TRUONG THPT CHUYEN DE THI THU DAI HOC LAN II- 2011 ‘NGUYEN HUE MON HOA HQC 12 Thi gian lam bai: 90 phir (60 ci trae nghiém) Ma dé thi 357 Ho, ten thi sin: Sé bio dant Cho nguyén tir khdi ciia cic nguyén t6: H= 1; C= 12; N= 14; O= 16; $ = 32; C1= 35,5; Br= 80; P= 31; Na= 23; Mg = 24; Al= 27; K= 39; _ Ca=40; Cr = 52; Mn= 55; Fe~ $6; Cu = 64; Zn= 65; Ag = 108; Ba= 137; Pb = 207; Ni= 59 1. Phin chung cho tét cd ede thi sinh( 40 cau, te edu {} dén cu (<40>)) (Cu 1: Hn hgp A gdm X, ¥ (Mx bing m@t lugng O; via di thu duge khi X. Hap thy hét X vio 1 lit dung dich cchira Ba(OH); 0,2M vi KOH 0,2M thu duge dung dich Y va 32,55 gam két tia, Cho dung dich NaOH véo dung dich Y lai thay xuat hign thém két tia, Gi tr elia m la A.24 gam B27 gam 30 gam D. 36 gam ‘Ciiu 24: Co 4 dung dich, mi dung dich chita | trong 4 chat: CH,O, CHsN, CHO, CH,0>, Ding chat nio dé nhin bi .- Giy quy, dd AgNO; /NH, B. Giy quy, dd FeCl, C. Giy quy, dd AgNO; NH, Na D. Gidy quy, dd AgNOs /NHs, Bry Cau 25: Cho céc chit: H)N-CH;-COOH; HOOC-CH;-CH,-CH(NH;}-COOH; H;NCH,COOC;Hs; CHsCOONHy; C.HeNHGNOs. S6 chat ludng tinh la Ad BG cs D.2 (Chiu 26: 11,05 thé hign tinh kha Ki tde dung vi chit nko Sau day A.AgO B.PbS C.K D.KNO, (Citu 27: Cho 84 gam Fe téc dung vir di v6i dung dich chia 0,4 mol HySO, dc, néng (ga thiét SO; la sin phim Khir uy nhit. Sau khi phan tg niy ra hodn toan c6 can dung dich duge m gam madi khan. Gi tea m li ’A.35,2 gam B. 22,8 gam C276 gam D. 30 gam (Cia 28: Cho 0.5 mol H, vi 0,15 mol vinyl axetilen vio binh kin 6 mit xi tée Ni ri mang néng Sau phn ing thu dye dn hop kt X o6 ti kid so vi CO, bing 0.5. Cho hn hyp X tic dng wi ding dich Bry du thiy o6 m gam Br, di tham gia phn ling Gi ia ml ‘4.40 gam B. 24 gam 16 gam D.32 gam chy x, 800, Xi B.CALCILCHO D.GHLCHOH)CH.OH Cho cic hidrocacbon sau dy phin ing vi clo theo ff 1 vés6 mol, tring hyp nio to think niu sin phim dng phn nh ‘A nopentan B.Pentan ctyxilopentan D. sopentan "Trang 2/6 - Ma dé thi 357(Ci 31: Cho hoi nude di qua than nung néng dé sau khi log bd ho nuée du thu duge 17,92 It ¢gim COs, CO va H:. Hap thy X vio dung dich Ba(OH)> du thu duge 39,4 gam két tia vi e6 V Y tic dung véi CuO dw nung néng sau phan tg thiy ki lugng chit rin giim m gam. Git cia m li ‘4.9.6 gain B. 8,4 gam C112 gam D.48 gam ‘Cfiu 32: Khir mét este E no don chite mach hé bing LiAIH, thu drgc mét ancol duy nhat G. Bét chay m gam G cin 2.4m gam 0. Dt m gam E thu duge tong khéi lngng CO, vi HO Ia 52,08 gam, Néu cho toin bé luyng COs, H30 nay vao 500 ml dung dich Ba(OH), 1M. Khoi lugng ket tia sinh ra la: 'A.25,61 gam B. 31,52 gam ©. 35,46 gain D. 39,4 gum 33: Dung dich X of cha KCl, FeCl, HCL. Bign phn dung dich X mée thai gian thu duge dung dich Y. Y khong lam <46i mit guy tim emg 6 qua tinh dign phn dd dimg ei ki . Av vita ht FeC B. via hit Fels C. visa hét ICL D. dign phin hét KCL (Ci 34: Chi ding mt thude thir nio sau diy 48 phan bigt ede dung dich dyng trong cée lo mit nhdn: anbumin, elucora, saccaroza, axit atic. A. dung dich NH; B. Cu(OH), C. CuSO, D. HNO; dic (Cu 35: Nhin dinh mio sau day khong ding: A. Hin hp Fe,O, va Cu 6 thé tan hét trong dung dich HCL B, Han hop AlO, vi K,0 06 thé tan hét trong nude C. Hin hop Cus vi FeS o6 thé tan hét trong dung dich HCL D. Hin hgp Al va BaO 6 thé tan hét trong nude (Cu 36: X la mst aamino axit ob cia véng thom va mgt hmm NH, trong phn we. Big 5O ml dung dich X phin ing vie 4 ‘vi 80 ml dung dich HCL0,5M, cu dich thu duye phn ing via di vei 50 ml dung dich NaOH 1,6M. Mt Ki néu tung ba 250 ml dang dich X bing lugng.vira di KOH ni dem o6 can thu dye 40,6 gam mui, CTCT ci Xi ‘A. GHi-CH(CH,)-CH(NH}COOH B.CiliCHINH}-CH.COOK (C, CH-CH(NH;)-COOH D. C,Hs-CH,CH(NH;)COOH: (Ci 37: Trong céng nghigp nga ta didu ché nude giaven bing cach ‘A. Cho khi Cl ditrtirque dung dich NaOH, NCO, B. Dign phin dung dich NaCl khing ming ngin Sue kh Cl, vio dung dich KOHL D. Cho ksi Ch vio dung dich NaxCOs (Ci 38: To mio sau dy duge ché tg0 tt polime tring hop: A. To enang B. To capron Ta lapsan D. Tornilon-6,6 Cau 39: Lic 13,14 gam Cu v6i 250 ml dung dich AgNO 0,6M mét thdi_gian thu due 22,56 gam chit A va dung: dich B, Nhing thanh kim loai M nng 15,45 gam vio dung dich B khudy déu dén khi phan dng hodn ton thu duge dung dich chi chia mgt mudi duy abit vi 17,385 gam chat rin Z. Kim loai M la ALZn B. Mg Pb D.Fe (Cu 40: Cho cde phan ting: NajSOs + HaSO, —> Khi X FeS | HCI KhiY NaNO: bione NHsChsonse 5 Khi Z KMn0, —* KhiT Cie khé tae dung duage véi nude elo Li AXYZT B.XY,Z GY,Z D.X,Y IL Phin rigng( 10 cu) Thi sinh duge chon lim 1 trong 2 phin (phan I hoje phan I) Phan I: Theo chwrong trinh Chuiin ( tir cu {<41>} dén cau {<50>}) (Cu 41: Nung m gam K:Cr0; véi $ dir thu duge hin hop chit rin X. Hoa tan hod toin X vao nuée, lge bo phn dng tan réithém BaCl; dy vio dung dich thu duge 18,64 gam kat tia. Gi team ‘8.2352 gam B. 24,99 gam 29,6 gam D.17,64 gam ‘Cu 42: Phan Gg ndo sau day thu duuge Ket tia sau phan tng ‘A. Cho khi HS vio dung dich FeCl, B, Cho dung dich NaOH di, di vio dung dich Pb(NO,)». C. Cho tir tie dén dur dung dich HC! va dung dich Na[Cr(OH)4) D. Sue khi H;S vio dung dich Pb(NO})>. ‘Cu 43: Cho edin bing: Hs (K) + b(K) = 2H (K) AH> 0. ‘Yéu 18 nio sau day khéng lim chuyén dich cn bing: A. Ap suit B. Nong d6 I ‘©. Nhigt 46 D. Ning d6 Hy 1u 44: Cho 4,44 gam axit cacboxylic, dom chite X tée dung hoan ton véi $00 ml gém: KOH 0,12M, NaOH 0,12M, can dung djch thu due 9,12 gam hén hgp chit rin khan, CTPT ota X lis ‘A. CHCHO, B. HCOOH, €.GILCOOH, D. CCOOH (Céu 4S: Miu xanh cia dung dich hoo X mat khi dun ning vi trai nr ban du Wid ngudi. Vay X A. dd (CH;COO),Cu B. dd J, trong tinh bot ‘C.dd ding (ID) glixerat—-D. dd I, trong xenluloza "Trang 3/6 - Ma dé thi 357(Cin 46: Cho m gam ancol don chit X qua ng dmg CuO dunn ning. Sau ki phn ig xy ra hod tn ng chat in tha «urge hin hop bos gm 2 chit ti Khai so w6i Ha 19, Ancol Xl A. CHOH B.CHOH C.GHOH D.GHOH ‘Cw 47: Dé khie mii tanh cia cd (gay ra do mét s6 amin) ta 66 thé ria cd véi B. Nuée voi trong c.Cén D.Giém [8 mbt tepeptt edu tgo tir mt amino axit (A) no, mgch hé e6 1 nhém~COOH: | nhém—NH,, Trong A %N = 15,73% (vé khdi lung). Thay phan m gam X trong méi truémg axit thu duge 41,58 gam tipeptt; 25,6 gam dipeptit vi 92,56 gam A. Git cia m lis ‘A149 gam B.161 gam 143,45 gam D. 159 gam (Cau 49: Tron pin ign ha Cu-Ag din eve dng xy aqui ink ‘A. Oxi hia LO BKhECe GKini1 0 D.Oxi hia Cu Cin 50: Cho so Citgo =i» x tl yy ste 7 200 i dra-2-meylprpan,X i A. Isobutilen B. Bul2en ©. But-l-en D. xiclobutan Phin Il: Theo chirong trinh nfing cao (tir cu 51 dén ci 60) Cu 51: Khi bin dam ure cho ey ngudi ta khéng bén ciing véi A. HNO; B. phan kali C. phan lan D. vai (CA $2: Cin a mol KzCr0, vib mol HCI dé diéu ché duge 6,72 lit Cls (dkte). Gié tricia a va b las: A.0,05 vA 0,7 B.0.2va28 C.0,1 va 14 1D. 0,1 va 0,35 fe Ee ° 7 (Cu 53: Cho thé dign cue cia ede cp oxi héa kh: 20/20 rere= o4av, Bre ins=0,t3y, Pe! te= 0,8V. Pin dign éa nio sau day o6 suit dign dng teu chudn li AZn—Fe B.Zn-Pb C.Pb- Ag D.Fe-Ag ‘Cf $4: Cho kbi CO Gi qua éng sir dyng 0,09 mol hén hyp A gdm Fe.0; vi FeO nung néng saw mt thé gian thu dduge 10,32 gam chit rin B. Din khi di ra khdi éng sit vio dung dich Ba(OH): du thu duge 17,73 gam két tia. Cho B tic dung hét véi dung djch HINO, du thu duge V lit NO (kt, sin phim khir duy ahi). Gid cla V a A134 lit B. 1,68 lit C114 tt D. 1,568 lit ‘Ci 58: Lén men 162 gam tinh bot véi higu suit cde qué trinh Ién men lan luyt li 80% vi 90%, Tin thé tich dung dich regu 40" thu duge? Bidt kh6i lugng riéng cia CHJOH nguyén chat 10,8 g/ml ALLSml B. 230ml C.207ml D. 82,8ml ‘Cfiu 56: Vinyl axctat duge digu ché bing phin img gitta: A. Btilen v6i axit axetic B. Ancol vinylic v6i axit axetie C. Axetilen véi axit axetic D. etanol véi anhidrit axetic ‘Ci $7: dt chiy hoin toin m gam hin hgp X gdm hai andeht no, dm chic, mach hd thu duge 0,4 mol COs. Mgt Khde hidro héa hoin toin m gam X cin 0,2 mol Hy (Ni, , sau phan tg thu duge hai ancol no don eh, Bot chy hho todn hn hgp hai ancol nay thi s6 mol HO thu duge a A.0,6 mol B,0,5 mol €.0,3 mol D.0,4 mol iu $8: Cho céc chit; Propan, Propin, 2,2-dilopropan, Propan-2-ol, Propan-I-ol, Propen, anlylclorua, 2-clopropen chit ob thé digu ché due axeton ehi bing mgt phan img li AS BG cs ba Ciw 59: Cho cic phin img: (Ch + Br + HO @ch+KoH > (3) H,0, “5 (4) Ch + Ca(OH), Khan (5) Br + $0; +10 6 phan tng 1 phan tg ty oxi ha kh a A4 BS ©.2 D.s ‘Ci 60; Cho 0,1 mol alanin phin img véi 100 mi dung dich HCI 1,5M thu duge dung dich A. Cho A tie dng via da ‘v6i dung djch NaOH thu duge dung dich B, lim bay hoi dung dich B thu dirge bao nhiéu gam chat in khan? ‘A.14025 gam B. 8,775 gam €.11,10 gam D. 19,875 gam ~HET "Trang 4/6 - Ma dé thi 357132 132 132 132 132 132 132 132 132 132 132 192 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 192 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 132 192 132 192 9 2 3 s 2000> 9900 FOF BI0>00>00>>>>0> 00> > 00> 20000000908>a000200m0> ac ma 2091 2092 209 3. 2094 209 5 2096 2097 209 8 209 9 209 10 20911 209 12 209 13, 209 14 20915 209 16 209 17 209 18 209 19 209 20 209 21 209 22 209 23, 209 24 209 25 209 26 209 27 209 28 209 29 209 30 209 31 209 32 209 33. 209 34 209 35 209 36 209 37, 209 38 209 39 209 40 209 41 209 42 209 43, 209 44 209 45 209 46 209 47 209 48 209 49 209 60 209 51 209 52 209 53 209 54 209 55 209 56 a & thi mén Héa Thi thie Dai hgc lan 2 nam 2011 280020000 SF O00>0>> 002085 R2F 05> >00000> 00 F00>>B00B>P>E000> 387 357 387 387 387 387 387 357 357 387 387 357 387 387 357 357 387 387 387 357 357 387 387 357 387 387 357 357 357 357 387 387 387 357 387 357 387 387 387 387 387 387 357 357 357 387 387 387 357 387 357 387 387 357 387 357 © 0 9000F0O0OGO>O>O> 2 000GFE FOF 00> 0>00000>000B00>> 002000200 485 485 485, 485 485 485 485 485 485 485, 485 485 485 485 485 485, 485 485 485. 485 485, 485 485 485, 485 485 485 485 485 485, 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 485 SStsaesses 40 4“ 2 48 45 46 47 49 BRLIVIS POOF D0TTF OFF B0000000 B20 B20 B>O>OB>00 D> >OEDOP>U>O>BTB>IOM>O 570 570 570 570 570 570 570 570 570 570 570 570 570 570 570 570 570 870 570 570 570 570 570 570 570 570 570 570 570 570 570 870 570 570 570 570 870 570 570 570 570 570 570 570 570 570 870 570 570 570 570 570 570 570 870 570 " 12 13 4 15 18 7 18 19 20 2 22 23 24 25 28 27 28 29 30 31 32 33 34 35 36 37 38 39 40 44 42 43 44 45 46 47 48 49 50 51 52 53 54 55 58 90992090 B900F000>000F8200000F >> 00s > 000T0BFBOBUDOF>OBS>0>0 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 743 45 46 47 48 49 50 51 52 53 54 55 56 "Trang 5/6 - Ma dé thi 35° OF OFODTDO BOO BMH OM>BTO>OB>BBO>>O>>OTDTBBONDOBOBOO>O0BO00>OR 896 896 896 896 896 896 896 896 896 896 896 896 896 896 896 896, 896, 896, 896 896 896 896 896 896, 896 896 896 896 896 896 896 896, 896 896, 896 896 896 896 896, 896, 896 896 896 896 898, 896 896 896 896 896 896 896 896 896 896 896 45 46 47 48 49 50 51 52 53 54 55 56 c B A B D B c A D D B D A A D D c D B B c A c A A A A B A B B c B D c A A D D c D B D A c c c c D c D B c B c A 719% 19% 133 13% 87 58 59 60 >aoo 20 20 20 20 ST 58 59 60 oreo 357 357 357 357 ST 58 59 60 >ao> 48 48 48 48 sr 58 59 60 oro 570 570 570 870 87 58 59 60 >or> 743 743 743 743 87 58 59 60 >ar> 896 896 898 896 Seed a>oo "Trang 6/6 - Ma dé thi 357