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BAN QUN L VN HNH SN XUT

Tng Quan Cng Ngh Urea

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BAN QUN L VN HNH SN XUT

NI DUNG
Tng
Tng Quan
Quan V
V m
m Urea
Urea

UREA

Cc
Cc Cng
Cng Ngh
Ngh Sn
Sn Xut
Xut Urea
Urea Trn
Trn Th
Th Gii
Gii

Cng
Cng Ngh
Ngh Sn
Sn Xut
Xut Urea
Urea Ti
Ti Nh
Nh My
My m
m C
C Mau
Mau

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BAN QUN L VN HNH SN XUT

I. Tng Quan V m Urea


Lch
Lch S
S Pht
Pht Trin
Trin
Tnh
Tnh Cht
Cht Vt
Vt L
L
Tnh
Tnh Cht
Cht Ha
Ha Hc
Hc
ng
ng Dng
Dng Ca
Ca Urea
Urea
u
u im
im ca
ca Urea
Urea so
so vi
vi cc
cc lo
lo m
m khc
khc

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BAN QUN L VN HNH SN XUT

Lch S Pht Trin


Hilaire Rouelle pht hin Urea t nc tiu nm 1773
Friedrich Woehler tng hp ra Urea ln u tin t
(NH4)2SO4 v KOCN vo nm 1828
Nm 1870, ur c sn xut bng cch t nng
ccbamat amn trong mt ng bt kn
Nhng hng ng u v cung cp chuyn giao cng
ngh sn xut urea trn th gii nh:
Stamicarbon (H Lan).
Snamprogetti (Italia).
TEC (Nht Bn).

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BAN QUN L VN HNH SN XUT

Tnh Cht Vt L
Cng thc phn t ca Urea: (NH2)2CO

Ur tinh th c mu trng, d ha tan trong nc


Urea rn l cht d ht m t mi trng xung quanh khi p
sut ring phn ca hi nc ln hn p sut hi nc trn b
mt ht ur.

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BAN QUN L VN HNH SN XUT

Tnh Cht Vt L

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BAN QUN L VN HNH SN XUT

Tnh Cht Ha Hc
Mt
Mt s
s phn
phn ng
ng c
c trng
trng ca
ca Ur
Ur
Phn
Phn ng
ng to
to Biuret
Biuret
Phn
Phn ng
ng thy
thy phn
phn
Phn
Phn ng
ng vi
vi Formandehyde
Formandehyde

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Phn ng To Biuret
Phn ng to Biuret
2(NH2CONH2) = NH2CONHCONH2 + NH3
Thch hp :
a) Nhit cao
b) Hm lng NH3 thp
c) p sut thp
d) Nng Urea cao
e) Thi gian lu di

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Phn ng Thy Phn


Phn ng:
NH2CONH2 + H2O = 2NH3 + CO2
Thch hp iu kin :
a) Nhit cao
b) p sut thp
c) Nng NH3 v CO2 thp
ng dng trong vic x l nc thi nhim Urea.

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Phn ng Vi Formandehyde

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ng dng ca Urea
S dng lm phn bn cho cy trng
S dng lm nguyn liu cho cc qu trnh khc:
Sn xut nha Urea Formandehyde
Sn xut Amino acide
S dng trong cc ng dng k thut:
S dng trong phng th nghim.
S dng trong y hc.

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u im ca m Urea
Hm lng Nitrogen trong Urea l nhiu nht so vi cc loi
phn bn c cha N2 khc (46%).
Ngun nguyn liu CO2 cho sn xut Urea hu nh khng tn
km, CO2 ch l sn phm ph trong sn xut NH3
L cht t c hi v tng i an ton trong tn tr v vn
chuyn
Urea c s dng lm ngun nguyn liu trong cng ngh dc
phm v cc ngnh cng nghip khc.

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BAN QUN L VN HNH SN XUT

II. Cng Ngh Sn Xut


Urea

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BAN QUN L VN HNH SN XUT

II. Cng Ngh Sn Xut Urea


Phn
Phn ng
ng Tng
Tng Hp
Hp Urea
Urea

Cc
Cc Yu
Yu T
T nh
nh Hng
Hng n
n Phn
Phn ng
ng Tng
Tng Hp
Hp Urea
Urea

Tng
Tng Quan
Quan Cc
Cc Cng
Cng Ngh
Ngh Sn
Sn Xut
Xut Urea
Urea Trn
Trn Th
Th Gii
Gii

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BAN QUN L VN HNH SN XUT

Phn ng Tng Hp Urea

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BAN QUN L VN HNH SN XUT

Phn ng Tng Hp Urea


Phn ng (1) ta nhit mnh
Phn ng (2) thu nhit nh.
iu kin tng hp (T = 185 1900C, P = 15.6
MPa (G))
Phn ng th nht xy ra nhanh v gn nh hon
ton
Phn ng th hai xy ra chm v quyt nh tc
ca phn ng
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Cc Yu T nh Hng n Phn ng Tng Hp


Urea.
nh
nh hng
hng ca
ca t
t l
l NH3/CO2
NH3/CO2
nh
nh hng
hng ca
ca t
t l
l H
H22O/CO
O/CO22
nh
nh hng
hng ca
ca nhit
nhit

nh
nh hng
hng ca
ca p
p sut
sut
nh
nh hng
hng ca
ca thi
thi gian
gian lu.
lu.

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BAN QUN L VN HNH SN XUT

nh Hng ca t l NH3/CO2
Tng NH3 hoc CO2 s tng chuyn ha.
T l NH3/CO2 theo l thuyt l 2, nhng chuyn ha ch
t 43.5% iu kin p sut v nhit l 170atm/155C
Khi t l NH3/CO2 thay i t 2 n 9 th chuyn ha thay
i t 43.5% n 85.2%
Khi t l NH3/CO2 thay i t 2 n 0.5 th chuyn ha
thay i t 43.5% n 46%, CO2 d tha t nh hng n
chuyn ha so vi d tha NH3
T l NH3/CO2 thng thng l 2.5 5

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nh Hng ca t l NH3/CO2

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nh Hng ca t l H2O/CO2
Tha nc:
nh hng n qu trnh to Urea.
Tng tiu hao nng lng
Gim th tch dnh cho phn ng chuyn ha Carbamat
thnh Urea
Thiu nc:
D gy tc ng ng, thit b.
T l H2O/CO2 thng thng l 0.4 - 1

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nh Hng ca t l H2O/CO2

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nh Hng Ca Nhit

Phn ng 1 thch hp nhit thp, xy ra nhanh v hon


ton
Phn ng 2 thch hp nhit cao, xy ra chm v khng
hon ton, c khng ch t chuyn ha ti u.
chuyn ha tng t l thun vi nhit (Frajacques)
chuyn ha cn bng t ti a 196-200C
(Otsuka)
Nhit cng cao th kh nng n mn cng ln

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nh Hng Ca Nhit

CO2 conversion Frejacques

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nh Hng Ca Nhit

CO2 conversion Otsuka

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nh Hng Ca Nhit

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nh Hng Ca p Sut
p sut cng cao cng thun li cho s to thnh Urea
p sut cn bng trong thp phn ng ph thuc vo
thnh phn v nhit ca dung dch
p sut phi cao hn p sut phn hy Carbamat ti
nhit tng ng

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nh Hng Ca p Sut

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nh Hng Ca p Sut

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nh Hng Ca p Sut

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nh hng ca thi gian lu


Thi gian lu cng cao th hiu sut chuyn ho cng
cao
NH3/CO2=4.0, Temp= 188C, RT=30min--Conversion=68%
NH3/CO2=2.8, Temp= 181C, RT=55min--Conversion=61%
Thi gian lu cng cao th chi ph u t cao.
RT ti nh my DCM l 45 min

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nh hng thi gian lu

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Cc phn ng ph trong qu trnh tng hp Urea


Phn ng thy phn ca ur:
CO(NH2)2 + H2O NH2COONH4 2 NH3 + CO2 (3)
Phn ng to biuret:
2 CO(NH2)2 NH2CONHCONH2 + NH3 (4)
Phn ng to axit isocyanic:
CO(NH2)2 NH4NCO NH3 + HNCO (5)

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Cacbamate v phn ng phn hy Cacbamate.


Cacbamat l mt cht rn tinh th mu trng ha tan trong
nc. N c hnh thnh nhit phng bng cch cho
NH3 kh i qua bng kh
nhit phng vi mt dung dch c cha nc n s
chuyn ha chm thnh cacbonat (NH4)2CO3
Trn 60oC dch cacbonat s chuyn thnh dch cacbamat v
iu kin nhit 100oC th ch c cacbamat l c mt trong
dung dch.
Trn 150oC cacbamat s b mt mt mol nc v hnh thnh
ur
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Cacbamate v phn ng phn hy Cacbamate.


Phn ng:
NH2COONH4 = 2NH3 + CO2
Thch hp :
a) p sut thp
b) Nhit cao
c) NH3 v CO2 sau khi phn gii c li cun i.
Phn ng ny c ng dng thu hi NH3 v CO2 (phn cha
chuyn ha thnh Urea)

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Cc Loi Cng Ngh Sn Xut Urea Trn Th Gii


THP
PHN
NG

Urea
Carbamate
Water
NH3 (excess)

thu c sn phm Urea, cn thit phi phn tch cc cht


khng tham gia phn ng, NH3 d v c c (tch nc) dung
dch Urea

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Cc Loi Cng Ngh Sn Xut Urea Trn Th Gii


Cn c vo kh nng thu hi NH3 v CO2, pht trin thnh ba
cng ngh chnh:
Cng ngh Once through
Cng ngh Partial recycle
Cng ngh Total recycle

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Cng ngh Once through


CO2 v NH3 (sn phm t qu trnh phn gii) c mang n cc phn
xng khc sn cut cc loi phn bn khc nh nh:ammonium
nitrate, ammonium sulphate

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Cng ngh Partial recycle


Kh thi ra t cng on phn hu c cha NH3, CO2:
Mt phn c s dng lm nguyn liu cho sn xut cc
loi phn bn khc
Phn cn li tun hon li h thng tham gia phn ng tip

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Nhc im Ca Cng Ngh Oncethrough/partial


recycle
Hiu sut chuyn ho thp
Tiu th nng lng ln
Ph thuc vo cc cng on s dng kh thi
lm nguyn liu
Gi c u t cao

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Cng Ngh Total Recycle


CO2 v NH3 c tch hon ton trong cc thit b phn hy nhiu giai
on v c thu hi n thit b phn ng
chuyn ha to Urea tnh theo NH3 c th t n 99%.
t sn phm ph to thnh
Ngy nay cc nh my Urea ch s dng cng ngh Total recycle

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Cng Ngh Total Recycle

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Cng Ngh Total Recycle


Cng ngh thng thng
(Phn hu bng phng
php gim p cp nhit)
1)Montedison
2)Mitsu-toatsu

Cng ngh Stripping


(S dng d NH3 hoc
CO2)
1) Stamicarbon (CO2
Stripping )
2) Snamprogetti
(Ammonia stripping )
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Cng ngh stripping CO2 Stamircacbon

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Cng ngh stripping CO2


Stamircacbon

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Cng ngh stripping CO2


Stamircacbon
Thp tng hp, thp phn hy cacbamat (stripper) v thit b ngng t
cacbamat u hot ng p sut khong 14 Mpa
T l mol NH3/CO2 l 2,8:1
Trn nh ca thp tng hp c thit b dng cho vic phn ly cc cht
khng ngng t ca dch sn phm ur.
Cc cht khng ngng t ch yu l khng kh th ng ha c ra
bi dch cacabamat t thp hp th thp p ti v thi ra ngoi qua h
thng thi kh tr trn cao

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Cng ngh stripping CO2


Stamircacbon
Thit b Stripper: Dng CO2 c np vo pha di ca Stripper
lm tc nhn li cun NH3 v CO2 (sn phm ca qu trnh phn
gii cacbamate)
Lng cacbamat cha chuyn ha c phn hy v tun hon
ng p ti cho thp tng hp do vy cng sut bm tun hon
cng c gim i.

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Cng ngh Stripping NH3


Snamprogetti
Cng ngh Snamprogetti ang c s dng ti nh my m C Mau
Chu trnh tng hp vn hnh p sut 15 Mpa v t l ton phn
NH3/CO2 l 3,8:1.
chuyn ha CO2 thnh Urea kh cao (khong 60%).

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Cng ngh Stripping NH3


Snamprogetti

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Cng ngh Stripping NH3


Snamprogetti
u im:
Chng n mn
Thc y s li cun
chuyn ho cao
To thnh Biuret thp
Vn hnh uyn chuyn
S dng t khng kh th ng

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Cng ngh Stripping NH3


Snamprogetti
Mt s c trng khc ca cng ngh Snamprogetti:
Lp t cc ejectors
S dng my nn ly tm
ng truyn nhit lng kim loi
B tr thit b theo chiu ngang lm gim ng k chiu
cao
Cn bng mng hi n nh
Vt liu cho TBP: Cr.Ni.Mo 25.22.2
Lp lt bn trong ng TN Stripper : Zirconium
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Cng Ngh Sn Xut


UREA Ti Nh My m
C Mau

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Cng Ngh Sn Xut UREA Ti Nh My m


C Mau
Nh my m C Mau l nh my sn xut Ur ht c
Cng sut 2385 tn/ngy, 800.000 tn/nm
Cng ngh Ur l ca Snamprogetti (Italia)
Cng ngh to ht l ca Toyo (Japan)

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BAN QUN L VN HNH SN XUT

Cng Ngh Sn Xut UREA Ti Nh


My m C Mau
Cc Cng on Chnh:
Cng on my nn CO2
Cng on tng hp v thu hi cao p
Cng on phn gii v thu hi trung p
Cng on phn gii v thu hi thp p
Cng on c c
Cng on to ht
Cng on x l nc cng ngh
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Cng Ngh Sn Xut UREA Ti Nh


My m C Mau
My nn CO2

Hi
nc

NH3, CO2

Amnic

Tng hp
cao p

31%NH3; 14,6%CO2:
20% H2O; 34% ur

Phn hy
trung p
(19,5 bar)

DD Ure 6063% KL

Phn hy
thp p (4
bar)

C c
chn
khng

DD ure 6971% KL

DD ure 96%
KL

H thng
to ht
tng si

Xng sn
phm

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BAN QUN L VN HNH SN XUT

Cng Ngh Sn Xut UREA Ti Nh


My m C Mau

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Cng on Nn CO2

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Cng on Nn CO2
Thuyt minh lu trnh cng ngh:
CO2 c ly t bn ngoi phn xng (t phn xng Amoniac)
450C v 0.05MPaG.
CO2 bo ha hi nc v tinh khit ti thiu l 99% th tch.
CO2 c a qua bnh tch S06119 v n ca ht cp mt ca my
nn.
Mt lng kh th ng ha (PA) thm vo trc bnh tch ti ca ht
cp 2 ca my nn nhm th ng ha b mt thit b cm cao p.
Lng oxi thm chim khong 0,25% th tch tng lng CO2 np liu.

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Cng on Nn CO2
p sut sau cc cp nn :
Sau cp 1 : 0.37 MPaG
Sau cp 2: 2.05 MPaG
Sau cp 3: 78.5 MPaG
Sau cp 4: 15.8 MPaG

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BAN QUN L VN HNH SN XUT

Cng on Nn CO2
My nn gm c bn cp. Sau mi cp nn u c trang b mt thit
b lm mt v mt thit b tch trung gian
Nhit ti ca ht ca cp nn th t c khng ch trnh hin
tng ha rn ca CO2
Lu lng nn c iu khin bng tc ca tuabin hi nc.
Nu im vn hnh ca my nn chm vo vng bo v Surge th h
thng chng surging s t ng m cc van Anti Surge bo v my
nn.

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Cng on Nn CO2

My nn CO2 c truyn ng bng tuabin hi KT06101 s dng nng


lng hi nc cao p.
Mt phn hi trung p 2.37MpaG c trch ra v s dng trong phn
xng ur.
Hi LS d ca mng hi nh my s c b xung vo phn thp p ca
Tuabine.

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Cng on Nn CO2
Dng hi nc sau khi i qua turbine s i vo h thng ngng t hi
nc (s dng nc sng lm mt)
H thng ngng t hi nc bao gm thit b ngng t hi nc
E06140, thit b to chn khng v bm condensate
Thit b to chn khng c trang b duy tr chn khng trong thit
b ngng t ca tuabin.
Dng nc ngng t E06140 c bm bng bm P06118A/B v a ra
bn ngoi phn xng.

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Cng on Tng Hp V Thu Hi Cao


p

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BAN QUN L VN HNH SN XUT

Cng on Tng Hp V Thu Hi Cao


p
Phn ng tng hp Ur
Qu trnh phn gii cao p ti thit b Stripper
Qu trnh ngng t ti thit b Carbamat Condensor
Vai tr ca kh th ng ha

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Cng on Tng Hp V Thu Hi Cao


p

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BAN QUN L VN HNH SN XUT

Cng on Tng Hp V Thu Hi Cao


p iu kin phn ng:
T=188C, P=155 barg.
T l NH3/CO2 = 3.3 3.6
T l H2O/CO2 = 0.5 0.7
Phn ng 1 xy ra nhanh v hon ton, phn ng 2 xy
ra chm nn quyt nh tc phn ng.
Hiu sut phn ng nh hng bi t l cc cht phn
ng, nhit , p sut v thi gian lu trong thp phn
ng.
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Cng on Tng Hp V Thu Hi Cao


p
T T06105 amoniac c bm n p sut 2.35MPaG bng
bm ly tm tng p amoniac P06105A/B. Mt phn amoniac
c a n thit b hp th trung p C06101, phn ch yu
cn li i vo chu trnh tng hp cao p.
Amoniac c a n thp tng hp bng bm ly tm
amomiac cao p P06101A/B, n p sut 22MPaG

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Cng on Tng Hp V Thu Hi Cao


p

Trc khi vo thp tng hp, amoniac c gia nhit


trong thit b tin gia nhit amoniac, E06107, v c
s dng nh l tc nhn y trong Ejector cacbamat,
J06101, ti y cacbamat i t thit b tch cacbamat,
S06101, c y n p sut tng hp.
Hn hp lng NH3 v cacbamat vo y thp tng hp
ni n phn ng vi dng kh nn CO2 t my nn
K06101.

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Cng on Tng Hp V Thu Hi Cao


pDng nguyn liu CO i t xng amoniac vo
2

phn xng ur p sut 0.05MPaG v nhit


45oC c nn trong cm my nn CO2 K06101, ln
n p sut khong 15.7MPaG
Hn hp lng NH3 v cacbamat vo y thp tng
hp ni n phn ng vi dng kh nn CO2.

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Cng on Tng Hp V Thu Hi Cao


p
Mt lng nh khng kh c a vo dng nguyn liu CO2 u
ht K06101 th ng ha b mt thp khng r ca cc thit b trong
chu trnh cao p, nh bo v chng khi b n mn do cc cht phn
ng v sn phm hnh thnh sau phn ng.
Sn phm ra khi thp tng hp i vo phn trn ca thit b phn hy
Stripper E06101, hot ng p sut khong 147 barg. Khi cht lng
chy xung, n c gia nhit, qu trnh phn hy cacbamat v qu
trnh bay hi b mt s xy ra. Hm lng CO2 ca dung dch c
gim nh nh hng stripping ca NH3 khi dung dch si v nh NH3
ra
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Cng on Tng Hp V Thu Hi Cao


p
Pha hi hnh thnh (ch yu l NH3 v CO2) i ngc ln nh cc ng
Lng nhit cho qu trnh phn hy cacbamat c cung cp bng qu
trnh ngng t hi p sut 2.18MpaG (hi bo ha).
Dng kh t nh ca stripper v dung dch thu hi ca dung dch thu
hi t y ca thit b hp th trung p C06101 vo cc thit b ngng t
E06105A/B, ti y tr cc kh khng ngng c, tt c cc phn
ngng t c c ngng t v hi lu li thp tng hp R06101 nh
ejector J06101

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Cng on Tng Hp V Thu Hi Cao


p
Qu trnh ngng dng kh cng ngh p sut cao
(khong 14.4MPaG) cho php sn xut hi nc bo ha
0.55MPaG bng thit b ngng t cacbamat th nht
E06105A v
0.34MPaG bng thit b ngng t
cacbamat th hai E06105B
T nh ca thit b tch cacbamat S06101 dng kh
khng ngng ch yu l kh tr (khng kh th ng ha
cng kh tr v CO2 u vo) cha mt t NH3 v CO2,
c a trc tip vo y thit b phn hy trung p
E06102.
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Cng on Tng Hp V Thu Hi Cao


p
Khng kh th ng ha c a vo y thit
b stripper qua my nn kh K06102A/B; lng kh
ny s th ng ha b mt y stripper, hot
ng iu kin lm vic c tnh n mn cao.
Dng lng i ra khi y Stripper E06101 vi thnh phn
31%NH3; 14,6%CO2; 20% H2O; 34% ur c a sang
thit b tch trung p S06102.

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Cng on Tng Hp V Thu Hi Cao


p
Khng kh th ng ha c a vo y thit b stripper
qua my nn kh K06102A/B; lng kh ny s th ng ha
b mt y stripper, hot ng iu kin lm vic c tnh n
mn cao.
Dng lng i ra khi y Stripper E06101 vi thnh phn
31%NH3; 14,6%CO2; 20% H2O; 34% ur c a sang
thit b tch trung p S06102.

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Cng on Tng Hp V Thu Hi Trung


p
Qu trnh phn gii trung p
Qu trnh hp th CO2
Qu trnh thu hi NH3 d
Qu trnh nhn NH3 t xng Amonia
Qu trnh vn chuyn NH3 n tng hp cao p
Qu trnh tun hon carbamat v cao p.

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Cng on Tng Hp V Thu Hi Trung


p

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Cng on Tng Hp V Thu Hi Trung


p

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Cng on Tng Hp V Thu Hi Trung


p
Dung dch ure vi nng 43%, i ra khi y ca thit b
stripper, E06101, c gin n n p sut 1.95MPaG v i
vo phn trn ca thit b phn hy trung p.

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Cng on Tng Hp V Thu Hi Trung


p

Thit b ny c chia thnh ba b phn:


Phn nh l thit b tch, S06102, ti y dng kh trong dung
dch c tch ra trc khi dung dch i vo chm ng.
Phn gia l thit b phn hy dng mng lng trong ng,
E06102A/B, ni cacbonat c phn hy v lng nhit cn
thit c cung cp bng qu trnh ngng t hi p sut
0.49MPaG (E06102A) v condensat i ra t thit b S06109,
p sut 2.15MPaG ( phn di ca thit b, E06102 B).
Phn cui l thit b gom dung dch ur T06122, dung dch ur
sau tinh ch giai on mt c nng 60-63%khi lng.
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Cng on Tng Hp V Thu Hi Trung


p
Kh giu NH3 v CO2 i ra khi nh thit b tch S06102, c a vo
thit b tin c c chn khng dng mng E06104, dng kh ny i bn
ngoi ng y n b hp th mt phn trong dung dch cacbonat n t
vng thu hi p sut 0.35MPaG.
Tt c lng nhit sinh ra nh qu trnh ngng t/hp th/phn ng bn
ngoi ng c s dng cho qu trnh c c dch Urea i bn trong
ng.
T thit b c c chn khng s cp E06104, dng hai pha hn hp bn
ngoi ng c a vo thit b ngng t trung p E06106, y hu
ht CO2 c hp th v nhit ngng t/phn ng c ly i bi dng
nc Fresh sau E06109
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Cng on Tng Hp V Thu Hi Trung


p
Dng hai pha hn hp t E06106 c a vo y
thit b hp th trung p, C06101, y pha kh i ln
t pha lng vo vng luyn. y l loi thp a chp
hnh chung v thc hin qu trnh hp th CO2 v tinh
luyn NH3
Cc a c cung cp dng hi lu NH3 tinh ch
hp th trit CO2 trong dng kh i ln bao gm kh
tr v NH3 d.
Hn hp kh ra t nh C06101 i vo E06109 c
ngng t mt phn trong thit b ngng t amoniac
E06109. T y dng hai pha c a n bnh nhn
amoniac T06105
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Cng on Tng Hp V Thu Hi Trung


p
Hi khng ngng ti E06109 vi amoniac ri T06105 i ln trong
thp thu hi amoniac, C06105, ti y thm mt lng amoniac
c ngng t nh dng lng amoniac i xung n t phn
xng NH3.
Dng kh ri nh thp C06105, i ln thit b hp th E06111, ti
y kh amoniac c hp th nh dng amoniac long chy
ngc chiu. duy tr nhit ti u, qu trnh hp th c
lm ngui bng dng nc lm mt i bn ngoi ng ca E06111

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Cng on Tng Hp V Thu Hi Trung


p
Thp ra kh tr trung p C06103, ni vi phn trn ca E06111, bao
gm 3 a van. Kh tr ti y c ra cng on cui bng dng nc
sch. Cui cng kh tr c a ra ng x.
T y thit b E06111 dung dch H2O-NH3 c hi lu tr v thit b
hp th trung p C06101 bng bm li tm P06107A/B
Dng y C06101 c hi lu bng bm dung dch cacbonat cao p
P06102A/B n vng tng hp sau khi c tin gia nhit trong ng ca
thit b tin gia nhit cacbonat cao p E06113. Trong thit b trao i
nhit ny dng nng i ngoi ng l dng nc ngng t y thp
chng ct C06102.

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Cng on Tng Hp V Thu Hi Thp


p
Qu trnh phn gii thp p
Qu trnh thu hi carbonate
Qu trnh chuyn dch carbonate v trung p

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Cng on Tng Hp V Thu Hi Thp


p

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Cng on Tng Hp V Thu Hi Thp


p

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Cng on Tng Hp V Thu Hi Thp


p

Dung dch, vi nng ur 62%, i ra khi y ca thit b phn hy trung p


c gin n n p sut 3.5 barg v i vo phn trn ca thit b phn hy
thp p.
Thit b ny c chia thnh ba b phn:
Phn nh l thit b tch S06103, ti y dng kh trong dung dch c
tch ra trc khi dung dch i vo chm ng.
Phn gia l thit b phn hy dng mng lng trong ng E06103 ni
cacbonat c phn hy v lng nhit cn thit c cung cp bng qu trnh
ngng t hi thp p 0.49MPaG
Phn cui l thit b gom dung dch ur T06103, dung dch ur sau tinh ch
giai on hai c nng 69-71%khi lng.

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Cng on Tng Hp V Thu Hi Thp


p
Kh ri nh S06103 u tin c trn vi dng hi i
t vng luyn ca thp chng ct C06102, sau c
a vo thit b tin gia nhit amoniac cao p E06107
y n c ngng t mt phn
Nhit ngng t c thu hi bng dng amoniac lng
cao p chy bn trong ng, dng amoniac ny c gia
nhit trc khi np liu vo thp tng hp ur.

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Cng on Tng Hp V Thu Hi Thp


p
Lu th bn ngoi ng i ra khi thit b E06107 c
a vo thit b ngng t thp p E06108, ti y hi
NH3 v CO2 c ngng t hon ton. Nhit ngng t
c thu hi bng nc lm mt i trong ng.
Dung dch cacbonat ra khi E06108 c thu hi trong
bnh thu gom dung dch cacbonat T06106.
Dch cacbonat c hi lu tr li y thit b hp th
trung p C06101, bng bm li tm P06103.
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Cng on Tng Hp V Thu Hi Thp


p
T06106 c thit k c mt thp ra kh tr thp p
C06104.
C06104 c ni vi phn trn ca thit b hp th
amoniac thp p E06112 ti y nc lm mt c s
dng thu hi lng nhit ta ra do qu trnh hp th.

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Cng on C c Chn Khng


Qu trnh c c dch ur trong iu kin chn khng
Qu trnh thu hi v tn tr dch ur
Qu trnh ngng t hi nc

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Cng on C c Chn Khng

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Cng on C c Chn Khng


Dung dch ur ri khi y thit b phn hy thp p c
gin n n p sut 0,33 bar tuyt i v i vo phn trn ca
thit b tin c c chn khng. Thit b ny c chia lm ba
phn chnh:
Phn nh l thit b tch S06104, ti y dng kh trong
dung dch c tch ra trc khi dung dch i vo chm ng.
Dng hi c ht bi h thng chn khng Z06105.

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Cng on C c Chn Khng


Phn gia l thit b c c dng mng ri E06104, ni
lng cacbonat cn d c phn hy v nc c bc hi.
Lng nhit cn thit c cung cp bng qu trnh ngng t
bn ngoi ng mt phn kh i t nh thit b phn hy trung
p.
Phn cui l thit b gom lng T06124, ti y dung dch
ur thu c c nng 84-87%khi lng.

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Cng on C c Chn Khng


Dung dch ur ra khi thit b tin c c chn khng,
T06124, c a n thit b c c chn khng,
E06114 bng bm dung dch ur, P06106. Thit b ny
hot ng p sut 25KPa.
Hi bo ha 3,4 barg c i bn ngoi ng thit b
E06114 gia nhit v c c dch ur trong ng.
Dch i ra t E06114 vo thit b tch chn khng,
S06114, t y hi c ht bng h thng chn khng
Z06105, trong khi dch ur (~ 96% khi lng) c
gom ti T06114 v c P06108AB bm i to ht.
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Cng on C c Chn Khng


Hi i ra t 2 thit b tch S06104 v S06114 bao gm
hi nc v mt phn NH3, CO2, Ur s c ngng t
ti cc thit b ngng ca h thng Z06105 v a v
bn T06102 x l.

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Cng on X L Nc Ngng Cng


Ngh
Qu trnh chng ct NH3 v CO2
Qu trnh thy phn Ur

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Cng on X L Nc Ngng Cng


Ngh

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Cng on X L Nc Ngng Cng


Ngh

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Cng on X L Nc Ngng Cng


Ngh
Nc ngng cng ngh cha NH3, CO2 v ur t h thng chn
khng, c tp trung trong bn cha nc ngng cng ngh
T06102.
Nc t h thng thi kn c thu gom trong bn cha T06104,
v c a sang T06102 bng bm P06116A/B.
T y nc ngng cng ngh c bm bng bm P06114A/B
vo phn trn a np liu ca thp chng C06102
Trc khi vo ct, nc ngng cng ngh c gia nhit trong
thit b trao i nhit E06116 bi chnh dng nc cng ngh
c tinh khit ra khi y ca thit b chng ct.
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Cng on X L Nc Ngng Cng


Ngh

Thp chng C06102 gm 55 a v c chia thnh 2 phn


chnh bng mt a ngn c t gia a th 35 v 36 (tnh
t y).
iu kin cng ngh ca ct:
p sut (y/nh): 4,7/4,2 barg;
Nhit (y/nh): 157/1300C

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Cng on X L Nc Ngng Cng


Ngh

Nc ngng t a chimney tray c bm bng bm ly tm


P06115A/B vo thit b thy phn ur R06102, y c cc iu
kin cng ngh thch hp cho phn hy ur thnh CO2 v NH3.
Thit b R06102 hot ng ging nh mt thit b phn ng v
dng hi c a vo cung cp nhit cho qu trnh phn hy
ur
iu kin hot ng ca thit b:
p sut: 3.43MPa (G)
Nhit : 2350C
Hi cao p: nhit 3700C, p sut 3.82 MPa (G).
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Cng on X L Nc Ngng Cng


Ngh
Dng hi ra khi thit b thy phn v hi t nh thp chng ct
c ha trn vi kh ra khi nh thit b phn hy thp p, trc
khi n thit b E06107 thu hi nhit.
Nc ngng thy phn ra khi y thit b R06102, sau khi
gim nhit khi qua thit b tin gia nhit E06118, i vo thp
chng ct ngay bn di a chimney,
Hi ( p sut 5.4 barg) c phun trc tip vo y thp chng
ct, lm tc nhn cho qu trnh chng ct.

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Cng on X L Nc Ngng Cng


Ngh
Nc ngng qu trnh lm sch ri y thp chng nhit
1570C c lm lnh ti 450C nh:
Gia nhit s b dng cacbonat cao p trong thit b E06113.
Gia nhit s b dng np liu thp chng ct trong E06116.
Lm lnh ln cui ti E06123.
Cc cht NH3 CO2 ur trong nc sau x l c gim xung
cn khong vi ppm.
Trong qu trnh khi ng v khi gp s c nc sau x l khng
t ch tiu cht lng c tun hon v T06102 hoc T06125.
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H Thng Ph Tr Ca Xng Urea


Bn cha dch Urea
Mng hi
Mng nc ra
H thng thu gom nc thi
H thng x l kh thi
Mt s mng ph tr khc

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Bn Cha Dch Urea T06101


Bn T06101 th tch 1050 m3 c s dng thu gom
c dch ur 7075%khi lng trong trng hp vng
c c v to ht c s c.
Bn ny cng c s dng thu hi dch ur t bn
cha ur T07601 sau khi c lc qua thit b lc
S06126A/B.
Dch ur cha trong bn T06101 c th c gia nhit
bng hi nc bo ha thp p thng qua gin ng trao
i nhit di y bn.
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Mng Hi Trong Xng Urea


Bao gm 5 mng hi:
Hi cao p qu nhit (HS)
Hi trung p qu nhit (MS)
Hi trung p bo ha (MSS)
Hi trung thp p bo ha (MLS)
Hi thp p bo ha (LSS)

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Mng Hi Trong Xng Urea

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Mng hi cao p qu nhit


Thng s : P = 3.82 MPa (G), T = 3700C.
c ly t mng hi nh my ( Boiller v hi trch t
KT04431 v KT04441)
H thng hi ny c dng cho:
turbine ca my nn CO2 v thit b thy phn ur R06102.

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Mng hi trung p qu nhit


Thng s : P = 2.37 MPa (G), T = 3200C.
H thng hi vi nhit 3200C v p sut 2.37 MPa (G)
c trch ra t tuabin dn ng cho my nn CO2.
N c s dng to thnh hi trung p bo ha.
Ngoi ra cn c 1 dng cp cho E06102B khi cn.

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Mng hi trung p bo ha
Thng s : P = 2.17 MPa (G), T= 2190C
c to thnh t hi trung p qu nhit sau khi i qua bnh
bo ha hi nc S06109.
c s dng chnh trong vic cp nhit cho stripper E06101,
v mt lng c a vo nh ca thit b tch kh tr trung
p.
Ngoi ra n cn c dung gia nhit cho ng khi ng
(start up line) trong qu trnh gia nhit v gia p cm cao p.
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Mng hi trung thp p bo ha


Thng s : P = 0.55 MPa (G), T= 1620C.
c sinh ra t vic un si nc pha v thit b ngng t
cacbamat th nht E06105A. Ngoi ra c th letdown xung
t mng Trung p qu nhit qua van PV1059A.
c s dng ti nhng thit b sau:
Thit b phn hy thp p E06103.
Thit b phn hy trung p E06102A.
Thp chng C06102.
Let down xung mng hi thp p
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Mng hi thp p bo ha
Thng s : P = 0.34 MPa (G), T= 1470C
Hi ca h thng ny c sinh ra t vic un si nc ngng t pha v
thit b ngng t cacbamat th hai E06015B. Ngoi ra c th letdown t
mng Trung thp p bo ha
c s dng ti nhng thit b sau:
Thit b c c chn khng.
H thng ejector ca cm chn khng.
H thng hi bo n v hi flushing
Cm to ht.

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H Thng Nc Ra
Dch Urea, Carbamat v carbonate d b kt tinh trong
ng ng v thit b nu nhit thp nn cn phi
ra ng ng thit b kp thi.
Hi nc sau khi gia nhit ngng t li c s dng
lm nc ra cho h thng cng ngh
Nc demi c ly t h thng bn ngoi cng c
s dng lm nc ra.

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H Thng Nc Ra

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H Thng Nc Ra
BAO GM 3 MNG NC RA
Mng cao p (HPW): P = 162 barg, T = 1200C c s
dng cho cm tng hp cao p.
Mng trung p (MPW): P = 30 barg, T = 1200C c s
dng cho khu trung p
Mng thp p (LPW): P = 8 barg, T = 1200C s dng
cho cc khu cn li

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H Thng Thu Gom Nc Thi


H thng thu gom nc thi kn
Bn cha cht thi kn cacbonat T06104 c lp t
trong xng thu hi cc im thi thng thng cha
cacbamate v dch ammonia t qu trnh
H thng thu gom nc thi h:
Thu gom nc thi khng gy tht thot mi ra mi
trng
Ngoi ra cn c bn cha trung gian T06125
H thng thu gom nc thi nhim du a sang ph
tr
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H Thng X L Kh Thi
CC NGUN KH THI N T
Cc bn cha
Kh cng ngh cao p.
Kh cng ngh trung p
Kh cng ngh thp p
Kh cng ngh t thp chng ct x l nc cng
ngh.

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H Thng X L Kh Thi

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im thi kh lin tc
H thng kh thi lin tc:
im x cm trung p (t C06103 qua PV1026)
im thi cm bay hi (t im x Scrubber h
thng chn khng C06135)
Cc im x kh ny c a n uc lin tc Z06112
t chy hon ton trc khi ra ngoi mi trng.

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im thi kh gin on
H thng kh thi gin on:
Cc im thi t im vent cm LP (PV1033)
im x cm HP (PV1021B)
im vent kh t cc bn T06101, T06102, T06104
Kh ra khi cm x l nc (trong trng hp dng my).
Cc im ny c gom v uc gin on Z06113 t chy
hon ton trc khi i ra mi trng
Ngoi ra cn c h thng Blowdown thu gom t sau cc van an
ton trong trng hp sy ra s c.
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Kt Thc !!!

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