14) Cho 3,584 lt (ktc) hn hp gm mt ankan (X), mt anken (Y), mt ankin (Z).

Ly

hn hp cho tc dng vi dung dch AgNO3 d trong amoniac thy th tch hn hp gim 12,5% v thu c 1,47 gam kt ta. Cho hn hp cn li i qua dung dch brom d thy khi lng bnh brom tng 2,22 gam v c 13,6 gam brom phn ng. t chy hon ton lng kh i ra khi bnh brom ri hp th ton b sn phm chy vo dung dch Ba(OH)2 d th thu c 2,955 gam kt ta. Cc cht X, Y, Z ln lt l: A - CH4, C2H4, C2H2. ---------- B - C3H8, C2H4, C3H4. C - C3H8, C2H4, C2H2. ---------- D - CH4, C2H4, C3H4. Cho B
2) Dung dch X cha 0,025 mol Al2(SO4)3 v 0,03 mol FeSO4. Cho V lt dung dch Y l hn hp Ba(OH)2 0,05M v KOH 0,1M vo dung dch X thu c dung dch Z v kt ta P. thu c kt ta P ln nht th gi tr ca V l A. 2,25. B. 2,10. C. 0,95. D. 1,05. 6) A ch cha mt loi nhm chc, c CTPT C4H6O2 v ph hp vi dy bin ha sau:
+ H2 H2O trug h n p A B C caosubuna Ni,to xt, to

S cng thc cu to hp l c th c ca A l A. 1. B. 2. C. 3. D. 4. 12) Cho m gam hn hp X gm hai ancol n chc, k tip nhau trong dy ng ng tc dng vi CuO d, nung nng thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d AgNO3 trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 6,76. B. 8,8. C. 7,8. D. 7,4. 13) Cho 2,7g Al vo 400 ml dung dch FeCl3 1M, sau khi phn ng hon ton thu c dung dch X. Cho dung dch NaOH long d vo dung dch X thu c kt ta Y (khng cho tip xc khng kh). Khi lng Y l A. 21,4g. B. 37,7g. C. 32,1g. D. 45,5g. 19) Phng php iu ch kim loi no sau y khng ng?
t 2Cr + Al2O3 A. Cr2O3 + 2Al t +CO, t CaO Ca C. CaCO3
o o o

t B. HgS + O2

Hg + SO2
+ Zn

D. Ag2S Na[Ag(CN)2] Ag

+ NaCN

20)

21) 24) Cho cht X tc dng c vi dung dch NaOH c dung dch Y, c cn dung dch

Y c cht rn Z v hn hp hi T. T T chng ct thu c P, em P i trng gng cho sn phm Q. Q tc dng vi dung dch NaOH li thu c Z. Vy X c cng thc cu to no sau y l ph hp ? B. HCOO - C = CH2 A. HCOO - CH2 - CH = CH2 CH3 C. HCOO-CH = CH - CH3 D. CH3-COO-CH = CH2
13) Ch t cc ho cht: KMnO4 (rn) ; Zn ; FeS ; dung dch HCl c, cc thit b v iu kin cn thit c , ta c th iu ch c ti a bao nhiu kh: A. 6. B. 4. C. 7. D. 5. 13) Ho tan hon ton hn hp gm MgO , Zn(OH)2 , Al , FeCO3 , Cu(OH)2 , Fe trong dung dch H2SO4 long d, sau phn ng thu c dung dch X. Cho vo dung dch X mt lng Ba(OH)2 d thu c kt ta Y. Nung Y trong khng kh n khi lng khng i c hn hp rn Z, sau dn lung kh CO d ( nhit cao) t t i qua Z n khi phn ng xy ra hon ton thu c cht rn G. Trong G cha A. BaO, Fe, Cu, Mg, Al2O3. B. MgO, BaSO4, Fe, Cu. C. MgO, BaSO4, Fe, Cu, ZnO. D. BaSO4, MgO, Zn, Fe, Cu. 14) 15) Pht biu no sau y l ng? A. Amin bc mt c phn ng vi axit nitr nhit thng cho ancol bc mt hoc phenol v gii phng nit. B. Hn hp rn gm cc cht: CuCl2, AgNO3, ZnCl2 cng s mol khng th tan ht trong dung dch NH3 d. C. Dng ho cht Cu(OH)2/OH-, khng th phn bit c ht cc dung dch khng mu: GlyAla; mantoz; glixerol; etanol ng trong cc l mt nhn. D. Kh este CH3COOC2H5 bng LiAlH4 thu c hn hp 2 ancol l ng ng k tip. 16) 17) X l hp cht thm c cng thc phn t C7H8O2. X va c th phn ng vi dung dch NaOH, va c th phn ng c vi CH3OH (c H2SO4 c lm xc tc, 1400C). S cng thc cu to c th c ca X l: A. 3. B. 6. C. 4. D. 5. 20) Dung dch A cha: 0,15 mol Ca2+ ; 0,6 mol Cl- ; 0,1 mol Mg2+ ; a mol HCO3- ; 0,4 mol Ba2+. C cn dung dch A, thu c cht rn B. Nung B trong khng kh n khi lng khng i thu c m gam cht rn khan. Gi tr ca m l: A. 102,2. B. 127,2. C. 90,1. D. 105,5. 22) Oxi ho hn hp X gm HCHO v CH3CHO bng oxi (c xc tc) n phn ng hon ton thu c hn hp axit tng ng Y c t khi hi so vi X bng145/97. Thnh phn % theo khi lngca HCHO trong hn hp u l A. 83,33 B. 79,31. C. 77,32 D. 12,00. 23) Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l : A. 26,05. B. 18,95. C. 34,60. D. 36,40. 24) X l dung dch AlCl3, Y l dung dch NaOH 2M. Thm 150 ml dung dch Y vo cc cha 100 ml dung dch X, khuy u ti phn ng hon ton trong cc c 7,8 gam kt ta. Thm tip 100 ml dung dch Y, khuy u ti kt thc cc phn ng thy trong cc c 10,92 gam kt ta. Nng CM ca dung dch X bng? Na = 23 , O = 16 , Al = 27 , Cl = 35,5). A - 1,6M ---------- B - 3,2M C - 2M ---------- D - 1M 25) Vi n ti thiu bng bao nhiu th c c hp cht X c cng thc phn t CnH2nO2, khng tc dng vi Na, khi un nng X vi axit v c c hai cht Y1,Y2. Oxi ha Y2 thu c HCHO; Y1 tham gia phn ng trng bc. A - n = 4 ---------- B - n = 3

C - n = 5 ---------- D - n = 2. 26) Ch ra iu ng khi ni v da tht v simili : A - Da tht l protit. Simili l polime tng hp. ---------- B - Da tht l protit ng vt. Simili l protit thc vt. C - Da tht v simili u l polime tng hp ---------- D - Da tht v simili u l polime thin nhin.

Da tht c ngun gc l da ng vt nn l protit ng vt. Simili l cht do, ngun gc t P.V.C (polime tng hp)
27) Nhn nh no sau y ng? A. X phng v cht git ra tng hp u gy nhim mi trng v khng b phn hy theo thi gian. B. X phng v cht git ra tng hp u c cu to u a nc v ui di k nc. C. Cht git ra tng hp v cht ty mu u c th dng git qun o. D. X phng v cht git ra tng hp c c ch git ra khc nhau. 28) 29) ng dng no di y khng phi l ng dng ca glucoz? A. Trng bc, trng phch. B. Lm thc phm dinh dng v thuc tng lc. C. Lm nguyn liu sn xut PVC. D. Lm nguyn liu sn xut ancol etylic. 30) u im ca x phng so vi cht git ra tng hp l A. c th s dng c vi nc cng. B. ng thi thu c glixerol khi iu ch t du m. C. khng gy hi cho da v mi trng. D. khng s dng thc phm lm nguyn liu iu ch. 37) Trn 3 dung dch H2SO4 0,1M; HNO3 0,2M; HCl 0,3M vi nhng th tch bng nhau thu c dung dch A. Ly 300 ml dung dch A cho tc dng vi V lt dung dch B gm NaOH 0,2M v KOH 0,29M thu c dung dch C c pH = 2. Gi tr ca V l A. 0,424 lt. B. 0,414 lt. C. 0,214 lt. D. 0,134 lt.

38) 40) 41) Chn cu sai A. Oligopeptit gm cc peptit c t 2 n 10 gc -amino axit. B. Lin kt ca nhm CO vi nhm NH gia 2 n v -amino axit c gi l lin kt peptit. C. Polipeptit gm cc peptit c t 10 n 50 gc -amino axit. D. Peptit l nhng hp cht cha t 2 n 50 gc -amino axit lin kt vi nhau bng cc lin kt peptit. 42) Nh 30 mol dung dch NaOH 2M vo 20 ml dung dch hn hp gm HCl C1 (mol/l) v HNO3 C2 (mol/l), thy NaOH d. Trung ho NaOH d cn 30 ml dung dch HBr 1M. Mt khc trn 10 ml dung dch HCl C1 vi 20 ml dung dch HNO3 C2 th th tch dung dch NaOH 1M cn trung ho l 20 ml. Gi tr C1 v C2 l A - 1,0 v 0,5 ---------- B - 0,5 v 1,0 C - 0,5 v 1,5 ---------- D - 1,0 v 1,0 43) Cho mt lng Fe ho tan ht vo dung dch cha 0,1 mol HNO3 v 0,15 mol AgNO3 sau phn ng thu c dung dch X ch cha Fe(NO3)3 , kh NO v cht rn Y. Cho x gam bt Cu vo dung dch X thu c dung dch Z trong c khi lng ca Fe(NO3)3 l 7,986 gam. X c gi tr l A - 1,344 gam. ---------- B - 20,624 gam. C - 25,984 gam. ---------- D - 19,104 gam. 46) Cho 0,5 lt hn hp gm mt hidrocacbon v kh CO2 trn vi 2,5 lt oxi(d) ri t chy hon ton Th tch ca hn hp sau khi t l 3,4lit.Cho hn hp qua thit b lm lnh , th tch hn hp kh ch cn 1,8 lt .Cho hn hp li qua dung dch KOH d th ch cn 0,5 lt kh.Cho rng th tch cc kh o cng iu kin .Hidrocacbon dng l A. propen B. propan C. xiclobutan D. xiclopropan

47) Cho mt lng bt CaCO3 tac dng hon ton vi dung dch HCl 32,85%.Sau phn ng thu c dung dch X trong nng cn li l 24,2%.Thm vo X mt lng bt MgCO3 khuy u cho phn ng x ra hon ton thu c dung dch Y trong nng HCl cn l 21,20 % .Nng phn trm cc mui CaCl2 v MgCL2 trong dung dch Y tng ng l A. 10,35% ; 3,54% B. 12,35% v 8,54% C. 12,35% v 3,54% D. 8,54% v 10,35% 49) Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc mch h l ng ng lin tip. t chy hn hp X v cho sn phm chy (CO 2, hi nc) ln lt qua bnh 1 ng H2SO4 c bnh 2 ng KOH thy khi lng bnh 2 tng nhiu hn bnh mt l 3,51 gam. Phn cht rn Y cn li sau khi t l Na 2CO3 cn nng 2,65 gam. Cng thc phn t ca hai mui natri l A. C3H7COONa v C4H9COONa. B. CH3COONa v C3H7COONa. C. C2H5COONa v C3H7COONa. D. CH3COONa v C2H5COONa. 50) Nhit phn hon ton 0,1 mol mui M(NO3)2 th thu c cht rn X v 5,04 lt hn hp NO2 v O2. Th tch dung dch H2SO4 ti thiu cn dng ha tan va ht cht rn X l A. 0,3l B. 0,1 C. 0,15 D. 0,2 51) Thu phn triglixerit X trong NaOH ngi ta thu c hn hp hai mui natrioleat v natristearat theo t l mol 1 : 2. Khi t chy a mol X thu c b mol CO2 v c mol H2O. Lin h gia a, b, c l: A. b c = 4a B. b c =3a C. b c =2a D. b = c a