AMINO AXIT

AMINO AXIT
I NH NGHA, CU TO V DANH PHP
1. nh ngha
- Amino axit l loi hp cht hu c tp chc m phn t cha ng thi nhm amino (NH2) v nhm cacboxyl
(COOH)
Cng thc tng qut
(H2N)a R (COOH)b
a, b 1
(H2N)a CxHy (COOH)b
a, b, x 1
y+a + b 2x+2
2. Danh php
a) Tn thay th: axit + v tr + amino + tn axit cacboxylic tng ng. V d:
H2NCH2COOH: axit aminoetanoic ; HOOC[CH2]2CH(NH2)COOH: axit 2-aminopentanioic
b) Tn bn h thng: axit + v tr ch ci Hi Lp (, , , , , ) + amino + tn thng thng ca axit cacboxylic tng
ng. V d:
CH3CH(NH2)COOH : axit -aminopropionic
H2N[CH2]5COOH : axit -aminocaproic
H2N[CH2]6COOH: axit -aminoenantoic
c) Tn thng thng: cc amino axit thin nhin (-amino axit) u c tn thng. V d:
H2NCH2COOH c tn thng l glyxin (Gly) hay glicocol

3. Cu to phn t
- Trong phn t amino axit, nhm NH2 v nhm COOH tng tc vi nhau to ion lng cc. V vy amino axit kt
tinh tn ti dng ion lng cc
- Trong dung dch, dng ion lng cc chuyn mt phn nh thnh dng phn t

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AMINO AXIT

II TNH CHT VT L
Cc amino axit l cc cht rn khng mu, v hi ngt, d tan trong nc v chng tn ti dng ion lng cc (mui
ni phn t), nhit nng chy cao (v l hp cht ion):
III TNH CHT HA HC
1. Tnh cht axit baz ca dung dch amino axit
a) Tc dng ln thuc th mu: (H2N)a R (COOH)b. Khi:
- a = b th amino axit trung tnh, qu tm khng i mu
- a > b th amino axit c tnh baz, qu tm ha xanh
- a < b th amino axit c tnh axit, qu tm ha
b) Tnh cht lng tnh:
- Tc dng vi dung dch baz (do c nhm COOH)
H2NCH2COOH + NaOH H2NCH2COONa + H2O
hoc: H3N+CH2COO + NaOH H2NCH2COONa + H2O
- Tc dng vi dung dch axit (do c nhm NH2)
H2NCH2COOH + HCl ClH3NCH2COOH
hoc: H3N+CH2COO + HCl ClH3NCH2COOH
2. Phn ng este ha nhm COOH
3. Phn ng ca nhm NH2 vi HNO2
H2NCH2COOH + HNO2 HOCH2 COOH + N2 + H2O
axit hiroxiaxetic
4. Phn ng trng ngng
- Do c nhm NH2 v COOH nn amino axit tham gia phn ng trng ngng to thnh polime thuc loi poliamit
- Trong phn ng ny, OH ca nhm COOH phn t axit ny kt hp vi H ca nhm NH2 phn t axit kia to
thnh nc v sinh ra polime
- V d:

IV - NG DNG
- Amino axit thin nhin (hu ht l -amino axit) l c s kin to nn cc loi protein ca c th sng
- Mui mononatri ca axit glutamic c dng lm m chnh (hay bt ngt)
- Axit -aminocaproic v axit -aminoenantoic l nguyn liu sn xut t tng hp (nilon 6 v nilon 7)
- Axit glutamic l thuc h tr thn kinh, methionin (CH3SCH2CH2CH(NH2)COOH) l thuc b gan
Bi tp l thuyt
Ch : ng phn
2x 2 t y
- Cng thc bt bo ha (s lin kt + v) ca CxHyOzNt:
2
Cng thc ch ng khi gi thit tt c cc lin kt u l lin kt cng ha tr, i vi hp cht ion th cng thc
2.2 2 1 7
0 nhng trong phn t CH3COONH4 lun 1 lin kt
khng cn ng na. V d CH3COONH4 c
2

Cng thc phn t CxHyO2N c cc ng phn cu to mch h thng gp:

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AMINO AXIT
- Amino axit H2NRCOOH
- Este ca amino axit H2NRCOOR
- Mui amoni ca axit ankanoic RCOONH4 v RCOOH3NR
- Hp cht nitro RNO2
V d 1: Tng s ng phn amino axit , este , mui amoni , ng phn dn xut nitro c CTPT C3H7O2N.
A.2
B.6
C.7
D.8
Vd1: cng thc C4H9NO2 c bao nhiu ng phn mch h tc dng NaOH to ra NH3
A.2
B.3
C.4
D.5
Vd2: cng thc C4H9NO2 c bao nhiu ng phn mch amino axit
A.2
B.3
C.4
D.5
Bi tp vn dng
Cu 1: ng vi CT C3H7O2N c bao nhiu ng phn amino axit ?
A.2
B.3
C.4
D.5
Cu 2: Hp cht khng lm i mu giy qu m l :
A.CH3NH2 B.C6H5ONa C.H2N CH2 CH(NH2) COOH D. H2NCH2 COOH
Cu 3: Cht X c CT l C3H7O2N . X c th tc dng vi NaOH , HCl v lm mt mu dd Br. CT ca X l:
A.CH2 = CH COONH4
B.CH3CH(NH2)COOH
C.H2NCH2CH2COOH
D.CH3CH2CH2NO2
Cu 4: dd cht no sau y ko lm chuyn mu qu tm. ?
A.H2N(CH2)2CH(NH2)COOH.
B.CH3CH(OH)COOH
C.H2NCH2COOH
D.C6H5NH3Cl
Cu 5: Axit glutamic (HCOO(CH2)2CH(NH2)COOH) l cht
A. Ch c tnh axit
B.ch c tnh bazo
C.Lng tnh
D.trung tnh.
Cu 6: Cho cc loi hp cht : amino axit(X) , mui amoni ca axit cacboxylic(Y) , amin(Z) este ca amino axit(T) ,
dy gm cc hp cht u p vi NaOH v dd HCl l :
A.X, Y,Z , T
B.X,Y,T
C.X,Y,Z
D.Y,Z,T
Bi 25: Hy sp xp cc cht sau y theo trnh t tnh baz tng dn t tri sang phi: amoniac, anilin, p-nitroanilin, pnitrotoluen, metylamin, imetylamin.
A.C6H5NH2 < O2NC6H4NH2 < H3CC6H4NH2 < NH3 < CH3NH2 < (CH3)2NH
B.O2NC6H4NH2 < C6H5NH2 < H3CC6H4NH2 < NH3 < CH3NH2 < (CH3)2NH
C.O2NC6H4NH2 < H3CC6H4NH2 < C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH
D. Tt c u sai
Bi 26: t chy ht a mol mt aminoaxit c 2a mol CO2v a/2mol N2. Aminoaxit trn c cng thc cu to l:
A.H2NCH2COOH
B.H2N(CH2)2COOH
C.H2N(CH2)3COOH
D.H2NCH(COOH)2
Bi 50: Cht no sau y khng kh nng tham gia phn ng trng ngng :
A. CH3CH(NH2)COOH
B. HCOOCH2CH2CH2NH2
C. CH3CH(OH)COOH
D. HOCH2 - CH2OH
Cu 1. Pht biu no di y v amino axit l khng ng?
A. Amino axit l hp cht hu c tp chc, phn t cha ng thi nhm amino v cacboxyl.
B. Hp cht H2NCOOH l amino axit n gin nht
C. Amino axit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-).
D. Thng thng dng ion lng cc l dng tn ti chnh ca amino axit.
Cu 2. . Tn gi ca amino axit no di y l ng?

A. H2N CH2 COOH (glixerin)

B. CH3 CH COOH(anilin)
NH2
D. HOOC [CH2]2 CH COOH

C. CH3 CH CH COOH(valin)
NH2
(axit glutaric)
CH3 NH2
Cu 3. . Khng nh v tnh cht vt l no ca amino axit di y khng ng?

A. Tt c u l cht rn

B. Tt c u l tinh th, mu trng

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AMINO AXIT
C. Tt c u tan trong nc
D. Tt c u c nhit nng chy cao
Cu 4. . Amino axit khng th phn ng vi loi cht no di y?
A. Ancol
B. Dung dch brom C. Axit (H+) v axit nitr
D. Kim loi, oxit baz, baz v mui
Cu 77. Cho dung dch cha cc cht sau:
C6H5 - NH2 (X1) (C6H5 l vng benzen); CH3NH2 (X2) ; H2N - CH2 - COOH (X3) ;
HOOC - CH2- CH2- CH(NH2)- COOH (X4) ; H2N - (CH2)4- CH(NH2)- COOH (X5)
Nhng dung dch lm giy qu tm ho xanh l:
A. X1 ; X2 ; X5.
B. X2 ; X3 ; X4.
C. X2 ; X5.
D. X3 ; X4 ; X5.
Cu 92. Axit - Aminopropionic tc dng c vi tt c cc cht trong dy no sau y :
A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2N-CH2-COOH
B. HCl, NaOH, CH3OH c mt HCl ,, H2N-CH2-COOH , Cu
C. HCl , NaOH, CH3OH c mt HCl , H2N-CH2-COOH
D. HCl, NaOH, CH3OH c mt HCl ,, H2N-CH2-COOH , NaCl
Cu 93. Cng thc tng qut ca cc Aminoaxit l :
A. R(NH2) (COOH)
B. (NH2)x(COOH)y
C. R(NH2)x(COOH)y
D. H2N-CxHy-COOH
Cu 94. ng dng no ca amino axit di y c pht biu khng ng?
A. Amino axit thin nhin (hu ht l -amino axit) l c s kin to protein ca c th sng.
B. Mui dinatri glutamat l gia v thc n (gi l bt ngt hay m chnh).
C. Axit glutamic l thuc b thn kinh, methionin l thuc b gan.
D. Cc amino axit (nhm amin v tr s 6, 7, ...) l nguyn liu sn xut t nilon.
Cho s chuyn ho sau:
NH3
HNO2
3OH / HCl
Alanin +CH

X
Y
Z
Cht Z l
A. CH3 CH(OH) COOH.
B. CH3 CH(OH) COOCH3.
C. H2N CH2 COOCH3.
D. H2N CH(CH3) COOCH3
ng dng no ca aminoaxit di y khng ng?
A. Aminoaxit thin nhin (hu ht l - aminoaxit) l c s kin to nn cc loi protein ca c th sng.
B. Cc axit amin c nhm NH2 t v tr s 6 tr ln l nguyn liu sn xut t nilon.
C. Mui inatri glutamat dng lm gia v thc n (gi l m chnh hay bt ngt).
D. Axit glutamic l thuc b thn kinh.
Cho dy chuyn ho sau:
HCl
Glyxin
+NaOH

Z
X
NaOH
Glyxin +HCl

T
Y
X v Y ln lt l
A. u l ClH3NCH2COONa.
B. ClH3NCH2COOH v ClH3NCH2COONa.
C. ClH3NCH2COONa v H2NCH2COONa.
D. ClH3NCH2COOH v H2NCH2COONa.
Cho Tirozin (HOC6H4CH2CH(NH2)COOH) (X) phn ng vi cc cht sau, trng hp no phng trnh ho hc vit
khng ng:
C6H4 CH2 CH(COOH)
NH3Cl +H2O
A. X +2HCl Cl
B. X +2NaOH
C. X +HNO2

NaOC6H 4CH2CH(NH 2)COONa +2H2O

HO
C6H4 CH2 CH(OH)COOH +N 2 +H2O

D. X +C2H5OH
HO C6H4 CH2 CH(NH2)COOC2H5 +H2O
Nhn nh no sau y khng ng?
A. Cc aminoaxit l nhng cht rn, c nhit nng chy cao v d tan trong nc v chng tn ti dng ion
lng cc.
B. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc H3N+RCOO-.
C. Aminoaxit l hp cht tp chc m phn t cha ng thi nhm cacboxyl v nhm amino.
khHCl

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AMINO AXIT
D. Nhit nng chy ca H2NCH2COOH > CH3(CH2)3NH2 > CH3CH2COOH.
Cht X c cng thc phn t C3H7O2N. X c th tc dng vi NaOH, HCl v lm mt mu dung dch Brom. Cng
thc cu to ca X l
A. CH2 = CHCOONH4.
B. CH3CH(NH2)COOH.
C. H2NCH2CH2COOH.
D. CH3CH2CH2NO2.
Cu 1: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit
(T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l
A. X, Y, Z, T
B. X, Y, T.
C. X, Y, Z.
D. Y, Z, T.
Cu 2: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht
lng trn l
A. dung dch phenolphtalein. B. nc brom.
C. dung dch NaOH.
D. giy qu tm.
Cu 3: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l:
A. anilin, metyl amin, amoniac.
B. amoni clorua, metyl amin, natri hiroxit.
C. anilin, amoniac, natri hiroxit.
D. metyl amin, amoniac, natri axetat.
Cu 4: Pht biu khng ng l:
A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu
c axit axetic.
B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c
phenol.
C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c
anilin.
D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li
thu c natri phenolat.
Cu 6: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht
lng trn l
A. giy qu tm.
B. nc brom.
C. dung dch NaOH.
D. dd phenolphtalein.
Cu 7: Pht biu khng ng l:

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AMINO AXIT
+

A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc [NH

3 -CH2-COO ]
B. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt C. Aminoaxit l hp cht hu c tp
chc, phn t cha ng thi nhm amino v nhm cacboxyl.
D. Hp cht H2 N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin).
Cu 8: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2 )-COOH,
ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa.
S lng cc dung dch c pH < 7 l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 9: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn
ng kt thc thu c sn phm l:
A. H N-CH -COOH, H N-CH -CH -COOH.
B. H N-CH -COOHCl-, H N+-CH -CH -COOHCl2

C. H3N -CH2-COOHCl , H3N -CH(CH3)-COOHCl-. D. H2N-CH2-COOH, H2N-CH(CH3)-COOH

Cu 16: Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch NaOH v vi
+

dung dch HCl, s phn ng xy ra l:

A. 3.
B. 5.
Cu 35: S ng phn cu to amino axit c CTPT C4H9O2N l
A. 5.
B. 2.
C. 3.
Dang bai amino axit tc ding voi bazo va axit
DNG 1: TNH LNG TNH CA AMINO AXIT

C. 6.

D. 4.
D. 4.

I. gii nhanh cc bi tp ny cn lu :
1. S dng tng phn ng ring bit:
* Phn ng vi dung dch axit:
R ( NH 2 ) x (COOH ) y + xHCl R( NH 3Cl ) x (COOH ) y
+ S nhm NH 2

nHCl pu
nA min oaxit ( pu )

+ mMui = mAmino axit (phn ng) +

mHCl( phn ng)

R ( NH 3Cl ) x (COOH ) y ( x y ) NaOH du R ( NH 2 ) x (COONa ) y xNaCl yH 2O

S nhm chc NH2 v - COOH = (x+y) =

nNaOH (pu)
nMuoi ( sau pu voi HCl)

* Phn ng vi bazo :
R ( NH 2 ) x (COOH ) y yNaOH R ( NH 2 ) x (COONa ) y yH 2O
+ S nhm -OH =

nNaOH pu
nA min axit ( pu )

+ mMui = mAmino axit (phn ng) + 22 x nNaOH (p)

R ( NH 2 ) x (COONa ) y (x+y) HCl R( NH 3Cl ) x (COOH ) y + y NaCl

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AMINO AXIT

S nhm chc NH2 v - COOH = (x+y) =

nHCl pu
nA min axit ( pu )

2. Ta cng c th s dng cch sau:

Nu bi ton cho ln lt HCl v dung dch NaOH vo dung dch amino axit.
Gi s ta c s bi ton:
R ( NH 2 ) x (COOH )
y

dd HCl

dung

dich A

ddNaOH

dung dich B

R ( NH 2 ) x (COOH ) y

Khi ta xem dung dch A gm

HCl

NaOH

R ( NH 2 ) x (COOH ) y + yNaOH R( NH 2 ) x (COONa ) y + yH 2O

HCl

NaOH

NaCl

H 2O

- Nu s bi ton l:
R ( NH 2 ) x (COOH ) y
dd NaOH

dung
dich A

ddHCl

dung dich B

R ( NH 2 ) x (COOH ) y

Tng t nh trn ta cng xem dung dch A gm :

NaOH

HCl

R ( NH 2 ) x (COOH ) y + xHCl R( NH 3Cl ) x (COOH ) y

HCl +
NaOH
NaCl +
H 2O
Phn t khi ca mt cht hu c X nm trong khong 140 < M < 150. 1 mol X phn ng c vi 2 mol NaOH
nhng ch phn ng c vi 1 mol HCl. X c th l
A. H2N(CH2)4CH(NH2)COOH.
B. H2NCH2CH(NH2)COOH.
C. HOOCCH2CH(NH2)COOH.
D. HOOC(CH2)2CH(NH2)COOH.
Cho 100 ml dung dch aminoaxit X 0,2M tc dng va vi 80 ml dung dch NaOH 0,25M. Sau phn ng c 2,5
gam mui khan. Mt khc ly 100 gam dung dch aminoaxit ni trn c nng 20,6% phn ng va vi 400 ml
dung dch HCl 0,5M. Cng thc phn t ca X l
A. H2NC3H6COOH.
B. H2NCH2COOH.
C. H2NCH(CH3)COOH.
D. H2N(CH2)2COOH.
Hp cht hu c X c cng thc tng qut CxHyOzNt. Thnh phn % khi lng ca N v O trong X ln lt l
15,730% v 35,955%. Khi X tc dng vi HCl ch to ra mui R(Oz)NH3Cl (R l gc hirocacbon). Bit X c trong
thin nhin v tham gia phn ng trng ngng. Cng thc cu to ca X l
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AMINO AXIT
A. H2NCH2COOCH3.
B. H2NCH2CH2COOH.
C. H2NCH(CH3)COOH.
D. CH2 = CHCOONH4.
Cho 0,1 mol hp cht X tc dng va vi 80 ml dung dch HCl 1,25M, sau c cn dung dch thu c 18,75 gam
mui. Mt khc, cho 0,1 mol X tc dng vi NaOH va ri c cn th c 17,3 gam mui. Bit X l mt aminoaxit v c kh nng phn ng vi Br2/Fe cho hp cht C8H9O2NBr. Cng thc cu to ca X l
A. C6H5CH(NH2)COOH.
B. H2NC6H4CH2COOH.
C. H2NCH2C6H4COOH.
D. H2NC6H4COOH
-aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit HCl d thu c 13,95 gam mui khan.
Cng thc cu to ca X l
A. H2NCH2COOH.
B. H2NCH2CH2COOH.
C. CH3CH2CH(NH2)COOH.
D. CH3CH(NH2)COO
VD1: Trong phn t amino axit X c mt nhm NH2 v mt nhm . Cho 15g X tc dng vi dd NaOH , c cn dd
thu c 19,4g mui khan. Cng thc ca X l
A. H2NC3H6COOH
B. H2NCH2COOH
C. H2NC2H4COOH
D. H2NC4H8COOH
VD2: Amino axit X cha 1 nhm - NH2. Cho 7,5g X tc dng vi dd HCl d, thu c 11,15g mui khan. Cng thc
ca X l
A. H2NCH2COOH
B. H2NCH2CH2COOH
C. CH3CH(NH2)COOH
D. H2NCH2CH2CH2COOH
VD3: Cho 0,01mol amino axit tc dng va vi 50ml dd HCl 0,2M. C cn dd sau phn ng thu c 1,835g mui.
Khi lng mol ca X l:
A. 147
B. 148
C. 183,5
D. 150
VD4: Cho 22g hh 3 amino axit tc dng va vi dd HCl 1,2M thu c 54,85g mui . Th tch HCl ti thiu cn
dng l:
A. 0,25 lt
B. 0,5 lt
C. 0,7 lt
D. 0,75 lt
VD5: X l mt - amino axit ch cha mt nhm -NH2 v mt nhm -COOH. Cho 0,89g X phn ng vi HCl to ra
1,255g mui. Cng thc cu to ca X c th l
A. H2NCH2COOH
B. H2NCH=CHCOOH
C. CH3CH(NH2)COOH
D. CH3CH(NH2)CH2COOH
VD6: Mt - amino axit ch cha mt nhm -NH2. Cho 10,3g X tc dung vi axit HCl d, thu c 13,95 g mui
khan. Cng thc cu to thu gn ca X l
A. H2NCH2COOH
B. H2NCH2CH2COOH
C. CH3CH2CH(NH2)COOH
D. CH3CH(NH2)COOH
VD7: Cho 0,01 mol amino axit X tc dng va vi 50ml dd NaOH 0,2M. C cn dd sau phn ng thu c 1,69g
mui. Khi lng mol ca X
A. 147
B.148
C. 169
D.170
VD8: X l mt amino axit ch cha 1 nhm - NH2 v 1 nhm - COOH. Ch 0,445 g X phn ng va vi NaOH to
ra 0,555g mui. Cng thc cu to c th c
A. H2NCH2COOH
B. CH3CH(NH2)COOH
C. H2NCH=CHCOOH
D. CH3CH(NH2)CH2COOH
VD9: Amino axit X mch thng X c ngun gc thin nhin, c dng H2NR(COOH)2. Cho 0,15 mol X tc dng ht
vi NaOH, c cn dd sau phn ng thu c 28,65g mui khan. Tn gi ca X
A. Axit 2- amino propandioic
B. Axit 2- amino butandioic
C. Axit 2- amino pentandioic
D. Axit 3- amino pentandioic
VD10: X l mt amino axit ch cha 1 nhm - NH2 v 1 nhm - COOH. Cho 8,9 g X phn ng vi 200ml dd HCl 1M,
thu c dd Y. phn ng ht vi cc cht trong dd Y cn dng 300ml dd NaOH 1M. X c tn l
A. Axit 3- amino propanoic
B. Axit 2- amino propanoic
C. Axit 2- amino butanoic
D. Axit 2- amino 3- metyl propanoic

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AMINO AXIT
VD11: Cho 1 mol amino axit X phn ng vi HCl d, thu c m1 gam mui Y. 1 mol amino axit X phn ng vi dd
NaOH d thu c m2 gam mui Z. bit m1=m2=7,5. Cng thc phn t X l
A. C4H10O2N2
B. C5H9O4N
C. C4H8O4N2
D. C5H11O2N
VD12: Cho 0,02 mol amino axit X phn ng vi 200ml HCl 0,1M thu c 3,67g mui khan. Mt khc 0,02 mol X
tc dng va vi 40g dd NaOH 4%. Cng thc ca X l
A. (H2N)2 C3H5 COOH
B. H2N C2C2H3 (COOH)2
C. H2N C3H6 COOH
D. H2N C3H5(COOH)2
VD13: Mt amino axit X c cha 3 nguyn t C trong phn t. Bit 1mol X phn ng vi va vi 2 mol NaOH.
Nhng ch phn ng va vi 1mol HCl. Cng thc cu to ca X l
A. CH3 CH(NH2) COOH
B. HOOC CH(NH2) COOH
C. H2N CH2CH2 COOH
D. HOOC CH(NH2) CH2 COOH
Dng 2: Amino axit tc dng vi axit hoc baz
Cu 1: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti
a vi 2 mol HCl hoc va vi 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol
N2. Cc gi tr x, y tng ng l
A. 8 v 1,0.
B. 8 v 1,5.
C. 7 v 1,0.
D. 7 v 1,5.
Cu 2: a) Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d),
thu c dung dch Y cha (m + 30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch
HCl, thu c dung dch Z cha (m + 36,5) gam mui. Gi tr ca m l
A. 112,2
B. 165,6
C. 123,8
D. 171,0
b) Hn hp X gm glyxin v Lysin. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung
dch Y cha (m + 22) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c
dung dch Z cha (m + 51,1) gam mui. Gi tr ca m l :
A. 112,2 g
B. 103,4 g
C. 123,8 g
D. 171,0 g
Cu 3: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui
khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l
A. H2NC2H3(COOH)2.
B. H2NC3H5(COOH)2.
C. (H2N)2C3H5COOH.
D. H2NC3H6COOH
Cu 4: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino
axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2- m1 = 7,5. Cng thc phn t ca X
l :
A. C4H10O2N2.
B. C5H9O4N.
C. C4H8O4N2.
D. C5H11O2N.
Cu 5: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va
vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l:
A. H2NC4 H8COOH.
B. H2NC3H6COOH.
C. H2NC2H4COOH.
D. H2NCH2COOH.
Cu 6: - aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam
mui khan. Cng thc cu to thu gn ca X l:
A. H2NCH2COOH.
B. H2NCH2CH2COOH.
C. CH3CH2CH(NH2)COOH.
D. CH3CH(NH2)COOH
Cu 7: -amino axit X cha mt nhm NH2. Cho 10,3 g X tc dng vi axit HCl (d), thu c 13,95 g mui
khan. CTCT thu gn ca X l
A. CH3CH2CH(NH2)COOH.
B. H2NCH2 CH2COOH.
C. CH3CH(NH2)COOH.
D. H2NCH2COOH.
Cu 8: Cho mt -amino axit X c mch cacbon khng phn nhnh.
- Ly 0,01mol X phn ng va vi dd HCl thu c 1,835g mui.
- Ly 2,94g X phn ng va vi dd NaOH thu c 3,82g mui.
Xc nh CTCT ca X?
A. CH3CH2CH(NH2)COOH.
B. HOOCCH2CH2CH(NH2)COOH.
C. HCOOCH2CH(NH2)CH2COOH.
D. HOOCCH2CH2CH2CH(NH2)COOH.
Cu 9: X l mt amino axit no ch cha 1 nhm NH2 v 1 nhm COOH. Cho 15,1 g X tc dng vi HCl
d thu c 18,75 g mui. CTCT ca X l
A. H2N-CH2-COOH.
B. CH3-CH(NH2)-COOH.
C. C6H5-CH(NH2)-COOH.
D. C3H7-CH(NH2)-COOH.
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AMINO AXIT
Cu 10: Trung ho 1 mol -amino axit X cn 1 mol HCl to ra mui Y c hm lng clo l 28,286% v khi
lng. CTCT ca X l
A. H2N-CH2-CH(NH2)-COOH.
B. H2N-CH2 -COOH.
C. CH3-CH(NH2 )-COOH.
D. H2N-CH2-CH2-COOH.
Cu 11: Hp cht Y l 1 - amino axit. Cho 0,02 mol Y tc dng va vi 80 ml dd HCl 0,25M. Sau c
cn c 3,67 gam mui. Mt khc trung ho 1,47 gam Y bng 1 lng va dd NaOH, c cn dd thu c
1,91 gam mui. Bit Y c cu to mch khng nhnh. CTCT ca Y l:
A. H2N CH2 CH2 COOH
B. CH3 CH(NH2) COOH
C. HOOC CH2 CH2 CH(NH2) COOH
D. HOOC CH2 CH(NH2) COOH
Cu 12: Amino axit X mch khng nhnh cha a nhm COOH v b nhm NH2. Khi cho 1 mol X tc dng ht
vi dd NaOH thu c 144 gam mui. CTPT ca X l:
A. C3H7 NO2
B. C4H7NO4
C. C4H6N2O2
D. C5H7NO2
Cu 13: Cht A c phn trm khi lng cc nguyn t C,H, O, N ln lt l 32,00%, 6,67%, 42,66%, 18,67%.
T khi hi ca A so vi khng kh nh hn 3. A va tc dng vi dd NaOH va tc dng vi dd HCl. CTCT ca
A l:
A. CH3-CH(NH2)-COOH
B. H2N-(CH2)2-COOH
C. H2N-CH2-COOH
D. H2N-(CH2)3-COOH
Cu 14: Cht A c phn trm cc nguyn t C,H, N, O ln lt l 40,45%, 7,86%, 15,73%, cn li l O. Khi
lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd HCl, c ngun
gc t thin nhin. Cng thc cu to ca A l:
A. CH3-CH(NH2)-COOH
B. H2N-(CH2)2-COOH
C. H2N-CH2-COOH
D.
H2N-(CH2)3-COOH
Cu 15: un 100ml dung dch mt aminoaxit 0,2M tc dng va vi 80ml dd NaOH 0,25M. Sau phn ng
ngi ta chng kh dung dch thu c 2,5g mui khan. Mt khc, li ly 100g dung dch aminoaxit ni trn c
nng 20,6% phn ng va vi 400ml dung dch HCl 0,5M. CTPT ca aminoaxit:
A. H2NCH2COOH
B. H2NCH2CH2COOH
C. H2N(CH2)3COOH D. a
v c ng
Cu 16: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va
vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l
A. H2NC4H8COOH.
B. H2NC3H6COOH.
C. H2NC2H4COOH.
D. H2NCH2COOH.
Cu 17: Hp cht hu c X ch cha hai loi nhm chc amino v cacboxyl. Cho 100ml dung dch X 0,3M phn
ng va vi 48ml dd NaOH 1,25M. Sau em c cn dung dch thu c c 5,31g mui khan. Bt X
c mch cacbon khng phn nhnh v nhm NH2 v tr alpha. CTCT ca X:
A. CH3CH(NH2)COOH
B. CH3C(NH2)(COOH)2
C. CH3CH2C(NH2)(COOH)2
D. CH3CH2CH(NH2)COOH
Cu 18: un nng 100 ml dung dch amino axit 0,2 M tc dng va vi 80 ml dung dch NaOH 0,25 M hoc
vi 80 ml dung dch HCl 0,5 M. Cng thc phn t ca amino axit l:
A. (H2N)2C2H3 -COOH
B. H2N-C2H3 (COOH)2 C. (H2N)2C2H2(COOH)2 D.
H2N-C2H4-COOH
Cu 19: Cho 15 gam hn hp 3 amino axit tc dng va vi dung dch HCl 1,2 M th thu c 18,504 gam
mui .V y th tch dung dch HCl phi dng l:
A. 0,8 lt
B. 0, 08 lt
C. 0,4 lt
D. 0,04 lt
Cu 20: X l mt amino axit no ch cha mt nhm COOH v 1 nhm NH2. Cho 2,06 gam X phn ng va
vi NaOH, c cn dung dch sau phn ng thu c 2,5 g mui. Vy cng thc ca X l:
A. H2N-CH2-COOH
B. CH3-CH(NH2)COOH
C. CH3 -CH(NH2)CH2COOH
D. C3H7CH(NH2)COOH.
Cu 21: Cho 22,15 g mui gm CH2NH2COONa v CH2NH2CH2COONa tc dng va vi 250 ml dung dch
H2SO4 1M. Sau phn ng c cn dung dch thlng cht rn thu c l :
A. 46,65 g
B. 45,66 g
C. 65,46 g
D. Kt qu khc
Cu 22: Cho 4,41 g mt aminoaxit X tc dng vi dung dch NaOH d cho ra 5,73 g mui.
Mt khc cng lng X nh trn nu cho tc dng vi dung dch HCl d thu c 5,505 g mui
cloruA. Xc nh CTCT ca X.
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10

AMINO AXIT
A. HOOC-CH2CH2CH(NH2)COOH
B. CH3CH(NH2)COOH
C. HOOCCH2CH(NH2)CH2COOH
D. C A v B
Cu 23: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino
axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X
l
A. C4H10O2N2.
B. C5H9O4N.
C. C4H8O4N2.
D. C5H11O2N.
Cu 24: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui
khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l
A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2.
C. (H2N)2C3H5COOH.
D. H2NC3H6COOH
Cu 25: Cho 2.46 gam hn hp gm HCOOH, CH3COOH, C6H5OH, H2NCH2COOH tc dng va vi 40 ml
dung dch NaOH 1M. Tng khi lng mui khan thu c sau khi phn ng l
A. 3,52 gam
B. 6,45 gam
C. 8,42 gam
D. 3,34 gam
Cu 26: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X.
Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l
A. 0,50.
B. 0,65.
C. 0,70.
D. 0,55.
Cu 27. Amino axit mch khng phn nhnh X cha a nhm -COOH v b nhm -NH2. Khi cho 1mol X tc dng
ht vi axit HCl thu c 169,5 gam mui. Cho 1 mol X tc dng ht vi dung dch NaOH thu c 177 gam
mui.CTPT ca X l
A. C4H7NO4
B. C3H7NO2
C. C4H6N2O2
D. C5H7NO2
Cu 28. Cho 0,1 mol -amino axit X tc dng va vi 50 ml dung dch HCl 2M. Trong mt th nghim khc,
cho 26,7 gam X vo dung dch HCl d, sau c cn cn thn dung dch thu c 37,65 gam mui khan. Vy X l:
A. Alanin.
B. Axit glutamic.
C. Valin.
D. Glyxin.
Cu 29. Hp cht X cha vng benzen, c cng thc phn t CxHyN. Khi cho X tc dng vi dung dch HCl
thu c mui Y c cng thc dng RNH3Cl (R l gc hirocacbon). Phn trm khi lng ca nit trong X l
13,084%. S ng phn cu to ca X tha mn cc iu kin trn l
A. 3.
B. 4.
C. 5.
D. 6.
Cu 30: Cho 25,65 gam mui gm H2NCH2COONa v H2NCH2CH2COONa tc dng va vi 250 ml dung
dch H2SO4 1M. Sau phn ng c cn dung dch th khi lng mui do H2NCH2COONa to thnh l:
A. 29,25 gam
B. 18,6 gam
C. 37,9 gam
D. 12,4 gam
Cu 31: Cho 0,02 mol cht X (X l mt -aminoaxit) phn ng va ht vi 160ml dd HCl 0,125 M th to ra
3,67g mui. Mt khc, 4,41g X khi tc dng vi mt lng NaOH va th to ra 5,73g mui khan. Bit X c
mch cacbon khng phn nhnh. Vy cng thc cu to ca X l :
A. HOOC-CH(NH2)-CH(NH2)-COOH.
B. CH3-CH2-CH(NH2 )-COOH
C. HOOC-CH2-CH2-CH(NH2 )-COOH.
D. CH3-CH2 -CH2-CH(NH2)-COOH
Cu 32: Cho 0,02 mol amino axit X tc dng va vi 200ml dung dch HCl 0,1M c 3,67gam mui khan.
Mt khc 0,02mol X tc dng va vi 40gam dung dch NaOH 4%. S cng thc cu to ca X l:
A. 2.
B. 3.
C. 4.
D. 5.
Cu 33: Cht X l mt aminoaxit. Cho 100ml dung dch X 0,02M phn ng va ht vi 160ml dung dch NaOH
0,25M. C cn dung dch sau phn ng ny th c 3,82g mui khan. Mt khc X tc dng vi HCl theo t l
1:1. Cng thc phn t ca X l:
A. C3H7NO2
B. C4 H7NO4
C. C5H11NO4
D. C5H9 NO4
Cu 34: Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d. Sau phn ng lm bay
hi cn thn dung dch thu c (m + 11,68) gam mui khan. Nu cho m gam hn hp X tc dng vi dung dch
KOH va , sau phn ng lm bay hi cn thn dung dch thu c (m + 19) gam mui khan. Gi tr ca m l:
A. 38,92 gam
B. 35,4 gam
C. 36,6 gam
D. 38,61 gam
Cu 35: Dung dch X cha 0,01 mol ClH3N-CH2-COOH, 0,02 mol CH3-CH(NH2)COOH; 0,05 mol
H COOC6 H5. Cho dung dch X tc dng vi 160 ml dung dch KOH 1M un nng phn ng xy ra hon ton.
C cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l:
A. 12,535 gam
B. 16,335 gam
C. 8,615 gam
D. 14,515 gam
Cu 36: Hn hp X gm 2 amino axit no, mch h. Ly 8,9 gam X cho tc dng vi dung dch HCl d c a
gam mui, cng lng 8,9 gam X khi tc dng vi dung dch NaOH d th lng mui thu c l (a 1,45) gam.
Nguyn Xun Dng

11

AMINO AXIT
Hai amino axit l
A. NH2C4H8COOH v NH2C3H6COOH.
B. NH2CH2COOH v NH2C2H4COOH.
C. NH2C2H4COOH v NH2C3H6COOH.
D. NH2CH2COOH v NH2C3H6COOH.
Cu 37: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam
mui khan. Cng thc cu to thu gn ca X l
A. H2NCH2COOH.
B. H2NCH2CH2COOH.
C. CH3CH2CH(NH2)COOH.
D. CH3CH(NH2)COOH.
Cu 38: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va
vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l
A. H2NC4 H8COOH.
B. H2NC3H6COOH.
C. H2NC2H4COOH.
D. H2NCH2COOH.
Cu 39: Hp cht A l mt -amino axit. Cho 0,01 mol A tc dng va vi 80 ml dung dch HCl 0,125M, sau
c cn cn thn thu c 1,835 gam mui. Mt khc, khi trung ho 2,94 gam A bng dung dch NaOH va
th c 3,82 gam mui. Hy:
a. Xc nh cng thc cu to v gi tn A, bit A c cu to mch khng phn nhnh.
b. Vit phng trnh phn ng ca A vi dung dch NaNO2 vi s c mt ca axit clohiric
Cu 40: Bit A l mt aminoaxit
1/ C 0,01 mol A p va vi 80 ml dd HCl 0,125M, sau em c cn dd th thu c 1,835 gam mui
khan. Tnh KLPT ca A?
2/ Trung ha 2,94 gam A bng NaOH va sau c cn c 3,82 gam mui khan. Tm CTCT v tn ca A
bit nhm amino v tr ?
Cu 41: Hp cht hu c A c 15,7303%N v 35,9551%O v khi lng. A tc dng vi HCl ch to ra
R(O)z-NH3Cl (R l gc hidrocacbon). Xc nh CTCT ca A. Bit A tham gia phn ng trng ngng.
Cu 42: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino
axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Mt khc cho 0,01 mol
A tc dng va vi dung dch HCl sau c cn cn thn thu c 1,835 gam mui. Cng thc ca X l :
A. H2NC2H3(COOH)2.
B. H2NC3H5(COOH)2.
C. (H2N)2C3H5COOH. D. H2NC3H6COOH.
Cu 43: Cho m1 gam -amino axit A (c tng s nhm chc khng vt qu 4) tc dng va vi 100 ml
dung dch HCl 1M, sau c cn cn thn thu c 18,35 gam mui khan. Mt khc, khi trung ho m2 gam A
bng 160ml dung dch NaOH 1,25M th c 19,1 gam mui khan.
a. Xc nh cng thc cu to v gi tn A, bit A c cu to mch khng phn nhnh?
b. Gi tn theo danh php thay th
Cu 44: Cho dung dch X c cha 0,01 mol Glixin, 0,02 mol ClH3N-CH2-COOH v 0,03 mol phenyl fomat tc
dng vi 150 ml dung dch NaOH 1M un nng c dung dch Y. C cn dung dch Y thu c cht rn khan c
khi lng l
A. 9,6 gam
B. 6,12 gam
C. 11,2 gam
D. 11,93 gam
Cu 45: Cho 17,8 gam hn hp hai amino axit no cha mt chc -COOH v mt chc -NH2 (t l khi lng phn
t ca chng l 1,373) tc dng vi 110 ml dung dch HCl 2M, c dung dch A. tc dng ht cc cht trong
dung dch A cn dng 140 ml dung dch KOH 3M. Phn trm s mol mi amino axit trong hn hp ban u bng
A. 25% v 75%.
B. 50% v 50%.
C. 20% v 80%.
D. 40% v 60%.
Cu 46: Cho m gam hn hp X gm axit glutamic v valin tc dng vi dung dch HCl (d), sau phn ng hon
ton lm bay hi cn thn dung dch, thu c (m + 9,125) gam mui khan. Nu cho m gam X tc dng vi dung
dch NaOH (d), kt thc phn ng to ra (m + 7,7) gam mui. Gi tr ca m l
A. 26,40.
B. 39,60.
C. 33,75.
D. 32,25.
Cu 20. X v Y u l aminoaxit no mch h v c cng s cacbon trong phn t. X c 1 nhm NH2 v 1 nhm
COOH cn Y c 1 nhm NH2 v 2 nhm COOH. Ly 0,25 mol hn hp Z gm X v Y tc dng vi dung dch
NaOH va thu c dung dch cha 40,09 gam cht tan gm 2 mui trung ha. Cng ly 0,25 mol hn hp Z trn
tc dng vi dung dch HCl va thu c dung dch cha 39,975 gam gm 2 mui. Phn trm khi lng X trong
hn hp Z l :
A. 23,15%
B. 30,34%
C. 19,65%
D. 26,71%
Cu 26. Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH2 trong phn t), trong t l mO : mN =
80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M. Mt khc, t chy hon ton 3,83
Nguyn Xun Dng

12

AMINO AXIT
gam hn hp X cn 3,192 lt O2 (ktc). Dn ton b sn phm chy vo nc vi trong d th khi lng kt ta thu
c l:
A. 13 gam.
B. 15 gam.
C. 10 gam.
D. 20 gam.
Dng 3: Amino axit tc dng vi axit hoc baz sau ly sn phm thu c tc dng vi baz hoc axit
Cu 1: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X.
Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l :
A. 0,50.
B. 0,65.
C. 0,70.
D. 0,55.
Cu 2: 0,01 mol amino axit Y phn ng va vi 0,01 mol HCl c cht Z. Cht Z phn ng va vi
0,02 mol NaOH. Cng thc ca Y c dng l
A. H2NR(COOH)2.
B. H2NRCOOH.
C. (H2N)2RCOOH.
D. (H2N)2R(COOH)2.
Cu 3: Mt amino axit A c cha 2 nhm chc amin, mt nhm chc axit. 100ml dd c cha A vi nng 1M
phn ng va vi 100ml dd HCl aM c dd X, dd X phn ng va vi 100ml dd NaOH bM. Gi tr ca a, b
ln lt l
A. 2; 1.
B. 1; 2.
C. 2; 2.
D. 2; 3.
Cu 3: Cho 0,2 mol amino axit X phn ng va vi 100 ml dung dch HCl 2M thu c dung dch A.
Cho dung dch A phn ng va vi dung dch NaOH, sau phn ng c cn sn phm thu c 33,9g mui. X c
tn gi l:
A. glixin
B. alanin
C. valin
D. axit glutamic
Cu 4: X l 1 amino axit c cng thc tng qut dng H2N R COOH. Cho 8,9 gam X tc dng vi 200 ml
dd HCl 1M thu c dung dch Y. phn ng ht vi cc cht trong dd Y cn dng 300 ml dd NaOH 1M. CTCT
ng ca X l:
A. H2N CH2 COOH
B. H2N CH2 CH2 COOH
C. CH3 CH(NH2) COOH
D. CH3 CH2 CH(NH2) COOH
Cu 5: A l mt -amino axit mch cacbon khng phn nhnh. Cho 0,1 mol A vo dung dch cha 0,25 mol HCl
(d), c dung dch B. phn ng ht vi dd B, cn va 300 ml dd NaOH 1,5 M un nng. Nu c cn
dung dch sau cng, th c 33,725 g cht rn khan. A l:
A. Glixin
B. Alanin
C. axit glutamic
D. axit -amino butiric
Cu 6: Cho 0,1 mol amino axit phn ng va vi 200 ml dung dch HCl 0,5M, thu c dung dch X. Cho
dd NaOH 0,5M vo dung dch X th thy cn dng va ht 600ml. Xc nh s nhm chc amino -NH2 v
cacboxyl - COOH ?
Cu 7: X l mt -amino axit c cha vng thm v mt nhm NH2 trong phn t. Bit 50 ml dung dch X phn ng
va vi 80 ml dung dch HCl 0,5M, dung dch thu c phn ng va vi 50 ml dung dch NaOH 1,6M. Mt
khc nu trung ha 250 ml dung dch X bng lng va KOH ri em c cn thu c 40,6 gam mui. CTCT ca
X l:
A. C6H5-CH(CH3)-CH(NH2)COOH
B. C6H5-CH(NH2)-CH2COOH
C. C6H5-CH(NH2)-COOH
D. C6H5-CH2CH(NH2)COOH
Cu 8: Cho 0,1 mol alanin phn ng vi 100 ml dung dch HCl 1,5M thu c dung dch A. Cho A tc dng va
vi dung dch NaOH thu c dung dch B, lm bay hi dung dch B thu c bao nhiu gam cht rn khan?
A. 14,025 gam
B. 8,775 gam
C. 11,10 gam
D. 19,875 gam
Cu 9: Cho 0,15 mol hn hp X gm hai aminoaxit : R(NH2)(COOH)2 v R(NH2)2(COOH) vo 200 ml dung
dch HCl 1,0 M, thu c dung dch Y. Y tc dng va ht vi 400 ml dung dch NaOH 1,0 M. S mol ca
R(NH2 )(COOH)2 trong 0,15 mol X l :
A. 0,1 mol
B. 0,125 mol .
C. 0,075 mol
D. 0,05 mol
Cu 10: Cho 27,15 gam tyrosin tc dng vi 225 ml dung dch HCl 1M thu c dung dch X. Cho X tc dng vi
600 ml dung dch NaOH 1M thu c dung dch Y. Tng khi lng cht rn khan thu c khi c cn cn thn
dung dch Y l
A. 40,9125 gam.
B. 49,9125 gam.
C. 52,6125 gam.
D. 46,9125 gam.
Cu 11: Ly 0,3 mol hn hp X gm H2NC3H5(COOH)2 v H2NCH2COOH cho vo 400ml dung dch HCl 1M th
thu c dung dch Y. Y tc dng va vi 800ml dung dch NaOH 1M nthu c dung dch Z. Lm bay hi Z
thu c m gam cht rn khan, gi tr ca m l?
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AMINO AXIT
A. 52,2 gam
B. 55,2 gam
C. 28,8 gam
D. 31,8 gam
Cu 12: Cho m gam hn hp X gm hai -aminoaxit cng s mol, u no mch h, c 1 nhm amino v 1
nhm cacboxyl tc dng vi dd cha 0,44 mol HCl c dd Y. Y td va ht vi dd cha 0,84 mol KOH. t chy
hon ton m gam X ri hp th sn phm chy bng dd KOH d thy khi lng bnh tng 65,6 g. CTCT 2 cht
trong X l
A. H2NCH(C2H5)COOH v H2NCH(CH3 )COOH
B. H2NCH2COOH v H2NCH(CH3)COOH
C. H2NCH(C2H5)COOH v H2NCH2 CH2COOH
D. H2NCH2 COOH v H2NCH(C2 H5)COOH
Cu 13: Cho -aminoaxit X ch cha mt chc NH2 tc dng vi 200ml dung dch NaOH 1M thu c dung dch
Y. Dung dch Y phn ng va vi 500ml dung dch HCl 1M thu c dung dch Z. C cn cn thn dung dch Z
thu c 49,35 gam cht rn khan. X l
A. Valin.
B. Lysin.
C. Glyxin.
D. Alanin.
Cu 14: Cho 20,15 gam hn hp X gm glyxin v alanin phn ng vi 200 ml dung dch HCl 1M, thu c dung
dch Y. Dung dch Y phn ng va vi 450 ml dung dch NaOH 1M. Thnh phn % v khi lng ca glyxin
trong hn hp X l
A. 55,83%.
B. 53,58%.
C. 44,17%.
D. 47,41%.
Cu 15: Cho dung dch cha 0,01 mol mt aminoaxit A tc dng va vi 100ml dung dch HCl 0,1M thu c
dung dch X , tc dng ht vi dung dch X cn ti thiu 300ml NaOH 0,1M, c cn dung dch sau phn ng thu
c 2,845 gam cht rn. A l:
A. Lysin.
B. Axit glutamic.
C. Tyrosin.
D. Alanin.
Cu 16: Cho 0,12 mol alanin tc dng va vi dung dch HCl thu c dung dch X. Thm vo dung dch X
300 ml dung dch NaOH 1M thu c dung dch Y. C cn dung dch Y thu c m gam cht rn khan. Gi tr
ca m l:
A. 17,70 gam
B. 22,74 gam
C. 20,10 gam
D. 23,14 gam
Cu 17: Cho 19,2 gam hn hp gm hai amino axit no cha mt chc axit v mt chc amin (t l khi lng
phn t ca chng l 1,373) tc dng vi 110 ml dung dch HCl 2M, c dung dch A. tc dng ht vi cc
cht trong dung dch A cn dng 140 ml dung dch KOH 3M. Phn trm s mol ca mi aminoaxit trong hn hp
ban u bng:
A. 25% v 75%.
B. 20% v 80%.
C. 50% v 50%.
D. 40% v 60%.
Cu 18: Cho 13,35 g hn hp X gm CH2 NH2CH2COOH v CH3CHNH2 COOH tc dng vi V ml dung dch
NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l
:
A. 100 ml
B. 150 ml
C. 200 ml
D. 250 ml
Cu 19: Cho 20,15 g hn hp X gm (CH2NH2COOH v CH3 CHNH2COOH) tc dng vi 200 ml dung dch
HCl 1M thu c dung dch Y. Y tc dng va vi 450 ml dung dch NaOH.Phn trm khi lng cc cht
trong X l
A. 55,83% v 44,17%
B. 53,58% v 46,42%
C. 58,53% v 41,47%
D. 52,59% v 47,41%
Cu 20 : Ly 20 ml amino axit X c 1 nhm -NH2 phn ng vi 100 ml dung dch HCl 0,1M thu c dung
dch Y. Cho dung dch Y phn ng va vi 300 ml dung dch NaOH 0,1M. Mt khc trung ha ht 250 ml X
bi KOH sau phn ng c cn sn phm thu c 26,125 g mui. Xc nh cng thc CT ca X ?
Cu 21: Ly m gam hn hp X gm hai amino axit c 1 nhm -NH2 v 1 nhm -COOH phn ng vi 55 ml
dung dch HCl 2M thu c dung dch Y. tc dng ht vi cc cht trong dung dch Y cn dng 70 ml dung
dch KOH 3M. Mt t chy hon ton m(g) X v cho sn phm chy qua dd KOH d th khi lng bnh ny
tng thm 14,85 gam . Bit t l phn t khi gia hai amino axit l 1,187. Xc nh cng thc CT ca X ?
Cu 22: Cho hn hp A gm ( 0,15 mol axit glutamic v 0,1 mol glyxin ) vo 175 ml dung dch HCl 2M, thu
c dung dch X. Cho NaOH d vo dd X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l
A. 0,80.
B. 0,60.
C. 0,75.
D. 0,65.
Cu 23: Cho m gam aminoaxt (trong phn t ch cha mt nhm NH2 v mt nhm COOH), tc dng vi
110ml dd HCl 2M c dd X. phn ng ht vi cc cht trong dd X cn 200 gam dd NaOH 8,4% c dd Y,
c can dd Y th c 32,27 gam cht rn. Cng thc phn t ca aminoaxt trn l:
A. NH2CH2COOH
B. NH2C2H2COOH
C. NH2C2H4COOH
D. NH2C3H6COOH
Cu 24: Hn hp X gm 2 aminoaxit (H2N)2R1COOH v H2NR2(COOH)2 c s mol bng nhau tc dng vi 550ml
dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 1 lt dung dch NaOH 1M. Vy khi to thnh dung
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AMINO AXIT
dch Y th ?
A. HCl v aminoaxit va
B. HCl d 0,1 mol
C. HCl d 0,3 mol
D. HCl d 0,25 mol
Cu 25: Hn hp M gm hai cht CH3COOH v NH2CH2COOH. trung ho m gam hn hp M cn 100ml
dung dch HCl 1M. Ton b sn phm thu c sau phn ng li tc dng va vi 300ml dung dch NaOH 1M.
Thnh phn phn trm theo khi lng ca cc cht CH3COOH v NH2CH2COOH trong hn hp M ln lt l ;
A. 61,54 v 38,46.
B. 72,80 v 27,20.
C. 44,44 v 55,56
D. 40 v 60.
Cu 26: X l axit , iaminobutiric. Cho dung dch cha 0,25 mol X tc dng vi 400 ml dung dch NaOH 1M,
sau cho vo dung dch thu c 800ml dung dch HCl 1M v sau khi phn ng kt thc c cn dung dch s thu
c bao nhiu gam cht rn khan :
A. 47,75 gam
B. 74,7 gam
C. 35 gam
D. 56,525 gam
Dng 4: Este ca amino axit v mui ca aminoaxit vi axit (v c, hu c) hoc vi (NH3 ,amin)
Cng thc CnH2n+1NO2 c cc ng phn sau:
- Amino axit , este aminoaxit , mui to ra t axit hu c khng no vi NH3 hoc amin no v ngc li; hp cht
nitro - NO2
V d: C3H7NO2 c cc p sau:
CH2 = CHCOONH4 ; H2NCOOCH2CH3 ; H2N CH2 COOCH3; H2NCH(CH3 )COOH;
H2NC2H4COOH;
HCOONH3CH = CH2 ;
CH3-CH2- CH2 -NO2 ;
CH3-CH(CH3)-NO2
Cu 1: (K) l hp cht hu c c CTPT l: C5H11NO2. un (K) vi dd NaOH thu c hp cht c CTPT l
C2H4 O2NNa v hp cht hu c (L). Cho hi (L) qua CuO/to thu c mt cht hu c (M) c kh nng tham gia
phn ng trng bc. CTCT ca (K) l
A. CH2=CH-COONH3-C2H5.
B. NH2-CH2-COO-CH2-CH2-CH3.
C. NH2-CH2-COO-CH(CH3)2.
D. H2N-CH2-CH2-COO-C2H5.
Cu 2: Cho 8,9 g mt hp cht hu c X c CTPT C3H7 O2N phn ng vi 100 ml dd NaOH 1,5M. Sau khi phn
ng x y ra hon ton, c cn dd thu c 11,7 g cht rn. CTCT thu gn ca X l
A. H2NCH2CH2COOH.
B. H2NCH2COOCH3.
C. CH2=CHCOONH4.
D. HCOOH3NCH=CH2.
Cu 3: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc)
v 3,15 g H2O. Khi X tc dng vi dd NaOH thu c sn phm c mui H2N-CH2COONa. CTCT thu gn ca X
l
A. H2N-CH2-COO-C3H7.
B. H2N-CH2 -COO-C2H5.
C. H2N-CH2-CH2-COOH.
D. H2N-CH2-COO-CH3.
Cu 4: Cho hn hp X gm 2 cht hu c c cng cng thc phn t C3H10N2O2 tc dng va vi dung dch
NaOH v un nng thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu
m) hn km nhau mt nguyn t C . T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi
lng mui khan l:
A. 16,5 gam
B. 20,1 gam
C. 8,9 gam
D. 15,7 gam
Cu 5: a) Hp cht X c CTPT trng vi cng thc n gin nht, va tc dng c vi axit va tc dng
c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t
C, H, N ln lt bng 40,449%; 7,865% v 15,73%, cn li l oxi. Khi cho 4,45 gam X phn ng hon ton
vi mt lng va dd NaOH (un nng) thu c 4,85 mui khan. CTCT thu gn ca X l:
A. CH2 = CHCOONH4
B. H2NCOOCH2CH3
C. H2NCH2COOCH3
D. H2NC2H4COOH
b) Khi cho 10,6 gam X c cng thc phn t C3 H10N2O2 phn ng vi mt lng va dd NaOH (un nng) thu
c 8,3 gam mui khan v kh Y bc 1 lm xanh qu m. CTCT thu gn ca X l:
A. NH2COONH2(CH3)2
B. NH2CH2CH2COONH4
C. NH2COONH3CH2CH3
D. NH2CH2COONH3CH3
Cu 6: a) Este A c iu ch t amino axit B v ancol met ylic. t chy hon ton 0,1 mol A thu c
1,12 lt N2 (ktc), 13,2 gam CO2 v 6,3 gam H2O. Bit t khi ca A so vi H2 l 44,5. CTCT ca A l:
A. H2N CH2 COOH
B. H2N CH2 CH2 COOCH3
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AMINO AXIT
C. CH3 CH(NH2) COOCH3
D. CH2 CH = C(NH2) COOCH3
b) Este A c iu ch t amino axit B v ancol metylic. t chy hon ton 8,9 gam A thu c 1,12 lt N2
(ktc), 13,2 gam CO2 v 6,3 gam H2O. Bit t khi ca A so vi H2 l 44,5. CTCT ca A l:
A. H2NCH2COOH
B. H2NCH2CH2COOCH3
C. CH3CH(NH2) COOCH3
D. CH2CH = C(NH2)COOCH3
Cu 7: Mt HCHC X c t l khi lng C: H: O: N = 9: 1,75: 8: 3,5 tc dng vi dd NaOH v dd HCl theo t l
mol 1: 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v
dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br2. Cng thc phn t ca X v
cng thc cu to ca X, Y ln lt l:
A. C3H7O2N; H2N-C2H4-COOH; H2 N-CH2-COO-CH3
B. C3H7O2N; H2N-C2H4-COOH; CH2=CH-COONH4
C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2
D. C3H5O2N; H2N-C2H2-COOH; CH2=CH-COONH4
Cu 8: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un
nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c Y, cho hi Y
qua CuO/to thu c cht hu c Z c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l:
A. CH3(CH2)4NO2
B. NH2-CH2COO-CH2 -CH2-CH3
C. NH-CH2-COO=CH(CH2)3
D. H2N-CH2-CH2-COOC2H5
Cu 9: Thc hin phn ng este gia amino axit X v ancol CH3OH thu c este Y c t khi hi so vi khng
kh bng 3,069. CTCT ca X:
A. H2N-CH2-COOH
B. H2N-CH2-CH2-COOH
C. CH2 -CH(NH2)-COOH
D. H2N-(CH2)3-COOH
Cu 10: Cht X c cng thc phn t C4H10O2NCl. un nng X vi dung dch NaOH thu c cc sn phm NaCl,
H2N- CH2- COONa, v ru Y. Cng thc cu to ca X l:
A. CH3-CH2-COO-CH2-NH3Cl
B. CH3-CH2-OOC-CH2-NH3Cl
C. CH3 -COO-CH2-CH2-NH3Cl
D. CH3 CH- COO-CH2-Cl
NH2
Cu 11: Cc cht X, Y, Z c cng CTPT C2H5O2N. X tc dng c c vi HCl v Na2O. Y tc dng c vi
H mi sinh to ra Y1 . Y1 tc dng vi H2SO4 to ra mui Y2. Y2 tc dng vi NaOH t i t o li Y1. Z tc
dng vi NaOH to ra mt mui v kh NH3. CTCT ng ca X, Y, Z l:
A. X (HCOOCH2NH2), Y (CH3COONH4), Z (CH2NH2COOH)
B. X (CH3COONH4), Y (HCOOCH2NH2), Z (CH2NH2COOH)
C. X (CH3COONH4), Y (CH2NH2COOH), Z (HCOOCH2NH2)
D. X (CH2 NH2COOH), Y (CH3CH2NO2), Z (CH3 COONH4)
Cu 12: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung
dch sau phn ng thu c m gam cht rn. Gi t r ca m l :
A. 15,65 g
B. 26,05 g
C. 34,6 g
D. Kt qu khc
Cu 13: A l mt hp cht hu c c CTPT C5H11O2N. un A vi dung dch NaOH thu c mt hp cht c
CTPT C2H4O2NNa v cht hu c B. Cho hi qua CuO/to thu c cht hu c D c kh nng cho phn ng
trng gng. CTCT ca A l :
A. CH2= CH - COONH3-C2H5
B. CH3(CH2)4NO2
C. H2N-CH2-CH2-COOC2H5
D. NH2-CH2COO-CH2-CH2- CH3
Cu 14: Cht hu c A c mt nhm amino, 1 chc este. Hm lng oxi trong A l 31,07%. X phng ha m
gam cht A c ancol, cho hi ancol i qua CuO d, to thu andehit B.Cho B phn ng vi dd AgNO3/NH3 thu
c 16,2 gam Ag v mt mui hu c. Gi tr ca m l
A. 3,3375 gam
B. 7,725 gam
C. 6,675 gam
D. 3,8625 gam
Cu 15: Cht hu c M c mt nhm amino, mt chc este. Hm lng oxi trong M l 35,96%. X phng ha a
gam cht M c ancol. Cho ton b hi ancol i qua CuO d, to thu andehit Z. Cho Z phn ng vi dung dch
AgNO3/NH3 d, thu c 16,2 gam Ag. Gi tr ca a l: (hiu sut phn ng 100%)
A. 7,725 gam
B. 3,3375 gam
C. 3,8625 gam
D. 6,675 gam
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AMINO AXIT
Cu 16: Hai ng phn X, Y trong c 1 cht lng v 1 cht rn c thnh phn 40,45%C, 7,86%H, 15,73%N
cn li l oxi. Khi cho cht lng bay hi thu c cht hi c t khi so vi khng kh l 3,069. Khi phn ng
vi NaOH, X cho mui C3H6 O2NNa, Y cho mui C2H4O2NNa. Cng thc cu to v trng thi ca X, Y l
A. X l cht lng CH3-CH(NH2)-COOH, Y l cht rn NH2 -CH2COOCH3
B. X l cht rn CH2(NH2)-CH2COOH, Y l cht lng NH2-CH2OOCCH3
C. X l cht lng CH2(NH2)-CH2COOH, Y l cht rn NH2-CH2OOCCH3
D. X l cht rn CH3-CH(NH2)-COOH, Y l cht lng NH2-CH2COOCH3.
Cu 17: X l este to bi -amino axit Y (cha 1 nhm -COOH v 1 nhm -NH2) vi ru n chc Z. Thy
phn hon ton 0,1 mol X trong 200 ml dung dch NaOH 1M, c cn dung dch thu c 13,7 gam cht rn v 4,6
gam ru Z. Vy cng thc ca X l:
A. CH3-CH(NH2)-COOC2H5
B. CH3-CH(NH2)-COOCH3
C. H2N-CH2-COOC2H5
D. H2N-CH2-COOCH2-CH=CH2
Cu 18: Mt hp cht X (c khi lng phn t bng 103). Cho 51,50 gam X phn ng ht vi 500 ml dung dch
NaOH 1,20M, thu c dung dch Y trong c mui ca aminaxit, ancol c khi lng phn t ln hn khi
lng phn t O2. C cn Y thu m gam cht rn. Gi tr m l
A. 52,50
B. 26,25
C. 48,50
D. 24,25
Cu 19: Este X c khi lng phn t bng 103 vC c iu ch t mt ancol n chc (c t khi hi so vi
oxi ln hn 1) v mt amino axit. un 25,75 gam X vi 300 ml dung dch NaOH 1M, sau phn ng hon ton
thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l
A. 27,75 gam
B. 26,25 gam
C. 29,75 gam
D. 24,25 gam
Cu 20. a) A l este ca axit glutamic , khng tc dng vi Na . Thy phn han ton mt lng cht A trong
100ml dung dch NaOH 1M ri c cn , thu c mt ru B v cht rn khan C . un nng lng ru B trn vi
H2SO4 c 170oC thu c 0,672 lt lfin (kc) vi hiu sut phn ng l 75% . Cho ton b cht rn C tc
dng vi dung dch HCl d ri c cn, thu c cht rn khan D. Khi lng cht rn D l :
A. 10,85gam
B. 7,34 gam
C. 9,52 gam
D. 5,88gam
b) Este X c iu ch t aminoaxit glutamic v ancol etylic. Cho 0,1 mol X vo 200 ml dung dch NaOH 1,5M,
sau khi phn ng xy ra hon ton, c cn cn thn dung dch thu c cht rn G. Cho ton b cht rn G vo
dung dch HCl d, sau c cn cn thn li thu c m gam cht rn E. Gi tr ca m l:
A. 26,4 g.
B. 18,35 g
C. 30,05 g
D. 35,9 g
Cu 21: Cht X c cng thc phn t C4H9 O2N
Bit:
X + NaOH Y + CH4O
Y + HCl (d) Z + NaCl
Cng thc cu to ca X v Z ln lt l
A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH.
B. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH.
C. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH.
D. H2NCH2COOC2H5 v ClH3NCH2COOH.
Cu 22: Cht hu c X c 1 nhm amino, 1 chc este. Hm lng N c trong X l 15,73%. X phng ho m gam
X thu c hi ancol Z, cho Zqua CuO d thu c andehit Y ( phn ng hon ton), cho Y phn ng hon ton
AgNO3/NH3d thu c 16,2 gam Ag . gi tr m l.
A. 7,725
B. 6,675
C. 3,3375
D.5,625
Cu 23: X l este to bi -amino axit Y (cha 1 nhm -COOH v 1 nhm -NH2) vi ancol n chc Z. Thy
phn hon ton 0,1 mol X trong 200 ml dung dch NaOH 1M, c cn dung dch thu c 13,7 gam cht rn v 4,6
gam ancol Z. Vy cng thc ca X l:
A. CH3-CH(NH2)-COOC2H5
B. CH3-CH(NH2)-COOCH3
C. H2N-CH2-COOC2H5
D. H2N-CH2-COOCH2-CH=CH2
Cu 24: Cht X c cng thc phn t C8H15O4N. T X, thc hin bin ha sau:
C8H15O4N+NaOH NaOOC(CH)2CH(NH2 )COONa + CH4O + C2H6O

Nguyn Xun Dng

17

AMINO AXIT
Hy cho bit, X c th c bao nhiu cng thc cu to?
A. 4.
B. 1.
C. 3.
D. 2.
Cu 25: Cht hu c X mch h c dng H2N-R-COOR(R, R' l cc gc hirocacbon), phn trm khi lng
nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra
cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ha thnh anehit). Cho ton b Y tc
dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l:
A. 2,67
B. 4,45
C. 5,34
D. 3,56
Dng 5: t chy aminoaxit
Cu 1: Dng 16,8 lt khng kh ktc (O2 chin 20% v N2 chim 80% th tch) t chy hon ton 3,21
gam hn hp A gm 2 aminoaxt k tip nhau c cng thc tng qut CnH2n+1O2N. Hn hp thu c sau phn
ng em lm kh c hn hp kh B, cho B qua dd Ca(OH)2 d thu 9,5gam kt ta.
a) Tm CTCT v khi lng ca 2 aminoaxt.
b) Nu cho kh B vo bnh dung tch 16,8 lt, nhit 136,5oC th p sut trong bnh l bao nhiu? Cho bit
aminoaxt khi t chy to kh N2.
Cu 2: t chy hon ton 8,7 gam aminoaxit A (axit n chc)th thu c 0,3 mol CO2 v 0,25 mol H2O
v 1,12 lt (kc) ca N2. Xc nh cng thc cu to ca A?
Cu 3: t chy 0,2 mol hp cht A thuc loi tp chc, thu c 26,4 gam kh CO2; 12,6 gam hi H2O v
2,24 lt kh N2 (ktc). Nu t chy 1 mol A cn 3,75 mol O2. Xc nh cng thc phn t ca A.
Cu 4: t chy hon ton 17,8 gam hp cht amino axit X c ly t thin nhin ngi ta thu c 13,44
lt kh CO2, 12,6 gam nc v 1,12 lt N2. Mt khc, khi cho 0,1 mol X phn ng ht vi hn hp NaNO2 v
HCl, ngi ta c 2,24 lt kh N2. Cc cht kh u o iu kin tiu chun. Cng thc cu to ca X l:
A. H2NCH(C2H5)COOH
B. H2NCH2COOH
C. H2NCH(CH3)COOH
D. H2NCH2CH2COOH
Cu 5: t chy hon ton 45,1 gam hn hp X gm CH3CH(NH2)COOH v CH3COONH3CH3 thu c CO2,
H2O v N2 c tng khi lng l 109,9 gam. Phn trm khi lng mi cht trong hn hp X ln lt l :
A.39,47% v 60,53%
B. 35,52% v 64,48%.
C. 59,20% v 40,80%
D. 49,33% v 50,67%
Cu 6: t chy hon ton 0,25 mol hn hp X gm aminoaxit H2NR(COOH)x v mt axit no, m c h h, n
chc thu c 0,6 mol CO2 v 0,675 mol nc. Mt khc 0,2 mol X phn ng va vi dung dch cha a
mol HCl. Gi tr ca a l :
A. 0,2 mol
B. 0,25 mol
C. 0,12 mol
D. 0,1 mol
Cu 7: Aminoaxit X (ch cha amin bc 1) c cng thc CxHyO2N. t chy hon ton 0,1 mol X ri cho ton
b sn phm chy hp th vo bnh ng dung dch NaOH c thy khi lng bnh tng thm 25,7 g. S cng
thc cu to ca X l:
A. 3.
B. 4.
C. 5.
D. 6.
Cu 8: Hn hp X gm 2 amino axit no bc 1 Y v Z. Y cha 2 nhm axit, mt nhm amino; Z cha mt
nhm axit, mt nhm amino. MY/MZ = 1,96. t chy 1mol Y hoc 1 mol Z th s mol CO2 thu c nh hn
6. Cng thc cu to ca hai amino axit l:
A. H2NCH2CH(COOH)CH2COOH v H2 NCH2COOH
B. H2NCH2CH(COOH)CH2COOH v H2N[CH2]2COOH
C. H2NCH(COOH)CH2COOH v H2NCH2COOH
D. H2NCH(COOH)CH2COOH v H2N[CH2]2COOH
Cu 9: Mt amino axit (X) c cng thc tng qut NH2RCOOH. t chy hon ton a mol X thu c
6,729(l) CO2 (ktc) v 6,75 g H2O. CTCT ca X l :
A. CH2NH2COOH
B. CH2NH2CH2COOH
C. CH3CH(NH2)COOH
D. C B v C
Cu 10: Xc n h th tch O2 (ktc) cn t chy ht 22,455g hn hp X gm (CH3CH(NH2)COOH
v CH3COOCNH3CH3). Bit sn phm chy c hp th h t vo bnh ng dung dch NaOH th khi
lng bnh tng 85,655 g.
A. 44,24 (l)
B. 42,8275 (l)
C. 128,4825 (l)
D. Kt qu khc
Cu 11: t chy hon ton 45,1 gam hn hp X gm CH3CH(NH2)COOH v CH3COONH3CH3 thu c CO2,
H2O v N2 c tng khi lng l 109,9 gam. Phn trm khi lng mi cht trong hn hp X ln lt l
A. 39,47% v 60,53%
B. 35,52% v 64,48%.
C. 59,20% v 40,80%
D. 49,33% v 50,67%
Cu 12: Amino axit (Y) c cng thc dng NCxHy(COOH)m. Ly mt lng axit aminoaxetic (X) v 3,82g (Y).
Nguyn Xun Dng

18

AMINO AXIT
Hai cht (X) v (Y) c cng s mol. t chy hon ton lng (X) v (Y) trn, th tch kh oxi cn dng t
chy ht (Y) nhiu hn t chy ht (X) l 1,344 lt (ktc). CTCT thu gn ca (Y) l
A. CH3NHCH2COOH.
B. H2NCH2CH2COOH. C. N(CH2COOH)3.
D. NC4H8 (COOH)2.
Cu 13: Ly m gam hn hp X gm hai amino axit c 1 nhm -NH2 v 1 nhm -COOH phn ng vi 55 ml
dung dch HCl 2M thu c dung dch Y . tc dng ht vi cc cht trong dung dch Y cn dng 70 ml
dung dch KOH 3M. Mt t chy hon ton m(g) X v cho sn phm chy qua dd KOH d th khi lng bnh
ny tng thm 14,85 gam. Bit t l phn t khi gia hai amino axit l 1,187. Cng thc phn t ca X :
A. C2H5 NO2 v C3H7NO2
B. C2H5NO2 v C4H9NO2
C. C2 H5NO2 v C5H11NO2
D. C3H7NO2 v C4H9NO2
Cu 14: Khi thy phn mt protein (X) thu c hn hp gm 2 aminoaxit no k tip nhau trong dy ng
ng. Bit mi cht u cha mt nhm NH2 v mt nhm COOH. t chy hon ton 0,2 mol hn hp
2 aminoaxit ri cho sn phm chy qua bnh ng dung dch NaOH d, thy khi lng bnh tng 32,8 gam.
Cng thc cu to ca 2 aminoaxit l
A. H2NCH(CH3)COOH, C2H5CH(NH2)COOH.
B. H2NCH2COOH, H2NCH(CH3)COOH.
C. H2NCH(CH3)COOH, H2N(CH2)3COOH.
D. H2NCH2COOH, H2NCH2CH2COOH.
Dng 6: Peptit v protein
S peptit ng phn c to thnh t n n v amino axit khc nhau l n! (cng CTPT)
C 2 n v amino axit th tch 1 phn t H2O
Vy c n n v amino axit th tch (n - 1) phn t H2 O
Mt phn t ipepit s cng 1 phn t H2O
Vy c 1peptit c n n v amino axit s cng (n-1) phn t H2O
Mt phn t dipepit s cng 2 phn t NaOH to ra 1 phn t H2O
Vy c 1peptit c n n v amino axit s cng n phn t NaOH to ra 1 phn t H2O
Mt phn t dipepit s cng 2 phn t HCl v 1 phn t H2O to sn phm mui
Vy c 1peptit c n n v amino axit s cng n phn t HCl v (n-1) phn t H2O to sn phm mui
Cu 1: Khi thy phn 500 g protein A thu c 170 g alanin. Nu phn t khi ca A l 50000 vC th s mt
xch alanin trong phn t ca A l
A. 190.
B. 191.
C. 192.
D. 193.
Cu 2: Cng thc no sau y ca tripeptit (A) tha iu kin sau:
+ Thy phn hon ton 1 mol A th thu c cc - amino axit l: 3 mol Glyxin , 1 mol Alanin, 1 mol Valin.
+ Thy phn khng hon ton A, ngoi thu c cc amino axit th cn thu c 2 ipeptit: Ala-Gly; Gly- Ala
v Gly-Gly-Val.
A. Ala-Gly-Gly-Gly-Val.
B. Gly-Gly-Ala-Gl y-Val.
C. Gly-Ala-Gly-Gly-Val.
D. Gly-Ala-Gly-Val-Gly.
Cu 3: Thu phn khng hon ton tetra peptit (X), ngoi cc - amino axit cn thu c cc ipetit: Gly-Ala;
Phe-Va; Ala-Phe. Cu to no sau y l ng ca X.
A. Val-Phe-Gly-Ala.
B. Ala-Val-Phe-Gly.
C. Gly-Ala-Val-Phe
D. Gly-Ala-PheVal.
Cu 4: Khi thy phn hon ton 1 polipeptit ta thu c cc aminoaxit X,Y,Z,E,F. Cn khi thy phn mt phn
th thu c cc i v tripeptit XE, ZY, EZ, YF , EZY. Hy la chn th t ng ca cc aminoaxit to thnh
polipeptit cho trn.
A. X-Z-Y-E-F;
B. X-E-Y-Z-F
C. X-E-Z-Y-F
D. X-Z-Y-E-F
Cu 5: Thu phn hon ton 1 mol pentapeptit X, thu c 2 mol gl yxin (Gly), 1 mol alanin (Ala), 1 mol
valin (Val) v 1 mol Phenylalanin (Phe). Thu phn khng hon ton X thu c ipeptit Val-Phe v tripeptit
Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l
A. Gly-Phe-Gly-Ala-Val
B. Gly-Ala-Val-Val-Phe
C. Gli-Ala-Val-Phe-Gly
D. Val-Phe-Gly-Ala-Gly
Cu 6: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong
phn t cha mt nhm NH2 v mt nhm COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng
CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong
d, to ra m gam kt ta. Gi tr ca m l
A. 120.
B. 60.
C. 30.
D. 45.
Cu 7: Ly 14,6g mt ipeptit to ra t glixin v alanin cho tc dng va vi dung dch HCl 1M. Th tch
dung dch HCl tham gia phn ng:
Nguyn Xun Dng

19

AMINO AXIT
A. 0,1 lit
B. 0,2 lt
C. 0,3 lt
D. 0,4 lt
Cu 8: Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC
th s mt xch alanin c trong phn t X l
A. 328.
B. 453.
C. 479.
D. 382.
Cu 9: Khi thy phn hon ton 0,1 mol tripeptit mch h X thu c alanin. t chy hon ton lng
alanin ny ly sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l:
A. 120.
B. 90.
C. 30.
D. 45.
Cu 10: Khi thy phn m (gam) protein A thu c 17,8 g alanin. Hy tnh m ?
Cu 11: Bradikinin c tc dng lm gim huyt p, l mt nonapeptit c cng thc l :
Arg Pro Pro Gly-Phe-Ser-Pro-Phe-Arg. Khi thy phn khng hon ton peptit ny c th thu c bao
nhiu tri peptit m thnh phn c cha phenyl alanin (Phe).
A. 3
B. 4
C. 5
D. 6
Cu 12. a) X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h, c
mt nhm -COOH v mt nhm -NH2. t chy hon ton 0,1 mol Y thu c sn phm gm CO2, H2O, N2,
trong tng khi lng ca CO2 v H2O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O2?
A. 2,8 mol
B. 2,025 mol
C. 3,375 mol
D. 1,875 mol
b)Tripeptit mch h X v tetrapeptit mch h Y u c to ra t mt amino axit no, mch h c 1 nhm
COOH v 1 nhm NH2. t chy hon ton 0,1 mol X thu c sn phm gm CO2, H2O, N2 trong tng
khi lng CO2 , H2O l 36,3 gam. Nu t chy hon ton 0,2 mol Y cn s mol O2 l:
A. 1,875
B. 1,8
C. 2,8
D. 3,375
Cu 13: Cho mt ipeptit Y c cng thc phn t C6 H12N2O3. S ng phn peptit ca Y (ch cha gc amino axit) mch h l
A. 6.
B. 7.
C. 5.
D. 4.
Cu 14: a) X l tetrapeptit Ala-Gl y-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v
Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung
dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l
A. 19,455.
B. 68,1.
C. 17,025.
D. 78,4
b) X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam
hn hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton
c cn dung dch thu c 257,36g cht rn khan. Gi tr ca m l:
A. 150,88 gam
B. 155,44 gam
C. 167,38 gam
D. 212,12 gam
c) X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v Y c t l s
mol nX : nY = 1 : 3 vi 780 ml dung dch NaOH 1M (va ), sau khi phn ng kt thc thu c dung dch Z.
C cn dung dch thu c 94,98 gam mui. m c gi tr l :
A. 68,1 gam.
B. 64,86 gam.
C. 77,04 gam.
D. 65,13 gam.
Cu 15: Tn gi cho peptit H2N-CH-CO-NH-CH2-CO-NH-CH-COOH
CH3
CH3
A. Ala-Gli-Ala.
B. Gli-Ala-Gli.
C. Gli-Ala-Val.
D. Ala-Ala-Gli.
Cu 16: X l mt tetrapeptit cu to t mt amino axit (A) no, mch h c 1 nhm COOH; 1 nhm NH2. Trong
A %N = 15,73% (v khi lng). Thy phn m gam X trong mi trng axit thu c 41,58 gam tripeptit; 25,6
gam ipeptit v 92,56 gam A. Gi tr ca m l:
A. 149 gam
B. 161 gam
C. 143,45 gam
D. 159 gam
Cu 17: Thy phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin, 1 mol alanin v 1 mol valin. Khi
thy phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly, Gly-Ala v tripeptit
Gly-Gly-Val. Vy trt t cu to cc amino axit trong pentapeptit A l:
A. Val-Gly-Gly-Gly-Ala.
B. Gly-Ala-Gly-Gly-Val.
C. Ala-Gly-Val-Gly-Gly.
D. Gly-Gly-Val-Gly-Ala.
Cu 18 a) Thu phn hon ton 150 gam hn hp cc ipeptit thu c 159 gam cc aminoaxit. Bit rng cc
ipeptit c to bi cc aminoaxit ch cha mt nguyn t N trong phn t. Nu ly 1/10 khi lng aminoaxit
thu c tc dng vi HCl d th lng mui thu c l:
A. 19,55 gam
B. 20,375 gam
C. 23,2 gam
D. 20,735 gam
b) Thy phn hon ton 60 gam hn hp hai ipetit thu c 63,6 gam hn hp X gm cc amino axit (cc
amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng
Nguyn Xun Dng

20

AMINO AXIT
vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l :
A. 7,09 gam.
B. 16,30 gam
C. 8,15 gam
D. 7,82 gam.
Cu 19: X l mt tripeptit c to thnh t 1 aminoaxit no, mch h c 1 nhm -COOH v 1 nhm -NH2. t
chy hon ton 0,3 mol X cn 2,025 mol O2 thu c sn phm gm CO2, H2O, N2. Vy cng thc ca amino
axit to nn X l
A. H2NC2H4COOH
B. H2NC3H6COOH
C. H2N-COOH
D. H2NCH2COOH
Cu 20: X l tetrapeptit (mch h) c to bi amino axit Y no, mch h, c mt nhm -COOH v mt
nhm -NH2. t chy hon ton 0,1 mol X thu c sn phm gm CO2, H2O, N2, trong tng khi lng
ca CO2 v H2O l 97,4 gam. S CTCT tho mn Y l:
A. 2
B. 1
C. 3
D. 5
Cu 21: Vi xc tc men thch hp cht h c G b thu phn hon ton cho hai aminoaxit thin nhin X v
Y vi t l s mol ca cc cht trong phn ng nh sau: 1 mol G + 2 mol H2O 2 mol X + 1 mol Y. Thu
phn hon ton 20,3 gam G thu c m1 gam X v m2 gam Y. t chy hon ton m2 gam Y cn 8,4 lt O2
kc thu c 13,2 gam CO2, 6,3 gam H2O v 1,23 lt N2 27oC, 1 atm. Y c cng thc phn t trng vi cng
thc n gin nht. X, Y v gi tr m1, m2 l.
A. NH2-CH2-COOH (15gam), CH2(NH2)-CH2-COOH; (8,95 gam).
B. NH2-CH2-CH2-COOH (15gam), CH3-CH(NH2)-COOH; (8,9 gam).
C. NH2-CH2-COOH (15gam), CH3-CH(NH2)-COOH, (8,9 gam).
D. NH2-CH2-COOH (15,5gam), CH3-CH(NH2)-COOH; (8,9 gam).
Cu 22: Tripeptit X c cng thc sau : H2NCH2 CONHCH(CH3)CONHCH(CH3)COOH.
Thy phn hon ton 0,1 mol X trong 400 ml dung dch NaOH 1M. Khi lng cht rn thu c khi c cn
dung dch sau phn ng l :
A. 28,6 gam.
B. 22,2 gam.
C. 35,9 gam.
D. 31,9 gam.
Cu 23: Phn t khi ca mt pentapeptit bng 373. Bit pentapeptit ny c to nn t mt amino axit m
trong phn t ch c cha mt nhm amino v mt nhm cacboxyl. Phn t khi ca amino axit ny l
A. 60,6.
B. 57,0.
C. 75,0.
D. 89,0.
Cu 24: X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m
gam hn hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon
ton c cn dung dch thu c 257,36g cht rn khan. Gi tr ca m l:
A. 167,38 gam
B. 150,88 gam
C. 212,12 gam
D. 155,44 gam
Cu 25: Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu
ipeptit khc nhau?
A. 4.
B. 2.
C. 3.
D. 1.
Cu 26: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong
phn t cha mt nhm NH2 v mt nhm COOH).t chy hon ton 0,1 mol Y, thu c tng khi lng
CO2 v H2O bng 54,9 gam. t chy hon ton m (g) X, lng CO2 sinh ra c hp th hon ton vo 600 ml
dd hn hp gm NaOH 0,1M v Ba(OH)2 0,2M sinh ra 11,82g kt ta. Tnh gi tr ca m
A. 1,6 v 6,4 gam
B. 1,6
C. 6,4
D. 8
Cu 27: Trong fibroin khi lng gc glyxyl chim 50%. Khi lng glyxin m cc con tm c to nn
1kg t l.
A. 646,55.
B. 500.
C. 386,66.
D. 556,5.
Cu 28: Khi thu phn hon ton 0,1 mol peptit A mch h (A to bi cc amino axit c mt nhm amino
v mt nhm cacboxylic) bng lng dung dch NaOH gp i lng cn phn ng, c cn dung dch thu c
hn hp cht rn tng so vi khi lng A l 78,2gam. S lin kt peptit trong A l:
A. 10
B. 20
C. 9
D. 18
Cu 29: Cho 0,1 mol mt peptit X ch c to thnh t mt -aminoaxit Y (ch cha 1 nhm amino v mt
nhm cacboxyl ) tc dng vi dung dch HCl va , sau phn ng thu c khi lng mui tng so vi ban
u l 30,9 gam. Mt khc t chy 0,1 mol X ri sc sn phm chy vo nc vi trong d thu c 180 gam
kt ta. Tn gi ca Y l.
A. Glyxin.
B. Alanin.
C. Valin.
D. Lysin.
Cu 30: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi
thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit
Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l
Nguyn Xun Dng

21

AMINO AXIT
A. Gly, Val.
B. Ala, Val.
C. Gly, Gly.
D. Ala, Gly.
Cu 31: Khi thy phn khng hon ton mt peptit A c khi lng phn t 293g/mol v cha 14,3% N
(theo khi lng) thu c 2 peptit B v C. Mu 0,472 gam peptit B khi em un nng, phn ng hon ton
vi 18 ml dung dch HCl 0,222 M. Mu 0,666 gam peptit C khi un nng, phn ng hon ton vi 14,7 ml
dung dch NaOH 1,6% (khi lng ring l 1,022 g/ml). Cu to c th c ca A l:
A. Ala-Phe-Gly hoc Gly-Phe-Ala
B. Phe-Gly-Ala hoc Ala-Gly-Phe
C. Phe-Ala-Gly hoc Gly-Ala-Phe
D. Phe-Ala-Gly hoc Ala-Gl y-Phe
Cu 32: Pht biu no sau y ng
A. Phn t peptit mch h c s lin kt peptit bao gi cng nhiu hn s gc -amino axit
B. Phn t peptit mch h to bi n gc -amino axit c cha (n 1) lin kt peptit
C. Cc peptit u c phn ng vi Cu(OH)2 to thnh phc cht c mu tm c trng
D. Phn t tripeptit c ba lin kt peptit
Cu 33: Cho 15 gam glyxin tc dng va vi 8,9 gam alanin thu c m gam hn hp tripeptit mch h.
Gi tr ca m l
A. 22,10 gam
B. 23,9 gam
C. 20,3 gam
D. 18,5 gam
Cu 34: X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amino axit no mch h, c
mt nhm - COOH v mt nhm -NH2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm
CO2, H2O, N2, c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y cho tc dng hon ton vi NaOH (ly d
20% so vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn?
A. 87,3 gam
B. 9,99 gam
C. 107,1 gam
D. 94,5 gam
Cu 35: Ly 8,76 g mt ipeptit to ra t glyxin v alanin cho tc dng va vi dung dch HCl 1M. Th tch
dung dch HCl tham gia phn ng l:
A. 0,1 lt
B. 0,06 lt
C. 0,24 lt
D. 0,12 lt
Cu 49: Trong hp cht sau y c my lin kt peptit?
H2N-CH2-CO-NH-CH-CO-NH-CH-CO-NH-CH2-CH2-CO-HN-CH2 -COOH
CH3
C6H5
A. 4.
B. 3.
C. 1.
D. 2.
Cu 50: Thy phn hon ton 1 mol oligopeptit X mch h thu c 2 mol Gly, 1 mol Ala, 1 mol Val, 1 mol
Tyr. Mt khc, nu thy phn khng hon ton thi thu c sn phn c cha Gly-Val, Val-Gly. S cng thc
cu to ph hp ca X l.
A. 4
B. 1
C. 2
D. 6
Cu 51: Mt peptit X khi thu phn hon ton ch thu c alanin. Bit phn trm khi lng N trong X bng
18,767%. Khi lng mui thu c khi cho 0,5 mol X tc dng vi dung dch KOH d l
A. 317,5 gam
B. 315,7 gam
C. 371,5 gam
D. 375,1 gam
Cu 52: Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s lin kt
CONH trong 2 phn t l 5) vi t l s mol nX : nY = 1:3 .Khi thy phn hon ton m gam M thu c
81gam glixin v 42,72 gam alanin. m c gi tr l
A. 104,28 gam
B. 109,5 gam
C. 116,28 gam
D. 110,28 gam
Cu 53: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi
thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit
Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l:
A. Gly, Gly.
B. Ala, Val.
C. Ala, Gly.
D. Gly, Val.
Cu 54: Thc hin tng hp tetra peptit t 5,0 mol glixin 4,0 mol alanin v 7,0 mol axit -2-aminobutanoic.
Bit phn ng xy ra hon ton, khi lng tetrapeptit thu c l
A. 1236 gam.
B. 1164 gam
C. 1452 gam
D. 1308 gam
Cu 55: Khi thy phn mt octanpetit X c cng thc cu to l Gly-Phe-Tyr-Lys-Gly-Phe-Tyr th thu c
bao nhiu tripeptit c cha Gly?
A. 3.
B. 4.
C. 5.
D. 6.
Cu 56: X l mt tetrapeptit. Cho m gam X tc dng va vi 0,3 mol NaOH thu c 34,95g mui. Phn
t khi ca X c gi tr l:
A. 324
B. 432
C. 234
D. 342
Cu 57: Tripeptit M v tetrapeptit Q u c to ra t mt amino axit X mch h, phn t c mt nhm
-NH2. Phn trm khi lng ca N trong X l 18,667%. Thu phn khng hon ton m gam hn hp M, Q (t
l mol 1: 1) trong mi trng axit thu c 0,945 gam M; 4,62 gam ipeptit v 3,75 gam X. Gi tr ca m l
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AMINO AXIT
A. 8,389.
B. 58,725.
C. 5,580.
D. 9,315.
Cu 58: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32
gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l
A. 90,6.
B. 111,74.
C. 81,54.
D. 66,44.
Cu 59: Khi thy phn khng hon ton pentapeptit Ala-Gly-Val-Gly-Ala c ti a bao nhiu tripeptit khc
nhau?
A. 1.
B. 4.
C. 3.
D. 2.
Cu 60: Thy phn 25,6 gam polipeptit X thu c 15 gam glyxin v 17,8 gam alanin. Cng thc cu to ca
mt xch c bn phn t X l :
A. [-NHCH2CO-NHCH(CH3)-CO-]
B. [-NHCH2CO-NHCH(CH3)-CO-NHCH2CO-]
C. [-NHCH2CO-NHCH(CH3)-CO-NHCH(CH3)CO-]
D. [-NHCH2CO-NHCH(CH3)-CO-NHCH(CH3)CO-NHCH2CO-]
Cu 61: X l tetrapeptit AlaGlyValAla, Y l tripeptit ValGlyVal. un nng m gam hn hp X v Y c t
l s mol nX : nY = 1:3 vi 1560 ml dung dch NaOH 1M (dng d gp 2 ln lng cn thit), sau khi phn ng
kt thc thu c dung dch Z. C cn dung dch thu c 126,18 gam cht rn khan. m c gi tr l :
A. 68,1 gam
B. 75,6 gam
C. 66,7 gam
D. 78,4 gam
Cu 62: Cho cc cu sau:
(1). Peptit l hp cht c hnh thnh t 2 n 50 gc amino axit.
(2). Tt c cc peptit u phn ng mu biure.
(3). T 3 - amino axit ch c th to ra 3 tripeptit khc nhau.
(4). Khi un nng nung dch peptit vi dung dch kim, sn phm s c phn ng mu biure.
S nhn xt ng l:
A. 1
B. 2
C. 3
D. 4
Cu 63: Cho cc pht biu sau:
(1). Phn t ipeptit c hai lin kt peptit.
(2). Phn t tripeptit c 3 lin kt peptit.
(3). S lkt peptit trong pt peptit mch h c n gc - amino axit l n-1.
(4). C 3 -amino axit khc nhau, c th to ra 6 peptit khc nhau c y cc gc -amino axit . S nhn
nh ng l:
A. 1
B. 2
C.3
D.4
Cu 64: Thc hin phn ng trng ngng hn hp gm glixin v alanin. S ipeptit c to ra r glixin v
alanin l:
A. 2
B. 3
C. 4
D. 5
Cu 65: X l mt tetrapeptit cu to t Aminoaxit A, trong phn t A c 1 nhm -NH2 v 1 nhm -COOH no,
mch h. Trong A Oxi chim 42,67% khi lng . Thy phn m gam X trong mi trng acid th thu c
28,35g trpeptit; 79,2g ipeptit v 101,25g A. Gi tr ca m l?
A. 184,5.
B. 258,3.
C. 405,9.
D. 202,95.
Cu 66: Thy phn hon ton 143,45 gam hn hp A gm hai tetrapeptit thu c 159,74 gam hn hp X gm
cc Aminoaxit(cc Aminoaxit ch cha 1nhm COOH v 1 nhm NH2). Cho ton b X tc dng vi dung dch
HCl d, sau c cn dung dch th nhn c m(gam) mui khan. Khi lng nc phn ng v gi tr ca m
ln lt bng?
A. 8,145(g) v 203,78(g).
B. 32,58(g) v 10,15(g).
C. 16,2(g) v 203,78(g)
D. 16,29(g) v 203,78(g).
Cu 67: X l mt hexapeptit cu to t mt Aminoaxit H2N-CnH2n-COOH (Y). Trong Y c tng % khi lng
Oxi v Nito l 61,33%. Thy phn ht m(g) X trong mi trng acid thu c 30,3(g) petapeptit, 19,8(g) ieptit
v 37,5(g) Y. Gi tr ca m l :
A. 69 gam.
B. 84 gam.
C. 100 gam.
D. 78 gam.
Cu 68: Thy phn 14(g) mt Polipeptit X vi hiu sut t 80%,th thu c 14,04g mt - Aminoaxit Y.
Xc nh cng thc cu to ca Y?
A. H2N(CH2)2COOH.
B. H2NCH(CH3)COOH.
C. H2NCH2COOH
D. H2NCH(C2H5)COOH
Cu 69: Xc nh phn t khi gn ng ca mt Polipeptit cha 0,32% S trong phn t. Gi s trong phn t
ch c 2 nguyn t S?
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AMINO AXIT
A. 20.000(vC)
B. 10.000(vC).
C. 15.000(vC).
D. 45.000(vC
Cu 70: un nng alanin thu c mt s peptit trong c peptit A c phn trm khi lng nit l 18,54%.
Khi lng phn t ca A l :
A. 231.
B. 160.
C. 373.
D. 302.
Cu 71: Khi thy phn hon ton 55,95 gam mt peptit X ch thu c 66,75 gam alanin. X l:
A. tripeptit.
B. tetrapeptit.
C. pentapeptit.
D. ipeptit.
Cu 72: Khi thy phn hon ton 65 gam mt peptit X thu c 22,25 gam alanin v 56,25 gam glyxin. X l :
A. tripeptit.
B. tetrapeptit.
C. pentapeptit.
D. ipeptit.

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