"TRUONG BAI HQC KHTN BAI KIEM TRA KIEN THUG MON HOA HOC LOP 12-1011 ‘rong THPT Chuyén KHTN Thoi gian lam bai: 90 phi ~ Ngay thi: 16-01-2011 Ma a thi: 270 ‘Hg va tén hoe sinh: : Cu 1: Hoa tan hoan toan 4,24gam Na,COs vao nuéc thu duge dung dich X. Cho tr tir dén hét ting giot 20gam dung dich HCI néng 46 9,125% vao X va khudy déu. Thé tich khi CO2 thu duge & dkte 1a ‘A. 0,224Iit, “ B.O,S6lit. C.2,24lit. D. 5,6lit. ‘Cfu 2: Hoa tan 4 gam hén hop gdm Fe va kim loai M (hod tri Il, ding trnéc hidro trong day dign hod) bing 12 dich HCI dur thu durge 2,24 lit khi Hz ¢ dktc. Mit khac dé hoa tan 2,4 gam kim logi M edn phai ding chtra én 250ml dung dich HC] IM. Kim logi M da cho la A.Ca, B.Mg. C.Ba. D.Zn. Cau 3: Nhing bén thanh sit nguyén chét vao bén dung dich sau: Cu(NO;)z, FeCl, CuSO,+H;S04, Pb(NOs)s. S6 trung hop xuat hign syn mon dign hod li ALD. . B.4. C3 Dil Céu 4: Hoa tan hét 46,4 gam hén hop gdm FeO, Fe,0s, Fe;0, bing dung dich HNOs dic néng thu duge 2,24 lit khi NO» (dktc), C6 can dung dich sau phan tmg thu duge m gam mudi khan. Gi trj cla m i A. 84,7 gam, B.145,2 gam. C.36,3 gam. ‘D.96,8 gam. ‘Cfu 5: Cho cde phan dng 1) SO, + HS —p 2)Na,$,0; + H,SO, —> 3)HI + FeCl; —> 4)HS + Ch —> 5)H,0; + KNO; —> 6)0; + Ag —> T)Mg + CO,» 8)KCIO; + HCI(4) —> 9)NH,+Cu0 86 phan tng tgo ra don chat 1 A.6. B.7. C.8. D.9. Cau 6: Cho ofc chit: Cy, CoH, CzHsOH, CH;COOCH=CH;, CH.=CH-CH,CI, CHs-CHCh, Sé Inong chit t20 {rye tiép ra andehit axetic bing 1 phan img 1A AS, B.6. c.4, D.3. (Cau 7: Muén tng hop 60kg thuy tinh hitu co (plexiglat) thi kh6i long axit va ancol phai ding lan luot 1a (Biét higu sudt qué trinh este hod va qua trinh tring hgp Ian hugt 18 60% va 80%). A.32,5kgva20kg, —_-B.85,5kgva dike, C, 85kg va 40kg. D. 107,5kg va 40k Au 8: Chia hén hop gdm hai andehit no, don chirc lam hai phén bing nhau. Phan 1 dem d6t chdy hod todn thu duge 1,08gam nude. Phan 2 tic dyng véi Hy dur (Ni, t*) thu duge hén hop X. Dem 48t chay hon toan hén hop X thi thu duge thé tich CO; & dkte 1a A. 1 568!it B.0,672Iit. C.1,344lit, D. 2,688 Céu 9: Hai chét X, Y 1a déng phan cia nhau, déu c6 chita vong benzen va cé c6ng thite phan tir 1a C7HyO. Ca X, YY dbu téc dung v6i Na gidi phdng Hp. Y khéng téc dung v6i dung dich Br,. X phan img véi nue brom theo ty 18 mol | :3 tao két tha X; (CHsOBrs). Cae chét X va Y lan lugt 1a ‘A.m-crezol vi metyl phenyl ete, B, m--crezol va ancol benzylic. C. p-crezol va ancol benzylic. D. 0 -crezol va ancol benzylic. \St chay hoan toan 0,01mol mOt ancol no mach hé Y edn 0,025mol O2. Néu oxi hod 0,02mol ¥ thinh (00%), ri cho tac dung hét véi dung dich AgNO;/NH5 dur thi s6 gam bac thu duge la ‘A. 4,32gam, B. 6,48gam. C. 8,64gam. D.2,16gam. Cu 11: Cho ede chét: NasPOg; NaH:POs; NasHPO« NaH:PO,; NaHS; Na,S; NaCl; NaHSO4; NazHPOs;Na,SOx; ‘NaHCO; Na;COs. $6 chat phan ting duge véi cd dung dich NaOH va dung dich HCI la A. 4 chat. B.5 chat. C.6 chit, D. 7 chat. . ‘CAu 12: Cho 24 gam Cu vio 400ml dung dich NaNOs 0,5M; sau d6 thém tiép 500ml dung dich HCI 2M dén khi phan img xay ra hodn toan thu duge dung dich X va V1 lit khi khong mau & dktc. Mat khée thém dung dich NaOH vao X den khi két tha hét Cu thay thé tich dung dich NaOH 0,5M t6i thiéu da ding 18 V2 lit. Gid tri V; va V2 lan Iuot fb A.448lit va 12, B, 5,6lit va 1,2lit. C.4,48litva L6lit, ——-‘D. 5,6it va 1,61it. ‘CA 13: Cho eéc chat: axetilen, vinylaxetilen, phenylaxetilen, andehit fomic, axit fomic, glucozo, natri fomiat. 6 chat khir duge Ag® trong [Ag(NH3);JOH 1 ALT chi B. 6 chat. C.4 chit. D.Schit . Céiu 14: Nhigt phan hoan fodn 0,05 mol FeCO; trong binh kin chifa 0,01 mol O, thu duge cht rin X. Dé hoa tan hodn toan chat rn X bing dung djch HSO, dc, néng thi s6 mol HzO, t6i thiéu can ding la ‘A. 0,08 mol B. 0,09 mol C. 0,05 mol. D..0,075 mol. Cf 15: Cho tir tir dung dich X (chita H’, CI’, SO#>) vio dung dich Y (chita Na", CO;", OF). ‘$6 phan img tdi da cé thé xay ra dang ion thu gon la Al. B.2. C.3. D4. . Clu 16: Hop chit X c6 céng thie phan tit CsHsCls. Thiy phén hoin toan X thu duge chat Y. Biét ring Y tée dung durgc v6i Na gidi phéng H, va Y cé phan img trang gong. Céng thite cfu tgo cla X 1a 'A.CHs-CH;-CCh. —-B.CH;CI-CHCI-CHCI. C. CHs-CCl-CH,Cl. _D: CH,CI-CHy-CHCh, ibm tra kin thie Lm 12-ldn 2 ncn 2017‘Cau 17; Dét chdy hét m§t lugng chat hitu co X thu duge 3,36lit khi CO>, 0,56lit khi No (cc khi do 6 dkte) va 3,15g HO. Khi X téc dung véi dung dich NaOH thu duge sin phdm e6 mudi H;N-CH,-COONa. Céng thife cfu tao thu. gon cia X lb ‘A. HN-CH;COO-C3H;. B. HjN-CH;COO-CHs. C. H:N-CHz-CH,COOH. —_D. H,N-CH;COO-C.Hs, Céu 18: Hop chét X la m6t ct-amino axit trong phan tir chi chtta mt nhém -NH, va mét nhém ~COOH. Liy 4,12gam X cho phan tmg vita di voi dung dich NaOH tgo ra 5 gam mui. Céng thire ela Xa ‘A. CH;CH(NF)CH,COOH. B. H:NCH;COOH. C. CHyCH(NHL)COOH. D. CHsCH,CH(NH)COOH. Cu 19: Hon hgp M gém 2 este don chire mach hé X va Y hon kém nhau mt nhém CH trong phan tit. Cho 6,7 gam hdn hop M téc dung vira dit véi 100ml dung dich NaOH 1M thu duge hén hop 2 mudi. Cong thie cia X, Y la ‘A. HCOOCH, vi HCOOC:Hs. B. HCOOC;H, va CH;COOCHs. C. CH;COOCH=CH; va HCOOCH=CHh. D. HCOOCH; vi CH;COOCHs. ‘Cu 20: Cho tit,cd cdc déng phan mach hé, cé cling céng thite phan tir C]H,O; lan lugt tic dung vi: Na, NaOH, "NaHCO. $6 phan img xy ra la A2. B.3. C4. DS. ‘Cfiu 21: Cho cae dung dich HCl, HNOs, NaOH, AgNO;, NaNO;. Néu chi duge ding thém thuéc thir duy nhét la . B. [CeH;OONOz)3]. C. [CoH;0(ONOz2)s]n- _-D. [CeHs0,(NO?)s]n. ‘Cu 28: Mot hgp chat hitu co X mach thing, c6 c6ng thie phan tr 1a C3HigO2N2. Khi cho X tie dung voi kiém go ra NH; va tac dung v6i axit tao ra mudi amin bac 1. Céng thite céu tao thu gon ciia X Ia ‘A. HiN-CH;COOCH;-NEh. B. H;N-CH,CH,COONH;. C. CH-NH-CH,COONH,. D. (CHs);N-COONF. ‘Cfiu 29: Goi tén hidrocacbon o6 céng thite edu tao nhur sau: CH;~CH[CH(CHs),} >~CHy-CHs, A. 2-isopropylhex-3-in, B. 2,3- dimetylhept-3-in. C. 5,6-dimetylhept-3-in. D. 5- isopropylhex-3-in. Cau 30: Hop chat hitu co X 06 céng thite phan tir CsH20 Khi bj oxi hod khéng hoan toan tao ra sin phim Y c6 ‘kha nang tham gia phan tng trang guong. Sé6 chat théa min tinh chit cla X la A.5 chat. B. 4 chat. C.3 chat. D.2 chat. ‘Cu 31: Cho dung djch Ba(OH), dén du vio dung dich X e6 chita FeCly; FeCly; AI(NOs)s va CuSO, thu duge két tha Y. Nung Y trong kh6ng khi dén khdi Iugng khéng dai thu duge chit rin Z. Sé lng chat rin 06 trong Z la A.2 chat, B.3 chat. C. 4 chat. D. 5 chat. ‘Ciu 32: Day gdm cc dung dich c6 chita cdc chat ndo duéi day déu o6 gid tri pH <7? ‘A. NaHSOg; NaHCOs; NaHS; Na;S. 1B. NH,NOs; Mg(NO3)a NaSO«; K2SOs, C. NHACI; (NHa;S05 CuCl; KHSO, D. CHsCOOK; CéHsCOOK; K,S; KCl. (Céu 33: Cho 9,6 gam hén hop kim loai Mg va Fe vio dung dich HSO, dur thay thoat ra 6,72 lit Hy (dtc). Mat hdc khi cho 9,6 gam hén hgp trén vao 500 ml dung dich AgNOs 1,5M dén phan tg hoan toan thu duge m gam chat rin, Gid trj ctia m la ‘A. 72,9 gam. B, 48,6 gam. C81 gam. D. 56,7 gam. ‘CAu 34: Cation X** 06 tng s6 hat co ban (p, n, e) bling 80, trong 46 ti s6 hat electron so véi hat notron la 4/5. Vi tri cla X trong bang tuan hoan la ‘A. chu ky 4, nhém ILA. B. chu ky 4, nhém VIA. C. chu ky 4, nhém VIIIB. D. chu ky 4, nhém TB. Kiém tra kién thite lép 12-In 2 ndim 2011«Clu 35: C6 ede thude thir sau: Cu, NaOH, HNO», H:S, KI, KMnO, + H,S0,, $6 thude thir e6 thé ding dé nhan bidt 2 dung dich FeSO, va Fex(SO.)s dug trong 2 lo mat nhfin 1a Ad. _ BB. .5. D.6. (Cu 36: Dun néng 7,62 hn hop X gdm CoH, CH, va Hy trong binh kin véi xe tée Ni thu duge hén hop khi Y. ét chy hodn ton hén hop Y, din sin phém chay thu durge lan lurgt qua bin 1 dung H»SO, de, binh 2 dung Ca(OH), dur thay kh6i luong bin 1 ting 14,4g. Kh6i lxgng binh 2 ting lén 1a ‘A.35,2gam, B. 22gam. CC. 24,93gam. D. 17,6gam. Cau 37: Dé trung hoa 8,3 gam hén hop 2 exit don chic X, Y cdn ding vita di 150 gam dung djch NaOH 4% Biét ring axit c6 kh6i lugng phn tir nhd c6 s6 mol gap 2 lan sé mol ciia axit 6 Khi Cong thite phan ti cia X va Y Han lugt la ‘A. CH;COOH va C;H,COOH. B. HCOOH vi CH,COOH. C. CH;COOH va C;if,COOH. D. HCOOH va C;H,COOH. Cu 38: Mét este c6 c6ng thtte phan tir 1a CyH.O2, khi thuy phan trong moi trang axit thu duge dimetyl xeton, ‘Céng thite cu tao thu gon cila este 1a ‘A. HCOOCH=CH-CH). B. HCOOC(CH,)=CH;. _C. CH;COOCH-CH. __D. CH:=CH-COOCHS. ‘Cu 39: Dét chay hoan toan 0,336 lit (dktc) mét ankadien lién hyp X sau d6 hip thy hét sin pham chay vao 400 ml dung dich Ba(OH), 0,15M thu duge 8,865 gam két tila. Céng thite phan tir ciia X la. A. CH. B. Cale. C. CH. D. CH; hoe CsHs. . Cau 40: Trong mét binh kin chita hoi chat hitu co X (¢6 dang C,H2,0:) mach hé va O; (s6 mol O2 gp d6i sd mol clin cho phan tmg chay) & 139,9°C, 4p suat trong binh la 0,8atm. Dot chay hoan toan X sau dé dua vé nhigt 44 ban du, fp suét trong binh hie nay Ia 0,95 atm. Cong thite phan tir cia X 18 ‘A. CoH,O>. B.CH,0;. C. COs. D. CsH.O>. (Cau 41: Tién hanh dign phan 200ml dung dich CuSO, véi dign cye tro dén khi khéi lngng dung dich gidm 8 gam thi dimg lai. Dan khi HS du vao dung dich sau ign phén thay c6 4,8 gam két tia den. Nong 49 moV/lit cia dung dich CuSO, ban dau la A.0,875M. B.0,65M. C.0,75M. D.0,55M. Cau 42: Mét binh kin dung tich khéng di chita hén hgp cing thé tich khi Nz va Hz & 0°C, 10atm, Sau khi tién hanh tng hop NHs, dura nhiét 46 binh vé 0°C, 4p sudt trong binh la 9atm. Higu suat phan img ting hop NHs la A. 10%. B.25%. C.20%. D.30%. Cu 43: Cho edie dung djth sau: AgNOs, CuSO, , FeCh, Al(S0,)s, ZnSO¢, Ba(NOs)s, Fe(NOs)s. Khi cho dung dich NH dén dur lan lugt vao cdc dung dich trén thi s6 dung dich tao két tia 1a A6. B.S. C3. D4. . Cu 44: Dign phan 100ml dung dich hn hgp gdm H,SO, 0,5M va NaCl 0,5M véi dign eye tro, mang ngin xp én khi 6 catot thoat ra 1,12 lit khi (dkte) thi dimg Iai. Thé tich khi (dktc) thoat ra 6 anot 18 A. LI2 lit, B. 0,56 lt. C.0,784 lit. D. 0,84 lit. Ding 100 tan quang cé chira 80% khé ng 14 Fe;04(cén lai la tap chat tro) dé luyén gang (cd 95% Fe vvé khéi huong) vi higu suat qué trinh 1a 93% thi khdi long gang thu durge 1A A, 55,8 td, B. 60,9 tin. C. 56,2 tan, D.56,71 tin, Cau 46: Bét chay hodn todn mot hén hop X gdm hai andehit no, mach hd thu durge s6 mol nuée bing ding s6 mol hén hop X di phan tg. Mat khac khi cho 0,25 mol hén hgp X téc dung vi AgNO3/NHs dur thu duge m gam bac, Gia tr cia m la A. 2Tgam. B. S4gam. C.8igam. D. 108gam, ‘CAu 47: Cho céc chdt sau: bac axetilua; metan; 1,2-dicloetan; canxi cacbua; propan; etyl clorua; metanol; etanol; rnhém cacbua. C6 bao nhiéu chat trong s6 cde chit trén 06 thé diéu ché duge andchit axetic bang 2 phan ting lin tiép? AS. B.6. C7. D8. Cfiu 48: Hén hop X gdm Hp, propan va propin (propan va propin cé cing s6 mol). Cho tir tir hén hop X di qua bét Ni nung néng dén phah'img hoan toan thu duge mét chat khi duy nhat. Ti kh6i hoi cia X so véi H, la AML. B.12. C14, D, 22. ‘Cau 49: Oxi hoa 12,8gam CH,OH (¢6 xéie tc) thu duge hn hop san phim X gém andehit, axit va ancol du. Chia hn hgp X thanh hai phan bang nhau. Phin 1 cho téc dyng véi trong dung dich AgNOs/NH5 dur thu doc Gé.8g bao, Phan 2 phn img vite 60 v6 30m dung dich KOH 2M. Hig sult qua tinh oxi hod CHOH a ‘A.37,5%, B. 50%. C.75%. D.90%. Cfu 50: Dét chéy hoan toan chat hiu co X thu duge CO; va H,O cé sé mol bing nhau, Mat khée khi thuy phan X trong méi trang, fuge chat Y (tham gia phan ing trang guong) va chat Z (c6 so nguyén tir cacbon bing mot nira sé nguyén tir cacbon trong X). Phat biéu nao sau day khéng ding? ‘A. Chat Y tan v6 han trong née. B. Dét chay hét Imol X thu durge 2mol CO, va 2mol H20. C. Chit X thude logi este no, don elite. D. Bun Z véi HySO, de & 170°C thu duge anken. Het 16; Na=23; Mg=24; Al=27, $= 32; Cl=35,5; K=39; 5; Sr= 88; Ag= 108; Cs = 133; Ba = 137; Nq = 6,02.10 , Kiém tra kién thite lop 12-lén 2 néim 2011TRUONG BAI HOC KHTN ‘Trwong THPT Chuyén KHTN DAP AN,BAI KIEM TRA KIEN THU'C MON HOA HOC LOP 42-1011 Ngdy thi: 16-01-2011 Ma dé thi: 214 Cau 1: D. Cau3: A. Cau 4: C, Cau 5:C. Cau 6: D. Cau 8: D. Cau 9: C. Cau 10: D. Cau 11D. Cau 13: B, Cau 14: B. Cau 15: D. Cau 16: B. Cau 18: A. Cau 19: D, Cau 20: C. Cau 21:B. Cau 23: B. (Cau 24: D. Cau 25: B, Cau 26: B. Cau 27: A, Cau 28: C. Cau 29: A. Cau 30: C, Cau 31:D. (Cau 32: D. Cau 33: D. Cau 34: B. Cau35:B. Cau 36: D. Cau 37: C. Cau 38: A. Cau 39: C. Cau 40: C. Cau al: C. Cau 42: B. Cau 43: C, Cau 44: A. Cau 45: D. Cau 46: A Cau 47: C, Cau 48: B, Cau 49: C, Cau 50: B. Ma dé thi: 236 Cau 1c. Cau2: D, Cau 4: D. Cau 5: D. Cau 6: D. Cau 7: C. Cau 9: D, Cau 10: D. Cau 11:B. au 12:€. Cau 14: A. Cau 15: C. Cau 16: D. Cau 19: C. Cau 20: D. Céu21:D. Cau 24: C. Cau 25: A Cau 26: B. Cau 30: B. (Cau 31: B, . Cau 35: C. Cau 39: D. Cau 40: D. Cau 44: B. Cau 45: C. Cau 49: B. Cau 50: C. ‘Ma a8 thi: 258, Cau 1:D. Cau 4: A. Cau 5:D, Cau6:C. Cau 9: C. Cau 10: D. Céu L1:C. Cau 14: B. Cau 15: D. Cau 16:C, Cau 19: D. Cau 20: C. Cau 24: B. Cau 25: B. Cau 30: C. Cau 35: D. Cau 38: C. Cau 39: B. Cau 43: A. Cau 48: C. (Ma dé thi: 270 Cau: A, Ciu2: B. cau3:C. Cau 5:€. Cau 6: A. Ciu7:D. Cau 8: C. Cau 10: C. Ci 11:B. Cu 12:€. Cau 13:C. Cau 15: C. Ciu 16: D. Cu 17:B. Cau 18: D. Cau 20: D, Cau Cau 23: A. Cau 25: A. Ciu 26: B. Cu 28: B, Ciu 30: B. Cau 31:B. Cau 35: D. Cau 36: B. . Cau 40: D. Cau al: C. Cau 43: C. Cau 45: D, Cau 46: D. Cau 47: C. Cau 48: A Cau 50: D, Kiém tra kién thite Iép 12-lén 2 nam 2011