TRNG THPT CHUYN NGUYN HU

THI TH I HC LN I - 2011 MN HA HC Thi gian lm bi: 90 pht; (60 cu trc nghim) M thi 132

Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Al = 27; S = 32; Cl = 35,5; Fe = 56; Cu = 64; Rb = 85,5; K=39; Li =7 ; Zn = 65 ; Ag = 108, Ba = 137 I. Phn chung cho tt c cc th sinh( 40 cu, t cu 1 n cu 40) Cu 1: Phenol phn ng c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br2, (CH3CO)2O, CH3COOH, Na, NaHCO3, CH3COCl: A. 4 B. 6 C. 5 D. 7 Cu 2: Kh 1,6 gam hn hp 2 anehit no bng H2 thu c hn hp 2 ancol. un nng hn hp 2 ancol vi H 2SO4 c c hn hp 2 olefin l ng ng lin tip. t chy ht 2 olefin ny c 3,52 gam CO 2. Cc phn ng xy ra hon ton. Cng thc ca 2 anehit l A. HCHO v CH3CHO B. CH3CHO v CH2(CHO)2 C. CH3CHO v C2H5CHO D. C2H5CHO v C3H7CHO Cu 3: Oxi ha 3,16 gam hn hp 2 ancol n chc thnh anehit bng CuO, t0, sau phn ng thy khi lng cht rn gim 1,44 gam. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO 3/NH3 thu c 36,72 gam Ag. Hai ancol l A. C2H5OH v C3H7CH2OH B. CH3OH v C2H5CH2OH C. CH3OH v C2H5OH D. C2H5OH v C2H5CH2OH Cu 4: Trung ha 28 gam mt cht bo cn dng 20 ml dung dch NaOH 0,175M. Ch s axit ca cht bo l: A. 9 B. 7 C. 8 D. 6 + 2+ Cu 5: Cho dung dch X gm 0,09 mol Na ; 0,05 mol Ca ; 0,08 mol Cl ; 0,1 mol HCO3-; 0,01 mol NO3-. loi b ht ion Ca2+ trong X cn dng 1 lng va dung dch cha a gam Ca(OH)2. Gi tr ca a l: A. 2,96 B. 4,44 C. 7,4 D. 3,7 Cu 6: Cho cc cht sau: CH3COOH (1), C2H5OH (2), C2H6 (3), C2H5Cl (4). Th t cc cht tng dn nhit si l: A. 4, 3, 2, 1 B. 3, 4, 2, 1 C. 1, 2, 3, 4 D. 4, 3, 1, 2 Cu 7: Thy phn hon ton 500 gam protein X thu c 14,85 gam glyxin. S mt xch glyxin trong X l (bit phn t khi ca X l 50.000): A. 201 B. 189 C. 200 D. 198 Cu 8: Cho kh H2S tc dng vi cc cht: dung dch NaOH, kh clo, nc clo, dung dch KMnO 4/H+, kh oxi d un nng, dung dch FeCl3, dung dch ZnCl2. S trng hp xy ra phn ng v s trng hp trong lu hunh b oxi ha ln S+6 l: A. 7 - 2 B. 6 - 3 C. 6 -1 D. 6 -2 Cu 9: C bao nhiu cht c th phn ng vi axit fomic trong s cc cht sau: KOH, NH 3, CaO, Mg, Cu, Na2CO3, Na2SO4, CH3OH, C6H5OH, AgNO3/NH3? A. 8 B. 9 C. 7 D. 6 Cu 10: Nung 8,42g hn hp X gm Al, Mg, Fe trong oxi sau mt thi gian thu c 11,62g hn hp Y. Ha tan hon ton Y trong dung dch HNO3 d thu c 1,344 lt NO (ktc) l sn phm kh duy nht. S mol HNO3 phn ng l: A. 0,56 mol B. 0,64 mol C. 0,48 mol D. 0,72 mol Cu 11: t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH4, C2H4, C2H6, C3H8 thu c 6,16 gam CO2 v 4,14 gam H2O. S mol C2H4 trong hn hp trn l: A. 0,02 mol B. 0,01 mol C. 0,08 mol D. 0,09 mol Cu 12: Cho cc cht: FeS, Cu2S, FeSO4, H2S, Ag, Fe, KMnO4, Na2SO3, Fe(OH)2. S cht c th phn ng vi H2SO4 c nng to ra SO2 l: A. 9 B. 8 C. 6 D. 7 Cu 13: X l dung dch Na[Al(OH)4]. Cho t t n d cc dung dch sau y vo dung dch X: AlCl3, NaHSO4, HCl, BaCl2, kh CO2. S trng hp thu c kt ta sau phn ng l: A. 3 B. 4 C. 2 D. 1 Cu 14: Kh hon ton m gam oxit MxOy cn va 10,752 lt H2 (ktc) thu c 20,16g kim loi M. Cho ton b lng kim loi ny tc dng vi dung dch HNO3 long d thu c 8,064 lt NO (ktc) l sn phm kh duy nht. Cng thc ca MxOy l:

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A. FeO B. Fe3O4 C. Cr2O3 D. Cu2O Cu 15: Cho 7,1g hn hp gm 1 kim loi kim X v 1 kim loi kim th Y tc dng ht vi lng d dung dch HCl long thu c 5,6 lt kh (ktc). Hai kim loi X v Y ln lt l: A. K, Ca B. Li, Be C. Na, Mg D. K, Ba Cu 16: Dy cc cht no sau y u khng lm i mu qu tm: A. Axit glutamic, valin, alanin B. Axit glutamic, lysin, glyxin C. Alanin, lysin, phenyl amin D. Anilin, glyxin, valin Cu 17: Hn hp X gm HCOOH, CH 3COOH (t l mol 1:1), hn hp Y gm CH 3OH, C2H5OH (t l mol 2:3). Ly 16,96 gam hn hp X tc dng vi 8,08 gam hn hp Y (c xc tc H 2SO4 c) thu c m gam este (hiu sut cc phn ng este ha u bng 80%). Gi tr ca m l: A. 12,064 gam B. 22,736 gam C. 17,728 gam D. 20,4352 gam Cu 18: Hn hp X gm O2 v O3 c t khi so vi H2 l x. t chy hon ton 1 lt hn hp Y gm CO v H 2 cn 0,4 lt hn hp X. Bit t khi ca Y so vi H2 bng 7,5 v cc th tch kh o cng iu kin nhit , p sut. Gi tr ca x l: A. 19,2 B. 22,4 C. 17,6 D. 20 Cu 19: Este X c CTPT C5H8O2 khi tc dng vi NaOH to ra 2 sn phm u c kh nng tham gia phn ng trng gng. S cht X tha mn iu kin trn l: A. 2 B. 1 C. 3 D. 4 Cu 20: Thm t t 70ml dung dch H2SO4 1M vo 100ml dung dch Na2CO3 1M thu c dung dch Y. Cho Ba(OH)2 d vo dung dch Y th khi lng kt ta thu c l: A. 22,22g B. 11,82g C. 28,13g D. 16,31g Cu 21: Cht no sau y c kh nng to ra 4 loi dn xut mono brom? A. m-imetylbenzen B. o-imetylbenzen C. p-imetylbenzen D. Etylbenzen Cu 22: Hn hp A gm CH4, C2H4, C3H4. Nu cho 13,4 gam hn hp X tc dng vi dung dch AgNO3/NH3 d th thu c 14,7gam kt ta. Nu cho 16,8 lt hn hp X (ktc) tc dng vi dung dch brom th thy c 108gam brom phn ng. % th tch CH4 trong hn hp X l: A. 30% B. 25% C. 35% D. 40% Cu 23: Ha tan a mol Fe trong dung dch H2SO4 thu c 12,32 lt SO2 (ktc) l sn phm kh duy nht v dung dch X. C cn dung dch X thu c 75,2 gam mui khan. Gi tr ca a l: A. 0,4 B. 0,6 C. 0,3 D. 0,5 Cu 24: Nhit phn cc mui sau: (NH4)2Cr2O7, CaCO3, Cu(NO3)2, KMnO4, Mg(OH)2, AgNO3, NH4Cl, BaSO4. S phn ng xy ra v s phn ng oxi ha kh l: A. 8 - 5 B. 7 - 4 C. 6 - 4 D. 7 - 5 Cu 25: Dy no sau y gm tt c cc cht u c lin kt cng ha tr, lin kt ion v lin kt cho nhn (theo quy tc bt t)? A. FeCl3, HNO3, MgCl2. B. H2SO4, NH4Cl, KNO2. C. KNO3, FeCl3, NaNO3. D. NH4NO3, K2SO4, NaClO4. Cu 26: X v Y l hai kim loi thuc cng mt nhm A. Bit ZX < ZY v ZX + ZY = 32. Kt lun no sau y l ng vi X, Y? A. X, Y u c 2 electron lp ngoi cng B. Tnh kim loi ca X mnh hn Y C. Nng lng ion ha ca X nh hn ca Y D. Bn knh nguyn t ca X ln hn Y Cu 27: Khi lng ca mt on mch t nilon-6,6 l 27346 u v ca mt on mch t capron l 17176 u. S mt xch trong on mch t nilon-6,6 v t capron nu trn ln lt l A. 121 v 152. B. 113 v 114. C. 121 v 114. D. 113 v 152. Cu 28: Cho cn bng: H < 0. cn bng trn chuyn dch sang phi th phi: A. Gim p sut, gim nhit B. Tng p sut, tng nhit C. Gim p sut, tng nhit D. Tng p sut, gim nhit Cu 29: X l mt tetrapeptit. Cho m gam X tc dng va vi 0,3 mol NaOH thu c 34,95g mui. Phn t khi ca X c gi tr l A. 324 B. 432 C. 234 D. 342 Cu 30: Tripeptit mch h X v tetrapeptit mch h Y u c to ra t mt amino axit no, mch h c 1 nhm COOH v 1 nhm NH2. t chy hon ton 0,1 mol X thu c sn phm gm CO 2, H2O, N2 trong tng khi lng CO2, H2O l 36,3 gam. Nu t chy hon ton 0,2 mol Y cn s mol O2 l A. 1,875 B. 1,8 C. 2,8 D. 3,375

2 SO2 (kh)+O 2 ( kh) 2 SO3 ( kh)

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Cu 31: Cho cc cht sau: Al, ZnO, CH3COONH4, KHSO4, H2NCH2COOH, H2NCH2COONa, KHCO3, Pb(OH)2, ClH3NCH2COOH, HOOCCH2CH(NH2)COOH. S cht c tnh lng tnh l A. 7 B. 6 C. 8 D. 5 Cu 32: Cho m gam glucoz ln men thnh ancol etylic vi hiu sut 75%. Hp th ton b kh CO 2 sinh ra vo dung dch Ca(OH)2 d thu c 90g kt ta. Gi tr ca m l: A. 81g B. 96g C. 108g D. 162g Cu 33: C 6 dung dch ring bit: Fe(NO3)3, AgNO3, CuSO4, ZnCl2, Na2SO4, MgSO4. Nhng vo mi dung dch mt thanh Cu kim loi, s trng hp xy ra n mn in ha l: A. 3 B. 1 C. 4 D. 2 Cu 34: Cho cc cht: CH3CH2OH, C2H6, CH3OH, CH3CHO, C6H12O6, C4H10, C2H5Cl. S cht c th iu ch trc tip ra axit axetic (bng 1 phn ng) l: A. 2 B. 3 C. 4 D. 5 Cu 35: Cho m gam KOH vo 2 lt dung dch KHCO3 a mol/l thu c 2 lt dung dch X. Ly 1 lt dung dch X tc dng vi dung dch BaCl2 d thu c 15,76g kt ta. Mt khc, cho 1 lt dung dch X vo dung dch CaCl 2 d ri un nng, sau khi cc phn ng xy ra hon ton thu c 10g kt ta. Gi tr ca m v a ln lt l: A. 8,96g v 0,12 M B. 5,6g v 0,04 M C. 4,48g v 0,06 M D. 5,04g v 0,07 M Cu 36: Sc clo t t n d vo dung dch KBr th hin tng quan st c l: A. Dung dch c mu vng B. Khng c hin tng g C. Dung dch c mu nu D. Dung dch t khng mu chuyn sang mu vng sau li mt mu. Cu 37: Hp cht thm X c cng thc phn t C6H8N2O3. Cho 28,08 gam X tc dng vi 200 ml dung dch KOH 2M sau phn ng thu c dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ca m l: A. 21,5 gam B. 38,8 gam C. 30,5 gam D. 18,1 gam Cu 38: Ha tan Fe3O4 trong lng d dung dch H2SO4 long c dung dch X. Hi dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al? A. 5 B. 6 C. 7 D. 4 Cu 39: Cho m gam bt Cu vo 200 ml dung dch AgNO3 0,2M, sau phn ng thu c 3,88g cht rn X v dung dch Y. Cho 2,925g bt Zn vo dung dch Y sau phn ng thu c 5,265g cht rn Z v dung dch ch cha 1 mui duy nht. Gi tr ca m l: A. 3,17 B. 2,56 C. 1,92 D. 3,2 Cu 40: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CuSO4, NaOH, NaHSO4, K2CO3, Ca(OH)2, H2SO4, HNO3, MgCl2, HCl, Ca(NO3)2. S trng hp c phn ng xy ra l: A. 9 B. 6 C. 8 D. 7 II. Phn ring (10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh Chun (t cu 41 n cu 50) Cu 41: t chy 10,4 gam mt axit cacboxylic no, a chc mch h, khng phn nhnh thu c 0,3 mol CO 2 v 0,2 mol H2O. Cng thc cu to ca 2 axit l: A. HOOC-(CH2)3-COOH. B. HOOC-CH2-COOH. C. HOOC-CH2-CH2-COOH. D. HOOC-(CH2)4-COOH. Cu 42: Hp cht A1 c CTPT C3H6O2 tho mn s dd NaOH dd H 2SO4 dd AgNO 3 / NH 3 A1 A2 A3 A4 Cng thc cu to ca A1 l: A. HCOO 2 3. CH CH B. CH3 CO 2 CH OH. C. CH3 2 CH COOH. D. HO 2 2 CH CH CHO. Cu 43: Dy no sau y gm cc kim loi u c th iu ch c bng phng php nhit luyn: A. Zn, Mg, Ag B. Ba, Fe, Cu C. Al, Cu, Ag D. Cr, Fe, Cu Cu 44: Cc ion no sau y khng th cng tn ti trong mt dung dch: A. K+, Mg2+, NO3 , Cl-. B. Cu2+, Fe2+, HSO4 , NO3 . C. Mg2+, Al3+, Cl , HSO4 . D. Na+, NH4+, SO42 , PO43 . Cu 45: Ha tan hon ton 30,4 gam cht rn X gm Cu, CuS, Cu 2S v S bng HNO3 d thy thot ra 20,16 lt kh NO duy nht (ktc) v dung dch Y. Thm dung dch Ba(OH)2 d vo dung dch Y c m gam kt ta.

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Gi tr ca m l: A. 81,55 gam. B. 115,85 gam. C. 110,95 gam. D. 29,4 gam. Cu 46: Hn hp kh X gm mt hirocacbon A v H2. T khi ca X so vi H2 bng 6,7. un X vi bt Ni nung nng n khi phn ng xy ra hon ton thu c hn hp Y gm ankan v H 2 d. T khi ca Y so vi H2 bng 16,75. Cng thc phn t ca A l: A. C2H2 B. C2H4 C. C3H4 D. C3H6 Cu 47: Mt - aminoaxit no X ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 3,56 gam X tc dng va vi HCl to ra 5,02 gam mui. Tn gi ca X l A. Alanin B. Valin C. Lysin D. Glyxin Cu 48: Oxi ha hon ton m gam mt ancol n chc X bng CuO th thu c hn hp kh v hi c t khi so vi H2 bng 19. Sau phn ng ngi ta nhn thy khi lng cht rn gim 4,8 g. Gi tr ca m l: A. 15 g B. 1,8 g C. 12 g D. 18 g Cu 49: Th nghim no sau y c kt ta sau phn ng? A. Thi CO2 n d vo dung dch Ca(OH)2. B. Cho dung dch HCl n d vo dung dch NaCrO2 C. Cho dung dch NaOH n d vo dung dch Cr(NO3)3. D. Cho dung dch NH3 n d vo dung dch FeCl3. Cu 50: Pht biu no sau y khng ng? A. m chy magie c th c dp tt bng ct kh. B. Pht pho trng c cu trc mng tinh th phn t C. Trong phng th nghim, N2 c iu ch bng cch un nng dung dch NH4NO2 bo ho. D. CF2Cl2 b cm s dng do khi thi ra kh quyn th ph hy tng ozon. Phn II: Theo chng trnh nng cao (t cu 51 n cu 60) Cu 51: Ch dng 1 ha cht phn bit cc cht sau: lng trng trng, dung dch glucoz, dung dch glixerol, dung dch metanal, etanol. Ha cht l: A. Cu(OH)2. B. KMnO4 C. HNO3 c D. HCl Cu 52: Khng th iu ch trc tip axetanehit t: A. Vinyl axetat B. Etilen C. Etanol D. Etan Cu 53: Trn 250 ml dung dch HCl 0,08 M v H2SO4 0,01M vi 250 ml dung dch Ba(OH)2 x M. Thu m gam kt ta v 500ml dung dch c pH = 12. Gi tr ca m v x ln lt l: A. 1,165g v 0,04M B. 1,165g v 0,04M C. 0,5825g v 0,03M D. 0,5825 v 0,06M Cu 54: Th tch dung dch Br2 0,5M cn dng oxi ha ht 200 ml dung dch CrBr3 1M l: A. 300 ml B. 600 ml C. 450 ml D. 900 ml Cu 55: Dung dch no sau y c th ha tan c vng? A. KNO3 B. HNO3 c nng C. HCl c D. HNO3 c + HCl c t l 1:3 Cu 56: Cho cc kim loi: Na, Ca, Al, Fe, Cu. Nu ch dng H2O c th phn bit c bao nhiu kim loi: A. 0 B. 3 C. 1 D. 5 Cu 57: Anehit X c cha 4 nguyn t C trong phn t. Khi cho 0,1 mol X tc dng vi dung dch AgNO 3/NH3 d thu c 43,2 gam Ag Mt khc 0,15 mol X lm mt mu va 200 ml dung dch Br2 1,5M. X l: . A. C2H4(CHO)2 B. C3H7CHO C. O=HC-C C-CHO D. O=CH-CH=CH-CHO Cu 58: C6H12 khi tc dng vi dung dch HBr ch to ra 1 sn phm monobrom duy nht. S cng thc cu to ca C6H12 tha mn iu kin trn l: A. 4 B. 2 C. 3 D. 1 Cu 59: Cho sut in ng chun ca cc pin in ho: Mg-Ni l 2,11 V; Ni-Ag l 1,06 V. Bit th in cc chun ca cp Ag+/Ag bng 0,8V. Th in cc chun ca cp Mg2+/Mg v cp Ni2+/Ni ln lt l: A. -2,37V v -0,26V. B. -1,87V v +0,26V. C. -1,46V v -0,34V. D. -0,76V v -0,26V. Cu 60: Cho 27,48 gam axit picric vo bnh kn dung tch 20 lt ri nung nng nhit cao phn ng xy ra hon ton thu c hn hp kh gm CO2, CO, N2 v H2. Gi bnh 12230C th p sut ca bnh l P atm. Gi tr ca P l: A. 7,724 atm B. 6,624 atm C. 8,32 atm D. 5,21 atm ---------------------------------------------------------- HT ----------

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TRNG THPT CHUYN NGUYN HU

THI TH I HC LN II - 2011 MN HA HC 12 Thi gian lm bi: 90 pht; (60 cu trc nghim) M thi 357

Cho nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; S = 32; Cl = 35,5; Br = 80; P = 31; Na = 23; Mg = 24; Al = 27; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba = 137; Pb = 207; Ni = 59. I. Phn chung cho tt c cc th sinh( 40 cu, t cu {<1>} n cu {<40>}) Cu 1: Hn hp A gm X, Y (MX < MY) l 2 este n chc c chung gc axit. un nng m gam A vi 400 ml dung dch KOH 1M d thu c dung dch B v (m 12,6) gam hn hp hi gm 2 anehit no, n chc ng ng k tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn khan. % khi lng ca X trong A l A. 54,66% B. 45,55% C. 36,44% D. 30,37% Cu 2: Cho 240 ml dung dch KOH 1,5M vo V lt dung dch AlCl 3 aM thu c 7,8 gam kt ta. Nu cho 100 ml dung dch KOH 1,5M vo V lt dung dch AlCl3 aM th s gam kt ta thu c l: A. 5,85 gam B. 3,9 gam C. 2,6 gam D. 7,8 gam Cu 3: Cho cc cht: CH3COOH (1); CH3-CH2-CH2OH (2); C2H5OH (3); C2H5COOH (4); CH3COCH3 (5). Th t cc cht theo chiu tng dn nhit si l: A. 5, 3, 2, 1, 4 B. 4, 1, 2, 3, 5 C. 5, 3, 2, 4, 1 D. 1, 4, 2, 3, 5 Cu 4: Cho 8,04 gam hn hp hi gm CH3CHO v C2H2 tc dng hon ton vi dung dch AgNO 3/NH3 thu c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht khng tan. Gi tr ca m l: A. 41,69 gam B. 55,2 gam C. 61,78 gam D. 21,6 gam Cu 5: Cho 3,84 gam Mg tc dng vi dung dch HNO 3 d thu c 1,344 lt NO (ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l: A. 23,68 gam B. 25,08 gam C. 24,68 gam D. 25,38 gam Cu 6: X phng ha 265,2 kg cht bo c ch s axit bng 7 cn 56,84 kg dung dch NaOH 15%. Khi lng glixerol thu c l (gi s phn ng xy ra hon ton v ch s axit l s mg KOH dng trung ha ht lng axit t do c trong 1 gam cht bo): A. 5,98 kg B. 4,62 kg C. 5,52 kg D. 4,6 kg Cu 7: Tnh cht no sau y khng bin i tun hon theo chiu tng ca in tch ht nhn ca cc nguyn t trong bng tun hon: A. Nguyn t khi B. m in C. Nng lng ion ha D. Bn knh nguyn t Cu 8: Trong qu trnh sn xut Ag t qung Ag2S bng phng php thy luyn ngi ta dng cc ha cht: A. Dung dch H2SO4, Zn B. Dung dch HCl long, Mg C. Dung dch NaCN, Zn D. Dung dch HCl c, Mg Cu 9: Cht no sau y c cu trc mng khng gian: A. Amilopectin B. Nha rezit C. Cao su buna-S D. Nha rezol Cu 10: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c, nhit cao, p sut cao thu c cht Y c cng thc C7H7O2Na. Hy cho bit X c bao nhiu CTCT: A. 3 B. 6 C. 5 D. 4 Cu 11: Ion M2+ c cu hnh e: [Ar]3d8. V tr ca M trong bng tun hon l: A. Chu k 4, nhm VIIIB B. Chu k 3, nhm VIIIA C. Chu k 3, nhm VIIIB D. Chu k 4, nhm VIIIA Cu 12: Phn ng no sau y chng t glucoz c cu trc dng vng A. tc dng vi H2/Ni, t0 B. tc dng vi AgNO3/NH3 C. tc dng vi CH3OH/HCl khan D. tc dng vi Cu(OH)2/OH- nhit thng Cu 13: Ha tan 17 gam hn hp X gm K v Na vo nc c dung dch Y v 6,72 lt H2 (ktc). trung ha mt na dung dch Y cn dng dung dch hn hp H2SO4 v HCl (t l mol 1:2). Tng khi lng mui c to ra l: A. 42,05 gam B. 20,65 gam C. 14,97 gam D. 21,025 gam Cu 14: C 4 gi bt trng: Glucoz, tinh bt, xenluloz, saccaroz. C th chn nhm thuc th no di y phn bit c c 4 cht trn: A. H2O, dd AgNO3/NH3, dd HCl B. H2O, dd AgNO3/NH3, dd I2 C. H2O, dd AgNO3/NH3, dd NaOH D. H2O, O2 ( t chy), dd AgNO3/NH3

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Cu 15: Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X trong iu kin khng c khng kh. Ha tan hon ton hn hp cht rn sau phn ng bng dung dch NaOH d thu c 2,016 lt H 2 (ktc) v 12,4 gam cht rn khng tan. Hiu sut ca phn ng nhit nhm l: A. 80% B. 75% C. 60% D. 71,43% Cu 16: Trong mt bnh kn dung tch 2 lt, ngi ta cho vo 9,8 gam CO v 12,6 gam hi nc. C phn ng xy ra: CO + H2O CO2 + H2 8500C, hng s cn bng ca phn ng l K = 1. Nng H2 khi t n trng thi cn bng l: A. 0,22M B. 0,12M C. 0,14M D. 0,75M Cu 17: t chy hon ton 0,1 mol ancol no A cn 15,68 lt O2 (ktc) bit t khi hi ca A so vi H2 bng 52. Ly 4,16 gam A cho tc dng vi CuO nung nng d sau phn ng thy khi lng cht rn gim 0,64 gam v thu c cht hu c B khng c kh nng trng bc. Vy A l: A. 2-metylbutan-1,4-iol B. Pentan-2,3-iol C. 2-metylbutan-2,3-iol D. 3-metylbutan-1,3-iol Cu 18: Mt mui X c CTPT C3H10O3N2. Ly 19,52 gam X cho phn ng vi 200 ml dung dch KOH 1M. C cn dung dch sau phn ng thu c cht rn v phn hi. Trong phn hi c cht hu c Y n chc bc I v phn rn ch l hn hp cc cht v c c khi lng m gam. Gi tr ca m l: A. 18,4 gam B. 13,28 gam C. 21,8 gam D. 19,8 gam Cu 19: Ha tan ht 6,08 gam hn hp gm Cu, Fe bng dung dch HNO 3 thu c dung dch X v 1,792 lt NO (ktc). Thm t t 2,88 gam bt Mg vo dung dch X n khi phn ng xy ra hon ton thu c 0,448 lt NO (ktc), dung dch Y v m gam cht rn khng tan. Gi tr ca m l : A. 4,96 gam B. 3,84 gam C. 6,4 gam D. 4,4 gam Cu 20: Ha tan ht 10,24 gam Cu bng 200 ml dung dch HNO3 3M c dung dch A. Thm 400 ml dung dch NaOH 1M vo dung dch A. Lc b kt ta, c cn dung dch ri nung cht rn n khi lng khng i thu c 26,44 gam cht rn. S mol HNO3 phn ng vi Cu l: A. 0,48 mol B. 0,58 mol C. 0,56 mol D. 0,4 mol Cu 21: Cho dung dch Ba(HCO3)2 ln lt tc dng vi cc dung dch sau: NaOH, NaHSO 4, HCl, KHCO3, K2CO3, H2SO4. S trng hp xy ra phn ng v s trng hp c kt ta l: A. 4 v 4 B. 6 v 5 C. 5 v 2 D. 5 v 4 Cu 22: Cho m gam Ba tc dng vi H2O d sau phn ng thu c 500 ml dung dch c pH = 13. Gi tr ca m l: A. 6,85 gam B. 13,7 gam C. 3,425 gam D. 1,7125 gam Cu 23: t chy hon ton m gam FeS2 bng mt lng O2 va thu c kh X. Hp th ht X vo 1 lt dung dch cha Ba(OH)2 0,2M v KOH 0,2M thu c dung dch Y v 32,55 gam kt ta. Cho dung dch NaOH vo dung dch Y li thy xut hin thm kt ta. Gi tr ca m l: A. 24 gam B. 27 gam C. 30 gam D. 36 gam Cu 24: C 4 dung dch, mi dung dch cha 1 trong 4 cht: CH4O, CH5N, CH2O, CH2O2. Dng cht no nhn bit chng: A. Giy qu, dd AgNO3 /NH3 B. Giy qu, dd FeCl3 C. Giy qu, dd AgNO3 /NH3, Na D. Giy qu, dd AgNO3 /NH3, Br2 Cu 25: Cho cc cht: H2N-CH2-COOH; HOOC-CH2-CH2-CH(NH2)-COOH; H2NCH2COOC2H5; CH3COONH4; C2H5NH3NO3. S cht lng tnh l: A. 4 B. 3 C. 5 D. 2 Cu 26: H2O2 th hin tnh kh khi tc dng vi cht no sau y: A. Ag2O B. PbS C. KI D. KNO2 Cu 27: Cho 8,4 gam Fe tc dng va vi dung dch cha 0,4 mol H2SO4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton c cn dung dch c m gam mui khan. Gi tr ca m l: A. 35,2 gam B. 22,8 gam C. 27,6 gam D. 30 gam Cu 28: Cho 0,5 mol H2 v 0,15 mol vinyl axetilen vo bnh kn c mt xc tc Ni ri nung nng. Sau phn ng thu c hn hp kh X c t khi so vi CO 2 bng 0,5. Cho hn hp X tc dng vi dung dch Br 2 d thy c m gam Br2 tham gia phn ng. Gi tr ca m l: A. 40 gam B. 24 gam C. 16 gam D. 32 gam + HCl + HCl + NaOH Cu 29: Cho s : But-1-in X1 X2 X3 th X3 l: A. CH3CO-C2H5 B. C2H5CH2CHO C. C2H5CO-COH D. C2H5CH(OH)CH2OH Cu 30: Cho cc hirocacbon sau y phn ng vi clo theo t l 1:1 v s mol, trng hp no to thnh nhiu sn phm ng phn nht: A. neopentan B. Pentan C. etylxiclopentan D. Isopentan Cu 31: Cho hi nc i qua than nung nng sau khi loi b hi nc d thu c 17,92 lt (ktc) hn hp kh X gm CO2, CO v H2. Hp th X vo dung dch Ba(OH)2 d thu c 39,4 gam kt ta v c V lt kh Y thot ra. Cho Y tc dng vi CuO d nung nng sau phn ng thy khi lng cht rn gim m gam. Gi tr ca m l: A. 9,6 gam B. 8,4 gam C. 11,2 gam D. 4,8 gam

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Cu 32: Kh mt este E no n chc mch h bng LiAlH4 thu c mt ancol duy nht G. t chy m gam G cn 2,4m gam O2. t m gam E thu c tng khi lng CO2 v H2O l 52,08 gam. Nu cho ton b lng CO2, H2O ny vo 500 ml dung dch Ba(OH)2 1M. Khi lng kt ta sinh ra l: A. 25,61 gam B. 31,52 gam C. 35,46 gam D. 39,4 gam Cu 33: Dung dch X c cha KCl, FeCl3, HCl. in phn dung dch X mt thi gian thu c dung dch Y. Y khng lm i mu qu tm chng t qu trnh in phn dng li khi: A. va ht FeCl3 B. va ht FeCl2 C. va ht HCl D. in phn ht KCl Cu 34: Ch dng mt thuc th no sau y phn bit cc dung dch ng trong cc l mt nhn: anbumin, glucoz, saccaroz, axit axetic. A. dung dch NH3 B. Cu(OH)2 C. CuSO4 D. HNO3 c Cu 35: Nhn nh no sau y khng ng: A. Hn hp Fe3O4 v Cu c th tan ht trong dung dch HCl B. Hn hp Al2O3 v K2O c th tan ht trong nc C. Hn hp CuS v FeS c th tan ht trong dung dch HCl D. Hn hp Al v BaO c th tan ht trong nc Cu 36: X l mt -amino axit c cha vng thm v mt nhm NH 2 trong phn t. Bit 50 ml dung dch X phn ng va vi 80 ml dung dch HCl 0,5M, dung dch thu c phn ng va vi 50 ml dung dch NaOH 1,6M. Mt khc nu trung ha 250 ml dung dch X bng lng va KOH ri em c cn thu c 40,6 gam mui. CTCT ca X l: A. C6H5-CH(CH3)-CH(NH2)COOH B. C6H5-CH(NH2)-CH2COOH C. C6H5-CH(NH2)-COOH D. C6H5-CH2CH(NH2)COOH Cu 37: Trong cng nghip ngi ta iu ch nc giaven bng cch: A. Cho kh Cl2 i t t qua dung dch NaOH, Na2CO3. B. in phn dung dch NaCl khng mng ngn C. Sc kh Cl2 vo dung dch KOH D. Cho kh Cl2 vo dung dch Na2CO3 Cu 38: T no sau y c ch to t polime trng hp: A. T e nang B. T capron C. T lapsan D. T nilon-6,6 Cu 39: Lc 13,14 gam Cu vi 250 ml dung dch AgNO 3 0,6M mt thi gian thu c 22,56 gam cht rn A v dung dch B. Nhng thanh kim loi M nng 15,45 gam vo dung dch B khuy u n khi phn ng hon ton thu c dung dch ch cha mt mui duy nht v 17,355 gam cht rn Z. Kim loi M l: A. Zn B. Mg C. Pb D. Fe Cu 40: Cho cc phn ng: Na2SO3 + H2SO4 Kh X FeS + HCl Kh Y o to NaNO2 bo ha + NH4Clbo ha KMnO4 t Kh Z Kh T Cc kh tc dng c vi nc clo l: A. X, Y, Z, T B. X, Y, Z C. Y, Z D. X, Y II. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh Chun ( t cu {<41>} n cu {<50>}) Cu 41: Nung m gam K2Cr2O7 vi S d thu c hn hp cht rn X. Ha tan hon ton X vo nc, lc b phn khng tan ri thm BaCl2 d vo dung dch thu c 18,64 gam kt ta. Gi tr ca m l: A. 23,52 gam B. 24,99 gam C. 29,4 gam D. 17,64 gam Cu 42: Phn ng no sau y thu c kt ta sau phn ng: A. Cho kh H2S vo dung dch FeCl2. B. Cho dung dch NaOH c, d vo dung dch Pb(NO3)2. C. Cho t t n d dung dch HCl v dung dch Na[Cr(OH)4] D. Sc kh H2S vo dung dch Pb(NO3)2. Cu 43: Cho cn bng: H2 (K) + I2 (K) 2HI (K) H > 0. Yu t no sau y khng lm chuyn dch cn bng: A. p sut B. Nng I2 C. Nhit D. Nng H2 Cu 44: Cho 4,44 gam axit cacboxylic, n chc X tc dng hon ton vi 500 ml gm: KOH 0,12M, NaOH 0,12M. C cn dung dch thu c 9,12 gam hn hp cht rn khan. CTPT ca X l: A. CH3CHO. B. HCOOH C. C3H7COOH D. C2H5COOH Cu 45: Mu xanh ca dung dch keo X mt i khi un nng v tr li nh ban u khi ngui. Vy X l: A. dd (CH3COO)2Cu B. dd I2 trong tinh bt C. dd ng (II) glixerat D. dd I2 trong xenluloz Cu 46: Cho m gam ancol n chc X qua ng ng CuO d nung nng. Sau khi phn ng xy ra hon ton ngoi cht rn thu c hn hp hi gm 2 cht c t khi so vi H2 l 19. Ancol X l:

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A. C3H5OH B. CH3OH C. C2H5OH D. C3H7OH Cu 47: kh mi tanh ca c (gy ra do mt s amin) ta c th ra c vi: A. Nc B. Nc vi trong C. Cn D. Gim Cu 48: X l mt tetrapeptit cu to t mt amino axit (A) no, mch h c 1 nhm COOH; 1 nhm NH2. Trong A %N = 15,73% (v khi lng). Thy phn m gam X trong mi trng axit thu c 41,58 gam tripeptit; 25,6 gam ipeptit v 92,56 gam A. Gi tr ca m l: A. 149 gam B. 161 gam C. 143,45 gam D. 159 gam Cu 49: Trong pin in ha Cu-Ag ti in cc ng xy ra qu trnh: A. Oxi ha H2O B. Kh Cu2+ C. Kh H2O D. Oxi ha Cu Cu 50: Cho s phn ng: 0 0 Br2 dd ) C4H10O H X ( Y + NaOH Z CuO ,t 2-hiroxi-2-metyl propan. X l: 2O ,t A. Isobutilen B. But-2-en C. But-1- en D. xiclobutan Phn II: Theo chng trnh nng cao (t cu 51 n cu 60) Cu 51: Khi bn m ure cho cy ngi ta khng bn cng vi A. NH4NO3 B. phn kali C. phn ln D. vi Cu 52: Cn a mol K2Cr2O7 v b mol HCl iu ch c 6,72 lt Cl2 (ktc). Gi tr ca a v b l A. 0,05 v 0,7 B. 0,2 v 2,8 C. 0,1 v 1,4 D. 0,1 v 0,35 Cu 53: Cho th in cc ca cc cp oxi ha kh: = -0,76V, = -0,44V, = -0,13V, = 0,8V. Pin in ha no sau y c sut in ng tiu chun ln nht ? A. Zn Fe B. Zn - Pb C. Pb - Ag D. Fe - Ag Cu 54: Cho kh CO i qua ng s ng 0,09 mol hn hp A gm Fe 2O3 v FeO nung nng sau mt thi gian thu c 10,32 gam cht rn B. Dn kh i ra khi ng s vo dung dch Ba(OH)2 d thu c 17,73 gam kt ta. Cho B tc dng ht vi dung dch HNO3 d thu c V lt NO (ktc, sn phm kh duy nht). Gi tr ca V l: A. 1,344 lt B. 1,68 lt C. 1,14 lt D. 1,568 lt Cu 55: Ln men 162 gam tinh bt vi hiu sut cc qu trnh ln men ln lt l 80% v 90%. Tnh th tch dung dch ru 40o thu c? Bit khi lng ring ca C2H5OH nguyn cht l 0,8 g/ml A. 115ml B. 230ml C. 207ml D. 82,8ml Cu 56: Vinyl axetat c iu ch bng phn ng gia: A. Etilen vi axit axetic B. Ancol vinylic vi axit axetic C. Axetilen vi axit axetic D. etanol vi anhirit axetic Cu 57: t chy hon ton m gam hn hp X gm hai anehit no, n chc, mch h thu c 0,4 mol CO2. Mt khc hiro ha hon ton m gam X cn 0,2 mol H2 (Ni, to), sau phn ng thu c hai ancol no n chc. t chy hon ton hn hp hai ancol ny th s mol H2O thu c l: A. 0,6 mol B. 0,5 mol C. 0,3 mol D. 0,4 mol Cu 58: Cho cc cht: Propan, Propin, 2,2-iclopropan, Propan-2-ol, Propan-1-ol, Propen, anlyl clorua, 2-clopropen. S cht c th iu ch c axeton ch bng mt phn ng l: A. 3 B. 6 C. 5 D. 4 Cu 59: Cho cc phn ng: (1) Cl2 + Br2 + H2O 0 (2) Cl2 + KOH t (3) H2O2 MnO2 (4) Cl2 + Ca(OH)2 khan (5) Br2 + SO2 + H2O S phn ng l phn ng t oxi ha kh l: A. 4 B. 3 C. 2 D. 5 Cu 60: Cho 0,1 mol alanin phn ng vi 100 ml dung dch HCl 1,5M thu c dung dch A. Cho A tc dng va vi dung dch NaOH thu c dung dch B, lm bay hi dung dch B thu c bao nhiu gam cht rn khan? A. 14,025 gam B. 8,775 gam C. 11,10 gam D. 19,875 gam --------------------------------------------------------- HT ---------0 EZn2+ / Zn 0 EFe2+ / Fe 0 EPb2+ / Pb
0 E Ag + / Ag

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TRNG THPT CHUYN NGUYN HU

THI TH I HC LN III - 2011 MN HA HC Thi gian lm bi: 90 pht; (60 cu trc nghim) M thi 896

Cu 1: Hirocacbon X c cng thc phn t C6H10. X tc dng vi dung dch AgNO3/NH3 to ra kt ta vng. Khi hiro ha hon ton X thu c neo-hexan. X l: A. 2,2-imetylbut-3-in B. 2,2-imetylbut-2-in C. 3,3-imetylbut-1-in D. 3,3-imetylpent-1-in Cu 2: X l hp cht thm c CTPT C7H8O khi cho X tc dng vi nc Br2 to ra sn phm Y c cha 69,565% Br v khi lng. X l: A. o-crezol B. m-crezol C. Ancol benzylic D. p-crezol Cu 3: Thy phn 95,76g mantoz trong mi trng axit vi hiu sut phn ng t 75% thu c hn hp X. Trung ha hn hp X bng NaOH thu c hn hp Y. Cho Y tc dng vi dung dch AgNO3/NH3 d un nng thu c m gam Ag kt ta. Gi tr ca m l: A. 120,96 gam B. 60,48 gam C. 105,84 gam D. 90,72 gam Cu 4: Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d. Sau phn ng lm bay hi cn thn dung dch thu c (m + 11,68) gam mui khan. Nu cho m gam hn hp X tc dng vi dung dch KOH va , sau phn ng lm bay hi cn thn dung dch thu c (m + 19) gam mui khan. Gi tr ca m l: A. 36,6 gam B. 38,92 gam C. 38,61 gam D. 35,4 gam Cu 5: Tng s ht c bn trong nguyn t ca nguyn t M, X ln lt l 58 v 52. Hp cht MX n c tng s ht proton trong mt phn t l 36. Lin kt trong phn t MXn thuc loi lin kt: A. Cho nhn B. Cng ha tr phn cc C. Ion D. Cng ha tr khng phn cc Cu 6: Cht no sau y khng c kh nng lm mt mu dung dch thuc tm: A. HCl B. SO3 C. H2S D. SO2 Cu 7: t chy hon ton 5,4g mt amin X n chc trong lng va khng kh. Dn sn phm kh qua bnh ng nc vi trong d thu c 24g kt ta v c 41,664 lt (ktc) mt cht kh duy nht thot ra. X tc dng vi HNO2 to ra kh N2. X l A. imetylamin B. anilin C. etylamin D. metylamin Cu 8: in phn 200 ml dung dch hn hp gm HCl 0,2M v CuSO 4 1M bng in cc tr. Khi catot c 6,4 gam Cu th th tch kh thot ra anot l: A. 0,672 lt B. 1,344 lt C. 1,12 lt D. 0,896 lt Cu 9: Hn hp X gm Al, FexOy. Tin hnh phn ng nhit nhm hon ton m gam hn hp X trong iu kin khng c khng kh thu c hn hp Y. Chia Y thnh 2 phn. Phn 1 cho tc dng vi dung dch NaOH d thu c 1,008 lt H2 (ktc) v cn li 5,04g cht rn khng tan. Phn 2 c khi lng 29,79gam, cho tc dng vi dung dch HNO 3 long d thu c 8,064 lt NO (ktc, l sn phm kh duy nht). Gi tr ca m v cng thc ca oxit st l: A. 39,72 gam v FeO B. 39,72 gam v Fe3O4 C. 38,91 gam v FeO D. 36,48 gam v Fe3O4 Cu 10: Cho 6,8g mt hp cht hu c n chc tc dng va vi dung dch cha 0,3 mol AgNO3/NH3 thu c 21,6g Ag. X l: A. 2-metylbut-3-inal B. But-1-inal C. but-2-inal D. But - 3- inal Cu 11: Trn cc dung dch HCl 0,75M; HNO 3 0,15M; H2SO4 0,3M vi cc th tch bng nhau th c dung dch X. Trn 300 ml dung dch X vi 200 ml dung dch Ba(OH)2 0,25M thu c m gam kt ta v dung dch Y c pH = x. Gi tr ca x v m ln lt l A. 1 v 2,23 gam B. 1 v 6,99 gam C. 2 v 2,23 gam D. 2 v 1,165 gam Cu 12: C 6 ng nghim ng 6 dung dch long FeCl3, NH4Cl, Cu(NO3)2, FeSO4, AlCl3, (NH4)2CO3. Ch dng mt ha cht no sau y nhn bit c c 6 dung dch trn: A. Qu tm B. Dung dch AgNO3 C. Dung dch BaCl2 D. dung dch NaOH Cu 13: Ha tan ht m gam Al trong dung dch hn hp NaOH, NaNO 3 thu c 6,048 lt (ktc) hn hp kh gm NH 3 v H2 c t l mol tng ng l 4:5. Gi tr ca m l: A. 11,34 gam B. 12,96 gam C. 10,8 gam D. 13,5 gam

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2 Cu 14: Dung dch X c cha H+, Fe3+, SO4 ; dung dch Y cha Ba2+, OH-, S2-. Trn X vi Y c th xy ra bao nhiu phn ng ha hc? A. 7 B. 5 C. 8 D. 6 Cu 15: Tin hnh cc th nghim sau y, trng hp no sau y s to ra kt ta khi kt thc th nghim? A. Cho dung dch Ba(OH)2 d vo dung dch Na[Al(OH)4]. B. Cho Al vo dung dch NaOH d C. Cho dung dch AlCl3 d vo dung dch Na[Al(OH)4]. D. Cho CaC2 tc dng vi nc d c dung dch A v kh B. t chy hon ton B ri hp thu ton b sn phm chy vo dung dch A. Cu 16: Hp cht hu c X c CTPT C4H8O2 mch thng tha mn cc tnh cht sau: - X lm mt mu dung dch Br2. - 4,4 gam X tc dng vi Na d thu c 0,56 lt H2 (ktc). - Oxi ha X bi CuO, t0 to ra sn phm Y l hp cht a chc. CTCT ca X l: A. CH3-CH2-CO-CHO B. CH2=CH-CH(OH)-CH2OH C. HO-(CH2)3-CH=O D. HO-CH2-CH(CH3)-CHO Cu 17: Axit no trong s cc axit sau c tnh axit mnh nht: A. CH2F-CH2-COOH B. CH3-CF2-COOH C. CH3CHF-COOH D. CH3-CCl2-COOH Cu 18: phn bit O3 v O2 khng th dng ha cht no sau y: A. Cacbon B. Ag C. PbS D. Dung dch KI Cu 19: un nng hn hp gm etanol v butan-2-ol vi H2SO4 c th thu c ti a bao nhiu sn phm hu c? A. 5 B. 7 C. 8 D. 6 Cu 20: Dy cht no sau y gm cc cht ch c tnh oxi ha? A. Cl2, H2O2, HNO3, H2SO4. B. SO2, SO3, Br2, H2SO4. C. Fe(NO3)3, CuO, HCl, HNO3 D. O3, Fe2O3, H2SO4, O2 Cu 21: ha tan mt mu Zn trong dung dch HCl 250C cn 243 pht. Cng mu Zn tan ht trong dung dch HCl nh trn 650C cn 3 pht. ha tan ht mu Zn trong dung dch HCl c nng nh trn 450C cn thi gian bao lu: A. 9 pht B. 81 pht C. 27 pht D. 18 pht Cu 22: Hn hp X gm 2 este n chc. Cho 0,5 mol X tc dng vi dung dch AgNO3/NH3 d thu c 43,2g Ag. Cho 14,08g X tc dng vi dung dch KOH va thu c hn hp 2 mui ca 2 axit ng ng lin tip v 8,256g hn hp 2 ancol no n chc ng ng lin tip, mch h. Cng thc ca 2 ancol l: A. C4H9OH v C5H11OH B. CH3OH v C2H5OH C. C2H5OH v C3H7OH D. C3H7OH v C4H9OH Cu 23: Hp cht hu c X c cng thc phn t l C4H6O4. Thy phn X trong mi trng NaOH un nng to ra mt mui Y v mt ancol Z. t chy Y th sn phm to ra khng c nc. X l: A. HCOOCH2CH2OOCH. B. HOOCCH2COOCH3. C. HOOC-COOC2H5. D. CH3OOC-COOCH3.

Br Cu 24: Cho s : C2H4 + X + KOH / C 2 H Y + AgNO3 3 Z + HBr Y. Y l 2 / NH 5 OH ,t A. C2H6. B. C2H2. C. C2H5OH. D. C2H4. Cu 25: Kh Cl2 tc dng c vi: (1) kh H 2S; (2) dung dch FeCl2; (3) nc Brom; (4) dung dch FeCl 3; (5) dung dch KOH. A. 1, 2, 4, 5 B. 1, 2, 3, 4, 5 C. 1, 2, 5 D. 1, 2, 3, 5 Cu 26: Cho cc dung dch: FeCl3 (1); NaHSO4 (2); NaHCO3 (3); K2S (4); NH4Cl (5); AlCl3 (6); CH3COONa (7). Cc dung dch c pH < 7 l: A. 1, 2, 5, 6 B. 1, 2, 6 C. 1, 2 D. 1, 2, 3, 5, 6 Cu 27: Hn hp A gm C3H4 v H2. Cho A i qua ng ng bt Ni nung nng thu c hn hp B ch gm 3 hirocacbon c t khi so vi H2 l 21,5. T khi ca A so vi H2 l: A. 10,4 B. 9,2 C. 7,2 D. 8,6 2+ + Cu 28: Trn dung dch cha Ba ; Na : 0,04 mol; OH : 0,2 mol; vi dung dch cha K+; HCO3-: 0,06 mol; CO32-: 0,05 mol thu c m gam kt ta. Gi tr ca m l: A. 15,76 gam B. 13,97 gam C. 19,7 gam D. 21,67 gam Cu 29: Ha tan 54,44 gam hn hp X gm PCl3 v PBr3 vo nc c dung dch Y. trung ha hon ton dung dch Y cn 500 ml dung dch KOH 2,6M. % khi lng ca PCl3 trong X l: A. 26,96% B. 12,125 C. 8,08% D. 30,31%
0

Page 10 of 17

Cu 30: X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam hn hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton c cn dung dch thu c 257,36g cht rn khan. Gi tr ca m l: A. 150,88 gam B. 155,44 gam C. 167,38 gam D. 212,12 gam Cu 31: Nhit phn 50,56 gam KMnO4 sau mt thi gian thu c 46,72 gam cht rn. Cho ton b lng kh sinh ra phn ng ht vi hn hp X gm Mg, Fe thu c hn hp Y nng 13,04 gam. Ha tan hon ton hn hp Y trong dung dch H2SO4 c, nng d thu c 1,344 lt SO2 (ktc). % khi lng Mg trong X l: A. 52,17% B. 39,13% C. 28,15% D. 46,15% Cu 32: Hn hp X gm 1 ankan v 1 anken. Cho X tc dng vi 4,704 lt H2 (ktc) cho n phn ng hon ton thu c hn hp Y gm 2 kh trong c H2 d v 1 hirocacbon. t chy hon ton Y ri cho sn phm vo nc vi trong d thy khi lng bnh ng nc vi trong tng 16,2 gam v c 18 gam kt ta to thnh. Cng thc ca 2 hirocacbon l: A. C2H6 v C2H4 B. C2H8 v C3H6 C. C4H10 v C4H8 D. C5H10 v C5H12 Cu 33: Trng hp no sau y khng tha mn quy tc bt t: A. NH3, HCl B. CO2, SO2 C. PCl5, SF6 D. N2, CO Cu 34: Mt ancol no, a chc X c s nhm OH bng s nguyn t cacbon. Trong X, H chim xp x 10% v khi lng. un nng X vi cht xc tc nhit thch hp loi nc th thu c mt cht hu c Y c M Y = MX 18. Kt lun no sau y hp l nht: A. T khi hi ca Y so vi X l 0,8 B. X l glixerol C. Y l anehit acrylic D. Y l etanal Cu 35: Mt hn hp kim loi gm: Zn, Ag, Fe, Cu. Ha cht c th ha tan hon ton hn hp kim loi trn l: A. Dung dch NaOH c B. Dung dch HCl c, d C. Dung dch HNO3 long, d D. Dung dch H2SO4 c, ngui, d Cu 36: Cho cc phn ng ha hc: (1) C2H5OH + H2SO4 c C2H5OSO3H + H2O 0 (2) C2H5OH H 2 SO4 dac ,170 C2H4 + H2O C (3) C2H5OH + CH3COOH CH3COOC2H5 + H2O 0 (4) C2H5Br + NaOH t C2H5OH + NaBr (5) C2H4 + H2O H C2H5OH Cc phn ng th l A. 1, 4 B. 1, 4, 5 C. 1, 3, 4 D. 4 Cu 37: Cho 200 ml dung dch KOH 0,9M; Ba(OH)2 0,2M vo 100 ml dung dch H2SO4 0,3M v Al2(SO4)3 0,3M. Sau khi cc phn ng xy ra hon ton, khi lng kt ta thu c l: A. 9,32 gam B. 10,88 gam C. 14 gam D. 12,44 gam Cu 38: Phn ng no sau y mch polime c gi nguyn? o + o A. PVA + NaOH t B. Xenluloz + H2O H ,t C. PS t D. Nha Rezol t Cu 39: t chy hon ton 18 gam mt este X n chc thu c 20,16 lt CO 2 (ktc) v 12,96 gam nc. Mt khc nu cho 21g X tc dng vi 200ml dung dch KOH 1,2M sau c cn dung dch thu c 34,44 gam cht rn khan. Cng thc phn ca axit to ra X l : A. C5H6O3. B. C5H8O3. C. C5H10O3 D. C5H10O2. Cu 40: Ha tan hon ton hn hp gm 0,18 mol FeS2 v a mol Cu2S bng dung dch HNO3 va thu c dung dch X ch cha mui sunfat v V lt NO (ktc) l sn phm kh duy nht. Gi tr ca V l A. 44,8 lt B. 22,4 lt C. 26,88 lt D. 33,6 lt II. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh Chun (t cu 41 n cu 50) Cu 41: Khi in phn dung dch no sau y ti catot xy ra qu trnh kh nc? A. Dung dch ZnCl2. B. Dung dch CuCl2 C. dung dch AgNO3. D. Dung dch MgCl2. Cu 42: phn bit SO2, CO2 v SO3 c th dng: A. Dung dch BaCl2 v dung dch Br2 B. Dung dch Ba(OH)2, dung dch thuc tm C. Dung dch Br2, nc vi trong. D. Dung dch BaCl2 v nc vi trong Cu 43: Pb tan d dng trong dung dch no sau y? A. Dung dch H2SO4 m c B. Dung dch HNO3 c C. Dung dch HCl long D. Dung dch H2SO4 long
o o +

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Cu 44: Dung dch X cha cc ion : Ba2+, Na+, HCO3-, Cl- trong s mol Cl- l 0,24. Cho dung dch X tc dng vi dung dch NaOH d thu c 9,85g kt ta. Cho dung dch X tc dng vi dung dch Ba(OH) 2 d thu c 15,76g kt ta. Nu un si dung dch X n cn th thu c m gam cht rn khan. Gi tr ca m l A. 15,81 B. 18,29. C. 31,62 D. 36,58 Cu 45: Cht c dng ty trng nc ng trong qu trnh sn ng saccaroz t cy ma l: A. nc gia-ven B. SO2. C. Cl2. D. CaOCl2. Cu 46: t chy hon ton 0,12 mol mt amin no, mch h X bng oxi va thu c 0,6 mol hn hp kh v hi. Cho 9,2 gam X tc dng vi dung dch HCl d th s mol HCl phn ng l: A. 0,4 B. 0,3 C. 0,1 D. 0,2 Cu 47: Hn hp M gm 2 axit cacboxylic u no, mch h A, B (B hn A mt nhm chc). Ha hi hon ton m gam M thu c th tch hi bng th tch ca 7 gam nit o cng iu kin nhit , p sut. Nu cho m gam M tc dng vi Na d thu c 4,48 lt H2 (ktc). Khi t chy hon ton m gam M thu c 28,6g CO2. Cng thc phn t ca A v B l: A. C2H4O2 v C3H4O4. B. CH2O2 v C3H4O4 . C. C2H4O2 v C4H6O4 D. CH2O2 v C4H6O2. Cu 48: Hn hp X gm Cu, Fe, Mg. Nu cho 10,88 gam X tc dng vi clo d th sau phn ng thu c 28,275g hn hp mui khan. Mt khc 0,44 mol X tc dng vi dung dch HCl d th thu c 5,376 lt H 2 (ktc). % khi lng ca Cu trong X l A. 67,92% B. 58,82% C. 37,23% D. 43,52% Cu 49: Oxi ha 16,8g anehit fomic bng oxi c mt Mn 2+ thu c hn hp X. Cho hn hp X tc dng vi dung dch AgNO3/NH3 d thu c 151,2g Ag. Hiu sut ca phn ng oxi ha anehit fomic l: A. 37,5% B. 80% C. 60% D. 75% Cu 50: Dy no sau y gm cc polime nhn to? A. T visco, t axetat, xenluloz trinitrat B. Xenluloz, tinh bt, t tm C. T lapsan, PVA, thy tinh hu c. D. T nilo-6,6; bng, tinh bt, t capron Phn II: Theo chng trnh nng cao (t cu 51 n cu 60) Cu 51: Cho 6,85 gam Ba kim loi vo 150ml dung dch CrSO 4 0,3M trong khng kh n phn ng hon ton thu c m gam kt ta. Gi tr ca m l: A. 14,09 gam B. 10,485gam C. 3,87 gam D. 14,355 gam Cu 52: Cho cc cht CH3 -CHCl2; ClCH=CHCl; CH2=CH-CH2Cl, CH2Br-CHBr-CH3; CH3-CHCl-CHCl-CH3; CH2BrCH2-CH2Br. S cht khi tc dng vi dung dch NaOH long un nng to ra sn phm c kh nng phn ng vi Cu(OH)2 l: A. 5 B. 4 C. 2 D. 3 0 0 Cu 53: Cho sut in ng chun ca 1 s pin in ha sau: E X-Cu = 0,78V; E Y-Cu = 2,0V; E0Cu-Z = 0,46V. Th t cc kim loi theo chiu gim dn tnh kh l: A. X,Y, Z, Cu B. X, Y, Cu, Z C. Y, X, Cu, Z D. Z, Cu, X, Y Cu 54: Kh no sau y l nguyn nhn gy hiu ng nh knh? A. NO B. CO2. C. SO2. D. CO

Cu 55: Cho s : Propilen A B D. D l: A. CH3CH2CH2OH B. CH3C(OH)(CH3)CN C. CH3CH(OH)CH3. D. CH3CH2CH(OH)CN Cu 56: Dung dch X cha 0,01 mol ClH3N-CH2-COOH, 0,02 mol CH3-CH(NH2)COOH; 0,05 mol HCOOC6H5. Cho dung dch X tc dng vi 160 ml dung dch KOH 1M un nng phn ng xy ra hon ton. C cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l A. 16,335 gam B. 8,615 gam C. 12,535 gam D. 14,515 gam Cu 57: Cho t t n d dung dch NH3 ln lt vo cc dung dch sau: CuCl 2, AlCl3, Fe(NO3)3, NiSO4, AgNO3, MgSO4. Sau khi cc phn ng xy ra hon ton, s kt ta thu c l: A. 2 B. 4 C. 5 D. 3 Cu 58: Dy no sau y gm cc polime c cu trc mch phn nhnh? A. T nilon-6,6; t lapsan, t olon B. Nha rezol, cao su lu ha C. Cao su Buna-S, xenluloz, PS D. Amilopectin, glicogen Cu 59: Dung dch X gm NH3 0,1M; NH4Cl 0,1M. pH ca dung dch X c gi tr l: (cho Kb ca NH3 l 1,75.10-5) A. 9,24 B. 4,76 C. 8,8 D. 9,42 Cu 60: Trung ha ht 10,36 gam axit hu c n chc bng dung dch Ba(OH) 2 va thu c 19,81 gam mui khan. Xc nh cng thc ca axit? A. CH3COOH B. C2H3COOH C. C3H5COOH D. C2H5COOH
+ HCN

+ H 2O , H +

+ CuO, t o

Page 12 of 17

TRNG THPT CHUYN NGUYN HU

THI TH AI HOC LN TH IV NM HOC 2010 - 2011 MN: HOA - KHI A, B Thi gian lm bi: 90 pht; ( co 4 trang, gm 60 cu trc nghim) M thi 132

Cu 1: t chy hon ton 80,08 gam hn hp X gm C 3H7OH, C2H5OH v CH3OC3H7 thu c 95,76 gam H2O v V lt kh CO2 (ktc). Gi tr ca V l? A. 129,6 lt B. 87,808 lt C. 119,168 lt D. 112 lt Cu 2: Trng bc hon ton 5,72g mt anehit X no n chc, mch h. Ton b lng bc thu c em ho tan ht vo dung dch HNO3 c nng gii phng V lt kh NO2 (sn phm kh duy nht). Sau phn ng khi lng dung dch thay i 16,12g (gi s hi nc bay hi khng ng k). Cng thc cu to thu gn ca X l: A. CH3CHO B. HCHO C. C2H5CHO D. C3H7CHO Cu 3: X c cng thc phn t l C8H10O. X tc dng c vi NaOH. X tc dng vi dd brom cho Y c cng thc phn t l C8H8OBr2. Hy cho bit X c bao nhiu cng thc cu to tha mn ? A. 6 B. 5 C. 4 D. 3 Cu 4: t chy 1,6 gam mt este E n chc c 3,52 gam CO2 v 1,152 gam H2O. Nu cho 10 gam E tc dng vi 150ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 11,6 gam cht rn khan. Vy cng thc ca axit to nn este trn c th l: A. CH2=CH-COOH B. CH2=C(CH3)-COOH C. HOOC(CH2)3CH2OH D. CH3CH2-COOH Cu 5: Mt loi nc cng c cha Ca 2+ 0,002M ; Mg2+ 0,003M v HCO-3. Hy cho bit cn ly bao nhiu ml dd Ca(OH)2 0,05M bin 1 lt nc cng thnh nc mm (coi nh cc phn ng xy ra hon ton v kt ta thu c gm CaCO3 v Mg(OH)2). A. 200 ml B. 140 ml C. 100 ml D. 160 ml Cu 6: Trong s cc cht toluen, benzen, Propilen, propanal, butanon, phenol, ancol anlylic, ivinyl, xiclobutan, stiren, metylxiclopropan. C bao nhiu cht lm mt mu dung dch Brom? A. 7 B. 8 C. 9 D. 6 Cu 7: Cho 43,6 gam cht hu c X mch h ch cha mt loi nhm chc tc dng vi 2 lt dung dch NaOH 0,5M thu c 49,2 gam mui v 0,2 mol ancol. Lng NaOH d c trung ho va ht bi 0,5 lt dung dch HCl 0,8M. Cng thc cu to ca X l: A. (CH3COO)2C2H4. B. C3H5(COOCH3)3. C. (HCOO)3C3H5. D. (CH3COO)3C3H5. Cu 8: C dung dch X gm (KI v mt t h tinh bt). Cho ln lt tng cht sau: O3, Cl2, S, H2O2, FeCl3, AgNO3 tc dng vi dung dch X. S cht lm dung dch X chuyn sang mu xanh l: A. 4 cht B. 2 cht C. 3 cht D. 5 cht Cu 9: Cht X c cng thc phn t C3H5Br3, un X vi dung dch NaOH thu c cht hu c Y c kh nng tc dng vi Cu(OH)2. S cu to X tha mn l: A. 4 B. 2 C. 3 D. 5 Cu 10: Cho hn hp X gm 12 gam Fe2O3 v 13 gam Cu vo 200 ml dung dch HCl thy cn li 14,92 gam cht rn khng tan. Xc nh nng mol/l ca dung dch HCl. A. 2,15M B. 1,89M C. 1,35M D. 0,7875M Cu 11: Hn hp X gm 2 cht hu c A, B ch cha mt loi nhm chc. Cho m gam X tc dng ht vi NaOH thu c mt mui ca axit hu c n chc v hn hp 2 ancol, tch nc hon ton hai ancol ny iu kin thch hp ch thu c mt anken lm mt mu va 24 gam Br2. Bit A, B cha khng qu 4 nguyn t cacbon trong phn t. Gi tr ca m l : A. 22,2 g B. 11,1 g C. 13,2 g D. 26,4 g Cu 12: Pht biu no sau y l ng: A. Photpho trng c cu trc mng tinh th nguyn t, photpho c cu trc polime B. Nitrophotka l hn hp ca NH4H2PO4 v KNO3 C. Thy tinh lng l dung dch m c ca Na2SiO3 v K2SiO3 D. Cacbon monooxit v silic ioxit l oxit axit Cu 13: Cho s phn ng sau: X + H2SO4 (c, nng) Fe2(SO4)3 + SO2 + H2O S cht X trong chng trnh ph thng c th thc hin phn ng trn l: A. 7. B. 6. C. 5. D. 4. Cu 14: Nhit phn nhng mui no sau y thu c cht rn u l oxit kim loi ? A. MgSO4, KNO3, CaCO3 B. Cu(NO3)2, KClO, KMnO4 C. CuSO3, Fe(NO3)2, (NH4)2Cr2O7 D. BaCO3, CuCO3, AgNO3

Page 13 of 17

Cu 15: Cho a gam Na vo 160 ml dung dch gm Fe2(SO4)3 0,125M v Al2(SO4)3 0,25M. Tch kt ta ri nung n khi lng khng i th thu c 5,24 gam cht rn. Gi tr a no sau y l ph hp? A. 5,25. B. 9,2. C. 5,98. D. 9,43. Cu 16: Cho 6,23 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 210 ml dung dch KOH 0,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 9,87 gam cht rn. Cng thc cu to thu gn ca X l A. H2NCH2CH2COOH B. H2NCH2COOCH3 C. HCOOH3NCH=CH2 D. CH2=CHCOONH4 Cu 17: Cho cc cht sau: C2H5OH, C6H5OH, C2H5NH2, dung dch C6H5NH3Cl, dung dch NaOH, CH3COOH, dung dch HCl long. Cho tng cp cht tc dng vi nhau c xc tc, s cp cht c phn ng xy ra l: A. 10 B. 11 C. 9 D. 8 Cu 18: C cc s phn ng to ra cc kh nh sau: t0 MnO2 + HClc kh X + ; KClO3 kh Y + ; MnO
2

t NH4Cl(r) + NaNO2(r) kh Z + ; FeS + HCl kh M + ...; Cho cc kh X, Y, Z , M tip xc vi nhau (tng i mt) iu kin thch hp th s cp cht c phn ng l: A. 5. B. 2. C. 4. D. 3. Cu 19: Pht biu no sau y ng? A. Cht git ra l nhng cht khi dng cng vi nc th c tc dng lm sch cc cht bn bm trn cc vt rn m khng gy ra phn ng ho hc vi cc cht bn. B. Cht git ra tng hp c u im l dng c vi nc cng v chng t b kt ta bi ion Ca2+ v Mg2+ C. Cht git ra l nhng cht c tc dng ging nh x phng nhng c tng hp t du m. D. Cht git ra tng hp c cha gc hirocacbon phn nhnh khng gy nhim mi trng v chng b cc vi sinh vt phn hu. Cu 20: A l hn hp cc mui Cu(NO3)2, Fe(NO3)2, Fe(NO3)3, Mg(NO3)2. Trong O chim 55,68% v khi lng. Cho dung dch KOH d vo dung dch cha 50 gam mui, lc kt ta thu c em nung trong chn khng n khi lng khng i thu c m gam oxit. Gi tr ca m l: A. 12,88 B. 23,32 C. 18,68 D. 31,44 Cu 21: Khi cracking hon ton 3,08g propan thu c hn hp kh X. Cho X sc chm vo 250 ml dung dch Br 2 thy dung dch Br2 mt mu hon ton v cn li V lt kh ktc v c t khi so vi CH4 l 1,25. Nng mol Br2 v V c gi tr l A. 0,14 M v 2,352 lt B. 0,04 M v 1,568 lt C. 0,04 M v 1,344 lt D. 0,14 M v 1,344 lt Cu 22: Hiro ha hon ton hirocacbon khng no, mch h X thu c isopentan. Hy cho bit c bao nhiu hirocacbon tha mn? A. 6 B. 8 C. 7 D. 9 Cu 23: A l hn hp kh gm SO2 v CO2 c t khi hi so vi H2 l 27. Dn a mol hn hp kh A qua bnh ng 1 lt dung dch KOH 1,5a M, sau phn ng c cn dung dch thu c m gam mui. Biu thc lin h gia m v a l: A. m=203a B. m=193,5a C. m=129a D. m=184a Cu 24: Cho phn ng : 3H2(kh) + Fe2O3 (rn) 2Fe + 3H2O (hi) Nhn nh no sau y l ng? A. Thm Fe2O3 cn bng ha hc chuyn dch theo chiu thun B. Nghin nh Fe2O3 cn bng ha hc chuyn dch theo chiu thun C. Thm H2 vo h cn bng ha hc chuyn dch theo chiu thun D. Tng p sut cn bng ha hc chuyn dch theo chiu thun Cu 25: Dy no sau y gm cc cht u c lin kt cho nhn (theo bt t): A. NaNO3, K2CO3, HClO3, P2O5. B. NH4Cl, SO2, HNO3, CO. C. KClO4, HClO, SO3, CO. D. NH4NO3, CO2, H2SO4, SO3. Cu 26: Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca mt nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 6 ht. Hp cht ca X, Y c dng: A. X2Y. B. XY2. C. X2Y3. D. X3Y2. Cu 27: Cho mt s tnh cht: C cu trc polime dng mch nhnh (1); tan trong nc (2); to vi dung dch I 2 mu xanh (3); to dung dch keo khi un nng (4); phn ng vi dung dch H2SO4 long (5); tham gia phn ng trng bc (6). Cc tnh cht ca tinh bt l A. (1); (3); (4) v (6) B. (3); (4) ;(5) v (6) C. (1); (2); (3) v (4) D. (1); (3); (4) v (5) Cu 28: Phn ng no sau y khng thuc phn ng t oxi ho kh ? A. 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O B. 4KClO3 KCl + 3KClO4 C. 2Na2O2+ 2H2O 4NaOH + O2 D. Fe3O4 + 4H2SO4 Fe2(SO4)3 + FeSO4 + 4H2O Cu 29: Cho cc cht sau: axit glutamic, valin, lysin, alanin, trimetylamin, anilin, metylamoni clorua, phenylamoni clorua. S cht lm qu tm chuyn mu , mu xanh, khng i mu ln lt l:

t0

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A. 3, 2, 3. B. 2, 2, 4. C. 3, 1, 4. D. 1, 3, 4. Cu 30: Ly 8,76 g mt ipeptit to ra t glyxin v alanin cho tc dng va vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng l: A. 0,12 lt B. 0,24 lt C. 0,06 lt D. 0,1 lt Cu 31: Phn ng no sau y c phng trnh ion rt gn HCO3- + OH- CO32- + H2O ? A. NaHCO3 + HCl NaCl + CO2 + H2O B. 2NaHCO3 + 2KOH Na2CO3 + K2CO3 + 2H2O C. 2NaHCO3 + Ca(OH)2 CaCO3 + Na2CO3 + 2H2O D. Ca(HCO3)2 + Ca(OH)2 CaCO3 + 2H2O Cu 32: Thy phn 68,4 gam saccaroz vi hiu sut 60%. Dung dnh sau phn ng chia thnh hai phn bng nhau. Phn I tc dng vi dung dch AgNO3 trong NH3 d thu c x mol Ag. Phn II lm mt mu va dung dch cha y mol brom. Gi tr ca x, y ln lt l A. 0,24; 0,06. B. 0,12; 0,06. C. 0,32; 0,1. D. 0,48; 0,12. Cu 33: in phn dung dch CuSO4 a mol v NaCl b mol. Khi mu xanh ca dung dch va mt, ngi ta thu c dung dch c mi trng trung tnh. Thit lp mi quan h gia a v b. A. b = 2a B. b = 0,5a C. b a D. b 2a Cu 34: Hiro ha hon ton anehit X thu c ancol Y. t chy hon ton Y thu c CO2 v H2O theo t l nCO2 : nH2O = 2 : 3 v s mol O2 t chy gp 2,5 ln s mol X t chy. Khi cho 0,1 mol X tc dng vi AgNO 3 trong dung dch NH3 d thu c ti a bao nhiu gam Ag? A. 10,8 gam B. 43,2 gam C. 21,6 gam D. 32,4 gam Cu 35: C 6 dung dch ng ring bit trong 6 ng nghim (NH 4)2SO4, FeCl2, Cr(NO3)3, K2CO3, NaHSO3 Al(NO3)3. Cho Ba(OH)2 n d vo 5 dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l: A. 5 B. 4 C. 3 D. 2 Cu 36: Dng mui it hng ngy phng nga dch bnh bu c. Mui it l A. I2 + NaCl B. NaCl + NaI C. NaCl + KI + KIO3 D. NaI3 + NaCl Cu 37: Cht hu c X c t khi hi so vi metan bng 4,625. Khi t chy X thu c s mol H2O bng s mol X chy, cn s mol CO2 bng 2 ln s mol nc. X tc dng c vi Na, NaOH v AgNO3 trong dung dch NH3 sinh ra Ag. Cng thc cu to ca X l A. HOCH2CH2CHO B. C2H5COOH C. HCOOCH2CH3 D. HOOC-CHO Cu 38: Cho phn ng oxi ha-kh sau : FeCl2 + KMnO4 + H2SO4 .. Vy cc cht sn phm l : (chn phng n ng nht) A. Fe2(SO4)3, MnSO4 , K2SO4, Cl2, H2O B. Fe2(SO4)3, MnSO4 , K2SO4, HCl, H2O C. FeSO4, MnSO4 , K2SO4, FeCl3, H2O D. FeCl3, Fe2(SO4)3, MnSO4 , K2SO4, H2O Cu 39: Cho a gam bt Al vo dung dch cha 0,1 mol AgNO 3 ; 0,15 mol Cu(NO3)2 v 0,2 mol Fe(NO3)3 thu c dung dch X v kt ta Y. Hy la chn gi tr ca a kt ta Y thu c cha 3 kim loi. A. a 3,6 gam B. 2,7 gam < a < 5,4 gam. C. 3,6 gam < a 9 gam D. 5,4 gam < a 9 gam Cu 40: Cho m gam mi cht vo trong bnh c dung tch khng i, ri nung cho n khi phn ng xy ra hon ton v sau u a v 273oC, c p sut bnh l P. Cht no sau y cho ra gi tr P ln nht ? A. AgNO3 B. KClO3 (xt: MnO2) C. KMnO4 D. KNO3 B. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh c bn. Cu 41: Hy cho bit anot trong pin in v anot trong bnh in phn xy ra qu trnh g ? A. pin in : qu trnh oxi ha v bnh in phn : qu trnh kh. B. ti pin in v bnh in phn u xy ra qu trnh oxi ha. C. ti pin in v bnh in phn u xy ra qu trnh kh. D. pin in : qu trnh kh v bnh in phn: qu trnh oxi ha. Cu 42: Hn hp X gm Al2O3, MgO, Fe3O4, CuO. Cho kh CO d qua X nung nng c cht rn Y . Ha Y vo dung dch NaOH d c dung dch E v cht rn G. Ha tan cht rn G vo dd Cu(NO3)2 d thu c cht rn F. Xc nh thnh phn ca cht rn F. A. Cu, MgO. B. Cu C. Cu, Al2O3, MgO. D. Cu, MgO, Fe3O4 Cu 43: Ho tan hon ton 21,1gam hn hp gm FeCl2 v NaF (c t l mol l 1:2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l: A. 39,5g B. 28,7g C. 57,9g D. 68,7g Cu 44: Tch s ion ca nc mt s nhit nh sau: 200C l 7,00.10-15, 250C l 1,00.10-14, 300C l 1,50.10-14. S in ly ca nc l A. khng xc nh ta nhit hay thu nhit B. ta nhit C. ta nhit hay thu nhit ty theo iu kin phn ng D. thu nhit

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Cu 45: Nhng cht l th phm chnh gy ra cc hin tng: hiu ng nh knh; ma axit; thng tng ozon (l cc nguyn nhn ca s bin i kh hu ton cu) tng ng ln lt l: A. CO2 - SO2 , N2 - CFC (freon: CF2Cl2 , CFCl3). B. N2 , CH4 - CO2, H2S - CFC (freon: CF2Cl2 , CFCl3). C. CO2 - SO2 , NO2 - CFC (freon: CF2Cl2 , CFCl3) D.CFC (freon: CF2Cl2 , CFCl3) - CO, CO2 - SO2, H2S. Cu 46: Oxi ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 8) gam hn hp Y gm hai axit. em t chy ht hn hp Y cn va 29,12 lt O2 ( ktc). Gi tr m l: A. 18,47 B. 22,47 C. 24,8 D. 26,2 Cu 47: Trong hp cht sau y c my lin kt peptit? H2N-CH2-CO-NH-CH-CO-NH-CH-CO-NH-CH2-CH2-CO-HN-CH2-COOH CH3 C6H5 A. 1. B. 2. C. 4. D. 3. Cu 48: X l este to bi -amino axit Y (cha 1 nhm -COOH v 1 nhm -NH2) vi ancol n chc Z. Thy phn hon ton 0,1 mol X trong 200 ml dung dch NaOH 1M, c cn dung dch thu c 13,7 gam cht rn v 4,6 gam ancol Z. Vy cng thc ca X l: A. CH3-CH(NH2)-COOC2H5 B. CH3-CH(NH2)-COOCH3 C. H2N-CH2-COOC2H5 D. H2N-CH2-COOCH2-CH=CH2 Cu 49: T toluen mun iu ch o-nitrobenzoic ngi ta thc hin theo s sau C6H5CH3 _____ + X(xt, t0) ( A ) _____+Y(xt, t0) o-O2N-C6H4-COOH X, Y ln lt l: A. KMnO4 v HNO3 B. HNO3 v H2SO4 C. HNO3 v KMnO4 D. KMnO4 v NaNO2 Cu 50: Cho cc cht sau y: 1) CH3COOH, 2) C2H5OH, 3) C2H2, 4) CH3COONa, 5) HCOOCH=CH2, 6) CH3COONH4, 7) C2H4. Dy gm cc cht no sau y u c to ra t CH3CHO bng mt phng trnh phn ng l: A. 1, 2, 4, 6. B. 1, 2, 6. C. 1, 2, 3, 6, 7 D. 2, 3, 5, 7. Phn II: Theo chng trnh nng cao Cu 51: S tripeptit ti a to ra c c glyxin, alanin v valin l: A. 3 B. 6 C. 5 D. 4 Cu 52: Cho 18,45 gam hn hp bt Mg, Al, Fe vo dung dch AgNO3 d thu c m gam cht rn. Cho NH3 d vo dung dch sau phn ng, lc kt ta ri em nhit phn trong iu kin khng c khng kh n khi lng khng i th thu c 29,65 gam cht rn Y. Gi tr ca m l: A. 75,6. B. 48,6. C. 151,2. D. 135,0. Cu 53: Xt phn ng thun nghch sau: SO2(k) + NO2(k) SO3(k) + NO(k). Cho 0,11(mol) SO2, 0,1(mol) NO2, 0,07(mol) SO3 vo bnh kn 1 lt. Khi t cn bng ha hc th cn li 0,02(mol) NO2. Vy hng s cn bng KC l A. 18 B. 0,05 C. 23 D. 20 Cu 54: Kh hon ton m gam Fe2O3 cn 5,376 lt CO (ktc). Mt khc cho m gam Fe2O3 tc dng va vi dung dch HI 0,3M thu c dung dch X. Nng ion I- c trong dung dch X l: A. 0,2M B. 0,05M C. 0,1M D. 0,3M
H 3O HCN CH3CHO X Y. Cng thc cu to ca X, Y ln lt l: t0 A. CH3CH2CN, CH3CH2COOH. B. OHCCH2CN, OHCCH2COOH C. CH3CH(OH)CN, CH3CH(OH)COOH. D. CH3CN, CH3COOH. Cu 56: Cho cc cht sau : axetilen, etilen, but-1-in, axit fomic, fomanehit, phenyl fomat, glucoz, anehit axetic, metyl axetat, mantoz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l A. 7 B. 8 C. 9 D. 6 Cu 57: Cho NH3 d vo ln lt cc dung dch sau: CrCl 3, CuCl2, ZnCl2, AgNO3, NiCl2. S trng hp kt ta hnh thnh ri b tan l: A. 3. B. 4. C. 5. D. 1. Cu 58: Mui A c cng thc l C3H10O3N2, ly 7,32 gam A phn ng ht vi 150ml dd KOH 0,5M. C cn dd sau phn ng th c phn hi v phn cht rn, trong phn hi c 1 cht hu c bc 3, trong phn rn ch l cht v c. Khi lng cht rn l: A. 6,90 g. B. 6,06 g. C. 11,52 g. D. 9,42 g. Cu 59: Cn ti thiu bao nhiu gam NaOH (m1) v Cl2 (m2) phn ng hon ton vi 0,01 mol CrCl3. Gi tr ca m1 v m2 ln lt l: A. 6,4 v 1,065 B. 3,2 v 0,5325 C. 6,4 v 0,5325 D. 3,2 v 1,065 Cu 60: Pht biu no sau y l ng ? A. Phn ng gia buta-1,3-ien vi acrilonitrin l phn ng trng ngng B. T axetat l t tng hp C. Trng hp isopren to ra sn phm thuc cht do D. T lapsan l mt polieste---------------------------------------------------- HT ----------

Cu 55: Cho s chuyn ha:

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P N M 132 LN 1 1C, 2C, 3B, 4B, 5D, 6B, 7D, 8C, 9C, 10B, 11B, 12B, 13C, 14B, 15C, 16D, 17A, 18D, 19A, 20C, 21A, 22A, 23A, 24B, 25D, 26A, 27A, 28D, 29A, 30B, 31B, 32C, 33B, 34C, 35A, 36D, 37C, 38C, 39D, 40C, 41B, 42A, 43D, 44B, 45C, 46C, 47A, 48D, 49D, 50A, 51A, 52D, 53D, 54B, 55D, 56D, 57A, 58C, 59A, 60B. P N M 357 LN 2 1C, 2B, 3A, 4C, 5B, 6C, 7A, 8C, 9B, 10A, 11A, 12C, 13D, 14B, 15B, 16B, 17C, 18A, 19D, 20C, 21D, 22C, 23B, 24A, 25B, 26A, 27C, 28D, 29A, 30C, 31A, 32B, 33B, 34B, 35C, 36D, 37B, 38B, 39A, 40D, 41A, 42D, 43A, 44D, 45B, 46D, 47D, 48C, 49D, 50A, 51D, 52C, 53D, 54 D, 55C, 56C, 57A, 58D, 59B, 60A. P N M 896 LN 3 1C, 2B, 3C, 4B, 5C, 6B, 7C, 8B, 9B, 10D, 11B, 12D, 13A, 14A, 15C, 16C, 17B, 18A, 19B, 20D, 21C, 22C, 23D, 24B, 25D, 26A, 27D, 28A, 29D, 30B, 31B, 32A, 33C, 34D, 35C, 36C, 37D, 38A, 39C, 40C, 41D, 42A, 43A, 44C, 45B, 46A, 47A, 48B, 49D, 50A, 51A, 52D, 53C, 54B, 55B, 56A, 57D, 58D, 59A, 60D. P N M 132 LN 4 1B, 2A, 3B, 4D, 5D, 6A, 7D, 8A, 9C, 10C, 11B, 12C, 13A, 14C, 15B, 16B, 17D, 18D, 19B, 20C, 21A, 22C, 23C, 24C, 25B, 26C, 27D, 28D, 29A, 30A, 31B, 32A, 33D, 34B, 35B, 36C, 37D, 38A, 39D, 40B, 41B, 42A, 43A, 44D, 45C, 46C, 47B, 48C, 49C, 50A, 51B, 52C, 53D, 54A, 55C, 56A, 57B, 58A, 59D, 60D. SU TM: V PHN ( http://violet.vn/vuphan62hn/ )

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