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Schedule of

Services & Fees

2016 USD
RIGHT SOLUTIONS
RIGHT PARTNER

www.alsglobal.com

The new ALS CoreViewer

Fast, secure core photo archive and core logging tool, now accessible
on any web-enabled device

ALS CoreViewer
n

On the cover:

Presents core photography in a continuous,


depth-reigstered core strip, with capability for
multiple photo sets (for example, wet and
dry or before and after sawing/sampling).

Displays any kind of downhole data along


the continuous core strip, including fieldportable and lab-based geochemistry,
downhole geophysics, measured and
interpreted geotechnical parameters like
RQD, and hyperspectral data.

TerraCore high resolution


RGB photograph with
overlaid hyperspectral
mineral identification map.

RGB Photo

Mineral Map
Illite-Chlorite

Illite-Quartz

Chlorite

Quartz

Illite

Archives core photographs and makes them


securely available over the web for a one-time
fee, removing all difficulties and limitations in
photo storage and accessibility for historical
and on-going drilling projects.

Can be used in the core shack on webenabled tablets and notebooks as a core
logging and verification tool. Photos can
be available in CoreViewer to match the
core logging schedule as early the day after
photography, with prior setup and testing.

Merges seamlessly with leading database


and 3D modelling programs for deep
investigation and verification of exploration,
resource, and geometallurgical models.

ALS CoreViewer and


The GeoSpectral Image
by TerraCore
CoreViewer Full Box View

CoreViewer Core Strip and Data View

CoreViewer Core Strip and Data View with TerraCore


GeoSpectral Image and Mineral Statistics

Contact your local ALS Geochemistry


representative for more information today.

ALS CoreViewer displays


GeoSpectral Image products
and the underlying data
generated by TerraCores Core
Imaging Spectrometers, which
are hosted in a number of ALS
Geochemistry locations around
the world.
Geologists with expertise in
hyperspectral mineralogy can
work with TerraCores unique
Intellicore platform to generate
images and data sets of interest,
which may then be exported
to ALS CoreViewer for use
in on-site core logging and
presentations to non-experts.

RELIABLE SUPER TRACE DETECTION LIMITS


FOR ROCKS AND DRILL CORE BY ME-MS61L
0.05

Pushing the envelope in


geochemical analysis.

0.04

Thallium (ppm)
ME-MS61
ME-MS61L

0.03

0.02

0.01

+
Ultra-clean laboratory
techniques

+
Low analytical
backgrounds with
state of the art
ICP-MS

0.00

=
Collision cell
technology
to reduce or
eliminate chemical
interferences

ALS Geochemistry continues to lead the industry in


developing new geochemical techniques and breaking
through stubborn analytical barriers to exploration success.
Our expert team of chemists have driven down detection
limits until geological trends in challenging elements like
arsenic, selenium, antimony, and thallium may appear

Detection limits
below or approaching
crustal abundance
for all elements

Our unique ICP-MS methodology minimizes the


usual problems preventing ultra-low detection
limits in the analysis of geological materials.
When combined with a near-total four acid
digestion in the ME-MS61L package, finely detailed
changes in pathfinders, alteration and lithology can
be tracked. Our four acid digestion is designed to
retain the semi-volatile elements like As, Sb and
Tl, which are also some of the most improved in
detection limit and precision using ALS techniques.
As an example, results for thallium are pictured
here. Clear definition of anomalous patterns in
unmineralized drill core can be identified where
before there was only analytical noise around
the detection limit.

in areas where they were previously undetectable.


Gold can now be reliably detected at parts per trillion levels.
Isotopic analysis is possible at commercial laboratory
pricing. And new frontiers in halogen analysis are on
the horizon.

Keep up with the latest technical developments and partnership


announcements on our website

www.alsglobal.com/en/our-services/minerals/geochemistry/news

On-Site Services

Your site Our quality, service


and deliverables

Expertise in sample processing,


laboratory efficiency, economies of
scale and a global network present
at your mine or exploration site.
ALS Mine Site coordinates the services of the
ALS Minerals Division (Geochemistry, Metallurgy
and Inspection) and other ALS Group offerings
(Environmental, Industrial) to provide tailored solutions
delivered at your exploration project or mine site.
From mobile sample preparation facilities to full-service
mine control labs, ALS Mine Site has a proven track
record of cost-effective, high quality on-site support
without compromise.

Enquire at your local ALS laboratory


for more information.
ALS Mine Site (Global Head Office)
2103 Dollarton Highway
North Vancouver, BC, Canada V7H 0A7
T: +1 604 984 0221
F: +1 604 998 2037
E: minesitelab@alsglobal.com

yy Online data management through ALS Webtrieve


and CoreViewer
yy Sample logistics and archive management
yy Core photography and in-situ analysis
yy Mobile sample preparation
yy Mine site labs: design, build, update, expand
yy Training and staffing on a contract basis
yy Metallurgical testwork and advanced mineralogy
yy Auxiliary support services: oil condition monitoring,
environmental analysis

ALS on-site solutions allow geologists and miners to


focus on exploration and extraction, while we focus on
delivering high quality, on-time analysis.

RIGHT SOLUTIONS, RIGHT PARTNER

Introducing the new ALS CoreViewer

Inside Cover

Analytical Innovation at ALS Geochemistry

Sample Preparation

Core Services and ALS CoreViewerTM 7


Spectral Mineralogy and Core Imaging 8
Sample Submission and Storage 9
Sample Preparation Packages10
Individual Sample Preparation Methods 11
Specific Gravity, Bulk Density and Miscellaneous12

Precious Metal Analysis

13

Gold13
Silver and Platinum Group Elements 15

TABLE OF CONTENTS

This edition of our Schedule of Services and Fees describes a broad selection of our
global services, but it is by no means a comprehensive list. For specific questions, please
contact your client services team or the lab nearest to you and we will be glad to help.
Prices listed here do not contain locally applicable taxes. ALS Geochemistry reserves the
right to alter listed prices at any time.

Concentrates, Bullions and Metallurgical Testing16

Generative Exploration

17

Super Trace Analysis 17


Ionic Leach and Other Selective Leaches19
Hydrogeochemistry and Biogeochemistry20

Targeted Exploration

21

Ultra Trace Methods21


Trace Level Methods23
Low Grade Mineralized Materials24
Individual Elements and Miscellaneous Methods25
Isotopic Analysis and Geochronology26

Whole Rock Analysis and Lithogeochemistry

27

Specific Ores and Commodities

29

Ores, High Grade Materials and Massive Sulfides29


Copper Methods31
Iron Ore Technical Center and Iron Ore Methods32
Uranium, Rare Earths and Other Metals33
Bauxites, Laterites, Phosphates and Other Commodities34

Carbon, Sulfur, ABA and Concentrates

35

Carbon & Sulfur Methods35


Acid-Base Accounting36
Concentrates and Metallurgical Samples37
ALS Mineralogy38

Quality Commitment and Locations

39

Quality Statement and Accreditation39


Terms & Conditions40
ALS Geochemistry Global Locations41

CORE SERVICES AND ALS COREVIEWER

Core Services

ALS Minerals offers a full spectrum of no-hassle Core Services that may be bundled in
any combination and offered at any of our labs or on-site at your project as needed.
ALS Core Services encompass core handling and warehouse management, core sawing
and sampling, secure and comfortable logging facilities, and core photography.
Our highly-trained core sawing technicians use state of the art computerized saws for
precision cutting of most rock types. Friable core may be sawn manually to preserve
material in the interval.
The following prices reflect in-lab services. For custom on-site quotes, please contact
minesitelab@alsglobal.com.

DESCRIPTION OF SERVICE

CODE

PRICE ($)

Log in core box for processing.

LOG-COREBX

2.00/box

SAW-01

2.70/foot, 8.85/meter
3.45/foot, 11.30/meter

Sampling core based on client-provided instructions. Includes bagging sample for further preparation.
Sampling regular core
Sampling friable core

SAM-COR01

3.65/sample
5.00/sample

Hourly rental of secure core logging facilities with full spectrum lights and other amenities.

LOG-COR10

50.00/hour

PHO-WET
PHO-DRY

4.00/box

STO-COR10

1.00/box

Sawing whole core based on client-provided instructions.

Automated high-speed saw


Manual sawing for friable core

High resolution core photography. Delivery via disc, USB key, or ALS CoreViewer (see below.) Core may be
photographed in multiple states, wet or dry, based on client preference and requirements.
Long-term storage of core boxes in ALS warehouses.

ALS CoreViewer

A secure core photo archive and data integration platform. CoreVeiwerTM is available
over the Internet and is integrated with the most powerful exploration, mine planning,
and 3D modelling software packages. ALS CoreViewer allows you to call up core
box photos and a depth-registered downhole core strip at one click. When linked with
downhole data such as geochemistry, spectral mineralogy, and geophysics, geologists
and managers in different offices and countries can simultaneously access, share and
discuss all relevant core-related imagery and data.
Core images are transferred to ALS via secure file sharing, and the photos are processed
into downhole strips using depth information in the photos themselves. Linking of
downhill data with drill hole depth can be done by the client or by ALS personnel if
requested. Granularity in security levels allows access control and assures that ALS
personnel cannot see data linked to photographs.
With prior discussion and setup, it is possible to process core photos and interpreted
hyperspectral data into CoreViewer in the short timeframe between drilling and
logging. Geologists can access CoreViewer on tablets in the core shack, providing
unparalleled insight into lithology and alteration.

DESCRIPTION OF SERVICE
Process core box photos into downhole strip for visualization in ALS CoreViewer. One-time fee includes secure online
access to the photo archive and downhole data linking tools in perpetuity. Multiple photo sets may be processed for
one drill hole (e.g., wet and dry core photos.)

CODE

PRICE ($)

PRC-PHOWET
PRC-PHODRY

5.00/box

Identifying alteration minerals, particularly clays, can be challenging during core logging.
Spectral mineralogy, the identification of minerals in geological materials using visible
and infrared light, is a powerful tool available to geologists for improved core logs and
better field decision-making in exploration and mining settings.
The major hurdle in implementing a routine spectral analysis program is interpreting
large volumes of raw spectral data and integrating it into the workflow. To resolve these
challenges, ALS Geochemistry has partnered with AusSpec International to provide
our clients access to the aiSIRIS (Spectral InfraRed Interpretation System) engine.
This program rapidly processes raw spectral files and outputs mineral assemblages and
key spectral parameters in a database-ready format, enabling quick assessment of the
relationships between alteration and mineralization by project geologists. Turnaround
time is typically two days, ensuring this crucial data set is in your hands for timely field
decision-making.

DESCRIPTION

DELIVERABLES

Rapid and accurate interpretation of hyperspectral scans by


the aiSIRIS expert software. Generic project geology (such as
porphyry or Carlin gold) must be provided with the scans.
VNIR/SWIR spectral scan files produced by ALS or by the client
are accepted.
Spectral scan in the VNIR and SWIR regions (350-2500nm) taken on
a sample using the ASD-PANalytical TerraSpec 4 HR spectrometer.
Crushed reject or RC chips are recommended as the optimal sample
type for spectral scanning.

HyLogging of drill core and chip trays - automated feed under a


hyperspectral spot analyzer at 10-25mm intervals. Interpretation
by aiSIRIS.

CODE

PRICE PER SAMPLE ($)

ALS certificate of analysis and database-ready


spreadsheet with mineral assemblages and
spectral parameters related to the project geology.

INTERP-11

3.00

Raw spectral files in ASD or ASCII format.

TRSPEC-20

2.50

HYLOG-10
HYLOG-20
INTERP-11

43.00/meter
3.60/sample
15.80/meter, 3.00/sample

Core photos delivered via ALS CoreViewer and


spreadsheet with mineral assemblages and
spectral parameters related to the project geology.
Core
Chip Trays
Spectral Interpretation

Hyperspectral Mineral
Mapping on Core

TerraCores Geospectral Imaging, a blend of hyperspectral core imaging hardware, advanced


analytic software and expert geological oversight provides unparalleled hyperspectral
investigation of drill core for exploration, mining and geometallurgical purposes. TerraCore and
ALS Geochemistry have partnered to host Core Imaging Spectrometers in major exploration
regions around the globe and provide a standard service package to ALS clients. These highly
advanced detectors measure the visible and shortwave infrared spectrum (400-2500nm at
5nm spectral resolution) on every square millimeter of core. Paired with TerraCores expert
processing software and guidance by experienced geologists, accurate spectral interpretation
of entire drilling campaigns is possible.

High resolution core photos.

Hyperspectral mineral map.

SPECTRAL MINERALOGY

aiSIRIS Expert
Hyperspectral
Interpretation

Visualization in ALS CoreViewer.

The standard service offered through ALS includes a high resolution RGB photograph of
the core, a mineral assemblage map and legend, and spectral mineral abundances and
feature values averaged over 10cm intervals. The full power of Core Imaging technology
lies in customization and deep investigation, with many more interpreted image
products available. Talk to your local client services for more information.
DESCRIPTION

DELIVERABLES

RGB and hyperspectral imaging of core boxes and chip trays with
TerraCores Core Imaging Spectrometer.

High resolution RGB photograph and mineral


assemblage map of each core box delivered via
ALS CoreViewer, archived securely in perpetuity.

Chip trays must be black plastic. ALS can transfer samples to black
trays for a fee.
Skeleton core boxes have custom pricing, please enquire.

Spectral mineral abundances and spectral features


delivered in database-ready file format as well as
via CoreViewer.

CODE

PRICE ($)

CORESC-11

5.50/foot
18.00/meter
4.00/sample

SAMPLE SUBMISSION AND STORAGE

Sample Submission

Please send your samples to any of the locations listed on the last two pages of this fee
schedule. Preaddressed adhesive labels and sample submission forms are available on
our website and can be sent to you on request. We can also offer advice on shipping
your samples to any of our laboratories by surface carrier, air cargo and air express.
Please enquire for detailed information on requirements and regulations for shipping
from your jurisdiction.
DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Samples received with barcode labels attached to sample bag.

LOG-21

0.60

Samples received without barcode labels attached.

LOG-22

APPLICATION

1.20

LOG-24

1.20

Pulps received without barcode labels attached.


At least one out of every 50 samples is selected at random for
routine pulp QC tests (LOG-QC). The default specification is 85%
passing 75 microns. Other specifications may be checked as per
client requirements.

Weigh raw sample and log into global


tracking system.

Workorder/administration fee applied per submittal.

Single charge for each batch of samples submitted.

BAT-01

26.45

Levy for disposal of all types of laboratory waste. Required for


relevant samples in certain jurisdictions.

Waste disposal levy.

LEV-01

0.60

QAR-01

0.70 (up to 500g)*

Quarantine (heat treatment, storage.) Required for relevant samples


AQIS approved heat treatment and storage.
imported into Australia.

*AQIS requires samples to be dried in portions not greater than 500g. Additional charges will apply for samples greater
than 500g.

Sample pick-up services can be arranged from any of our locations. Please contact your nearest
ALS office for details.
DESCRIPTION

APPLICATION

CODE

PRICE ($)

Sample pick-up service.

All sample types.

PKP-21

By Quotation

Sample Storage

Confidence and security in the chain of custody for your samples as they pass through
our system are paramount. To provide complete traceability, your samples are given
a barcode and logged into our proprietary global laboratory information management
system on receipt. We encourage clients to barcode samples prior to sending them to
our laboratories. Our system will accommodate all major barcode formats.

Materials submitted for analysis are retained free of charge at our laboratories for a
limited time, starting from the day we issue the final Certificate of Analysis. Prepared
master pulps are stored for 90 days and coarse and fine reject fractions are stored for
45 days. Reasonable monthly charges will apply to samples archived for longer periods
in our facilities. ALS Geochemistry sample storage facilities provide a secure and
organized environment protected from the elements, and all sample archive locations
are included in the laboratory tracking system.

DESCRIPTION

APPLICATION

CODE

PRICE PER SAMPLE ($)

Monthly archive of coarse rejects after the first 45 days.


Monthly archive of pulps >250g after the first 90 days.

Longer term archiving of coarse rejects.


Longer term archiving of large pulps.

STO-REJ
STO-BLK

0.65
0.65

Monthly archive of master pulps after the first 90 days.

Longer term storage of pulps.

STO-PUL

0.30

Monthly archive of screening reject fractions after the first 45 days.

Longer term storage of screening reject fractions.

STO-SCR

0.30

Handling and retrieval of archived samples.

Stored samples.

RET-21

59.55/hour

Disposal of pulps and coarse fractions.

Pulps and coarse fractions.

DIS-21

By Quotation

Return of samples to client.

Returned samples.

RTN-21

By Quotation

The sample preparation process is designed to produce a small, representative and


homogeneous sub-sample from the material you submit to the laboratory. Many
variations on these packages are available, and sample preparation schemes can also
be readily customized to suit any particular project requirement. We have a wide range
of expertise available within the ALS Group to help you with any questions you might
have about sample preparation.
All PREP packages below include sample login to the laboratory tracking system and
weighing. Excessively wet samples may require additional drying, which can result in
the application of a surcharge.

Drill Core, Rock, and Chip Samples


The packages described below illustrate the most common procedures used to prepare
drill core, rock and chip samples for representative analysis. It is very helpful to advise
us of mineralized samples that may require special equipment cleaning cycles to
eliminate contamination of other samples that might follow in a batch.
DESCRIPTION

APPLICATION

Preliminary coarse crushing of large drill core and rock samples.

Large drill core and rock samples.

Crush to 70% less than 2mm, riffle split off 250g, pulverize split to
better than 85% passing 75 microns.
Crush to 70% less than 2mm, riffle split off 1kg, pulverize split to
better than 85% passing 75 microns.

CODE

PRICE PER SAMPLE ($)

CRU-21*

2.65 plus 0.43/kg

PREP-31**

7.20 plus 0.70/kg

PREP-31B**

8.35 plus 0.70/kg

PREP-33D

9.85 plus 1.20/kg

PREP-22

9.55

Drill core, rock and chip samples.

Crush to 90% less than 2mm, riffle split off 1kg, pulverize split to
better than 95% passing 106 microns.

Drill core and rocks containing high-grade or


coarse gold and/or silver.

Crush to 70% less than 6mm, pulverize entire sample to better than
85% passing 75 microns.

Drill core, rock and chip samples up to 3kg.

* Size used varies by region; please contact your local client services for the appropriate method code.
**Please request PREP-31Y or PREP-31BY for a rotary split option on these packages.

Soil and Sediment Samples


Soil and sediment samples are commonly screened to remove large cobbles and organic
material before analysis. Drying temperature should be kept low to avoid the loss of
volatile elements. Air drying may be requested when the samples are intended for
selective leaches targeting the most weakly-bound trace elements.
DESCRIPTION

APPLICATION

Login, dry at <60C/140F, sieve sample to -180 micron (80 mesh).


Retain both fractions.

Soil or sediment samples.

Portable XRF on
Prepared Pulps

CODE

PRICE PER SAMPLE ($)

PREP-41

1.40 plus 2.35/kg

ALS Geochemistry offers portable XRF analysis on pulps immediately after sample
preparation, within three days of receipt at the prep lab closest to your project. pXRF
analysis on a sample pulp produces a more representative view of the samples
geochemistry than an analysis taken on the solid surface of rock or drill core, and the
results are available while traditional geochemical analyses are pending in the laboratory.
Detection limits, precision and accuracy of this method are suitable for identifying higher
grade anomalies to aid in short-term exploration plans and identification of significant
resource characteristics in mine or processing operations.

DESCRIPTION

DELIVERABLES

Portable XRF scan of a pulverized sample immediately after sample


preparation, to identify anomalous samples for exploration drilling and
preliminary resource identification.

ALS certificate of analysis with


pXRF-30 results. Provided immediately
after sample prep.

Analytes & Lower Limits (ppm)


As

50

Fe

0.5%

0.1%

Ca

0.5%

Mn

100

Zn

50

Cr

100

Ni

50

Cu

50

Pb

50

CODE

PRICE PER SAMPLE ($)

pXRF-30*

4.50

SAMPLE PREP PACKAGES AND PORTABLE XRF

Sample Preparation
Packages

*Ag and Mo may be added on request.

10

SAMPLE PREPARATION

Individual Sample
Preparation Procedures

The following procedures can be used either separately or combined in a package in order
to meet specific needs regarding sample size and composition. Most of these procedures are
charged at a rate that is based on sample weight.

Drying
Drying charges are only applied to samples that are excessively wet. Local laboratory
managers will determine the applicability of such charges in consultation with the client
when the samples are received.
DESCRIPTION

APPLICATION

CODE

PRICE PER SAMPLE ($)

Drying of excessively wet samples in drying ovens.

Default drying procedure for most rock chip and


drill samples.

DRY-21

2.35 plus 0.48/kg

Drying of excessively wet samples in drying ovens that are


controlled to a maximum temperature of 60C.

Most soil and sediment samples that are analyzed


for volatile elements.

DRY-22

2.35 plus 0.48/kg

Air-drying of samples.

Selective Leach procedures and others.

DRY-23

2.35 plus 0.48/kg

Crushing
Jaw crushers may be used to reduce sample particle size prior to pulverization. Very fine
crushing may be desirable when nugget effect and sample homogeneity is a concern. Other
nominal sizes and fineness options are available on request.
DESCRIPTION

APPLICATION

CODE

PRICE PER SAMPLE ($)

CRU-21

2.65 plus 0.43/kg

Standard preparation procedure for samples where


a representative split will be pulverized.

CRU-31

2.65 plus 0.43/kg

Fine crushing of rock chip and drill samples to 85% nominal -2mm.

Option for when a finer grind is desired.

CRU-36

3.00 plus 0.95/kg

Fine crushing of rock chip and drill samples to 90% nominal -2mm.

Option for when a finer grind is desired.

CRU-32

3.60 plus 1.15/kg

Used when the entire sample is to be pulverized


but the material is too coarse for introduction
Coarse crushing of rock chip and drill samples to 70% nominal -6mm into the pulverizing mill; or as a preliminary step
or better.
before fine crushing of larger sample sizes. No QC
is performed for this method. If QC is required,
request CRU-21q.
Fine crushing of rock chip and drill samples to 70% nominal -2mm.

Splitting
After crushing, some samples may require splitting into representative sub-samples. In many
locations automated rotary splitters can be attached to crushers to produce demonstrably
superior precision in sub-sample analyses.
DESCRIPTION

APPLICATION

CODE

Split sample using a riffle splitter.

Standard splitting procedure.

SPL-21

1.80 plus 0.33/kg

SPL-22

2.65 plus 0.85/kg

SPL-22Y

1.80 plus 0.33/kg

SPL-34

0.65

Split sample using a rotary splitter.


Split sample using a Boyd crusher/rotary splitter combination.
Split a received pulp sample for various uses.

Premium splitting procedure.


Pulp splitting procedure.

PRICE PER SAMPLE ($)

Pulverizing
While larger pulps offer better sub-sample representation and are required for metallic
screen assays, 250g pulps are routine for low-grade or non-mineralized rock. All pulverizing
procedures make use of flying disk or ring and puck style low-chrome steel grinding mills
unless otherwise specified. Please enquire if you are interested in non-metallic pulverization
media such as agate, tungsten carbide or zirconia.
DESCRIPTION

APPLICATION

Pulverize a split or total sample up to 250g to 85%


passing 75 microns.

Default procedure for samples that are finely


crushed and split to 250g or less.

Pulverize a 1,000g split to 85% passing 75 microns.


Pulverize a 1,000g split to 95% passing 106 microns.
Pulverize entire sample to 85% passing 75 microns.
Riffle split sample to maximum of 3kg and pulverize split
to 85% passing 75 microns. Retain and bag unpulverized reject.
Riffle split sample to maximum of 3kg and pulverize split
to 85% passing 75 microns. Dispose of unpulverized reject.
Pulverize concentrate sample to 85% passing 75 microns.

11

Large sample size to mitigate nugget effect.


Appropriate for samples up to 3kg.
Appropriate for RC drill chip samples
not requiring crushing.
Cost includes careful cleaning of the pulverizing
bowl after grinding.

CODE

PRICE PER SAMPLE ($)

PUL-31

4.20

PUL-32

5.95

PUL-35a

7.20

PUL-21

9.80

PUL-23

7.20 plus 0.90/kg

PUL-24

7.20 plus 0.65/kg

PUL-51

17.85

Specific gravity and bulk density of ores are important parameters that are often undercharacterized in the determination of grade and tonnage of deposits. Calculations for SG and
BD are corrected for air temperature. Wax coating and solvents other than water are available
in some locations; please enquire for more information. Incorrect assumptions or inadequate
characterization of these basic rock properties can lead to gross errors in deposit tonnage. SG
is determined by weighing a sample in air and in water, and it is reported as a ratio between
the density of the sample and the density of water. BD is the density of a material in weight
per unit volume, and it is determined by the weight of a sample and the volume of water the
sample displaces. Calculations for SG and BD are corrected for air temperature and the density
of the wax coating, if a wax coating is used. Solvents other than water are available in some
locations; please enquire for more information.

DESCRIPTION

RANGE

CODE

PRICE PER SAMPLE ($)

Specific Gravity on solid objects

OA-GRA08

11.90

Specific Gravity on pulps using pycnometer

OA-GRA08b

11.90

Bulk Density by water displacement

0.01 20g/cm 3

OA-GRA09

11.90

Bulk Density after wax coating (wax removal not included)

0.01 20g/cm 3

OA-GRA09a

19.05

Miscellaneous
Procedures

These procedures may be used when specialized preparation or sample compositing is


required. An hourly labor charge may apply to time-intensive projects.

DESCRIPTION

APPLICATION

CODE

PRICE PER SAMPLE ($)

Compositing of two or more samples. May be done by volume/core


length (CMP-21) or by weight (CMP-22).

As requested.

CMP-21
CMP-22

2.10
3.90

Clean crushers with barren material after every sample.

As required. The standard procedure uses


compressed air cleaning between samples
and barren material between each batch.

WSH-21

2.35

Clean pulverizers with barren material after every sample.

As required. The standard procedure uses


compressed air cleaning or vacuuming between
samples and barren material between each batch.

WSH-22

3.00

Transfer sample to drying tray or new sample bag.

As required for samples received in containers


unsuitable for laboratory storage, or requiring
tray drying.

TRA-21

1.20

Bagging large pulps for storage.

For large pulps/bulk masters.

BAG-01

1.20

Double bag coarse rejects.

As requested.

BAG-06

1.20

Homogenize stored or composited samples by light pulverizing.

As required.

HOM-01

5.30

Screening of samples to any number of standard size fractions, as


specified by the client. Weight of undersize fraction reported for
each screen size.

Fraction sizing or custom screening as requested.

SCR-51

5.95/screen size

SAMPLE PREPARATION

Specific Gravity
& Bulk Density

12

GOLD IN ROCKS AND DRILL CORE

Gold in Rocks, Drill Core


and Chip Samples

ANALYTE

RANGE (ppm)*

DESCRIPTION

Au

0.001-10

Au

Selection of the best fire assay method for the accurate determination of total gold content
in a sample is highly dependent on the nature of the sample matrix, the grain size and
distribution of the gold and the objective of the analytical result. ALS Geochemistry uses
an optimal flux recipe and rigorous quality control program to handle all but the highest
concentrations of problem materials including chromite, base metal sulfides and oxides,
selenides, and tellurides. With prior knowledge of the presence of these minerals and metals,
ALS Geochemistry can further modify the flux constituents to improve recoveries.
CODE

PRICE PER SAMPLE ($)

Au by fire assay and ICP-AES.


30g nominal sample weight
50g nominal sample weight

Au-ICP21
Au-ICP22

16.10
19.00

0.005-10

Au by fire assay and AAS.


30g nominal sample weight
50g nominal sample weight

Au-AA23
Au-AA24

15.50
18.45

Au

0.01-100

Au by fire assay and AAS.


30g nominal sample weight
50g nominal sample weight

Au-AA25
Au-AA26

16.10
19.00

Au

0.05-1,000

Au by fire assay and gravimetric finish.


30g nominal sample weight
50g nominal sample weight

Au-GRA21
Au-GRA22

20.20
24.35

Au
Ag

0.05-1,000
5-10,000

Au and Ag by fire assay and gravimetric finish.


30g nominal sample weight
50g nominal sample weight

ME-GRA21
ME-GRA22

26.20
30.35

Trace Level

Ore Grade

* 1 oz/ton = 34.2857ppm

When samples contain very high grade or coarse gold occurrences, the screen metallic
procedure is recommended to help avoid over- or under-estimating gold grades.
Custom method triggers can be set up for your project such that gold over a certain
concentration will automatically be re-run using a higher-grade method, including
screen metallics. Client services at ALS Geochemistry can help you customize a gold
assay program to meet your project needs.
ANALYTE

RANGE (ppm)*

DESCRIPTION

Au

0.05-1,000

1kg screen fire assay. Screen to 100 microns.


Duplicate assay on screen undersize. Assay of entire oversize fraction.
30g nominal sample weight
50g nominal sample weight

CODE

PRICE PER SAMPLE ($)

Au-SCR21**
Au-SCR24**

53.65
59.45

* 1 oz/ton = 34.2857ppm
** Other screen sizes may be available - please contact your local office for details.

13

Aqua regia and cyanide digestions offer very low detection limits for geochemical orientation
surveys. While cyanide methods can achieve lower detection limits than aqua regia, they are
more susceptible to preg robbing behavior by organic matter and sulfide minerals.
New this year, aqua regia multi-element methods for soils and sediments are offered from 25g
or 50g nominal sample weight digestions for best correlation of trace element geochemistry and
Au results. Methods using 0.5g sample are listed on page 18.

Super Trace Level


ANALYTE

RANGE

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Au

0.02ppb-1ppm

Au by cyanide extraction with ICP-MS finish.


25g nominal sample weight
50g nominal sample weight

Au-CN43
Au-CN44

20.00
22.20

Au

0.1ppb-0.1ppm

Au by aqua regia extraction with ICP-MS finish.


25g nominal sample weight
50g nominal sample weight

Au-ST43
Au-ST44

16.65
18.50

CODE

PRICE PER SAMPLE ($)

AuME-ST43
(25g Au &
multi element)

34.00

AuME-ST44
(50g Au &
multi element)

36.00

CODE

PRICE PER SAMPLE ($)

Au-TL43
Au-TL44

14.55
16.20

ANALYTES & RANGES (ppm)


Au

0.1ppb-1ppm

Cu

0.01-250

Nb

0.002-250

Ta

0.005-250

Ag

0.001-100

Fe

0.001%-50%

Ni

0.04-250

Te

0.01-250

Al

0.01%-25%

Ga

0.004-250

0.001%-1%

Th

0.002-250

As

0.01-250

Ge

0.005-250

Pb

0.005-250

Ti

0.001%-10%

10-10,000

Hf

0.002-250

Pd

0.001-100

Tl

0.002-250

Ba

0.5-10,000

Hg

0.004-250

Pt

0.001-100

0.005-100

Be

0.01-250

In

0.005-250

Rb

0.005-250

0.1-250

Bi

0.001-250

0.01%-10%

Re

0.001-50

0.001-250

Ca

0.01%-25%

La

0.002-250

0.01%-10%

0.003-250

Cd

0.001-250

Li

0.1-250

Sb

0.005-250

Zn

0.1-250

Ce

0.003-250

Mg

0.01%-25%

Sc

0.005-250

Zr

0.01-500

Co

0.001-250

Mn

0.1-10,000

Se

0.1-250

Cr

0.01-250

Mo

0.01-250

Sn

0.01-250

Cs

0.005-250

Na

0.001%-10%

Sr

0.01-10,000

Trace Level
ANALYTE

RANGE (ppm)

DESCRIPTION

Au

0.001-1

Au by aqua regia extraction with ICP-MS finish.


25g nominal sample weight
50g nominal sample weight

CODE

PRICE PER
SAMPLE ($)

AuME-TL43
(25g Au &
multi element)

24.00

AuME-TL44
(50g Au &
multi element)

26.00

ANALYTES & RANGES (ppm)


Au

0.001-1

Co

0.1-500

La

0.2-500

Re

0.001-50

Tl

0.02-500

Ag

0.01-100

Cr

1-10,000

Li

0.1-500

0.01%-10%

0.05-500

Al

0.01%-25%

Cs

0.05-500

Mg

0.01%-25%

Sb

0.05-500

1-500

As

0.1-500

Cu

0.2-500

Mn

5-10,000

Sc

0.1-500

0.05-500

10-10,000

Fe

0.01%-50%

Mo

0.05-500

Se

0.2-500

0.05-500

Ba

10-10,000

Ga

0.05-500

Na

0.01%-10%

Sn

0.2-500

Zn

2-500

Be

0.05-500

Ge

0.05-500

Nb

0.05-500

Sr

0.2-500

Zr

0.5-500

Bi

0.01-500

Hf

0.02-500

Ni

0.2-500

Ta

0.01-500

Ca

0.01%-25%

Hg

0.01-500

0.001%-1%

Te

0.01-500

Cd

0.01-500

In

0.005-500

Pb

0.2-500

Th

0.2-500

Ce

0.02-500

0.01%-10%

Rb

0.1-500

Ti

0.005%-10%

GOLD IN SOILS AND SEDIMENTS

Gold in Soils and


Stream Sediments

Ore Grade
ANALYTE

RANGE (ppm)

DESCRIPTION

Au

0.01-100

Au by aqua regia extraction with ICP-MS finish.


25g nominal sample weight
50g nominal sample weight

CODE

PRICE PER SAMPLE ($)

Au-OG43
Au-OG44

13.90
15.50

Cyanide Leach for Stream Sediments


Bulk Leach Extractable Gold (BLEG) is used where cyanide extraction from a very large stream
sediment sample can sometimes detect small gold anomalies that would otherwise go
unnoticed. Prices for cyanide leaching of samples over 1kg by quotation.
ANALYTE

RANGE (ppm)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Au

0.0001-10

BLEG ICP-MS finish


BLEG extraction AA finish

Au-CN12*
Au-AA12

35.70

Au

0.001-10

BLEG ICP-MS finish


BLEG extraction AA finish

Au-CN11*
Au-AA11

23.85

*Silver and copper may also be reported by these methods for an additional fee.

14

SILVER AND PLATINUM GROUP ELEMENTS

Silver

15

ANALYTE

Trace level and low-grade silver samples may be analyzed by acid digestion for
maximum sensitivity and precision. Because silver, like gold, can suffer from the nugget
effect, occasional duplicate analysis of silver acid digestion methods may help detect
sampling error at these low levels.
RANGE (ppm)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Ag

0.2-100

Ag by aqua regia digestion and AAS.

Ag-AA45

5.90

Ag

0.5-100

Ag by HF-HNO3-HClO4 digestion, HCl leach and AAS.

Ag-AA61

8.30

Trace Level

Note: See also multi-element methods that include Ag in the Targeted Exploration section (pages 21-23).

Ore Grade
Ag

1-1,500

Ag by aqua regia digestion, ICP-AES or AAS finish.

Ag-OG46
(Ag-AA46)

10.70

Ag

1-1,500

Ag by HF-HNO3-HClO4 digestion with HCl leach, ICP-AES or AAS finish.

Ag-OG62
(Ag-AA62)

13.10

Ag

5-10,000

Ag by fire assay and gravimetric finish.


30g nominal sample weight
50g nominal sample weight

Ag-GRA21
Ag-GRA22

21.40
25.55

Au
Ag

0.05-1,000
5-10,000

Au and Ag by fire assay and gravimetric finish.


30g nominal sample weight
50g nominal sample weight

ME-GRA21
ME-GRA22

26.20
30.35

Platinum, Palladium &


Other Precious Metals
ANALYTE

Platinum, palladium, rhodium and gold may be determined by standard lead oxide collection
fire assay and ICP-MS or ICP-AES finish. For the full list of platinum group elements, nickel
sulfide collection fire assay and neutron activation must be used for a quantitative analysis.

RANGE (ppm)

DESCRIPTION

Pt
Pd
Au

0.0001-1
0.0001-1
0.001-1

Super trace Pt, Pd and Au by fire assay and ICP-MS finish.


30g nominal sample weight

Pt
Pd
Au

0.0005-1
0.001-1
0.001-1

Pt, Pd and Au by fire assay and ICP-MS finish.


30g nominal sample weight
50g nominal sample weight

Rh

0.001-1

Rh by fire assay, gold collection and ICP-MS


30g nominal sample weight

CODE

PRICE PER SAMPLE ($)

PGM-MS23L

22.30

PGM-MS23
PGM-MS24

19.30
22.25

Rh-MS25

22.10

PGM-ICP23
PGM-ICP24

18.90
22.05

PGM-NAA26

By Quotation

PGM-ICP27

22.05

Trace Level

Intermediate Level
Pt
Pd
Au

0.005-10
0.001-10
0.001-10

Pt, Pd and Au by fire assay and ICP-AES finish.


30g nominal sample weight
50g nominal sample weight

Pt
Pd
Ir
Os
Rh
Ru
Au

0.02-10
0.02-10
0.001-10
0.01-10
0.005-10
0.05-10
0.001-10

Pt, Pd, Ir, Os, Rh, Ru and Au by fire assay with nickel sulfide collection and
neutron activation analysis.
30g nominal sample weight
Note: Au is not quantitative by this method.

Ore Grade
Pt
Pd
Au

0.01-100
0.01-100
0.01-100

Pt, Pd and Au by fire assay and ICP-AES finish.


30g nominal sample weight

In mining and exploration applications, cyanide leach tests are used to establish the potential
cyanide extraction efficiency for gold and silver. Various temperature and cyanide concentration
configurations are available; please contact client services for more information. Specific to
gold, the preg-rob leach test can identify the tendency of certain ores to re-adsorb gold from
the cyanide solution, causing lower recoveries than anticipated. Graphite and certain sulfide
minerals such as chalcopyrite can cause preg-robbing behavior.

ANALYTE

RANGE (ppm)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Au
Ag
Cu

0.03-50
0.03-350
0.1-2000

Au, Ag, Cu by cyanide leach with AAS finish.


30g nominal sample weight.

Au-AA13
Ag-AA13
Cu-AA13

9.55 plus 4.75/element

Au

0.01-200

Au by cyanide leach with AAS finish. (12hr Leach)


Up to 1kg nominal sample weight.

Au-AA14

29.75

Au

0.01-300

Au by accelerated cyanide leach using LeachWELL Assay Tabs


with AAS finish. (4hr Leach)
Up to 2kg nominal sample weight.

Au-AA15

35.70

Au

0.03-500

Au Preg Rob Leach with Gold Spike


Au Preg Rob Leach without Gold Spike

Au-AA31
Au-AA31a

10.70 each

Note: Cyanide disposal fees apply in some countries.

Gold in Metallurgical
Samples

Gold in solution in cyanide liquor or captured on activated carbon may be determined for
metallurgical purposes.

ANALYTE

RANGE (ppm)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Au

0.001 - 2500 mg/L

Au

1-10,000

Au in cyanide liquor by extraction with AAS finish.

Au-AA16

21.40

Au on carbon by ashing, aqua regia digestion and AAS. Duplicate analysis.

Au-AA44

38.10

Note: A range of elements can be determined on the ashed carbon by ICP-AES/ICP-MS. Please enquire for full details.

Precious Metals in
Concentrates and Bullion
ANALYTE

METALLURGICAL SAMPLES AND BULLION

Gold Cyanidation

High precision analysis and umpire assay of precious metals in concentrates and bullion are
performed by the most senior fire assay technicians and checked by certified assayers to
ensure accuracy.

RANGE (ppm)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

0.07-999,985
0.7-995,000

Au and Ag by fire assay and gravimetric finish.


30g sample weight required.

Au-CON01
Ag-CON01

82.50 each

0.07-1,000,000

Pt, Pd and Rh by fire assay and AAS finish.


30g sample weight required.

Pt-CON01
Pd-CON01
Rh-CON01

86.40 each

Au
Ag

0.01-1,000 fineness
0.01-1,000 fineness

Routine bullion assays by fire assay with gravimetric finish.

Au-GRA24
Ag-GRA24

126.00 each

Au
Ag

0.07-1,000,000
0.7-1,000,000

Umpire assay for bullion samples by fire assay with gravimetric finish.

Au-UMP20
Ag-UMP20

198.00 each

Umpire assay for bullion samples by fire assay with gravimetric finish.

Pt-UMP20
Pd-UMP20
Rh-UMP20

185.65 each

Concentrates
Au
Ag
Pt, Pd, Rh

Bullion

Pt, Pd, Rh

0.07-1,000,000

16

SUPER TRACE ANALYSIS FOR ROCKS AND DRILL CORE

Innovative Super Trace


Analysis

ALS Geochemistrys expert technical team is always working to refine industry-standard


methods and develop completely new techniques to solve thorny geochemical problems.
The availability of new quadrupole ICP-MS technology with gas collision cells has opened up
new frontiers in geochemical analysis, both in lower detection limits for better precision, and
in increased accuracy for very difficult elements like the halogens. ALS Geochemistry has been
focusing on method development for this new analytical platform over the last two years, in
order to bring you exciting new exploration tools found over the next four pages of this schedule.

Four Acid Digestion for


Near-Total Super Trace
Analysis

Four acid multi-element analysis has replaced aqua regia as the go-to method for analysis of
rocks and drill core. These methods offer a full pathfinder element suite at very low detection
limits and can be further used as a proxy for mineralogy and lithology, when lithogeochemical
analysis is not possible across an entire drilling program. Four acid methods can also be used
effectively in areas of thick regolith for bedrock lithomapping.
ALS Geochemistry has developed a super trace package suitable for greenfield exploration and
regional drilling, with elements such as As, Sb, Se and Tl showing anomalous patterns at levels
previously unrecognizable due to technical limitations.

ANALYTES & RANGES (ppm)


Ag

0.002-100

Cu

0.02-10,000

Na

0.001%-10%

Sr

0.02-10,000

Al

0.01%-25%

Fe

0.002%-50%

Nb

0.005-500

Ta

0.01-500

As

0.05-10,000

Ga

0.05-10,000

Ni

0.08-10,000

Te

0.04-500

Ba

1-10,000

Ge

0.05-500

0.001%-1%

Th

0.004-10,000

Be

0.02-1,000

Hf

0.004-500

Pb

0.01-10,000

Ti

0.001%-10%

Bi

0.005-10,000

In

0.005-500

Rb

0.02-10,000

Tl

0.004-10,000

Ca

0.01%-25%

0.01%-10%

Re

0.002-50

0.01-2,500

Cd

0.005-1,000

La

0.005-10,000

0.01%-10%

0.1-10,000

Ce

0.01-500

Li

0.2-10,000

Sb

0.02-10,000

0.008-10,000

Co

0.005-10,000

Mg

0.01%-25%

Sc

0.01-10,000

0.01-500

Cr

0.3-10,000

Mn

0.2-50,000

Se

0.2-1000

Zn

0.2-10,000

Cs

0.01-500

Mo

0.02-10,000

Sn

0.02-500

Zr

0.1-500

CODE

PRICE PER SAMPLE ($)

ME-MS61L

33.50

Add-on Packages for ME-MS61L


Lead isotope concentrations analyzed on the same run as the multi-element package add a new
dimension to super trace data by fingerprinting certain units or hydrothermal fluids. In some
cases these fingerprints can be used to distinguish generations of mineralization and alteration.
For a more precise and robust Pb isotopic analysis, see the method PbIS-RAT61 on page 25.
ANALYTES & RANGES (ppm)
Pb

0.01

206

Pb

0.01

Pb

0.01

208

Pb

0.01

204
207

CODE

PRICE PER SAMPLE ($)

MS61L-PbIS

9.00

The rare earth elements can correlate with mineralization in a variety of non-REE deposit types.
Four acid digestion will not fully dissolve resistive rare earth oxides, but the information in this
suite of elements can be very useful in exploration.
ANALYTES & RANGES (ppm)
Dy

0.005

Ho

0.002

Sm

0.004

Er

0.004

Lu

0.002

Tb

0.002

Eu

0.004

Nd

0.005

Tm

0.002

Gd

0.005

Pr

0.004

Yb

0.004

CODE

PRICE PER SAMPLE ($)

MS61L-REE

5.75

Silicon, titanium and zirconium may be added to four acid methods for a more complete element
suite. While four acid digestion does not fully dissolve all rock-forming minerals, it is often the
only data set available across an entire project. The addition of these crucial lithogeochemical
elements by portable XRF analysis on the sample pulp greatly increases the utility of four acid
packages beyond the trace elements.
ANALYTES & RANGES
Si 0.05%-47%
Ti 0.01%-60%
Zr 1-10,000ppm

17

New developments in sample introduction techniques and


collision/reaction cells for the ICP-MS have allowed ALS to achieve
dramatic reductions in detection limits on a wide range of methods.

CODE

PRICE PER SAMPLE ($)

pXRF-34

3.40

The aqua regia digestion, in combination with sophisticated software and careful analysis by
ICP-MS and ICP-AES, provides extremely low detection limits useful for exploration in soils or
sediments requiring ultra-trace analytical sensitivity. Alternatively, a weak acid digestion using
1:1 nitric to hydrochloric acids at room temperature may be used for more selective digestion
of oxyhydroxide minerals.

ANALYTES & RANGES (ppm)

CODE

Ag

0.001-100

Co

0.001-10,000

La

0.002-10,000

Pt

0.002-25

Th

0.002-10,000

Al

0.01%-25%

Cr

0.01-10,000

Li

0.1-10,000

Rb

0.005-10,000

Ti

0.001%-10%

As

0.01-10,000

Cs

0.005-500

Mg

0.01%-25%

Re

0.001-50

Tl

0.002-10,000

Au

0.0002-25

Cu

0.01-10,000

Mn

0.1-50,000

0.01%-10%

0.005-10,000

10-10,000

Fe

0.001%-50%

Mo

0.01-10,000

Sb

0.005-10,000

0.1-10,000

Ba

0.5-10,000

Ga

0.004-10,000

Na

0.001%-10%

Sc

0.005-10,000

0.001-10,000

Be

0.01-1000

Ge

0.005-500

Nb

0.002-500

Se

0.1-1000

0.003-500

Bi

0.001-10,000

Hf

0.002-500

Ni

0.04-10,000

Sn

0.01-500

Zn

0.1-10,000

Ca

0.01%-25%

Hg

0.004-10,000

0.001%-1%

Sr

0.01-10,000

Zr

0.01-500

Cd

0.001-1000

In

0.005-500

Pb

0.005-10,000

Ta

0.005-500

Ce

0.003-500

0.01%-10%

Pd

0.001-25

Te

0.01-500

PRICE PER
SAMPLE ($)

ME-MS41L
Aqua Regia

27.95

ME-MS41W
Weak Acid Leach

Add-on Packages for ME-MS41L and ME-MS41W


Lead isotope concentrations analyzed on the same run as the multi-element package add a new
dimension to super trace data by fingerprinting certain units or hydrothermal fluids. In some
cases these fingerprints can be used to distinguish generations of mineralization and alteration.
For a more precise and robust Pb isotopic analysis, see the method PbIS-RAT41 on page 26.
ANALYTES & RANGES (ppm)
Pb

0.005

206

Pb

0.005

Pb

0.005

208

Pb

0.005

204
207

CODE

PRICE PER SAMPLE ($)

MS41L-PbIS
MS41W-PbIS

9.00

The rare earth elements can correlate with mineralization in a variety of non-REE deposit
types. Aqua regia will not dissolve the majority of resistive oxides hosting REEs, but in soils and
sediments the elements may be useful exploration indicators.
ANALYTES & RANGES (ppm)
Dy

0.002

Ho

0.001

Sm

0.002

Er

0.002

Lu

0.001

Tb

0.001

Eu

0.002

Nd

0.002

Tm

0.001

Gd

0.002

Pr

0.002

Yb

0.002

CODE

PRICE PER SAMPLE ($)

MS41L-REE
MS41W-REE

5.75

Super Trace Selenium in Soils


With ultra-clean disposable digestion vessels and the ICP-MS collision cell tuned specifically for
Se, we can achieve a super trace detection limit without external sensitivity tweaks. Selenium
at this level holds information for exploration geochemistry, environmental baselines, and
lithomapping in areas of thick cover.
ANALYTE

RANGE (ppm)

DESCRIPTION

Se

0.003-100

25g aqua regia digestion and ICP-MS analysis.

CODE

PRICE PER SAMPLE ($)

Se-MS46

16.65

Clay Separation
ALS Geochemistry now offers a rapid, high-quality clay size fraction separation on screened soils.
The clay fraction in soils acts as a trap for labile elements migrating to the surface environment
from depth, and may be used to enhance subtle geochemical signals.
DESCRIPTION
Separation of the -10 micron fraction from soils. Requires 50-300g of sieved soil.

CODE

PRICE PER SAMPLE ($)

SCR-CLAY

15.00

Halogen Analysis in Surficial Materials


Analysis of the halogens fluorine, chlorine, bromine, and iodine holds significant promise
in exploration, since many precious and base metals are transported through the crust as
halide complexes. Until now, the utility of halogen analysis was severely limited by instrument
technology, but with cutting-edge technology and technical innovation by ALS chemists it is
possible to measure these important elements. We have developed a robust method for iodine
and continue to work on a complete halogen package by deionized water leach.
ANALYTE

RANGE (ppm)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

0.008-100

Water leach and ICP-MS analysis with collision cell tuned specifically for iodine.

I-MS03

16.40

SUPER TRACE ANALYSIS FOR SOILS AND SEDIMENTS

Aqua Regia and Weak


Acid Digestion for Soils
and Sediments

18

SELECTIVE LEACHES

Ionic Leach

Ionic Leach is a static sodium cyanide leach using the chelating agents ammonium
chloride, citric acid and EDTA with the leachant buffered at an alkaline pH of 8.5. This
innovative leach technique is designed for near surface soils; sample handling is limited
to minimize opportunity for super trace contamination. It is designed to enhance the
potential to detect and resolve geochemical anomalies for a range of commodity
elements.
Minimum sample size is 50g (wet weight) of soil for Ionic Leach. Specially prepared
vegetation samples may be leached at a 5g sample size.

ANALYTES & DETECTION LIMITS (ppb)


Ag

0.1

Eu

0.1

Nb

0.1

Tb

As

Fe

0.1ppm

Nd

0.1

Te

Au

0.02

Ga

0.5

Ni

Th

0.02

Ba

10

Gd

0.1

Pb

Ti

Be

0.2

Ge

0.1

Pd

0.1

Tl

0.5

Bi

Hf

0.5

Pr

0.1

Tm

0.1

Br

0.05ppm

Hg

0.1

Pt

0.1

0.1

Ca

0.2ppm

Ho

0.1

Rb

0.1

Cd

0.01ppm

Re

0.1

0.1

Ce

0.1

In

0.1

Sb

0.5

Yb

0.1

Co

0.3

La

0.1

Sc

Zn

10

Zr

0.1

Cr

Li

0.2

Se

Cs

0.1

Lu

0.1

Sm

0.1

Cu

Mg

0.01ppm

Sn

0.2

206

Dy

0.1

Mn

0.01ppm

Sr

207

Er

0.1

Mo

0.5

Ta

208

CODE

PRICE PER SAMPLE ($)

ME-MS23

37.65 complete package

ME-MS22

21.35 plus 0.80/element,


2.30 pH after leach

0.1

Pb

Pb

Pb

Other Selective Leaches


In addition to Ionic Leach, ALS Geochemistry offers a variety of partial leaches targeting particular
soil fractions. They can be done individually or in sequence to best suit project needs. Minimum
sample size is 1g for each leach or for any combination in sequence.
ANALYTES & DETECTION LIMITS (ppm)

CODE

Ag

0.002

Dy

0.0005

Mg

0.5

Sr

0.005

Al

Er

0.0005

Mn

0.05

Ta

0.001

As

0.01

Eu

0.0005

Mo

0.001

Tb

0.0001

Au

0.001

Fe

Na*

Te

0.005

0.2

Ga

0.05

Nb

0.0005

Th

0.0005

Ba

0.01

Gd

0.0005

Nd

0.0005

Ti

0.05

Be

0.005

Ge

0.005

Ni

0.05

Tl

0.001

Bi

0.003

Hf

0.0005

P*

Tm

0.0001

Br

Hg

0.01

Pb

0.005

0.0005

Ca

10

Ho

0.0001

Pr

0.0001

0.05

Cd

0.001

0.05

Rb

0.005

0.001

Ce

0.0005

In

0.001

Re

0.0002

0.0005

Co

0.001

Sb

0.0005

Yb

0.0005

Cr

0.05

La

0.0005

Se

0.02

Zn

0.05

Cs

0.0005

Li

0.01

Sm

0.0005

Zr

0.001

Cu

0.05

Lu

0.0001

Sn

0.005

*Na and P are not reported in ME-MS07

19

PRICE PER
SAMPLE ($)

Deionized Water
ME-MS03
Ammonium Acetate
ME-MS04
Cold Hydroxylamine-HCl
ME-MS05
Hot Hydroxylamine-HCl
ME-MS06
Sodium Pyrophosphate
ME-MS07*

41.70/leach

Super Trace Analysis of Natural Waters


Trace metal analysis in ground and surface waters can reveal mineralization-related
anomalies in areas where traditional soil sampling is difficult or impossible, such as
swampy terrain, desert, and agricultural disturbance. Using the latest generation of
collision-cell equipped ICP-MS, ALS Geochemistry offers a reliable and cost-effective water
analysis package with optional anions by ion chromatography and a full suite of physical
parameters. Sampling kits may be purchased in some locations, please enquire.

ANALYTES & DETECTION LIMITS (g/L)


Au

0.002

Cu

0.1

Ni

0.2

Ta

Ag

0.005

Fe

0.003mg/L

0.005mg/L

Te

0.01

Al

Ga

0.05

Pb

0.05

Th

0.005

As

0.05

Hf

0.005

Pd

0.005

Ti

0.2

Hg

0.05

Pt

0.005

Tl

0.002

Ba

0.05

In

0.01

Rb

0.01

0.002

Be

0.005

0.01mg/L

Re

0.002

0.05

Bi

0.01

La

0.005

0.2mg/L

0.01

Ca

0.02mg/L

Li

0.1

Sb

0.01

0.005

Cd

0.005

Mg

0.005mg/L

Sc

0.01

Zn

0.5

Zr

0.02

Ce

0.005

Mn

0.05

Se

0.05

Co

0.005

Mo

0.05

Si

0.03mg/L

Cr

0.5

Na

0.01mg/L

Sn

0.05

Cs

0.005

Nb

0.005

Sr

0.05

Dy

0.005

Gd

0.005

Nd

0.005

Tb

0.005

Er

0.005

Ho

0.005

Pr

0.005

Tm

0.005

Eu

0.005

Lu

0.005

Sm

0.005

Yb

0.005

Br

0.05mg/L

NO3

0.005mg/L

pH

0.1 units

Conductivity 2S/cm

Cl

0.5mg/L

SO4

0.5mg/L

TDS

3mg/L

Alkalinity

0.02mg/L

Biogeochemistry

CODE

PRICE PER SAMPLE ($)

ME-MS14L

62.50

MS14L-REE

18.50

MS14L-ANPH

44.00

0.01

1mg/L

WATER AND VEGETATION

Hydrogeochemistry

Plants may be viewed as large-scale geochemical sampling devices, with root systems that can
selectively absorb elements from a large volume of soil, groundwater, and even bedrock. Careful
selection of plant species is important as biological effects control geochemical response.

Vegetation Sample Preparation


CODE

PRICE PER SAMPLE ($)

Maceration of dry plant tissue to produce a homogeneous and representative pulp that can be subsampled for analysis.
A 100g sample is milled to 100% passing 1mm.

DESCRIPTION

VEG-MILL01

6.30

A 100g sample is ashed at 475C for 24 hours. Pre- and post-ashing weights are reported. Average ash yields are 2-4%
for species commonly used in exploration surveys.

VEG-ASH01

6.30

65 Elements in Vegetation by HNO3 /HCl Digestion and ICP-MS


This method is available with unashed and ashed certified reference materials. The unashed
method uses 1g of sample while the ashed method uses 0.25g.
ANALYTES & DETECTION LIMITS (ppm)
Ag

0.001

Cu

0.01

CODE
Nb

0.002

Ta

Al

0.01%

Fe

Ni

0.04

Te

0.02

As

0.01

Ga

0.004

0.001%

Th

0.002

Au

0.0002

Ge

0.005

Pb

0.01

Ti

0.001%

Hf

0.002

Pd

0.001

Tl

0.002

Ba

0.1

Hg

0.001

Pt

0.001

0.005

Be

0.01

In

0.005

Rb

0.01

0.05

Bi

0.001

0.01%

Re

0.001

0.01

Ca

0.01%

La

0.002

0.01%

0.003

Cd

0.001

Li

0.1

Sb

0.01

Zn

0.1

Zr

0.02

Ce

0.003

Mg

0.001%

Sc

0.01

Co

0.002

Mn

0.1

Se

0.005

Cr

0.01

Mo

0.01

Sn

0.01

Cs

0.005

Na

0.001%

Sr

0.02

PRICE PER SAMPLE ($)

0.001

Dy

0.002

Gd

0.002

Nd

0.001

Tb

0.001

Er

0.002

Ho

0.001

Pr

0.002

Tm

0.001

Eu

0.002

Lu

0.001

Sm

0.003

Yb

0.003

ME-VEG41
(unashed)
ME-VEG41a
(ashed)

VEG41-REE
VEG41a-REE

17.50

4.30

20

ULTRA TRACE AQUA REGIA

Ultra Trace Level


Methods Aqua Regia
Digestion for Drill Core
and Rocks

Method selection can be key to achieving exploration success. Sample type, target commodity,
and pathfinder elements should all be considered when selecting the most appropriate
method for your project.
Aqua regia readily dissolves many sulfide, oxide and carbonate minerals quantitatively while
leaving silicates and resistive oxides untouched. Many volatile pathfinder elements, particularly
mercury, are preserved during digestion. These considerations make aqua regia an excellent
exploration tool for various deposit types that involve gold, silver and base metals hosted in
sulfide and carbonate minerals.
Native metals such as gold and silver may not be representatively characterized by the small
sample sizes used in these methods (nugget effect), and some refractory minerals and
elements such as molybdenum are not brought into solution in aqua regia. In these cases, fire
assay may be used in combination with ME-MS41, or a four acid digestion may be preferable.
Please contact your nearest lab with any questions.
Minimum sample size is 1g.

51 Element Package by Aqua Regia and ICP-AES/ICP-MS


ANALYTES & RANGES (ppm)
Ag

0.01-100

Cs

0.05-500

Mo

0.05-10,000

Sr

0.2-10,000

Al

0.01-25%

Cu

0.2-10,000

Na

0.01%-10%

Ta

0.01-500

As

0.1-10,000

Fe

0.01%-50%

Nb

0.05-500

Te

0.01-500

Au*

0.2-25

Ga

0.05-10,000

Ni

0.2-10,000

Th

0.2-10,000

10-10,000

Ge

0.05-500

10-10,000

Ti

0.005%-10%

Ba

10-10,000

Hf

0.02-500

Pb

0.2-10,000

Tl

0.02-10,000

Be

0.05-1,000

Hg

0.01-10,000

Rb

0.1-10,000

0.05-10,000

Bi

0.01-10,000

In

0.005-500

Re

0.001-50

1-10,000

Ca

0.01%-25%

0.01%-10%

0.01%-10%

0.05-10,000

Cd

0.01-1,000

La

0.2-10,000

Sb

0.05-10,000

0.05-500

Ce

0.02-500

Li

0.1-10,000

Sc

0.1-10,000

Zn

2-10,000

Co

0.1-10,000

Mg

0.01%-25%

Se

0.2-1,000

Zr

0.5-500

Cr

1-10,000

Mn

5-50,000

Sn

0.2-500

CODE

PRICE PER SAMPLE ($)

ME-MS41

22.35

* Gold determinations by this method are semi-quantitative due to the small sample weight used.

Single Elements by Aqua Regia and ICP-MS


An effective option when analytical results for one or only a few elements are required. You
can create your own package of elements specific to your exploration program. Many more
elements are available on request.
ANALYTES & RANGES (ppm)
Ag

0.01-25

Hg

0.005-25

Se

0.2-250

As

0.1-250

Re

0.001-250

Te

0.01-250

Bi

0.01-250

Sb

0.05-250

Tl

0.02-250

+ Add element symbol as prefix to method code.

21

CODE

PRICE PER SAMPLE ($)

(+)-MS42

11.90 plus 1.20/element

0.05-250

Four acid digestion quantitatively dissolves nearly all minerals in the majority of geological
materials. However, it may sometimes be necessary to use even stronger dissolution
techniques such as fusions in order to achieve fully quantitative results for refractory minerals.
These may include barite, rare earth oxides, columbite-tantalite, and tin and tungsten
minerals.
Four acid digestion can also volatilize certain exploration pathfinder elements, in particular
mercury. Mercury may be added to the package at a special price detailed below, or a custom
suite of elements can be added using the single-element aqua regia method on the opposite
page as well. Four acid digestions are not recommended for gold analysis; the fire assay
methods described on page 13 may be paired with ME-MS61 for exploration purposes.
Minimum sample size is 1g.

48 Element Package by Four Acid and ICP-AES/ICP-MS


ANALYTES & RANGES (ppm)
Ag

0.01-100

Cu

0.2-10,000

Na

0.01%-10%

Sr

0.2-10,000

Al

0.01%-50%

Fe

0.01%-50%

Nb

0.1-500

Ta

0.05-100

As

0.2-10,000

Ga

0.05-10,000

Ni

0.2-10,000

Te

0.05-500

Ba

10-10,000

Ge

0.05-500

10-10,000

Th

0.2-10,000

Be

0.05-1,000

Hf

0.1-500

Pb

0.5-10,000

Ti

0.005%-10%

Bi

0.01-10,000

In

0.005-500

Rb

0.1-10,000

Tl

0.02-10,000

Ca

0.01%-50%

0.01%-10%

Re

0.002-50

0.1-10,000

Cd

0.02-1,000

La

0.5-10,000

0.01%-10%

1-10,000

Ce

0.01-500

Li

0.2-10,000

Sb

0.05-10,000

0.1-10,000

Co

0.1-10,000

Mg

0.01%-50%

Sc

0.1-10,000

0.1-500

Cr

1-10,000

Mn

5-100,000

Se

1-1,000

Zn

2-10,000

Cs

0.05-500

Mo

0.05-10,000

Sn

0.2-500

Zr

0.5-500

CODE

PRICE PER SAMPLE ($)

ME-MS61

26.80

ME-MS61m

36.35

Note: To include Hg by a separate procedure in the suite of elements above, please request ME-MS61m instead of ME-MS61.

Add-on Packages to ME-MS61

ULTRA TRACE FOUR ACID

Ultra Trace Level Methods


Four Acid Digestion for
Drill Core and Rocks

Silicon, titanium and zirconium may be added to four acid methods for a more complete
element suite. While four acid digestion does not fully dissolve all rock-forming minerals,
it is often the only data set available across an entire project. The addition of these crucial
lithogeochemical elements by portable XRF analysis on the sample pulp greatly increases
the utility of four acid packages beyond the trace elements.
ANALYTES & RANGES
Si 0.05%-47%
Ti 0.01%-60%
Zr 1ppm-10,000ppm

CODE

PRICE PER SAMPLE ($)

pXRF-34

3.40

A full suite of rare earth elements can be added to this package, keeping in mind that this data
will represent the acid leachable portion of the rare earth elements only.
To include rare earth elements in the suite of elements above, please request ME-MS61r
instead of ME-MS61.
ANALYTES & RANGES (ppm)
Dy

0.05-1,000

Gd

0.05-1,000

Nd

0.1-10,000

Tb

0.01-1,000

Er

0.03-1,000

Ho

0.01-1,000

Pr

0.03-1,000

Tm

0.01-1,000

Eu

0.03-1,000

Lu

0.01-1,000

Sm

0.03-1,000

Yb

0.03-1,000

CODE

PRICE PER SAMPLE ($)

ME-MS61r

6.70 (add-on price)

Single Elements by Four Acid and ICP-MS


An effective option when analytical results for one or only a few elements are required. You
can create your own package of elements specific to your exploration program. Many more
elements are available on request.
ANALYTES & RANGES (ppm)
Ag

0.02-100

Ga

0.05-500

Se

0.5-500

Tl

0.02-500

As

0.2-500

Mo

0.05-500

Sn

0.2-500

0.1-500

Bi

0.01-500

Re

0.002-50

Te

0.05-500

0.1-500

Cd

0.02-500

Sb

0.05-500

Th

CODE

PRICE PER SAMPLE ($)

(+)-MS62

14.30 plus 1.20/element

0.2-500

+ Add element symbol as prefix to method code.

22

TRACE LEVEL METHODS

Trace Level Methods by


Aqua Regia

These methods are economical tools for first pass exploration geochemistry. Data reported
from an aqua regia digestion should be considered as representing only the leachable portion
of the particular analyte.
Minimum sample size is 1g.

35 Element Package by Aqua Regia and ICP-AES


ANALYTES & RANGES (ppm)
Ag

0.2-100

Co

1-10,000

Mn

5-50,000

Sr

1-10,000

Al

0.01%-25%

Cr

1-10,000

Mo

1-10,000

Th

20-10,000

As

2-10,000

Cu

1-10,000

Na

0.01%-10%

Ti

0.01%-10%

10-10,000

Fe

0.01%-50%

Ni

1-10,000

Tl

10-10,000

Ba

10-10,000

Ga

10-10,000

10-10,000

10-10,000

Be

0.5-1,000

Hg

1-10,000

Pb

2-10,000

1-10,000

Bi

2-10,000

0.01%-10%

0.01%-10%

10-10,000

Ca

0.01%-25%

La

10-10,000

Sb

2-10,000

Zn

2-10,000

Cd

0.5-1,000

Mg

0.01%-25%

Sc

1-10,000

CODE

PRICE PER SAMPLE ($)

ME-ICP41

10.75 complete package or


5.25 plus 0.65/element

ME-ICP41m

16.65

Note: To include Hg to a lower detection limit of 0.005ppm in this suite of elements, please request method ME-ICP41m instead of ME-ICP41.

Single Elements by Aqua Regia and AAS


ANALYTES & RANGES (ppm)
Ag

0.2-100

Co

1-10,000

Mo

1-10,000

Pb

1-10,000

As

5-10,000

Cu

1-10,000

Ni

1-10,000

Zn

1-10,000

CODE

PRICE PER SAMPLE ($)

(+)-AA45

3.55 plus 2.35/element

+ Add element symbol as prefix to method code.

Trace Level Methods


by Four Acid

Four acid digestions are able to dissolve most minerals, but although the term near-total is
used, not all elements are quantitatively extracted in some sample matrices.
Minimum sample size is 1g.

33 Element Package by Four Acid and ICP-AES


ANALYTES & RANGES (ppm)
Ag

0.5-100

Cr

1-10,000

Na

0.01%-10%

Ti

0.01%-10%

Al

0.01%-50%

Cu

1-10,000

Ni

1-10,000

Tl

10-10,000

As

5-10,000

Fe

0.01%-50%

10-10,000

10-10,000

Ba

10-10,000

Ga

10-10,000

Pb

2-10,000

1-10,000

Be

0.5-1,000

0.01%-10%

0.01%-10%

10-10,000

Bi

2-10,000

La

10-10,000

Sb

5-10,000

Zn

2-10,000

Ca

0.01%-50%

Mg

0.01%-50%

Sc

1-10,000

Cd

0.5-1,000

Mn

5-100,000

Sr

1-10,000

Co

1-10,000

Mo

1-10,000

Th

20-10,000

CODE

PRICE PER SAMPLE ($)

ME-ICP61

14.30 complete package or


7.65 plus 0.65/element

ME-ICP61m

23.85

Note: To include Hg in the suite of elements above, please request method ME-ICP61m instead of ME-ICP61.

Single Elements by Four Acid and AAS


ANALYTES & RANGES (ppm)
Ag

0.5-100

Co

5-10,000

Mo

2-10,000

Pb

5-10,000

As

10-10,000

Cu

2-10,000

Ni

5-10,000

Zn

5-10,000

+ Add element symbol as prefix to method code.

23

CODE

PRICE PER SAMPLE ($)

(+)-AA61

5.95 plus 2.35/element

These packages can be used as an economical alternative to analyzing low grade ore
or samples with known mineralization. The method precision is intermediate between
exploration geochemistry and an assay procedure.
Minimum sample size is 1g.

34 Element Package by Aqua Regia and ICP-AES


Data reported from an aqua regia digestion should be considered as representing only the
leachable portion of the particular analyte.
ANALYTES & RANGES (ppm)
Ag

1-200

Cr

5-50,000

Mo

5-50,000

Th

100-50,000

Al

0.05%-50%

Cu

5-50,000

Na

0.05%-50%

Ti

0.05%-50%

As

10-100,000

Fe

0.05%-50%

Ni

5-50,000

Tl

50-50,000

Ba

50-50,000

Ga

50-50,000

50-50,000

50-50,000

Be

5-500

Hg

5-50,000

Pb

10-50,000

5-50,000

Bi

10-50,000

0.05%-50%

0.05%-10%

50-50,000

Ca

0.05%-50%

La

50-50,000

Sb

10-50,000

Zn

10-50,000

Cd

5-2,500

Mg

0.05%-50%

Sc

5-50,000

Co

5-50,000

Mn

25-50,000

Sr

5-50,000

CODE

PRICE PER SAMPLE ($)

ME-ICP41a

17.85 complete package or


10.70 plus 2.35/element

33 Element Package by Four Acid and ICP-AES


Four acid digestions are able to dissolve most minerals, but although the term near-total is
used, not all elements are quantitatively extracted in some sample matrices.
ANALYTES & RANGES (ppm)
Ag

1-200

Cr

10-100,000

Na

0.05%-30%

Ti

0.05%-30%

Al

0.05%-30%

Cu

10-100,000

Ni

10-100,000

Tl

50-50,000

As

50-100,000

Fe

0.05%-50%

50-100,000

50-50,000

Ba

50-50,000

Ga

50-50,000

Pb

20-100,000

10-100,000

Be

10-10,000

0.1%-30%

0.05%-10%

50-50,000

Bi

20-50,000

La

50-50,000

Sb

50-50,000

Zn

20-100,000

Ca

0.05%-50%

Mg

0.05%-50%

Sc

10-50,000

Cd

10-10,000

Mn

10-100,000

Sr

10-100,000

Co

10-50,000

Mo

10-50,000

Th

50-50,000

Low Level Resistive


Elements

CODE

PRICE PER SAMPLE ($)

ME-ICP61a

20.25 complete package or


13.10 plus 2.35/element

LOW GRADE MINERALIZATION

Low Grade Mineralized


Materials

Single Elements by Fusion and ICP-MS


A lithium metaborate fusion followed by acid dissolution of the fused bead quantitatively
digests most mineral species, including those that are highly refractory. ICP-MS techniques
allow elements in these difficult-to-analyze minerals to be determined at trace levels.
Additional elements are available on request.

ANALYTES & RANGES (ppm)


Ce

0.5-1,000

Rb

0.2-1,000

Ta

0.1-1,000

1-1,000

La

0.5-1,000

Sn

1-1,000

Th

0.05-1,000

0.5-1,000

Nb

0.2-1,000

Sr

0.1-1,000

0.05-1,000

Zr

2-1,000

CODE

PRICE PER SAMPLE ($)

(+)-MS85

14.30 plus 1.20/element

+ Add element symbol as prefix to method code.

Single Elements by Pressed Pellet XRF


Pressed pellet XRF is a suitable method for determining certain elements that are not easily
solubilized by acid digestion techniques, but may be subject to interferences arising from
matrix effects including particle size and sample mineralogy.
A finely ground sample powder is mixed with a few drops of liquid binder, compressed in a
pellet press, and analyzed by XRF spectrometry. Minimum sample size is 10g.
ANALYTES & RANGES (ppm)
Ba

10-10,000

Nb

2-4,000

Ta

10-5,000

2-4,000

Ce

10-4,000

Rb

2-4,000

Th

4-4,000

Zr

2-4,000

Cr

5-4,000

Sn

5-5,000

4-5,000

La

10-4,000

Sr

2-4,000

10-5,000

CODE

PRICE PER SAMPLE ($)

(+)-XRF05

9.55 plus 2.35/element

+ Add element symbol as prefix to method code.

24

INDIVIDUAL METHODS

Individual and
Miscellaneous Methods

Halogens
Elemental analysis of the halide minerals containing chlorine and fluorine require specific
instrumentation and special fusions or digestions that will completely dissolve and retain
the elements in solution. For bromine and iodine, solid sampling by neutron activation
must be used.
Minimum sample size is 5g.

ANALYTE

RANGE (ppm)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Cl

50-20,000

KOH fusion and ion chromatography.

Cl-IC881

20.00

50-20,000

Specific to Cl in phosphates only.


KOH fusion and ion selective electrode.

Cl-ELE81a

17.85

Cl
Cl

0.001%-6%

Lithium metaborate fusion and XRF.

Cl-XRF20

17.85

Cl

0.01%-80%

Nitric acid digestion and titration.

Cl-VOL66

35.70

20-20,000

KOH fusion and ion selective electrode.

F-ELE81a

17.85

0.01%-20%

Na2O2 fusion, citric acid leach and ion


selective electrode.

F-ELE82

26.45

F
F

20-20,000

KOH fusion and ion chromatography.

F-IC881

20.00

Cl
F

50-20,000
20-20,000

KOH fusion and ion chromatography.

ME-IC881

27.50

Br
Cl
I

0.5-10,000
90-10,000
0.5-10,000

Halogen package by neutron activation.

Br-NAA05
Cl-NAA06
I-NAA07

By Quotation

Mercury
Mercury poses special analytical challenges and may be partially or completely
volatilized by high temperature digestions. Aqua regia is the digestion of choice for a
range of concentrations.
Minimum sample size is 1g.
ANALYTE

RANGE (ppm)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Hg

0.005-100

Hg

1-100,000

Trace level Hg by aqua regia and ICP-MS.

Hg-MS42

9.50

High grade Hg by aqua regia and ICP-AES.

Hg-ICP42

Hg

1-10,000

9.50

Hg in ores by acid digestion and ICP-AES.

Hg-CON01

71.45

CODE

PRICE PER SAMPLE ($)

OA-GRA10

14.30

Water Content and LOI


ANALYTE

RANGE (%)

DESCRIPTION

H2O (Moisture)

0.01-100

Gravimetric procedure after drying at 105C.


Requires 5g sample.

H2O + (Water of Crystallization)

0.01-100

Combustion furnace and infrared spectrometry.


Requires 1g sample.

OA-IR06

14.30

LOI @ 550C

0.01-100

Loss on ignition at 550C. Requires 1g sample.

OA-GRA05a

11.90

LOI @ 1000C

0.01-100

Loss on ignition at 1000C. Requires 1g sample.

OA-GRA05

8.40

Other

25

ANALYTE

RANGE

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Acid Insoluble

0.01%-100%

Acid insoluble content. Requires 1g sample.

OA-GRA04

14.30

pH

0.1-14

pH on 1:10 sample to water ratio. Requires 5g


sample minimum.

OA-ELE03

9.55

Conductivity

1-100,000S/cm

Specific conductivity on 1:10 sample to water


ratio. Requires 5g sample minimum.

OA-ELE04

11.90

Soil pH

0.1-14

Soil pH on 1:1 sample to water ratio. Requires


20g sample minimum.

OA-ELE05

11.90

Soil Conductivity

1-100,000S/cm

Soil conductivity on 1:1 sample to water ratio.


Requires 20g sample minimum.

OA-ELE06

8.35

Paste pH

0.1-14

Paste pH on 10g sample saturated with water.

OA-ELE07

7.20

Isotopic Analysis

Lead Isotopes for Mineral Exploration

ANALYTE

DESCRIPTION

Six isotope ratios


including 204Pb,
206
Pb, 207Pb, and
208
Pb isotopes

Pb isotope ratios by acid digestion and ICP-MS analysis. Total Pb content of the sample is required in advance.
May be run on whole rock pulps.
Aqua Regia Digestion
Four Acid Digestion

CODE

PRICE PER
SAMPLE ($)

PbIS-RAT41
PbIS-RAT61

35.00
32.00

Stable Isotopes
Many important parameters of mineralizing fluids maybe be determined from stable isotope
ratios. The isotopic alteration halo may extend beyond visible mineralogy changes, creating a
larger deposit footprint for easier exploration vectoring.
ANALYTE

DESCRIPTION

C and O in Carbonate Newly developed method offered in partnership with the Mineral Deposit Research Unit (MDRU) at the
Minerals
University of British Columbia. Carbon and oxygen isotopic composition is determined specifically on
carbonate minerals in whole-rock pulps using cavity enhanced absorption Spectrometry.

CODE

PRICE PER
SAMPLE ($)

LS-ISTP01

35.00

OH-ISTP01

110.00 each

S-ISTP01

55.00

(+)-ISTP01

260.00/
element

ISOTOPE METHODS

This fast, robust, low-cost analysis of Pb isotope ratios in standard geochemical samples
was developed in house by ALS Geochemistrys senior technical team. Lead isotope
fingerprints can be used to discriminate between barren lithologies and multiple
generations of alteration fluid flow, providing a new vector to ore deposits. Accuracy of the
ALS method closely matches that of research-grade Pb isotopic analysis, with a precision
and TAT appropriate for routine exploration.

Price does not include sample preparation. Turnaround time 16 days.


O and H in Silicate
Minerals
Sulfur

Specific to clays and silicate minerals. Determination using a complex gas collection procedure and IRMS.
Sample must be supplied as a single-mineral separate.
Price does not include mineral separation. Turnaround time 30 days.
Specific to S minerals such as particular sulfides and sulfates. Determination using TC/EA and IRMS. Sample
must be supplied as a single-mineral separate.
Price does not include mineral separation. Turnaround time 30 days.

Cu, Fe, Mo, Zn

Specific to minerals formed with one of these base metals. Determination using acid digestion and HR-ICPMS. Sample must be supplied as a single-mineral separate. Use element symbol in
place of + when requesting this method.
Price does not include mineral separation. Turnaround time 30 days.

Radiogenic Isotopes
These methods provide insight into provenance and character of fluids and rocks, helping you to
unravel geological history for a more sophisticated understanding of your ore body. In rare cases
these methods can also be used for age dating of minerals or lithological units.
ANALYTE

Pb/Pb

Sm/Nd

DESCRIPTION
May be done on whole rock pulps or on specific Pb-bearing minerals. Measurement by acid digestion
and HR-ICP-MS.
Price does not include mineral separation. Samples may require Hg separation at an additional cost.
Turnaround time 30 days.
May be done on whole rock pulps. Measurement by column separation and HR-ICP-MS.
Price does not include sample preparation. Turnaround time 30 days.

CODE

PRICE PER
SAMPLE ($)

Pb-ISTP01

260.00

Nd-ISTP01

545.00

Geochronology
These methods may be used to date the ages of specific minerals, hydrothermal alteration events,
and emplacement of volcanic-plutonic units. Age constraints on important events can help refine
the deposit model and identify alteration that did not contribute to mineralization.
ANALYTE

DESCRIPTION

Re/Os

Specific to molybdenite. Rock or drill core must be received whole as steel jaw crushing will contaminate
the sample with Re. Age can only be determined for rocks of >0.5 Ma, and the molybdenite separate must
contain >100ppm Re.

CODE

PRICE PER
SAMPLE ($)

Re-ISTP01

1750.00

U-ISTP01

By Quotation

Ar-ISTP01

655.00

Price includes mineral separation and analysis by solvent extraction, column separation and TIMS. Turnaround
time 70 days.
U/Pb

Specific to U-bearing minerals such as zircon, monazite, and uraninite. Thin sections or mineral separates are
analyzed by laser ablation and HR-ICP-MS. Laser ablation averages 40 data points per day; minimum charge
is day.
Prices do not include mineral separation or thin section preparation. Turnaround time 45 days.

Ar/Ar

Done on whole rock samples. Rock and drill core should be submitted intact or crushed only, as sample prep
is included in the price. Measurement by irradiation and step heating in a mass spectrometer.
Price includes sample preparation. Turnaround time approximately 9 months.

26

WHOLE ROCK ANALYSIS

Whole Rock Analysis

The nature of lithophile elements and the matrices in which they occur require fusion methods for
complete dissolution. Both X-Ray Fluorescence (XRF) and ICP-AES instrument finishes can be used
effectively for the major rock-forming elements when following a fusion.
These methods are not suitable for samples with base or precious metals mineralization.
Specific commodities such as iron ore, bauxite, and base metal sulfides should be analyzed
with packages designed for those sample types. Please see the Ores & Commodities section
starting on page 29 for more whole rock analysis options.

14 Element Package by Lithium Borate Fusion and XRF


Minimum sample size is 2g.
ANALYTES AND RANGES (%)
Al2O3

0.01-100

DESCRIPTION

Fe2O3

0.01-100

Na2O

0.01-10

SrO

CODE

PRICE PER SAMPLE ($)

0.01-1.5

BaO

0.01-66

K 2O

0.01-15

P 2O 5

0.01-46

TiO2

0.01-30

CaO

0.01-60

MgO

0.01-50

SO3

0.01-34

LOI

0.01-100

Cr2O3

0.01-10

MnO

0.01-39

SiO2

0.01-100

Fused disc XRF

ME-XRF26*

Furnace or Thermogravimetric Analyzer


(TGA)

OA-GRA05x
ME-GRA05

29.75

Loss on Ignition at 1000C

*Other elements are available on request. Please enquire.

For non-mineralized samples with moderate sulfide content, please request ME-XRF06.

13 Element Package by Lithium Borate Fusion and ICP-AES


Minimum sample size is 2g.
ANALYTES AND RANGES (%)
Al2O3

0.01-100

Fe2O3

0.01-100

DESCRIPTION
Na2O

0.01-100

TiO2

0.01-100

LOI

0.01-100

BaO

0.01-100

K 2O

0.01-100

P 2O 5

0.01-100

CaO

0.01-100

MgO

0.01-100

SiO2

0.01-100

Cr2O3

0.01-100

MnO

0.01-100

SrO

0.01-100

Fused bead, acid digestion and ICP-AES

CODE

PRICE PER SAMPLE ($)

ME-ICP06

29.75

A lithium borate fusion of the sample prior to acid dissolution and ICP-MS analysis provides
the most quantitative analysis approach for a broad suite of trace elements. This technique
solubilizes most mineral species, including those that are highly refractory. Options for adding
the whole rock elements from an ICP-AES analysis from the same fusion or base metals from
a separate four acid digestion are available.

30 Element Package by Lithium Borate Fusion and ICP-MS


Minimum sample size is 1g, or 3g with add-on packages.
ANALYTES AND RANGES (ppm)

DESCRIPTION

Ba

0.5-10,000

Hf

0.2-10,000

Sn

1-10,000

0.5-10,000

Ce

0.5-10,000

Ho

0.01-1,000

Sr

0.1-10,000

Yb

0.03-1,000

Cr

10-10,000

La

0.5-10,000

Ta

0.1-2,500

Zr

2-10,000

Cs

0.01-10,000

Lu

0.01-1,000

Tb

0.01-1,000

Dy

0.05-1,000

Nb

0.2-2,500

Th

0.05-1,000

Er

0.03-1,000

Nd

0.1-10,000

Tm

0.01-1,000

Eu

0.03-1,000

Pr

0.03-1,000

0.05-1,000

Ga

0.1-1,000

Rb

0.2-10,000

5-10,000

Gd

0.05-1,000

Sm

0.03-1,000

1-10,000

Fused bead, acid digestion


and ICP-MS

Combination of Rare Earth & Trace Elements from method ME-MS81 plus whole rock package
by method ME-ICP06.

27

Ag

0.5-100

Co

1-10,000

Mo

1-10,000

Sc

1-10,000

As

5-10,000

Cu

1-10,000

Ni

1-10,000

TI

10-10,000

Cd

0.5-1,000

Li

10-10,000

Pb

2-10,000

Zn

2-10,000

Four acid digestion and ICP-AES

CODE

PRICE PER
SAMPLE ($)

ME-MS81

29.50

ME-MS81d

41.25

ME-4ACD81
Add-on only

7.15

Analyses related to lithogeochemistry, alteration minerals, and trace element mobility are
important tools for understanding ore-forming geological environments. Managing and
interpreting large datasets generated by lithogeochemical techniques, while traditionally
challenging, has been greatly simplified thanks to powerful software tools now available to
geologists and geochemists.

LITHOGEOCHEMISTRY

Lithogeochemistry

No single analytical method is able to encompass the full range of elements required for
effective lithogeochemical investigation. To this end, ALS Geochemistry offers two analytical
packages that are designed to provide comprehensive information for these studies using the
most appropriate techniques for every element; essentially, complete rock characterization.

Complete Characterization
Package

By combining a number of methods into one cost effective package, a complete sample
characterization is obtained. This package combines the whole rock package ME-ICP06
plus carbon and sulfur by combustion furnace (ME-IR08) to quantify the major elements
in a sample. Trace elements including the full rare earth element suites are reported
from three digestions with either ICP-AES or ICP-MS finish: a lithium borate fusion for the
resistive elements (ME-MS81), a four acid digestion for the base metals (ME-4ACD81) and
an aqua regia digestion for the volatile gold related trace elements (ME-MS42). Gold is
analyzed separately see page 13 for methods.
This package is suitable only for unmineralized samples. Minimum sample size is 10g.

ANALYTES AND RANGES (ppm)

CODE

SiO2

0.01-100%

MgO

0.01-100%

TiO2

0.01-100%

BaO

0.01-100%

Al2O3

0.01-100%

Na2O

0.01-100%

MnO

0.01-100%

LOI

0.01-100%

Fe2O3

0.01-100%

K 2O

0.01-100%

P 2O 5

0.01-100%

CaO

0.01-100%

Cr2O3

0.01-100%

SrO

0.01-100%

Ba

0.5-10,000

Gd

0.05-1,000

Sm

0.03-1,000

1-10,000

Ce

0.5-10,000

Hf

0.2-10,000

Sn

1-10,000

0.5-10,000

Cr

10-10,000

Ho

0.01-1,000

Sr

0.1-10,000

Yb

0.03-1,000

Cs

0.01-10,000

La

0.5-10,000

Ta

0.1-2,500

Zr

2-10,000

Dy

0.05-1,000

Lu

0.01-1,000

Tb

0.01-1,000

Er

0.03-1,000

Nb

0.2-2,500

Th

0.05-1,000

Eu

0.03-1,000

Nd

0.1-10.000

Tm

0.01-1,000

Ga

0.1-1,000

Pr

0.03-1,000

0.05-1,000

Ge

5-1,000

Rb

0.2-10,000

5-10,000

Ag

0.5-100

Cu

1-10,000

Ni

1-10,000

Cd

0.5-1,000

Li

10-10,000

Pb

2-10,000

Co

1-10,000

Mo

1-10,000

Sc

1-10,000

As

0.1-250

In

0.005-250

Se

0.2-250

Bi

0.01-250

Re

0.001-250

Te

0.01-250

Hg

0.005-25

Sb

0.05-250

TI

0.02-250

0.01-50%

0.01-50%

ME-ICP06

Sold only as a
complete package.*
ME-MS81

Zn

PRICE PER SAMPLE ($)

CCP-PKG01
70.45
CCP-PKG03
Includes ME-XRF26 instead of
ME-ICP06.
84.30

2-10,000
ME-4ACD81

ME-MS42
ME-IR08

28

ORES AND HIGH GRADE MATERIALS

Ores & High Grade


Materials

Procedures for the evaluation of ores and high grade materials are optimized for accuracy,
precision and recovery of the target element. No single dissolution or analytical method is
suitable for all cases, and ALS Geochemistry provides a wide variety of procedures so the
preferred method can be selected. Choices include acid digestions with either ICP-AES or AAS
finish; XRF determination for resistive elements and minerals that are difficult to decompose or
retain in stable solutions at high concentrations; and classical volumetric methods for very high
grade commodities.
These methods may be triggered automatically as over-range analyses added to multielement geochemistry packages on request. Many other procedures are available; please
contact ALS Geochemistry staff for information.

Aqua Regia Digestion with ICP-AES or AAS Finish


Aqua regia is a powerful solvent for sulfides, which dissolves Ag and base metals but may not
completely dissolve more resistive elements. Minimum sample weight 0.5g.
ANALYTES & RANGES (%)
Ag

1-1,500ppm

Co

0.001-20

Mn

0.01-50

Pb

CODE

PRICE PER SAMPLE ($)

(+)-OG46

8.35 plus 2.35/element

(+)-AA46

5.95 plus 4.75/element

0.001-20

As

0.01-60

Cu

0.001-40

Mo

0.001-10

0.01-10

Cd

0.001-10

Fe

0.01-100

Ni

0.001-10

Zn

0.001-30

Ag

1-1,500ppm

Bi

0.001-30

Fe

0.01-100

Pb

0.001-30

As

0.01-30

Cu

0.001-50

Mo

0.001-10

Zn

0.001-60

+ Add element symbol as prefix to method code.

Four Acid Digestion with ICP-AES or AAS Finish


Four acid digestion breaks down most silicates and all but the most resistive minerals.
Minimum sample weight 0.5g.
ANALYTES & RANGES (%)
Ag

1-1,500ppm

Co

0.0005-20

Mg

0.01-50

Pb

0.001-20

As

0.001-30

Cr

0.002-30

Mn

0.01-50

0.01-50

Bi

0.001-30

Cu

0.001-40

Mo

0.001-10

Zn

0.001-30

Cd

0.001-10

Fe

0.01-100

Ni

0.001-30

Ag

1-1,500ppm

Cu

0.001-50

Mo

0.001-10

Pb

0.001-30

Co

0.001-30

Fe

0.01-100

Ni

0.001-50

Zn

0.001-30

CODE

PRICE PER SAMPLE ($)

(+)-OG62

10.75 plus 2.35/element

(+)-AA62

8.35 plus 4.75/element

+ Add element symbol as prefix to method code.

XRF for Resistive Minerals


Some resistive minerals, particularly those containing Sn, W, Nb or Ta require a fusion
for complete recovery. This method is suitable for samples with <4% sulfides. Minimum
sample weight 5g.
ANALYTES & RANGES (%)
Ba

0.009-45

Ta

0.01-50

Nb

0.01-10

Th

0.01-15

Sb

0.01-50

0.01-15

Sn

0.01-60

0.01-50

Zr

CODE

PRICE PER SAMPLE ($)

(+)-XRF10

14.30 plus 3.55/element

0.01-50

+ Add element symbol as prefix to method code.

Classical Titration Methods


Certain ore deposits naturally have extremely high (>30%) base metal content over short
intervals. Specialized digestions and classical chemistry methods are required to analyze
these samples. Minimum sample weight 1g.

29

ANALYTE

RANGE (%)

DESCRIPTION

Cu

0.01-100

Cu by Titration.

Cu-VOL61

CODE

PRICE PER SAMPLE ($)


41.70

Zn

0.01-100

Zn by Titration.

Zn-VOL50

23.85

Pb

0.01-100

Pb by Titration.

Pb-VOL70

35.70

Fe

0.01-100

Total Fe in Concentrates.

Fe-VOL51

42.60

FeO

0.01-100

FeO (Ferrous Iron).

Fe-VOL05

21.10

Assay determinations in massive sulfides present some specific challenges. ALS Geochemistry
is able to offer a number of approaches including a strongly oxidizing acid digestion, a sodium
peroxide fusion and an XRF package.

Oxidizing Acid Digestion with ICP-AES Finish


This procedure is equivalent to the ICPORE method previously offered by OMAC Laboratories.
The sample is subjected to a highly oxidizing attack with HNO3 , KClO4 and HBr and the final
solution in dilute aqua regia is determined by ICP-AES.
ANALYTES & RANGES (%)
Ag

1-1500ppm

Co

0.001-20

Mn

0.005-50

0.05-50

As

0.005-30

Cu

0.005-40

Mo

0.001-10

Sb

0.005-5

Bi

0.005-30

Fe

0.01-100

Ni

0.001-30

Tl

0.005-1

Zn

0.01-100

Ca

0.01-50

Hg

0.0008-1

0.01-20

Cd

0.001-10

Mg

0.01-50

Pb

0.01-30

CODE

PRICE PER SAMPLE ($)

ME-ICPORE

24.10 complete package,


5 elements 21.75

Sodium Peroxide Fusion with ICP-AES Finish


Sodium peroxide fusions are effective for the decomposition of sulfides, arsenides and many
refractory minerals such as chromite, rutile, ilmenite and titanite. It is the method of choice for
nickel sulfide deposits.
ANALYTES & RANGES (%)
Al

0.01-50

Cr

0.01-30

Mg

0.01-30

0.01-60

As

0.01-10

Cu

0.002-30

Mn

0.01-50

Si

0.1-50

Ca

0.05-50

Fe

0.05-70

Ni

0.002-30

Ti

0.01-30

Co

0.002-30

0.1-30

Pb

0.01-30

Zn

0.002-30

CODE

PRICE PER SAMPLE ($)

(+)-ICP81

36.75 complete package or


11.90 plus 2.35/element

+ Add element symbol as prefix to method code.

Oxidizing Fusion with XRF Finish


High sulfide samples can be analyzed by XRF following a lithium borate fusion with the addition
of a strong oxidizing agent. The following method is suitable for a wide range of elements in
sulfide ores, and other elements are available to report on request please enquire.
ANALYTES & RANGES (%)
Al2O3

0.01-100

La2o3

0.01-50

Sn

0.005-20

As

0.01-10

MgO

0.01-40

Sr

0.01-5

BaO

0.01-66

Mn

0.01-30

Ta

0.002-16.4

Bi

0.01-5

Mo

0.005-2

Th

0.002-5

CaO

0.01-40

Nb

0.005-20

TiO2

0.01-30

Ce02

0.01-50

Ni

0.005-20

0.001-5

Co

0.01-7

P 2O 5

0.01-25

0.01-5.6

Cr

0.01-10

Pb

0.005-20

0.001-15.9

Cu

0.005-20

0.01-20

Zn

0.005-20

Fe

0.01-75

Sb

0.005-20

Zr

0.01-20

K 2O

0.01-6.3

SiO2

0.01-100

Loss on Ignition

Furnace or
Thermogravimetric Analyzer (TGA)

CODE

PRICE PER SAMPLE ($)

ME-XRF15b*

31.50 plus 3.30/element

OA-GRA05x
ME-GRA05

5.25 plus 3.15/temperature

ORES AND HIGH GRADE MATERIALS

Base Metals in Massive


Sulfides

* A method for sulfide concentrates, ME-XRF15c, is also available.

30

COPPER
Copper Methods

New and existing copper deposits are increasingly challenging to develop and mine due
to lower grades and complex mixed ore types. Early geometallurgical investigation of
the potential ore body is crucial for informed decision-making on the economic viability
of many copper projects.

Mineral Selective Methods and Sequential Leaches


Oxidized copper minerals such as malachite, azurite, chrysocolla and portions of cuprite and
tenorite can be leached using sulfuric acid to identify the acid soluble content in copper ores.
Cyanide leach will dissolve the oxides (with the exception of chrysocolla, which is only partially
digested), secondary sulfides like chalcocite and covellite, and bornite. The chalcopyrite
content in ores will remain largely undissolved by either sulfuric acid or cyanide leach. These
mineral-selective leaches and others may be run in sequence on a single sample to semiquantitatively identify the potential recovery by various copper ore processing methods. The
actual amount of each mineral dissolved in each leach may vary depending on the sample
mineralogy, grain size, and other physical characteristics.
ALS Geochemistry provides custom methods using different leach conditions upon request,
including some uncommon leach chemistries with specific applications not listed below.
ANALYTE

RANGE (%)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

Copper Oxides & Carbonates


Cu

0.01-10

Citric acid leach and AAS finish. 0.25g sample weight.

Cu-AA04

11.90

Cu

0.001-10

Sulfuric acid leach and AAS finish. 1g sample weight.

Cu-AA05

11.90

Cu

0.001-100

Sulfuric acid/Na sulfite leach and AAS finish. 1g sample weight.

Cu-AA07n

11.90

Cu-AA08q

12.70

Cu-AA17

17.30

Cu-PKG06LI

35.70

Copper Oxides & Secondary Sulfides


Cu

0.001-100

Sulfuric acid/ferric sulfate leach and AAS finish. 1g sample weight.

Cu

0.001-10

Cyanide leach and AAS finish. 2g sample weight.

Sequential Leach Packages


Cu

Various

Sequential leach using sulfuric acid, cyanide leach and four acid digestion on
the final residue. 0.5g sample weight.

Total Copper Methods


Aqua regia is an effective solvent for copper oxides and sulfides, but copper occurring with
other commodities like molybdenum can be analyzed by four acid digestion for consistency
across data sets.
ANALYTE

31

RANGE (%)

DESCRIPTION

Trace Cu

1-10,000 ppm

Aqua regia digestion and ICP or AAS finish.

Trace Cu

2-10,000 ppm

Four acid digestion and ICP or AAS finish.

Cu Assay

0.001-40
0.001-50

Aqua regia digestion and ICP or AAS finish.

Cu Assay

0.001-40
0.001-50

Native Cu

Cu Concentrate

CODE

PRICE PER SAMPLE ($)

Cu-ICP41
Cu-AA45

5.90 each

Cu-ICP61
Cu-AA61
Cu-OG46
Cu-AA46

8.30 each
10.70 each

Four acid digestion and ICP or AAS finish.

Cu-OG62
Cu-AA62

13.10 each

0.01-100

Copper metallic screen assay by four acid digestion and AAS finish on 1kg pulp
sample.
Screen to 100 microns, duplicate assay on 0.25g of undersize fraction and
assay of entire oversize fraction.

Cu-SCR21

116.00

0.01-100

HNO3-HCl-HF-H 2SO4 acid digestion followed by titration.


Cu-CON02 done in duplicate.

Cu-VOL61
Cu-CON02

41.70
71.45

Unique integration of analytical, metallurgical, mineralogical, and ancillary


testing services, specifically focused on the iron ore sector.
Through the establishment of a large purpose-built facility, ALS has achieved a quantum
expansion of analytical and metallurgical testing capacity in the global iron ore sector.
With industry leading expertise in elemental analysis, metallurgy and mineralogy, the
ALS Group can provide a wide range of iron ore testing, certification and inspection
services to cover complete project life cycles.

ALS Iron Ore Technical Center

26 Rigali Way, Wangara, Western Australia


Australia 6065
T: +61 8 9406 1300
F: +61 8 6305 0367
E: ClientServices.IOTC@alsglobal.com

Iron Ore Procedures

IRON ORE

ALS Iron Ore


Technical Center

XRF Analysis for Iron Ore


X-Ray Fluorescence (XRF) is the method of choice for the analysis of oxide iron ores.
The lithium borate fusion technique, coupled with XRF, offers a robust and repeatable
method consistent with industry requirements. The relatively low flux to sample ratio
offers good sensitivity for the majority of elements and creates a matrix which is not
subject to particle size effects. With very few spectral interferences and high instrument
stability, the XRF method delivers highly accurate and precise results across the full
range of iron oxide ore types.
Loss on Ignition (LOI) is a critical component of iron ore analysis. LOI determination
allows a better understanding of mineral composition of the ore and how it will behave
during processing. Single temperature or multi temperature LOI determinations are
available, and temperatures can be customized as required.

ANALYTES & RANGES (%)


Al2O3

0.01-100

K 2O

DESCRIPTION
0.001-6.3

Sn

0.001-1.5
0.001-1.5

As

0.001-1.5

MgO

0.01-40

Sr

Ba

0.001-10

Mn

0.001-25

TiO2

0.01-30

CaO

0.01-40

Na2O

0.005-8

0.001-5

Cl

0.001-6

Ni

0.001-8

Zn

0.001-1.5

Co

0.001-5

0.001-10

Zr

0.001-1

Cr203

0.001-10

Pb

0.001-2

Total

0.01-110

Cu

0.001-1.5

0.001-5

Fe

0.01-75

SiO2

0.01-100

Loss on Ignition

Fused disc XRF

Furnace or
Thermogravimetric Analyzer
(TGA)

CODE

ME-XRF21n
(normalized)
ME-XRF21u
(un-normalized)

OA-GRA05x
ME-GRA05

PRICE PER SAMPLE ($)

39.40
LOI must be done as part
of this procedure.

5.25 plus 3.15/temperature

Magnetite Analysis Davis Tube Recovery (DTR)


Preparation for analysis of magnetic separates requires a complex protocol involving a staged
wet sieving process and use of a Davis Tube to provide a beneficiated sample representative
of large scale metallurgical processes. Procedures are very specific to individual ore types
encountered. Prior to commencement of any project, it is highly recommended that clients
discuss their requirements with ALS staff to determine the optimum protocol for their
particular ore type. Grind curve confirmation tests including laser sizing, cyclo-sizing and wet
screening are also available.
ANALYTE

CODE

Multi-stage sieving and pulverizing

DTR-PREP

Wash time and mass recovery

DTR-REC

Weight of DTR fractions

WT-DTR

DTR iron recovery

DTR-FeRec

XRF analysis on various DTR fractions


- Head
- Concentrate
- Tails

ME-XRF21h
ME-XRF21c
ME-XRF21t

PRICE PER SAMPLE ($)


By Quotation
By Quotation
39.40 each

Ferrous iron by titration (FeO; 0.01%)

Fe-VOL05

21.10

Magnetic susceptibility

MAG-SUS

11.85

32

URANIUM, RARE EARTHS AND OTHER METALS

Uranium

33

ALS Geochemistry is qualified and experienced in handling NORM samples in every jurisdiction
with active uranium exploration and mining. Were known internationally for leading the
industry in lowest detection limits and innovative solutions, shown in our new UEXP-PKG01
exploration package.

ANALYTE

CODE

PRICE PER SAMPLE ($)

UEXP-PKG01

50.75

ME-MS61u

40.25

U-XRF10

17.85

An exploration package targeted at unconformity-hosted uranium deposits where the ore is in the basin
sedimentary rocks.
Includes full 62 element suite from ME-MS41L. See page 18 for ranges. Includes REEs and Pb isotope
concentrations.
204
Pb, 206Pb, 207Pb, 208Pb 0.005-250ppm
Also includes ultra-trace boron by fusion from B-MS82L.
B 5-10,000ppm
Full 48 element suite from ME-MS61, optimized for U with specific CRMs for superior quality control.
See page 22 for ranges.
Ore grade U assay (0.01%-15%)

Rare Earth Elements

Many rare earth elements (REEs) occur in oxide and silicate minerals particularly resistant to
acid digestion, so fusion is usually the preferred method of decomposition. ALS Geochemistry
offers ICP-MS and XRF determinations of these special commodities. Please see page 27 for a
trace-level method (ME-MS81) appropriate for REE exploration.

Mineralized REEs by ICP-MS


ANALYTES & RANGES (ppm)
Ce*

3-50,000

Ho

0.05-5,000

Rb

1-50,000

Tm

0.05-5,000

Dy*

0.3-5,000

La*

3-50,000

Sm*

0.2-5,000

0.3-5,000

Er

0.2-5,000

Lu

0.05-5,000

Sn

5-50,000

5-50,000

Eu

0.2-5,000

Nb

1-5,000

Ta

0.5-5,000

3-50,000

Gd*

0.3-5000

Nd*

0.5-50,000

Tb*

0.05-5,000

Yb

0.2-5,000

Hf

1-50,000

Pr*

0.2-5,000

Th

0.3-5,000

Zr

10-50,000

CODE

PRICE PER SAMPLE ($)

ME-MS81h

47.25

*These elements may be determined up to 30% by ME-OGREE.

Mineralized REEs by XRF


ANALYTES & RANGES (%)
CeO2

0.01-50

Ho2O2

0.01-10

Sm 2O3

0.01-10

Dy2O3

0.01-10

La2O3

0.01-50

Tb 4O7

0.01-10

Er2O3

0.01-10

Lu2O3

0.01-10

Tm 2O3

0.01-10

Eu2O3

0.01-10

Nd2O3

0.01-10

0.01-10

Gd2O3

0.01-10

Pr6O11

0.01-10

Yb2O3

0.01-10

Furnace or
Thermogravimetric Analyzer (TGA)

Loss on Ignition

Uncommon Metals

ANALYTE

RANGE (ppm)

DESCRIPTION

Be

0.01%-100%

Li

0.005%-10%

Li

CODE

PRICE PER SAMPLE ($)

ME-XRF30

31.50

OA-GRA05x
ME-GRA05

5.25 plus 3.15/temperature

These elements have many high-tech applications in electronics, engineering and


pharmaceuticals. They require specialized digestions and instrument methods for precise and
accurate measurement.
CODE

PRICE PER SAMPLE ($)

Sodium peroxide fusion and ICP finish.

Be-ICP81

11.90

Four acid and ICP finish.

Li-OG63

11.75

10-3000

Lithium brine analysis using ICP-OES. Other elements reported from this method.

ME-ICP15

34.50

5-10,000

NaOH fusion and ICP-MS finish for super trace B.

B-MS82L

19.40

B and
Li

0.02%-100%
0.002%-10%

Na2O2 fusion and ICP finish. B and/or Li may be reported.

ME-ICP82b

34.50
Add 5.00 for Li

Ge

1-500

HNO3 and HF digestion with orthophosphoric acid leach and ICP-MS finish.

Ge-MS66

29.75

Bauxite Analysis

ANALYTES & RANGES (%)


Al2O3

0.01-100

DESCRIPTION

MgO

0.01-40

SrO

0.01-1.5

BaO

0.01-10

MnO

0.01-31

TiO2

0.01-30

CaO

0.01-40

Na2O

0.01-5.3

V 2O 5

0.01-8

Cr203

0.01-10

P 2O 5

0.01-23

Zn

0.01-1.6

Fe2O3

0.01-100

SiO2

0.05-100

ZrO2

0.01-1.5

K 20

0.001-6.3

SO3

0.01-12.5

Total

0.01-110

CODE
ME-XRF13n
(normalized)

Fused disc XRF

ME-XRF13u
(un-normalized)

Furnace or
Thermogravimetric Analyzer (TGA)

Loss on Ignition
Total Organic Carbon (Non Carbonate Carbon)

TOC by Combustion Furnace.

Reactive Silica
Available Alumina

Microwave digestion, chemical


separation/ICP-AES analysis.*

PRICE PER SAMPLE ($)

39.40
LOI determination
must be done as
part of procedure.

OA-GRA05x
ME-GRA05

5.25 plus 3.15/temperature

C-IR17

29.75

Si-LICP01
Al-LICP01

17.85
16.10

*Digestion temperature, caustic strength and sample/caustic weight ratio to be specified by client.

XRF on Other Commodities

OTHER COMMODITIES

X-ray fluorescence (XRF) is the industry-standard analytical method for bauxite analysis.
Results are reported on a dry weight (110C) basis by default. Additional characterization
methods such as organic carbon, reactive silica and available alumina comply fully with CETEM
performance criteria. Multi-screen sizing to determine the optimum screen size for recovery
and subsequent wet beneficiation are also available.

The elements listed are reported by default, but others are available if they are significant in
your deposit. Loss on Ignition (LOI) is an important component of the total analysis.

Nickel Laterite
ANALYTES & RANGES (%)

DESCRIPTION

Al2O3

0.01-100

Fe2O3

0.01-100

Ni

0.005-7.8

Zn

0.001-1.6

CaO

0.01-40

K 2O

0.01-6.3

P 2O 5

0.005-23

Total

0.01-110

Co

0.001-7

MgO

0.01-50

Pb

0.005-1.8

Cr2O3

0.005-10

MnO

0.005-30

SiO2

0.05-100

Cu

0.001-1.6

Na2O

0.01-5.3

TiO2

0.01-30

Fused disc XRF.

Loss on Ignition

CODE
ME-XRF12n
(normalized)
ME-XRF12u
(un-normalized)

PRICE PER SAMPLE ($)


39.40
LOI determination
must be done as
part of procedure.

Furnace or
Thermogravimetric
Analyzer (TGA)

OA-GRA05x
ME-GRA05

5.25 plus 3.15/temperature

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

ME-XRF24

39.40
LOI determination
must be done as
part of procedure.

OA-GRA05x
ME-GRA05

5.25 plus 3.15/temperature

CODE

PRICE PER SAMPLE ($)

Fused disc XRF.

ME-XRF26s

29.75
LOI determination
must be done as
part of procedure.

Furnace or
Thermogravimetric
Analyzer (TGA)

OA-GRA05x
ME-GRA05

5.25 plus 3.15/temperature

Phosphates
ANALYTES & RANGES (%)
Al2O3

0.01-100

K 2O

0.01-10

Na2O

0.01-11

TiO2

0.01-30

CaO

0.01-60

MgO

0.01-50

P 2O 5

0.01-50

Total

0.01-110

Fe2O3

0.01-100

MnO2

0.01-48

SiO2

0.01-100

Fused disc XRF.


Furnace or
Thermogravimetric
Analyzer (TGA)

Loss on Ignition

Chromite and Manganese Ores


ANALYTES & RANGES (%)

DESCRIPTION

Al2O3

0.01-100

Fe2O3

0.01-100

Na2O

0.01-10

TiO2

0.01-30

BaO

0.01-66

K 2O

0.01-15

P 2O 5

0.01-46

Total

0.01-110

CaO

0.01-60

MgO

0.01-50

SO3

0.01-34

Cr2O3

0.01-60

MnO

0.01-80

SiO2

0.05-100

Loss on Ignition

34

CARBON AND SULFUR

Sulfur Methods

The wide variety of sulfur compounds present in many deposits can complicate the
determination of acid drainage potential or oxygenation requirements for ore processing.
Accurate sulfur speciation can be crucial to early identification of recovery and environmental
issues on many projects. Variations on the most common speciation methods can be
implemented to suit your projects specific mineralogy; please contact client services in your
region for more information.
Some ICP-OES methods can report ore grade sulfur content; please see the Ores
& Commodities section for information on packaging sulfur determinations with
multi-element analyses. When total S and a sulfur speciation method are requested
together, a third species may be calculated by difference and reported on the
certificate of analysis. Please indicate if a difference calculation should be included
on sample submission.

Sulfur Determinations
ANALYTE

RANGE (%)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

S (Total)

0.01%-50%

Total sulfur by Leco furnace.

S-IR08

14.30

S (Elemental)

0.01%-100%

Solvent leach and gravimetric finish.

S-GRA07

32.15

S-GRA06a

26.20

S-IR06a

19.05

HCI digestion of sulfates - little to no dissolution of BaSO4 and SrSO4


S (Sulfate)

0.01%-50%

HCI (15%) leach of sulfates, gravimetric finish.

S (Sulfide)

0.01%-50%

HCI (25%) leach of sulfates, Leco furnace.

Sodium carbonate digestion of sulfates - complete dissolution of BaSO4 and SrSO4


S (Sulfate)

0.01%-40%

NaCO3 leach of sulfates, gravimetric finish.

S (Sulfide)

0.01%-50%

NaCO3 leach of sulfates, Leco furnace.

S-GRA06

29.75

S-IR07

29.75

CODE

PRICE PER SAMPLE ($)

Carbon and Sulfur Packages


ANALYTE

RANGE (%)

DESCRIPTION

C (Total) and
S (Total)

0.01%-50%
0.01%-50%

Total carbon and sulfur by Leco furnace.

ME-IR08

19.95

C (Organic) and
S (Sulfide)

0.01%-50%
0.01%-50%

Organic carbon and sulfide sulfur by HCI (25%) leach of carbonates and sulfates, Leco
furnace.

ME-IR06a

26.65

Carbon Methods

Sulfide sulfur may be overstated if BaSO4 or SrSO4 are present.

Carbon has important metallurgical and environmental implications for many types of mineral
deposits. Carbonates may consume acid, impacting leach process design and mine waste
remediation, while preg robbing by organic carbon can interfere with the cyanidation of gold
and silver ores.
When total C and a carbon speciation method are requested together, a third species may
be calculated by difference and reported on the certificate of analysis. Please indicate if a
difference calculation should be included on sample submission.

Carbon Determinations

35

ANALYTE

RANGE (%)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

C (Total)

0.01%-50%

Total carbon by Leco furnace.

C-IR07

14.30

C (Organic)

0.01%-50%

HCl (25%) leach of carbonates, Leco furnace.


Other acid strengths available, please inquire

C-IR06a

19.05

CO2 (Carbonate)

0.2%-50%

HClO4 digestion and CO2 coulometer.

C-GAS05

20.20

C (Graphite)

0.02%-50%

HCl (50%) leach of carbonates, roasting to remove organic carbon, Leco furnace.

C-IR18

33.90

C (Non-Carbonate)

0.02%-100%

Dilute acid digestion follow by combustion furnace.

C-IR17

29.75

C (Carbonate)

0.02%-100%

Carbonate carbon by difference.

C-CAL-15

Requires C-IR07, C-IR17

ACID
Acid-base accounting (ABA), also called static testing, calculates a net neutralization
potential (NNP) representing the ability of a body of rock to produce acid rock drainage or
to consume free acid and neutralize it. The mineralogy of carbonates, sulfates, sulfides and
other rock-forming minerals in the sample will affect the accuracy of the ABA prediction,
so mineralogical knowledge of the sample is an important augmentation to the static ABA
tests. For a more detailed discussion of ABA methodology, please ask our client services
team for more information.
ALS Geochemistry offers a number of options for the determination of the NNP including
the original Sobek method, the Modified Sobek method, and a correction for the presence
of siderite. We also offer the MEND 1991 method in a single package.

Acid-Base Accounting Packages


PACKAGE CODES
ABA-PKG01 (M/S)

ABA-PKG02 (M/S)

ABA-PKG03 (M/S)

ABA-PKG04 (M/S)

ABA-PKG05 (M/S/B)

Sobek Method

77.40

101.90

130.15

121.10

149.35

Modified Sobek (M)

133.50

158.40

186.70

177.60

205.90

Siderite Correction (S)

133.50

158.40

186.70

177.60

205.90

205.90

PARAMETERS
Net Neutralization Potential (NNP)
Maximum Potential Acidity (MPA)
Neutralization Potential (NP) & Fizz
Ratio (NP : MPA)
Paste pH
Total Sulfur
HCl-leachable Sulfate
Sulfide*
Total Sulfate (Carbonate Leach)
Inorganic Carbon (CO2)

MEND Method (B)

BASE ACCOUNTING

Acid-Base Accounting
Procedures

* Sulfide is determined by calculation in these packages. If you would prefer sulfide determined by analysis,
add A to the package code for an additional cost of $20.00.

Net Acid Generation


Net Acid Generation (NAG) provides a quantitative estimation of the amount of acid that can
be generated by mine waste rock or tailings where the NNP does not, provided the rock is
acid-generating and not acid-neutralizing. In order to analyze for metals in the leachate
in addition to the NAG test, a full second leach must be performed and the procedure
will be charged twice.
DESCRIPTION
Net Acid Generation (NAG) - Hydrogen peroxide is used to facilitate the rapid oxidation of sulfide. NAG is
reported in kg H2SO4 /tonne at pH 4.5 and pH 7.0.

Other Acid Rock


Drainage Tests

CODE

PRICE PER SAMPLE ($)

OA-VOL11

119.05

ALS Geochemistry can help you arrange a wide variety of sample preparation protocols,
mineralogical identification, kinetic testing, water analysis, and more for environmental
assessment purposes with our sister company ALS Environmental. Please enquire at your
local lab for more information.

36

CONCENTRATES

Various Elements
in Concentrates

Accurate analysis of concentrate samples is critical for the purchase and sale of commodities.
All control assays are overseen by experienced certified assayers and performed using classical
techniques, analyzed in duplicate at a minimum to assure quality. Umpire assays (analyzed in
triplicate) are also available please enquire.

Precious Metals in Concentrates and Bullions


See page 16 for a complete list.

Base Metals in Concentrates


ANALYTE

RANGE (%)

DESCRIPTION

Zn, Cu, Pb, Mo,


Co, Ni

0.01%-100%

Appropriate digestion and titration or gravimetric finish.

CODE

PRICE PER SAMPLE ($)

(+)-CON02

71.45/element

+ Add element symbol as prefix to method code. More elements are available. Please enquire.

Low-Grade Elements in Concentrates


We also offer methods suitable for high precision analysis at lower concentrations all of the
base metals listed above, in addition to common contaminants:
ANALYTE

RANGE (%)

DESCRIPTION

CODE

PRICE PER SAMPLE ($)

As

0.01%-15%

Four acid digestion and AAS finish.

As-CON01

71.45

Hg

1-10,000ppm

HCl digestion and ICP-OES finish.

Hg-CON01

71.45

20-20,000ppm

KOH fusion and ion selective electrode.

F-CON01

86.40

More elements are available. Please enquire.

Multi-Element
Determinations in
High-Grade Material

ALS Geochemistry has multi-element procedures specifically designed for major, minor and
trace elements in high-grade samples and concentrates. As high-grade samples often have
difficult matrices with many analytical pitfalls, extra care is taken for these methods with
senior staff reviewing the results in detail for quality control.
Below the four-acid digestion and ICP-MS analysis is listed; an aqua regia digestion and ICP-MS
option (ME-MS41c) and a fusion with XRF option (ME-XRF15c) are also available.

ANALYTES & RANGES (ppm)


Ag

0.1-1,000

Fe

0.02%-100%

Ni

2-100,000

Th

2-5,000

Al

0.02%-100%

Ga

0.5-5,000

100-100,000

Ti

0.01%-100%

As

2-100,000

Ge

0.5-5,000

Pb

5-100,000

Tl

0.2-5,000

Ba

50-100,000

Hf

1-5,000

Rb

1-5,000

1-10,000

Be

0.5-10,000

In

0.05-2,500

Re

0.02-500

5-100,000

Bi

0.1-100,000

0.02%-100%

0.05%-10%

1-100,000

Ca

0.05%-100%

La

5-5,000

Sb

0.5-10,000

1-5,000

Cd

0.2-5,000

Li

2-5,000

Sc

1-10,000

Zn

20-100,000

Ce

0.1-5,000

Mg

0.02%-100%

Se

10-10,000

Zr

5-5,000

Co

1-100,000

Mn

10-100,000

Sn

2-5,000

Cr

10,100,000

Mo

0.5-100,000

Sr

2-100,000

Cs

0.5-5,000

Na

0.02%-100%

Ta

0.5-1,000

Cu

2-100,000

Nb

1-5,000

Te

0.5-5,000

Industrial Minerals

37

CODE

PRICE PER SAMPLE ($)

ME-MS61c

238.15

Industrial minerals commonly have highly refractory components requiring aggressive


digestions. These methods are designed to completely dissolve the analytical sub-sample,
leaving no inhomogeneous residual material behind.

ORE/PRODUCT

ANALYTES

DESCRIPTION

Cementitious Materials

Al2O3, CaO, Fe2O3, K 2O, LOI, MgO, Mn 2O3, Na2O, SiO2,


SO3, TiO2

CODE

PRICE PER SAMPLE ($)

Fusion, XRF

ME-XRF26

29.75

Limestone, Dolomite,
Magnesite, Magnesia

CaO, MgO, Al2O3, Fe2O3, SiO2, LOI

Fusion, ICP, AES

ME-ICP86

42.00

Rutile Product

Al2O3, CaO, Cr2O3, Fe2O3, LOI, MgO, MnO, Nb2O5, P2O5,


SiO2, TiO2 V 2O5, ZrO2
(Other elements available on request)

Fusion, XRF

ME-XRF31r

36.75 plus 21.00/element

Zircon Product

Al2O3, CaO, Fe2O3, HfO2 , LOI, MgO, P2O5, SiO2, TiO2, ZrO2,
Fusion, XRF
(Other elements available on request)

ME-XRF31z

36.75 plus 21.00/element

Ilmenite Product

Al2O3, CaO, Cr2O3, Fe, LOI, MgO, MnO, Nb2O5, P2O5, SiO2,
TiO2, V 2O5, ZrO2
(Other elements available on request)

Fusion, XRF

ME-XRF31i

36.75 plus 21.00/element

Intermediate Plant Flows

Al2O3, CaO, Cr2O3, Fe2O3, LOI, MgO, MnO, Nb2O5, P2O5,


SiO2, TiO2, V 2O5, ZrO2
(Other elements available on request)

Fusion, XRF

ME-XRF31h

36.75 plus 21.00/element

ALS Mineralogy

ALS Minerals has a market leading position in the range and capabilities of our
automated mineralogy equipment, which includes the Mineral Liberation Analyzer
(MLA), QEMSCAN, X-ray Diffraction, ParticleSCAN and HyLogger.
The technology can be utilized to add value to a wide range of commodities including
precious and base metals, rare earth elements, mineral sands, coal, iron ore, graphite
and phosphate deposits. The technology is also applicable to the management of
smelters and undertaking of environmental assessments.
Access to state-of-the-art technology and a highly trained technical team ensures your
requirements are understood and you are provided with relevant, representative and
high-quality quantitative data.

Mineralogical data available from our range of technologies include:


yy
yy
yy
yy
yy
yy
yy

Mineral species, compositions and abundances


Mineral grain & particle size distributions
Elemental distributions
Mineralogical limiting grade recovery curves
Liberations & locking and mineral association
Textural information and color-coded particle images
Rare and trace mineral quantification and high resolution photomicrographs
for rare phases

ALS MINERALOGY

ALS Minerals provides quantitative mineral analysis for the exploration, mining,
metallurgical and environmental sectors. Our integrated mineralogical and metallurgical
services provide you with the tools to maximize productivity and efficiency of
exploration projects, plant and flow sheet design and optimization, mining, production,
marketing and rehabilitation processes.

The costs presented below are only indicative. Contact mineralogy@alsglobal.com to


determine methods and pricing specific to your project.
ANALYTE

DETAILS

Precious Metals,
PGMs, REE and U
Mineralogy

Mineral identification,
distribution of elements,
grain sizes and relationship
to host minerals.

Process Plant
and Ore samples
for a range of
commodities

Basic to detailed analyses


tailored for commodity,
ore type and client
requirements

RANGE OF SERVICE

PRICE ($)*

High resolution Field Emission Gun (FEG) system to detect grains to ~0.2m.

500.00 - 650.00

Standard MLA precious metals search to detect grains to ~1-5m.

400.00 - 550.00

XMOD - Mineral list with abundances (to ~0.1-0.5wt%), elemental distributions + basic
report.

350.00 - 450.00

XBSE - Add grain/particle size, locking and liberation data, surface mineralogy, textures and
images.

400.00 - 900.00

Analysis of low-grade tails samples to characterize losses.

400.00 - 550.00

*Pricing indicative for analysis of 1 polished mount excluding crushing, sizing and chemical assays.
Reporting not included unless specified (POA).

38

QUALITY STATEMENT AND ACCREDITATION

Quality Management
Systems

ALS Geochemistry believes that one of the foremost requirements of our business
is providing exceptional quality assays to our clients. We achieve this through
strategically designed processes and a global quality management system that meets
all requirements of International Standards ISO/IEC 17025:2005 and ISO 9001:2015.
All major ALS Geochemistry analytical laboratories are accredited to ISO/IEC 17025:2005
for specific analytical procedures.
The ALS quality program includes quality control steps through sample preparation and
analysis, inter-laboratory test programs, and regular internal audits. It is an integral
part of day-to-day activities, involves all levels of ALS staff and is monitored at top
management levels.

ISO 17025:2005 Accredited


Methods & ISO 9001:2008
Registration in Australia

ISO 17025:2005 Accredited


Methods in South Africa

ISO 17025:2005
Accredited Methods
in North America

ISO 17025:2005
Accredited Methods
in Romania

ISO 17025:2005 Accredited Methods in Russia.

ISO 17025:2005
Accredited Methods
in New Caledonia

ISO 17025:2005 Accredited


Methods & ISO 9001:2015
Registration in Peru

ISO 17025:2005
Accredited Methods
in Turkey

ISO 17025:2005
Accredited Methods
in Mongolia

ISO 17025:2005
Accredited Methods
in Kazakhstan

ISO 17025:2005 Accredited Methods & ISO 9001:2015


Registration in Kyrgyz Republic

ISO 17025:2005 Accredited Methods & ISO 9001:2015


Registration in China

ISO 9001:2015
Registration in
Chile & Argentina

ISO 17025:2005
Accredited Methods
in Ireland

ISO 9001:2015
Registration
in Brazil

ISO 9001:2015
Registration
in Spain

ISO 9001:2015
Registration in Laos

Please contact us for details regarding the scope of ISO registration at individual laboratories.

Open Lab Initiative

The Open Lab Initiative is about enabling complete confidence in the accuracy of data
produced by ALS Geochemistry through transparency in the laboratory process.
Through the Open Lab Initiative, we provide access to all of your results in perpetuity and
the ability to track sample status in real time through Webtrieve, our on-line interface to
laboratory data. Webtrieve also displays complete chain of custody audit trails, important
QC data, and standard reference material control charts relevant to your samples. Please ask
your local laboratory to have a Webtrieve account set up for you, or request one through
our convenient online form:
http://www.alsglobal.com/en/Our-Services/Minerals/Geochemistry/Webtrieve

39

Selected Terms & Conditions

b) Notwithstanding any other provision in this Agreement,


the cumulative liability of ALS under this Agreement to the
Client and any third party is limited for any claim for loss
or damage whatsoever, whether arising in tort or contract
or any other cause of action, to the value of the Services
provided by ALS to the Client.
c) Without limiting the generality of clauses 4.a) and 4.b), it is
agreed that, to the full extent permitted by any applicable
laws having jurisdiction, ALS will not be liable to the Client
or any other person for any special, indirect or Consequential
Loss arising from the Clients use of, reliance on, or benefit
of, the Services or any ALS Report.
d) The Client acknowledges that during the performance of the
Services, any samples supplied by, or on behalf of, the Client
or parts thereof may be altered, lost, damaged or destroyed.
ALS will not be liable whatsoever to the Client or any third
party for any samples so altered, lost, damaged or destroyed.
5. Termination
a) ALS may suspend or terminate its obligations under this
Agreement if (a) monies payable to ALS by the client are
outstanding 60 days or more (unless otherwise agreed) after
the date of invoice, (b) other substantial breach by the Client
of their obligations under the Agreement, which breach is
not remedied within 30 days of written notice from ALS
requiring the breach to be remedied, (c) by giving the Client
60 days written notice of ALSs intention to terminate.
b) The Client may terminate its obligations under this
Agreement in the event of a substantial breach by ALS of its
obligations under the Agreement, which breach has not been
remedied within 30 days of written notice from the Client to
ALS requiring the breach to be remedied.
c) If ALS, acting reasonably, suspects that the Client is insolvent
or is having difficulties paying its debts as and when they
become due, or the Client is insolvent, ALS may give written
notice to the Client of ALSs intention to immediately suspend
or terminate is obligations under this Agreement.
d) In the event of termination, ALS is entitled to be paid for all
work performed before the date of termination and for any
unavoidable commitments entered into by ALS before the
date of termination.
6. Confidential Information
a) Neither ALS nor the Client will disclose Confidential
Information of the other party to any third party without the
prior written consent of the other party, unless required by
law or the rules of a relevant stock exchange.
b) ALS and the Client will only use Confidential Information of
the other party for the purpose of the supply of the Services.

TERMS AND CONDITIONS

1. Terms and Conditions


Complete Terms and conditions of service are included with
each service quotation provided to clients. The following lists
some of the key terms and conditions that will be applicable
to every quotation for work.
2. Provision of Services
a) The Client acknowledges that it is the Clients sole
responsibility to make its own assessment of the suitability
for any purpose of the Services, detection limits and
confidence intervals inherent in ALSs standard testing
methodology, the ALS Report and its contents.
b) If the Client requires the Services to be performed by specific
test method, or requires detection limits and/or confidence
intervals different to those inherent in ALSs standard testing
methodology, then the Client must instruct ALS of such a
variation prior to ALS performing the Services.
3. Fees and Payment
a) ALS reserves the right to review prices at any time if
significant changes to ALSs costs are incurred that are
beyond ALSs control. Such changes may include, but
are not limited to, changes in legislative requirements,
Client variations to sample numbers, analytes requested,
turnaround required, or reporting requirements.
b) Payment terms are 30 days from the date of invoice (Due
Date), unless negotiated otherwise prior to the placement of
an order or submission of samples. Any such variance from
the standard payment terms must be stipulated separately in
writing in the Agreement.
c) All prices quoted by ALS are exclusive of GST (or other value
added tax if relevant) unless stated otherwise.
d) All fees due and payable after the Due Date (Outstanding
Amount) will be subject to the payment of interest at a rate
of 1.5% per month of the Outstanding Amount from the Due
Date up to and including the date of payment, unless ALS
and the Client otherwise agree in writing.
e) The Client will indemnify ALS for any fees incurred by ALS to
recover the Outstanding Amount, including any solicitor fees,
or collection agency fees.
4. Limitation of Liability
a) To the full extent permitted by law, ALS excludes all
warranties, terms, conditions or undertakings (Terms),
whether expressed or implied, in relation to the Services, the
ALS Report, or its contents. Where any legislation implies any
Terms in this Agreement that cannot be modified or excluded
then, such Terms shall deem to be included. However, to the
full extent permitted by law, ALSs liability to the Client for
any breach of any Terms that cannot be excluded by law is
limited at ALSs option to the re-performance of the Services
or the refund of the fee for the Services.

Please refer to the ALS Website for full Terms and Conditions:
http://www.alsglobal.com/en/Our-Services/Minerals/Geochemistry/Downloads

40

GLOBAL LOCATIONS
ALS Geochemistry is the leading full-service provider of analytical geochemistry
services to the global mining industry. Our integrated network of over 70 laboratories
around the world ensures consistent quality and dependable client service wherever
we might meet you. Our services are available through any one of the many general
service laboratories listed on these pages. We also provide custom services for on-site
laboratory and sample preparation facilities, as well as mobile laboratories and sample
preparation installations.
Visit our website for complete location details at www.alsglobal.com/locations.
ARGENTINA
Mendoza
Tel: +54 261 431 9880
Email: alsargentina@alsglobal.com

AUSTRALIA

Perth Iron Ore Technical Center


Tel: +61 8 9406 1300
Email: alsironore@alsglobal.com

Adelaide
Tel: +61 8 8359 0890
Email: alsminerals.adelaide@alsglobal.com

Townsville
Tel: +61 7 4796 0600
Email: alsminerals.townsville@alsglobal.com

Alice Springs
Tel: +61 8 8952 6020
Email: alsminerals.alicesprings@alsglobal.com

BOLIVIA
Oruro
Tel: +591 2 527 8235
Email: alsbolivia@alsglobal.com

CAMBODIA
Phnom Penh
Tel: + 855 23 729 236
Email: alsminerals.phnompenh@alsglobal.com

CAMEROON
Yaounde
Tel: +237 2218 2540
Email: alsm.yaounde@alsglobal.com

CANADA
ClientServicesECAN@alsglobal.com
ClientServicesWCAN@alsglobal.com

BRAZIL

Kamloops
Tel: +1 250 573 5700
Email: alsm.kamloops@alsglobal.com

Burnie
Tel: +61 3 6431 6333
Email: alsminerals.burnie@alsglobal.com

Belo Horizonte
Tel: +55 31 3045 8400
Email: alsbrasil@alsglobal.com

Sudbury
Tel: +1 705 560 7225
Email: alsm.sudbury@alsglobal.com

Kalgoorlie
Tel: +61 8 9021 1457
Email: alsminerals.kalgoorlie@alsglobal.com

Goiania
Avenida Anhanguera
Tel: +55 62 3088 4800
Email: alsbrasil@alsglobal.com

Terrace
Tel: +1 250 635 3309
Email: alsm.terrace@alsglobal.com

Brisbane
Tel: +61 7 3243 7222
Email: alsminerals.brisbane@alsglobal.com

Mount Isa
Tel: +61 7 4740 1700
Email: alsminerals.mtisa@alsglobal.com
Orange
Tel: +61 2 6393 1100
Email: alsminerals.orange@alsglobal.com

41

Perth
Tel: +61 8 9347 3222
Email: alsminerals.perth@alsglobal.com

BURKINA FASO
Ouagadougou
Tel: +226 5035 6077
Email: alsm.ouagadougou@alsglobal.com

Thunder Bay
Tel: +1 807 475 3329
Email: alsm.thunderbay@alsglobal.com
Timmins
Tel: +1 705 360 1987
Email: alsm.timmins@alsglobal.com
Val dOr
Tel: +1 819 825 0178
Email: alsm.valdor@alsglobal.com

Whitehorse
Tel: +1 867 633 4746
Email: alsm.whitehorse@alsglobal.com
Yellowknife
Tel: +1 867 873 5159
Email: alsm.yellowknife@alsglobal.com

CHILE
Antofagasta
Tel: +56 55 289 2113
Email: alschile@alsglobal.com

LAOS

RUSSIA

Pakse
Tel: + 856 31 900 472
Email: alsminerals.vientiane@alsglobal.com

Chita
Tel: +7 3022 368038
Email: chita.office@alsglobal.com

Vientiane
Tel: +856 21 31 3438
Email: alsminerals.vientiane@alsglobal.com

Moscow
Tel: +7 495 419 0474
Email: alsm.moscow@alsglobal.com

LIBERIA

SAUDI ARABIA

Monrovia
Tel: +233 244 314509
Email: alsm.monrovia@alsglobal.com

Jeddah
Tel: +966 12 6361199
Email: alsjd.lab@alsarabia.com

MALI

SERBIA

Copiapo
+56 52 254 3570
Email: alschile@alsglobal.com

Bamako
Tel: +223 223 6949
Email: alsm.bamako@alsglobal.com

La Serena
Tel: +56 51 267 2783
Email: alschile@alsglobal.com

MAURITANIA

Santiago Mineral Services Center


Tel: +56 2 2654 6100
Email: Santiago.MineralServices@alsglobal.com

CHINA
Guangzhou
Tel: +86 20 3687 5966
Email: alsgz@alsglobal.com

COLOMBIA
Medellin
Tel: +57 4 306 9122
Email: alscolombia@alsglobal.com

ECUADOR

Nouakchott
Tel: +222 45290034
Email: alsm.nouakchott@alsglobal.com

MEXICO

ClientServicesMEX@alsglobal.com
Chihuahua
Tel: +52 614 417 9728
Email: alsm.chihuahua@alsglobal.com
Guadalajara
Tel: +52 33 3619 7438
Email: alsm.guadalajara@alsglobal.com
Hermosillo
Tel: +52 662 218 4403
Email: alsm.hermosillo@alsglobal.com

Bor
Tel: +381 648243340
Email: alsm.bor@alsglobal.com

SOUTH AFRICA

ClientServicesAfrica@alsglobal.com
Johannesburg
Tel: +27 11 608 0555
Email: alsm.johannesburg@alsglobal.com

SPAIN
Seville
Tel: +34 9555 13 035
Email: alssv.lab@alsglobal.com

SWEDEN
Mal
Tel: +46 70 565 4728
Email: alsms.lab@alsglobal.com

Quito
Tel: +59 32 247 6475
Email: alschemex-ecuador@andinanet.net

Zacatecas
Tel: +52 492 768 1474
Email: alsm.zacatecas@alsglobal.com

Pite
Tel: +46 911 65 800
Email: alspi.lab@alsglobal.com

ETHIOPIA

MONGOLIA

TANZANIA

Addis Ababa
Tel: +251 9454 36 909
Email: alsm.addisababa@alsglobal.com

Ulaanbaatar
Tel: +976 11 343882
Email: alsmongolia@alsglobal.com

Mwanza
Tel: +255 754 302047
Email: alsm.mwanza@alsglobal.com

FIJI

MYANMAR

TURKEY

Suva
Tel: +67 9336 4288
Email: alsminerals.suva@alsglobal.com

Mandalay
Tel: +95 2515 2036
Email: alsminerals.mandalay@alsglobal.com

Izmir
Tel: +90 232 281 71 10
Email: alsiz.lab@alsglobal.com

FINLAND

NAMIBIA

USA

Outokumpu
Tel: +358 50 415 28 12
Email: alsot.lab@alsglobal.com

Swakopmund
Tel: +264 644 06498
Email: alsm.swakopmund@alsglobal.com

GHANA

NEW CALEDONIA

Kumasi
Tel: +233 54 444 4440
Email: alsm.kumasi@alsglobal.com

Noumea
Tel: +687 44 1580
Email: alsminerals.noumea@alsglobal.com

IRELAND

PERU

Loughrea
Tel: +353 91 841 741
Email: alsm.loughrea@alsglobal.com

Arequipa
Tel: +51 54 46 3649
Email: alsperu@alsglobal.com

IVORY COAST

Cusco
Tel: +51 84 23 3406
Email: alsperu@alsglobal.com

Yamoussoukro
Tel: +225 071 74445
Email: alsm.bamako@alsglobal.com

KAZAKHSTAN
Karaganda
Pustynnoye
Ust-Kamenogorsk
Tel: +7 7232 527 096
+7 7779 701 666
email: alsm.kazlab@alsglobal.com

GLOBAL LOCATIONS

Vancouver
Tel: +1 604 984 0221
Email: alsm.vancouver@alsglobal.com

ClientServicesUSA@alsglobal.com
Elko
Tel: +1 775 738 2054
Email: alsm.elko@alsglobal.com
Fairbanks
Tel: +1 907 452 2188
Email: alsm.fairbanks@alsglobal.com
Reno
Tel: +1 775 356 5395
Email: alsm.reno@alsglobal.com
Tucson
Tel: +1 520 747 3218
Email: alsm.tucson@alsglobal.com

Lima
Tel: +51 1 574 5700
Email: alsperu@alsglobal.com

ROMANIA
Rosia Montana
Tel: +40 258 780 395
Email: alsrm.lab@alsglobal.com

KYRGYZ REPUBLIC
Kara Balta
Tel: +996 3133 61925
Email: alsm.karabalta@alsglobal.com

42

Geochemistry

www.alsglobal.com

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