Tuyen Chon Bai Tap Luyen Thi Dai Hoc Hoa Hoc

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012.
Mi
thc mc v bi xin lin h st 098.555.6536 hoc e-mail thanhtungk56bcnghh@gmail.com
CHUYN TUYN TP CC DNG

BI TP LUYN THI I HC, CAO
NG NM HC 2011-2012
1. CUNG CP Y CC DNG BI TP GIP HC SINH NH HNH
C CC PHNG PHP S DNG TRONG CC BI TON
2. CUNG CP MT S THI I HC HO HC HAY V KH
3. RT NGN THI GIAN N LUYN CA CC EM HC SINH
CHC CC EM MT K THI THNH CNG V T C C M
Chuyn bi tp luyn thi i hc nm hc 2011-2012. Ngi son: V Thanh Tng sv

khoa ho HKHTN-HQGHN
Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Chuyn 01: Cu to nguyn t v bng h thng tun hon

I/ Bi tp t lun
Bi1: Vit cu hnh e ca 26Fe, 29Cu , 35Br , 20Ca , 16S , Fe2+, Fe3+ , Cu2+, Br-. Xc nh v tr ca chng trong bng
h thng tun hon .Nu tnh cht ho hc c trng ca Fe, Cu, Ca, S, Br2, v vit phng trnh phn ng minh
ho
Bi 2: Cation R+ c cu hnh e lp ngoi cng l 3p6
-Vit cu hnh e v xc nh v tr ca chng trong bng h thng tun hon.
-Anion X- c cu hnh e ging R+ vit cu hnh e ca X.
Bi 3: Cho 3 ngyn t A, M, X c cu hnh e lp ngoi cng l ns1, ns2np1,ns2np5.
-Da vo cu hnh e hy xc nh v tr ca A, M,X trong bng HTTH bit n = 3
-Vit phng trnh phn ng gia cc cht trn vi H2O, dung dch NaOH, dung dch AlBr3
Bi 4: A v B l 2 nguyn t thuc hai chu k k tip nhau trong cng mt phn nhm chnh ca bng HTTH.
Tng s ht prton trong ht nhn nguyn t ca A v B l 32.
-Vit cu hnh e ca A v B v xc nh v tr ca chng trong bng h thng tun hon.
Bi 5: A v B l hai nguyn t thuc hai phn nhm chnh k tip nhau, B nhm V, trng thi n cht , A v
B phn ng vi nhau. Tng s ht proton trong ht nhn nguyn t ca A v B l 23. Vit cu hnh e ca A v B.
Xc nh v tr ca A, B trong bng HTTH
-Vit 5 phng trnh phn ng iu ch trc tip A t cc cht khc nhau.
Bi 6: Trong cc ng v sau y ca M th ng v no tha mn iu kin:
S proton : sntron =13: 15 . (55M, 56M , 57M, 58M ).
-Vit phng trnh phn ng ca M vi Cl2 , MCl3 , H2SO4, v cho MO tc dng vi HNO 3 c, KMnO4 trong
H2SO4 long, CO nhit cao.
Bi 7:Hp cht A c cng thc M2X. Tng s ht trong mt phn t A l 140, trong ht mang in nhiu hn
ht khng mang in l 44, s khi ca M+ ln hn s khi ca X2- l 23. Tng s ht trong M+ ln hn X2- l 31
-Vit cu hnh e ca M, M+, X, X2- v xc nh v tr ca M, X trong bng HTTH.
-Vit phng trnh phn ng ca M vi H2O, dung dch NaOH , dd CuCl2 dd NH4NO3, dd AlCl3
Bi 8: (H Quc Gia TPHCM 2001)
Nguyn t ca nguyn t A c tng s electron trong cc phn lp p l 7. Nguyn t ca nguyn t B c tng s
ht mang in nhiu hn s ht mang in ca A l 8. xc nh A v B
Bi 9: (H Hu 2001)
Cho 2 nguyn t A v B c s hiu nguyn t ln lt l 11 va13
Vit cu hnh e v cho bit v tr ca chng trong bng h thng tun hon
A c kh nng to ra ion A+ , B to ion B3+. Hy so snh bn knh ca A v A+ , B v B3+ gii thch.
Bi 10: (H Cn Th 2001)
Mt nguyn t R c tng s ht mang in l 34, trong ht khng mang in gp 1,833 ln s ht khng
mang in. Xc nh R v v tr R trong bng HTTH.
Bi 11: (H Xy Dng 2001)

khoa ho HKHTN-HQGHN

Nguyn t ca mt nguyn t X c tng s ht c bn l 82, trong s ht mang in nhiu hn s ht khng
mang in la 22 . Xc nh s hiu nguyn t , s khi v tn nguyn t . Vit cu hnh e ca nguyn t X v
cc ion to thnh t X.
Vit cc phng trnh phn ng ca X tc dng ln lt vi Fe2(SO4)3, HNO3 c nng.
Bi 12: (HSPKT TPHCM 2001)
Cation X3+ v anion Y2- u c cu hnh e phn lp ngoi cng l 2p6. Xc nh v tr ca X,Y trong bng
HTTH.
Bi 13: (H TCKT H Ni 2001)
Cho Fe c s hiu nguyn t l 26
Khng dng bng HTTH hy xc nh v tr ca Fe trong bng. Cho bit s oxi ho c th c ca Fe
Bi 14:( CSP Bn Tre 2003)
Mt kim loi M c s khi l 54. Tng s ht trong ion M2+ l 78
Xc nh s th t ca M trong bng HTTH v cho bit M l nguyn t no trong cc nguyn t sau y: 5424Cr,
54
54
54
25Mn,
26Fe,
27Co
Bi 15: (H khi B 2003)
Tng s ht p v n ,e trong hai nguyn t kim loi A, B l 142. Trong tng s ht mang in nhiu hn s ht
khng mang in l 42. S ht mang in ca nguyn t B nhiu hn nguyn t A l 12. Xc nh 2 kim loi A,
B Bit 11Na , 12Mg , 20Ca , 30Zn , 26Fe
Bi 16: Hp cht X to bi hai nguyn t A, B c khi lng phn t l 76. A, B c s oxi ho cao nht l +a,
+b v c s oxi ho m l -x, -y tho mn iu kin; a = x, b = 3y. XCTPH ca X bit rng trong X th A c s
oxi ho l +a .
Bi 17: (H QG H Ni 2001)
Hp cht Z c to bi hai nguyn t M, R c cng thc M aRb trong R chim 6,667% v khi lng. Trong
ht nhn nguyn t M c n = p + 4, trong ht nhn nguyn t R c n , = p, .Bit rng tng s ht trong phn t Z
bng 84, v a + b = 4. Tm cng thc phn t ca Z.
Bi 18: Hp cht X c cng thc phn t l RAB3 trong R chim 40% v khi lng. Trong ht nhn ca R,
A,B u c s proton bng s ntron . Tng s proton trong phn t X l 50, B l phi kim. Xc nh cng thc
phn t ca X
2
3
Bi 19: Tng s e trong anion AB l 42, B l phi kim, trong ht nhn ca A, B u c s ht proton bng s
ntron. Vit cu hnh e ca A,B v tnh s khi ca A, B.
Bi 20: Mt nguyn t ca mt nguyn t X ha hc c Z = 12,8.10 -19C, vit cu hnh e ca nguyn t v
cho bit v tr ca X trong bng HTTH, tnh cht ho hc c trng ca X l g? Vit phng btrinhf phn ng
minh ho.
II/ Bi tp trc nghim

Cu 1: Mt ion M3+ c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn s ht
khng mang in l 19. Cu hnh electron ca nguyn t M l
A. [Ar]3d54s1. B. [Ar]3d64s2.*
C. [Ar]3d64s1.
D. [Ar]3d34s2.
Cu 2: Cc cht m phn t khng phn cc l:
A. HBr, CO2, CH4.
B. Cl2, CO2, C2H2.* C. NH3, Br2, C2H4.
D. HCl, C2H2, Br2.
Cu 3:Cc kim loi X, Y, Z c cu hnh electron nguyn t ln lt l: 1s22s22p63s1; 1s22s22p63s2;
1s22s22p63s23p1. Dy gm cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l:
A. Z, Y, X*.
B. Y, Z, X.
C. Z, X, Y.
D. X, Y, Z.
khoa ho HKHTN-HQGHN

Cu 4:Mt nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52 v c s khi l 35. S hiu
nguyn t ca nguyn t X l
A. 17*.
B. 15.
C. 23.
D. 18.
Cu 5:Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s electron ca anion v
tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi ha duy nht. Cng thc XY l
A. NaF.
B. AlN.
C. MgO.
D. LiF.
Cu 6:Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca mt
nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t X v Y ln lt l
A. Al v P.
B. Fe v Cl.
C. Al v Cl*.
D. Na v Cl.
63
65
Cu
Cu
29
29
Cu 7:Trong t nhin, nguyn t ng c hai ng v l
v
. Nguyn t khi trung bnh ca ng l
65
29
Cu
63,54. Thnh phn phn trm tng s nguyn t ca ng v

l
A. 73%*.
B. 54%.
C. 50.
D. 27%.
Cu 8: Dy gm cc ion X+, Y- v nguyn t Z u c cu hnh electron 1s22s22p6 l:

A. K+, Cl-, Ar.
B. Na+, F-, Ne*.
C. Na+, Cl-, Ar.
D. Li+, F-, Ne.
2+
Cu 9: Anion X v cation Y u c cu hnh electron lp ngoi cng l -3s23p6. V tr ca cc
nguyn t trong bng tun hon cc nguyn t ha hc l:
A. X c s th t 17, chu k 3, nhm VIIA ;Y c s th t 20, chu k 4, nhm IIA *
B. X c s th t 18, chu k 3, nhm VIIA; Y c s th t 20, chu k 3, nhm IIA
C. X c s th t 17, chu k 4, nhm VIIA; Y c s th t 20, chu k 4, nhm IIA
D. X c s th t 18, chu k 3, nhm VIA; Y c s th t 20, chu k 4, nhm IIA
Cu 10:Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon cc nguyn t ho hc,
nguyn t X thuc.
A. chu k 3, nhm VIB.
B. chu k 4, nhm VIIIB*.C. chu k 4, nhm IIA. D. chu k 4, nhm VIIIA.
Cu 11:Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y
cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron
hn km nhau l 2. Nguyn t X, Y ln lt l
A. kh him v kim loi. B. kim loi v kim loi.C. phi kim v kim loi*. D. kim loi v kh him.
Cu 12:Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII), theo chiu tng
ca in tch ht nhn nguyn t th.
A. tnh kim loi tng dn, m in tng dn.
B. tnh kim loi tng dn, bn knh nguyn t gim dn.
C. m in gim dn, tnh phi kim tng dn.
D. tnh phi kim gim dn, bn knh nguyn t tng dn*.
Cu 13: Cho cc nguyn t 11M , 17X , 9Y v 19R m in ca cc nguyn t tng dn theo th t.
A. R < M < X < Y*. B. M < X < R < Y.
C. Y < M < X < R.
D. M < X < Y < R.
Cu 14: Bn knh nguyn t ca cc nguyn t: 3Li, 8O, 9F, 11Na c xp theo th t tng dn t tri sang phi
l
A. F, Li, O, Na.
B. F, Na, O, Li.
C. Li, Na, O, F.
D. F, O, Li, Na.*
Cu 15: Cho cc nguyn t: 19K , 7N, 14Si , 12Mg . Dy gm cc nguyn t c sp xp theo chiu gim dn
bn knh nguyn t t tri sang phi l:
A. K, Mg, N, Si.
B. Mg, K, Si, N.
C. K, Mg, Si, N*.
D. N, Si, Mg, K.
Cu 16: Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l:
A. P, N, O, F.*
B. P, N, F, O.
C. N, P, F, O.
D. N, P, O, F.
Cu 17: Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong oxit m R c ho tr
cao nht th oxi chim 74,07% v khi lng. Nguyn t R l
khoa ho HKHTN-HQGHN

A. As.
B. S.
C. N.*
D. P.
Cu 18: Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns2np4. Trong hp cht kh ca
nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm khi lng ca nguyn t X trong oxit cao nht
l
A. 40,00%.
B. 50,00%.
C. 27,27%.
D. 60,00%.
Cu 19: Hp cht trong phn t c lin kt ion l
A. NH4Cl.*
B. HCl.
C. NH3.
D. H2O.
Cu 20: Dy gm cc cht trong phn t ch c lin kt cng ho tr phn cc l:
A. HCl, O3, H2S.
B. H2O, HF, H2S*.
C. O2, H2O, NH3.
D. HF, Cl2, H2O.
Cu 21: Nguyn t ca nguyn t X c cu hnh electron 1s22s22p63s23p64s1, nguyn t ca nguyn t Y c cu
hnh electron 1s22s22p5. Lin kt ho hc gia nguyn t X v nguyn t Y thuc loi lin kt.
A. cho nhn.
B. kim loi.
C. cng ho tr.
D. ion*.
Cu 22: Pht biu no sau y l ng ?
A. th rn, NaCl tn ti di dng tinh th phn t. B. Photpho trng c cu trc tinh th nguyn t*.
C. Kim cng c cu trc tinh th phn t.
D. Nc thuc loi tinh th nguyn t.
Cu 23: Khi so snh NH3 vi NH4+, pht biu khng ng l:
A. Trong NH3 v NH4+, nit u c s oxi ha -3.
B. NH3 c tnh baz, NH4+ c tnh axit.
C. Trong NH3 v NH4+, nit u c cng ha tr 3. *
D. Phn t NH3 v ion NH4+ u cha lin kt cng ha tr.
Cu 24: Cu hnh electron ca ion Cu2+ v Cr3+ ln lt l :
A. [Ar]3d9 v [Ar]3d3 *.
B. [Ar]3d74s2 v [Ar]3d14s2.
9
1
2
C. [Ar]3d v [Ar]3d 4s .
D. [Ar]3d74s2 v [Ar]3d3.
Cu 25Pht biu no sau y l sai?
A. Tinh th nc , tinh th iot u thuc loi tinh th phn t.
B. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht.
C. Tt c cc tinh th phn t u kh nng chy v kh bay hi.*
D. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ha tr.
37
35
17 Cl
17 Cl
Cu 26 Trong t nhin clo c hai ng v bn:
chim 24,23% tng s nguyn t, cn li l
. Thnh
37
17 Cl
phn % theo khi lng ca
trong HClO4 l:
A. 8,92% *
B. 8,43%
C. 8,56%
D. 8,79%
Cu 27 Mc phn cc ca lin kt ho hc trong cc phn t c sp xp theo th t gim dn t tri sang
phi l:
A. HBr, HI, HCl
B. HI, HBr, HCl
C. HCl , HBr, HI *
D. HI, HCl ,
HBr
Chuyn 2: S in ly
1. (C-2008) Cho cc dung dch c cng nng : Na 2CO3 (1), H2SO4 (2), HCl (3), KNO3 (4). Gi tr pH ca
cc dung dch c sp xp theo chiu tng dn t tri sang phi l:
A. (3), (2), (4), (1)
B. (4), (1), (2), (3)
C. (1), (2), (3), (4)
D. (2), (3), (4),
(1)
khoa ho HKHTN-HQGHN

2. (C-2008) Cho dy cc cht: KOH, Ca(NO 3)2, SO3, NaHSO4, Na2SO3, K2SO4. S cht trong dy to thnh
kt ta khi phn ng vi dung dch BaCl2 l
A. 4
B. 6
C. 3
D. 2
3. (H B-2008) Cho dy cc cht: KAl(SO 4)2.12H2O, C2H5OH, C12H22O11 (saccaroz), CH3COOH, Ca(OH)2,
CH3COONH4. S cht in li l
A. 3
B. 4
C. 5
D. 2
4. (H B-2008) Trn 100ml dung dch c pH=1 gm HCl v HNO 3 vi 100ml dung dch NaOH nng a
(mol/l) thu c 200ml dung dch c pH=12. Gi tr ca a l (bit trong mi dung dch [H+][OH-]=10-14)
A. 0,15
B. 0,30
C. 0,03
D. 0,12
5. (H B-2008) Cho 0,1mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht:
A. K3PO4, K2HPO4
B. K2HPO4, KH2PO4
C. K3PO4, KOH
D.
H3PO4,
KH2PO4
6. (C-2007) Trong s cc dung dch: Na 2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa. Nhng dung
dch c pH>7 l
A. Na2CO3, C6H5ONa, CH3COONa
B. Na2CO3, NH4Cl, KCl
C. NH4Cl, CH3COONa, NaHSO4
D. KCl, C6H5ONa, CH3COONa
7. (H B-2008) Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03M c 2V ml dung dch
Y. Dung dch Y c pH l
A. 4
B. 3
C. 2
D. 1
8. (C-2008) Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc dng vi
lng d dung dch Ba(OH)2 to thnh kt ta l
a. 5
B. 4
C. 1
D. 3
9. (C-2008) Dung dch X cha cc ion: Fe3+, SO42, NH4+, Cl-. Chia dung dch X thnh 2 phn bng nhau:
- Phn 1 tc dng vi lng d dung dch NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta
- Phn 2 tc dng vi lng d dung dch BaCl 2, thu c 4,66 gam kt ta. Tng khi lng mui khan thu
c khi c cn dung dch X l (qu trnh c cn ch c nc bay hi)
A. 3,73 gam
B. 7,04 gam
C. 7,46 gam
D. 3,52 gam
10. (H A-2009) Nung 6,58 gam Cu(NO 3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c
4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300ml dung dch Y. Dung dch Y
c pH bng
A. 1
B. 4
C. 3
D. 2
11. (H A-2009) Dy gm cc cht u tc dng vi dung dch HCl long l:
A. KNO3, CaCO3, Fe(OH)3
B. Mg(HCO3)2, HCOONa, CuO
C. FeS, BaSO4, KOH
D. AgNO3, (NH4)2CO3, CuS
12. (H A-2009) Dung dch X cha hn hp gm Na 2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n
ht 200ml dung dch HCl 1M vo 100ml dung dch X, sinh ra V lit kh (ktc). Gi tr ca V l
A. 3,36
B. 1,12
C. 4,48
D. 2,24
13. (H A-2009) C nm dung dch ng ring bit trong nm ng nghim: (NH 4)2SO4, FeCl2, Cr(NO3)3,
K2CO3, Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng
nghim c kt ta l
A. 3
B. 5
C. 2
D. 4
14. (H B-2009) Trn 100ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100ml dung dch hn hp
gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l
A. 13,0
B. 1,2
C. 1,0
D. 12,8
15. (H B-2009) Cho cc phn ng ha hc sau:
(1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2
khoa ho HKHTN-HQGHN

(3) Na2SO4 + BaCl2
(4) H2SO4 + BaSO3
(5) (NH4)2SO4 + Ba(OH)2
(6) Fe2(SO4)3 + Ba(NO3)2
Cc phn ng u c cng 1 phng trnh ion rt gn l:
A. (1), (2), (3), (6)
B. (1), (3), (5), (6)
C. (2), (3), (4), (6)
D. (3), (4), (5),
(6)
16. (H B-2009) Cho dung dch X cha hn hp gm CH 3COOH 0,1M v CH3COONa 0,1M. Bit 250C, Ka
ca CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 250C l
A. 1,00
B. 4,24
C. 2,88
D. 4,76
17. (H A-2010) Dung dch X cha: 0,07 mol Na+; 0,02 mol SO42 v x mol OH-. Dung dch Y c cha ClO4-,
NO3- v y mol H+; tng s mol ClO4- v NO3- l 0,04. Trn X v Y c 100ml dung dch Z. Dung dch Z c pH
(b qua s in li ca nc) l
A. 2
B. 12
C. 13
D. 1
18. (H A-2010) Nh t t tng git n ht 30ml dung dch HCl 1M vo 100ml dung dch cha Na 2CO3 0,2M
v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l
A. 0,015
B. 0,020
C. 0,010
D. 0,030
19. (H A-2010) Cho dung dch X gm: 0,007 mol Na +; 0,003 mol Ca2+; 0,006 mol Cl-; 0,006 mol HCO3- v
0,001 mol NO3-. loi b ht Ca2+ trong X cn mt lng va dung dch cha a(g) Ca(OH)2. Gi tr ca a
l
A. 0,444
B. 0,222
C. 0,180
D. 0,120
20. (C-2010) Dy cc ion cng tn ti trong mt dung dch l
A. K+, Ba2+, OH-, ClB. Na+, K+, OH-, HCO3C. Ca2+, Cl-, Na+, CO32D. Al3+, PO43-, Cl-, Ba2+
21. (C-2010) Dung dch no sau y c pH>7?
A. Dung dch CH3COONa
B. Dung dch Al2(SO4)3
C. Dung dch NH4Cl
D. Dung dch NaCl
22. (H B-2007) Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2. Dy gm cc cht
u tc dng c vi dung dch Ba(HCO3)2 l
A. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2
B. HNO3, Ca(OH)2, KHSO4, Na2SO4
C. NaCl, Na2SO4, Ca(OH)2
D. HNO3, NaCl, Na2SO4
23. (H B-2007) Cho bn phn ng:
(1) Fe + 2HCl FeCl2 + H2
(2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O
(3) BaCl2 + Na2CO3 BaCO3 + 2NaCl
(4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4
S phn ng thuc loi phn ng axit-baz l
A. (1), (2)
B. (2), (3)
C. (2), (4)
D. (3), (4)
24. (H A-2007) Dung dch HCl v dung dch CH 3COOH c cng nng mol/l, pH ca hai dung dch tng
ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li)
A. y = 100x
B. y = x-2
C. y = 2x
D. y = x+2
25. (H A-2007) Cho dy cc cht: Ca(HCO 3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong
dy c tnh cht lng tnh l
A. 5
B. 4
C. 3
D. 2
Chuyn 3: kim loi, phi kim
Dng 1.
XC NH TN NGUYN T KIM LOI

khoa ho HKHTN-HQGHN

Bi 1. Ho tan hon ton 2 gam kim loi thuc nhm IIA vo dung dch HCl v sau c cn dung dch ngi
ta thu c 5,55 gam mui khan. Kim loi nhm IIA l:
A. Be.
B. Ba.
C. Ca.
D. Mg.
Bi 2. Nhit phn hon ton 3,5 gam mt mui cacbonat kim loi ho tr 2 thu c 1,96 gam cht rn. Mui
cacbonat ca kim loi dng l:
A. FeCO3.
B. BaCO3.
C. MgCO3.
D. CaCO3.
Bi 3. Ho tan hon ton 0,575 gam mt kim loi km vo nc. trung ho dung dch thu c cn 25 gam
dung dch HCl 3,65%. Kim loi ho tan l:
A. Li.
B. K.
C. Na.
D. Rb.
Bi 4. Lng kh clo sinh ra khi cho dung dch HCl c d tc dng vi 6,96 gam MnO2 oxi ho kim loi M
(thuc nhm IIA), to ra 7,6 gam mui khan. Kim loi M l:
A. Ba.
B. Mg.
C. Ca.
D. Be.
Bi 5. Ho tan 2,52 gam mt kim loi bng dung dch H2SO4 long d, c cn dung dch thu c 6,84 gam
mui khan. Kim loi l:
A. Mg.
B. Al.
C. Zn.
D. Fe.
Bi 6. Ho tan ht m gam kim loi M bng dung dch H2SO4 long, ri c cn dung dch sau phn ng thu c
5m gam mui khan. Kim loi M l:
A. Al.
B. Mg.
C. Zn.
D. Fe.
Bi 7: Ngm mt l kim loi c khi lng 50 gam trong dung dch HCl. Sau khi thu c 336 ml kh H2 (ktc)
th khi lng l kim loi gim 1,68%. Kim loi l
A. Zn.
B. Fe.
C. Ni.
D. Al.
Bi 8. Ho tan 1,3 gam mt kim loi M trong 100 ml dung dch H2SO4 0,3M. trung ho lng axit d cn
200 ml dung dch NaOH 0,1M. Xc nh kim loi M?
A. Al.
B. Fe.
C. Zn.
D. Mg.
Bi 9. Khi in phn mui clorua kim loi nng chy, ngi ta thu c 0,896 lt kh (ktc) anot v 3,12 gam
kim loi catot. Cng thc mui clorua in phn l
A. NaCl.
B. CaCl2.
C. KCl.
D. MgCl2.
Bi 10. Cho 19,2 gam kim loi (M) tan hon ton trong dung dch HNO3 long th thu c 4,48 lt kh NO
(ktc, sn phm kh duy nht). Kim loi (M) l:
A. Cu.
B. Zn.
C. Fe.
D. Mg.
Bi 11: t mt kim loi trong bnh cha kh Clo thu c 32,5 gam mui, ng thi th tch kh Clo trong
bnh gim 6,72 lt (ktc). Kim loi em t l:
A. Mg
B. Al
C. Fe
D. Cu
Bi 12: Ha tan hon ton 3,2 gam mt kim loi R ha tr II bng dung dch H2SO4 c nng thu c 1,12 lt
kh SO2 (ktc). Xc nh tn ca R.
Bi 13: Ha tan 1,35 gam mt kim loi R bng dung dch HNO3 long d thu c 2,24 lt hn hp kh X gm
NO v NO2. Xc nh tn ca R, bit t khi ca X so vi H2 bng 21.
Bi 14 : C 15,06 gam mt hn hp A gm Fe v mt kim loi R (ha t khng i) c chia thnh 2 phn
bng nhau.
-Phn 1: Ha tan ht vi dung dch HCl thu c 3,696 lt kh ktc.
- Phn 2: Ha tan ht vi dung dch HNO3 long thu c 3,36 lt (ktc) mt kh khng mu ha nu ngoi
khng kh duy nht. Tm R.
Bi 15: Kh 3,48 gam mt oxit ca kim loi R cn 1,344 lt H2 (ktc). Ton b lng kim loi to thnh c
cho tan ht trong dung dch HCl thu 1,008 lt H2 (ktc). Tm kim loi R v oxit ca n.

khoa ho HKHTN-HQGHN

Bi 16: Cho 10,5 gam hn hp gm bt Al v mt kim loi kim R vo H2O, sau phn ng thu c dung dch
A v 5,6 lt kh (ktc). Cho tt t dung dch HCl vo dung dch A thu c lng kt ta l ln nht. Lc ly
kt ta, sy kh, cn c 7,8 gam. Xc nh R.
Bi 17: Ha tan 4,95 gam hn hp A gm 2 kim loi Fe v R (c ha tr khng i) trong dung dch HCl d thu
c 4,032 lt kh H2 (ktc). Mt khc nu cng ha tan mt lng hn hp kim loi trn bng dung dch HNO3
d th c 1,344 lt hn hp kh B gm NO v N2O c t khi hi so vi H2 bng 20,25. Xc nh R.
Bi 18: Ha tan hon ton 19,2 gam kim loi R trong dung dch HNO3 d thu c 8,96 lt (ktc) hn hp kh
gm NO2 v NO c t l th tch 3:1. Xc nh R.
Bi 19: Hn hp A cha Fe v kim loi R c ha tr khng i, t l s mol ca R v Fe trong hn hp l 1:3.
Cho 19,2 gam hn hp A tan ht trong dung dch HCl thu c 8,96 lt kh H2. Cho 19,2 gam hn hp A tc
dng ht vi kh Clo th cn dng 12,32 lt kh Clo. Xc nh R.
Bi 20: Ha tan kim loi M vo HNO3 thu c dung dch A(khng c kh thot ra). Cho NaOH d vo dung
dch A thu c 2,24 lt kh (ktc) v 23,2g kt ta. Xc nh M.
A. Fe
B. Mg
C. Al
D. Ca
Bi 21 : Cho 17 gam hn hp gm 2 kim loi kim ng k nhau trong nhm IA tc dng ht vi H2O thu c
6.72 lt kh H2 (ktc) v dung dch Y.
a- Xc nh tn ca hai kim loi trn.
b- Tnh th tch dung dich HCl 2M cn dng trung ha ht dung dch Y
Bi 22: Cho 7,2 gam mui cacbonat ca hai kim loi k tip nhau trong nhm IIA ha tan ht trong dung dch
H2SO4 long thu c kh B. Cho ton b kh B hp th vo 450 ml dung dch Ba(OH)2 0,2M thu c 15,76
gam kt ta. Tm cng thc ca hai mui cacbonat ban u.
Bi 23: Cho 7,505 gam hp kim gm hai kim loi tc dng vi dung dch H2SO4 long, d thu c 2,24 lt kh
H2, ng thi cn 1,005 gam kim loi khng tan. Ha tan lmg kim loi cn li ny trong dung dch H2SO4
c, d th thu c 112ml SO2. Cc kh o ktc. Xc nh tn ca hai kim loi trong hp kim.
Bi 24: Ha Tan hon ton 3,6 gam hn hp gam mui cacbonat ca hai kim loi k tip nhau trong phn nhm
chnh nhm II trong dung dch HCl thu c kh B. Cho ton b kh B tc dng ht vi 3 lt dung dch Ca(OH)2
0,015M thu c 4 gam kt ta. Hai kim loi l:
A. Mg,Ca
B. Ca,Ba
C. Be,Mg
D. A v C u ng.
Bi 25: Ha tan hon ton 7,6 gam hn hp hai kim loi kim th lin tip nhau tc dng vi dung dch HCl d
thu c 5,6 lt kh (ktc). Hai kim loi ny l:
A. Be,Mg
B. Mg,Ca
C. Ca,Sr
D. Sr,Ba
Bi 26. Cho 9,1 gam hn hp hai mui cacbonat trung ho ca 2 kim loi kim 2 chu k lin tip tan hon
ton trong dung dch HCl d thu c 2,24 lt CO2(ktc). Hai kim loi l:
A. K v Cs.
B. Na v K.
C. Li v Na.
D. Rb v Cs.
Bi 27: Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm IIA tc dng ht vi dung dch
HCl (d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l (Mg= 24, Ca= 40, Sr= 87, Ba = 137)
A. Be v Mg.
B. Mg v Ca.
C. Sr v Ba.
D. Ca v Sr.
Bi 28: X l kim loi thuc phn nhm chnh nhm II (hay nhm IIA). Cho 1,7 gam hn hp gm kim loi X v
Zn tc dng vi lng d dung dch HCl, sinh ra 0,672 lt kh H2 ( ktc). Mt khc, khi cho 1,9 gam X tc
dng vi lng d dung dch H2SO4 long, th th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X
l
A. Ba.
B. Ca.
C. Sr.
D. Mg.
Dng 2
KIM LOI TC DNG VI DUNG DCH AXIT.
Bi 1. Cho 10 gam hn hp cc kim loi Mg v Cu tc dng ht vi dung dch HCl long d thu c 3,733 lit
H2(kc). Thnh phn % ca Mg trong hn hp l:
khoa ho HKHTN-HQGHN

A. 50%.
B. 35%.
C. 20%.
D. 40%.
Bi 2. Mt hn hp gm 13 gam km v 5,6 gam st tc dng vi dung dch axit sunfuric long d. Th tch kh
hidro (ktc) c gii phng sau phn ng l.
A. 2,24 lit.
B. 4,48 lit.
C. 6,72 lit.
D. 67,2 lit.
Bi 3. Cho 4,05 gam Al tan ht trong dung dch HNO3 thu V lt N2O (kc) duy nht. Gi tr V l
A. 2,52 lt.
B. 3,36 lt.
C. 4,48 lt.
D. 1,26 lt.
Bi 4: Hn hp X gm Fe v Cu, trong Cu chim 43,24% khi lng. Cho 14,8 gam X tc dng ht vi
dung dch HCl thy c V lt kh (ktc) bay ra. Gi tr ca V l
A. 1,12 lt.
B. 3,36 lt.
C. 2,24 lt.
D. 4,48 lt.
Bi 5: Ho tan hon ton 1,5 gam hn hp bt Al v Mg vo dung dch HCl thu c 1,68 lt H 2 (kc). Phn %
khi lng ca Al trong hn hp l
A. 60%.
B. 40%.
C. 30%.
D. 80%.
Bi 6: Ha tan 6,5 gam Zn trong dung dch axit HCl d, sau phn ng c cn dung dch th s gam mui khan
thu c l (Cho H = 1, Zn = 65, Cl = 35,5)
A. 20,7 gam.
B. 13,6 gam.
C. 14,96 gam.
D. 27,2 gam.
Bi 7. Ho tan hon ton 7,8 gam hn hp gm Mg, Al trong dung dch HCl d thy to ra 8,96 lt kh H2 (kc).
C cn dung dch sau phn ng thu c m gam mui khan. Gi tr ca m l
A. 18,1 gam.
B. 36,2 gam.
C. 54,3 gam.
D. 63,2 gam.
Bi 8: Cho 20 gam hn hp bt Mg v Fe tc dng ht vi dung dch HCl thy c 1 gam kh H 2 bay ra. Lng
mui clorua to ra trong dung dch l bao nhiu gam ?
A. 40,5g.
B. 45,5g.
C. 55,5g.
D. 60,5g.
Bi 9. Cho 11,9 gam hn hp gm Zn, Al tan hon ton trong dung dch H2SO4 long d thy c 8,96 lit kh
(kc) thot ra. Khi lng hn hp mui sunfat khan thu c l:
A. 44,9 gam. B. 74,1 gam. C. 50,3 gam. D. 24,7 gam.
Bi 10. Cho 1,86 gam hn hp Al v Mg tc dng vi dung dch HNO3 long d th thu c 560 ml lt kh N2O
(ktc, sn phm kh duy nht) bay ra. Khi lng mui nitrat to ra trong dung dch l:
A. 40,5 gam.
B. 14,62 gam.
C. 24,16 gam.
D. 14,26 gam.
Bi 11: Ho tan 6,4 gam Cu bng axit H 2SO4 c, nng (d), sinh ra V lt kh SO 2 (sn phm kh duy nht,
ktc). Gi tr ca V l
A. 4,48.
B. 6,72.
C. 3,36.
D. 2,24.
Bi 12: Ho tan 5,6 gam Fe bng dung dch HNO 3 long (d), sinh ra V lt kh NO (sn phm kh duy nht,
ktc). Gi tr ca V l
A. 6,72.
B. 4,48.
C. 2,24.
D. 3,36.
Bi 13: Cho 10 gam hn hp gm Fe v Cu tc dng vi dung dch H2SO4 long (d). Sau phn ng thu c
2,24 lt kh hiro ( ktc), dung dch X v m gam cht rn khng tan. Gi tr ca m l (Cho H = 1, Fe = 56, Cu =
64)
A. 6,4 gam.
B. 3,4 gam.
C. 5,6 gam.
D. 4,4 gam.
Bi 14: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt
kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn
ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 15,6.
B. 10,5.
C. 11,5.
D. 12,3.
Bi 15. Cho m gam Fe vo dung dch HNO3 ly d ta thu c 8,96 lit(kc) hn hp kh X gm 2 kh NO v
NO2 c t khi hi hn hp X so vi oxi bng 1,3125. Gi tr ca m l
A. 0,56 gam.
B. 1,12 gam.
C. 11,2 gam.
D. 5,6 gam.
Bi 16Cho 60 gam hn hp Cu v CuO tan ht trong dung dch HNO3 long d thu c 13,44 lit kh NO (kc,
sn phm kh duy nht). Phn % v khi lng ca Cu trong hn hp l:
khoa ho HKHTN-HQGHN

A. 69%.
B. 96%.
C. 44%
D. 56%.
Bi 17. Cho 2,8 gam hn hp bt kim loi bc v ng tc dng vi dung dch HNO3 c, d th thu c 0,896
lt kh NO2 duy nht ( ktc). Thnh phn phn trm ca bc v ng trong hn hp ln lt l:
A. 73% ; 27%.
B. 77,14% ; 22,86%
C. 50%; 50%.
D. 44% ; 56%
Bi 18: Ho tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO 3 c, nng thu c 1,344 lt
kh NO2 (sn phm kh duy nht, ktc). Phn trm v khi lng ca Cu trong hn hp X l
A. 21,95%.
B. 78,05%.
C. 68,05%.
D. 29,15%.
Bi 19. Cho a gam bt Al tc dng va vi dung dch HNO3 long thu c dung dch A ch cha mt mui
duy nht v 0,1792 lt (ktc) hn hp kh NO, N2 c t khi hi so H2 l 14,25. Tnh a ?
A. 0,459 gam.
B. 0,594 gam.
C. 5,94 gam.
D. 0,954 gam.
Bi 20: Cho hn hp A gm Cu v Mg vo dung dch HCl d thu c 5,6 lt kh (kc) khng mu v mt cht
rn khng tan B. Dng dung dch H2SO4 c, nng ho tan cht rn B thu c 2,24 lt kh SO2 (kc). Khi
lng hn hp A ban u l:
A. 6,4 gam.
B. 12,4 gam.
C. 6,0 gam.
D. 8,0 gam.
Bi 21: Cho a gam hn hp Mg v Al vo 250 ml dung dch X cha 2 axit : HCl 1M v H 2SO4 0,5M c dung
dch B v 4,368 lt H2 (ktc) th trong dung dch B s:
A. D axit
B. Thiu axit
C. Dung dch mui D. Tt c u sai
Bi 22: Cho 2,06 gam hn hp gm Fe, Al, Cu tc dng vi dung dch HNO 3 long d thu c 0,896 lt NO
duy nht ktc. Khi lng mui NO3- sinh ra l :
A. 9,5 gam
B. 7,44 gam
C. 7,02 gam
D. 4,54 gam
Bi 23: Cho 2,16 gam Mg tc dng vi dung dch HNO 3 (d). Sau khi phn ng xy ra hon ton thu c
0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi
dung dch X l
A. 8,88 gam. B. 13,92 gam.
C. 6,52 gam. D. 13,32 gam.
Bi 24: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh
ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt
thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 11,5.
B. 10,5.
C. 12,3.
D. 15,6.
Bi 25: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol
Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO)
A. 1,0 lt.
B. 0,6 lt.
C. 0,8 lt.
D. 1,2 lt.
Bi 26: Chia hn hp 2 kim loi c ho tr khng i lm 2 phn bng nhau. Phn 1 tan ht trong dung dch HCl
to ra 1,792 lt H2 (ktc). Phn 2, nung trong oxi thu c 2,84 gam hn hp oxit. Khi lng hn hp 2 kim
loi ban u l:
A. 2,4 gam
B. 3,12 gam
C. 2,2 gam
D. 1,8 gam
Bi 27: Cho m gam Cu tc dng ht vi dung dch HNO 3 thu c 1,12 lt (ktc) hn hp kh NO v NO 2 c t
khi so vi H2 l 16,6 . Gi tr ca m l:
A. 3,9 gam
B. 4,16 gam
C. 2,38 gam
D. 2,08 gam
Bi 28: Cho hn hp X gm Mg v Fe vo dung dch axit H 2SO4 c, nng n khi cc phn ng xy ra hon
ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l
A. MgSO4 v FeSO4.
B. MgSO4.
C. MgSO4 v Fe2(SO4)3.
D. MgSO4, Fe2(SO4)3 v FeSO4
Bi 29: Cho 6,72 gam Fe vo dung dch cha 0,3 mol H 2SO4 c, nng (gi thit SO2 l sn phm kh duy
nht). Sau khi phn ng xy ra hon ton, thu c (cho Fe = 56)
A. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.
B. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.
C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.
D. 0,12 mol FeSO4.
khoa ho HKHTN-HQGHN

Bi 30: Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt ( ktc) hn
hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng
19. Gi tr ca V l:
A. 2,24.
B. 4,48.
C. 5,60.
D. 3,36.
Bi 31: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4
0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l
A. 1.
B. 6.
C. 7.
D. 2.
Bi 32: Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu c
dung dch ch cha mt cht tan v kim loi d. Cht tan l
A. Cu(NO3)2.
B. HNO3.
C. Fe(NO3)2.
D. Fe(NO3)3.
Bi 33: Thc hin hai th nghim:
1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO.
2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO.
Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l
A. V2 = V1.
B. V2 = 2V1.
C. V2 = 2,5V1.
D. V2 = 1,5V1.
Bi 34: Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch
H2SO4 long, thu c 1,344 lt hiro ( ktc) v dung dch cha m gam mui. Gi tr ca m l (Cho H = 1;
O = 16; Mg = 24; S = 32; Fe = 56; Zn = 65)
A. 9,52.
B. 10,27.
C. 8,98.
D. 7,25
Bi 35: Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20%, thu c
dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn trm ca MgCl2 trong dung dch
Y l (Cho H = 1; Mg = 24; Cl = 35,5; Fe = 56)
A. 24,24%.
B. 11,79%.
C. 28,21%.
D. 15,76%.
Bi 36: Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X (sn phm kh duy nht,
ktc). Kh X l
A. N2O.
B. NO2.
C. N2.
D. NO.
Bi 37: Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v H2SO4 0,28M
thu c dung dch X v 8,736 lt kh H2 ( ktc). C cn dung dch X thu c lng mui khan l
A. 38,93 gam.
B. 103,85 gam.
C. 25,95 gam.
D. 77,86 gam.
Bi 38 Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau khi
cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A. 0,746.
B. 0,448.
C. 1,792.
D. 0,672.
Bi 39: Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu c
0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l
A. 8,88 gam. B. 13,92 gam.
C. 6,52 gam. D. 13,32 gam.
Bi 40: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt
kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn
ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 11,5.
B. 10,5.
C. 12,3.
D. 15,6.
Bi 41: Cho 2,7 g hh Mg, Al, Cu tan vo dd HNO3 d to ra 0,02 mol NO, 0,08 mol NO2.
Khi lng mui thu c l:
A. 6,42 g
B. 8,68 g
C. 11,38 g
D. 7,66
Bi 42: Ha tan ht cng mt Fe trong dung dch HNO3 d thy sinh ra hn hp kh cha 0,03 mol NO2 v
0,02 mol NO. Khi lng Fe b ha tan bng bao nhiu gam?
A. 0,56 gam
B. 1,12 gam
C. 1,68 gam
D. 2,24 gam
khoa ho HKHTN-HQGHN

BI TP IN PHN
Bi 1. Khi cho dng in mt chiu I=2A qua dung dch CuCl 2 trong 10 pht. Khi lng ng thot ra catod
l
A. 40 gam.
B. 0,4 gam.
C. 0,2 gam.
D. 4 gam.
Bi 2. in phn n ht 0,1 mol Cu(NO3)2 trong dung dch vi in cc tr, th sau in phn khi lng dung
dch gim bao nhiu gam?
A. 1,6 gam.
B. 6,4 gam.
C. 8,0 gam.
D. 18,8 gam.
Bi 3. in phn dng in cc tr dung dch mui sunfat kim loi ho tr 2 vi cng dng in 3A. Sau
1930 giy thy khi lng catot tng 1,92 gam. Mui sunfat in phn l
A. CuSO4.
B. NiSO4.
C. MgSO4.
D. ZnSO4.
Bi 4. in phn hon ton 1 lt dung dch AgNO3 vi 2 in cc tr thu c mt dung dch c pH= 2. Xem
th tch dung dch thay i khng ng k th lng Ag bm catod l:
A. 0,54 gam.
B. 0,108 gam.
C. 1,08 gam.
D. 0,216 gam.
Bi 5: in phn 200 ml dung dch mui CuSO4 trong thi gian, thy khi lng dung dch gim 8 gam. Dung
dch sau in phn cho tc dng vi dd H2S d thu c 9,6g kt ta en. Nng mol ca dung dch CuSO4
ban u l
A. 1M.
B.0,5M.
C. 2M.
D. 1,125M.
Bi 6: in phn dung dch AgNO3 (in cc tr) trong thi gian 15 pht, thu c 0,432 gam Ag catot. Sau
lm kt ta ht ion Ag+ cn li trong dung dch sau in phn cn dng 25 ml dung dch NaCl 0,4M.
Cng dng in v khi lng AgNO3 ban u l (Ag=108)
A. 0,429 A v 2,38 gam.
B. 0,492 A v 3,28 gam.
C. 0,429 A v 3,82 gam.
D. 0,249 A v 2,38 gam.
Bi 7: in phn 200 ml dung dch AgNO3 0,4M (in cc tr) trong thi gian 4 gi, cng dng in l
0,402A. Nng mol/l cc cht c trong dung dch sau in phn l
A. AgNO3 0,15M v HNO3 0,3M.
B. AgNO3 0,1M v HNO3 0,3M.
C. AgNO3 0,1M
D. HNO3 0,3M
Bi 8: Sau mt thi gian in phn 200 ml dung dch CuCl 2 thu c 1,12 lt kh X ( ktc). Ngm inh st vo
dung dch sau in phn, khi phn ng xy ra hon ton thy khi lng inh st tng thm 1,2 gam. Nng
mol ca CuCl2 ban u l
A. 1M.
B. 1,5M.
C. 1,2M.
D. 2M.
Bi 9: in phn bng in cc tr dung dch mui sunfat ca kim loi ho tr II vi dng in c cng 6A.
Sau 29 pht in phn thy khi lng catot tng ln 3,45 gam. Kim loi l:
A. Zn.
B. Cu.
C. Ni.
D. Sn.
Bi 10: in phn 400 ml dung dch CuSO4 0,2M vi cng dng in 10A trong 1 thi gian thu c 0,224
lt kh (kc) anot. Bit in cc dng l in cc tr v hiu sut in phn l 100%. Khi lng catot tng
l
A. 1,28 gam.
B. 0,32 gam.
C. 0,64 gam.
D. 3,2 gam.
Bi 11: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra
A. s kh ion Cl-.
B. s oxi ho ion Cl-. C. s oxi ho ion Na+. D. s kh ion Na+.
Bi 12: in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl 2 0,1M v NaCl 0,5M (in cc tr,
hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c
kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05.
B. 2,70.
C. 1,35.
D. 5,40
Bi 13: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al catot v
67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo
dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l
khoa ho HKHTN-HQGHN

A. 108,0.
B. 75,6.
C. 54,0.
D. 67,5.
Bi 14: in phn 100ml dung dch cha ng thi HCl0,1M v NaCl 0,2M vi in cc tr v mng ngn xp
ti khi anot tot ra 0,224 lt kh (KTC) th ngng in phn. Coi th tch dung dch khng thay i, dung
dch sau in phn c pH l:
A. 6
B. 7
C. 12
D. 13
Bi 15: Dung dch X cha HCl, CuSO4 v Fe2(SO4)3. Ly 400ml dung dch X em in phn (in cc tr) vi
cng dng in I = 7,72 A n khi Catot c 0,08 mol Cu th dng li. Khi anot c 0,1 mol cht kh
bay ra. Thi gian in phn v nng mol/l ca Fe2+ trong dung dch sau phn ng l
A. 2300s v o,1M
B. 2500s v 0,1M C. 2300s v 0,15M
D. 2500s v 0,15M
Bi 16: i n phn (vi i n cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau m t thi gian thu c
dung dch Y vn cn mu xanh, c khi lng gim 8g so vi dung dch ban u. Cho 16,8g b t Fe vo Y, sau
khi cc phn ng xy ra hon ton, thu c 12,4g kim loi. Gi tr ca x l
A. 2,25
B. 1,5
C. 1,25
D. 3,25
Bi 17: Tin hnh in phn dung dch CuSO 4 mt hti gian, khi ngng in phn Catt xut hin 3,2 gam kim
loi Cu. Tnh th tch kh KTC thu c Anot.
Bi 18: Tin hnh in phn 200ml dung dch CuSO4 vi dng in c I = 1,93A cho n khi Catt xut hin
kh th thi gian cn l 250 giy. Tnh nng mol/l ca dung dch CuSO4 v th tch kh thu c Ant.
Bi 19: Tin hnh in phn dung dch CuCl 2 bng in graphit vi thi gian l 16 pht thy Catt xut hin
0,554 gam kim loi. Tnh cng dng in dng tin hnh in phn.
Bi 20: in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu Catt v lng
kh X Ant. Hp th hon ton lng kh X trn vo 200ml dung dch NaOH ( nhit thng). Sau phn
ng nng dung dch NaOH trong dung dch cn li 0,05M (gi thit th tch dung dch khng thay i). Tnh
nng mol/l ca dung dch NaOH ban u.
Bi 21: in phn 0,8 lt dung dch hn hp HCl, Cu(NO 3)2 vi in cc tr, cng dng in I = 2,5A, thi
gian t giy c mt kh duy nht ant c th tch 3,136 lt (KTC). Dung dch sau khi in phn phn ng
va vi 550ml dung dch NaOH 0,8M c 1,96 gam kt ta. Tnh thi gian in phn v nng mol/l ca
cc cht trong dung dch ban u.
Bi 22: C hai bnh in phn mc ni tip: Bnh 1 cha dug dch AgNO 3, bnh 2 ng dung dch RSO4. Tin
hnh in phn mt thi gian ri ngng th thy Catt bnh 1 tng 5 gam cn Catt bnh 2 tng 1,48 gam. Tm
R.
Bi 23: C hai bnh in phn mc ni tip: Bnh 1 cha 10ml dung dch CuSO 4 0,1M; bnh 2 cha 100ml dung
dch NaOH 0,1M. Tin hnh in phn c mng ngn xp cho n khi bnh 2 to ra dung dch c pH = 13 th
ngng in phn. Gi s th tch dung dch 2 bnh khng thay i. Tnh nng mol/l ca Cu 2+ trong dung
dch sau in phn.
Bi 23: in hn dung dch cha a mol CuSO 4 v b mol NaOH (in cc tr, mng ngn xp). Xc nh iu
kin v mi lin quan ca a v b dung dnh sau in phn lm Phenolphtalein chuyn sang mu hng.
Bi 24: Cho dng in mt chiu, cng khng i, qua hai bnh in phn mc ni tip: Bnh 1 cha 100ml
dung dch CuSO4 0,01M; bnh 2 cha 100ml dung dch AgNO 3 0,01M. Tin hnh in phn trong thi gian 500
giy th bnh 2 bt u xut hin kh Catot. Tnh th tch kh (KTC) xut hin Catt bnh 1.
Bi 25: Tin hnh in phn c mng ngn xp, hai in c tr 500ml dung dch hn hp HCl 0,02M v NaCl
0,2M. Sau khi anot thot ra 0,448 lt kh (KTC) th ngng in phn. Gi s th tch dung dch khng thay
i. Tnh pH ca dung dch thu c sau in phn.
Bi 26: Tin hnh in phn 150 ml dung dch CuSO 4 1M vi hai in cc tr. Sau mt thi gian, khi ngng
in phn thy khi lng dung dch gim 8 giam. Tnh ngng mol/l ca cc cht trong dung dch thu c
sau phn ng.
khoa ho HKHTN-HQGHN

Bi 27: in phn nng chy a gam mui G to bi kim loi R v halogen X, ta thu c 0,96 gam kim loi R
Catot v 0,04 mol kh X Anot. Mt khc ha tan hon ton a gam mui G vo nc, sau cho tc dng vi
dung dch AgNO3 d thu c 11,48 gam kt ta. Xc nh X.
Bi 28: in phn vi in cc tr dung dch AgNO3 trong thi gian 14 pht 15 giy, cng dng in 0,8A.
a. Tnh khi lng Ag iu ch c.
b. Tnh th tch kh (KTC) thu c Catt.
Bi 29: in phn dung dch CuSO4 vi in cc ng (ng knh 1mm, nhng su trong dung dch 4cm),
cng dng in 1,2A. Tnh thi gian ton b phn anot nhng vo dung dch bi ha tan ht.
Bi 30: in pn 200ml dung dch hn hp dung dch gm CuSO 4 0,1M v MgSO4 0,05M cho khi bt u
xut hin kh th ngng in phn. Tnh khi lng kim loi bm vo Catot ca bnh in phn.
BI TON KIM LOI TC DNG VI
DUNG DCH MUI
Bi 1. Ngm mt inh st sch trong 200 ml dung dch CuSO4 sau khi phn ng kt thc, ly inh st ra khi
dung dch ra nh lm kh nhn thy khi lng inh st tng thm 0,8 gam. Nng mol/lt ca dung dch
CuSO4 dng l:
A. 0,25M.
B. 0,4M.
C. 0,3M.
D. 0,5M.
Bi 2. Ngm mt l km vo dung dch c ho tan 8,32 gam CdSO4. Phn ng xong ly l km ra khi dung
dch, ra nh, lm kh th thy khi lng l km tng thm 2,35% so vi khi lng l km trc phn ng.
Khi lng l km trc phn ng l:
A. 80gam
B. 60gam
C. 20gam
D. 40gam
Bi 3. Nhng mt inh st c khi lng 8 gam vo 500ml dung dch CuSO4 2M. Sau mt thi gian ly inh st
ra cn li thy nng 8,8 gam. Nng mol/l ca CuSO4 trong dung dch sau phn ng l:
A. 0,27M
B. 1,36M
C. 1,8M
D. 2,3M
Bi 4: Ngm l km trong dung dch cha 0,1 mol CuSO4. Phn ng xong thy khi lng l km:
A. tng 0,1 gam.
B. tng 0,01 gam.
C. gim 0,1 gam.
D. khng thay i.
Bi 5: Ho tan hon ton 28 gam bt Fe vo dung dch AgNO3 d th khi lng cht rn thu c l
A. 108 gam.
B. 162 gam.
C. 216 gam.
D. 154 gam.
Bi 6: Nhng 1 thanh nhm nng 50 gam vo 400ml dung dch CuSO 4 0,5M. Sau mt thi gian ly thanh nhm
ra cn nng 51,38 gam. Hi khi lng Cu thot ra l bao nhiu?
A. 0,64gam.
B. 1,28gam.
C. 1,92gam.
D. 2,56gam.
Bi 7: Ngm mt l Fe trong dung dch CuSO 4. Sau mt thi gian phn ng ly l Fe ra ra nh lm kh, em
cn thy khi lng tng thm 1,6 gam. Khi lng Cu bm trn l Fe l bao nhiu gam?
A. 12,8 gam.
B. 8,2 gam.
C. 6,4 gam.
D. 9,6 gam.
Bi 8: Ngm mt l km trong 100 ml dung dch AgNO3 0,1M. Khi phn ng kt thc, khi lng l km tng
thm
A. 0,65 gam.
B. 1,51 gam.
C. 0,755 gam.
D. 1,3 gam.
Bi 9: Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO 4. Sau khi phn ng kt thc, lc b
phn dung dch, thu c m gam bt rn. Thnh phn % theo khi lng ca Zn trong hn hp ban u l:
A. 12,67%
B. 82,2%
C. 85,3%
D. 90,27%
Bi 10: Cho 16 gam Cu vo dung dch cha 0,075 mol Cu(NO3)2 v 0,4 mol HCl thy c V1 lt kh NO thot ra
v dung dch A. Cho thm H2SO4 long, d vo dung dch A thy thot ra V2 lt kh NO na. Cc kh o
KTC. Gi tr V1 v V2 l:
A. V1= 1,12 v V2= 2,24
B. V1=1,12 v V2=3,36
C. V1=V2=2,24
D. V1=2,24 v V2=1,12
khoa ho HKHTN-HQGHN

Bi 11: Cho hn hp bt Al, Fe vi dung dch cha Cu(NO3)2 v AgNO3. Sau khi cc phn ng xy ra
hon ton, thu c hn hp rn gm ba kim loi l:
A. Fe, Cu, Ag.
B. Al, Cu, Ag.
C. Al, Fe, Cu.
D. Al, Fe, Ag.
Bi 12: Ho tan hon ton Fe3O4 trong dung dch H2SO4 long (d) c dung dch X1. Cho lng d bt Fe
vo dung dch X1 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c dung dch
X2 cha cht tan l
A. Fe2(SO4)3 v H2SO4.
B. FeSO4.
C. Fe2(SO4)3.
D. FeSO4 v H2SO4.
Bi 13: Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi
cc phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l (bit th t trong dy th
in ho: Fe3+/Fe2+ ng trc Ag+/Ag)
A. 59,4.
B. 64,8.
C. 32,4.
D. 54,0.
Bi 14: Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO
(sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l
A. 1,92.
B. 3,20.
C. 0,64.
D. 3,84.
Bi 15: Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu c
dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l
A. Fe(NO3)3 v Zn(NO3)2.
B. Zn(NO3)2 v Fe(NO3)2.
C. AgNO3 v Zn(NO3)2.
D. Fe(NO3)2 v AgNO3
Bi 16: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M
v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy
nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu
ca V l
A. 360.
B. 240.
C. 400.
D. 120.
Bi 17: Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu 2+ v 1 mol Ag+ n khi cc
phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi tr no
ca x tho mn trng hp trn?
A. 1,8.
B. 1,5.
C. 1,2.
D. 2,0.
Bi 18: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M. Sau
khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l
A. 2,80.
B. 2,16.
C. 4,08.
D. 0,64
Bi 19: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO 3)2 0,2M v H2SO4 0,25M. Sau khi cc
phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht,
ktc). Gi tr ca m v V ln lt l
A. 10,8 v 4,48.
B. 10,8 v 2,24.
C. 17,8 v 2,24.
D. 17,8 v 4,48
Bi 20: Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO 3)2 0,2M v AgNO3
0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi to
thnh u bm ht vo thanh st). Khi lng st phn ng l
A. 1,40 gam.
B. 2,16 gam.
C. 0,84 gam.
D. 1,72 gam
Bi 21: Ho tan hon ton 24,4 gam hn hp gm FeCl 2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt
lng nc (d), thu c dung dch X. Cho dung dch AgNO 3 (d) vo dung dch X, sau khi phn ng xy ra
hon ton sinh ra m gam cht rn. Gi tr ca m l
A. 57,4.
B. 28,7.
C. 10,8.
D. 68,2.
Bi 22: Nhng mt thanh kim loi R ho tr II vo dung dch cha a mol CuSO4, sau mt thi gian thy khi
lng thanh kim loi gim 0,05%. Cng thanh kim loi trn nhng vo dung dch cha a mol Pb(NO3)2 th khi
lng thanh kim loi tng 7,1%. Kim loi R l:
A. Mg
B.Fe
C.Zn
D.Ni
khoa ho HKHTN-HQGHN

Bi 23: Cho a gam bt Fe phn ng vi hn hp gm 14,6 gam HCl v 25,6 gam CuSO4, sau khi phn ng xy
ra hon ton thu c hn hp kim loi c khi lng 0,7a gam v x lt kh (KTC). Gi tr ca a v X l:
A. 33.067 v 22.4
B. 3.3067 v 4.48
C. 3.3067 v 2,24
D. 33.067 v 4,48
Bi 24: Cho 3,08 gam Fe vo 150 ml dung dch AgNO3 1M, lc k cho n khi phn ng xy ra hon ton thu
c m gam cht rn. Gi tr ca m l:
A. 11.88
B. 16,2
C. 18,2
D. 17,96
Bi 25: Cho 19,2 gam Cu vo 1 lt dung dch hn hp gm H2SO4 0,1M v KNO3 0,2M thu c V lt kh NO
duy nht (KTC). Gi tr ca V l:
A. 1.12
B. 2.24
C. 4.48
D. 3.36
Bi 26: Nhng mt thanh graphit c ph mt lp kim loi ho tr II vo dung dch CuSO4 d. Sau khi phn
ng xy ra hon ton thy khi lng thanh graphit gim 0,24 gam. Cng thanh graphit trn nhng vo dung
dch AgNO3 d th sau khi phn ng xy ra hon ton khi lng thanh graphit tng 0,52 gam. Kim loi ho tr
II l:
A. Pb
B. Cd
C. Al
D. Sn
Bi 27: Ngm mt vt bng Cu c khi lng 15 gam vo 340 gam dung dch AgNO3 6%. Sau mt thi gian
nhc thanh Cu ra thy khi lng AgNO3 trong dung dch gim 25%. Khi lng ca vt sau phn ng l:
A. 3.24 gam
B. 2,28 gam
C. 17,28 gam
D. 24,12 gam.
Bi 28: Cho 3,78 gam bt Al phn ng va vi dung dch mui XCl3 to thnh dung dch Y. Khi lng cht
tan trong dung dch Y gim 4,06 gam so vi dung dch X. Xc nh cng thc ca mui XCl3.
A. InCl3
B. GaCl3
C. FeCl3
D. GeCl3.
Bi 29: Cho 0,3 mol b t Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi cc phn
ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
B.
A. 6,72
B. 8,96
C. 4,48
D. 10,08
BI TON NHIT KIM LOI
Bi 1: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v
Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V
l
A. 0,448.
B. 0,112.
C. 0,224.
D. 0,560.
Bi 2: Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe2O3 ( nhit
cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung
dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l
A. 1,120.
B. 0,896.
C. 0,448.
D. 0,224.
Bi 3: Cho kh CO kh hon ton n Fe mt hn hp gm: FeO, Fe 2O3, Fe3O4 thy c 4,48 lt CO2 (ktc) thot
ra. Th tch CO (ktc) tham gia phn ng l
A. 1,12 lt.
B. 2,24 lt.
C. 3,36 lt.
D. 4,48 lt.
Bi 4: Thi mt lung kh CO i qua ng s ng m gam hn hp Fe 3O4 v CuO nung nng thu c 2,32 gam
hn hp rn. Ton b kh thot ra cho hp th ht vo bnh ng dung dch Ca(OH) 2 d thu c 5 gam kt ta.
Gi tr ca m l:
A. 3,22 gam.
B. 3,12 gam.
C. 4,0 gam.
D. 4,2 gam.
Bi 5: kh hon ton 30 gam hn hp CuO, FeO, Fe2O3, Fe3O4, MgO cn dng 5,6 lt kh CO ( ktc). Khi
lng cht rn sau phn ng l
A. 28 gam.
B. 26 gam.
C. 22 gam.
D. 24 gam.
Bi 6: Kh hon ton 17,6 gam hn hp X gm Fe, FeO, Fe 2O3 cn 2,24 lt CO ( ktc). Khi lng st thu
c lA. 5,6 gam.
B. 6,72 gam.
C. 16,0 gam.
D. 8,0 gam.
khoa ho HKHTN-HQGHN

Bi 7: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al 2O3 nung nng n khi phn ng hon
ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l
A. 0,8 gam.
B. 8,3 gam.
C. 2,0 gam.
D. 4,0 gam.
Bi 8. Cho dng kh CO d i qua hn hp (X) cha 31,9 gam gm Al 2O3, ZnO, FeO v CaO th thu c 28,7
gam hn hp cht rn (Y). Cho ton b hn hp cht rn (Y) tc dng vi dung dch HCl d thu c V lt H 2
(kc). Gi tr V l
A. 5,60 lt.
B. 4,48 lt.
C. 6,72 lt.
D. 2,24 lt.
Bi 9: Kh 6,4 gam CuO bng H2 nhit cao thu c cht rn A v hn hp kh B. Dn ton b lng kh
B qua bnh ng H2SO4 m c, thy khi lng bnh tng 0,9 gam. Thnh phn % CuO b kh trong phn
ng trn l:
A. 62,5%
B. 75%
C. 80%
D. 65%.
Bi 10: Dn t t lung kh H 2 qua 16 gam hn hp gm MgO v CuO un nng n khi khi lng hn hp
khng i thu pc cht rn A. Cht rn A tc dng va vi 1 lt dung dch H 2SO4 0,2M. Phn trn theo
khi lng ca CuO trong hn hp ban u l:
A. 40%
B. 60%
C. 75%
D. 50%
Bi 11: Cho lung kh CO d qua ng s ng 1,6 gam Fe 2O3 n khi phn ng xy ra hon ton thu c cht
rn A v kh B. Cho ton b lng kh B thu c vo bnh ng dung dch Ca(OH) 2 d, thy xut hin 3 gam
kt ta. Phn trm khi lng Fe2O3 b kh l:
A. 75%
B. 80%
C. 90%
D. 100%
Bi 12: C m gam hn hp cha Fe v Fe 2O3. Cho lung kh CO d i qua m gam hn hp trn, un nng n
khi phn ng xy ra hon ton thu c 11,2 gam Fe. Cng m gam hn hp trn cho tc dng vi dung dch
HCl d ngi ta thu c 2,24 lt kh H 2 (ktc). Thnh phn % theo khi lng ca Fe trong hn hp ban u
l:
A. 30%
B. 41,7%
C. 58,83%
D. 70%
Bi 13: Kh hon ton 4,06 gam oxit kim loi R bi kh CO thu c 1,568 lt kh CO 2. Lng kim loi sinh ra
cho tc dng hon ton vi dung dch HCl d thu c 0,0525 mol H2. Cng thc phn t ca oxit kim loi l:
A. Al2O3
B. CuO
C. Fe2O3
D. Fe3O4
Bi 14: Cho lung kh CO qua ng s ng 0,04 mol hn hp X gm FeO v Fe 2O3 nung nng, c cht rn Y
nng 4,784 gam v 0,046 mol CO2. S mol tng cht trong hn hp X l.
A. 0,015 mol FeO v 0,0025 mol Fe2O3
B. 0,01 mol FeO v 0,03mol Fe2O3
C. 0,02 mol FeO v 0,02 mol Fe2O3.
D. 0,02 mol FeO v 0,03 mol Fe2O3.
Bi 15: Cho mt lung kh CO i qua 29 gam mt oxit st. Sau khi phn ng xy ra hon ton ngi ta thu
c mt cht rn c khi lng 21 gam. Xc nh cng thc oxit st.
A. Khng xc nh c
B. Fe2O3
C. FeO
D. Fe3O4
Bi 16: Dng CO d kh hon tan m gam bt st oxit. Dn tan b lng kh sinh ra i tht chm qua 1 lt
dung dch Ba(OH)2 0,1M th va v thu c 9,85gam kt ta. Mt khc ha tan tan b m gam bt st oxit
trn bng dd HCl d ri c cn th thu c 16,25gam mui khan. m c gi tr l bao nhiu gam? V cng thc
oxit (FexOy).
A, 8gam; Fe2O3
B. 15,1gam, FeO
C. 16gam; FeO
D. 11,6gam; Fe3O4
Bi 17: Dng CO d kh han tan m gam bt st oxit(Fe xOy) dn tan b lng kh sinh ra i tht chm
qua 1 lt dung dch Ba(OH)2 0,1M th phn ng va thu c 9,85gam kt ta. S mol kh CO 2 thu c l
bao nhiu?
A. 0,05mol
B. 0,15 mol
C. 0,025mol
D. 0,05 v 0,075 mol
Bi 18: Dng CO d kh han tan m gam bt st oxit (Fe xOy), dn tan b lng kh sinh ra i tht chm
qua 1 lt dung dch Ba(OH)2 0,1M th va v thu c 9,85gam kt ta. Mt khc ha tan tan b m gam bt
st oxit bng dung dch HCl d ri c cn th thu c 16,25 gam mui khan. m c ga tr l?
khoa ho HKHTN-HQGHN

A. 8 gam
B. 15,1gam
C. 16gam
D. 11,6gam
Bi 19: Hn hp X gm Fe v oxit st c khi lng 2,6gam. Cho kh CO d i qua X nung nng, Kh sinh ra
hp th vo dung dch nc vi trong d th c 10gam kt ta. Tng khi lng Fe c trong X l?
A. 1 gam
B. 0,056gam
C. 2 gam
D. 1,12gam
Bi 20: Dn 1 lung CO d qua ng ng m gam hn hp X gm Fe 2O3 v CuO nung nng thu c cht rn
Y; kh ra khi ng c dn vo bnh ng dung dch Ca(OH) 2 d, thu c 40 gam kt ta. Ha tan cht rn Y
trong dung dch HCl d thy c 4,48 lt kh H2 bay ra (ktc). Ga tr m l?
A. 24
B. 16
C. 32
D. 12
Bi 21: Nung nng 7,2gam Fe 2O3 vi kh CO. Sau mt thi gian thu c m gam cht rn X. Kh sinh ra sau
phn ng c hp th ht bi ddBa(OH)2 c 5,91g kt ta, tip tc cho Ba(OH)2 d vo dung dch trn thy
c 3,94 gam kt ta na. Tm m?
A. 0,32gam
B. 64gam
C. 3,2gam
D. 6,4gam
Bi 22: Cho kh CO qua ng s cha 15,2gam hn hp cht rn CuO v Fe 3O4 nung nng , thu c kh X v
13,6 gam cht rn Y. Dn t t kh X vo dung dch Ca(OH) 2 d thy c kt ta. Lc ly kt ta v nung n
khi lng khng i c m gam cht rn. m c ga tr l?
A. 10gam
B. 16gam
C. 12gam
D. 18gam
Bi 23: Cho lung kh H 2 (d) qua hn hp cc oxit CuO, Fe 2O3, ZnO, MgO nung nhit cao. Sau phn ng
hn hp rn cn li l:
A. Cu, Fe, Zn, MgO. B. Cu, Fe, ZnO, MgO. C. Cu, Fe, Zn, Mg.
D. Cu, FeO, ZnO, MgO
Bi 24: Phn ng ho hc xy ra trong trng hp no di y khng thuc loi phn ng nhit nhm?
A. Al tc dng vi Fe3O4 nung nng.
B. Al tc dng vi CuO nung nng.
C. Al tc dng vi Fe2O3 nung nng.
D. Al tc dng vi axit H2SO4 c, nng
Bi 25: Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO
thu c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi
s cc phn ng xy ra hon ton. Phn khng tan Z gm
A. MgO, Fe, Cu.
B. Mg, Fe, Cu.
C. MgO, Fe3O4, Cu. D. Mg, Al, Fe, Cu.
Bi 26: Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng
xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn
trm th tch ca kh CO2 trong hn hp kh sau phn ng l (Cho H = 1; C = 12; O = 16; Fe = 56)
A. FeO; 75%.
B. Fe2O3; 75%. C. Fe2O3; 65%.
D. Fe3O4; 75%.
Bi 27: Cho V lt hn hp kh ( ktc) gm CO v H 2 phn ng vi mt lng d hn hp rn gm CuO v
Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V
l
A. 0,448.
B. 0,112.
C. 0,224.
D. 0,560.
Bi 28: Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi
phn ng xy ra hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau:
- Phn 1 tc dng vi dung dch H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc);
- Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l
A. 22,75
B. 21,40.
C. 29,40.
D. 29,43.
Bi 29: Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe 2O3 ( nhit
cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung
dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l
A. 1,120.
B. 0,896.
C. 0,448.
D. 0,224.
Bi 30: t nng mt hn hp gm Al v 16 gam Fe 2O3 (trong iu kin khng c khng kh) n khi phn
ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra
3,36 lt H2 (ktc). Gi tr ca V l
khoa ho HKHTN-HQGHN

A. 150.
B. 100.
C. 200.
D. 300.
Bi 31: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al 2O3 nung nng n khi phn ng hon
ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l
A. 0,8 gam.
B. 8,3 gam. C. 2,0 gam.
D. 4,0 gam.
Bi 32: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy
ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn
Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l
A. 45,6.
B. 48,3.
C. 36,7.
D. 57,0.
Bi 33: Kh hon ton m gam oxit M xOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ha
tan ht a gam M bng dung dch H 2SO4 c nng (d), thu c 20,16 lt kh SO 2 (sn phm kh duy nht,
ktc). Oxit MxOy l
A. Cr2O3.
B. FeO.
C. Fe3O4.
D. CrO
BI TP: V CC HP CHT LNG TNH
Bi 1. Ly 20 g hn hp bt Al v Fe2O3 ngm trong dung dch NaOH(d), phn ng xong ngi ta thu c
3, 36l kh hidro (ktc). Khi lng Fe2O3 ban u l:
A. 13,7 gam
B. 17,3 gam
C. 18 gam
D. 15,95gam
Bi 2. Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra
hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau:
- Phn 1 tc dng vi dung dch H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc);
- Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l
A. 22,75
B. 21,40.
C. 29,40.
D. 29,43.
Bi 3. Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy
ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn
Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l
A. 36,7.
B. 48,3.
C. 45,6.
D. 57,0.
Bi 4. Chia 20g hn hp X gm Al; Fe; Cu thnh hai phn bng nhau. Phn 1 cho tc dng ht vi dung dch
HCl thu c 5,6lt kh ktc. Phn 2 cho tc dng vi dung dch NaOH d thu c 3,36lt kh ktc. Thnh
phn phn trm theo khi lng ca Cu trong hn hp X l:
A. 8,5%
B. 13%
C. 16%
D. 17%
Bi 5. Cho m gam Na vo 50 ml dung dch AlCl3 1M. Sau khi phn ng xy ra hon ton, th thu c V lt kh
(ktc), dung dch X v 1,56 gam kt ta.Khi thi CO2 d vo dung dch X li thy xut hin thm kt ta.Khi
lng Na ban u l:
A. 4,14 g
B. 1,44 g
C. 4,41 g
D. 2,07 g
Bi 6. Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l
15,6 gam. Gi tr ln nht ca V l (cho H = 1, O = 16, Al = 27)
A. 1,2.
B. 1,8.
C. 2,4.
D. 2.
Bi 7. : Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp
kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l
A. 0,55.
B. 0,60.
C. 0,40.
D. 0,45.
Bi 8. Cho 200 ml dung dch NaOH 1M vo 200 ml dung dch HCl thu c dung dch B. Cho dung dch B vo
200 ml dung dch NaAlO2 0,2M thu c 2,34 gam kt ta. Tnh nng ca dung dch HCl.
A. 1,15M
B. 1,35M
C. 1,15M v 1,35M
D. 1,2M.

khoa ho HKHTN-HQGHN

Bi 9. Cho m gam kim loi Na vo 200 gam. dung dch Al2(SO4)3 1,71%. Sau khi phn ng xong thu c 0,78
gam kt ta. m c gi tr l
A. 0,69 gam.
B. 1,61 gam.
C. c A v B u ng.
D. p n khc
Bi 10. Cho 0,54 gam Al vo 40 ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch X. Cho
t t dung dch HCl 0,5M vo dung dch X thu c kt ta. thu c lng kt ta ln nht cn th tch
dung dch HCl 0,5M l
A. 110 ml.
B. 90 ml.
C. 70 ml.
D. 80 ml.
Bi 11. Hn hp A gm Na v Al4C3 ha tan vo nc ch thu c dung dch B v 3,36 lt kh C. Khi lng
Na ti thiu cn dng l:
A. 0,15g
B. 2,76g
C. 0,69g
D. 4,02g
Bi 12. Hn hp A gm Na, Al , Cu cho 12 gam A vo nc d thu 2,24 lt kh (ktc) , cn nu cho vo dung
dch NaOH d thu 3,92 lt kh ( ktc) . % Al trong hn hp ban u ?
A. 59,06%
B. 22,5%
C. 67,5 %
D. 96,25%
Bi 13. Cho m gam hn hp X gm Na2O v Al ho tan ht vo H2O d thu c 200 ml dung dch A ch cha
1 cht tan duy nht c nng 0,2M. Gi tr ca m l :
A. 2,32 B. 3,56
C. 3,52
D. 5,36
Bi 14. Ha tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110ml dung dch KOH 2M vo X, thu
c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi
tr ca m l
A. 20,125.
B. 12,375.
C. 22,540.
D. 17,710.
Bi 15. Hn hp X gm cc kim loi Al; Fe; Ba. Chia X thnh 3 phn bng nhau:
- Phn 1 tc dng vi nc d thu c 0,04 mol H2.
- Phn 2 tc dng vi dung dch NaOH d thu c 0,07 mol H2.
- Phn 3 tc dng vi dung dch HCl d thu c 0,1 mol H2.
Cc phn ng xy ra hon ton. S mol Ba, Al, Fe trong 1 phn ca hn hp X ln lt l:
A. 0,01; 0,04; 0,03
B. 0,01; 0,02; 0,03
C. 0,02; 0,03; 0,04
D. 0,01; 0,03; 0,03
Bi 16. : Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh. Nu cng cho
m gam X vo dung dch NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na trong
X l (bit cc th tch kh o trong cng iu kin, cho Na = 23, Al = 27)
A. 77,31%.
B. 39,87%.
C. 49,87%.
D. 29,87%.
Bi 17. Cho hn hp gm Na v Al c t l s mol tng ng l 1 : 2 vo nc (d). Sau khi cc phn ng xy
ra hon ton, thu c 8,96 lt kh H2 ( ktc) v m gam cht rn khng tan. Gi tr ca m l
A. 10,8.
B. 5,4.
C. 7,8.
D. 43,2.
Bi 18. Cho a gam Na ha tan ht vo 86,8 gam dung dch c cha 13,35 gam AlCl3, sau phn ng hon ton
thu c m gam dung dch X v 3,36 lt kh H2 ( 0oC, 2atm). Hy chn cu tr li ng trong cc cu sau:
A. m = 100,6 gam v dung dch X c 3 cht tan.
B. m = 100,6 gam v dung dch X c 2 cht tan.
C. m = 100 gam v dung dch X c 3 cht tan.
D. m = 100 gam v dung dch X c 2 cht tan.
Bi 19. Mt hn hp A gm Ba v Al. Cho m gam A tc dng vi nc d, thu c 2,688 lit kh (ktc). Cho
2m gam A tc dng vi dung dch Ba(OH)2 d thu c 8, 064 lt kh(ktc). Xc nh m.
A. 10,05 gam
B. 12,54 gam
C. 20,76 gam
D. p n khc.
Bi 20. Cho m gam hn hp (Na, Al) vo nc d thy thot ra 8,96 lt kh (ktc) v cn li 2,7 gam kim loi
khng tan. Khi lng m ca hn hp ban u l
A. 12,7 gam.
B. 9,9 gam.
C. 21,1 gam.
D. tt c u sai
khoa ho HKHTN-HQGHN

Bi 18. Ho tan hon ton m gam hn hp X gm Na; K v Al (trong Na v K c t l mol l 1 : 1) vo mt
lng nc d thu c dung dch Y; 2,7g cht rn Z v 8,96lt kh T ktc. Gi tr ca m l:
A. 17g
B. 11,6g
C. 14,3g
D. 16,1g
Bi 21. Cho 38,775 gam hn hp bt Al v AlCl3 vo lng va dung dch NaOH thu c dung dch A (kt
ta va tan ht) v 6,72 lt H2 (ktc). Thm 250ml dung dch HCl vo dung dch A thu c 21,84 gam kt ta.
Nng M ca dung dch HCl l :
A. 1,12M hoc 2,48M
B. 2,24M hoc 2,48M
C. 1,12M hoc 3,84M
D. 2,24M hoc 3,84M
Bi 22. Cho 23,45 gam hn hp X gm Ba v K vo 125 ml dung dch AlCl3 1M thu c V lt kh H2(ktc);
dung dch A v 3,9 gam kt ta. V c gi tr l :
A. 10,08 lt
B. 3,92 lt
C. 5,04 lt
D.6,72 lt
BI TP V HIU SUT PHN NG
Bi 1. Trn 13,5 g bt Al vi 34,8g bt Fe3O4 ri tin hnh phn ng nhit nhm. Gi s lc ch xy ra phn
ng kh Fe3O4 thnh Fe. Ho tan hon ton hn hp cht rn sau phn ng bng dung dch H2SO4 long d th
thu c 14,112 lt H2 ( ktc). Tnh hiu sut phn ng nhit nhm.
A. 70%
B. 75%
C. 80%
D.60%
Bi 2. Khi oxi ha 11,2 lt NH3 ( ktc) iu ch HNO3 vi hiu sut ca c qu trnh l 80% th thu c
khi lng dung dch HNO3 6,3% l
A. 300 gam.
B. 500 gam.
C. 250 gam.
D. 400 gam.
Bi 3. Da nhn to (PVC) c iu ch t kh thin nhin theo s :
CH4 C2H2 CH2=CHCl [CH2CHCl]n.
Nu hiu sut ca ton b qu trnh iu ch l 20%, mun iu ch c 1 tn PVC th th tch kh thin nhin
(cha 80% metan) iu kin tiu chun cn dng l
A. 4375 m3.
B. 4450 m3.
C. 4480 m3.
D. 6875 m3
Bi 4. Nung 8,1 gam Al vi 23,2 gam Fe3O4 nhit cao ( gi s ch c phn ng kh oxit st thnh st) thu
c hn hp X. Cho hn hp X vo dung dch H2SO4 long d, un nng thu c 8,064 lt H2 (ktc). Hy
cho bit hiu sut ca phn ng nhit nhm ?
A. 75%
B. 80%
C. 85%
D. 90%
Bi 5. Khi lng este metylmetacrylat thu c l bao nhiu khi un nng 215g axit metacrylic vi 100g
ancol metylic, gi thit hiu sut phn ng este ho t 60%.
A. 125g
B. 175g
C. 150g
D. 200g
Bi 6. in phn Al2O3 nng chy trong thi gian 2 gi 40 pht 50 giy, cng dng in 5 A , thu c
3,6 gam nhm kim loi catot. Hiu sut ca qu trnh in phn ny l:
A. 80%
B. 90%
C. 100%
D. 70%
Bi 7.Tnh khi lng glucozo cn dng ln men thu c 200 lt C2H5OH 30o ( D= 0,8 gam/ml), bit hiu
sut ln men t 96%?
A. 90,15 kg
B. 45,07 kg
C. 48,91 kg
D. 97,83 kg
Bi 8. Cho hn hp A gm N2 v H2 ( t l mol 1:3), tin hnh phn ng tng hp NH3, sau phn ng thu c
hn hp B c t khi dA/B= 0,7. Hiu sut phn ng l:
A. 55%
B. 60%
C. 80%
D. 75%
Bi 9. T 1 tn mui n c cha 10,5% tp cht , ngi ta iu ch c 1250lit dung dch HCl 37% ( d =1,19
g/ml) bng cch cho lng mui n trn tc dng vi axit sunfuric m c nhit cao . Tnh hiu sut ca
qu trnh iu ch trn ?
A. 95,88%
B. 98,55%
C. 98, 58%
D. 98,85%.
khoa ho HKHTN-HQGHN

Bi 10. un nng hn hp X gm 0,25 mol C2H3COOH v 0,15 mol C3H6(OH)2 c mt ca H2SO4 c lm xc
tc, sau mt thi gian thu c 19,55 gam mt este duy nht. Hiu sut ca phn ng este ho l
A. 25%.
B. 70%.
C. 80%.
D. 85%.
Bi 11. Khi lng glucoz cn iu ch 0,1 lt ru tylic nguyn cht (khi lng ring D = 0,8 g/ml) vi
hiu sut 80% l
A. 180 gam.
B. 195,65 gam.
C. 186,55 gam.
D. 200 gam.
Bi 12. Ha tan hon ton 16 gam ru etylic vo nc c 250 ml dung dch ru, cho bit khi lng ring
ca ru etylic nguyn cht l 0,8 g/ml. Dung dch c ru l:
A. 5,120
6,40
C. 120
D. 80
Bi 13. Mt loi go cha 75% tinh bt. Ly 78,28 kg go ny i nu ru etylic 400, hiu sut p ca c qu
trnh l 60%. Khi lng ring ca ru etylic l 0,8 g/ml. Th tch ru 400 thu c l:
A. 60(lt)
B. 52,4(lt)
C. 62,5(lt)
D. 45(lt)
Bi 14. T 3 tn qung pirit (cha 58% FeS2 v khi lng, phn cn li l cc tp cht tr) iu ch c bao
nhiu tn dung dch H2SO4 98%, hiu sut chung ca qu trnh iu ch l 70%?
A. 2,03 tn
B. 2,50 tn
C. 2,46 tn
D. 2,90 tn
Bi 15. Thc hin phn ng nhit nhm gia 6,48 gam Al vi 17,6 gam Fe2O3. Ch c phn ng nhm kh oxit
kim loi to kim loi. em ha tan cht rn sau phn ng nhit nhm bng dung dch xt d cho n kt thc
phn ng, thu c 1,344 lt H2 (ktc). Hiu sut phn ng nhit nhm l:
A. 100%
B. 90,9%
C. 83,3%
D. 70%
Bi 16. Thy phn m gam tinh bt, sn phm thu c em ln men sn xut ancoletylic, ton b kh CO2
sinh ra cho qua dung dch Ca(OH)2 d, thu c 750 gam kt ta. Nu hiu sut mi qu trnh l 80% th gi tr
m l
A. 949,2 gam. B. 945,0 gam.
C. 950,5 gam.
D. 1000 gam.
Bi 17. Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c m gam cht
rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y c pH bng 1. Hiu sut ca
phn ng nhit phn l:
A. 42,86%
B.40,56%
C. 58,86%
D. 62,68%
Bi 18. Nung qung lmit ( CaCO3.MgCO3) nng 184 gam mt thi gian, thy cn li 113,6 gam cht rn.
Hiu sut ca phn ng nhit phn l:
A. 60%
B. 75%
C. 80%
D. 85%
Chuyn 04: Bi tp v hirocacbon

Cu 1. t chy hon ton hn hp X gm 2 hidrocacbon mch h cng dy ng ng hp th hon ton sn
phm vo 1,8 lt dung dch Ca(OH)2 0,05M thu c kt ta v khi lng dung dch tng 3,78g. Cho Ba(OH)2
d vo dung dch thu c kt ta v tng khi lng tng cng c 2 ln l 18,85g. T khi ca X vi H2 l 20.
Dy ng dng ca hai hidrocacbon l:
a. Ankin
b. Ankadien
c. Aren
d. Ankin hoc Ankadien
Cu 2. Cho hn hp kh X gm 2 hidrocacbon A, B mch thng v khi lng phn t ca A nh hn khi
lng phn t ca B. Trong hn hp X, A chim 75% theo th tch . t chy hon ton X cho sn phm chy
hp th qua bb nh cha dung dch Ba(OH)2 d, sau th nghim khi lng dung dch trong bb nh gim 12,78g ng
khoa ho HKHTN-HQGHN

thi thu c 19,7g kt ta. Bit t khi hi ca X i vi hidro bng 18,5 v A, B cng dy ng ng.
1) Xc nh dy ng ng ca 2 hidrocacbon
a. Ankan
b. Anken
c. Aren
d. Ankadien
2) Tb m cng thc phn t ca A, B?
a. C3H6 v C4H8
b. C2H6 v C4H10
b. C4H8 v C5H10
d. C2H6 v C3H8
Cu 3. Mi hn hp X gm 2 hidrocacbon A, B ( thuc mt trong 3 dy ng ng ankan, anken, ankin) s
nguyn t C trong mi phn t nh hn 7; A v B c trn theo t l mol l 1:2. t chy hon ton 14,8g hn
hp X bng oxi ri thu ton b sn phm ln lt dn qua bb nh cha dung dch H2SO4 c, d; bb nh 2 cha
890ml dung dch Ba(OH)2 1M thb khi lng bb nh 1 tng 14,4g v bb nh 2 thu c 133,96g kt ta trng.
Xc nh dy ng ng ca A v B.
a. Ankin
b. Anken
c. Ankedien
d. Ankan
Cu 4. t chy hon ton mt hidrocacbon X vi mt lng va oxi. Dn hn hp sn phm chy qua
H2SO4 m c thb th tch kh gim hn mt na. Dy ng dng ca hidrocacbon X l:
a. Ankin
b. Anken
c. Ankedien
d. Ankan
Cu 5. Cho 2 hidrocacbon X v Y ng ng nhau, phn t khi ca X gp i phn t khi ca Y.
a) Xc nh cng thc tng qut ca 2 hidrocacbon.
a. CnH2n 2
b. CnH2n + 2
b. CnH2n 6
c. CnH2n
b) Xc nh cng thc phn t ca X v Y, bit rng: T khi ca hn hp ng th tch X v Y so
vi kh C2H6 bng 2,1.
a. C3H8 v C6H14
b. C3H4 v C6H6
c. C3H6 v C6H12
b. Cu C ng
Cu 6. t chy V (lit) hn hp kh X iu kin tiu chun gm 2 hidrocacbon to thnh 4,4g CO2 v 1,8g
H2O. Cho bit 2 hidrocacbon tren cng hay khc dy ng ng v thuc dy ng ng no? ( Ch xt cc dy
ng ng hc trong chng trnh).
a. Cng dy ng ng Anken hay cng dy ng ng xicloankan.
b. Khc dy ng ng: anken v xicloankan.
c. Khc dy ng ng: ankan v ankin ( s mol bng nhau)
d. Khc dy ng ng: ankan v ankadien (s mol bng nhau )
Cu 7. t chy hon ton 2,8g mt hp cht hu c X ri cho ton b sn phm hp th vo dd NaOH thb dung
dch ny c khi lng tng thm 12,4g, thu c 2 mui ny c t l 1:1 Xc nh dy ng ng ca cht X.
a. a. Ankin
b. Anken
c. Ankadien
d. Ankan
Cu 8. t chy hon ton 2,8 cht hu c X bng 6,72 lit O2 (ktc) ch to thnh kh CO2 v hi nc c th
tch bng nhau trong cng iu kin.
a) Tb m dy ng ng ca hp cht hu c X.
a. Anken
b. Ankan
c. Ankadien
d. Kt qu khc
c) Nu cho 2,8g X ni trn vo dung dch Br2 d thb c 9,2g sn phm cng. Tb m cng thc phn
t.
a. C5H10
b. C4H8
c. C4H10
d. Kt qu khc
Cu 9. t chy 2 lit hn hp hai hidrocacbon X, Y th kh v cng dy ng ng, cn 10 lit O2 to thnh
6 lit CO2 ( cc th tch u ktc).
a) Xc nh dy ng ng ca 2 hidrocacbon?
a. Ankan
b. Anken
c. Aren
d. Ankadien
o
Cu 10. t chy hon ton 24,64 lit (27,3 C; 1 atm) hn hp kh X gm 3 hidrocacbon ng ng lin tip, thu
sn phm cho hp th ht vo mt bb nh nc vi trong d thi khi lng ton bb nh tng 149,4g v khi lc thu
c 270g kt ta trng.
khoa ho HKHTN-HQGHN

a) Xc nh dy ng ng ca 3 hidrocacbon
a. CnH2n 2
b. CnH2n + 2
b. CnH2n 6
d. CnH2n
b) Xc nh cng thc phn t 3 hidrocacbon:
a. C2H4, C3H6 v C4H8
b. C6H6, C7H8 v C8H10
b. C2H6, C3H8 v C4H10
d. C2H2, C3H4 v C4H6
CH 2 : Xc nh CTPT CTCT ca hidrocacbon
Dng 1:Hn hp hidrocacbon cng dy ng ng k tip
Cu 11. Mt hn hp gm hai cht ng ng ankan k tip c kl 24,8g. Th tch tng ng l 11,2 lit (ktc).
Hy xc nh cng thc phn t ca ankan.
a. C6H8 v C3H8
b. C5H12 v C6H14
c. C3H8 v C4H10
d. Cu C ng
Cu 12. Cho 5,6 lit hn hp hai olefin l ng ng k tip nhau hp nc (c xc tc) c hn hp 2 ru.
Chia hn hp hai ru ny dng khan ri chia lm 2 phn bng nhau. Phn th nht phn ng ht vi Na d
thu c 840ml kh. t chy ht phn th hai ri cho ton b sn phm chy hp th vo bb nh ng NaOH d
thb khi lng bb nh NaOH tng 13,75g.
Cng thc phn t ca hai olefin l:
a. C2H6 v C3H8
b. C3H4 v C4H6
c. C2H4 v C3H6
d. C4H8 v C3H6
Dng 2:Hn hp hidrocacbon cng dy ng ng khng k tip
Cu 13. Cho 6,72 lit hn hp kh gm 2 olefin li qua nc brom d thy khi lng bb nh tng 16,8g. Hy tb m
cng thc phn t cc olefin bit rng s nguyn t cacbon trong mi olefin khng qu 5.
a. C2H4 v C4H8
b. C3H6 v C4H8
c. C5H10 v C6H12
d. C2H4 v C4H8 ; C3H6 v C4H8
Cu 14. t chy 560cm3 hn hp kh (ktc) gm hai hidrocacbon c cng s nguyn t cacbon ta thu c
4,4g CO2 v 1,9125g hi nc. Xc nh cng thc phn t cc hidrocacbon.
a. C4H8 v C4H10
b. C4H6 v C4H10
c. C4H4 v C4H10
d. Cu A, B, C cha cp p s
Dng 3: S dng mt s d kin thc nghim khi xc nh cng thc , thnh phn ca hidrocacbon
Cu 15. t 10cm3 mt hidrocacbon bng 80cm3 oxi (ly d). Sn phm thu c sau khi cho H2O ngng t c n
65cm3 trong 25cm3 l oxi. Cc th tch u o ktc. Xc nh cng thc phn t ca hidrocacbon.
a. C4H10
b. C4H6
c. C5H10
d. C3H8
Cu 16. Mt hn hp gm hai hidrocacbon mch h. Cho 1680ml hn hp trn i chm qua nc brom d.
Sauk hi phn ng hon ton c n li 1120ml v lng brom tham gia phn ng l 4,0g. Mt khc nu t chy
hon ton 1680ml hn hp trn ri cho ton b sn phm chy hp th vo nc vi trong d thb thu c 12,5g
kt ta.
Cng thc phn t ca hai hidrocacbon l:
a. C4H8 v C3H6
b. C2H6 v CH4
c. C4H10 v CH4
d. C3H6 v CH4
Cu 17. Hn hp kh A gm hidro, mt paraffin v hai olefin l ng ng lien tip. Cho 560ml A i qua ng
cha bt niken nung nng c 448ml hn hp kh A1 li qua bb nh nc brom thy nc brom nht mu mt
phn v khi lng bb nh nc brom tng thm 0,343g. Hn hp kh A2 i ra khi bb nh nc brom chim th tch
291,2ml v c t khi i vi khng kh bng 1,313. Gi thit cc phn ng xy ra hon ton, cc olefin phn
ng vi tc bng nhau ( ngha l t l vi thnh phn % th tch ca chng) v cc th tch kh o ktc. Xc
nh cng thc phn t ca cc hidrocacbon.
a. C2H4; C3H6 v C5H10
b. C2H6; C3H6 v C4H8
c. C3H8; C4H10 v C5H12
d. C2H6; C4H8 v C5H10
khoa ho HKHTN-HQGHN

Cu 18. Cho 0,672 lit (ktc) hn hp kh A gm hai hidrocacbon mch h. Chia A thnh 2 phn bng nhau. Cho
phn 1 qua dung dch Br2 d, khi lng dung dch tng Xg, lng Br2 phn ng ht 3,2g khng c kh thot
ra khi dung dch. t chy phn 2 v cho sn phm chy qua bb nh dung dch P2O5. Sau cho qua KOH rn.
Sau th nghim bb nh ng P2O5 tng Yg v bb nh ng KOH tng 1,76g. Tb m cng thc phn t ca 2 hidrocacbon.
a. C2H4 v C3H6
b. C3H6 v C4H8
c. C2H4 v C4H6 hoc C2H2 v C3H6
d. Cu C ng
Cu 19. Cho 0,896 lit (ktc) hn hp kh A gm 2 hidrocacbon mch h. Chia A thnh 2 phn bng nhau:
Phn 1: Cho qua dung dch Br2 c tha, lng Br2 nguyn cht phn ng 5,6g
Phn 2: t chy hon ton to ra 2,2g CO2. Tb m cng thc phn t 2 hidrocacbon.
a. C4H8 v C2H2
b. C4H2 v C2H4
c. C4H8 v C2H2 ; C4H2 v C2H4
d. p s khc
Cu 20. Trn hn hp X1 gm hidrocacbon B vi H2 c d dx/H2 = 4,8. Cho X1 i qua Ni nung nng n phn
ng hon ton c hn hp X2 c dX2/H2 = 8. Cng thc phn t hidrocacbon B l:
a. C3H6
b. C3H4
c. C4H8
d. C5H8
Cu 21. Trn hn hp X gm 1 hidrocacbon khi (A) v H2 vi dX/H2 = 6,1818. Cho X qua Ni un nng n khi
phn ng hon ton thu c hn hp Y dY/H2 = 13,6. Xc nh cng thc phn t ca A.
a. C3H4
b. C3H6
c. C4H6
d. C5H12
Cu 22. Cho 1,568 lit hn hp kh X gm 2 hidrocacbon mch h vo bb nh nc brom d. Sauk hi phn ng
hon ton ch c n li 448cm3 kh thot ra v c 8 gam brom phn ng. Mt khc, nu t chy hon ton
lng X trn ri dn ton b sn phm chy vo bb nh nc vi trong thb c 15g kt ta. Lc b kt ta ri un
nng nc lc, thu thm ti a 2 gam kt ta na. ( Cc th tch kh u c o ktc).
Tb m cng thc cu to 2 phn t hidrocacbon.
a. C2H4 v C4H8
b. C3H6 v C4H8
c. C2H2 v C5H12
d. C2H6 v C3H6
Cu 23. Cho 0,42 lit hn hp kh B gm hai hidrocacbon mch h i rt chm qua bb nh ng nc brom d.
Sauk hi phn ng hon ton thy c 0,28 lit kh i ra khi bb nh v c 2 gam brom tham gia phn ng. Cc th
tch kh o ktc. T khi hi ca B so vi hidro l 19. Hy xc nh cng thc phn t hai hidrocacbon.
a. C2H6 v C4H6
b. C3H8 v C2H2
c. C2H6 v C4H6 hoc C3H8 v C2H2
d. C3H6 v C4H6 hoc C2H8 v C2H2
Dng 4: Bin lun xc nh CTPT hidrocacbon
Cu 24. t chy hon ton 3,24 gam hn hp X gm 2 cht hu c (A) v (B) khc dy ng ng, trong
(A) hn (B) mt nguyn t cacbon,ngi ta ch thu c H2O v 9,24 gam CO2. Bit t khi hi ca X i vi
hidro l dx/H2 = 13,5. Tb m cng thc phn t ca (A), (B)?
a. C2H4 v C2H5OH
b. C2H6 v C3H8
c. C2H2 v CH2O
d. C3H8O v C2H6O
Cu 25. t hon ton hn hp 2 hidrocacbon X, Y thuc cng mt dy ng ng (ankan, anken, ankin), hp
thu sn phm chy vo 4,5 lit dung dch Ca(OH)2 0,02M thb thu c kt ta, khi lng dung dch tng ln
3,78g. Cho dung dch Ba(OH)2 d vo dung dch thu c kt ta. Tng kt ca 2 ln nng 18,85g. Bit rng s
mol X bng 60% tng s mol X, Y trong hn hp. Xc nh cng thc phn t ca X, Y?.
a. C2H4 v C3H6
b. C3H4 v C5H6
c. C2H6 v C3H8
d. C2H2 v C4H6
Cu 26. t chy mt hidrocacbon X mch h, kh vi 1,92 gam kh oxi trong bb nh kn ri cho cc sn phm sau
phn ng qua bb nh mt cha trong H2SO4 c d, bb nh hai cha 3,5 lit Ca(OH)2 0,01M thu c 3g kt ta, kh
duy nht bay ra c th tch 0,224 lit o 27,3oC v 1,1 atm. Xc nh cng thc phn t ca X, gi thit cc
phn ng xy ra hon ton.
khoa ho HKHTN-HQGHN

a. C2H2
b. C2H8
c. C3H8 hoc C2H2
d. C3H8 hoc C2H2 hoc CH4
Cu 27. Cho hn hp kh gm hidrocacbon A v oxi ly d, trong c 10% A theo th tch vo mt kh nhin
k, to p sut 1 atm 0oC. Bt tia la in A chy hon ton ri cho nc ngng t 0oC thb p sut trong
bb nh gim c n 0,8 atm. Bit lng oxi d khng qu 50% lng oxi ban u. Hy tbm cng thc phn t ca A.
a. C4H8
b. C4H10
c. C4H4
d. C5H12
Cu 28. Mt hn hp gm hai hidrocacbon, mch h, trong phn t mi cht cha khng qu mt lien kt ba
hay hai lien kt i. S cacbon mi cht ti a bng 7. t chy hon ton 0,05 mol hn hp thu c 0,25 mol
CO2 v 0,23 mol H2O. Tb m cng thc phn t ca 2 hidrocacbon?
a. C2H2 v C7H14
b. C5H8 v C5H10
c. C5H8 v C5H12
d. p s A + B + C
Cu 29. t chy mt hidrocacbon X vi lng va oxi. Ton b sn phm chy c dn qua bb nh ng
canxi clorua khan c d th tch gim i hn mt na. Bit rng X cacbon chim 80% v khi lng. Xc nh
cng thc cu to ca X.
a. C3H8
b. C2H4
c. C4H6
d. C2H6
Cu 30. t chy hai hidrocacbon c cng cng thc tng qut CnH2n + 2 2k thu c sn phm sau khi t chy
c khi lng 22,1g. Khi cho ton b lng sn phm ny vo 400g dung dch NaOH thb thu c dung dch
gm hai mui c nng 9,0026%. T l s mol hai mui l 1:1.
Cho bit t l s mol ca chng trong hn hp l 1:2 ( theo chiu khi lng phn t tng dn). Bit k < 3. Cng
thc phn thc phn t ca hai hidrocacbon l:
a. C2H4 v C3H6
b. C3H8 v C4H10
c. C2H2 v C3H4
d. Kt qu khc
Cu 31. Mt hidrocacbon X c cng thc CnH2n + 2 2k. Khi t X ta c t l s mol ca CO2 v H2O bng 2 ( k
hiu l b), ng vi k nh nht. Cng thc phn t ca X l:
a. C2H4
b. C2H6
c. C2H2
d. C6H6
Cu 32. C mt hn hp hai hidrocacbon A v B th kh. Phn t khi ca B ln hn phn t khi ca A 24
vC. T khi hi so vi H2 ca B bng 9/5 t khi hi so vi H2 ca A. Khi t chy V lit hn hp thu c 11,2
lit CO2 (ktc) v 8,1g H2O. Hi A v B l nhng hidrocacbon no?
a. C2H8 v C4H10
b. C2H6 v C4H6
c. C3H8 v C5H10
d. Kt qu khc
Cu 33. t chy hon ton hn hp X gm hi ca hidrocacbon A v kh oxi d thu c hn hp kh v hi.
Lm lnh hn hp ny, th tch gim 50%. Nu cho hn hp c n li qua KOH, th tch gim 83,3% s c n li.
Xc nh cng thc phn t ca hidrocacbon.
a. C2H6
b. C5H8
c. C5H12
d. C6H6
Cu 34. Trong mt hn hp kh X gm hidrocacbon A v kh oxi d trong bb nh ri t chy, sau khi xong,lm
lnh hn hp kh thu c, nhn thy th tch gim 33,3% so vi th tch hn hp thu c. Nu dn hn hp
kh tip tc qua dung dch KOH th tc b gim 75% s c n li. Tb m cng thc phn t hidrocacbon A.
a. C3H6
b. C3H4
c. C2H6
d. C6H6
Cu 35. nhit 100oC, khi lng phn t trung bb nh ca hn hp gm mt s hidrocacbon lien tip trong
cng dy ng ng no bng 64. Sau khi lm lnh nhit ph ng thb mt s cht trong hn hp b ha
lng. Khi lng phn t trung bb nh ca nhng cht c n li th kh bng 54, c n khi lng phn t trung bb nh
ca nhng cht lng l 74. Tng khi lng phn t cc cht trong hn hp ban u bng 252 vC v phn t
khi ca ng ng nng nht bng 2 ln ca phn t khi ca ng ng nh nht. Hy xc nh cng thc
phn t ca cc cht trong hn hp ban u?
a. C3H8; C4H10; C5H12
b. C2H6 v C3H6
c. C4H8; C5H10 v C6H12
d. Kt qu khc
Cu 36. Mt hn hp kh c khi lng 7,6g gm 2,24 lit mt hidrocacbon mch thng A v 1,12 lit mt ankin
khoa ho HKHTN-HQGHN

B (ktc). t chy hon ton hn hp trn ri cho ton b sn phm chy hp th ht trong dung dch Ba(OH)2
d thb c 108,35g kt ta. A thuc loi hidrocacbon no?
a. C3H4 v C4H8
b. C2H2 v C3H8
c. C6H6 v C7H8
d. Kt qu khc
Cu 37. Hn hp hai olefin ( th kh) lien tip trong cng dy ng ng hp nc to thnh 2 ru (mt ru
c dng mch nhnh) hiu sut u bng 40%. Bit th tch hn hp V lit ( 0oC, 1 atm)
Chia hn hp ru thnh 2 phn bng nhau. Cho Na tc dng vi phn 1 thu c 2,464 lit H2 ( 27,3oC, 1
atm). un nng phn 2 vi H2SO4 c to 3,852g hn hp 3 ete. 50% lng ru c s nguyn t cacbon t hn
v 40% lng ru c s nguyn t cacbon nhiu hn to thnh ete. Xc nh cng thc phn t 2 olefin.
a. C3H6 v C4H8
b. C2H4 v C4H8
c. C4H8 v C5H10
d. C2H4 v C3H6
Cu 38a) Trn 0,02 mol C2H2 v 0,03 mol H2 vi 1,68 lit O2 (kct) np vo mt kh k c th tch 4 lit ri t
chy.p sut hn hp sau phn khi to = 109,2oC l:
a. 0,392 atm
b. 1,176 atm
c. 0,784 atm
d. 1,568 atm
b) Cho 11 gam hn hp gm 6,72 lit mt hidrocacbon mch h A v 22,4 lit mt ankin. t chy hn hp ny
thb tiu th 25,76 lit oxi. Cc th tch o trong iu kin tiu chun.
Cng thc phn t ca hidrocacbon A v B ln lt l:
a. C2H6 v C2H2
b. C3H6 v C3H4
c. C2H2 v C3H4
d. C2H4 v C2H2
Cu 39a) Trong mt bb nh kn th tch 5,6 lit cha 3,36 lit H2 v 2,24 lit C2H4 (ktc) v mt t bt niken. t nng
bb nh mt thi gian, Sau lm lnh v 0oC, p sut trong bb nh lc l p. Nu cho hn hp kh trong bb nh sau
phn ng li qua nc brom thy c 0,8g Br2 tham gia phn ng.
Hy tnh phn trm phn ng:
a. 31,65%
b. 63,3%
c. 94,95%
d. 100%
3
b) t chy hon ton 50 cm hn hp kh A gm C2H6, C2H4, C2H2 v H2 thu c 45 cm3 CO2. Mt khc nung
nng th tch hn hp kh A c mt Pd xc tc thb thu c 40 cm3 hn hp kh B. Sau cho hn hp kh B
qua Ni un nng cho mt kh duy nht. (Gi s cc phn ng xy ra hon ton) Thnh phn phn trm theo th
tch cc kh trong hn hp A ( H2, C2H2, C2H4, C2H6) ln lt l:
a. 20%, 30%, 20%,30%
b. 25%, 15%, 30%, 30%
c. 55%, 20%, 15%, 10%
d. Kt qu khc
Cu 40a) t chy 60 cm3 hn hp ankin X, Y l hai ng ng lien tip nhau thu c 220 cm3 CO2 ( cc th
tch kh o trong cng iu kin). Cng thc phn t ca X v Y ln lt l:
a. C2H2 v C3H4
b. C3H4 v C4H6
c. C4H6 v C5H8
d. Kt qu khc
o
b) Mt bb nh kn 2 lit 27,3 C cha 0,03 mol C2H2; 0,015 mol C2H4 v 0,04 mol H2 c p sut p1.
Nu trong bb nh c mt t bt Ni lm xc tc ( th tch khng ng k), nung bb nh n nhit cao phn ng
xy ra hon ton, sau a v nhit ban u c hn hp kh A c p sut p2. Cho hn hp A tc dng vi
lng d dung dch AgNO3 trong NH3 thu c 3,6g kt ta. Hy tnh p sut p2:
a. 0,277 atm
b. 0,6925 atm
c. 1,108 atm
d. 0,554 atm
Cu 41. a) t chy hon ton 2,24 lit kh C2H4 (ktc) ri hp th ton b sn phm vo dung dch cha 11,1
gam Ca(OH)2. Hi sau khi hp th khi lng phn dung dch tng hay gim bao nhiu gam?
a. tng 4,8g
b. gim 2,4g
c. tng 2,4g
d. gim 3,6g
e. tng 3,6g
b) Mt hn hp A gm 0,12 mol C2H2 v 0,18 mol H2. Cho A qua Ni nung nng,phn ng khng hon ton v
thu c kh B. Cho B qua bb nh dung dch Br2 d, thu hn hp kh thot ra X. t chy hon ton X ri cho ton
b sn phm vo bb nh cha dung dch Ca(OH)2 d, thu c 12 gam kt ta v khi lng bb nh tng ln 8,88
gam. Tnh tng khi lng ca bb nh dung dch Br2.
a. 0,82g
b. 2,46g
c. 1,64g
d. 3,28g
e. kt qu khc
Cu42. a) Trn 11,2 lit hn hp X gm C3H6 (chim 40%V) v C3H4 (chim 60%V) vi H2 trong bb nh kn 33,6
lit c t bt Ni ktc. Sau thi gian t chy nng bb nh v a v nhit ban u thy p sut kh trong bb nh l
2/3 atm. Bit khi cho hn hp qua dung dch mui Ag+ trong ammoniac th tch ca n gim 1/10. Hy xc nh
khoa ho HKHTN-HQGHN

thnh phn v s mol hn hp kh thu c sau phn ng:
a. C3H8 (0,5 mol) v H2 (0,5 mol)
b. C3H8 (0,9 mol) v C3H6 (0,1mol)
c. C3H8 (0,3 mol) v C3H6 (0,1 mol)
d. C3H4 (0,1 mol) v H2 (0,5 mol)
e. Kt qu khc
b) Mt hn hp R gm C2H4 v C3H6, trong C3H6 chim 71,43% v th tch. Mt hn hp X gm R v H2
vi s mol R bng 5 ln s mol H2. Ly 9,408 lit X (ktc) ung nng vi Ni xc tc, phn ng hon ton, thu
c hn hp kh Z. Bit t l mol ca 2 ankan sinh ra bng t l mol ca 2 olefin tng ng ban u.
S mol cc kh C2H6, C3H8, C2H4, C3H6 ln lt l:
a. 0,01; 0,06; 0,08 v 0,2
b. 0,03; 0,04; 0,06 v 0,22 c. 0,02; 0,05; 0,08 v 0,2
d. kt qu khc
Cu43. a) t mt hn hp gm hai hidrocacbon A, B (c M hn km nhau 28g) thb thu c 0,3 mol CO2 v
0,5 mol H2O.Cng thc phn t ca A v B ln lt l:
a. C2H6 v C3H8
b. CH4 v C4H10
c. CH4 v C2H6
d. CH4 v C3H8
b) Hp cht A c 8 nguyn t ca hai nguyn t MA < 32. Hy lp lun tbm ra cng thc ca A:
a. C4H4
b. C3H5
c. C2H6
d. Kt qu khc
Cu44. a) Hn hp D gm hp cht C2H6 v mt ankin B ( th kh) trn vi nhau theo t l mol 1:1. Thm O2
vo hn hp D c hn hp D1 c t khi so vi H2 = 18. Hy tb m cng thc phn t ca ankin B?
a. C3H4
b. C2H2
c. C4H6
d. C5H8
b) t chy 0,3 mol hn hp 2 hidrocacbon mch h ( thuc trong s 3 loi hidrocacbon paraffin, olefin v
ankin) c t l khi lng phn t l 22/13, ri cho sn phm sinh ra i vo bb nh dng dung dch Ba(OH)2 d thb
thy bb nh nng thm 46,5g v c 147,75g kt ta. hy xc nh cng thc phn t hai hidrocacbon.
a. C3H8 v C3H4
b. C2H2 v C2H6
c. C3H8 v C3H6
d. C3H8 v C2H2
Cu45. t chy hon ton mt hn hp c t l mol bng nhau ca cht C8H8 v mt hidrocacbon B trong oxit
thu c CO2 v hi nc theo t l th tch 13/10. Bit rng cht B ch to ra mt sn phm duy nht cha mt
nguyn t brom trong phn t v khi lng phn t di 152 vC. Cht B c cng thc phn t l:
a. CH4
b. C5H12
c. C3H6
d. C5H8
Cu46. t chy hon ton 3,24 gam hn hp X gm hai cht huuwx c A v B khc dy ng ng, trong s
A hn B mt nguyn t cacbon, ngi ta ch thu c H2O v 9,4g gam CO2. Bit t khi hi ca X i vi
Hidro l 13,5. Cng thc phn t ca A v b l:
a. CH4 v C2H2
b. CH4O v C2H2
c. CH2O v C2H2
d. CH2O2 v C2H2
Cu47. t chy V lit hn hp X ktc gm 2 hidrocacbon to thnh 4,4g CO2 v 1,8g H2O.
Hy cho bit hai hidrocacbon trn cng hay khc dy ng ng v thuc dy ng ng no? ( ch xt cc dy
ng ng hc trong chng trnh).
a. Cng dy ng ng c hai hidrocacbon l anken hay xicloankan
b.Khc dy ng ng: 1 ankan v 1 ankadien
c.Khc dy ng ng: 1 ankin v 1 ankan
d.Cu A + B + C u ng
Cu48. t chy hon ton mt hn hp A gm 2 hidrocacbon ( iu kin thng, th kh), c khi lng mol
phn t km nhau 28g, sn phm to thnh cho i qua bb nh ng P2O5 v bb nh CaO. Bbnh ng P2O5 nng thm
9g c n bb nh ng CaO nng thm 13,2g.
a) Cc hidrocacbon thuc dy ng ng no?
a. ankan
b. anken
c. ankin
d. aren
b) Cng thc 2 hidrocacbon l:
a. C2H4 v C4H8
b. C2H2 v C4H6
c. CH4 v C3H8
d. Kt qu khc
Cu49. t chy hon ton hn hp hai hidrocacbon ng ng hp th hon ton sn phm sinh ra bng
Ba(OH)2 d cha trong bb nh thy nng thm 22,1g v c 78,8g kt ta trng.
a) Xc inh dy ng ng ca 2 hidrocacbon, bit chng thuc mt trong ba dy ankan, anken v ankin.
a. ankan
b. ankin
c. anken
d. cu A ng
khoa ho HKHTN-HQGHN

b) Xc nh hai hidrocacbon cho, bit chng ( xp theo th t tng dn phn t khi) c trn theo t l s
mol 1:2.
a. C2H4 v C3H6
b. C2H2 v C3H4
c. C3H4 v C4H6
d. CH4 v C2H6
Cu50. A l hn hp kh (ktc) gm 3 hidrocacbon X, Y, Z thuc 3 dy ng ng. B l hn hp O2 v O3 c t
khi so vi hidro bng 19,2. t chy 1 mol hn hp A cn 5 mol hn hp B, thu c CO2 v hi nc c
s mol nh nhau.
Khi cho 22,4 lit hn hp A i qua bb nh nc brom d thy c 11,2 lit kh bay ra, khi lng bb nh nc brom tng
27g, c n khi cho 22,4 lit hn hp A i qua dung dch AgNO3 trong NH3 thy to thnh 32,4g kt ta vng. Cc
kh o c ktc. Ba hidrocacbon trong hn hp l:
a. C3H8, butin-1 v butadiene-1
b. C4H10, butin-1 v butadiene-1
c. C5H12, butin-1 v butadiene-1 hoc butadiene 1-3
d. Kt qu khc
Cu51. Mt hn hp X gm hidrocacbon lien tip nhau trong dy ng ng c khi lng 10,5g v c th tch
hn hp l 2,352 lit 109,2oC v 2,8at. H nhit xung 0oC, mt s hidrocacbon (c s C 5) ha lngconf
li hn hp Y c th tch 1,24 lit 2,8at. T khi hi ca hn hp Y so vi khng kh bng 1,402. Tng phn t
khi ca hn hp bng 280.Xc nh dy ng ng ca hidrocacbon, bit rng phn t khi ca cc cht sau
cng bng 1,5 ln phn t khi ca cht th 3.
a. anken
b. arken
c. ankadien
aren
Cu52. Mt hn hp X gm hi hidrocacbon mch h A v H2 d c t khi hi vi Hli bng 3. Cho hn hp
X qua bt Ni nung nng trong iu kin xy ra phn ng hon ton thu c hn hp kh Y c t khi hi so
vi He bng 7,5. Bit s nguyn t cacbon trong mt mol A nh hn 7. Cng thc phn t ca A l:
a. C3H4
b. C4H4
c. C5H10
d. C3H6
Cu53. t chy hon ton hidrocacbon trong bb nh kn c th tch 10 lit bng lng khng kh gp i lng
cn thit. Sau phn ng lm lnh bb nh xung 0oC thy p sut trong bb nh l 1,948 atm.
Mt khc khi hp th lng nc sinh ra bng 25ml dung dch H2SO4 98% (D = 1,84g/cm3) s c dung dch
c nng 95,75%. Tb m cng thc phn t ca A bit n khng c ng phn.
a. C3H6
b. C2H2
c. C2H4
d. C6H6
Cu54. Cho hp cht c cng thc phn t C8H8, bit 3,12g cht ny phn ng ht vi dung dch cha 4,8g Br2
hoc vi ti a 2,688 lit H2 (ktc). Hidro ha C8H8 theo t l 1:1 c hidrocacbon cng loi X. Khi Brom ha
mt ng phn Y ca X vi xc tc bt Fe theo t l mol 1:1 c mt sn phm duy nht. Cng thc cu to
ca C8H8 l:
a. C6H4(CH3)2
b. C6H5CH=CH2
c. C6H5CH2=CH3
d. Cu b ng
Cu55. Mt hn hp hai ankan k cn trong dy ng ng c t khi hi vi H2 l 24,8.
a) Cng thc phn t ca hai ankan l:
a. C2H2 v C3H4
b. C2H4 v C4H8
c. C3H8 v C5H12
d. Kt qu khc
b) Thnh phn % th tch, thnh phn hn hp l:
a. 30% v 70%
b. 35% v 65%
c. 60% v 40%
d. Cng 50%
Cu56. ktc c mt hn hp kh hidrocacbon no A v B t khi hi so vi hidro l 12 (dhh/H2 = 12).
a) Tb m khi lng CO2 v hi nc sinh ra khi t 15,68 lit hn hp ( ktc)
a. 24,2g v 16,2g
b. 48,4g v 32,4g
c. 40g v 30g
d. Kt qu khc
b) Cng thc phn t ca A v B l:
a. CH4 v C2H6
b. CH4 v C3H8
c. CH4 v C4H10
d. C ba cu a + b + c
Cu57. Mt hn hp gm 2 kh hidrocacbon mch h. T khi hi hn hp so vi H2 l 17. ktc 400cm3 hn
hp tc dng va vi 71,4cm3 dung dch Br2 0,2M v c n li 240cm3 kh. Xc nh cng thc phn t ca hai
hidrocacbon.
khoa ho HKHTN-HQGHN

a. C2H6 v C2H2
b. C3H8 v C3H4
c. C2H6 v C3H4
d. C4H10 v C2H2
Cu58. Hn hp kh A gm hai hidrocacbon c cng s nguyn t cacbon (ktc).
a) Tb m t khi hi ca hn hp A i vi Nito, bit rng 560cm3 hn hp nng 1,3625g.
a. 1,9
b. 2
c. 1,6
d. kt qu khc
b) t chy Vcm3 hn hp A cho cc sn phm phn ng ln lt qua bb nh 1 ng P2O5 v bb nh 2 ng Ba(OH)2
thy khi lng bb nh 1 tng 2,34g v bb nh 2 tng 7,04g. Xc nh cng thc phn t ca cc hidrocacbon bit
rng c mt hidrocacbon l olefin.
a. C4H8 v C4H6
b. C4H8 v C4H4
c. C4H8 v C4H2
d. C ba cu a + b + c
o
Cu59. Cho 10 lit hn hp kh ( 54 C v 0,8064 atm) gm hai anken li qua bb nh ng nc brom d thy
khi lng bb nh nc brom tng ln 16,8g.
a) Tnh tng s mol ca 2 anken.
a. 0,1 mol
b. 0,2 mol
c. 0,3 mol
d. Kt qu khc
b) Hy bin lun cc cp anken c th c trong hn hp kh ban u bit rng s nguyn t C trong mi anken
khng qu 5.
a. C5H10 v C2H4
b. C5H10 v C3H6
c. C5H10 v C4H8
d. C hai cu a + b
Cu60. Cho 1232cm3 hn hp gm ankan A v anken B th kh ( s nguyn t C trong A, B nh nhau) vo
nc brom d thy khi lng bb nh tng thm 1,4g. t chy hon ton cht kh sau khi qua nc brom v cho
sn phm chy vo dung dch NaOH d thu c 180ml dung dch mui 0,5M. Cng thc phn t ca A, B l:
a. C2H4 v C2H6
b. C3H8 v C4H8
c. C4H8 v C5H12
d. C2H4 v C4H10
Cu61. Mt hn hp gm ankan v ankin. t chy hon ton hn hp ny thu c 12,6g H2O. Khi lng
oxi cn dung cho phn ng l 36,8g. Th tch CO2 sinh ra bng 8/3 th tch hn hp kh ban u.
a) Tng s mol ca hn hp ban u l:
a. 0,3 mol
b. 0,2 mol
c. 0,4 mol
d. Kt qu khc
b) Xc nh cng thc cu to c th ca ankan v ankin.
a. C3H8 v C2H2
b. C2H6 v C3H4
c. C4H10 v C2H2
d. C hai cu b + c
Cu62. Mt hn hp gm hai hidrocacbon mch h. Cho 840ml hn hp li qua dung dch brom d thb c n li
560ml, ng thi c 2g Br2 tham gia phn ng. Ngoi ra nu t chy hon ton 840ml hn hp ri cho kh CO2
qua dung dch Ca(OH)2 d thb c 6,25g kt ta (cc kh o ktc).
Cng thc phn t ca 2 hidrocacbon l:
a. CH4 v C4H10
b. C2H6 v C3H6
c. CH4 v C3H6
d. Kt qu khc
chuyn bi tp 05: ancol, anhit, xeton
1/ bi tp ancol
Cu 1: C bao nhiu ancol no bc 2, n chc mch h, l ng phn cu to ca nhau m phn t ca chng
c phn trm khi lng C l : 68,18%
Cu 2: Mt loi go cha 75% tinh bt. Ly 78,28 kg go ny i nu ru etylic
, hiu sut pu ca c qu
trnh l 60%. Khi lng ring ca ru etylic l 0,8 g/ml. Th tch ru
thu c l?
Cu 3: t chy hon ton 27,6 gam hn hp X gm
thu c 32,4 gam
v V lt
(ktc). Gi tr ca V l
Cu 4: Tch nc hn hp ng mol X gm metanol v etanol
c
c, thu c sn phm ete
v 1.8 gam nc vi hiu sut 70%.Khi lng hn hp X l
Cu 5: Oxi ha 6g ru n chc thu c 8,4g hn hp gm andehit, ru d v nc. Hiu sut phn
ng OXI ha ru t bao nhiu %
khoa ho HKHTN-HQGHN

Cu 6: Cho m gam mt ancol no, n chc X qua bnh ng
d nung nng.Sau khi phn ng hon ton.
khi lng cht rn trong bnh gim 0.32g.Hn hp hi thu c c t khi i vi
l 15.5
Cu 7: Cho 1,52g hn hp hai ancol n chc l ng ng k tip nhau tc dng vi Na va , sau phn ng
thu c 2,18g cht rn. Cng thc phn t ca hai ancol l
Cu 8: Hn hp X gm ancol metylic v ancol no, n chc A. Cho 7,6g X tc dng vi Na d thu c 1,68 lt
(ktc), mt khc oxi ha hon ton 7,6g X bng CuO ( ) ri cho ton b sn phm thu c tc dng vi
dung dch
d thu c 21,6g kt ta. Cng thc cu to ca A l:
Cu 9: t chy hon ton m gam hn hp X gm hai ancol A v B thuc cng dy ng ng thu c 6,72 lt
v 7,65g
. Mt khc khi cho m gam hn hp X tc dng vi Na d thu c 2,8 lt
. Bit t khi
hi ca mi cht so vi hiro u nh hn 40, cc th tch kh o ktc. A v B c cng thc phn t ln lt l
Cu 10: un 132,8g hn hp 3 ancol no, n chc vi
c
thu c hn hp gm cc ete c
s mol bng nhau v c khi lng l 111,2g. S mol ca mi ete trong hn hp l gi tr no di y ?
Cu 11: t chy hon ton 0,3 mol hn hp X gm 2 ru lin tip trong dy ng ng Cu 24: Oxi ha ht
0,2 mol ru n chc A, B lin tip trong dy ng ng bng CuO un nng c hn hp X gm 2 anhit.
Cho X tc dng vi lng d dung dich
c
v 0,5 mol
c 54g bc. A, B l 2 ru no ?
. Cng thc phn t 2 ru trn ln lt l?
Cu 12: Dn 4g hi ru n chc A qua CuO nung nng c 5,6g hn hp hi. A l ru c cng thc cu
to
Cu 13: Khi phn tch cht hu c A (cha C,H,O) th c
. Ly hai ru n chc X,
Y em un nng vi
c nhit thch hp th thu c A.Cng thc (mch h) A, X, Y (bit A l
ete) l
Cu 14: Ru A tc dng vi
d cho mt th tch
bng vi th tch hi ru A dng. Mt khc t
chy ht mt th tch hi ru A thu c cha n ba th tch kh
(cc th tch o cng iu kin).
Ru A c tn gi
Cu 15: Mt hn hp X gm 2 ru no n chc A, B ng ng k tip. t chy 0,2 mol X cn 10,08 lt
(dkc). Cng thc phn t v s mol ca A v B l
Cu 16: Hn hp A gm 2 ru. un nng m gam hn hp A vi
m c, thu c 3,584 lt hn hp
2 olefin k tip nhau trong dy ng ng (ktc). Nu em t chy ht lng olefin ny, ri cho hp th sn
phm chy trong bnh ng dung dch NaOH d, th khi lng bnh tng 24,18g. Cc phn ng xy ra hon
ton. Tr s ca m l
khoa ho HKHTN-HQGHN

Cu 17: Mt ru no a chc mch h X, c n nguyn t cacbon v m nhm
vi
d, thu c 0,1 mol kh
. Biu thc lin h gia n v m l
. Cho 7,6 gam X phn ng
Cu 18: Cho hn hp X gm ancol etylic v ancol Y thuc dy ng ng ca ancol etylic, cho 0.76 gam X tc
dng ht vi Na thy thot ra 0,168 lt kh (kc), cho bit t l s mol ca ancol etylic v ancol Y l 2:1, cng
thc phn t ca ancol Y l
Cu 19: Hn hp ru X gm 2 ru no mch h A v B c cng s nguyn t C trong phn t. Chia 14.7gam
X thnh 2 phn bng nhau:
- Phn 1 tc dng ht vi Na to ra 1.68lit
(ktc)
- Phn 2 t chy hon ton, sinh ra 14,85gam kh

C my cp ru tho mn iu kin trn
Cu 20: t chy hon ton 5,6 lt hi 2 ru no, n chc thu c 7,84 lt
Dn ton b sn phm chy vo bnh ng 200 ml dung dch
(cc th tch u o ktc).
1,5M. Khi lng dung dch sau phn
ng so vi khi lng dung dch

Cu 21: Hn hp A gm 0,1 mol etylenglicol v 0,2 mol cht X . t chy hon ton hh A cn 21,28 l
thu c 35,2g
v 19,8g
.Tnh khi lng phn t X ( X cha C, H ,O)
Cu 22: un nng mt hn hp gm 2 ru vi
hp 3 ete c s mol bng nhau. Cng thc hai ru l?
thu c 21,6gam
v 72gam hn
Cu 23: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23.

Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn
hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng
d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Tnh phn trm khi lng ca propan-1-ol trong X
Cu 25: Cho 7,8 gam hn hp 2 ancol n chc k tip nhau trong dy ng ng tc dng ht vi 4,6 gam Na
c 12,25 gam cht rn. Xc nh CTPT ca 2 ancol
Cu 29: un nng hn hp hai ankanol lin tip trong dy ng ng vi H 2SO4 c 1400C, thu c 21,6
gam H2O v 139,2 gam hn hp ba ete c s mol bng nhau.Xc nh CTPT ca hai ankanol
Cu 30 : un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi
H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Xc
nh cng thc phn t ca hai ru trn
Cu 31 : un nng ancol n chc X vi H2SO4 c 140oC thu c Y. T khi hi ca Y i vi X l
1,4375. Xc nh CTPT ca X
khoa ho HKHTN-HQGHN

Cu 32: Khi un nng mt ancol n chc no A vi H2SO4 c iu kin nhit thch hp thu c sn
phm B c t khi hi so vi A l 0,7. Xc nh cng thc ca A.
Cu 33: Cho 12,9g hn hp 3 ancol no, n chc, mch h tham gia phn ng tch nc iu kin thch hp
thu c hn hp X gm 2 kh l ng ng k tip, c t khi so vi hn hp ancol ban u l 0,651
a. Xc nh CTPT ca cc ancol
b. Nu cho ton b lng ancol trn phn ng vi CuO un nng, sn phm thu c cho tc dng vi lng d
ddAgNO3/NH3 d thu c 37,8g kim loi bc. Xc nh phn trm khi lng mi ancol trong hn hp ban
u
cu 34: t chy han tan m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c
8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H 2SO4 c tnh tng khi lng
ete ti a thu c.
A. 7,85 gam. B. 7,40 gam. C. 6,50 gam.
D. 5,60 gam
cu 35: un nng hn hp hai ancol n chc, mch h vi H 2SO4 c, thu c hn hp gm cc ete. Ly
7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO 2 ( ktc) v 7,2 gam H2O. Xc
nh CTPT ca hai ancol
Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y) l ng ng k tip thnh
hai phn bng nhau:
- t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O.
o
- un nng phn 2 vi H2SO4 c 140 C to thnh 1,25 gam hn hp ba ete. Ho hi hon ton hn hp ba
ete trn, thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut). Tnh
hiu sut phn ng to ete ca X, Y .
A. 25% v 35%.
B. 20% v 40%.
C. 40% v 20%.
D. 30% v 30%.
Cu 36: Trong mt bnh kn dung tch 16 lt cha hn hp hi ca 3 ancol n chc, k tip nhau trong dy
ng ng. Gi nhhit bnh 136,5 0C ri bm thm vo bnh 17,92g oxi, thy p sut bnh t 1,68 atm. Bt
tia la in t chy ht hn hp, sn phm chy cho qua bnh ng dung dch Ca(OH)2 d thy khi lng
bnh tng ln 22,92g, ng thi xut hin 30g kt ta.
a. Nu sau khi bt tia la in t chy ht hn hp, gi bnh 2730C, th p sut trong bnh l bao nhiu?
b. Xc nh cng thc ca 3 ancol
2/ bi tp anhit
Phn t lun
Bi 1: vit phng trnh phn ng xy khi cho : Etanal; mtanal ; tanial ln lt tc dng vi cc cht :
H2/Ni,t ; AgNO3/NH3 ; NaHSO3 ; O2 ; Cu(OH)2/H+ ; Cu(OH)2/NaOH
Cho nh n xt t l mol ca cc cht , hi n tng quan st c .
Bi 2: X, Y l hai hp cht hu c ng chc thnh cha C,H,O khi cho tc dng vi AgNO3/NH3 th 1mol X
ho c Y u ta ra 4 mol Ag. Cn khi t chy X,Y th s mol O2 v CO2, H2O to thnh c t l tng ng l:
- i vi X cho t l 1:1:1
- i vi Y cho t l 1,5 : 2: 1
Xc nh cng thc ca X,Y . Vit phng trnh phn ng iu ch X,Y t anken tng ng, gi thit rng cc
cht v c v iu ki n cn thit c sn.
Bi 3: X l hn hp gm 2 ankanal A,B c tng s mol l 0,25 mol. Khi cho hn hp X tc dng vi dung dch
AgNO3/NH3 d th thu c 86,4 gam Ag v khi lng dung dch gim 77,5 gam .
1. Chng minh bng hai cch khc nhau hn hp X c mtanal.
2. Gi tn anhit cn li ,tinhs s mol mi cht.
Bi 4: Chuyn ha 4,2 gam anhit A mnh h bng phn trng gng vi dung dch AgNO3/NH3 d thu c
hn hp mui B. Nu cho lng Ag thu c tan ht trong dung dch HNO3 gii phng 3,792 lt NO2 270C
khoa ho HKHTN-HQGHN

740mmHg . T khi hi ca A so vi N2 nh hn 4. Mt khc cng lng A trn tc dng 0,5mol H2 c Ni,to thu
c cht C vi hiu xut 100% > Ha tan C vo nc c dung dch D, ly 1/10 dung dch D tc dng vi
Na d gii phng 12,04 lt khi H2(KTC) .Tm cng thc ca A ,B, C v tnh nng % ca cht C trong dung
dch D.
Bi 5: Cho bay hi ht 5,8 gam mt cht hu c X thu c 4,48 lt hi X 109 0C v 0,7atm. Mt khc 5,8
gam cht X phn ng trng gng vi AgNO3/NH3 d thu c 43,2 gam Ag . Tm CTPTcuar X.
Bi 6: Mt hn hp gm 2 anht X,Y ng ng k tip nhau ca anehit no n chc, mch h khc HCHO
ly 2,04 gam hn hp ny thc hin phn ng trng gng vi dung dch AgNO3/NH3 d thu c 8,64 gam Ag
kim loi hiu xut ca phn ng 100% .
Xc nh CTPT ca 2 aneht.
Bi 7: Cho 13,6 gam mt anht X tc dng va vi 300ml dung dch AgNO3/NH3 thu c 43,2 gam Ag.
Xc nh ctct ca X bit t khi hi ca X so vi O2 l 2,125.
Bi 8 : A l hp cht hu c thnh phn ch ca C,H,O trong phn t trong lng O2 chim 37,21 % v khi
lng . A ch cha mt loi nhm chc, khi cho 1mol A tc dng vi dung dch AgNO3/NH3 th thu c 4mol
Ag ., Xc inh CTCT ca A.
Bi 9: X l hp cht thnh phn ch cha C,H,O . Khi t chy hon ton 0,03 mol cht X thu c 2,016 lt
CO2 ktc . Mt khc khi Hydr ha hon ton 0,15 mol X cn dng ht 3,36 lt H 2 o 00C, 2atm thu c
ru no. Xc nh CTCT ca X .Bit rng X tc dng vi dung dch AgNO3/NH3 d thu c Ag
BI TP TRC NGHIM ANEHIT XETON
Cu 2: Cho 2,44 g hn hp A gm hai andehit no, n chc c phn t khi hn km nhau 14 vc tc dng vi
dung dch AgNO3 trong NH3 sinh ra 6,48 g Ag. CTPT cc cht trong hn hp A l:
A. C2H5CHO, C3H7CHO
B. C3H7CHO, C4H9CHO
C. C4H9CHO, C5H11CHO
D. C5H11CHO,
C6H13CHO
Cu 3: t chy mt hn hp cc ng ng ca anehit ta thu c nCO2= nH2O. Cc cht thuc ng ng
no trong cc cht sau?
A. Anehit n chc no
B. Anehit vng no
C. Anehit hai chc no D. Anehit khng
no n chc
Cu 4: Cho Andehit c CTCT: CH3-CH(C2H5)-CH2-CH(CH3)-CH2-CHO. Theo danh php IUPAC andehit trn
c tn gi l:
A. 5-etyl-3-metylhexanal
B. 3,5-dimetylhept-7-al
C. 3,5-dimetylheptanal
D.
2-etyl-4metylheptanl
Cu 5: CH3CHO phn ng vi nhng cht no?
A. H2, CuO, H2O
B. dung dch Br2, Na
C. Na, O2, dung dch Cu(OH)2
D. H2,
dung dch AgNO3/NH3
Cu 6: Mt hn hp X gm hai anehit A, B n chc. Cho 0,25 mol hn hp X tc dng vi dung dch
AgNO3/NH3 d to ra 86,40 gam kt ta. Bit MA < MB. A ng vi cng thc phn t no di y?
A. C2H3CHO.
B. HCHO.
C. CH3CHO.
D. C2H5CHO.
Cu 14: Hp cht A c cng thc C nH 2n+2-2a-k(CHO)k vi gi tr no ca n, k, a khi A tc dng vi kh hiro
cho ancol propylic theo th t n, k, a l: A. 3, 1, 1
B. 2, 2, 0
C. 2, 1, 0
D. 3, 1, 2
Cu 15: Tin hnh oxi ha 2,5 mol ru metylic thnh fomanehyt bng CuO ri cho fomanehit tan ht vo
nc thu c 160g dd fomalin 37,5%. Vy hiu sut phn ng oxi ho l bao nhiu A. 90% B. 80%
C.
70%
D. 60%.
Cu 16: CH3CHO c th iu ch trc tip t: A. C2H5OH
B. C2H2
C. CH3COOCH=CH2
D. A,
B, C ng
khoa ho HKHTN-HQGHN

Cu 17: Cho 0,1 mol hn hp 2 anehit l ng phn ca nhau c khi lng phn t nh hn 68 vC phn ng
hon ton vi dung dch AgNO3 (d) trong NH3 cho 38,88 gam Ag (hiu sut 100%). Cng thc phn t ca 2
anehit l:
A. CH3CHO v HCHO
B. C2H5CHO v C2H3CHO C. HOC-CHO v C2H5CHO D. HOC-CH2-CHO v
C3H7CHO
Cu 18: Oxi ho 2,2 gam mt anehit n chc X thu c 3,0 gam axit tng ng (hiu sut phn ng bng
100%). X c cng thc cu to no di y?A. CH3CHO. B. CH3CH2CH2CHO.
C. CH3CH(CH3)CHO.
D. C2H5CHO.
Cu 19: Cho 1,97g fomalin tc dng vi AgNO3 d (NH3) c 5,4g Ag. C% ca HCHO trong fomalin l:
A. 19,03%
B. 38,07%
C. 40%
D. 27%
Cu 20: Cho 2,4 gam mt hp cht hu c X (cha C , H , O) tc dng hon ton vi dung dch AgNO 3 d
trong NH3 thu c 7,2 gam Ag . Xc nh cng thc cu to thu gn ca X:A. CH3CHO
B. C2H5CHO
C. HCHO
D. C3H7CHO
Cu 21: T khi hi ca mt anehit X i vi hiro bng 28. Cng thc cu to ca anehit l:
A. CH3CHO
B. CH2=CH-CHO
C. HCHO
D. C2H5CHO
Cu 22: iu no sau y khng ng?
A. Xeton kh b oxi ha
B. Andehit va th hin tnh kh va th hin tnh
oxi ha
C. Tt c cc andehit u tham gia phn ng trng bc theo t l n Andehit : nAg = 1 : 2
D. Xeton cng hp hidro
to ru bc 2
Cu 24: Cc anehit th hin tnh oxi ha trong phn ng vi cht:
A. H2/Ni, to.
B. AgNO3/NH3.
C. Cu(OH)2/NaOH.
D. O2
Cu 25: C th dng dung dch AgNO3/NH3 phn bit nhng cp cht no?
A. CH3CHO v CH3CH2OH
B. HCOOH v CH3COOH C. C6H5OH v CH3OCH3
D. C A, B
Cu 27 : Cho 3,6 gam ankanal X phn ng hon ton vi dung dch AgNO 3/NH3 , lng Ag sinh ra cho tc
dng ho ton vi dung dch HNO3 c thu oc 2,8 lt kh NO2 ( sn phm kh duy nht 136,50C , p sut
1,2 atm) . Cng thc phn t ca ankanal l: A. HCHO
B. CH3CHO
C.
C2H5CHO
D. Kt qu khc
Cu 29 : Hp cht hu c X c cng thc phn t C4H6O2 v ch cha mt loi nhm chc . T X v cc cht
v c khc , bng 3 phn ng lin tip c th iu ch c cao su Buna . Cng thc cu to c th c ca X l :
A. O=CH-CH2-CH2-CH=O B. HO-CH2-C=C-CH2-OH
C. CH3-CO-CO-CH3
D. C A , B ,
C u ng
Cu 30 : Ly 0,94 gam hn hp hai andehit no , n chc , k tip trong cng mt dy ng ng tc dng ht
vi dung dch AgNO3/NH3 d thu c 3,24 gam Ag . Cng thc phn t hai andehit l :
A. HCHO v CH3CHO
B. CH3CHO v C2H5CHO
C. C2H5CHO v C3H7CHOD. C3H7CHO v
C4H9CHO
Cu 31 : Hp cht hu c X khi un nng nh vi dung dch AgNO 3/NH3 (d) thu c sn phm Y . Y tc
dng c vi dung dch HCl hoc dung dch NaOH u cho 2 kh v c . Hp cht X l
A. HCHO
B. HCOOH
C.HCOONH4
D. C A , B , C u
ng
Cu 33 Cho 47,84 gam ru etylic tc dng vi hn hp K2Cr2O7/H2SO4 . Sn phm ca phn ng c tch
ngay ra khi mi trng phn ng bng phng php chng ct v dn vo dung dch AgNO 3/NH3 d . Sau khi
kt thc phn ng , thu c 124,2 gam Ag . Tnh hiu sut ca phn ng oxi ho ru etylic: A. 55,29%
B. 70,12%
C. 75,53% D. Kt qu khc

khoa ho HKHTN-HQGHN

Cu 34 : Mt cht h c Y cha C, H, O. Khi t chy hon ton 0,1 mol Y cho 6,72 lt CO 2 (ktc). Mt khc,
hiro ho hon ton 0,05 mol Y ngi ta dng ng 1,12 lt kh H2 (00C, 2 atm) v c ru no, n chc
Z. Bit rng X tc dng c vi AgNO3/NH3 cho Ag. Cho bit cng thc cu to ng ca Y?
A. CHCHO
B. C2H5CHO
C. CH2=CH-CHO
D. Kt qu khc
Cu 36 : Dng nhng ha cht no phn bit cc cht: andehit axetic, ancol etylic, glixerol, dimetyl ete?
A. dung dch AgNO3/NH3, Cu(OH)2, Na
B. dung dch AgNO3/NH3, CuO
C. Na, dung dch KMnO4
D. dung dch Br2 , Cu(OH)2
Cu 37 : ng vi CTPT C3H6O s c bao nhiu ng phn mch h: A. 1 B. 2 C. 3 D. 4
Cu 38 : Cho hp cht hu c X (phn t ch cha C , H , O v mt loi nhm chc) . Bit khi cho 5,8 gam X
tc dng vi dung dch AgNO3 d trong NH3 to ra 43,2 gam Ag . Mt khc 0,1mol X sau khi c hidro ha
hon ton phn ng va vi 4,6 gam Na . Cng thc cu to ca X l A. HCOOH
B. CH 3CHO
C. O=CH-CH=O
D. CH2=CH-CHO
Cu 39 : Cho 13,6 gam mt hp cht hu c X cha C , H , O tc dng va vi 300ml dung dch AgNO 3
2M trong NH3 thu c 43,2 gam Ag . Bit t khi hi ca X so vi oxi bng 2,125 . Xc nh cng thc cu to
ca X
A. CH3CH2CHO
B. CH2=CH-CH2-CHO
C. CHC-CH2CHO D.
CHCCHO
Cu 40 : Mt hp cht hu c Y cha cc nguyn t C , H , O ch cha mt loi nhm chc . khi cho 0,01 mol
Y tc dng vi dung dch AgNO 3 trong NH3 d thu c 4,32 gam Ag . Y c cu to mch thng v cha
37,21% oxi v khi lng . Cng thc cu to ng ca Y l: A. HCHO
B. CH 3CHO
C.
O=CH-CH=O
D. O=CH-(CH2)2CH=O
Cu 41 : Cho 0,1 mol andehit X tc dng hon ton vi H 2 th cn 6,72 lt H2(ktc) v thu c sn phm Y .
Cho ton b lng Y tc dng vi Na d thu c 2,24 lt kh H 2(ktc) . Mt khc ly 8,4 gam X tc dng vi
dung dch AgNO3 d thu c 43,2 gam Ag . Xc nh cng thc cu to ca X v Y
A. CH3CHO v C2H5OH
B. C2H2(CHO)2 v HOCH2CH(CH3)CH2OH
C. C2H2(CHO)2 v HO-CH2(CH2)2CH2OH
D. C B v C
Cu 42 : CxHyO2 l mt anehit mch h, no, 2 chc khi: A. y = 2x
B. y= 2x + 2
C. y = 2x 2
D.
y = 2x 4
Cu 43 : Cho 2,4 gam mt hp cht hu c X (cha C , H , O) tc dng hon ton vi dung dch AgNO 3 d
trong NH3 thu c 7,2 gam Ag . Xc nh cng thc cu to thu gn ca X:A. CH3CHO
B. C2H5CHO
C. HCHO
D. C3H7CHO
Cu 44 : Cho 3 hp cht hu c X , Y , Z . Bit X cha 3 nguyn t C, H ,Cl trong clo chim 71,72% theo
khi lng . Y cha 3 nguyn t C , H , O trong oxi chim 55,71% theo khi lng . Khi thu phn X trong
mi trng kim hoc hidro ho Y u thu c hp cht Z . Xc nh cng thc cu to ca X , Y , Z
A. CH3Cl , HCHO , CH3OH B. C2H5Cl , CH3CHO , C2H5OH
C. C2H4Cl2 , (CHO)2 , C2H4(OH)2 D. Kt
qu khc
Cu 45 : X l hp cht hu c mch h n chc cha C , H , O . t chy hon ton 1 mol X cn 4 mol oxi v
thu c CO2 v hi H2O c th tch bng nhau (o cng iu kin nhit v p sut) . Xc nh cng thc
cu to c th c ca X
A. CH3-CH2-CHO hoc (CH3)2CO B. CH2=CH-CH2-OH
C. CH2=CH-O-CH3
D. c A , B , C
Cu 46 : t chy 2,9 g mt andehit X thu c 6,6 g CO2 v 2,7 g H2O. Vy X c cng thc cu to thu gn
l:
A. CH3CHO
B. C2H5CHO
C. HCHO
D.
(CHO)2
Cu 47 : t chy hon ton 0,6 g HCHO v 1,74 g C 2H5CHO ri cho sn phm chy i qua bnh ng dung
dch Ba(OH)2 thy khi lng bnh tng thm m gam. Gi s Ba(OH)2 hp th ht CO2 v H2O. Gi tr m l:
khoa ho HKHTN-HQGHN

A. 1,98
B. 6,82
C. 11,16
D. 2,48
Cu 48 : Cho 14,6g hn hp 2 anehit no n chc ng ng lin tip nhau tc dng ht vi H 2 to ra 15,2g
hn hp 2 ancol. Cng thc ca 2 anehit l
A. HCHO, CH3CHO
B. CH3CHO, C2H5CHO
C. C2H5CHO, C3H7CHO
D. C3H7CHO,
C4H9CHO
Cu 49 : C th dng nc Brom phn bit
A. Andehit no v xeton no B. Andehit no v ru khng no
C. Phenol v anilin D. A hoc C
.
Chuyn Este; lipit; axit cacboxylic

a. Bi ton xc nh CTCT ca 1 este.
Bi 1. Este n chc X c t khi hi so vi CH 4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH
1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Xc nh cng thc cu to ca
X.
Bi 2. Mt este to bi axit n chc v ancol n chc c t khi hi so vi CO 2 bng 2. Khi un nng este
ny vi dung dch NaOH to ra lng mui c khi lng ln hn lng este phn ng . Xc nh CTCT
ca este.
Bi 3. Mt este n chc X c phn t khi l 88 vC. Cho 17,6 gam X tc dng vi 300 ml dung dch NaOH
1M. Khi phn ng xy ra hon ton, c cn dung dch sau phn ng thu c 23,2 gam cht rn khan. Xc nh
cng thc cu to ca X.
Bi 4. Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2
( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng
hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Xc nh CTCT ca X
Bi 5. t chy 1,6 gam mt este X n chc thu c 3,52 gam CO 2 v 1,152 gam H2O. Cho 10 gam X tc
dng vi dung dch NaOH (va ), c cn dung dch sau phn ng thu c 14 gam mui khan Y. Cho Y tc
dng vi axit v c long thu c Z khng phn nhnh. Xc nh cng thc cu to ca Z
Bi 6. Thy phn 1 este n chc no E bng dung dch NaOH thu c mui khan c khi lng phn t bng
24/29 khi lng phn t E.T khi hi ca E i vi khng kh bng 4. Xc nh CTCT ca E.
Bi 7. Cho 0,1 mol este X n chc vo 100 gam dung dch NaOH 8%, un nng phn ng thy phn hon
ton thu c 110 gam dung dch. C cn dung dch sau phn ng thu c 14,8 gam cht rn khan. Hy cho
bit X c th c bao nhiu cng thc cu to ?
Bi 8. un nng 10 gam este X n chc vi 200 ml dung dch NaOH 1,5M (ly d). C cn dung dch sau
phn ng thu c cht rn G c khi lng 17,4g v mt ancol Y. hirat ha Y thu c 2,24 lt anken.
(Hiu sut tch nc t 100%). Xc nh CTCT ca X
Bi 9. Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th
lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. Xc nh CTCT
ca X
Bi 10. un nng hp cht X vi H2O (xc tc H+) c axit hu c Y v ancol Z n chc. Cho hi Z i qua ng
ng CuO, t0 c hp cht T c kh nng tham gia phn ng trng bc. t chy hon ton 2,8 gam X phi dng ht
d Y 2,57
VCO2 : VH2O 3 : 2
N2
3,92 lt oxi ( ktc), c kh CO2 v hi nc theo t l th tch:
. Bit
.
Bi 11. Mt este n chc X bit dX/O2 = 3,125 . Xc nh CTCT ca X trong mi trng hp sau:
a. 20 gam X tc dng vi 300 ml dd NaOH 1M . C cn dd sau phn ng thu c 23,2 gam b
rn.
khoa ho HKHTN-HQGHN

b. 0.15 mol X tc dng va vi dd NaOH . C cn dd sau phn ng thu 21 gam mui khan
( mch khng nhnh )
b.Bi ton xc nh CTCT ca 2 este trong hn hp.

Bi 1. Hai este l ng phn ca nhau do cc axit no n chc v ancol no n chc to thnh. x phng ha
22,2 gam hn hp hai este phi dng ht 12 gam NaOH nguyn cht. Cc mui thu c c khi lng 21,8
gam. Xc nh CTCT ca hai este ?
Bi 2. X l hn hp hai este l ng phn ca nhau. cng iu kin 1 lit hi X nng gp hai ln 1 lit O 2 .Thy
phn 35,2 gam X bng 4 lit dd NaOH 0,2M c dd Y . C cn ddY thu c 44,6 gam cht rn khan . Bit hai
este do ancol no n chc v axit no n chc to thnh. Xc nh CTCT ca cc este ?
Bi 3. Hn hp y l hai este n chc mch h l ng phn ca nhau . Cho m gam Y tc dng va vi 100
ml dd NaOH 0,5M thu c mt mui v hn hp hai ancol. t chy hon ton m gam Y cn 5,6 lit O 2 4,48 lit
CO2 (u ktc). Xc nh CTCT ca hai este trong Y ?
Bi 4. Hn hp E gm hai cht hu c A , B cng chc. un 13,6 gam E vi dd NaOH thu c sn phm gm
mt mui duy nht ca mt axit n chc ,khng no v hn hp hai ancol no n chc k tip nhau . t hon
ton 27,2 gam E cn dng ht 33,6 lit O2 thu c 29,12 lit CO2 v H2O ( cng ktc ). Xc nh CTPT ca A
v B ?
Bi 5. Hn hp X gm 2 este n chc A, B. Cho 19,9 gam hn hp X phn ng vi NaOH va th thu c
20,5 gam mt mui v hn hp hai ancol ng ng k tip. Cho hn hp 2 ancol thu c phn ng vi Na d
th thy c 2,8 lt H2 (ktc). Xc nh CTCT ca A, B.
Bi 6. Hn hp X gm 2 este n chc A, B. un nng 16,2 gam hn hp X vi NaOH va th thu c 15
gam hn hp 2 mui ca 2 axit ng ng k tip v mt ancol. t chy hon ton lng ancol thu c th
thy to ra 17,6 gam CO2 v 10,8 gam H2O. Xc nh CTCT ca A, B.
c.Hai cht hu c A, B phn ng vi NaOH Mui + ancol

Bi 1. Mt hn hp X gm hai cht hu c A, B (cha C, H, O) u n chc. Cho hn hp X phn ng va
vi 100ml dd NaOH 5M thu c 43,8 gam hn hp hai mui ca hai axit no n chc v mt ancol no n
chc Y . Cho ton b Y tc dng ht vi vi Natri thu c 3,36 lit H 2 (ktc). Xc nh CTCT ca A, B bit
MB= MA + 28
Bi 2. Cho 13,4 gam hn hp M gm hai cht hu c n chc X , Y ( ch cha C ,H ,O ) tc dng va vi 4
gam NaOH thu c mui ca mt axit hu c n chc v 9,2 gam mt ancol. Lng ancol thu c cho tc
dng vi Na d thy thot ra 2,24 lit kh H2 (ktc). Xc nh CTCT ca X, Y
Bi 3. Hn hp X gm 2 cht hu c n chc. Cho 0,1 mol hh X tc dng va 0,1 mol NaOH, c cn dung
dch sau phn ng thu c 7,36 gam hn hp mui v ancol Y. Oxi ha hon ton ancol Y bng CuO thu c
anehit. Cho ton b lng anehit tc dng vi AgNO 3/ NH3 thu c 25,92 gam Ag. Xc nh cng thc
ca 2 cht trong hn hp X.
Bi tp axit cacboxylic
Bi 1: iu khng ng khi ni v mt axit cacboxylic ng vi CTPT CnH2n-2O2 l trong CTCT:
A. C th mch h, 2 lin kt i
B. Ch c mt nhm COOH
C. C th cha mt vng
D. Ch cha mt lin kt i
khoa ho HKHTN-HQGHN

Bi 1.1: Cho 14,8 gam hn hp 2 axit hu c n chc tc dng vi mt lng va Na2CO3 sinh ra 2,24 lt
kh CO2 ktc. Khi lng mui thu c l:
A. 17,6
B. 19,2
C. 21,2
D. 29,1
Bi 1.2: Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch
NaOH 0,1M. C cn dung dch sau phn ng thu c hn hp rn khan c khi lng l:
A. 8,64g
B. 6,84g
C. 4,9g
D. 6,8g
Bi 2: oxi ho a gam ancol metylic bi CuO nung nng thu c hn hp kh v hi X. Chia X thnh 3 phn
bng nhau:
- Phn 1: Cho tc dng vi dung dch AgNO3/NH3 d thu c 64,8 gam Ag
- Phn 2: Cho tc dng vi dung dch NaHCO3 d sau phn ng thu c 2,24 lt kh CO2 ktc
- Phn 3: Cho tc dng vi Na d thu c 4,48 lt kh H2 ktc. Hiu sut phn ng oxi ho
CH3OH l:
A. 50%
B. 25%
C. 75%
D. 100%
Bi 3: t chy hon ton 0,44 gam mt axit hu c, sn phm chy c hp th hon ton vo bnh 1 ng
P2O5 v bnh 2 ng KOH. Sau th nghim thy khi lng bnh 1 tng 0,36g v bnh 2 tng 0,88g. CTPT ca
axit l:
A. C2H4O2
B. C3H6O2
C. C5H10O2
D. C4H8O2
Bi 3.1: t chy hon ton 13,2 gam mt axit hu c A, sn phm sau phn ng c hp th hon ton vo
dung dch Ca(OH)2 d th thu c 50g kt ta v khi lng bnh tng ln 29,2 gam. Mt khc trung ho
0,15 mol A th cn va 300 ml dung dch NaOH 1M. Vit CTCT ca A bit A c cu to mch thng.
Bi 3.2: X l mt axit hu c n chc. t chy 0,1 mol X cn 6,72 lt O2 ktc. X c tn gi l:
A. Axit axetic
B. axit propionic
C. axit butiric
D. axit acrylic
Bi 4: Hn hp X gm 2 axit no A1 v A2. t chy hon ton 0,3 mol X thu c 11,2 lt kh CO2 ktc.
trung ho 0,3 mol X cn 500 ml dung dch NaOH 1M, CTCT ca 2 axit l:
A. CH3COOH ; C2H5COOH
B. HCOOH; C2H5COOH
C. HCOOH; HOOC-COOH
D. CH3COOH ; HOOC-CH2-COOH
Bi 4.1: t chy hon ton 7,3 gam mt axit no, a chc thu c 0,3 mol CO2 v 0,25 mol nc. Xc nh
CTCT ca axit trn, bit axit c mach cacbon khng phn nhnh.
A. HOOC CH2-COOH
B. HOOC-[CH2]2-COOH
C. HOOC-[CH2]3-COOH
D. HOOC-[CH2]4-COOH
Bi 5: Axit hu c X tho mn iu kin sau. A gam X tc dng vi NaHCO3 d thu c V lt kh CO2. t
chy hon ton a gam X thu c V lt kh CO2 cng k. X l:
A. oxalic v adipic
B. fomic v oxalic
C. axetic v stearic D. fomic v axetic
Bi 6: Cho 29,8 gam hn hp 2 axit a chc tc dng va ht vi 2 lt dung dch hn hp NaOH 0,1M v
Ca(OH)2 0,1M. Khi lng mui khan thu c l
A. 31g
. 52,6g
C. 46,2g
D. 41,8g
Bi 6.1: Cho 1,16 gam axit hu c X tc dng va vi 100 ml dung dch NaOH 2M. Bit MX < 150. X c
CTCT thu gn l:
A. CH2(COOH)2
B. C2H2(COOH)2 C. (COO)2
D. CH3COOH
Bi 7: t chy hon ton m gam hn hp gm andehit fomic; axit axetic; Glucoz (C6H12O6); axit lactic
(C3H6O3). Sn phm chy thu c hp th hon toanf vvo dung dch Ca(OH)2 d thu c 40g kt ta. Gi
tr ca m l:
A. 14,1
B. 12
c. 12,4
D. Khng xc nh
Bi 8: Cho a gam hn hp lng gm axit axetic v phenol tc dng ht vi 9,2 gam Na thu c cht rn X v
3,36 lt kh H2 ktc. phn ng hon ton vi X cn ti thiu V ml dung dch HCl 0,5M. Gi tr ca V l:
khoa ho HKHTN-HQGHN

A. 200
B. 500
C. 800
D. 600
Bi 9: (TSC A 2010) Cho 16,4 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau phn ng
hon ton vi 200 ml dung dch NaOH 1M v KOH 1M, thu c dung dch Y. C cn dung dch Y, thu c
31,1 gam hn hp cht rn khan. Cng thc ca 2 axit trong X l:
A. C2H4O2 v C3H4O2
B. C2H4O2 v C3H6O2
C. C3H4O2 v C4H6O2
D. C3H6O2 v C4H8O2.
Bi 10: (TSC A 2010) Axit cacboxylic X c cng thc n gin nht l C3H5O2. Khi cho 100 ml dung dch
axit X nng 0,1M phn ng ht vi dung dch NaHCO3 (d), thu c V ml kh CO2 (ktc). Gi tr ca V l
A. 448.
B. 224.
C. 112.
D. 336
Bi 10.1: Cho 11,84 gam mt axit hu c n chc tc dng va vi dung dch NaOH, c cn dug dch sau
phn ng thu c 15,36 gam mui khan. Vy tn ca Axit l:
A. Axit axetic
B. Axit propionic
C. Axit acrylic
D. Axit fomic
Bi 10.2: Hn hp X gm 2 axit cacboxylic no, n chc ng ng k tip nhau. Cho a gam X tc dng va
vi 100 ml dung dch NaOH 2M, phn ng xong coo cn dung dch thu c 15 gam hn hp 2 mui hu c
khan. Tm CTCT ca 2 axit.
Bi 10.3: 0,1 mol mt axit n chc tc dng vi 200 ml dung dch NaOH 1M c dung dch mi. C cn
dung dch mi c 13,4 gam cht rn khan. Cng thc ca axit l:
A. axit propionic
B. axit metacrylic
C. axit acrylic
D. axit axetic
Bi 11: Hn hp X gm axit axetic, axit fomic v axit acrylic. trung ho m gam X cn 450 ml dung dch
KOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 19,04 lt kh CO2 ktc v 12,6 gam H2O.
Khi lng ca Axit acrylic trong m gam hn hp X l:
A. 10,8g
B. 7,2g
C. 14,4g
D. 3,6g
Bi 11.1: (TSH B 2010)Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X
cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO 2
(ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l
A. 0,015.
B. 0,010.
C. 0,020.
D. 0,005
Bi 12: (TSH B 2010) Hn hp Z gm hai axit cacboxylic n chc X v Y (M X > MY) c tng khi
lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt
khc, nu cho Z tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 21,6 gam Ag. Cng thc v
phn trm khi lng ca X trong Z l
A. C3H5COOH v 54,88%.
B. C2H3COOH v 43,90%.
C. C2H5COOH v 56,10%.
D. HCOOH v 45,12%.
Bi 12.1: Hn hp X gm 2 axit cacboxylic no, n chc A,B. Cho 26,8 gam Xho tan hon ton vo nc ri
chia lm 2 phn bng nhau:
- Phn 1: Phn ng ht vi dung dch AgNO3 trong NH3 ly d, thu c 21,6 gam Ag kim loi.
- Phn 2: Cn ng 100 ml dung dch KOH 2M trung ho. Tm 2 axit.
Bi 12.2: Hn hp A gm 1 axit v 2 andehit, c 3 u no, n chc. Ly m gam A tc dng ht vi dung dch
AgNO3/NH3 c 54g Ag. Dng 2m gam A tc dng vi lng d dung dch Na2CO3 thu c 0,616 lt CO2.
Mt khc phi dng 10,472 lt oxi mi t chy ht m gam A. Lng axit sau trng bc c th trung ho
c 150 ml dung dch KOH 0,5M. Hy cho bit CTPT, CTCT ca cc cht trong A. Bit cc V kh o 27,30C
v p sut 1 atm. H = 100%.

khoa ho HKHTN-HQGHN

Bi 12.3: Hn hp X gm hai axit hu c no, n chc, mch h. Trung ho 8,3 gam X bng dung dch NaOH
ri c cn dung dch sau phn ng thu c 11,6 gam mui khan. Mt khc, nu cho 8,3 gam X tc dng vi
lng d dung dch AgNO3 trong NH3 th thu c 21,6 gam bc. Cng thc ca 2 axit l:
A. HCOOH; C2H5COOH
B. HCOOH; CH3COOH
C. C2H5COOH; C3H7COOH
D. CH3COOH; C2H5COOH
Bi 13: Cho hn hp gm 0,1 mol HCOOH v 0,2 mol HCHO tc dng ht vi AgNO3 /NH3 d th khi lng
Ag thu c l : A. 108 g
B. 10,8 g
C. 64,8 g
D. 6,48 g
Bi 14: Cho 5,76 gam axit hu c n chc tc dng ht vi vi thu c 7,28 gam mui. Cho bit tn axit
trn
A. Axit axetic
B. Axit fomic
C. Axit propionic
D. Axit acrylic
Bi 15: A l mt hn hp cc cht hu c gm mt parafin, mt ru n chc v mt axit hu c n
chC.t chy hon m gam hn hp A bng mt lng khng kh va (khng kh gm
20% Oxi v 80% Nit theo th tch.. Cho cc cht sau phn ng chy hp th vo bnh ng dung dch
Ba(OH)2 lng d. C 125,44 lt mt kh tr thot ra (ktC.v khi lng bnh ng dung dch Ba(OH)2 tng
thm 73,6 gam. Tr s ca m l:
A. 37,76 gam
B. Khng d kin tnh
C. 25,2 gam
D. 28,8 gam
Bi 16: Hn hp X gm 1 ru n chc v 1 axit n chc. Chia X thnh 3 phn bng nhau:
- Phn I: tc dng vi Na d thy bay ra 5,6 lt H2 (KTC).
- Phn II: t chy hon ton thu 26,88 l CO2 (KTC).
- Phn III: un vi axit sunfuric c thu c 20,4 gam 1 este c t khi so vi nit l 3,64. Xc nh CTPT ca
2 ru axit trong hn hp ban u v khi lng ca chng.
S: 2 TH
C2H5OH v C2H5COOH; C3H7OH v CH3COOH
Bi 17: Hn hp gm hai andehit n chc A v B c chia thnh 2 phn bng nhau:
- Phn 1 un nng vi dung dch AgNO3/NH3 th to ra 10,8 gam Ag
- Phn 2 oxi ho to thnh hai axit tng ng sau cho 2 axit ny phn ng vi 250 ml dung
dch NaOH 0,26M c dung dch A. trung ho lng NaOH d trong dung dch A cn
dng ng 100 ml dung dch HCl 0,25M. c cn dung dch A, em t chy cht rn c cn to
c 3,52 gam CO2 v 0,9 gam H2O. CTPT ca 2 andehit A v B l:
A. HCHO v C2H5CHO
B. HCHO v C2H3CHO
C. HCHO v CH3CHO
D. CH3CHO v C2H5CHO
Bi 18: Cht X l HO-R-COOH tc dng vi CuO, un nng to ra andehit. 13,5 gam X tc dng vi Na2CO3
to ra 16,8 gam mui v CO2. Tm cu to ca X.
A. CH3-CH(OH)-COOH
B. CH3-CH(OH)-CH-COOH
C. HO-CH2-CH2-COOH
D. Khng xc nh
Bi 19: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH; CH3COOH v CH2=CH-CHO phn ng va
vi dung dch 6,4 gam Brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dung dch NaOH
0,75M, Khi lng CH2=CH-COOH trong X l:
A. 1,44
B. 2,88
C. 0,72
D. 0,56
Bi 20: Hn hp X gm axit hu c Y no, n chc v axit hu c Z hai chc (Y nhiu hn Z mt nguyn t
cacbon). Chia X thnh 2 phn bng nhau. Cho phn 1 tc dng ht vi Na, sinh ra 0,25 mol H2. t chy hon
ton phn 2, sinh ra 0,7 mol CO2. CTCT thu gn v % khi lng ca Z trong hn hp X l
A. HOOC-COOH v 70,87%
B. HOOC-CH2-COOH v 29,13%
C. HOOC-COOH v 55,42%
D. HOOC-CH2-COOH v 70,87%
hng dn: R-COOH: a mol ; R(COOH)2 : b mol

khoa ho HKHTN-HQGHN

a/2 + b = 0,25 mol

0,25 < a + b < 0,5. Da vo phn ng t chy tnh s nguyn t cacbon trung bnh.
x
1,4 < < 2,8
ly C2 v C3
Chuyn 06: Bi tp amin, aminoaxit

Cu 1: Cho dy chuyn ha:
Glyxin
NaOH

HCl

X
Y;
NaOH

Glyxin
Z
T.
HCl
Y v T ln lt l:
A. u l ClH3NCH2COONa
C. ClH3NCH2COONa v H2NCH2COONa
Cu 2: Cho bit s amin bc III ca C4H11N:
A. 1
B. 2
C. 3
Cu 3: C7H9N c bao nhiu ng phn thm?
A. 3
B. 4
C. 5
Cu 4: C3H9N c bao nhiu ng phn amin?
A. 2
B. 3
B. ClH3NCH2COOH v ClH3NCH2COONa
D. ClH3NCH2COOH v H2NCH2COONa
D.4
D. 6
C. 4
D. 5
Cu 5: Cho CTCT: CH3NHC2H5 gi tn theo danh php thay th?

A. Etyl metyl amin
B. N- Metyl etan amin
C. N- etyl metan amin
D. N, N- i metyl amin
Cu 6: Phn ng no sau y ca anilin khng xy ra :

A. C6H5NH2 + H2SO4
B. C6H5NH3Cl + NaOH (dd)
C. C6H5NH2 + Br2(dd)
D. C6H5NH2 + NaOH.
Cu 7: Phng trnh chy ca amin CnH2n+3N, c 1 mol amin trn cn dng lng xy l:
A. (6n+3)/4
B. (2n+3)/2
C. (6n+3)/2
D. (2n+3)/4.
Cu 8: Khi cho etylamin vo dung dch FeCl3 ,hin tng no xy ra c:

A. kh bay ra
C. kh mi khai bay ra
B. kt ta mu nu
D.Khng hin tng g.

khoa ho HKHTN-HQGHN

Cu 9: Sp xp no sau y l ng?
A. C6H5NH2> C2H5NH2
B. CH3NH2> NH3> C2H5NH2
C. C2H5NH2> CH3NH2> C6H5NH2
D. C6H5NH2>CH3NH2> NH3
Cu 10: Cng thc chung ca amin no n chc, mch h l:
A. CnH2n+1N
B. CnH2n+1NH2
C. CnH2n+3N
D. CxHyN
Cu 11: Cht tham gia phn ng trng ngng l
A. C2H5OH.
B. CH2 = CHCOOH.
C. H2NCH2COOH.
D. CH3COOH.
Cu 12: nhn bit 3 cht hu c H2NCH2COOH, HOOCCH(NH2)COOH, H2NCH(NH2)COOH, ta
ch cn th vi mt trong cc cht no sau y:
A. NaOH
B. HCl
C. Qy tm
D. CH3OH/HCl
Cu 13: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, .
Trong cc cht ny, s cht tc dng c vi dung dch NaOH l
A. 4.
B. 6.
C. 5.
D. 3.
Cu 14: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca
aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc
dng c vi dung dch HCl l
A. X, Y, Z, T.
B. X, Y, T.
C. X, Y, Z.
D. Y, Z, T.
Cu 15: Thc hin phn ng trng ngng 2 aminoaxit : Glixin v Alanin s ipeptt thu c ti a l:
A.1
B.2
C.3
D.4
Cu 16: Khi thy phn tripeptit H2N CH(CH3)CO-NH-CH2-CO-NH-CH2-COOH s to ra cc
aminoaxit
A. H2NCH2COOH v CH3CH(NH2)COOH
B. H2NCH2CH(CH3)COOH v H2NCH2COOH
C. H2NCH(CH3)COOH v H2NCH(NH2)COOH
D. CH3CH(NH2)CH2COOH v H2NCH2COOH
Cu 17: chng minh tnh lng tnh ca NH2-CH2-COOH (X) , ta cho X tc dng vi
A. HCl, NaOH.
B. Na2CO3, HCl.
C. HNO3, CH3COOH.
D. NaOH, NH3.
Cu 18: Mot amino axit co cong thc phan t la C4H9NO2. So ong phan amino axit la
A. 3
B. 4
C. 5
D. 6
Cu 19: Cho 9,85 gam hn hp 2 amin n chc, bc mt tc dng va vi dung dch HCl thu
c 18,975 g mui. Khi lng ca HCl phi dng l:
A. 9,521g
B. 9,125g
C. 9,215g
D. 9,512g
Cu 20: t chy mt amin no n chc X thu c CO2 v H2O vi t l mol 2:3. X l:

A. Etyl amin
B. Etyl metyl amin
C. Trietyl amin
D. B v C u ng
Cu 21: Mt amin no n chc X c thnh phn % v N l 23,73% theo khi lng. X l:

A. CH3NH2
B. C2H5NH2
C. C3H7NH2
D. C3H5NH2
Cu 22: trung ho 3,1g mt amin n chc cn 100ml dung dch HCl 1M. Amin l:
A. CH5N
C. C3H9N
B. C2H7N
D. C3H7N
Cu 23: Cho 7,6 g hh hai amin n chc, b c m t k tip nhau, tc dng va vi 200ml dd HCl
1M.
CTCT ca hai amin trn l
A. CH3NH2, CH3NHCH3,
B. CH3NH2, C2H5NH2
khoa ho HKHTN-HQGHN

C. C2H5NH2,C3H7NH2
D. p n khc
Cu 24: Cho 0,1 mol X (-amino axit dng H2NRCOOH) phn ng ht vi HCl to 11,15 gam mui. X
l:
A. Glyxin
B. Alanin
C. Phenylalanin
D. Valin
Cu 25: Cho -amino axit mch thng X c cng thc H2NR(COOH)2 phn ng ht vi 0,1 mol NaOH
to 9,55 gam mui. X l:
A. Axit 2-aminopropanioic
B. Axit 2-aminobutanioic
C. Axit 2-aminopentanioic
D. Axit 2-aminohexanioic
Cu 26: t chy hon ton amol mt aminoaxit X c 2a mol CO2 v 2,5a mol nc. X c CTPT l:
A. C2H5NO4
B. C2H5N2O2
C. C2H5NO2
D. C4H10N2O2
Cu 27: 0,1 mol aminoaxit X phn ng va vi 100ml dung dch HCl 2M. Mt khc18g X cng
phn ng va vi 200ml dung dch HCl trn. X c khi lng phn t l
A. 120
B. 90
C. 60
D. 80
Cu 28: Cho cc dung dch : (1) H2NCH2COOH ; (2) ClH3N-CH2COOH ;
(3) H2NCH2COONa ; (4) H2N[CH2]2CH(NH2)COOH ; (5) HOOC[CH2]2CH(NH2)COOH
S dung dch lm qu tm ha l:
A. (3)
B. (2)
C. (1), (4)
D. (2), (5)
Cu 29: Sp xp cc hp cht sau theo th t gim dn tnh baz:
(1) C6H5NH2 ; (2) C2H5NH2 ; (3) (C6H5)2NH ; (4) (C2H5)2NH ; (5) NaOH ;
(6) NH3
A. (5) > (4) > (2) > (6) > (1) > (3)
B. (5) > (4) > (2) > (1) > (3) > (6)
C. (1) > (3) > (5) > (4) > (2) > (6)
D. (6) > (4) > (3) > (5) > (1) > (2).
Cu 30: Tnh baz ca cc cht tng dn theo th t:
A. NH3 < CH3CH2NH2 < CH3NHCH3< C6H5NH2
B. NH3 < C6H5NH2 < CH3NHCH3 < CH3CH2NH2
C. C6H5NH2 < NH3 < CH3NHCH3 < CH3CH2NH2
D. C6H5NH2 < NH3 < CH3CH2NH2 < CH3NHCH3
Cu 31: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoniclorua),
H2NCH2CH2CH(NH2)COOH, ClH3N-CH2-COOH, HOOCCH2-CH2-CH(NH2)-COOH, H2N-CH2COONa.
S lng cc dung dch c pH < 7 l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 32: ng vi cong thc C4H11N co so ong phan amin bac 2 la:
A. 3.
B. 4.
C. 5.
D. 6.
Cu 33: Nhn bit ba dung dch cha ba cht glixin, metylamin, axit axtic ngi ta dng:
A . Qu tm
B . Dung dch NaOH
C . Dung dch HCl
D . Tt c u ng.
Cu 34: iu khng nh no sau y khng ng:
A . Cc aminoaxit u tan c trong nc.
B . Phn t lng ca mt aminoaxit cha mt nhm NH2 v mt nhm COOH lun l s l.
C . Thy phn protein trong mi trng axit thu c hn hp cc aminoaxit.
D . Cc dung dch cha cc amino axit u lm i mu qu tm.
Cu 35: Gi tn CTCT: CH3CH2CH(NH2)COOH theo danh php thay th
A. Axit 2-amino butanoic
B. Axit 2- amino propionic
B. Axit 3-amino butiric
D. Axit 2- amino butiric
Cu 36: ng vi CTPT C4H9NO2 c bao nhiu amino axit l ng phn ca nhau?
A. 3
B. 4
C. 5
D. 6
khoa ho HKHTN-HQGHN

Cu 37: Cng thc no sau y ng vi tn gi: Axit 2-amino propanonic
A. H2NCH2COOH
B. HOOCCH2CH2NH2
C. CH2-CH(NH2)COOH
D. CH3CH(NH2)COOH
Cu 38: Axit amino axetic tc dng c bao nhiu cht cho di y: (iu kin c ) NaOH, Na,
CH3CHO, CH3OH, H2SO4
A. 2
B. 3
C. 4
D. 5
Cu 39: t chy hon ton hn hp 2 amin no, n chc, mch h ng ng lin tip, ta thu c t
VCO2 5
VH 2O 8
l th tch
( cng iu kin). Cng thc ca 2 amin l
A. CH3NH2 , C2H5NH2
B. C3H7NH2 , C4H9NH2
C. C2H5NH2 , C3H7NH2
D. C4H9NH2 , C5H11NH2
Cu 40: Cho 9,3 gam ankyl amin tc dng vi dd FeCl3 d thu c 10,7 gam kt ta. ankyl amin l
A. CH3NH2
B. C2H5NH2
C. C3H7NH2
D. C4H9NH2
Cu 41: Cho lng d anilin phn ng vi dd cha 0,05 mol H2SO4 long, lng mui thu c bng:
A. 28,4 gam
B. 8,8 gam
C. 19,1 gam
D. 14,2 gam
Cu 42: X l mt -aminoaxit mch thng ch cha mt nhm NH2 v mt nhm -COOH. Cho 10,3
gam X tc dng vi dd HCl d thu c 13,95 gam mui clorua ca X. CTCT thu gn ca X l:
A. CH3CH(NH2)COOH
B. H2NCH2COOH
C. H2NCH2CH2COOH
D. CH3CH2CH(NH2)COOH
Cu 43: Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phn ng ht vi dung dch NaOH. Sau
phn ng, khi lng mui thu c l (Cho H = 1, C = 12, O = 16, Na = 23)
A. 11,05 gam.
B. 9,8 gam.
C. 7,5 gam.
D. 9,7 gam.
Cu 44: t chy ht amol 1 aminoaxit X bng Oxi va ri ngng t hi nc c 2,5a mol hn
hp CO2 v N2. Cng thc phn t ca X l:
A. C2H5NO2
B. C3H7NO2
C. C3H7N2O4
D. C5H11NO2
Cu 45: 0,01mol aminoaxit X tc dng va vi 50ml dd HCl 0,2M. C cn dd sau phn ng c
1,835g mui khan. Khi lng phn t ca X l :
A. 89
B. 103
C. 117
D. 147
Cu 46: Este X c iu ch t -amino axit v ancol metylic. T khi hi ca X so vi hidro bng

44,5. Cng thc cu to ca X l:
A. CH3CH(NH2)COOCH3.
B. H2N-CH2CH2-COOH
C. H2NCH2COOCH3.
D. H2NCH2CH(NH2)COOCH3.
Cu 47: Cho dy cc cht: C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2,
C6H5OH (phenol). S cht trong dy tc dng c vi dung dch HCl l
A. 4.
B. 2.
C. 3.
D. 5.
Cu 48: S ng phn tripeptit to thnh t 1 phn t glyxin v 2 phn t alanin l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 49: T glyxin (Gly) v alanin (Ala) c th to ra my ipeptit?
A. 1
B. 2
C. 3
D. 4
Cu 50: Glixin khng tc dng vi
A. H2SO4 long.
B. CaCO3.
C. C2H5OH.
D. NaCl.

khoa ho HKHTN-HQGHN

Chuyn 07: bi ton CO2 tc dng vi dd kim

Bi 1.
Hp th hon ton 2,688 lit kh CO2 ( ktc) vo 2,5 lit dd Ba(OH)2 nng a mol/l thu c 15,76g kt
ta.Gi tr ca a l bao nhiu ?
a.0,032
b.0,06
c.0,04
d.0,048
Bi 2.
Hp th hon ton 4,48 lit kh SO 2 ( ktc) vo dd cha 16g NaOH thu c dd X.Khi lng mui tan thu
c trong dd X l bao nhiu?
a.20,8g
b.18,9g
c.23,0g
d.25,2g.
Bi 3.
Sc Vlit CO2 ktc vo 150ml dd Ba(OH)2 1M,sau phn ng thu c 19,7g kt ta.Gi tr ca V l bao nhiu?
a.2,24 lit; 4,48lit.
b.2,24lit; 3,36lit
c.3,36lit; 2,24lit
d.22,4lit; 3,36lit.
Bi 4.
Sc 2,24lit CO2 ktc vo 750ml dd NaOH 0,2M..S mol ca Na2CO3 v NaHCO3 l bao nhiu?
a.0,05 v 0,05
b.0,06 v 0,06
c.0,05 v 0,06
d.0,07 v 0,05
Bi 5.
Hp th hon ton x lit kh CO2 ktc vo 2 lit dd Ca(OH)2 0,01M th c 1g kt ta.Tnh gi tr ca x?
a.0,224lit v 0,672lit
b.0,224 lit v 0,336 lit
c.0,42 lit v 0,762 lit.
d.0,24 lit v 0,762 lit
Bi 6.
Dn 10 lit hn hp kh gm N2 v CO2 o ktc sc vo 2 lit dd Ca(OH) 2 0,02M thu c 1g kt ta.Tnh phn
trm theo th tch CO2 trong hn hp kh.
s:2,24% v 15,68%
Bi 7.
Cho 3 l ,mi l u ng 200ml dd NaOH 1M..Th tch kh SO 2 c sc vo 3 l ln lt l 5,6lit ; 1,68lit;
3,36 lit ktc.S mol mui to ra mi l l bao nhiu?
s: 0,1 mol NaHSO3; 0,05 mol Na2SO3
Bi 8.
Nung m g hn hp A gm 2 mui MgCO3 v CaCO3 cho n khi khng cn kh thot ra, thu c 3,52 g cht
rn B v kh C. Cho ton b kh C hp th ht bi 2 lit dd Ba(OH)2 thu c 7,88g kt ta. un nng tip tc dd
li thy to thnh thm 3,94 g kt ta.Bit cc phn ng xy ra hon ton.Tnh khi lng m v nng ca dd
Ba(OH)2 dng.
s: m=7,04g ;CM=0,03M
Bi 9.
Cho 10,8 gam hn hp 2 mui cacbonat ca 2 kim loi k tip nhau trong phn nhm chnh nhm II tc dng
vi dung dch H2SO4 long d.Cht kh thu c cho hp th hon ton vo dd Ba(OH) 2 d,th thu c 23,64g
kt ta .Hai mui cacbonat v % theo khi lng ca chng trong hn hp l bao nhiu?
s: 58,33% ;41,67%
Bi 10.

khoa ho HKHTN-HQGHN

Nhit phn hon ton 20g mui cacbonat kim loi ho tr II thu c kh B v cht rn A.Ton b kh B cho vo
150 lit dd Ba(OH)2 0,001M thu c 19,7g kt ta .Xc nh khi lng A v cng thc ca mui cacbonat .
s: 11,2g ; CaCO3
Cu 11:
Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v Ba(OH) 2
0,12M, thu c m gam kt ta. Gi tr ca m l ( KHI A 2009 )
A. 3,940.
B. 1,182.
C. 2,364.
D. 1,970.
Cu 12:
Hp th hon ton 2,24 lt CO2 (ktc) vo 0,075 mol Ca(OH)2 . Tnh khi lng mui sinh ra
A. 9,05 gam
B . 9,5 gam
C. 10,08 gam
D. 10 gam
Cu 13: Hp th hon ton 4,48 lt kh CO 2 ( ktc) vo 500 ml dung dch hn hp gm NaOH 0,1M v
Ba(OH)2 0,2M, sinh ra m gam kt ta. Gi tr ca m l:
A. 19,70.
B. 9,85.
C.11,82.
D. 17,73.
BI 15. Hai cc ng axit HCl t trn 2 a cn A v B ,cn trng thi cn bng .Cho ag CaCO 3 vo cc A
v bg M2CO3 (M l kim loi kim) vo cc B.Sau khi 2 mui tan hon ton ,cn tr li trng thi cn bng.
33,6a 16
x
2b 1,12a
Xy dng biu thc tnh nguyn t khi ca M theo a v b?
p s: M=
Bi 12.Cho 112ml kh CO2(ktc) hp th hon ton bi 400ml dd nc vi trong ta thu c 0,1g kt ta .Nng
mol/l ca dd nc vi trong l bao nhiu?
s: 0,0075M
Bi 13. Ho tan hon ton 11,2g CaO vo nc ta c dd A .Nu cho kh cacbonic sc qua dd A v sau khi kt
thc th nghim thy c 2,5g kt ta .S lit CO 2 tham gia phn ng l bao nhiu?
s: 0,56 lit; 8,4
lit
Bi 14.Ho tan 5,8g hn hp X gm Fe3O4 v FeCO3 trong mt lng dd H2SO4 long d ta thu c dd Y v
kh Z.Nh t t dd thuc tm vo dd Y th c hin tng .Khi ht hin tng y th tn ht 160ml dd thuc tm
0,05M.Thu ton b kh Z cho hp th ht vo 100ml dd Ba(OH) 2 0,2M th thu c mg kt ta trng .Phn trm
khi lng cc cht trong hn hp X v khi lng kt ta m l bao nhiu?
s: % Fe 3O4= 40; % FeCO3 =60;
m=1,97g.
Bi 15. Nung m g hn hp a gm 2 mui MgCO3 v CaCO3 cho n khi khng cn kh thot ra ,thu c 3,52g
cht rn B v kh C .Cho ton b kh C hp th ht bi 2 lit dd Ba(OH)2 , thu c 7,88g kt ta . un nng tip
dd li thy to thm 3,94g kt ta (bit rng cc phn ng xy ra hon ton).Khi lng m v nng ca dd
Ba(OH)2 ln dng l bao nhiu?
s:7,04g; 0,03M.
Bi 16. t chy hon ton 1,6g lu hunh ri cho sn phm chy hp th hon ton vo 200ml dd Ba(OH) 2
0,5M thu c mt kt ta.Tnh khi lng kt ta thu c?
s:10,85g
Bi 17.Dung dch A cha NaOH 1M v Ca(OH)2 0,01M.Sc 2,24 lit kh CO2 vo 400ml dd A ta thu c mt
kt ta c khi lng l bao nhiu?
s:0,4g.
--------------------

khoa ho HKHTN-HQGHN

Phn II: mt s thi tham kho

TRNG THPT CHUYN
NGUYN HU
THI TH I HC LN TH HAI
NM HC 2009 - 2010
MN: HOA - KHI A, B
Thi gian lm bi: 90 pht;

( c 5 trang, gm 60 cu trc nghim)
I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40).
Cu 1: Cho cc polime sau : t nilon-6,6; poli(vinyl ancol); t capron; teflon; nha novolac; t lapsan, t
nitron, cao su buna-S Trong s polime trng hp l:
A. 3
B. 5
C. 6
D. 4
Cu 2: Cho a gam Fe3O4 tc dng va vi 1 lng dung dch HNO3 sao phn ng thu c dung dch X.
Cho HCl d vo dung dch X th dung dch thu c ha tan c ti a 17,28g Cu. Tnh a:
A. 41,76g
B. 3,712g
C. 4,64g
D. 4,176g
Cu 3: Cht X c cng thc C4H6O4 c tnh cht sau : Tc dng NaOH to ra mui Y. t Y ch thu c CO 2
v Na2CO3 . Cng thc cu to X l :
A. CH2=C(COOH)2
B. CH3OOC-COOCH3
C. HOOC-CH2CH2COOH
D. HCOOCH2COOCH3
Cu 4: C bao nhiu pht biu sai trong cc cu sau y:
1 Trong cng mt chu k bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim.
2 Trong cng mt nhm A, nguyn t ca nguyn t kim loi c in tch ht nhn ln hn so
vi nguyn t ca nguyn t phi kim.
3 Nguyn t ca hu ht tt c cc nguyn t kim loi u c s electron lp v ngoi cng
3.
4. Nguyn t cc nhm IA, IIA, IIIA u l nhng nguyn t kim loi v chng c s electron ngoi cng ln
lt l 1e, 2e, 3e.
A. 3
B. 1
C. 4
D. 2
Cu 5: Cho cc cht sau: sec-butyl clorua, neo-pentyl clorua, benzyl clorua, 3-clobut-1-en, 4-clo-2-metylpent1-en, p-clotoluen. S cht b thy phn khi un vi nc, b thy phn khi un vi dung dch NaOH, b thy
phn khi un vi dung dch NaOH c, nhit v p sut cao ln lt l:
A. 1 5 1
B. 2 5 6
C. 1 4 6
D. 2 3 1
Cu 6: X mch h c CTPT C8H14 tc dng vi HBr cho 3 sn phm monobrom. S ng phn cu to tha
mn l:
A. 6
B. 4
C. 9
D. 15
Cu 7: Mt cht bo c ch s axit bng 7, ch s x phng ha bng 196. un nng 100gam cht bo vi
dung dch NaOH va c bao nhiu gam glyxerol (ch s axit l s mg KOH dng trung ha ht lng
axit t do c trong 1 gam cht bo, ch s x phng ha l s mg KOH dng x phng ha ht lng
triglixerit v lng axit t do c trong 1 gam cht bo):
A. 9,38 gam
B. 10,35 gam
C. 11,04 gam
D. 11,5 gam
Cu 8: Nung nng hn hp gm 0,4 mol N2 v 1,6 mol H2 trong bnh kn (c xc tc) ri a v nhit t 0C
thy p sut trong bnh lc ny l P 1. Sau cho mt lng d H 2SO4 c vo bnh (nhit lc ny trong bnh
l t0C) n khi p sut n nh th thy p sut trong bnh lc ny l P2 (P1 = 1,75P2). Hiu sut tng hp NH3 l:
A. 50%.
B. 65,25%.
C. 60%.
D. 75%.

khoa ho HKHTN-HQGHN

Cu 9: Xenluloz tc dng vi anhirit axetic iu kin thch hp to ra 9,84 gam hp cht X v 4,8 gam
CH3COOH. Cng thc ca X c dng l:
A. [C6H7O2(OCOCH3)2OH]n
B. [C6H7O2(OCOCH3)3]n hoc [C6H7O2(OCOCH3)2OH]n
C. [C6H7O2(OCOCH3)(OH)2]n
D. [C6H7O2(OCOCH3)3]n
Cu 10: C cc dung dch sau: (1): K2Cr2O7 + H2SO4; (2): H2SO4c; (3): Na2S; (4): HCl; (5): KBr; (6):
Fe(NO3)2. Trn ln lt cc dung dch vi nhau tng cp mt th c bao nhiu cp c phn ng xy ra, trong
bao nhiu cp xy ra phn ng oxh- kh:
A. 10-8
B. 11 8
C. 8 7
D. 11 7
Cu 11: Cho 17,6 gam Cht X cng thc C4H8O2 tc dng hon ton vi 100 ml dung dch cha NaOH 1,5M
v KOH 1,0M. Sau phn ng c cn thu 20 gam cht rn. Cng thc X l
A. HCOO-C3H7
B. C2H5COOCH3
C. CH3COO-C2H5
D. C3H7COOH
Cu 12: in phn mt dung dch cha FeCl 3 , NaCl , HCl , CuCl2 vi in cc tr, mng ngn xp. Cho qu
tm vo dung dch sau in phn thy qu tm khng i mu, chng t dng in phn thi im va ht:
A. HCl
B. CuCl2
C. FeCl3
D. FeCl2
Cu 13: loi b kh clo gy c trong phng th nghim ngi ta s dng cht no sau y:
A. NH3
B. AgNO3
C. Ca(OH)2
D. H2
Cu 14: Cc A ng 0,3 mol Na2CO3 v 0,2 mol NaHCO3. Cc B ng 0,4 mol HCl. rt t t cc A vo cc
B . S mol CO2 thot ra l gi tr no?
A. 0,4
B. 0,25
C. 0,1
D. 0,3
Cu 15: m gam phi st ngoi khng kh, sau 1 thi gian Fe b oxi ho thnh hn hp X gm 4 cht rn c
khi lng 27,2 gam. Ho tan va ht X trong 300 ml dung dch HCl nng a mol/l thy thot ra 3,36 lt H 2
(ktc) v dung dch Y. Cho tip dung dch HNO 3 ti d vo dung dch Y c dung dch Z cha hn hp FeCl 3 ,
Fe(NO3)3 , HNO3 d v c 2,24 lt NO duy nht thot ra (ktc). Gi tr ca m v a ln lt l:
A. 22,4 gam v 2M
B. 16,8 gam v 3M
C. 22,4 gam v 3M
D. 16,8 gam v 2M
Cu 17: t chy hon ton 2,01 gam hn hp gm axit acrylic, vinyl axetat, metyl metacrylat. Ton b sn
phm chy cho qua bnh 1 ng H2SO4 c thy khi lng bnh 1 tng m gam, bnh 2 ng Ca(OH) 2 d thu
c 9 gam kt ta. m c gi tr l:
Cu 18: Cho cc kim loi v ion sau: Cr, Fe 2+, Mn, Mn2+, Fe3+ (cho ZCr = 24, ZMn= 25, ZFe = 26 ). Nguyn t v
ion c cng s electron c thn l:
A. Cr v Mn
B. Mn, Mn2+ v Fe3+
C. Mn2+, Cr, Fe3+
D. Cr v Fe2+
Cr2O72 H 2 O 2CrO42 2 H
Cu 19: Cho cn bng ha hc sau:
. Trong cc trng hp sau: (1) thm OHvo h; (2) pha long; (3) thm BaCl 2; (4) thm Na2CO3; (5) thm NH4Cl; (6) thm NaCl. S trng hp khi tc
ng vo h lm cho dung dch chuyn sang mu vng l:
A. 4
B. 5
C. 3
D. 6
Cu 20: T Canxi cacbua c th iu ch anilin theo s phn ng :
H O
HNO /H SO
C
HCl
CaC2
hs80% C2H
C,600
C
6H6
C6H5NO2 Fe
C6H5NH3Cl hsNaOH
C6H5NH2
2
hs 75%
hs60%
hs80%
95%
2
hs=hiu sut
T 1 tn Canxi cacbua cha 80% CaC2 c th iu ch c bao nhiu kg anilin theo s trn ?
A. 101,78 kg
B. 106,02 kg
C. 130,28 kg
D. 162,85 kg

khoa ho HKHTN-HQGHN

Cu 22: Kh hon ton 7,1 gam hn hp X gm 2 anehit n chc A, B bng H2 thu c hn hp Y. Nu cho
Y tc dng ht vi Na d thu c 1,68 lt H 2 (ktc). Nu cho 7,1 gam hn hp X tc dng vi dung dch
AgNO3/NH3 d thu c 43,2 gam Ag. CTCT ca 2 anhit l :
A. CH3-CHO ; CH2=CH-CHO
B. CH3-CHO ; CH2=CH-CH2-CHO
C. HCHO ; CH3-CH2-CHO
D. HCHO ; CH2=CH-CHO
Cu 23: So snh nng ca cc dung dch sau c cng pH:
(1). Natri axetat
(2). Natri cacbonat (3). Kali aluminat
(4). Kali fomiat
A. (2) < (1) < (4) < (3)
B. (3) < (4) < (1) < (2) C. (3) < (2) < (1) < (4) D. (2) < (3) < (1) < (4)
Cu 24: Cho hn hp gm etanol v phenol tc dng vi Na d thu c 1,68 lt kh (ktc). Nu cho hn hp
trn tc dng vi dung dch brom va thu c 9,93 gam kt ta trng. Tnh % khi lng ca phenol trong
hn hp:
A. 33,81%
B. 66,19%
C. 50%
D. 70,99%
Cu 25: C cc kim loi ring bit sau: Na, Ca, Al, Fe, Cu. Ch dng thm nc c th phn bit c bao
nhiu kim loi trong s cc kim loi trn bng bng phng php ho hc ?
A. 5
B. 2
C. 0
D. 3
Cu 26: Mt ancol 2 chc, phn t khng c nguyn t C bc 3. un nh m gam hi ancol trn vi bt CuO (d) n khi phn ng xy hon ton thy khi lng cht rn trong bnh gim 2,24gam ng thi thu c hn
hp kh v hi ( ktc) c t khi hi so vi H2 l 18. m c gi tr l:
A. 12,88 gam
B. 7,84 gam
C. 5,32 gam
D. 1,54 gam
Cu 27: Hn hp kh no sau y c th cng tn ti nhit thng: (1): Cl2, NH3;
(2): SO 2, O2 ;
(3): F2, HCl;
(4): N2, Cl2 ;
(5): H2S, O2.
A. 2, 4
B. 1, 3
C. 2, 5
D. 1, 2
Cu 28: Ha tan hon ton hn hp X gm 0,002 mol FeS2 v 0,003 mol FeS vo lng H2SO4 c nng d thu
c kh X. Hp th X bng lng va Vml dung dch KMnO4 0,05M. V c gi tr l:
A. 228 ml
B. 172 ml
C. 280ml
D. 188 ml
Cu 29: Cho dy gm cc cht Na, Mg; Ag, O 3, Cl2, HCl, Cu(OH)2, Mg(HCO3)2, CuO, NaCl, C2H5-OH, C6H5OH, C6H5-NH2, CH3ONa, CH3COONa, s cht tc dng c vi axit propionic l:
A. 8
B. 10
C. 7
D. 9
Cu 30: Cho 18,32 gam axit picric vo mt bnh ng bng gang c dung tch khng i 560cm 3 (khng c
khng kh), ri gy n 19110C . p sut trong bnh ti nhit l P atm, bit rng sn phm n l hn hp
CO, CO2, N2, H2 v p sut thc t nh hn p sut l thuyt 8%. P c gi tr l
A. 223,635
B. 211,836
C. 207,365
D. 201,000
Cu 31: Trong mt cc nc c cha 0,01 mol Na+; 0,01 mol Al3+; 0,015 mol Ca2+; 0,01 mol Mg2+; 0,045 mol
HCO3-; 0,045 mol Cl-. lm mm nc cng u dng cc cch:
A. un nng, Na3PO4, Ca(OH)2.
B. Na3PO4, Na2CO3, HCl.
C. Na2CO3, Na3PO4, NaOH
D. un nng, Na2CO3, Na3PO4
Cu 32: Cho 15 gam glyxin tc dng va vi 8,9 gam alanin thu c m gam hn hp tripeptit mch h.
Gi tr ca m l
A. 23,9 gam
B. 18,5 gam
C. 22,10 gam
D. 20,3 gam
Cu 33: Dy no sau y gm tt c cc cht c lin kt cho nhn (vit theo quy tc bt t):
A. Na2CO3, CH3COONH4, SO2, HNO3, H2SO4
B. H2CO3, H2SO4, N2O5, NH3, K2S
C. Ba(NO3)2, NH4Cl, CO2, H3PO4, H2SO3
D. HNO3, H2SO3, P2O5,CO, Na2SO4
Cu 35: Cho 3,92 gam mt este n chc X tc dng va vi 100ml KOH 0,4M thu c 6,16 gam mui Y.
Axit ha Y thu c cht Z. Z c cng thc phn t l:
A. C5H6O2
B. C5H8O3
C. C6H12O2
D. C6H12O3

khoa ho HKHTN-HQGHN

Cu 36: Cn ly bao nhiu lt dung dch H2SO4 98% (D= 1,84g/ml) sn sut 1 tn supephotphat kp 80%.
bit hiu sut mi phn ng l 80%.
A. 0,5806 m3
B. 0,2378 m3
C. 0,8052 m3
D. 0,4645 m3
Cu 37: Cht X: C2H7NO2 A tc dng vi dung dch HCl v dung dch NaOH. X thuc loi hp cht:
A. Aminoaxit
B. Aminoaxit v mui amoni
C. Mui amoni
D. Aminoaxit v este ca aminoaxit
Cu 38: Dung dch X cha a mol NaAlO 2; a mol NaOH khi thm vo dung dch X b mol hoc 2b mol HCl th
lng kt ta u nh nhau . T s b/a c gi tr l:
A. 1
B. 0,625
C. 1,6
D. 1,5
Cu 39: Hp th 6,72 lt SO2 (ktc) vo 200 ml dung dch KOH 1M; NaOH 0,85M; BaCl 2 0,45M sau cho
tip 300ml dung dch Ba(OH)2 0,1M thu c m gam kt ta, gi tr ca m l:
A. 26,04 gam
B. 19,53 gam
C. 28,21 gam
D. 13,02 gam
Cu 40: Ha tan 7,92g hn hp Na, Mg, Al va trong 500ml dung dch HNO 3 1,65M thu c V lt N2O l
sn phm kh duy nht. Tm V, khi lng mui thu c:
A. 3,696 lt 28,38g
B. 2,05lt 53,38g
C. 1,848 lt 48,84g D. 3,08 lt 42,02g
II. PHN T CHN ( th sinh c chn 1 trong 2 phn A hoc B):
A: Theo chng trnh chun (10 cu, t cu 41 n cu 50):
Cu 41: un nng V lt hi andehit mch h X vi 3 V lt H 2 ( xc tc Ni ) n phn ng xy ra hon ton
c hn hp Y c th tch 2V lt ( kh o cng iu kin ). Ngng t Y c cht Z, cho Z tc dng Na sinh
mol H2 bng mol Z. X l anehit no :
A. Khng no, cha 1 lin kt i n chc
B. No n chc
C. Khng no, cha 1 lin kt i hai chc
D. No hai chc
Cu 42: t chy hon ton hn hp gm FeS 2 v Ag2S vi s mol bng nhau thu c 3,696 lt SO 2 (ktc) v
cht rn B . Cho B tc dng vi dung dch H 2SO4 long d, sau phn ng hon ton thy cn li m gam cht rn
khng tan. Gi tr ca m l:
A. 13,64
B. 11,88
C. 17,16
D. 8,91
Cu 43: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi
thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit
Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l:
A. Gly, Gly.
B. Ala, Val.
C. Ala, Gly.
D. Gly, Val.
Cu 44: Hirocacbon X c cng thc phn t C8H10 khng lm mt mu dd brom. Khi un nng X trong dd
thuc tm to thnh hp cht C8H4K2O4 (Y). X c kh nng to ra 4 dn xut monobrom. Tn ca X l:
A. 1,4-imetylbenzen.
B. 1,3-imetylbenzen. C. 1,2-imetylbenzen. D. etylbenzen.
Cu 45: Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a
(mol/l) thu c dung dch c pH = 12. Gi tr ca a l :
A. 0,21.
B. 0,12.
C. 0,11.
D. 0,22.
Cu 46: Cho m gam Al vo 500ml dung dch Cu(NO3)2 0,2M, AgNO3 0,1M. Sau khi phn ng xy ra hon ton
thu c cht rn nng (m+7,71) gam. Gi tr ca m l :
A. 5,29
B. 4,02
C. 1,53
D. 1,89
Cu 47: Thuc th duy nht nhn ra cc dung dch axit ring bit sau : NaCl, NaNO3, Na2S, Na3PO4 l:
A. Na
B. Fe(NO3)2
C. Fe(NO3)3
D. AgNO3
H 2O

Cu 48: Cho s phn ng sau: S
X
H2S
X l:
A. Al2S3.
B. Na2S.
C. Na2S2O3.
D. CaS.
Cu 49: phn bit phenol, anilin, benzen, stiren ngi ta s dng cc thuc th l:
khoa ho HKHTN-HQGHN

A. dung dch NaOH, dung dch brom
B. dung dch HCl, dung dch KmnO4
C. dung dch brom, qu tm
D. qu tm, dung dch brom
Cu 50: Chia 23,6 gam hn hp gm HCHO v cht hu c X l ng ng ca HCHO thnh 2 phn bng
nhau. Phn 1, cho tc dng vi H2 d (t0C, xc tc), sau phn ng thu c 12,4 gam hn hp ancol. Phn 2,
cho tc dng vi dung dch AgNO3/NH3 d thu c108 gam bc . Cng thc phn t ca X l:
A. C2H3CHO
B. C2H5CHO
C. (CHO)2
D. CH3CHO
B: Theo chng trnh nng cao (10 cu, t cu 51 n cu 60):
Cu 51: Cho a gam hn hp bt gm Ni v Cu vo dung dch AgNO 3 (d). Sau khi kt thc phn ng thu c
54 gam cht rn. Mt khc cng cho a gam hn hp 2 kim loi trn vo dung dch CuSO 4 (d), sau khi kt thc
phn ng thu c cht rn c khi lng (a + 0,5) gam. Gi tr ca a l:
A. 42,5 gam
B. 53,5 gam
C. 15,5 gam
D. 33,7 gam
Cu 52: Nguyn liu iu ch axeton trong cng nghip l:
A. propan-2-ol
B. propan-1- ol
C. isopropylbenzen
D. propin
Cu 53: Thuc gim au Paracetamol c cha lin kt amit trong phn t v c to thnh bng cch cho axit
axetic tc dng vi p- amino phenol. Cng thc ca thuc l:
CH3 - C - N CH3 - C - N -
OH
O H
O H
A.
OH
B.
CH3 - C - O O
NH2
CH3 - C - N O H
OH
C.
D.
Cu 54: Kh hon ton m gam Fe2O3 cn 5,376 lt CO (ktc). Mt khc cho m gam Fe 2O3 tc dng va vi
dung dch HI 0,3M thu c dung dch X. Nng ion I- c trong dung dch X l:
A. 0,1M
B. 0,05M
C. 0,2M
D. 0,3M
Cu 55: Hn hp X cha glixerol v mt ancol no, n chc mch h Y. Cho 20,3 gam X tc dng vi Na d
thu c 5,04 lt H2 (ktc). Mt khc 8,12 gam X ho tan va ht 1,96 gam Cu(OH) 2. Cng thc phn t ca Y
v thnh phn phn trm khi lng ca Y trong hn hp l:
A. C5H12O v 65,94%
B. C4H10O v 54,68% C. C3H8O v 77,34% D. C2H6O v 81,87%
Cu 56: X c cng thc phn t C4H7ClO2 X tc dng NaOH cho mui X1 + ancol etylenglicol + NaCl cng
thc X l :
A. Cl-CH2-COO-CH2 -CH3
B. CH3 -COO-CH2-CH2Cl
C. CH3- CHCl- COO -CH3
D. CH3-COO-CHCl-CH3
Cu 57: Cp ancol v amin c cng bc l:
A. (CH3)3COH v (CH3)3CNH2
B. (C6H5)2NH v C6H5CH2OH
C. (CH3)2CHOH v (CH3)2CH-NH2
D. C6H5NHCH3 v C6H5CH(OH)CH3
Cu 58: Trong cu mui ca pin in ha Zn-Cu c s di chuyn ca:
A. Cc electron
B. Cc nguyn t Zn C. Cc nguyn t Cu D. Cc ion
Cu 59: Cho sut in ng ca cc pin in ha: E0(Fe-Cu) = 0,78V
E0(Cu-Ag) = 0,46V .
Sut in ng ca pin Fe - Ag l:
A. 0,34V
B. 0,44V
C. 0,8V
D. 1,24V

khoa ho HKHTN-HQGHN

Cu 60: Hn hp kh X gm 0,1mol vinylaxetilen v 0,4 mol H2. Nung nng hn hp X (c xc tc Ni) mt
thi gian, thu c hn hp Y c t khi so vi hiro bng 10. Nu dn hn hp Y qua dung dch Brom th khi
lng Brom tham gia phn ng l:
A. 0 gam (khng phn ng)
B. 8 gam
C. 16 gam
D. 24 gam
----------------------------------------------TRNG I HC S PHM H NI
THI TH I HC LN I NM
2010
TRNG THPT CHUYN
MN HA HC
PHN CHUNG CHO TT C TH SINH (40 cu)
Cu 1: T phn ng: Fe(NO3)2 + AgNO3

Fe(NO3)3 + Ag.
Pht biu no di y l ng?
A. Fe2+ c tnh oxi ha mnh hn Fe3+.
B. Fe3+ c tnh oxi ha mnh hn Ag+.
C. Ag+ c tnh kh mnh hn Fe2+.
D. Fe2+ kh c Ag+.
Cu 2: Cho 100 ml dung dch hn hp CuSO4 1M v Al2(SO4)3 1,5M tc dng vi dung dch NH3 d, lc ly
kt ta em nung n khi lng khng i thu c cht rn c khi lng l
A. 15,3 gam.
B. 30,6 gam
C. 23,3 gam.
D. 8,0 gam.
Cu 3: X mch h c cng thc C3Hy. Mt bnh c dung tch khng i cha hn hp kh X v O2 d 1500C,
c p sut 2atm. Bt tia la in t chy X sau a bnh v 1500C, p sut bnh vn l 2atm.Ngi ta
trn 9,6 gam X vi hidro ri cho qua bnh ng Ni nung nng ( H = 100%) th thu c hn hp Y. Khi lng
mol trung bnh ca Y l
A. 48,5.
B. 42,5.
C. 46,5.
D. 52,5.
Cu 4: Cho X l mt aminoaxit. Khi cho 0,01 mol X tc dng vi HCl th dng ht 80ml dung dch HCl
0,125M v thu c 1,835 gam mui khan. Khi cho 0,01 mol X tc dng vi dung dch NaOH th cn dng 25
gam dung dch NaOH 3,2%. Cng thc cu to ca X l
A. NH2C3H5(COOH)2.B. (NH2)2C3H5COOH.
C. NH2C3H6COOH.
D. (NH2)2C5H9COOH.

+
Cu 5: Cho phn ng : Cu + H + NO3
Cu2+ + NO + H2O.
Tng cc h s cn bng (ti gin, c ngha) ca phn ng trn l
A. 22.
B. 23.
C. 28.
D. 10.
Cu 6: Ha tan hon ton m gam hn hp X gm Al, Fe, Zn bng dung dch HCl d. Dung dch thu c sau
phn ng tng ln so vi ban u (m 2) gam. Khi lng ( gam) mui clorua to thnh trong dung dch l
A. m +73.
B. m + 35,5.
C. m + 36,5.
D. m + 71.
Cu 7: un nng 7,6 gam hn hp X gm C2H2, C3H4 v H2 trong bnh kn vi xc tc Ni thu c hn hp kh
Y. t chy hon ton hn hp Y, dn sn phm chy thu c ln lt qua bnh 1 ng H2SO4 c, bnh 2
ng Ca(OH)2 d thy khi lng bnh 1 tng 14,4 gam. Khi lng tng ln bnh 2 l
A. 22,0 gam.
B. 35,2 gam.
C. 6,0 gam.
D. 9,6 gam.
Cu 8: Cho mt lng st d tan trong dung dch HNO3 long thu c dung dch X c mu nu nht. Cht tan
trong dung dch l
A. Fe(NO3)2, Fe(NO3)3.
B. Fe(NO3)2.
C. Fe(NO3)2, HNO3.
D. Fe(NO3)3, HNO3.
Cu 9: Hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m
gam hn hp X thu c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin phn
ng trng bc thy c p gam Ag kt ta. Gi tr ca p l
A. 2,16.
B. 8,64.
C. 10,8.
D. 9,72.
khoa ho HKHTN-HQGHN

Cu 10: Ha tan hon ton 6,0 gam hn hp hai kim loi trong dung dch HCl d thy to ra 4,48 lt kh H2
(ktc). C cn dung dch sau phn ng thu c m gam mui khan. Gi tr ca m l
A. 20,6.
B. 20,2.
C. 13,3.
D. 13,1.
Cu 11: Trn 3 dung dch HCl 0,3M; H2SO4 0,2M v H3PO4 0,1M vi nhng th tch bng nhau thu c dung
dch X. Dung dch Y gm NaOH 0,1M v Ba(OH)2 0,2M. trung ha ht 300ml dung dch X cn va Vml
dung dch Y. Gi tr ca V l
A. 1000.
B. 333,3.
C. 600.
D. 200.
Cu 12: Dy no di y gm tt c cc cht u lm i mu qu tm m?
A. H2NCH2COOH; C6H5OH; C6H5NH2.
B. H2NCH2COOH; HCOOH; CH3NH2.
C. H2N[CH2]2NH2;HOOC[CH2]4COOH; C6H5OH. D. CH3NH2; (COOH)2;
HOOC[CH2]2CH(NH2)COOH.
Cu 13: t chy hon ton a gam hn hp cc este no, n chc, mch h. Sn phm chy c dn vo bnh
ng dung dch nc vi trong thy khi lng bnh tng 6,2 gam. S mol CO2 v H2O to ra ln lt l:
A. 0,05 v 0,05.
B. 0,05 v 0,1.
C. 0,1 v 0,1.
D. 0,1 v 0,15.
Cu 14: Thy phn m gam tinh bt, sn phm thu c em ln men sn xut ancol etylic, ton b kh CO2
sinh ra cho qua dung dch Ca(OH)2 d, thu c 750 gam kt ta. Nu hiu sut qu trnh sn xut ancol etylic
l 80% th m c gi tr l
A. 949,2.
B. 486,0.
C. 759,4.
D.607,5.
Cu 15: Oxi ha m gam mt hn hp X gm fomanehit v axetanehit bng oxi iu kin thch hp thu
c hn hp Y ch gm cc axit hu c. T khi hi ca Y so vi X bng x. Khong bin thin ca x l
A. 1,30 < x < 1,50. B. 1,36 < x < 1,53.
C. 1,30 < x < 1,53.
D. 1,36 < x < 1,50.
Cu 16: Hn hp X gm 2 ancol. t chy hon ton 8,3 gam X bng 10,64 lt O2 thu c 7,84 lt CO2, cc
th tch kh u o ktc. Hai ancol trong X l
A. HOCH2CH2CH2OH v CH3CH2CH2CH2OH. B. CH3CH2CH2OH v CH3CH2CH2CH2OH.
C. CH3CH2CH2OH v HOCH2CH2CH2OH.
D. HOCH2CH2CH2OH v
HOCH2CH2CH2CH2OH.
Cu 17: X l hn hp kim loi Ba v Al. Ha tan m gam X vo lng d nc thu c 8,96 lt H2 (ktc).
Cng ha tan m gam X vo dung dch NaOH d th thu c 12,32 lt kh H2 (ktc). Gi tr ca m l:
A. 58,85.
B. 21,80.
C. 13,70.
D. 57,50.
Cu 18: Phn ng no di y khng dng chng minh c im cu to phn t ca glucoz?
A. Ha tan Cu(OH)2 chng minh phn t c nhiu nhm chc OH.
B. Phn ng trng gng chng t trong phn t glucoz c nhm chc CHO.
C. Phn ng vi 5 phn t CH3COOH chng minh c 5 nhm OH trong phn t
D. Tc dng vi Na chng minh phn t c 5 nhm OH.
Cu 19: Chn cu ng trong cc cu sau:
A. Khi oxi ha ancol no, n chc th thu c anehit.
B. Phng php chung iu ch ancol no, n chc bc 1 l cho an ken cng nc.
C. un nng ancol metylic vi H2SO4 c 1700C thu c ete.
D. Ancol a chc ha tan Cu(OH)2 to thnh dung dch mu xanh.
Cu 20: Hn hp X c 2 este n chc l ng phn ca nhau. Cho 5,7 gam hn hp X tc dng ht vi 100ml
dung dch NaOH 0,5M thu c hn hp Y c hai hai ancol bn, cng s nguyn t cacbon trong phn t. Y kt
hp va ht vi t hn 0,06 gam H2. Cng thc hai este l
A. C2H3COOC3H7 v C3H7COOC2H5.
B. C2H3COOC3H7 v C2H5COOC3H5.
C. C3H5COOC2H5 v C3H7COOC2H3.
D. C3H5COOC3H7 v C3H7COOC3H5.
Cu 21: Dy gm tt c cc cht u phn ng vi HCOOH l
A. CH3NH2; C2H5OH; KOH; NaCl.
B. NH3; K; Cu; NaOH; O2; H2.
khoa ho HKHTN-HQGHN

C. AgNO3/ NH3; CH3NH2; C2H5OH; KOH; Na2CO3.
D. Na2O; NaCl; Fe;
CH3OH; C2H5Cl.
Cu 22: loi cc kh: SO2; NO2; HF trong kh thi cng nghip, ngi ta thng dn kh thi i qua dung
dch no di y?
A. HCl.
B. NaCl.
C. NaOH.
D. Ca(OH)2.
Cu 23: TNT (2,4,6- trinitrotoluen) c iu ch bng phn ng ca toluen vi hn hp gm HNO3 c v
H2SO4 c, trong iu kin un nng. Bit hiu sut ca ton b qu trnh tng hp l 80%. Lng TNT (2,4,6trinitrotoluen) to thnh t 230 gam toluen l
A. 550,0 gam.
B. 687,5 gam.
C. 454,0 gam.
D. 567,5 gam.
Cu 24: Thuc th duy nht c th dng nhn bit 3 cht lng ng trong 3 l mt nhn: phenol, stiren,
ancol benzylic l
A. dung dch NaOH. B. Na.
C. qu tm.
D. dung dch Br2.
Cu 25: Trong cng nghip, ngi ta tng hp NH3 theo phng trnh ha hc sau:

N2 (k) + 3H2 (k)
NH3 (k).
Khi tng nng H2 ln hai ln ( gi nguyn nng ca kh nit v nhit ca phn ng) th tc phn
ng tng ln bao nhiu ln?
A. 8 ln.
B. 2 ln.
C. 4 ln.
D. 16 ln.
Cu 26: Cho kh CO (d) i qua ng s ng hn hp X gm: Al2O3 , MgO , Fe3O4 , CuO nung nng thu c
hn hp rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc phn ng
xy ra hon ton. Phn khng tan Z gm
A. Mg, FeO, Cu.
B. Mg, Fe, Cu.
C. MgO, Fe, Cu.
D. MgO, Fe3O4, Cu.
Cu 27: X phng ha hon ton 2,22 gam hn hp X gm hai este ng phn ca nhau cn dng va ht 30ml
dung dch NaOH 1M. Mt khc khi t chy hon ton hn hp X thu c kh CO2 v hi H2O vi th tch
bng nhau ( cng iu kin). Cng thc ca hai este l
A. HCOOCH2CH2CH3 v HCOOCH(CH3)CH3. B. CH3COOCH3 v HCOOC2H5.
C. CH3COOC2H5 v C2H5COOCH3.
D. CH3COOCH=CH2 v CH2=CHCOOCH3.
Cu 28: Cho 1,0 gam bt st tip xc vi oxi mt thi gian thy khi lng bt vt qu 1,41 gam. Nu ch to
thnh mt oxit st duy nht th oxit l
A. Fe3O4 hoc Fe2O3. B. FeO.
C. Fe3O4.
D. Fe2O3.
Cu 29: t chy 0,15 gam cht hu c X thu c 0,22 gam CO2; 0,18 gam H2O v 56ml N2 (ktc). Bit t
khi hi ca X so vi oxi l 1,875. Cng thc phn t ca X l
A. C3H10N.
B. C2H8N2.
C. CH4N.
D. C2H6N2.
Cu 30: C cc l ring bit ng cc dung dch khng mu: AlCl3, ZnCl2, MgCl2, FeSO4, Fe(NO3)3, NaCl. Ch
dng dung dch no di y phn bit cc l mt nhn trn?
A. Na2CO3.
B. Ba(OH)2.
C. NaOH.
D. NH3.
Cu 31: Hn hp X gm HCOOH v CH3COOH trn theo t l mol 1 : 1. Cho 10,6 gam hn hp X tc dng
vi 11,5 gam C2H5OH (c H2SO4 c lm xc tc) thu c m gam este (hiu sut phn ng este ha t 80%).
Gi tr ca m l
A. 14,08.
B. 12,96.
C. 17,6.
D. 16,2.
Cu 32: Cho 100ml dung dch aminoaxit X 0,2M tc dng va vi 80ml dung dch NaOH 0,25M. Mt khc
100ml dung dch aminoaxit trn tc dng va vi 80ml dung dch HCl 0,5M. Bit X c t khi hi so vi H2
bng 52. Cng thc ca X l
A. (H2N)2C2H2(COOH)2.
B. H2NC3H5(COOH)2.
C. (H2N)2C2H3COOH.
D. H2NC2H3(COOH)2.

khoa ho HKHTN-HQGHN

Cu 33: Cho 18,5 gam hn hp X gm Fe, Fe3O4 tc dng vi 200ml dung dch HNO3 long, un nng v
khuy u. Sau khi phn ng xy ra hon ton c 2,24 lt kh NO duy nht (ktc), dung dch Y v cn li 1,46
gam kim loi. Khi lng mui trong Y v nng mol ca dung dch HNO3 l
A. 65,34 gam; 2,7M. B. 65,34 gam; 3,2M.
C. 48,6 gam; 2,7M.
D. 48,6 gam; 3,2M.
Cu 34: Khi cho ankan X (trong phn t c %C = 83,72) tc dng vi clo ch thu c 2 dn xut monoclo
ng phn ca nhau. Tn ca X l
A. 2 metylpropan. B. 2,3 imetylbutan.
C. n hexan.
D. 3 metylpentan.
Cu 35: Cho 28,8 gam bt Cu vo 200ml hn hp axit HNO31,0M v H2SO4 0,5M thy thot ra V lt kh NO
(sn phm kh duy nht, o ktc). Gi tr ca V l
A. 2,24 lt.
B. 6,72 lit.
C. 4,48 lt.
D. 1,12 lit.
Cu 36: Cho cc cht sau: tinh bt; glucoz; saccaroz; mantoz; xenluloz. S cht khng tham gia phn ng
trng gng l
A. 2.
B. 1.
C. 4.
D. 3.
Cu 37: Cho ancol X tc dng vi axit Y c este E. Lm bay hi 8,6 gam E thu c th tch hi ng bng
th tch ca 3,2 gam O2 (o cng iu kin). Bit MX > MY. Cng thc cu to ca E l
A. CH2=CHCOOC2H5.
B. HCOOCH=CHCH3. C. HCOOCH2CH=CH2.
D. CH2=CHCOOCH3.
Cu 38: Cho 3 cht ring bit: Al, Mg, Al2O3. Dung dch c th phn bit 3 cht rn trn l
A. NaOH.
B.HCl.
C. CuCl2.
D. HNO3.
Cu 39: Ha tan hon ton 3,9 gam kali vo 36,2 gam nc thu c dung dch c nng
A. 4,04%.
B. 15,47%.
C. 14,00%.
D. 13,97%.
Cu 40: Cho cc cht sau: HCl; NaOH; Na3PO4; Na2CO3; Ca(OH)2. S cht ti a c th lm mm nc cng
tm thi l
A. 2.
B. 3.
C. 4.
D. 5.
PHN RING (10 cu)
Th sinh ch c lm mt trong hai phn
Phn 1: Theo chng trnh chun:
Cu 41: C mt loi polime nh sau: - CH2 CH2 CH2 CH2 CH2 CH2 -
Cng thc mt mt xch ca polime ny l
A. CH2 CH2
B. CH2 CH2 CH2 CH2 CH2 CH2
C. CH2 CH2 CH2
D. CH2
Cu 42: Hin tng quan st c khi cho dung dch etylamin tc dng vi dung dch FeCl3 l
A. xut hin kt ta mu nu .
B. c khi mu trng bay ra.
C. xut hin kt ta mu trng.
D. c kh thot ra lm xanh giy qu m.
Cu 43: trung ha 500ml dung dch X cha hn hp HCl 0,1M v H2SO4 0,3M cn bao nhiu ml dung dch
hn hp gm NaOH 0,3M v Ba(OH)2 0,2M?
A. 750.
B. 250.
C. 125.
D. 500.
Cu 44: Ha tan 4,0 gam hn hp gm Fe v kim loi X ( ha tr II, ng trc hidro trong dy in ha) bng
dung dch HCl d, thu c 2,24 lt kh H2 (ktc). ha tan 2,4 gam X th cn dng cha n 250ml dung
dch HCl 1M. Kim loai X l
A. Ba.
B. Zn.
C. Ca.
D. Mg.
Cu 45: t mt lng Al trong 6,72 lt O2. Cht rn thu c sau phn ng cho ha tan hon ton vo dung
dch HCl thy thot ra 6,72 lt H2 ( cc th tch kh o ktc). Khi lng Al dng l
A. 16,2 gam.
B. 5,4 gam.
C. 8,1 gam.
D. 10,8 gam.

khoa ho HKHTN-HQGHN

Cu 46: Cho x gam hn hp bt cc kim loi Ni v Cu vo dung dch AgNO3 d, khuy k cho n khi phn
ng kt thc thu c 54 gam kim loi. Mt khc cng cho x gam hn hp bt kim loi trn vo dung dch
CuSO4 d, khuy k cho n khi phn ng kt thc thu c (x + 0,5) gam kim loi. Gi tr ca x l
A. 5,9.
B. 9,6.
C. 15,5.
D. 32,4.
Cu 47: t chy hon ton 2,24 lt (ktc) hn hp X gm C2H4 v C4H4 th th tch kh CO2 (ktc) v khi
lng hi H2O thu c ln lt l
A. 3,36 lit v 3,6 gam.B. 8,96 lit v 3,6 gam.
C. 6,72 lit v 3,6 gam.
D. 5,6 lt v 2,7 gam.
Cu 48: Nung m gam bt st trong oxi thu c 3,0 gam hn hp cht rn X. Ha tan ht hn hp X trong
dung dch HNO3 (d), thot ra 0,56 lt kh NO (l sn phm kh duy nht, o ktc). Gi tr ca m l
A. 2,90.
B. 2,52.
C. 2,10.
D. 4,20.
Cu 49: Ha tan hon ton 13,92 gam Fe3O4 bng dung dch HNO3 thu c 4,48ml kh NxOy (ktc). Kh NxOy
l
A. N2O.
B. NO2.
C. N2O5.
D. NO.
Cu 50: Trong dy bin ha:

C2H6
C2H5Cl
C2H5OH
CH3CHO
CH3COOH
CH3COOC2H5
C2H5OH.
S phn ng oxi ha - kh trn dy bin ha l
A. 2.
B. 4.
C. 3.
D. 5.
Phn 2: Theo chng trnh nng cao:
Cu 51: Hn hp X nng 9 gam gm Fe3O4 v Cu. Cho X vo dung dch HCl d thy cn 1,6 gam Cu khng
tan. Khi lng Fe3O4 c trong X l
A. 5,8 gam.
B. 7,4 gam.
C. 3,48 gam.
D. 2,32 gam.
Cu 52: Criolit c cng thc phn t l Na3AlF6 c thm vo Al2O3 trong qu trnh in phn Al2O3 nng
chy sn xut nhm vi l do chnh l
A. lm tng dn in ca Al2O3 nng chy.
B. to mt lp ngn cch bo v nhm nng chy khi b oxihoa.
C. bo v in cc khi b n mn.
D. lm gim nhit nng chy ca Al2O3 cho php in phn nhit thp, gip tit kim nng
lng.
Cu 53: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va
vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l
A. H2NC2H4COOH. B. H2NC4H8COOH.
C. H2NC3H6COOH.
D. H2NCH2COOH.
Cu 54: Nung nng hon ton 27,3 gam hn hp NaNO3, Cu(NO3)2. Hn hp kh thot ra c dn vo nc
d th thy c 1,12 lt kh (ktc) khng b hp th ( lng O2 ha tan khng ng k). Khi lng Cu(NO3)2
trong hn hp ban u l
A. 18,8 gam.
B. 28,2 gam.
C. 8,6 gam.
D. 4,4 gam.
Cu 55: un nng ancol no, n chc, mch h X vi hn hp KBr v H2SO4 c thu c cht hu c Y
(cha C,H,Br), trong Br chim 73,4% v khi lng. Cng thc phn t ca X l
A. C3H7OH.
B. C2H5OH.
C. C4H9OH.
D. CH3OH.
Cu 56: Ha tan hon ton 104,25 gam hn hp X gm NaCl v NaI vo nc c dung dch Y. Sc kh Cl2
d vo dung dch Y. Kt thc th nghim, c cn dung dch thu c 58,5 gam mui khan. Khi lng NaCl c
trong hn hp X l
A. 17,55 gam.
B. 58,50 gam
C. 29,25 gam.
D. 23,40 gam.
Cu 57:Ch dng ha cht no di y phn bit hai ng phn khc chc c cng cng thc phn t
C3H8O?
A. CuO.
B. dung dch AgNO3/ NH3. C. Cu(OH)2.
D. Al
khoa ho HKHTN-HQGHN

Cu 58: Ngm mt inh st sch trong 200ml dung dch CuSO4. Sau khi phn ng kt thc, ly inh st ra khi
dung dch ra sch nh bng nc ct v sy kh ri em cn thy khi lng inh st tng 0,8 gam so vi ban
u. Nng mol ca dung dch CuSO4 dng l
A. 0,0625M.
B. 0,05M.
C. 0,625M.
D. 0,5M.
Cu 59: C 5 gi bt mu tng t nhau l ca cc cht: CuO, FeO, MnO2, Ag2O, (Fe+FeO). C th dng dung
dch no trong cc dung dch di y phn bit cc cht trn?
A. Ba(OH)2.
B. AgNO3.
C. HCl.
D. HNO3.
Cu 60: Polime X c cng thc ( NH [CH2]2 CO )n. Pht biu no sau y khng ng?
A. X ch c to ra t phn ng trng ngng.
B. X c th ko si.
C. X thuc loi poliamit.
D. % khi lng C
trong X khng thay i vi mi gi tr ca n.
..Ht
TRNG THPT CHUYN
NGUYN HU
THI TH I HC LN I - 2011
MN HOA HC
(60 cu trc nghim)
I. Phn chung cho tt c cc th sinh( 40 cu, t cu 1 n cu 40)

Cu 1: Phenol phn ng c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br 2, (CH3CO)2O,
CH3COOH, Na, NaHCO3, CH3COCl:
A. 4
B. 6
C. 5
D. 7
Cu 2: Kh 1,6 gam hn hp 2 anehit no bng H 2 thu c hn hp 2 ancol. un nng hn hp 2 ancol vi
H2SO4 c c hn hp 2 olefin l ng ng lin tip. t chy ht 2 olefin ny c 3,52 gam CO 2. Cc
phn ng xy ra hon ton. Cng thc ca 2 anehit l:
A. HCHO v CH3CHO
B. CH3CHO v CH2(CHO)2
C. CH3CHO v C2H5CHO
D. C2H5CHO v C3H7CHO
Cu 3: Oxi ha 3,16 gam hn hp 2 ancol n chc thnh anehit bng CuO, t 0, sau phn ng thy khi lng
cht rn gim 1,44 gam. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO 3/NH3 thu c
36,72 gam Ag. Hai ancol l:
A. C2H5OH v C3H7CH2OH
B. CH3OH v C2H5CH2OH
C. CH3OH v C2H5OH
D. C2H5OH v C2H5CH2OH
Cu 4: Trung ha 28 gam mt cht bo cn dng 20 ml dung dch NaOH 0,175M. Ch s axit ca cht bo l:
A. 9
B. 7
C. 8
D. 6
+
2+
Cu 5: Cho dung dch X gm 0,09 mol Na ; 0,05 mol Ca ; 0,08 mol Cl ; 0,1 mol HCO3-; 0,01 mol NO3-.
loi b ht ion Ca2+ trong X cn dng 1 lng va dung dch cha a gam Ca(OH)2. Gi tr ca a l:
A. 2,96
B. 4,44
C. 7,4
D. 3,7
Cu 6: Cho cc cht sau: CH3COOH (1), C2H5OH (2), C2H6 (3), C2H5Cl (4). Th t cc cht tng dn nhit
si l:
A. 4, 3, 2, 1
B. 3, 4, 2, 1
C. 1, 2, 3, 4
D. 4, 3, 1, 2
Cu 7: Thy phn hon ton 500 gam protein X thu c 14,85 gam glyxin. S mt xch glyxin trong X l (bit
phn t khi ca X l 50.000):
A. 201
B. 189
C. 200
D. 198

khoa ho HKHTN-HQGHN

Cu 8: Cho kh H2S tc dng vi cc cht: dung dch NaOH, kh clo, nc clo, dung dch KMnO 4/H+, kh oxi
d un nng, dung dch FeCl3, dung dch ZnCl2. S trng hp xy ra phn ng v s trng hp trong lu
hunh b oxi ha ln S+6 l:
A. 7 - 2
B. 6 - 3
C. 6 -1
D. 6 -2
Cu 9: C bao nhiu cht c th phn ng vi axit fomic trong s cc cht sau: KOH, NH 3, CaO, Mg, Cu,
Na2CO3, Na2SO4, CH3OH, C6H5OH, AgNO3/NH3?
A. 8
B. 9
C. 7
D. 6
Cu 10: Nung 8,42g hn hp X gm Al, Mg, Fe trong oxi sau mt thi gian thu c 11,62g hn hp Y. Ha
tan hon ton Y trong dung dch HNO 3 d thu c 1,344 lt NO (ktc) l sn phm kh duy nht. S mol
HNO3 phn ng l:
A. 0,56 mol
B. 0,64 mol
C. 0,48 mol
D. 0,72 mol
Cu 11: t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH 4, C2H4, C2H6, C3H8 thu c 6,16 gam CO2 v
4,14 gam H2O. S mol C2H4 trong hn hp trn l:
A. 0,02 mol
B. 0,01 mol
C. 0,08 mol
D. 0,09 mol
Cu 12: Cho cc cht: FeS, Cu2S, FeSO4, H2S, Ag, Fe, KMnO4, Na2SO3, Fe(OH)2. S cht c th phn ng vi
H2SO4 c nng to ra SO2 l:
A. 9
B. 8
C. 6
D. 7
Cu 13: X l dung dch Na[Al(OH)4]. Cho t t n d cc dung dch sau y vo dung dch X: AlCl 3,
NaHSO4, HCl, BaCl2, kh CO2. S trng hp thu c kt ta sau phn ng l:
A. 3
B. 4
C. 2
D. 1
Cu 14: Kh hon ton m gam oxit MxOy cn va 10,752 lt H2 (ktc) thu c 20,16g kim loi M. Cho
ton b lng kim loi ny tc dng vi dung dch HNO 3 long d thu c 8,064 lt NO (ktc) l sn phm
kh duy nht. Cng thc ca MxOy l:
A. FeO
B. Fe3O4
C. Cr2O3
D. Cu2O
Cu 15: Cho 7,1g hn hp gm 1 kim loi kim X v 1 kim loi kim th Y tc dng ht vi lng d dung
dch HCl long thu c 5,6 lt kh (ktc). Hai kim loi X v Y ln lt l:
A. K, Ca
B. Li, Be
C. Na, Mg
D. K, Ba
Cu 16: Dy cc cht no sau y u khng lm i mu qu tm:
A. Axit glutamic, valin, alanin
B. Axit glutamic, lysin, glyxin
C. Alanin, lysin, phenyl amin
D. Anilin, glyxin, valin
Cu 17: Hn hp X gm HCOOH, CH3COOH (t l mol 1:1), hn hp Y gm CH3OH, C2H5OH (t l mol 2:3).
Ly 16,96 gam hn hp X tc dng vi 8,08 gam hn hp Y (c xc tc H 2SO4 c) thu c m gam este (hiu
sut cc phn ng este ha u bng 80%). Gi tr ca m l:
A. 12,064 gam
B. 22,736 gam
C. 17,728 gam
D. 20,4352 gam
Cu 18: Hn hp X gm O2 v O3 c t khi so vi H2 l x. t chy hon ton 1 lt hn hp Y gm CO v H2
cn 0,4 lt hn hp X. Bit t khi ca Y so vi H 2 bng 7,5 v cc th tch kh o cng iu kin nhit , p
sut. Gi tr ca x l:
A. 19,2
B. 22,4
C. 17,6
D. 20
Cu 19: Este X c CTPT C5H8O2 khi tc dng vi NaOH to ra 2 sn phm u c kh nng tham gia phn ng
trng gng. S cht X tha mn iu kin trn l:
A. 2
B. 1
C. 3
D. 4
Cu 20: Thm t t 70ml dung dch H2SO4 1M vo 100ml dung dch Na2CO3 1M thu c dung dch Y. Cho
Ba(OH)2 d vo dung dch Y th khi lng kt ta thu c l:
A. 22,22g
B. 11,82g
C. 28,13g
D. 16,31g
Cu 21: Cht no sau y c kh nng to ra 4 loi dn xut mono brom?
A. m-imetylbenzen
B. o-imetylbenzen
C. p-imetylbenzen
D. Etylbenzen
khoa ho HKHTN-HQGHN

Cu 22: Hn hp A gm CH4, C2H4, C3H4. Nu cho 13,4 gam hn hp X tc dng vi dung dch AgNO3/NH3 d th thu
c 14,7gam kt ta. Nu cho 16,8 lt hn hp X (ktc) tc dng vi dung dch brom th thy c 108gam brom phn
ng. % th tch CH4 trong hn hp X l:
A. 30%
B. 25%
C. 35%
D. 40%
Cu 23: Ha tan a mol Fe trong dung dch H 2SO4 thu c 12,32 lt SO 2 (ktc) l sn phm kh duy nht v
dung dch X. C cn dung dch X thu c 75,2 gam mui khan. Gi tr ca a l:
A. 0,4
B. 0,6
C. 0,3
D. 0,5
Cu 24: Nhit phn cc mui sau: (NH 4)2Cr2O7, CaCO3, Cu(NO3)2, KMnO4, Mg(OH)2, AgNO3, NH4Cl, BaSO4.
S phn ng xy ra v s phn ng oxi ha kh l:
A. 8 - 5
B. 7 - 4
C. 6 - 4
D. 7 - 5
Cu 25: Dy no sau y gm tt c cc cht u c lin kt cng ha tr, lin kt ion v lin kt cho nhn (theo
quy tc bt t)?
A. FeCl3, HNO3, MgCl2.
B. H2SO4, NH4Cl, KNO2.
C. KNO3, FeCl3, NaNO3.
D. NH4NO3, K2SO4, NaClO4.
Cu 26: X v Y l hai kim loi thuc cng mt nhm A. Bit Z X < ZY v ZX + ZY = 32. Kt lun no sau y l
ng vi X, Y?
A. X, Y u c 2 electron lp ngoi cng
B. Tnh kim loi ca X mnh hn Y
C. Nng lng ion ha ca X nh hn ca Y
D. Bn knh nguyn t ca X ln hn Y
Cu 27: Khi lng ca mt on mch t nilon-6,6 l 27346 u v ca mt on mch t capron l 17176 u. S
mt xch trong on mch t nilon-6,6 v t capron nu trn ln lt l
A. 121 v 152.
B. 113 v 114.
C. 121 v 114.
D. 113 v 152.
2 SO2 (kh)+O 2 ( kh)

2 SO3 (kh)
Cu 28: Cho cn bng:
H < 0. cn bng trn chuyn dch sang phi
th phi:
A. Gim p sut, gim nhit
B. Tng p sut, tng nhit
C. Gim p sut, tng nhit
D. Tng p sut, gim nhit
Cu 29: X l mt tetrapeptit. Cho m gam X tc dng va vi 0,3 mol NaOH thu c 34,95g mui. Phn t
khi ca X c gi tr l:
A. 324
B. 432
C. 234
D. 342
Cu 30: Tripeptit mch h X v tetrapeptit mch h Y u c to ra t mt amino axit no, mch h c 1
nhm COOH v 1 nhm NH2. t chy hon ton 0,1 mol X thu c sn phm gm CO 2, H2O, N2 trong
tng khi lng CO2, H2O l 36,3 gam. Nu t chy hon ton 0,2 mol Y cn s mol O2 l:
A. 1,875
B. 1,8
C. 2,8
D. 3,375
Cu 31: Cho cc cht sau: Al, ZnO, CH3COONH4, KHSO4, H2NCH2COOH, H2NCH2COONa, KHCO3,
Pb(OH)2, ClH3NCH2COOH, HOOCCH2CH(NH2)COOH. S cht c tnh lng tnh l:
A. 7
B. 6
C. 8
D. 5
Cu 32: Cho m gam glucoz ln men thnh ancol etylic vi hiu sut 75%. Hp th ton b kh CO 2 sinh ra
vo dung dch Ca(OH)2 d thu c 90g kt ta. Gi tr ca m l:
A. 81g
B. 96g
C. 108g
D. 162g
Cu 33: C 6 dung dch ring bit: Fe(NO3)3, AgNO3, CuSO4, ZnCl2, Na2SO4, MgSO4. Nhng vo mi dung dch
mt thanh Cu kim loi, s trng hp xy ra n mn in ha l:
A. 3
B. 1
C. 4
D. 2
Cu 34: Cho cc cht: CH3CH2OH, C2H6, CH3OH, CH3CHO, C6H12O6, C4H10, C2H5Cl. S cht c th iu ch
trc tip ra axit axetic (bng 1 phn ng) l:
A. 2
B. 3
C. 4
D. 5
khoa ho HKHTN-HQGHN

Cu 35: Cho m gam KOH vo 2 lt dung dch KHCO3 a mol/l thu c 2 lt dung dch X. Ly 1 lt dung dch X
tc dng vi dung dch BaCl2 d thu c 15,76g kt ta. Mt khc, cho 1 lt dung dch X vo dung dch CaCl 2
d ri un nng, sau khi cc phn ng xy ra hon ton thu c 10g kt ta. Gi tr ca m v a ln lt l:
A. 8,96g v 0,12 M
B. 5,6g v 0,04 M
C. 4,48g v 0,06 M
D. 5,04g v 0,07 M
Cu 36: Sc clo t t n d vo dung dch KBr th hin tng quan st c l:
A. Dung dch c mu vng
B. Khng c hin tng g
C. Dung dch c mu nu
D. Dung dch t khng mu chuyn sang mu vng sau li mt mu.
Cu 37: Hp cht thm X c cng thc phn t C 6H8N2O3. Cho 28,08 gam X tc dng vi 200 ml dung dch
KOH 2M sau phn ng thu c dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ca m l:
A. 21,5 gam
B. 38,8 gam
C. 30,5 gam
D. 18,1 gam
Cu 38: Ha tan Fe3O4 trong lng d dung dch H2SO4 long c dung dch X. Hi dung dch X tc dng
c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al?
A. 5
B. 6
C. 7
D. 4
Cu 39: Cho m gam bt Cu vo 200 ml dung dch AgNO 3 0,2M, sau phn ng thu c 3,88g cht rn X v dung
dch Y. Cho 2,925g bt Zn vo dung dch Y sau phn ng thu c 5,265g cht rn Z v dung dch ch cha 1 mui
duy nht. Gi tr ca m l:
A. 3,17
B. 2,56
C. 1,92
D. 3,2
Cu 40: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CuSO4, NaOH, NaHSO4, K2CO3, Ca(OH)2,
H2SO4, HNO3, MgCl2, HCl, Ca(NO3)2. S trng hp c phn ng xy ra l:
A. 9
B. 6
C. 8
D. 7
II. Phn ring (10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II )
Phn I: Theo chng trnh Chun (t cu 41 n cu 50)
Cu 41: t chy 10,4 gam mt axit cacboxylic no, a chc mch h, khng phn nhnh thu c 0,3 mol CO 2
v 0,2 mol H2O. Cng thc cu to ca 2 axit l:
A. HOOC-(CH2)3-COOH.
B. HOOC-CH2-COOH.
C. HOOC-CH2-CH2-COOH.
D. HOOC-(CH2)4-COOH.
Cu 42: Hp cht A1 c CTPT C3H6O2 tho mn s
dd NaOH
dd H2SO4
dd AgNO3 / NH3
A1
A2
A3
A4
Cng thc cu to ca A1 l:
A. HCOOCH2CH3.
B. CH3COCH2OH.
C. CH3CH2COOH.
D. HOCH2CH2CHO.
Cu 43: Dy no sau y gm cc kim loi u c th iu ch c bng phng php nhit luyn:
A. Zn, Mg, Ag
B. Ba, Fe, Cu
C. Al, Cu, Ag
D. Cr, Fe, Cu
Cu 44: Cc ion no sau y khng th cng tn ti trong mt dung dch:
A. K+, Mg2+, NO3, Cl-.
B. Cu2+, Fe2+, HSO4, NO3.
C. Mg2+, Al3+, Cl, HSO4.
D. Na+, NH4+, SO42, PO43.
Cu 45: Ha tan hon ton 30,4 gam cht rn X gm Cu, CuS, Cu 2S v S bng HNO3 d thy thot ra 20,16 lt
kh NO duy nht (ktc) v dung dch Y. Thm dung dch Ba(OH)2 d vo dung dch Y c m gam kt ta.
Gi tr ca m l:
A. 81,55 gam.
B. 115,85 gam.
C. 110,95 gam.
D. 29,4 gam.
khoa ho HKHTN-HQGHN

Cu 46: Hn hp kh X gm mt hirocacbon A v H2. T khi ca X so vi H2 bng 6,7. un X vi bt Ni
nung nng n khi phn ng xy ra hon ton thu c hn hp Y gm ankan v H 2 d. T khi ca Y so vi H2
bng 16,75. Cng thc phn t ca A l:
A. C2H2
B. C2H4
C. C3H4
D. C3H6
Cu 47: Mt - aminoaxit no X ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 3,56 gam X tc dng va
vi HCl to ra 5,02 gam mui. Tn gi ca X l:
A. Alanin
B. Valin
C. Lysin
D. Glyxin
Cu 48: Oxi ha hon ton m gam mt ancol n chc X bng CuO th thu c hn hp kh v hi c t khi
so vi H2 bng 19. Sau phn ng ngi ta nhn thy khi lng cht rn gim 4,8 g. Gi tr ca m l:
A. 15 g
B. 1,8 g
C. 12 g
D. 18 g
Cu 49: Th nghim no sau y c kt ta sau phn ng?
A. Thi CO2 n d vo dung dch Ca(OH)2.
B. Cho dung dch HCl n d vo dung dch NaCrO2
C. Cho dung dch NaOH n d vo dung dch Cr(NO3)3.
D. Cho dung dch NH3 n d vo dung dch FeCl3.
Cu 50: Pht biu no sau y khng ng?
A. m chy magie c th c dp tt bng ct kh.
B. Pht pho trng c cu trc mng tinh th phn t
C. Trong phng th nghim, N2 c iu ch bng cch un nng dung dch NH4NO2 bo ho.
D. CF2Cl2 b cm s dng do khi thi ra kh quyn th ph hy tng ozon.
Phn II: Theo chng trnh nng cao (t cu 51 n cu 60)
Cu 51: Ch dng 1 ha cht phn bit cc cht sau: lng trng trng, dung dch glucoz, dung dch glixerol,
dung dch metanal, etanol. Ha cht l:
A. Cu(OH)2.
B. KMnO4
C. HNO3 c
D. HCl
Cu 52: Khng th iu ch trc tip axetanehit t:
A. Vinyl axetat
B. Etilen
C. Etanol
D. Etan
Cu 53: Trn 250 ml dung dch HCl 0,08 M v H2SO4 0,01M vi 250 ml dung dch Ba(OH)2 x M. Thu m gam
kt ta v 500ml dung dch c pH = 12. Gi tr ca m v x ln lt l:
A. 1,165g v 0,04M
B. 1,165g v 0,04M
C. 0,5825g v 0,03M D. 0,5825 v 0,06M
Cu 54: Th tch dung dch Br2 0,5M cn dng oxi ha ht 200 ml dung dch CrBr3 1M l:
A. 300 ml
B. 600 ml
C. 450 ml
D. 900 ml
Cu 55: Dung dch no sau y c th ha tan c vng?
A. KNO3
B. HNO3 c nng
C. HCl c
D. HNO3 c + HCl c t l 1:3
Cu 56: Cho cc kim loi: Na, Ca, Al, Fe, Cu. Nu ch dng H2O c th phn bit c bao nhiu kim loi:
A. 0
B. 3
C. 1
D. 5
Cu 57: Anehit X c cha 4 nguyn t C trong phn t. Khi cho 0,1 mol X tc dng vi dung dch
AgNO3/NH3 d thu c 43,2 gam Ag. Mt khc 0,15 mol X lm mt mu va 200 ml dung dch Br2 1,5M.
X l:
A. C2H4(CHO)2
B. C3H7CHO
C. O=HC-CC-CHO
D. O=CH-CH=CH-CHO
Cu 58: C6H12 khi tc dng vi dung dch HBr ch to ra 1 sn phm monobrom duy nht. S cng thc cu to
ca C6H12 tha mn iu kin trn l:
khoa ho HKHTN-HQGHN

A. 4
B. 2
C. 3
D. 1
Cu 59: Cho sut in ng chun ca cc pin in ho: Mg-Ni l 2,11 V; Ni-Ag l 1,06 V. Bit th in cc
chun ca cp Ag+/Ag bng 0,8V. Th in cc chun ca cp Mg2+/Mg v cp Ni2+/Ni ln lt l:
A. -2,37V v -0,26V.
B. -1,87V v +0,26V. C. -1,46V v -0,34V. D. -0,76V v -0,26V.
Cu 60: Cho 27,48 gam axit picric vo bnh kn dung tch 20 lt ri nung nng nhit cao phn ng xy
ra hon ton thu c hn hp kh gm CO2, CO, N2 v H2. Gi bnh 12230C th p sut ca bnh l P atm.
Gi tr ca P l:
A. 7,724 atm
B. 6,624 atm
C. 8,32 atm
D. 5,21 atm
TRNG THPT CHUYN
NGUYN HU
THI TH I HC LN III - 2011

MN HA HC
(60 cu trc nghim)
Cu 1: Hirocacbon X c cng thc phn t C6H10. X tc dng vi dung dch AgNO3/NH3 to ra kt ta vng.
Khi hiro ha hon ton X thu c neo-hexan. X l:
A. 2,2-imetylbut-3-in
B. 2,2-imetylbut-2-in
C. 3,3-imetylbut-1-in
D. 3,3-imetylpent-1-in
Cu 2: X l hp cht thm c CTPT C7H8O khi cho X tc dng vi nc Br2 to ra sn phm Y c cha
69,565% Br v khi lng. X l:
A. o-crezol
B. m-crezol
C. Ancol benzylic
D. p-crezol
Cu 3: Thy phn 95,76g mantoz trong mi trng axit vi hiu sut phn ng t 75% thu c hn hp X.
Trung ha hn hp X bng NaOH thu c hn hp Y. Cho Y tc dng vi dung dch AgNO 3/NH3 d un nng
thu c m gam Ag kt ta. Gi tr ca m l:
A. 120,96 gam
B. 60,48 gam
C. 105,84 gam
D. 90,72 gam
Cu 4: Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d. Sau phn ng lm bay hi
cn thn dung dch thu c (m + 11,68) gam mui khan. Nu cho m gam hn hp X tc dng vi dung dch KOH va
, sau phn ng lm bay hi cn thn dung dch thu c (m + 19) gam mui khan. Gi tr ca m l:
A. 36,6 gam
B. 38,92 gam
C. 38,61 gam
D. 35,4 gam
Cu 5: Tng s ht c bn trong nguyn t ca nguyn t M, X ln lt l 58 v 52. Hp cht MX n c tng s
ht proton trong mt phn t l 36. Lin kt trong phn t MXn thuc loi lin kt:
A. Cho nhn
B. Cng ha tr phn cc
C. Ion
D. Cng ha tr khng phn cc
Cu 6: Cht no sau y khng c kh nng lm mt mu dung dch thuc tm:
A. HCl
B. SO3
C. H2S
D. SO2
Cu 7: t chy hon ton 5,4g mt amin X n chc trong lng va khng kh. Dn sn phm kh qua bnh
ng nc vi trong d thu c 24g kt ta v c 41,664 lt (ktc) mt cht kh duy nht thot ra. X tc dng vi
HNO2 to ra kh N2. X l:
A. imetylamin
B. anilin
C. etylamin
D. metylamin
Cu 8: in phn 200 ml dung dch hn hp gm HCl 0,2M v CuSO 4 1M bng in cc tr. Khi catot c 6,4
gam Cu th th tch kh thot ra anot l:
A. 0,672 lt
B. 1,344 lt
C. 1,12 lt
D. 0,896 lt
Cu 9: Hn hp X gm Al, FexOy. Tin hnh phn ng nhit nhm hon ton m gam hn hp X trong iu kin
khng c khng kh thu c hn hp Y. Chia Y thnh 2 phn.

khoa ho HKHTN-HQGHN

Phn 1 cho tc dng vi dung dch NaOH d thu c 1,008 lt H 2 (ktc) v cn li 5,04g cht rn khng
tan.
Phn 2 c khi lng 29,79gam, cho tc dng vi dung dch HNO 3 long d thu c 8,064 lt NO (ktc, l
sn phm kh duy nht). Gi tr ca m v cng thc ca oxit st l:
A. 39,72 gam v FeO
B. 39,72 gam v Fe3O4
C. 38,91 gam v FeO
D. 36,48 gam v Fe3O4
Cu 10: Cho 6,8g mt hp cht hu c n chc tc dng va vi dung dch cha 0,3 mol AgNO3/NH3 thu
c 21,6g Ag. X l:
A. 2-metylbut-3-inal
B. But-1-inal
C. but-2-inal
D. But - 3- inal
Cu 11: Trn cc dung dch HCl 0,75M; HNO3 0,15M; H2SO4 0,3M vi cc th tch bng nhau th c dung
dch X. Trn 300 ml dung dch X vi 200 ml dung dch Ba(OH)2 0,25M thu c m gam kt ta v dung dch Y
c pH = x. Gi tr ca x v m ln lt l:
A. 1 v 2,23 gam
B. 1 v 6,99 gam
C. 2 v 2,23 gam
D. 2 v 1,165 gam
Cu 12: C 6 ng nghim ng 6 dung dch long FeCl3, NH4Cl, Cu(NO3)2, FeSO4, AlCl3, (NH4)2CO3. Ch
dng mt ha cht no sau y nhn bit c c 6 dung dch trn:
A. Qu tm
B. Dung dch AgNO3 C. Dung dch BaCl2
D. dung dch NaOH
Cu 13: Ha tan ht m gam Al trong dung dch hn hp NaOH, NaNO 3 thu c 6,048 lt (ktc) hn hp kh
gm NH3 v H2 c t l mol tng ng l 4:5. Gi tr ca m l:
A. 11,34 gam
B. 12,96 gam
C. 10,8 gam
D. 13,5 gam
2
SO4
+
3+
Cu 14: Dung dch X c cha H , Fe ,
; dung dch Y cha Ba2+, OH-, S2-. Trn X vi Y c th xy ra bao
nhiu phn ng ha hc?
A. 7
B. 5
C. 8
D. 6
Cu 15: Tin hnh cc th nghim sau y, trng hp no sau y s to ra kt ta khi kt thc th nghim?
A. Cho dung dch Ba(OH)2 d vo dung dch Na[Al(OH)4].
B. Cho Al vo dung dch NaOH d
C. Cho dung dch AlCl3 d vo dung dch Na[Al(OH)4].
D. Cho CaC2 tc dng vi nc d c dung dch A v kh B. t chy hon ton B ri hp thu ton b sn
phm chy vo dung dch A.
Cu 16: Hp cht hu c X c CTPT C4H8O2 mch thng tha mn cc tnh cht sau:
- X lm mt mu dung dch Br2.
- 4,4 gam X tc dng vi Na d thu c 0,56 lt H2 (ktc).
- Oxi ha X bi CuO, t0 to ra sn phm Y l hp cht a chc. CTCT ca X l:
A. CH3-CH2-CO-CHO
B. CH2=CH-CH(OH)-CH2OH
C. HO-(CH2)3-CH=O
D. HO-CH2-CH(CH3)-CHO
Cu 17: Axit no trong s cc axit sau c tnh axit mnh nht:
A. CH2F-CH2-COOH
B. CH3-CF2-COOH
C. CH3CHF-COOH
D. CH3-CCl2-COOH
Cu 18: phn bit O3 v O2 khng th dng ha cht no sau y:
A. Cacbon
B. Ag
C. PbS
D. Dung dch KI
Cu 19: un nng hn hp gm etanol v butan-2-ol vi H 2SO4 c th thu c ti a bao nhiu sn phm
hu c?
A. 5
B. 7
C. 8
D. 6
Cu 20: Dy cht no sau y gm cc cht ch c tnh oxi ha?
A. Cl2, H2O2, HNO3, H2SO4.
B. SO2, SO3, Br2, H2SO4.
C. Fe(NO3)3, CuO, HCl, HNO3
D. O3, Fe2O3, H2SO4, O2

khoa ho HKHTN-HQGHN

Cu 21: ha tan mt mu Zn trong dung dch HCl 25 0C cn 243 pht. Cng mu Zn tan ht trong dung
dch HCl nh trn 650C cn 3 pht. ha tan ht mu Zn trong dung dch HCl c nng nh trn 45 0C
cn thi gian bao lu:
A. 9 pht
B. 81 pht
C. 27 pht
D. 18 pht
Cu 22: Hn hp X gm 2 este n chc. Cho 0,5 mol X tc dng vi dung dch AgNO 3/NH3 d thu c
43,2g Ag. Cho 14,08g X tc dng vi dung dch KOH va thu c hn hp 2 mui ca 2 axit ng ng
lin tip v 8,256g hn hp 2 ancol no n chc ng ng lin tip, mch h. Cng thc ca 2 ancol l:
A. C4H9OH v C5H11OH
B. CH3OH v C2H5OH
C. C2H5OH v C3H7OH
D. C3H7OH v C4H9OH
Cu 23: Hp cht hu c X c cng thc phn t l C 4H6O4. Thy phn X trong mi trng NaOH un nng
to ra mt mui Y v mt ancol Z. t chy Y th sn phm to ra khng c nc. X l:
A. HCOOCH2CH2OOCH.
B. HOOCCH2COOCH3.
C. HOOC-COOC2H5.
D. CH3OOC-COOCH3.
Br2
KOH / C 2 H 5 OH , t 0
AgNO
3 / NH 3 HBr

Cu 24: Cho s : C2H4
X
Y
Z
Y. Y l
A. C2H6.
B. C2H2.
C. C2H5OH.
D. C2H4.
Cu 25: Kh Cl2 tc dng c vi: (1) kh H 2S; (2) dung dch FeCl2; (3) nc Brom; (4) dung dch FeCl 3; (5)
dung dch KOH.
A. 1, 2, 4, 5
B. 1, 2, 3, 4, 5
C. 1, 2, 5
D. 1, 2, 3, 5
Cu 26: Cho cc dung dch: FeCl3 (1); NaHSO4 (2); NaHCO3 (3); K2S (4); NH4Cl (5); AlCl3 (6); CH3COONa
(7). Cc dung dch c pH < 7 l:
A. 1, 2, 5, 6
B. 1, 2, 6
C. 1, 2
D. 1, 2, 3, 5, 6
Cu 27: Hn hp A gm C3H4 v H2. Cho A i qua ng ng bt Ni nung nng thu c hn hp B ch gm 3
hirocacbon c t khi so vi H2 l 21,5. T khi ca A so vi H2 l:
A. 10,4
B. 9,2
C. 7,2
D. 8,6
Cu 28: Trn dung dch cha Ba2+; Na+: 0,04 mol; OH-: 0,2 mol; vi dung dch cha K+; HCO3-: 0,06 mol;
CO32-: 0,05 mol thu c m gam kt ta. Gi tr ca m l:
A. 15,76 gam
B. 13,97 gam
C. 19,7 gam
D. 21,67 gam
Cu 29: Ha tan 54,44 gam hn hp X gm PCl3 v PBr3 vo nc c dung dch Y. trung ha hon ton
dung dch Y cn 500 ml dung dch KOH 2,6M. % khi lng ca PCl3 trong X l:
A. 26,96%
B. 12,125
C. 8,08%
D. 30,31%
Cu 30: X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam
hn hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton c
cn dung dch thu c 257,36g cht rn khan. Gi tr ca m l:
A. 150,88 gam
B. 155,44 gam
C. 167,38 gam
D. 212,12 gam
Cu 31: Nhit phn 50,56 gam KMnO4 sau mt thi gian thu c 46,72 gam cht rn. Cho ton b lng kh
sinh ra phn ng ht vi hn hp X gm Mg, Fe thu c hn hp Y nng 13,04 gam. Ha tan hon ton hn
hp Y trong dung dch H2SO4 c, nng d thu c 1,344 lt SO2 (ktc). % khi lng Mg trong X l:
A. 52,17%
B. 39,13%
C. 28,15%
D. 46,15%
Cu 32: Hn hp X gm 1 ankan v 1 anken. Cho X tc dng vi 4,704 lt H 2 (ktc) cho n phn ng hon ton thu
c hn hp Y gm 2 kh trong c H2 d v 1 hirocacbon. t chy hon ton Y ri cho sn phm vo nc vi
trong d thy khi lng bnh ng nc vi trong tng 16,2 gam v c 18 gam kt ta to thnh. Cng thc ca 2
hirocacbon l:
A. C2H6 v C2H4
B. C2H8 v C3H6
C. C4H10 v C4H8
D. C5H10 v C5H12
Cu 33: Trng hp no sau y khng tha mn quy tc bt t:
A. NH3, HCl
B. CO2, SO2
C. PCl5, SF6
D. N2, CO
khoa ho HKHTN-HQGHN

Cu 34: Mt ancol no, a chc X c s nhm OH bng s nguyn t cacbon. Trong X, H chim xp x 10%
v khi lng. un nng X vi cht xc tc nhit thch hp loi nc th thu c mt cht hu c Y
c MY = MX 18. Kt lun no sau y hp l nht:
A. T khi hi ca Y so vi X l 0,8
B. X l glixerol
C. Y l anehit acrylic
D. Y l etanal
Cu 35: Mt hn hp kim loi gm: Zn, Ag, Fe, Cu. Ha cht c th ha tan hon ton hn hp kim loi trn l:
A. Dung dch NaOH c
B. Dung dch HCl c, d
C. Dung dch HNO3 long, d
D. Dung dch H2SO4 c, ngui, d
Cu 36: Cho cc phn ng ha hc:
(1) C2H5OH + H2SO4 c C2H5OSO3H + H2O
0
H 2 SO 4 dac
,170
C
(2) C2H5OH
C2H4 + H2O
(3) C2H5OH + CH3COOH CH3COOC2H5 + H2O
0
t
(4) C2H5Br + NaOH
C2H5OH + NaBr
H

(5) C2H4 + H2O
C2H5OH
Cc phn ng th l:
A. 1, 4
B. 1, 4, 5
C. 1, 3, 4
D. 4
Cu 37: Cho 200 ml dung dch KOH 0,9M; Ba(OH) 2 0,2M vo 100 ml dung dch H2SO4 0,3M v Al2(SO4)3
0,3M. Sau khi cc phn ng xy ra hon ton, khi lng kt ta thu c l:
A. 9,32 gam
B. 10,88 gam
C. 14 gam
D. 12,44 gam
Cu 38: Phn ng no sau y mch polime c gi nguyn?
o
o
t
H ,t
A. PVA + NaOH
B. Xenluloz + H2O
o
to

t
C. PS
D. Nha Rezol
Cu 39: t chy hon ton 18 gam mt este X n chc thu c 20,16 lt CO 2 (ktc) v 12,96 gam nc.
Mt khc nu cho 21g X tc dng vi 200ml dung dch KOH 1,2M sau c cn dung dch thu c 34,44
gam cht rn khan. Cng thc phn ca axit to ra X l :
A. C5H6O3.
B. C5H8O3.
C. C5H10O3
D. C5H10O2.
Cu 40: Ha tan hon ton hn hp gm 0,18 mol FeS2 v a mol Cu2S bng dung dch HNO3 va thu c
dung dch X ch cha mui sunfat v V lt NO (ktc) l sn phm kh duy nht. Gi tr ca V l:
A. 44,8 lt
B. 22,4 lt
C. 26,88 lt
D. 33,6 lt
II. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II )
Phn I: Theo chng trnh Chun (t cu 41 n cu 50)
Cu 41: Khi in phn dung dch no sau y ti catot xy ra qu trnh kh nc?
A. Dung dch ZnCl2.
B. Dung dch CuCl2
C. dung dch AgNO3.
D. Dung dch MgCl2.
Cu 42: phn bit SO2, CO2 v SO3 c th dng:
A. Dung dch BaCl2 v dung dch Br2
B. Dung dch Ba(OH)2, dung dch thuc tm
C. Dung dch Br2, nc vi trong.
D. Dung dch BaCl2 v nc vi trong
Cu 43: Pb tan d dng trong dung dch no sau y?
A. Dung dch H2SO4 m c
B. Dung dch HNO3 c
C. Dung dch HCl long
D. Dung dch H2SO4 long

khoa ho HKHTN-HQGHN

Cu 44: Dung dch X cha cc ion : Ba2+, Na+, HCO3-, Cl- trong s mol Cl- l 0,24. Cho dung dch X tc
dng vi dung dch NaOH d thu c 9,85g kt ta. Cho dung dch X tc dng vi dung dch Ba(OH) 2 d
thu c 15,76g kt ta. Nu un si dung dch X n cn th thu c m gam cht rn khan. Gi tr ca m l :
A. 15,81
B. 18,29.
C. 31,62
D. 36,58
Cu 45: Cht c dng ty trng nc ng trong qu trnh sn ng saccaroz t cy ma l:
A. nc gia-ven
B. SO2.
C. Cl2.
D. CaOCl2.
Cu 46: t chy hon ton 0,12 mol mt amin no, mch h X bng oxi va thu c 0,6 mol hn hp kh v hi.
Cho 9,2 gam X tc dng vi dung dch HCl d th s mol HCl phn ng l:
A. 0,4
B. 0,3
C. 0,1
D. 0,2
Cu 47: Hn hp M gm 2 axit cacboxylic u no, mch h A, B (B hn A mt nhm chc). Ha hi hon ton m
gam M thu c th tch hi bng th tch ca 7 gam nit o cng iu kin nhit , p sut. Nu cho m gam M tc
dng vi Na d thu c 4,48 lt H2 (ktc). Khi t chy hon ton m gam M thu c 28,6g CO 2. Cng thc phn
t ca A v B l:
A. C2H4O2 v C3H4O4.
B. CH2O2 v C3H4O4 .
C. C2H4O2 v C4H6O4
D. CH2O2 v
C4H6O2.
Cu 48: Hn hp X gm Cu, Fe, Mg. Nu cho 10,88 gam X tc dng vi clo d th sau phn ng thu c
28,275g hn hp mui khan. Mt khc 0,44 mol X tc dng vi dung dch HCl d th thu c 5,376 lt H 2
(ktc). % khi lng ca Cu trong X l:
A. 67,92%
B. 58,82%
C. 37,23%
D. 43,52%
2+
Cu 49: Oxi ha 16,8g anehit fomic bng oxi c mt Mn thu c hn hp X. Cho hn hp X tc dng vi
dung dch AgNO3/NH3 d thu c 151,2g Ag. Hiu sut ca phn ng oxi ha anehit fomic l:
A. 37,5%
B. 80%
C. 60%
D. 75%
Cu 50: Dy no sau y gm cc polime nhn to?
A. T visco, t axetat, xenluloz trinitrat
B. Xenluloz, tinh bt, t tm
C. T lapsan, PVA, thy tinh hu c.
D. T nilo-6,6; bng, tinh bt, t capron
Phn II: Theo chng trnh nng cao (t cu 51 n cu 60)
Cu 51: Cho 6,85 gam Ba kim loi vo 150ml dung dch CrSO 4 0,3M trong khng kh n phn ng hon ton
thu c m gam kt ta. Gi tr ca m l:
A. 14,09 gam
B. 10,485gam
C. 3,87 gam
D. 14,355 gam
Cu 52: Cho cc cht CH3 -CHCl2; ClCH=CHCl; CH2=CH-CH2Cl, CH2Br-CHBr-CH3; CH3-CHCl-CHCl-CH3;
CH2Br-CH2-CH2Br. S cht khi tc dng vi dung dch NaOH long un nng to ra sn phm c kh nng
phn ng vi Cu(OH)2 l:
A. 5
B. 4
C. 2
D. 3
Cu 53: Cho sut in ng chun ca 1 s pin in ha sau: E 0X-Cu = 0,78V; E0Y-Cu = 2,0V; E0Cu-Z = 0,46V. Th
t cc kim loi theo chiu gim dn tnh kh l:
A. X,Y, Z, Cu
B. X, Y, Cu, Z
C. Y, X, Cu, Z
D. Z, Cu, X, Y
Cu 54: Kh no sau y l nguyn nhn gy hiu ng nh knh?
A. NO
B. CO2.
C. SO2.
D. CO
H 2O , H
CuO, t o
HCN

Cu 55: Cho s : Propilen
A
B
D. D l:
A. CH3CH2CH2OH
B. CH3C(OH)(CH3)CN
C. CH3CH(OH)CH3.
D.
CH3CH2CH(OH)CN
Cu 56: Dung dch X cha 0,01 mol ClH 3N-CH2-COOH, 0,02 mol CH3-CH(NH2)COOH; 0,05 mol
HCOOC6H5. Cho dung dch X tc dng vi 160 ml dung dch KOH 1M un nng phn ng xy ra hon
ton. C cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l:
A. 16,335 gam
B. 8,615 gam
C. 12,535 gam
D. 14,515 gam
khoa ho HKHTN-HQGHN

Cu 57: Cho t t n d dung dch NH3 ln lt vo cc dung dch sau: CuCl2, AlCl3, Fe(NO3)3, NiSO4,
AgNO3, MgSO4. Sau khi cc phn ng xy ra hon ton, s kt ta thu c l:
A. 2
B. 4
C. 5
D. 3
Cu 58: Dy no sau y gm cc polime c cu trc mch phn nhnh?
A. T nilon-6,6; t lapsan, t olon
B. Nha rezol, cao su lu ha
C. Cao su Buna-S, xenluloz, PS
D. Amilopectin, glicogen
Cu 59: Dung dch X gm NH3 0,1M; NH4Cl 0,1M. pH ca dung dch X c gi tr l: (cho K b ca NH3 l
1,75.10-5)
A. 9,24
B. 4,76
C. 8,8
D. 9,42
Cu 60: Trung ha ht 10,36 gam axit hu c n chc bng dung dch Ba(OH) 2 va thu c 19,81 gam
mui khan. Xc nh cng thc ca axit?
A. CH3COOH
B. C2H3COOH
C. C3H5COOH
D. C2H5COOH
----------- HT ---------KHI THPT CHUYN
H QUC GIA H NI
THI TH I HC CAO NG MN HA HC
KHI A
NN HC 2010 2011 LN II
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)

Cu 1: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l:
A. CH3CHO, C2H5OH, C2H5COOCH3.
B. C2H4(OH)2, CH3OH, CH3CHO.
C. CH3OH, C2H5OH, CH3CHO.
D. CH3CHO, C6H12O6 (glucoz), CH3OH.
Cu 2: Cho t t 150 ml dung dch HCl 1M vo 500 ml dung dch X gm Na2CO3 v NaHCO3 th thu c 1,008 lt kh
(ktc) v dung dch Y. Cho dung dch Y tc dng vi dung dch Ba(OH) 2 d th thu c 29,55 gam kt ta. Nng mol
ca Na2CO3 v NaHCO3 trong dung dch X ln lt l:
A. 0,21M v 0,18M
B. 0,2M v 0,4M
C. 0,21M v 0,32M
D. 0,8M v 0,26M
Cu 3: Thy phn dung dch cha 34,2 gam mantoz mt thi gian. Ly ton b sn phm thu c sau phn
ng thy phn cho tc dng vi lng d dung dch AgNO3 trong NH3, sau phn ng hon ton thu c 31,32
gam Ag. Hiu sut ca phn ng thy phn mantoz l:
A. 45%
B. 50%
C. 25%
D. 55%
Cu 4: X l hp cht hu c, mch h ch cha mt loi nhm chc. t chy hon ton X ch thu c CO2 v H2O.
Khi lm bay hi hon ton 4,5 gam X thu c th tch bng th tch ca 2,1 gam kh N2 cng iu kin. S cng thc
cu to ca X tha mn l:
A. 5
B. 6
C. 3
D. 4
Cu 5: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l:
A. Na, K, Ba
B. Ca, Sr, Ba
C. Mg, Ca, Ba
D. Na, K, Mg
Cu 6: Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l
A. Gly, Glu, Lys
B. Gly, Val, Ala
C. Val , Lys, Ala
D. Gly, Ala, Glu
Cu 7: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo X, thu
c 2a gam kt ta. Mc khc, nu cho 400 ml dung dch NaOH 1M vo X, cng thu c a gam kt ta. Cc
phn ng xy ra hon ton, gi tr ca m l
A. 18,81
B. 15,39
C. 20,52
D. 19,665
Cu 8: Cho phng trnh ho hc: FeSO4 + KMnO4 + KHSO4 Fe2(SO4)3 + MnSO4 + K2SO4 + H2O. Tng h
s ( s nguyn t, ti gin) ca cc cht c trong phng trnh phn ng l:
A. 48
B. 52
C. 54
D. 40
khoa ho HKHTN-HQGHN

Cu 9: Dy gm cc cht no sau y u c tnh lng tnh ?
A. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO
B. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH
C. H2O, Zn(OH)2, HOOC-COONa, H2NCH2COOH, NaHCO3
D. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2
Cu 10: tch c CH3COOH t hn hp gm CH3COOH v C2H5OH ta dng ho cht no sau y?
A. Na v dung dch HCl
B. Ca(OH)2 v dung dch H2SO4
C. CuO (to) v AgNO3/NH3 d
D. H2SO4 c
Cu 11: Cho m gam Fe tc dng ht vi dung dch cha y mol CuSO 4 v z mol H2SO4 long, sau phn ng
hon ton thu c kh H2, m gam Cu v dung dch ch cha mt cht tan duy nht. Mi quan h gia y v z l
A. y = 7z.
B. y = 5z.
C. y = z.
D. y = 3z.
Cu 12: un nng 10,71 gam hn hp X gm propyl clorua v phenyl clorua vi dung dch NaOH long, va
v un nng, sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng thu c 8,61 gam kt
ta, cc phn ng xy ra hon ton. Khi lng phenyl clorua c trong hn hp X l
A. 4,0 gam.
B. 2,71 gam.
C. 4,71 gam
D. 6,0 gam.
Cu 13: Sc V lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH) 2 1M v NaOH 1M. Sau phn ng thu c
19,7 gam kt ta, gi tr ln nht ca V l:
A. 8,96
B. 11,2
C. 6,72
D. 13,44
Cu 14: Cho 3,2 gam Cu tc dng vi 100 ml dung dch hn hp HNO3 0,8M v H2SO4 0,2M, sn phm kh duy nht
l kh NO. S gam mui khan thu c khi c cn dung dch sau phn ng l:
A. 8,84
B. 5,64
C. 7,90
D. 10,08
Cu 15: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol), C6H6
(benzen), CH3CHO. S cht trong dy lm mt mu dung dch brom l
A. 6
B. 5
C. 7
D. 8
Cu 16: Cho hn hp gm 3,36 gam Mg v 0,4 gam MgO tc dng vi dung dch HNO 3 long d thu c
0,448 lt kh N2 l sn phm kh duy nht (ktc). C cn dung dch sau phn ng thu c 23 gam cht rn
khan. S mol HNO3 phn ng l:
A. 0,32 mol
B. 0,28 mol
C. 0,34 mol
D. 0,36 mol
Cu 17: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco,
t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l:
A. 5
B. 6
C. 7
D. 4
Cu 18: Ha tan mt lng ancol X vo nc thu c 6,4 gam dung dch Y, nng ca X trong Y l 71,875%. Cho
6,4 gam dung dch Y tc dng vi lng d Na thu c 2,8 lt H2 (dktc). S nguyn t H c trong cng thc phn t
ancol X l:
A. 10
B. 4
C. 8
D. 6
Cu 19: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3.
Cht to ra lng O2 t nht l
A. KMnO4
B. KNO3
C. AgNO3
D. KClO3
Cu 20: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc
vi trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc
phn t ca X l
A. CH4
B. C4H8
C. C4H10
D. C3H6
Cu 21: Cho m gam Ca vo 500 ml dung dch cha NaHCO 3 1M v CaCl2 0,5M. Sau khi phn ng xy ra hon
ton thu c 40 gam kt ta. Gi tr ca m l:
A. 16,0
B. 6,0
C. 8,0
D. 10,0

khoa ho HKHTN-HQGHN

Cu 22: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin
(6). Th t tng dn lc baz ca cc cht l:
A. (3) < (2) < (4) < (1) < (5) < (6)
B. (2) < (3) < (4) < (1) < (5) < (6)
C. (2) > (3) > (4) > (1) > (5) > (6)
D. (3) < (1) < (4) < (2) < (5) < (6)
Cu 23: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O 2 (iu kin
chun). Dn sn phm chy qua bnh ng dung dch Ca(OH) 2 d, sau phn ng hon ton thu c m gam kt
ta. Gi tr ca m l
A. 10,0
B. 12,0
C. 15,0
D. 20,5
Cu 24: in phn 2 lt dung dch cha hn hp gm NaCl v CuSO 4 vi in cc tr, c mng ngn n khi
H2O bt u in phn c hai cc th dng li. Ti catt thu 1,28 gam kim loi ng thi ti ant thu 0,336 lt
kh ( ktc). Coi th tch dung dch khng i th pH ca dung dch sau in phn l:
A. 3
B. 12
C. 13
D. 2
3+
5
Cu 25: Ion R c cu hnh electron phn lp ngoi cng l 3d . V tr ca R trong bng tun hon l:
A. Chu k 4, nhm VIIB
B. Chu k 3 nhm VIIIB
C. Chu k 4 nhm VIIIB
D. Chu k 4,
nhm IIB
Cu 26: Cht bo X c ch s axit l 7. trung ha lng axit c trong 10 kg X cn va m gam NaOH. Gi
tr ca m l:
A. 55
B. 70
C. 50
D. 60
Cu 27: Khi cho hn hp Fe3O4 v Cu vo dung dch H 2SO4 long d thu c cht rn X v dung dch Y. Dy
no di y gm cc cht u tc dng c vi dung dch Y?
A. KI, NH3, NH4Cl
B. BaCl2, HCl, Cl2
C. NaOH, Na2SO4,Cl2
D. Br2, NaNO3,
KMnO4
Cu 28: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat,
mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l
A. 8
B. 5
C. 6
D. 7
Cu 29: Cho m gam hp cht hu c X c cng thc phn t l C 3H6O2 tc dng hon ton vi 200 ml dung
dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Cng thc cu to ca X
v gi tr ca m l
A. HCOOCH2CH3 v 8,88 gam.
B. CH3COOCH3 v 6,66 gam.
C. C2H5COOH v 8,88 gam.
D. C2H5COOH v 6,66 gam.
Cu 30: t chy 3,2 gam mt este E n chc, mch h c 3,584 lt CO2 (ktc) v 2,304 gam H2O. Nu cho
15 gam E tc dng vi 200 ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 14,3 gam cht rn
khan. Vy cng thc ca ancol to nn este trn c th l
A. CH2=CH-OH
B. CH3OH
C. CH3CH2OH
D. CH2=CH-CH2OH
Cu 31: Ancol X, anehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t v u no, n chc, mch h. t
hon ton hn hp 3 cht trn (c s mol bng nhau) thu c t l mol gia CO2 v H2O l 11:12. Cng thc phn t ca
X, Y, Z l:
A. CH4O, C2H4O, C2H4O2
B. C4H10O, C5H10O, C5H10O2 C. C2H6O, C3H6O, C3H6O2 D. C3H8O, C4H8O,
C4H8O2
Cu 32: S nguyn t ha hc m nguyn t ca n c electron cui cng in vo phn lp 4s l:
A. 12
B. 1
C. 10
D. 2
Cu 33: a mt hn hp kh N2 v H2 c t l 1: 3 vo thp tng hp, sau phn ng thy th tch kh i ra
gim 1/10 so vi ban u. Hiu sut ca phn ng tng hp NH3 l:
A. 10%
B. 20%
C. 15%
D. 25%

khoa ho HKHTN-HQGHN

Cu 34: X l hn hp cc mui Cu(NO3)2, Zn(NO3)2, Fe(NO3)3, Mg(NO3)2. Trong O chim 9,6% v khi
lng. Nung 50 gam X trong bnh kn khng c oxi n khi phn ng xy ra hon ton thu c m gam oxit.
Gi tr ca m l
A. 44,6
B. 39,2
C. 17,6
D. 47,3
Cu 35: Cho 29,8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung dch
thu c 51,7 gam mui khan. Cng thc phn t 2 amin l
A. C2H5N v C3H7N
B. CH5N v C2H7N
C. C3H9N v C4H11N D. C2H7N v C3H9N
Cu 36: Trong cc ho cht Cu, C, S, Na 2SO3, FeS2 , O2, H2SO4 c. Cho tng cp cht phn ng vi nhau
trong iu kin thch hp th s cp cht c phn ng to ra kh SO2 l
A. 6
B. 7
C. 9
D. 8
Cu 37: nhn bit ba l mt nhn: phenol, stiren, ancol benzylic, ngi ta dng mt thuc th duy nht l
A. Ca(OH)2
B. Dung dch NaOH
C. Nc brom
D. Na
Cu 38: Ha tan hon ton 6,44 gam hn hp bt X gm Fe xOy v Cu bng dung dch H 2SO4 c nng (d).
Sau phn ng thu c 0,504 lt kh SO 2 (sn phm kh duy nht, ktc) v dung dch cha 16,6 gam hn hp
mui sunfat. Cng thc ca oxit st l:
A. FeO
B. Fe3O4
C. FeO hoc Fe3O4.
D. Fe2O3
Cu 39: Thc hin cc th nghim sau:
(1). Sc kh C2H4 vo dung dch KMnO4.
(2). Sc CO2 d vo dung dch NaAlO2
. (3). Chiu sng vo hn hp kh (CH4; Cl2).
(4). Sc kh H2S vo dung dch FeCl3.
(5). Sc kh NH3 vo dung dch AlCl3.
(6). Sc kh SO2 vo dung dch H2S.
S th nghim c phn ng oxi ho- kh xy ra l
A. 1,3,4,6.
B. 1,2,4,5
C. 2,4,5,6.
D. 1,2,3,4.
Cu 40: Pht biu no sau y l khng ng:
A. Thy tinh lng l dung dch m c ca Na2SiO3 v K2SiO3
B. Nc Gia-ven l dung dch hn hp natri clorua v natri hipoclorit.
C. Photpho trng c cu trc mng tinh th phn t.
D. Phn bn phc hp l sn phm trn ln cc loi phn n theo t l khc nhau.
II. PHN RING [10 cu]: Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Ch dng mt thuc th phn bit cc kim loi sau: Mg, Zn, Fe, Ba?
A. Dung dch NaCl
B. Nc
C. Dung dch NaOH D. Dung dch H2SO4 long
Cu 42: Cho hp cht X tc dng vi NaOH to ra kh Y lm xanh qu tm m. Mt khc, cht X tc dng vi
axit HCl to ra kh Z va lm vn c nc vi trong, va lm mt mu dung dch Brom. Cht X khng tc
dng vi dung dch BaCl2. Vy cht X c th l:
A. NH4HSO3
B. NH4HCO3
C. (NH4)2CO3
D. (NH4)2SO3
Cu 43: Dy gm cc kim loi u tc dng c vi dung dch FeCl3 l:
A. Fe, Mg, Cu, Ag, Al
B. Au, Cu, Al, Mg, Zn C. Fe, Zn, Cu, Al, Mg
D. Cu, Ag, Au, Mg, Fe
Cu 44: Hn hp X gm HCHO v CH3CHO c t l mol 1 : 1. un nng 7,4 gam X vi lng d dung dch
AgNO3 trong NH3 ti phn ng hon ton thu c m gam cht rn. Gi tr ca m l
A. 86,4
B. 64,8
C. 43,2
D. 32,4
Cu 45: Cho cc cht sau: C2H5OH, C6H5OH, C6H5NH2, dung dch C6H5ONa, dung dch NaOH, dung dch
CH3COOH, dung dch HCl. Cho tng cp cht tc dng vi nhau iu kin thch hp, s cp cht c phn ng
xy ra l
A. 8
B. 12
C. 9
D. 10
khoa ho HKHTN-HQGHN

Cu 46: Cho 0,1 mol hp cht ha c c cng thc phn t CH 6O3N2 tc dng vi dung dch cha 0,2 mol NaOH un
nng, sau khi phn ng xy ra hon ton thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y
thu c m gam rn khan. Gi tr ca m l
A. 21,8
B. 15
C. 12,5
D. 8,5
Cu 47: Ln men mt lng glucoz thnh ancol etylic th thu c 100 ml ancol 46 0. Khi lng ring ca ancol
nguyn cht l 0,8 gam/ml. Hp th ton b kh CO2 sinh ra trong qu trnh ln men vo dung dch NaOH d thu c
mui c khi lng l (cc phn ng xy ra hon ton)
A. 106 gam
B. 84,8 gam
C. 212 gam
D. 169,6 gam
Cu 48: nhit khng i, cn bng ca phn ng thun - nghch b chuyn dch theo chiu thun khi tng
p sut ca h l:
A. 2SO3(k) 2SO2(k) + O2(k)
B. CaCO3(r) CaO(r) + CO2(k)
C. N2(k) + 3H2(k) 2NH3(k)
D. I2(k) + H2(k) 2HI(k)
Cu 49: Trong s cc pht biu sau v anilin (C6H5NH2):
(1) Anilin tan t trong nc nhng tan nhiu trong dung dch NaOH.
(2) Anilin c tnh baz, dung dch anilin khng lm i mu qu tm.
(3) Anilin dng sn xut phm nhum, dc phm, polime.
(4) Anilin tham gia phn ng th brom vo nhn thm d hn benzen.
Cc pht biu ng l
A. (1), (2), (3)
B. (1), (2), (4)
C. (1), (3), (4)
D. (2), (3), (4)
Cu 50: Cho 200 ml dung dch AgNO3 2,5a mol/l tc dng vi 200 ml dung dch Fe(NO 3)2 a mol/l. Sau khi
phn ng kt thc thu c 17,28 gam cht rn v dung dch X. Cho dung dch HCl d vo dung dch X thu
c m gam kt ta. Gi tr ca m l
A. 34,44
B. 28,7
C. 40,18
D. 43,05
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Cho hn hp HCHO v H 2 qua ng ng bt Ni nung nng. Ton b sn phm thu c em ho tan
trong bnh ng nc lnh thy khi lng bng tng 1,564 gam. Thm tip dung dch AgNO 3/NH3 n d v
un nh th thu c 7,776 gam Ag. Hiu sut phn ng hiro ho l:
A. 20%
B. 64%
C. 80%
D. 36%
Cu 52: Hp cht X c cng thc C2H7NO2 c phn ng trng gng, khi phn ng vi dung dch NaOH long
to ra dung dch Y v kh Z, khi cho Z tc dng vi dung dch hn hp gm NaNO 2 v HCl to ra kh P. Cho
11,55 gam X tc dng vi dung dch NaOH va , c cn dung dch thu c s gam cht rn khan l:
A. 14,32 g
B. 9,52 g
C. 8,75 g
D. 10,2 g
0
Cu 53: Xt cn bng: N2O4 (k) 2NO2 (k) 25 C. Khi chuyn dch sang mt trng thi cn bng mi nu
nng ca N2O4 tng ln 16 ln th nng ca NO2
A. tng 9 ln.
B. gim 3 ln.
C. tng 4 ln.
D. tng 3 ln.
Cu 54: Trong cc cht sau: dung dch NaOH, C 2H5OH, et xng, dung dch [Cu(NH3)4](OH)2. s cht ho tan
xenluloz l
A. 3
B. 1
C. 2
D. 4
Cu 55: un 1 mol hn hp C2H5OH v C4H9OH (t l mol tng ng l 3:2) vi H2SO4 c 140oC thu c
m gam ete, bit hiu sut phn ng ca C2H5OH l 60% v ca C4H9OH l 40% . Gi tr ca m l
A. 53,76 gam
B. 28,4 gam
C. 19,04 gam
D. 23,72 gam
Cu 56: Hon tan 0,1 mol FeS2 trong 1 lt dung dch HNO3 1,2M, sau khi phn ng hon ton thu c dung
dch X. Tnh khi lng Cu ti a c th tan trong X, bit sn phm kh HNO 3 trong cc qu trnh trn l NO
duy nht.
khoa ho HKHTN-HQGHN

A. 12,8 gam
B. 25,6 gam
C. 22,4 gam
D. 19,2 gam
Cu 57: Cho dung dch axit axetic tc dng vi mt lng va dung dch NaOH 10% thu c dung dch
mui nng 10,25%. Nng ca dung dch axit axetic ban u l:
A. 20%
B. 15%
C. 14%
D. 16%
Cu 58: nhn bit cc kh: CO2, SO2, H2S, N2 cn dng cc dung dch:
A. Nc brom v Ca(OH)2
B. NaOH v Ca(OH)2 C. KMnO4 v NaOH D. Nc brom v NaOH
Cu 59: Cho gi tr th in cc chun E 0(V) cu cc cp oxi ha - kh Mg 2+/Mg; Zn2+/Zn; Pb2+/Pb, Cu2+/Cu
ln lt l: - 2,37; -0,76; -0,13; +0,34. Cho bit pin in ha to ra t cp oxi ha - kh no c sut in ng
chun nh nht?
A. Zn v Pb
B. Pb v Cu
C. Zn v Cu
D. Mg v Cu
Cu 60: iu ch c 3,36 lt kh Cl2 (ktc) cn a mol K2Cr2O7 v b mol HCl. Gi tr a v b ln lt l:
A. 0,05 v 0,35
B. 0,05 v 0,7
C. 0,1 v 0,35
D. 0,1 v
0,7------------------------------- HT ----------

khoa ho HKHTN-HQGHN

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Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012.

CHUYN TUYN TP CC DNG

Chuyn bi tp luyn thi i hc nm hc 2011-2012. Ngi son: V Thanh Tng sv

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Chuyn 01: Cu to nguyn t v bng h thng tun hon

Chuyn bi tp luyn thi i hc nm hc 2011-2012. Ngi son: V Thanh Tng sv

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

II/ Bi tp trc nghim

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

63,54. Thnh phn phn trm tng s nguyn t ca ng v

Cu 8: Dy gm cc ion X+, Y- v nguyn t Z u c cu hnh electron 1s22s22p6 l:

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

XC NH TN NGUYN T KIM LOI

Chuyn bi tp luyn thi i hc nm hc 2011-2012. Ngi son: V Thanh Tng sv

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Chuyn bi tp luyn thi i hc nm hc 2011-2012. Ngi son: V Thanh Tng sv

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

KIM LOI TC DNG VI DUNG DCH AXIT.

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Chuyn bi tp luyn thi i hc nm hc 2011-2012. Ngi son: V Thanh Tng sv

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Chuyn 04: Bi tp v hirocacbon

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

d thu c 21,6g kt ta. Cng thc cu to ca A l:

. Cng thc phn t 2 ru trn ln lt l?

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

. Cho 7,6 gam X phn ng

- Phn 2 t chy hon ton, sinh ra 14,85gam kh

(cc th tch u o ktc).

1,5M. Khi lng dung dch sau phn

ng so vi khi lng dung dch

Cu 23: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23.

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Chuyn bi tp luyn thi i hc nm hc 2011-2012. Ngi son: V Thanh Tng sv

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

Chuyn Este; lipit; axit cacboxylic

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm 2011-2012. Mi

b.Bi ton xc nh CTCT ca 2 este trong hn hp.

c.Hai cht hu c A, B phn ng vi NaOH Mui + ancol