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TCVN 6002:1995
ISO 6333: 1986
CHT LNG NC - XC NH MANGAN. PHNG PHP TRC QUANG DNG FOMALDOXIM
Water quality - Determination of manganese - Formaldoxime spectrometric method
M u
Khi nc c cha oxi, hu ht mangan tn ti di cc dng khng tan, thng lin kt vi cc vi sinh
vt v to phc, th d vi axit humic. Nu nc khng cha oxi hoc c mi trng axit mnh, tt c
mangan tn ti dng ha tan.
1. Phm vi p dng
Tiu chun ny a ra phng php trc quang dng fomaldoxim xc nh tng lng
mangan (gm mangan ha tan, huyn ph v mangan lin kt vi cc cht hu c) trong nc mt v
nc ung.
Phng php ny dng xc nh mangan trong khong nng t 0,01mg/l n 5mg/l. Nhng
nng mangan ln hn 5mg/l cng c th xc nh c sau khi pha long mu thch hp.
Cc yu t cn tr c nu mc 8.
Ch thch: Phng php ny khng p dng cho cc loi nc b nhim cao nh nc thi cng
nghip.
2. Nguyn tc
Thm dung dch fomaldoxim vo mu th v o qang phc mu da cam bc sng khong
450nm.
Nu mangan tn ti di dng huyn ph hoc lin kt vi cc hp cht hu c, cn phi x l trc
chuyn mangan thnh dng phn ng c vi fomaldoxim.
Phc cht mangan foinaldoxim bn pH gia 9,5 v l0,5 v cng mu t l vi lng mangan c
trong dung dch. Quan h tuyn tnh gia nng hp th t ti nng mangan 5 mg/l. Hp th cc
i khong 450mn (h s hp th mol l 11 x 103 l/mol.cm).
3. Thuc th
Cnh bo - Cc thuc th nu 3.4, 3.5.l v 3.5.3. l nhng cht c hi c bit. Phi lm vic vi
cc cht ny trong t ht rrnh n hoc ht phi hi ca chng v phi bo
v mt, mt v tay cn thn. Phi dng gng tay v knh cc cht ny bm vo da, phi ra ngay v
ra k. Ht phi hi fomaldehyt v fomaldoxim s gy kch thch mnh v
ph n phn trn ca b my h hp.
Trong phn tch, ch dng cc thuc th tinh khit phn tch, nc qua trao i ion hoc nc ct
bng thit b thy tinh m lng vt mangan cng thp cng tt.
3.1. Cht oxi ha
Dng kali pesunfat (K2S2O8) hoc natn pesunfat (Na2S208)
3.2. Natri sunfit khan (Na2SO3)
3.3. Dung dch EDTA 0,24 mol/l, dng mui tetranatri
Ha tan 90g dinatri EDTA dihidrat (Na2EDTA.2H2O) v 19 g natri hidroxit (NaOH) trong nc v pha
long thnh 1000ml.
Cch khc l ha tan l09g tetranatri EDTA tetrahidrat (Na4EDTA.4H2O) hoc tetra natn
(C10H12N2NNa4O8.2H2O) trong nc v pha long n 1000ml.
3.4. Dung dch fomaldoxim
Ha tan 10g hidroxylamoni clorua (NH3OHCL) trong khong 50ml nc. Thm 5ml dung dch metanal
35% (khi lng/khi lng) (HCHO) (fomandehyd) (d-1,08 g/ml) v pha long bng nc n
l00ml.
Gi dung dch trong bnh ni ti v mt. Dung dch bn t nht mt thng.
3.5. Dung dch hidroxylamoni clorua/amoniac
3.5.1. Dung dch hidroxylamoni clorua (NH3oHc/), 6mol/l
V1
V2
Phng th
nghim
S cc kt qu Gi tr trung bnh
(mg/l)
0,050
30
0,049
0,0035
0,100
30
0,12
0,025
0,100
30
0,099
0,0021
0,500
30
0,497
0,0085
1,000
30
1,01
0,04
1,000
30
1,001
0,0091
2,000
30
1,99
0,035
2,000
30
2,055
0,0111
4,000
30
4,02
0,047
4,000
360
4,198
0,1333