CHUYN : NHM OXI- LU HUNH

A.L THUYT
I.
LU HUNH V HP CHT
1/. ac iem cau tao:
Nguyen t S thuoc phan nhom chnh nhom VI (VIA), co 6e ngoai
cung ns2np4
De nhan 2e, the hien tnh oxi hoa, ac biet khi S phan ng vi
kim loai manh (Na2S)
Gop chung 2e tao 2 lien ket cong hoa tr, khi S phan ng vi phi
kim (H2S)
S cung co the tao them 2 lien ket cho nhan sau khi gop chung 2e
vi nguyen t khac (SO3, H2SO4), trong trng hp nay, S co so oxi
hoa dng.
2/. Tnh oxi hoa kh cua S va SO2.
S hay SO2 cha S mang so oxi hoa trung gian nen va co tnh oxi
hoa (khi tac dung vi chat kh), va the hien tnh kh (khi tac
dung vi chat oxi hoa).
Tnh oxi hoa
Tnh kh
S
S oxi hoa khi loai (tr Au,
Pt) thanh sunfua kim loai
hoa tr thap.
Fe + S FeS
S + O2 SO2
S oxi hoa phi kim co o
S + 2H2SO4 3SO2 + 2H2O
am ien kem hn S (tr S + 4HNO3 SO2 + 4NO2 + 2H2O
N2, I2).
3S + KClO3 2SO2 + 2KCl
350o

S + H
H2S
2
o
450
o

SO2

2S + C t CS2 (long)
SO2 + 2H2 S + 2H2O
SO2 + 2CO S + 2CO2
SO2 + 2Mg S + 2MgO

2SO2 + O2 SO3
SO2 + Cl2 + 2H2O H2SO4 + 2HCl
5SO2 + 2KMnO4 + 2H2O 2MnSO4 + K2SO4 +
H2SO4
SO2 + NO2 SO3 + NO

3/. Tnh kh cua H2S

Trong H2S, S co so oxi hoa -2, thap nhat nen the hien tnh kh
khi tac dung vi chat oxi hoa nh O2, Cl2, SO2, KMnO4, FeCl3, K2Cr2O4.
H2S + O2 S + H2O
2H2S + 3O2(d) 2SO2 + 2H2O
H2S + Cl2 S + 2HCl
2H2S + SO2 3S + 2H2O
H2S + 2FeCl3 2FeCl2 + S + HCl
5H2S + 2KMnO4 + 3 H2SO4
2MnSO4 + K2SO4 + 5S + 8H2O
4/. Tnh oxi hoa cua H2SO4
Tac dung vi
San pham
Do H+
H2SO4
Kim loai trc H
Muoi sunfat (tan) + H2
loang
2
H2SO4
Kim loai manh hn Sunfat kim loai + (SO2, S, H2S) +
Do SO4
ac,
Fe
H2O
nong
Fe va kim loai
Sunfat kim loai + SO2 + H2O
yeu hn
Phi kim (C, S, P)
Oxit axit hay oxiaxit + SO2 + H2O
Chu y: Fe, Al, Cr: khong tac dung vi H2SO4 ac nguoi.

Cac hp chat cua kim loai co hoa tr thap cung b H2SO4 ac

oxi hoa.
2FeO + 4H2SO4 () Fe2(SO4)3 + SO2 + 4H2O
2FeS + 10H2SO4 () Fe2(SO4)3 + 9SO2 + 10H2O
Nhan biet goc SO24 : dung ion Ba2+ (Ba(NO3)2 hoac Ba(OH)2 hoac
BaCl2)
KIEN THC BO SUNG:
Giai toan lien quan en lu huynh va hp chat
1/. Nhan biet:
SO2: lam phai mau dung dch KMnO4 hay dung dch Br2
SO2 tac dung vi Ba(OH)2 tao ket tua BaSO3 tan trong dung dch HCl
con SO3 tac dung vi Ba(OH)2 tao ket tua BaSO4 khong tan trong
dung dch HCl.
H2S tao ket tua en vi dung dch muoi kim loai nang
CuCl2 + H2S CuS + 2HCl
2/. Sunfua kim loai:
Tan trong nc gom sunfua kim loai kiem, BaS, CaS, SrS, MgS.
Khong tan trong nc, tan trong HCl: sunfua kim loai trc Pb (trong
day hhh).
Khong tan trong HCl, tan trong HNO3: CuS, Ag2S, PbS.
Sunfua kim loai + O2 oxit kim loai (hoa tr cao) + SO2
o
Kim loai (trc Pb) + S t hon hp ran +HCl phan khong tan la
S d
3/. Oxi hoa SO2 bang oxi
Goi mt va ms lan lt la khoi lng hon hp trc va sau phan
ng

m =m
Bao toan khoi lng n t >n s M t < M s
t
s
dt <ds
Vi M : Phan t khoi trung bnh, d: t khoi hon hp, n: so mol
hon hp kh.
nsp (thc te)
n chatthgia (aphan ng)

Hieu suat phan ng: h =

nsp (l thuyet)
n chatthgia (toia)
nSO

Neu

nO

2 SO2 d vahie
u sua
t tnh theo O2

Neu

nSO

nO

2 O2 d vahie
u sua
t tnh theo SO2

II.

OXI OZON
A. OXI
1. V TR CU TO
- th 8
- Nhm VIA
- Chu k 2
Cu hnh e: 1s2 2s22p2
CTCT: O=O
&
&&
&
CT electron: :O::O:
2. TNH CHT VT L

- Trng thi
- Mu sc
- Mi v
- T khi
- Nhit ha lng
- tan
III-TNH CHT HO HC
1. Tc dng vi kim loi
Mg + O2
Al + O2
2. Tc dng vi phi kim
C + O2
P + O2
3. Tc dng vi hp cht
C2H5OH + O2
4. NG DNG
- Kh th
- Cng nghip
5. IU CH
1)Trong phng th nghim
o
KMnO4 t
2)Trong cng nghip
- Chng ct phn on khng kh lng
- in phn nc (c cht in li)
B-OZON
I-TNH CHT
1. Tnh cht vt l:
- Trng thi
- Mu sc
- Mi v
- T khi
- Nhit ha lng
- tan
2. Tnh cht ha hc:
* Tnh oxi ha rt mnh, mnh hn oxi.
a. Tc dng vi hu ht cc kim loi (tr Au, Pt)
2Ag + O3 Ag2O + O2
2Ag + O2 khng tc dng
b. Tc dng vi phi kim
C + O3
S + O3
c. Tc dng vi nhiu hp cht v c, hu c
CO + O3
FeO + O3
II-OZON TRONG T NHIN
Tng Ozon

3O 2

Tia tngoai

2O3

III-NG DNG
- Trong cng nghip
- Trong y hc
Trong i sng
B. BI TP
Cu1: Cho 855g dd Ba(OH)2 10% vo 200g dung dch H2SO4. Lc tch b kt ta. trung
ho nc lc ngi ta phi dng 125ml dung dch NaOH 25%, d= 1,28. Nng phn trm ca
dung dch H2SO4 l:
A. 63
B.25
C.49
D.83
Cu2: Cu hnh lp electron ngoi cng ca cc nguyn t nhm oxi l:
A. ns2np6
B. ns2np5
C.ns2np4
D. (n-1)d10ns2np6
Cu3: Trong cc hp cht ho hc s oxi ho thng gp ca lu hunh l:
A. 1,4,6
B. -2,0,+2,+4,+6
C.-2,0,+4,+6
D. kt qu khc
Cu4: Cho st kim loi tc dng vi oxi khng kh thu c hn hp cht rn A. Cho A tc dng
vi dd H2SO4 long d thu c dung dch B. Cho dd B tc dng vi dd NaOH d thu c kt
ta C , nung C trong khng kh ti khi lng khng i c chy rn D. D cha cht no sau
y:
A. Fe, FeO
B. FeO, Fe2O3
C. FeO
D.Fe2O3
Cu5: Dy cht no sau y gm cc cht ch c tnh oxi ho:
A. O3, H2SO4, F2 B. O2, Cl2, H2S
C. H2SO4, Br2, HCl
D. c A,B,C u ng
Cu6: H s ca phn ng:FeS + H2SO4 c, nng Fe2(SO4)3 + SO2 + H2O l:
A. 5,8,3,2,4 B. 4,8,2,3,4
C. 2,10,1,5,5
D. c A,B,C u sai
Cu7: H s ca phn ng: FeCO3 + H2SO4 Fe2(SO4)3 +SO2 + CO2 +H2O
A. 2,8,1,3,2,4
B. 4,8,2,4,4,4
C. 8,12,4,5,8,4
D.kt qu khc
Cu8: H s ca phn ng:P + H2SO4 H3PO4 + SO2 + H2O
A. 2, 3,2,1,2
B. 2,4,2,5,1 C. 2,5,2,5,2
D. kt qu khc
Cu9: Cho 11,2 g st tc dng vi dung dch H2SO4 c nng th s mol e nhng ca Fe cho
axit l:
A. 0,6
B. 0,4
C.0,2
D.0,8
Cu 10: Trong phn ng no cht tham gia l axit Sunfuric c?
A. H2SO4 + Na2SO3 Na2SO4 + SO2+ H2O
B. H2SO4 + Fe3O4 FeSO4 + Fe2(SO4)3+ H2O
C. H2SO4 + Fe(OH)2 Fe2(SO4)3+ SO2 + H2O
D. C Av C
Cu 11: Cho ln lt cc cht sau : MgO, NaI, FeS, Fe3O4, Fe2O3, FeO, Fe(OH)2, Fe(OH)3,
FeSO4, Fe2(SO4)3 tc dng vi dung dch H2SO4 c, nng. S phn ng oxi ho - kh l:
A. 9
B. 8
C. 7
D. 6
Cu12: khi gi lu hunh t phng (S) di ngy nhit phng, gi tr khi lng ring v
nhit nng chy thay i nh th no?
A.khi lnh ring tng v nhit nng chy gim
B. khi lng ring gim v nhit nng chy tng
C.C 2 u tng
D. khng i
Cu13: Nguyn tc pha long axit Sunfuric c l:
A.Rt t t axit vo nc v khuy nh
B. Rt t t nc vo axit v khuy nh
C. Rt t t axit vo nc v un nh
D. Rt t t nc vo axit v un nh
Cu14:Cho pthh: H2SO4 c, nng + KBr A+ B +C+ D. A, B, C,D l dy cht no sau y:
A.HBr, SO2, H2O, K2SO4
B. SO2, H2O, K2SO4, Br2
C. SO2, HbrO, H2O, K2SO4
D. , H2O, K2SO4, Br2, H2S
Cu15: Dy cht no sau y ch c tnh oxi ho?
A. O2, SO2, Cl2, H2SO4
B. S, F2, H2S, O3
C. O3, F2, H2SO4, HNO3
D.HNO3, H2S, SO2, SO3

Cu16: Dy cht no sau y va c tnh kh va c tnh oxi ho?

A. Cl2, SO2, FeO, Fe3O4
B.SO2, Fe2O3, Fe(OH)2, H2S
C. O2, Fe(OH)3, FeSO4, Cl2
D. Fe, O3, FeCO3, H2SO4
2Cu 17: Ion X c cu hnh electron lp ngoi cng l 3s23p6 . X l nguyn t no trong bng h
thng tun hon?
A. Oxi
B. Lu hunh
C.Selen
D.Telu
Cu18: Trong phng th nghim ngi ta iu ch oxi bng cch:
A. in phn nc
B. nhit phn Cu(NO3)2
C. chng ct phn on khng kh lng
D. nhit phn KClO3 c xc tc MnO2
Cu 19: Lu hunh si 4500C, nhit no lu hunh tn ti di dng pgn t n nguyn
t?
A. 4500C
B. 14000C.
C. . 17000C
D. nhit phng
Cu20: Cho pthh: SO2 + KmnO4 +H2OK2SO4 + MnSO4 +H2SO4
Sau khi cn bng h s ca cht oxi ho v cht kh l:
A. 5 v 2
B. 2 v 5
C. 2 v 2
D. 5 v 5
Cu21: ho tan st II sunfua vo dd HCl thu c kh A. t hon ton kh A thu c kh C c
mi hc. kh A,C ln lt l:
A. SO2, hi S
B. H2S, hi S
C. H2S, SO2
D. SO2, H2S
Cu22: Axit Sunfuric c phn ng vi cht no sau y (c un nng) sinh ra kh SO2? 1, Cu
2, NaOH 3, Al 4, C 5, ZnO 6, HCl 7, HI
A. 1,2,3,4,5
B.1,3,4,6,7
C. 1,3,4,7
D. tt c
Cu23: C 3 ng nghim ng cc kh SO2, O2, CO2. Dng phng php thc nghim no sau
y nhn bit cc cht trn:
A. Cho tng kh li qua ddCa(OH)2 d, dng u que m cn tn
B. Cho tng kh li qua dd H2S , dng u que m cn tn
C. Cho hoa hng vo cc kh , dng u que m con tn
D. B v C ng
Cu24: C 5 kh ng trong 5 l ring bit l Cl2, O2, HCl, O3, SO2. Hy chn trnh t tin hnh
no sau y phn bit cc kh:
A. Nhn bit mu ca kh, dng dung dch AgNO3,dung dch HNO3 c, dng u que m cn
tn , dung dch KI.
B. Dung dch H2S, dung dch AgNO3, dung dch KI
C. dung dch AgNO3, dung dch KI, dng u que m cn tn
D. Tt c u sai
Cu25: Cho 4,6g Na kim loi tc dng vi mt phi kim to mui v phi kim trong hp cht c s
oxi ho l -2 , ta thu c 7,8g mui, phi kim l phi kim no sau y:
A. Clo
B. flo
C. Lu hunh
D. kt qu khc
Cu26: C 3 bnh, mi bnh ng mt dung dch sau: HCl, H2SO3, H2SO4. Nu ch dng thm
mt cht lm thuc th th c th chn cht nop sau y phn bit cc dung dch trn :
A. Bari hiroxit
B. Natri hirxit C. Bari clorua
D. Av C u ng
Cu27: Cho hn hp gm Fe v FeS tc dgn vi dung dch HCl d , thu c 2,464 lt hn hp
kh X(ktc). Cho hn hp kh ny qua dung dch Pb(NO3)2 d thu 23,9g kt ta mu en . th tch
cc kh trong hn hp kh X l:
A. 0,224lt v 2,24 lt
B. 0,124lt v 1,24 lt
C. 0,224lt v 3,24 lt
D. Kt qu khc
Cu28: Hp th hon ton 12,8g SO2 vo 250ml dung dch NaOH 1M. Khi lng mui to
thnh sau phn ng l:
A. 15,6g v 5,3g
B. 18g v 6,3g
C. 15,6g v 6,3g
D. Kt qu khc
Cu29: ho tan 3,38g oleum X vo nc ngi ta phi dng 800ml dd KOH 0,1 M trung ho
dd X. Cng thc phn t oleum X l cng thc no sau y:
A. H2SO4.3SO3
B. H2SO4.2SO3
C. H2SO4.4SO3
D.H2SO4nSO3
Cu30: C 200ml dd H2SO4 98% (D = 1,84 g/ml). Ngi ta mun pha long th tch H2SO4 trn
thnh dung dch H2SO4 40% th th tch nc cn pha long l bao nhiu

A. 711,28cm3
B. 533,60 cm3
C. 621,28cm3
D. 731,28cm
Cu31: T 1,6 tn qung c cha 60% FeS2, ngi ta c th sn xut c khi lng axit
sunfuric l bao nhiu?
A. 1558kg
B. 1578kg
C. 1548kg
D. 1568kg
Cu 32: C mt loi qung pirit cha 96% FeS2. Nu mi ngy nh my sn xut 100 tn axit
sunfuric 98% th lng qung pirit trn cn dng l bao nhiu ?Bit hiu sut iu ch H2SO4 l
90%
A. 69,44 tn
B. 68,44tn
C. 67,44 tn
D. 70,44tn
Cu33: Ho tan mt oxit kim loi X ho tr II bng mt lng va ddH2SO4 10% ta thu c
dung dch mui c nng 11,97%. X l kim loi no sau y:
A. Ca
B. Fe
C. Ba
D. Mg
Cu34: Cho H2SO4 long d tc dng vi 6,660 hn hp 2 kim loi X v Y u ho tr II, ngi
ta thu c 0,1 mol kh, ng thi khi lng hn hp gim 6,5g. ho tan phn cn li bng
H2SO4 c nng ngi ta thy thot ra 0,16g kh SO2. X,Y l nhng kim loi no sau y:A. Hg
v Zn
B. Cu v Zn
C. Cu v Ca
D.Kt qu khc
Cu35: Cho 31,4g hn hp hai mui NaHSO3v Na2CO3vo 400g dung dchdd H2SO49,8%, ng
thi un nng ddthu c hn hp kh A c t khi hi so vi hir bng 28,66v mt ddX. C
%cc cht tan trong dd ln lt l:
A. 6,86% v 4,73% B.11,28% v 3,36% C. 9,28% v 1,36%
D. 15,28%v 4,36%
Cu36: Ho tan 9,875g mt mui hirrcacbonat (mui X)vo nc v cho tc dng vi mt
lng H2SO4 va , ri em c cn th thu c 8,25g mt mui sunfat trung ho khan. Cng
thc phn t ca mui Xl :
A.Ba(HCO3)2
B.NaHCO3
C.Mg(HCO3)2
D. NH4HCO3
Cu37: Cho 33,2g hn hp X gm Cu, Mg, Al tc dng va vi dung dch HCl thu c 22,4
lt kh ktc v cht rn khng tan B. Cho B ho tan hon ton vo dung dch H2SO4 c, nng
d thu c 4,48 lt kh SO2(ktc). Khi lng mi kim loi trong hn hp X ln lt l:
A. 13,8g; 7,6; 11,8
B. 11,8; 9,6; 11,8
C.12,8; 9,6; 10,8
D. kt qu khc
Cu38: Cho 12,8g Cu tc dng vi H2SO4 c nng d , kh sinh ra cho vo 200ml dung dch
NaOH 2M. Hi mui no c to thnh v khi lng l bao nhiu:
A. Na2SO3v 24,2g
B.Na2SO3 v 25,2g
C. NaHSO315g v Na2SO326,2g
D.Na2SO3 v 23,2g
Cu39: Ho tan hon ton 12,1 g hn hp Xgm Fe v kim loi M ho tr II trong dd H2SO4
long th thu c 4,48 lt kh H2(ktc) .Cng cho lng hn hp trn ho tan hon ton vo
H2SO4 c nng , d th thu c 5,6 lt kh SO2 (ktc). M l kim loi no sau y:
A. Ca
B. Mg
C.Cu
D. Zn
Cu40: Cho11,2g Fe v 2,4g Mg tc dng vi dung dch H2SO4 long d sau phn ng thu c
ddA v V lt kh H2 ktc. Cho ddNaOH d vo ddA thu c kt taB lc B nung trong khng
kh n khi lng khng i c mg cht rn.
1/ V c gi tr l:
A. 2,24lt
B. 3,36 lt
C. 5,6l
D. 4,48l
E. 6,72l
2/ khi lng cht rn thu dc l
A. 18g
B.20g
C.24g
D.36g
E.40
Cu41: phn bit 4 bnh mt nhn ng rieng bit cc kh CO2, SO3, SO2 vN2, mt hc sinh
d nh dng thuc th(mt cch trt t) theo 4 cch di y cch no ng:
A.ddBaCl2, ddBrom, ddCa(OH)2
B.ddCa(OH)2, ddBa(OH)2, ddbrom
C. qu tm m, dd Ca(OH)2, ddBr2
D. ddBr2, ddBaCl2, que m
Cu42:Cho phn ng ho hc sau: HNO3 + H2SNO+ S +H2O
H s cn bng ca phn ng l:
A. 2,3,2,3,4
B. 2,6,2,2,4
C. 2,2,3,2,4
D. 3,2,3,2,4
Cu43: Cho 2,52g mt kim loi tc dng v dd H2SO4 long to ra 6,84g mui sunfat. Kim loi
l:
A.Mg
B.Fe
C.Cr
D. Mn

Cu44:chokh CO i qua ng s cha 3,2g Fe2O3un nng, sau phn ng thu c hn hp rn

Xgm Fe v cc oxit. Ho tan hon ton X bng H2SO4c nng thu c ddY. C can ddY ,
lng mui khan thu c la:
A.4g
B.8g
C.20g
D.48g
Cu45: Ho tan hon ton 2,81g hn hp gm Fe2O3, MgO, ZnO trong 500ml
ddH2SO40,1M(va ).Sau phn ng ,c cn dung dch thu c mui khan c khi lng l:A.
6.81g
B. 4,81g
C.3,81g
D.5,81g
Cu 46:Ho tan hon ton 3,22g hn hp X gm Fe, Mg Zn bng mt lng va H2SO4 long
thy thot 1,344l H2 ktc v dung dch cha m gam mui. Gi tr ca m l:A. 10,27g
B.8.98
C.7,25g
D. 9,52g
Cu 47: Ho tan 0,54 g KL c ho tr n khng i trong 100 ml dd H2SO4 0,4 M . trung ho
lng H2SO4 d cn 200 ml dd NaOH 0,1 M . Vy ho tr n v KL Ml :
A. n=2 , Zn
B. n=2, Mg
C.n=1, K
D. n=3 ,Al
Cu 48: Cng mt lng R khi ho tan ht bng d2 HCl & H2SO4 ,n th lng SO2 gp 48 ln H2
sinh ra.Mt khc khi lng mui Clorua bng 63,5% khi lng mui sunpht .R l:
A. Mg
B. Fe
C. Al
D.Zn
CC BI TP TRONG CC THI I HOC CAO NG
THI TUYN SINH CAO NG NM 2007
Cu 1: Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dd H2SO4 20% thu c
ddmui trung ho c nng 27,21%. Kim loi M l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe =
56; Cu = 64; Zn = 65)
A. Cu.
B. Zn.
C. Fe.
D. Mg.
Cu 2: SO2 lun th hin tnh kh trong cc phn ng vi
A. H2S, O2, nc Br2.
B. dung dch NaOH, O2, dung dch KMnO4.
C. dung dch KOH, CaO, nc Br2.
D. O2, nc Br2, dung dch KMnO4.
Cu 3: Ha tan hon ton 3,22 gam hh X gm Fe, Mg v Zn bng mt lng va dd H2SO4
long, thu c 1,344 lt hiro ( ktc) v dd cha m gam mui. Gi tr ca m l:
A. 9,52.
B. 10,27.
C. 8,98.
D. 7,25.
THI TUYN SINH CAO NG NM 2008
Cu 1: Trng hp khng xy ra phn ng ha hc l
o
A. 3O2 + 2H2S t
2H2O + 2SO2.
B. FeCl2 + H2S FeS + 2HCl.
C. O3 + 2KI + H2O 2KOH + I2 + O2. D. Cl2 + 2NaOH NaCl + NaClO + H2O.
Cu 2: X l kim loi thuc PNC nhm II (hay nhm IIA). Cho 1,7 gam hn hp gm kim loi X
v Zn tc dng vi lng d dung dch HCl, sinh ra 0,672 lt kh H2 ( ktc). Mt khc, khi cho
1,9 gam X tc dng vi lng d dung dch H2SO4 long, th th tch kh hiro sinh ra cha n
1,12 lt ( ktc). Kim loi X l
A. Ba.
B. Ca.
C. Sr.
D. Mg.
Cu 3: Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c
khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng
hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt
kh O2 ( ktc). Gi tr ca V l
A. 2,80.
B. 3,36.
C. 3,08.
D. 4,48.
Cu 4: Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v
H2SO4 0,28M thu c dung dch X v 8,736 lt kh H2 ( ktc). C cn dung dch X thu c
lng mui khan l
A. 38,93 gam.
B. 103,85 gam.
C. 25,95 gam.
D. 77,86 gam.
THI TUYN SINH CAO NG NM 2009
Cu 1: phn bit CO2 v SO2 ch cn dng thuc th l
A. nc brom.
B. CaO.
C. dung dch Ba(OH)2.
D. dung dch
NaOH.

Cu 2: Cht kh X tan trong nc to ra mt dd lm chuyn mu qu tm thnh v c th c

dng lm cht ty mu. Kh X l
A. NH3.
B. CO2.
C. SO2.
D. O3.
THI TUYN SINH I HC, CAO NG NM 2007, Khi A
Cu 1: nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l b mt
nhn, ta dng thuc th l
A. Fe.
B. CuO.
C. Al.
D. Cu.
Cu 2: Ho tan 5,6 gam Fe bng dd H2SO4 long (d), thu c dd X. dd X phn ng va vi
V ml dd KMnO4 0,5M. Gi tr ca V l (cho Fe = 56):
A. 80.
B. 40.
C. 20.
D. 60.
Cu 3: Cho m gam hh Mg, Al vo 250 ml dd X cha hh axit HCl 1M v axit H2SO4 0,5M, thu
c 5,32 lt H2 ( ktc) v dd Y (coi th tch dd khng i). dd Y c pH l:
A. 1.
B. 6.
C. 7.
D. 2.
Cu 4: Ho tan hon ton 2,81 gam hh gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M
(va ). Sau phn ng, hh mui sunfat khan thu c khi c cn dd c khi lng l (cho H = 1,
O = 16, Mg = 24, S = 32, Fe = 56, Zn = 65)
A. 6,81 gam.
B. 4,81 gam.
C. 3,81 gam.
D. 5,81 gam.
THI TUYN SINH I HC, CAO NG NM 2008, khi A
Cu 1: Trong phng th nghim, ngi ta iu ch oxi bng cch
A. in phn nc.
B. nhit phn Cu(NO3)2.
C. nhit phn KClO3 c xc tc MnO2.
D. chng ct phn on khng kh lng.
Cu 2: X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi
dung dch Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe3+/Fe2+
ng trc Ag+/Ag)
A. Fe, Cu.
B. Cu, Fe.
C. Ag, Mg.
D. Mg, Ag.
THI TUYN SINH I HC, CAO NG NM 2009, khi A
Cu 1: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4
10%, thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l
A. 101,68 gam.
B. 88,20 gam.
C. 101,48 gam.
D. 97,80 gam.
Cu 2: Trng hp no sau y khng xy ra phn ng ho hc?
A. Sc kh Cl2 vo dung dch FeCl2. B. Sc kh H2S vo dung dch CuCl2.
C. Sc kh H2S vo dung dch FeCl2. D. Cho Fe vo dung dch H2SO4 long, ngui.
Cu 3: Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha
mt oxit) nng 0,95m gam. Phn trm khi lng PbS b t chy l
A. 95,00%.
B. 25,31%.
C. 74,69%.
D. 64,68%.
THI TUYN SINH I HC, CAO NG NM 2007, Khi B
Cu 1: Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t
CuFeS2 s
A. nhn 13 electron.
B. nhn 12 electron.
C. nhng 13 electron.
D. nhng 12 electron.
Cu 2: Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn
phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c (cho Fe = 56)
A. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.
B. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.
C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.
D. 0,12 mol FeSO4.
Cu 3: C th phn bit 3 dung dch: KOH, HCl, H2SO4 (long) bng mt thuc th l
A. giy qu tm.
B. Zn.
C. Al.
D. BaCO3.
Cu 4: Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng (d), thot ra 0,112
lt ( ktc) kh SO2 (l sn phm kh duy nht). Cng thc ca hp cht st l
A. FeS.
B. FeS2.
C. FeO
D. FeCO3.
THI TUYN SINH I HC, CAO NG NM 2008, khi B
Cu 1: Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh
(d). Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy

nht l Fe2O3 v hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi
lin h gia a v b l (bit sau cc phn ng, lu hunh mc oxi ho +4, th tch cc cht rn l
khng ng k)
A. a = 0,5b.
B. a = b.
C. a = 4b.
D. a = 2b.
Cu 2: Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c dng
rc ln thu ngn ri gom li l
A. vi sng.
B. ct.
C. mui n.
D. lu hunh.
THI TUYN SINH I HC, CAO NG NM 2009, khi B
Cu 1: Ho tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn
ng xy ra hon ton, thu c dung dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu
c kt ta Y. Nung Y trong khng kh n khi lng khng i, thu c cht rn Z l
A. hn hp gm BaSO4 v FeO.
B. hn hp gm Al2O3 v Fe2O3.
C. hn hp gm BaSO4 v Fe2O3.
D. Fe2O3.
Cu 2: Trn 100 ml dd hh gm H2SO4 0,05M v HCl 0,1M vi 100 ml dd hh gm NaOH 0,2M
v Ba(OH)2 0,1M, thu c dd X. dd X c pH l
A. 13,0.
B. 1,2.
C. 1,0.
D. 12,8.
Cu 3: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3
v AgNO3. Cht to ra lng O2 ln nht l
A. KClO3.
B. KMnO4.
C. KNO3.
D. AgNO3.
Cu 4: C cc th nghim sau:
(I)
Nhng thanh st vo dung dch H2SO4 long, ngui.
(II)
(II) Sc kh SO2 vo nc brom.
(III) Sc kh CO2 vo nc Gia-ven.
(IV) (IV) Nhng l nhm vo dung dch H2SO4 c, ngui.
S th nghim xy ra phn ng ho hc l :
A. 2.
B. 1.
C. 3.
D. 4.
Cu 5: Ha tan hon ton 20,88 gam mt oxit st bng dd H2SO4 c, nng thu c dd X v
3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dd X, thu c m gam mui sunfat
khan. Gi tr ca m l:
A. 52,2.
B. 54,0.
C. 58,0.
D. 48,4.
Cu 6: ng dng no sau y khng phi ca ozon?
A. Ty trng tinh bt, du n.
B. Cha su rng.
C. iu ch oxi trong phng th nghim.
D. St trng nc sinh hot.

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