ON Resonence” Educating for better tomorrow TARGET : JEE (ADVANCED) 2016 Course : VIJETA & VIAY (ADP & ADR) Date : 17.04.2016 TEST INFORMATION DATE : 20.04.2016 PART TEST - 02 (PT - 02) Syllabus : Gaseous State, Solid State, Surface Chemistry, Thermodynamics & Thermochemistry. DPP No. # 04 (JEE-ADVANCED) Total Marks : 157 Max. Time : 116 min. 1" negative marking) Q.1 to Q.15 (3 marks, 2 min.) [45,30] e('=1" negative marking) Q.16 to@.20 (4 marks, 2 min.) __[20, 10] Single correct Objective ( One or more correct obje Assertion and Reason ('-1' negative marking) Q.21 to Q.23 (3 marks, 3 min.) [09,09] Comprehension (‘-1" negative marking) Q.24 to 0.32 (B marks, 2 min.) (24, 16] Single digit integer type ('-1" negative marking) Q.33 to Q.37 (3 marks, 3 min.) [15,15] Double digit integer type ('-1" negative marking) 2.38 to Q.41 (3 marks, 3 min.) [12,12] Match the Following (no negative marking) Q.42 to Q.45 (8 marks, 6 min.) [32,24] 4. Forthe following V-T plot for a gas undergoing a process from state A to state B, select the correct altemative(s). (A) Pressure constantly increases (B) Pressure first Increases, then decreases (C) Final pressure is less than initial pressure _(D) Pressure first decreases then increases. 2. —_Inwhich of the following cases, the work done in an ideal gas system with constant moles ‘n' be represented by-nRAT? (A) Isochoric reversible heating (8) Isobaric reversible expansion (C) Isothermal reversible expansion. (0) Adiabatic irreversible expansion, 3. _Attemperature above 85 K, decarboxylation of acetic acid becomes a spontaneous process under standard state conditions. What is the standard entropy change (in J/K-mol) of the reaction. CH,COOH(aq) —> CH,(@) + CO,(@) Given aH? [CH.COOH(@q)] — 484 kuimole AH? [CO,(Q)] = —392 kJ/mole AH [CH.@)] -75 ki/mole (A) 100 J/K mole (8) 200 JK mole (C) 300 J/K mole (0) 400 J/K mole e Resonance’ fra Educating for better tomorrow | Freres aSS TON SET THOU EE SEES] CONE UBSIOTR OO PLO40. 1. ‘A monoatomic ideal gas at 1200 K is expanded adiabatically from 1 L to BL, such that its final temperature is 280 K, Which of the following statements is/are true for this process ? (A) This free adiabatic expansion. © Thisis reversible adiabatic expansion (©) Thisisimeversible adiabatic expansion (0) This is an impossible process The enthalpy of formation of CH, is -84 kiimol. For CsHs, it is -105 ku/mol. What is the enthalpy of formation of n-pentane ? (A) Date is insufficient (B)-147 kJ/mol (©)-187 ksimol ()-114 ksimol Inhop (ABAB...) and cop (ABCABC...) structures made up of spheres of equal size, the volume occupied per sphere (including the empty spaces) is (a = radius of sphere) (A) 5.66 a? (8) 1.33.2 (©)2.66.2° (0)7.40.a° What is the maximum number of layers of atoms in close packed planes that will ie within two imaginary . parallel planes having adistance between them of 13 & Rin the copper erystal (FCC) ? Consider the atoms to be within the parallel planes if their centres are on or within the two parallel planes. [R = radius of sphere] As 6 (7 (os The number of atoms in 100 g of an FCC crystal with density d= 10 gem and cell edge of 200 pm is equal to (A) 3 x 10 (B)5« 10% (©)1 «10% ()2« 10" lonic solid B°A- crystallizes in rock salt type of structure. 0.132 gm ionic solid salt BA” is dissolved in water to make one litre solution. The pH of the solution is measured to be 6.0. If the length of face diagonal in the unit cell of B*A~ be 600./3 pm. Calculate the density of ionic solid. (T = 298 K), K,, for BOH is 10°. [Avogadro Number = 6.022 x 10°, HA = strong acid) (A) Sgice (B) 4 g/cc (©)45 goo (0) 8.5 glee s P| Ra Vv The above isotherm was observed for a monoatomic gas at certain temperature. Which of the following is correct ? (A) The gas is behaving ideally (B) The gasis above its critical temperature (C) Inthe horizontal QR, the pressure is more than critical pressure (D) The gas shows negative deviation from ideal gas in PQ and QR. 10 ml of gaseous hydrocarbon is exploded with 100 ml oxygen. The residual mixture on cooling is found to measure 95 ml, of which, 20 ml is absorbed by KOH and remaining by alkaline pyrogallol. itis known that alkaline pyrogallol absorbs O, . Predict the formula of hydrocarbon ACH, CH, (CH, (CAH Resonance’ fiz Educating for better tomorow12. 13. 14, 15. ae 18° If the number of molecules of SO, (atomic weight = 64) effusing through an orifice of unit area of cross- section in unit time at 0°C and 1 atm pressure is n, the number of He molecules (atornic weight = 4) effusing under similar conditions at 273°C and 0.25 atm is 0 0 Oe nya (©2n o> ‘A gas X' undergoes physisorption on charcoal. ifthe magnitude of enthalpy change and entropy change were observed to be 20 kslmol and 75 Jimol-K, then the temperature range at which adsorption takes place spontaneously is: (A) T= 2875 K (© T>287.5K (©) T<287.5K (O)Atany temperature adsorption willbe spontaneous, AL70 K, the adsorption of N, gas at iron surface obeys freundlich adsorption isotherm. The experimental data is x where 7 is the mass of Nin gram, adsorbed per gram of iron at P bar pressure . The mass of N, gas adsorbed by 59 of Fe at 36 bar and 70 K is (A)069 ®29 (©)0.89 () Cannot be found from given data Which of the following statementsis not correct ? (A) Higher is the gold number of a lyophilic sol, lesser is its coagulating power. (®)Aneelectrolyte can coagulate both positive sol and negative sol (C) Impurities present in a colloid makes it more stable. (©) Dialysis isa process to remove impurties of ions and molecules from a colloid Which of the following are correct statements ? (A) vander Waals constant 'a’is a measure of attractive force (B) van der Waals constant ’'is also called co-volume or excluded volume (C)'b’is expressed in L mot (0) 2’ is expressed in atm L? mot? The origin of charge on colloidal solution is (A) Self dissociation (in soaps and detergents) _(B) Electron capture during Bredig's arc method (©) Selective adsorption of ion on theirsurface (0) Itis due to addition of protective colloids Consider the process carried out for an ideal gas. PY, T= Taran | oT. diathermi wall One by one, stoppers 5, S:, Se are removed slowly and the gas expands to V., L with final pressure P, and final temperature T,. Which of the following is/are correct for the above process. TFT, @)P,=P, (O)U,=U; O)w=0,q= Resonance’ fiz Educating for better tomorow19" 20 2 22. 23, Which of the following statements) is/are false ? (A) AS tor ; C1(@) > Clg) is positive (©) AE <0 for combustion of CH.,(a) ina sealed container with rigid adiabatic system (©) AG is always zero for a reversible process in a closed system (0) AG* for an ideal gas reaction is a function of pressure The Vander waal's equation of state for a non-ideal gas can be rearranged to give 10 Pyv_Voa pv RT” Vb va {1 1MOle of gas. The constants a & bare positive numbers. RE When applied to H, at 80K, the equation gives the curve as shown in the figure. 04080 Which one of the following statements is(are) correct Pratm Vong 8 = °° VRT (A) The two terms are never equal v (®) ALBO atm, thetwoterms 1+ G7 py & aVRT are equal (©) Ata pressure greater than 80 atm, the term V(V -b) is greater than (@/VRT+1), a m, m mi 1 (0) At 60 atm, the term V/(V - b) is smaller than Statement-1 : Gases like N,, O, behave as ideal gases at high temperature and low pressure Statement-2 : Molecular interaction diminishes at high temperature and low pressure (A) Statement-t is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-t is True, Statement-2 is False. (O) Statement-1 is False, Statement-2 is True. Statement-1 : Tyndall effect is due to scattering of light & not shown by true solution Statement-2 : Ina true solution there are no particles of sufficiently large diameter to scatter light & hence the beams invisible, (A) Statement-t is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-t is True, Statement-2 is False. (0) Statement-t is False, Statement-2 is True. STATEMENT-1 : In ZnS crystal, Zn ions are placed at 50% of tetrahedral voids (at alternate positions) created by S* ion in c.c.. lattice. STATEMENT-2: Ratio of number of Sion and number of tetrahedral voids is2 1 where as ratio of number of S* ion and number of Zn jon is 1:1 inzinc blende. (A) Statement is True, Statement-2 is True; Statement-2is a correct explanation for Statement-1 (@) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-t is True, Statement-2 is False (©) Statement-+ is False, Statement-2 is True Comprehension #1 ‘The speed of a molecule of a gas changes continuously as a result of collisions with other molecules and with the walls of the container. The speeds of individual molecules therefore change, but itis expected that the distribution of molecular speeds does not change with time. A direct consequence of the distribution of speeds is that the average kinetic energy is constant for a given temperature. [corporate Office : CG Toner, Aa & 62, PIA, Near Cy Mal Jhlanar Road, Kota (a) 224005 Resonsnce® a aaa24. 25. The average KE, is defined as we= 1 (Liv stivds..stowe) = + mugevet..tvg=tmy? KE jy (QIN tga tt pal | = 3 mv? + vs woe 5 mv 4(4 2)_4 NY 7 eee dN, where 5 is the fraction of molecules having speeds between v, and v, + dv and as proposed by Maxwell exp Cmvi/2kT).v2.dv (4dN) “gy | ISplotted for a particular gas at two different temperatures against ‘v' as shown. The The plot of majority of molecules have speeds which cluster around vy. in the middle of the range of v. The area under the curve between any two speeds v, and v, isthe fraction of molecules having speeds between v, and v;, The speed distribution also depends on the mass of the molecule. As the area under the curve is the same (equal to unity) for all gas samples, samples which have the same Vj,-will have identical Maxwellian plots. On tthe basis of the above passage answer the questions that follow. For the following graph drawn for two different samples of gases at two different temperatures T, and T>, ‘which of the following statements is necessarily true (A) IfT,>T,, Mj is necessarily greater than Ms (B) If T, > T:, Mg is necessarily greater than M, Roth Nav) Om > My (D) Nothing can be predicted If two gases ‘A’ and ‘B' and at temperature T,, and T,, respectively have identical Maxwellian plots, then which of the following statements are true ? ™_M @TE=T @)Ma= My On m, (D) Gases and B may be ©, and SO, at 27°C and 327°C respectively. Comprehension # 2 A reaction is spontaneous if free energy change, AG, for the reaction is negative. The question arises, how we can explain the spontaneity of reversible reactions. Let us take the example of dissociation equilibrium of NO, =2NO,(g). The variation of free energy withthe fraction of NO, dissociated under standard conditions, is shown in the figure below 2 mole of NO, ‘1 mole of NO, 5.40 ks Free energy 6" - Fradion ofN,0, dissodated (OG Tovar, AB & 62, PIA Noo Cy Mal, Jalawar Road, Kota (Ra) 324005 Resonance’ fiz Educating for better tomorow28. 27. 28. The standard free energy change for the conversion of 1 mole of N,O, into 2 moles of NO, is (A) 5.40 kd (8) -5.40kJ (©) (6.404084) kJ (D) (5.4042 x 0.84) kd When 1 mole of N,O, changes into the equilibrium mixture, the value of AG is (A) 0.84 kd (B)-0.84 kd (©)5.40-0.84 kd (0) 0.84-5.40 kd When 2 moles of NO, change into equilbrium mixture, the value of AG is (A) (6.40 +0.84)kJ — (B) (5.40-0.84) kJ (C)(-5.40-0.84) kJ (D) -5.40 Kd Comprehension # 3 29. 30. Zeta potential isa scientific term for electrokinetic potential in colloidal dispersions. itis usualy denoted by using greek letter zeta (~) itis the potential difference between dispersion medium and the stationary layer of fluid attached to the dispersed particle. What does a high value of zeta potential indicate (A) High degree of repulsion between colloidal particles and medium (B) High degree of repulsion between colloidal particles. (C) Easy coagulation (0) Electrically unstable colloid. Zeta potential approaches zero (A) in acidic modium (© basic medium (C)atpH=7 (O)atpH of isoelectric point Comprehension # 4 at. 32. 33. Minerals having the formula AB,O, and crystallsing in cubic system with © ion forming fec and A” & B™ ‘occupying octahedral & tetrahedral sites are generally termed as spinels. Spinels are mainly two types : normal and inverse. In normal spinels, A®* occupy one tetrahedral void and B® occupy two octahedral voids per foc unt cell of O-. Butin inverse spinel, A®* occupy 1 octahedral void and B occupy one tetrahedral and one octahedral void per foc unit cell of O%- ion. MgAl,0, ishaving normal spinel structure. Mg2 and AP are isoelectronic then which of the following statements is comrect for MgAl,0, ? (A) Mg* being larger in size fits in octahedral void (8) Al being larger in size fits in octahedral void (C)AI* occupy tetrahedral and octahedral void equally (D) Mg” occupy tetrahdral void irrespective of the larger size than AI. ‘Some spinels have distribution of A2* and B°* ions in tetrahedral and octahedral voids . If the formula is A,B, | ©, then yis = de (A,B, at @x ory 2x The density of gas Ais twice that of a gas B at the same temperature. The molecular weight of gas B is thrice that of A. The ratio of the pressure acting on A and B will be KCI has NaCl type face centred cubic crystal structure and CsF has CsCl type cubic crystal structure. Calculate the ratio of densities of CsF and KCI. Itis given that the molar mass of CsF is twice that of KCI and edge length of KCI unit cell is 2 times that for CsF. Resonance’ fiz Educating for better tomorow36. 36. 37. 38. 39. 40. a. ‘One mole of a monoatomic ideal gas is taken from ato b by expansion along two paths denoted by the solid and dashed line, as shown in the graph below. If w, is work done along solid line path and w, is work done along dotted line path then find wal o e [wel ect or ‘A cubic unit cell contains ‘A’** ions at the comers and 'BY-" ions at the centre of each face. () The difference of coordination number of A and B = p (Assuming no anion-anion or no cation-cation contact) {i Ifall atoms along one of the C, axis are removed, then the formula becomes A.B, id px gir. 1.9 of charcoal adsorbs 100 mL of 0.5 M CH,COOH to form mono layer and there by the molarity of CH,COOH reduces to 0.49 M. Calculate the surface area of the charcoal adsorbed by each molecule of CH,COOH. Surface area of charcoal = 3.01 « 10? m’/gm. Give your answer by multiplying with 10%. ‘The nonstoichiometric oxide of iron called Wustite has empirical formula Fe,©. It has a density of 6.33 g/ ‘em?, a cubic unit cell with cell constant of 400 pm and an FCC arrangement of oxygen atoms. Find the percentage of occupied iron sites (Fe = 56) (N,= 6 x 10%) ‘The compression factor (compressibility factor) for 1 mole of a van der Waals’ gas at 727°C and100 atmosphere pressure is found to be 0.5. Assuming that the volume of gas molecule is negligible, calculate the van der Waal's constant a, [R = 0.082 atm « litre/mol K] The average eneray required to break a P -P bond in P, (6) info gaseous atoms is $3.2 kcal mol-’. The bond dissociation energy of H,(Q) is 104.2 keal mol" ; AH? of PH,(Q) from P,(s) is 5.5 kcal mol. The P-H bond energy in kcal mot-"is [Neglect presence of Van der Waals forces in P,(s)] The difference between AH and AE on a molar and magnitude basis for the combustion of n-octane at 25°C would be [corporate Office : CG Toner, Aa & 62, PIA, Near Cy Mal Jhlanar Road, Kota (a) 224005 Resonsnce® a aan42. Note: In answering this problem, do not neglect vanderwaal's forces in condensed state of matter. Column “ ” 1 (A) pHe@) — Ho) ©) C(graphite)—> C(Diamond) (©) Sthombic)—> Sg) 2 ©) 3 039) —> 0,0) 43, Column (A) simple cubic and face-centred cubic (B) cubic and rhombohedral (©) cubic and tetragonal (D) hexagonal and monoclinic Column (p) Enthalpy of formation of Y. (@) Xand Y are allotropes (9) Xand Y are two different phases (6) The enthalpy change can be used to calculatebond energy in X (without other data) Column (p) have these cell parameters a = =candu= (Q) are two crystal systems (have only two crystallographic angles of 90° (6) belong to same crystal system 44, Column Column Name of method by which sol is prepared (A) As,0, + HS —> As,Su(sol) + H,0 (p) Hydrolysis (B)AuCl, + HCHO + H,0 —» Au(sol) + HCOOH + HCI (@) Double decomposition (©) FeCl, + Hj0—> Fe(OH).(s0)) + HCI (Reduction +FeCl, (0) Fe(OH) (Fresh ppt) “Figy” Fe(OH) (609 (6) Peptization 45. Match the processes given in column-I performed on an ideal gas sample with changes in columr-ll Column Column (A) Isothermal expansion against constant external pressure (B) Free expansion against vacuum under isothermal conditions, (C) Reversible isothermal expansion (D) Free expansion against vacuum under adiabatic conditions. ©) AS. > 0 @as,,=0 AS. =0 (8) A8,,> 0 () AG, < 0 IDPP No. #03 (JEE-ADVANCED) 4. ® 2. ® 3 © 4 8. ® 9% oO 10. e n. 158.) 16.) 17 (AB) 184 22." (ACD) 23. A 24, A 25. 29. (A) 30. © 3. @) 32. 36. 64K, 42, (A) 9.9: (8) 99; >p,r;O) 48 44. (A) > p(B) 7: (C)>s;)>q ANSWERE KEY os. © & #® 2 © (Dei se i eeds! ey eetiateec te) (ABC) 19.* (ABD) 21." (ACD) (Deen eee ©) eee 2 eee) e® 33. © 34. 1 35. 1 2 4. 6 4. 40 43. A)>s;®)>r; (C)>9;0)>P,q) 48. (A) >4q;@) 91: ©>s; Q>p Resonance’ Educating for better tomorow