A.

cAc CONG THUC CAN NHO

1. Tinh sa mol:

a) Tinh s6 mol khi bH~t kh6i IU'Q'ng(m) :

I F ~ ~>m~M.n I

b) Tinh s6 mol khi bH~t th@ tich khi fr dktc.

V(lit)

n =-- => V= n.22 4

224 '

,

c) Tinh s6 mol khi bH~t n6ng d{l moIllit(CM)

n = CM. V (lit) => V = _!!_ CM

d) Tinh s6 mol khi fr di@u ki~n khfmg chu§n.

P.V

n=--

R.T

P: Ap su~t(atm), V: Th6 tich(lit) R= 0,082

T= 273 +tOC

2. Tinh n6ng do:

at N6ng d{l ph§n triim(C%)

CO/ - met 1000/ _ _ C%.mdd

/0 - • /0 -> m - --.....:;;;;;_

mdd et 100%

i eM = V(~it)

3. Khai IU'ang rU~ng ella dung dieh(d) ! m"d = V(ml).d(glml)

4. Lien quan giua CM va C%

C = C%.lO.d => C% = CM·M

M M 10.d

1

5. Rieu su~t ph~m ung(R):

C 1: Tinh thea san ph~m:

H = mtt .100% mit

C2: Tinh thea eh~t phan irng:

m

H% = tgpu .100%

mbd

6. Ti kh6i:

MA MB

7. D6i dan vi:

111t = 1000ml; 111t = l drrr' ; 1ml = l crrr'

8. CT Hnh % kh6i hidng ella 1 h6n hdp:

H6n hop g6m A co khdi hrong rnA va B co khdi hrong mB

%A = mA x100% mhh

%B = mB x 100% hoac %B = 100% - %A

mhh

2

lANG TRia M cAc CHA'T THONG DIING

@.Juk tJii gik M @.hUL hila eo' M @.hUL tJij eo' JIl @.hUL tJij eo' M
C 12 HCHO 30 H2O 18 FeO 72
H 1 CH3CHO 44 CO2 44 Fe203 160
0 16 C2HsCHO 58 CO 28 Fe304 232
N 14 CH30H 32 H2SO4 98 Fe(OH)z 90
Na 23 C2HsOH 46 RN03 63 Fe(OH)3 107
Ca 40 C3H7OH 60 HCI 36.5 FeS04 152
Mg 24 C4H9OH 74 NaOH 40 Fe2(S04)3 400
K 39 CSHllOH 88 KOH 56 FeS2 129
Ba 137 HCOOH 46 CaO 56 CuO 80
Fe 56 CH3COOH (C2H402) 60 Ca(OH)z 74 Cu(OH)z 98
Zn 65 C2HsCOOH (C3H602) 74 Ba(OH)z 171 CUS04 160
Cu 64 C3H7COOH (C4Hg02) 88 CaC03 100 Ah03 102
Al 27 C1sH31COOH A Pamitic 256 Ca(HC03)z 162 AI(OH)3 78
Ag 108 C17H3SCOOH A Stearic 284 BaC03 197 Ah(S04)3 342
Br 80 C17H33COOH AOleic 282 Ba(HC03)z 259 Cr203 152
I 127 C17H31COOH A linoleic 280 Na2C03 106 Cr(OH)3 103
-CHO 29 C17H29COOH A linolenic 278 NaHC03 84 Cr2(S04)3 392
-COOH 45 C3Hs(OH)3 Glierol 92 K2C03 138 N oangllglixerat 246
-COO- 44 (C17H3SCOO)3C3Hs tristearin 890 KHC03 100
-OH 17 (C17H33COO)3C3Hs triolein 884 AgCI 143.5
-NH2 16 (ClsH31COO)3C3Hs tripanmitin 806 NaCI 58.5
-CH3 15 C6HSNH2 Anilin 93 Na2S04 142
-C2HS 29 C6HsOH Phenol 94 BaS04 233
-C3H7 43 NH2CH2COOH Glyxin 75 AgN03 170
-C4H9 57 CH3CH(NH2)-COOH Alanin 89 MgO 40
-CSHll 71 C6H1206 fructozo / Glucozo 180
-C6HS 77 (C6HlOOS)n Tinh boat/ xenlulozo 162n
CH2=CH- 27 C12H22011 Mantozo/ Saccarozo 342 CHUONG 1: ESTE - LIPIT I> TRA.C NGHIEM LY THyuET.

CaD 1: S6 dang phan este irng voi cong tlnrc phan til C3H602lll

A.5. B.4. C.2. D.3.

CaD 2: S6 dang phan este irng voi cong tlnrc phan til C4Hg02lll

A.2. B.3. C.4. D.5.

CaD 3: S6 dang phan dan clnrc irng voi cong tlnrc phan til C3H602lll

A.2. B.3. C.4. D.5.

CaD 4: S6 dang phan dan clnrc irng voi cong tlnrc phan til C4Hg02lll

A.6. B.3. C.4. D.5.

CaD 5: Cho t~t ca cac dang phan dan clnrc, mach ho, co cung cong tlnrc phan til C2H402lAn hrot tac dung voi: Na, NaOH, NaHC03. S6 phan irng xay ra III

A.2. B.5. C.4. D.3.

CaD 6: Ch~t X co cong tlnrc phan til C3H602, III este cua axit axetic. Cong tlnrc du tao thu gon cua X III

A. C2HsCOOH. B. HO-C2H4-CHO. C. CH3COOCH3. D. HCOOC2Hs.

3

Call 7: HQ'P ch~t X co cong tlnrc du tao: CH3CH2COOCH3. Ten goi cua X la:

A. etyl axetat. B. metyl propionat. C. metyl axetat. D. propyl axetat.

Call 8: Thuy phan este E co cong tlnrc phan til C4Hg02 (co ~t H2S04 loang) thu ducc 2 san pham him co X va Y. Til X co th6 di6u ch6 tnrc ti6p ra Y bang mQt phan irng duy nhdt, Ten goi cua E la:

A. metyl propionat. B. propyl fomat. C. ancol etylic. D. etyl axetat.

Call 9: Este etyl axetat co cong tlnrc la

A. CH3CH20H. B. CH3COOH. C. CH3COOC2Hs. D. CH3CHO.

Call 10: Dun nang este HCOOCH3 voi mQt hrong vira du dung dich NaOH, san pham thu ducc la

A. CH3COONa va C2HsOH. B. HCOONa va CH30H.

C. HCOONa va C2HsOH. D. CH3COONa va CH30H.

Call 11: Este etyl fomiat co cong tlnrc la

A. CH3COOCH3. B. HCOOC2Hs. C. HCOOCH=CH2. D. HCOOCH3.

Call 12: Dun nang este CH3COOC2Hs voi mQt hrong vira du dung dich NaOH, san pham thu ducc la

A. CH3COONa va CH30H. B. CH3COONa va C2HsOH.

C. HCOONa va C2HsOH. D. C2HsCOONa va CH30H.

Call 13: Thuy phan este X trong moi tnrong kiem, thu ducc natri axetat va ancol etylic. Cong tlnrc cua X la

A. C2H3COOC2Hs. B. CH3COOCH3.

C. C2HsCOOCH3.

D. CH3COOC2Hs.

Call 14: Este metyl acrilat co cong tlnrc la

A. CH3COOCH3. B. CH3COOCH=CH2.C. CH2=CHCOOCH3. D. HCOOCH3.

Call 15: Este vinyl axetat co cong tlnrc la

A. CH3COOCH3. B. CH3COOCH=CH2. C. CH2=CHCOOCH3. D. HCOOCH3.

Call 16: Dun nang este CH3COOCH=CH2 voi mQt hrong vira du dung dich NaOH, san pham thu ducc la

A. CH2=CHCOONa va CH30H. B. CH3COONa va CH3CHO.

C. CH3COONa va CH2=CHOH. D. C2HsCOONa va CH30H.

Call 17: Dun nang este CH2=CHCOOCH3 voi mQt hrong vira du dung dich NaOH, san pham thu ducc la

A. CH2=CHCOONa va CH30H. B. CH3COONa va CH3CHO.

C. CH3COONa va CH2=CHOH. D. C2HsCOONa va CH30H.

Call 18: Khi d6t chay hoan toan mQt este no, don clnrc thi s6 mol C02 sinh ra bang s6 mol 02 da phan

irng, Ten goi cua este la A. n-propyl axetat. B. metyl axetat. C. etyl axetat. D.

metyl fomiat.

Call 19: Hai chat him co Xi va X2 d6u co kh6i hrong phan til bang 60 dvC. Xi co kha nang phan irng voi: Na, NaOH, Na2C03. Xz phan irng voi NaOH (dun nang) nlnrng khong phan irng Na. Cong tlnrc du

tao cua x., X2lAn hrot la.A, CH3-COOH, CH3-COO-CH3. B. (CH3)2CH-OH, H-COO-CH3.

C. H-COO-CH3, CH3-COOH. D. CH3-COOH, H-COO-CH3.

Call 20: Cho sa d6 chuyen hoa sau (m6i miii ten la mQt phuong trinh phan irng):

Tinh bQt ~ X ~ Y ~ Z ~ metyl axetat. Cac ch~t Y, Z trong sa d6 tren IAn hrot la:

A. C2HsOH, CH3COOH. B. CH3COOH, CH30H.

C. CH3COOH, C2HsOH. D. C2H4, CH3COOH.

Call 21: MQt este co cong tlnrc phan til la C4H602, khi thuy phan trong moi tnrong axit thu ducc axetandehit. Cong tlnrc du tao thu gon cua este do la

A. HCOO-C(CH3)=CH2. B. HCOO-CH=CH-CH3.

C. CH3COO-CH=CH2. D. CHz=CH-COO-CH3.

Call 22: Cho glixerol phan irng voi h6n hQ'P axit beo g6m C17H3SCOOH va CIsH3ICOOH, s6 loai trieste

ducc tao ra t6i da IliA. 6. B.3. C.5. D.4.

Call 23: Cho cac ch~t: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni c1orua, ancol benzylic, p-crezol. Trong cac ch~t nay, s6 ch~t tac dung ducc voi dung dich NaOH la

A.4. B.6. C.5. D.3.

Call 24: Khi thuy phan ch~t beo trong moi tnrong kiem thi thu ducc muoi cua axit beo va

4

A. phenol. B. glixerol. C. ancol dan clnrc, D. este dan clnrc,

Call 25: Khi xa phong hoa tristearin ta thu ducc san pham la

A. C1sH31COONa va etanol. B. C17H3SCOOH va glixerol.

C. C1sH31COOH va glixerol. D. C17H3SCOONa va glixerol.

Call 26: Khi xa phong hoa tripanmitin ta thu ducc san pham la

A. C1sH31COONa va etanol. B. C17H3SCOOH va glixerol.

C. C1sH31COONa va glixerol. D. C17H3SCOONa va glixerol.

Call 27: Khi xa phong hoa triolein ta thu ducc san pham la

A. C1sH31COONa va etanol. B. C17H3SCOOH va glixerol.

C. C1sH31COONa va glixerol. D. C17H33COONa va glixerol.

Call 28: Khi thuy phan trong moi tnrong axit tristearin ta thu ducc san pham la

A. C1sH31COONa va etanol. B. C17H3SCOOH va glixerol.

C. C1sH31COOH va glixerol. D. C17H3SCOONa va glixerol

Call 29: Este co cong tlnrc phan til C3H602 co g6c ancol la etyl thi axit tao nen este do la

A. axit axetic B. Axit propanoic C. Axit propionic D. Axit fomic

Call 30: Khi d6t chay hoan toan han hQ'P cac este no, dan clnrc, mach ho thi san pham thu ducc co:

A. s6 mol CO2 = s6 mol H20. B. s6 mol CO2> s6 mol H20.

C. s6 mol CO2 < s6 mol H20. D. kh6i hrong CO2 = kh6i hrong H20.

Call 31: Cong tlnrc tang quat cua este mach (he) ducc tao thanh til axit no, dan clnrc va ancol no, dan

clnrc la A. CnH2n-lCOOCmH2m+l . B. CnH2n-lCOOCmH2m-l .

C. CnH2n+lCOOCmH2m-l . D. CnH2n+lCOOCmH2m+l

Call 32: San pham phan irng xa phong hoa vinyl axetat co chua chat nao sau day?

A. CH2=CHCI B. C2H2 C. CH2=CHOH D. CH3CHO

Call 33: Metyl propionat la ten goi cua hQ'P chat co cong tlnrc du tao nao sau day?

A. HCOOC3H7 B. C2HsCOOCH3 C. C3H7COOH D. CH3COOC2Hs

Call 34:Metyl fomiat phan irng voi chat nao sau day?

A. Dung dich NaOH.

C. Dung dich AgN03 trong amoniac.

Call 35:Etyl axetat co th6 phan irng voi chat nao sau day?

A. Dung dich NaOH.

C. Dung dich AgN03 trong mroc amoniac.

Call 36: Ch~t nao duoi day khong phai la este?

A. HCOOCH3 . B.CH3COOH . C.CH3COOCH3. D.HCOOC6HS.

Call 37 :Este C4Hg02 tham gia ducc phan irng trang bac, co cong tlnrc du tao nlnr sau

A. CH3COOC2Hs. B. C2HsCOOCH3.

B. C. CH3COOCH=CH2. D. HCOOCH2CH2CH3.

Call 38: Khi thuy phan b~t ky chat beo nao ciing thu ducc

A. glixerol. B. axit oleic. C. axit panmitic.

Call 39: Phan irng thuy phan este trong dd axit:

A. La phan irng xa phong hoa B. La pir dung d6 di6u ch6 axit va ancol

C. Luon tao san pham la axit va ancol D. La pir thuan nghich

Call 40: Khi thuy phan ch~t nao sau day se thu ducc glixerol?

A. Lipit. B. Este dan clnrc, C. Ch~t beo,

Call 41: Ma tu nhien co thanh phAn chinh la

A. este cua axit panmitic va cac dang dllng. B. muoi cua axit beo,

C. cac triglixerit . D. este cua ancol voi cac axit beo,

Call 42: Trong cac hQ'P chat sau, hQ'P ch~t nao thuoc loai chat beo?

A. (C17H31COO)3C3Hs. B. (C16H33COO)3C3Hs.

C. (C6HsCOO)3C3HS. D. (C2HsCOO)3C3HS.

Call 43: D6 di6u ch6 xa phong, nguci ta co th6 tlnrc hien phan irng

A. Dun nang axit beo voi dd kiem B. Dun nang glixerin voi axit beo

5

B. Natri kim loai,

D. H20 (xuc tac H+)

B. Natri kim loai,

D. Dung dich Na2C03.

D. axit stearic.

D. Etyl axetat.

C. Dun nang lipit voi dd kiem D. A, C dung

Call 44 Dun han hQ'P glixerol va axit stearic, axit oleic ( co H2S04 lam xuc tac) co th6 thu ducc mAy loai trieste dang phan du tao cua nhau?

A 3 . B. 5 . C. 4 . D. 6 .

Call 45:. Este co CTPT C2H402 co ten goi nao sau day:

Aetyl axetat B. metyl propionat C. metyl fomat D. etyl fomat

Call 46: Este co cong tlnrc phan til CH3 -COO-CH3 co ten goi la:

A. metyl axetat. B. vinyl axetat. C. metyl fomiat. D. metyl propionat

Cau 47 Chon phat bieu dung:

a. Pharr ling thuy pharr este trong dd kiern la pharr ling thuan nghich

b. Pharr ling thuy pharr este trong dd axit thu diroc mu6i va ancol

c. Este co th~ tac dung dong thoi voi dd NaOH va Na

d. Este co nhiet d9 soi thap han so voi axit tirong ling

Cau 48: Tim cau sai trong cac cau sau:

a. Este cua axit thirong la nhfrng chat long, de bay hoi

b. Isoamyl axetat co mui chu6i

c. Do khong co lien ket hidro giita cac pharr tit nen este co nhiet d9 soi thap han axit urong ling

d. Khi d6t chay este no, dan clnrc co sO' mol C02l6n han sO' mol H20

Call 49: Cho cac ch~t sau: CH30H (1); CH3COOH (2); HCOOC2Hs (3). Thu 11,r nhiet dQ soi giam dAn la

A. (3);(1);(2). B. (2);(1);(3). C. (1);(2);(3). D. (2);(3);(1).

Call 50: B6n cha"t sau day deu co khdi hrcng phan til' 60. Char co nhiet d9 soi cao nhat?

A H-COO-CH3 B. HO-CH2-CHO C. CH3-COOH D. CH3-CH2-CH2-OH

Call 51: Este X co CTPT C4Hg02 co th6 ducc tao nen til ancol metylic va axit nao duoi day

A. Axit propionic. B. Axit butiric. C. Axit fomic. D. Axit axetic.

Call 52: S6 hQ'P ch~t dan clnrc, dang phan du tao cua nhau co cung cong tlnrc phan til C4Hg02, d6u tac dung voi dung dich NaOH

A3 BA C.5 D.6 (CD 2007)

Call 53: Xac dinh nhan xet khong dung v6 chat giat rna tang hQ'P trong cac nhan xet sau:

A Gay hai cho da khi gi~t bang tay B. Dung ducc cho ca mroc cirng

C. Khong gay 0 nhiem moi tnrong D. T~y trang va lam sach quan ao han xa phong

Call 54: Ung voi cong tlnrc C3H602 co bao nhieu dang phan tac dung ducc voi dung dich NaOH?

A. 2 B. 3 C. 4 D. 1

Call 55 .Thuy phan 0,2 mol este CH3COOC6HS cAn dung bao nhieu mol NaOH

A 0,1 mol B. 0,2 mol C. 0,3 mol D. 0,4 mol

Call 56: Ch~t hiru co X khi dun nang voi NaOH thi thu ducc ancol etylic va muoi natri axetat. V~y

CTPT cua esteX la: AC2H402 B. C3H602 C. C4Hg02 D. CH202

Call 57: Ch~t nao sau day cho k6t tua do gach voi Cu(OHh khi dun nang.

AHCHO B.HCOOCH3 C.HCOOC2HS D.Ca 3 ch~t tren,

Call 58: Ch~t nao sau day tham gia phan irng trang guong:

A. CH3COOH. B. C3H7COOH. C. HCOOC3H7.

D.

CH3COOCH3

Call 59: MQt este co cong tlnrc phan til la C3H602 co phan irng trang guong voi dd AgN03 trong NH3 Cong tlnrc du tao cua este do la cong tlnrc nao?

A HCOOC2Hs B. CH3COOCH3 C. HCOOC3H7 D. C2HsCOOCH3

Cau 60: Thuy phan este trong moi tnrong kiem va dun nang goi la:

A Xa phong hoa B. Hidrat hoa D. Crackinh D. S1,f len men

Call 61: Dun nang este X co CTPT C4Hg02 trong dd NaOH thu ducc muoi natri va ancol metylic v~y

X co CTCT la :A CH3COOC2Hs B. HCOOCH2CH2CH3 C.HCOOCH(CH3h D.

CH3CH2COOCH3

6

Call 62: Este nao sau day sau khi thuy phan trong moi tnrong axit thu ducc h6n hQ'P san pham gam 2 ch~t d6u tham gia phan irng voi dd AgN03INH3

A. HCOOCH2CH3 B. CH3COOCH2CH3

C.HCOOCH=CH-CH3 D. HCOOCH2CH

Call 63: MQt este co cong tlnrc phan til III C4Hg02, khi thuy phan trong moi tnrong axit thu duoc nrou etylic,CTCT cua C4Hg02 III

A. C3H7COOH B. CH3COOC2Hs C. HCOOC3H7 D. C2HsCOOCH3

Call 64:Este C4Hg02 tham gia phan irng trang bac co th6 co ten sau:

A. C2HsCOOCH3 B. C3H7COOH. C. HCOOC3H7. D.

CH3COOCH3

Call 65:Cho chu6i bien d6i sau: C2H2 ----)0 X ----)0 Y ----)0 Z ----)0 CH3COOC2Hs .X, Y, Z IAn hrot Ill:

A. C2H4, CH3COOH, C2HsOH B. CH3CHO, C2H4, C2HsOH

C. CH3CHO, CH3COOH, C2HsOH D. CH3CHO, C2HsOH, CH3COOH

Call 66 : Este CH3COO~Hs phan ling duoc voi chat nao sau day?«, HCl b. K c. Dd Br2 d.

NaOH

Call 67: Este CH3COOC2Hs khong phan ling duoc voi chat nao sau day?

a. H20 b.KOH c. ~HsOH d. NaOH

Call 68: CH3COO~Hs va CH3COOH cung tac dung diroc voi chat nao sau day?

a. Ca b. CH30H c. KOH d. H20

Call 69: Chat nao sau day tac dung diroc voi CH30H rna khong tac dung voi CH3COOC2Hs?

a. K b. KOH C. H20 d. CU(OH)2

Call 70: Chat nao sau day tac dung diroc voi CH3COOC2Hs rna khong tac dung voi CH30H?

a. Na b. NaOH c. AgNOjNH3 d. CU(OH)2

Call 71: Chat nao sau day tac dung d6ng thoi voi phenol va metyl axetat?

a. NaOH b. H20 c. ddBr2 d. K

Call 72: Chat nao sau day tac dung voi phenol rna khong tac dung voi etyl fomat

a. KOH b. ddBr2 c. H20 d. CuO

Call 73: Khi thuy pharr Etyl axetat trong dd H20 thi san pham cua phan ling la:

a. CH3COONa va CH30H b. CH3COOH va C2HsOH

c. CH3COONa va C2HsOH d. ~HsCOONa va CH30H

Call 74: Khi thuy pharr Etyl fomat trong dd H20 thi san pham cua phan ling la:

a. CH3COONa va CH30H b. HCOOH va C2HsOH

c. HCOONa va C2HsOH d. ~HsCOOH va CH30H

Call 75: Phan ling este hoa giita ancol Metylic va axit axetic tao thanh san pharr co ten goi la gi?

A. Metyl axetat B. axyletylat C. Etyl axetat D. axetyl atylat.

Call 76: Phan ling este hoa giita ancol etylic va axit axetic tao thanh san pharr co ten goi la gi?

A. Metyl axetat B. axyletylat C. Etyl axetat D. axetyl atylat.

Call 77: Khi thuy pharr vinyl axetat trong moi tnrong axit thu diroc nhfrng chat gi?

A. axit axetic va nrou vinylic B.Axit axetic va andehit axetic

C. axit axetic va nrou etylic D. axetat va nrou vinylic

Call 78 : Thuy pharr este C4H602 trong moi tnrong axit ta thu diroc m9t h6n hop cac chat deu co phan ling trang girong, V ~y cong thuc diu t{1O clla este co thi ta if dap an sau day?

A. CH3COOCH = CH2 B. HCOOCH2 - CH = CH2 C.HCOOCH=CH-CH3 D. CH2 = CH - COOCH3. Call 79: Thuy pharr este C4H602 trong moi tnrong axit ta thu diroc m9t h6n hop cac chat deu khong co phan ling trang girong, V ~y cong thuc cdu t{1O clla este co thi ta if dap an sau day?

A. CH3COOCH = CH2 B. HCOOCH2 - CH = CH2

C. HCOOCH = CH - CH3 D.CH2=CH-COOCH3

Call 80: M9t este co cong tlnrc pharr tit la C3H602, co phan ling trang girong voi dung dich AgN03 trong NH3. Cong thuc cdu t{1O clla este do ta cong thuc nao?

A. HCOO~HsB. CH3COOCH3 C. HCOOC3H7 D. C2HsCOOCH3

Cau 81 :Cho cac cau sau:

7

a. Chat ben thuoc loai hop chat este.

b. Cac este khong tan trong mroc do nhe han mroc.

c. Cac este khong tan trong mroc do khong co lien ket hidro voi mroc,

d. Khi dun chat ben long voi hidro co Ni xiic tac thi thu diroc chat ben ran

e. Chat ben long la cac triglixerin clnra goc axit khong no. Nhiing cau nao khong dung?

A. a, d B. b, c C. a, b, d, e D. b

Cau 82;,. Co cac nh(in dinh' sau:

1. Chat bOO la trieste cua gilxerol vm cac axit monocacboxylic co mach C dai khong pharr nhanh,

2. Lipit g6m chat beo, sap, sterit, photpholipit, ...

3. Chat ben la cac chat long.

4. Chat bOO clnia cac g6c axit khong no thnong la chat long a nhiet dt'_) tlnrong va ducc goi la MU.

5. Phan iing thuy pharr chat boo trong moi tnrong kiem la phan iing thuan nghich,

6. Chat ben la thanh phan chfnh cua dau rna dong, thirc vat, Cdc nh(in dinh' dung la:

A. 1,2,4,5 B. 1,2,4,6 C. 1,2,3 D. 3,4,5

Cau 83;,. CO hai bmh khong nhan dung rieng biet hai loai h6n hop: MU boi tron may, MU thirc vat, Co thi nh(in bitt hai hon hap tren bdng cacb nao ?

A. Dung KOH dir B. Dung CU(OH)2

C DUng NaOH dun n6ng D. Dun n6ng voi dd KOH, de nguoi, cho them timg giot dd CuS04

Cau 84;,. Xa phong diroc dieu che bang each nao trong cac each sau:

A. Pharr huy rna B. Thuy pharr rna trong kiem

C. Phan iing cua axit voi kim loai D. Dehidro hoa rna tv nhien

Cau 85: Chon cau sai trong cac cau sau:

A. Xa phong la san pham cua phan iing xa phong hoa,

B. Muoi natri cua axit hiru CO la thanh phan chfnh cua xa phong,

C Khi dun n6ng chat bOO voi dung dich NaOH hoac KOH ta dln;1C muoi d~ san xuai xa phong, D. TIt dau rna co th~ san xuat diroc chat gi~t rita t6ng hop va xa phong,

Cau 86: Sllpx6p thea thir tu nhiet dQ soi cua cac chat: Aneol etylie, Axitaxetie, etylaxetat

A. Aneol etylie< Axitaxetie< etylaxetat B. Aneol etylie<etylaxetat < Axitaxetie

C. etylaxetat < Aneol etylie< Axitaxetie D. etylaxetat < Axitaxetie < Aneol etylie

Cau 87 : Khong nen dung xa phong khi gi~t rita voi mroc ciing VI:

A. Xuat hien ket tiia lam giam tac dung gi~t rita va anh huang den chat luong s¢ vai,

B. Gay hai cho da tay.

C. Gay 6 nhiern moi tnrong,

D. Tao ra ket tua CaC03, MgC03 bam len soi vai, Cau 88: Ch~t giat rita tang hop co iru di6m la

A. co th6 dung d6 giat rita ca trong mroc cirng B. re ti6n han xa phong

C. d6 kiem D. co kha nang hoa tan t6t trong mroc

Cau 89:_MQt este co cong tlnrc phan til la C4H602, khi thuy phan trong moi tnrong axit thu ducc han hop cac chat d6u co kha nang trang guong, Cong thirc du tao thu gon cua este do la?

A. HCOO-C(CH3)=CH2. B. HCOO-CH=CH-CH3.

C. CH3COO-CH=CH2. D. CHz=CH-COO-CH3.

II. TRAc NGHIEM BAI TAp

. .

DANG 1: TIM CTPT CVA ESTE NO, DON CHUC

DITA vAo PUDDT CHAy

Phu-O'ng phap: + f)~t CTTQ cua este: CnH2n02

3n-2

+ Vi6t ptpir chay: CnH2n02 + -- O2 -7 nC02 + n H20

2

+ f)~t s6 mol cua CO2 hoac H20 van ptr riJi suy ra s6 mol cua CnH2n02

8

+ TilCT : M =m Th6 cac dfr kien d6 bai eho vao CT => n => CTPT cAn tim.
C.H2.02 «'
D§u hieu: + nH20 = nco
2
+ Este ducc tao boi axit no don chuc va ancol no don chu».
+ Nhin vao dap an n6u chi toan la este no dan chirc
=> N@u th§y co 1 trong 3 d§u hi~u nay thi efr d~t CTTQ la (!;.nH2n02} r6i ghii nhu hutrng d§n 0-
tren.
, Vd: Dot chdy hoan toan 2,2 gam este Xthu duac 2,24 lit CO2 (dkte) va 1,8 gam H20. CTPT cua Xla:

a. C2H402 b. C3H602 e. C4Hs02 d. C5HlO02

HD: Nhan thay: n C02 n H20 = 0,1 mol do d6 ta dat CTTQ cua este la

3n-2 to

CnH2n02 + (-2-)02 ~nC02 + nH20

De 0,1

0,1

0,1

mol

n

Til CT:

n

=> 14n + 32 = 22.n

32

-7 22n-14n = 32 -7 8n=32 -7n= - =4 -7 CTPT: C4Hs02

8

DANG 2: TIM CTCT DIT A V Ao PU xA PHONG HoA THUY PHAN TRONG MT KIEM}

PhU'ang phap: + D~t CTTQ ella este don clnrc: R -COO-R'

+ Vi@t ptpfr thuy phan: R-COO-R' + NaOH -7 R-COONa + R'OH

J nmu6i -7 MMu6i -7 MR

+ D~t nNaom hay neste (d@ cho) vao ptr ='l_ => CTCT este

nancol -7 MAncol -7 MR'

LU'u y: Thong thuimg khi tlJ cho m ella chat nao ta tlinh hU'6'ng tim M ella chat tlo, rai kit hf/jJ vOi tlJ -7 tlap an

+ CH3 - (15), C2Hs- (29), C2H3- (27), CH3COONa = 82, C2HsOH =46".

Vd: Thuy phan hoan toan 11,44 gam este no, dan chile, mach ho X voi 100ml dung dich NaOH 1,3M (vira du) thu ducc 5,98 gam mQt aneol Y. Ten goi cua X la

A. Etyl fomat B. Etyl axetat C. Etyl propionat D. Propyl axetat

HD: Day la bai toan thuV ph lin este no dun chuc nen ta d~t CTTQ la: R-COO-R'

Tinh n ~0,1.1,3 = 0,13 mol

NaOH

Dinh huang: Bai eho m( kh6i IUQ'ng) cua este va m cua an col do d6 til s6 mol NaOH ta phai suy fa s6 mol cua este va aneol => Meste va Mancol => MR va MR'

Vi6t pir thuy phan: R-COO-R' + NaOH -7 R-COONa + R'OH

+ MROH =

0,13 ~0,13~

5,98 = 46 => MR = 46- 17= 29 => R la C2Hs- 0,13

0,13

, 11,44 ,

+ M RCOOR = -- = 88 => MR = 88- (44+ 29) =15 => R la CH3 0,13

9

V~y CTCT cua este la: CH3 coo C2Hs( etyl axetat)

DANG 3: xAc DINH CTPT DUA V Ao TY KHOI Hal

M

Deste/B =~ => Meste => n=> CTPT

MB

Nh6' CT:

Vd: Este A di6u ch6 til ancol metylic co ti kh6i so voi met an la 3,75. Cong tlnrc cua Ala:

A. C2HsCOOCH3. B. HCOOCH3. C. C2HsCOOC2Hs' D. HCOOC2Hs

HD: Mesle = 3 75

,

MCH

4

=> Meste = 3,75 . MCH

4

=> Meste = 3,75. 16 = 60. Ta nhin vao d/ a thay chi co este no dan

14n + 32 = 60 => n= 2( phan til co 2C) => d/an B D~NG 4: CHi so AXiT vA CHi so xA PHONG

./ Chi sa axit cua chat beo: La s6 miligam KOH cAn d6 trung hoa hrong axit beo tu do co trong 1 gam ch~t beo,

C6ng thuc:

Chi s6 axit =

./ Chi sa xu phimg hoa cua chat beo: la tang s6 miligam KOH cAn d6 trung hoa hrong axit tu do va xa phong hoa h6t hrong este trong 1 gam chat beo

C6ng thue:

VCrnl)' eM. 56 Chi s6 xa phong =

CAnnha:

=> tir nNaOH suy ra VNaOH =; ho~c mNaOH = n.M tuy theo d@ bal yeu M

duo

Vd: Xa phong hoa hoan toan 37,0 gam han hQ'P 2 este la HCOOC2Hs va CH3COOCH3 bang dung dich NaOH, dun nang. Kh6i hrong NaOH cAn dung la

A.8,Og B.20,Og C. 16,Og D. 12,Og

HD: Th§y MHCOOC2H, = MCH]cOOCH] = 74

Ap dung CT: nNaOH = mesle => nNaOH = 3774 = 0,5 => mNaOH= 0,5.40 = 20g

u.:

DANG 6: TiNH KHOI LUONG CHAT BEO noxc KHOI LUONG xA PHONG

Ta co PTTQ: (RCOO)3C3Hs + 3 NaOH 7 3RCOONa +C3Hs(OH)3

(chat beo) (Xil phimg) (glixeroI)

Ap dung DLBT KL: l11ch~t beo + mNaOH = mxiL phong + mglixerol => m cua chat cAn tim

Vd: Xa phong hoa hoan toan 17,24 gam chat beo can vira du 0,06 mol NaOH. Co can dung dich sau phan irng thu ducc kh6i hrong xa phong la

A. 16,68 gam. B. 18,38 gam. C. 18,24 gam. D. 17,80 gam.

HD: f)~t s6 mol NaOH vao phirong trinh d6 suy fa s6 mol glixerol 10

(RCOO)3C3Hs + 3 NaOH 7 3RCOONa +C3Hs(OH)3

0,06~ 0,02

Ap dung: Illch~t beo + mNaOH = mxiL phong + mglixerol

=> mxp = Illch~t beo + mNaOH - ffiglixerol

= 17,24 + 0,06.40 - 0,02. 92 = 17,8g Biti tap ap dung:

1. D6t chay hoan toan 0.1 mol este don clnrc thu 0.3 mol CO2 va 0.3 mol H20. CTIQ cua este la:

a. ~H402 b. ~H602 C. C4Hg02 d. CSHlO02

2. D6t chay hoan toan 0,1 mol este X r6i cho san pham chay vao dd Ca(OH)2 dir thu diroc 20 gam ket tua, CTPT cua X la:

a. HCOOCH3 b. CH3COOCH3 c. HCOO~Hs d. CH3COO~Hs

3. D6t chay hoan toan 2,2 gam este X thu duoc 2,241it CO2 (dktc) va 1,8 gam H20. CTPT cua X la:

a. ~H402 b. ~H602 C. C4Hg02 d. CSHlO02

4. D6t chay hoan toan 4.4 gam este X thu duoc 8.8 lit CO2 (dktc) va 3.6 gam H20. CTPT cua X la:

a. ~H402 b. ~H602 C. C4Hg02 d. CSHlO02

5. D6t chay hoan toan 14.8 gam este X thu duoc 13.441it CO2 (dktc) va 10.8 gam H20. CTPT cua X la:

a. ~H402 b. ~H602 C. C4Hg02 d. CSHlO02

6. D6t chay hoan toan 7.8 gam este X thu duoc 11.44 gam CO2 (dktc) va 4.68 gam H20. CTPT cua X:

a. ~H402 b. ~H602 C. C4Hg02 d. CSHlO02

7. D6t chay hoan toan 7,4 gam este X thu duoc 6,721it CO2 (dktc) va 5,4 gam H20. CTPT cua X la:

a. ~H402 b. ~H602 C. C4Hg02 d. CSHlO02

8. D6t chay hoan toan h6n hop g6m 2 este no don clnrc ke tiep nhau trong day dong dang thu diroc 4,48 lit CO2 (dktc) va m gam H20. Gia tri cua m la:

a.3,6g b. 1,8g c.2,7g d.5,4g

9. D6t chay m9t este cho sO' mol CO2 va H20 bang nhau. Thuy pharr hoan toan 6 gam este tren can dung vira du 0,1 mol NaOH. CTPTcua este la:

a. ~H402 b. ~H602 C. C4H602 d. CSHlO02

10. Cho 18,5 gam este don clnrc tac dung vira du vm 500 m1 dd KOH 0,5M. CTPTcua este la:

a. HCOOCH3 b. CH3COO~H7

c. HCOO~Hs d. CH3COO~Hs

11. Xa phong hoa 17.6 gam 1 este don clnrc can dung vira du 40 gam dung dich NaOH 20%. CTPT cua etste la:

a. C2H402 b. ~H602 C. C4Hg02 d. CSHlO02

12. Cho 7,4 gam este don clnrc tac dung vira du voi 100 m1 dd NaOH 1M. CTPT cua este la:

a. HCOOCH3 b. CH3COO~H7 c. HCOO~Hs d. CH3COO~Hs

13. Thuy pharr hoan toan 8,8 gam este don clnrc X voi 100 m1 dd NaOH 1M. CTPT cua este la:

a. HCOOCH3 b. CH3COO~H7 c. HCOO~Hs d. CH3COO~Hs

14. MQt este X co CTPT la C4Hg02. Khi cho 0,1 mol X tac dung voi dung dich NaOH thu ducc 8,2 gam

muoi Ten goi X la :A.Etylaxetat B.Metylpropionat C.Metylaxetat D.propylfomat

15.ThuY phan hoan toan 8,8 gam mQt este dan clnrc, mach ho X voi 100ml dung dich KOH 1M (vira du) thu ducc 4,6 gam mQt ancol Y. Ten goi cua X la:

A. etyl fomat B. etyl propionat C. etyl axetat D. propyl axetat 16. D6 thuy phan hoan toan este X no dan clnrc mach ho cAn dung 150 ml dung dich NaOH 1M. Sau phan

irng thu ducc 14,4 gam muoi va 4,8 gam ancol. Ten goi cua X la:

A. etyl axetat B. . propyl fomat C. metyl axetat D. metyl propionat

17. X co CTPT C4Hg02. Cho 20g X tac dung vira du voi NaOH ducc 15,44g muoi, X la:

A. C2HsCOOCH3 B. HCOOC3H7 C. CH3COOC2Hs D. C3H7COOH

18. Thuy pharr hoan toan 4,4 gam este don clnrc A bang 200 m1 dd NaOH 0,25M thu diroc 3,4 g

11

muoi hiru CO B. CTCT thu gon Ala:

A. HCOOCH3 B. CH3COOC2Hs

C. CH3COOC2H3 D. HCOOC3H7

19. Xa phong hoa horn torn 2,5g chat beo can 50m1 dung dich KOH O,lM. Chi s6 xa phong hoa cua chat beo la:

A. 280 B. 140 C. 112 D.224

20. Mudn trung hoa 5,6 gam mot cha"t ben X do c~n 6m1 dung dich KOH O,lM . Hay tinh chi s6 axit cua cha"t ben X va tinh hrong KOH c~n trung hoa 4 gam cha"t ben co chi s6 axit bang 7 ?

A. 4 va 26mg KOH B. 6 va 28 mg KOH C. 5 va 14mg KOH D. 3 va 56mg KOH

21. Muon trung hoa 2,8 gam chAt beo dn 3 m1 dd KOH O,lM. Chi s6 axit cua chAt beo 1ftA.2 B.5 C.6

D.lO

22. Be trung hoa 4 chAt beo co chi s6 axit la 7. Kh6i hrong cua KOH 1ft:A.28 mg B.280 mg D.O,28 mg

23. Thuy phan hoan toan 11,44 gam este no, dan clnrc, mach ho X voi 100m1 dung dich NaOH 1,3M (vira du) thu ducc 5,98 gam mQt aneo1 Y. Ten goi cua X la

A. Ety1 fomat B. Ety1 axetat C. Ety1 propionat D. Propyl axetat

24. Thuy phan hoan toan 8,88 gam este no, dan clnrc, mach ho X voi 100m1 dung dich NaOH 1,2M (vira du) thu ducc 8,16 gam mQt muoi Y. Ten goi cua X la

A. Ety1 fomat B. Ety1 axetat C. Mety1 axetat D. Propyl axetat

25 Thuy phan hoan toan l3,2 gam este no, dan clnrc, mach ho X voi 100m1 dung dich NaOH 1,5M (vira du) thu ducc 4,8 gam mQt aneo1 Y. Ten goi cua X la

A. Ety1 fomat B. Ety1 axetat C. Mety1 propionat D. Propyl axetat

26. Thuy phan hoan toan mQt este no, dan clnrc, mach ho X voi 200m1 dung dich NaOH 2M (vira du) thu ducc 18,4 gam aneo1 Y va 32,8 gam mQt muoi Z. Ten goi cua X la

A. Ety1 fomat B. Ety1 axetat C. Mety1 axetat D. Propyl axetat

27. Thuy phan este X co CTPT C4Hg02 trong dung dich NaOH thu ducc han hQ'P hai chat hiru co Y va Z trong do Yeo ti kh6i hoi so voi H2 la 16. X co cong tlnrc la

A. HCOOC3H7 B. CH3COOC2Hs C. HCOOC3HS D. C2HsCOOCH3

28. Xa phong hoa 22,2g han hQ'P 2 este ill HCOOC2Hs va CH3COOCH3 da dung h6t 200 ml dd NaOH .

Nang dQ moll1 cua dd NaOH 1a.A. 0,5 B. 1 M C. 1,5 M D.

2M

29. Xa phong hoa hoan toan 26,7 g trig1ixerit bang dd NaOH thu ducc 2,76 g glixero1 va b g xa phong .Gia tri

30. Cho 6 gam mQt este cua axit eaeboxy1ie no dan clnrc va aneo1 no dan clnrc phan irng vira h6t voi 100 m1 dung dich NaOH 1M. Ten goi cua este do la

A. ety1 axetat. B. propyl fomiat. C. mety1 axetat. D. mety1 fomiat.

31. Dun nang chat ben cAn vira du 40 kg dung dich NaOH 15%, gia su phan irng xay ra hoan toano Kh6i

hrong (kg) glixero1 thu ducc la A. l3,8 B. 4,6 C. 6,975 D. 9,2

32. Xa phong hoa hoan toan 22,2 gam han hQ'P gam hai este HCOOC2Hs va CH3COOCH3 bang dung dich NaOH 1M (dun nang). Th6 tieh dung dich NaOH t6i thieu cAn dung la

A. 400 ml. B. 300 ml. C. 150 ml. D. 200 ml.

33. Xa phong hoa hoan toan 17,24 gam chat ben cAn vira du 0,06 mol NaOH. Co can dung dich sau

phan irng thu ducc kh6i hrong xa phong IliA. 16,68 gam. B. 18,38 gam. C. 18,24 gam. D. 17,80 gam.

34. Ty khoi hoi cua mQt este so voi khong kill bang : 2,07 . CTPT cua este la:

a. C2H402 b. ~H602 C. C4Hg02 d. CSHlO02

35. Este A di6u eh6 til aneo1 mety1ie co ti kh6i so voi oxi la 2,3125. Cong tlnrc cua Ala:

A. C2HsCOOC2Hs' B. CH3COOCH3. C. CH3COOC2Hs' D. C2HsCOOCH3

36. Este A di6u eh6 til aneo1 mety1ie co ti kh6i so voi met an la 3,75. Cong tlnrc cua Ala:

A. C2HsCOOCH3. B. HCOOCH3. C. C2HsCOOC2Hs' D. HCOOC2Hs'

C.2,8 mg

12

37: Xa phong hall hoan toan 17,6 gam han hQ'P 2 este la etyl axetat va metyl propionat bang hrong vira du v (ml) dung dich NaOH 0,5M. Gia tri v da dung la

A. 200 ml. B. 500 ml. C. 400 ml. D. 600 ml.

38: Xa phong hoa hoan toan 37,0 gam han hQ'P 2 este la HCOOC2Hs va CH3COOCH3 bang dung dich NaOH, dun n6ng. Kh6i hrong NaOH cAn dung la

A.8,Og B.20,Og C. 16,Og D. 12,Og

39: D6 trung hoa 14 gam mQt eh~t beo cAn 1,5 ml dung dich KOH 1M. Chi s6 axit cua chat beo d6 la

A. 6 B. 5 C. 7 D. 8

40: D6 trung hoa hrong axit tu do e6 trong 14 gam mQt mftu chat beo cAn 15ml dung dich KOH O,lM. Chi s6 axit cua mftu chat beo tren la (Cho H = 1; 0 = 16; K = 39)

A.4,8 B.6,0 C.5,5 D.7,2

41. D6 xa phong hoa hoan toan 2,52g mQt lipit cAn dung 90ml dd NaOH O,lM. Tinh chi s6 xa phong cua lip it

A 100 B. 200 C.300 D.400

42. D6 trung hoa axit tu do e6 trong 5,6g lipit cAn 6ml dd NaOH O,lM. Chi s6 axit cua eh~t beo la:

A5

B. 6 C. 5,5 D. 6,5

DE DAI HOC, CAO DANG PH AN ESTE-LIPIT QUA cAc NAM

Cau 1: Este X khong no, mach ho, e6 ti kh6i hoi so voi oxi bang 3,125 va khi tham gia phan irng xa phong hoa tao ra mQt andehit va mQt muoi cua axit him co. C6 bao nhieu cong tlnrc phu hQ'P voi

X?

A2 B.3 C.4 D.5 (CD 2007)

Cau 2: S6 hQ'P eh~t dan clnrc, dang phan du tao cua nhau e6 cung cong tlnrc phan til C4Hg02, d6u tac dung voi dung dich NaOH

A3 B.4 C.5 D.6 (CD 2007)

Cau 3:Cho eh~t X tac dung voi mQt hrong vira du dung dich NaOH, sau d6 co can dung dich thu ducc eh~t d.n Y va chat him co Z. Cho Z tac dung voi dung dich AgN03 trong NH3 thu ducc eh~t him co T. Cho T tac dung voi dung dich NaOH lai thu ducc chat Y. Ch~t X e6 th6 la: (CD 2007) AHCOOCH=CH2 B.CH3COOCH=CH2 C.HCOOCH3 D.CH3COOCH=CH-CH3

Cau 4: Dun 12 gam axit axetie voi 13,8 gam etanol ( e6 H2S04 dac lam xuc tac) d6n khi phan irng dat toi trang thai can bang, thu ducc 11 gam este. Hieu su~t cua phan irng este hoa la:

A55% B.50% C.62,5% D.75% (CD 2007)

Cau 5 S6 dang phan este irng voi cong tlnrc phan til C4Hg02 la:

A5 B.2 C.4 D.6 (DH kh6i A 2008)

Cau 6 .Phat bieu dung la:

APhan irng gifra axit va aneol e6 ~t H2S04 dac la phan irng mQt chieu,

B. T~t ca cac este phan irng voi dung dich kiem luon thu ducc san pham eu6i cung la muoi va

aneol.

C.Khi thuy phan chat beo luon thu ducc C2H4(OH)z.

D.Phan irng thuy phan este trong moi tnrong axit la phan irng thuan nghich (DH kh6i A 2008) Cau 7 : X la mQt este no dan clnrc, e6 ti kh6i hoi so voi CH4 la 5,5. N6u dem dun 2,2 gam este X voi

dd NaOH dir, thu ducc 2,05 gam muoi, Cong tlnrc du tao thu gon cua X la: (DH kh6i B

2007)

AHCOOCH2CH2CH3 B.HCOOCH(CH3)z C.C2HsCOOCH3 D.CH3COOC2HS

Cau 8 :Hai este dan clnrc X va Y la dang phan cua nhau. Khi hoa hoi 1,85 gam X, thu ducc th6 tieh

hoi dung bang th6 tieh cua 0,7 gam N2 ( do 6 cung di6u kien), CTCT cua X, Y la: (DH - B 2007)

AC2HsCOOCH3 va HCOOCH(CH3)z B.HCOOC2Hs va CH3COOCH3

C.C2H3COOC2Hs va C2HsCOOC2H3 D.HCOOCH2CH2CH3 va CH3COOC2Hs

Cau 9: Cho glixerol phan irng voi han hQ'P axit beo gam C17H3SCOOH va C1sH31COOH, s6 loai tries

13

ducc tao ra t6i da la:A.6

B.5

C.4

D.3

DH- B 2007

Cau 10: Thuy phan este co cong tlnrc phan til C4Hg02 (vai xuc tac axit), thu ducc 2 san pham him co X, Y.Til X co th6 di6u eh6 tnrc ti6p ra Y. V~y chat X la:

A.Aneol metylie B.Etyl axetat C.axit fomie D.aneol etylie DH - B 2007

Cau 11: Thuy phan hoan toan 444 gam mQt lipit thu ducc 46 gam glixerol va 2 loai axit beo, Hai loai axit

beo do la:

A.C1sH31COOH va C17H3SCOOH C.C17H31COOH va C17H33COOH

B.C17H33COOH va C1sH31COOH D.C17H33COOH va C17H3SCOOH

DH-A

2007

Cau 12:Xa phong hoa 8,8 gam etyl axetat bang 200 ml dung dich NaOHO,2M. Sau khi phan irng xay ra hoan toan co can dung dich thu ducc chat d.n khan co kh6i hrong la:

A.8,56 gam B.3,28 gam C.10,4 gam D.8,2 gam DH - A 2007

Cau 13: Han hQ'P x gam axit HCOOH va axit CH3COOH (ti l~ mol 1:1). L~y 5,3 gam han hQ'P x tac dung voi 5,75 gam C2HsOH ( co xuc tac H2S04 d~e) thu ducc m gam han hQ'P este (hi~u su~t cua cac phan irng este hoa d6u bang 80%). Gia tri cua m la:

A.10,12 B.6,48 C.8,10 D.16,20 DH - A 2007

Cau 14: Khi tlnrc hien phan irng este hoa 1 mol CH3COOH va 1 mol C2HsOH, hrong este Ian nh~t thu ducc la 2/3 mo1.D6 dat hieu su~t cue dai la 90% (tinh thea axit) khi ti6n hanh este hoa 1 mol CH3COOH

cAn s6 mol C2HsOH la (bi6t cac phan irng este hoa tlnrc hien a cung nhiet dQ)

A.0,342 B.2,925 C.2,412 D.0,456 DH -A 2007

Cau 15: Khi d6t chay hoan toan este no don chirc thi s6 mol CO2 sinh ra bang s6 mol O2 da: phan img. Ten goi cua este la:

A.etyl axetat B.metyl axetat C.metyl fomiat D.propyl axetat (DH kh6i B- 2008)

Cau 16: HQ'P chAt hfru co no, da clnrc X co cong thirc phan t11 C7H1204. Cho 0,1 mol X tac dun g vira du voi 100

gam

dd NaOH 8% thu ducc chAt hfru co Y va 17,8 gam h6n hQ'P mu6i. Cong thirc du tao thu gon cua X la:

A.CH3COO-[CH2 ]-00CC2H5 B.CH3 00C[CH2 hCOOC2H5

C.CH3 00CCH2COOC3H7 D.CH3COO[CH2 hCOOC2H5 (DH kh6i B- 2008)

Cau 17: Xa phong hoa hoan toan 17,24 gam chAt beo dn vira du 0,06 mol NaOH. Co can dung dich sau phan trng thu ducc kh6i hrong xa phong la

A.17,80gam B.18,24 gam C.16,68 gam D.18,38gam (DHkh6iB-2008)

Cau 18 :Este don clnrc X co ti kh6i hoi so voi CH4 la 6,25.Cho 20 gam X tac dung voi 300 ml dung dich KOH 1M

(dun nong), Co can dung dich ducc sau phan trng thu ducc 28 gam chAt r~n khan. CTCT cua X la

A.CH2=CH -CH2COOCH3 B.CH2=CH -COOCH2CH3

C.CH3COOCH=CH-CH3 D.CHrCH2COOCH=CH2 (CD kh6i A-2008)

Cau 19 Xa phong hoa hoan toan 22,2 gam h6n hQ'P g6m 2 este HCOOC2H5 va CH3COOCH3 b~ng dung dich NaOH

1M (dun nong), The tich dung dich NaOH t6i thieu dn dung la

A.400 ml B.300 ml C.150 ml

D.200 ml CD kh6i A-2008

Cau 20: MQt h6n hQ'P X g6m 2 chAt hfru co don clnrc, Cho X phan irng vira du voi 500ml dung dich KOH 1M. Sau

phan trng thu ducc h6n hQ'P Y g6m 2 mu6i cua hai axit cacboxylic va mQt ancol, Cho toan bQ hrong ancol

thu

ducc (] tren tac dung voi Na du, sinh ra 3,36 lit H2( dktc). H6n hQ'P X g6m:

A.mQt axit va mQt este B.mQt este va mQt ancol

C.hai este D.mQt axit va mQt ancol (CD kh6i A-2008)

Cau 21: Bun nong 6,0 gam CH3COOH voi 6,0 gam C2H50H ( co H2S04 lam xuc tac, hieu suAt phan img este hoa b~ng 50%). Kh6i hrong este tao thanh la:

A.6,0 gam B.4,4 gam C.8,8 gam D.5,2 gam ( CD kh6i A-2008)

14

D~I HOC KHOI A- 2009

Call 22 Xa phong h6a hoan toan 66,6 gam han hQ'P hai este HCOOC2Hs va CH3COOCH3 bang dung dich

NaOH, thu ducc han hQ'P x gam hai ancol. Dun n6ng han hQ'P x voi H2S04 dac 6 140°C, sau

khi

phan irng xay ra hoan toan thu ducc m gam mrcc. Gia tri cua m la

A. 18,00. B. 8,10. C. 16,20. D.4,05.

Call 23: Xa phong h6a hoan toan 1,99 gam han hQ'P hai este bang dung dich NaOH thu ducc 2,05 gam muoi cua mQt axit cacboxylic va 0,94 gam han hop hai ancol la dang dllng k6 ti6p nhau. Cong tlnrc cua hai

este do la: A. HCOOCH3 va HCOOC2Hs. B. C2HsCOOCH3 va C2HsCOOC2Hs.

C. CH3COOC2Hs va CH3COOC3H7. D. CH3COOCH3 va CH3COOC2Hs.

Call24: Dun n6ng han hQ'P hai ancol don clnrc, mach ho voi H2S04 dac, thu ducc han hQ'P gam cac ete. L~y 7,2 gam mQt trong cac ete d6 dem d6t chay hoan toan, thu ducc 8,96 lit khi CO2 (6 dktc) va 7,2 gam H20. Hai ancol d6 la

A. CH30H va CH2=CH-CH2-OH. B. C2HsOH va CH2=CH-CH2-OH.

C. CH30H va C3H70H. D. C2HsOH va CH30H.

Call 25: Len men m gam glucozo voi hieu su~t 90%, IUQ'ng khi CO2 sinh ra h~p thu h6t vao dung dich mroc voi trong, thu ducc 10 gam k6t tua, Kh6i IUQ'ng dung dich sau phan irng giam 3,4 gam so voi kh6i IUQ'ng dung dich mroc voi trong ban dAu. Gia tri cua m la

A. 13,5. B. 30,0. C. 15,0. D.20,0.

Call 26: Xa phong h6a mQt hQ'P chat c6 cong tlnrc phan til ClOH1406 trong dung dich NaOH (du), thu ducc

glixerol va han hQ'P gam ba muoi (khong c6 dang phan hinh hoc), Cong tlnrc cua ba muoi d6 la:

A. CH2=CH-COONa, HCOONa va CH=C-COONa.

B. CH3-COONa, HCOONa va CH3-CH=CH-COONa.

C. HCOONa, CH=C-COONa va CH3-CH2-COONa.

D. CH2=CH-COONa, CH3-CH2-COONa va HCOONa.

D~I HOC KHOI B - 2009

Call 27: Day gam cac chat ducc slip x6p thea chieu tang dAn nhiet dQ soi til trai sang phai la:

A. CH3CHO, C2HsOH, HCOOH, CH3COOH. B. CH3COOH, HCOOH, C2HsOH, CH3CHO. C. HCOOH, CH3COOH, C2HsOH, CH3CHO D. CH3COOH, C2HsOH, HCOOH, CH3CHO.

Call 33: Han hQ'P x gam hai este no, dan clnrc, mach ho. D6t chay hoan toan mQt IUQ'ng X cAn dung vira du 3,976 lit khi O2 (6 dktc), thu ducc 6,38 gam CO2. M~t khac, X tac dung voi dung dich NaOH, thu ducc mQt muoi va hai ancol la dang dllng k6 ti6p. Cong tlnrc phan til cua hai este trong X la

A. C2H402 va C3H602 B. C3H402 va C4H602

C. C3H602 va C4Hg02 D. C2H402 va CSHlO02

Call 28: Cho han hQ'P X gam hai hQ'P chat him co no, dan clnrc tac dung vira du voi 100 ml dung dich KOH 0,4M, thu ducc mQt muoi va 336 ml hoi mQt ancol (6 dktc). N6u d6t chay hoan toan IUQ'ng han hQ'P X tren, sau d6 h~p thu h6t san pham chay vao binh dung dung dich Ca(OH)z (du) thi khoi hrong binh tang 6,82 gam. Cong tlnrc cua hai hQ'P chat him co trong X la

A. HCOOH va HCOOC2Hs B. CH3COOH va CH3COOC2Hs

C. C2HsCOOH va C2HsCOOCH3 D. HCOOH va HCOOC3H7

Call 29: HQ'P chat him co X tac dung ducc voi dung dich NaOH dun n6ng va voi dung dich AgN03 trong

NH3. Th6 tich cua 3,7 gam hoi chat X bang th6 tich cua 1,6 gam khi O2 (cung di6u kien v6 nhiet

dQ

Va ap suat). Khi d6t chay hoan toan 1 gam X thi th6 tich khi CO2 thu ducc virot qua 0,7 lit (6 dktc) Cong tlnrc du tao cua X la

A. CH3COOCH3 B. 0=CH-CH2-CH20H C. HOOC-CHO D. HCOOC2Hs

15

CAO DANG KHOI A,B -2009

Call 30: Cho 20 gam mQt este X (co phan til kh6i la 100 dvC) tac dung voi 300 ml dung dich NaOH 1M. Sau phan irng, co can dung dich thu ducc 23,2 gam chat d.n khan. Cong tlnrc du tao cua X

la

A. CH2=CHCH2COOCH3• B. CH3COOCH=CHCH3•

C. C2H5COOCH=CH2. D. CH2=CHCOOC2H5.

Call 31: Cho cac eh~t HCI (X); C2H50H (Y); CH3COOH (Z); C6H50H (phenol) (T). Day gam cac eh~t

ducc slip x6p thea tinh axit tang dAn (til trai sang phai) la:

A. (T), (Y), (X), (Z). B. (X), (Z), (T), (Y). C. (Y), (T), (Z), (X). D. (Y), (T), (X), (Z)

Call 32: Han hQ'P khi X gam 0,3 mol H2 va 0,1 mol vinylaxetilen. Nung X mQt thai gian voi xuc tac Ni thu ducc han hQ'P khi Y co ti kh6i so voi khong khi la 1. N6u eho toan bQ Y sue til til vao dung dich brom (du) thi co m gam brom tham gia phan irng. Gia tri cua m la

A. 16,0. B.3,2. C.8,0. D.32,0.

Call 33: Cho m gam han hQ'P gam hai chat him co dan clnrc, mach ho tac dung vira du voi dung dich chua 11,2 gam KOH, thu ducc muoi cua mQt axit eaeboxylie va mQt aneol X. Cho toan bQ X tac dung h6t voi Na thu ducc 3,36 lit khi H2 (a dkte). Hai chat him co do la

A. mQt este va mQt axit. B. hai axit. C. hai este. D. mQt este va mQt aneol.

Call 34: Len men hoan toan m gam glucozo thanh aneol etylie. Toan bQ khi CO2 sinh ra trang qua trinh nay ducc h~p thu h6t vao dung dich Ca(OH)2 (du) tao ra 40 gam k6t tua, N6u hieu su~t cua qua

trinh len men la 75% thi gia tri cua m la : A. 60. B. 58. C. 30. D. 48.

CHUONG 2: CACBOHIDRAT II TRA.C NHI¥M LY THUYET:

Ciill 1: Trong phan t11 cua cacbohydrat lufm co

A. nhom chirc axit. B. nhom chirc xeton. C. nhom chirc ancol. D. nhom chirc andehit.

Call 2: Chat thuec loai disaccarit la

A. glucozo. B. saccarozo, C. xenlulozo, D. fructozo,

Call 3: Hai chAt d6ng phan cua nhau la

A. glucozo va mantozo, B. fructozo va glucozo, C. fructozo va mantozo, D. saccarozo va

glucozo,

Call 4: Trong dieu kien thich hQ'P glucozo len men tao thanh khi CO2 va

A. C2H50H. B. CH3COOH. C. HCOOH. D. CH3CHO.

Call 5: Saccarozo va glucozo deu co

A. phan img voi AgN03 trong dung dich NH3, dun nong,

B. phan trng voi dung dich N aCl.

C. phan img voi Cu(OH)2 0 nhiet dQ tlnrong tao thanh dung dich xanh lam.

D. phan img thuy phan trong moi tnnrng axit.

Call 6: Cho sa d6 chuyen hoa: Glucozo ---)- X ---)- Y ---)- CH3COOH. Hai chAt X, Y l~n hrot la

A. CH3CHO va CH3CH20H. B. CH3CH20H va CH3CHO.

C. CH3CH(OH)COOH va CH3CHO. D. CH3CH20H va CH2=CH2.

Call 7: Chat tham gia phan trng trang guong la

A. xenlulozo, B. tinh bQt. C. fructozo, D. saccarozo.

Call 8: Chat kh6ng phan irng voi AgN03 trong dung dich NH3, dun nong tao thanh Ag la

A. C6H1206 (glucozo), B. CH3COOH. C. HCHO. D. HCOOH.

Call 9: Day g6m cac dung dich deu tac dung voi Cu(OH)2 la

A. glucozo, glixerol, ancol etylic. B. glucozo, andehit fomic, natri axetat.

C. glucozo, glixerol, axit axetic. D. glucozo, glixerol, natri axetat.

Call 10: Be chirng minh trong phan t11 cua glucozo co nhieu nhom hidroxyl, ngmri ta cho dung dich glucozo phan

trng voi A. Cu(OH)2 trong NaOH, dun nong. B. AgN03 trong dung dich NH3, dun nong,

C. Cu(OH)2 0 nhiet dQ tlnrong. D. kim loai Na.

Call 11 Bun nong xenlulozo trong dung dich axit vo co, thu ducc san pham la

16

A. saccarozo. B. glucozo, C. fructozo, D. mantozo,

Call 12: Cho sa d6 chuyen hoa sau: Tinh bQt ~ X ~ Y ~ axit axetic. X va Y l~n hrot la

A. ancol etylic, andehit axetic. B. glucozo, ancol etylic.

C. glucozo, etyl axetat. D. glucozo, andehit axetic.

Call 13: Tinh bQt, xenlulozo, saccarozo, mantozo deu co kha nang tham gia phan trng

A. hoa tan Cu(OH)2. B. trung ngung, C. trang guong. D. thuy phan,

Call 14: MQt chAt khi thuy phan trong moi tnnrng axit, dun nong kh6ng tao ra glucozo. Chat dola

A. protit. B. saccarozo, C. tinh bQt. D. xenlulozo,

Call 15 Cho day cac chat: glucozo, xenlulozo, saccarozo, tinh bet, fructozo, se chAt trong day tham gia phan irng trang guong la

A. 3. B. 4. C. 2. D. 5.

Call 16: Cho cac chat: ancol etylic, glixerol, glucozo, dimetyl ete va axit fomic. se chAt tac dung ducc voi

Cu(OH)2 la A.3. B. 1. C. 4. D. 2.

Call 17 Thuoc thir de phan biet glucozo va fructozo la

A. CU(OH)2 B. dung dich brom. C. [Ag(NH3)2] N03

D.Na

Call 18 Trong cac chAt sau: axit axetic, glixerol, glucozo, ancol etylic, xenlulozo. se chAt hoa tan ducc CU(OH)2

(] nhiet dQ tlnrong la A. 3 B. 5 C. 1 D. 4

Call 19: Cho cac dung dich sau: saccarozo, glucozo, andehit axetic, glixerol, ancol etylic, axetilen, fructozo. se hrong dung dich co the tham gia phan irng trang guong la

A. 3. B. 4. C. 5. D. 2.

Call 20: Khi thuy phan saccarozo thi thu ducc

A. ancol etylic. B. glucozo va fructozo, C. glucozo.

D. fructozo,

Call 21: Cong thirc nao sau day la cua xenlulozo?

A. [C6H702(OH)3]n. B. [C6H802(OH)3]n.

Call 22 : Day cac chAt nao sau day deu co phan trng thuy phan trong moi tnrong axit?

A. Tinh bQt, xenluloze, glucozo, B. Tinh bQt, xenlulozo, fructozo,

C. Tinh bQt, xenluloze, saccarozo, D. Tinh bQt, saccarozo, fructozo

Call 23: Cho cac dd: Glucozo, glixerol, fomandehit, etanol. Co the dung thuoc thir nao sau day de phan biet ducc

ca 4 dd tren A. Nurre Br2 B. Na kim loai C. CU(OH)2 D. Dd AgN03INH3

Call 24: Be phan biet saccarozo, tinh bet, xenlulozo (] dang bQt nen dung each nao sau day?

A. Cho tirng chAt tac dung voi HN03/H2S04

B. Cho nrng chAt tac dung voi dd lz

C. Hoa tan tirng chAt vao mroc, dun nong nhe va thir voi dd iot

D. Cho tirng chAt tac dung voi voi sua

Call 25: glucozo khong co ducc tinh chAt nao dinri day?

A. Tinh chAt cua nhom andrhit B. Tinh chAt poliol C. Tham gia pir thuy phan D. Tac dung voi

CH30H/HCl

Call 26: Thuoc thir duy nhAt co the chon de phan biet cac dung dich glucozo, etylic, andehitfomic, glixerin la

A. Ag20INH3 B. CU(OH)2 C. Na D. H2

Call 27: Cacbohidrat Z tham gia chuyen hoa

Cu(OH)2/OW t"

Z dung dich xanh lam ket tua do gach

V~y Z khong the la chAt nao trong cac chAt cho duoi day?

A. Glucozo B. Fructozo C. Saccarozo D. Mantozo

Call 28: Frutozo khong pir voi chat nao sau day?

A. H2INilc B. CU(OH)2 C. Nurre Br2 D. Dd AgN03INH3

Call 29: Be chirng minh glucozo co nhom chirc andehit, co the dung mQt trong ba pir hoa hoc, Trong cac pir sau, pir nao khong chirng minh ducc nhom chirc cua glucozo?

A. Oxihoa glucozo b~ng AgN03INH3 B. Oxi hoa glucozo b~ng CU(OH)2 dun nong

C. Len men glucozo b~ng xtac enzim D. Khir glucozo b~ng H21 Ni, to

Call 30: Cacbonhidrat(gluxit,saccarit) la:

A. HQ"P chAt da chirc, co cong thirc chung la Cn(H20)m

B. HQ"P chAt tap chirc, da s6 co cong tlnrc chung la Cn(H20)m C. HQ"P chAt chua nhieu nhom hidroxyl va nhom cacbonyl

17

D. HQ"P chAt chi co nguen g6c tir thuc v~t

Cau 31: Chat tham gia phan ling trang guong la

A. xenlulozo, B. tinh bQt. C. glucozo. D. saccarozo.

Cau 32: Khi thuy phan tinh bQt ta thu san pham cu6i cung la:

A.mantozo. B. frutozo, C. glucozo. D. saccarozo.

Cau 33: D6 xac dinh trong mroc ti6u cua ngirci benh nhan dai thao duong nguoi ta dung:

A Axit axetit B. Dang (II) hidroxit C. Dang oxit D. Natri hidroxit

Cau 34: Diem giong nhau giira glucozo va sacarozo la;

A D6u c6 trong cu cai duong C. D6u hoa tan dd Cu(OH)z a nhiet dQ tlnrong cho dd mau xanh

B. D6u tham gia pir trang girong D. D6u ducc su dung trong y hoc

Cau 35: Cau nao dung trong cac cau sau: Tinh bQt va xenlulozo khac nhau v6

A Cong tlnrc phan tir B. Tinh tan trong mroc lanh C. Phan irng thuy phan D. C~u true phan tir

Cau 36: Nhan xet nao sau day khong dung?

A RUQt banh mi ngot hon vo banh B. Khi an com, n6u nhai ki se thay vi ngot

C. Nho dd i6t len mieng chuoi xanh thay xuat hien mau xanh D. Nurre ep chuoi chin cho pir trang

bac

Cau 37: Ung dung nao khong phai la irng dung cua glucozo?

A Lam tlnrc pham dinh duong va thuoc tang hrc B. Trang girong, trang phich

C. Nguyen lieu san xuat ancoletylic D. Nguyen li~u san xuat PVC

Cau 38: Cac ch~t glucozo(C6H1206), fornandehit(HCHO), Axetandehit(CH3CHO), metylfomiat(HCOOCH3), trong phan tir d6u c6 nh6m -CHO nlnrng trong tlnrc t6 d6 trang guong ngirci

ta chi dung.A, C6H1206 B.HCOOCH3 C. CH3CHO D. HCHO

Cau 39:Cho bi6t ch~t nao sau day thuoc monosacarit:

AGlucozo B.Saccarozo C.Tinh bQt DXenlulozo

Cau 40:Cho bi6t ch~t nao sau day thuoc polisacarit:

AGlucozo B.Saccarozo C.Mantozo D.Xenlulozo

Cau 41: Ch~t nao sau day la dang phan cua Fructozo?

AGlucozo B.Saccarozo C.Mantozo D.Xenlulozo

Cau 42:Dung dich saccarozo tinh khiet khong c6 tinh klnr.nlurng khi dun n6ng voi dung dich H2S04 lai c6 th6 cho phan irng trang girong.Do la do:

ADa c6 su tao thanh andehit sau phan irng,

B.Saccarozo bi thuy phan tao thanh glucozo va fructozo. C.Saccarozo bi thuy phan tao thanh glucozo . D.Saccarozo bi thuy phan tao thanh fructozo.

Cau 43:Trong cong nghiep ch6 tao ruot phich.nguci ta thuong su dung phan irng hoa hoc nao sau day?

ACho axetilen tac dung voi dung dich AgN03INH3. B.Cho andehit fomic tac dung voi dung dich AgN03INH3. C.Cho axit fomic tac dung voi dung dich AgN03INH3. D.Cho glucozo tac dung voi dung dich AgN03INH3.

Cau 44:B~nh nhan phai ti6p duong (tiem hoac truyen dung dich duong vao tinh machj.do la loai duong

nao? AGlucozo B.Mantozo C.Saccarozo D.Fructozo

Cau 45:Duang saccarozo ( duong mia) thuoc loai saccarit nao?

AMonosaccarit B.Disaccarit C.Polisaccarit D.Oligosaccarit

Cau 46:HQ'P ch~t duong chiem thanh phan chu y6u trong mat ong la:

AGlucozo B.Fructozo C.Saccarozo D.Mantozo

Cau 47:S11p x6p cac ch~t sau day thea thir tv dQ ngot tang dAn:Glucozo,Fructozo, Saccarozo AGlucozo < Saccarozo < Fructozo. B.Fructozo < glucozo < Saccarozo

C.Glucozo < Fructozo < Saccarozo. D. Saccarozo <Fructozo < glucozo,

Cau 48:MQt dung dich c6 cac tinh ch~t:

- Tac dung lam tan Cu(OH)z cho plnrc dang mau xanh lam.

- Tac dung klnr [Ag(NH3)z JOH va Cu(OH)z khi dun n6ng.

18

-Bi thuy phan khi c6 ~t xuc tac axit hoac enzim.

Dung dich d6 la: AGlucoza B.Fructoza C.Saccaroza D.Mantoza ..

Call 49:Di6u khang dinh nao sau day khong dung?

AGlucoza va fructozo la 2 ch~t dang phan cua nhau. B.Glucoza va fructozo d6u tham gia phan irng trang guong. C.Glucoza va fructozo d6u lam m~t mau mroc bromo D.Glucoza va fructozo d6u tham gia phan irng cong H2(NiltO).

Call 50:Glucoza la hQ'P chat him co thuoc loai:

ADan clnrc B.Da clnrc C. T;;tp clnrc D.Polime.

Call 51: Nh6m rna t~t ca cac ch~t d6u tac dung voi Cu(OH)z a nhiet dQ phong cho dung dich xanh lam la:

Aglixerol, glucozo, andehit axetic.mantozo. B.glixerol, glucozo, fructozo, mantoza.

C.axetilen, glucozo, fructozo, mantoza. D.saccaroza, glucozo, andehit

axetic.mantozo.

Call 52:Cho cac dung dich sau: saccarozo, glucozo, andehit axetic.mantozo, glixerol, etilenglicol, metanol.So hrong dung dich c6 th6 hoa tan Cu(OH)z la:

A4 B.5 C.6 D.7

Call 53: Cho cac dung dich sau: saccarozo, glucozo, andehit axetic.mantozo, glixerol, etilenglicol, axetilen, fructozo.So hrong dung dich c6 th6 tham gia phan irng trang guong la:

A3 B.4 C.5 D.6

Call 54:Day cac chat sau thi day nao d6u tham gia phan irng trang girong va phan irng voi Cu(OH)z dun n6ng cho Cu20 k6t tua do gach?

AGlucoza, mantozo, andehit axetic. B.Glucoza, saccarozo, andehit axetic.

C.Glucoza, saccarozo, mantoza. D.Xenluloza, fructozo, mantoza.

Call55:Chi dung Cu(OH)z c6 th6 phan biet ducc nh6m chat nao sau day?(Dl,mg cu c6 du)

AGlixerol, glucozo, fructozo. B.Saccaroza, glucozo, mantoza.

C.Saccaroza, glucozo, andehit axetic. D.Saccaroza, glucozo, glixerol.

Call 56:Cho cac ch~t: X.glucoza; Y.fiuctoza; Z.Saccaroza; T.Xenluloza. Cac chat phan irng ducc voi

dung dich AgN03INH3l cho ra Ag la: AZ, T B.X, Z C.Y, Z D.X, Y

Call 57:Saccaroza va glucozo d6u c6:

APhan irng voi dung dich NaCl.

B.Phan irng voi Cu(OH)z a nhiet dQ tlnrong tao thanh dung dich xanh lam. C.Phan irng thuy phan trong moi tnrong axit.

D.Phan irng voi dung dich AgN03INH3 dun n6ng. TNPT -2007

Call 58 Chi dung Cu(OH)z a nhiet dQ tlnrong va khi dun n6ng c6 th6 nhan bi6t ducc t~t ca cac ch~t trong day nao duoi day?

ACac dung dich glucozo, glixerol, ancol etylic, andehit axetic B.Cac dung dich glucozo, ani lin, metyl fomiat, axit axetic. C.cac dung dich saccarozo, mantozo, tinh bot, natrifomiat.

D. T~t ca d6u dung.

Call 59: Thu6c thir nao trong cac thuoc thir duoi day dung d6 nhan bi6t ducc t~t ca cac dung dich trong day sau: glucozo, glixerol, fomandehit, propan-1-ol?

Add AgN03INH3 B.Na C.Nuac Br2 D.Cu(OH)zINaOHl

Call 60: C6 4 lo ~t nhan chua 4 dd C2HsOH, CH3COOH, glucozo, saccarozo. bang plnrong phap hoa hoc nao sau day c6 th6 nhan bi6t 4 dd tren (ti6n hanh thea trinh tu sau)

ADung quy tim, dung AgN03INH3, them vai giot dd H2S04 dun nhe, dd AgN03INH3 B.Dung dd AgN03INH3, quy tim.

C.Dung Na2C03, them vai giot dd H2S04 dun nhe, dd AgN03INH3.

D.Dung Na, dd AgN03INH3, them vai giot dd H2S04 dun nhe.dd AgN03INH3.

Call 61: Tinh bQt va xenlulozo d6u la poli saccarit c6 CTPT (C6HlOOS)n nlnrng xenlulozo c6 th6 keo thanh sci, can tinh bQt thi kh6ng. Cach giai thich nao sau day la dung.

19

APhan til xenlulozo khong phan nhanh, cac phan til dt dai d6 xoan lai thanh SQ'i.

B.Phan til xenlulozo khong phan nhanh, cac phan til dt dai slip x6p song song voi nhau thea mQt true xoan lai thanh SQ'i.

C. Tinh bQt la han hQ'P cua 2 thanh phAn amilozo va amilopectin, mach phan til cua cluing x6p song song voi nhau lam cho tinh bQt a dang hat.

D.Hai thanh phan amilozo va amilopectin xoan lai thanh vong xoan, cac vong xoan d6 cuon lai lam cho tinh bQt a dang bot.

III TRA.c NGHI¥M BAI T~P

D~NG 1: PHAN UNG TRANG GUONG CVA GLUCOZO (C6H120d

C6H1206 -7 2Ag (glucozo )

Nh6 -7 (Mc H 0 = 180, MA = 108)

6 12 6 g

PhU'tmg phlip: + Phan tich xem d6 cho gi va hoi gi

+ Tinh n cua chat rna tlJ cho -7 Tinh s6 mol cua chat tlJ hoi -7 kh6i IUQ'ng cua chat d6 hoi

VD: Dun n6ng dd chua 9g glucozo voi AgN03 du pir trong dd NH3 thay Ag tach ra. Tinh IUQ'ng Ag thu ducc,

A 10,8g

B.20,6

C.28,6

D.26,1

!!ill.;, pir: d6:

HD: - Phan tich d6 : + Cho mC6H1206 =9g + Hoi mAg = ?g

- Huang giai: +Tinh nC H 0 =!!!_=_!j_= 0 05 mol

6 126M 180 '

+ D~t nC6H1206 VaG ptr -7 nAg-7mAg C6H1206 -7 2Ag

0,05 ----)0 0,1

mAg = n.M = 0,1 .108=10,8g

C6H1206 -7 2Ag

180 2.108

9 m=?

mAg = 9.2.108 = 10 8g

180 '

D~NG 2: PHAN UNG LEN MEN CVA GLUCOZO (C6H120d :

H%

C6H1206 -7 2C2HsOH

+ 2C02

LU'u V: Bai toan thuong gan vai dang toan ddn CO2 vao nutrc voi trong Ca(OH) 2 thu duac kh6i IU(J'YIg k~t tua CaC03. Tit ao tinh duac s6 mol CO2 dua vao s6 mol CaC03 (nC02 = nCaco)

Phurrng phap: + Phan tich xem d6 cho gi va hoi gi

+ Tinh n cua chat rna tlJ cho -7 n cua ch~t tlJ hoi -7 m cua chat rna d6 bai yeu cAu Vd: Cho m gam glucozo len men, khi thoat ra duoc d~n VaG dd mroc voi trong dir thu ducc 55,2g k6t tua trang, Tinh kh6i IUQ'ng glucozo dll len men, biet hieu su~t len men la 92%.

A 54 B. 58 C. 84 D. 46

HD1: Phan tich d6: + D6 cho ITIcaC03 = 55,2g

+ D6 hoi: mC6H1206 =? g ( H= 92%)

Huang giai: + Tinh ncoz = n -J... (CaC03) = !!!_ = 55,2 = 0,552 mol (vi nC02 =nCaC03) M 100

+ D~t nC02 VaG ptr suy ra n C6H1206 => m C6H1206

20

C6H1206 -7 2C2HsOH + 2C02

0,276 ~ 0,552

mC6H1206 = n.M . 1~0 = 0,276.180. 1~~ = 54 g (N6u d6 khong cho hieu su~t thi khong nhan

hieu su~t)

Hoac co th@ ghii:

D~t true ti@p vito phutrng trinh r6i tinh.

C6H1206 -7 2C2HsOH + 2C02

180 2

m=? 0,552

180.0,552.100 = 54

2 92 g

D~NG 3: PHAN UNG THUY PHAN SACARoza (C12H22011}

1/ C12H22011 (Saccarozo) ---+ C6H1206 (glucozo) ---+ 2C2HsOH + 2C02

342 180

PhU'O'ng phap: nhu tren

V d: Mu6n co 2610 gam glucozo thi kh6i hrong saccarozo cAn dem thuy phan hoan toan III

A. 4595 gam. B. 4468 gam. C. 4959 gam. D. 4995 gam.

HD: Phan tich: + Cho mglu = 2610 + Hoi msac =?

Huang giai> Tinh s6 mol cua chat a~ bili cho la glucoza d~t vao ptrinh fiJi suy fa s6 mol cua ch~t a~ bai hoi la saccaroza

m 2610

n lu =_= --= 14 5mol

g M 180 '

C12H22011(Saccaroza)---+ C6H1206

14,5 ~ 14,5mol

msac = n. M = 14,5.342= 4959 g

Hoac co th@ ghii: D~t true ti@p vito phutrng trinh r6i tinh.

C12H22011 (Saccarozo) ---+ C6H1206

342 g 180 g

m=? 2610g

msac = 342.2610 = 4959g

180

DANG 4: PHAN UNG THUY PHAN XENLULOZa HoAc TINH BOT (C6H100Sl!!:

HI% (C6HIOOS)n ~ 162n

H2%

nC6H1206 ~ 2nC02 + 2nC2HsOH

180n

PhU'O'ng phap: nhu tren

Vd: N6u dung 1 t~n khoai chua 20% tinh bQt thi thu ducc bao nhieu kg glucoza? Bi6t hieu su~t pir III 70%.

A. 160,55

B. 150,64

C. 155,54

C.165,65

20 '

HD: Phan tich: + Cho mtb = 1. - =0,2 tan

100

21

+ Hoi mglu(H=70%)

(C6HIOOS)n ~ nC6H1206

162n 180n

0,2 m= ?

mGIu = 0,2.180n. 70 = 0 15555 t~n = 15555 kg

162n 100 ' ,

DANG 5: XenlulozO' + axitnitrit -7 xenlulozO'trinitrat

[C6H702(OH)3]n + 3nHN03 -7 [C6H702(ON02)3]n + 3nH20

162n 3n.63 297n

VD: Til 16,20 t~n xenlulozo ngirci ta san xuat ducc m t~n xenlulozo trinitrat (biet hieu su~t phan irng tinh thea xenlulozo III 90%). Gia tri cua m III

A.26,73. B.33,00. C.25,46. D.29,70.

HD: Phan tich: - D6 cho mxen =16,2 t~n

- D6 hoi mxenlulozotrinitrat = ? (H=90%) [C6H702(OH)3]n + 3nHN03 -7 [C6H702(ON02)3]n + 3nH20

162n 3n.63 297n

16,2 m=?

m = 16,2.297n. 90 = 26 73 t~n

162n 100 '

DANG 6: KHU GLUCOZa BANG HIDRO

C6H1'206 + H2 -7 C6H1406 (Glucozo) (sobitol)

DANG 8: tic DINH s6 MAc XiCH( n)

VD: Kh6i hrong phan til trung binh cua xenlulozo trong soi bong III 1 750000 dvC. S6 g6c glucozo C6HlOOS trong phan til cua xenlulozo III

A10 802 g6c B.1 621 g6c C. 422 g6c D. 21 604 g6

HD: n = PTKTB = 1750000 10802 g6c

-- MCH 0 162

6 105

LU1l y:

H ) B ( H lit hi~u su§t phan 6ng)

1) A

I~ -m-A-=--m-B-.~l~~O--;-------m-B-=-m--A-·-l-:=-O-----'

B

100 100 rnA = Illc.-.-;

HI H2

HI H2 Illc = rnA. -.- •

100 100

BAI TAp Ap DUNG:

Cau 1/ Dun n6ng dd chua 9g glucozo voi AgN03 du pir trong dd NH3 thay Ag tach ra. Tinh IUQ'ng Ag thu ducc,

A 10,8g B.20,6 C.28,6 D.26,1

Cau 2/ Dun n6ng dd chua 36g glucozo voi ddAgN03INH3 thi kh6i IUQ'ng Ag thu ducc t6i da Ill:

A 21,6g B. 32,4 C. 19,8 D.43.2

22

Call 3/ Dun n6ng dd chua m g glucozo voi ddAgN03INH3 thi thu ducc 32,4 g Ag .gia tri mill:

A. 21,6g B. 108 C.27 D. S6 khac,

Call 4. Dun n6ng dd chua m g glucozo voi dd AgN03INH3 thi thu ducc 16,2 Ag gia tri m la (H= 75%):

A. 21,6g B. 18 g C. 10,125g D. s6 khac

Call 5. Tinh hrong k6t tua bac hinh thanh khi ti6n hanh trang girong hoan toan dd chua 18g glueoza.(H=85% )

A. 21,6g B. 10,8 C.5,4 D.2,16

Call 6. Cho 200ml dd glucozo pir hoan toan voi dd AgN03 trong NH3 thay e6 10,8g Ag tach ra. Tinh nang dQ mol/lit cua dd glueozo dll dung.

A. 0,25M B. 0,05M C. 1M D. s6 khac

Call 7. Dun n6ng dd chua 54g glucozo voi hrong dir dd AgN03 INH3 thi hrong Ag t6i da thu ducc la m

gam. Hi~u su~t pir dat 75%. Gia tri m la.A. 32,4 B. 48,6 C. 64,8 D. 24,3g.

Call 8: Cho 10,8 gam glucozo phan irng hoan toan voi dung dich AgN03INH3 (du) thi khoi hrong Ag thu ducc la:

A.2,16 gam B.3,24 gam C.12,96 gam D.6,48 gam

Call 9/ Cho m gam glucozo len men, khi thoat ra duoc d~n vao dd mroc voi trong dir thu ducc 55,2g k6t tua trang, Tinh kh6i hrong glucozo dll len men, biet hieu su~t len men la 92%.

A. 54 B. 58 C. 84 D. 46

Call 10:Khi len men 360 gam glucozo voi hieu su~t 100%, kh6i hrong aneol etylie thu ducc la:

A.184 gam B.138 gam C.276 gam D.92 gam TNPT-2007

Cau 11 : Thuy phan hoan toan 1 kg saccarozo thu ducc :

A. 1 kg glucozo va 1 kg fructozo B. 2 kg glucozo

C. 2 kg fructozo D. 0,5263 kg glucozo va 0,5263 fructozo

Cau 12: Kh6i hrong saccarozo cAn d6 pha 500 ml dung dich 1M la:

A. 85,5g B. 342g C. 171g D.684g

Call 13: Luong glucozo cAn dung d6 tao ra 1,82 gam sobitol voi hieu su~t 80% la

A. 2,25 gam. B. 1,80 gam. C. 1,82 gam. D. 1,44 gam.

Call 14: Til 16,20 t~n xenlulozo ngirci ta san xuat ducc m t~n xenlulozo trinitrat (biet hieu su~t phan irng tinh thea xenlulozo la 90%). Gia tri cua m la

A.26,73. B.33,00. C.25,46. D.29,70.

A. 4595 gam. B. 4468 gam. C. 4959 gam. D. 4995 gam.

Call 15: Mu6n e6 2610 gam glucozo thi khoi hrong saccarozo cAn dem thuy phan hoan toan la

Call 16: Dun n6ng 37,5 gam dung dich glucozo voi hrong AgN03/dung dich NH3 dir, thu ducc 6,48 gam bac, Nang dQ % cua dung dich glucozo la

A. 11,4 % B. 14,4 % C. 13,4 % D. 12,4 %

Call 17: CO2 chiem 0,03% th6 tieh khong khi. muon e6 du hrong CO2 eho phan irng quang hQ'P d6 tao ra 500 g tinh bQt thi cAn mQt th6 tieh khong khi la:

a. 1382666,7 lit B. 1382600,0 lit e. 1402666,7 lit d. 1492600,0 lit

Call 18: Cho m g tinh bQt len men d6 san xuat aneol etylie. Toan bQ CO2 sinh ra eho vao dung dich Ca(OH)z l~y dir ducc 750 gam k6t tua, Hieu su~t m6i giai dean len men la 80%. Gia tri cua m la:

A.940 g B.949,2 g C.950,5 g D.1000 g

Call 19 : Len men 1 t~n tinh bQt chua 5% tap eh~t tro thanh aneol etylie voi hieu su~t cua tirng giai dean la 85%. Kh6i hrong aneol thu ducc la:

A.398,8 Kgam B.390 Kgam C.389,8K gam D. 400Kgam

Call 20._ Kh6i hrong phan til trung binh cua xenlulozo trong soi bong la 1 750000 dvC. S6 g6e glucozo C6HlOOS trong phan til cua xenlulozo la

A.10 802 g6c B.1 621 g6c C. 422 g6c D. 21 604 g6c

Call 21: Phan til kh6i trung binh cua xenlulozo la 1620000. Gia tri n trong cong tlnrc (C6HlOOS)n la

A. 10000 B. 8000 C. 9000 D. 7000

23

Call 22: Kh6i hrong phan til trung binh cua xenlulozo trong soi bong la 4.860.000 (u). V~y s6 mAc xich

cua glucozo c6 trong xenlulozo n6u tren la: A.250.000 B.270.000 C.300.000

D.350.000

Call 23:. Bi6t kh6i IUQ'ng phan til trung binh cua PVC va xenlululozo IAn IUQ'1la 250000 va 1620000. H~ s6 polimehoa cua cluing IAn IUQ'1la:

A. 6200va 4000 B. 4000 va 2000 C. 400va 10000 D. 4000 va 10000

Call 24/ Cho m gam glucozo len men, khi thoat ra ducc d~n vao dd mroc voi trong dir thu ducc 50g k6t tua trang, Tinh kh6i IUQ'ng glucozo dll len men bi6t hieu su~t len men la 80%.

A. 33,7 B. 20 C.56,25 D.S6 khac

Call 25/ Cho 360gam glucozo len men, khi thoat ra ducc d~n vao dd mroc voi trong dir thu ducc m g k6t tua trang. Bi6t hieu su~t cua qua trinh len men dat 80%. Gia tri cua m la:

A. 400 B. 320 C.200 D.160

Call 26: Thuy phan 324 gam tinh bQt voi hieu su~t phan irng la 75%, kh6i IUQ'ng glucozo thu ducc la:

A.360 gam B.480 gam C.270 gam D.300 gam TNPT - 2007

Call 27: Len men glucozo thanh ancol etylic. Toan bQ khi CO2 sinh ra trong qua trinh nay duoc h~p thu h6t vao dd Ca(OH)2 dir tao ra 50 gam k6t tua, bi6t hieu su~t qua trinh len men dat 80%. V~y kh6i IUQ'ng glucozo cAn dung la:

A.33,7 gam B.56,25 gam C.20 gam 90 gam

Call 28: N6u dung 1 t~n khoai chua 20% tinh bQt thi thu ducc bao nhieu kg glucoza? Bi6t hieu su~t pir

la 70%. A. 160,55 B. 150,64 C. 155,54 C.165,65

Call 29 Khi len men 1 t~n ngo chua 65% tinh bQt thi kh6i IUQ'ng ancol etylic thu ducc la bao nhieu? Bi6t hieu su~t phan irng len men dat 80%.

A.290 kg B.295,3 kg C.300 kg D.350 kg

Call 30: Luong glucozo thu ducc khi thuy phan lkg khoai chua 20% tinh bQt (hieu su~t dat 81 %) la:

A. 162g B. 180g C. 81g D.90g

Call 31: Cho 18 gam glucozo len men thanh ancol etylic. Kh6i IUQ'ng ancol thu ducc la bao nhieu (

H=100%)? A. 9,2 am. B.4,6 gam. C. 120 gam. D. 180 gam.

cAc DE D~I HOC - CAO DANG QUA cAc NAM

Call 41:Saccaroza va glucozo d6u c6:

A.Phan irng voi dung dich NaCl.

B.Phan irng voi Cu(OH)z a nhiet dQ tlnrong tao thanh dung dich xanh lam. C.Phan irng thuy phan trong moi tnrong axit.

D.Phan irng voi dung dich AgN03INH3 dun n6ng. TNPT -2007

Call 42Phat bieu khong dung la:

A.Dung dich fructozo hoa tan ducc Cu(OH)z.

Bi'Thuy phan (xuc tac H+l) saccarozo cling nlnr mantozo d6u cho cung mQt monosacarit. C.san pham thuy phan xenlulozo (xuc tac H+l) c6 th6 tham gia phan irng trang guong, D.Dung dich mantozo tac dung voi Cu(OH)z khi dun n6ng cho k6t tua Cu20.DH kh6i B-2007

Call 43D6 clnrng minh trong phan til cua glucozo c6 nhieu hidroxyl, nguoi ta cho dung dich glucozo phan irng voi

A.kim loai N a B.AgN03 trong dung dich NH3 dun n6ng

C.Cu(OH)z trong NaOH, dun n6ng D.Cu(OH)z a nhiet dQ tlnrong. DH kh6i A-2007

Call 44hi dung Cu(OH)z c6 th6 phan biet ducc t~t ca cac dung dich rieng biet sau:

A.glucoza, mantozo, glixerin (glixerol), andehit axetic. B.glucoza, long trang tnrng, glixerin (glixerol), fructozo. C.saccaroza, glixerin (glixerol), andehit axetic,ancol etylic.

D.glucoza, long trang tnrng, glixerin (glixerol), acol etylic. CD kh6i A-2007

Call 45luxit (cacbonhidrat)chi chua hai g6c Glucozo trong phan til la:

A.saccaroza B.Tinh bQt C.mantoza D.xenluloza. DH kh6i A-2008

Call 46Tinh bQt .xenlulozo.saccarozo.mantozo d6u c6 kha nang tham gia phan irng

24

Ahoa tan Cu(OH)z. B.trimg ngung, C.tning guong. D.thuY phan DH kh6i A-2008

CaD47Cho cac ch~t (an col)etylic,glixein(glixeral),glucoza,dimetyl ete va axit fomit.So ch~t tac dung ducc voi Cu(OH)z la:

A 3 B.2 C.4 D.l. DH kh6i B-2008

CaD 48Cho day cac chat :C2H2,HCHO,HCOOH,CH3CHO,(CH3)zCO,C12H22011 (mantozoj.So ch~t trang day tham gia ducc phan irng trang girong la:

A5 B.3 C.6 D.4 DH kh6i B-2008

CaD49Cho day cac ch~t:glucoza,xenluloza,saccarazow,tinh bot.mantozo.So ch~t trang day tham gia phan irng trang girong la:

A3 B.4 C.2 D.5. CD kh6i A-2008

CaD 50ho sa da chuyen hoa sau(m6i miii ten la mot phirong trinh phan irng):

Tinh bQt ~ X ~ Y ~ z~ metyl axetat. Cac chat Y ,Z trang sa da tren IAn hroc la :

AC2HsOH,CH3COOH. B.CH3COOH,CH30H. CD kh6i A-2008

C.CH3COOH,C2HsOH. D.C2H4,CH3COOH.

CHUONG 3: AMIN - AMINOAXIT - PEPTIT - PROTEIN I. TRA.C NGHIEM LY THUYET:

CaD 1: S6 dang phan amin co cong tlnrc phan til C2H7N la

A.4. B.3. C.2. D.5.

CaD 2: S6 dang phan amin co cong tlnrc phan til C3H9N la

A.4. B.3. C.2. D.5.

CaD 3: S6 dang phan amin co cong tlnrc phan til C4HllN la

A.5. B.7. C.6. D.8.

CaD 4: S6 dang phan amin bac mQt irng voi cong tlnrc phan til C3H9N la

A.4. B.3. C.2. D.5.

CaD 5: S6 dang phan amin bac mQt irng voi cong tlnrc phan til C4HllN la

A.4. B.3. C.2. D.5 ..

CaD 7: Anilin co cong tlnrc la A. CH3COOH. B. C6HsOH.

CaD 8: Trang cac ch~t sau, ch~t nao la amin bac 2?

A. H2N-[CH2J6-NH2 B. CH3-CH(CH3)-NH2 C. CH3-NH-CH3 D. C6HsNH2

CaD 10: Trang cac ten goi duoi day, ten nao phu hQ'P voi chat CH3-CH(CH3)-NH2?

A. Metyletylamin. B. Etylmetylamin. C. Isoprapanamin. D. Isoprapylamin.

CaD 11: Trang cac ten goi duoi day, chat nao co hrc bazo manh nh~t ?

A. NH3 B. C6HsCH2NH2 C. C6HsNH2

CaD 12: Trang cac ten goi duoi day, chat nao co hrc bazo y6u nh~t ?

A. C6HSNH2 B. C6HsCH2NH2 C. (C6Hs)zNH

CaD 13: Trang cac ten goi duoi day, ten nao phu hQ'P voi chat C6Hs-CH2-NH2?

A. Phenylamin. B. Benzylamin. C. Anilin.

CaD 14: Trang cac ch~t duoi day, chat nao co tinh bazo manh nhat ?

A. C6HSNH2. B. (C6HS)zNH C. p-CH3-C6H4-NH2.

CaD 15: Ch~t khfmg co kha nang lam xanh mroc quy tim la

A. Anilin B. Natri hidraxit. C. Natri axetat.

CaD 16: Ch~t khfmg phan irng voi dung dich NaOH la

A. C6HSNH3Cl. B. C6HsCH20H. C. p-CH3C6H40H. D. C6HsOH.

CaD 17: D6 tach rieng tirng ch~t til h6n hQ'P benzen, ani lin, phenol ta chi cAn dung cac hoa ch~t (dung cl,l,di6u kien thi nghiem dAy du) la

A. dung dich NaOH, dung dich HCI, khi CO2. C. dung dich Br2, dung dich NaOH, khi CO2.

D. Phenylmetylamin.

D. Amoniac.

B. dung dich Br2, dung dich HCI, khi CO2. D. dung dich NaOH, dung dich NaCl, khi

CO2.

CaD 18: Day gam cac chat d6u lam gi~y quy tim ~m chuyen sang mau xanh la:

25

A. anilin, metyl amin, amoniac. B. amoni c1orua, metyl amin, natri hidroxit.

C. anilin, amoniac, natri hidroxit. D. metyl amin, amoniac, natri axetat.

Cau 19: K6t tua xuat hien khi nho dung dich brom vao

A. ancol etylic. B. benzen. C. anilin. D. axit axetic.

Cau 20: Ch~t lam gi~y quy tim ~m chuyen thanh mau xanh la

A. C2HsOH. B. CH3NH2. C. C6HSNH2. D. NaCl.

Cau 21: Anilin (C6HsNH2) phan irng voi dung dich

A. NaOH. B. HCl. C. Na2C03. D. NaCl.

Cau 22: C6 3 ch~t long benz en, anilin, stiren, dung rieng biet trong 3 lo ~t nhan, Thu6c thir d6 phan biet 3 ch~t long tren la

A. dung dich phenolphtalein. B. mroc bromo C. dung dich NaOH. D. gi~y qui

tim.

Cau 23: Anilin (C6HSNH2) va phenol (C6HsOH) d6u c6 phan irng voi

A. dung dich NaCl. B. dung dich HCl. C. mroc Br2.

Cau 24: Dung dich metylamin trong mroc lam A. qui tim khong d6i mau,

C. phenolphtalein hall xanh.

Cau 25: Ch~t c6 tinh bazo la

A. CH3NH2. B. CH3COOH. C. CH3CHO. D. C6HsOH.

Cau 26: Ba ch~t long: C2HsOH, CH3COOH, CH3NH2 dung trong ba lo rieng biet, Thu6c thir dung d6 phan biet ba ch~t tren la

A. quy tim. B. kim loai Na. C. dung dich Br2. D. dung dich NaOH.

Cau 27. Day gam cac chat ducc x6p thea chieu tinh bazo giam dAn til trai sang phai la

A. CH3NH2, NH3, C6HSNH2. B. CH3NH2, C6HSNH2, NH3.

D. dung dich NaOH.

B. qui tim h6a xanh.

D. phenolphtalein khong d6i mau,

Cau 28: Cho day cac ch~t: phenol, ani lin, phenylamoni c1orua, natri phenolat, etanol. S6 ch~t trong day phan irng ducc voi NaOH (trong dung dich) la

A.3. B.2. C.1. D.4.

Cau 29: C6 th6 nhan bi6t lo dung dd CH3NH2 bang each nao trong cac each sau:

A. Nhan bi6t bang mui

B. Them vai giot dd H2S04

C. Them vai giot Na2C03

D. Dira dua thuy tinh da nhung vao dd HCl d~m d~c len phia tren mieng lo dung dd CH3NH2 d~m d~c. Cau 30: Cac hien tuong nao sau day rna ta khong chinh xac?

A. Nhung quy tim vao dd etylamin thay quy chuyen thanh mau xanh

B. Phan irng giita khi metylamin va khi hidroc1orua lam xuat hien "kh6i trang"

C. Nho vai giot dd mroc brom vao 6ng nghiem dung dd ani lin thay c6 k6t tua trang

D. Them vai giot phenolphtalein vao dd dimetylamin thay xuat hien mau xanh. Cau 31: trong cac ch~t duoi day ten nao phu hQ'P voi chat :

CH3 -CH-NH2

I

A. Metyletylamin B. Etylmetylamin C. Isopropan D. Isopropinamin

Cau 32. Cho amin c6 du tao: CH3-CH(CH3)-NH2. Chon ten goi khong aung?

A. Prop-l-ylamin B. Propan-2-amin C. isoproylamin

Cau 33. Ten goi dung C6HSNH2 dung? A. Benzyl amoni

Hexylamin D. Anilin

Cau 34: Amin nao duoi day la amin bac 2?

A. CH3-CH2NH2 B. CH3-CHNH2-CH3 C. CH3-NH-CH3 D. CH3-NCH3-CH2-CH3

Cau 35: Cfmg tlnrc nao duoi day la cong tlnrc chung cua day dang dllng amin thorn (chua 1 vong bezen) dan clnrc bac nhat?

D. Prop-2-ylamin

B. Phenyl amoni C.

26

Call 36: Ten goi cac amin nao sau day la khong aung?

A. CH3-NH-CH3 dimetylamin B. CH3-CH2-CH2NH2 n-propylamin

C. CH3CH(CH3)-NH2 isopropylamin D. C6HSNH2 alanin

Call 37: Amin nao duoi day c6 4 dang phan du tl;to?A. C2H7N B. C3H9N C. C4HllN D. CsH13N

Call 38: D6 phan biet phenol, ani lin, benz en, stiren nguoi ta sil dung IAn hrot cac thuoc thir nao sau?

A. Qui tim, brom B. dd NaOH va brom C. brom va qui tim D. dd HCI va qui tim

Call 39: Nhan xet nao duoi day khong dung?

A. Phenol la axit can ani lin la bazo.

B. Dd phenol lam qui tim h6a do can dd anilin lam qui tim h6a xanh.

C. Phenol va anilin d6u d6 tham gia phan irng th6 va d6u tao k6t tua trang voi dd bromo

D. Phenol va ani lin d6u kh6 tham gia phan irng cong va d6u tao hQ'P chat vong no khi cong voi hidro.

Call 40: Sa di ani lin c6 tinh bazo y6u han NH3 la do y6u t6 nao?

A. Nh6m NH2- can 1 c~p electron tu do chua tham gia lien k6t.

B. Nh6m NH2- c6 tac dung d~y electron v6 phia vong benzen lam giam mat dQ electron cua N.

C. G6c phenyl c6 anh huang lam giam mat dQ electron cua nguyen til N.

D. Phan til kh6i cua ani lin Ian han so voi NH3 Call 41: Hay chi ra di6u sai trong cac di6u sau?

A. Cac amin d6u c6 tinh bazo B. Tinh bazo cua anilin y6u han NH3

C. Amin tac dung voi axit cho ra muoi D. Amin la hQ'P chat him co c6 tinh chat luang tinh

Call 42 : Dd etylamin tac dung voi dd mnrc cua chat nao sau day?

A. NaOH B. NH3 C. NaCI D. FeCh va H2S04

Call 43: HQ'P ch~t nao duoi day c6 tinh bazo y6u nhat?

A. Anilin B. Metylamin C. Amoniac

Call 44: slip x6p cac ch~t sau day thea tinh bazo giam dAn?

(1) C6HSNH2 (2) C2HSNH2 (3) (C6Hs)zNH (4) (C2HS)zNH

A.1>3>5>4>2>6 B.6>4>3>5>1>2 C.5>4>2>1>3>6

D. Dimetylamin

(5) NaOH (6) NH3

D. 5>4>2>6> 1>3

Call 45: Dd nao duoi day khong lam qui tim d6i mau?

A. C6HSNH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3

Call 46: Dd etylamin khong tac dung voi chat nao sau day?

A. axit HCI B. dd CuCh C. dd RN03 D. Cu(OH)z

Call 47: Dung mroc brom khong phan biet ducc 2 ch~t trong cac c~p nao sau day?

A. dd ani lin va dd NH3 B. Anilin va xiclohexylamin C. Anilin va phenol D. Anilin va benz en.

II. TRA.C NGHIEM BAI TAp:

II/BAI TAp:

D~NG 1: TiNH KHDI LUQNG AMIN (MUDI) TRONG PHAN UNG Val AXiT HO~C VOl BROM

* can nhti 2 phU'tmg trinh:

+ V tri Htl]: RNH2 + HCI -7

+V&i Brom: C6HsNH2 + 3Br2 -7

RNH3CI (1)

C6H2Br3NH21 + 3HBr k~t tua trdng

*PP:l) Ap dung dinh IWJt tang giam kh6i luang

2) Ap dung dinh IWJt bao toan kh6i luang kh6i luang

3) Tinh mol cua chat tlJ bili cho r6i aijt VGO ptrinh a~ suy ra s6 mol cua cha.t tlJ bili hoi => tinh m

* Vd: Cho 9,3 gam ani lin (C6HSNH2) tac dung vira du voi axit HCI. Khoi IUQ'ng muoi thu ducc la

A. 11,95 gam. B. 12,95 gam. C. 12,59 gam. D. 11,85 gam.

Phiin tich tlJ: - D~ cho mC6HSNH2 = 9,3g -7 Tinh nC6HsNH2

- D6 hoi mmu6i =? -7 D~t mol cua C6HSNH2 vira tinh vao phirong trinh d6 suy ra mol cua muoi cAn tim => mmu6i

HD: nC6HSNH2 = 9,3 = 0,1 mol

- 93

27

C6HSNH2 + HCl -7 C6HsNH3Cl

0,1 -7 0,1

mmu6;= 0,1.129,5 =12,95g

!!f!i:£.;_ Ap dung pp tang giam kh6i luang

C6HSNH2 + HCl -7 C6HsNH3Cl

93 -7 Tang 36,5

9,3 -7 Am = 9,3.36,5 =3.65

93

~ mMu6; = 9,3 + 3,65 = •••••••••••••• (g)

Ho¥c: Dinh lu

DANG 2: xAc BINH CAU TAO AMIN BaN CHUC DUA V AO PHAN UNG TAO MUC)J V A BOT

CHAy .. . .

* n6i v6"i pu i16t chay nh6": + D~t CTTQ cua amin no Qtm chuc hoac amin Qtm chuc la: CxHylV

, x nco

Ap dung CT: _ = __ 2

Y 2nHO

2

* Phan ung tao mu6i: D~t CTTQ cua amin no Qtm chuc hoac amin Qtm chuc la: R-NH2 Vi dan clnrc nen ta luon co nRCl = nNH2

Ap dung CT:

mRNH

M = __ 2 = a => MR =a -16 => CTPT

RNH2 n HCl

Luu y: D6 tim CTPT cua mQt eh~t nao do phai luon nho d6n CT: M= m n

Vd1: Dot chay mQt dong dang cua metylamin, ngirci ta thay ti l~ the tieh cac khi va hoi V C02:VH20 sinh ra bang 2:3 Cong tlnrc phan til cua amin la:

A. C3H9N B. CHsN C. C2H7N D. C4HllN

HD x nC02 VC02 2 1 C~ tlni h~ t" . l' CHN

: - = -- = = - = - => ong ue p an u eua amm a: 3 9

Y 2nH 0 2.VH 0 6 3

2 2

Vd2: Trung hoa 11,8 gam mQt amin dan clnrc cAn 200 ml dung dich HCllM. Cong tlnrc phan til cua X la

A. C2HSN

B. CHsN

nRCl = 0,2.1=0,2mol-7 MRN= 11,8 =59 -7 MR = 59-14=45-7 CTPT C3H9N

0,2

BAI ~P Ap Dl}NG:

Call 1: Cho 5,9 gam Prapylamin (C3H7NH2) tac dung vira du voi axit HCl. Kh6i hrong muoi (C3H7NH3Cl) thu ducc la (Cho H = 1, C = 12, N = 14)

A. 8,15 gam. B. 9,65 gam. C. 8,10 gam. D. 9,55 gam.

Call 2: Cho 4,5 gam etylamin (C2HsNH2) tac dung vira du voi axit HCl. Kh6i hrong muoi thu ducc la

A. 7,65 gam. B. 8,15 gam. C. 8,10 gam. D. 0,85 gam.

Call 3: Cho ani lin tac dung vira du voi dung dich HCl thu ducc 38,85 gam muoi, Kh6i hrong anilin dll

phan irng la,: A. 18,6g B.9,3g, <;.37,2g , Q.27,9g.

Call 4: The tieh mroc brom 3% (d = 1,3g/ml) can dung de dieu che 4,4 gam ket tua 2,4,6 - tribram ani lin la

A. 164,lml. B.49,23ml. C 146,lml. D. 16,41ml.

Call 5 Cho 11,25 gam C2HSNH2 tac dung voi 200 ml dung dich HCl x (M). Sau khi phan irng xong thu ducc dung dich co chua 22,2 gam chat tan. Gia tri cua x la

A. 1,3M B. 1,25M C. 1,36M D. 1,5M

Call 6: Cho etyl amin tac dung du 2000 ml dd HCl 0,3M. kh6i hrong san pham

A. 48,3g. B. 48,9g. C. 94,8g. D. 84,9g.

28

Call 7: Cho 7,75 metyl amin tac dung du HCl kh6i hrong san pham la

A. 11,7475. B. 16,785. C. 11,7495. D.16,875.

Call 8: Cho anilin tac dung 2000ml dd Br2 0,3M. Kh6i hrong k6t tua thu ducc la

A.66.5g B.66g C.33g D.44g

Call 9: ( TN- PB- 2007)Cho 9 gam C2HSNH2 tac dung vira du voi dung dich HCl, hrong muoi thu ducc

la A. 0,85gam. B. 16,3 gam. C.7,65gam. D.8,10gam.

Call 10: (TN- B6 toe -2009) Cho 0,1 mol anilin (C6HSNH2) tac dung vira du voi axit HCI. Kh6i hrong muoi phenylamonic1orua ( C6HsNH3Cl) thu ducc la

A. 25,900 gam. B. 6,475gam. C. 19,425gam. D. 12,950gam

Call 11: Cho m gam Anilin tac dung h6t voi dung dich Br2 thu ducc 9,9 gam k6t tua, Gia tri m dll dung la

A. 0,93 g~m B. 2,79 gam ,C. 1,86 g;;tm , , D. 3,72 gam

Call 12: The tich mroc brom 5 % (d = 1,3g/ml) can dung de dieu che 3,96 gam ket tua 2,4,6 - tribram ani lin la

A. 164,lmI. B.49,23mI. C 88,61 mi. D. s6 khac .

Call 13:D6t chay hoan toan mot amin dan clnrc ba 1 thu ducc CO2 va H20 thea tile CO2 =~. Yay CT

. .. . H 0 7 .

2

C. CHsN

Call 14:D6t chay hoan toan mot amin dan clnrc chua no thu ducc CO2 va H20 thea ti Ie CO2 =~. Yay

. . . H 0 9 .

2

Call 15. £)6t chay hoan toan mQt amin don chirc chua no co mQt lien ket doi (] mach cacbon ta thu ducc CO2 va H20 thea ti Ie mol = 6:9. V~y cong tlnrc phan t11 cua amin la cong thirc nao?

A. CH3NH2 B. C4H9N C. C2H7N D. C3H9N

Call 16. D6 trung hoa 25 gam dung dich cua mQt amin dan clnrc X nang dQ 12,4% cAn dung 100ml dung dich HCllM. Cong tlnrc phan til cua X la (Cho H = 1; C = 12; N = 14)

A.C3H7N. B.C2H7N. C.C3H5N. D.CH5N.

Call 17 : D6 trung hoa 20 gam dung dich cua mQt amin dan clnrc X nang dQ 22,5% cAn dung 100ml dung dich HCllM. Cong tlnrc phan til cua X la (Cho H = 1; C = 12; N = 14)

A. C2H7N B. CHsN C. C3HSN D. C3H7N

H' d:t C%.mdd = 4 5 am 0 1 ....3Iio.. M 4 5/0 1 45....31io.. A

U'O'ng an: mAmin = 100 ' g , nHel = , = n Amin "'7 Amin =, , = "'7 •

C2H7N

Call 18: Trung hoa 3,1 gam mQt amin dan clnrc cAn 100 ml dung dich HCllM. Cong tlnrc phan til cua X la

A. C2HSN B. CHsN C. C3H9N D. C3H7N

Call 19. Khi d6t chay hoan toan mQt amin dan clnrc X, thu ducc 8,4 lit khi C02, 1,4 lit khi N2 (cac th6 tich khi do 6 dktc) va 10,125 gam H20. Cong tlnrc phan til cua X la (cho H = 1,0 = 16)

A.C2H7N. B.C4H9N. C.C3H7N. D.C3H9N.

Cau 20: Dot chay mot amin no don chile mach thang ta thu diroc CO2 va H20 co ti l~ mol ncoz : nHzO = 8 : 11. CTCT cua X la :A. (C2Hs)2NH B. CH3(CH2)3NH2 C. CH3NHCH2CH2CH3 D. Ca 3 Call 21. D6t chay mQt amin dan clnrc no (ho) thu ducc ti l~ s6 mol CO2: H20 la 2 : 5. Amin dll cho co ten goi nao duoi day?

A. Dimetylamin, B. Metylamin. C. Trimetylamin. D.lzoprapylamin

Call 22: D6t chay hoan toan 5,9 gam mQt amin no ho dan clnrc X thu ducc 6,72 lit CO2, . Cong tlnrc

cua X la A. C3H60. B. C3HsN03. C. C3H9N. D. C3H7N02.

Call 23: D6t chay hoan toan 6,2 gam mQt amin no ho dan clnrc, cAn 10,08 lit O2 dktc. CTPT la

A. C4HllN. H. CHsN. C. C3H9N. D. CsH13N.

29

Call 24: Ddt chay hoan toan amin no dan clnrc X, thu ducc 16,8 lit CO2; 2,8 lit N2 (dktc) va 20,25 g H20. Cong tlnrc phan til cua X la

A. C4H9N. B. C3H7N. C. C2H7N. D. C3H9N.

Call 25: (SBT) Khi ddt chay hoan toan mQt amin dan clnrc X, thu ducc 16,8 lit khi CO2. 2,8 lit khi N2 ( dktc) va 20,25 gam mrcc. Cong tlnrc phan til cua X la

A. C4H9N. B. C3H7N. C. C2H7N. D. C3H9N.

Call 26. Khi ddt chay hoan toan mQt amin dan clnrc X, thu ducc 8,4 lit khi CO2 va 1,4 lit khi N2 va 10,125g H20. Cong tlnrc phan til la (cac khi do a dktc)

A. C3HS-NH2. B. C4H7-NH2. C. C3H7-NH2. D. CSH9-NH2.

AMINOAXIT - PEPTIT - PROTEIN I. TRA.C NGHIEM LY THUYET:

Call 1: Amino axit la hQ'P chat him co trang phan til

A. chua nh6m cacboxyl va nh6m amino. B. chi chua nh6m amino.

C. chi chua nh6m cacboxyl. D. chi chua nita hoac cacbon.

Call 2: C4H902N c6 ~y dang phan amino axit c6 nh6m amino a vi tri a?

A.4. B.3. C.2. D.5.

Call 3: C6 bao nhieu amino axit c6 cung cong thirc phan til C4H902N?

A. 3 chk B. 4 chat, c. 5 chk D. 6 chk

Call 4: C6 bao nhieu amino axit c6 cung cong thirc phan til C3H702N?

A. 3 chk B. 4 chat, c. 2 chk D. 1 chk

Call 5: Trang cac ten goi duoi day, ten nao khfmg phu hQ'P voi chat CH3-CH(NH2)-COOH ?

A. Axit 2-aminoprapanoic. B. Axit a-aminoprapionic. C. Anilin. D. Alanin.

Call 6: Trang cac ten goi duoi day, ten nao khfmg phu hQ'P voi chat CH3-CH(CH3)-CH(NH2)-COOH?

A. Axit 3-metyl-2-aminobutanoic. B. Valin.

C. Axit 2-amino-3-metylbutanoic. D. Axit a-amino isovaleric.

Call 7: Trang cac ch~t duoi day, chat nao la glixin?

A. H2N-CH2-COOH B. CH3-CH(NH2)-COOH

C. HOOC-CH2CH(NH2)COOH D. H2N-CH2-CH2-COOH

Call 8: Dung dich cua chat nao sau day khong lam d6i mau quy tim :

A. Glixin (CH2NH2-COOH) B. Lizin (H2NCH2-[CH2hCH(NH2)-COOH)

C. Axit glutamic (HOOCCH2CHNH2COOH) D. Natriphenolat (C6HsONa)

Call 9: Ch~t X vira tac dung ducc voi axit, vira tac dung ducc voi bazo. Ch~t X la

A. CH3COOH. B. H2NCH2COOH. C. CH3CHO. D. CH3NH2.

Call 10: Ch~t nao sau day vira tac dung ducc voi H2NCH2COOH, vira tac dung ducc voi CH3NH2?

A. NaCl. B. HCl. C. CH30H. D. NaOH.

Call 11: Ch~t d.n khong mau, d6 tan trang mroc, k6t tinh a di6u kien thuong la

A. C6HSNH2. B. C2HsOH. C. H2NCH2COOH. D. CH3NH2.

Call 12: Ch~t tham gia phan irng trung ngirng la

A. C2HsOH. B. CH2 = CHCOOH. C. H2NCH2COOH. D. CH3COOH.

Call 13: Cho day cac ch~t: C6HSNH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6HsOH (phenol). se ch~t trang day tac dung ducc voi dung dich HClia

A.4. B.2. C.3. D.5.

Call 14: D6 clnrng minh aminoaxit la hQ'P chat luang tinh ta c6 th6 dung phan irng cua chat nay IAn hrot

voi

A. dung dich KOH va dung dich HCl.

C. dung dich HCI va dung dich Na2S04 .

B. dung dich NaOH va dung dich NH3. D. dung dich KOH va CuO.

Call 15: Ch~t phan irng ducc voi cac dung dich: NaOH, HClia

A. C2H6. B. H2N-CH2-COOH. C. CH3COOH. D. C2HsOH.

Call 16: Axit aminoaxetic (H2NCH2COOH) tac dung ducc voi dung dich

A. NaN03. B. NaCl. C. NaOH. D. Na2S04.

30

Cau 17: Dung dich cua chat nao trong cac ch~t duoi day khfmg lam d6i mau quy tim ?

A. CH3NH2. B. NH2CH2COOH C. HOOCCH2CH2CH(NH2)COOH. D.

CH3COONa.

Cau 18: D6 phan biet 3 dung dich H2NCH2COOH, CH3COOH va C2HSNH2 chi cAn dung mQt thuoc thir la

A. dung dich NaOH. B. dung dich HCI. C. natri kim loai, D. quy tim.

Cau 19: Co cac dung dich rieng biet sau: C6Hs-NH3CI (phenylamoni c1orua), H2N-CH2-CH2-CH(NH2)COOH, C1H3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S6lm;mg cac dung

dich co pH < 7la A.2. B.5. C.4. D.3.

Cau 20: Glixin khfmg tac dung voi

A. H2S04loang. B. CaC03. C. C2HsOH. D. NaCl.

Cau 20: Tri peptit la hQ'P chat

A. rna m6i phan til co 3 lien k6t peptit.

B. co lien k6t peptit rna phan til co 3 g6c amino axit giong nhau.

C. co lien k6t peptit rna phan til co 3 g6c amino axit khac nhau.

D. co 2 lien k6t peptit rna phan til co 3 g6c a-amino axit.

Cau 21: Co bao nhieu tripeptit rna phan til chua 3 g6c amino axit khac nhau?

A. 3 chk B. 5 chat, C. 6 chk D. 8 chk

Cau 22: Trong cac ch~t duoi day, chat nao la dipeptit ?

A. H2N-CH2-CO-NH-CH2-CH2-COOH.

B. H2N-CH2-CO-NH-CH(CH3)-COOH.

C. H2N -CH2-CO- NH -CH(CH3)-CO- NH -CH2-COOH.

D. H2N -CH(CH3)-CO- NH -CH2-CO- NH -CH(CH3)-COOH

Cau 23: Til glyxin (Gly) va alanin (Ala) co th6 tao ra ~y chat dipeptit ?

A. 1 chk B. 2 chat, C. 3 chk D. 4 chk

Cau 24: S6 dang phan tripeptit tao thanh til 1 phan til glyxin va 2 phan til alanin la

A.2. B.3. C.5. D.4.

Cau 25: S6 dang phan tripeptit co chua g6c cua ca glyxin va alanin la

A.6. B.3. C.5. D.4.

Cau 26: San pham cu6i cung cua qua trinh thuy phan cac protein dan gian nho chat xuc tac thich hop la

A. u-aminoaxit, B. ~-aminoaxit. C. axit cacboxylic. D. este.

Cau 27: S6 dang phan dipeptit tao thanh til 1 phan til glyxin va 1 phan til alanin la III Biti tap:

D~NG 1: TiNH KHOI LUQNG CVA AMINO AXIT TRONG PHAN UNG Val AXiT HO~C BAZa

* Phai vi~t auac 2 phuang trinh co dang: + V tri axit Htl]:

H2N- R - COOH+ HCI 7 CIH3N- R - COOH + V&i baza NaOH:

H2N- R - COOH+ NaOH 7 H2N- R - COONa+ H20 **PP: - Ap dung phuong phdp tang giam kh6i luang

- Ap dung iinh IWJt bao toan kh6i luang

- Dijt s6 mol vao ptrinh r6i tinh gi6ng pp cua cae bai ail trinh bay a tren.

Vd1: (TN- KPB- 2007- L2)Khi cho 3,75 gam axit amino axetic (NH2CH2COOH) tac dung het voi dung dich NaOH, kh6i IUQ'ng muoi tao thanh la

A. 4,5gam. B. 9,7gam. C.4,85gam. D. 10gam.

HD: NH2CH2COOH + NaOHo7 H2N- CH2 - COONa+ H20

Ap dungpp tanggiam kh6i luang: 75 7 tang 22

3,75 7 tang =Am

31

Am = 3,75.22 -1,1 g => mmu6i =3,75 + 1,1 =4,85g 75

Hoac: NH2CH2COOH + NaOH-7 H2N- CH2 - COONa+ H20

75 97

3,75

m = 97.3,75 =485

75 '

m=?

Vd 2: Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phan irng h6t voi dung dich HCI. Sau phan irng, kh6i hrong muoi thu ducc la (Cho H = 1, C = 12,0 = 16, Cl = 35,5)

A. 43,00 gam. B. 44,00 gam. C. 11,05 gam. D. 11,15 gam.

HD: H2N- CH2 - COOH+ HCl -7 CIHH2N- CH2 - COOH

Ap dungpp fanggiam kh6i luang 75 -7 tang 36,5

7,5 -7 tang =Am

Am= 7,5.36,5 - 3,65g => mmu6i = 7,5 + 3,65 = 11,15g 75

H2N- CH2 - COOH+ HCl -7 CIHH2N- CH2 - COOH

75 111,5

7,5 m= ? m= 111,5.7,5 -1115g

75 '

D~NG 2: TIM CTCT CVA AMINO AXiT DT/A V Ao PU T~O MUDI

*TI d{mg v6i NaOH:.

Ptpu: (H2N)a - R - (COOH)b + bNaOH -7 (H2N)a - R - (COONa)b + bH20

-7 nNaOH = b = s6 nh6m clnrc axit - COOH

namin

* Tldv6iHCl

Ptpu: (H2N)a - R - (COOH)b + aHCI -7 (CIH3N)a - R - (COOH)b

-7 nHCl = a = s6 nh6m clnrc baz -NH2

namin

Vd1: MQt (1- amino axit X chi chua 1 nh6m amino va 1 nh6m cacboxyi. Cho 10,68 gam X tac dung voi HCl dir thu ducc 15,06 gam muoi, Ten goi cua X la

A. axit glutamic. B. valin. C. alanin. D. Glixin

CTTQ: H2N-R-COOH + HCl-7 CIH3N -R- COOH

R+61 -7 tang 36,5

10,68 -7 tang 4,38

R+61 = 10,68.36,5 =89 => R= 89-61 =28 (C2H4) => CTPT: CH3-CH(NH2)-COOH 4,38

Vd 2:0,1 mol aminoaxitX phan irng vira du voi 0,2 molHCl hoac 0,1 mol NaOH. Cong tlnrc cua X c6 dang la.

A. (H2N)zR(COOH)z. B. H2NRCOOH. C. H2NR(COOH)z. D. (H2N)zRCOOH

HD: CTTQ: (H2N)a - R - (COOH)b

a = n HCl = 0,2 = 2.

° 1 '

namin ,

b= nNaOH = 0,1 = 1 => CTPT:

namin 0,1

DANG 3: DDT CHAy AMINOAXIT

D~t CTTQ c.n.o.x,

m m m m . ma .

x: y: z:t = ____s;_: ___!!._ : ___Q_ : ____!!_ = nC02 : 2.nH20 . - . 2.nN2

12 1 16 14 16

32

Hay

Call 1: (TN- PB- 2007) Cho 8,9 gam alanin (CH3CH(NH2)COOH) phan irng het voi dung dich NaOH. Kh6i hrong muoi thu ducc la

A. 11,2gam. B.31,9gam. C.11,1gam. D. 30,9 gam.

Call 2: Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phan irng h6t voi dung dich HCI. Sau phan irng, kh6i hrong muoi thu ducc la (Cho H = 1, C = 12,0 = 16, Cl = 35,5)

A. 43,00 gam. B. 44,00 gam. C. 11,05 gam. D. 11,15 gam.

Call 3: Cho m gam alanin phan irng h6t voi dung dich NaOH. Sau phan irng, kh6i hrong muoi thu ducc 11,1 gam. Gia tri m da dung la (Cho H = 1, C = 12,0 = 16, Na = 23)

A. 0,89 gam. B. 10,3 gam. C. 8,9 gam. D. 7,5 gam.

Call 4: Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phan irng h6t voi dung dich NaOH. Sau phan irng, kh6i hrong muoi thu ducc la (Cho H = 1, C = 12,0 = 16, Na = 23)

A. 9,9 gam. B. 9,8 gam. C. 7,9 gam. D. 9,7 gam.

Call 5: ( TN- KPB- 2007- L2)Khi cho 3,75 gam axit amino axetic (NH2CH2COOH) tac dung h6t voi dung dich NaOH, kh6i hrong muoi tao thanh la

A. 4,5gam. B. 9,7gam. C.4,85gam. D. 10gam.

Call 6. x la mQt a - amioaxit no chi chua 1 nh6m -NH2 va 1 nh6m -COOH. Cho 23,4 gam X tac dung voi HCl dir thu ducc 30,7 gam muoi, Cong tlnrc du tao thu gon cua X la cong tlnrc nao?

A. CH3-CH(NH2)-COOH B. H2N-CH2-COOH

C.H2N-CH2CH2-COOH D.CH2=C(CH3)CH(NH2)COOH

Call 7. X la mQt aminoaxit no chi chua 1 nh6m - NH2 va 1 nh6m COOH. Cho 0,89 gam X tac dung voi HCl vira du tao r a 1,255 gam muoi, Cong tlnrc du tao cua X la cong tlnrc nao sau day?

A. H2N- CH2-COOH B. CH3- CH(NH2)-COOH.C. CH3-CH(NH2)-CH2-COOH.D. C3H7-CH(NH2)-

COOH

Call 8. X la mQt a - amioaxit no chi chua 1 nh6m -NH2 va 1 nh6m -COOH. Cho 15,1 gam X tac dung voi HCl dir thu ducc 18,75 gam muoi, Cong tlnrc du tao cua X la cong tlnrc nao?

A. C6Hs- CH(NH2)-COOH B. CH3- CH(NH2)-COOH

C. CH3-CH(NH2)-CH2-COOH D. C3H7CH(NH2)CH2COOH

Call 9 : X la m9t amino axit. Khi cho 0,01 mol X tac dung voi HCl thi dung het 80 ml dung dich HCl 0,125 M va thu diroc 1,835 g mu6i khan. Con khi cho 0,01 mol X tac dung voi dung dich NaOH thi can 25 gam dung dich NaOH 3,2%. Cong tlnrc nao sau day la cua X?

A. C7H12-(NH)-COOH B. C3H6-(NH)-COOH C. NH2-C3Hs-(COOH) D. (NH2kC3Hs-

COOH

Call 10: M9t amino axit (X) co cong tlnrc t6ng quat NH2RCOOH. D6t chay hoan toan a mol X thu diroc 6,729 (1) CO2 (dktc) va 6,75 g H20. CTCT cua X la :

D.OiBvaC

Call l1:Cho 4,41g m9t aminoaxit X tac dung voi dung dich NaOH dir cho ra 5,73g mu6i. Mat khac cling hrong X nhir tren neu cho tac dung voi dung dich HCl dir thu diroc 5,505 g mu6i c1orua. Xd CTCT cua X.

A. HOOC-CH2CH2CH(NH2)COOH B. CH3CH(NH2)COOH C. HOOCCH2CH(NH2)CH2COOH D.Ca A,B

Call 12: 0,1 mol aminoaxit A pharr irng vira du voi 0,2 mol HCl, san pham tao thanh pir vira h6t voi 0,3 mol NaOH. Gill tri n, m iAn hrot la:

A. (H2N)zR(COOH)z. B. H2NRCOOH. C. H2NR(COOH)z. D. (H2N)zRCOOH

33

CHUONG 4: POLIME - VAT LIEU POLIME

. .

I. TRA.C NGHIEM LY THUYET:

Call 1: Polivinyl clorua c6 cong tlnrc III

A. (-CH2-CHCI-)z. B. (-CH2-CH2-)n. C. (-CH2-CHBr-)n. D. (-CH2-CHF-)n.

Call 2: Ch~t khfmg c6 kha nang tham gia phan irng trung hQ'P III

A. stiren. B. isopren. C. prop en. D. toluen.

Call 3: Ch~t c6 kha nang tham gia phan irng trung hQ'P III

A. propan. B. prop en. C. etan. D. toluen.

Call 4: Qua trinh nhieu phan til nho (monome) k6t hQ'P voi nhau thanh phan til Ian (po lime) dang thai giai ph6ng nhirng phan til mroc goi III phan irng

A. nhiet phan, B. trao d6i. C. trung hQ'P. D. trung ngung,

Call 5: Qua trinh nhieu phan til nho (monome) k6t hQ'P voi nhau thanh phan til Ian (po lime) dang thai giai ph6ng nhirng phan til mroc ducc goi III phan irng

A. trao d6i. B. nhiet phan, C. trung hQ'P. D. trung ngung,

Call 6: Ten goi cua polime c6 cong tlnrc (-CH2-CH2-)n III

A. polivinyl c1orua. B. polietilen. C. polimetyl metacrylat. D. polistiren.

Call 7: Til monome nao sau day c6 th6 di6u ch6 ducc poli(vinyl ancol)?

A. CH2=CH-COOCH3. B. CH2=CH-OCOCH3. C. CH2=CH-COOC2HS. D. CH2=CHCH20H.

Call 8: Ch~t tham gia phan irng trung hQ'P tao ra polime III

A. CH3-CH2-Cl. B. CH3-CH3. C. CH2=CH-CH3. D. CH3-CH2-CH3.

Call 9: Monome ducc dung d6 di6u ch6 polietilen III

A. CH2=CH-CH3. B. CH2=CH2. C. CH=CH. D. CH2=CH-CH=CH2.

Call 10: Day gam cac chat ducc dung d6 t6ng hQ'P cao su Buna-S Ill:

A. CHz=C(CH3)-CH=CH2, C6HsCH=CH2. B. CHz=CH-CH=CH2, C6HsCH=CH2.

C. CHz=CH-CH=CH2, hru huynh, D. CHz=CH-CH=CH2, CH3-CH=CH2.

Call 11: Cho cac polime sau: (-CH2 - CH2-)n; (- CH2- CH=CH- CH2-)n; (- NH-CH2 -CO-)n Cong tlnrc cua cac monome d6 khi trung hQ'P hoac trung ngirng tao ra cac polime tren IAn hrot III

A. CH2=CHCI, CH3-CH=CH-CH3, CH3- CH(NH2)- COOH.

B. CH2=CH2, CH2=CH-CH= CH2, NH2- CH2- COOH.

C. CH2=CH2, CH3- CH=C= CH2, NH2- CH2- COOH.

D. CH2=CH2, CH3- CH=CH-CH3, NH2- CH2- CH2- COOH.

Call 12: Trong s6 cac loai to sau:

(1) [-NH-(CH2)6-NH-OC-(CH2)4-CO-]n (2) [-NH-(CH2)S-CO-]n (3) [C6H702(OOC-CH3)3]n.

To nilon-6,6 III

A. (1). B. (1), (2), (3). C. (3). D. (2).

Call 13: Nlnra phenolfomandehit ducc di6u ch6 bang each dun n6ng phenol (du) voi dung dich

A. HCOOH trong moi tnrong axit. B. CH3CHO trong moi tnrong axit.

C. CH3COOH trong moi tnrong axit. D. HCHO trong moi tnrong axit.

Call 14: Polivinyl axetat (hoac poli(vinyl axetat)) III polime ducc di6u ch6 bang phan irng trung hQ'P

A. C2HsCOO-CH=CH2' B. CH2=CH-COO-C2HS.

C. CH3COO-CH=CH2. D. CH2=CH-COO-CH3.

Call 15: Nilon-6,6 III mQt loai

A. to axetat. B. to poliamit. C. polieste. D. to visco.

Call 16: Polime dung d6 ch6 tao thuy tinh hiru co (plexiglas) ducc di6u ch6 bang phan irng trung hQ'P

A. CH2=C(CH3)COOCH3. B. CH2 =CHCOOCH3.

C. C6HsCH=CH2. D. CH3COOCH=CH2.

Call 17: Polivinyl clorua (PVC) di6u ch6 til vinyl clorua bang phan irng

A. trao d6i. B. oxi hoa - khir. C. trung hQ'P. D. trung ngung,

34

Call 18: Cong tlnrc du tao cua polibutadien la

A. (-CF2-CF2-)n. B. (-CH2-CHCI-)n. C. (-CH2-CH2-)n.

Call 19: TO' ducc san xuat til xenlulozo la

A. to' t~m. B. to' capron. C. to' nilon-6,6.

Call 20: Monome ducc dung d6 di6u ch6 polipropilen la

A. CH2=CH-CH3. B. CH2=CH2. C. CH=CH.

D. (-CH2-CH=CH-CH2-)n.

D. to' visco.

D. CH2=CH-CH=CH2.

Call 21: TO' ducc san xuat til xenlulozo la

A. to' visco. B. to' nilon-6,6. C. to' t~m. D. to' capron.

Call 22: TO' lapsan thuoc loai

A. to' poliamit. B. to' visco. C. to' polieste. D. to' axetat.

Call 23: TO' capron thuoc loai

A. to' poliamit. B. to' visco. C. to' polieste. D. to' axetat.

Call 24: TO' nilon - 6,6 ducc di6u ch6 bang phan irng trung ngirng

A. HOOC-(CH2)2-CH(NH2)-COOH. B. HOOC-(CH2)4-COOH va HO-(CH2)2-

OH.

C. HOOC-(CH2)4-COOH va H2N-(CH2)6-NH2.

D. H2N-(CH2)S-COOH.

Call 25: Cho sa d6 chuyen hoa: Glucozo ----)0 X ----)0 Y ----)0 Cao su Buna. Hai chat X, Y IAn hrot la

A. CH3CH20H va CH3CHO. B. CH3CH20H va CH2=CH2.

C. CH2CH20H va CH3-CH=CH-CH3. D. CH3CH20H va CH2=CH-CH=CH2.

Call 26: Cao su buna ducc tao thanh til buta-l ,3-dien bang phan irng

A. trung hQ'P B. trung ngirng C. cong hQ'P D. phan irng th6

Call 27: Cong tlnrc phan til cua cao su thien nhien

A. (CSHg)n B. (C4Hg)n C. (C4H6)n D. (C2H4)n

Call 28: Ch~t khfmg c6 kha nang tham gia phan irng trung ngirng la :

A. glyxin. B. axit terephtaric. C. axit axetic. D. etylen glycol.

Call 29: TO' nilon -6,6 thuoc loai

A. to' nhan tao. B. to' ban tang hQ'P. C. to' thien nhien, D. to' tang hQ'P.

Call 30: To visco khfmg thuoc loai

A. to' h6a hoc. B. to' tang hQ'P. C. to' ban tang hQ'P. D. to' nhan tao.

Call 31. Trong cac loai to' duoi day, to' nhan tao la

A. to' visco. B. to' capron. C. to' nilon -6,6. D. to' t~m.

Call 32. Teflon la ten cua mQt polime ducc dung lam

A. ch~t deo, B. to' tang hQ'P. C. cao su tang hQ'P. D. keo dan.

Call 33: Polime c6 du true mang khong gian (mang lucri) la

A. PVC. B. nlnra bakelit. C. PE. D. amilopectin.

Call 34: TO' nilon-6,6 ducc tang hQ'P til phan irng

A. trung hQ'P giira axit adipic va hexametylen di amin C. trung hQ'P til caprolactan

B. trung ngirng gifra axit adipic va hexametylen di aminD. trung ngirng til caprolactan Call 35. Trong cac phan ling giira cac c~p chAt sau, phan ling nao lam giam mach polime

A. poli(vinyl clorua) + Clz ~ B. cao su thien nhien + HCI ~

C. poli(vinyl axetat) + H20 OH-,tO) D. amilozo + H20 H+,tO)

Call 36. Trong so cac loai to sau:(1)[-NH-(CH2)6-NH-CO-(CH2)4-CO-]n (2) [-NH-(CH2)S-CO-]n

(3) [C6H702(0-CO-CH3)3]n' To thuoc loai sci poliamit la:

A. (1) va (3) B. (2) va (3) C. (1) va (2) D. (1), (2) va (3).

Call 37. Tai sao cac polime khong co nhiet dQ nong chay xac dinh,

A. do chiing co khci hrong qua IOn B. do chiing co diu tnic khong xac dinh,

c. do chiing la Mn hQP cua nhieu phan nr co khoi hrong khac nhauD. do chiing co tfnh chat hoa hoc khac nhau. Call 38. Polime co cong thirc [(-CO-(CH2kCO-NH-(CH2kNH-]n thuec loai nao?

A. Chat deo B. Cao su C. TO' nilon D. TO' capron

Call 39. Be t6ng hQ'P polime, ngmri ta co the S11 dung:

A. Phan ling trung hQ'P. C. Phan ling trung ngimg.

35

B. Phan ling d6ng trung hop hay phan ling d6ng trung ngung, Call 40. Polime nao co du tao mang khong gian:

A: Nhua bakelit; B: Poliisopren; C: Cao su Buna-S;

Call 41. Trong cac polime sau, polime co the dung lam chAt deo:

A. Nhua PE B. Nhua PVC C. Thuy tinh hfru co

D: Polietilen

II. BAI TAp TRA.C NGHIEM:

Call 1. Khi clo hoa PVC thu ducc to clorin chua 66,78% clo. se ~t xich trung binh tac dung voi 1 phan tu clo.

A: 1,5; B: 3; C: 2; D: 2,5

Call 2. Tir 100m! dung dich ancol etylic 33,34% (D = 0,69) co the dieu che dUQ"C bao nhieu kg PE (coi hieu suAt 100%)

A: 23; B: 14; C: 18; D: Ket qua khac

Call 3. Tir 13kg axetilen co the dieu che dUQ"C bao nhieu kg PVC (coi hieu suAt la 100%):

A: 62,5; B: 31,25; C: 31,5; D: Ket qua khac

Call 4. Tir 13kg axetilen co the dieu che dUQ"C bao nhieu kg PVC (coi hieu suAt la 100%):

A: 62,5; B: 31,25; C: 31,5; D: Ket qua khac

Call 5. Cho 0,3 mol phenol trung ngirng vOi 0,25 mol HCHO (xt H\tO ) ( hspir 100% ) thu diroc bao nhieu gam nhua phenolfomandehit (PPF) mach thang?

A. 10,6 gam B. 15,9 gam e. 21,2 gam D. 26,5 gam

Call 6. D~ dieu che 100 gam thuy tinh hfiu co can bao nhieu gam nrou metylic va va bao nhieu gam axit metacrrylic, biet hieu suat qua trlnh phan ling dat 80%.

A. axit 68,8 gam; nrou 25,6 gam. B. axit 86,0 gam; nrou 32 gam.

e. axit 107,5 gam; nrou 40 gam. D. axit 107,5 gam; nrou 32 gam.

Call 7. D~ dieu che cao su buna ngtroi ta co th~ thirc hien thea cac so d6 bien hoa sau:

C2HsOH hsSO% butadien -1,3 hs80% cao su bun a

Tfnh kh6i hrong ancol etylic can lay d~ co th~ dieu che diroc 54 gam cao su buna thea so d6 tren?

A. 92 gam B. 184 gam e. 115 gam D. 230 gam.

Call 8. Mot doan mach PVC co khoang 1000 mat xfch, Hay xac dinh kh6i hrong cua doan mach do.

A. 62500 dvC B. 625000 dvC e. 125000 dvC D.250000dve.

36