Truong THPT Yen Thanh 2

DE THI THU D~I HQC LAN 1 NAM 2011, MON HOA HQC

ThiYi gian lam bai: 90 phut 1'"""1 --M-a-d-~ -1-2-2--'

HQ, ten thi sinh: SB bao danh: .

Cho bi~t khBi hrong nguyen ill (theo dve) cua cac nguyen tB:

H = 1; Li = 7; C = 12; N= 14; 0 = 16; Na= 23; Mg =24; AI = 27; S = 32; Cl = 35,5; K= 39; Ca = 40; Fe = 56; Cu =64; Zn = 65; Sr = 87; Br = 80; Ag = 108; Ba = 137, Cr =52, (Thf sinh khong diroc sir dung bang tuh hoan)

I. pllAN CHUNG CHO TAT cA THI SINH (40 diu, til'diu 1 d@ndiu40)

Cau 1: Co 4 cac chua dung dich HCl cung nAng dQ va thB tich. Cho vao cac 1 mQt thanh Zn, cho vao cac hai mQt thanh Fe, cho vao cac ba hai thanh Fe va Cu d~t tiBp xuc nhau, Cho vao cac ban hai thanh Zn va Cu d~t tiBp xuc nhau, Tac dQ giai phong khi & ban cac

A. 1>2>3>4. B. 3>4>1>2. C. 4>3> 1>2. D. 4>3>2> 1.

Cau 2: Trong cac cMt sau: etanol, vinyl axetat, vinyl axetilen, butan, 1,3- diclobutan, isobutan, xic1obutan. Cac cMt rna chi bang 2 phuong trinh phan irng co thB diBu chB duoc caosubuna la:

A. etanol, butan, isobutan, xiclobutan, 1,3- dic1obutan.

B. etanol, vinyl axetilen, butan, 1,3- dic1obutan.

C. etanol, vinyl axetilen, butan.

D. etanol, vinyl axetat, vinyl axetilen, butan, 1,3- dic1obutan.

Cau 3: Cho cac cMt: MgO, CaC03, Ah03, dung dich HC~ NaOH, CuS04,NaHC03,.Khi cho cac cMt tren tac dung voi nhau tirng doi mQt thi tang sa c~p cMt phan img dtroc voi nhau la:

A.6. B.7. C.8. D.9.

Cau 4:Cho cac polime sau: to' nilon-6,6 (a); poli(ure-fomandehit) (b); to' nitron (c); teflon (d); poli(metyl metacrylat) (e); poli(phenol-fomandehit) (f). Day gAm cac po lime diroc diBu chB bang phan img tnmg hop la

A. (a), (b), (f). B. (b), (c), (e). C. (b), (c), (d). D. (c), (d), (e).

Cau 5:MQt loai mroc cimg chua Ca2+ 0,004M ; Mi+ 0,003M va HCO-3. Hay cho biBt cfin Ifty bao nhieu ml dung djch Ca(OH)2 2.10-2 M dB biBn l lit mroc cimg do thanh mroc mBm (coi nhu kBt IDa thu diroc gam CaC03 va Mg(OH)2).

A. 200 ml B. 300 ml C. 400 ml D. 500 ml.

Cau 6: Glyxin phan img diroc v6'i bao nhieu chAt cho sau : Ba(OHh, CH30H, HCl, Cu, CH3NH2, C2HsOH, Na2S04, Ag, KC~ H2S04, CH3COOH, CH3CHO, Ca :

A.5 &6 C8 R7

Cau 7: Trong cac cMt NaHS04, NaHC03, ~C~ Na2C03,C02, AlCh, FeCh sa cMt khi tac dung voi dung djch NaAI02 thu duoc A1(OH)3 Ia:

A. 1 B. 5 C. 3 D. 4

Ciiu 8: Cho dung dich acid nitric loang vao mQt cac thuy tinh co dung 5,6 gam Fe va 9,6 gam Cu. Khuay dBu dB phan img xay ra hoan toan ; co 3,13611t NO( dktc) va con lai m gam cMt rfu1 khong tan. Gill tri m bang :

A.2,56 B.1,92 CA,48 D.5,76

Ciu 9: Hoa tan 46g hh Ba va hai kim loai kiBmA,B thuoc hai chu ky lien tiBp vao mroc duoc diroc dd D va 11,211t khi dktc, nBu them 0,18 mol Na2S04 vao dd D thi chua kBt rna hBt ion Ba2+ , Con nBu them 0,21 mol Na2S04 vao dd D thi sau phan img lai du ion sol- . Tim hai kim loai A,B ?

A. Li va Na B. Na va K C. K va Rb D. Rb va Cs

Ciu 10: Han hop A gAm hidro va hidrocacbon X mach h& co ti khai so vtri H2 la 7,5 .Cho hh nung voi Ni phan img hoan toan diroc hh khi B khong lam mat mau mroc Brom, B co ti khai so v6'i A la 2. Tim CTPT cua X ?

A. C2~ B. C4a; C. C2H2 D. A va C dung,

Ciiu 11: Khi phan tich ete A ta co m, + mR =3,5mo. LAy 2 ancol don chirc X va Y dun voi H2S04 d dircc chAt A .Tim CTCT Cua A,X,Y?

A. CH3-0-CH=CH-CH3; CH30H; CH2=CH-CH20H. C.C2HS-O-CH=CH2; C2HsOH; CH2=CH-OH.

B.CH3-0-CH2-CH=CH2; CH30H; CH2=CH-CH20H. D.CH3-0-C3H7; CH30H; C3H70H.

Trang 1/5 ma de122

Can 12. Cho 7,68 gam h6n hQP gam FeO, Fe304, Fe203 tac dung vira h6t v6'i 260 ml HCI1M thu diroc dung dich X. Cho X phan irng v6'i dung dich NaOH du thu diroc k6t rna Y. Nung Y ngoai khong khi d6n kh6i hrong khong d6i thu duoc d6n kh6i hrong khong d6i dtroc m(g) cMt r~n. Tinh m

A. 8,5 gam. B. 8 gam. C. 16 gam. D.4gam

Cau 13: Cho cac cMt sau: toluen, etilen, xiclopropan, stiren, S02, Axit fomic, vinylaxetilen, etanal, dimetyl xeton, propilen. S6 cMt lam mAt mau dung dich KMn04 0 nhiet d(l thirong la

A.4. B.6. C.7. D.5.

Cau 14: Cho cac c~p cMt sau:

(1). Khi Br2 va khi O2. (6). Dung dich KMn04 va khi S02.

(2). Khi H2S va khi FeCh. (7). Hg va S.

(3). Khi H2S va dung dich Pb(N03h. (8). Khi CO2 va dung dich NaCIO.

(4). Khi Ch va dung dich NaOH. (9). CuS va dung dich HCI.

(5). Khi NH3 va dung dich FeCh. (10). Dung dich AgN03 va dung dich Fe(N03h.

S6 c~p cMt xay ra phan img hoa hoc 0 nhist d(l thuong la

A.9. B.8. C. 10. D.7.

Cau 15: DB trung hoa 8,3 gam 2 axit don chirc X, Y (Mx<My) cAn 150gam dd NaOH 4% . Ciing hrong hh X tren tac dung v6'i ddAgN03 du trong dd NH3 diroc 21,6 g Ag. V~y X va Y IAn hrot la :

A. Axit axetic va axit propionic B. Axit fomic va axit axetic

C. Axit fomic va axit butiric D. Axit fomic va axit propionic

Cau 16: Cho 3,36 lit khi CO2 (dktc) vao 400 ml dung dich h6n hQP KOH 0,25M va K2C03 0,4M thu duoc dung djch X. Cho dung dich BaCh du vao dung dich X thu duoc k6t rna, IQc lAy k6t rna dem nung d6n kh6i hrong khong d6i thu duoc m gam cMt ~. Gia tri ella m m:

A.21,67. B. 16,83. C.71,91. D.48,96

Can 17: Thuy phan m gam xenlulozo trong moi tnrong axit. Sau m(lt thai gian phan (eng, dem trung hoa axit bfing kiem, sau do cho h6n hQP tac dung hoan toan v6'i dung dich AgN03 trong NH3 thu duoc m gam Ag. Xac dinh hieu suat cua phan img thuy phan xenlulozo ?

A. 66,67%. B. 75%. C. 80%. D. 50%.

Can 18: Khi cho timg cMt KMn04, Mn02, KCI03, K2Cr207 co cung s6 mol tac dung hoan toan voi dung dich HCI d~c, du thi chat cho hrong khi Ch it nhat la:

A. KCI03. B. KMn04. C. Mn02. D. K2Cr207.

Can 19: Cho 21,6 gam Mg tao dung voi dung dich RN03 (du). phan img xay ra hoan toan duoc 8,96 lit NO (0 dktc) va dung djch X. Them dung dich NaOH du vao dung dich X sinh ra V lit khi Y (dktc). Gia tri cua V la:

A.3,36 B. 1,66 C. 1,68 D.6,72

Can 20 : Cho m g Fe vao dung dich chua H2S04 va RN03 duoc dung dich X va 4,48 lit NO. Them ti6p H2S04 vao X thi lai thu dircc them 1,792 lit NO duy nhat nita va dung dich Y. Dung dich Y hoa tan vira h6t 8,32 gam Cu khong co khi bay ra (cac khi do 0 dktc). Kh6i hrong cua Fe da cho vao la:

A. 11,2 g. B. 16,24 g. C. 16,8 g. D. 9,6 g.

Can 21: Cho 15,6 g Zn trong 200 mL dung dich FeCh 2M duoc m g cMt r~n. Tri sA cua m la:

A. 2,24 B. 8,96 C. 2,6 D. Tat cit deu sai

Can 22: HQP chat X mach ho co cong thirc la C4H9N02. Cho 10,3 g X phan img vira du dung dich NaOH sinh ra m(lt chat khi Y va dung dich Z. Khi Y nang hon khong khi, lam giay quy tim dm chuyen mau xanh. Dung dich Z co kha nang lam mAt mau mroc bromo Co can dung djch Z diroc m gam mu6i . Gia tri m la;

A. 9,4 B. 8,2 C. 10,8 D. 9,6

Can 23: Cho cac phan (eng sau:

a) FeO + RN03 (d~c, nang) ---+ b) FeS + H2S04 (d~c, nang) ---+

c) Al203 + RN03 (d~c, nang) ---+ d) Cu + dung djch FeCl3 ---+

e) CH3CHO + H2---+ f) glucozo + AgN03 trong dung dich NH3 ---+

g) C2H4 + Br2 ---+ h) glixerol + Cu(OH)2 ---+

Day gam cac phan (eng d6u thuoc loai phan img oxi hoa - khir Ia:

A. a, b, d, e, f, h. B. a, b, d, e, f, g. C. a, b, c, d, e, h. D. a, b, c, d, e, g.

Trang2j5 rna de122

Can 24: Hoa tan hoan toan 0,6 mol h6n hQ'P g6m Al va A4C3 vao dung djch KOH (du), thu duoc a mol h6n hQ'P khi va dung dich X. S\lC khi CO2 (du) vao dung dich X, hrong k6t rna thu diroc la 93,6 gam. Gia tri cua a la

A. 1,1. B. 1,2. C.O,8. D.O,9.

Can 25: B6t hoan toan m g Ancol etylic diroc 0,2 mol C02. B6t chay hoan toan p gam axit axetic duoc 0,2 mol CO2. Hay cho bi6t thirc hien phan img este hoa gifra m g nrou etylic v6'i p gam axit axetic, H2S04 d~c lam xuc tao thu duoc bao nhieu g este bi6t hieu sufit este hoa ill 80 %:

A. 7,04 g B. 8,8 g C. 14,08 g D. 17,6 g

Can 26: Cho m g h6n hop X gAm Ba, BaO, AI vao mroc du phan irng k~ thuc diroc dung dich A; 3,02411t khi (dktc) va 0,54 g cMt riin khong tan. Rot 110 ml dung dich HCIIM vao dung dich A duoc 5,46 g k6t tua, m co gia tri la :

A. 7,21 gam B. 8,74 gam C. 8,2 gam D. 8,58 gam

Can 27: Dung dich Y c6 chua cac ion: NH/, N03-, SO/-. Cho dd Y tac dung vtri hrong du dd Ba(OHh, dun n6ng thu duoc 11,65 gam k6t rna va 4,48 lit khi (dktc). N6u cho m gam dung dich Y cho tac dung voi mQt hrong bQt Cu du va H2S04loang du sinh ra V lit NO (san pham klnr duy nhfit, do (y dktc). Gia tri cua V la

A. 1,87 B.2,24 C. 1,49 D.3,36

Can 28: MQt dung dich A chua: K+, Mi+, Al3+ va SO/-. Cho 75 ml dung dich A tao dung hrong du BaCh tao thanh 55,92g k6t rna. Bi6t cac cation trong A c6 ti l~ moll: 2 : 1. Co can 75ml dd A diroc kh6i hrong mu6i khan la:

A. 23,04 gam B. 28,44 gam C. 25,00 gam D. 29,88 gam

Con 29: Khi xa phong hoa 1 mol este cAn 120 gam NaOH nguyen chfit. M~t khac khi xa phong hoa 1,27 gam este d6 thi dn 0,6 gam NaOH va thu duoc 1,41 gam mu6i duy nMt. Bi6t ancol hoac axit ill dan clnrc, Cong tlnrc cau tao cua este ill

A. (COOC2Hs)2. B. CH2(COOCH3h- C. (CH3COO)3C3Hs. D. (C2H3COO)3C3Hs.

Can 30: Cho 13,5 g h6n hQ'P A g6m Fe va Zn vao 200 ml dung dich Z chua CuCh va FeCh. duoc chfit rful B nguyen cMt va dung dich C. Cho C tao dung voi NaOH dir duoc k6t tua D va dung dich E. S\lC CO2 du vao E, loc k6t tua nung hoan toan duoc 8,lg chfit rful. Thanh phan %(m) Fe va Zn trong A Ifin hrot ill:

A. 51,85; 48,15. B. 50,85; 49,15. C. 49,85; 50,15. D. 30,85; 69,15.

Can 31:.Hoa tan h6n hQ'P g6m s~t va 1 oxit cua s~t cAn vira du 0,2 mol H2S04 d~c ; thoat ra 0,448 lit S02 ( dktc). Co can dung dich sau phan img thu dircc bao nhieu gam muei khan ?

A.16 B.24 C.32 D. 40

Can 32: H6n hQ'P A g6m CUS04 + FeS04 + Fe2(S04)3 c6 % kh6i hrong cua 0 la 44%. Lfiy 50 gam h6n hQ'P A hoa tan trong mroc, them dd NaOH du, k6t tua thu duoc dem nung ngoai khong khi toi kh6i hrong khong d6i. Luong oxit sinh ra dem khir hoan toan b~ng CO thu dircc m gam cMt rful. Gia tri cua m la:

A. 17 g B. 19 g C. 20 g D. 18 g

Can 33:TrQn dung dich X chua NaOH O,IM; Ba(OHh 0,2M voi dung dich Y (HCl 0,2M; H2S04 O,IM) theo ti l~ nao v6 th6 tich d6 dung djch thu diroc c6 pH=13?

A. Vx:Vy=5:4 B. Vx:Vy=4:5 C. Vx:Vy=5:3 D. Vx:Vy=6:4

Can 34: Cho 0,02 mol cMt X (X ill mQt a -aminoaxit) phan img vira h6t voi 160ml dd HCl 0,125 M thi tao ra 3,67g muoi, M~t khac, 4,41g X khi tao dung voi mot hrong NaOH vira du thi tao ra 5,73g mu6i khan. Bi6t X c6 mach cacbon khong phan nhanh. V~y cong thirc cfiu tao cua X ill :

A. HOOC-CH(NH2)-CH(NH2)-COOH. B. CH3-CH2-CH(NH2)-COOH

C. HOOC-CH2-CH2-CH(NH2)-COOH. D. CH3-CH2-CH2-CH(NH2)-COOH

Can 35: Hoa tan h6t 4 gam h6n hQ'P A g6m Fe va 1 oxit s~t trong dung djch acid HCl du thu duoc dung dich X. S\lC khi Ch cho d6n du vao X thu duoc dung dich Y chua 9,75 gam muoi tan. N6u cho 4 gam A tao dung voi dung dich HN03 loang du thi thu duoc V lit NO ( san pham klnr duy nMt ,dktc) V= ?

A.O,896 B.O,726 C.0,747 D.l,120

Can 36: Bi~n phan dung dich chua m gam h6n hQ'P 2 mu6i CuS04 va NaCl voi cuong dQ dong di~ I = 5A cho d6n khi (y 2 di~n C\IC mroc cling di~n phan thi dimg lai, Dung dich thu diroc sau di~n phan hoa tan vira du 1,6 gam CuO va (y anot cua binh di~n phan c6 448 m1 khi bay ra (dktc).Gia tri cua m ill:

A.5,97 gam. B.4,8 gam. C.4,95 gam. D. 3,875 gam.

Can 37: B6t hoan toan 1 hrong cao su buna-S voi hrong oxi vira du, tMy tao 1 h6n hQ'P khi (y nhiet dQ 135°C rna hoi mroc chiem 36% v6 th6 tich. Ti l~ mol gifra butadien va stiren trong polime nay la:

Trang3j5 rna de122

A. 2/3 B.3/4 C.4/5 D. Dap an khac

Cau 38: C6 cac dung dich sau:CH3-NH3Cl , H2N-CH2-CH2-CH(NH2)-COOH, CIH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa.s6luQ'Ilg cac dung dich c6 pH < 7 ill

A.2. B.5. C.4. D.3.

Cau 39: :D6t chay hoan toan 45,1 gam h6n hQP X g6m CH3CH(NH2)COOH va CH3COONH3CH3 thu dUQ"C CO2, H20 va N2 c6 tang kh6i hrong la 109,9 gam. PMn tram kh6i hrong m6i chAt trong h6n hQP X Ifin hrot ill :

A. 39,47% va 60,53% B. 35,52% va 64,48%.

C. 59,20% va 40,80% D. 49,33% va 50,67%

Cau 40: hoan toan mQt este don clnrc, mach ha x (phan ill c6 s6 lien k6t 1t nho hon 3) duoc th6 tich khi C02 bAng 6/7 th6 tich khi 02 da phan img (do a cimg di€u kien). Cho m gam X tac dung hoan toan voi 200 ml dung dich KOH 0,7M thu duoc dung dich Y. Co can Y thu ducc 12,88 gam cMt r~n khan. Gia tri cua mill

A. 10,56. B.7,20. C.8,88. D.6,66.

II. plIAN ruENG [10 cau]: Thi sinh chi d1l1}'C lam IDqt trong hai pllAn (pllAn A ho,c B) A. Theo chmmg trinh chuin (10 cau, tir cau 41 d@n cau SO)

Cau 41: Hai este A va B ill d6ng phan cua nhau va d€u do cac acid cacboxylic no don clnrc va Ancol no don clnrc tao thanh, Dun 33,3g h6n hQP A, B cAn 450ml NaOH 1M dtroc 32,7g muoi, Xac dinh CTPT A va B?

A. CH3COOC2Hs va CH3COOCH3 B. HCOOC2Hs va CH3COOCH3

C. C2HsCOOCH3 va CH3COOCH3 D. C2HsCOOC2Hs va C2HsCOOCH3D6t chay

Cau 42: Dun n6ng 32, Ig h6n hQP X g6m hai cMt htru co Y va Z cung nh6m chirc voi dung dich NaOH dir, thu dircc h6n hQP mu6i natri cua hai axit ankanoic k6 ti6p nhau trong day d6ng d~ng va mQt chAt long L (ti kh6i hoi

dLICH4 = 3,625). ChAt L phan irng voi CuO dun n6ng cho san phdm c6 phan img trang guong. Cho 1 ~ hrong chAt L phan img voi Na dircc 0,015 mol H2. N1$l dinh nao sau day la sai ?

A. Nung mQt trong hai mu6i thu diroc v6'i NaOH (co voi toi) se tao metan.

B. Ten goi cua L ill ancol anlylic.

C. Trong h6n hQP X, hai cMt Y va Z c6 s6 mol b~ng nhau.

D. D6t chay h6n hQP X se thu duoc nC02 - nH20 = 0,02 .

Cau 43: Dung dich A chua NaOH 1M va Ca(OH)z 0,02M, hAp thu 0,5 mol khi CO2 vao 500 ml dung dich A thu dtroc k~t rna c6 kh6i hrong?

A. 109 B. 12g C.20g D. 19

Cau 44: Khi Crackinh V lit butan diroc h6n hQP A chi g6m cac anken va ankan. Ti kh6i hoi cua h6n hQP A so voi khong khi bang 1,5. Hieu suAt cua phan img Crackinh butan la bao nhieu?

A. 33,33% B. 50.33% C. 46,67% D. 66,67%

Cau 45: Khi di~n phan dung dich chua h6n hQP cac cMt tan: NaBr ; FeCh ; CuCh ; HCl thi thir ttr ph6ng di~n a catot l§n hrot ill (bi~t trong day di~n hoa, c~p Fe3+lFe2+ dimg sau c~p Cu2+/Cu)

A. Cu2+, W, Fe3+, Fe2+, H20. B. Fe3+, Cu2+, H+, Fe2+, H20.

C. Fe3+, Fe2+, Cu2+, W, H20. D. Fe3+, Cu2+, Fe2+, W, H20.

Cau 46: Trong cac phan img sau, xay ra trong dung dich :

1, Na2C03 + H2S04 2, Na2C03 + FeCh 3, Na2C03 + CaCh 4, NaHC03 + Ba(OH)2

5, CNH4)2S04 + Ba( OH)2 6, Na2S + AlCh Cac phan img c6 tao d6ng thoi ca k~t tua va khi bay ra ill:

A. 2, 6 B. 2, 3, 5 C. 1, 3, 6 D. 2, 5, 6

Cau 47: Cho cac cMt: glucozo, tinh bQt, to' nilon-6, protein, etyl axetat, alanin, fructozo, saccarozo, s6 chAt c6 th~ thuy phan :

A. 5 B. 4 C. 3. D. 6

Cau 48: C6 bao nhieu d6ng phan este mach tMng cong tlnrc C6HlO04 tac dung NaOH tao ra lancol + Imuoi?

A. 4. B.3. C.2. D. 5.

Cau 49: Cho cac phan img sau:

to

(1) CU(N03)z -~

Trang4j5 rna de122

to (3) NH3 + CuO -~

HCI(O-50) (5) C6HSNH2 + HN02 -____;'-------'--~

sa phan irng thu duoc N2 Ia

A. 3, 4, 5. B. 2, 3, 4. C. 4, 5, 6. D. 1,2,3.

Cill 50: H6n hQ'P X g6m 2 ancol no don chirc X, va X2 co ty l~ sa mol tuong img la 1 : 4 ( MXI < MX2). Cho 12,2 gam h6n hQ'P X vao binh dung Na dir thAy khai IUQ'ng binh tang them 11,95 gam. V~y Xj, X2 wong irng la:

A. CH30H va CH2=CH-CH20H B. C2HsOH va CH3CH2CH20H

C. C3H70H va CH3CH20H D. CH30H va CH3CH2CH20H

B. Theo chuong trinh Nang cao (10 call, til' call 51 d~n call 60)

Call 51: Cho bi6t th6 di~n cue chuan cua cac c~p oxi hoa - klnr Mi+/Mg; 'hJ?+I'hJ.; CU2+/CU; Ag+/Ag; Hi+/Hg llin hrot la : -2,37 V ; -D,76 V ; 0,34 V ; 0,8 V; va 0,85 V. EO (pin) = 3,22 V Ia sufit di~n dQng chuftn cua pin nao trong s6 cac pin sau ?

A.Zn -Ag B.Mg-Zn C.Zn -Ag D.Mg-Hg

Call 52: Bat Hidrocacbon mach h6' X (the khi trong di~u ki~n thuong) duoc Ilc02 = 2nH20. M~t khac 0,1 mol X tao dung dung dich AgN03INH3 (dir) dtroc 15,9(g) k6t rna mau yang. Cong thirc cAu tao X la:

A. CH=C-C=CH B. CH=CH C. CH=C-CH=CH2 D. CH3-CH2-C=CH Call 53: MQt Ancol X d<1I1 chrrc tac dung vrri dd HBr diroc Y co 69,56 % Br , My <260 . dun X voi H2S04 dac duoc hidrocacbon co nai doi khong k~ nhau. sa d6ng phan diu tao X thoa man :

A. 2 B. 3 C. 4 D. 5.

Call 54: Cho sO'd6 sau C2HSBr Mg,ete) A CO2) B +HCl C. ChAt C co cong thirc Ia :

A. CH3COOH B. CH3CH2COOH. C. CH3CH20H. D. CH3CH2CH2COOH.

Call 55: Cho KLNT Au la 196,97. d 25°C, khai hrong rieng Au kim loai la 19,32 g/cm'. Gia thi6t cac nguyen tir Au 1a nhirng hinh cau chiem 75% th6 tich cua kim loai, con 25% Ia cac khe r6ng. Ban kinh gan dung Au la:

A. 1,34 AO. B. 1,45 AO. C. 1,18 AO. D. 1,29 AO'

Call 56: Cho cac chAt sau: C2HsOH, C6HsOH, C6HSNH2, dung dich C6HsONa, dung dich NaOH, dung dich CH3COOH, dung dich HCl. Cho tirng c~p chAt tao dung 6' di~u kien thich hQ'P, sa cap cMt co phan ung la

A.8 B. 12 C.9 D. 10

Call 57: Tic Flo d6n lot, bi6n d6i 000 sau day khfmg chinh xac:

A. Cac axit hidrohalogenua manh dAn, dQ tan muai AgX giam dk

B. Ban kinh nguyen tir tang dk, mau don chAt d~ dan

C. Phan img voi H2, H20 manh dk len

D. Tinh oxi hoa, dQ am di~n giam dAn

Call 58: MQt phan img don gian xay ra trong binh kin: 2NO(k) + 02(k)7 2N02(k). Khi th6 tich binh phan irng giam di ba Ian thi tac dQ phan img tang len:

A. 16 Ifin B.641An C. 27 Ifin D. 81 Ifin

Call 59: Thuy phan hoan toan m gam h6n hQ'P cung sa mol mantozo va saccarozo thu diroc h6n hQ'P san phftm X. Cho toan bQ h6n hQ'P X tlnrc hien phan img voi dung dich AgNO 3INH3 (dir) thu diroc 64,8 gam Ag. Dung

dich X co kha nang lam mat mau hoan toan tai da V m1 dung dich Br2 1M. Gill tri cua VIa:

A. 225. B.260. C. 300. D. 200.

Call 60:POOt bi6u 000 sau day 1a sai :

A. Phan tir sacarozo khong chua nhom OH hemiaxetal nen khong co kha nang chuyen thanh dang mach h6'

B. Lipit Ia trieste cua glixerol voi cac monocacboxylic co sa chin nguyen ill cac bon (12-24, khong nhanh)

C. Xenlulozo 1a polisacarit khong nhanh do cac mAt xich f3 -glucozo nai b~ng lien k6t p -1,4 - glucozit

D. Phuong poop dung d6 di~u ch6 este cua Ancol la dun h6i hru Ancol v6'i axit hiiu co co mat H2S04 d~c .

TRl1CNG THPTYEN THANH 2-N.A

eAp AN eE THI THlI e~1 HQC LAN 1 -2011-MCN HoA HQC

Trang5j5 made122

MA122 MA123 MA124 MA125 BAPAN PHAN HWNG DAN
C©U 1 21 11 8 C HQc sinh tu suy luan
2 22 12 9 B HQc sinh tu suy luan
3 23 13 10 C HQc sinh tu suy luan
4 24 14 1 D HQc sinh tu suy luan
5 25 15 2 D Ptpu : HC03- +OR-->CO/-+HzO
C03z-+Caz+ -->CaC03
20R +Mgz+-->Mg(OH)z
nCa2+=0,004+0,02V, nMg2+=0,003, Tfnh theo OR can
0,004+0,02V+O,006 = 0,04V => V=0,5Ht
6 26 20 3 B Ba(OH)z, CH30H, HCI,CzHsOH, HZS04, Ca
7 27 21 4 B nhtrng chat tao mt axit
8 28 22 5 A Qtcho e Fe72e
Cu72e
rna ne nhan =3 nNO=0,42 mol, Cu du =0,04 mol,
mCu =2,56 gam
9 35 23 6 B nBa=x, nM=y l~p he tim diroc x theo M (triet tieu an y) sau
do gi6i han 0,21>x>0,18 ta tim diroc 33,3>M>29,7
nen hai KL la Na va K
10 36 24 7 C Gia sir hh dffu co 1 mol (mbh=15g) , theo Ctlnrc d BjA= nt/ns
c:> ns=0,5 mol =nHz pu ,
ti:r do suy ra mol hidrocacbon X bd
c:> (do X het) va mol Hz bd .l~p pt kh6i hrong hh 15 gam
ta diroc ket qua CzHz
11 1 25 11 B Do A la etc tao ti:r 2 ancol dan chtrc nen A co dang <:"HyO.
c:> 12x+y =3,5. 16=56 => C4HsO
c:> d6i chieu dk ben cua ancol ta duoc 2 ancol tirong iing
c:> la CH30H; CHz=CH-CHzOH
12 2 26 14 B Ta hieu oxit tic dung dd HClla O+2HCI nen nO=O,13mol,
mFe=7,68-0,13xI6=5,6 gam (0, 1 mol) => nFez03=O,05 mol,
m=8gam
13 3 27 15 C etilen, stiren, SOz, Axit fomic, vinylaxetilen, etanal, propilen.
14 4 28 12 B G6m: 6,7,8,10,2,3,4,5
15 5 29 13 D nHCOOH= 0,1 mol. =>n RCOOH= 0,05 mol
Hlp pt kh6i luang ta diroc R=29
16 6 30 16 A Ptpu : COz+OR -->HC03-
COz+ CO/+HzO --> HC03-
ta thay C03 z- con du 0,11 mol.nen chat ran sau khi nung ket tua
la BaO (0,11 mol). m=16,83 gam
17 7 31 17 B HQc sinh tl! suy luan
18 8 32 18 C Theo bao toan e ta ssanh thay MnOz nhan It e nhat
19 9 33 19 C NO-->3e
NH4N03--> 8e tu ne cho =1,8 mol tim diroc
n N~N03= 0,075=nNH3 => V
20 10 34 20 B DD Y hoa tan diroc Cu rna khog tao khf nen chua Fe3+
co the chua Fez+
Fe --> Fez+ +2e
Fe----> Fe3++3e
rna fie nhan tinh theo NO =0,28.3=0,84 mol
Ttr pt 2Fe3+ + Cu --> 2Fez+ +Cuz+ ta tim diroc nFe3+=0,26 mol.
ti:r do suy ra mol Fez+.v~y t6ng mol Fe = 0,29 mol Trang6j5 rna de122

21 11 35 27 A Phan tmg theo trmh nr
Zn+2Fe3+-->Zn2++2Fe2+ do Zn du nen co phan img
Zn +Fe2+--->Zn2++Fe
Tit do tfnh diroc nFe =0,04mol , m= 2,24gam
22 12 36 28 A Tit gt suy du<!c CTCT X la : CzH3COONH3CH3
23 13 37 21 B HQc sinh t1:1' suy luan
24 14 38 22 B Theo bao toan ngt6 Al , nA1 trong hh dffu = 1,2 mol
ta co he x+y =0,6 va x+4y = 1,2
x=0,4, y=0,2
Nen kill gom H2(0,6), CH4 (0,6 mol) ==> a=I,2
25 15 39 23 A n Ax=O,1 mol, nAcol = 0,1 mol, n este = 0,8 mol, m=70,4 g
26 16 40 24 D Ba + 2 H20 -->20R +H2
BaO + H20 --> 20R
Al+OR+H20 --> AI02-+ 3/2 H2 do con chat rfin nen OH het
Al02-+H++H20 --> Al(OH)3
Al(OHh+ 3H+ --> Tan
Goi mol Al pir la x, n AI(0H)3 con sau tan = x-(0,II-x)/3=0,07
x =0,08 mol, Tit kill H2 tim mol Ba, Tit sO' mol OR
apt 3 tim mol BaO , m=8,58 gam
27 17 16 33 B Theo Ba(OH2 tim n NH/=0,2 , n SOt=0,05 , theo BTDT
nN03- = 0,1 mol=n NO, V= 2,24 lit
28 18 17 34 D goi mol K+ =X , ta co theo DLBTT x+4x+3x=0,24 . 2
--> x=0,06
Kh6i IUO'ng mu6i bang t6ng kh6i IUO'ng cac ion
29 19 18 35 D Este 3 liln M=254 , (RCOOhR' hoac R(COOR')3
ta tim diroc R va R'
30 20 19 36 A Chat rfin B nguyen chtit la Cu , Fe va Zn het,
nZn = nZnO=O,1 mol
31 37 37 B nS trong mu6i = 0,18 mol nen n Fe2(S04)3 = 0,06 mol
Tit do tfnh kh6i hrong mu6i
32 38 2 25 A mO = 44%.50=22g
nSOt=I/4 nO=034375 mol, mFe =50-0,34375.96=17 gam
33 39 3 26 A nOR=0,5 v«. n H+=O,4 v-
nOR du = 0,I(Vx+Vy)=0,5 Vx- 4 Vy
--->A
34 40 4 29 C nX: nHCI=I:1 nen co 1 nhom NH2, M=147dvc
, nNaOH =(5,73- 4,41)/22=0,06, nX:nNaOH= 1:2
nen 2 nhom COOH, diU ct R(COOH)2NH2 ta co R = 41 (~H5)
35 29 5 30 C nFe=nFeCI3=0,06 mol, mo=0,64 gam (0,04 mol)
Cho e: Fe 73e, ne cho =0,18 mol
Nhan e : 072e
N073e
7nNO = 0,1/3 mol
36 30 6 31 A CuS04+2NaCI 7 Cu + CI2+NazS04
CuS04dU+H207Cu +1/202 + H2SO4
nH2S04=nCuO=0,02, 7 n02=0,01 , nCI2=0,0l
Tir do tfnh m
37 31 7 32 A D6t chay cao su bu na -S xem nhir d6t chay hh C4H6 va CgHg
sau do d~t sO' mol m6i chat la x va y
viet pt chay lap ti le la diroc
38 32 8 38 D CH3-NH3CI , CIH3N-CH2-COOH
HOOC-CH2-CH2-CH(NH2)-COOH Trang7/5 rna de122

39 33 9 39 A Quy ve ctpt la C;H7N02 va C3~N02 vi€t ptpu chay ,
thea dlbt kh6i lugn_g_ fun klugn_g_ O2 sua do l~p he binh thirong,
40 34 10 40 C goi ct este ~H2n+2-2a02dl!a vao ptpu chay xet a=I, hoac a=2
ta tim dU<lc ct C;H602,
Dua vao pu vm dd KOH ta tim dU<lc nX =0,12 mol.
m=8,88gam
41 49 44 45 B Ta tim diroc M=74 chi co 2dp este chinh la 2 chat can tim
42 50 45 46 D ML =58 dvc -7 ancol Alylic.
-
goi cttb 2 este CnH2n+tCOO-CH2-CzH3' GUn ra ta dU<lC n=I,5
nhhX=0,03 mol rna m&i chat chua 2 1t
nen nhh=nc02- nH20=nL =0,3 mol
43 41 41 47 D HQc sinh tu suy luan
44 42 42 48 A ta co phan tmg cracking cu 1 mol butan tao 2 mol san pham
gia si'r bd 1 mol
I\t/n.=MsfM.t -7 n, = 4/3 molvay tang len 1/3 mol chfnh
la IU<1n_g_p_han Un_g_ nen H=33,333%
45 43 43 49 B Theo day dien hoa
46 44 46 50 D HQc sinh tu suy luan
47 45 47 41 A G6m : saccarozo. tinh bQt, to nilon-6, protein, etyl axetat
48 46 48 42 A Hs t1! vi€t
49 47 49 43 B
50 48 50 44 C klblnh tang = rnX-mH2 -7 nH2= 0,125 mol. MTBhhx=48,8
Xt+4X2=244
tir do tim dU<lc CT.
51 55 56 54 D Theo cong thirc tinh suat di~n dQng chuan cua pin.
52 56 57 55 C HQc sinh tu suy luan
53 57 58 56 D rnn dU<lc CTPT Ancol CSH90H.
54 58 59 57 B HQc sinh tu suy luan
55 59 60 51 D HQc sinh tu suy luan
56 60 51 52 A HQc sinh tu suy luan
57 51 52 53 C HQc sinh tu suy luan
58 52 53 58 C HQc sinh tu suy luan
59 53 54 59 C Theo bao toan e
Ag-71e
Br2-72e
60 54 55 60 B HQc sinh tu suy luan Ch~c cae em mgt m~a thi thanh cc3n9 ) hl?-n 9~P It;:\i ,

--------------lIet--------------

Trang8/5 made122