TRC NGHIM AMINOAXITPEPTITPROTEIN Cu 1.Amin RNH2 c iu ch theo phn ng : NH3+RI RNH2+HI Trong RI , Iot chim 84,41%.

%. t 0,15 mol RNH2 cn bao nhiu lt O2 (ktc)? A. 7,56 lt B. 12,6 lt C. 17,64 lt D. 15,96 lt Cu 2.T Canxi cacbua c th iu ch anilin theo s phn ng : HNO3 /H2SO4 H2O C,6000 C Fe+ HCl NaOH CaC2 C2H2 C6H6 C6H5NO2 C6H5NH3Cl C6H5NH2 hs= 80% hs= 75% hs= 60% hs=80% hs= 95%

(hs=hiu sut).T 1 tn Canxi cacbua cha 80% CaC2 c th iu ch c bao nhiu kg anilin theo s
trn ? A. 106,02 kg B. 101,78 kg C.162,85 kg D. 130,28 kg Cau 3: Cho 3,04g hon hp A gom 2 amin no n chc tac dung va u vi 400ml dd HCl 0,2M c 5,96g muoi. Tm the tch N2 (ktc) sinh ra khi ot het hon hp A tren ? A.0,224 lt B.0,448 lt C.0,672 lt D.0,896 lt Cu 4 : Hn hp X gm hai amino axit X v Y. X cha 2 nhm axit v mt nhm amino, Y cha mt nhm axit v mt nhm amino. t chy hon ton 1 mol X hoc 1 mol Y th thu c s mol CO 2 nh hn 6. Bit t l khi lng phn t M = 1,96 . Cng thc cu to ca 2 amino axit l: Y A.H2NCH2CH(COOH)CH2COOH v H2NCH2COOH B.H2NCH2CH(COOH)CH2COOH v H2N(CH2)2COOH C.H2NCH(COOH)CH2COOH v H2N(CH2)2COOH D.H2NCH(COOH)CH2COOH v H2NCH2COOH Cu 5: Bradikinin c tc dng lm gim huyt p, l mt nanopeptit c cng thc l : Arg Pro Pro GlyPheSerProPheArg. Khi thy phn khng hon ton peptit ny c th thu c bao nhiu tri peptit m thnh phn c cha phenyl alanin ( phe). A.3 B.4 C.5 D.6 Cu 6: C 4 dung dch long khng mu ng trong bn ng nghim ring bit, khng dn nhn: Abumin, Glixerol, CH3COOH, NaOH. Chn mt trong cc thuc th sau phn bit 4 cht trn: A. Qu tm B. Phenol phtalein. C. HNO3 c. D. CuSO4. Cu 7: 1 mol aminoaxit X tc dng va ht vi 1 mol HCl to ra mui Y c hm lng clo l 28,287%. CTCT ca X l : A. CH3 CH(NH2) COOH. B. H2N CH2 CH2 COOH. C. H2N CH2 COOH. D. H2N CH2 CH(NH2) COOH. Cu 8 : Mt hp cht X c cng thc phn t C3H7O2N. X khng phn ng vi dung dch brom, khng tham gia phn ng trng ngng. X c cng thc cu to no sau y? A. H2NCH2CH2COOH B. CH2=CHCOONH4 C. H2NCH(CH3)COOH D. CH3CH2CH2NO2 +Y +Z Cu 9. C qu trnh chuyn ho sau:C6H12O3N2 X C3H6NO2K X, Y, Z l nhng cht no sau y? A. amino butanoic, NaOH, HCl. B. amino propanoic, HCl, KOH. C. amino axetic, KOH, HCl. D. C A, B, C u sai. Cu 10: Mt hp cht hu c X mch thng c Cng thc phn t l C 3H10O2N2. X tc dng vi dung dch kim to cht kh lm qu tm m ho xanh, mt khc X tc dng vi dung dch axit to thnh mui amin bc mt. X c Cng thc phn t no sau y? A. H2NCH2CH2COONH4 B. CH3CH(NH2)COONH4 C. CH3CH2CH(NH2)COONH4. D. A v B ng Cu 11: nhn bit cc cht lng du ho, du m, gim n v lng trng trng ta c th tin hnh theo th t no sau y: A. Dng qu tm, dng vi git HNO3 c, dng dung dch NaOH. B. Dng dung dch Na2CO3, dng dung dch HCl, dng dung dch NaOH. C. Dng dung dch Na2CO3, dng dung dch iot, dng Cu(OH)2. D. Dng phenolphtalein, dng HNO3 c, dng H2SO4 c. Cu 12 : khi thy phn cc pentapeptit di y : (1) : AlaGliAlaGluVal (2) : GluGliValAlaGlu (3) : AlaGliValValGlu(4) : GliGliValAla Ala pentapeptit no di y c th to ra ipeptit c khi lng phn t bng 188? A. (1), (3) B. (2),(3) C. (1),(4) D. (2),(4) Cu 13 : tripeptit X to thnh t 3 amino axit no n chc mch h v c phn t khi nh nht. Thy phn 55,44 gam X bng 200 ml dung dch NaOH 4,8M un nng, sau c cn dung dch thu c bao nhiu gam cht rn khan? A. 89,520 gam B. 92,096 gam C. 93,618 gam D. 73,14 gam Cu 14 : Cho 1 ipeptit phn ng vi NaOH c, un nng. H2NCH2CONHCH2COOH + 2NaOH Y+ H2O Y l hp cht hu c g? A. Natri aminoaxetat B. Natri axetat C. Metylamin D. Amoniac Cu 15 : Cho 1ml anbumin (lng trng trng) vo mt ng nghim, thm vo 0,5ml HNO3 c. Hin tng quan st c l: Nguyn Trung Kin Lp 12A1 Trang 1
MX

A. dung dch chuyn t khng mu thnh mu vng. B. dung dch chuyn t khng mu thnh mu da cam. C. dung dch chuyn t khng mu thnh mu xanh tm. D. dung dch chuyn t khng mu thnh mu en. Cu 16 : Thy phn 73,8 gam mt peptit ch thu c 90 gam glixin (axit aminoaxetic). Peptit ban u l : A. ipeptit B. tripeptit C. tetrapeptit D. pentapeptit Cu 17 : Mt poli peptit c to ra t glyxin v alanin c phn t khi 587 vC. Hi c bao nhiu mt xch to ra t glyxin v alanin trong chui peptit trn? A. 5 v 4 B. 2 v 6 C. 4 v 5 D. 4 v 4 Cu 18 : Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l : A. 15,65 B. 26,05 C. 34,6 D. 35,5 Cu 19 : Thy phn hon ton 14,6g mt ipeptit thin nhin X bng dung dch NaOH, thu c sn phm trong c 11,1g mt mui cha 20,72% Na v khi lng. Cng thc ca X l : A. H2N CH2 CO NH CH2 COOH. B. H2N CH(CH3) CO NH CH(CH3) COOH. C. H2N CH(CH3) CO NH CH2 COOH hoc H2N CH2 CO NH CH(CH3) COOH. D. H2N CH(C2H5) CO NH CH2 COOH hoc H2N CH2 CO NH CH(C2H5) COOH. Cu 20 : Khi thu phn mt cht protein (A) ta thu c mt hn hp 3 amino axit k tip trong dy ng ng. Mi amino axit cha mt nhm amino, mt nhm cacboxyl. Nu t chy 0,2 mol hn hp 3 amino axit trn ri cho sn phm chy qua bnh ng dung dch NaOH c, khi lng bnh tng 32,8 g, bit rng sn phm chy c kh N2. Cc amino axit l A.CH5O2N, C2H5O2N, C2H7O2N B.CH3O2N, C2H5O2N, C3H7O2N C.C2H5O2N, C3H7O2N, C4H9O2N D.C2H7O2N, C3H9O2N, C4H11O2N Cu 21 : (X) l hp cht hu c c cng thc phn t C5H11O2N. un X vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca (X) l: A.CH3(CH2)4NO2 B. H2N CH2COO CH2 CH2 CH3 C. H2N CH2 COO CH(CH3)2 D.H2N CH2 CH2 COOC2H5 Cu 22 : X c cng thc phn t l C4H12O2N2. Cho 0,1 mol X tc dng vi 135 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 11,1 gam cht rn. X l: A. H2NC3H6COONH4 B. H2NCH2COONH3CH2CH3 C. H2NC2H4COONH3CH3 D. (H2N)2C3H7COOH Cu 23 : X,Y,Z l 3 amino axit no n chc mch h. *t chy X thu c hn hp sn phm CO2, hi H2O v N2 trong VCO2 : VH2O = 8 : 9 . *MY=1,1537MX *Trong Z phn trm khi lng C l 54,96%. Peptit no di y c phn t khi l 273? A.XXXY B. XZX C. XXY D.XZY Cu 24 : X l tetrapeptit , Y tripeptit u to nn t 1 loi aminoaxit (Z) c 1 nhm COOH v 1 nhm NH2 v MX =1,3114 MY. Cho 0,12 mol pentapeptit to thnh t Z tc dng vi dung dch NaOH va sau c cn thu c bao nhiu cht rn khan? A. 75,0 gam B. 58,2 gam C. 66,6 gam D. 83,4 gam Cu 25 : X v Y l 2 tetrapeptit, khi thy phn trong mi trng axit u thu c 2 loi amino axit no n chc mch h l A v B. Phn trm khi lng oxi trong X l 23,256% v trong Y l 24,24%.A v B ln lt l : A. alanin v valin B. glyxin v alanin C. glyxin v axit aminobutiric D. alanin v axit aminobutiric Cu 26 : X v Y ln lt l tripeptit v tetrapeptit to thnh t 1 loi aminoaxit no mch h c 1 nhm NH2 v 1 nhm COOH. t chy 0,1 mol Y thu c CO2, H2O v N2 trong tng khi lng CO2 v H2O l 47,8 gam. Nu t 0,1 mol X cn bao nhiu mol O2? A. 0,560 mol B. 0,896 mol C. 0,675 mol D. 0,375 mol Cu 27 : X l hexapeptit AlaGlyAlaValGlyVal; Y l tetrapeptit GlyAlaGlyGlu Thy phn m gam hn hp gm X v Y trong mi trng axit thu c 4 loi aminoaxit trong c 30 gam glixin v 28,48 gam alanin. m c gi tr l :A. 87,4 gam B. 73,4 gam C. 77,6 gam D. 83,2 gam Cu 28 : Cht hu c A c 1 nhm amino v 1 chc este. Hm lng nit trong A l 15,73%.X phng ha m gam cht A, hi ancol bay ra cho i qua CuO nung nng c anehit B. Cho B thc hin phn ng trng bc thy c 16,2 gam Ag kt ta. Gi tr ca m l : A. 7,725 gam B. 3,375 gam C.6,675 gam D. 5,625 gam Cu 29 : X l 1 pentapeptit cu to t 1 amino axit no mch h c 1 nhm COOH v 1 nhm NH2 (A), A c tng phn trm khi lng oxi v nit l 51,685%. Khi thy phn ht m gam X trong mi trng axit thu c 30,2 gam tetrapeptit; 30,03 gam tripeptit; 25,6 gam ipeptit v 88,11 gam A. m c gi tr l : A. 149,2 gam B. 167,85 gam C. 156,66 gam D. 141,74 gam Trang 2 Nguyn Trung Kin Lp 12A1

Cu 30 : Thy phn ht 1 lng pentapeptit trong mi trng axit thu c 32,88 gam AlaGlyAlaGly; 10,85 gam AlaGlyAla; 16,24 gam AlaGlyGly; 26,28 gam AlaGly; 8,9 gam Alanin cn li l GlyGly v Glyxin. T l s mol GlyGly:Gly l 5:4. Tng khi lng GlyGly v Glyxin trong hn hp sn phm l : A. 43,2 gam B. 32,4 gam C. 19,44 gam D. 28,8 gam Cu 31 : Mt peptit X to thnh t 1 aminoaxit no mch h c 1 nhm COOH v 1 nhm NH2 trong phn trm khi lng oxi l 19,324%. X l : A. ipeptit B. tripeptit C. tetrapeptit D. pentapeptit BI TP TRC NGHIM AMIN Cu 1.Tnh baz ca etylamin mnh hn amoniac c gii thch l do: A.Nguyn t N cn cp electron cha tham gia lin kt B.Nguyn t N trng thi lai ho sp3 C.Etylamin lm qu tm tm nc ho xanh, amoniac khng c tnh cht ny D.Do gc C2H5 c tnh y electron Cu 2. Pht biu no sau y lun ng vi amin: A.Khi lng phn t ca amin n chc lun l s l B.Khi lng phn t ca amin n chc lun l s chn C.Khi t chy hon ton a mol amin X lun thu c a/2 mol N2 D A v C u ng Cu 3 Pht biu no sau y khng ng: A.Cc amin u c tnh baz B.Tnh baz ca cc amin u mnh hn NH3 C.Phenylamin c tnh baz yu hn NH3 D.Tt c cc amin n chc u cha s l nguyn t H trong phn t Cu 4. Hy sp xp cc cht sau y theo trt t tng dn tnh baz: (1) anilin; (2) etylamin; (3) ietylamin; (4) natri hiroxit; (5) amoniac. A. (1) < (5) < (2) < (3) < (4) B. (1) < (2) < (5) < (3) < (4) C. (2) < (1) < (3) < (4) < (5) D. (2) < (5) < (4) < (3) < (1) Cu 5. Hy sp xp cc cht sau y theo the t tng dn tnh baz: (1) metylamin; (2) amoniac; (3) etylamin; (4) anilin; (5) propylamin. A. (4) < (5) < (2) < (3) < (1) B. (4) < (2) < (1) < (3) < (5) C. (2) < (1) < (3) < (4) < (5) D. (2) < (5) < (4) < (3) < (1) Cu 6.t chy m gam hn hp gm 2 amin no n chc mch h thu c 28,6 gam CO2 v 18,45 gam H2O. m c gi tr l : A. 13,35 gam B. 12,65 gam C. 13 gam D. 11,95 gam Cu 7.t chy hn hp gm 2 amin no n chc mch h ng ng k tipthu c N2, CO2 v hi H2O V H O 251 2 = c t l . % khi lng cc amin trong hn hp ln lt l : VCO 176
2

A. 42,73% v 57,27% B. 44,70% v 55,30% C. 43,27% v 56,73% D. 41,32% v 58,68% Cu 8. t chy hn hp X gm 2 amin no n chc mch h ng ng k tip thu c CO2 v hi H2O c V CO 7 2 = .Nu cho 24,9 gam hn hp X tc dng vi dung dch HCl va thu c bao nhiu gam t l VH O 13
2

mui? A. 39,5 gam B. 43,15 gam C. 46,8 gam D. 52,275 gam Cu 9.13,35 gam hn hp X gm 2 amin no n chc mch h ng ng k tip tc dng vi dung dch HCl va thu c dung dch cha 22,475 gam mui . Nu t 13,35 gam hn hp X th trong sn phm V CO 2 chy c bng : A. 8/13 B. 5/8 C. 11/17 D. 26/41 VH O
2

Cu 10.X v Y l 2 amin n chc mch h ln lt c phn trm khi lng Nit l 31,11% v 23,73%. Cho m gam hn hp gm X v Y c t l s mol nX:nY=1:3 tc dng vi dung dch HCl va thu c dung dch cha 44,16 gam mui . m c gi tr l : A. 22,2 g B. 22,14 g C. 33,3 g D. 17,76 g Cu 11.Cho 26 gam hn hp 2 amin no n chc mch h bc mt c s mol bng nhau tc dng ht vi axit nitr nhit thng thu c 11,2 lt N2 (ktc). Kt lun no sau y l sai? A. 2 amin trn l 2 ng ng k tip. B. Nu t chy hon ton 26 gam hn hp X thu c 55 gam CO2. C. Tng khi lng 2 ancol sinh ra l 26,5 gam D. Cho amin c phn t khi nh tc dng vi CH3I theo t l mol 1:1 thu c amin bc hai c phn trm khi lng nit l 19,178%. Cu 12.Hn hp X gm 2 amin no n chc mch h ng ng k tip c phn trm khi lng nit l 20,144%. Phn trm s mol cc amin trong X theo chiu tng dn phn t khi l : A. 50% v 50% B. 25% v 75% C. 20% v 80% D. 30 v 70% Cu 13.X l dung dch anilin trong benzen. t chy hon ton 12,97 gam X cn 151,76 lt O2(ktc). Phn trm s mol anilin trong X l : A. 20% B. 22,22% C. 30% D.11,11% Nguyn Trung Kin Lp 12A1 Trang 3

Cu 14.t chy hon ton hn hp gm 1 amin no n chc mch h X v 1 amin khng no n chc mch h Y c 1 ni i C=C c cng s nguyn t C vi X cn 55,44 lt O2(ktc) thu c hn hp kh v hi V CO 10 2 = trong v VN2 = 5,6lit (ktc). Khi lng ca hn hp amin ban u l : VH O 13
2

A. 35,9 gam B. 21,9 gam C. 29 gam D. 28,7 gam Cu 15.Cho nc brom vo dung dch anilin thu c 16,5 gam kt ta 2,4,6tribromanilin. Khi lng anilin tham gia phn ng l : A. 30 gam B. 34 gam C. 36 gam D. 32 gam Cu 16.Hn hp X gm metylamin, etylamin v propylamin c tng khi lng 21,6 gam l v t l v s mol l 1:2:1. Cho hn hp X trn tc dng ht vi dung dch HCl thu c dung dch cha bao nhiu gam mui? A.36,2 gam B. 39,12 gam C. 43,5 gam D. 40,58 gam Cu 17.X l 1 amin no mch h 2 ln amin (c 2 chc amin u bc 1) c khi lng phn t bng khi lng phn t ca 1 este n chc c phn trm khi lng oxi l 36,36%.. X c bao nhiu ng phn cu to? A. 6 B. 7 C. 8 D. 9 Cu 18.Cho 24,9 gam hn hp X gm 2 amin no n chc mch h ng ng k tip tc dng vi dung dch FeCl3 d thu c 21,4 gam kt ta. Cng thc v % khi lng ca 2 amin l : A. C2H7N( 27,11%) v C3H9N (72,89%) B. C2H7N( 36,14%) v C3H9N (63,86%) C. CH5N( 18,67%) v C2H7N (81,33%) D. CH5N( 31,12%) v C2H7N (68,88%) Cu 19. kt ta ht 400ml dung dch hn hp HCl 0,5M v FeCl3 0,8M cn bao nhiu gam hn hp gm metylamin v etylamin c t khi so vi H2 l 17,25? A.41,4 gam B. 40,02 gam C. 51,75 gam D. Khng iu kin tnh. Cu 20.Cho 3 amin mch h ln lt c cng thc phn t l C3H9N, C4H11N v C5H13N. C tng s bao nhiu ng phn amin bc hai ? A. 8 B. 9 C. 10 D. 11 Cu 21.C bao nhiu ng phn amin c 1 vng benzen v c cng thc phn t l C8H11N? A. 8 B. 9 C. 10 D. 11 Cu 22.t chy mt hn hp amin A cn V lt O2(ktc) thu c N2 v 31,68 gam CO2 v 7,56 gam H2O. Gi tr V l : A. 25,536 B. 20,16 C. 20,832 D. 26,88 Cu 23.Cho 0,14 mol mt amin dn chc tc dng vi dung dch cha 0,1 mol H2SO4. Sau c cn dung dch thu c 13,72 gam hn hp 2 mui .Phn trm khi lng mi mui trong hn hp mui l : A.67,35% v 32,65% B. 44,90% v 55,10% C. 53,06% v 46,94% D. 73,47% v 26,53% Cu 24.t chy mt amin thm X thu c 3,08 gam CO2; 0,99 gam CO2 v 336 ml N2(ktc). Mt khc 0,1 mol X tc dng va vi 300 ml dung dch HCl 1M. Phn t khi ca X l : A.151 B. 137 C. 165 D. 179 Cu 25.X l amin no n chc mch h v Y l amin no 2 ln amin mch h.c cng s cacbon. Trung ha hn hp gm a mol X v b mol Y cn dung dch cha 0,5 mol HCl v to ra 43,15 gam hn hp mui. Trung ha hn hp gm b mol X v a mol Y cn dung dch cha 0,4 mol HCl v to ra p gam hn hp mui. p c gi tr l : A. 40,9 gam B. 38 gam C. 48,95 gam D. 32,525 gam Cu 26.Cho m gam amin n chc bc mt X tc dng vi dung dch HCl va thu c m+7,3 gam mui. t m gam X cn 23,52 lt O2(ktc). X c th l : A. CH3NH2 B. C2H5NH2 C.C3H7NH2 C. C3H5NH2 Cu 27.Hn hp kh X gm NH3 v metylamin c t khi so vi CO2 l 0,45. t hon ton m gam X bng lng oxi va thu c hn hp gm CO2, hi H2O v N2 c khi lng l 26,7 gam. A. 19,8 gam B.9,9 gam C. 11,88 gam B. 5,94 gam Cu 28. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A.100ml B.50ml C.200ml D. 320ml Cu 29. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Bit phn t khi ca cc amin u < 80. Cng thc phn t ca cc amin l p n A, B, C hay D? A.CH3 NH2; C2H5NH2 v C3H7NH2 B. C2H3 NH2; C3H5NH2 v C4H7NH2 C. C2H5 NH2; C3H7NH2 v C4H9NH2 D.C3H7 NH2; C4H9NH2 v C5H11NH2
Cu 30. Cho 10 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 15,84 gam hn hp mui. Nu trn 3 amin trn theo t l mol 1 : 20 : 5 theo th t phn t khi tng dn th cng thc phn t ca 3 amin l p n no sau y? A. CH5N, C2H7N, C3H7NH2 B.C2H7N, C3H9N, C4H11N C.C3H9N, C4H11N, C5H11N D.C3H7N, C4H9N, C5H11N

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Nguyn Trung Kin Lp 12A1

Cu 31.Ngi ta iu ch anilin bng s sau

Fe+HCl 3 Benzen Nitrobenzen Anilin 0 H SO a c 2 4 t + HNO a c

Bit hiu sut giai on to thnh

nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 186,0 gam B. 111,6 gam C. 55,8 gam D.93,0 gam

Bi tp t lun.
Cu 1: Vit cng thc cu to c th c ca cc amin c cng thc phn t C3H9N, C4H11N. Gi tn v ch r bc ca chng. Cu 2: Vit phn ng gia cc cp hp cht sau. CH 3NH2 v HCl, CH3NH2 v H2SO4 (t l mol l 1:1), CH3NH2 v H2SO4 (t l mol l 2:1), CH3NH2 v CH3COOH. Cu 3: So snh tnh baz ca cc cht sau: NaOH, NH3, CH3NH2, C2H5NH2, C6H5NH2 Cu 4: Nhn bit cc cht ng trong cc bnh mt nhn sau: a. phenol, anilin, benzen, styren b. anilin, metyl amin, axit axetic, anehit axetic Cu 5: t chy hon ton 1,605 gam hp cht A thu c 4,62 gam CO2 v 1,215 gam H2O v 168 Cm3 N2 (ltc). a. Tnh thnh phn % cc nguyn t. b. Bit 3,21 gam hp cht A phn ng ht 30 ml dung dch HCl 1M. Vit cng thc cu to c th c ca A. Bit A l ng ng ca anilin. Cu 6: Hn hp A gm 4 hp cht hu c no, n chc l ng phn ca nhau. Bn hp cht u d phn ng vi dung dch HCl. Phn t mi cht u cha cc nguyn t C, H, N (chim 23,7% v khi lng). Vit cng thc cu to ca 4 hp cht v tnh khi lng hn hp A, bit t chy hn hp A cho 4,48 lit N2 (ktc). Cu 7: (i hc khi A-2006). t chy hon ton 1,18 gam amin n chc B bng mt lng khng kh va . Dn ton b hn hp kh sau phn ng vo bnh ng dung dch Ca(OH)2 d, c 6 gam kt ta v c 9,632 lt kh (ktc) duy nht thot ra khi bnh. a. Tm cng thc phn t ca B b. Vit cc cng thc cu to c th c ca B v gi tn. (bit khng kh c 20% O 2 v 80% N2 v th tch)

Bi tp trc nghim.
Cu 8: Cho cc cu sau cu no sai. a. Cc amin c tnh baz b. Cc amin u l xanh qy tm c. amin l nhng hp cht hu c c cu thnh bng cch thay th mt hay nhiu nguyn t hiro trong phn t amoniac bi mt hay nhiu gc hyrocacbon. d. bc ca amin l s nguyn t H trong amonic b thay th bi gc hyrocacbon. Cu 9: ( i hc khi A-2007) Pht biu khng ng l. a. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng v dung dch HCl li thu c phenol. b. axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. c. dung dch natri phenolat phn ng vi kh CO 2, ly kt ta va to c cho tc dng vi dung dch NaOH li thu c natri phenolat. d. anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH l thu c anilin. Cu 10: So snh tnh baz ca cc cht sau: CH3NH2, (CH3)2 NH, NH3 a. CH3NH2 < (CH3)2 NH < NH3 b. NH3 < CH3NH2 < (CH3)2 NH c. NH3 < (CH3)2 NH < CH3NH2 d. (CH3)2 NH < CH3NH2 < NH3 Cu 11: So snh tnh baz ca cc cht sau: CH3NH2, C2H5NH2, NH3, C6H5NH2 Nguyn Trung Kin Lp 12A1 Trang 5

a. CH3NH2 < C2H5NH2 < NH3 < C6H5NH2 C2H5NH2 c. C6H5NH2 < NH3 < CH3NH2 < C2H5NH2 CH3NH2

b. NH3 < C6H5NH2 <

CH3NH2 <

d. C6H5NH2 < NH3 < C2H5NH2<

Cu 12: (i hc khi B-2007) Dy gm cc cht u lm giy qy tm m chuyn sang mu xanh l: a. metyl amin, amoniac, natri axetat b. anilin, amoniac, natri hiroxit c. amoni clorua, metyl amin, natri hiroxit d. anilin, metyl amin, amoniac. Cu 13: Mt amin c cng thc phn t l C3H9N s ng phn ca amin l: a. 2 b. 3 c. 4 d. 5 Cu 14: ( thi tt nghip- 2007) S ng phn amin bc 1 ng vi cng thc phn t l C3H9N l. a. 4 b. 3 c. 5 d. 2 Cu 15: Mt amin c cng thc phn t l C4H11N, s ng phn ca amin l: a. 7 b. 8 c. 9 d. 10 Cu 16: Mt amin c cng thc phn t l C4H11N, s ng phn amin bc I l: a. 3 b. 4 c. 5 d. 6 Cu 17: (Cao ng khi A-2009) S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l a. 4. b. 5. c. 2. d. 3. Cu 18: (i hc khi A-2009) Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l a. 5. b. 8. c. 7. d. 4. Cu 19: Cho cc cu sau cu no khng ng: a. Cc amin u c tnh baz. b. Tnh baz ca tt c cc amin u mnh hn NH3. c. Anilin c tnh baz yu hn NH3. d. Tt c cc amin n chc u cha mt s l nguyn t H trong phn t. Cu 21: S d anilin c tnh baz yu hn NH3 l do: a. Nhm NH2 cn mt cp electron cha lin kt. b. phn t khi ca anilin ln hn NH2. c. Nhm NH2 c tc dng y electron v pha bng benzen lm gim mt electron ca nguyn t N. d. Gc phnyl c nh hng lm gim mt electron ca nguyn t N. Cu 21b: (i hc khi A-2009) Pht biu no sau y l ng? a. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. b. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. c. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. d. Benzen lm mt mu nc brom nhit thng. Cu 22: Cho s phn ng sau: A + HNO3, B + H xt H2SO4 dac C6H5NH2 vy cng thc phn t ca A l: a. C6H6 b. C6H5NH3Cl c. C6H5CH3 d. tt c u sai Cu 23: nhn bit cc cht: CH3NH2, C6H5NH2, C6H5OH, CH3COOH trong cc bnh mt nhn ngi ta dng. a. dung dch HCl, v qy tm b. qy tm v dung dch Br2 c. dung dch NaOH v dung dch Br2 d. Tt c u ng. Cu 24: (i hc khi B-2007) Trang 6 Nguyn Trung Kin Lp 12A1

C 3 cht lng benzen, anilin, stiren ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l. a. dung dch NaOH b. giy qy c. dung dch d. nc brom phenolphtalein Cu 25: (i hc khi A-2009) C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? a. 4. b. 5. c. 3. d. 6. Cu 26: t chy hon ton hn hp hai amin bc mt mch h, no, n chc, k tip nhau trong cng dy ng ng thu c CO2 v H2O vi t l s mol nCO2:nH2O = 1: 2. Hai amin c cng thc phn t ln lt l a. C2H5NH2 v C3H7NH2 b. CH3NH2 v C2H5NH2 c. C3H7NH2 v C4H9NH2 d. C4H9NH2 v C5H11NH2 Cu 27: t chy hon ton hn hp 2 amin no n chc, l ng ng lin tip thu c 2,24 lit kh CO2 (ktc) v 3,6 gam H2O. Cng thc phn t ca 2 amin l: a. CH3NH2 v C2H5NH2 b. C2H5NH2 v C3H7NH2 c. C3H7NH2 v C4H9NH2 d. Tt c u sai. Cu 28: Khi t chy hon ton mt amin n chc X, ngi ta thu c 10,125 gam H2O v 8,4 lit kh CO2 v 1,4 lit N2 (ktc). Cng thc phn t ca amin l: a. C4H11N b. C2H7N c. C3H9N d. C5H13N Cu 29: Khi cho 13,95 gam anilin tc dng hon ton vi 0,2 lit dung dch HCl 1M th khi lng ca mui phenylamoniclorua thu c l a. 25,9 b. 20,25 c. 19,425 d. 27,15 Cu 30: ( thi tt nghip -2007) Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l. a. 7,65 gam b. 0,85 gam c. 8,10 gam d. 8,15 gam Cu 31: t chy hon ton m gam mt amin X bng mt lng khng kh va thu c 17,6 gam CO2 v 12,6 gam H2O v 69,44 lit N2 (ktc). Gi thit khng kh ch gm N2 v O2, trong oxi chim 20% th tch khng kh . Vy X c cng thc l. a. C4H11N b. C2H7N c. C3H9N d. CH5N Cu 32: t chy hon ton 1,18 gam amin n chc B bng mt lng khng kh va , dn ton b hn hp kh sau phn ng vo bnh Ca(OH) 2 d, c 6 gam kt ta v c 9,632 lit kh (dktc) duy nht thot ra khi bnh. Xc nh cng thc phn t ca B a. C4H11N b. C2H7N c. C3H9N d. CH5N Cu 33: (i hc khi A-2007) Khi t chy hon ton mt amin n chc X, thu c 8,4 lit kh CO2, 1,4 lit kh N2 (cc th tch kh o iu kin tiu chun) v 10,125 gam H2O. Cng thc phn t ca X l. a. C3H7N b. C3H9N c. C4H9N d. C2H7N Cu 34: (Cao ng khi A-2007) trung ha 25 gam dung dch mt amin n chc X nng 12,4 % cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l. a. CH5N b. C2H7N c. C3H7N d. C3H5N Cu 35: (Cao ng khi A-2008) Cho dy cc cht: Phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi dung dch NaOH l. a. 3 b. 4 c. 1 d. 2 Cu 36: (Cao ng khi A-2008)

Nguyn Trung Kin Lp 12A1

Trang 7

Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y thu c 9,55 gam mui khan. S cng thc cu to tng ng vi phn t ca X l. a. 5 b. 4 c. 3 d. 2 Cu 37: (i hc khi B-2008) Cht phn ng c vi dung dch FeCl3 cho kt ta l. a. CH3NH2 b. CH3COOH c. CH3OH d. CH3COOCH3 Cu 38: (i hc khi B-2009) Ngi ta iu ch anilin bng s sau: H SO dac , HNO Benzen dac nitrobenzen
2 4 3

Fe + HCl ,t

anilin.

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l a. 111,6 gam. b. 55,8 gam. c. 93,0 gam. d. 186,0 gam.
Chng 3 AMIN, AMINOAXIT, PROTIT I. AMIN Cu 1. Trong cc cht di y cht no l amin bc 2? 1. CH3 NH2 2. CH3 NH CH3 3. (CH3)(C2H5)2N 4. (CH3)(C2H5)NH 5.(CH3)2CHNH2 A. 1, 2 B. 3, 4 C. 4, 5 D. 4, 5 Cu 2. C bao nhiu cht ng phn amin c cng cng thc phn t C3H9N ? A. 1 B. 2 C. 3 D. 4 Cu 3. C bao nhiu cht ng phn amin c cng cng thc phn t C4H11N? A. 4 B. 5 C. 6 D. 7 Cu 4. C bao nhiu amin cha vng benzen c cng cng thc phn t C7H9N A. 3 B. 4 C. 5 D. 6 Cu 5. C bao nhiu amin bc 2 c cng cng thc phn t C5H13N A. 4 B. 5 C. 6 D. 7 Cu 6. Amin c CTCT: (CH3)2CHNH2 c tn gi l A. Metyl etyl amin B. Etyl metyl amin C. Izo propyl amin D. izo- propan amin Cu 7. Amin c CTCT: (CH3)2CH NH CH3 c tn gi l A. N-Metyl propan amin B. N-izo-propyl metan amin C. N-Metyl izo-propan amin D. N-Metyl propan -2 amin Cu 8. Amin c CTCT: CH3(CH2)3N(CH3)2 c tn gi l A. N,N- imetyl propan amin B. N,N- imetyl butan-1-amin C. N,N butyl metyl metan amin C. N,N imetyl butan-2-amin Cu 9. Amin c CTCT: (CH3)2(C2H5)N c tn goi l A. Etyl imetyl amin B. imetyl etyl amin C. Etyl metyl amin C. izo-propyl metyl amin Cu 10. Amin tn gi: Etyl izo-propyl amin c CTCT l A. CH3(CH2)2(C2H5)NH B. (CH3)2CH(C2H5)NH C. (CH3)2CHNH2 C. (C2H5)(CH3)NH Cu 11. N,N- Etyl metyl propan-1-amin c CTCT l A. (CH3)(C2H5)(CH3CH2CH2)N B. (CH3)2CH(CH3)(C2H5)N C. (CH3)2(C2H5)N D. (CH3)(C2H5)(CH3)2CHN Cu 12. S ng phn cu to ca amin bc mt c cng ctpt C4H11N l A. 2 B. 3 C. 4 D. 5 Cu 13. Amin no di y l amin bc 2? A. CH3NH2 B. CH3-CHNH2CH3 C. CH3NHCH3 D. (CH3)2NCH2CH3 Cu 14. Amin no, n chc, mch h c cng thc chung l A. CxHyN (x 1) B. CnH2n + 3N (n 1) C. CnH2n +1 N (n 1) D. C2H2n - 5N Cu 15. Cng thc chung ca amin thm ( cha 1 vng bezen) n chc bc nht l A. CnH2n 7NH2 (n 6) B. CnH2n + 1NH2 (n6) C. C6H5NHCnH2n+1 (n6) D. CnH2n 3NH2 (n6) Cu 16. Amin no di y c 4 ng phn cu to? A. C2H7N B. C3H9N C. C4H11N D. C5H13N Cu 17. Pht biu no sau y v tnh cht vt l ca amin l khng ng? A. Metyl amin, imetyl amin, etyl amin l cht kh, d tan trong nc B. Cc amin kh c mi tng t aminiac, c C. Anilin l cht lng kh tan trong nc, mu en

Trang 8

Nguyn Trung Kin Lp 12A1

D. tan trong nc ca amin gim dn khi s nguyn t cacbon trong phn t tng Cu 18. Nhn xt no di y khng ng? A Anilin c tnh baz, phenol c tnh axit B. Dd anilin lm xanh qu tm, dd phenol lm qu tm C. Anilin v phenol u d tham gia phn ng th vi dd Br2 to kt ta trng D. Anilin v phenol u tham gia phn ng cng H2 vo nhn thm Cu 19. Nhn xt no sau y khng ng? A. Cc amin u c tnh baz B. Tnh baz ca anilin yu hn NH3 C. Amin tc dng c vi axit to ra mui D. Amin l hp cht hu c c tnh cht lng tnh Cu 20. Hin tng no sau y khng ng? A. Nhng qu tm vo metyl amin thy qu tm chuyn sang mu xanh B. Phn ng gia kh metyl amin v kh HCl xut hin khi trng C. Nh vi git dd Br2 v dd anilin thy xut hin kt ta trng D. Thm vi git phenolphtalein vo dd etyl amin thy xut hin mu xanh Cu 21. Ancol v amin no sau y cng bc? A. (CH3)2CHOH & (CH3)2CHNH2 B. (CH3)3COH & (CH3)3CNH2 C. C6H5CHOHCH3 & C6H5NHCH3 D. C6H5CH2OH & (C6H5)2NH Cu 22. kh mi tanh ca c, nn s dng dd no sau y? A. Nc ng B. Nc mui C. dd gim D. dd Ru Cu 23. Anilin thng bm vo ng nghim. ra sch anilin ngi ta thng dng dd no sau y trc khi ra li bng nc? A. dd axit mnh B. dd baz mnh C. dd mui n D. dd nc ng Cu 24. So snh tnh baz ca cc cht sau: CH3NH2 (1), (CH3)2NH (2), NH3 (3) A. (1) < (2) < (3) B. (3) < (1) < (2) C. (3) < (2) < (1) D. (2) < (1) < (3) Cu 25. Xp cc cht sau theo chiu gim dn tnh baz: C2H5NH2 (1), CH3NH2 (2), NH3 (3), NaOH (4) A. (4) > (1) > (2) > (3) B. (2) > (4) > (1) > (3) C. (3) > (1) > (2) > (4) D. (4) > (2) > (1) . (3). Cu 26. Trt t tng dn lc baz ca dy no sau y l khng ng? A. C6H5NH2 < NH3 B. NH3 < CH3NH2 < C2H5NH2 C. CH3CH2NH2 < (CH3)3NH D. p CH3C6H4NH2 < p O2NC6H4NH2 Cu 27. C 4 cht ng trong 4 l mt nhn: phenol, anilin, benzen, styren. Th t nhm thuc th no sau y c th nhn bit 4 cht trn? A. Qu tm, dd Br2 B. dd Br2, dd NaOH C. dd Br2, dd HCl D. B, C Cu 28. C 4 dd ring bit mt nhn: anilin, metyl amin, axit axetic, anhyt axetic (axetanhyt). Th t thuc th no sau y nhn bit c 4 dd trn? A. dd HCl, dd Br2 B. Qu tm, dd AgNO3/NH3,tOC C.Qu tm, dd Br2 D. B, C Cu 29. nhn bit cc cht: CH3NH2, C6H5NH2, C6H5OH, CH3COOH trong cc bnh mt nhn ring bit, ngi ta dng A. dd HCl v qu tm B. Qu tm v dd Br2 C. dd NaOH v dd Br2 D. Tt c ng Cu 30. C 3 cht lng bezen, anilin, styren ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dd NaOH B. Qu tm C. Dd phenolphtalein D. Nc Br2 Cu 31. C 3 dd amoni hyrocacbonat, Natri aluminat, natri phenolat v 3 cht lng ancol etylic, bezen, anilin ng trong 6 ng nghim ring bit. Nu ch dng mt thuc th duy nht l dd HCl th nhn bit c ti a bao nhiu ng nghim? A. 3 B. 4 C. 5 D. 6 Cu 32. Cho cc cht sau: 1. p- CH3C6H4NH2 2. m- CH3C6H4NH2 3. C6H5NHCH3 4. C6H5NH2 Xp cc cht sau theo chiu tng dn tnh baz A. 1 < 2 < 4 < 3 B. 4 < 2 < 1 < 3 C. 4 < 3 < 2 < 1 D. 4 < 3 < 1 < 2 Cu 33. Cho cc cht: 1. ancol etylic 2. etyl amin 3. metyl amin 4. axit axetic. Xp cc cht trn theo chiu tng dn nhit si. A. 2 < 3 < 4 < 1 B. 3 < 2 < 1 < 4 C. 1 < 3 < 2 < 4 D. 3 < 1 < 2 < 2 Cu 34. C 4 l mt nhn ng 4 cht: metanol, glyxerol, dd glucoz, anilin. C th dng 2 cht no trong s cc cht sau nhn bit cc cht trn? 1. dd KOH 2. Na kim loi 3. Cu(OH)2 4. dd Br2 5. dd AgNO3/NH3, tOC A. 2, 5 B. 1,4 C. 3,4 D. 4,5 Cu 35. Pht biu khng ng l A. Phenol p vi dd NaOH, ly mui va to ra cho tc dng vi dd HCl li to ra phenol B. Axit axetc p vi dd NaOH, ly mui va to ra cho tc dng vi CO2 thu c axit axetic C. Dd natri phenolat p vi kh CO2, ly kt ta va to c cho tc dng vi dd NaOH li thu c natriphenolat D. Anilin p vi dd HCl, ly mui va to ra cho tc dng vi dd NaOH thu c anilin Cu 36. Cho dy cc cht: Phenol, anilin, phenylamoni clorua, natriphenolat, etanol. S cc cht p c vi dd NaOH l Nguyn Trung Kin Lp 12A1 Trang 9

A. 1 B. 2 C. 3 D. 4 Cu 37. Dung dch no di y khng lm i mu qu tm? A. CH3NHCH3 B. NH3 CH3NH2 D. C6H5NH2 Cu 38. Dung dch metyl amin c th tc dng vi cht no sau y: Na2CO3, FeCl3, H2SO4 long, CH3COOH, C6H5oNa, qu tm A. FeCl3, H2SO4long, CH3COOH, qu tm B. Na2CO3, FeCl3, H2SO4 long, C6H5Ona C. FeCl3, qu tm D. Na2CO3, H2SO4 long, qu tm Cu 39. Dy gm cc cht lm qu tm chuyn sang mu xanh l A. anilin, metyl amin, NH3 B. amoniclorua, metyl amin, natrihyroxit B. anilin, amoniac, natri hyroxit D. metyl amin, amoniac, natri axetat Cu 40. Khi t chy hon ton mt amin n chc X, thu c 16,80 lit CO2, 2,80 lit N2 ( cc kh o ktc) v 20,25g H2O. ctpt ca X l A. C4H9N B. C3H7N C. C2H7N D. C3H9N Cu 41. t chy hon ton amin n chc X thu c 10,125g H2O, 8,4 lit CO2 v 1,4 lit N2 (cc kh o ktc). Ctpt ca X l A. C2H7N B. C3H9N C. C4H11N D. C5H13N Cu 42. t chy hon ton 2 amin no, n chc, mch h ng ng k tip thu c 4,4g CO2 v 3,6g H2O. Ctpt ca 2 amin l A. Metyl amin v etyl amin B. Etyl amin v propyl amin C. propyl amin v butyl amin D. Etyl metyl amin v imetyl amin Cu 43. t chy hon ton mt amin no n chc thu c VH2O = 1,5 VCO2. Ctpt ca amin l A. C2H7N B. C3H9N C. C4H11N D. C5H13N Cu 44. t chy hon ton 2 amin no, n chc ng ng lin tip, thu c hn hp sn phm v hi nc vi t l V(CO2) : V(H2O) = 8 : 17. Cng thc ca 2 amin l A. C2H5NH2 v C3H7NH2 B. C3H7NH2 v C4H9NH2 C. CH3NH2 v C2H5NH2 D. C4H9NH2 v C5H11NH2 Cu 45. t chy hon ton 6,2g mt amin no, n chc phi dng ht 10,08 lit kh oxi (ktc). Ctpt ca amin l A. C2H5NH2 B. CH3NH2 C. C4H9NH2 D. C3H7NH2 Cu 46. t chy hon ton 2 amin no, n chc, mch h bc 1 k tip trong dy ng ng thu c CO2 v nc vi t l s mol n(CO2) : n(H2O) = 1 : 2. Ctpt ca 2 amin ln lt l A. C2H5NH2 v C3H7NH2 B. CH3NH2 v C2H5NH2 C. C3H7NH2 v C4H9NH2 D. C4H9NH2 v C5H11NH2 Cu 47. t chy hon ton hn hp 2 amin no, n chc, ng ng k tip thu c 2,24 lit CO2 (ktc) v 3,6g H2O. Ctpt ca 2 amin l A. CH3NH2 v C2H5NH2 B. C2H5NH2 v C3H7NH2 C. C3H7NH2 v C4H9NH2 D. Tt c u sai Cu 48. t chy hon ton m gam mt amin X bng 1 lng khng kh va thu c 17,6g CO2, 12,6g H2O v 69,44 lit N2 (ktc). Gi thit khng kh ch gm N2 v O2, trong O2 chim 20% th tch khng kh. Ctpt ca X l A. C4H11N B. C2H7N C. C3H9N D. CH5N Cu 49. t chy hon ton 1,18g amin n chc X bng 1 lng khng kh va , dn ton b lng hn hp kh sau phn ng vo bnh ng Ca(OH)2 d, c 6g kt ta v c 9,632 lt kh (ktc) duy nht thot ra khi bnh. Tm ctpt ca X A. C4H11N B. C2H7N C. C3H7N D. CH5N Cu 50. t chy hon ton hn hp 3 amin X, Y, Z bng 1 lng khng kh va 1/5 th tch l oxi, cn li l nit) thu c 26,4g CO2, 18,9g H2O, 104,16 lit N2 (ktc). Gi tr m l A. 12g B. 13,5g C. 16g D. 14,72g Cu 51. t chy hon ton mt amin thm bc mt X thu c 3,08g CO2, 0,99g H2O v 336 ml kh N2 (ktc). trung ho 0,1 mol X cn 600ml dd HCl 0,5M. X c ctct l A. CH3C6H2(NH2)3 B. CH3NHC6H3(NH2)2 C. H2NCH2C6H3(NH2)2 D. A, C Cu 52. t chy hon ton mt amin thm bc 1 A, thu c 1,568 lit CO2, 1,232 lit hi H2O v 0,336 lit N2. trung ho 0,05 mon A cn 200 ml dd HCl 0,75M. Bit cc kh o ktc. Ctpt ca A l A. C6H5NH2 B. (C6H5)2NH C. C6H4(NH2)2 D. C7H11N3 Cu 53. Cho 3,04g hn hp A gm 2 amin no n chc tc dng va vi 400 ml dd HCl 0,2M thu c a gam mui. Tm th tch N2 (ktc) sinh ra khi t chy ht hn hp A trn A. 0,224 lit B. 0,448 lit C. 0,672 lit D. 0,896 lit Cu 54. Trong bnh kn cha 35 ml hn hp gm H2, mt amin n chc v 40 ml O2. Bt tia la in t chy hon ton hn hp, ri a hn hp thu c v iu kin ban u. Th tch cc cht to thnh bng 20 ml gm 50% l CO2, 25% l N2, 25% l O2. Ctpt ca amin l A. CH5N B. C2H7N C. C3H6N D. C3H5N Cu 55. t chy hon ton 0,02 mol mt amin bc mt X vi lng oxi va . Cho ton b sn phm qua bnh ng nc vi trong d, thy khi lng bnh tng 3,2g v 0,448 lit mt cht kh (ktc) khng b hp th. Lc dd thu c 4,0g kt ta. Ctpt ca X l A. C2H5N B. C2H7N C. C2H8N2 D. C2H6N2 Cu 55. Cho 4,5g metyl amin tc dng va vi dd HCl. Khi lng mui thu c l

Trang 10

Nguyn Trung Kin Lp 12A1

A. 7,65g B. 0,85g C. 8,10g D. 8,15g Cu 56. Khi cho 13,95g anilin tc dng hon ton vi 0,2 lit dd HCl 1M. Khi lng mui thu c l A. 25,9g B. 20,25g C. 19,425g D. 27,15g Cu 57. Cho lng d anilin p hon ton vi 0,05 mol H2SO4 long, khi lng mui thu c l A. 7,1g B. 14,2g C. 19,1g D. 28,4g Cu 58. Amin n chc bc 1 X tc dng va vi lng HCl c trong 120 ml dd HCl 0,1M thu c 0,81g mui. X l A. mtanamin B. etanamin C. propanamin D. benzenamin Cu 59. Cho 3 amin no, n chc, mch h ng ng lin tip tc dng va vi dd HCl 1M. C cn dd thu c 31,68g hn hp mui. Th tch dd HCl dng l A. 16 ml B. 32 ml C. 100 ml D. 320 ml Cu 60. Hn hp 2 amin no, n chc, mch h ng ng lin tip. Cho 20g hn hp tc dng va vi dd HCl. C cn dd sau p thu c 31,68g hn hp mui khan. Ctpt 2 amin l A. CH3NH2, C2H5NH2 B. C2H5NH2, C3H7NH2 C. C3H7NH2, C4H9NH2 D. C4H9NH2, C5H11NH2 Cu 61. Cho 3,6g etylamin tc dng v vi 100 ml dd H2SO4. Sinh ra 8,5g mui. Dd H2SO4 c ng mol/lit l A. 0,5M B. 0,6M C. 0,7M D. 0,8M Cu 62.C 2 amin bc 1:(A) l ng ng ca anilin, (B) l ng ng ca metylamin.t chy hon ton 3,21g (A) thu c 336 ml N2 (ktc). Khi t chy hon ton (B) cho hn hp kh, trong V(CO2) : V(H2O) = 2 : 3. CTCT ca (A),(B) l A. C6H5CH2NH2 v CH3CH2CH2NH2 B. C6H5(CH2)2NH2 v CH3CH2CH2NH2 C. C6H5CH2NH2 v CH3(CH2)4NH2 D. A v B ng Cu 63. Trung ho 3,1g mt amin n chc X cn 100 ml dd HCl 1M. Ctpt ca X l A. C2H5N B. CH5N C. C3H9N D. C3H7N Cu 64. Cho 1,52g hn hp 2 amin no, n chc (c s mol bng nhau) tc dng va vi0 ml d HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc? A. dd HCl c CM = 0,2M B. ctpt 2 amin l CH5N v C2H7N C. S mol mi cht l 0,02 mol D. Tn gi 2 amin l metylamin v etylamin Cu 65. trung ho 25g dd mt amin n chc (X) 12,4% cn dng 100 ml dd HCl 1M. Ctpt ca X l A. CH5N B. C2H7N C. C3H7N D. C3H5N Cu 66. Cho 5,9g amin n chc (X) tc dng va vi dd HCl, sau khi p xy ra hon ton thu c dd Y. Lm bay hi dd Y thu c 9,55g mui khan. S ctct ca (X) l A. 2 B. 3 C. 4 D. 5 Cu 67. Cho hn hp M gm 2 amin no, n chc, bc 1: (X) v (Y). Ly 2,28g hn hp trn tc dng vi 300 ml dd HCl th thu c 4,47g mui. S mol 2 amin trong hn hp bng nhau. nng mol/lit ca dd HCl v tn gi ca 2 amin ln lt l A. 0,2M; metylamin; etylamin B. 0,06M; metylamin; etylamin C. 0,2M; etylamin; propylamin D. 0,03M; etylamin; propylamin Cu 68. Cho 29,8g hn hp 2 amin n chc, k tip trong dy ng ng tc dng ht vi dd HCl, C cn dd sau p thu c 51,7g mui khan. Ctpt hai amin l A. CH5N v C2H7N B. C2H7N v C3H9N C. C3H9N v C4H11N D. C3H7N v C4H9N Cu 69. Hp cht hu c X mch h (cha C. H, N), trong N chim 23,73% v khi lng. Bit X tc dng vi HCl yheo t l mol 1:1. Ctpt ca X l A. C2H7N B. C3H7N C. C3H9N D. C4H11N Cu 70. Trong bnh kn cha 35 ml hn hp H2, mt amin n chc v 40 ml O2. Bt tia la in t chy hon ton hn hp ri a hn hp thu c v iu kin ban u, th tch cc cht to thnh bng 29 ml gm 50% CO2, 25% N2, 25% O2. Ctpt ca amin l A. CH5N B. C2H7N C. C3H6N D. C3H5N

Chng IV: Aminoaxitprotein 4.1. Tm cc ng phn aminoaxit c cng thc phn t C 4H9O2N (ch vit vi nhm amin bc nht). Gi tn chng theo danh php IUPAC. Ch r cc ng phn hot ng quang hc v biu din tng cp i quang bng cng thc chiu Fischer. 4.2. tng hp cc aminoaxit, ngi ta chn mt anehit tc dng vi axit malonic trong dung dch amoniacru. Da trn phng php ny, hy tng hp axit aminovaleric. 4.3. Lp s tng hp L(+)alanin t L()serin:

4.4. Hai ng phn A v B c cng thc phn t C9H11O2N, chng u tan c trong axit v kim. Khi A v B tc dng vi NaNO2 trong HCl thu c 2 cht tng ng A. v B. Nguyn Trung Kin Lp 12A1 Trang 11

COOH H2N H CH2OH L-(-)-serin

COOH H2N H CH3 L-(+ )-alanin

u c cng thc C9H10O3, trong ch c B. c tnh quang hot. Khi un nng A. v B. u thu c mt cht c cng thc phn t C9H8O2. Khi oxi ha tip cht ny th thu c axit terephtalic v CO2. Hy xc nh cng thc cu to ca A, B v vit cng thc Fischer ca cp i quang. 4.5. Tin hnh Naxetyl ha cc aminoaxit c th dn n sn phm vng gi l 5oxazolon hay azlacton theo phn ng sau:

H iu kin . Hy vit c ch cho s hnh thnh azlacton trong3C 4.6. tng hp aminoaxit, trc ht c th cho glyxin tc dng vi anhirit axetic thu c 5oxazolon hay azlacton (C4H5O2N). Sn phm ngng t ny phn ng vi anehit trong mi trng baz cho mt dn xut d b thu phn ha, hiro ha v thu phn thu c mt aminoaxit RCH2CH(NH2)COOH t anehit l RCHO (S thu phn ch n thun l cng nc, sau axit axetic c to ra). Theo cch trn, hy vit cc phn ng to thnh phenylalanin. 4.7. Hy vit cc giai on c bn tng hp peptit t aminoaxit. Ly v d minh ho cho mi giai on. 4.8. Vit cng thc cu to ca cc peptit sau: a. GlyLysPheCysAlaNH2. b. TreIleMetLeuNH2. 4.9. S thoi phn peptit theo Edman l phng php phn tch cho aminoaxit c lin kt cui m khng ph hu mch peptit cn li. Peptit u c x l vi phenylisothioxianat C6H5N=C=S, tip theo cho phn ng vi axit to phenylthiohiantoin v mt peptit vi phn cn li t hn mt aminoaxit. Hy vit cc giai on c th ca phng php ny. 4.10. T cc cht protein thc vt, ngi ta tch ra c mt cht Y c cng thc phn t C5H10O3N2. Kt qu nghin cu chng t rng Y c cha 1 nhm amino. Khi un nng Y vi dung dch kim thy gii phng NH3 v to thnh mui ca axitaminoicacboxylic c cng thc phn t C3H5(NH2)(COOH)2. Khi tin hnh phn ng thoi phn Hoffman dn xut axetyl ca Y ri thu phn s to ra axit , iaminobutyric. T cc d kin trn, hay suy ra cng thc cu to ca Y v vit phng trnh phn ng minh ho. 4.11. Xc nh cng thc cu to ca cht c cng thc phn t C3H7O2N v cc d kin sau: C tnh cht lng tnh. Khi phn ng vi HNO2 tch ra nit. Khi tc dng vi etanol to thnh hp cht C5H11O2N. Khi un nng n to thnh hp cht C6H10O2N2. 4.12. Xc nh cng thc cu to ca cht c cng thc phn t C 5H11O2N v cc d kin sau: C tnh cht lng tnh. Tc dng vi etanol to thnh hp cht c cng thc phn t C7H15O2N. Khi ung nng s tch ra NH3 v chuyn thnh hp cht m khi oxi ha n s to thnh axeton v axit oxalic. 4.13. Lp s iu ch: a. Valin t isobutanol b. Alanin t etilen c. Axit3aminopropanoic t axetilen 4.14. Hon thnh cc s phn ng sau:
NH3 A HCl A PCl5 A (CH3CO)2O A a/ CH3 CH CHO HCN A 1 2 3 4 5 lo ng CH3 NH un b/ CH2 CH CH2 COOH HBr B12 3 B2 HCl B3 nng B4
Trang 12 Nguyn Trung Kin Lp 12A1

(CH3CO)2O + H2N CH COOH R

CH3COONa

C O O

n c/ CH2 CH2HOCl C1 KCN C2HBr C3 NH3 C4thu ph C5 d/ CH CH CH COOH HBr D KCN D 4[H] D
3 1 2 3

TRC NGHIM AMINOAXIT Cu 1 : C bao nhiu tn gi ph hp vi cng thc cu to: (1). H2NCH2COOH : Axit amino axetic. (2). H2N[CH2]5COOH : axit amino caproic. (3). H2N[CH2]6COOH : axit amino enantoic. (4). HOOC[CH2]2CH(NH2)COOH : Axit amino glutaric. (5). H2N[CH2]4CH (NH2)COOH : Axit , iamino caproic. A. 2 B. 3 C. 4 D.5 Cu 2: Cho cc cu sau y: (1). Khi cho axit glutamic tc dng vi NaOH d th to sn phm l bt ngt, m chnh. (2). Phn t cc amino axit ch c mt nhm NH2 v mt nhm COOH. (3). Dung dch ca cc amino axit u c kh nng lm qu tm chuyn mu. (4). Cc mino axit u l cht rn nhit thng. (5). Khi cho amino axit tc dng vi hn hp NaNO2 v CH3COOH kh thot ra l N2. S nhn nh ng l: A. 1 B. 2 C. 3 D.4 Cu 3:1 thuc th c th nhn bit 3 cht hu c : axit aminoaxetic, axit propionic, etylamin l A. NaOH. B. HCl. C. Qu tm. D. CH3OH/HCl. Cu 4 Thuc th thch hp nhn bit 3 dung dch sau y: Axit fomic, Glyxin, axit , diaminobutyric. A. AgNO3/NH3 B. Cu(OH)2 C. Na2CO3 D. Qu tm. Cu 5:C 4 dung dch long khng mu ng trong bn ng nghim ring bit, khng dn nhn: Abumin, Glixerol, CH3COOH, NaOH. Chn mt trong cc thuc th sau phn bit 4 cht trn: A. Qu tm B. Phenol phtalein. C. HNO3 c. D. CuSO4. Cu 6:Khi trng ngng m g axit aminocaproic vi hiu sut 80%, ngoi aminoaxit cn d ngi ta thu c p gam polime v 1,44g nc. Gi tr m l A. 10,48g. B. 9,04g. C. 11,02g. D. 13,1g. Cu 7: Este X c iu ch t aminoaxit A v ancol etylic. 2,06 gam X ha hi hon ton chim th tch bng th tch ca 0,56 gam N2 cng iu kin nhit , p sut . Nu cho 2,06 gam X tc dng va vi dung dch NaOH s thu c dung dch cha bao nhiu gam mui? A.2,2 g B. 1,94 g C. 2,48 g D. 0,96 g Cu 8 : Cht hu c A c 1 nhm amino v 1 chc este. Hm lng nit trong A l 15,73%.X phng ha m gam cht A, hi ancol bay ra cho i qua CuO nung nng c anehit B. Cho B thc hin phn ng trng bc thy c 16,2 gam Ag kt ta. Gi tr ca m l : A. 7,725 g B. 3,375 g C.6,675 g D. 5,625 g Cu 9: un nng 100ml dung dch mt aminoaxit 0,2 M tc dng va vi 80ml dung dch NaOH 0,25M. Sau phn ng ngi ta c cn dung dch thu c 2,5 g mui khan. Mt khc, ly 100g dung dch aminoaxit trn c nng 20,6 % phn ng va vi 400ml dung dch HCl 0,5 M. Cng thc phn t ca aminoaxit l: A. H2NCH2COOH B. CH3CH(NH2)COOH C. CH3CH2CH(NH2)COOH. D. CH3COONH4 Cu 10: Khi t chy hon ton mt ng ng ca glixin thu c nH 2O : nCO2 = 7 : 6 (phn ng chy sinh ra kh N2). X c cng thc cu to l: A. H2NCH2COOH B. CH3CH(NH2)COOH C. NH2CH2CH2COOH. D. B v C ng. Cu 11: T l th tch CO2: H2O (hi) sinh ra khi t chy hon ton mt ng ng (X) ca glixin l 6:7 (phn ng chy sinh ra kh N2). (X) tc dng vi glixin cho sn phm l mt ipeptit (X) l: A. H2N CH2 CH2 COOH (1) B. C2H5 CH(NH2) COOH (3) C. CH3 CH(NH2) COOH (2) D. (1) v (2) ng Cu 12:Hn hp X gm hai aminoaxit mch h no n chc ng ng k tip c phn trm khi lng oxi l 37,427%. Cho m gam X tc dng vi 600ml dung dch KOH 1M (d) sau khi phn ng kt thc c cn dung dch thu c 60,6gam cht rn khan. m c gi tr l :A. 34,2 g B.38,65 g C. 26,7 g D. 37,8 g Cu 13 : Hn hp M gm hai amino axit X v Y u cha 1 nhmCOOH v 1 nhm NH2 (t l mol nX:nY= 3:2). Cho 17,24 gam M tc dng ht vi 110 ml dung dch HCl 2M c dung dch Z. tc dng ht vi cc cht trong Z cn 210 ml dung dch KOH 2M. Cng thc cu to ca X v Y l : A. H2NC2H4COOH, H2NC3H6COOH B. H2NCH2COOH, H2NC2H4COOH C. H2NCH2COOH, H2NC3H6COOH D. H2NCH2COOH, H2NC4H8COOH Cu 14: Cho 0,012 mol aminoaxit X phn ng va vi HCl to ra 1,506 g mui Y. Cng thc cu to ca X l: A. H2NCH2COOH. B.H2NCH2CH(NH2)COOH. C.H2NCH2CH2COOH. D.HOOCCH2CH2CH(NH2)COOH. Nguyn Trung Kin Lp 12A1 Trang 13

Cu 15: trung ho 200 ml dung dch aminoaxit M 0,5M cn 100 gam dung dch Na0H 8%, c cn dung dch sau phn ng c 16,3 gam mui khan. M c cng thc cu to: A. H2NCH2 COOH B. H2NCH(COOH)2 C. H2NCH2CH(COOH)2 D. (H2N)2CHCOOH Cu 16 : Hp cht hu c A c M = 89 cha C, H, O, N. Hp cht A va tc dng vi NaOH, va tc dng vi HCl, c tham gia phn ng trng ngng. A c trong t nhin. Cng thc cu to thu gn ca A l: A. H2NCH2CH2COOH B. CH3CH(NH2)COOH C. C3H7NHCOOH D. HCOO H3NCH3 Cu 17 : Hp cht hu c X c cng thc tng qut CxHyOzNt c % N = 15,7303% ; %O = 35,9551%. Bit X tc dng HCl to mui c dng R(Oz) NH3Cl. Bit X c tnh lng tnh v tham gia phn ng trng ngng. Vy CTCT ca X l: A. H2N(CH2)2COOH ; CH3CH(NH2)COOH B. H2N (CH2)3 COOH ; CH3 CH2 CH(NH)2 COOH C. H2N CH = CH COOH ; CH2 = C(NH2) COOH D. Tt c u sai Cu 18 : Mt hn hp (X) gm 2 aminoaxit c cng s mol. Ly m gam (X) cho phn ng vi H2SO4 th thu c 2 mui c khi lng bng m + 9,8g. Mt khc, ly cng khi lng m gam (X) phn ng vi NaOH to ra 2 mui c tng khi lng bng m + 3,3g. Xc nh s mol ca mi aminoaxit. Hai aminoaxit ny thuc loi aminoaxit trung tnh, baz hay axit? A. 0.05mol. mt aminoaxit trung tnh, 0.05 mol aminoaxit l axit B. 0.2mol. mt aminoaxit trung tnh, 0,2 mol aminoaxit l axit C. 0.1mol c hai l aminoaxit trung tnh D. 0.2mol. mt aminoaxit baz, mt aminoaxit l axit Cu 19 : t chy hon ton 45,1 gam hn hp X gm CH3CH(NH2)COOH v CH3COONH3CH3 thu c CO2, H2O v N2 c tng khi lng l 109,9 gam. Phn trm khi lng mi cht trong hn hp X ln lt l : A. 59,20% v 40,80% B. 49,33% v 50,67% C. 39,47% v 60,53% D. 35,52% v 64,48% Cu 20: (X) l hp cht hu c c cng thc phn t C5H11O2N. un X vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca (X) l: A.CH3(CH2)4NO2 B. H2N CH2COO CH2 CH2 CH3 C. H2N CH2 COO CH(CH3)2 D.H2N CH2 CH2 COOC2H5 Cu 21 : X l 1 amino axit ch c 1 nhm amino NH2 v 1 nhm cacboxyl COOH. Cho 66,75 gam X phn ng va vi HCl to ra 94,125 gam mui. Vy cng thc cu to ca X l : A.H2NCH2COOH B.H2NCH=CHCOOH C.H2NCH(CH3)COOH D.CH3CH(NH2)CH2COOH Cu 22 : X c cng thc phn t l C4H12O2N2. Cho 0,1 mol X tc dng vi 135 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 11,1 gam cht rn. X l: A. H2NC3H6COONH4 B. H2NCH2COONH3CH2CH3 C. H2NC2H4COONH3CH3 D. (H2N)2C3H7COOH Cu 23 : Hn hp A gm 2 amino axit no mch h ng ng k tip , c cha 1 nhm amino v 1 nhm chc axit trong phn t. Ly 23,9 gam hn hp A cho tc dng vi 100 ml dung dch HCl 3,5M (c d). tc dng ht cc cht trong dung dch D cn dng 650 ml dung dch NaOH 1M. Cng thc hai cht trong hn hp A l : A. CH3CH(NH2)COOH, CH3CH2CH(NH2)COOH B. CH3CH2CH(NH2)COOH, CH3CH2CH2CH(NH2)COOH C. H2NCH2COOH, CH3CH(NH2)COOH D. CH3CH2CH2CH(NH2)COOH, CH3CH2CH2CH2CH(NH2)COOH Cu 24 : Cht hu c X (cha C,H,O,N) c phn t khi l 89. X tc dng vi c HCl v NaOH. Khi cho 0,1 mol X tc dng vi dung dch NaOH d thu c 9,4 gam mui. X l : A. Axit amino propionic B Axit amino propionic. C. Metyl aminoaxetat D. amoni acrylat Cu 25 : Cho 0,02 mol cht X (X l mt amino axit) phn ng va ht vi 160 ml dd HCl 0,125M th to ra 3,67 g mui. Mt khc 4,41 gam X khi phn ng vi 1 lng NaOH va th to ra 5,73g mui khan. Bit X c mch cacbon khng phn nhnh. Vy cng thc cu to ca X l: A.HOOCCH(NH2)CH(NH2)COOH B.HOOCCH2CH2CH(NH2)COOH C.CH3CH2CH(NH2)COOH D.CH3CH2CH2CH(NH2)COOH Cu 26 : Hn hp A gm hai aminoaxit no cha mt chc amin, mt cha axit, lin tip nhau trong dy ng ng. Dng khng kh d t chy hon ton 3,21 g hn hp A. Hn hp thu c sau phn ng em lm kh c hn hp kh B. Cho B qua dung dch Ca(OH)2 d thu c 9,5 g kt ta. Phn trm s mol cc amino axit trong hn hp A ln lt l : A. 50% v 50% B. 62,5% v 37,5% C. 40% v 60 D.27,5% v 72,5% Cu 27 : tc dng va vi 29,94 gam hn hp X gm 1 s amino axit (ch c nhm chc COOH v NH2 , khng c nhm chc khc) cn 380 ml dung dch KOH 1M. Mt khc t chy 29,94 gam hn hp X cn 24,528 lt O2 (ktc) thu c m gam CO2; p gam H2O v 3,36 lt N2(ktc). a)m c gi tr l : A.39,60 gam B. 42,24 gam C. 52,80 gam D.38,72 gam b)p c gi tr l : A. 18,54 gam B. 18,72 gam C. 19,44 gam D. 20,16 gam Trang 14 Nguyn Trung Kin Lp 12A1

Cu 28 Hn hp X gm 1 s amino axit no (ch c nhm chc COOH v NH2 , khng c nhm chc khc) c t l khi lng mO:mN=48:19. tc dng va vi 39,9 gam hn hp X cn 380 ml dung dch HCl 1M. Mt khc t chy 39,9 gam hn hp X cn 41,776 lt O2 (ktc) thu c m gam CO2. m c gi tr l : A. 66 gam B. 59,84 gam C. 61,60 gam D. 63,36 gam BI TP AMIN AMINO AXIT PROTEIN I. Trc nghim l thuyt: Cu 1: 1: Cng thc ca amin cha 15,05% khi lng nit l cng thc no sau? A. C2H5NH2 B. (CH3)2NH C. C6H5NH2 D. (CH3)3N Cu 2: Cng thc phn t C3H9N ng vi bao nhiu ng phn?A. 5 B. 4 C. 3 D. 2 Cu 3: Cho amin c cu to: CH3-CH(CH3)-NH2 . Chn tn gi khng ng? A. Prop-1-ylamin B. Propan-2-amin C. isoproylamin D. Prop-2-ylamin Cu 4: Tn gi ng C6H5NH2 ng? A. Benzyl amoni B. Phenyl amoni C. Hexylamin D. Anilin Cu 5: Hp cht hu c X mch h cha cc nguyn t C, H, N trong c 23,72% khi lng N. X tc dng vi HCl theo t l mol 1:1. Chn cu pht biu sai? A. X l hp cht amin. B. Cu to ca X l amin no, n chc C. Nu cng thc X l CxHyNz th z = 1 D. Nu cng thc X l CxHyNz th : 12x - y = 45 Cu 6: Pht biu no sau y khng ng? A. Amin c cu to bng cch thay th H ca amoniac bng 1 hay nhiu gc H-C. B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amin. C. Ty thuc vo gc H-C, c th phn bit thnh amin thnh amin no, cha no v thm. D. Amin c t 2 nguyn t cacbon trong phn t bt u xut hin ng phn. Cu 7: Amin no di y l amin bc 2? A. CH3-CH2NH2 B. CH3-CHNH2-CH3 C. CH3-NH-CH3 D. CH3-NCH3-CH2CH3 Cu 8: Cng thc no di y l cng thc chung ca dy ng ng amin thm (cha 1 vng bezen) n chc bc nht? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 Cu 9: Tn gi cc amin no sau y l khng ng? A. CH3-NH-CH3 imetylamin B. CH3-CH2-CH2NH2 n-propylamin C. CH3CH(CH3)-NH2 isopropylamin D. C6H5NH2 alanin Cu 10: Amin no di y c 4 ng phn cu to?A. C2H7N B. C3H9N C. C4H11N D. C5H13N Cu 11: Pht biu no sau y v tnh cht vt l ca amin l khng ng? A. Metyl-, etyl-, imetyl-, trimetylamin l nhng cht kh, d tan trong nc.B. Cc amin kh c mi tng t amoniac, c. C. Anilin l cht lng, kh tan trong nc, mu en.D. tan ca amin gim dn khi s nguyn t cacbon trong phn t tng. Cu 12: Cc gii thch v quan h cu trc, tnh cht no sau y khng hp l? A. Do c cp electron t do trn nguyn t N m amin c tnh baz. B. Do nhm NH2- y e nn anilin d tham gia vo phn ng th vo nhn thm hn v u tin v tr o- v pC. Tnh baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. D. Vi amin R-NH2, gc R ht electron lm tng mnh ca tnh baz v ngc li. Cu 13: Nhn xt no di y khng ng? A. Phenol l axit cn anilin l baz. B. Dd phenol lm qu tm ha cn dd anilin lm qu tm ha xanh. C. Phenol v anilin u d tham gia phn ng th v u to kt ta trng vi dd brom. D. Phenol v anilin u kh tham gia phn ng cng v u to hp cht vng no khi cng vi hiro. Cu 14: S d anilin c tnh baz yu hn NH3 l do yu t no? A. Nhm NH2- cn 1 cp electron t do cha tham gia lin kt. B. Nhm NH2- c tc dng y electron v pha vng benzen lm gim mt electron ca N. C. Gc phenyl c nh hng lm gim mt electron ca nguyn t N. D. Phn t khi ca anilin ln hn so vi NH3 Cu 15: Hy ch ra iu sai trong cc iu sau? Nguyn Trung Kin Lp 12A1 Trang 15

A. Cc amin u c tnh baz B. Tnh baz ca anilin yu hn NH3 C. Amin tc dng vi axit cho ra mui D. Amin l hp cht hu c c tnh cht lng tnh Cu 16: Dd etylamin tc dng vi dd nc ca cht no sau y? A. NaOH B. NH3 C. NaCl D. FeCl3 v H2SO4 Cu 17: Hp cht no di y c tnh baz yu nht? A. Anilin B. Metylamin C. Amoniac D. imetylamin Cu 18: Cht no di y c tnh baz mnh nht? A. NH3 B. CH3CONH2 C. CH3CH2CH2OH D. CH3CH2NH2 Cu 19: Sp xp cc cht sau y theo tnh baz gim dn? (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. 1>3>5>4>2>6 B. 6>4>3>5>1>2 C. 5>4>2>1>3>6 D. 5>4>2>6>1>3 Cu 20: Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl 3+ + C. Fe + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3 D. CH3NH2 + HNO2 CH3OH + N2 + H2O Cu 21: Dd no di y khng lm qu tm i mu? A. C6H5NH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3 Cu 22: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. FeCl3 + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3Cl C. C6H5NH2 + 2Br2 3,5-Br2-C6H3NH2 + 2HBr D. C6H5NO2 + 3Fe +7HCl C6H5NH3Cl + 3FeCl2 + 2H2O Cu 23: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. CH3NH2 + O2 CO2 + N2 + H2O C. C6H5NH2 + 3Br2 2,4,6-Br3C6H2NH3Br + 2HBr D. C6H5NO2 + 3Fe +6HCl C6H5NH2 + 3FeCl2 + 2H2O Cu 24: Dd etylamin khng tc dng vi cht no sau y? A. axit HCl B. dd CuCl2 C. dd HNO3 D. Cu(OH)2 Cu 25: Pht biu no sai? A. Anilin l baz yu hn NH3 v nh hng ht electron ca nhn ln nhm NH2- bng hiu ng lin hp. B. Anilin khng lm i mu giy qu tm. C. Anilin t tan trong nc v gc C6H5- k nc. D. Nh tnh baz, anilin tc dng vi dd Brom. Cu 26: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B. Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. Cu 27: Cc hin tng no sau y m t khng chnh xc? A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh. Cu 28: Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen? A. Dd Brm B. dd HCl v dd NaOH C. dd HCl v dd brm D. dd NaOH v dd brm Cu 29: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng? A. Ha tan dd HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan dd Brm d, lc ly kt ta, dehalogen ha thu c anilin. C. Ha tan NaOH d v chit ly phn tan v thi CO2 vo sau n d thu c anilin tinh khit. D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen. Cu 30: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng? A. Ha tan dd HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan dd Brm d, lc ly kt ta, dehalogen ha thu c anilin. C. Ha tan NaOH d v chit ly phn tan v thi CO2 vo sau n d thu c anilin tinh khit. D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen Cu 31: Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen? A. Dd Brm B. dd HCl v dd NaOH C. dd HCl v dd brm D. dd NaOH v dd brm Cu 32: Cc hin tng no sau y m t khng chnh xc? Trang 16 Nguyn Trung Kin Lp 12A1

A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh. Cu 33: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B. Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. Cu 34: Pht biu no sai? A. Anilin l baz yu hn NH3 v nh hng ht electron ca nhn ln nhm NH2- bng hiu ng lin hp. B. Anilin khng lm i mu giy qu tm. C. Anilin t tan trong nc v gc C6H5- k nc. D. Nh tnh baz, anilin tc dng vi dd Brom. Cu 35: phn bit phenol, anilin, benzen, stiren ngi ta s dng ln lt cc thuc th no sau? A. Qu tm, brm B. dd NaOH v brom C. brm v qu tm D. dd HCl v qu tm Cu 36: Ancol v amin no sau y cng bc? a. (CH3)2CHOH v (CH3)2CHNH2 b. (CH3)3COH v (CH3)3CNH2 c. C6H5NHCH3 v C6H5CH(OH)CH3 d. (C6H5)2NH v C6H5CH2OH Cu 37: Cho dung dch etylamin (c mi khai) tc dng va vi cht X thy c kh bay ra v dung dch sau phn ng c mi thm ca ru. X l: a. CH3I b. CH3OH c. HNO2 d. HONH2 Cu 38: Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l: a. xiclohexan, C6H5-CH3 b. C2H2, C6H5-NO2 c. CH4, C6H5-NO2 d. C2H2, C6H5-CH3 Cu 39: Khi t chy cc ng ng ca metylamin thu c CO2 v H2O th t l v th tch K=VCO2:VH2O bin i nh th no theo s lng nguyn t cacbon trong phn t: a. 0,4<K<1 b. 0,25<K<1 c. 0,75<K<1 d. 1<K<1,5 Cu 40: Pht biu no di y v aminoaxit l khng ng? A. Aminoaxit l HCHC tp phc, phn t chc ng thi nhm amino v nhm cacboxyl. B. Hp cht H2NCOOH l aminoaxit n gin nht. C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-) D. Thng thng dng ion lng cc l dng tn ti chnh ca aminoaxit trong dung dch. Cu 41: Tn gi ca aminoaxit no di y l ng? A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)-COOH (valin) D. HOOC-(CH2)2-CH(NH2)-COOH (axit glutaric) Cu 42: C3H7O2N c my ng phn aminoaxit (Vi nhm amin bc nht)?A.5 B. 2 C. 3 D. 4 Cu 43: Khng nh no sau y khng ng v tnh cht vt l ca aminoaxit? A. Tt c u cht rn. B. Tt c u l tinh th, mu trng. C. Tt c u tan tt trong nc. D. Tt c u c nhit nng chy cao. Cu 44: Aminoaxetic khng th phn ng vi: A. Ancol B. Cu(OH)2 C. axit nitric D. Ba(OH)2 Cu 45: Cho cc dy chuyn ha : +NaOH +HCl +HCl NaOH Glixin A X; Glixin B Y X v Y ln lt l cht no? A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa Cu 46: Cho cc cht sau: (X1) C6H5NH2; (X2)CH3NH2 ; (X3) H2NCH2COOH; (X4) OOCCH2CH2CH(NH2)COOH (X5) H2NCH2CH2CH2CH2CH(NH2)COOH. Dd no lm qu tm ha xanh? A. X1, X2, X5 B. X2, X3,X4 C. X2, X5 D. X1, X5, X4 Cu 47: Dd no di y lm qu tm ha ? (1) NH2CH2COOH ; (2) Cl-NH3+-CH2COOH ; + (3) H3N CH2COO ; (4) H2N(CH2)2CH(NH2)COOH; (5) HOOCCH2CH2CH(NH2)COOH A. (3) B. (2) C. (2), (5) D. (1), (4) Cu 48: A l HCHC c cng thc phn t C5H11O2N. un A vi dd NaOH thu c mt hh cht c CTPT C2H4O2NNa v cht hu c B. Cho hi ca B qua CuO/t0 thu c cht C bn trong dd hn hp ca AgNO3 v NH3. CTCT ca A l: A. CH3(CH2)4NO2 B. H2NCH2COOCH2CH2CH3 C. H2NCH2COOCH(CH3)2 D. H2NCH2CH2COOC2H5
+

Nguyn Trung Kin Lp 12A1

Trang 17

Cu 49: Tn gi no sau y l ca peptit H2NCH2CONHCH(CH3)CONHCH2COOH? A. Gly-ala-gly B. Gly-gly-ala C. Ala-gly-gly D. Ala-gly-ala Cu 50: Trong bn ng nghim mt nhn cha ring bit tng dd: glyxin, lng trng trng, tinh bt, x phng. Thuc th phn bit ra mi dd l?A. Qu tm, dd it, Cu(OH)2. B. Qu tm, NaOH, Cu(OH)2 C. HCl, dd it, Cu(OH)2. D. HCl, dd it, NaOH. Cu 51: Cu no sau y khng ng? A. Khi nh axit HNO3 c vo lng trng trng thy xut hin mu vng. B. Phn t cc protein gm cc mch di polipeptit to nn. C. Protein rt t tan trong nc v d tan khi un nng. D. Khi cho Cu(OH)2 v lng trng trng thy xut hin mu tm xanh. Cu 52: Trong cc cht sau Cu, HCl, C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxxetic tc dng c vi nhng cht no? A. Tt c cc cht. B. HCl, KOH, CH3OH/ kh HCl. C. C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl D. Cu, HCl, KOH, Na2SO3, CH3OH/ kh HCl. Cu 53: Khi thy phn hon ton policapromit (policaproic) trong dd NaOH nng d thu c sn phm no di y? A. H2N(CH2)5COOH B. H2N(CH2)6COONa C. H2N(CH2)5COONa D. H2N(CH2)6COOH Cu 54: Protein (protein) c th c m t nh th no? A. Cht polime trng hp. B. Cht polieste. C. Cht polime ng trng hp. D. Cht polime ngng t (trng ngng). Cu 55: Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu v.C) B. Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc v -aminoaxit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axitnucleic,... Cu 56: Hp cht C3H7O2N tc dng c vi NaOH, H2SO4 v lm mt mu dd brom. CTCT ca hp cht? A. CH3CH(NH2)COOH B. H2NCH2CH2COOH C. CH2=CHCOONH4 D. CH2=CHCH2COONH4 Cu 57: Cho qu tm vo mi dd di y, dd lm qu tm ha xanh l? A. CH3COOH B. H2NCH2COOH C. H2NCH2(NH2)COOH D. HOOC-CH2-CH2-CH(NH2)COOH Cu58: Tn gi ca hp cht C6H5-CH2-CH(NH2)-COOH nh th no? A. Axitaminophenyl propionic. B. Axit -amino-3-phenyl propionic. C. Phenylalanin D. Axit 2-amino-3-phenyl propanoic. Cu 59: Cho dd qu tm vo 2 dd sau: (X) H2N-CH2-COOH; (Y) HOOC-CH(NH2)-CH2-COOH. Hin tng xy ra? A. X v Y khng i mu qu tm. B. X lm qu chuyn xanh, Y ha . C. X khng lm qu i mu, Y lm qu ha . D. X, Y lm qu ha Cu 60: Sn phm thu c khi thy phn hon ton t enang trong dd HCl d l: A. ClH3N(CH2)5COOH B.ClH3N(CH2)6COOH C. H2N(CH2)5COOH D. H2N(CH2)6COOH Cu 61: Khi un nng, cc phn t alanin (axit -aminopropionic) c th tc dng vi nhau to ra cc sn [-NH-CH- CO-]n phm no di y: [-CH2-CH- CO-]n [ -CH2-CH- CH2-]n A. [-NH-CH2- CO-]n B. C. CH3 D.
NH2 COOH

Cu 62: C cc pht biu sau v protein, Pht biu no ng. 1. Protein l hp cht cao phn t thin nhin c cu trc phc tp. 2. Protein ch c trong c th ngi v ng vt. 3. C th ngi v ng vt khng th tng hp c protein t nhng cht v c m ch tng hp c t cc aminoaxit. 4. Protein bn i vi nhit, i vi axit v vi kim. A. 1, 2 B. 2, 3 C. 1, 3 D. 3, 4 Cu 63: Axit -aminopropionic tc dng c vi tt c cc cht trong dy A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2NCH2COOH B. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, Cu C. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH D. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, NaCl Cu 64: Pht biu no sau y l khng ng v enzim? A. Hu ht cc enzim c bn cht protin Trang 18 Nguyn Trung Kin Lp 12A1

B. Enzim c kh nng lm xc tc cho qu trnh ha hc C. Mi enzim xc tc cho rt nhiu chuyn ha khc nhau D. Tc phn ng nh xc tc enzim thng nhanh hn n 109- 1011 ln Cu 65: Thy phn n cng protein n cng ta thu c cc cht no? A. Cc aminoaxit B. aminoaxit C. Hn hp cc aminoaxit D. Cc chui polipeptit Cu 66: M t hin tng no di y l khng chnh xc? A. Nh vi git axit nitric c vo dd lng trng trng thy kt ta mu vng. B. Trn ln lng trng trng, dd NaOH v mt t CuSO4 thy xut hin mu c trng . C. un nng dd lng trng trng thy hin tng ng t li, tch ra khi dd. D. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. Cu 67: Tn gi ca Sn phm v cht phn ng trong phn ng polime ha no sau y l ng? A. nH2N(CH2)5COOH (-HN(CH2)5CO-)n + n H2O B. nH2N(CH2)5COOH (-HN(CH2)6CO-)n + n H2O Axit -aminocaproic t nilon-6 Axit -aminoenantoic t enang C. nH2N(CH2)6COOH (-HN(CH2)6CO-)n + n H2O D. B, C ng Axit 7-aminoheptanoic t nilon-7 Cu 68: ng dng no sau y ca aminoaxit l khng ng? A. Aminoaxit thin nhin (hu ht l -aminoaxit) l c s kin to protein trong c th sng. B. Mui inatriglutamat l gia v cho thc n (gi l bt ngt hay m chnh) C. Axitglutanic l thuc b thn kinh, methionin l thuc b gan. D. Cc aminoaxit (nhm NH2 v s 6, 7...) l nguyn liu sn xut t nilon. Cu 69: Pht biu no sau y khng ng: A. Nhng hp cht hnh thnh bng cch ngng t 2 hay nhiu -aminoaxit c gi l peptit. B. Phn t c 2 nhm -CO-NH- c gi l i peptit, 3 nhm -CO-NH- c gi l tri peptit C. Cc peptit c t 10 n 50 n v aminoaxit cu thnh c gi l polipeptit. D. Trong mi phn t peptit, cc aminoaxit c sp xp theo mt th t xc nh. Cu 70: Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu v.C) B. Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc v -aminoaxit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axitnucleic,... Cu 71: Cc cht no sau y lng tnh? a) Metylaxetat b) amoni axetat c) glixin d) metyl amoni fomiat e) metyl amoni nitrat f) axit glutamic g) natriaxetat a. c, f b. b, d, e, f c. b, c, d, f d. a, b, c, d, f, g Cu 72: tiu ho casein (protein c trong sa) trc ht phi: a. thu phn cc lin kt glucozit b. thu phn cc lin kt peptit c. thu phn cc lin kt este d. kh cc cu ni isunfua Cu 73: nhn bt dung dch cc cht: Glixin, tinh bt, lng trng trng, ta tin hnh theo trnh t: a. dng qu tm, dng dd iot b. Dng dd iot, dng dd HNO3 c. dng qu tm, dng dd HNO3 d. dng Cu(OH)2, dng dd HNO3 Cu 74: HCHC X c cng thc C3H9O2N. Cho X phn ng vi dd NaOH, un nh thu c mui Y v kh Z lm xanh giy qu tm m. Cho Y tc dng vi NaOH rn, un nng c CH4, X c cng thc cu to no sau y? a. C2H5-COO-NH4 b. CH3-COO-NH4 c. CH3-COO-H3NCH3 d. b v c ng Cu 75: Mt hchc X c cng thc C3H7O2N. X phn ng vi dung dch brom, X tc dng vi dd NaOH v HCl. Cht hu c X c cng thc cu to: a. H2N CH = CH COOH b. CH2 = CH COONH4 c. NH2 CH2 CH2 COOH d. a v b ng. II. Trc nghim tnh ton: Cu 1: Phn tch nh lng 0,15 gam hp cht hu c X thy t l khi lng cc nguyn t C:H:O:N = 4,8:1:6,4:2,8. Nu phn tch nh lng m gam cht X th t l khi lng cc nguyn t C:H:O: N l bao nhiu? A. 4 : 1 : 6 : 2 B. 2,4 : 0,5 : 3,2 : 1,4 C. 1,2 : 1 : 1,6 : 2,8 D. 1,2 : 1,5 : 1,6 : 0,7 Cu 2: Ngi ta iu ch anilin bng cch nitro ha 500 g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu? Bit hiu sut phn ng mi giai on l 78%, 80%, 97,5%. Nguyn Trung Kin Lp 12A1 Trang 19

A. 346,7 g B. 362,7 g C. 463,4 g D. 358,7 g Cu 3: Mt HCHC X c t l khi lng C:H:O:N = 9: 1,75: 8: 3,5 tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br2. Cng thc phn t ca X v cng thc cu to ca X, Y ln lt l: A. C3H7O2N; H2N-C2H4-COOH; H2N-CH2-COO-CH3 B. C3H7O2N; H2N-C2H4-COOH; CH2=CH-COONH4 C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2 D. C3H5O2N; H2N-C2H2-COOH; CH C-COONH4 Cu 4: Este A c iu ch t amino axit B(ch cha C, H, O, N) v ru metylic. t chy hon ton 8,9 gam este A thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2(o ktc). Bit CTPT ca A trng vi CTGN. CTCT ca A l: A. NH2 - CH2 -COOCH3 B. NH2- CH(CH3)- COOCH3 C.CH3- CH(NH2)- COOCH3 D. NH2- CH(NH2) - COOCH3 Cu 5: Cht A c phn trm khi lng cc nguyn t C,H, O, N ln lt l 32,00%, 6,67%, 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng vi dd NaOH va tc dng vi dd HCl. CTCT ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 6: Cht A c phn trm cc nguyn t C,H, N, O ln lt l 40,45%, 7,86%, 15,73%, cn li l O. Khi lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd HCl, c ngun gc t thin nhin. Cng thc cu to ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 7: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: A. CH3(CH2)4NO2 B. NH2-CH2COO-CH2-CH2-CH3 C. NH-CH2-COO=CH(CH2)3 D. H2N-CH2-CH2-COOC2H5 Cu 8: Dung dch NH3 1M c = 0,43% . Hng s KB ca dung dch NH3 l: A. 1,85.10-5 B. 1,75.10-5 C. 1,6.10-5 D. -6 1,9.10 Cu 9: Mt hn hp gm 2 amin n chc no k tip nhau trong dy ng ng. Ly 21,4g hn hp cho vo 250ml dung dch FeCl3 (c d) thu c mt kt ta c khi lng bng khi lng hn hp trn. Loi b kt te ru thm t t dung dch AgNO3 v cho n khi phn ng kt thc th phi dng 1lt dd agNO3 1,5M. Cng thc phn t ca 2 amin trn l: a. CH3NH2 v C2H5NH2 b. C2H5NH2 v C3H7NH2 c. C3H7NH2 v C4H9NH2 d. tt c u sai Cu 10: t chy hon ton m g mt amin X bng lng khng kh va thu c 17,6g CO2 v 12,6g hi nc v 69,44 lt N2. Gi thit khng kh ch gm nit v oxi trong oxi chim 80% th tch. Cc th tch o ktc. Amin X c cng thc phn t l: a. C2H5NH2 b. C3H7NH2 c. CH3NH2 d. C4H9NH2 Cu 11: C 2 amin bc 1: A (ng ng ca anilin) v B ( ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra kh CO2, hi nc v 336cm3 kh nit (ktc). Khi t chy hon ton amin B cho VCO2:VH2O = 2: 3. Cng thc phn t ca 2 amin l: a. CH3C6H4NH2 v CH3CH2CH2NH2 b. C2H5C6H4NH2 v CH3CH2CH2NH2 c. CH3C6H4NH2 v CH3(CH2)4NH2 d. a v b ng Cu 12: Hp cht X l mt - aminoaxit. Cho 0,01 mol X tc dng vi 80ml dung dch HCl 0,125M. Sau em c cn thu c 1,835g mui. Phn t khi ca X bng bao nhiu ? a. 145vC b. 149vC c. 147vC d. 189vC Cu 13: un 100ml dung dch mt aminoaxit 0,2M tc dng va vi 80ml dd NaOH 0,25M. Sau phn ng ngi ta chng kh dung dch thu c 2,5g mui khan. Mt khc, li ly 100g dung dch aminoaxit ni trn c nng 20,6% phn ng va vi 400ml dung dch HCl 0,5M. CTPT ca aminoaxit: a. H2NCH2COOH b. H2NCH2CH2COOHc. H2N(CH2)3COOH d. a v c ng Cu 14: Cho hh M gm 2 amin no n chc bc 1 X v Y. ly 2,28g hh trn tc dng vi 300ml dung dch HCl th thu c 4,47g mui. S mol ca hai amin trong hh bng nhau. Nng mol ca dung dch HCl v tn ca X, Y ln lt l: a. 0,2M; metylamin; etylamin b. 0,06M; metylamin; etylamin Trang 20 Nguyn Trung Kin Lp 12A1

c. 0,2M; etylamin; propylamin d. 0,03M; etylamin; propylamin Cu 15: t chy hon ton mt amin thm X thu c 3,08g CO 2, 0,99g H2O v 336ml N2 (ktc). trung ho 0,1mol X cn 600ml dd HCl 0,5M. Cng thc phn t ca X l cng thc no? a. C7H11N b. C7H10N c. C7H11N3 d. C7H10N2 Cu 16: t chy hon ton mg hh 3 amin X, y, Z bng mt lng khng kh va (cha 1/5 th tch l oxi, cn li l nit) thu c 26,4g CO2, 18,9g H2O v 104,16 lt N2 (ktc). Gi tr ca m? a. 12g b. 13,5g c. 16g d. 14,72g Cu 17: Cho 3 hchc X, Y, z u cha cc nguyn t C, H, N. Thnh phn phn trm khi lng ca N trong phn t X, Y , Z ln lt l: 45,16%; 23,73%; 15,05%. Bit c X, Y, Z khi tc dng vi axit clohiric u cho mui amoni c dng cng thc R NH3Cl. Cng thc X, Y (mch thng), Z ln lt l: a. CH3 NH2, C2H5 NH2, C6H5 NH2 b. C2H5 NH2, CH3 CH2 CH2 NH2, C6H5 NH2 c. CH3 NH2, CH3 CH2 CH2 NH2, C6H5 NH2 d. CH3 NH2, CH3 CH2 CH2 NH2, C6H5 CH2 NH2 Cu 18: Mt mui X c cng thc C3H10O3N2. ly 14,64g X cho phn ng ht vi 120ml dung dch KOH 1M. C cn dd sau phn ng thu c phn hi v cht rn. Trong phn hi c mt cht hu c Y (bc 1). Trong phn rn ch l mt cht v c. Cng thc phn t ca Y l: a. C2H5NH2 b. C3H7OH c. C3H7NH2 d. CH3NH2 Cu 19: Hn hp X gm 2 amino axit no bc 1 Y v Z. Y cha 2 nhm axit, mt nhm amino; Z cha mt nhm axit, mt nhm amino. MY/MZ = 1,96. t chy 1mol Y hoc 1 mol Z th s mol CO 2 thu c nh hn 6. Cng thc cu to ca hai amino axit l: a. H2NCH2 CH(COOH) CH2 COOH v H2NCH2 COOH b. H2NCH2 CH(COOH) CH2 COOH v H2N [CH2]2 COOH c. H2N CH(COOH) CH2 COOH v H2NCH2 COOH d. H2N CH(COOH) CH2 COOH v H2N [CH2]2 COOH Cu 20: t chy 1mol amino axit H2N [CH2]n COOH phi cn s mol oxi l: a. (2n+3)/2 b. (6n+3)/2 c. (6n+3)/4 d. (2n+3)/4 Cu 21: Hp cht hu c X ch cha hai loi nhm chc amino v cacboxyl. Cho 100ml dung dch X 0,3M phn ng va vi 48ml dd NaOH 1,25M. Sau em c cn dung dch thu c c 5,31g mui khan. Bt X c mch cacbon khng phn nhnh v nhm NH2 v tr alpha. CTCT ca X: a. CH3CH(NH2)COOH b. CH3C(NH2)(COOH)2 c. CH3CH2C(NH2)(COOH)2 d. CH3CH2CH(NH2)COOH Cu 22: Thc hin phn ng este gia amino axit X v ancol CH3OH thu c este Y c t khi hi so vi khng kh bng 3,069. CTCT ca X: a. H2N-CH2-COOH b. H2N-CH2-CH2-COOH c. CH2-CH(NH2)-COOH d. H2N(CH2)3-COOH Cu 23: t chy ht a mol mt amino axit X n chc bng oxi va ri ngng t ht hi nc c 2,5 mol hh CO2 v N2. CTPT ca X: a. C5H11NO2 b. C3H7N2O4 c. C3H7NO2 d. C2H5NO2 Cu 24: Ly 14,6g mt ipeptit to ra t glixin v alanin cho tc dng va vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng: a. 0,1 lit b. 0,2 lt c. 0,3 lt d. 0,4 lt
Amin va anilin Bi tp t lun. Cu 1: Vit cng thc cu to c th c ca cc amin c cng thc phn t C 3H9N, C4H11N. Gi tn v ch r bc ca chng. Cu 2: Vit phn ng gia cc cp hp cht sau. CH3NH2 v HCl, CH3NH2 v H2SO4 (t l mol l 1:1), CH3NH2 v H2SO4 (t l mol l 2:1), CH3NH2 v CH3COOH. Cu 3: So snh tnh baz ca cc cht sau: NaOH, NH3, CH3NH2, C2H5NH2, C6H5NH2 Cu 4: Nhn bit cc cht ng trong cc bnh mt nhn sau: a. phenol, anilin, benzen, styren b. anilin, metyl amin, axit axetic, anehit axetic

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Cu 5: t chy hon ton 1,605 gam hp cht A thu c 4,62 gam CO2 v 1,215 gam H2O v 168 Cm3 N2 (ltc). a. Tnh thnh phn % cc nguyn t. b. Bit 3,21 gam hp cht A phn ng ht 30 ml dung dch HCl 1M. Vit cng thc cu to c th c ca A. Bit A l ng ng ca anilin. Cu 6: Hn hp A gm 4 hp cht hu c no, n chc l ng phn ca nhau. Bn hp cht u d phn ng vi dung dch HCl. Phn t mi cht u cha cc nguyn t C, H, N (chim 23,7% v khi lng). Vit cng thc cu to ca 4 hp cht v tnh khi lng hn hp A, bit t chy hn hp A cho 4,48 lit N2 (ktc). Cu 7: (i hc khi A-2006). t chy hon ton 1,18 gam amin n chc B bng mt lng khng kh va . Dn ton b hn hp kh sau phn ng vo bnh ng dung dch Ca(OH)2 d, c 6 gam kt ta v c 9,632 lt kh (ktc) duy nht thot ra khi bnh. a. Tm cng thc phn t ca B b. Vit cc cng thc cu to c th c ca B v gi tn. (bit khng kh c 20% O 2 v 80% N2 v th tch) Bi tp trc nghim. Cu 8: Cho cc cu sau cu no sai. a. Cc amin c tnh baz b. Cc amin u l xanh qy tm c. amin l nhng hp cht hu c c cu thnh bng cch thay th mt hay nhiu nguyn t hiro trong phn t amoniac bi mt hay nhiu gc hyrocacbon. d. bc ca amin l s nguyn t H trong amonic b thay th bi gc hyrocacbon. Cu 9: ( i hc khi A-2007) Pht biu khng ng l. a. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng v dung dch HCl li thu c phenol. b. axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. c. dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to c cho tc dng vi dung dch NaOH li thu c natri phenolat. d. anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH l thu c anilin

Cu 10: So snh tnh baz ca cc cht sau: CH3NH2, (CH3)2 NH, NH3 a. CH3NH2 < (CH3)2 NH < NH3 b. NH3 < CH3NH2 < (CH3)2 NH c. NH3 < (CH3)2 NH < CH3NH2 d. (CH3)2 NH < CH3NH2 < NH3 Cu 11: So snh tnh baz ca cc cht sau: CH3NH2, C2H5NH2, NH3, C6H5NH2 a. CH3NH2 < C2H5NH2 < NH3 < C6H5NH2 b. NH3 < C6H5NH2 < CH3NH2 < C2H5NH2 c. C6H5NH2 < NH3 < CH3NH2 < C2H5NH2 d. C6H5NH2 < NH3 < C2H5NH2< CH3NH2 Cu 12: (i hc khi B-2007) Dy gm cc cht u lm giy qy tm m chuyn sang mu xanh l: a. metyl amin, amoniac, natri axetat b. anilin, amoniac, natri hiroxit c. amoni clorua, metyl amin, natri hiroxit d. anilin, metyl amin, amoniac. Cu 13: Mt amin c cng thc phn t l C3H9N s ng phn ca amin l: a. 2 b. 3 c. 4 d. 5 Cu 14: ( thi tt nghip- 2007) S ng phn amin bc 1 ng vi cng thc phn t l C3H9N l. a. 4 b. 3 c. 5

d. 2

Cu 15: Mt amin c cng thc phn t l C4H11N, s ng phn ca amin l: a. 7 b. 8 c. 9 d. 10 Cu 16: Mt amin c cng thc phn t l C4H11N, s ng phn amin bc I l:

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a. 3

b. 4

c. 5

d. 6

Cu 17: (Cao ng khi A-2009) S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l a. 4 b. 5. c. 2 d. 3. Cu 18: (i hc khi A-2009) Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l a. 5. b. 8. c. 7. d. 4. Cu 19: Cho cc cu sau cu no khng ng: a. Cc amin u c tnh baz. b. Tnh baz ca tt c cc amin u mnh hn NH3. c. Anilin c tnh baz yu hn NH3. d. Tt c cc amin n chc u cha mt s l nguyn t H trong phn t. Cu 21: S d anilin c tnh baz yu hn NH3 l do: a. Nhm NH2 cn mt cp electron cha lin kt. b. phn t khi ca anilin ln hn NH2. c. Nhm NH2 c tc dng y electron v pha bng benzen lm gim mt electron ca nguyn t N. d. Gc phnyl c nh hng lm gim mt electron ca nguyn t N. Cu 21b: (i hc khi A-2009) Pht biu no sau y l ng? a. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. b. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. c. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. d. Benzen lm mt mu nc brom nhit thng. Cu 22: Cho s phn ng sau: A + HNO3, B + H xt H2SO4 dac C6H5NH2 vy cng thc phn t ca A l: a. C6H6 b. C6H5NH3Cl c. C6H5CH3 d. tt c u sai Cu 23: nhn bit cc cht: CH3NH2, C6H5NH2, C6H5OH, CH3COOH trong cc bnh mt nhn ngi ta dng. a. dung dch HCl, v qy tm b. qy tm v dung dch Br2 c. dung dch NaOH v dung dch Br2 d. Tt c u ng. Cu 24: (i hc khi B-2007) C 3 cht lng benzen, anilin, stiren ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l. a. dung dch NaOH b. giy qy c. dung dch d. nc brom phenolphtalein Cu 25: (i hc khi A-2009) C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? a. 4. b. 5. c. 3. d. 6. Cu 26: t chy hon ton hn hp hai amin bc mt mch h, no, n chc, k tip nhau trong cng dy ng ng thu c CO2 v H2O vi t l s mol nCO2:nH2O = 1: 2. Hai amin c cng thc phn t ln lt l a. C2H5NH2 v C3H7NH2 b. CH3NH2 v C2H5NH2 c. C3H7NH2 v C4H9NH2 d. C4H9NH2 v C5H11NH2 Cu 27: t chy hon ton hn hp 2 amin no n chc, l ng ng lin tip thu c 2,24 lit kh CO2 (ktc) v 3,6 gam H2O. Cng thc phn t ca 2 amin l: a. CH3NH2 v C2H5NH2 b. C2H5NH2 v C3H7NH2 c. C3H7NH2 v C4H9NH2 d. Tt c u sai. Cu 28: Khi t chy hon ton mt amin n chc X, ngi ta thu c 10,125 gam H2O v 8,4 lit kh CO2 v 1,4 lit N2 (ktc). Cng thc phn t ca amin l: a. C4H11N b. C2H7N c. C3H9N d. C5H13N

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Cu 29: Khi cho 13,95 gam anilin tc dng hon ton vi 0,2 lit dung dch HCl 1M th khi lng ca mui phenylamoniclorua thu c l a. 25,9 b. 20,25 c. 19,425 d. 27,15 Cu 30: ( thi tt nghip -2007) Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l. a. 7,65 gam b. 0,85 gam c. 8,10 gam d. 8,15 gam Cu 31: t chy hon ton m gam mt amin X bng mt lng khng kh va thu c 17,6 gam CO2 v 12,6 gam H2O v 69,44 lit N2 (ktc). Gi thit khng kh ch gm N 2 v O2, trong oxi chim 20% th tch khng kh . Vy X c cng thc l. a. C4H11N b. C2H7N c. C3H9N d. CH5N Cu 32: t chy hon ton 1,18 gam amin n chc B bng mt lng khng kh va , dn ton b hn hp kh sau phn ng vo bnh Ca(OH)2 d, c 6 gam kt ta v c 9,632 lit kh (dktc) duy nht thot ra khi bnh. Xc nh cng thc phn t ca B a. C4H11N b. C2H7N c. C3H9N d. CH5N Cu 33: (i hc khi A-2007) Khi t chy hon ton mt amin n chc X, thu c 8,4 lit kh CO2, 1,4 lit kh N2 (cc th tch kh o iu kin tiu chun) v 10,125 gam H2O. Cng thc phn t ca X l. a. C3H7N b. C3H9N c. C4H9N d. C2H7N Cu 34: (Cao ng khi A-2007) trung ha 25 gam dung dch mt amin n chc X nng 12,4 % cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l. a. CH5N b. C2H7N c. C3H7N d. C3H5N Cu 35: (Cao ng khi A-2008) Cho dy cc cht: Phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi dung dch NaOH l. a. 3 b. 4 c. 1 d. 2 Cu 36: (Cao ng khi A-2008) Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y thu c 9,55 gam mui khan. S cng thc cu to tng ng vi phn t ca X l. a. 5 b. 4 c. 3 d. 2 Cu 37: (i hc khi B-2008) Cht phn ng c vi dung dch FeCl3 cho kt ta l. a. CH3NH2 b. CH3COOH c. CH3OH d. CH3COOCH3 Cu 38: (i hc khi B-2009) Ngi ta iu ch anilin bng s sau: H 2 SO4dac , HNO 3 Fe + Benzen dac nitrobenzen HCl anilin. ,t
O

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l a. 111,6 gam. b. 55,8 gam. c. 93,0 gam. d. 186,0 gam. I. Trc nghim l thuyt: Cu 1: 1: Cng thc ca amin cha 15,05% khi lng nit l cng thc no sau? A. C2H5NH2 B. (CH3)2NH C. C6H5NH2 D. (CH3)3N Cu 2: Cng thc phn t C3H9N ng vi bao nhiu ng phn? A. 5 B. 4 C. 3 D. 2 Cu 3: Cho amin c cu to: CH3-CH(CH3)-NH2 . Chn tn gi khng ng? A. Prop-1-ylamin B. Propan-2-amin C. isoproylamin D. Prop-2-ylamin Cu 4: Tn gi ng C6H5NH2 ng? A. Benzyl amoni B. Phenyl amoni C. Hexylamin D. Anilin Cu 5: Hp cht hu c X mch h cha cc nguyn t C, H, N trong c 23,72% khi lng N. X tc dng vi HCl theo t l mol 1:1. Chn cu pht biu sai? A. X l hp cht amin. B. Cu to ca X l amin no, n chc C. Nu cng thc X l CxHyNz th z = 1

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Nguyn Trung Kin Lp 12A1

D. Nu cng thc X l CxHyNz th : 12x - y = 45 Cu 6: Pht biu no sau y khng ng? A. Amin c cu to bng cch thay th H ca amoniac bng 1 hay nhiu gc H-C. B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amin. C. Ty thuc vo gc H-C, c th phn bit thnh amin thnh amin no, cha no v thm. D. Amin c t 2 nguyn t cacbon trong phn t bt u xut hin ng phn. Cu 7: Amin no di y l amin bc 2? A. CH3-CH2NH2 B. CH3-CHNH2-CH3 C. CH3-NH-CH3 D. CH3-NCH3-CH2CH3 Cu 8: Cng thc no di y l cng thc chung ca dy ng ng amin thm (cha 1 vng bezen) n chc bc nht? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 Cu 9: Tn gi cc amin no sau y l khng ng? A. CH3-NH-CH3 imetylamin B. CH3-CH2-CH2NH2 n-propylamin C. CH3CH(CH3)-NH2 isopropylamin D. C6H5NH2 alanin Cu 10: Amin no di y c 4 ng phn cu to?A. C2H7N B. C3H9N C. C4H11N D. C5H13N Cu 11: Pht biu no sau y v tnh cht vt l ca amin l khng ng? A. Metyl-, etyl-, imetyl-, trimetylamin l nhng cht kh, d tan trong nc. B. Cc amin kh c mi tng t amoniac, c. C. Anilin l cht lng, kh tan trong nc, mu en. D. tan ca amin gim dn khi s nguyn t cacbon trong phn t tng. Cu 12: Cc gii thch v quan h cu trc, tnh cht no sau y khng hp l? A. Do c cp electron t do trn nguyn t N m amin c tnh baz. B. Do nhm NH2- y e nn anilin d tham gia vo phn ng th vo nhn thm hn v u tin v tr o- v pC. Tnh baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. D. Vi amin R-NH2, gc R ht electron lm tng mnh ca tnh baz v ngc li. Cu 13: Nhn xt no di y khng ng? A. Phenol l axit cn anilin l baz. B. Dd phenol lm qu tm ha cn dd anilin lm qu tm ha xanh. C. Phenol v anilin u d tham gia phn ng th v u to kt ta trng vi dd brom. D. Phenol v anilin u kh tham gia phn ng cng v u to hp cht vng no khi cng vi hiro. Cu 14: S d anilin c tnh baz yu hn NH3 l do yu t no? A. Nhm NH2- cn 1 cp electron t do cha tham gia lin kt. B. Nhm NH2- c tc dng y electron v pha vng benzen lm gim mt electron ca N. C. Gc phenyl c nh hng lm gim mt electron ca nguyn t N. D. Phn t khi ca anilin ln hn so vi NH3 Cu 15: Hy ch ra iu sai trong cc iu sau? A. Cc amin u c tnh baz B. Tnh baz ca anilin yu hn NH3 C. Amin tc dng vi axit cho ra mui D. Amin l hp cht hu c c tnh cht lng tnh Cu 16: Dd etylamin tc dng vi dd nc ca cht no sau y? A. NaOH B. NH3 C. NaCl D. FeCl3 v H2SO4 Cu 17: Hp cht no di y c tnh baz yu nht? A. Anilin B. Metylamin C. Amoniac D. imetylamin Cu 18: Cht no di y c tnh baz mnh nht? A. NH3 B. CH3CONH2 C. CH3CH2CH2OH D. CH3CH2NH2 Cu 19: Sp xp cc cht sau y theo tnh baz gim dn? (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. 1>3>5>4>2>6 B. 6>4>3>5>1>2 C. 5>4>2>1>3>6 D. 5>4>2>6>1>3 Cu 20: Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl C. Fe3+ + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3+ D. CH3NH2 + HNO2 CH3OH + N2 + H2O Cu 21: Dd no di y khng lm qu tm i mu? A. C6H5NH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3

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Cu 22: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. FeCl3 + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3Cl C. C6H5NH2 + 2Br2 3,5-Br2-C6H3NH2 + 2HBr D. C6H5NO2 + 3Fe +7HCl C6H5NH3Cl + 3FeCl2 + 2H2O Cu 23: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. CH3NH2 + O2 CO2 + N2 + H2O C. C6H5NH2 + 3Br2 2,4,6-Br3C6H2NH3Br + 2HBr D. C6H5NO2 + 3Fe +6HCl C6H5NH2 + 3FeCl2 + 2H2O Cu 24: Dd etylamin khng tc dng vi cht no sau y? A. axit HCl B. dd CuCl2 D. Cu(OH)2 s C. dd HNO3 Cu 25: Pht biu no sai? A. Anilin l baz yu hn NH3 v nh hng ht electron ca nhn ln nhm NH2- bng hiu ng lin hp. B. Anilin khng lm i mu giy qu tm. C. Anilin t tan trong nc v gc C6H5- k nc. D. Nh tnh baz, anilin tc dng vi dd Brom. Cu 26: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B.Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. Cu 27: Cc hin tng no sau y m t khng chnh xc? A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh. Cu 28: Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen? A. Dd Brm B. dd HCl v dd NaOH C. dd HCl v dd brm D. dd NaOH v dd brm Cu 29: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng? A. Ha tan dd HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan dd Brm d, lc ly kt ta, dehalogen ha thu c anilin. C. Ha tan NaOH d v chit ly phn tan v thi CO2 vo sau n d thu c anilin tinh khit. D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen. Cu 30: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng? A. Ha tan dd HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan dd Brm d, lc ly kt ta, dehalogen ha thu c anilin. C. Ha tan NaOH d v chit ly phn tan v thi CO2 vo sau n d thu c anilin tinh khit. D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen Cu 31: Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen? A. Dd Brm B. dd HCl v dd NaOH C. dd HCl v dd brm D. dd NaOH v dd brm Cu 32: Cc hin tng no sau y m t khng chnh xc? A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh. Cu 33: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B. Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. Cu 34: Pht biu no sai? A. Anilin l baz yu hn NH3 v nh hng ht electron ca nhn ln nhm NH2- bng hiu ng lin hp. B. Anilin khng lm i mu giy qu tm. C. Anilin t tan trong nc v gc C6H5- k nc. D. Nh tnh baz, anilin tc dng vi dd Brom. Cu 35: phn bit phenol, anilin, benzen, stiren ngi ta s dng ln lt cc thuc th no sau? A. Qu tm, brm B. dd NaOH v brom C. brm v qu tm D. dd HCl v qu tm Cu 36: Ancol v amin no sau y cng bc? a. (CH3)2CHOH v (CH3)2CHNH2 b. (CH3)3COH v (CH3)3CNH2 c. C6H5NHCH3 v C6H5CH(OH)CH3 d. (C6H5)2NH v C6H5CH2OH

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Cu 37: Cho dung dch etylamin (c mi khai) tc dng va vi cht X thy c kh bay ra v dung dch sau phn ng c mi thm ca ru. X l: a. CH3I b. CH3OH c. HNO2 d. HONH2 Cu 38: Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l: a. xiclohexan, C6H5-CH3 b. C2H2, C6H5-NO2 c. CH4, C6H5-NO2 d. C2H2, C6H5-CH3 Cu 39: Khi t chy cc ng ng ca metylamin thu c CO 2 v H2O th t l v th tch K=VCO2:VH2O bin i nh th no theo s lng nguyn t cacbon trong phn t: a. 0,4<K<1 b. 0,25<K<1 c. 0,75<K<1 d. 1<K<1,5 Cu 40: Pht biu no di y v aminoaxit l khng ng? A. Aminoaxit l HCHC tp phc, phn t chc ng thi nhm amino v nhm cacboxyl. B. Hp cht H2NCOOH l aminoaxit n gin nht. C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-) D. Thng thng dng ion lng cc l dng tn ti chnh ca aminoaxit trong dung dch. Cu 41: Tn gi ca aminoaxit no di y l ng? A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)-COOH (valin) D. HOOC-(CH2)2-CH(NH2)-COOH (axit glutaric) Cu 42: C3H7O2N c my ng phn aminoaxit (Vi nhm amin bc nht)? A.5 B. 2 C. 3 D. 4 Cu 43: Khng nh no sau y khng ng v tnh cht vt l ca aminoaxit? A. Tt c u cht rn. B. Tt c u l tinh th, mu trng. C. Tt c u tan tt trong nc. D. Tt c u c nhit nng chy cao. Cu 44: Aminoaxetic khng th phn ng vi: A. Ancol B. Cu(OH)2 C. axit nitric D. Ba(OH)2 Cu 45: Cho cc dy chuyn ha : +NaOH +HCl +HCl NaOH Glixin A X; Glixin B Y X v Y ln lt l cht no? A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa Cu 46: Cho cc cht sau: (X1) C6H5NH2; (X2)CH3NH2 ; (X3) H2NCH2COOH; (X4) OOCCH2CH2CH(NH2)COOH (X5) H2NCH2CH2CH2CH2CH(NH2)COOH. Dd no lm qu tm ha xanh? A. X1, X2, X5 B. X2, X3,X4 C. X2, X5 D. X1, X5, X4 Cu 47: Dd no di y lm qu tm ha ? (1) NH2CH2COOH ; (2) Cl-NH3+-CH2COOH ; + (3) H3N CH2COO ; (4) H2N(CH2)2CH(NH2)COOH; (5) HOOCCH2CH2CH(NH2)COOH A. (3) B. (2) C. (2), (5) D. (1), (4) Cu 48: A l HCHC c cng thc phn t C5H11O2N. un A vi dd NaOH thu c mt hh cht c CTPT C 2H4O2NNa v cht hu c B. Cho hi ca B qua CuO/t0 thu c cht C bn trong dd hn hp ca AgNO3 v NH3. CTCT ca A l: A. CH3(CH2)4NO2 B. H2NCH2COOCH2CH2CH3 C. H2NCH2COOCH(CH3)2 D. H2NCH2CH2COOC2H5 Cu 49: Tn gi no sau y l ca peptit H2NCH2CONHCH(CH3)CONHCH2COOH? A. Gly-ala-gly B. Gly-gly-ala C. Ala-gly-gly D. Ala-gly-ala Cu 50: Trong bn ng nghim mt nhn cha ring bit tng dd: glyxin, lng trng trng, tinh bt, x phng. Thuc th phn bit ra mi dd l? A. Qu tm, dd it, Cu(OH)2. B. Qu tm, NaOH, Cu(OH)2 C. HCl, dd it, Cu(OH)2. D. HCl, dd it, NaOH. Cu 51: Cu no sau y khng ng? A. Khi nh axit HNO3 c vo lng trng trng thy xut hin mu vng. B. Phn t cc protein gm cc mch di polipeptit to nn. C. Protein rt t tan trong nc v d tan khi un nng. D. Khi cho Cu(OH)2 v lng trng trng thy xut hin mu tm xanh.
+

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Cu 52: Trong cc cht sau Cu, HCl, C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxxetic tc dng c vi nhng cht no? A. Tt c cc cht. B. HCl, KOH, CH3OH/ kh HCl. C. C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl D. Cu, HCl, KOH, Na2SO3, CH3OH/ kh HCl. Cu 53: Khi thy phn hon ton policapromit (policaproic) trong dd NaOH nng d thu c sn phm no di y? A. H2N(CH2)5COOH B. H2N(CH2)6COONa C. H2N(CH2)5COONa D. H2N(CH2)6COOH Cu 54: Protein (protein) c th c m t nh th no? A. Cht polime trng hp. B. Cht polieste. C. Cht polime ng trng hp. D. Cht polime ngng t (trng ngng). Cu 55: Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu v.C) B. Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc v -aminoaxit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axitnucleic,... Cu 56: Hp cht C3H7O2N tc dng c vi NaOH, H2SO4 v lm mt mu dd brom. CTCT ca hp cht? A. CH3CH(NH2)COOH B. H2NCH2CH2COOH C. CH2=CHCOONH4 D.CH2=CH-CH2COONH4 Cu 57: Cho qu tm vo mi dd di y, dd lm qu tm ha xanh l? A. CH3COOH B. H2NCH2COOH C. H2NCH2(NH2)COOH D. HOOC-CH2-CH2-CH(NH2)-COOH Cu58: Tn gi ca hp cht C6H5-CH2-CH(NH2)-COOH nh th no? A. Axitaminophenyl propionic. B. Axit -amino-3-phenyl propionic. C. Phenylalanin D. Axit 2-amino-3-phenyl propanoic. Cu 59: Cho dd qu tm vo 2 dd sau: (X) H2N-CH2-COOH; (Y) HOOC-CH(NH2)-CH2-COOH. Hin tng xy ra? A. X v Y khng i mu qu tm. B. X lm qu chuyn xanh, Y ha . C. X khng lm qu i mu, Y lm qu ha . D. X, Y lm qu ha Cu 60: Sn phm thu c khi thy phn hon ton t enang trong dd HCl d l: A. ClH3N(CH2)5COOH B.ClH3N(CH2)6COOH C. H2N(CH2)5COOH D. H2N(CH2)6COOH Cu 62: C cc pht biu sau v protein, Pht biu no ng. 1. Protein l hp cht cao phn t thin nhin c cu trc phc tp. 2. Protein ch c trong c th ngi v ng vt. 3. C th ngi v ng vt khng th tng hp c protein t nhng cht v c m ch tng hp c t cc aminoaxit. 4. Protein bn i vi nhit, i vi axit v vi kim. A. 1, 2 B. 2, 3 C. 1, 3 D. 3, 4 Cu 63: Axit -aminopropionic tc dng c vi tt c cc cht trong dy A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2NCH2COOH B. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, Cu C. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH D. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, NaCl Cu 64: Pht biu no sau y l khng ng v enzim? A. Hu ht cc enzim c bn cht protin B. Enzim c kh nng lm xc tc cho qu trnh ha hc C. Mi enzim xc tc cho rt nhiu chuyn ha khc nhau D. Tc phn ng nh xc tc enzim thng nhanh hn n 109- 1011 ln Cu 65: Thy phn n cng protein n cng ta thu c cc cht no? A. Cc aminoaxit B. aminoaxit C. Hn hp cc aminoaxit D. Cc chui polipeptit Cu 66: M t hin tng no di y l khng chnh xc? A. Nh vi git axit nitric c vo dd lng trng trng thy kt ta mu vng. B. Trn ln lng trng trng, dd NaOH v mt t CuSO4 thy xut hin mu c trng .

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C. un nng dd lng trng trng thy hin tng ng t li, tch ra khi dd. D. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. Cu 67: Tn gi ca Sn phm v cht phn ng trong phn ng polime ha no sau y l ng? A. nH2N(CH2)5COOH (-HN(CH2)5CO-)n + n H2O Axit -aminocaproic t nilon-6 B. nH2N(CH2)5COOH (-HN(CH2)6CO-)n + n H2O Axit -aminoenantoic t enang C. nH2N(CH2)6COOH (-HN(CH2)6CO-)n + n H2O Axit 7-aminoheptanoic t nilon-7 D. B, C ng Cu 68: ng dng no sau y ca aminoaxit l khng ng? A. Aminoaxit thin nhin (hu ht l -aminoaxit) l c s kin to protein trong c th sng. B. Mui inatriglutamat l gia v cho thc n (gi l bt ngt hay m chnh) C. Axitglutanic l thuc b thn kinh, methionin l thuc b gan. D. Cc aminoaxit (nhm NH2 v s 6, 7...) l nguyn liu sn xut t nilon. Cu 69: Pht biu no sau y khng ng: A. Nhng hp cht hnh thnh bng cch ngng t 2 hay nhiu -aminoaxit c gi l peptit. B. Phn t c 2 nhm -CO-NH- c gi l i peptit, 3 nhm -CO-NH- c gi l tri peptit C. Cc peptit c t 10 n 50 n v aminoaxit cu thnh c gi l polipeptit. D. Trong mi phn t peptit, cc aminoaxit c sp xp theo mt th t xc nh. Cu 70: Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu v.C) B. Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc v -aminoaxit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axitnucleic,... Cu 71: Cc cht no sau y lng tnh? a) Metylaxetat b) amoni axetat c) glixin d) metyl amoni fomiat e) metyl amoni nitrat f) axit glutamic g) natriaxetat A. c, f B. b, d, e, f C. b, c, d, f D. a, b, c, d, f, g Cu 72: tiu ho casein (protein c trong sa) trc ht phi: a. thu phn cc lin kt glucozit b. thu phn cc lin kt peptit c. thu phn cc lin kt este d. kh cc cu ni isunfua Cu 73: nhn bt dung dch cc cht: Glixin, tinh bt, lng trng trng, ta tin hnh theo trnh t: a. dng qu tm, dng dd iot b. Dng dd iot, dng dd HNO3 c. dng qu tm, dng dd HNO3 d. dng Cu(OH)2, dng dd HNO3 Cu 74: HCHC X c cng thc C3H9O2N. Cho X phn ng vi dd NaOH, un nh thu c mui Y v kh Z lm xanh giy qu tm m. Cho Y tc dng vi NaOH rn, un nng c CH4, X c cng thc cu to no sau y? a. C2H5-COO-NH4 b. CH3-COO-NH4 c. CH3-COO-H3NCH3 d. b v c ng Cu 75: Mt hchc X c cng thc C3H7O2N. X phn ng vi dung dch brom, X tc dng vi dd NaOH v HCl. Cht hu c X c cng thc cu to: a. H2N CH = CH COOH b. CH2 = CH COONH4 c. NH2 CH2 CH2 COOH d. a v b ng. II. Trc nghim tnh ton: Cu 1: Phn tch nh lng 0,15 gam hp cht hu c X thy t l khi lng cc nguyn t C:H:O:N = 4,8:1:6,4:2,8. Nu phn tch nh lng m gam cht X th t l khi lng cc nguyn t C:H:O: N l bao nhiu? A. 4 : 1 : 6 : 2 B. 2,4 : 0,5 : 3,2 : 1,4 C. 1,2 : 1 : 1,6 : 2,8 D. 1,2 : 1,5 : 1,6 : 0,7 Cu 2: Ngi ta iu ch anilin bng cch nitro ha 500 g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu? Bit hiu sut phn ng mi giai on l 78%, 80%, 97,5%. A. 346,7 g B. 362,7 g C. 463,4 g D. 358,7 g Cu 3: Mt HCHC X c t l khi lng C:H:O:N = 9: 1,75: 8: 3,5 tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br2. Cng thc phn t ca X v cng thc cu to ca X, Y ln lt l: A. C3H7O2N; H2N-C2H4-COOH; H2N-CH2-COO-CH3 B. C3H7O2N; H2N-C2H4-COOH; CH2=CH-COONH4 C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2 D. C3H5O2N; H2N-C2H2-COOH; CH C-COONH4 Cu 4: Este A c iu ch t amino axit B(ch cha C, H, O, N) v ru metylic. t chy hon ton 8,9 gam este A thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2(o ktc). Bit CTPT ca A trng vi CTGN. CTCT ca A l: A. NH2 - CH2 -COOCH3 B. NH2- CH(CH3)- COOCH3 C.CH3- CH(NH2)-COOCH3 D.NH2-CH(NH2) - COOCH3

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Cu 5: Cht A c phn trm khi lng cc nguyn t C,H, O, N ln lt l 32,00%, 6,67%, 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng vi dd NaOH va tc dng vi dd HCl. CTCT ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 6: Cht A c phn trm cc nguyn t C,H, N, O ln lt l 40,45%, 7,86%, 15,73%, cn li l O. Khi lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd HCl, c ngun gc t thin nhin. Cng thc cu to ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 7: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: A. CH3(CH2)4NO2 B. NH2-CH2COO-CH2-CH2-CH3 C. NH-CH2-COO=CH(CH2)3 D.H2N-CH2-CH2-OOC2H5 Cu 8: Dung dch NH3 1M c = 0,43 % . Hng s KB ca dung dch NH3 l: A. 1,85.10-5 B. 1,75.10-5 C. 1,6.10-5 D. 1,9.10-6 Cu 9: Mt hn hp gm 2 amin n chc no k tip nhau trong dy ng ng. Ly 21,4g hn hp cho vo 250ml dung dch FeCl3 (c d) thu c mt kt ta c khi lng bng khi lng hn hp trn. Loi b kt te ru thm t t dung dch AgNO3 v cho n khi phn ng kt thc th phi dng 1lt dd agNO 3 1,5M. Cng thc phn t ca 2 amin trn l: a. CH3NH2 v C2H5NH2 b. C2H5NH2 v C3H7NH2 c. C3H7NH2 v C4H9NH2 d. tt c u sai Cu 10: t chy hon ton m g mt amin X bng lng khng kh va thu c 17,6g CO 2 v 12,6g hi nc v 69,44 lt N2. Gi thit khng kh ch gm nit v oxi trong oxi chim 80% th tch. Cc th tch o ktc. Amin X c cng thc phn t l: a. C2H5NH2 b. C3H7NH2 c. CH3NH2 d. C4H9NH2 Cu 11: C 2 amin bc 1: A (ng ng ca anilin) v B ( ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra kh CO2, hi nc v 336cm3 kh nit (ktc). Khi t chy hon ton amin B cho VCO 2:VH2O = 2: 3. Cng thc phn t ca 2 amin l: a. CH3C6H4NH2 v CH3CH2CH2NH2 b. C2H5C6H4NH2 v CH3CH2CH2NH2 c. CH3C6H4NH2 v CH3(CH2)4NH2 d. a v b ng Cu 12: Hp cht X l mt - aminoaxit. Cho 0,01 mol X tc dng vi 80ml dung dch HCl 0,125M. Sau em c cn thu c 1,835g mui. Phn t khi ca X bng bao nhiu ? a. 145vC b. 149vC c. 147vC d. 189vC Cu 13: un 100ml dung dch mt aminoaxit 0,2M tc dng va vi 80ml dd NaOH 0,25M. Sau phn ng ngi ta chng kh dung dch thu c 2,5g mui khan. Mt khc, li ly 100g dung dch aminoaxit ni trn c nng 20,6% phn ng va vi 400ml dung dch HCl 0,5M. CTPT ca aminoaxit: a. H2NCH2COOH b. H2NCH2CH2COOH c. H2N(CH2)3COOH d. a v c ng Cu 14: Cho hh M gm 2 amin no n chc bc 1 X v Y. ly 2,28g hh trn tc dng vi 300ml dung dch HCl th thu c 4,47g mui. S mol ca hai amin trong hh bng nhau. Nng mol ca dung dch HCl v tn ca X, Y ln lt l: a. 0,2M; metylamin; etylamin b. 0,06M; metylamin; etylamin c. 0,2M; etylamin; propylamin d. 0,03M; etylamin; propylamin Cu 15: t chy hon ton mt amin thm X thu c 3,08g CO2, 0,99g H2O v 336ml N2 (ktc). trung ho 0,1mol X cn 600ml dd HCl 0,5M. Cng thc phn t ca X l cng thc no? a. C7H11N b. C7H10N c. C7H11N3 d. C7H10N2 Cu 16: t chy hon ton mg hh 3 amin X, y, Z bng mt lng khng kh va (cha 1/5 th tch l oxi, cn li l nit) thu c 26,4g CO2, 18,9g H2O v 104,16 lt N2 (ktc). Gi tr ca m? a. 12g b. 13,5g c. 16g d. 14,72g Cu 17: Cho 3 hchc X, Y, z u cha cc nguyn t C, H, N. Thnh phn phn trm khi lng ca N trong phn t X, Y , Z ln lt l: 45,16%; 23,73%; 15,05%. Bit c X, Y, Z khi tc dng vi axit clohiric u cho mui amoni c dng cng thc R NH3Cl. Cng thc X, Y (mch thng), Z ln lt l: a. CH3 NH2, C2H5 NH2, C6H5 NH2 b. C2H5 NH2, CH3 CH2 CH2 NH2, C6H5 NH2 c. CH3 NH2, CH3 CH2 CH2 NH2, C6H5 NH2 d. CH3 NH2, CH3 CH2 CH2 NH2, C6H5 CH2 NH2 Cu 18: Mt mui X c cng thc C3H10O3N2. ly 14,64g X cho phn ng ht vi 120ml dung dch KOH 1M. C cn dd sau phn ng thu c phn hi v cht rn. Trong phn hi c mt cht hu c Y (bc 1). Trong phn rn ch l mt cht v c. Cng thc phn t ca Y l: a. C2H5NH2 b. C3H7OH c. C3H7NH2 d. CH3NH2 Cu 19: Hn hp X gm 2 amino axit no bc 1 Y v Z. Y cha 2 nhm axit, mt nhm amino; Z cha mt nhm axit, mt nhm amino. MY/MZ = 1,96. t chy 1mol Y hoc 1 mol Z th s mol CO2 thu c nh hn 6. Cng thc cu to ca hai amino axit l:

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Nguyn Trung Kin Lp 12A1

a. H2NCH2 CH(COOH) CH2 COOH v H2NCH2 COOH b. H2NCH2 CH(COOH) CH2 COOH v H2N [CH2]2 COOH c. H2N CH(COOH) CH2 COOH v H2NCH2 COOH d. H2N CH(COOH) CH2 COOH v H2N [CH2]2 COOH Cu 20: t chy 1mol amino axit H2N [CH2]n COOH phi cn s mol oxi l: a. (2n+3)/2 b. (6n+3)/2 c. (6n+3)/4 d. (2n+3)/4 Cu 21: Hp cht hu c X ch cha hai loi nhm chc amino v cacboxyl. Cho 100ml dung dch X 0,3M phn ng va vi 48ml dd NaOH 1,25M. Sau em c cn dung dch thu c c 5,31g mui khan. Bt X c mch cacbon khng phn nhnh v nhm NH2 v tr alpha. CTCT ca X: a. CH3CH(NH2)COOH b. CH3C(NH2)(COOH)2 c. CH3CH2C(NH2)(COOH)2 d. CH3CH2CH(NH2)COOH Cu 22: Thc hin phn ng este gia amino axit X v ancol CH 3OH thu c este Y c t khi hi so vi khng kh bng 3,069. CTCT ca X: a. H2N-CH2-COOH b. H2N-CH2-CH2-COOH c. CH2-CH(NH2)-COOH d. H2N-(CH2)3-COOH Cu 23: t chy ht a mol mt amino axit X n chc bng oxi va ri ngng t ht hi nc c 2,5 mol hh CO2 v N2. CTPT ca X: a. C5H11NO2 b. C3H7N2O4 c. C3H7NO2 d. C2H5NO2 Cu 24: Ly 14,6g mt ipeptit to ra t glixin v alanin cho tc dng va vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng: a. 0,1 lit b. 0,2 lt c. 0,3 lt d. 0,4 lt BI TP AMIN-AMINO AXIT-PROTEIN Phn I : T lun Bi 1: Vit cng thc cu to v gi tn cc amin c cng thc phn t di y bng danh php gc-chc v danh php thay th: (a) CH5N, (b) C2H7N, (c) C3H9N, (d) C4H11N, (e) C6H7N (amin thm). Bi 2: So snh v gii thch tnh cht vt l ca hai cp cht cho di y: Cht C2H5OH C2H5NH2 Cht C6H5OH C6H5NH2 Ts 78,3oC 16,6oC tnc 43oC -6,2oC tan tan tt tan tt t tan t tan Bi 3: Sp xp cc hp cht ng phn etylimetylamin (A), n-butylamin (B), v ietylamin (C) theo trt t gim dn ca nhit si v gii thch. Bi 4: t chy amin A bng lng khng kh va (cha 80% N 2 v 20% O2 v th tch), thu c 0,528 gam CO 2 ; 0,54 gam H2O v 2,5536 lit N2 (ktc). Xc nh cng thc cu to v vit phn ng th hin tnh baz ca A. Bi 5: ngh phng php ha hc (c vit cc PTHH minh ha) (a) ra l ng anilin, (b) kh mi tanh ca c trc khi nu. Bit rng mi tanh ca cc amin (nhiu nht l trimetylamin) v mt s tp cht khc. Bi 6: Cho 1,52 gam hn hp hai amin no, n chc, mch h tc dng va vi 200 ml dung dch HCl, thu c 2,98 gam mui. (a) tnh nng mol ca dung dch HCl. (b) xc nh cng thc cu to ca hai amin, bit rng hn hp hai amin c trn vi s mol bng nhau. Bi 7: Khi chng ct than , c mt phn cht lng b tch ra. l dung dch long ca amoniac, phenol, anilin (dung dch A) v mt lng khng ng k cc cht khc. trung ha 1 lit dung dch A cn 100ml dung dch HCl 1M. Mt lit dung dch A cng b trung ha bi 10 ml dung dch NaOH 1M. Mt khc ly 1 lit dung dch A phn ng vi dung dch Br2 d th thu c 19,81 gam kt ta. Hy xc nh nng mol ca amoniac, phenol v anilin c trong dung dch A, gi thit cc phn ng xy ra hon ton. Bi 8: Ha tan hn hp gm anilin, phenol, axit axetic v ancol etylic trong n-hexan, ri chia dung dch thnh 4 phn bng nhau. Phn th nht tc dng vi dung dch brom d cho 9,91 gam kt ta. trung ha phn 3 cn 18,5ml NaOH 11% (d=1,1 g/ml). Thi kh hiro clorua qua phn th t, sau phn ng tch ra c 1,072 gam mui. Vit phn ng v xc nh thnh phn phn trm khi lng mi cht trong hn hp, bit rng cc phn ng xy ra hon ton. Bi 9: Cho chuyn ha sau: C7H16
A H H 2S N3
4O

, la s : 1

e / H

C N l a O

H d

(a) Vit phng trnh v hon thnh dy chuyn ha trn, bit B l ng phn para-. (b) So snh mnh tnh baz
ca cc nhm chc trong F. Bi 10: C ba dung dch NH4HCO3, NaAlO2, C6H5ONa, v ba cht lng C2H5OH, C6H6, C6H5NH2 ng trong 6 l mt nhn. Nu ch dng dung dch HCl th c th nhn bit c cht no trong s 6 cht trn. Bi 11: (a) Trnh by phng php phn bit cc cht lng ng trong cc bnh mt nhn cha benzen, anilin v phenol. (b) Trnh by phng php tch ring cc cht ra khi hn hp gm benzen, phenol v anilin. Bi 12: Ti sao nhit thng cc amino axit u l cht rn v u tan tt trong nc? So snh v gii thch nhit nng chy ca cc hp cht hu c H2NCH2COOH, n-C4H9NH2, C2H5COOH, n-C4H9OH. Bi 13: a) cho nhn xt chung v tnh cht ha hc ca amino axit. b) Vit PTHH ca phn ng xy ra khi cho glyxin ln lt tc dng vi: i) dung dch HCl, ii) dung dch NaOH, iii) CH 3OH c mt HCl m c, iv) NaNO2 trong dung dch HCl.

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Bi 14: Hp cht hu c A cha c nguyn t C, H, O, N v c M = 89u. t chy hon ton 1 mol A thu c 3 mol CO2 v 0,5 mol N2. (a) Tm cng thc phn t v vit cng thc cu to mch h ca A, bit A l hp cht lng tnh, vit phng trnh minh ha tnh cht . (b)A c lm mt mu nc brom hay khng? Nu c, hy vit phng trnh ha hc ca phn ng. Bi 15: Cho 26,1 gam hn hp G gm axit glutamic v glyxin vo 175 ml dung dch HCl 2M, thu c dung dch G 1. Dung dch G1 phn ng va vi 200ml dung dch NaOH 3,5M. Vit cc PTHH ca phn ng xy ra v tnh phn trm theo khi lng ca mi amino axit c trong hn hp G. Bi 16: Hp cht A l mt -amino axit. Cho 0,01 mol A tc dng va ht vi 80ml dung dch HCl 0,125M, sau thu c 1,835 gam mui. Mt khc, khi trung ha 2,94 gam A bng dung dch NaOH va th thu c 3,82 gam mui. A c cng thc cu to mch khng phn nhnh, hy gi tn thng dng ca A, dn xut no thng c dng trong cuc sng hng ngy ? Vit phng trnh ha hc ca A vi NaNO2 trong s c mt ca axit clohiric. Bi 17: Cho 0,01 mol mt amino axit A tc dng va vi 100ml dung dch HCl 0,2M, thu c dung dch B. Dung dch ny phn ng va ht vi 100ml dung dch NaOH 0,3M thu c 2,85 gam mui. 1. Xc nh cng thc cu to v gi tn thng dng ca A. Bit rng A l mt loi amino axit thit yu mch cacbon khng phn nhnh c cha nhm amin cui mch. 2. Dung dch A trong nc c mi trng g? Ti sao? 3. Vit phng trnh ha hc ca phn ng xy ra khi cho A tc dng vi H 2SO4, Ba(OH)2, C2H5OH trong HCl, NaNO2 trong HCl. Bi 18: Cho bit cu to sn phm to thnh khi un nng: (a) -amino axit, (b) -amino axit, (c) -amino axit, (d) -amino axit v (e) -amino axit. Cho v d minh ha. Bi 19: A l mt -amino axit mch khng phn nhnhc khi lng phn t bng 131. Cho 1,965 gam A tc dng va vi dung dch HCl to ra 2,5125 gam mui. Cng lng A trn khi tc dng vi dung dch naOH d thy to thnh 2,295 gam mui. Xc nh cng thc cu to, gi tn A v hon thnh dy chuyn ha: NaO H A t0 B t C (poliamit) + D H Cl E Bi 20: Cho ma gam hn hp 2 amino axit no cha mt chc axit v mt chc amin tc dng vi 110 ml dung dch HCl 2M, thu c dung dch A. tc dng ht cc cht trong A cn dng 140ml dung dch KOH 3M. Mt khc, t chy m gam hn hp 2 amino axit trn cho sn phm chy qua dung dch NaOH d th khi lng bnh ny tng thm 32,8 gam. Bit rng khi t chy to nit dng n cht. (a) Xc nh cng thc phn t ca 2 amino axit, bit khi lng phn t ca chng l 1,37. (b) Tnh s mol mi amino axit trong hn hp ban u. Bi 21: Trnh by phng php phn bit cc dung dch mt nhn cha alanin, lysin, axit glutamic v prolin (cng thc cho di y).
o

N H

COOH

prolin

Bi 22: (a) Lin kt peptit l g ? (b) peptit l g ? (c) Phn bit khi nim oligopeptit v polipeptit. (d) Vit cng thc cu to v gi tn cc tripeptit c th hnh thnh t glyxin, alanin v phenylalanin (C 6H5CH2CH(NH2)COOH vit tt l Phe). Bi 23: Thy phn tripeptit A ngi ta thu c 2,25 gam amino axit X c 32%C, 6,67%H v 18,67%N v khi lng, MX =75 ; 1,335 gam -amino axit Y c 40,45%C, 7,87%H v 15,73%N v khi lng, M Y=89. (a) Vit cc cng thc cu to c th c ca A. (b) Tnh th tch dung dch HCl 0,5M cn dng thu phn hon ton 3,045 gam A. Bi 24: (a) Khi thu phn tng phn tetrapeptit Ala-Met-Gly-Val th c th thu c bao nhiu loi peptit mi ? (b) Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin, 1 mol alanin v 1 mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly, Gly-ala v tripeptit Gly-Gly-Val. Hy xc nh trnh t cc -amino axit trong A. Bi 25: Vit cc phng trnh ha hoc theo s phn ng di y :
+ N + H a O C x t , t , P

(D1)
l +

(D2)
H

(A)

(NH-(CH2)5-CO)n

(D3) (D4) Bi 26: a) Ti sao khng git qun o lm t t nilon, len, t tm bng x phng c kim cao? b) Phn bit cc khi nim (a) protein, (b) protein n gin v (c) protein phc tp. c) Xt cc phn t protein: keratin, miozin, fibroin, anbumin v hemolobin. Trong cc phn t ny, phn t no c hnh si, phn t no c dng hnh cu? Phn t no tan trong nc? v phn t no khng tan trong nc? Bi 27: Xc nh phn t khi gn ng ca mt hemoglobin (hng cu ca mu) cha 0,4% Fe (mi phn t hemoglobin ch cha 1 nguyn t Fe). (b) Khi thu phn 500 gam protein A thu c 170 gam alanin. Nu phn t khi ca A l 50.000 u th s mt xch alanin trong phn t A l bao nhiu? Phn 2: Bi tp trc nghim Cu 1: Pht biu no sau y khng ng? A. Amin c cu thnh bng cch thay th mt hay nhiu nguyn t hiro ca NH 3 bng mt hay nhiu gc hirocacbon. B. Tu thuc vo cu trc ca gc hirocacbon c th phn bit amin thnh amin no, cha no, thm

a O

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Nguyn Trung Kin Lp 12A1

C. A min c t hai nguyn t cacbon tr ln trong phn t bt u xut hin hin tng ng phn D. Bc amin c nh ngha theo bc ca nguyn t cacbon lin kt trc tip vi nhm chc amin
Cu 2: Xt cc amin: (X) etylamin, (Y) isopropylamin, (Z) imetylamin v (T) etylimetylamin. Amin bc 2 l : A. X B. Y C. Z D. T Cu 3: Cng thc no di y l cng thc ca dy ng dng amin thm, cha mt vng bezen, n chc bc nht ? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 Cu 4: ng vi cng thc phn t C4H11N, c x ng phn amin bc nht, y ng phn amin bc 3. Gi tr x, y, z ln lt bng: A. 4, 3 v 1 B. 3, 3 v 0 C. 4, 2 v 1 D. 3, 2 v 1 Cu 5: Tn gi no sau y ng? A. 2-etylpropan-1-amin B. N-propyletanamin C. butan-3amin D. N, N-imetylpropan-2-amin Cu 6: Xt cc kh CH4, CH3Cl, HCHO v CH3NH2 th cht kh d ha lng nht l : A. CH4 B. CH3Cl C. HCHO D. CH3NH2 Cu 7: Trong cc cht di y, cht no l cht kh? A. ancol metylic B. ancol propylic C. trimetylamin D. axit propionic Cu 8: Xt cc cht: benzen (C6H6), anilin (C6H5NH2), phenol (C6H5OH) v axit benzoic (C6H5COOH). Trong bn cht ny, th cng iu kin thng, s cht tn ti trng thi lng l A. 1 B. 2 C. 3 D. 4 Cu 9: Cho bn hp cht hu c l C2H5Cl, C2H5OH, CH3COOH v CH3CH2NH2. Cht c nhit si cao th 2 trong dy trn l A. C2H5OH B. C2H5Cl C. C2H5NH2 D. CH3COOH Cu 10: Pht biu no sau y l cha chnh xc v tnh cht vt l ca amin? A. Cc amin kh c mi tng t amoniac, c. B. Anilin nguyn cht l cht lng, kh tan trong nc, mu en C. tan ca amin gim khi s nguyn t cacbon trong phn t tng D. Metyl, etyl, imetyl, trimetyl amin l nhng cht kh d tan trong nc Cu 11: Cc gii thch quan h cu trc- tnh cht no sau y khng hp l? A. Do c cp electron t do trn nguyn t N m amin c tnh baz B. Tnh baz ca amin cbg mnh khi nguyn t nit c giu electron C. Vi amin RNH2, gc R ht electron lm tng mnh tnh baz v ngc li D. Do NH2 y electron nn anilin d tham gia phn ng th vo nhn thm hn v u tin th vo cc v tr o-, pCu 12: Trt t tng dn mnh ca tnh baz ca dy no sau y l khng ng? A. C6H5NH2<NH3 B. NH3<CH3NH2<CH3CH2NH2 C. CH3CH2NH2<CH3NHCH3 D. p-CH3C6H4NH2<p-O2NC6H4NH2 Cu 13: Phn ng no di y khng th hin tnh baz ca amin? + A. CH3NH2 + H2O CH3NH 3 + OH B. C6H5NH2 + HCl C6H5NH3Cl + C. Fe3+ + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH 3 D. CH3NH2 + HNO2 CH3OH + N2 + H2O Cu 14: Dung dch no di y khng lm i mu qu tm? A. C6H5NH2 B. NH3 C. C2H5NH2 D. CH3NHC2H5 Cu 15: Cho lng d anilin phn ng hon ton vi dung dch cha 0,05 mol H2SO4 long, lng mui thu c bng: A. 7,1gam B. 14,2 gam C. 19,1 gam D. 28,4 gam Cu 16: Amin bc nht n chc X tc dng va vi lng HCl c trong 120ml dung dch HCl 0,1M thu c 0,81 gam mui X l: A. metanamin B. Etanamin C. propanamin D. benzenamin Cu 17: Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng va vi 0,075 mol Br2, to kt ta trng. Lng cht NH3, C6H5NH2 v C6H5OH ln lt bng:

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NH3 C6H5NH2 C6H5OH A. 0,001 mol 0,005 mol 0,02 mol B. 0,005 mol 0,005 mol 0,02 mol C. 0,005 mol 0,02 mol 0,005 mol D. 0,01 mol 0,005 mol 0,02 mol Cu 18: kh mi tanh ca cc, nn s dng loi nc no di y? A. nc ng B. nc mui C. nc gim D. nc ru Cu 19: ra sch ng nghim cn dnh anilin, ngi ta nn ra ng nghim bng dung dch no di y, trc khi ra li bng nc? A. dung dch axit mnh B. dung dch baz mnh C. dung dch mui n D. dung dch ng n Cu 20: Cho CH3NH2 tc dng vi dung dch hn hp NaNO2 v HCl th thu c sn phm hu c no sau y:A. A. CH3NH3Cl B. CH3N2Cl C. CH3OH D. CH3NO2 Cu 21: Phn ng no di y l ng? 5 C A. C2H5NH2 + HNO2 + HCl C2H5N2Cl + 2H2O B. C6H5NH2 + HNO2 + HCl 0 C6H5N2Cl + 2H2O 0 5 C C. C6H5NH2 + HNO2 + HCl C6H5N2Cl + 2H2O D. C6H5NH2 + HNO2 C6H5OH + N2 + H2O Cu 22: Cc hin tng no sau y m t khng chnh xc? A. Nhng mu qu tm vo dung dch etylamin thy qu tm chuyn sang mu xanh B. Phn ng gia metylamin v hiro clorua to ra khi trng C. Nh vi git dung dch brom vo ng nghim ng dung dch anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dung dch metylamin dung dch khng i mu Cu 23: t chy hon ton hn hp hai amin no, n chc, bc nht, l ng ng lin tip thu c 2,24 lit kh CO 2 (ktc) v 3,6 gam H2O. Cng thc phn t ca hai amin l: A. CH3NH2 v C2H5NH2 B. C2H5NH2 v C3H7NH2 C. C3H7NH2 v C4H9NH2 D.C4H9NH2 v C5H11NH2 Cu 24: t chy hon ton m gam mt amin X bng mt lng khng kh (gi thit khng khi c 20% th tch kh O 2) va thu c 17,6 gam CO2, 12,6 gam H2O v 69,44 lit N2 (ktc). Cng thc phn t ca X l A. CH5N B. C2H7N C. C2H8N2 D. C2H7N2 Cu 25: Phn ng iu ch amin no sau y khng hp l? A. CH3I + NH3 CH3NH2 + HI B. 2C2H5I + NH3 (C2H5)2NH + 2HI C. C6H6 + NH3 C6H5NH2 + H2 D. C6H5CN + 2H2 N C6H5CH2NH2 i,t Cu 26: Cho dy chuyn ha: Benzen HNO3 / H X F e/H C Y NH3 Z l 2 SO4 Cht Y l A. anilin B. Phenylamoniclorua C. P-aminoanilin D. p-nitroanilin Cu 27: Pht biu no sau y l khng ng? A. Hp cht H2NCOOH l amino axit n gin nht. B. Amino axit l hp cht hu c tp chc, phn t c ng thi nhm COOH v NH2 C. Amino axit c th tn ti dng H2NRCOOH hoc H3N+RCOOD. Thng thng dng ion lng cc l dng tn ti chnh ca amino axit Cu 28: Amino axit khng th phn ng vi loi cht no di y? A. ancol B. dung dch brom C. axit (H+) v axit nitr D. dung dch HCl, NaOH Cu 29: Xt cc dy chuyn ha: Glyxin N aO H A H C X l Glyxin H C B N aH Y l O X v Y l (bit NaOH va HCl ly d trong cc giai on phn ng) A. u l ClH3NCH2COONa B. ln lt l ClH3NCH2COOH v ClH3NCH2COONa C. ln lt l ClH3NCH2COONa v H2NCH2COONa D. ln lt l ClH3NCH2COOH v H2NCH2COONa Cu 30: Cho 0,1 mol -amino axit A (dng H2NRCOOH) phn ng ht vi HCl to ra 11,15 gam mui. A l A. Gly B. Ala C. Phe D. Val Cu 31: Cho -amino axit mch khng phn nhnh A c cng thc dng H2NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 9,55 gam mui. A l A. axit 2-aminopropanioic B. axit 2-aminobutanioic C. axit 2-aminopentanioic
o o o

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D. axit 2-aminohexanioic Cu 32: X l mt aminoaxit t nhin, 0,01 mol X tc dng va vi 0,01 mol HCl to mui Y. Lng Y sinh ra tc dng va vi 0,02 mol NaOH to 1,11 gam mui hu c Z. X l: A. axit aminoaxetic B. axit -aminopropionic C. axit aminopropionic D. axit aminoglutaric Cu 33: X l mt -aminoaxit mch khng nhnh cha mt nhm amin (NH2) v mt nhm axit (COOH). Cho 0,1 mol X tc dng vi dung dch NaOH d to ra mui hu c Y. Cho ton b lng Y ny tc dng vi HCl thu c 18,15 gam mui hu c Z. T X c th trc tip iu ch A. nilon-6 B. nilon-7 C. nilon-8 nilon-6,6 Cu 34: X l mt -amino axit mch khng nhnh. Cho 0,015 mol X tc dng va vi dung dch HCl to ra 2,5125 gam mui. Cng lng X trn khi tc dng vi dung dch NaOH ly d thy to thnh 2,295 gam mui. Cng thc ca X l A. H2N(CH2)5COOH B. H2N(CH2)3CH(NH2)COOH C. H2N(CH2)6COOH D. H2N(CH2)4CH(NH2)COOH Cu 35: Cho 0,01 mol mt aminoaxit A (mt amino axit thit yu, mch khng nhnh, c cha nhm amin cui mch) tc dng va vi 100 ml dung dch HCl 0,2M, thu c dung dch B. Dung dch ny tc dng va ht vi 100 ml dung dch NaOH 0,3M, thu c 2,85 gam mui. A l A. H2(CH2)3CH(NH2)COOH B. H2N(CH2)4CH(NH2)COOH C. (H2N)2CH(CH2)3COOH D. (H2N)2CH(CH2)4COOH Cu 36: S ng phn va tc dng vi dung dch HCl, va tc dng vi dung dch NaOH bng A. 1 B. 2 C. 3 D. 4 Cu 37: Cht hu c X c cng thc phn t l C3H7O2N. X tc dng vi dung dch NaOH, dung dch HCl nhng khng tc dng vi dung dch Br2, khng tc dng vi dung dch AgNO3/NH3 d. Cng thc cu to ca X l: A. CH3CH(NH2)COOH B. CH2=CHCOONH4 C. H2NCH2CH2COOH D. HCOONH3CH=CH2 Cu 38: C ba l mt nhn, mi l cha mt trong cc amino axit sau: glyxin, lysin v axit glutamic. Thuc th no sau y c th nhn bit c c ba dung dch trn? A. qu tm B. dung dch NaHCO3 B. Kim loi Al D. dung dch NaNO2/HCl Cu 39: X l mt -amino axit cha mt nhm COOH v mt nhm NH2. Cho 8,9 gam X tc dng vi 200ml dung dch HCl 1M thu c dung dch Y. phn ng vi cc cht c trong Y cn dng 300 mol dung dch NaOH 1M. Cng thc ng ca X l: A. CH3CH(NH2)COOH B. (CH3)2C(NH2)COOH C. CH3CH2CH(NH2)COOH D. (CH3)2CHCH(NH2)COOH Cu 40: Amino axit Y cha mt nhm COOH v 2 nhm NH2. Cho 1 mol Y tc dng ht vi dung dch HCl v c cn th thu c 205 gam mui khan. Cng thc phn t ca Y l A. C4H10N2O2 B. C5H12N2O2 C. C6H14N2O2 D. C5H10N2O2 Cu 41: Amino axit X cha a nhm COOH v b nhm NH2. Cho 1 mol X tc dng ht vi dung dch HCl v c cn th thu c 169,5 gam mui khan. Cho X tc dng vi NaOH thu c 177 gam mui. Cng thc phn t ca X l A. C3H7NO2 B. C4H7NO4 C. C4H6N2O2 D. C5H7NO2 Cu 42: Dung dch metylamin c th tc dng vi cht no sau y: Na2CO3, FeCl3, H2SO4 long, CH3COOH, C6H5ONa, qu tm. A. FeCl3, H2SO4 long, CH3COOH, qu tm B. Na2CO3, FeCl3, H2SO4 long, C6H5ONa C. FeCl3, qu tm D. Na2CO3, H2SO4 long, qu tm Cu 43: Cho 0,1 mol cht X (C2H8O3N) tc dng vi dung dch cha 0,2 mol naOH un nng thu c cht kh lm xanh giy qu tm tm t v dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ng ca m l A. 5,7 g B. 12,5 g C. 15 g D. 21,8 g Cu 44: Cho bit glyxin c pK1 = 2,35, pK2 = 9,78. Hi dung dch glyxin (trong nc) c

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A. pH >7 B. pH = 7 C. pH < 7 D. Khng xc nh, tu nng Cu 45: -aminoaxit X cha mot nhom -NH2. Cho 10,3 gam X tac dung vi axit HCl (d), thu c 13,95 gam muoi khan. Cong thc cau tao thu gon cua X la (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5) A. H2NCH2COOH B. H2NCH2CH2COOH C. CH3CH2CH(NH2)COOH D. CH3CH(NH2)COOH (Trch thi H khi A 2007) Cu 46: Cho hon hp X gom hai chat hu c co cung cong thc phan t C2H7NO2 tac dung va u vi dung dch NaOH va un nong, thu c dung dch Y va 4,48 lt hon hp Z ( ktc) gom hai kh (eu lam xanh giay, quy am).. T khoi hi cua Z oi vi H2 bang 13,75. Co can dung dch Y thu c khoi lng muoi khan la (cho H = 1, C = 12, N = 14, O = 16, Na = 23) A. 16,5 gam B. 14,3 gam C. 8,9 gam D. 15,7 gam (Trch thi H khi A 2007) Cu 47: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. (Trch thi H khi B 2007) Cu 48: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. (Trch thi H khi B 2007) Cu 49: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. (Trch thi H khi B 2007) Cu 50: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCOO-CH2CH3. B. CH2=CHCOONH4. C. H2NC2H4COOH. D. H2NCH2COO-CH3 (Trch thi C 2007) Cu 51: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C4H10O2N2. B. C5H9O4N. C. C4H8O4N2. D. C5H11O2N. (Trch thi H khi A 2009) Cu 52: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. Cu(OH)2 trong mi trng kim. B. dung dch NaCl. C. dung dch HCl. D. dung dch NaOH. (Trch thi H khi A 2009) Cu 53: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 8,2. B. 10,8. C. 9,4. D. 9,6. (Trch thi H khi A 2009) Cu 54: Pht biu no sau y l ng? A. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. B. Benzen lm mt mu nc brom nhit thng. C. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh.

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D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. (Trch thi H khi A 2009) Cu 55: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3NH2 v NH3. B. C2H5OH v N2. C. CH3OH v CH3NH2. D. CH3OH v NH3. (Trch thi H khi B 2009) Cu 56: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC3H5(COOH)2. B. (H2N)2C3H5COOH. C. H2NC2H3(COOH)2. D. H2NC3H6COOH. (Trch thi H khi B 2009) Cu 57: Ngi ta iu ch anilin bng s sau:

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 111,6 gam. B. 55,8 gam. C. 186,0 gam. D. 93,0 gam. (Trch thi H khi B 2009) Cu 58: Pht biu khng ng l: A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N +-CH2-COO B. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. C. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. D. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). (Trch thi H khi A 2008) Cu 59: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2)-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2. B. 3. C. 5. D. 4. (Trch thi H khi B 2008) Cu 60: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH2-CH2-COOH. B. H3N-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. C. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. D. H2N-CH2-COOH, H2N-CH(CH3)-COOH. (Trch thi H khi B 2008) Cu 61: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. HCOOH3NCH=CH2. B. H2NCH2CH2COOH. C. CH2=CHCOONH4. D. H2NCH2COOCH3. (Trch thi H khi B 2008) Cu 62: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 6. B. 8. C. 7. D. 5. (Trch thi H khi B 2008) Cu 63: Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l A. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,2 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,3 mol. (Trch thi H khi B 2008) Cu 64: Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. metyl aminoaxetat. B. axit -aminopropionic. C. amoni acrylat. D. axit -aminopropionic. (Trch thi C khi 2009) Cu 65: S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 4. B. 5. C. 2. D. 3. (Trch thi C khi 2009)

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Cu 66: Cht X c cng thc phn t C4H9O2N Bit:

Cng thc cu to ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH. C. H2NCH2COOC2H5 v ClH3NCH2COOH. (Trch thi C khi 2009) Cu 67: Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 328. B. 453. C. 479. D. 382. (Trch thi C khi 2009) Cu 68: Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. HCOONH3CH2CH3. B. CH3CH2COONH4. C. HCOONH2(CH3)2. D. CH3COONH3CH3. (Trch thi C khi 2009) Cu 69: Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch NaOH (to) v vi dung dch HCl (to). S phn ng xy ra l A. 3. B. 5. C. 6. D. 4. (Trch thi C khi 2009) Cu 70: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC4H8COOH. B. H2NC3H6COOH. C. H2NC2H4COOH. D. H2NCH2COOH. (Trch thi C khi 2008) Cu 71: Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5. B. 2. C. 3. D. 4. (Trch thi C khi 2008) Cu 72: Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 5. B. 2. C. 3. D. 4. (Trch thi C khi 2008) Cu 73: Cht no sau y va lng tnh, va tc dng vi H2? A. CH2=CH-COONH4 B. H2N-CH2CH2-COOH C. CH3CH(NH2)COOH D. CH3-CH2-CH2-NO2 Cu 74: C 4 dung dch khng mu: glucoz, glixerol, h tinh bt v lng trng trng. Hy chn cht no trong s cc cht cho di y nhn bit c c bn cht? A. HNO3 c, nng, to B. I2 C. Ag2O trong dung dch NH3 D. Cu(OH)2 trong dung dch NaOH, to Cu 75: C 5 dung dch khng mu: axit fomic, glyxin, natri ioua, axit glutamic, lysin. Hy chn cp thuc th thch hp nhn bit c 5 cht. A. HCl v AgNO3 trong NH3 B. HCl v BaCl2 C. qu tm v dung dch BaCl2 D. qu tm v AgNO3/NH3 Cu 76: Cht X c cng thc phn t l C4H10O2NCl. un nng X vi dung dch NaOH thu c sn phm NaCl, H2N-CH2-COONa v ancol Y. Cng thc cu to ca Y l A. CH3CH2COOCH2NH3Cl B. CH3CH2OOCCH2NH3Cl C. CH3COOCH2CH2NH3Cl D. CH3CH(NH2)COOCH2Cl Cu 77: Tin hnh phn ng t hn hp glyxin v alanin. hi c th thu c ti a bao nhiu ipeptit? A. 2 B. 3

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Nguyn Trung Kin Lp 12A1

C. 4 D. 5 Cu 78: Thu phn hon ton polipeptit sau thu c bao nhiu amino axit? H2N CH2 CO NH CH CO NH CH CONH CH2 COOH H2C COOH H 2C A. 2 B. 3 C. 4 D. 5 Cu 79: Thu phn tng phn mt pentapeptit thu c cc ipeptit v tripeptit gm C-B, D-C, A-D, B-E v D-C-B (A, B, C, D, E l k hiu cc gc -amino axit khc nhau). Trnh t cc amino axit trong peptit trn l A. A-B-C-D-E B. D-C-B-E-A C. C-B-E-A-D D. A-D-C-B-E

CHNG 3: AMIN AMINO AXIT PROTEIN

Cu1. Amin c CTPT C4H11N c my ng phn mch khng phn nhnh ? A. 2 D. 6
C. 7 D. 8

B. 3

C.
B.

5
6

Cu2.C bao nhiu ng phn amin ng vi CTPT C4H11N ? A. 5 Cu 3. Nguyn nhn no sau y lm anilin tc dng c vi nc brom? A. Do nhn thm benzen c h thng lin kt bn vng. B. Do nhn thm benzen ht electron. C. Do nhn thm benzen y electron. D. Do nhm - NH2 y electron lm tng mt electron cc v tr o- v p-

Cu 4. Cho cc cht sau : CH3CH2NHCH3(1), CH3CH2CH2NH2(2), (CH3)3N (3).Tnh baz tng dn theo dy no ? A. (1) < (2) < (3) (3) < (1) < (2) B. (2) < (3) < (1) C. (3) < (2) < (1) D.

Cu 5.Cho cc cht sau: Ancol etylic (1), etylamim (2), (4). A. (2) < (3) < (4) < (1) D. (1) < (3) < (2) < (4) Cu 6.Hp cht c CTCT nh sau: thng l A. etylmetyl amino butan C. butyletylmetylamin Cu 7.Hp cht c CTCT nh sau php IUPAC l: A. 3-amino-5-hiroxi-2-metylhexanal. aminohexanal. C. 5-oxo-4-aminohexanol-2.
CH 3 CH CH2 CH CH CH3 | | | OH NH 2 CHO

metylamim (3), axit axetic

Dy sp sp theo chiu c nhit si tng dn l dy no ? B. (2) < (3) < (4) < (1)
CH3 CH2 CH2 2 N CH | CH3 CH2

C.
CH 3

(3) < (2) < (1) < (4)

.Tn theo danh php thng

B. metyletyl amino butan D. metyletylbutylamin . Tn hp cht theo danh

B.

5-hiroxi-2-metyl-3-

D. 4-amino-5-oxohexanol.

Cu 8. Khi t nng mt ng ng ca metylamin ngi ta thy t l th tch cc kh v hi VCO2 : VH2O = 2 : 3 . Cng thc phn t ca amin l

Nguyn Trung Kin Lp 12A1

Trang 39

A. C2H7N khc

B. C3H9N

C. C4H11N

D. Kt qu

Cu 9.Cho 9 g hn hp X gm 3 amin: propylamin, etylmetylamin, trimetylamin X tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l A. 100ml B. 150 ml C. 200 ml D. Kt qu khc Cu 10. t chy hon ton a mol hn hp X gm 2 amin no n chc thu c 5,6 lt CO2 (ktc) v 7,2 g H2O. Gi tr ca a l A. 0,05 mol B. 0,1 mol C. 0,15 mol D. 0,2 mol

Cu 11.t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng, thu c 22 g CO2 v 14,4 g H2O. CTPT ca hai amin l A. CH3NH2 v C2H7N v C5H13N B. C2H7N v C3H9N C. C3H9N v C4H11N D. C4H11N

Cu 12. Cho 13,35 g hn hp X gm CH2NH2CH2COOH v CH3CHNH2COOH tc dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V: A. 100 ml D. 250 ml B. 150 ml C. 200 ml

Cu 13.Cho 20,15 g hn hp X gm (CH2NH2COOH v CH3CHNH2COOH) tc dng vi 200 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 450 ml dung dch NaOH 1M. Phn trm khi lng ca mi cht trong X l A. 55,83 % v 44,17 % D.52,59%v 7,41% B. 58,53 % v 41,47 % C. 53,58 % v 46,42 %

Cu 14 .A l mt hp cht hu c c CTPT C5H11O2N. un A vi dung dch NaOH thu c mt hp cht c CTPT C2H4O2NNa v cht hu c B. Cho hi B qua CuO/t0 thu c cht hu c D c kh nng cho phn ng trng gng. CTCT ca A l A. CH2 = CH - COONH3 - C2H5 B. CH3(CH2)4NO2 C. H2N- CH2 - CH2 - COOC2H5 D. NH2 - CH2COO - CH2 - CH2 - CH3 Cu 15. t chy ht a mol aminoaxit X c 2a mol CO2 v a/2 mol N2. Aminoaxit trn c cng thc cu to l: A.H2NCH2COOH B.H2NCH2CH2COOH C.H2NCH2CH2CH2COOH D. H2NCH(COOH)2 Cu 16 . Cho m gam hn hp X gm glixin v alanin tc dng vi dung dch NaOH va thu c m+11 gam mui. Nu t chy hon ton m gam hn hp X th cn 35,28 lt O2 (ktc). m c gi tr l : A. 43,1 gam B. 40,3 gam C. 41,7 gam D. 38,9 gam Cu 17. Khi thy phn hon ton 55,95 gam mt peptit X thu c 66,75 gam alanin (amino axit duy nht). X l A. tripeptit B. tetrapeptit C.pentapeptit D. ipeptit Cu 18. Hn hp X gm 2 amin no n chc mch h ng ng k tip c phn trm khi lng nit l 20,144%. Phn trm s mol cc amin trong X theo chiu tng dn phn t khi l : A. 50% v 50% B. 25% v 75% C. 20% v 80% D. 30 v 70% Cu 19. DD X gom HCl va H2SO4 co pH=2. e trung hoa hoan toan 0,58g hon hp 2 amin no n chc bac 1 (co so ngt C nho hn hoac bang 4) phai dung 1 lt dd X. Cong thc cua 2 amin co the la A. CH3NH2 va C4H9NH2. B. C2H5NH2 va C4H9NH2. C. C3H7NH2 va C4H9NH2. D. Ca A va B. Cu 20 . Cht A c thnh phn % cc nguyn t C, H, N ln lt l 40,45%, 7,86%, 15,73% cn li l oxi. Khi lng mol phn t ca A <100 g/mol. A tc dng c vi NaOH v vi HCl, c ngun gc t thin nhin, A c CTCT nh th no. A. CH3 CH(NH2) COOH B. H2N (CH2)2 COOH C. H2N CH2 COOH D. H2N (CH2)3 COOH Cu 21. Mt hemoglobin (hng cu ca mu) cha 0,4% Fe (mi phn t hemoglobin ch cha 1 nguyn t Fe). Phn t khi gn ng ca hemoglobin trn l : Trang 40 Nguyn Trung Kin Lp 12A1

A. 12000 B. 14000 C. 15000 D. 18000 Cu 22. kt ta ht 400ml dung dch hn hp HCl 0,5M v FeCl3 0,8M cn bao nhiu gam hn hp gm metylamin v etylamin c t khi so vi H2 l 17,25? A.41,4 gam B. 40,02 gam C. 51,75 gam D. Khng iu kin tnh. Cu 23. Metylamin d tan trong H2O do nguyn nhn no sau y ? A. Do nguyn t N cn cp electron t do d nhn H+ ca H2O. B. Do metylamin c lin kt H lin phn t. C. Do phn t metylamin phn cc mnh. D. Do phn t metylamin to c lin kt H vi H2O Cu 24. X l amin no n chc mch h v Y l amin no 2 ln amin mch h.c cng s cacbon.
Trung ha hn hp gm a mol X v b mol Y cn dung dch cha 0,5 mol HCl v to ra 43,15 gam hn hp mui. Trung ha hn hp gm b mol X v a mol Y cn dung dch cha 0,4 mol HCl v to ra p gam hn hp mui. p c gi tr l : A. 40,9 gam B. 38 gam C. 48,95 gam D. 32,525 gam + Cu 25. Mui C6H5N2 Cl (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l A. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,2 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,3 mol.

thi mn hoa 12 kiem tra bai 2 ( 25 cau ) (M 126)

Cu -aminoaxit X cha 1 nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), 1 : thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l: . . D CH3CH2CH(NH2 A. H2NCH2CH2CO B. CH3CH(NH2)CO C. H2NCH2COOH . )COOH OH OH Cu Cu 2: chng minh amino axit l hp cht lng tnh ta c th dng phn ng ca cht ny 2 : ln lt vi A. dung dch NaOH v dung dch NH3. B. dung dch KOH v dung dch HCl. C. dung dch KOH v CuO. D. dung dch HCl v dung dch Na2SO4 . Cu Cho cc cht sau y : C2H5-NH2 (1), (C2H5)2NH (2), C6H5NH2 (3). Dy cc cht 3 : sp xp theo chiu gim dn tnh baz l: D A. 3 , 1 ,2 B. 2 , 1 ,3 C. 2 , 3 ,1 1 , 2 ,3 . Cu S ng phn ca C3H9N l 4: D A. 4 B. 5 C. 2 3 . Cu Phn bit 3 dung dch H2N-CH2-COOH, CH3COOH , C2H5-NH2. ch cn 5 : mt thuc th Dung dch D A. B. Qu tm C. natri kim loa Dd HCl NaOH. . Cu Trng hp han tan 6,25gam vinylclorua c m gam PVC. S mt xch -CH2-CHCl- c 6 : trong m gam PVC trn l A. 6,02.1021. C. 6,02.1 B. . 6,02.1022. D. . 6,02.1020. Cu Cht khng c kh nng lm xanh nc qu tm l 7: A. anilin. C. natri hiroxit B. amoniac. D. natri axetat Cu Cho 500 gam benzen phn ng vi HNO3 (c) c mt H2SO4 (c), sn phm thu c em 8 : kh thnh anilin. Nu hiu sut chung ca qu trnh l 78% th khi lng anilin thu c l D A. 465 g B. 456 g C. 564 g 546 g . Cu Trong s cc loi t sau: 9 : [-NH-(CH2)6-NH-OC-(CH2)4-CO-]n (1). [-NH-(CH2)5-CO-]n (2). Nguyn Trung Kin Lp 12A1 Trang 41

D 1,3 . Cu Hp cht hu c A c cng thc C3H9O2N. Cho A phn ng vi dd NaOH, 10 : un nh thu c mui B v kh C lm xanh giy qu m. Nung B vi NaOH rn thu c 1 hidrocacbon n gin nht. Xc nh CTCT ca A ? . CH3COONH3CH CH3CH2COONH D HCOONH2(CH3) A. B. HCOONH3CH2C C. . 2 3 4 H3 Cu Cu 21 : Thy tinh hu c c tng hp t nguyn liu no sau y :. 11 : A. Vinyl clorua C. Propilen. B. Metyl metacrilat D. . Styren. Cu CTCT ca alanin l : 12 : H2N-CH2-CH2CH3-CH(NH2)A. C. H2N-CH2-COOH D. B. C6H5NH2. COOH. COOH Cu Cht tham gia phn ng trng hp l 13 : A. toluen. C. vinyl clorua B. propan D. Etan Cu tch ring tng cht t hn hp benzen, anilin, phenol ta ch cn dng cc ho cht (dng 14 : c, iu kin th nghim y ) l A. dung dch NaOH, dung dch NaCl, kh B. dung dch NaOH, dung dch HCl, kh CO2 CO2. C. . dung dch Br2, dung dch HCl, kh CO2 D. dung dch Br2, dung dch NaOH, kh CO2 Cu Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dd NaOH, 15 : thu c cht hu c n chc Y v cc cht v c. Khi lng phn t theo vC ca Y l: D A. 85 B. 46 C. 68 45 . Cu Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn 16 : ng vi 100 ml dd NaOH 1,5 M. Sau khi phn ng xy ra hon ton, c cn dd c 11,7 gam cht rn. Cng thc cu to thu gn ca X l: CH2=CHHCOOH3NCH= H2NCH2COOCH D H2NCH2CH2CO A. B. C. COONH4 CH2 . OH 3 Cu Cu 1: Nhm c cha dung dch (hoc cht) khng lm giy qu tm chuyn sang mu xanh l 17 : NaOH, CH3-NH2. A. NH3, anilin C. NH3, CH3-NH2 B. NaOH, NH3. D. A. 1 , 2 B. 1 , 2 ,3 C. 2 , 3 Cu 18 : A. Cu 19 : A. t chy hon ton 5,9g mt hp cht hu c n chc X thu c 6,72 lt CO2, 1,12 lt N2 (ktc) v 8,1g H2O. Cng thc ca X l : C. C3H9N C3H6O B. C3H5NO3 D. C3H7NO2 Cho 10 gam hn hp gm 3 amin no, n chc l ng ng k tip nhau tc dng va vi dd HCl 1M, c cn dd thu c 21,68 gam mui. Th tch dd HCl dng: D 160ml B. 16ml C. 320ml 32ml . Cho cc polime sau: (-CH2- CH2-)n, (- CH2- CH=CH- CH2-)n, (- NH-CH2-CO-)n. Cng thc ca cc monome khi trng hp hoc trng ngng to ra cc polime trn ln lt l CH2=CHCl, CH3- CH=CH- CH3, CH3- CH(NH2)- COOH CH2=CH2, CH3- CH=C=CH2, H2N- CH2- COOH. CH2=CH2, CH2=CH- CH= CH2, H2N- CH2- COOH. CH2=CH2, CH3- CH=CH-CH3, H2N- CH2- CH2- COOH Trng hp 5,6 lt C2H4 (ktc), nu hiu sut phn ng l 90% th khi lng polime thu c l

[C6H7O2(OOC-CH3)3]n (3). T thuc loi poliamit l

Cu 20 : A. B. C. D. Cu 21 : A. 4,3 gam. C. 6,3 gam. B. 7,3 gam. D. 5,3 gam. Cu Cho bit cng thc no di y l thnh phn chnh ca m chnh ? 22 : Trang 42 Nguyn Trung Kin Lp 12A1

A. C. Cu 23 : A.

NaOOCCH2CH2CH(NH2)COONa (c) B. H2NCH2COONa HOOCCH2CH2CH(NH2)COONa (b) D. C b v c u ng Mt trong nhng im khc nhau gia protein vi gluxit v lipit l protein lun c khi lng phn t ln hn

B. phn t protein lun c cha nguyn t nit. C. phn t protein lun c nhm chc -OH D. protein lun l cht hu c no Cu Cu 7: Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l 24 : A. C2H2, C6H5-NO2 B. C2H2, C6H5-CH3. C. CH4, C6H5-NO2 D. C6H12(xiclohexan), C6H5-CH3 Cu Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo 25 : phn ng vi k mt xch trong mch PVC. Gi tr ca k l D A. 6 B. 5 C. 4 3 .

AMIN
Cau 1: Co 4 hoa chat: metylamin (1), phenylamin (2), iphenylamin (3), imetylamin (4). Th t tang dan lc baz la : A. (4) < (1) < (2) < (3) B. (2) < (3) < (1) < (4) C. (2) < (3) < (1) < (4) D.(3) < (2) < (1) < (4) Cau 2 : Phat bieu nao sau ay la ung : A. Khi thay H trong hirocacbon bang nhom NH2 ta thu c amin B. Amino axit la hp chat hu c a chc co 2 nhom NH2 va COOH C. Khi thay H trong phan t NH3 bang goc hirocacbon ta thu c amin. D.Khi thay H trong phan t H2O bang goc hirocacbon ta thu c ancol. Cau 3 : Hp chat CH 3 N(CH 3 ) CH 2CH 3 co ten la: A. Trimetylmetanamin B. imetyletanamin C. N-imetyletanamin D. N,Nimetyletanamin Cau 4 : Hp chat CH3 NH CH2CH3 co ten ung la A. imetylamin B. etylmetylamin C. N-etylmetanamin D. imetylmetanamin. Cau 5 : Co the nhan biet lo ng dung dch CH3NH2 bang cach A. Ngi mui B. Them vai giot H2SO4 C. Qu tm D.Them vai giot NaOH Cau 6 : ng vi cong thc C3H9N co so ong phan amin la A. 3 B. 4 C. 5 D.6 Cau 7 : ng vi cong thc C4H11N co so ong phan amin bac 2 la A. 3 B. 4 C. 5 D.6 Cau 8 : ng vi cong thc C5H13N co so ong phan amin bac 3 la A. 3 B. 4 C. 5 D.6 Cau 9 : ng vi cong thc C7H9N co so ong phan amin cha vong benzen la A. 3 B. 4 C. 5 D.6 Cu 10: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi A. dd HCl B. dd NaOHC. nc Br2 D.dd NaCl Cau 11 : Chat nao la amin bac 2 ? A. H2N [CH2] NH2 B. (CH3)2CH NH2 C. (CH3)2NH CH3 D. (CH3)3N Cau 12 : Chat nao co lc baz manh nhat ? A. CH3NH2 B. (CH3)2CH NH2 C. (CH3)2NH CH3 D. (CH3)3N Cau 13 : Chat nao co lc baz yeu nhat ? A. CH3NH2 B. (CH3)2CH NH2 C. (CH3)2NH CH3 D. (CH3)3N

AMINO AXIT VA PROTEIN.

Cu 14: chng minh tnh lng tnh ca NH2 CH2 COOH (X), ta cho X tc dng vi: A. HCl, NaOH B. Na2CO3, HCl C. HNO3, CH3COOH D. NaOH, NH3 Cau 15. Aminoaxit nao sau ay co hai nhom amino. A. Axit Glutamit B. Lysin C. Alanin D. Valin Cau 16 : Aminoaxit co cong thc cau tao sau ay, ten goi nao khong ung : CH 3 CH CH COOH CH3 NH 2 A. Valin B. axit 2amino3metyl butanoicC. Axit amino Glutaric D. Axit amino isovaleric Cau 17. Co bao nhieu ten goi phu hp vi cong thc cau tao: (1) H2N 2 CH COOH : axit amino axetic. (2) H2N [CH2]5 COOH : axit - amino caporic. (3) H2N [CH2]6 COOH : axit - amino enantoic. (4) HOOC [CH2]2 CH(NH2) COOH : Axit - amino Glutaric. (5) H2N [CH2]4 CH (NH2) COOH : Axit , - iamino caporic. A. 3 B. 4 C. 5 D. 2

Nguyn Trung Kin Lp 12A1

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Cau 18. Cho cac nhan nh sau: (1) Alanin lam quy tm hoa xanh. (2) Axit Glutamic lam quy tm hoa o. (3) Lysin lam quy tm hoa xanh. (4) Axit -amino caporic la nguyen lieu e san xuat nilon6. So nhan nh ung la: A. 1 B. 2 C. 3 D.4 Cau 19. Cho cac cau sau ay: (1) Khi cho axit Glutamic tac dung vi NaOH d th tao san pham la bot ngot, m chnh. (2) Phan t cac amino axit ch co mot nhom NH2 va mot nhom COOH. (3) Dung dch cua cac amino axit eu co kha nang lam quy tm chuyen mau. (4) Cac mino axit eu la chat ran nhiet o thng. (5) Khi cho amino axit tac dung vi hon hp NaNO2 va CH3COOH kh thoat ra la N2. So nhan nh ung la: A. 1 B. 2 C. 3 D.4 Cau 20. Mot amino axit co cong thc phan t la C4H9NO2. So ong phan amino axit la A. 3 B. 4 C. 5 D.2 Cau 21 : 1 thuoc th co the nhan biet 3 chat hu c : axit aminoaxetic, axit propionic, etylamin la A. NaOH B. HCl C. Qu tm D.CH3OH/HCl Cau 22 : Cong thc cau tao cua glyxin la: A. H2NCH2CH2COOH B. H2N CH2 COOH C. CH CH COOH D.CH CH CH 3 2 2 OH OH OH NH 2 Cau 23 : Hp chat A co cong thc phan t CH6N2O3. A tac dung c vi KOH tao ra mot baz va cac chat vo c. Cong thc cau tao cua A la: + A. H2N COO NH3OH B. CH3NH 3 NO 3 . C. HONHCOONH4. D.H2N CHOH 2 NO Cau 24 : Cho cac cau sau: (1) Peptit la hp chat c hnh thanh t 2 en 50 goc amino axit. (2) Tat ca cac peptit eu phan ng mau biure. (3) T 3 - amino axit ch co the tao ra 3 tripeptit khac nhau. (4) Khi un nong nung dch peptit vi dung dch kiem, san pham se co phan ng mau biure. So nhan xet ung la: A. 1 B. 2 C. 3 D.4 Cau 25 : Peptit co cong thc cau tao nh sau: H 2 N CH CO NH CH 2 CO NH CH COOH

CH3 CH(CH3 )2 Ten goi ung cua peptit tren la: A. Ala Ala Val B. Ala Gly Val C. Gly Ala Gly D.Gly Val Ala Cau 26 : Cho cac phat bieu sau: (1) Phan t ipeptit co hai lien ket peptit. (2) Phan t tripeptit co 3 lien ket peptit. (3) So lket peptit trong pt peptit mach h co n goc - amino axit la n -1. (4) Co 3 -amino axit khac nhau, co the tao ra 6 peptit khac nhau co ay u cac goc So nhan nh ung la: A. 1 B. 2 C. 3 D. 4 Cau 27 : Cong thc nao sau ay cua pentapeptit (A) thoa ieu kien sau: + Thuy phan hoan toan 1 mol A th thu c cac - amino axit la: 3 mol Glyxin , 1 mol Alanin, 1 + Thuy phan khong hoan toan A, ngoai thu c cac amino axit th con thu c 2 i peptit: Ala-Gly; Gly- Ala va 1 tripeptit Gly-Gly-Val. A. Ala-Gly-Gly-Gly-Val B. Gly-Gly-Ala-Gly-Val C. Gly-Ala-Gly-Gly-Val D.Gly-Ala-Gly-Val-Gly Cau 28 : Thuy phan khong hoan toan tetra peptit (X), ngoai cac -amino axit con thu c cac i petit: Gly-Ala; Phe-Va; Ala-Phe. Cau tao nao la ung cua X. A. Val-Phe-Gly-Ala B. Ala-Val-Phe-Gly C. Gly-Ala-Val-Phe D. Gly-Ala-Phe-Val Cau 29 : Cho cac nhan nh sau: (1) Peptit la nhng hp chat cha cac goc -amino axit lien ket vi nhau bang nhng lien ket peptit , protein la nhng poli peptit cao phan t. (2) Protein n gian c tao thanh ch t cac -amino axit. Protein phc tap tao thanh t cac protein n gian cong vi thanh thanh phan phiprotein. A. (1) ung, (2) sai B. (1) sai, (2) ung C. (1) ung, (2) ung D. (1) sai, (2) sai Cau 30 : e phan biet xa phong, ho tinh bot, long trang trng ta se dung thuoc th nao sau ay: A. Ch dung I2 B. Ket hp I2 va Cu(OH)2 C. Ch dung Cu(OH)2 D. Ket hp I2 va AgNO3/NH3 Cau 31 : Cho cac nhan nh sau, tm nhan nh khong ung. A. Oligo peptit gom cac peptit co t 2 en 10 goc -amino axit
mol Valin. amino axit o.

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B. Poli peptit gom cac peptit co t 11 en 50 goc -amino axit C. Poli Amit la ten goi chung cua Oligo peptit va poli pepit D.Protein la nhng polipeptit cao phan t co phan t khoi ln Cau 32 : Cho cac cau sau: (1) Amin la loai hp chat co cha nhom NH2 trong phan t. (2) Hai nhom chc COOH va NH2 trong amino axit tng tac vi nhau thanh ion lng cc. (3) Poli peptit la polime ma phan t gom 11 en 50 mac xch -amino axit noi vi nhau bi (4) Protein la polime ma phan t ch gom cac polipeptit noi vi nhau bang lien ket peptit. Co bao nhieu nhan nh ung trong cac nhan nh tren: A. 1 B. 2 C. 3 D.4 Cau 33 : Cho cac dung dch sau ay: CH3NH2; NH2-CH2-COOH; CH3COONH4, long trang trng (anbumin). e nhan biet ra abumin ta khong the dung cach nao sau ay: A. un nong nhe B. Cu(OH)2 C. HNO3 D. NaOH Cau 34 : Bradikinin co tac dung lam giam huyet ap, o la mot nonapeptit co cong thc la: Arg-Pro-Pro-Gly-Phe-Ser-Pro-Phe-Arg Khi thuy phan khong hoan toan peptit nay co the thu c bao nhieu tri peptit ma thanh phan co cha phenyl alanin (phe). A. 3 B. 4 C. 5 D.6 Cau 35 : Khi b day axit HNO3 len da th cho da o mau vang: ieu giai thch nao sau ay ung. A. La do protein vung da o co phan ng mau biure tao mau vang B. La do phan ng cua protein vung da o co cha goc hidrocacbon thm vi axit tao ra san pham the mau vang C. La do protein tai vung da o b ong tu mau vang di tac dung cua axit HNO3 D.La do s toa nhiet cua axit, nhiet toa ra lam ong tu protein tai vung da o Cau 36 : Ly do nao sau ay lam cho protein b ong tu: (1) Do nhiet. (2) Do axit. (3) Do Baz. (4) Do Muoi cua KL nang. A. Co 1 l do tren B. Co 2 l do tren C. Co 3 l do tren D. Co 4 l do tren Cau 37: Hp chat nao khong phai la amino axit. A. H2N CH2 COOH B. CH3 NH CH2 COOH C. CH3 CH2 CO NH2 D. HOOC CH2(NH2) CH2 COOH Cau 38: Cho cac cong thc sau: So CTCT ng vi ten goi ung (1) H2N CH2-COOH : Glyxin (2) CH3 CHNH2 COOH : Alanin. (3) HOOC- CH2-CH2-CH(NH2)-COOH: Axit Glutamic. (4) H2N (CH2)4 CH(NH2)COOH : lizin. A. 1 B. 2 C. 3 D.4 Cau 39: Polipeptit ( NH CH2 CO n la san pham cua phan ng trung ngng: ) A. axit glutamic B. Glyxin C. axit -amino propionic D. alanin Cau 40 : H2N CH2 COOH phan ng c vi: (1) NaOH. (2) CH3COOH (3) C2H5OH A. (1,2) B. (2,3) C. (1,3) D.(1,2,3) Cau 41 : Cho cac chat sau ay: (1) Metyl axetat. (2) Amoni axetat. (3) Glyxin. (4) Metyl amoni fomiat. (5) Metyl amoni nitrat (6) Axit Glutamic. Co bao nhieu chat lng tnh trong cac chat cho tren: A. 3 B. 4 C. 5 D.2 Cau 42: Amino axit co bao nhieu phan ng cho sau ay: phan ng vi axit, phan ng vi baz, phan ng trang bac, phan ng trung hp, phan ng trung ngng, phan ng vi ancol, phan ng vi kim loai kiem. A. 3 B. 4 C. 5 D.6 Cau 43: Alanin co the phan ng c vi bao nhieu chat trong cac chat cho sau ay: Ba(OH)2; CH3OH; H2N CH2 COOH; HCl, Cu, CH3NH2, C2H5OH, Na2SO4, H2SO4. A. 7 B. 4 C. 5 D.6 + NaOH + HCl Cau 44: Cho s o bien hoa sau: Alanin X Y Chat Y la chat nao sau ay: A. CH3-CH(NH2)-COONa B. H2N-CH2-CH2-COOH C. CH3-CH(NH3Cl)COOH D. CH3H(NH3Cl)COONa Cau 45: Cho cac nhan nh sau: (1) Thuy phan protein bang axit hoac kiem khi un nong se cho hon hp cac aminoaxit. (2) Phan t khoi cua mot aminoaxit ( gom mot chc NH2 va mot chc COOH ) luon luon la so le. (3) Cac aminoaxit eu tan c trong nc. (4) Dung dch aminoaxit khong lam quy tm oi mau. Co bao nhieu nhan nh khong ung: A. 1 B. 2 C. 3 D.4 Cau 46: Cho cac nhan nh sau ay: (1) Co the tao c 2 ipeptit t hai aminoaxit la Alanin va Glyxin. (2) Khac vi axit axetic, axit amino axetic co the tham gia phan ng vi axit HCl hoac phan
ng trung ngng. cac lien ket peptit.

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(3) Giong vi axit axetic, aminoaxit co the tdung vi bazo tao muoi va nc. (4) Axit axetic va amino axetic co the ieu che t muoi Natri tng ng cua chung bang 1 phan ng hoa hoc. Co bao nhieu nhan nh ung. A. 1 B. 2 C. 3 D.4 Cau 47: Thuoc th thch hp e nhan biet 3 dung dch sau ay: Axit fomic; Glyxin; axit , diaminobutyric. A. AgNO3/NH3 B. Cu(OH)2 C. Na2CO3 D. Quy tm Cau 48: Co 4 dung dch loang khong mau ng trong bon ong nghiem rieng biet, khong dan nhan: Abumin, Glixerol, CH3COOH, NaOH. Chon mot trong cac thuoc th sau e phan biet 4 chat tren: A. Quy tm B. Phenol phtalein C.HNO3 acD. CuSO4 Cau 49 : Thuoc th nao di ay e nhan biet c tat ca cac dung dch cac chat trong day sau: Long trang trng, glucoz, Glixerol va ho tinh bot. A. Cu(OH)2/OH- un nong B. Dd AgNO3/NH3 C. Dd HNO3 ac D. Dd Iot Cau 50: e nhan biet dung dch cac chat : Glixin, ho tinh bot, long trang trang ta the the tien hanh theo trnh t nao sau ay: A. Dung quy tm, dung dch Iot B. Dung dch Iot, dung dung dch HNO3 C. Dung quy tm, dung dch HNO3 D.Dung Cu(OH)2, dung dung dch HNO3 Cu 51: Cho cc phn ng : H2NCH2COOH + HCl ClH3N+CH2COOH. H2NCH2COOH + NaOH H2NCH2COONa + H2O. Hai phn ng trn chng t axit aminoaxetic. A. ch c tnh axit B. c tnh cht lng tnh C.ch c tnh baz D.c tnh oxi ha v tnh kh Cau 52: iem khac nhau gia protein vi cabohirat va lipit la A. Protein co khoi lng phan t ln B. Protein luon co cha nguyen t nit C. Protein luon co nhom chc OH D. Protein luon la chat hu c no. Cau 53 : Tripeptit la hp chat A. ma moi phan t co 3 lien ket peptit B. co 3 goc aminoaxit giong nhau C. co 3 goc aminoaxit khac nhau D. co 3 goc aminoaxit Cau 54: Co bao nhieu peptit ma phan t co 3 goc aminoaxit khac nhau ? A. 3 chat B. 4 chat C. 5 chat D. 6 chat Cau 55 : Hp chat nao sau ay thuoc loai ipeptit ? A. H2N CH2CONH CH2CONH CH2COOH B. H2N CH2CONH CH(CH3) COOH C. H2N CH2CH2CONH CH2CH2COOH D. H2N CH2CH2CONH CH2COOH Cu 56: Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 8,15 g B. 0,85 g C. 7,65 g D. 8,10 g Cau 57: The tch nc brom 3% (d = 1,3g/ml) can dung e ieu che 4,4g tribormanilin la A. 164,1ml B. 49,23ml C. 146,1ml D. 16,41ml Cau 58: Khoi lng anilin can dung e tac dung vi nc brom thu c 6,6g ket tua trang la A. 1,86g B. 18,6g C. 8,61g D.6,81g Cu 59: Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. X c th l : A. axit glutamic B. valin C. glixin D. alanin Cau 60: 1 mol -aminoaxit X tac dung va het vi 1 mol HCl tao ra muoi Y co ham lng clo la 28,287%. Cong thc cau tao cua X la A. CH3 CH(NH2) COOH B. H2N CH2 CH2 COOH C. NH2 CH2 COOH D. H2N CH2 CH(NH2) COOH Cau 61: Khi trung ngng 13,1g axit -aminocaproic vi hieu suat 80%, ngoai aminoaxit con d ngi ta thu c m gam polime va 1,44g nc. Gia tr m la A. 10,41g B. 9,04g C. 11,02g D.8,43g Cau 62: Mot amin n chc cha 19,718% nit ve khoi lng. Cong thc phan t cua amin la A. C4H5N B. C4H7N C. C4H9N D.C4H11N Cau 63: ot chay hoan toan mot amin no n chc thu c V H2 O = 1,5V CO2 . Cong thc phan t cua amin la A. C2H7N B. C3H9N C. C4H11N D.C5H13N Cau 64: Cho 3,04g hon hp A gom 2 amin no n chc tac dung va u vi 400ml dd HCl 0,2M c 5,96g muoi. Tm the tch N2 (ktc) sinh ra khi ot het hon hp A tren ? A. 0,224 lt B. 0,448 lt C. 0,672 ltD. 0,896 lt Cau 65: Cho 17,7g mot ankylamin tac dung vi dung dch FeCl 3 d thu c 10,7g ket tua. Cong thc phan t cua ankylamin la A. C2H7N B. C3H9N C. C4H11N D.CH5N

Trac nghiem bai tap AMIN - AMINO AXIT VA PROTEIN

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Cu 66. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A. 100ml B. 50ml C. 200ml D. 320ml Cu 67. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Bit phn t khi ca cc amin u < 80. Cng thc phn t ca cc amin l p n A, B, C hay D? A. CH3 NH2; C2H5NH2 v C3H7NH2 B. C2H3 NH2; C3H5NH2 v C4H7NH2 C. C2H5 NH2; C3H7NH2 v C4H9NH2 D. C3H7 NH2; C4H9NH2 v C5H11NH2 Cu 68. Cho 10 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 15,84 gam hn hp mui. Nu trn 3 amin trn theo t l mol 1 : 20 : 5 theo th t phn t khi tng dn th cng thc phn t ca 3 amin l p n no sau y? A. CH5N, C2H7N, C3H7NH2 B. C2H7N, C3H9N, C4H11N C. C3H9N, C4H11N, C5H11N D.C3H7N, C4H9N, C5H11N Cu 69. t chy hon ton 6,2 gam mt amin no, n chc phi dng ht 10,08 lt kh oxi (ktc). Cng thc ca amin l cng thc no sau y? A. C2H5NH2 B.CH3NH2 C. C4H9NH2 D. C3H7NH2 Cu 70. Hp cht hu c to bi cc nguyn t C, H, N l cht lng, khng mu, rt c, t tan trong nc, d tc dng vi cc axit HCl, HNO2 v c th tc dng vi nc brom to kt ta. Hp cht o c cng thc phn t nh th no? A. C2H7N B. C6H13N C. C6H7N D. C4H12N2 Cu 71. t chy hon ton 100ml hn hp gm imetylamin v hai hirocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc th tch o cng iu kin). Cng thc phn t ca hai hirocacbon l p n no? A. C2H4 v C3H6 B. C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 Cu 72. Trung ha 3,1 gam mt amin n chc X cn 100ml dung dch HCl 1M. Cng thc phn t ca X l p n no? A. C2H5N B. CH5N C. C3H9N D. C3H7N Cu 73. t chy hon ton hn hp hai amin no n chc ng ng lin tip, ta thu c hn hp sn phm kh vi t l th tch nCO2: nH2O = 8 : 17. Cng thc ca hai amin l p n no? A. C2H5NH2, C3H7NH2 B. C3H7NH2, C4H9NH2 C. CH3NH2, C2H5NH2 D.C4H9NH2, C5H11NH2 Cu 74. t chy hon ton mt amin n chc cha no c mt lin kt i mch cacbon ta thu c CO2 v H2O theo t l mol = 8:9. Vy cng thc phn t ca amin l cng thc no? A. C3H6N B. C4H9N C. C4H8N D. C3H7N Cu 75. Cho 1,52 gam hn hp hai amin no n chc (c trn vi s mol bng nhau) tc dng va vi 200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc. A. Nng mol ca dung dch HCl bng 0,2M B. S mol ca mi cht l 0,02mol C. Cng thc thc ca hai amin l CH5N v C2H7N D. Tn gi hai amin l metylamin v etylamin Cu 76. Ngi ta iu ch anilin bng cch nitro ha 500g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu, bit hiu sut mi giai on 78% ? A. 346,7g B. 362,7g C. 463,4g D. 358,7g Cu 77. Cho lng d anilin phn ng hon ton vi dung dch cha 0,05mol H2SO4 long. Khi lng mui thu c bng bao nhiu gam? A. 7,1g B. 14,2g C. 19,1g D. 28,4 g Cu 78. Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng vi vi 0,075 mol Br2 to kt ta. Lng cc cht NH3, C6H5NH3 v C6H5OH ln lt bng bao nhiu? A. 0,01 mol; 0,005mol v 0,02mol B. 0,05 mol; 0,005mol v 0,02mol C. 0,05 mol; 0,002mol v 0,05mol D. 0,01 mol; 0,005mol v 0,02mol Cu 79. t chy hon ton 100ml hn hp gm imetylamin v 2 hirocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc th tch o cng iu kin). Thnh phn % th tch ca ba cht trong hn hp theo tng phn t khi ln lt bng bao nhiu? A. 20%; 20% v 60% B. 25%; 25% v 50% C. 30%; 30% v 40% D. 20%; 60% v 20% Cu 80. Este X c iu ch t aminoaxit v ru etylic. T khi hi ca X so vi hiro 5,15 . t chy hon ton 10,3 gam X thu c 17,6gam kh CO2 v 8,1gam nc v 1,12 lt nit (ktc). Cng thc cu to thu gn ca X l cng thc no sau y? A. H2N (CH2)2 COO C2H5 B. H2N CH(CH3) COO C. H2N CH2 CH(CH3) COOHD. H2N CH2 COO CH3 Cu 81. X l mt aminoaxit no ch cha 1 nhm - NH2 v 1 nhm COOH. Cho 0,89 gam X tc dng vi HCl va to r a 1,255 gam mui. Cng thc cu to ca X l cng thc no sau y? A. H2N CH2 COOH B. CH3 CH(NH2) COOH C. CH3 CH(NH2) CH2 COOH D. C3H7 CH(NH2) COOH Cu 82. X l mt amioaxit no ch cha 1 nhm NH2 v 1 nhm COOH. Cho 15,1 gam X tc dng vi HCl d thu c 18,75 gam mui. Cng thc cu to ca X l cng thc no? A. C6H5 CH(NH2) COOH B. CH3 CH(NH2) COOH C. CH3 CH(NH2) CH2 COOH D. C3H7CH(NH2)CH2COOH Cu 83. X l mt amioaxit no ch cha 1 nhm NH2 v 1 nhm COOH. Cho 23,4 gam X tc dng vi HCl d thu c 30,7 gam mui. Cng thc cu to thu gn ca X l cng thc no? A. CH3 CH(NH2) COOH B. H2N CH2 COOH C. H2N CH2CH2 COOH D. CH2 = C(CH3)CH(NH2)COOH

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Cu 84. Cht A c % khi lng cc nguyn t C, H, O, N ln lt l 32%, 6,67% 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng NaOH va tc dng dd HCl, A c cng thc cu to nh th no? A. CH3 CH(NH2) COOH B. H2N (CH2)2 COOH C. H2N CH2 COOH D. H2N (CH2)3 COOH Cu 85. Cht A c thnh phn % cc nguyn t C, H, N ln lt l 40,45%, 7,86%, 15,73% cn li l oxi. Khi lng mol phn t ca A <100 g/mol. A tc dng c vi NaOH v vi HCl, c ngun gc t thin nhin, A c CTCT nh th no. A. CH3 CH(NH2) COOH B. H2N (CH2)2 COOH C. H2N CH2 COOH D. H2N (CH2)3 COOH Cau 86 : Este A c ieu che t aminoaxit B (ch cha C, H, O, N) va ancol metylic. T khoi hi cua A so vi H2 la 44,5. CTCT cua A la A. H2N CH2 CH2 COOCH3 B. H2N CH2 COOCH3 C. H2N CH2 CH(NH2) COOCH3 D. CH3 CH(NH2) COOCH3 Cau 87. Dung dch X gom HCl va H2SO4 co pH = 2. e trung hoa hoan toan 0,58g hon hp 2 amin no n chc bac 1 (co so ngt C nho hn hoac bang 4) phai dung 1 lt dd X. Cong thc cua 2 amin co the la A. CH3NH2 va C4H9NH2 B. C2H5NH2 va C4H9NH2 C. C3H7NH2 va C4H9NH2 D. Ca A va B Cau 88: ot chay hoan toan ong ang X cua axit aminoaxetic, thu c t le so mol CO2 : H2O la 6 : 7. Cac cong thuc cau tao co the co cua X la: A. CH3CH(NH2)COOH ; H2NCH2CH2COOH B.CH3CH2CH(NH2)COOH; H2NCH2CH2CH2COOH C. CH3CH2CH2CH(NH2)COOH ; H2N[CH2]4COOH D. CH3[CH2]3CH(NH2)COOH ; H2N[CH2]5COOH Cau 89: ot chay hoan toan a mol aminoaxit A thu c 2a mol CO 2 va a/2 mol N2. Aminoaxit A la A. H2NCH2COOH B. H2N[CH2]2COOH C. H2N[CH2]3COOH D.H2NCH(COOH)2 Cau 90: Cho 0,01 mol aminoaxit X tac dung va u vi 80ml dd HCl 0,125M, sau o co can dd thu c 1,835g muoi. Phan t khoi cua X la A. 174 B. 147 C. 197 D. 187 Cu 91: Sp xp tnh baz cc cht sau theo th t tng dn. A. NH3 < C2H5NH2 < C6H5NH2 B. C2H5NH2 < NH3 < C6H5NH2 C. C6H5NH2 < NH3 < C2H5NH2 D. C6H5NH2 < C2H5NH2 < NH3 Cu 92:Cho cc cht H2NCH2COOH, CH3COOH, CH3NH2. Dng thuc th no sau y phn bit cc dung dch trn? A. NaOH B. HCl C. CH3OH/HCl D. Qu tm Cu 93:Thuc th no sau y dng phn bit cc dung dch b mt nhn gm: glucoz, glixerol, etanol, lng trng trng.(dng c th nghim xem nh ) A. NaOH B. AgNO3/NH3 C. Cu(OH)2 D. HNO3 Cu 94: Anilin khng phn ng vi cht no sau y? A. HCl B. NaOH C. Br2 D. HNO2 Cu 95:Cht no sau y l amin bc 3? A. (CH3)3C NH2 B. (CH3)3N C. (NH3)3C6H3 D. CH3NH3Cl Cu 96: Amin c cng thc CH3 CH(NH2) CH3 tn l: A. metyletylamin B. etylmetylamin C. isopropylamin D. propylamin Cu 97:Trong cc tn gi sau y, tn gi no khng ng vi cht CH3 CH(NH2) COOH? A. axit 2 aminopropanoic B. Alanin C. axit aminopropionic D. valin Cu 98:T glyxin v alanin c th to ra my ipeptit ? A. 1 B. 2 C. 3 D. 4 Cu 99: Cho cc cht CH3NH2, C2H5NH2, CH3CH2CH2NH2. Theo chiu tng dn phn t khi Nhn xt no sau y ng? A. Nhit si tng dn, tan trong nc tng dn B. Nhit si gim dn, tan trong nc tng dn C. Nhit si tng dn, tan trong nc gim dn D. Nhit si gim dn, tan trong nc gim dn Cu 100:Cht no sau y lm qu tm m ha xanh? A. glyxin B. anilin C. phenol D. lysin Cu 101: Cht hu c C3H9N c s ng phn amin l : A. 2 B. 3 C. 4 D. 5 Cu 102: Nguyn nhn gy nn tnh baz ca amin l: A. Do amin tan nhiu trong H2O B. Do phn t amin b phn cc mnh C. Do nguyn t N c m in ln nn cp electron chung ca nguyn t N v H b ht v pha N D. Do nguyn t N cn cp eletron t do nn phn t amin c th nhn proton Cu 103: Hp cht no sau y thuc loi ipeptit ? A. H2N CH2CONH CH2CONH CH2COOH B. H2N CH2CONH CH(CH3) COOH C. H2N CH2CH2CONH CH2COOH D. H2N CH2CONH CH2CH2COOH Cu 104: Mt peptit c cng thc: Tn ca peptit trn l H 2 N CH CO NH CH 2 CO NH CH COOH

CH3

CH(CH3 )2

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A. glyxinalaninvalin

B. Glyxylalanylvalyl C. glyxylalanylvalin D. glyxylalanyllysin Cu 105: Trong dung dch cc amino axit thng tn ti: A. ch dng ion lng cc B. va dng ion lng cc va dng phn t vi s mol nh nhau C. ch dng phn t D. dng ion lng cc v mt phn nh dng phn t Cu 106: t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng, thu c 22 g CO2 v 14,4 g H2O. Cng thc phn t ca hai amin l : A. CH3NH2 v C2H7N B. C2H7N v C3H9N C. C3H9N v C4H11N D. C4H11N v C5H13 N Cu 107: Khi t chy hon ton cht X l ng ng ca axit aminoaxetic th t l th tch CO 2: H2O (hi) l 6 : 7. Xc nh cng thc cu to ca X (X l amino axit) A. CH3 CH(NH2) COOH B. CH3 CH2 CH(NH2) COOH C. CH3 CH(NH2) CH2 COOH D. H2NCH2 CH2 COOH Cu 108: Mt dung dch amin n chc X tc dung va vi 200ml dung dch HCl 0,5M. Sau phn ng thu c 9,55 gam mui. Xc nh cng thc ca X? A. C2H5NH2 B. C6H5NH2 C. C3H5NH2 D. C3H7NH2 Cu 109: Thy phn hon ton 1 mol pentapeptit Y th thu c 3 mol alanin, 1 mol valin v 1 mol glyxin. Khi thy phn khng hon ton Y th thu c cc ipeptit AlaVal, ValAla v tri peptit GlyAlaAla. Trnh t cc amino axit trong Y l: A. Ala Val Ala Ala Gly B. Val Ala Ala Gly Ala C. Gly Ala Ala Val Ala D. Gly Ala Ala Ala Val Cu 110: Khi b axit nitric dy vo da th ch da c mu A. vng B. Tm C. xanh lam D. hng Cu 111:Axit amino axetic khng tc dng vi cht : A. CaCO3 B. KCl C. CH3OH D. H2SO4 long Cu 112: Khi thy phn n cng protit thu c cc cht A. Gucoz B. Axit C. Amin D. Aminoaxit Cu 113:Trong cc cht sau : X1: H2N CH2 COOH X2: CH3 NH2 X3: C2H5OH X4: C6H5OH Nhng cht c kh nng th hin tnh baz l : A. X1,X3 B. X1,X2 C. X2,X4 D. X1,X2,X3 Cu 114: Khi cho axit amino axetic tc dng vi ancol etylic c mt dung dch HCl th sn phm hu c thu c l A. ClH3N CH2 COOH B. H2NCH2 COOC2H5 C. ClNH3 CH2 COOC2H5 D. ClH3N CH2 COOH Cu 115: Cho phn ng: C4H11O2N + NaOH A + CH3NH2 + H2O Vy cng thc cu to ca C4H11O2N l : A. CH3COOCH2CH2NH2 B. C2H5COONH3CH3 C. C2H5COOCH2 NH2 D. C2H5COOCH2CH2NH2 Cu 116:Cht khng tham gia phn ng trng hp l: A. isopren B. Cloropren C. vinyl axetat D. axit aminocaproic Cu 117: Polime sau c tn l: ( CH 2 CH )n

COOCH3
A. poli(metylacrylat) B. poli(metylmetacrylat) C. poli(vinylaxetat) D. poli(metylpropionat) Cu 118: thu c poli(vinyl ancol) ta thc hin A. trng hp CH2 = CH OH B. trng ngng CH2 = CH OH C. thy phn poli(vinylaxetat) trong mi trng kim D. trng hp vinyl ancol Cu 119: T nilon-7 thuc loi A. t nhn to B. t thin nhin C. t tng hp D. t este Cu 120: Khi clo ha PVC, trung bnh c k mt xch trong mch PVC phn ng vi 1 phn t clo. Sau khi clo ha thu c mt polime cha 63,96% clo v khi lng. Gi tr ca k l A. 3 B. 4 C. 5 D. 6 Cu 121: Tnh cht no di y khng phi tnh cht ca cao su t nhin? A. tnh n hi B. khng thm kh v nc C. khng tan trong xng v benzen D. khng dn nhit Cu 122: ng dng ca polime no di y khng ng ? A. PE c dng lm mng mng, ti ng. B. PVC c dng lm ng dn nc, vi che ma. C. poli(metyl metacrylat) c dng knh t, rng gi. D. nha novolac c dng lm vt liu cch in, v my. Cu 123: Loi cao su no di y l kt qu ca phn ng ng trng hp? A. cao su BuNa B. cao su isopren C. cao su BuNa-N D. cao su clopren Cu 124:Khi trng ngng phnol vi fomanehit trong iu kin: phnol ly d, mi trng H+ th thu c A. nha rezol B. nha rezit C. nha novolac D. nha bakelit Cu 125: Cao su lu ha c dng cu trc mch polime A. khng phn nhnh B. mch phn nhnh C. mng khng gian D. mch thng Cu 126:Tn no sau y sai khi gi polime ( HN [CH 2 ] CO )n A. policaproamit B. nilon 6 C. t capron D. t caprolactam

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Cu 127: Hp cht hu c H2N CO NH CH2OH c tn: A. monometylolure B. monometylure C. Monometylicure D. metylolure Cu 128: Vinyl xianua cn c tn gi A. acrilonitrin B. acrilicnitrin C. acrilonitric D. acrilonitr Cu 129: Polime c cng thc: ( CO C6 H4 COO CH 2 C 6 H10 CH 2 O ) n Polime ny c iu ch t monome A. HOOCC6H4COOH v HOCH2C6H10CH2OH B. HOOCC6H4CH2OH v HOOCC6H10CH2OH C. HOOCC6H4COOH v HOCH2C6H10COOH D. HOOCC6H4CH2OH v HOCH2C6H10COOH Cu 130: Cht c kh nng trng hp thnh cao su l: A. B. CH 2 = C CH CH 2 CH 2 C = C = CH 2

CH CH 3 C. CH 3 CH 3 C = CH D. CH2=CHCH2CH2CH3 2 Cu 131: T monome no su y c th iu ch c poli(vinyl ancol): A. CH2=CHCOOCH3 B. CH2=CHOCOCH3 C. CH2=CHCOOC2H5 D. CH2=CHCH2OH Cu 132. nhn bit cc cht metanol, glixerol, dung dch glucoz, dung dch anilin ta c th tin hnh theo trnh t no sau y? A. Dung dch AgNO3/NH3, dng Cu(OH)2/OH B. Dng Na kim loi, dng dung dch brom C. Dng Cu(OH)2/OH , dng dung dch brom D. Dng dung dch NaOH, dng dung dch HCl Cu 133. Hy sp xp cc cht sau y theo trt t tng dn tnh baz: (1) anilin; (2) etylamin; (3) ietylamin; (4) natri hiroxit; (5) amoniac. A. (1)<(5)<(2)<(3)<(4) B. (1)<(2)<(5)<(3)<(4) C. (2)<(1)<(3)<(4)<(5) D. (2)<(5)<(4)<(3)<(1) Cu 134. Ancol v amin no sau y cng bc: A. (CH3)3COH v (CH3)3CNH2 B. (CH3)2CHOH v (CH3)2CHNH2 C. CH3NHCH3 v CH3CH(OH)CH3 D. (C6H5)2NH v C6H5CH2OH Cu 135. Tnh baz ca etylamin mnh hn amoniac c gii thch l do: A. Nguyn t N cn cp electron cha tham gia lin kt B. Nguyn t N trng thi lai ho sp3 C. Etylamin lm qu tm tm nc ho xanh, amoniac khng c tnh cht ny D. Do gc C2H5 c tnh y electron Cu 136. Pht biu no sau y lun ng vi amin: A. Khi lng phn t ca amin n chc lun l s l B. Khi lng phn t ca amin n chc lun l s chn C. Khi t chy hon ton a mol amin X lun thu c a/2 mol N2 D. A v C u ng Cu 137. Pht biu no sau y khng ng: A. Cc amin u c tnh baz B. Tnh baz ca cc amin u mnh hn NH3 C. Phenylamin c tnh baz yu hn NH3 D. Tt c cc amin n chc u cha s l nguyn t H trong phn t Cu 138. Hy sp xp cc cht sau y theo the t tng dn tnh baz: (1) metylamin; (2) amoniac; (3) etylamin; (4) anilin; (5) n propylamin. A. (4)<(5)<(2)<(3)<(1) B. (4)<(2)<(1)<(3)<(5) C. (2)<(1)<(3)<(4)<(5) D. (2)<(5)<(4)<(3)<(1) Cu 139. Thuc th no di y dng nhn bit oc tt c cc cht cha trong cc dung dch ring bit: lng trng trng, glucoz, glixerol v h tinh bt. A. Dung dch AgNO3/NH3 B. dung dch HNO3 c C. Cu(OH)2/OH D. Dung dch iot Cu 140. Pht biu no sau y khng ng: A. Thu phn protein bng axit hoc kim khi un nng sn phm thu c l hn hp cc aminoaxit. B. Khi lng phn t ca mt aminoaxit cha mt nhm - NH2 v mt nhm COOH lun l s l C. Cc aminoaxit u tan trong nc D. Tt c cc dung dch aminoaxit u lm i mu qu tm Cu 141. Hy ch ra cu khng ng trong cc cu sau: A. Tt c cc amin u c kh nng nhn proton. B. Tnh baz ca cc amin u mnh hn NH3 C. Cng thc ca amin no n chc, mch h l CnH2n + 3N D. Metylamin c tnh baz mnh hn amoniac Cu 142. Mt hp cht hu c X c cng thc phn t C3H9O2N. Cho X phn ng vi dung dch NaOH, un nh thu c mui Y v kh Z lm giy qu tm nc ho xanh. Cht rn Y tc dng vi NaOH rn (CaO, t0 cao) thu c CH4. X c cng tc cu to : A. CH3 COO NH4 B. C2H5 COO NH4 C. CH3 COO H3NCH3 D. A v C u ng Cu 143. Hp cht no di y c tnh baz mnh nht: A. CH3 C6H4 NH2 B. O2N C6H4 NH2 C. CH3 O C6H4 NH2 D. Cl C6H4 NH2 Cu 144. Hp cht no sau ay c nhit si cao nht: A. n butylamin B. Tert butylamin C. Metyl n propylamin D. imetyl etylamin Cu 145 . nhn bit cc cht trong cc dung dch: glixin, h tinh bt, anbumin ta dng thuc th no sau y: A. Dng qu tm v dung dch iot B. Dng dung dch iot v dung dch HNO3 c C. Dng dung dch HNO3 v qu tm D. Dng Cu(OH)2 v dung dch HNO3 Cu 146. Mt hp cht hu c c CTPT C3H7O2N c bao nhiu ng phn aminoaxit? A. 1 B. 2 C. 3 D. 4

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Cu 147. t chy hon ton mt amin khng no n chc trong phn t c mt lin kt i gc hirocacbon thu c n H2 O : n CO2 = 9 : 8 . Cng thc phn t ca amin l: A. C4H9N B. C4H11N C. C3H7N D. C2H5N Cu 148. t chy hon ton hn hp 2 amin no n chc k tip nhau trong dy ng ng thu c n H2 O : n CO2 = 2 :1 . Cng thc phn t ca hai amin l: A. C3H7NH2 v C4H9NH2 B. CH3NH2 v C2H5NH2 C. C2H5NH2 v C3H7NH2 D. C4H9NH2 v C5H11NH2 Cu 149. Mt hn hp gm 2 amin no n chc k tip nhau trong dy ng ng. Ly 21,4 gam hn hp cho vo dung dch FeCl3 c d thu c mt kt ta c khi lng bng khi lng ca hn hp trn. Cng thc phn t ca hai amin l: A. C3H7NH2 v C4H9NH2 B. CH3NH2 v C2H5NH2 C. C2H5NH2 v C3H7NH2 D. C4H9NH2 v C5H11NH2 Cu 250. t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6 gam CO2, 12,6 gam H2O v 69,44 lt N2. Bit trong khng kh ch cha N2 v O2 (80%). Cc th tch kh o ktc. Amin X c Cng thc phn t: A. C3H7NH2 B. CH3NH2 C. C4H9NH2 D. C2H5NH2 Cu 151. Cho 20 hn hp 3 amin n chc no, ng ng lin tip nhau tc dng vi dung dch HCl 1M va , sau c cn dung dch thu c 31,68 gam hn hp mui. Bit t l mol ca cc amin theo th t t amin nh n amin ln l 1:10:5 th ba amin c Cng thc phn t l: A. CH3NH2, C2H5NH2, C3H7NH2 B. C2H5NH2, C3H7NH2, C4H9NH2 C. C3H7NH2, C4H9NH2, C5H11NH2 D. Tt c u sai Cu 152. t chy hon ton amin no n chc X thu c n H2 O : n CO2 = 3 : 2 . X tc dng vi axit nitr gii phng kh N2. Tn ca amin X l: A. Metylamin B. Etylamin C. Metyletylamin D. Trimetylamin Cu 153. Mt mui X c cng thc C3H10O3N2. Ly 14,64 gam X cho phn ng ht vi 150 ml dung dch KOH 1M. C cn dung dch sau phn ng thu c phn hi v cht rn. Trong phn hi c cha cht hu c Y (bc 1). Trong cht rn ch cha mt hp cht v c. Cng thc phn t ca Y l: A. C3H7NH2 B. CH3OH C. C4H9NH2 D. C2H5OH Cu 154. t chy ht a mol aminaxit X c 2a mol CO2 v a/2 mol N2. Aminoaxit trn c cng thc cu to l: A. H2NCH2COOH B. H2NCH2CH2COOH C. H2NCH2CH2CH2COOH D. H2NCH(COOH)2 Cu 155. Hp cht hu c X mch h, thnh phn phn t gm C, H, N. Trong %N chim 23,7% (theo khi lng), X tc dng vi HCl theo t l mol 1:1. X c Cng thc phn t: A. C3H7NH2 B. CH3NH2 C. C4H9NH2 D. C2H5NH2 Cu 156. t chy hon ton mt amin thm X thu c 3,29 gam CO 2, 0,99 gam H2O v 336ml N2 (ktc). trung ho 0,1 mol X cn 600ml dung dch HCl 0,5M. Cng thc phn t ca X: A. C7H11N B. C7H7NH2 C. C7H11N3 D. C7H9N2 Cu 157. C hai amin bc mt: A (ng ng ca anilin) v B (ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra 336ml kh N2 (ktc). Khi t chy hon ton amin B cho n H2 O : n CO2 = 3 : 2 . Cng thc phn t ca hai amin l: A. CH3C6H4NH2 v CH3CH2CH2NH2 B. C2H5C6H4NH2 v CH3CH2CH2NH2 C. CH3C6H4NH2 v CH3CH2CH2CH2NH2 D. C2H5C6H4NH2 v CH3CH2CH2CH2NH2 Cu 158. Hn hp X gm hai amin no bc mt X v Y. X cha 2 nhm axit v mt nhm amino, Y cha mt nhm axit v mt nhm amino. t chy hon ton 1 mol X hoc 1 mol Y th thu c s mol CO2 nh hn 6. Bit t l khi MX = 1,96 . Cng thc cu to ca 2 amino axit l: lng phn t MY A. H2NCH2CH(COOH)CH2COOH v H2NCH2COOH B. H2NCH2CH(COOH)CH2COOH v H2N(CH2)2COOH C. H2NCH(COOH)CH2COOH v H2N(CH2)2COOH D. H2NCH(COOH)CH2COOH v H2NCH2COOH Cu 159. t chy hon ton 17,4 gam amino axit X (axit n chc) th thu c 0,6 mol CO 2; 0,5 mol H2O v 0,1 mol N2. X c cng thc cu to l: A. H2NCH2CH2COOH hoc CH3CH(NH2)COOH B. H2NCH = CHCOOH hoc CH2 = C(NH2)COOH C. H2NCH2COOH D. H2NCH2CH(NH2)COOH Cu 160. A l mt aminoaxit cha mt nhm amino v mt nhm axit. Cho 1,335g A phn ng va vi dung dch HCl to ra 1,8825g mui. A c cng thc cu to l: A. H2NCH2COOH B. CH3CH2CH(NH2)COOH C. CH3CH(NH2)COOH D. Kt qu khc Cu 161. Hp cht X l mt aminoaxit. Cho 0,01 mol X tc dng va vi 80ml dung dch HCl 0,125M. Sau c cn dung dch thu c 1,875g mui. Khi lng phn t X bng bao nhiu ? A. 145 vC B. 151 vC C. 189 vC D. 149 vC Cu 162. Cho 0,01 mol aminoaxit X phn ng ht vi 40ml dung dch HCl 0,25M to thnh 1,115g mui khan. X c cng thc cu to l: A. H2NCH2COOH B. CH3CH(NH2)COOH C. CH3CH2CH(NH2)COOH D. CH3COONH4 Cu 163. Mt hp cht hu c X mch thng c Cng thc phn t l C3H10O2N2. X tc dng vi dung dch kim to cht kh lm qu tm m ho xanh, mt khc X tc dng vi dung dch axit to thnh mui amin bc mt. X c Cng thc phn t no sau y? A. H2NCH2CH2COONH4 B. CH3CH(NH2)COONH4 C. CH3CH2CH(NH2)COONH4 D. A v B ng Cu 164. Hy ch ra nhng gii htch sai trong cc hin tng sau: A. Khi lm sch nc ng ngi ta thng cho lng trng trng g vo v un ln l hin tng vt l

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B. Khi nu canh cua, xut hin gch cua ni ln l hin tng ho hc C. Sa ti lu ngoi khng kh cho mi chua l hin tng vt l D. Ancol lu ngoi khng kh cho mi chua l hin tng ho hc Cu 165. nhn bit dung dch cc cht lng trng trng, x phng, glixol, h tinh bt ta c th tin hnh theo trnh t sau: A. un nng, dng Na kim loi, dng Cu(OH)2 B. Dng vi git HNO3 c, dng Cu(OH)2, ng dung dch iot C. Dng dung dch iot, dng Cu(OH)2 D. Dng vi git HNO3 c, un nng, dng dung dch iot Cu 166. nhn bit cc cht lng du ho, du m, gim n v lng trng trng ta c th tin hnh theo th t no sau y: A. Dng qu tm, dng vi git HNO3 c, dng dung dch NaOH B. Dng dung dch Na2CO3, dng dung dch HCl, dng dung dch NaOH C. Dng dung dch Na2CO3, dng dung dch iot, dng Cu(OH)2 D. Dng phenolphtalein, dng HNO3 c, dng H2SO4 c Cu 167. Cc amino axit no c th phn ng vi tt c cc cht trong nhm no sau y: A. Dd NaOH, dd HCl, C2H5OH, C2H5COOH B. Dd NaOH, dd HCl, CH3OH, dd brom C. Dd H2SO4, dd HNO3, CH3OC2H5, dd thuc tm D. dd HCl, C2H5OH, C2H5COOH Cu 168. tch ring hn hp gm ba cht lng: C 6H6, C6H5OH v C6H5NH2 ngi ta c th tin hnh theo trnh t sau: A. Dng dung dch HCl, lc, chit, sc kh CO2 B. Dng dung dch NaOH, lc nh, chit, dung dung dch HCl, chit, dng dung dch NaOH C. Dng dung dch NaOH, lc nh, chit, sc kh CO2. D. Dng dung dch brom, lc nh, chit, dng dung dch NaOH, kh CO2 Cu 169. nhn bit dung dch cc cht: glucoz, etylamin, anilin, glixerol, ta c th tin hnh theo trnh t no di y? A. Dng dung dch AgNO3/NH3, dng qu tm, dng nc brom B. Dng dung dch AgNO3/NH3, dng Cu(OH)2 lc nh C. Dng qu tm, dng Na kim loi, dng nc brom D. Dng phnolphtalein, dng Cu(OH)2 lc nh Cu 170. chng minh alanin l mt aminoaxit, ch cn cho phn ng vi: A. CH3OH/HCl B. Dd NaOH C. Dung dch HCl D. Dd NaOH v ddch HCl Cu 171. Cho qu tm vo dung dch phenylalanin. Ta thy hin tng qu tm. A. Ho B. Ho xanh C. Khng i mu D. Ho vng Cu 172. Nhng cng thc cu to no di y tng ng vi Cng thc phn t C2H5O2N. A. CH3CH2NO2 B. H2NCH(OH)CHO C. H2NCH2COOH D. Tt c u ng Cu 173. Mt hp cht hu c X c Cng thc phn t C 3H7O2N. X phn ng vi dung dch brom, X tc dng vi dung dch HCl v dung dch NaOH. Cht hu c X c cng thc cu to: A. H2N CH = CHCOOH B. CH2 = CH COONH4 C. H2N CH2 CH2COOH D. A v B ng Cu 174. Amin c Cng thc phn t C3H7N c tt c bao nhiu ng phn? A. 1 B. 2 C. 3 D. 4 Cu 175. t chy hon ton 6,2g mt amin no n chc cn dng 10,08 lt kh oxi (ktc). Cng thc phn t ca amin l: A. C2H5NH2 B. CH3NH2 C. C3H7NH2 D. C4H9NH2 Cu 176. un nng 100ml dung dch mt aminoaxit 0,2 M tc dng va vi 80ml dung dch NaOH 0,25M. Sau phn ng ngi ta c cn dung dch thu c 2,5 g mui khan. Mt khc, ly 100g dung dch aminoaxit trn c nng 20,6 % phn ng va vi 400ml dung dch HCl 0,5 M. Cng thc phn t ca aminoaxit l: A. H2NCH2COOH B. CH3CH(NH2)COOH C. CH3CH2CH(NH2)COOH D. CH3COONH4 Cu 177. Khi t chy hon ton mt ng ng ca glixin thu c n H2 O : n CO2 = 7 : 6 (phn ng chy sinh ra kh N2). X c cng thc cu to l: A. H2NCH2COOH B. CH3CH(NH2)COOH C. NH2CH2CH2COOH D. B v C ng Cu 178. Aminoaxit X cha mt nhm amin bc mt trong phn t. t chy hon ton mt lng X thu c CO 2 v N2 t l th tch l 4:1 . X c cng thc cu to l: A. H2NCH2COOH B. CH3CH(NH2)COOH C. NH2CH2CH2COOH D. CH3CH2CH(NH2)COOH Cu 179. t chy hon ton hn hp 2 amin no n chc ng ng lin tip nhau, thu c n H2 O : n CO2 = 2 :1 . Hai amin c Cng thc phn t l: A. C3H7NH2 v C4H9NH2 B. CH3NH2 v C2H5N C. C2H5NH2 v C3H7NH2 D. C4H9NH2 v C5H11NH2 Cu 180. Mt hp cht hu c X c Cng thc phn t C 2H7NO2, X tc dng c vi dung dch NaOH v dung dch HCl. X c th c cng thc cu to: A. H2NCH2COOH B. CH3COONH4 C. HCOOH3NCH3 D. B v C ng Cu 181. Cht X c phn trm khi lng cc nguyn t C, H, O, N ln lt l 32%, 6,67%, 42,66% v 18.67%. T khi hi ca X so vi khng kh nh hn 3. X va tc dng vi dung dch HCl va tc dng vi dung dch NaOH. Cng thc cu to ca X: A. H2NCH2COOH B. CH3CH(NH2)COOH C. NH2CH2CH2COOH D. CH3CH2CH(NH2)COOH Cu 182. Thy tinh hu c c th iu ch c bng cch thc hin phn ng trng hp monome no sau y: A. Metylmetacrylat B. Axit acrylic C. Axit metacrylic D. Etilen Cu 183. Mt s polime c iu ch t cc monome sau: (1) CH2 = CHCl+ CH2 = CH OCOCH3 (2) CH2 = CH CH3 (3) CH2 = CH CH = CH2 +C6H5 CH = CH2

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Nguyn Trung Kin Lp 12A1

4) H2N (CH2)10 COOH Cc phn ng thuc loi phn ng l trng ngng? A. (1) v (2) B. (3) C. (2) v (3) D. (4) Cu 184. Mt s polime c iu ch t cc monome sau: (1) CH2 = CHCl+ CH2 = CH OCOCH3 (2) CH2 = CH CH3 (3) CH2 = CH CH = CH2 +C6H5 CH = CH2 (4) H2N (CH2)10 COOH Cc phn ng thuc loi phn ng ng trng hp A. (1) v (3) B. (3) C. (2) v (3) D. (4) Cu 185. Lm th no phn bit c cc d dng lm bng da tht v bng da nhn to ( P.V.C )? A. t da tht khng cho mi kht, t da nhn to cho mi kht B. t da tht cho mi kht v da nhn to khng cho mi kht C. t da tht khng chy, da nhn to chy D. t da tht chy, da nhn to khng chy Cu 186. Lm th no phn bit la sn xut t t nhn to (t visco, t xenluloaxtat) v t thin nhin (t tm, len) A. t t nhn to cho mi kht, t thin nhin khng cho mi kht B. t t nhn to khng cho mi kht, t thin nhin cho mi kht C. t t nhn to khng chy, t thin nhin chy D. t t nhn to chy, t thin nhin khng chy Cu 187. Metyl acrylat c iu ch t axit v ru no? A. CH2=C(CH3)COOH v C2H5OH B. CH2=CH-COOH v C2H5OH C. CH2=C(CH3) COOH v CH3OH D. CH2=CH-COOH v CH3OH Cu 188. Ch ra pht biu no sau y l sai? A. Bn cht cu to ho hc ca t tm v len l protit B. Bn cht cu to ho hc ca t nilon l poliamit C. Qun o nilon, len, t tm khng nn git vi x phng c kim cao D. T nilon, t tm, len rt bn vng vi nhit Cu 189. Ch ra iu ng khi ni v da tht v simili (PVC) A. Da tht l protit, simili l polime tng hp B. Da tht l protit ng vt, simili l protit thc vt C. t hai mu, da tht c mi kht, simili khng c mi kht D. B, C u ng Cu 190. T nilon 6,6 l: A. Hexaclo xiclohexan B. Poliamit ca axit adipic v hexametylendiamin C. Poliamit ca - aminocaproic D. Polieste ca axit adipic v etylenglycol Cu 191. Polime thin nhin no sau y l sn phm ca phn ng trng ngng? A. Tinh bt (C6H10O5)n B. T tm C. Cao su ( C5H8)n D. Cng thc khc Cu 192. Dng t nilon ph bin nht l nilon 6,6 c 63,68% C; 12,38% N; 9,8%H; 14,4% O. Cng thc thc nghim ca nilon 6 l: A. C5NH9O B. C6N2H10O C. C6NH11O D. C6NH11O2 Cu 193. Polime no c iu ch bng phn ng trng hp? A. T Capron B. Xenluloztrinitrat C. Nilon 6,6 D. Poliphnolfomandehit Cu 194. Nilon 6,6 l polime c iu ch bng phn ng? A. Trng hp B. Trng ngng C. ng trng hp D.ng trng ngng Cu 195. S kt hp cc phn t nh( monome) thnh cc phn t ln (polime) ng thi loi ra cc phn t nh nh H2O , NH3 , HClc gi l A. s tng hp B. s polime ha C. s trng hp D. s trngngng Cu 196. Phn t polime bao gm s lp i lp li ca rt nhiu cc A. Monome B. an mch C. nguyn t D. mt xch cu trc Cu 197. Qa trnh polime ha c km theo s to thnh cc phn t n gin gi l A. ime ha B. polime ha C. trng ngng D. ng trng hp Cu 198. Cht no sau y c kh nng trng hp thnh cao su. Bit rng khi hir ha cht thu c isopentan? A. CH3-C(CH3)=CH=CH2 B. CH3-CH2-CCH C. CH2=C(CH3)-CH=CH2 D. Tt c u sai Cu 199. Nha polivinylclorua (P.V.C) c ng dng rng ri trong i sng, tng hp ta dng phn ng ? A. trng ngng B. trng hp C. polime ha D. thy phn Cu 200. Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang, nhng loi t no thuc loi t nhn to? A. T tm v t enan B. T visco v t nilon-6,6 C. T visco v t axetat D. T nilon-6,6 v t capron Cu 201. Phn t protit c th xem l mt polime t nhin nh s t cc monome l cc -aminoaxi A. trng ngng B. trng hp C. polime ha D. thy phn Cu 202. T c tng hp t xenluloz c tn l A. t axetat B. polieste C. t poliamit D. t visco Cu 203. iu no sau y khng ng ? A. t tm , bng , len l polime thin nhin B. t visco, t axetat l t tng hp C. Nilon-6,6 v t capron l poliamit D. Cht do khng c nhit nng chy c nh Cu 204. Cht no trong phn t khng c nit ? A. t tm B. protit C. t visco D. t capron Cu 205. Cng thc no sai vi tn gi?

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A. teflon (-CF2-CF2-)n B. thy tinh hu c [-CH2-CH(COOCH3)-]n C. nitron(-CH2-CHCN-)n D. t enng [-NH-(CH2)6-CO-]n Cu 206. Nilon-6,6 c cng thc cu to l A. [-NH-(CH2)5-CO-]n B. [-NH-(CH2)6-NH-CO-(CH2)4-CO-]n C. [-NH-(CH2)6-CO-]n D. Tt c u sai Cu 207. Polime no c cu trc mch phn nhnh ? A. poli isopren B. PVC C. Amilopectin ca tinh bt D. PE Cu 208. Polime no c kh nng lu ha ? A. cao su buna B. poli isopren C. cao su buna s D. Tt c u ng Cu 209. iu no sau y khng ng v t capron ? A. thuc loi t tng hp B. l sn phm ca s trng hp C. to thnh t monome caprolactam D. l sn phm ca s trng ngng Cu 300. Polivinyl ancol l polime c iu ch bng phn ng trng hp t monome sau y ? A. CH2=CH-COOCH3 B. CH2=CH-OCOCH3 C. CH2=CH-COOC2H5 D. CH3OCO-CH=CH2 Cu 301. T aminoaxit c cng thc phn t C3H7O2N c th to thnh bao nhiu loi poliamit khc nhau? A. 2 B. 3 C. 4 D. 5 Cu 302. Pht biu no khng ng ? A. phn ng trng hp khc vi phn ng trng ngng. B. trng hp 1,3-butadien ta c cao su buna l sn phm duy nht C. phn ng este ha l phn ng thun nghch D. Phn ng thy phn este trong mi trng baz l phn ng mt chiu Cu 303. Hp cht A c cng thc phn t l C11H22O4 . Bit A tc dng c vi NaOH to ra mui ca axit hu c B mch thng v 2 ru l etanol v propan-2-ol. Tm cu sai. A. l dieste B. t B c th iu ch c t nilon-6,6 C. l HCOO-(CH2)4-COOH (axit glutamic) D. tn gi ca A l etyl isopropyl adipat Cu 304. Trong s cc dn xut ca benzen c cng thc phn t C8H10O. C bao nhiu ng phn X tha mn? (X) + NaOH khng phn ng. H 2O xt X Y polime A. 1 B. 2 C. 3 D. 4 Cu 305. Polime [-CH2-CH(CH3)-CH2-CH(C6H5)-]nc to t: A. 2-metyl-3-phenyl B. 2-metyl-3-phenylbutan C. propilen vstiren D. isopren v toluen Cu 306. Polime[-CH2-CH(CH3)-CH2-C(CH3)=CH-CH2-]n c iu ch bng phn ng trng hp monome A. CH2=CH-CH3 B. CH2=C(CH3)-CH=CH2 C. C A v B D. CH2=C(C2H5)-CH2-CH=CH2 Cu 307. Chn pht biu sai A. Thy tinh hu c l polime c dng mch thng. B. H s trng hp l s lng n v mt xch monome trong phn t monome, c th xc nh mt cch chnh xc C. Do phn t ln hoc rt ln nn nhiu polime khng tan hoc kh tan trong dung mi thng thng D. Polime c dng mng li khng gian l dng polime chu nhit km nht Cu 308. Trong s cc loi t sau: (1) [-NH(CH2)6 NH OC (CH2)4 CO-]n , (2) [-NH-(CH2)5-CO-]n, (3) [C6H7O2(OOC-CH3)3]n T thuc loi si poliamit l: A. (1), (3) B. (1), (2) C. (2), (3) D. (1),(2),(3) Cu 309. Protin c th m t nh A. cht polime B. cht polieste C. polime ng trng hp D. polime trng ngng Cu 310. Cho hp cht sau: [-CO-(CH4)4-CO-NH-(CH2)6-NH]n. Hp cht ny thuc loi polime no A. cht do B. cao su C. t nilon D. t capron Cu 311. Cho s phn ng sau: A B+H2; B+D E; E+O2 F; F+ B G ; nG polivinyl axetat A l cht no ? A. ancol etylic B. metan C. andehit axetic D. tt c ng Cu 312. T c sn xut t xenluloz l : A. t capron B. t nilon-6,6 C. t visco D. t tm Cu 313. Cho cc polime sau: (-CH2- CH2-)n, (-CH2- CH=CH- CH2-)n, (-NH-CH2-CO-)n. Cng thc ca cc monome khi trng hp hoc trng ngng to ra cc polime trn ln lt l A. CH2=CH2,CH2=CH- CH= CH2,H2N-CH2-COOH B. CH2=CH2,CH3- CH=CH-CH3,H2N-CH2-CH2-COOH C. CH2=CH2,CH3- CH=C=CH2,H2N- CH2- COOH D. CH2=CHCl, CH3- CH=CH- CH3,CH3- CH(NH2)- COOH Cu 314. Polietilen c khi lng phn t 500 vCc h s trng hp n l: A. 50 B. 500 C. 1700 D. 178 Cu 315. Polisaccarit ( C6H10O5)n c khi lng phn t l 162000 vC c h s trng hp l : A. 1600 B. 162 C. 1000 D. 10000 Cu 316. Polime X c phn t khi M=280.000 vC v h s trng hp n =10.000. X l A. PE B. PVC C. (-CF2-CF2-)n D. Polipropilen Cu 317. Trng hp etilen c polietilen. Nu t chy ton b lng polime s thu c 8800g CO 2. H s trng hp ca qu trnh l A. 100 B. 150 C. 200 D. 300

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Nguyn Trung Kin Lp 12A1

Cu 318. H s polime ha trong mu cao su buna (M 40.000) bng A. 400 B. 550 C. 740 D. 800 Cu 319. Clo ho PVC c mt loi t Clorin cha 66,6% Clo. Trung bnh mt phn t Clo tc dng vi bao nhiu mc xch PVC? A. 1 B. 2 C. 3 D. 4 Cu 320. Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l A. 3 B. 6 C. 4 D. 5 Cu 321. Xenluloz trinitrat l cht d chy v n mnh c iu ch t xenluloz v axit nitric. Tnh th tch axit nitric 99,67% (c khi lng ring 1,52g/ml) cn sn xut 59,4 kg xenluloz trinitrat . ( H= 90%.) A. 11,28 lt B. 7,86 lt C. 36,5 lt D. 27,72 lt Cu 322. Khi lng phn t ca t capron l 15000 vC. Tnh s mt xch trong cng thc phn t ca lai t ny A. 113 B. 133 C. 118 D. 150 Cu 323. Polivinyl clorua c iu ch t kh thin nhin (metan chim 95%) theo s chuyn ha v hiu sut mi giai an nh sau 15% 95% 90% CH4 C2H2 C2H3Cl PVC Mun tng hp 1 tn PVC th cn bao nhiu m3 kh thin nhin ( ktc) ? A. 5589m3 B. 5883m3 C. 2941m3 D. 5880m3 Cu 324. Khi trng ngng 7,5g axit amino axetic vi hiu sut l 80%, ngoi amino axit d ngi ta cn thu c m gam polime v 1,44g nc. Ga tr ca m l A. 5,25 g B. 5,56 g C. 4,56 g D. 4,25 g Cu 325. Trng hp han tan 6,25gam vinylclorua c m gam PVC. S mt xch -CH2-CHCl- c trong m gam PVC trn l A. 6,02.1021 B. 6,02.1022 C. 6,02.1020 D. 6,02.1023 Cu 326. C 2 mt xch ca PVC phn ng vi 1 phn t clo to thnh t clorin . Phn trm khi lng clo trong t clorin l A. 56,8% B. 66,7% C. 73,2% D. 79,7% ---------------------------Ht---------------------------.1 1. C bao nhiu ng phn amin ng vi CTPT C4H11N ? A. 5

B. 6

C. 7 B. 4

D. 8
.2 2. Amin thm c cng thc phn t C7H9N c my ng phn ?A. 3

C. 5 D. 6
.3 3. Cht no sau y l amin bc 2 ?

A. H2N - CH2 - CH2-NH2 C

B. CH3 - NH- C2H5

CH3 CH CH3 | C. NH2

D. A, B,

.4 4. Ru v amin no sau y cng bc ? .5

A. (CH3)3COH v (CH3)3CNH2 C. (CH3)2CHOH v (CH3)2CHNH2

B. C6H5NHCH3 v C6H5CHOHCH3 D. (CH3)2CHOH v (CH3)2CHCH2NH2.

.6 5. Cho cc cht c cu to nh sau:

(1) CH3 - CH2 - NH2 , (2) CH3 - NH - CH3, (3) CH3 - CO - NH2, (4) NH2 - CO - NH2 (5) NH2 - CH2 COOH, (6) C6H5 - NH2, (7) C6H5NH3Cl, (8) C6H5 - NH - CH3, (9) CH2 = CH NH2. Cht no l amin ? A. (1); (2); (6); (7); (8) B. (1); (3); (4); (5); (6); (9) C. (3); (4); (5) D. (1); (2); (6); (8); (9).
.7 6. Phng php no thng dng iu ch amin ? A. Cho dn xut halogen tc

dng vi NH3
.8 B. Cho ru td vi NH3

C. Hiro ho hp cht nitrin

D. Kh hp cht nitro bng hiro

ngt .
.9 7. ng dng no sau y khng phi ca amin ?

A. Cng ngh nhum. Cng ngh giy

B. Cng nghip dc C. Cng ngh tng hp hu c.

D.

.10 8. Nguyn nhn no gy nn tnh baz ca amin ?

A. Do amin tan nhiu trong H2O. B. Do phn t amin b phn cc mnh. C. Do nguyn t N c m in ln nn cp e chung ca ng t N v H b ht v pha N. Nguyn Trung Kin Lp 12A1 Trang 55

D. Do nguyn t N cn cp eletron t do nn phn t amin c th nhn proton.

.11 9. Amin no sau y c tnh baz ln nht ?

A. CH3CH=CH-NH2 A. NH3

B. CH3C C-NH2

C. CH3CH2CH2NH2 D. CH3CH2NH2 D. CH3-CH(CH3)-NH2

.12 10. Cht no sau y c tnh baz mnh nht ?

B. C6H5NH2

C. CH3-CH2-CH2-NH2

.13 11. C cc cht: CH3CH2NHCH3(1), CH3CH2CH2NH2(2), (CH3)3N (3).Tnh baz tng dn

theo dy no A. (1) < (2) < (3) (2)

B. (2) < (3) < (1) C. (3) < (2) < (1)

D. (3) < (1) <

.14 12. Cho cc cht sau: Ancol etylic (1), etylamim (2), metylamim (3), axit axetic (4).

Dy sp sp theo chiu c nhit si tng dn l dy no ? A. (2) < (3) < (4) < (1) B. (2) < (3) < (4) < (1) C. (3) < (2) < (1) < (4) (3) < (2) < (4)
.15 13. Cho cc cht : (1) C6H5NH2,

D. (1) <

(2) C2H5NH2, (3) (C6H5)2NH, (4) (C2H5)2NH, (5) NaOH, (6) NH3. Dy sp xp ng theo th t gim dn tnh baz l dy no A. (1) > (3) > (5) > (4) > (2) > (6) B. (5) > (6) > (2) > (1) > (2) > (4) C. (5) > (4) > (3) > (5) > (1) > (2) D. (5) > (4) > (2) > (6) > (1) > (3) A. C6H5NH2 + Cl2. B, C p/bit cc kh A. Dung dch HCl v C A. CaCl2 ng C6H5NH3Cl. X + Y c th l Y B. C6H5NH2 + HCl C. (C6H5)2NH + HCl. D. C A,

.16 14. Cho phn ng : X +

.17 15. C 3 cht kh : imetylamin, metylamin, trimetylamin.C th dng dd no

B. Dung dch FeCl3

C. Dung dch HNO2

D. C B

.18 16. Dung dch etylamin c tc dng vi dung dch ca mui no di y ?

B. NaCl

C. FeCl3 v FeCl2

D. Tt c u phn

.19 17. Khi t nng mt ng ng ca metylamin ngi ta thy t l th tch cc kh

v hi VCO2 : VH2O = 2 : 3 . Cng thc phn t ca amin l A. C2H7N B. C3H9N C. C4H11N vi V ml dd HCl 1M. Gi tr ca V l D. Kt qu khc v 7,2 g H2O. Gi tr ca a l mol D. 0,2 mol A. 100

D. Kt qu khc B. 150 C. 200

.20 18. Cho 9 g hh X gm 3 amin: propylamin, etylmetylamin, trimetylamin X tc dng va

.21 19. t chy hon ton a mol hh X gm 2 amin no n chc thu c 5,6 lt CO2 (ktc)

A. 0,05 mol

B. 0,1 mol

C. 0,15

.22 20. t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy

ng ng, thu c 22 g CO2 v 14,4 g H2O. CTPT ca hai amin l A. CH3NH2 v C2H7N B. C2H7N v C3H9N C. C3H9N v C4H11N C5H13N
.23 21. C cc dung dch:(1) Dd HCl,

D.

C4H11N

(2) Dd H2SO4, (3) Dd NaOH, (4) Dung dch brom, (5) Dd CH3 - CH2- OH, (6) Dung dch CH3COOC2H5, Anilin tc dng c vi nhng dd no? A. (1), (2), (3) B. (4), (5), (6) C. (3), (4), (5) D. (1), (2), (4) hu c s 14 - AMIN l A. (1), (4) cht Trang 56 B. (1), (3) C. (1), (3), (4) D. C 4

.24 1. Cho cc dd: (1) HNO2, (2) FeCl2, (3)CH3COOH, (4) Br2 Cc dd tc dng c vi anilin

Nguyn Trung Kin Lp 12A1

.25 2. Pht biu no sau y sai ?

A. Anilin l baz yu hn NH3 v nh hng ht el ca nhn benzen ln nhm - NH2 bng hiu ng lin hp. B. Anilin khng lm thay i mu giy qu tm m. C. Anilin t tan trong H2O v gc C6H5 - k nc. D. Nh c tnh baz , anilin tc dng c vi dung dch brom.
.26 3. Cho cc cht :C2H6 ; C2H5Cl ; C2H5NH2 ; CH3COOC2H5 ; CH3COOH ; CH3CHO ; CH3OCH3.

Cht no to c lin kt H lin phn t ? A. C2H6 B. CH3COOCH3 C. CH3CHO ; C2H5Cl

D. CH3COOH ; C2H5NH2

.27 4. Nguyn nhn no sau y lm anilin tc dng c vi nc brom?

A. Do nhn thm benzen c h thng lin kt bn vng. B. Do nhn thm benzen ht electron. C. Do nhn thm benzen y electron. D. Do nhm - NH2 y electron lm tng mt electron cc v tr o- v p.28 5. Pht biu no sau y sai ?

A. Cch tnh bc ca amin khc vi ca ru. B. Nguyn nhn gy ra tnh baz ca cc amin l do trn nguyn t N cn mt cp e cha tham gia lin kt c th nhng cho proton H+ C. Anilin lm qu tm m ha xanh. D. Gc phenyl (-C6H5) v nhm chc amino (-NH2) trong phn t anilin c nh hng qua li vi nhau. A. Phenol trong nc lm qu tm ha . B. Anilin trong nc lm qu tm ha xanh. C. Etylamin trong nc lm cho qu tm chuyn thnh mu xanh. D. Dung dch natriphenolat khng lm qu tm i mu.

.29 6. Cu no ng khi ni v s i mu ca cc cht khi gp qu tm ?

.30 7. Cho s :

trn l ? A. X (C6H6), Y (C6H5NO2), Z (C6H5NH2) B. X (C6H5CH(CH3)2), Y (C6H5OH), Z (C6H5NH2) C. X (C6H5NO2), Y (C6H5NH2), Z (C6H5OH) D. C A v C
.31 8. C 4 ng nghim cha cc hn hp sau: (1) Anilin + nc. (2) Anilin + dung dch HCl

(X) (Y) (Z) M (trng). Cc cht X, Y, Z ph hp s

d, (3) Anilin + C2H5OH ,(4) Anilin + benzen. Trong ng nghim no c s tch lp ?

.32 A. Ch c (1)

B. (3), (4 )

C. (1), (3), (4)

D. C 4

ng
.33 9. Thuc th thch hp phn bit 3 cht lng : phenol, anilin, benzen l

A. Dung dch HNO2 sau y A. Dung dch HCl C A, B, C A. CH3 - CH2 - CH2 - NH2 CH3 - NH - CH3

B. Dung dch FeCl3

C. A v D

D. Nc Br2

.34 10. ti to li anilin t dung dch phenyl amoniclorua phi dng dung dch cht no

B. Dung dch NaOH

C. Dung dch Br2

D.

.35 11. A + HCl RNH3Cl. Trong A (CxHyNt) c %N = 31,11%. CTCT ca A l

B. CH3 - NH - CH3

C. C2H5NH2

D.

C2H5NH2

.36 12. Nhit si ca cc cht C4H10 (1), C2H5NH2 (2), C2H5OH (3) tng dn theo th t

no ? A. (1) < (2) < (3) B. (1) < (3) < (2) C. (2) < ( 3) < (1) 2) < ( 1) < (3) 12. Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi A.dd HCl B.dd NaOH C. nc Br2 D. dd NaCl 13. Co the nhan biet lo ng dung dch CH3NH2 bang cach A.Ngi mui B.Them vai giot H2SO4 C. Qu tm D.Them vai NaOH 14: Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A.8,15 g B.0,85 g C.7,65 g D. 8,10 g Nguyn Trung Kin Lp 12A1

D. (

giot

Trang 57

15: The tch nc brom 3% (d = 1,3g/ml) can dung e ieu che 4,4g tribormanilin la A.164,1ml B. 49,23ml C.146,1ml D. 16,41ml 17: Mot amin n chc cha 19,718% nit ve khoi lng. Cong thc phan t cua amin la A.C4H5N B.C4H7N C.C4H9N D. C4H11N 18: ot chay hoan toan mot amin no n chc thu c V H O = 1,5V CO . Ctpt cua amin la A.C2H7N B.C3H9N C.C4H11N D. C5H13N 19: Cho 3,04g hon hp A gom 2 amin no n chc tac dung va u vi 400ml dd HCl 0,2M c 5,96g muoi. Tm the tch N 2 (ktc) sinh ra khi ot het hon hp A tren ? A.0,224 lt B. 0,448 lt C.0,672 lt D. 0,896 lt 20: Cho 17,7g mot ankylamin tac dung vi dung dch FeCl3 d thu c 10,7g ket tua. Ctpt cua ankylamin la. A. C2H7NB. C3H9NC. C4H11N D. CH5N Cu 66. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A.100ml B.50ml C.200ml D. 320ml 16: Khoi lng anilin can dung e tac dung vi nc brom thu c 6,6g ket tua trang la A.1,86g B.18,6g C.8,61g D. 6,81g
2 2

Cho cc amin: NH3, CH3NH2, CH3-NH-CH3, C6H5NH2. mnh ca tnh baz c sp theo th t tng dn nh sau: A. NH3 < C6H5NH2 < CH3-NH-CH3 < CH3NH2 B. C6H5NH2 < NH3 < CH3NH2 < CH3-NH-CH3 C. CH3-NH-CH3 < NH3 < CH3NH2 < C6H5NH2 D. C6H5NH2 < CH3NH2 < NH3 < CH3-NH-CH3 Pht biu no sau y l sai: A. Anilin l mt baz c kh nng lm qu tm ha xanh. B. Anilin cho c kt ta trng vi nc brom. C. Anlilin c tnh baz yu hn amoniac. D. Anilin c iu ch trc tip t nitrobenzen. Nguyn nhn anilin c tnh baz l: A. Phn ng c vi dung dch axit. B. Xut pht t amoniac. C. C kh nng nhng proton. D. Trn N cn mt i electron t do c kh nng nhn H+ . Tin hnh th nghim trn hai cht phenol v anilin, hy cho bit hin tng no sau y sai: A. Cho nc brom vo th c hai u cho kt ta trng. B. Cho dung dch HCl vo th phenol cho dung dch ng nht, cn anilin tch lm hai lp. C. Cho dung dch NaOH vo th phenol cho dung dch ng nht, cn anilin tch lm hai lp. D. Cho hai cht vo nc, vi phenol to dung dch c, vi anilin hn hp phn lm hai lp. Mt amin n chc trong phn t c cha15,05% N. Amin ny c cng thc phn t l: A. CH5N B. C2H5N C. C6H7N

Trang 58

Nguyn Trung Kin Lp 12A1

D. C4H9N Cho chui bin i sau:dd NaOH Benzen I. C6H5NO2 III. C6H5NH3Cl X, Y ln lt l: A. I, II B. II, IV C. II, III D. I, III Andehit l hp cht hu c trong phn t c mang nhm chc: X Y Anilin II. C6H4(NO2)2 IV. C6H5OSO2H

B1: Pht biu no di y v aminoaxit l khng ng? A. Aminoaxit l HCHC tp phc, phn t chc ng thi nhm amino v nhm cacboxyl. B. Hp cht H2NCOOH l aminoaxit n gin nht. C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-) D. Thng thng dng ion lng cc l dng tn ti chnh ca aminoaxit trong dung dch. B2: Tn gi ca aminoaxit no di y l ng? A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)-COOH (valin) D. HOOC-(CH2)2-CH(NH2)-COOH (axit glutaric) B3: C3H7O2N c my ng phn aminoaxit (Vi nhm amin bc nht)?A.5 B. 2 C. 3 D. 4 B4: Khng nh no sau y khng ng v tnh cht vt l ca aminoaxit? A. Tt c u cht rn. B. Tt c u l tinh th, mu trng. C. Tt c u tan tt trong nc. D. Tt c u c nhit nng chy cao. B5: Aminoaxetic khng th phn ng vi: A. Ancol B. Cu(OH)2 C. axit nitric D. Ba(OH)2 B6: 0,01 mol aminoaxit A phn ng va vi 0,02 mol HCl hoc 0,01 mol NaOH. Cng thc ca A c dng: A. H2NRCOOH B. (H2N)2RCOOH C. H2NR(COOH)2 D. (H2N)2R(COOH)2 B7: Cho 0,1 mol A ( - aminoaxit dng H2NRCOOH) phn ng ht vi HCl to 11,15g mui. A l? A. Glixin B. Alanin C. Phenylalanin D. Valin B8: Cho - aminoaxit mch thng A c cng thc dng H2NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 9,55 g mui. A l cht no sau y? A. Axit 2-aminopropanionic B. Axit 2-aminobutanioic C. Axit 2-aminopentaioic D. Axit 2- aminohexanioic B9: Cho cc dy chuyn ha : +HCl +HCl NaOH Glixin +NaOH A X; Glixin B Y X v Y ln lt l cht no? A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa B10: Cho glixin (X) phn ng vi cc cht i y, trng hp no PTHH c vit khng chnh xc? A. X + HCl ClH3NCH2COOH B. X + NaOH H2NCH2COONa + H2O C. X + CH3OH + HCl ClH3NCH2COOCH3 + H2O HCl(kh ) D. X + CH3OH NH2CH2COOCH3 + H2O B11: Mt HCHC X c t l khi lng C:H:O:N = 9: 1,75: 8: 3,5 tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br2. Cng thc phn t ca X v cng thc cu to ca X, Y ln lt l: A. C3H7O2N; H2N-C2H4-COOH; H2N-CH2-COO-CH3 B. C3H7O2N; H2N-C2H4COOH; CH2=CH-COONH4
+

Nguyn Trung Kin Lp 12A1

Trang 59

C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2 D. C3H5O2N; H2N-C2H2-COOH; CH C-COONH4 B12: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: A. CH3(CH2)4NO2 B. NH2-CH2COO-CH2-CH2-CH3 C. NH-CH2-COO=CH(CH2)3 D. H2N-CH2-CH2-COOC2H5 B13: X l - aminoaxit no ch cha mt nhm -NH2 v mt nhm -COOH. Cho 10,3g X tc dng vi dd HCl d thu c 13,95g mui clohirat ca X. CTCT thu gn ca X l: A. CH3CH(NH2)COOH B. H2NCH2COOH C. H2NCH2CH2COOH D. CH3CH2CH(NH2)COOH B14: Cho cc cht sau: (X1) C6H5NH2; (X2)CH3NH2 ; (X3) H2NCH2COOH; (X4) HOOCCH2CH2CH(NH2)COOH (X5) H2NCH2CH2CH2CH2CH(NH2)COOH. Dd no lm qu tm ha xanh? A. X1, X2, X5 B. X2, X3,X4 C. X2, X5 D. X1, X5, X4 B15: Dd no di y lm qu tm ha ? (1) NH2CH2COOH ; (2) Cl-NH3+-CH2COOH ; (3) H3N+CH2COO- ; (4) H2N(CH2)2CH(NH2)COOH ; (5) HOOCCH2CH2CH(NH2)COOH A. (3) B. (2) C. (2), (5) D. (1), (4) B16: A l HCHC c cng thc phn t C5H11O2N. un A vi dd NaOH thu c mt hh cht c CTPT C2H4O2NNa v cht hu c B. Cho hi ca B qua CuO/t0 thu c cht C bn trong dd hn hp ca AgNO3 v NH3. CTCT ca A l: A. CH3(CH2)4NO2 B. H2NCH2COOCH2CH2CH3 C. H2NCH2COOCH(CH3)2 D. H2NCH2CH2COOC2H5 B17: Este X c iu ch t aminoaxit Y v ancol etylic. T khi hi ca X so vi H2 bng 51,5. t chy hon ton 10,3g X thu c 8,1 g H2O v 1,12 lt N2(ktc). CTCT thu gn ca X l: A. H2N-(CH2)2-COO-C2H5 B. H2N-CH2-COO-C2H5 C. H2N-CH(CH3)COOH D. H2N-CH(CH3)-COOC2H5 B18: HCHC X c cha 15,7303% nguyn t N; 35,9551% nguyn t O v khi lng v cn c cc nguyn t C v H. Bit X c tnh lng tnh v khi dd X tc dng vi dd HCl ch xy ra mt phn ng duy nht. CTCT thu gn ca X l: A. H2NCOOCH2CH3 B. H2NCH2CH(CH3)COOH C. H2NCH2CH2COOH D. H2NCH2COOCH3 B19: Tn gi no sau y l ca peptit H2NCH2CONHCH(CH3)CONHCH2COOH? A. Gly-ala-gly B. Gly-gly-ala C. Ala-gly-gly D. Ala-gly-ala B20: Mt hp cht cha cc nguyn t C, H, O, N c phn t khi bng 89 c.C. t chy hon ton 1 mol hp cht thu c 3 mol CO2 0,5 mol N2 v a mol hi nc. CTPT ca hp cht l? A. C4H9O2N C. - CH NO D. H2NB.CH2HCO2NNH - CH - CO - NH C3H7- CO2 - NH - CH2 - COOHC3H5NO2 - C2 - 5O B21: Thy phn hp cht:
CH2-COOH CH2- C6H5

Thu c aninoaxit no sau y: A. H2N-CH2-COOH B. HOOC-CH2-CH(NH2)-COOH C. C6H5-CH2-CH(NH2)-COOH D. Hn hp A, B, C. B23: Trong cc cht sau Cu, HCl, C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxxetic tc dng c vi nhng cht no? A. Tt c cc cht. B. HCl, KOH, CH3OH/ kh HCl. C. C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl D. Cu, HCl, KOH, Na2SO3, CH3OH/ kh HCl. B24: X l mt aminoaxit no ch cha mt nhm NH2- v mt nhm -COOH. Cho 0,89 gam X tc dng vi dd HCl va to ra 1,255 gam mui. CTCT ca X l? A. H2N-CH2-COOH B. CH3 - CHNH2-COOH C. CH3 -CHNH2 -CH2-COOH D. C3H7-CHNH2-COOH B25: X l - aminoaxit no ch cha mt nhm -NH2 v mt nhm -COOH. Cho 15,1 gam X tc dng vi dd HCl d thu c 18,75g mui ca X. X c th l cht no sau: A. C6H5CH(NH2)COOH B. CH3CH(H2N)COOH C. CH3CH(H2N)CH2COOH D. C3H7CH(NH2)COOH B26: - aminoaxit l aminoaxit m nhm amino gn cacbon v tr th my? Trang 60 Nguyn Trung Kin Lp 12A1

A. 1

B. 2

C. 3

D. 4

01). Vit phn ng trng ngng mt s cht quan trng thng gp sau : a) Axit -amino caproic to t capron ( l axit 6- amino hexanoic ). b) Axit -amino enantoic to t enang ( l axit 7-ammino heptanoic ). c) Axit a ipic + hexametylen iamin to t nilon-6,6 ( l axit hexaioic- 1,6 ). 02). C 3 ng phn A, B ,C cng cng thc phn t C4H9O2N : -A t/dng vi HCl v Na2O - B t/d Hiro mi sinh t o B1, B1 t/d H2SO4 to B2 , B2 t/d NaOH to B1. - C t/d ng NaOH to Mu i + NH3. Xc nh cng thc cu to ca A ,B , C v vit cc phn ng minh ho. 03). A mch thng c cng thc phn t C3H10O2N2 ; A tc dng vi baz kim cho kh NH3 ; A tc dng vi axit v c cho mui ca amin bc mt . Tm cng thc cu to ca A. Vit phn ng ca A vi Ba(OH)2 v H2SO4. 04). -Vit phn ng to ipeptit v tripeptit t Glyxin - Vit cng thc cu to thu gn ca cc cht thu c sau khi thu phn tng cht sau trong mi trng axit v m i trng kim ring r. + ) H2N-CH2-CO-NH CH(CH3)-CO-NH-CH2-COOH. + ) CH3-CH(NH2)-CO-NH-CH(CH2C OOH)-CO-NH-CH(CH2C6H5)-CO-NH-CH2-COOH PHN BI TP TRC NGHIM Cu 1 : ( 2008-A) Pht biu khng ng l : A. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt B. Aminoaxit l nhng hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl C. Trong dd, H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2-COOD. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin Cu 2:C cc dd ring bit sau: Phenylamoni clorua, H2N-CH2-CH2-CH(NH2)COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dd c pH < 7 l: A. 3 B. 4 C. 5 D. 2 Cu 3: (2008-B) Cht phn ng vi dung dch FeCl3 cho kt ta l: A. CH3NH2 B. CH3COOH C. CH3OH D. CH3COOCH3 Cu 4: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dd HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl- B. H2N-CH2-COOH, H2N-CH2CH2-COOH C. .H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl- D. H2N-CH2-COOH, H2NCH(CH3) -COOH Cu 5: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N p vi 100ml NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7gam cht rn. Cng thc cu to thu gn ca X l A. H2NCH2COOCH3 B. HCOOH3NCH=CH2 C. H2NCH2CH2COOH D. CH2=CHCOONH4 Cu 6: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, anilin, phenol, benzen. S cht trong dy phn ng c vi nc Br2 l: A. 8 B. 6 C. 5 D. 7 Cu 7:(2007-A). Khi t chy hon ton mt amin n chc X, thu c 8,4 lit kh CO2, 1,4 lt kh N2 (Cc th tch kh o ktc) 10,125gam nc. Cng thc phn t ca X l A. C4H9N B. C3H7N C. C2H7N D. C3H9N -aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit Cu 8: HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2N-CH2-COOH B. CH3CH2CH(NH2)COOH C. H2NCH2CH2COOH D. CH3CH(NH2)COOH Nguyn Trung Kin Lp 12A1 Trang 61

Cu 9: Cho hn hp X gm 2 cht hu c c cng CTPT C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48lit hn hp kh Z(ktc) gm 2 kh u lm xanh giy qu m. T khi hi ca Z i vi H2 bng 13,75. C cn dd Y thu c khi lng mui khan l A. 16,5 g B. 14,3 g C. 8,9g D. 15,7g Cu 10: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lit kh N2 (ktc) v 3,15gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l: A. H2N-CH2-CH2-COOH B. H2N-CH2-COO-CH3 C. H2N-CH2-COO-C3H7 D. H2N-CH2-COOC2H5 Cu 11: (2007-B) Cho cc loi hp cht: aminoaxit(X), mui amoni ca axit cacboxylic(Y), amin(Z), este ca aminoaxit(T). Dy gm cc loi hp cht u tc dng c vi dd NaOH v u tc dng c vi dung dch HCl l: A. X, Y, Z, T B. X, Y, T C. X, Y, Z D. Y, Z, T Cu 12 : Cho cc cht etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni clorua, ancol benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dd NaOH l : A. 6 B. 4 C. 5 D. 3 Cu 13 : C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l :A. dd phenolphtalein B. dd NaOH C. Nc Br2 D. Giy qu tm Cu 14 : Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. Protit lun l cht hu c no B. Protit lun cha chc hirxyl C. Protit c khi lng phn t ln hn D. Protit lun cha Nit Cu 15 : Dy gm cc cht u lm qu tm m chuyn sang mu xanh l : A. Anilin, metyl amin, amonic B. Amoni clorua, metyl amin, natri hiroxit C. Anilin, amoniac, natri hiroxit D. Metyl amin, amoniac, natri axetat A. 25% v 75% B. 50% v 50% C. 43,6% v 56,4% D.Kt qu khc Cu 16: Cho 0,1 mol amino axit X tc dng va vi 0,1 mol HCl. Ton b sn phm thu c tc dng va vi 0,3 mol NaOH. X l amino axit c A. 1 nhm -NH2 v 1 nhm COOH B. 2 nhm NH2 v 1 nhm COOH C. 1 nhm NH2 v 3 nhm COOH D. 1 nhm NH2 v 2 nhm COOH Cu 17: Khi un nng hn hp glixin v alanin s thu c ti a bao nhiu loi phn t tri peptit cha ng thi c 2 loi amino axit trong phn t? A. 4 B. 8 C. 6 D. 5 Cu 18: X l este ca mt -aminoaxit vi ancol metylic. Ho hi 25,75g X th thu c th tch hi bng th tch ca 8g kh O2 cng iu kin. Cng thc cu to ca X l A. H2N-CH2-CH2-COO-CH3 B. CH3-CH(NH2)-COO-CH3 C. H2N-CH2COO-CH3 D. CH3-CH2-CH(NH2)-COO-CH3 Cu 19: Ngi ta iu ch anilin bng cch nitro ho 500g benzen ri kh hp cht nitro sinh ra. Bit hiu sut 2 giai on trn ln lt bng 78% v 80%. Khi lng anilin thu c l A. 327 gam B. 476,92 gam C. 596,15 gam D. Kt qu khc Cu 20:Cho 2 cng thc phn t C4H10O v C4H11N. S ng phn ancol bc 2 v amin bc 2 tng ng l: Trang 62 Nguyn Trung Kin Lp 12A1

A. 1,1 B. 4,8 C. 4,1 C. 1,3 Cu 21: Hp cht hu c X l este c to bi axit glutamic v mt ancol bc nht. phn ng va ht 37,8 gam X cn 400ml dung dch NaOH 1M. Cng thc cu to thu gn ca X A. C3H5(NH2)(COOH)(COOCH2-CH2-CH3 B. C3H5(NH2)(COOCH2-CH2CH3)2 C. C2H3(NH2)(COOCH2CH3)2 D. C2H3(NH2)(COOH)(COOCH2-CH2CH2-CH3) Cu 22: Hy chn cng thc sai trong s cc cng thc cho di y ca aminoaxit? A. C5H12O2N2 B. C3H7O2N C. C4H9O2N D. C4H8O2N Cu 23. X l mt amino axit no cha 1 nhm amino v 1 nhm cacboxyl. Cho 1,31g X tc dng vi HCl d thu c 1,675 g mui clorua ca X. Cng thc cu to thu gn X l. A. H2N-(CH2 )6-COOH B. H2N-(CH2 )3-COOH C. H2N-(CH2 )4-COOH D. H2N-(CH2 )5-COOH CHNG 3: AMIN, AMINO AXIT V PROTEIN A. BI TP L THUYT TRC NGHIM 1. Khng nh no sau y lun ng? A. Tnh baz ca amin tng dn theo th t : bc I < bc II < bc III. B. Tnh baz ca anilin l do nhm NH2 nh hng ln gc C6H5. C. V c tnh baz nn anilin lm i mu cht ch th mu. D. Do nh hng ca nhm C6H5 lm gim mt e trn nit nn anilin c tnh baz yu. 2. Bc ca amin phu thuc vao A. Bc ca nguyn t cacbon mang nhom -NH2. B. Ha tr ca nit . C. S nguyn t H trong NH3 a c thay bng gc hidro cacbon. D. S nhm NH2 . 3. Nhn nh no sau y khng ng v anilin? A. Tnh baz ca anilin yu hn NH3 do gcC6H5 hut e nn lm gim mt e trn nguyn t nit. B. Nh c tnh baz, anilin tc dng c vi dung dich Brom. C. Anilin khng tc dng c vi dung dich NaOH. D. Anilin t tan trong nc v rt c. 4. S ng phn amin bc II ca C4H11N l A. 1 B. 2 C. 3 D. 4 5. Vi cc cht amoniac (1), metylamin (2), etylamin (3), anilin (4). Tnh baz tng dn theo trnh t A. (4) < (1) <(2) < (3) B. (4) < (1) < (3) < (2) C. (3) < (2) < (1) <(4) D. (3) < (2) < (4) < (1) 6. Cho vi git anilin vo nc, sau thm dung dich HCl (d) vo, ri li nh tip dung dch NaOH vo, s xy ra hin tng: A. Lc u dung dich b vn c, sau trong sut v cui cng b vn c li. B. Lc u dung dich trong sut, sau b vn c v cui cng tr li trong sut. C. Dung dch trong sut. D. Dung dch b vn c hon ton. 7. phn bit anilin v etylamin ng trong 2 lo ring bit, ta dng thuc th no su y? A. Dung dch Br2 B. Dung dich HCl C. Dung dich NaOH D. Dung dich AgNO3 8. Vi s phn ng bn di th cht B l cht no? HNO3,(1 mol) Fe, HCl (d) NaOH C6H6------------------->A--------------->B ------------->C H2SO4, a c A. Nitro benzen B. anilin C. Natri phenolat D. Mt loi mui clorua 9. Theo s phn ng sau: t0 HNO 3, H 2 SO 4 t0 Fe , HCl , du CH4 A B C D. A, B, C, D ln lt l C 1:1 A. C2H2, C6H6, C6H5NO2, C6H5NH2 B. C2H2, C6H6, C6H5NO2, C6H5NH3Cl C. C2H4, C6H6, C6H5NH2, C6H5NH3Cl D. C6H6, C6H5NO2, C6H5NH2, C6H5NH3Cl 10. phn bit phenol, anilin, benzen bng phng phap hoa hoc, ta cn dung cac hoa cht la: A. Dung dich Brm, Na B. Qui tim C. Kim loai Na D. Qui tim, Na. Nguyn Trung Kin Lp 12A1 Trang 63

11. C 3 cht hu c : H2N-CH2-COOH; CH3-CH2-COOH v CH3-CH2-CH2-NH2. nhn ra dung dch ca cc hp cht trn, ngi ta ch cn th vi mt cht no trong cc cht sau y? A. NaOH B. HCl C. CH3OH/HCl D. Qu tm 12. chng minh glyxin C2H5O2N l mt amino axit, ch cn cho phn ng vi A. HCl B. NaOH C. CH3OH/HCl D. Hai phn ng A v B 13. Cho cc cht sau y: 1. H2N-CH2-CH2-COOH 2. CH2 = CH-COOH 3. CH2O v C6H5OH 4. HO-CH2-COOH Cc trng hp no c kh nng tham gia phn ng trng ngng ? A. 1,2,3 B.1,2,4 C. 1,3,4 D. 2,3,4 14. iu khng nh no sau y khng ng? A. Khi lng phn t ca mt amino axit (gm mt chc NH2 v mt chc COOH) lun l s l B. Hp cht amino axit phi c tnh lng tnh C. Dung dch amino axit khng lm giy qu tm i mu D. Thu phn protit bng axit hoc kim s cho mt hn hp cc amino axit 15. Cho dung dch cha cc cht sau: C6H5 NH2 (X1); CH3NH2 (X2); H2N - CH2 - COOH (X3); HOOC - CH2- CH2- CH(NH2)- COOH (X4); H2N - (CH2)4- CH(NH2)- COOH (X5) C. X2 ; X5. D. X3 ; X4 ; X5. 16. Khi thy phn H2N-CH2-CO-NH-CH-CO-NH-CH2-COOH s to ra CH3 A. H2N-CH2-COOH ; CH3-CH-COOH v H2N-CH2-CH2-COOH NH2 B. H2N-CH2-COOH v CH3-CH-COOH NH2 C. CH3-CH-COOH D. CH3-CH2-CH-COOH NH2 NH2 17. Mt hp cht hu c X c cng thc C3H7O2N. X phn ng vi dung dch brom, X tc dng vi dung dch NaOH v HCl. Cht hu c X c cng thc cu to l A. H2N-CH=CH-COOH B. CH2=CH-COONH4 C. H2N-CH2-CH2-COOH D. A v B ng 18. Trong cc cht sau, cht no lm qu tm chuyn sang mu hng? A. H2N-CH2-COOH B. H2N-CH2-CH2-CH(NH2)-COOH C. CH3-CH2-NH2 D. HOOC-CH2-CH2-CH(NH2)-COOH 19. Hp cht no sau y khng phi l amino axit ? A. H2N-CH2-COOH B. CH3-CH(NH2)-COOH C. CH3-CH2-CO-NH2 D. HOOC-CH2-CH(NH2)-COOH 20. Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B. Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. 21. Cc hin tng no sau y m t khng chnh xc? A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh. 22. Tn gi ca amino axit no di y l ng? A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)-COOH (valin) D. HOOC.(CH2)2-CH(NH2)-COOH (axit glutaric) 23. Khng nh no sau y khng ng v tnh cht vt l ca amino axit? A. Tt c u cht rn. B. Tt c u l tinh th, mu trng. C. Tt c u tan trong nc. D. Tt c u c nhit nng chy cao. 24. Cho glixin (X) phn ng vi cc cht i y, trng hp no PTHH c vit khng ng? A. X + HCl ClH3NCH2COOH B. X + NaOH H2NCH2COONa C. X + CH3OH + HCl ClH3NCH2COOCH3 + H2O D. X + HNO2 OHCH2COOH + N2 + H2O 25. Tn gi no sau y l ca peptit H2NCH2CONHCH(CH3)CONHCH2COOH? Trang 64 Nguyn Trung Kin Lp 12A1 Nhng dung dch lm giy qu tm ho xanh l A. X1 ; X2 ; X5. B. X2 ; X3 ; X4.

A. Glixinalaninglyxin B. Glixylalanylglyxin C. Alaningyxylalanin D. Alanylglyxylglyxyl 26. Pht biu no sau y khng ng? A. Khi nh axit HNO3 c vo lng trng trng thy xut hin mu vng. B. Phn t cc protit gm cc mch di polipeptit to nn. C. Protit rt t tan trong nc v d tan khi un nng. D. Khi cho Cu(OH)2 v lng trng trng thy xut hin mu tm xanh. 27. Trong cc cht sau Cu, HCl, C2H5OH, HNO2, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxetic tc dng c vi nhng cht no? A. Tt c cc cht. B. HCl, HNO2, KOH, Na2SO3, CH3OH/ kh HCl. C. Cu, C2H5OH, HNO2, KOH, Na2SO3, CH3OH/ kh HCl D. Cu, HCl, HNO2, KOH, Na2SO3, CH3OH/ kh HCl. 28. - amino axit l amino axit m nhm amino gn cacbon v tr th my? A. 1 B. 2 C. 3 D. 4 29. Cho cc cht H2N-CH2-COOH (X); H3C-NH-CH2-CH3 (Y); CH3-CH2-COOH (Z); C6H5-CH(NH2)COOH (T); HOOC.CH2-CH(NH2)-COOH (G); H2N-CH2-CH2-CH2-CH(NH2)-COOH (P). Amino axit l A. X, Z, T, P B. X, Y, Z, T C. X, Z, G, P D. X, Y, G, P. 30. Cho qu tm vo mi dd di y, dd lm qu tm ha xanh l? A. CH3COOH B. H2NCH2COOH C. H2NCH2(NH2)COOH D. HOOC-CH2-CH2-CH(NH2)-COOH 31. Cho dd qu tm vo 2 dd sau: (X) H2N-CH2-COOH; (Y) HOOC-CH(NH2)-CH2-COOH. Hin tng xy ra? A. X v Y khng i mu qu tm. B. X lm qu chuyn xanh, Y ha . C. X khng i mu, Y ha . D. X, Y lm qu ha 32. Khi un nng, cc phn t -alanin (axit -aminopropionic ) c th tc dng vi nhau to ra cc sn [-NH-CH- CO-]n [-CH2-CH- CO-]n [ -CH2-CH- CH2-]n phm no di y: COOH A. [-NH-CH2- CO-]n B. C. D. NH2 CH3 33. Axit -aminopropionic tc dng c vi tt c cc cht trong dy A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2NCH2COOH B. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, Cu C. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH D. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, NaCl 34. Mt amino axit c mt nhm -NH2 v mt nhm -COOH v c cng thc phn t l C4H9O2N. Amino axit ny c bao nhiu cng thc cu to ca cc ng phn? A. 3 B. 4 C. 5 D. 6 35. Pht biu no sau y khng ng: A. Nhng hp cht hnh thnh bng cch ngng t 2 hay nhiu -amino axit c gi l peptit. B. Phn t c 2 nhm -CO-NH- c gi l ipeptit, 3 nhm -CO-NH- c gi l tripeptit C. Cc peptit c t 10 n 50 n v amino axit cu thnh c gi l polipeptit. D. Trong mi phn t peptit, cc amino axit c sp xp theo mt th t xc nh. 36. Alanin khng tc dng vi A. CaCO3 B. C2H5OH C. H2SO4 long D. NaCl 37. C s phn ng sau C3H7O2N + NaOH CH3-OH + (X) Cng thc cu to ca (X) l A. H2N-CH2-COOCH3 B. CH3- CH2-COONa C. H2N-CH2-COONa D. H2N-CH2-CH2-COOH 38. Hp cht no khng lng tnh? A. Amoni axetat B. Alanin C. Etyl amin D. Amino axetat metyl 39. Cho s d phn ng sau:
axit

Amino axit (Y) + CH3OH

o

C3H7O2N + H2O

Amino axit (Y) l

t A. H2N-CH2-CH2-COOH B. H2N-CH2-COOCH3 C. CH3-CH(NH2)-COOH C. H2N-CH2-COOH 40. Cho cc cht: (1)amoniac. (2)metylamin. (3)anilin. (4)dimetylamin. Tnh baz tng dn theo th t no sau y? A. (1) < (3) < (2) < (4). B. (3) < (1) < (2) < (4). C. (1) < (2) < (3) < (4). D. (3) < (1) < (4) < (2) 41. Cho cc cht: C6H5NH2, C6H5OH, CH3NH2, CH3COOH. Cht no lm i mu qu tm sang mu xanh? Nguyn Trung Kin Lp 12A1 Trang 65

A. CH3NH2 B. C6H5NH2, CH3NH2 C. C6H5OH, CH3NH2 D. C6H5OH, CH3COOH 42. Cht no l amin? (1) CH3-NH2; (2) CH3-NH-CH2-CH3; (3) CH3-NH-CO-CH3; (4) NH2-(CH3)2-NH2; (5) (CH3)2NC6H5; (6) NH2-CO-NH2; (7) CH3-CO-NH2; (8) CH3-C6H4-NH2 A. 1, 2, 5 B. 1, 5, 8 C. 1, 2, 4, 5, 8 D. 3, 6, 7 43. Pht biu nao sau y sai? A. Cc amin u c tnh baz. B. Tnh baz ca cc amin u mnh hn NH3. C. Anilin c tnh baz rt yu. D. Amin co tinh baz do N co cp electron t do. 44. Hp cht C4H11N c bao nhiu ng phn amin? A. 6 B. 7 C. 8 D. 9 45. Amin c tnh baz do: A. Amin tan nhiu trong nc B. C nguyn t N trong nhm chc C. Nguyn t N cn cp e t do c th nhn proton D. Phn t amin c lin kt hiro vi H2O 46. Cc amino axit no c th phn ng vi tt c cc cht trong nhm no sau y? A. Dng dd NaOH, dd HCl, C2H5COOH, C2H5OH B. Dng dd NaOH, ddBrom, dd HCl, CH3OH C. Dng dd Ca(OH)2 , dd thuc tm, dd H2SO4, C2H5OH D. Dng dd H2SO4, dd HNO3, CH3OC2H5, dd thuc tm 47. Mt hp cht hu c X c cng thc C3H9O2N. Cho X phn ng dung dch NaOH, un nh thu c mui Y v kh Z lm xanh giy qu tm t. Cho Y tc dng vi NaOH rn, un nng c CH4 . X c cng thc cu to no sau y? A. C2H5-COO-NH4 B. CH3-COO-NH4 C. CH3-COO-H3NCH3 D. B v C ng 48. Polipeptit (-NH-CH2-CO-)n l sn phm ca phn ng trng ngng A. axit glutamic B. axit amino axetic C. axit -amino propionic D. alanin 49. Mt trong nhng im khc nhau gia protein vi gluxit v lipit l A. protein lun c khi lng phn t ln B. protein lun c nhm chc OH trong phn t. C. protein lun c nguyn t N trong phn t D. protein lun l cht hu c no. 50. Pht biu no sau y khng ng? A. Thy phn protein bng axit hoc kim khi nung nng s cho mt hn hp cc amino axit. B. Phn t khi ca mt amino axit (gm mt chC.NH2 v mt chc COOH) lun l s l C. Cc amino axit u tan tt trong nc D. Dung dch amino axit khng lm giy qu i mu. 51. nhn bit bn dung dch khng nhn gm: albumin, CH3COOH, NaOH, glixerol ngi ta dng A. qu tm B. phenolphtalein C. HNO3 c D. CuSO4. 52. nhn bit cc dung dch: glixin, h tinh bt, lng trng trng ngi ta dng A. Cu(OH)2/OH v un nng B. dd AgNO3/NH3 C. dd HNO3 c D. dd iot 53. nhn bit cc cht: glixerol, glucoz, anilin, albumin ngi ta tin hnh theo trnh t sau: A. Dng dd AgNO3/NH3, dng dd CuSO4, dng dd NaOH B. Dng dd CuSO4, dng dd H2SO4, dng dd iot C. Dng Cu(OH)2 lc v un nh, dng nc brom. D. Dng dd HNO3, dng dd NaOH, dng dd H2SO4. 54. Cho cc cht sau: CH3CH2NHCH3(1), CH3CH2CH2NH2(2), (CH3)3N (3). Dy cht c xp theo chiu tng dn tnh baz l A. (1) < (2) < (3) B. (2) < (3) < (1) C. (3) < (2) < (1) D. (3) < (1) < (2) 55. Thuc th duy nht nhn bit cc cht lng anilin, stiren, benzen l A. dung dch HCl B. dung dch brom C. dung dch NaOH D. dung dch H2SO4. 56. Tnh baz ca etylamin mnh hn amoniac c gii thch l do: A. Nguyn t N cn i e cha lin kt B. Nguyn t N c m in ln hn C. Ch cha 1 nguyn t D. nh hng y e ca nhm C2H5. 57. Cht hu c no sau y l cht lng iu kin thng? A. CH3Cl B. CH3OH C. CH3OCH3 D. CH3NH2. 58. nhn bit hai kh CH3NH2 v NH3, ngi ta dng cch no sau y? A. Mi ca kh B. Qu tm m C. t ri cho sn phm qua dung dch Ca(OH)2. D. Th bng HCl c 59. nhn bit dung dch cc cht C6H5NH2, CH3CH(NH2)COOH, (CH3)2NH v Anbumin. Ta c th tin hnh theo trnh t no sau y: A. Dng qu tm, dng Cu(OH)2, dng H2SO4 c B. Dng phenolphtalein, dng CuSO4, dng HNO3 c C. Dng nc Brom, dng H2SO4 c, dng qu tm Trang 66 Nguyn Trung Kin Lp 12A1

D. Dng nc Brom, dng HNO3 c, dng qu tm 60. Hy sp xp cc cht sau theo th t tng dn tnh baz: (1) C6H5NH2; (2) C2H5NH2; (3) (C2H5)2NH2; (4)NaOH; (5) NH3. Trng hp no sau y ng? A. (1)<(5)<(2)<(3)<(4) B. (1)<(2)<(5)<(3)<(4) C. (1)<(5)<(3)<(2)<(4) D. (2)<(1)<(3)<(5)<(4) 61. C cc cht: metanol, glixerol, dd glucoz, dd anilin. nhn cc cht trn bit ngi ta thc hin: A. Dng dd AgNO3/NH3, dng Cu(OH)2, dng nc brom B. Dng dd AgNO3/NH3, dng nc brom C. Dng Na kim loi, dng dd AgNO3/NH3 D. Dng Na kim loi, dng nc brom 62. Anilin v phenol u c phn ng vi A. dd NaOH B. dd HCl C. dd NaCl D. nc Br2. 63. Hp cht no sau y khng phi l amino axit? A. CH3CONH2 B. HOOC CH(NH2)CH2COOH C. CH3CH(NH2)COOH D. CH3CH(NH2)CH(NH2)COOH 64. C 3 ng nghim khng nhn cha 3 dung dch sau: NH2 (CH2)2CH(NH2)COOH ; NH2CH2COOH ; HOOCCH2CH2CH2CH(NH2)COOH. C th nhn ra c 3 dung dch bng: A. Giy qu B. Dung dch NaOH C. Dung dch HCl D. Dung dch Br2 65. Axit aminoaxetic khng tc dng vi A. CaCO3 B. H2SO4 long C. CH3OH D. KCl 66. Thc hin phn ng trng ngng 2 amino axit glixin v alanin thu c ti a bao nhiu ipeptit A. 1 B. 2 C. 3 D. 4 67. Khi thy phn tripeptit H2N CH(CH3)CO-NH-CH2-CO-NH-CH2-COOH s to ra cc amino axit A. H2NCH2COOH v CH3CH(NH2)COOH B. H2NCH2CH(CH3)COOH v H2NCH2COOH C. H2NCH(CH3)COOH v H2NCH(NH2)COOH D. CH3CH(NH2)CH2COOH v H2NCH2COOH 68. Cho cc cht sau: etilen glicol (A), hexa metylen diamin (B), axit -amino caproic (C), axit acrylic (D), axit aipic (E). Cht c kh nng tham gia phn ng trng ngng l A. A, B B. A, C, E C. D, E D. A, B, C, E. 69. Cho C4H11O2N + NaOH A + CH3NH2 + H2O CTCT ca C4H11O2N l A. C2H5COOCH2 NH2 B. C2H5COONH3CH3 B. CH3COOCH2CH2NH2 D. C2H5COOCH2CH2NH2 70. Phenol v anilin u lm mt mu nc brom cn toluen th khng, iu ny chng t A. nhm OH v NH2 y e mnh hn nhm CH3 B. nhm OH v NH2 y e yu hn nhm CH3. C. kh nng y e ca nhm OH>-CH3>-NH2 D. nhm CH3 ht e mnh hn nhm OH v NH2. 71. ra sch chai l ng anilin, nn dng cch no sau y? A. Ra bng x phng B. Ra bng nc C. Ra bng dd NaOH sau ra li bng nc D. Ra bng dd HCl sau ra li bng nc 72. tch phenol ra khi hn hp lng gm: phenol, benzen v anilin. Ngi ta c th lm theo cch: A. Ha tan hn hp vo dd HCl d, sau chit tch ly phn tan ri cho phn ng vi NaOH d, tip tc chit tch ly phn phenol khng tan. B. Ha tan hn hp vo dd NaOH d, sau chit tch ly phn mui tan ri cho phn ng vi CO2 d, tip tc chit tch phenol khng tan. C. Ha tan hn hp vo nc d, sau chit tch ly phenol D. Ha tan hn hp vo xng, chit ly phenol 73. Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l: A. C6H12 (xiclohexan), C6H5-CH3 B. C2H2, C6H5-NO2. C. CH4, C6H5-NO2 D. C2H2, C6H5-CH3. 74. Cc cht no sau y l amino axit? a) glixin, b)glixerol, c) etylenglicol, d) alanin, e) anilin, f) amoni axetat, g) axit glutamic, h) axit lactic, i) glicocol, j) etylamino axetat, k) axit -aminocaproic. A. a, d, f, g, i, k B. g, h, k C. a, c, e, j, k D. a, d, g, i, k 75. Dung dch lm qu tm ha l A. axit glutamic B. axit -amino propionic C. axit 2,3-iamino butiric D. axit phenic 76. Dung dch khng lm i mu qu tm l A. axit 2-amino pentanioic B. axit -amino aipic C. axit lactic D. axit -amino isovaleric. Nguyn Trung Kin Lp 12A1 Trang 67

77. Cht lng tnh l: a). metyl axetat, b) amoni axetat, c) glixin, d) metyl amoni fomiat, e) metyl amoni nitrat, f) axit glutamic, g) natri axetat. A. c,f B. b,d,e,f C. b,c,d,f D. a,b,c,d,f,g. 78. Alanin c th phn ng vi cc cht trong dy cht A. Ba(OH)2, CH3OH, CH2NH2-COOH B. HCl, Cu, CH3NH2 C. C2H5OH, FeCl2, Na2SO4 D. H2SO4, CH3-CH=O, H2O. 79. Cc amino axit c th phn ng tt c cc cht trong dy A. dd NaOH, dd HCl, C2H5COOH, C2H5OH B. dd NaOH, dd brom, dd HCl, CH3OH C. dd Ca(OH)2, dd thuc tm, dd H2SO4, C2H5OH D. dd H2SO4, dd HNO3, CH3OCH3, dd thuc tm 80. Dung dch metylamin khng tc dng vi cht no sau y? A. HNO2. B. Dung dch HCl. C. Dung dch FeCl3. D. Dung dch Br2. 81. Dung dch cht no sau y khng lm chuyn mu qu tm? A. CH3 - CHOH - COOH. B. H2N(CH2)2CH(NH2)COOH. C. H2N - CH2 - COOH. D. C6H5NH3Cl. 82. Trong cc cht sau, dung dch cht no khng lm chuyn mu qu tm? A. HOOC.CH2-CH2CH(NH2)COOH B. H2N-CH2-COOH C. H2N-CH2CH2CH2CH2-CH(NH2)-COOH D. CH3-CHOH-COOH 83. Hp cht khng lm i mu giy qu m l A. CH3NH2. B. H2NCH2COOH. C. C6H5ONa. D. H2N - CH2 - CH(NH2)COOH. 84. Anilin v phenol u c phn ng vi: A. Dung dch NaOH. B. Dung dch NaCl. C. Dung dch Br2. D. Dung dch HCl. 85. un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l A. H2N-CH2-COOH, H2N-CH(CH3)-COOH. B. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. C. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. D. H2N-CH2-COOH, H2N-CH2-CH2-COOH. 86. Tng s ng phn amin ca cht c cng thc phn t C3H9N l A. 5 B. 1 C. 4 D. 3 87. Dng nc Br2 khng phn bit c 2 cht trong cp no sau y? A. Anilin v stiren. B. Anilin v amoniac. C. Anilin v alylamin (CH2 = CH - CH2 - NH2). D. Anilin v phenol. 88. Nhn nh no sau y khng ng? A. Metyl amin c tnh baz mnh hn anilin. B. Cng thc tng qut ca amin no, mch h l CnH2n+2+kNk. C. Tnh baz ca cc amin u mnh hn NH3. D. Cc amin u c kh nng nhn proton. 89. Mt cht khi thy phn trong mi trng axit, un nng khng to ra glucoz. Cht l A. Tinh bt. B. Xenluloz. C. Saccaroz. D. Protit. 90. Phn ng no di y khng th hin tnh baz ca amin? A. C6H5NH2 + HCl C6H5NH3Cl .
3+ + B. Fe +3RNH 2 + 3H 2O Fe(OH) 3 + 3RNH 3 .

C. RNH 2 +HNO2 ROH + N 2 + H 2O .

+ D. RNH2 +H 2O RNH 3 +OH . CuO 3 2 91. Cho s phn ng: NH3 X Y Z . (1 :1) t0 CH I HNO

Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l A. CH3OH, HCHO. B. CH3OH, HCOOH. C. C2H5OH, HCHO. D. C2H5OH, CH3CHO. 92. B thuc th no sau y c th phn bit c cc dung dch mt nhn sau: C2H5NH2, C6H5NH2, glucoz, glixerol? A. Qi tm, dung dch Br2.B. C A, B, C u ng. C. Phenolphtalein, Cu(OH)2. D. AgNO3/NH3, dung dch Br2, qi tm. 93. Chn phng n tt nht phn bit dung dch cc cht mt nhn ring bit sau: CH3NH2, H2NCH2COOH, CH3COONH4, anbumin. Trang 68 Nguyn Trung Kin Lp 12A1

A. Qi tm, dung dch HNO3 c, dung dch NaOH. B. Dung dch AgNO3/NH3, dung dch Br2, dung dch HNO3 c. C. Cu(OH)2, qy tm, ung dch Br2. D. Dung dch Br2, dung dch HNO3 c, dung dch I2. 94. Cho dy chuyn ho sau: + NaOH + HCl + HCl + NaOH Glyxin Z X ; Glyxin T Y . X v Y ln lt l A. ClH3NCH2COOH v ClH3NCH2COONa. B. ClH3NCH2COOH v H2NCH2COONa. C. ClH3NCH2COONa v H2NCH2COONa. D. u l ClH3NCH2COONa. 95. Nhn nh no sau y cha chnh xc? A. Tc phn ng nh xc tc enzim rt chm, mi enzim ch xc tc cho mt s chuyn ho. B. Peptit l nhng hp cht c hnh thnh bng cch ngng t hai hay nhiu phn t -amino axit. C. Enzim l nhng cht hu ht c bn cht protein, c kh nng xc tc cho cc qu trnh ho hc, c bit trong c th sinh vt. D. Protein l nhng polipeptit cao phn t c vai tr l nn tng v cu trc v chc nng ca mi s sng. 96. Nhn nh no sau y khng ng? A. Nhit nng chy ca H2NCH2COOH > CH3(CH2)3NH2 > CH3CH2COOH. B. Amino axit l hp cht tp chc m phn t cha ng thi nhm cacboxyl v nhm amino. C. Amino axit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc H3N+RCOO-. D. Cc amino axit l nhng cht rn, c nhit nng chy cao v d tan trong nc v chng tn ti dng ion lng cc. 97. Thy phn hon ton polipeptit sau thu c bao nhiu amino axit? H2N - CH2- CO - NH - CH - CO - NH - CH - CO - NH - CH2- COOH
CH2COOH CH2- C6H 5

A. 3. B. 4. C. 5. D. 2. 98. Khi lm th nghim xong vi anilin, trc khi trng li bng nc, nn ra ng nghim bng dung dch A. dd HCl B. dd NH3 C. dd Ca(OH)2 D. dd NaCl 99. S ipeptit to thnh t glyxin v alanin l A. 1. B. 2. C. 4. D. 3. 100. Pht biu khng ng l A. Phenol phn ng vi dung dch NaOH, ly mui thu c cho tc dng vi dung dch HCl li thu c phenol. B. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta thu c tc dng vi dung dch NaOH li thu c natri phenolat. C. Axit axetic phn ng vi NaOH, ly mui thu c cho tc dng vi CO2 li thu c axit axetic. D. Anilin phn ng vi dung dch HCl, ly mui thu c cho tc dng vi dung dch NaOH li thu c anilin. 101. Amin no di y l amin bc 2? A. CH3-CH2NH2 B. CH3-CHNH2-CH3 C. CH3-NH-CH3 D. CH3-NCH3-CH2-CH3 102. Cng thc no di y l cng thc chung ca dy ng ng amin thm (cha 1 vng bezen) n chc bc nht? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 103. Hp cht no di y c tnh baz yu nht? A. Anilin B. Metylamin C. Amoniac D. imetylamin 104. Sp xp cc cht sau y theo tnh baz gim dn? (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. 1>3>5>4>2>6 B. 6>4>3>5>1>2 C. 5>4>2>1>3>6 D. 5>4>2>6>1>3 105. Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl 3+ + C. Fe + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3 D. CH3NH2 + HNO2 CH3OH + N2 + H2O 106. Dung dch no di y khng lm qu tm i mu? A. C6H5NH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3 107. X l cht hu c c cng thc phn t C5H11O2N. un X vi dung dch NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c Y. Cho hi Y qua CuO, t0 c cht Z c kh nng trng gng. Cng thc cu to ca X l A. H2NCH2CH2COOC2H5. B. CH3(CH2)4NO2. Nguyn Trung Kin Lp 12A1 Trang 69

C. H2NCH2COOCH2CH2CH3. D. H2NCH2COOCH(CH3)2. 108. Nhn nh no sau y khng ng? A. Anilin c tnh baz nn lm mt mu nc brom. B. Anilin khng lm i mu qu tm. C. Trong phn t anilin c nh hng qua li gia nhm amino v gc phenyl. D. Amin c tnh baz v trn nguyn t N c i electron t do nn c kh nng nhn proton. 109. Dy gm cc cht u lm giy qi tm m chuyn sang mu xanh l A. Anilin, metylamin, amoniac. B. Anilin, amoniac, natri hiroxit. C. Metylamin, amoniac, natri axetat. D. Amoniclorua, metylamin, natri hiroxit. 110. Cho cc cht sau: C6H5NH2 (1); C2H5NH2 (2); (C2H5)2NH2 (3); NaOH (4); NH3 (5) Trt t tng dn tnh baz (t tri qua phi) l A. (1), (2), (5), (3), (4). B. (1), (5), (3), (2), (4). C. (1), (5), (2), (3), (4). D. (2), (1), (3), (5), (4). 111. Khi thy phn hon ton mt polipeptit ta thu c cc amino axit X, Y, Z, E, F. Cn khi thu phn tng phn th thu c cc i- v tripeptit XE, ZY, EZ, YF, EZY. Trnh t cc amino axit trong polipeptit trn l A. X - Z - Y - F - E. B. X - E - Z - Y - F. C. X - Z - Y - E - F. D. X - E - Y - Z - F. 112. Axit glutamic (HOOC[CH2]2CH(NH2)COOH) l cht c tnh A. trung tnh. B. axit. C. baz. D. lng tnh. 113. Trong phn t hp cht hu c no sau y c lin kt peptit? A. Xenluloz. B. alanin. C. Protein. D. Glucoz. 114. Dy gm cc cht c xp theo chiu tnh baz gim dn t tri qua phi l A. C6H5NH2, NH3, CH3NH2. B. NH3, CH3NH2, C6H5NH2. C. CH3NH2, C6H5NH2, NH3. D. CH3NH2, NH3, C6H5NH2. 115. chng minh glyxin C2H5O2N l mt amino axit, ch cn cho phn ng vi A. NaOH v HCl. B. HCl. C. NaOH. D. CH3OH/HCl. 116. Sn phm cui cng ca qu trnh thu phn cc protein n gin nh xc tc thch hp l. A. amino axit. B. amino axit. C. Axit cacboxylic. D. Este. 117. Cho cc loi hp cht: amino axit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca amino axit (T). Dy gm cc hp cht u tc dng c vi dung dch NaOH v u tc dng vi dung dch HCl l A. X, Y, T. B. X, Y, Z, T. C. X, Y, Z. D. Y, Z, T. + 118. Cho cc phn ng: H2NCH2COOH + HCl Cl H3N CH2COOH .
H2NCH2COOH + NaOH H2NCH2COONa +H2O . Hai phn ng trn chng t axit aminoaxetic A. ch c tnh baz. B. ch c tnh axit. C. va c tnh oxi ho, va c tnh kh. D. c tnh lng tnh. 119. Cho dung dch NaOH vo dung dch metyl amoni propionat. Phn ng no sau y tng ng vi th nghim ny? A. CH3-CH2-COONH4 + NaOH CH3-CH2-COONa + NH3 + H2O B. CH3-CH2-COO-NH3CH3 + NaOH CH3-CH2-COONa + CH3NH2.+ H2O C. CH3-COO-CH3NH2 + NaOH CH3COONa + CH3NH2. D. CH3-CH2-COO-NH3-C2H5 + NaOH CH3-CH2-COONa + C2H5NH2+ H2O 120. T hai amino axit l alanin v glixin c th to thnh bao nhiu ipeptit? A. 2 B. 3 C. 4 D. 1

B. BI TP TON TRC NGHIM 1. Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi dung dch HCl. Khi lng mui thu c l A. 7,65 gam B. 8,10 gam C. 8,15 gam D. 0,85 gam 2. t chy hon ton 6,2 gam mt amin no n chc th phi dng 10,08 lt O2(ktc). Cng thc ca amin l A. C2H5NH2 B. CH3NH2 C. C3H7NH2 D. C4H9NH2. 3. Cho 0,01 mol amino axit X phn ng ht vi 40ml dd HCl 0,25M to thnh 1,115 gam mui khan. X c cng thc cu to l A. H2N-CH2-COOH B. H2N-(CH2)2-COOH C. CH3COONH4 D. H2N-(CH2)3-COOH 4. Thc hin phn ng este ha gia amino axit X v ancol CH3OH thu c este Y c t khi hi so vi khng kh bng 3,069. Cng thc cu to ca X l A. H2N-CH2-COOH B. H2N-CH2-CH2-COOH C. CH3-CH(NH2)-COOH D. H2N-CH2-CH2-CH2-COOH 5. Khi t chy hon ton mt amin no, n chc X thu c 13,2 gam kh CO2 ,kh N2 v 8,1 gam H2O. Cng thc phn t ca X l A. C3H7N B. C2H7N C. C3H9N D. C4H9N Trang 70 Nguyn Trung Kin Lp 12A1

6. Cho 9,3 gam anilin tac dung vi dung dch brom, thu c m gam chat ket tua mau trang. Khoi lng ket tua la A. 93 gam B. 33 gam C. 330 gam D. 39 gam 7. 1 mol amino axit A tc dng va vi 1mol HCl 0,5 mol amino axit A tc dng va vi 1mol NaOH. A c cng thc phn t A. C5H9NO4 B. C4H7N2O4 C. C8H5NO2 D. C7H6N2O4 8. 0,01 mol amino axit A tc dng va vi 50 ml dung dch HCl 0,2M. C cn dung dch sau phn ng c 1,835g mui. A c phn t khi l A. 89 vC B. 103 vC C. 117 vC D. 147 vC 9. A l hp cht hu c cha C, H, O, N. t chy A c hn hp CO2, hi nc, N2 c t khi so vi hidro l 13,75. Bit th tch CO2 = th tch hi nc v s mol O2 dng bng na tng s mol CO2, H2O to ra. A l A. C2H5NO2 B. C2H7NO2 C. C4H7NO2 D. C4H9NO 10. Cho 23,9g hn hp gm axit aminoaxetic v axit -aminopropionic vo 0,6 lt dung dch NaOH 0,5M. Phn trm v s mol ca 2 axit ln lt l A. 40,5% v 59,5% B. 20,3% v 79,7% C. 24,5% v 75,5% C. 33,3% v 66,7% 11. Khi lng anilin thu c khi kh 246g nitrobenzen ( hiu sut H=80%) l A. 186g B. 148,8g C. 232,5g D. 260,3g 12. t chy 2 amin no n chc ng ng lin tip nhau thu c 2,24 lit CO 2 (kc) v 3,6g nc. Hai amin c CTPT l A. CH5N v C2H7N B. C3H9N v C4H11N C. C2H7N v C3H9N D. C4H11N v C5H13N 13. Hm lng nit trong amin n chc A l 19,17%. A c CTPT A. CH5N B. C2H7N C. C3H7N D C4H11N 14. Cho 1,87 g hn hp anilin v phenol tc dng va vi 20g dung dich Brom 48%. Khi lng kt ta thu c l A. 6,61g B. 11,745 g C. 3,305 g D. 1,75g 15. Mt hn hp gm ancol etylic, phenol, anilin co khi lng 23,3 gam. Nu cho hn hp tac dung vi Na d, thy thoat ra 2,24 lit khi (kc). Cung lng hn hp o, nu cho tac dung vi dung dich NaOH thy cn va ung 100 ml dung dich NaOH 1M. Khi lng mi cht trong hn hp ln lt la A. 4,6g; 9,4g va 9,3g B. 9,4g; 4,6 g va 9,3g C. 6,2g; 9,1g va 8 g D. 9,3g; 4,6g va 9,4g. 16. 0,1 mol amino axit A phn ng va vi 100ml dung dch HCl 2M. Mt khc 18g A cng phn ng va vi 200ml dung dch HCl trn. A c khi lng mol phn t l A. 120 B. 90 C. 60 D. 80 17. A l mt amino axit c khi lng phn t l 147. Bit 1 mol A tc dng va vi 1 mol HCl; 0,5 mol tc dng va vi 1mol NaOH. Cng thc phn t ca A l A. C5H9NO4 B. C4H7N2O4 C. C5H25NO3 D. C8H5NO2

a) b) c) d)

289. Nylon-6,6 l mt loi t si tng hp c to ra do: S trng ngng gia axit aipic vi hexametyleniamin S trng ngng gia axit tereptalic vi etylenglicol S trng ngng ca axit -aminoenantoic S Clo ha PVC
C O

NH Capron l mt t si tng hp, c iu ch t monome (cht n phn) l Caprolactam ( ) Mt loi t Capron c khi lng phn t l 14 916 vC. S n v mt xch c trong phn t loi t si ny l: a) 200 b) 150 c) 66 d) 132 331. Phn ng trng hp, ng trng hp l: a) Phn ng cng b) Phn ng oxi ha kh c) Phn ng th d) Phn ng phn hy 333. Polyeste l mt loi t si tng hp, n c to ra do s trng ngng (ng trng ngng) gia axit Tereptalic (axit 1,4-Bezenicacboxilic) vi Etylenglicol (Etaniol-1,2). Mt loi t Polyeste c khi lng phn t l 153600. C bao nhiu n v mt xch trong phn t polyme ny?

290.

Nguyn Trung Kin Lp 12A1

Trang 71

a) 808 n v mt xch b) 800 n v mt xch c) 768 n v mt xch d) 960 n v mt xch 38. Polistiren (nha PS) l mt polime dng rn, mu trng, khng dn in, khng dn nhit. Nha PS c to ra do s trng hp ca stiren. Khi lng polistiren thu c khi em trng hp 10 mol stiren, hiu sut qu trnh trng hp 80%, l: a) 650 gam b) 798 gam c) 832 gam d) 900 gam (C = 12; H = 1)

39. Khi lng phn t ca mt loi t capron bng 14 916 vC. S n v mt xch c trong phn t t capron l bao nhiu? a) 117 b) 150 c) 210 d) 132 341. T visco, t axetat l: a) Thuc loi t tng hp b) Thuc loi t polieste c) Thuc loi t amit (amid) d) Thuc loi t nhn to 345. Cht no cho c phn ng trng hp? (1): Isopren (2): Isopentan (3): Axetilen (4): Vinylaxetilen (5): Etylenglicol (6): Axit propionic (7): Vinyl axetat (8): Axit oxalic a) (1), (3), (4), (7) b) (1), (3), (4), (5), (7), (8) c) (1), (4), (7) d) Tt c cc cht trn
Cu 24. Trong tt c cc c th ng vt, thc vt u c: A. lipit. A. Lipit. B. protein. B. Gluxit. C. glucoz. C. Protein. Cu 25. Bn cht ca cc men xc tc l: D. Amino axit. Cu 26. Trong hemoglobin ca mu c nguyn t: A. ng. B. st. C. km. D. ch. Cu 27. Protein trong lng trng trng c cha nguyn t: A. lu hunh. B. silic. C. st. D. brom. D. saccaroz.

Cu28. Khi thu phn protein n cng thu c A. glucoz. C. chui polipeptit. Cu 29. S kt ta protein bng nhit c gi l: A. S ng c. D. S ng rn.
Cu 38. Dung dch lng trng trng gi l dung dch

B. amino axit. D. amin. B. S ng t. C. S ng kt.

A. cazein.
A. s ng t. un nng:

B. anbumin.

C. hemoglobin.

D. insulin. D. s ng kt.

Cu 31. Hin tng riu cua ni ln khi nu canh cua l do : B. s ng rn. C. s ng c. C u 32. Hin tng xy ra khi cho axit nitric m c vo dung dch lng trng trng v A. Xut hin mu trng. B. Xut hin mu xanh. C. Xut hin mu vng. D. Xut hin mu tm.

Cu 33. Hin tng xy ra khi cho ng (II) hiroxit vo dung dch lng trng trng: A. Xut hin mu . C. Xut hin mu vng. B. Xut hin mu nu. Cu 34. Cho polipeptit: NH D. Xut hin mu tm c trng.

CH

NH

CH

CH3 O CH3 O y l sn phm ca phn ng trng ngng cht no?

A. Glixin. B. Alanin. C. Glicocol. A . ng. D. Axit aminocaproic. B. st. C. km. Cu 35. Trong hemoglobin ca mu c nguyn t: D. ch.

Cu 36. Khi thu phn protein n cng, thu c bao nhiu amino axit khc nhau? A. 10 D. 30 Trang 72 Nguyn Trung Kin Lp 12A1

B. 20 C.22

Cu 37. Hin tng xy ra khi cho axit nitric m c vo dung dch lng trng trng v un nng: C. Xut hin mu trng. D. Xut hin mu xanh. C. Xut hin mu vng. D. Xut hin mu tm.

Cu 38. Hin tng xy ra khi cho ng (II) hiroxit vo dung dch lng trng trng: C. Xut hin mu . C. Xut hin mu vng. D. Xut hin mu nu. D. Xut hin mu tm c trng.

44: Khi un nng, cc phn t alanin (axit -aminopropionic) c th tc dng vi nhau to ra cc sn phm [-CH2-CH- CO-]n [ -CH2-CH- CH2-]n [-NH-CH- CO-]n no di y: A. [-NH-CH2- CO-]n B. C. CH3 D. NH2 COOH 48: Thy phn n cng protein n cng ta thu c cc cht no? A. Cc aminoaxit B. aminoaxit C. Hn hp cc aminoaxit D. Cc chui polipeptit 49: M t hin tng no di y l khng chnh xc? A. Nh vi git axit nitric c vo dd lng trng trng thy kt ta mu vng. B. Trn ln lng trng trng, dd NaOH v mt t CuSO4 thy xut hin mu c trng . C. un nng dd lng trng trng thy hin tng ng t li, tch ra khi dd. D. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. 50: Tn gi ca Sn phm v cht phn ng trong phn ng polime ha no sau y l ng? A. nH2N(CH2)5COOH (-HN(CH2)5CO-)n + n H2O B. nH2N(CH2)5COOH (-HN(CH2)6CO-)n + n H2O Axit -aminocaproic t nilon-6 Axit -aminoenantoic t enang C. nH2N(CH2)6COOH (-HN(CH2)6CO-)n + n H2O D. B, C ng Axit 7-aminoheptanoic t nilon-7 52: Pht biu no sau y khng ng: A. Nhng hp cht hnh thnh bng cch ngng t 2 hay nhiu -aminoaxit c gi l peptit. B. Phn t c 2 nhm -CO-NH- c gi l i peptit, 3 nhm -CO-NH- c gi l tri peptit C. Cc peptit c t 10 n 50 n v aminoaxit cu thnh c gi l polipeptit. D. Trong mi phn t peptit, cc aminoaxit c sp xp theo mt th t xc nh.

TRAC NGHIEM BAI TAP AMIN - AMINO AXIT VA PROTEIN.

Cu 1 : Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 8,15 gam B. 0,85 gam C. 7,65 gam D. 8,10 gam Cu 2 : The tch nc brom 3% (d = 1,3g/ml) can dung e ieu che 4,4g tribormanilin la A. 164,1ml. B. 49,23ml. C 146,1ml. D. 16,41ml. Cu 3 : Khoi lng anilin can dung e tac dung vi nc brom thu c 6,6g ket tua trang la A. 1,86g. B. 18,6g. C. 8,61g. D. 6,81g. Cu 4 : Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. X c th l : A. axit glutamic. B. valin. C. glixin D. alanin. Cu 5 : 1 mol -aminoaxit X tac dung va het vi 1 mol HCl tao ra muoi Y co ham lng clo la 28,287%. CTCT cua X la A. CH3 CH(NH2) COOH. B. H2N CH2 CH2 COOH. C. NH2 CH2 COOH. D. H2N CH2 CH(NH2) COOH. Cu 6 : Khi trung ngng 13,1g axit -aminocaproic vi hieu suat 80%, ngoai aminoaxit con d ngi ta thu c m gam polime va 1,44g nc. Gia tr m la A. 10,41g. B. 9,04g. C. 11,02g. D. 8,43g. Cu 7 : Mot amin n chc cha 19,718% nit ve khoi lng. CTPT cua amin la A. C4H5N. B. C4H7N. C. C4H9N. D. C4H11N.
Nguyn Trung Kin Lp 12A1 Trang 73

Cu 8 : ot chay hoan toan mot amin no n chc thu c VH2O = 1,5VCO2. CTPT cua amin la A. C2H7N. B. C3H9N. C. C4H11N. D. C5H13N. Cu 9 : Cho 3,04g hon hp A gom 2 amin no n chc tac dung va u vi 400ml dd HCl 0,2M c 5,96g muoi. Tm the tch N2 (ktc) sinh ra khi ot het hon hp A tren ? A. 0,224 lt. B. 0,448 lt. C. 0,672 lt. D. 0,896 lt. Cu 10 : Cho 17,7g mot ankylamin tac dung vi dd FeCl 3 d thu c 10,7g ket tua. CTPT cua ankylamin la A. C2H7N. B. C3H9N. C. C4H11N. D. CH5N. Cu 11 . Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A. 100ml B. 50ml C. 200ml D. 320ml Cu 12 . Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Bit phn t khi ca cc amin u < 80. Cng thc phn t ca cc amin l p n A, B, C hay D? A. CH3 NH2; C2H5NH2 v C3H7NH2 B. C2H3 NH2; C3H5NH2 v C4H7NH2 C. C2H5 NH2; C3H7NH2 v C4H9NH2 D. C3H7 NH2; C4H9NH2 v C5H11NH2 Cu 13 . Cho 10 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 15,84 gam hn hp mui. Nu trn 3 amin trn theo t l mol 1 : 20 : 5 theo th t phn t khi tng dn th cng thc phn t ca 3 amin l p n no sau y? A. CH5N, C2H7N, C3H7NH2 B. C2H7N, C3H9N, C4H11N C. C3H9N, C4H11N, C5H11N D. C3H7N, C4H9N, C5H11N Cu 14 . t chy hon ton 6,2 gam mt amin no, n chc phi dng ht 10,08 lt kh oxi (ktc). Cng thc ca amin l cng thc no sau y? A. C2H5NH2 B. CH3NH2 C. C4H9NH2 D. C3H7NH2 Cu 15 . Hp cht hu c to bi cc nguyn t C, H, N l cht lng, khng mu, rt c, t tan trong nc, d tc dng vi cc axit HCl, HNO2 v c th tc dng vi nc brom to kt ta. Hp cht o c cng thc phn t nh th no? A. C2H7N B. C6H13N C. C6H7N D. C4H12N2 Cu 16 . t chy hon ton 100ml hn hp gm imetylamin v hai hirocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc th tch o cng iu kin). Cng thc phn t ca hai hirocacbon l p n no? A. C2H4 v C3H6 B. C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 Cu 17 . Trung ha 3,1 gam mt amin n chc X cn 100ml dung dch HCl 1M. Cng thc phn t ca X l p n no? A. C2H5N B. CH5N C. C3H9N D. C3H7N Cu 18 . t chy hon ton hn hp hai amin no n chc ng ng lin tip, ta thu c hn hp sn phm kh vi t l th tch nCO2: nH2O = 8 : 17. Cng thc ca hai amin l p n no? A. C2H5NH2, C3H7NH2 B. C3H7NH2, C4H9NH2 C. CH3NH2, C2H5NH2 D. C4H9NH2, C5H11NH2 Cu 19 . t chy hon ton mt amin n chc cha no c mt lin kt i mch cacbon ta thu c CO2 v H2O theo t l mol = 8:9. Vy cng thc phn t ca amin l cng thc no? A. C3H6N B. C4H9N C. C4H8N D. C3H7N Cu 20 . Cho 1,52 gam hn hp hai amin no n chc (c trn vi s mol bng nhau) tc dng va vi 200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc. A. Nng mol ca dung dch HCl bng 0,2M. B. S mol ca mi cht l 0,02mol C. Cng thc thc ca hai amin l CH5N v C2H7N D. Tn gi hai amin l metylamin v etylamin Cu 21 . Ngi ta iu ch anilin bng cch nitro ha 500g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu, bit hiu sut mi giai on 78%? A. 346,7gam B. 362,7gam C. 463,4gam D. 358,7 gam
Trang 74 Nguyn Trung Kin Lp 12A1

Cu 22 . Cho lng d anilin phn ng hon ton vi dung dch cha 0,05mol H2SO4 long. Khi lng mui thu c bng bao nhiu gam? A. 7,1gam B. 14,2gam C. 19,1gam D. 28,4 gam Cu 23 . Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng vi vi 0,075 mol Br2 to kt ta. Lng cc cht NH3, C6H5NH3 v C6H5OH ln lt bng bao nhiu? A. 0,01 mol; 0,005mol v 0,02mol B. 0,05 mol; 0,005mol v 0,02mol C. 0,05 mol; 0,002mol v 0,05mol. D. 0,01 mol; 0,005mol v 0,02mol Cu 24 . t chy hon ton 100ml hn hp gm imetylamin v 2 hirocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc th tch o cng iu kin). Thnh phn % th tch ca ba cht trong hn hp theo tng phn t khi ln lt bng bao nhiu? A. 20%; 20% v 60% B. 25%; 25% v 50% C. 30%; 30% v 40% D. 20%; 60% v 20% Cu 25 . Este X c iu ch t aminoaxit v ru etylic. T khi hi ca X so vi hiro 5,15 . t chy hon ton 10,3 gam X thu c 17,6gam kh CO2, 8,1gam nc v 1,12 lt nit (ktc). Cng thc cu to thu gn ca X l cng thc no sau y? A. H2N- (CH2)2 - COO-C2H5. B. H2N- CH(CH3) - COOC. H2N- CH2 CH(CH3) - COOH D. H2N-CH2 -COO-CH3 Cu 26 . X l mt aminoaxit no ch cha 1 nhm - NH 2 v 1 nhm COOH. Cho 0,89 gam X tc dng vi HCl va to r a 1,255 gam mui. Cng thc cu to ca X l cng thc no sau y? A. H2N- CH2-COOH B. CH3- CH(NH2)-COOH. C. CH3-CH(NH2)-CH2-COOH. D. C3H7-CH(NH2)-COOH - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 15,1 gam X tc Cu 27 . X l mt dng vi HCl d thu c 18,75 gam mui. Cng thc cu to ca X l cng thc no? A. C6H5- CH(NH2)-COOH B. CH3- CH(NH2)-COOH C. CH3-CH(NH2)-CH2-COOH D. C3H7CH(NH2)CH2COOH Cu 28 . X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 23,4 gam X tc dng vi HCl d thu c 30,7 gam mui. Cng thc cu to thu gn ca X l cng thc no? A. CH3-CH(NH2)-COOH B. H2N-CH2-COOH C. H2N-CH2CH2 -COOH D.CH2=C(CH3)CH(NH2)COOH Cu 29 . Cht A c % khi lng cc nguyn t C, H, O, N ln lt l 32%, 6,67% 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng NaOH va tc dng dd HCl, A c cng thc cu to nh th no? A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 30 . Cht A c thnh phn % cc nguyn t C, H, N ln lt l 40,45%, 7,86%, 15,73% cn li l oxi. Khi lng mol phn t ca A <100 g/mol. A tc dng c vi NaOH v vi HCl, c ngun gc t thin nhin, A c CTCT nh th no. A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 31 : Este A c ieu che t aminoaxit B (ch cha C, H, O, N) va ancol metylic. T khoi hi cua A so vi H2 la 44,5. CTCT cua A la A. H2N CH2 CH2 COOCH3. B. H2N CH2 COOCH3. C. H2N CH2 CH(NH2) COOCH3. D. CH3 CH(NH2) COOCH3. Cu 32 : DD X gom HCl va H2SO4 co pH=2. e trung hoa hoan toan 0,58g hon hp 2 amin no n chc bac 1 (co so ngt C nho hn hoac bang 4) phai dung 1 lt dd X. Cong thc cua 2 amin co the la A. CH3NH2 va C4H9NH2. B. C2H5NH2 va C4H9NH2. C. C3H7NH2 va C4H9NH2. D. Ca A va B. Cu 33 : ot chay hoan toan ong ang X cua axit aminoaxetic, thu c t le so mol CO2 : H2O la 6 : 7. Cac CTCT co the co cua X la A.CH3CH(NH2)COOH;H2NCH2CH2COOH. B.CH3CH2CH(NH2)COOH; H2NCH2CH2CH2COOH.
Nguyn Trung Kin Lp 12A1 Trang 75

C. CH3CH2CH2CH(NH2)COOH ; H2N[CH2]4COOH. D. CH3[CH2]3CH(NH2)COOH ; H2N[CH2]5COOH. Cu 34 : ot chay hoan toan a mol aminoaxit A thu c 2a mol CO2 va a/2 mol N2. Aminoaxit A la A. H2NCH2COOH. B. H2N[CH2]2COOH. C. H2N[CH2]3COOH. D. H2NCH(COOH)2. Cu 35 : Cho 0,01 mol aminoaxit X tac dung va u vi 80ml dd HCl 0,125M, sau o co can dd thu c 1,835g muoi. Phan t khoi cua X la A. 174. B. 147. C. 197. D. 187.

CHNG 3: AMIN AMINO AXIT PROTEIN

Cu1. Amin c CTPT C4H11N c my ng phn mch khng phn nhnh ? A. 2 D. 6
C. 7 D. 8

B. 3

C.
B.

5
6

Cu2.C bao nhiu ng phn amin ng vi CTPT C4H11N ? A. 5 Cu 3. Nguyn nhn no sau y lm anilin tc dng c vi nc brom? A. Do nhn thm benzen c h thng lin kt bn vng. B. Do nhn thm benzen ht electron. C. Do nhn thm benzen y electron. D. Do nhm - NH2 y electron lm tng mt electron cc v tr o- v p-

Cu 4. Cho cc cht sau : CH3CH2NHCH3(1), CH3CH2CH2NH2(2), (CH3)3N (3).Tnh baz tng dn theo dy no ? A. (1) < (2) < (3) (3) < (1) < (2) B. (2) < (3) < (1) C. (3) < (2) < (1) D.

Cu 5.Cho cc cht sau: Ancol etylic (1), etylamim (2), (4). A. (2) < (3) < (4) < (1) D. (1) < (3) < (2) < (4) Cu 6.Hp cht c CTCT nh sau: thng l A. etylmetyl amino butan C. butyletylmetylamin Cu 7.Hp cht c CTCT nh sau php IUPAC l: A. 3-amino-5-hiroxi-2-metylhexanal. aminohexanal. C. 5-oxo-4-aminohexanol-2.
CH 3 CH CH 2 CH CH CH 3 | | | OH NH 2 CHO

metylamim (3), axit axetic

Dy sp sp theo chiu c nhit si tng dn l dy no ? B. (2) < (3) < (4) < (1)
CH3 CH2 CH2 2 N CH | CH3 CH2

C.
CH 3

(3) < (2) < (1) < (4)

.Tn theo danh php thng

B. metyletyl amino butan D. metyletylbutylamin . Tn hp cht theo danh

B.

5-hiroxi-2-metyl-3-

D. 4-amino-5-oxohexanol.

Cu 8. Khi t nng mt ng ng ca metylamin ngi ta thy t l th tch cc kh v hi VCO2 : VH2O = 2 : 3 . Cng thc phn t ca amin l Trang 76 Nguyn Trung Kin Lp 12A1

A. C2H7N khc

B. C3H9N

C. C4H11N

D. Kt qu

Cu 9.Cho 9 g hn hp X gm 3 amin: propylamin, etylmetylamin, trimetylamin X tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l A. 100ml B. 150 ml C. 200 ml D. Kt qu khc Cu 10. t chy hon ton a mol hn hp X gm 2 amin no n chc thu c 5,6 lt CO2 (ktc) v 7,2 g H2O. Gi tr ca a l A. 0,05 mol B. 0,1 mol C. 0,15 mol D. 0,2 mol

Cu 11.t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng, thu c 22 g CO2 v 14,4 g H2O. CTPT ca hai amin l A. CH3NH2 v C2H7N v C5H13N B. C2H7N v C3H9N C. C3H9N v C4H11N D. C4H11N

Cu 12. Cho 13,35 g hn hp X gm CH2NH2CH2COOH v CH3CHNH2COOH tc dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V: A. 100 ml D. 250 ml B. 150 ml C. 200 ml

Cu 13.Cho 20,15 g hn hp X gm (CH2NH2COOH v CH3CHNH2COOH) tc dng vi 200 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 450 ml dung dch NaOH 1M. Phn trm khi lng ca mi cht trong X l A. 55,83 % v 44,17 % D.52,59 % v 47,41% B. 58,53 % v 41,47 % C. 53,58 % v 46,42 %

Cu 14 .A l mt hp cht hu c c CTPT C5H11O2N. un A vi dung dch NaOH thu c mt hp cht c CTPT C2H4O2NNa v cht hu c B. Cho hi B qua CuO/t0 thu c cht hu c D c kh nng cho phn ng trng gng. CTCT ca A l A. CH2 = CH - COONH3 - C2H5 B. CH3(CH2)4NO2 C. H2N- CH2 - CH2 - COOC2H5 D. NH2 - CH2COO - CH2 - CH2 - CH3 Cu 15. t chy ht a mol aminoaxit X c 2a mol CO2 v a/2 mol N2. Aminoaxit trn c cng thc cu to l: A.H2NCH2COOH B.H2NCH2CH2COOH C.H2NCH2CH2CH2COOH D. H2NCH(COOH)2 Cu 16 . Cho m gam hn hp X gm glixin v alanin tc dng vi dung dch NaOH va thu c m+11 gam mui. Nu t chy hon ton m gam hn hp X th cn 35,28 lt O2 (ktc). m c gi tr l : A. 43,1 gam B. 40,3 gam C. 41,7 gam D. 38,9 gam Cu 17. Khi thy phn hon ton 55,95 gam mt peptit X thu c 66,75 gam alanin (amino axit duy nht). X l A. tripeptit B. tetrapeptit C.pentapeptit D. ipeptit Cu 18. Hn hp X gm 2 amin no n chc mch h ng ng k tip c phn trm khi lng nit l 20,144%. Phn trm s mol cc amin trong X theo chiu tng dn phn t khi l : A. 50% v 50% B. 25% v 75% C. 20% v 80% D. 30 v 70% Cu 19. DD X gom HCl va H2SO4 co pH=2. e trung hoa hoan toan 0,58g hon hp 2 amin no n chc bac 1 (co so ngt C nho hn hoac bang 4) phai dung 1 lt dd X. Cong thc cua 2 amin co the la A. CH3NH2 va C4H9NH2. B. C2H5NH2 va C4H9NH2. C. C3H7NH2 va C4H9NH2. D. Ca A va B. Cu 20 . Cht A c thnh phn % cc nguyn t C, H, N ln lt l 40,45%, 7,86%, 15,73% cn li l oxi. Khi lng mol phn t ca A <100 g/mol. A tc dng c vi NaOH v vi HCl, c ngun gc t thin nhin, A c CTCT nh th no. A. CH3 CH(NH2) COOH B. H2N (CH2)2 COOH C. H2N CH2 COOH Nguyn Trung Kin Lp 12A1 D. H2N (CH2)3 COOH Trang 77

Cu 21. Mt hemoglobin (hng cu ca mu) cha 0,4% Fe (mi phn t hemoglobin ch cha 1 nguyn t Fe). Phn t khi gn ng ca hemoglobin trn l : A. 12000 B. 14000 C. 15000 D. 18000 Cu 22. kt ta ht 400ml dung dch hn hp HCl 0,5M v FeCl3 0,8M cn bao nhiu gam hn hp gm metylamin v etylamin c t khi so vi H2 l 17,25? A.41,4 gam B. 40,02 gam C. 51,75 gam D. Khng iu kin tnh. Cu 23. Metylamin d tan trong H2O do nguyn nhn no sau y ? A. Do nguyn t N cn cp electron t do d nhn H+ ca H2O. B. Do metylamin c lin kt H lin phn t. C. Do phn t metylamin phn cc mnh. D. Do phn t metylamin to c lin kt H vi H2O Cu 24. X l amin no n chc mch h v Y l amin no 2 ln amin mch h.c cng s cacbon.
Trung ha hn hp gm a mol X v b mol Y cn dung dch cha 0,5 mol HCl v to ra 43,15 gam hn hp mui. Trung ha hn hp gm b mol X v a mol Y cn dung dch cha 0,4 mol HCl v to ra p gam hn hp mui. p c gi tr l : A. 40,9 gam B. 38 gam C. 48,95 gam D. 32,525 gam + Cu 25. Mui C6H5N2 Cl (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l A. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,2 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,3 mol.

CHUYN AMIN-AMINOAXIT Cu 1. Hy cho bit kt lun no sau y ng nht? A. Nguyn nhn gy ra tnh cht baz ca amin l do phn t c cha N c m in ln. B. Do amin c to lin kt hiro vi nc v vi cc axit. C. Do amin c nguyn t Nit lin kt vi cc gc hirocacbon. D. Do nguyn t Nit trong amin cn cp electron cha lin kt linh ng c th to lin kt cho nhn vi H+. Cu 2. Cht no sau y khng c kt ta trng khi cho dung dch Br2 vo dung dch cht ? A. phenyl amoni clorua B. phenol B. anilin D. p-Metylanilin. Cu 3. Khi cho dung dch NaOH vo dung dch phenyl amoni clorua, hy cho bit hin tng no s xy ra? A. thu c dung dch ng nht B. thu c kt ta trng C. ban u thu c dung dch ng nht sau tch thnh 2 lp. D. tch lun thnh 2 lp. Cu 4. Cht X c cha vng benzen v c cng thc phn t l C 7H9N. Khi cho X tc dng vi brom (dd) thu c kt ta Y c cng thc phn t khi l C7H6NBr3. Hy cho bit X c bao nhiu cng thc cu to ? A. 1 B. 2 C. 3 D. 4 Cu 5. Hp cht X c vng benzen v c CTPT l CxHyN. Khi cho X tc dng vi HCl thu c mui Y c cng thc dng RNH2Cl. Trong cc phn t X, % khi lng ca N l 11,57%; Hy cho bit X c bao nhiu cng thc cu to? A. 3 B. 4 C. 5 D. 6 Cu 6. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A. 100 ml B. 50 ml C. 200 ml D. 320 ml Cu 7. Cht X c cng thc phn t l C7H9N. Khi cho X tc dng vi dung dch Br2 thu c kt ta trng. Hy cho bit X c bao nhiu cng thc cu to ? A. 2 B. 3 C. 4 D. 5 Cu 8. tch ring tng cht t hh benzen, anilin v phenol ta ch cn dng cc ho cht (dng c, iu kin th nghim y ) l: A. dung dch NaOH, dung dch HCl v kh CO2 B. dung dch NaOH, dung dch NaCl v kh CO2 . C. dung dch NaOH, dung dch Br2 v kh CO2 . D. dung dch HCl, dung dch Br2 v kh CO2 . Cu 9. Cho cht X c cng thc phn t l C3H7O2N. un nng X vi NaOH thu c mui cacboxylat, H2O v cht hu c Y. Hy cho bit X c bao nhiu cng thc cu to tha mn. A. 2 B. 3 C. 4 D. 5 Cu 10. C cc dung dch : natriphenolat, anilin, phenol, phenyl amoni clorua. Ha cht no c th s dng nhn bit cc dung dch (Nu gi thit rng chng c t trong cc bnh mt nhn). Cc dng c v thit b c . A. dd NaOH, dd Br2, qu tm B. qu tm, dung dch HCl v dung dch NaOH Trang 78 Nguyn Trung Kin Lp 12A1

C. qu tm, dung dch HCl v dung dch Br2. D. phenolphtalein, dung dch HCl v dung dch NaOH. Cu 11. Mt l ha cht m c nghi l phenyl amoni clorua. Ha cht no c th s dng kim tra l ha cht . A. dd NaOH , dd HCl B. dd NaOH, dd AgNO3 C. dd NaOH, dd NH3 D. dd AgNO3, dd HCl Cu 12. Dng tn ti ch yu ca glyxin l dng no sau y: A. H2N-CH2-COOH B. H3N+-CH2-COO -, C. H3N+-CH2-COOH. D. H2N-CH2-COO-. Cu 13. Trng hp no sau y lm hng qu tm tm H2O: A. CH3-CH(NH2)-COOH B. H2N-CH2-COONa C. H2N-CH2-CH(NH2)-COOH. D.ClH3N-CH2-CH2-COOH Cu 14. Cho cc cht sau: Glyxin (I); axit glutamic (II) ; HOOC-CH2-CH2-CH(NH3Cl)-COOH (III) ; H2NCH2-CH(NH2)-COOH (IV) Sp xp cc cht trn theo th t tng dn v pH (gi s chng c cng nng mol/l). A. (I) < (II) < (III) < (IV) B. (III) < (I) < (II) < (IV) C. (III) < (II) < (I) < (IV) D. (III)<(IV) < (I) <(II) Cu 15. Cho dung dch phenolphtalein vo cc dung dch sau: H2N-CH2-CH(NH2)-COOH (1); H2N-CH2COONa (2); ClH3N-CH2COOH (3) ; HOOC-CH2-CH2-CH(NH2)-COOH (4) ; NaOOC-CH2-CH2-CH(NH2)-COONa (5). Hy cho bit dung dch no chuyn sang mu hng? A. (1) (2) (4) (5) B. (1) (2) (5) C. (1) (3) (5) D. (2) (3) (4) (5) Cu 16. Cht X c cng thc phn t C8H15O4N. T X, thc hin bin ha sau: C8H15O4N + dung dch NaOH d ,t0 Natri glutamat + CH4O + C2H6O Hy cho bit, X c th c bao nhiu cng thc cu to? A. 1 B. 2 C. 3 D. 4 + NaOH ,t 0 + HCl du ,t 0 Cu 17. Cho s sau: C4H9O2N C3H6O2NNa X. Hy cho bit X c cng thc phn t l g? A. C3H7O2N B. C3H7O2NaCl C. C3H8O2NCl D. C3H9O2NCl. Cu 18. Cho axit glutamic tc dng vi hn hp ru etylic v metylic trong mi trng HCl khan, hy cho bit c th thu c bao nhiu loi este? A. 5 B. 6 C. 7 D. 8 Cu 19. Cht no sau y c nhit nng chy cao nht? A. CH3CH2CH(NH2)-COOH B. CH3CH(NH2)-COOCH3 C. H2N-CH2-COOC2H5 D. CH3COOCH2CH2NH2 Cu 20. Mt hn hp gm alanin v glixin. Hy cho bit t hn hp d c th to nn bao nhiu loi ipeptit mch h. A. 1 B. 2 C. 3 D. 4 Cu 21. Trong mi trng HCl khan, khi thc hin P este ha gia glyxin vi ru metylic, sn phm hu c cui cng thu c l: A. H2N-CH2-COOCH3 B. ClH3N-CH2-COOCH3 C. ClH3N-CH2COOH D. ClH3NCH(CH3)COOCH3 Cu 22. Hy cho bit, trong cc dng tn ti sau, dng tn ti no l ch yu ca axit glutamic trong dung dch ca n ? A. HOOC-CH2-CH2-CH(NH+3)-COOB. - OOC-CH2-CH2-CH(NH+3)-COOH C. HOOC-CH2-CH2-CH(NH+3)-COOH D. - OOC-CH2-CH2-CH(NH2)-COO Cu 23. Cho s sau: dd NaOH, t0 X -NH3, -H2O X1 H2SO4 -Na2SO4 C2H5OH/ H2SO4 c, X2 t0 CH3-CH-COOC2H5 -H2O NH3HSO4

Hy cho bit cht X l A. CH3-CH(NH2)-COONH4 B. CH3-CH(NH3Cl)-COOH C. CH3-CH(NH2)-COONH2 D. H2N-CH2-COONH4 Cu 24. Hy cho bit dng qu tm c th phn bit c dy cc dung dch no sau y ? A. glyxin ; H2N-CH2COOCH3 ; H2N-CH2COONa. B. glyxin ; H2N-CH2COONa ; H2N-CH2-CH2COONa. C. glyxin ; H2N-CH2-COONa ; axit glutamic. D. ClH3N-CH2COOH, axit glutamic, glyxin. Nguyn Trung Kin Lp 12A1

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Cu 25. Cht X c cng thc phn t l C3H9O2N. un nng X trong NaOH thu c mui cacboxylat Y, H2O v cht hu c Z. T khi ca Z i vi H2 > 15. Hy cho bit c bao nhiu cht hu c X tha mn. A. 1 B. 2 C. 3 D. 4 Cu 26. Cht X c cng thc phn t l C4H9O2N. X tc dng vi NaOH v HCl. un nng X trong NaOH thu c mui X1 c cng thc l C3H3O2Na. Hy cho bit tn gi ca X. A. metyl amoni axetat B. metyl amoni acrylat C. amoni metacrrylat D. mety amoni propionat. Cu 27. Cht X c CTPT l C4H9O2N. Khi cho X tc dng vi NaOH un nng thu c mui X1 c cng thc l C2H4O2NNa. Hy cho bit cng thc cu to ca X. A. H2N-CH2-COOCH3 B. H2N-CH2-CH2-COOCH3 C. H2N-CH2-COOCH2-CH3 D. CH3-CH(NH2)-COOCH3 Cu 28. Mt aminoaxit no X tn ti trong t nhin (ch cha mt nhm - NH2 v mt nhm - COOH). Cho 0,89g X phn ng va vi HCl to ra 1,255g mui. Cng thc cu to ca X l: A. H2N-CH2-COOH. B. CH3-CH(NH2)-COOH C. H2N-CH2-CH2-COOH. D. B, C u ng. Cu 29. Este X c iu ch t aminoaxit X1 v ru etylic. X khng tc dng vi Na. t chy hon ton 2,03 gam cht X thu c 3,96 gam CO2; 1,53gam nc v 112 ml N2 (ktc). a/ X c cng thc phn t trng vi cng thc n gin nht. Cng thc phn t ca X l: A. C5H11O2N B. C7H13O2N C. C9H17O4N D. C10H17O4N b/ un nng 0,1 mol X vi 200 ml NaOH 1,5M; sau khi phn ng hon ton, em c cn cn thn dung dch sau phn ng, thu c cht rn G c khi lng l: A. 19,1 gam B. 23,1 gam C. 27,7 gam D. 32,3 gam. c/ Cho ton b cht rn G vo dd HCl d, sau em c cn cn thn dung dch sau phn ng thu c cht rn E c khi lng l: A. 54,25 gam B. 48,4 gam C. 42,55 gam D. 35,9 gam Cu 30. X l cht hu c c dng: ROOC-(CH2)n-CH(NH2)-COOR. un nng 0,1 mol X trong 200 ml dung dch NaOH 1,5M, sau khi phn ng xy ra hon ton, c cn cn thn dung dch sau phn ng thu c 9,2 gam ru v dung dch Y. a/ Cng thc ca ru l : A. CH3OH B. C2H5OH C. CH3CH2CH2OH D. CH2=CH-CH2OH b/ C cn dung dch Y thu c cht rn Z c khi lng l 23,1 gam. Xc nh n. A. n = 0 B. n = 1 C. n = 2 D. n = 3 c/ Cho ton b cht rn Z vo dung dch HCl d, sau em c cn cn thn thu c bao nhiu gam cht rn khan. A. 35,9 gam B. 30,05 gam C. 24,2 gam D. 18,35 gam. Cu 31. Cht no sau y lm i mu qu tm: H2N-CH2-CH(NH2)-COOH (I) ; HOOC-CH(NH2)-CH2COOH (II) ; H2N-CH2-COOH (III) ; CH3CH(NH2)COOH (IV); ClH3N-CH2COOH (V); ClH3N-CH2-COOCH3 (VI) v H2N-CH2COONa (VII). A. (I) (II) (V) (VI) v (VII) B. (I) (II) (III) (IV) v (VII) C. (I) (II) v (VII) D. (I) v (II) Cu 32. Cho 0,1 mol -amino axit X tc dng va vi 0,1 mol HCl. Trong mt th nghim khc, cho 26,7 gam X vo dung dch HCl d, sau c cn cn thn thu c 37,65 gam mui khan. Vy X l: A. glixin B. alanin C. glutamic D. -amino butiric. Cu 33. Thc hin phn ng este ha gia alanin vi ru metylic trong mi trng HCl khan, thu c cht hu c X. Dung dch cht X c mi trng axit. Vy X l: A. H2NCH(CH3)-COOCH3 B. ClH3N-CH(CH3)-COOCH3 C. H2NCH2COOCH3 D. ClH3NCH2COOCH3 Cu 34. Cho 0,1 mol -amino axit X (X c mch cacbon khng phn nhnh) tc dng va vi 0,2 mol NaOH thu c 17,7 gam mui. Mt khc, 2,66 gam X tc dng vi HCl (va ) cho 3,39 gam mui Y. a/ Vy X l: A. HOOC-CH(NH2)-COOH B. HOOC-CH2-CH(NH2)-COOH C. HOOC-(CH2)2-CH(NH2)-COOH D. HOOC-(CH2)3-CH(NH2)-COOH b/ Nu cho 3,39 gam mui Y tc dng vi 200 ml dung dch NaOH (ly d) , sau phn ng hon ton, c cn cn thn dung dch thu c 5,91 gam cht rn khan. Xc nh nng mol/l ca dung dch NaOH? A. 0,3M B. 0,35M C. 0,4M D. 0,45M

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Nguyn Trung Kin Lp 12A1

Cu 35. Cho aminoaxit X (cha 1 nhm amino v 1 nhm cacboxyl). Cho m gam X tc dng va vi NaOH, thu c 8,88 gam mui Y. Mt khc, cho m gam X tc dng vi dung dch HCl d, c cn cn thn dung dch thu c 10,04 gam hn hp mui Z. a/ Xc nh m. A. 7,12 gam B. 7,18 gam C. 8,04 gam D. 8,16 gam b/ Xc nh s cng thc cu to c th c ca X. A. 1 B. 2 C. 3 D. 4 Cu 36. Cho cc cht v ion no sau: H3N+-CH2COOH; H2N-CH2-CH(NH2)-COONa; HOOC-CH2-CH2CH(NH2)-COOH; H2N-CH2COOH; CH2=CH-COONH3CH3; CH3-CH(NH2)-COOH. Hy cho bit c bao nhiu cht hoc ion c tnh cht lng tnh. A. 1 B. 2 C. 3 D. 4 Cu 37. Cho s sau: X(C3H7O2N) X1(C3H8O2NCl) X2 (C2H4O2NNa) X3 (C2H6O2NCl) a/ Hy cho bit cht no trong s cc cht trong s c nhit nng chy thp nht. A. cht X B. cht X1 C. cht X2 D. cht X3 b/ Hy cho bit c bao nhiu cht c kh nng i mu qu tm? A. 1 B. 2 C. 3 D. 4 Cu 38. Hp cht X, Y l ng phn ca nhau c cng thc phn t l C4H11O2N. Khi cho 0,15 mol hn hp G gm X, Y tc dng vi dung dch NaOH va th thu c 13,7 gam hn hp mui natri ca 2 axit cacboxylic n chc v hn hp hi gm 2 amin l ng ng k tip nhau. a/ Cng thc cu to ca X, Y l: A.CH3COOH3NCH2CH3vHCOOH3NCH2CH2CH3 B.CH3COOH2N(CH3)2vHCOOH2N(CH3)CH2CH3 C. CH3COOH3NCH2CH3 v CH3CH2COOH3NCH3 D.CH3COOH2N(CH3)2 v HCOOHN(CH3)3 b/ Hp th hon ton lng amin thu c bi dung dch HCl, sao em c cn cn thn dung dch sau phn ng thu c cht rn c khi lng l: A. 10,675 gam B. 10,825 gam C. 11,19 gam D. 12,125 gam c/ chng minh tnh lng tnh ca X hoc Y cn cho X hoc Y tc dng vi cht no sau y? A. dung dch NaOH v dung dch NH4Cl B. dung dch HCl v dung dch NH3 C. dung dch HCl v dung dch NaOH D. dung dch NH4Cl v dung dch NH3 Cu 39. Mt aminoaxit no X tn ti trong t nhin (ch cha mt nhm - NH2 v mt nhm - COOH). Cho 0,89g X phn ng va vi HCl to ra 1,255g mui. Cng thc cu to ca X l: A. H2N CH2 COOH. B. CH3-CH(NH2)-COOH C. H2N-CH2-CH2-COOH. D. B, C u ng. Cu 40. Cho X l mt aminoaxit. Khi cho 0,01mol X tc dng vi HCl th dng ht 80ml dd HCl 0,125M v thu c 1,835g mui khan. Cn khi cho 0,01mol X tc dng vi dung dch NaOH th cn dng 25gam dd NaOH 3,2%. Cng thc cu to ca X l: A. C3H6(NH2)-COOH B. C2H4(NH2)COOH C. H2N-C3H5(COOH)2 D. (H2N)2C3H5 COOH Cu 41. t chy hon ton 6,52 gam cht X (cha C, H, O, N) thu c 10,56 gam CO 2, 4,68 gam H2O v 0,448 lt N2 (ktc). a/ Xc nh CTPT ca X, bit n trng vi cng thc n gin. A. C6H7O2N B. C6H7O4N C. C6H13O2N D. C6H13O4N o b/ T X, ngi ta thc hin dy bin ha sau: X + NaOH d, t X1 + CH4O + C2H6O Bit rng X1 c nhm NH2 v tr - v X1 c mch cacbon khng phn nhnh. Hy cho bit X c bao nhiu cng thc cu to ? A. 1 B. 2 C. 3 D. 4 c/ Hy cho bit 0,1 mol X1 tc dng ti a bao nhiu mol HCl. A. 0,1 mol B. 0,2 mol C. 0,3 mol D. 0,4 mol. Cu 42. X l -aminoaxit c mch cacbon no khng phn nhnh cha 2 nhm amino 2 cacbon khng cnh nhau v 1 nhm cacboxyl. a/ Cng thc chung ca dy ng ng cha X l: A. CnH2n(NH2)2COOH (n 2) B. CnH2n-1(NH2)2COOH (n 2) C. CnH2n-1(NH2)2COOH (n 3) D.CnH2n(NH2)2COOH(n 3) b/ Cho 1,18 gam X vo dung dch HCl d, c cn cn thn dung dch sau phn ng thu c 1,91 gam cht rn E. Mt khc, cho 1,18 gam cht rn E vo 200 ml dung dch KOH (d) , un nng cc phn ng xy ra hon ton. C cn cn thn dung dch sau phn ng thu c 3,8 gam cht rn khan. Xc nh nng mol/l ca dung dch KOH. A. 0,2M B. 0,25M C. 0,3M D. 0,35M Nguyn Trung Kin Lp 12A1 Trang 81

Cu 43. E, F l ng phn ca nhau v c cng thc phn t l C4H9O2N. Khi cho E, F cng tc dng vi dung dch NaOH un nng th t E thu c mui E1 c cng thc phn t C4H8O2NNa cn F thu c mui F1 c cng thc phn t l C3H6O2NNa. C E1 v F1 u c nhm NH2. a/ Xc nh s lng ng phn ca E v ca F. A. E-3 ; F -2 B. E -4 ; F -3 C. E - 5 ; F -2 D. E - 5 ; F -3 b/ S sp xp no sau y ng vi chiu tng dn v pH ca 2 dung dch E, F nu chng c cng nng mol/l ? A. E > F B. E < F C. E = F D. khng xc nh. Cu 44. X l amino axit no ch cha mt nhm -COOH v mt nhm -NH2 v tr -. Cho X tc dng va vi 16,6 ml dung dch HCl 20% ( d = 1,1 g/ml) thu c dung dch G. Cho dung dch G tc dng hon ton v va vi V ml dung dch NaOH 0,5M thu c dung dch F. a/ Xc nh V. A. 200 ml B. 300 ml C. 400 ml D. 250 ml b/ C cn cn thn dung dch F thu c 15,55 gam mui khan. Cng thc ca X l: A. H2N-CH2-COOH B. H2N-CH(CH3)-COOH C. CH3CH2CH(NH2)COOH D.(CH3)2C(NH2)-COOH Cu 45. Cht hu c X cng thc phn t l C3H9O2N. un nng cc cht vi NaOH u thu c mui cacboxylat v amin. Hy cho bit c bao nhiu cng thc cu to ph hp vi X. A. 1 B. 2 C. 3 D. 4 Cu 46. Cht no sau y l cht rn : A. C3H5(OH)3 ; B. CH2Cl-CHCl-CH2Cl C. H2N-CH2-COOH ; D. C6H6 Cu 47. Cho 0,1 mol X tc dng va vi 0,1 mol axit H2SO4; 0,1 mol X tc dng va vi 0,1 mol NaOH. Hy cho bit cng thc chung no ng vi axit X. A. R(NH2)COOH B. R(NH2)2COOH C. R(NH2)(COOH)2 D. R(NH2)2(COOH)2 Cu 48. Cho s sau: X(C3H7O2N) X1(C3H8O2NCl) X2 (C2H4O2NNa) X3 (C2H6O2NCl) X4 (C2H6O5N2) a/ Hy cho bit cht no trong s cc cht trong s c nhit nng chy thp nht. A. cht X B. cht X1 C. cht X2 D. cht X3 b/ Nhng cht no lm qu tm i sang mu ? A. cht Cu 49. Thc hin phn ng ca glixin vi CH3OH trong mi trng HCl khan, ngi ta thu c cht X c cng thc l: ClH3N-CH2-COOCH3. Hy cho bit c th ch ha X vi cht no sau y c th thu c cht Y c cng thc H2N-CH2COOCH3 vi hiu sut cao nht: A. NaOH B. AgNO3 C. NH3 D. Ba(OH)2

gluxit - aminoaxit
Phn 1 : Bi tp v l thuyt Cu 1: C th dng Cu(OH)2 phn bit c cc cht trong nhm A. CH3COOH, C2H3COOH. B. C3H7OH, CH3CHO. C. C3H5(OH)3, C2H4(OH)2. D. C3H5(OH)3, C12H22O11 (saccaroz). Cu 2: un nng dung dch cha 27 gam glucoz vi dung dch AgNO3/NH3 (d) th khi lng Ag ti a thu c l A. 32,4 gam. B. 21,6 gam. C. 16,2 gam. D. 10,8 gam. Cu 3: Dy gm cc dung dch u tc dng vi Cu(OH)2 l A. glucoz, glixerol, anehit fomic, natri axetat. B. glucoz, glixerol, mantoz, natri axetat. C. glucoz, glixerol, mantoz, axit axetic. D. glucoz, glixerol, mantoz, ancol etylic. Cu 4: Mt cacbonhirat X c cng thc n gin nht l CH2O. Cho 18 gam X tc dng vi dung dch AgNO3/NH3 (d, un nng) thu c 21,6 gam bc. Cng thc phn t ca X l A. C2H4O2. B. C3H6O3. C. C6H12O6. D. C5H10O5. Trang 82 Nguyn Trung Kin Lp 12A1

Cu 5: Nhm m tt c cc cht u tc dng c vi dd AgNO3/NH3 l A. C2H2 , C2H5OH, Glucoz B. C3H5(OH)3, Glucoz, CH3CHO C. C2H2 , C2H4 , C2H6 D. C2H2 , Glucoz, CH3CHO Cu 6: Phn ng no sau y chuyn Glucz v Fructoz thnh mt sn phm duy nht? A. Phn ng vi Cu(OH)2 un nng B. Phn ng vi Na C. Phn ng vi dd AgNO3 trng NH3 D. Phn ng vi H2(Ni, t0) Cu 7: Thuc th no sau y dng nhn bit c tt c cc dd: Glucoz, glixerin, fomanehit, ru etylic. A.Na kim loi B.Nc brom C. Cu(OH)2 D.Dung dch AgNO3/NH3 Cu 8: Cho Glucoz ln men thnh ru etylic. Ton b kh CO2 sinh ra trong qu trnh ny c hp th ht vo dd Ca(OH)2 d to ra 25 gam kt ta. Khi lng glucoz dng l?bit hiu sut qu trnh ln men l 80%. A. 23,25 g B.28,125g C.30,4g D.31,76g Cu 9: Cho 2,5 kg glucoz (cha 20% tp cht) ln men thnh ru etylic. Trong qu trnh ch bin, ru b hao ht 10%. Khi lng ru thu c l? A. 800g B. 870g C.920g D. 925g Cu 10 phn bit glucoz, saccaroz v anehit axetic c th dng cht no trong s cc cht sau lm thuc th? A. Cu(OH)2 B.NaOH C. HNO3 D. AgNO3/NH3 Cu 11: Khi lng glucoz to thnh khi thu phn 10 kg go c 80% tinh bt l? A. 7,79 kg B. 8,08 kg C. 8,78 kg D.8,889 kg Cu 12: Cho s chuyn ha sau: Tinh bt X Y axit axetic. X v Y ln lt l A. ancol etylic, anehit axetic. B. glucoz, ancol etylic. C. glucoz, etyl axetat. D. mantoz, glucoz. Cu 13: Cho 5 nhm cht hu c sau: (I) Glucoz v anehit axetic , (II) Glucoz v ru etylic, (III) Glucoz v glixerin, (IV) Glucoz v axit nitric , (V)Glucoz v anehitfomic. Thuc th no sau y c th nhn bit c tt c cc cht trong mi nhm trn? A. Na B. Cu(OH)2/NaOH C.NaOH D.AgNO3?NH3 E. Qu tm Cu 14: Cho 3 nhm cht hu c sau: (I) Saccaroz v dd glucoz, (II) Saccaroz v mantoz, (III)Saccaroz, mantoz v anehit axetic thuc th no sau y c th nhn bit tt c cc cht trong mi nhm cho trn? A. Na2CO3 B. Cu(OH)2/NaOH C.Na D.AgNO3?NH3 E. H2SO4 Cu 15: Pht biu no sau y khng ng. A.Hp cht saccaroz thuc loi isaccarit, phn t ny c cu to bi 2 gc glucoz. B.ng phn ca saccaroz l mantoz. C.ng saccaroz l ng ma, ng tht nt, ng c ci, ng knh , ng phn. D.Phn t saccaroz c nhiu nhm hiroxyl nhng khng c nhm cacbonyl. Cu 16: Ch dng mt thuc th, hy phn bit 3 dd : ru n - propylic, Glyxerol, Glucoz ng trong 3 l mt nhn. Vit phng trnh ho hc ca cc phn ng xy ra. Cu17: Dung dch saccaroz khng cho phn ng trng gng nhng khi ung nng vi vi git axit H2SO4 th dd thu c li cho phnt ng trng gng. Hy gii thch v vit ptp. Cu 18: 2,5 kg glucoz c 20 % tp cht tr cho ln men thnh ru etylic. Tm th tch ru etylic 400 thu c? Bit : - Khi lng ring ca C2H5OH nguyn cht l 0,8 g/ml. - Hiu sut qu trnh l 90 %. A. 2875 ml B. 4325 ml C. 1124 ml D. 4434 ml Cu 19: Nguyn Trung Kin Lp 12A1 Trang 83

Trnh by phng php ho hc nhn bit 3 dd : fructz , Glyxerol, Glucoz ng trong 3 l ring bit. Vit phng trnh ho hc ca cc phn ng xy ra. Cu 20: Vit phng trnh ho hc ca cc phn ng theo s chuyn ho sau y: Saccaroz Glucoz ru etylic axit axetic vinyl axetat Cu 21: trng mt s gng soi, ngi ta phi un nng dd cha 36 gam glucoz vi lng va dd AgNO3 trong NH3 . Khi lng bc sinh ra bm vo mt knh ca gng v khi lng bc nitrat cn dng ln lt l? ( bit p xy ra hon ton ) A. 42,3 g v 86 g B. 43,2 g v 68 g C. 43,2 g v 78 g D. 34,2 g v 68g Cu 22: Hon thnh ptp theo s p sau , ghi r kp nu c : Sobitol
Quang hp

Cy xanh

Glucoz

Ru etylic Axit gluconic .

axit axetic .

Cu 23: trng mt s rut phch, ngi ta phi dng 100 gam saccaroz . Hy vit cc pt ho hc ca phn ng xy ra. Khi lng AgNO3 cn dng v khi lng Ag to ra l ?. Ga thit cc p xy ra hon ton . A. 198,83g v 126,3g B. 198,83g v 256,7g C. 223.4g v 126,3g Cu 24: Tnh khi lng glucoz to thnh khi thu phn ; a, 1kg bt go c 80 % tinh bt . b, 1kg saccaroz . Ga thit cc p xy ra hon ton .

bi tp v tinh bt - xenluloz - amino axit

Cu 1: Mantoz, xenluloz v tinh bt u c phn ng A. mu vi it. B. vi dung dch NaCl. C. trng gng. D. thu phn trong mi trng axit. Cu 2: Nhm m tt c cc cht u tc dng c vi H2O (khi c mt cht xc tc trong iu kin thch hp) l A. Saccaroz, CH3COOCH3, benzen. B. C2H4, CH4, C2H2. C. C2H6, CH3-COO-CH3, tinh bt. D. Tinh bt, C2H4, C2H2. Cu 3: Polime no c cu trc dng mch phn nhnh? A. Poli isopren B. PVC C. Aminopectin ca tinh bt D. Tt c u ng. Cu 4: chng minh amino axit l hp cht lng tnh ta c th dng phn ng ca cht ny vi A. dung dch HCl v dung dch Na2SO4 . B. dung dch KOH v CuO. C. dung dch KOH v dung dch HCl. D. dung dch NaOH v dung dch NH3. Cu 5: Phn bit 3 dung dch: H2N-CH2-COOH, CH3COOH v C2H5-NH2 ch cn dng 1 thuc th l A. natri kim loi. B. dung dch NaOH. C. qu tm. D. dung dch HCl. Cu 6: C 3 cht hu c : NH2 -CH2 -COOH, CH3 -CH2 -COOH v NH2 -CH2-CH(NH2)-COOH nhn ra dd ca cc hp cht trn, ngi ta ch cn dng mt thuc th duy nht, vy thuc th l: A. NaOH B. HCl C. CH3OH/HCl D. Qu tm. Cu 7: Trang 84 Nguyn Trung Kin Lp 12A1

Este A c iu ch t amino axit B(ch cha C, H, O, N) v ru metylic. t chy hon ton 8,9 gam este A thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2(o ktc). Bit CTPT ca A trng vi CTGN. CTCT ca A l: A. NH2 - CH2 -COOCH3 B. NH2- CH(CH3)- COOCH3 C.CH3- CH(NH2)- COOCH3 D. NH2- CH(NH2) - COOCH3 Cu 8: cht no sau y u tc dng c vi: NaOH, CaCO3 , Mg, CaO, CH3OH/HCl, HCl. A. Axit axetic B. Glixin C. Alanin D. B hoc C ng Cu 9: t chy ht a mol mt amino axit c 2a mol CO2 v a/2 mol N2. Amino axit trn c CTCT l: A. H2NCH2COOH B. H2N(CH2)2COOH C. H2N(CH2)3COOH D. H2NCH(COOH)2 Cu 10: t chy hon ton m gam amino axit X ( X cha mt nhm -NH2 v mt nhm -COOH) th thu c 0,3 mol CO2 ; 0,25 mol H2O v 1,12 lt kh N2 (ktc). Cng thc ca X l A. H2N-C2H2 -COOH B. H2N-CH2 -COOH C. H2N -C2H4 -COOH D. H2N-C C -COOH Cu 11: Mt amino axit A c 3 nguyn t C trong phn t. Bit 1 mol A phn ng va vi 2 mol NaOH nhng ch phn ng va vi 1 mol HCl. CTCT ca A l: A. CH3 - CH(NH2) - COOH B. HOOC - CH(NH2) - COOH C.H2N - CH2 - CH2 - COOH C. HOOC - CH(NH2) - CH2 - COOH Cu 12: Cho 100 ml dd amino axit A 0,2 M tc dng va vi 80 ml dd NaOH 0,25M. Mt khc 100 ml dd amino axit trn tc dng va vi 80 ml dd HCl 0,5 M. Bit A c t khi hi so vi H2 bng 52. CTPT ca A l: A. (H2N)2C2H3 COOH B. H2NC2H3 (COOH)2 C. (H2N)2C2H2 (COOH)2 D. H2NC3H5(COOH)2 Cu 13: Thu phn m gam tinh bt, sn phm thu c em ln men sn xut ru etylic, ton b kh CO2 sinh ra cho qua dd Ca(OH)2 d, thu c 750 gam kt ta. Nu hiu sut mi qu trnh l 80% th gi tr m l A. 949,2 gam B. 945,0 gam C. 950,5 gam D. 1000 gam Cu 14: Trong mt nh my ru, ngi ta dng nguyn liu l mn ca cha 50 % xenluloz sn xut ru etylic, bit hiu sut ca ton b qu trnh l 70%. sn xut mt tn ru etylic th khi lng mn ca cn dng l: A. 500 kg B. 5051 kg C. 6000 kg D. 5031 kg Cu 15: Este A c iu ch t amino axit B(ch cha C, H, O, N) v ru metylic. t chy hon ton 8,9 gam este A thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2(o ktc). Bit CTPT ca A trng vi CTGN. CTCT ca A l: A. NH2 - CH2 -COOCH3 B. NH2- CH(CH3)- COOCH3 C.CH3- CH(NH2)- COOCH3 D. NH2- CH(NH2) - COOCH3 Cu 16: A l mt - amino axit no, ch cha mt nhm -NH2 v mt nhm - COOH. Cho 8,9 gam A tc dng vi dd HCl d thu c 12,55 gam mui. Xc nh cng thc cu to ca A. Cu 17: A l mt - amino axit no, c mch cacbon khng phn nhnh, ch cha mt nhm -NH2 v hai nhm COOH. Khi t chy hon ton 1 mol A th thu c hn hp kh trong 4,5 mol < nCO2 < 6 mol. Xc nh CTCT ca A. Cu 18: Khi lng xenluloz v khi lng HNO3 cn sn xut 1 tn xeluloz trinitrat, bit s hao ht trong sn xut l 12%. A.619,8 kg v 723 kg B. 619,8 kg v 820 kg C.567,2 kg v 723 kg D. 723 kg v 546kg Cu 19: Th tch dd HNO3 99,67 % ( D = 1,52 g/ml ) cn sn xut 59,4 kg xenluloz trinitrat vi hiu sut phn ng l 90% A. 26,7 lt B. 27,72 lt C. 33,2 lt D. 42,3 lt Nguyn Trung Kin Lp 12A1 Trang 85

Cu 20: T mt loi mn ca cha 60% xenluloz c dng lm nguyn liu sn xut ru etylic. Nu dng mt tn mn ca trn c th iu ch c bao nhiu lt ru 700 ? Bit hiu sut ca qu trnh l 70%, khi lng ring ca ru etylic nguyn cht l 0,8 gam/ml. A. 425,92 lt B. 533,24 lt C. 645, 77 lt D. Mt kt qu khc. Cu 21: t chy hon ton mt amin no n chc, bc 2, mch h X thu c CO2 v hi H2O theo t l s mol tng ng l 2 : 3. CTCT ca X l A. CH3 - NH - CH3 B. CH3 - NH- C2H5 C. CH3 - CH2 - CH2 - NH2 D. C2H5 - NH - C2H5 Cu 22: Cho 20 gam hn hp gm 3 aminno n chc l ng ng k tip nhau tc dng va vi dd HCl 1M. Sau phn ng em c cn dd thu c 31,68 gam mui khan.Th tch ca dd HCl dng l. A. 16 ml B. 32 ml C. 160 ml D. 320 ml Cu 23: t chy hon ton 30 gam mt aminoaxit no, mch h (A) c mt nhm amino v mt nhm cacboxyl cn 20,16 lt kh O2 ( ktc). a) Xc nh CTCT ca A. b) Cho A vo dd HCl d thu c dd B. Cho NaOH n d vo dd B thu c dd C. Vit cc phng trnh ho hc xy ra v xc nh c trong dd B v dd C.

Phn 2 : Bi tp bt buc Cu 1: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l: A. 30kg B. 21 kg C. 42kg D. 10kg Cu 2: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 6,0 kg. B. 5,4 kg. C. 5,0 kg. D. 4,5 kg. Cu 3: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20%) A. 70 lt. B. 49 lt. C. 81 lt. D. 55 lt. Cu 4: T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut phn ng tnh theo xenluloz l 90%). Gi tr ca m l: A. 29,70. B. 33,00. C. 26,73. D. 25,46. Cu 5: Dng 340,1 kg xenluloz v 420 kg HNO3 nguyn cht c th thu c bao nhiu tn zenluloz trinitrat, bit s hao ht trong qa trnh sn xut l 20%? A. 0,75 tn B. 0,6 tn C. 0,5 tn D. 0,85 tn Cu 6: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20%) A. 70 lt. B. 49 lt. C. 81 lt. D. 55 lt. Cu 7: C th tng hp ru etylic t CO2 theo s sau: CO2 tinh bt glucoz ru etylic. Tnh th tch CO2 sinh ra km theo s to thnh ru etylic nu CO2 lc u dng l 1120 lt (ktc) v hiu sut ca mi qun trnh ln lt l 50%; 75%; 80%. A. 373,3 lt B. 280,0 lt C. 149,3 lt D. 112,0 lt Cu 8: Thu phn hon ton 62,5g dung dch saccaroz 17,1% trong mi trng axit (va) ta thu c dung dch M. Cho AgNO3 trong NH3 vo dung dch M v un nh, khi lng bc thu c l: A. 6,25g B. 6,5g C. 6,75g D. 8g

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Cu 9: Phn t khi trung bnh ca xenluloz trong bng l 1750000 vC v trong si gai l 5900000 vC. S mt xch C6H10O5 gn ng c trong cc si trn ln lt l: A. 10802 v 36420 B. 1080 v 3642 C. 108024 v 364197 D. 10803 v 36419 Cu 10: Cho m gam hn hp gm glucoz v fructoz tc dng vi lng d Ag2O trong dung dch NH3 to ra 6,48gam Ag. Cng m gam hn hp ny tc dng ht vi 1,20 gam Br2 trong dung dch. Phn trm s mol ca glucoz trong hn hp l: A. 25% B. 50% C. 12,5% D. 40% Cu 11: Cho 85,5 gam cabohirat A tc dng vi dung dch HCl, ri cho sn phm thu c tc dng vi lng d AgNO3/NH3 to thnh 108 gam Ag kt ta. Vy A l cht no trong cc cht sau y? A. Glucoz B. Fructoz C. Saccaroz D. Xenluloz Cu 12: Thu phn hon ton 62,5 gam dung dch saccaroz 17,1% trong mi trng axit (va ) c dung dch X. Cho dung dch AgNO3/NH3 vo X v un nh c m gam Ag. Gi tr ca m l: A. 6,75 B. 13,5 C. 10,8 D. 7,5 Cu 13: T 1 tn mn ca cha 50% xenluloz c th iu ch c bao nhiu kg etanol. Bit hiu sut ca mi qu trnh thu phn xenluloz v ln men glucoz u t 70%. A. 139,13 B. 198,76 C. 283,94 D. 240,5 Cu 14: T nguyn liu g cha 50% xenluloz, ngi ta iu ch c ancol etylic vi hiu sut 81%. Tnh khi lng g cn thit iu ch c 1000 lt cn 920 (bit ancol nguyn cht c D = 0,8 g/ml). A. 3115kg B. 3200kg C. 3810kg D. 4000kg Cu 15: Hn hp X gm glucoz v saccaroz. Thu phn ht 7,02 gam hn hp X trong mi trng axit thnh dung dch Y. Trung ho ht axit trong dung dch Y ri cho tc dng vi lng d dung dch AgNO3/NH3 th thu c 8,64g Ag. Phn trm khi lng ca saccaroz trong hn hp l: A. 97,14% B. 48,71% C. 24,35% D. 12,17% II. Phn t luyn. Cu 1: Tnh khi lng kt ta Ag hnh thnh khi tin hnh trng gng hon ton dung dch cha 18 gam glucoz? A. 2,16 gam B. 5,40 gam C. 10,80 gam D. 21,60 gam Cu 2: t chy hon ton 0,5130 gam mt cacbonhirat (X) thu c 0,4032 lt CO2 (ktc) v 2,97 gam nc. X c phn t khi < 400 vC v c kh nng d phn ng trng gng. Vy tn gi ca X l g? A. Glucoz B. Saccaroz C. Fructoz D. Mantoz. Cu 3: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l: A. 2,25 gam B. 1,82 gam C. 1,44 gam D. 1,80 gam Cu 4: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l: A. 30kg B. 21 kg C. 42kg D. 10kg Cu 5: trng mt tn gng, ngi ta phi dng 5,4g glucoz, bit hiu sut ca phn ng t 95%. Khi lng bc bm trn tm gng l: A. 6,156g B. 6,35g C. 6,25g D. 6,15g Cu 6: T mt tn nc ma cha 13% saccaroz c th thu c bao nhiu kg saccaroz (trong cc s cho di y). Cho bit hiu sut thu hi saccaroz t 80%. A. 104kg B. 105kg C. 110kg D. 124kg Cu 7: Cho 34,2g mu saccaroz c ln mantoz phn ng hon ton vi dung dch AgNO3/NH3 d thu c 0,216g Ag. Tnh tinh khit ca mu saccaroz trn? A. 1% B. 99% C. 90% D. 10% Cu 8: Nu dng 1 tn khoai cha 20% tinh bt th khi lng glucoz s thu c bao nhiu (trong cc s cho di y) bit hiu sut phn ng l 70%? Nguyn Trung Kin Lp 12A1 Trang 87

A. 160,5kg B. 150,64kg C. 155,55kg D. 165,6kg Cu 9: T 1 tn tinh bt c th u ch mt lng cao su Buna (vi hiu sut chung l 30%) l: A. 0,5 tn B. 0,3 tn C. 0,2 tn D. 0,1 tn Cu 10: sn xut mt tn thuc n piroxilin (xem nh l xenluloz trinitrat nguyn cht) th cn dng mt lng xenluloz l: A. 545,45kg B. 1000kg C. 865kg D. 1135kg. Cu 11: Thu phn hon ton 17,1gam saccaroz, sn phm sinh ra cho tc dng vi lng d ng (II) hioroxit trong dung dch xt nng. Khi lng kt ta ng (I) oxit thu c khi phn ng xy ra hon ton l: A. 2,88gam B. 7,20gam C. 14,40gam D. 28,08gam Cu 12: Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO2 sinh ra hp th ht vo dung dch Ca(OH)2, thu c 55gam kt ta v dung dch X. un k dung dch X thu thm c 10 gam kt ta na. Gi tr ca m l: A. 55 B. 81 C. 83,33 D. 36,11 Cu 13: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 59,4gam xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l: A. 84 B. 20 C. 60 D. 42 Cu 14: Cho 5kg glucoz (cha 20% tp cht) ln men. Bit rng khi lng ancol b hao ht l 10% v khi lng ring ca ancol nguyn cht l 0,8 (g/ml). Th tch dung dch ru 400 thu c l: A. 2,30 lt B. 5,75 lt C. 63,88 lt D. 11,50 lt Cu 15: Th tch dung dch HNO3 96% (D = 1,52 g/ml) cn dng tc dng vi lng d xenluloz to 297 gam xenluloz trinitrat l: A. 43,17 ml B. 150,00ml C. 14390ml D. 129,52ml Cu 16: Ly 51,3 gam mt gluxit X, ho tan X trong nc v thu phn hon ton X (xc tc axit v c). Dung dch thu c cho tc dng vi lng d Ag2O trong dung dch NH3 to ra 64,8 gam Ag kt ta. Cng thc phn t ca X l: A. C12H22O11 B. C12H24O12 C. C18H30O15 D. C18H32O16 Cu 17: un nng dung dch c 10,260 gam cacbohirat X vi lng nh HCl. Cho sn phm thu c tc dng vi lng d AgNO3/NH3 hnh thnh 1,296 gam Ag kt ta. Vy X c th l: A. xenluloz B. glucoz C. fructoz D. saccaroz Cu 18: T m kg nho chn cha 40% ng nho, sn xut c 1000lit ru vang 200. Bit khi lng ring ca C2H5OH l 0,8 gam/ml v hao ph 10% lng ng. Gi tr ca m l: A. 860,75kg B. 8700,00kg C. 8607,5 kg D. 8690,56kg Cu 19: T axit nitric d v 2 tn xenluloz c th sn xut c bao nhiu tn thuc sng khng khi xenluloz trinitrat vi hiu sut phn ng l 60%? A. 1,84 tn B. 3,67 tn C. 2,2 tn D. 1,1 tn Cu 20: Mt loi xenluloz c khi lng phn t 1.500.000 u (vC). Hi thu phn hon ton 1 mol xenluloz thu c bao nhiu mol glucoz? A. 8627 B. 9259 C. 12.048 D. 12.815 5 Cu 21: Mt mu tinh bt c M = 5.10 vC. Thu phn hon ton 1 mol tinh bt th s mol glucoz thu c l: A. 2778 B. 4200 C. 3086 D. 3510 Cu 22: Kh glucoz bng hiro to sobitol. Khi lng glucoz dng to ra 1,82 gam socbitol vi hiu sut 80% l bao nhiu gam?

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A. 2,25 gam

B. 1,44 gam

C. 22,5 gam

D. 14,4

gam Cu 23: Xenluloz trinitrat l cht d chy, n mnh. Mun iu ch 29,7 kg xenluloz trinitrat t xenluloz v axit nitric vi hiu sut 90% th th tch HNO3 96% (D = 1,52 g/ml) cn dng l bao nhiu lt? A. 14,390 lt B. 15,000 lt C. 1,439 lt D. 24,390 lt Cu 24: Cho glucoz ln men vi hiu sut 70% hp th ton b sn phm kh chy thot ra vo 2 lt dung dch NaOH 0,5M (D = 1,05 g/ml) thu c dung dch cha hai mui vi tng nng 12,27%. Khi lng ca glucoz dng l: A. 129,68 gam B. 168,29 gam C. 192,86 gam D. 185,92 gam Cu 25: Tnh th tch dung dch HNO3 96% (D = 1,52 g.ml) cn dng tc dng vi lng d xenluloz to 29,7 gam xeluloz trinitrat. A. 24,39 lt B. 15,00 lt C. 14,39 lt D. 1,439 lt Cu 26: Cho 360 gam glucoz ln men thnh ru etylic (gi s ch xy ra phn ng to thnh ru etylic)v tt c kh cacbonic thot ra hp th vo dung dch NaOH d th thu c 318 gam Na2CO3. Tnh hiu sut phn ng ln men ru. Hy chn p s ng? A. 50% B. 62,5% C. 75% D. 80% Cu 27: Mt loi xenluloz c khi lng phn t 1.500.000 u (vC). Hi thu phn hon ton 1 mol xenluloz thu c bao nhiu mol glucoz? A. 8627 B. 9259 C. 12048 D. 12815 Cu 28: Cho 6,84 gam hn hp saccaroz v mantoz tc dng vi lng d dung dch AgNO3/NH3 c 1,08 gam Ag. S mol saccaroz v mantoz trong hn hp ln lt l: A. 0,01mol v 0,01 mol B. 0,05mol v 0,05 mol C. 0,015mol v 0,005 mol D. 0,01mol v 0,02 mol Cu 29: T 100kg go cha 81% tinh bt c th iu ch c V lt ancol etylic 46%. Bit hiu sut iu ch l 75% v ancol etylic nguyn cht c D = 0,8g/ml. Gi tr ca V l: A. 100 B. 93,75 C. 50,12 D. 43,125 Cu 30: Kh CO2 chim th tch 0,03% th tch khng kh. Mun to ra 500 gam tinh bt th cn bao nhiu m3 khng kh cung cp CO2 cho phn ng quang hp? A. 1382,7 B. 1382,4 C. 140,27 D. 691,33 Cu 31: Xenluloz tc dng vi (CH3CO)2O (xc tc H2SO4 c) to ra 9,84 gam este axetat v 4,8 gam CH3COOH. Cng thc ca este axetat l: A. [C6H7O2(OOCCH3)3]n B. [C6H7O2(OOCCH3)2OH]n C. [C6H7O2(OOCCH3)(OH)2]n D. [C6H7O2(OOCCH3)3]n v [C6H7O2(OOCCH3)OH]n Cu 32: Thu phn 324 gam tinh bt vi hiu sut phn ng l 75% khi lng glucoz thu c l: A. 300 gam B. 270 gam C. 360 gam D. 250 gam Cu 33: Cho m gam glucoz ln men thnh etanol vi hiu sut 80%. Hp th hon ton kh CO2 sinh ra vo dung dch nc vi trong d thu c 20 gam kt ta. Gi tr ca m l: A. 45 B. 22,5 C. 14,4 D. 11,25 ****************** Ht ******************

B GIO DC V O TO

THI TRC NGHIM MN Ho - chng 3 Thi gian lm bi: 90 pht; (50 cu trc nghim) Nguyn Trung Kin Lp 12A1

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M thi HO H, tn th sinh:.......................................................................... Lp :............................................................................... Cu 1: Cng thc ca amin cha 15,05% khi lng nit l cng thc no sau? A. C2H5NH2 B. (CH3)2NH C. C6H5NH2 D. (CH3)3N Cu 2: Cng thc phn t C3H9N ng vi bao nhiu ng phn? A. 5 B. 4 C. 3 D. 2 Cu 3: Cho amin c cu to: CH3-CH(CH3)-NH2 . Chn tn gi khng ng? A. Prop-1-ylamin B. Propan-2-amin C. isoproylamin D. Prop-2-ylamin Cu 4: Amin no di y l amin bc 2? A. CH3-CH2NH2 B. CH3-CHNH2-CH3 C. CH3-NH-CH3 D. CH3-NCH3-CH2CH3 Cu 5: Cng thc no di y l cng thc chung ca dy ng ng amin thm (cha 1 vng bezen) n chc bc nht? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 Cu 6: : Ly 14,6g mt ipeptit to ra t glixin v alanin cho tc dng va vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng: a. 0,1 lit b. 0,2 lt c. 0,3 lt d. 0,4 lt Cu 7: t chy ht a mol mt amino axit X n chc bng oxi va ri ngng t ht hi nc c 2,5a mol hh CO2 v N2. CTPT ca X: a. C5H11NO2 b. C3H7N2O4 c. C3H7NO2 d. C2H5NO2 Cu 8: S d anilin c tnh baz yu hn NH3 l do yu t no? A. Nhm NH2- cn 1 cp electron t do cha tham gia lin kt. B. Nhm NH2- c tc dng y electron v pha vng benzen lm gim mt electron ca N. C. Gc phenyl c nh hng lm gim mt electron ca nguyn t N. D. Phn t khi ca anilin ln hn so vi NH3 Cu 9: Thc hin phn ng este gia amino axit X v ancol CH3OH thu c este Y c t khi hi so vi khng kh bng 3,069. CTCT ca X: a. H2N-CH2-COOH b. H2N-CH2-CH2-COOH c. CH2-CH(NH2)-COOH d. H2N-(CH2)3-COOH Cu 10: Dd etylamin tc dng vi dd nc ca cht no sau y? A. NaOH B. NH3 C. NaCl D. FeCl3 v H2SO4 Cu 11: Hp cht no di y c tnh baz yu nht? A. Anilin B. Metylamin C. Amoniac D. imetylamin Cu 12: Hp cht hu c X ch cha hai loi nhm chc amino v cacboxyl. Cho 100ml dung dch X 0,3M phn ng va vi 48ml dd NaOH 1,25M. Sau em c cn dung dch thu c c 5,31g mui khan. Bt X c mch cacbon khng phn nhnh v nhm NH2 v tr alpha. CTCT ca X: a. CH3CH(NH2)COOH b. CH3C(NH2)(COOH)2 c. CH3CH2C(NH2)(COOH)2 d. CH3CH2CH(NH2)COOH Cu 13: Sp xp cc cht sau y theo tnh baz gim dn? (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. 1>3>5>4>2>6 B. 6>4>3>5>1>2 C. 5>4>2>1>3>6 D. 5>4>2>6>1>3 Cu 14: Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl 3+ + C. Fe + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3 D. CH3NH2 + HNO2 CH3OH + N2 + H2O Cu 15: t chy 1mol amino axit H2N [CH2]n COOH phi cn s mol oxi l: a. (2n+3)/2 b. (6n+3)/2 c. (6n+3)/4 d. (2n+3)/4 Cu 16: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. CH3NH2 + O2 CO2 + N2 + H2O Trang 90 Nguyn Trung Kin Lp 12A1

C. C6H5NH2 + 3Br2 2,4,6-Br3C6H2NH3Br + 2HBr D. C6H5NO2 + 3Fe +6HCl C6H5NH2 + 3FeCl2 + 2H2O Cu 17: Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l: a. xiclohexan, C6H5-CH3 b. C2H2, C6H5-NO2 c. CH4, C6H5-NO2 d. C2H2, C6H5-CH3 Cu 18: Khi t chy cc ng ng ca metylamin thu c CO2 v H2O th t l v th tch K=VCO2:VH2O bin i nh th no theo s lng nguyn t cacbon trong phn t: a. 0,4<K<1 b. 0,25<K<1 c. 0,75<K<1 d. 1<K<1,5 Cu 19: Tn gi ca aminoaxit no di y l ng? A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)-COOH (valin) D. HOOC-(CH2)2-CH(NH2)-COOH (axit glutaric) Cu 20: C3H7O2N c my ng phn aminoaxit (Vi nhm amin bc nht)? A.5 B. 2 C. 3 D. 4 Cu 21: Aminoaxetic khng th phn ng vi: A. Ancol B. Cu(OH)2 C. axit nitric D. Ba(OH)2 Cu 22: Cho cc cht sau: (X1) C6H5NH2; (X2)CH3NH2 ; (X3) H2NCH2COOH; (X4) OOCCH2CH2CH(NH2)COOH (X5) H2NCH2CH2CH2CH2CH(NH2)COOH. Dd no lm qu tm ha xanh? A. X1, X2, X5 B. X2, X3,X4 C. X2, X5 D. X1, X5, X4 Cu 23: Dd no di y lm qu tm ha ? (1) NH2CH2COOH ; (2) Cl-NH3+-CH2COOH ; (3) H3N+CH2COO- ; (4) H2N(CH2)2CH(NH2)COOH; (5) HOOCCH2CH2CH(NH2)COOH A. (3) B. (2) C. (2), (5) D. (1), (4) Cu 24: A l HCHC c cng thc phn t C5H11O2N. un A vi dd NaOH thu c mt hh cht c CTPT C2H4O2NNa v cht hu c B. Cho hi ca B qua CuO/t0 thu c cht C bn trong dd hn hp ca AgNO3 v NH3. CTCT ca A l: A. CH3(CH2)4NO2 B. H2NCH2COOCH2CH2CH3 C. H2NCH2COOCH(CH3)2 D. H2NCH2CH2COOC2H5 Cu 25: Tn gi no sau y l ca peptit H2NCH2CONHCH(CH3)CONHCH2COOH? A. Gly-ala-gly B. Gly-gly-ala C. Ala-gly-gly D. Ala-gly-ala Cu 26: Trong bn ng nghim mt nhn cha ring bit tng dd: Glu, lng trng trng, tinh bt, x phng. Thuc th phn bit ra mi dd l? A. Qu tm, dd it, Cu(OH)2. B. Qu tm, NaOH, Cu(OH)2 C. HCl, dd it, Cu(OH)2. D. HCl, dd it, NaOH. Cu 27: Hn hp X gm 2 amino axit no bc 1 Y v Z. Y cha 2 nhm axit, mt nhm amino; Z cha mt nhm axit, mt nhm amino. MY/MZ = 1,96. t chy 1mol Y hoc 1 mol Z th s mol CO 2 thu c nh hn 6. Cng thc cu to ca hai amino axit l: a. H2NCH2 CH(COOH) CH2 COOH v H2NCH2 COOH b. H2NCH2 CH(COOH) CH2 COOH v H2N [CH2]2 COOH c. H2N CH(COOH) CH2 COOH v H2NCH2 COOH d. H2N CH(COOH) CH2 COOH v H2N [CH2]2 COOH Cu 28: Trong cc cht sau Cu, HCl, C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxxetic tc dng c vi nhng cht no? A. Tt c cc cht. B. HCl, KOH, CH3OH/ kh HCl. C. C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl D. Cu, HCl, KOH, Na2SO3, CH3OH/ kh HCl. Cu 29: Axit -aminopropionic tc dng c vi tt c cc cht trong dy A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2NCH2COOH B. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, Cu C. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH D. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, NaCl Cu 30: Mt mui X c cng thc C3H10O3N2. ly 14,64g X cho phn ng ht vi 120ml dung dch KOH 1M. C cn dd sau phn ng thu c phn hi v cht rn. Trong phn hi c mt cht hu c Y (bc 1). Trong phn rn ch l mt cht v c. Cng thc phn t ca Y l: a. C2H5NH2 b. C3H7OH c. C3H7NH2 d. CH3NH2 Cu 31: Tn gi ca Sn phm v cht phn ng trong phn ng polime ha no sau y l ng? A. nH2N(CH2)5COOH (-HN(CH2)5CO-)n + n H2O B. nH2N(CH2)5COOH (-HN(CH2)6CO-)n + n H2O Nguyn Trung Kin Lp 12A1 Trang 91

Axit -aminocaproic t nilon-6 Axit -aminoenantoic t enang C. nH2N(CH2)6COOH (-HN(CH2)6CO-)n + n H2O D. B, C ng Axit 7-aminoheptanoic t nilon-7 Cu 32: ng dng no sau y ca aminoaxit l khng ng? A. Aminoaxit thin nhin (hu ht l -aminoaxit) l c s kin to protein trong c th sng. B. Mui inatriglutamat l gia v cho thc n (gi l bt ngt hay m chnh) C. Axitglutanic l thuc b thn kinh, methionin l thuc b gan. D. Cc aminoaxit (nhm NH2 v s 6, 7...) l nguyn liu sn xut t nilon. Cu 33: HCHC X c cng thc C3H9O2N. Cho X phn ng vi dd NaOH, un nh thu c mui Y v kh Z lm xanh giy qu tm m. Cho Y tc dng vi NaOH rn, un nng c CH4, X c cng thc cu to no sau y? a. C2H5-COO-NH4 b. CH3-COO-NH4 c. CH3-COO-H3NCH3 d. b v c ng Cu 34: Mt hchc X c cng thc C3H7O2N. X phn ng vi dung dch brom, X tc dng vi dd NaOH v HCl. Cht hu c X c cng thc cu to: a. H2N CH = CH COOH b. CH2 = CH COONH4 c. NH2 CH2 CH2 COOH d. a v b ng. Cu 35: Ngi ta iu ch anilin bng cch nitro ha 500 g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu? Bit hiu sut phn ng mi giai on l 78%, 80%, 97,5%. A. 346,7 g B. 362,7 g C. 463,4 g D. 358,7 g Cu 36: Mt HCHC X c t l khi lng C:H:O:N = 9: 1,75: 8: 3,5 tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br2. Cng thc phn t ca X v cng thc cu to ca X, Y ln lt l: A. C3H7O2N; H2N-C2H4-COOH; H2N-CH2-COO-CH3 B. C3H7O2N; H2N-C2H4-COOH; CH2=CH-COONH4 C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2 D. C3H5O2N; H2N-C2H2-COOH; CH C-COONH4 Cu 37: Este A c iu ch t amino axit B(ch cha C, H, O, N) v ru metylic. t chy hon ton 8,9 gam este A thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2(o ktc). Bit CTPT ca A trng vi CTGN. CTCT ca A l: A. NH2 - CH2 -COOCH3 B. NH2- CH(CH3)- COOCH3 C.CH3- CH(NH2)- COOCH3 D. NH2- CH(NH2) - COOCH3 Cu 38: Cht A c phn trm khi lng cc nguyn t C,H, O, N ln lt l 32,00%, 6,67%, 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng vi dd NaOH va tc dng vi dd HCl. CTCT ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 39:Cht A c phn trm cc nguyn t C,H, N, O ln lt l 40,45%, 7,86%, 15,73%, cn li l O. Khi lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd HCl, c ngun gc t thin nhin. Cng thc cu to ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 40: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: A. CH3(CH2)4NO2 B. NH2-CH2COO-CH2-CH2-CH3 C. NH-CH2-COO=CH(CH2)3 D. H2N-CH2-CH2-COOC2H5 = 0,43 % . Hng s KB ca dung dch NH3 l: Cu 41: Dung dch NH3 1M c A. 1,85.10-5 B. 1,75.10-5 C. 1,6.10-5 D. -6 1,9.10 Cu 42: Mt hn hp gm 2 amin n chc no k tip nhau trong dy ng ng. Ly 21,4g hn hp cho vo 250ml dung dch FeCl3 (c d) thu c mt kt ta c khi lng bng khi lng hn hp trn. Loi b kt te ru thm t t dung dch AgNO3 v cho n khi phn ng kt thc th phi dng 1lt dd agNO3 1,5M. Cng thc phn t ca 2 amin trn l: a. CH3NH2 v C2H5NH2 b. C2H5NH2 v C3H7NH2 c. C3H7NH2 v C4H9NH2 d. tt c u sai Cu 43: t chy hon ton m g mt amin X bng lng khng kh va thu c 17,6g CO2 v 12,6g hi nc v 69,44 lt N2. Gi thit khng kh ch gm nit v oxi trong oxi chim 80% th tch. Cc th tch o ktc. Amin X c cng thc phn t l: Trang 92 Nguyn Trung Kin Lp 12A1

a. C2H5NH2 b. C3H7NH2 c. CH3NH2 d. C4H9NH2 Cu 44: C 2 amin bc 1: A (ng ng ca anilin) v B ( ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra kh CO2, hi nc v 336cm3 kh nit (ktc). Khi t chy hon ton amin B cho VCO2:VH2O = 2: 3. Cng thc phn t ca 2 amin l: a. CH3C6H4NH2 v CH3CH2CH2NH2 b. C2H5C6H4NH2 v CH3CH2CH2NH2 c. CH3C6H4NH2 v CH3(CH2)4NH2 d. a v b ng - aminoaxit. Cho 0,01 mol X tc dng vi 80ml dung dch HCl 0,125M. Sau Cu 45: Hp cht X l mt em c cn thu c 1,835g mui. Phn t khi ca X bng bao nhiu ? a. 145vC b. 149vC c. 147vC d. 189vC Cu 46: un 100ml dung dch mt aminoaxit 0,2M tc dng va vi 80ml dd NaOH 0,25M. Sau phn ng ngi ta chng kh dung dch thu c 2,5g mui khan. Mt khc, li ly 100g dung dch aminoaxit ni trn c nng 20,6% phn ng va vi 400ml dung dch HCl 0,5M. CTPT ca aminoaxit: a. H2NCH2COOH b. H2NCH2CH2COOHc. H2N(CH2)3COOH d. a v c ng Cu 47: Cho hh M gm 2 amin no n chc bc 1 X v Y. ly 2,28g hh trn tc dng vi 300ml dung dch HCl th thu c 4,47g mui. S mol ca hai amin trong hh bng nhau. Nng mol ca dung dch HCl v tn ca X, Y ln lt l: a. 0,2M; metylamin; etylamin b. 0,06M; metylamin; etylamin c. 0,2M; etylamin; propylamin d. 0,03M; etylamin; propylamin Cu 48: t chy hon ton mt amin thm X thu c 3,08g CO 2, 0,99g H2O v 336ml N2 (ktc). trung ho 0,1mol X cn 600ml dd HCl 0,5M. Cng thc phn t ca X l cng thc no? a. C7H11N b. C7H10N c. C7H11N3 d. C7H10N2 Cu 49: t chy hon ton mg hh 3 amin X, y, Z bng mt lng khng kh va (cha 1/5 th tch l oxi, cn li l nit) thu c 26,4g CO2, 18,9g H2O v 104,16 lt N2 (ktc). Gi tr ca m? a. 12g b. 13,5g c. 16g d. 14,72g Cu 50: Cho 3 hchc X, Y, Z u cha cc nguyn t C, H, N. Thnh phn phn trm khi lng ca N trong phn t X, Y , Z ln lt l: 45,16%; 23,73%; 15,05%. Bit c X, Y, Z khi tc dng vi axit clohiric u cho mui amoni c dng cng thc R NH3Cl. Cng thc X, Y (mch thng), Z ln lt l: a. CH3 NH2, C2H5 NH2, C6H5 NH2 b. C2H5 NH2, CH3 CH2 CH2 NH2, C6H5 NH2 c. CH3 NH2, CH3 CH2 CH2 NH2, C6H5 NH2 d. CH3 NH2, CH3 CH2 CH2 NH2, C6H5 CH2 NH2 1 Amin ng vi cng thc phn t C4H11N c my ng phn? A. 2 A. 3 B.3 B. 4 *C. 5 *C. 5 D. 6 D. 6. 2 Amin thm ng vi cng thc phn t C7H9N c my ng phn? 3 Cho cc cht c cu to nh sau: (1) CH3 CH2 NH2 (3) CH3 C NH2 (2) CH3 NH CH3 (4) NH2 C NH2

O
(5) NH2 CH2 COOH (7) C6H5NH3Cl (9) CH2 = CH NH2. Cht no l amin? A. (1) ; (2) ; (6) ; (7) ; (8) B. (1) ; (3) ; (4) ; (5) ; (6) ; (9) C. (3) ; (4) ; (5)

O
(6) C6H5 NH2 (8) C6H5 NH CH3

*D. (1) ; (2) ; (6) ; (8) ; (9). Nguyn Trung Kin Lp 12A1

Trang 93

4 Anilin tc dng c vi nhng cht no sau y? (1) dd HCl (3) dd NaOH (5) dd CH3 CH2 OH A. (1) , (2) , (3) C. (3) , (4) , (5) 5 Pht biu no sau y sai ? A. Anilin l baz yu hn NH3 v nh hng ht electron ca nhn benzen ln nhm NH2 bng hiu ng lin hp. B. Anilin khng lm thay i mu giy qu tm m. C. Anilin t tan trong H2O v gc C6H5 k nc . *D. Nh c tnh baz , anilin tc dng c vi dd brom. 6 -Khi t chy ng ng ca metylamin, t l th tch K = VCO2 / VH 2O(hoi) bin i nh th no theo s lng nguyn t cacbon trong phn t ? *A. 0,4 < K < 1 C. 0,75 < K < 1 B. 0,25 < K < 1 D. 1 < K < 1,5. (2) dd H2SO4 (4) dd brom (6) dd CH3COOC2H5 B. (4) , (5) , (6) *D. (1) , (2) , (4).

7 - Phng php no thng dng iu ch amin ? A. Cho dn xut halogen tc dng vi NH3 B. Cho ru tc dng vi NH C. Hiro ho hp cht nitril *D. Kh hp cht nitro bng hiro nguyn t . 8- ng dng no sau y khng phi ca amin? A. Cng ngh nhum. C.Cng ngh tng hp hu c. 9- Ru v amin no sau y cng bc? A. (CH3)3COH v (CH3)3CNH2 *B. C6H5NHCH3 v C6H5CHOHCH3 C. (CH3)2CHOH v (CH3)2CHNH2 D. (CH3)2CHOH v (CH3)2CHCH2NH2. 10 - Tm pht biu sai trong cc pht biu sau ? A. Etylamin d tan trong H2O do c to lin kt H vi nc . B. Nhit si ca ru cao hn so vi hirocacbon c phn t khi tng ng do c lin kt H gia cc phn t ru. C. Phenol tan trong H2O v c to lin kt H vi nc . *D. Metylamin l cht lng c mi khai, tng t nh amoniac. Trang 94 Nguyn Trung Kin Lp 12A1 B.Cng nghip dc *D.Cng ngh giy.

11- Trong s cc cht sau: C2H6 ; C2H5Cl ; C2H5NH2 ; CH3COOC2H5 ; CH3COOH ; CH3CHO ; CH3OCH3 cht no to c lin kt H lin phn t? A. C2H6 C. CH3CHO ; C2H5Cl B. CH3COOCH3 *D. CH3COOH ; C2H5NH2.

12- Metylamin d tan trong H2O do nguyn nhn no sau y ? A. Do nguyn t N cn cp electron t do d nhn H+ ca H2O. B. Do metylamin c lin kt H lin phn t. C. Do phn t metylamin phn cc mnh. *D. Do phn t metylamin to c lin kt H vi H2O. 13 - Nguyn nhn no sau y lm anilin tc dng c vi dung dch nc brom ? A. Do nhn thm benzen c h thng lin kt bn vng. B. Do nhn thm benzen ht electron. C. Do nhn thm benzen y electron. *D. Do nhm NH2 y electron lm tng mt electron cc v tr o- v p-. 14 Nguyn nhn gy nn tnh baz ca amin l: A. Do amin tan nhiu trong H2O. B. Do phn t amin b phn cc mnh. C. Do nguyn t N c m in ln nn cp e chung ca nguyn t N v H b ht v pha N. *D. Do nguyn t N cn cp eletron t do nn phn t amin c th nhn proton. 15 Dy sp xp ng theo th t gim dn tnh baz l dy no? (1) C6H5NH2 (3) (C6H5)2NH (5) NaOH (2) C2H5NH2 (4) (C2H5)2NH (6) NH3.

A. (1) > (3) > (5) > (4) > (2) > (6). B. (5) > (6) > (2) > (1) > (2) > (4). C. (5) > (4) > (3) > (5) > (1) > (2). *D. (5) > (4) > (2) > (6) > (1) > (3). 16 Trong bnh kn cha 35 ml hn hp gm H2, mt amin n chc v 40 ml O2. Bt tia la in phn ng chy xy ra hon ton ri a hn hp v iu kin ban u, th tch cc cht to thnh bng 20 ml gm 50% l CO2, 25% l N2 v 25% l O2. CTPT no sau y l ca amin cho? *A. CH5N C. C3H6N B. C2H7N D. C3H5N.

17- Trong thnh phn cht protein ngoi cc nguyn t C, H, O th nht thit phi c nguyn t no di y? Nguyn Trung Kin Lp 12A1 Trang 95

A Pht pho

B Lu hunh

*C Nit

D St

18- git o bng len lng cu cn dng loi x phng c tnh cht no di y? A X phng c tnh baz *C X phng trung tnh 19hc thch hp. 1. un nng dung dch saccaroz vi xc tc l .. c dung dch v .. chng c cng thc phn t l.. 2. un nng tinh bt vi xc tc l., tinh bt b thnh..c cng thc phn t l.. 3. un nng protein trong dung dch long hoc dung dch..long, protein b thnh cc phn t nh l.... 20- Nhiu phn t amino axit kt hp c vi nhau bng cch tch - OH ca nhm COOH v - H ca nhm - NH2 to ra cht polime (gi l phn ng trng ngng) . Polime c cu to mch: - HN CH2 CH2 COO HN CH2 CH2 COO Mnome to ra polime trn l: A H2N CH2 COOH C H2N CH2 CH2 CH2 COOH *B H2N CH2 CH2COOH D Khng xc nh c B X phng c tnh axit D Loi no cng c

in vo ch trng trong nhng cu sau bng nhng cm t, cng thc, t ho

21- S ng phn ca amino axit, phn t cha 3 nguyn t C l: A1 22sau: A- Ngm vo nc xem mnh no ngm nc nhanh hn l lm t g. B Git ri phi, mnh no mau kh hn mnh lm bng t tm. *C - t mt mu, c mi kht l lm bng t tm. D Khng th phn bit c. 23- u xanh cha khong 30% protein, protein ca u xanh cha khong 40% axit glutamic:
HOOC CH2 CH2 CH NH2 COOH

*B 2

C3

D4

C 2 mnh la b ngoi ging nhau, mt mnh lm bng t tm v mt mnh

c ch to t g bch n. Chn cch n gin phn bit chng trong cc cch

Mui natri ca axit ny l m chnh ( bt ngt):

NaOOC CH2 CH2 CH NH2 COOH

( mono natri glutamat) S gam m chnh c th iu ch c t 1 kg u xanh l: Trang 96 Nguyn Trung Kin Lp 12A1

*A 137,96g

B 173,96g

C 137,69g

D 138,95g

24- Thy phn hp cht sau th thu c hp cht no trong s cc cht sau? H2N CH2 NH CH CO NH CH CO NH CH2 COOH CH2 COOHCH2 C6H15 A. NH2 CH2 COOH B. HOOC CH2 CH COOH NH2 C. C6H5 CH2 CH COOH NH2 *D.C A, B, C. 25- Cho qu tm vo mi dung dch hn hp di y, dung dch no lm qu tm ha ? (1) H2N CH2 COOH (2) Cl NH3+ - CH2 COOH (3) NH2 CH2 COONa (4) H2N CH2 CH2 CH COOH NH2 (5) HOOC CH2 CH2 CH COOH NH2 A. (2) (4) C. (1) (5) X1: C6H5 NH2 X3 : NH2 CH2 COOH X4: HOOC CH2 CH2 CH COOH NH2 X5 : H2N CH2 CH2 CH2 CH COOH NH2 Dung dch no lm qu tm ha xanh? A. X1 , X2 , X5 *C. X2 , X5 CTCT ca n l: A. CH3 CH COOH NH2 B. CH2 CH2 COOH NH2 *C. CH2 = CH COONH4 Nguyn Trung Kin Lp 12A1 Trang 97 B. X2 , X3 , X4 D. X1 , X3 , X5. B. (3) (1) *D. (2) (5). X2: CH3 NH2

26- Cho dung dch cha cc cht sau:

27- Hp cht C3H7O2N tc dng c vi NaOH, H2SO4 v lm mt mu dung dch brom,

D. A v B ng. 28- X l mt amino axit no ch cha mt nhm NH2 v mt nhm COOH. Cho 0,89 gam X phn ng va vi HCl to ra 1,25 gam mui. CTCT ca X l: A- NH2-CH2-COOH *C- CH3-CH(NH2)CH2-COOH B-CH3-CH(NH2) -COOH D- C3H7-CH(NH2)-COOH

29- X l mt amino axit. Khi cho 0,01 mol X tc dng vi HCl th dng ht 80 ml dung dch HCl 0,125 M v thu c 1,835 g mui khan. Cn khi cho 0,01 mol X tc dng vi dd NaOH th cn 25 gam dd NaOH 3,2%. Cng thc no sau y l ca X ? A- C7H12-(NH2)-COOH *C- NH2-C3H5-(COOH) B- C3H6-(NH2)-COOH D- (NH2)2-C3H5-COOH X

30- T l VCO2: VH2O (hi) sinh ra khi t chy hon ton mt ng ng X ca glixin l 6:7 ( phn ng sinh ra kh N2). X tc dng vi glixin cho sn phm l ipeptit. l: A- CH3-CH-(NH2)-COOH C- C2H5-CH-(NH2)-COOH *B- NH2-CH2-CH2-COOH D- Kt qu khc

31- Gi tn hp cht c CTCT nh sau theo danh php thng thng. CH3CH2CH2CH2 - N(CH3) - CH2CH3 A.Etylmetyl amino butan. B.Metyletyl amino butan. *C.Etyl metylbutylamin. D.metyletylbutylamin.

32- Gi tn hp cht c CTCT nh sau theo danh php thng thng: NH2

CH3 A.1-amino-3 -metyl benzen. C.m-toludin. B.m-metylanilin. * D.C B,C. 33- Gi tn hp cht c CTCT nh sau theo danh php IUPAC: CH3 - CH - CH2 - CH - CH - CH3 OH NH2 CHO *A. 3-amino-5-hidroxi-2-metyl hexanal. C.5- oxo -4-aminohexanol-2 B. 5-hidroxi-2-metyl-3-aminohexanal. D.4-amino - 5-oxohexanol. Lu : theo quy tc ca IUPAC mc u tin ca cc nhm chc gim theo dy sau: -COOH >-SO3H>-COOR>-COCl>-CONH2>-CHO>-CO->-OH>-NH2>-OR>-R. 34- Cht no sau y l amin bc 2. A.H2N -CH2-CH2-NH2. B. CH3 - CH - CH3. NH2 Trang 98 Nguyn Trung Kin Lp 12A1 *C. CH3 - NH- C2H5. D. C B,C.

35- Pht biu no sau y SAI? A.Cch tnh bc ca amin khc vi ca ru. B.Nguyn nhn gy ra tnh baz ca cc amin l do trn nguyn t N cn mt cp e cha chia c th nhng cho proton H+. *C.Anilin lm qu tm m ha xanh. D.Gc phennyl (-C6H5) v nhm chc amino (-NH2) trong phn t anilin c nh hng quali vi nhau. 36- Amin no sau y c tnh baz ln nht: A.CH3CH=CH-NH2. B.CH3C C-NH2. 37- Cho cc cht sau: CH3CH2NHCH3(1) ,CH3CH2CH2NH2(2), (CH3)3N (3). Tnh baz tng dn theo dy: A.(1)<(2)<(3). B.(3)<(2)<(1). *B.(2)<(3)<(1). D.(3)<(1)<(2). *C.CH3CH2CH2NH2. D.CH3CH2NH2.

Lu :-Nguyn nhn gy ra tnh baz ca cc amin l do trn nguyn t N cn mt cp e t do c th nhng cho proton H+.

Mi yu t lm tng linh ng ca cp e t do s lm cho tnh baz

tng v ngc li.

Nu R l gc y e s lm tng mt e trn N tnh baz tng. Nu R l gc ht e s lm gim mt e trn N tnh baz tng. Amin bc 3 kh kt hp vi proton H+do s n ng khng gian ca nhiu nhm
R cn tr s tn cng ca H+ vonguyn t N. 38- Cho cc cht sau: p- CH3C6H5NH2(1), m-CH3C6H5NH2 (2),C6H5NHCH3 (3),C6H5NH2 (4). Tnh baz tng dn theo dy: A.(1)<(2)<(4)<(3). B.(4)<(3)<(2)<(1). 39- Cho cc cht sau: p-NO2C6H4NH2 (1), p-ClC6H5NH2 (2),p-CH3C6H5NH2 (3). Tnh baz tng dn theo dy: *A.(1)<(2)<(3). (3)<(2)<(1). 40- C bao nhiu ng phn amin ng vi CTPT C4H11N? Nguyn Trung Kin Lp 12A1 Trang 99 B.(2)<(1)<(3). C.(1)<(3)<(2). D. *C.(4)<(2)<(1)<(3). D.(4)<(3)<(1)<(2).

A.5.

B.6.

*C.7.

D.8.

41- Cho cc cht sau: Ru etylic (1) ,etylamim (2), metylamim (3),axit axetic (4). Sp sp theo chiu c nhit si tng dn: A.(2)<(3)<(4)<(1). *B.(3)<(2)<(1)<(4). C.(2)<(3)<(4)<(1). D.(1)<(3)<(2)<(4).

42- Chn cu ng khi ni v s i mu ca cc cht khi gp qu tm: A.Phenol trong nc lm qu tm ha . B.Anilin trong nc lm qu tm ha xanh. *C.Etylamin trong nc lm cho qu tm chuyn thnh mu xanh. D.dung dch Natriphenolat khng lm qu tm i mu. 43- Nguyn nhn no sau y gy ra tnh baz ca cc amin: A.Do anilin c th tc dng c vi dung dch axit. B.Do phn t anilin b phn cc. C.Do cp electron gia N v H b ht mnh v pha N. *D.Do nguyn t N cn cp electron t do c kh nng nhng cho proton H+. 44- Anilin c th phn ng vi dung dch cht no sau y: 1)HNO2. *A.(1),(4). 45- Cho phn ng: C6H5NH3Cl V tri ca phn ng l phng n no sau y? A.C6H5NH2 + Cl2. B. (C6H5 )2NH + HCl. 46- C 4 ng nghim cha cc hn hp sau: 1)Anilin + nc. 3)Anilin + C2H5OH. 2)Anilin + dung dch HCl d. 4)Anilin + benzen. *C.C6H5NH2 + HCl . D.C A,B,C. 2)FeCl2. B.(1),(3). 3)CH3COOH C.(1),(3),(4). 4)Br2. D.C 4 cht.

Cho bit trong ng nghim no c s tch lp: *A.Ch c (1). ng. 47- Cho s : (X) (Y) (Z)

B.(3),(4 ).

C.(1),(3),(4).

D.C 4

(trng).

Cc cht X,Y,Z ph hp s trn l: A.X(C6H6),Y(C6H5NO2),Z(C6H5NH2). Trang 100 Nguyn Trung Kin Lp 12A1

B.X(C6H5CH(CH3)2),Y(C6H5OH),Z(C6H5NH2). C.X(C6H5NO2),Y(C6H5NH2),Z( C6H5OH). *D.C A v C. 48- Hy chn thuc th thch hp phn bit 3 cht kh sau: imetyl amin, metylamin, trimetyl amin. A.Dung dch HCl. C. 49- Hy chn thuc th thch hp phn bit 3 cht lng sau: Phenol, anilin, benzen A.Dung dch HNO2. B.Dung dch FeCl3. C.Dung dch H2SO4. *D.Nc Br2. B.Dung dch FeCl3. *C.Dung dch HNO2 D.C B v

50- Phn ng no sau y sai: C6H5NH2 + H2O ( CH3 )2NH + HNO2 C6H5NO2 NH2 + 3 HNOH2SO4 3 + 3 Fe + 7 HCl C6H5NH3OH 2CH3OH + N2 (1) (2)

C6H5NH3Cl + 3 FeCl2 + 2 H2O. (3) NH2 O2N NO2 + 3H2O (4)

NO2 *A. (1)(2)(4). B.(2)(3)(4). C.(2)(4) D.(1)(3). 51- ti to li anilin t dung dch phenyl amoniclorua phi dng dung dch cht no sau y: A.Dung dch HCl. C.Dung dch Br2. *B.Dung dch NaOH D.C A,B,C.

52- t chy mt amin no n chc mch thng ta thu c CO2 v H2O c t l mol
n

CO2 ; nH2O = 8:11.Xc nh CTCT ca X. A.(C2H5)2NH. B.CH3 (CH2)2NH2. *C.CH3NHCH2CH2CH3 D.C 3.

53- Cho 9 g hn hp X gm 3 amin:n-propyl amin,etylmetylamin,trimetyl amin.Tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l: A. 100ml. *B.150 ml. C.200 ml. D.Kt qu khc.

54- t chy hon ton a mol hn hp X gm 2 amin no n chc thu c 5,6 (l) CO2(ktc) v 7,2 g H2O. Gi tr ca a l: A.0 ,05 mol. *B.0,1 mol. C.0,15 mol. D.0,2 mol.

55- t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng , thu c 22 g CO2 v 14,4 g H2O.CTPT ca hai amin l: Nguyn Trung Kin Lp 12A1 Trang 101

A.CH3NH2 v C2H7N. *B.C3H9N v C4H11N. 56- Gi tn hp cht c CTCT nh sau:

C.C2H7N v C3H9N. D.C4H11N v C5H13 N.

CH3- CH - CH2 - CH - COOH C2H5 NH2 C. Axit 3-metyl - 1-aminocaproic. *D.Axit1- amino-3-metylcaproic.

A. 3-metyl-1-cacboxipentyl amin. B.1-cacboxi- 3-metyl-pentylamin. 57- Gi tn hp cht c CTCT nh sau: CH3 - CH - CH - COOH OH NH2

A. Axit 3-hiddroxi-2-amino butanoic C. Axit - 2-hidroxi -1 -amino butanoic. *B.Axit 2-amino - 3 -hidroxi butanoic. butanoic. Lu : khi trong phn t c cha ng thi mt s nhm chc thuc cc loi khc nhau(hp cht tp chc )th nhm c hn cp cao nht c chn lm nhm chc chc chnh v c go tn nh tip v ng ,cc nhm cn li c gi tn di dng tip u ng theo th t bng ch ci. 58- Dung dch ca cht no sau y khng lm i mu qu tm : *A.Glixin (CH2NH2-COOH). B.Lizin(H2NCH2-(CH2)3-CH(NH2)-COOH). C.Axit glutamic (HOOCCH2CHNH2COOH). D.Natriphenolat.(C6H5ONa). D.Axit 1-amino - 2 -hidroxi

59- Cht no sau y ng thi tc dng c vi dung dch HCl v dung dch NaOH. A.C2H3COOC2H5. B .CH3COONH4. C.CH3CHNH2COOH. *D.C A,B,C.

60- Cc cht X,Y,Z c cng CTPT C2H5O2N .X tc dng c c vi HCl v Na2O.Y tc dng c vi H mi sinh to ra Y1.Y1 tc dng vi H2SO4 to ra mui Y2 . Y2 tc dng vi NaOH ti to li Y.Z tc dng vi NaOH to ra mt mui v kh NH3.Cho bit CTCT ng ca X,Y,Z ? A.X (HCOOCH2NH2),Y (CH3COONH4),Z (CH2NH2COOH). B.X(CH3COONH4),Y (HCOOCH2NH2), Z(CH2NH2COOH). C.X(CH3COONH4),Y(CH2NH2COOH),Z(HCOOCH2NH2). *D.X(CH2NH2COOH),Y(CH3CH2NO2), Z(CH3COONH4). 61- Mt cht hu c X c CTPT C3H9O2N.Cho tc dng vi dung dch NaOH un nh ,thu c mui Y v kh lm xanh giy qu tm t.Nung Y vi vi ti xt thu c kh metan. Cho bit CTCT ph hp ca X? Trang 102 Nguyn Trung Kin Lp 12A1

A.CH3COOCH2NH2. B.C2H5COONH4 .

*C.CH3COONH3CH3 D.C A.B.C.

62- Tng ng vi CTPT C2H5O2N c bao nhiu ng phn c cha 3 nhm chc: A. 1. B.2. *C.3. D.4.

63- Mt hp cht hu c X c CTPT C3H7O2N .X phn ng c vi dung dch Br2,X tc dng c vi NaOH v HCl .CTCT ng ca X l: A.CH(NH2)=CHCOOH. *B.CH2=CHCOONH4. C. CH2= C(NH2)COOH. D.C A,B,C.

64- Mt hp cht hu c X c CTPT C2H7O2N .X d dng phn ng vi dung dch NaOH v dung dch HCl .CTCT ph hp ca X l: A.CH2NH2COOH. B.CH3COONH4. 65- Cho s : C.HCOONH3CH3. *D.C B v C.

A) Caosu buna
Vi ti -Xt

(C)
HNO2

(D)
Xt:Al2O3,450
0

(E)
Nanc

C4H12O2N2 (X) (B)

HNO2

(F)
CuO,t0

(G)
Xt:Ca(OH)2

(H)

H2,xt:Ni,t0

Etylenglicol

CTCT ng ca X l: A.CH2NH2CH2COONH3CH3. B.CH2(NH2)COONH3C2H5. C.CH3CH(NH2)COONH3CH3. *D.C A,C.

66- Tng ng vi CTPT C3H9O2N c bao nhiu ng phn cu to va tc dng c vi dung dch NaOH va tc dng vi dung dch HCl. *A. 3. 67- Cho s : B.9. C.12. D.15.

(A)

HNO2

(C) H2SO4,18
0
0

(D)

t0,p,xt

P.E.

C4H11O2N Nguyn Trung Kin Lp 12A1

HNO2 C2H2 t0,p,xt

Trang 103

(X) axetat).

(B)

(E)

(F)

P.V.A(polivinyl

CTCT ph hp ca X l: A.C2H5COOCH2NH2. B.C2H5COONH3CH3. C.CH3COOCH2CH2NH2. *D.CH3COONH3CH2CH3.

68- Cht no sau y khng kh nng tham gia phn ng trng ngng: A.CH3CH(NH2)COOH. B. CH3CH(OH)COOH. *C.HCOOCH2CH2CH2NH2. D. HOCH2-CH2OH.

69- Cho 12,55 g mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M .C cn dung dch thu c sau phn ng thu c m g cht rn. Gi tr ca m l : A.15,65g. B.26,05g. *C.34,6g. D.Kt qu khc.

70- Cho 22,15 g mui gm CH2NH2COONa v CH2NH2CH2COONa tc dng va vi 250 ml dung dch H2SO4 1M.Sau phn ng c cn dung dch th lng cht rn thu c l: *A.46,65g. B.45,66g. C.65,46g. D.Kt qu khc.

71- Cho 13,35 g hn hp X gm (CH2NH2CH2COOH v CH3CHNH2COOH) tc dng vi V ml dung dch NaOH 1 M thu c dung dch Y.Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M.Gi tr ca V l: *A.100ml. B.150ml. C.200ml. D.250ml.

72- Cho 20,15 g hn hp X gm (CH2NH2COOH v CH3CHNH2COOH) tc dng vi 200ml dung dch HCl 1M thu c dung dch Y.Dung dch Y tc dng va vi 450 ml dung dch NaOH.Phn trm khi lng ca mi cht trong X l: *A.55,83% v 44,17%. B.58,53% v 41,47%. C.53,58% v 46,42%. D.52,59% v 47,41%.

73- Cho 4,41g mt aminoaxit X tc dng vi dung dch NaOH d cho ra 5,73 g mui .Mt khc cng lng X nh trn nu cho tc dng vi dung dch HCl d thu c 5,505 g mui clorua. Xc nh CTCT ca X. A.HOOC-CH2CH2CH(NH2)COOH. B.CH3CH(NH2)COOH. C.HOOCCH2CH(NH2)CH2COOH. *D.C A v B.

74- Mt amino axit (X) c cng thc tng qut NH2RCOOH .t chy hon ton a mol X thu c 6,72 9(l) CO2 (ktc) v 6,75 g H2O.CTCT ca X l: *A.CH2NH2COOH. B.CH2NH2CH2COOH. C.CH3CH(NH2)COOH. D.C B v C.

Trang 104

Nguyn Trung Kin Lp 12A1

75- Xc nh th tch O2 (ktc) cn t chy ht 22,455g hn hp X gm (CH3CH(NH2) COOH v CH3COOCNH3CH3) .Bit sn phm chy c hp th ht vo bnh ng dung dch NaOH th khi lng bnh tng 85,655g. *A.44,24 (l). B.42,8275(l). C.128,4825(l). D.Kt qu khc. 76- Cht

no sau y c tnh baz mnh nht?

A) NH3

B) C6H5NH2

C) CH3CH2CH2NH2 *D) CH3CHNH2 CH3 77- Mt amino axit no X ch cha mt nhm NH2 v mt nhm COOH. Cho 0,89g X phn ng va vi HCl to ra 1,255g mui. Cng thc cu to ca X l: A) H2NCH2COOH *B) CH3CH- CH2COOH NH2 C) H2NCH2CH2COOH
A) CH3 CH2 CH2 NH2 *C) C2H5NH2

D) B, C, u ng.
B) CH3 NH CH3 D) C2H5NH2 v CH3 NH CH3

78- ( A) ( CxHyNt) c % N = 31,11% A + HCl RNH3Cl. CTCT ca A l:

79- L do no sau y gii thch tnh baz ca monoetylamin mnh hn amoniac: A) Nguyn t N cn i electron cha to lin kt *B) nh hng y electron ca nhm C2H5 C) Nguyn t N c m in ln D) Nguyn t nit trng thi lai ho 80- Nhng cht no sau y lng tnh: A) NaHCO3 C) CH3COONH4 B) H2N CH2 COOH *D- C A, B, C

81- Nhit si ca C4H10 (1), C2H5NH2 (2), C2H5OH (3) tng dn theo th t: *A) (1)< (2) < (3) C) (2) < ( 3) < (1) B) (1) < (3) < (2) D) ( 2) < ( 1) < (3)

82- Ngi ta iu ch anilin bng cch nitro ho 500g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu bit rng hiu sut mi giai on u t 78%. *A) 362,7g B) 463,4g C) 358,7g D) 346,7g 83- Hy ch r cht no l amin: Nguyn Trung Kin Lp 12A1 Trang 105

(1) CH3 NH2 (5) (CH3)2NC6H5 (7) CH3CO NH2 A) (1), (2), (5) *C) (1), (2), (4), (5), (8) A) C6H5OH + H2O

(2) CH3 NH CH2CH3 (6) NH2 CO NH2 (8) CH3 C6H4 NH2 B) (1), (5), (8) D) Tt c u l amin

(3) CH3 NH CO CH3 (4) NH2(CH2)2 NH2

84- Phn ng no sau y l phn ng axit baz: B) CH3NH2+ H2O v C6H5OH + H2O C) C2H5O + H2O *D) CH3NH2 + H2O, C6H5OH + H2O v C2H5O + H2O 85- 9,3 g mt ankyl amin cho tc dng vi dd FeCl3 d thu c 10,7g kt ta. CTCT l: A) C2H5NH2 C) C4H9NH2 ho : (1) H2N CH2 COOH (3) H2N CH2 COONa *A) (2), (5) C) (1), (5) B) (1), (4) D (2) (4) H2N(CH2)2CH(NH2) COOH (2) Cl-NH3+ - CH2COOH (5) HOOC(CH2)2CH(NH2) COOH B) C3H7NH2 *D) CH3NH2

86- Cho qu tm vo dung dch mi hp cht di y, dung dch no s lm qu tm

87- (A) l mt hp cht hu c c CTPT C5H11O2N. un (A) vi dung dch NaOH thu c mt hp cht c CTPT C2H4O2NNa v cht hu c (B). Cho hi qua CuO/t 0 thu c cht hu c (D) c kh nng cho phn ng trng gng. CTCT ca A l: A) CH2 = CH COONH3 C2H5 B) CH3(CH2)4NO2 *C) H2N CH2 CH2 COOC2H5 D) NH2 CH2COO CH2 CH2 CH3 88- Khi t chy ng ng ca metylamin, t l th tch k = VCO2 : VH2O bin i nh th no theo s lng nguyn t cacbon trong phn t? A) 0,25 < k < 1 C) Kt qu khc A) FeCl3 *C) Hai mui FeCl3 v NaCl 90- Pht biu no sau y SAI ? A) Anilin t tan trong nc v gc C6H5 k nc. Trang 106 Nguyn Trung Kin Lp 12A1 B) 0,75 < k < 1 *D) 0,4 < k < 1 B) NaCl D) AgNO3

89- Dung dch etylamin c tc dng vi dung dch ca mui no di y:

B) Anilin l baz yu hn NH3 v nh hng ht electron ca nhn ln nhm NH2 bng hiu ng lin hp. *C) Nh c tnh baz anilin tc dng c vi dung dch nc Br2 D) Anilin tc dng c vi dung dch HBr v trn N c i e t do 91- Khi t nng mt ng ng ca metylamin ngi ta thy t l th tch cc kh v hi VCO2 : VH2O sinh ra bng 2:3 . Cng thc phn t ca anilin l: A) C2H7N C) C4H11N *B) C3H9N D) Kt qu khc (3) (C6H5)2NH, (4) (C2H5)2NH

92- Sp xp cc hp cht sau y theo th t gim dn tnh baz: (1) C6H5NH2, (2) C2H5NH2, (5) NaOH (6) NH3

A) (5) > (4) > (2) > (1) > ( 3) > (6)B) (1) > (3) > (5) > (4) > (2) > (6) C) (4) > (5) > ( 2) > (6) > ( 1) > (3)*D) (5) > (4) > (2) > (6) > (1) > (3) 93- T l th tch CO2: H2O ( hi) sinh ra khi t chy hon ton mt ng ng (X) ca glixerol l 6: 7 ( phn ng chy sinh ra kh N 2). (X) tc dng vi glixerol cho sn phm l mt ipeptit. (X) l: A) NH2 CH2 CH2 COOH C) CH3 CH( NH2) COOH B) C2H5 CH(NH2) COOH *D) Kt qu khc

94- un hn hp brometan v dung dch amoniac trong etanol 100 0C (phng php Hoffman) ngi ta thu c phm vt g? A) Cc loi mui clorua C) ietylamin 95- Pht biu no sau y ng? (1) Protein l loi hp cht cao phn t thin nhin c cu trc phc tp (2) Protein ch c trong c th ngi v ng vt (3) C th ngi v ng vt khng th tng hp c protein t nhng cht v c, m ch tng hp t cc aminoaxit (4) Protein bn i nhit, i vi axit v baz kim A) (2), (3) C) (1), (3) *B) (1), (3) D) (3), (4) B) Tt c cc sn phm trn *D) Trietyllamin

AMIN 1: Cng thc ca amin cha 15,05% khi lng nit l cng thc no sau? A. C2H5NH2 B. (CH3)2NH C. C6H5NH2 D. (CH3)3N 2: Cng thc phn t C3H9N ng vi bao nhiu ng phn?A. 5 B. 4 C. 3 D. 2 3: Cho amin c cu to: CH3-CH(CH3)-NH2 . Chn tn gi khng ng? A. Prop-1-ylamin B. Propan-2-amin C. isoproylamin D. Prop-2-ylamin 4: Tn gi ng C6H5NH2 ng? A. Benzyl amoni B. Phenyl amoni C. Hexylamin D. Anilin 5: Hp cht hu c X mch h cha cc nguyn t C, H, N trong c 23,72% khi lng N. X tc dng vi HCl theo t l mol 1:1. Chn cu pht biu sai? A. X l hp cht amin. B. Cu to ca X l amin no, n chc C. Nu cng thc X l CxHyNz th z = 1 D. Nu cng thc X l CxHyNz th : 12x - y = 45 6: Pht biu no sau y khng ng?

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A. Amin c cu to bng cch thay th H ca amoniac bng 1 hay nhiu gc H-C. B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amin. C. Ty thuc vo gc H-C, c th phn bit thnh amin thnh amin no, cha no v thm. D. Amin c t 2 nguyn t cacbon trong phn t bt u xut hin ng phn. 7: Amin no di y l amin bc 2?A. CH3-CH2NH2 B. CH3-CHNH2-CH3 C. CH3-NH-CH3 D. CH3-NCH3-CH2-CH3 8: Cng thc no di y l cng thc chung ca dy ng ng amin thm (cha 1 vng bezen) n chc bc nht? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 9: Tn gi cc amin no sau y l khng ng? A. CH3-NH-CH3 imetylamin B. CH3-CH2-CH2NH2 n-propylamin C. CH3CH(CH3)-NH2 isopropylamin D. C6H5NH2 alanin 10: Amin no di y c 4 ng phn cu to?A. C2H7N B. C3H9N C. C4H11N D. C5H13N 11: Pht biu no sau y v tnh cht vt l ca amin l khng ng? A. Metyl-, etyl-, imetyl-, trimetylamin l nhng cht kh, d tan trong nc.B. Cc amin kh c mi tng t amoniac, c. C. Anilin l cht lng, kh tan trong nc, mu en.D. tan ca amin gim dn khi s nguyn t cacbon trong phn t tng. 12: Cc gii thch v quan h cu trc, tnh cht no sau y khng hp l? A. Do c cp electron t do trn nguyn t N m amin c tnh baz. B. Do nhm NH2- y e nn anilin d tham gia vo phn ng th vo nhn thm hn v u tin v tr o- v p-. C. Tnh baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. D. Vi amin R-NH2, gc R ht electron lm tng mnh ca tnh baz v ngc li. 13: Nhn xt no di y khng ng? A. Phenol l axit cn anilin l baz. B. Dd phenol lm qu tm ha cn dd anilin lm qu tm ha xanh. C. Phenol v anilin u d tham gia phn ng th v u to kt ta trng vi dd brom. D. Phenol v anilin u kh tham gia phn ng cng v u to hp cht vng no khi cng vi hiro. 14: S d anilin c tnh baz yu hn NH3 l do yu t no? A. Nhm NH2- cn 1 cp electron t do cha tham gia lin kt. B. Nhm NH2- c tc dng y electron v pha vng benzen lm gim mt electron ca N. C. Gc phenyl c nh hng lm gim mt electron ca nguyn t N. D. Phn t khi ca anilin ln hn so vi NH3 15: Hy ch ra iu sai trong cc iu sau? A. Cc amin u c tnh baz B. Tnh baz ca anilin yu hn NH3 C. Amin tc dng vi axit cho ra mui D. Amin l hp cht hu c c tnh cht lng tnh 16: Dd etylamin tc dng vi dd nc ca cht no sau y?A. NaOH B. NH3 C. NaCl D. FeCl3 v H2SO4 17: Hp cht no di y c tnh baz yu nht?A. Anilin B. Metylamin C. Amoniac D. imetylamin 18: Cht no di y c tnh baz mnh nht?A. NH3 B. CH3CONH2 C. CH3CH2CH2OH D. CH3CH2NH2 19: Sp xp cc cht sau y theo tnh baz gim dn? (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. 1>3>5>4>2>6 B. 6>4>3>5>1>2 C. 5>4>2>1>3>6 D. 5>4>2>6>1>3 20: Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl C. Fe3+ + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3+ D. CH3NH2 + HNO2 CH3OH + N2 + H2O 21: Dd no di y khng lm qu tm i mu? A. C6H5NH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3 22: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. FeCl3 + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3Cl C. C6H5NH2 + 2Br2 3,5-Br2-C6H3NH2 + 2HBr D. C6H5NO2 + 3Fe +7HCl C6H5NH3Cl + 3FeCl2 + 2H2O 23: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. CH3NH2 + O2 CO2 + N2 + H2O C. C6H5NH2 + 3Br2 2,4,6-Br3C6H2NH3Br + 2HBr D. C6H5NO2 + 3Fe +6HCl C6H5NH2 + 3FeCl2 + 2H2O 24: Dd etylamin khng tc dng vi cht no sau y?A. axit HCl B. dd CuCl2 C. dd HNO3 D. Cu(OH)2 25: Dd etylamin tc dng c vi cht no sau y?A. Giy pH B. dd AgNO3 C. ddNaCl D. Cu(OH)2 26: Pht biu no sai? A. Anilin l baz yu hn NH3 v nh hng ht electron ca nhn ln nhm NH2- bng hiu ng lin hp. B. Anilin khng lm i mu giy qu tm. C. Anilin t tan trong nc v gc C6H5- k nc. D. Nh tnh baz, anilin tc dng vi dd Brom. 27: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B. Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. 28: Cc hin tng no sau y m t khng chnh xc? A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh. 29: Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen? A. Dd Brm B. dd HCl v dd NaOH C. dd HCl v dd brm D. dd NaOH v dd brm 30: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng? A. Ha tan dd HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan dd Brm d, lc ly kt ta, dehalogen ha thu c anilin. C. Ha tan NaOH d v chit ly phn tan v thi CO2 vo sau n d thu c anilin tinh khit. D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen.

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31: Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng va vi 0,075 mol Br2 to kt ta. Lng cc cht NH3, C6H5NH2 v C6H5OH ln lt bng? A. 0,01 mol; 0,005 mol v 0,02 mol B. 0,005 mol; 0,005 mol v 0,02 mol C. 0,005 mol; 0,02 mol v 0,005 mol D. 0,01 mol; 0,005 mol v 0,005 mol 32: Cho mt lng anilin d phn ng hon ton vi dd cha 0,05 mol H2SO4 long. Khi lng mui thu c? A. 7,1 g B. 14,2 g C. 19,1 g D. 28,4 g 33: phn bit phenol, anilin, benzen, stiren ngi ta s dng ln lt cc thuc th no sau? A. Qu tm, brm B. dd NaOH v brom C. brm v qu tm D. dd HCl v qu tm 34: t chy hon ton mt amin n chc, bc mt thu c CO2 v nc theo t l mol 6:7. Amin c tn gi l g? A. Propylamin B. Phenylamin C. isopropylamin D. Propenylamin 35: t chy hon ton mt ng ng metylamin ngi ta thy t l th tch cc kh v hi ca cc sn phm sinh ra l V 2 : V 2O = CO H 2:3. CTPT ca amin?A. C3H9N B. CH5N C. C2H7N D. C4H11N 36: Cho 20 gam hn hp 3 amin n chc, ng ng k tip nhau tc dng va vi dd HCl 1M, c cn dd thu c 31,68 gam hn hp mui. Th tch ca dd HCl 1M dng?A. 100ml B. 50ml C. 200ml D. 320ml 37: Cho 20 gam hn hp 3 amin no, mch h, n chc, ng ng k tip nhau tc dng va vi dd HCl 1M, c cn dd thu c 31,68 gam hn hp mui. Bit khi lng phn t cc amin u nh hn 80. CTPT ca cc amin? A. CH3NH2, C2H5NH2 v C3H7NH2 B. C2H3NH2, C3H5NH2 v C4H7NH2 C. C2H5NH2, C3H7NH2 v C4H9NH2 D. C3H7NH2, C4H9NH2 v C5H11NH2 38: Cho 10 gam hn hp 3 amin no, mch h, n chc, ng ng k tip nhau tc dng va vi dd HCl 1M, c cn dd thu c 15,84 gam hn hp mui. Nu 3 amin trn c t l mol 1:10:5 theo th t phn t khi tng dn th cng thc phn t ca cc amin? A. CH5N, C2H7N v C3H7NH2 B. C2H7N, C3H9N v C4H11N C. C3H9N, C4H11N v C5H11N D. C3H7N, C4H9N v C5H11N 39: t chy hon ton 6,2 gam mt amin no, mch h, n chc phi dng ht 10,08 lt kh O2 ktc. CTPT ca amin? A. C2H5NH2 B. CH3NH2 C. C4H9NH2 D. C3H7NH2 40: Mt HCHC to bi C, H, N, l cht lng, khng mu, rt c, t tan trong nc, d tc dng vi dd HCl v c th tc dng vi dd brm to kt ta trng. CTPT ca HCHC c th l?A. C2H7N B. C6H13N C. C6H7N D. C4H12N2 41: t chy hon ton 100ml hn hp gm imetylamin v 2 H-C l ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc kh o cng iu kin). CTPT ca 2 hirocacbon?A. C2H4 v C3H6 B. C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 42: Trung ha 3,1 gam mt amin n chc X cn va 100ml dd HCl 1M. CTPT X l? A. C2H5N B. CH5N C. C3H9N D. C3H7N 43: t chy hon ton hn hp gm 2 amin no n chc l ng ng k tip nhau trong dy ng ng, thu c CO2 v hi nc t l th tch CO2 : H2O = 8 : 17. CTPT ca 2 amin? A. C2H5NH2 v C3H7NH2 B. C3H7NH2 v C4H9NH2 C. CH3NH2 v C2H5NH2 D. C4H9NH2 v C5H11NH2 44: t chy hon ton mt amin n chc, cha no, c mt lin kt i mch cacbon, thu c CO2 v hi nc t l th tch CO2 : H2O = 8 : 9. CTPT ca amin? A. C3H6N B. C4H9N C. C4H8N D. C3H7N 45: Cho 9,3 gam mt ankylamin tc dng vi dd FeCl3 d thu c 10,7 gam kt ta. Ankylamin CTPT? A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2 46: Cho 1,52 gam hn hp 2 amin no n chc (trn vi s mol bng nhau) tc dng va vi 200ml dd HCl, thu c 2,98 gam mui. Kt lun no sau y khng chnh xc? A. Nng mol/l dd HCl 0,2M B. S mol ca mi cht 0,02 mol C. Cng thc ca 2 amin CH5N v C2H7N D. Tn gi ca 2 amin metylamin v etylamin 47: Phn tch nh lng 0,15 gam hp cht hu c X thy t l khi lng cc nguyn t C:H:O:N = 4,8:1:6,4:2,8. Nu phn tch nh lng m gam cht X th t l khi lng cc nguyn t C:H:O: N l bao nhiu? A. 4 : 1 : 6 : 2 B. 2,4 : 0,5 : 3,2 : 1,4 C. 1,2 : 1 : 1,6 : 2,8 D. 1,2 : 1,5 : 1,6 : 0,7 48: Ngi ta iu ch anilin bng cch nitro ha 500 g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu? Bit hiu sut phn ng mi giai on l 78%, 80%, 97,5%. A. 346,7 g B. 362,7 g C. 463,4 g D. 358,7 g

AMINOAXIT - PROTEIN 1: Pht biu no di y v aminoaxit l khng ng? A. Aminoaxit l HCHC tp phc, phn t chc ng thi nhm amino v nhm cacboxyl. B. Hp cht H2NCOOH l aminoaxit n gin nht. C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-) D. Thng thng dng ion lng cc l dng tn ti chnh ca aminoaxit trong dung dch. 2: Tn gi ca aminoaxit no di y l ng? A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)-COOH (valin) D. HOOC-(CH2)2-CH(NH2)-COOH (axit glutaric) 3: C3H7O2N c my ng phn aminoaxit (Vi nhm amin bc nht)?A.5 B. 2 C. 3 D. 4

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4: Khng nh no sau y khng ng v tnh cht vt l ca aminoaxit? A. Tt c u cht rn. B. Tt c u l tinh th, mu trng. C. Tt c u tan tt trong nc. D. Tt c u c nhit nng chy cao. 5: Aminoaxetic khng th phn ng vi: A. Ancol B. Cu(OH)2 C. axit nitric D. Ba(OH)2 6: 0,01 mol aminoaxit A phn ng va vi 0,02 mol HCl hoc 0,01 mol NaOH. Cng thc ca A c dng: A. H2NRCOOH B. (H2N)2RCOOH C. H2NR(COOH)2 D. (H2N)2R(COOH)2 7: Cho 0,1 mol A ( - aminoaxit dng H2NRCOOH) phn ng ht vi HCl to 11,15g mui. A l? A. Glixin B. Alanin C. Phenylalanin D. Valin 8: Cho - aminoaxit mch thng A c cng thc dng H2NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 9,55 g mui. A l cht no sau y? A. Axit 2-aminopropanionic B. Axit 2-aminobutanioic C. Axit 2-aminopentaioic D. Axit 2- aminohexanioic 9: Cho cc dy chuyn ha : +HCl + +NaOH +HCl NaOH Glixin A X; Glixin B Y X v Y ln lt l cht no? A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa 10: Cho glixin (X) phn ng vi cc cht i y, trng hp no PTHH c vit khng chnh xc? A. X + HCl ClH3NCH2COOH B. X + NaOH H2NCH2COONa + H2O HCl(kh ) C. X + CH3OH + HCl ClH3NCH2COOCH3 + H2O D. X + CH3OH NH2CH2COOCH3 + H2O 11: Mt HCHC X c t l khi lng C:H:O:N = 9: 1,75: 8: 3,5 tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br2. Cng thc phn t ca X v cng thc cu to ca X, Y ln lt l: A. C3H7O2N; H2N-C2H4-COOH; H2N-CH2-COO-CH3 B. C3H7O2N; H2N-C2H4-COOH; CH2=CH-COONH4 C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2 D. C3H5O2N; H2N-C2H2-COOH; CH C-COONH4 12: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: A. CH3(CH2)4NO2 B. NH2-CH2COO-CH2-CH2-CH3 C. NH-CH2-COO=CH(CH2)3 D. H2N-CH2-CH2-COOC2H5 13: X l - aminoaxit no ch cha mt nhm -NH2 v mt nhm -COOH. Cho 10,3g X tc dng vi dd HCl d thu c 13,95g mui clohirat ca X. CTCT thu gn ca X l: A. CH3CH(NH2)COOH B. H2NCH2COOH C. H2NCH2CH2COOH D. CH3CH2CH(NH2)COOH 14: Cho cc cht sau: (X1) C6H5NH2; (X2)CH3NH2 ; (X3) H2NCH2COOH; (X4) HOOCCH2CH2CH(NH2)COOH (X5) H2NCH2CH2CH2CH2CH(NH2)COOH. Dd no lm qu tm ha xanh? A. X1, X2, X5 B. X2, X3,X4 C. X2, X5 D. X1, X5, X4 15: Dd no di y lm qu tm ha ? (1) NH2CH2COOH ; (2) Cl-NH3+-CH2COOH ; (3) H3N+CH2COO- ; (4) H2N(CH2)2CH(NH2)COOH ; (5) HOOCCH2CH2CH(NH2)COOH A. (3) B. (2) C. (2), (5) D. (1), (4) 16: A l HCHC c cng thc phn t C5H11O2N. un A vi dd NaOH thu c mt hh cht c CTPT C2H4O2NNa v cht hu c B. Cho hi ca B qua CuO/t0 thu c cht C bn trong dd hn hp ca AgNO3 v NH3. CTCT ca A l: A. CH3(CH2)4NO2 B. H2NCH2COOCH2CH2CH3 C. H2NCH2COOCH(CH3)2 D. H2NCH2CH2COOC2H5 17: Este X c iu ch t aminoaxit Y v ancol etylic. T khi hi ca X so vi H2 bng 51,5. t chy hon ton 10,3g X thu c 8,1 g H2O v 1,12 lt N2(ktc). CTCT thu gn ca X l: A. H2N-(CH2)2-COO-C2H5 B. H2N-CH2-COO-C2H5 C. H2N-CH(CH3)-COOH D. H2N-CH(CH3)-COOC2H5 18: HCHC X c cha 15,7303% nguyn t N; 35,9551% nguyn t O v khi lng v cn c cc nguyn t C v H. Bit X c tnh lng tnh v khi dd X tc dng vi dd HCl ch xy ra mt phn ng duy nht. CTCT thu gn ca X l: A. H2NCOOCH2CH3 B. H2NCH2CH(CH3)COOH C. H2NCH2CH2COOH D. H2NCH2COOCH3 19: Tn gi no sau y l ca peptit H2NCH2CONHCH(CH3)CONHCH2COOH? A. Gly-ala-gly B. Gly-gly-ala C. Ala-gly-gly D. Ala-gly-ala 20: Trong bn ng nghim mt nhn cha ring bit tng dd: glyxin, lng trng trng, tinh bt, x phng. Thuc th phn bit ra mi dd l?A. Qu tm, dd it, Cu(OH)2. B. Qu tm, NaOH, Cu(OH)2 .C. HCl, dd it, Cu(OH)2. D. HCl, dd it, NaOH. 21: Cu no sau y khng ng? A. Khi nh axit HNO3 c vo lng trng trng thy xut hin mu vng. B. Phn t cc protein gm cc mch di polipeptit to nn. C. Protein rt t tan trong nc v d tan khi un nng. D. Khi cho Cu(OH)2 v lng trng trng thy xut hin mu tm xanh. 22: Mt hp cht cha cc nguyn t C, H, O, N c phn t khi bng 89 c.C. t chy hon ton 1 mol hp cht thu c 3 mol H2N - CH2 - CO - NH - CH - CO - NH - CH - CO - NH - CH2 - COOH CO2 0,5 mol N2 v a mol hi nc. CTPT ca hp cht l? A. C4H9O2N B. C2H5O2N C. C3H7NO2 D. C3H5NO2 CH2-COOH CH2- C6H5 23: Thy phn hp cht: Thu c aninoaxit no sau y: A. H2N-CH2-COOH B. HOOC-CH2-CH(NH2)-COOH C. C6H5-CH2-CH(NH2)-COOH D. Hn hp A, B, C. 24: Trong cc cht sau Cu, HCl, C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxxetic tc dng c vi nhng cht no? A. Tt c cc cht. B. HCl, KOH, CH3OH/ kh HCl. C. C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl D. Cu, HCl, KOH, Na2SO3, CH3OH/ kh HCl. 25: X l mt aminoaxit no ch cha mt nhm NH2- v mt nhm -COOH. Cho 0,89 gam X tc dng vi dd HCl va to ra 1,255 gam mui. CTCT ca X l?

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A. H2N-CH2-COOH B. CH3 - CHNH2-COOH C. CH3 -CHNH2 -CH2-COOH D. C3H7-CHNH2-COOH 26: Khi thy phn hon ton policapromit (policaproic) trong dd NaOH nng d thu c sn phm no di y? A. H2N(CH2)5COOH B. H2N(CH2)6COONa C. H2N(CH2)5COONa D. H2N(CH2)6COOH 27: X l - aminoaxit no ch cha mt nhm -NH2 v mt nhm -COOH. Cho 15,1 gam X tc dng vi dd HCl d thu c 18,75g mui ca X. X c th l cht no sau: A. C6H5CH(NH2)COOH B. CH3CH(H2N)COOH C. CH3CH(H2N)CH2COOH D. C3H7CH(NH2)COOH 28: Protein (protein) c th c m t nh th no? A. Cht polime trng hp. B. Cht polieste. C. Cht polime ng trng hp. D. Cht polime ngng t (trng ngng). 29: Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu v.C) B. Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc v -aminoaxit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axitnucleic,... 30: X l - aminoaxit no ch cha mt nhm -NH2 v mt nhm -COOH. Cho 23,4 gam X tc dng vi dd HCl d thu c 30,7g mui ca X. CTCT thu gn ca X c th l: A. CH3CH(NH2)COOH B. H2NCH2COOH C. H2NCH2CH2COOH D. CH3CH(CH3)CH(NH2)COOH 31: Hp cht C3H7O2N tc dng c vi NaOH, H2SO4 v lm mt mu dd brom. CTCT ca hp cht? A. CH3CH(NH2)COOH B. H2NCH2CH2COOH C. CH2=CHCOONH4 D. CH2=CH-CH2COONH4 32: Aminoaxit l hp cht hu c trong phn t cha: A. Cha nhm amino. B. Cha nhm cacboxyl. C. Mt nhm amino v mt nhm cacboxyl. D. Mt hoc nhiu nhm amino v mt hoc nhiu nhm cacboxyl 33: - aminoaxit l aminoaxit m nhm amino gn cacbon v tr th my?A. 1 B. 2 C. 3 D. 4 34: Cho cc cht H2N-CH2-COOH (X); H3C-NH-CH2-CH3 (Y); CH3-CH2-COOH (Z);C6H5-CH(NH2)COOH (T); HOOC-CH2-CH(NH2)-COOH (G); H2N-CH2-CH2-CH2-CH(NH2)-COOH (P). Aminoaxit l cht: A. X, Z, T, P B. X, Y, Z, T C. X, T, G, P D. X, Y, G, P. 35: C4H9O2N c my ng phn aminoaxit (Vi nhm amin bc nht)?A.5 B. 2 C. 3 D. 4 36: Cho qu tm vo mi dd di y, dd lm qu tm ha xanh l? A. CH3COOH B. H2NCH2COOH C. H2NCH2(NH2)COOH D. HOOC-CH2-CH2-CH(NH2)-COOH 37: Tn gi ca hp cht C6H5-CH2-CH(NH2)-COOH nh th no? A. Axitaminophenyl propionic. B. Axit -amino-3-phenyl propionic. C. Phenylalanin D. Axit 2-amino-3-phenyl propanoic. 38: Cho dd qu tm vo 2 dd sau: (X) H2N-CH2-COOH; (Y) HOOC-CH(NH2)-CH2-COOH. Hin tng xy ra? A. X v Y khng i mu qu tm. B. X lm qu chuyn xanh, Y ha . C. X khng lm qu i mu, Y lm qu ha . D. X, Y lm qu ha 39: Sn phm thu c khi thy phn hon ton t enang trong dd HCl d l: A. ClH3N(CH2)5COOH B.ClH3N(CH2)6COOH C. H2N(CH2)5COOH D. H2N(CH2)6COOH 40: Phn ng gia alanin vi axit HCl to ra cht no sau y? A. H2N-CH(CH3)-COCl B. H3C-CH(NH2)-COCl. C. HOOC-CH(CH3)NH3Cl D. HOOC-CH(CH2Cl)NH2 41: Cht A c phn trm khi lng cc nguyn t C,H, O, N ln lt l 32,00%, 6,67%, 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng vi dd NaOH va tc dng vi dd HCl. CTCT ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH 42: Cht A c phn trm cc nguyn t C,H, N, O ln lt l 40,45%, 7,86%, 15,73%, cn li l O. Khi lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd HCl, c ngun gc t thin nhin. Cng thc cu to ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH 43: Cng thc tng qut ca cc amino axit l: A. RNH2COOH B. (NH2)x(COOH)y C. R(NH2)x(COOH)y D. H2N-CxHy-COOH 44: Khi un nng, cc phn t alanin (axit -aminopropionic) c th tc dng vi nhau to ra cc sn phm no di y: A. [-NH-CH2- CO-]n B.[-CH2-CH- CO-]n C. D.[ -CH2-CH- CH2-]n [-NH-CH- CO-]n NH2 CH3 COOH 45: C cc pht biu sau v protein, Pht biu no ng. 1. Protein l hp cht cao phn t thin nhin c cu trc phc tp. 2. Protein ch c trong c th ngi v ng vt. 3. C th ngi v ng vt khng th tng hp c protein t nhng cht v c m ch tng hp c t cc aminoaxit. 4. Protein bn i vi nhit, i vi axit v vi kim. A. 1, 2 B. 2, 3 C. 1, 3 D. 3, 4 46: Axit -aminopropionic tc dng c vi tt c cc cht trong dy A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2NCH2COOH B. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, Cu C. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH D. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, NaCl 47: Pht biu no sau y l khng ng v enzim? A. Hu ht cc enzim c bn cht protin B. Enzim c kh nng lm xc tc cho qu trnh ha hc C. Mi enzim xc tc cho rt nhiu chuyn ha khc nhau D. Tc phn ng nh xc tc enzim thng nhanh hn n 109- 1011 ln 48: Thy phn n cng protein n cng ta thu c cc cht no? A. Cc aminoaxit B. aminoaxit C. Hn hp cc aminoaxit D. Cc chui polipeptit 49: M t hin tng no di y l khng chnh xc?

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A. Nh vi git axit nitric c vo dd lng trng trng thy kt ta mu vng. B. Trn ln lng trng trng, dd NaOH v mt t CuSO4 thy xut hin mu c trng . C. un nng dd lng trng trng thy hin tng ng t li, tch ra khi dd. D. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. 50: Tn gi ca Sn phm v cht phn ng trong phn ng polime ha no sau y l ng? A. nH2N(CH2)5COOH (-HN(CH2)5CO-)n + n H2O B. nH2N(CH2)5COOH (-HN(CH2)6CO-)n + n H2O Axit -aminocaproic t nilon-6 Axit -aminoenantoic t enang C. nH2N(CH2)6COOH (-HN(CH2)6CO-)n + n H2O D. B, C ng Axit 7-aminoheptanoic t nilon-7 51: ng dng no sau y ca aminoaxit l khng ng? A. Aminoaxit thin nhin (hu ht l -aminoaxit) l c s kin to protein trong c th sng. B. Mui inatriglutamat l gia v cho thc n (gi l bt ngt hay m chnh) C. Axitglutanic l thuc b thn kinh, methionin l thuc b gan. D. Cc aminoaxit (nhm NH2 v s 6, 7...) l nguyn liu sn xut t nilon. 52: Pht biu no sau y khng ng: A. Nhng hp cht hnh thnh bng cch ngng t 2 hay nhiu -aminoaxit c gi l peptit. B. Phn t c 2 nhm -CO-NH- c gi l i peptit, 3 nhm -CO-NH- c gi l tri peptit C. Cc peptit c t 10 n 50 n v aminoaxit cu thnh c gi l polipeptit. D. Trong mi phn t peptit, cc aminoaxit c sp xp theo mt th t xc nh. 53: Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu v.C) B. Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc v -aminoaxit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axitnucleic,...

BAI TAP VE AMIN

1. 2. 3. 4.

1500 C 2CH 4 C2 H 2 + 3H 2 lm lanh nhanh

600 C 3C2 H 2 C6 H 6 C
H 2 SO4 (d ) C6 H 6 + HONO2 C6 H 5 NO2 + H 2O

C6 H 5 NO2 + 6 [ H ] C6 H 5 NH 2 +2 H 2O
Hay Hay
o

C6 H 5 NO2 + 3 Fe + 6 HCl C6 H 5 NH 2 + 3FeCl2 + 2 H 2O

t 4C6 H 5 NO2 + 9 Fe + 4 H 2 O 4C6 H5 NH2 + 3Fe3 O4

5.

C6 H 5 NH 2 + CH 3COOH CH 3COO N H 3C 6H 5

6. 7. 8.

C6 H 5 NH 2 + HCl C6 H5 NH3 Cl

C6 H 5 NH 3Cl + NaOH C 6 H 5 NH 2 + NaCl + H 2O

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Nguyn Trung Kin Lp 12A1

9. 10. 11. 12. 13. 14.

600 C 3C2 H 2 C6 H6 C

bot Fe C6 H 6 + Cl 2 C 6H 5Cl + HCl

C6 H 5Cl + 2NaOH C6 H5ONa + NaCl + H 2 O

C6 H 5ONa + CO2 + H 2O C 6H 5OH + NaHCO 3

H 2 SO4 ( d ) C6 H 6 + HONO2 C 6H 5NO 2+ H 2O

Fe / HCl C6 H 5 NO2 + 6 [ H] C6 H5 NH2 +2 H2 O

15. 16. 17. 18. 19. 20. 21. 22. 23.

900 C CaCO3 CaO + CO2

2000 C CaO + 3C CaC 2+ CO
o

CaC2 + 2 H 2 O C 2 H 2 + Ca( OH) 2

t , xt , p 2C2 H 2 C4 H 4
o

CaC 2 + 2HCl CaCl2 + C2 H 2

C4 H 4 + 3H 2 C4 H10
Cracking C4 H10 CH 4 + C3H 6
s' CH 4 + Cl2 CH3Cl + HCl

t o , Ni

C2 H 5OH CH 3Cl + NH 3 CH 3 NH 2 + HCl 100o C

Hoac 24.

xt CH 3Cl + NaNH 2 CH 3NH 2 + NaCl

+ 2CH 3 NH 2 + H 2SO4 CH 3 NH 3 SO 4 2

CH 3 NH 2 + H 2SO4 CH 3N H 3 HSO 4
01). Vit phn ng trng ngng mt s cht quan trng thng gp sau : d) Axit -amino caproic to t capron ( l axit 6- amino hexanoic ). e) Axit -amino enantoic to t enang ( l axit 7-ammino heptanoic ). f) Axit a ipic + hexametylen iamin to t nilon-6,6 ( l axit hexaioic- 1,6 ). 02). C 3 ng phn A, B ,C cng cng thc phn t C4H9O2N : -A t/dng vi HCl v Na2O Nguyn Trung Kin Lp 12A1 Trang 113

- B t/d Hiro mi sinh t o B1, B1 t/d H2SO4 to B2 , B2 t/d NaOH to B1. - C t/d ng NaOH to Mu i + NH3. Xc nh cng thc cu to ca A ,B , C v vit cc phn ng minh ho. 03). A mch thng c cng thc phn t C3H10O2N2 ; A tc dng vi baz kim cho kh NH3 ; A tc dng vi axit v c cho mui ca amin bc mt . Tm cng thc cu to ca A. Vit phn ng ca A vi Ba(OH)2 v H2SO4. 04). -Vit phn ng to ipeptit v tripeptit t Glyxin - Vit cng thc cu to thu gn ca cc cht thu c sau khi thu phn tng cht sau trong mi trng axit v m i trng kim ring r. + ) H2N-CH2-CO-NH CH(CH3)-CO-NH-CH2-COOH. + ) CH3-CH(NH2)-CO-NH-CH(CH2C OOH)-CO-NH-CH(CH2C6H5)-CO-NH-CH2-COOH PHN BI TP TRC NGHIM Cu 1 : ( 2008-A) Pht biu khng ng l : A. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt B. Aminoaxit l nhng hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl C. Trong dd, H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2-COOD. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin Cu 2:C cc dd ring bit sau: Phenylamoni clorua, H2N-CH2-CH2-CH(NH2)COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dd c pH < 7 l: A. 3 B. 4 C. 5 D. 2 Cu 3: (2008-B) Cht phn ng vi dung dch FeCl3 cho kt ta l: A. CH3NH2 B. CH3COOH C. CH3OH D. CH3COOCH3 Cu 4: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dd HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl- B. H2N-CH2-COOH, H2N-CH2CH2-COOH C. .H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl- D. H2N-CH2-COOH, H2NCH(CH3) -COOH Cu 5: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N p vi 100ml NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7gam cht rn. Cng thc cu to thu gn ca X l A. H2NCH2COOCH3 B. HCOOH3NCH=CH2 C. H2NCH2CH2COOH D. CH2=CHCOONH4 Cu 6: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, anilin, phenol, benzen. S cht trong dy phn ng c vi nc Br2 l: A. 8 B. 6 C. 5 D. 7 Cu 7:(2007-A). Khi t chy hon ton mt amin n chc X, thu c 8,4 lit kh CO2, 1,4 lt kh N2 (Cc th tch kh o ktc) 10,125gam nc. Cng thc phn t ca X l A. C4H9N B. C3H7N C. C2H7N D. C3H9N Cu 8: -aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2N-CH2-COOH B. CH3CH2CH(NH2)COOH C. H2NCH2CH2COOH D. CH3CH(NH2)COOH Cu 9: Cho hn hp X gm 2 cht hu c c cng CTPT C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48lit hn hp kh Z(ktc) gm 2 kh u lm xanh giy qu m. T khi hi ca Z i vi H2 bng 13,75. C cn dd Y thu c khi lng mui khan l A. 16,5 g B. 14,3 g C. 8,9g D. 15,7g Cu 10: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lit kh N2 (ktc) v 3,15gam H2O. Khi X tc dng vi dung dch NaOH thu Trang 114 Nguyn Trung Kin Lp 12A1

c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l: A. H2N-CH2-CH2-COOH B. H2N-CH2-COO-CH3 C. H2N-CH2-COO-C3H7 D. H2N-CH2-COOC2H5 Cu 11: (2007-B) Cho cc loi hp cht: aminoaxit(X), mui amoni ca axit cacboxylic(Y), amin(Z), este ca aminoaxit(T). Dy gm cc loi hp cht u tc dng c vi dd NaOH v u tc dng c vi dung dch HCl l: A. X, Y, Z, T B. X, Y, T C. X, Y, Z D. Y, Z, T Cu 12 : Cho cc cht etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni clorua, ancol benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dd NaOH l : A. 6 B. 4 C. 5 D. 3 Cu 13 : C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l :A. dd phenolphtalein B. dd NaOH C. Nc Br2 D. Giy qu tm Cu 14 : Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. Protit lun l cht hu c no B. Protit lun cha chc hirxyl C. Protit c khi lng phn t ln hn D. Protit lun cha Nit Cu 15 : Dy gm cc cht u lm qu tm m chuyn sang mu xanh l : A. Anilin, metyl amin, amonic B. Amoni clorua, metyl amin, natri hiroxit C. Anilin, amoniac, natri hiroxit D. Metyl amin, amoniac, natri axetat A. 25% v 75% B. 50% v 50% C. 43,6% v 56,4% D.Kt qu khc Cu 16: Cho 0,1 mol amino axit X tc dng va vi 0,1 mol HCl. Ton b sn phm thu c tc dng va vi 0,3 mol NaOH. X l amino axit c A. 1 nhm -NH2 v 1 nhm COOH B. 2 nhm NH2 v 1 nhm COOH C. 1 nhm NH2 v 3 nhm COOH D. 1 nhm NH2 v 2 nhm COOH Cu 17: Khi un nng hn hp glixin v alanin s thu c ti a bao nhiu loi phn t tri peptit cha ng thi c 2 loi amino axit trong phn t? A. 4 B. 8 C. 6 D. 5 Cu 18: X l este ca mt -aminoaxit vi ancol metylic. Ho hi 25,75g X th thu c th tch hi bng th tch ca 8g kh O2 cng iu kin. Cng thc cu to ca X l A. H2N-CH2-CH2-COO-CH3 B. CH3-CH(NH2)-COO-CH3 C. H2N-CH2COO-CH3 D. CH3-CH2-CH(NH2)-COO-CH3 Cu 19: Ngi ta iu ch anilin bng cch nitro ho 500g benzen ri kh hp cht nitro sinh ra. Bit hiu sut 2 giai on trn ln lt bng 78% v 80%. Khi lng anilin thu c l A. 327 gam B. 476,92 gam C. 596,15 gam D. Kt qu khc Cu 20:Cho 2 cng thc phn t C4H10O v C4H11N. S ng phn ancol bc 2 v amin bc 2 tng ng l: A. 1,1 B. 4,8 C. 4,1 C. 1,3 Cu 21: Hp cht hu c X l este c to bi axit glutamic v mt ancol bc nht. phn ng va ht 37,8 gam X cn 400ml dung dch NaOH 1M. Cng thc cu to thu gn ca X A. C3H5(NH2)(COOH)(COOCH2-CH2-CH3 B. C3H5(NH2)(COOCH2-CH2CH3)2 C. C2H3(NH2)(COOCH2CH3)2 D. C2H3(NH2)(COOH)(COOCH2-CH2CH2-CH3) Nguyn Trung Kin Lp 12A1 Trang 115

Cu 22: Hy chn cng thc sai trong s cc cng thc cho di y ca aminoaxit? A. C5H12O2N2 B. C3H7O2N C. C4H9O2N D. C4H8O2N Cu 23. X l mt amino axit no cha 1 nhm amino v 1 nhm cacboxyl. Cho 1,31g X tc dng vi HCl d thu c 1,675 g mui clorua ca X. Cng thc cu to thu gn X l. A. H2N-(CH2 )6-COOH B. H2N-(CH2 )3-COOH C. H2N-(CH2 )4-COOH D. H2N-(CH2 )5-COOH

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