NO3)3 2M. Kt thc phn ng thu c
(m+4) gam kim loi. Gi a l tng cc gi tr m tha mn bi ton trn, gi tr ca a l?
B. 25,3
C. 18,5
D. 24,8
A. 7,3
Cu 40: Cht X c cng thc phn t C5H8O4 l este 2 chc, cht Y c CTPT C4H6O2 l este n chc. Cho X v Y ln
lt tc dng vi NaOH d, sau c cn cc dung dch ri ly cht rn thu c tng ng nung vi NaOH khan (c
mt CaO) th trong mi trng hp ch thu c CH4 l cht hu c duy nht. Cng thc cu to ca X, Y l:
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A. CH3OOC-CH2-COOCH3, CH3COOC2H3.
B. CH3COO-CH2-COOCH3, CH3COOC2H3
C. CH3-CH2-OOC- COOCH3, CH3COOC2H3
D. CH3COO-CH2-COOCH3, C2H3COOCH3
Cu 41: Cho cc phng trnh phn ng:
to
(1) MnO2 + HCl c
(2) Hg + S

to
(4) NH4Cl + NaNO2
(3) F2 + H2O

to
(5) K + H2O
(6) H2S + O2 d

(7) SO2 + dung dch Br2

(8) Mg + dung dch HCl
Trong cc phn ng trn, s phn ng to n cht l
A. 6.
B. 4 .
C. 7.
D. 5.
Cu 42: X l dung dch cha a mol AlCl3, Y l dung dch cha b mol NaOH.
- Cho t t dung dch X vo dung dch Y thu c m1 gam kt ta.
- Cho t t dug dch Y v dung dch X thu c m2 gam kt ta.
Mi quan h gia m1 v m2?
B. m1 > m2
A. m1 < m2
C. Ty thuc vo gi tr a, b
D. m1 = m2
Cu 43: Dng t nilon ph bin nht l nilon 6,6 c 5 khi lng cc nguyn t l: 63,68% C; 12,38% N; 9,8%H;
14,4% O. Cng thc thc nghim ca nilon 6,6 l:
A. C6N2H10O
B. C5NH9O
C. C6NH11O2
D. C6NH11O
Cu 44: Mt phn ng thun nghch trng thi cn bng th tc phn ng thun (vt) bng tc phn ng nghch
(vn). Khi thay i cc yu t nng , p sut, nhit th c th xy ra cc trng hp sau:
1. vt tng, vn gim
2. vt v vn u gim nhng vn gim nhiu hn vt
3. vt v vn u tng nhng vn tng nhiu hn vt
4. vn tng, vt khng i
5. vn v vt u khng i
Trong s cc trng hp trn, c bao nhiu trng hp lm cn bng dch chuyn theo chiu thun
A. 2
B. 3
C. 4
D. 1
Cu 45: Hn hp X gm C2H2, C2H6 v C3H6. t chy hon ton 24,8g hn hp X thu c 28,8g nc. Mt khc
0,5 mol hn hp ny tc dng va vi 500g dung dch Brom 20%. Phn trm v th tch ca mi kh trong hn
hp ln lt l:
A. 30; 30; 40.
B. 50; 25; 25.
C. 25; 25; 50.
D. 20; 40; 40.
Cu 46: Ly 16 gam hn hp Mg v M (c cng s mol) tc dng hon ton vi dung dch HNO3 d thu c dung
dch A cha 84 gam mui v 4,48 lt (ktc) hn hp kh X gm NO v NO2 (t l 1:1 v s mol). Nu ly 22,4 gam
kim loi M tc dng hon ton vi 300ml dung dch H2SO4 1M th thu c V lt kh (ktc). Gi tr ca ln nht ca
V l?
A. 8,96
B. 6,72
C. 12,544
D. 17,92
Cu 47: Hn hp X gm vinylaxetilen v hiro c t khi hi so vi H2 l 16. un nng hn hp X mt thi gian
thu c 1,792 lt hn hp kh Y ( ktc). Hn hp kh Y phn ng va vi dung dch cha 25,6 gam Br2 trong
CCl4. Th tch khng kh (cha 20% O2 v 80% N2 v th tch, ktc) cn dng t chy hon ton hn hp Y l:
A. 38,08.
B. 7,616.
C. 7,168.
D. 35,84.
Cu 48: Thu phn hon ton 14,6 gam mt ipeptit X c cu to bi -amino axit c 1 nhm -NH2 v 1 nhmCOOH bng dung dch NaOH thu sn phm trong c 11,1 gam mt mui c cha 20,72% Na v khi lng. Cng
thc cht X l:
A. H2NCH(CH3)CONHCH(CH3)COOH.
B. H2NCH(C2H5)CONHCH2COOH hoc H2NCH2CONHCH2(CH3)COOH.
C. H2NCH2CONHCH2COOH.
D. H2NCH(CH3)CONHCH2COOH hoc H2NCH2CONHCH2(CH3)COOH.
Cu 49: Dung dch A c cha m gam cht tan gm Na2CO3 v NaHCO3. Nh t t n ht 100ml dung dch gm
HCl 0,4M v H2SO4 0,3M vo dung dch A, sau khi phn ng hon ton thu c 0,04 mol CO2 v dung dch B. Nh
tip Ba(OH)2 d vo dung dch B thu c 18,81 gam kt ta. Gi tr m l
A. 9,72.
B. 9,28.
C. 11,40.
D. 13,08.
Cu 50: Cho m gam NaOH vo dung dch cha 0,04 mol H3PO4, sau phn ng hon ton thu c dung dch Y. c
cn dung dch Y thu c 1,22m gam cht rn khan. Gi tr m l
A. 8.
B. 4.
C. 6.
D. 2.
----------- HT ---------Cho bit khi lng nguyn t (theo u) ca cc nguyn t:
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H = 1; Li = 7; Be =9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca =
40; Cr=52; Fe = 56; Cu = 64; Zn = 65; As = 75; Br = 80; Rb = 85,5; Ag = 108; I=127; Ba = 137

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