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THI TH I HC LN I - 2011
MN HA HC
Thi gian lm bi: 90 pht;
(60 cu trc nghim)
M thi 132

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Al = 27; S = 32; Cl = 35,5; Fe = 56; Cu = 64; Rb = 85,5; K=39;
Li =7 ; Zn = 65 ; Ag = 108, Ba = 137
I. Phn chung cho tt c cc th sinh( 40 cu, t cu 1 n cu 40)
Cu 1: Phenol phn ng c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br2, (CH3CO)2O, CH3COOH, Na,
NaHCO3, CH3COCl:
A. 4
B. 6
C. 5
D. 7
Cu 2: Kh 1,6 gam hn hp 2 anehit no bng H2 thu c hn hp 2 ancol. un nng hn hp 2 ancol vi H2SO4 c
c hn hp 2 olefin l ng ng lin tip. t chy ht 2 olefin ny c 3,52 gam CO2. Cc phn ng xy ra hon
ton. Cng thc ca 2 anehit l:
A. HCHO v CH3CHO
B. CH3CHO v CH2(CHO)2
C. CH3CHO v C2H5CHO
D. C2H5CHO v C3H7CHO
Cu 3: Oxi ha 3,16 gam hn hp 2 ancol n chc thnh anehit bng CuO, t 0, sau phn ng thy khi lng cht rn
gim 1,44 gam. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO 3/NH3 thu c 36,72 gam Ag.
Hai ancol l:
A. C2H5OH v C3H7CH2OH
B. CH3OH v C2H5CH2OH
C. CH3OH v C2H5OH
D. C2H5OH v C2H5CH2OH
Cu 4: Trung ha 28 gam mt cht bo cn dng 20 ml dung dch NaOH 0,175M. Ch s axit ca cht bo l:
A. 9
B. 7
C. 8
D. 6
+
2+
Cu 5: Cho dung dch X gm 0,09 mol Na ; 0,05 mol Ca ; 0,08 mol Cl ; 0,1 mol HCO3-; 0,01 mol NO3-. loi b ht
ion Ca2+ trong X cn dng 1 lng va dung dch cha a gam Ca(OH)2. Gi tr ca a l:
A. 2,96
B. 4,44
C. 7,4
D. 3,7
Cu 6: Cho cc cht sau: CH3COOH (1), C2H5OH (2), C2H6 (3), C2H5Cl (4). Th t cc cht tng dn nhit si l:
A. 4, 3, 2, 1
B. 3, 4, 2, 1
C. 1, 2, 3, 4
D. 4, 3, 1, 2
Cu 7: Thy phn hon ton 500 gam protein X thu c 14,85 gam glyxin. S mt xch glyxin trong X l (bit phn t
khi ca X l 50.000):
A. 201
B. 189
C. 200
D. 198
Cu 8: Cho kh H2S tc dng vi cc cht: dung dch NaOH, kh clo, nc clo, dung dch KMnO 4/H+, kh oxi d un
nng, dung dch FeCl3, dung dch ZnCl2. S trng hp xy ra phn ng v s trng hp trong lu hunh b oxi ha
ln S+6 l:
A. 7 - 2
B. 6 - 3
C. 6 -1
D. 6 -2
Cu 9: C bao nhiu cht c th phn ng vi axit fomic trong s cc cht sau: KOH, NH3, CaO, Mg, Cu, Na2CO3,
Na2SO4, CH3OH, C6H5OH, AgNO3/NH3?
A. 8
B. 9
C. 7
D. 6
Cu 10: Nung 8,42g hn hp X gm Al, Mg, Fe trong oxi sau mt thi gian thu c 11,62g hn hp Y. Ha tan hon
ton Y trong dung dch HNO3 d thu c 1,344 lt NO (ktc) l sn phm kh duy nht. S mol HNO3 phn ng l:
A. 0,56 mol
B. 0,64 mol
C. 0,48 mol
D. 0,72 mol
Cu 11: t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH 4, C2H4, C2H6, C3H8 thu c 6,16 gam CO2 v 4,14 gam
H2O. S mol C2H4 trong hn hp trn l:
A. 0,02 mol
B. 0,01 mol
C. 0,08 mol
D. 0,09 mol
Cu 12: Cho cc cht: FeS, Cu2S, FeSO4, H2S, Ag, Fe, KMnO4, Na2SO3, Fe(OH)2. S cht c th phn ng vi H 2SO4
c nng to ra SO2 l:
A. 9
B. 8
C. 6
D. 7
Cu 13: X l dung dch Na[Al(OH)4]. Cho t t n d cc dung dch sau y vo dung dch X: AlCl3, NaHSO4, HCl,
BaCl2, kh CO2. S trng hp thu c kt ta sau phn ng l:
A. 3
B. 4
C. 2
D. 1
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Cu 14: Kh hon ton m gam oxit MxOy cn va 10,752 lt H2 (ktc) thu c 20,16g kim loi M. Cho ton b lng
kim loi ny tc dng vi dung dch HNO 3 long d thu c 8,064 lt NO (ktc) l sn phm kh duy nht. Cng thc
ca MxOy l:
A. FeO
B. Fe3O4
C. Cr2O3
D. Cu2O
Cu 15: Cho 7,1g hn hp gm 1 kim loi kim X v 1 kim loi kim th Y tc dng ht vi lng d dung dch HCl
long thu c 5,6 lt kh (ktc). Hai kim loi X v Y ln lt l:
A. K, Ca
B. Li, Be
C. Na, Mg
D. K, Ba
Cu 16: Dy cc cht no sau y u khng lm i mu qu tm:
A. Axit glutamic, valin, alanin
B. Axit glutamic, lysin, glyxin
C. Alanin, lysin, phenyl amin
D. Anilin, glyxin, valin
Cu 17: Hn hp X gm HCOOH, CH3COOH (t l mol 1:1), hn hp Y gm CH3OH, C2H5OH (t l mol 2:3). Ly
16,96 gam hn hp X tc dng vi 8,08 gam hn hp Y (c xc tc H2SO4 c) thu c m gam este (hiu sut cc phn
ng este ha u bng 80%). Gi tr ca m l:
A. 12,064 gam
B. 22,736 gam
C. 17,728 gam
D. 20,4352 gam
Cu 18: Hn hp X gm O2 v O3 c t khi so vi H2 l x. t chy hon ton 1 lt hn hp Y gm CO v H2 cn 0,4 lt
hn hp X. Bit t khi ca Y so vi H2 bng 7,5 v cc th tch kh o cng iu kin nhit , p sut. Gi tr ca x l:
A. 19,2
B. 22,4
C. 17,6
D. 20
Cu 19: Este X c CTPT C5H8O2 khi tc dng vi NaOH to ra 2 sn phm u c kh nng tham gia phn ng trng
gng. S cht X tha mn iu kin trn l:
A. 2
B. 1
C. 3
D. 4
Cu 20: Thm t t 70ml dung dch H2SO4 1M vo 100ml dung dch Na2CO3 1M thu c dung dch Y. Cho Ba(OH) 2
d vo dung dch Y th khi lng kt ta thu c l:
A. 22,22g
B. 11,82g
C. 28,13g
D. 16,31g
Cu 21: Cht no sau y c kh nng to ra 4 loi dn xut mono brom?
A. m-imetylbenzen
B. o-imetylbenzen
C. p-imetylbenzen
D. Etylbenzen
Cu 22: Hn hp A gm CH4, C2H4, C3H4. Nu cho 13,4 gam hn hp X tc dng vi dung dch AgNO3/NH3 d th thu c
14,7gam kt ta. Nu cho 16,8 lt hn hp X (ktc) tc dng vi dung dch brom th thy c 108gam brom phn ng. % th tch CH 4
trong hn hp X l:
A. 30%
B. 25%
C. 35%
D. 40%
Cu 23: Ha tan a mol Fe trong dung dch H2SO4 thu c 12,32 lt SO2 (ktc) l sn phm kh duy nht v dung dch
X. C cn dung dch X thu c 75,2 gam mui khan. Gi tr ca a l:
A. 0,4
B. 0,6
C. 0,3
D. 0,5
Cu 24: Nhit phn cc mui sau: (NH4)2Cr2O7, CaCO3, Cu(NO3)2, KMnO4, Mg(OH)2, AgNO3, NH4Cl, BaSO4. S phn
ng xy ra v s phn ng oxi ha kh l:
A. 8 - 5
B. 7 - 4
C. 6 - 4
D. 7 - 5
Cu 25: Dy no sau y gm tt c cc cht u c lin kt cng ha tr, lin kt ion v lin kt cho nhn (theo quy tc
bt t)?
A. FeCl3, HNO3, MgCl2.
B. H2SO4, NH4Cl, KNO2.
C. KNO3, FeCl3, NaNO3.
D. NH4NO3, K2SO4, NaClO4.
Cu 26: X v Y l hai kim loi thuc cng mt nhm A. Bit ZX < ZY v ZX + ZY = 32. Kt lun no sau y l ng vi
X, Y?
A. X, Y u c 2 electron lp ngoi cng
B. Tnh kim loi ca X mnh hn Y
C. Nng lng ion ha ca X nh hn ca Y
D. Bn knh nguyn t ca X ln hn Y
Cu 27: Khi lng ca mt on mch t nilon-6,6 l 27346 u v ca mt on mch t capron l 17176 u. S mt xch
trong on mch t nilon-6,6 v t capron nu trn ln lt l
A. 121 v 152.
B. 113 v 114.
C. 121 v 114.
D. 113 v 152.

2 SO3 ( kh)
2 SO2 (kh)+O 2 ( kh)

Cu 28: Cho cn bng:

H < 0. cn bng trn chuyn dch sang phi th
phi:
A. Gim p sut, gim nhit
B. Tng p sut, tng nhit
C. Gim p sut, tng nhit
D. Tng p sut, gim nhit
Cu 29: X l mt tetrapeptit. Cho m gam X tc dng va vi 0,3 mol NaOH thu c 34,95g mui. Phn t khi ca
X c gi tr l:
A. 324
B. 432
C. 234
D. 342
Cu 30: Tripeptit mch h X v tetrapeptit mch h Y u c to ra t mt amino axit no, mch h c 1 nhm
COOH v 1 nhm NH2. t chy hon ton 0,1 mol X thu c sn phm gm CO2, H2O, N2 trong tng khi lng
CO2, H2O l 36,3 gam. Nu t chy hon ton 0,2 mol Y cn s mol O2 l:
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A. 1,875
B. 1,8
C. 2,8
D. 3,375
Cu 31: Cho cc cht sau: Al, ZnO, CH3COONH4, KHSO4, H2NCH2COOH, H2NCH2COONa, KHCO3, Pb(OH)2,
ClH3NCH2COOH, HOOCCH2CH(NH2)COOH. S cht c tnh lng tnh l:
A. 7
B. 6
C. 8
D. 5
Cu 32: Cho m gam glucoz ln men thnh ancol etylic vi hiu sut 75%. Hp th ton b kh CO2 sinh ra vo dung
dch Ca(OH)2 d thu c 90g kt ta. Gi tr ca m l:
A. 81g
B. 96g
C. 108g
D. 162g
Cu 33: C 6 dung dch ring bit: Fe(NO3)3, AgNO3, CuSO4, ZnCl2, Na2SO4, MgSO4. Nhng vo mi dung dch mt thanh
Cu kim loi, s trng hp xy ra n mn in ha l:
A. 3
B. 1
C. 4
D. 2
Cu 34: Cho cc cht: CH3CH2OH, C2H6, CH3OH, CH3CHO, C6H12O6, C4H10, C2H5Cl. S cht c th iu ch trc tip ra
axit axetic (bng 1 phn ng) l:
A. 2
B. 3
C. 4
D. 5
Cu 35: Cho m gam KOH vo 2 lt dung dch KHCO3 a mol/l thu c 2 lt dung dch X. Ly 1 lt dung dch X tc dng
vi dung dch BaCl2 d thu c 15,76g kt ta. Mt khc, cho 1 lt dung dch X vo dung dch CaCl 2 d ri un nng,
sau khi cc phn ng xy ra hon ton thu c 10g kt ta. Gi tr ca m v a ln lt l:
A. 8,96g v 0,12 M
B. 5,6g v 0,04 M
C. 4,48g v 0,06 M
D. 5,04g v 0,07 M
Cu 36: Sc clo t t n d vo dung dch KBr th hin tng quan st c l:
A. Dung dch c mu vng
B. Khng c hin tng g
C. Dung dch c mu nu
D. Dung dch t khng mu chuyn sang mu vng sau li mt mu.
Cu 37: Hp cht thm X c cng thc phn t C6H8N2O3. Cho 28,08 gam X tc dng vi 200 ml dung dch KOH 2M
sau phn ng thu c dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ca m l:
A. 21,5 gam
B. 38,8 gam
C. 30,5 gam
D. 18,1 gam
Cu 38: Ha tan Fe3O4 trong lng d dung dch H2SO4 long c dung dch X. Hi dung dch X tc dng c vi
bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al?
A. 5
B. 6
C. 7
D. 4
Cu 39: Cho m gam bt Cu vo 200 ml dung dch AgNO 3 0,2M, sau phn ng thu c 3,88g cht rn X v dung dch Y. Cho
2,925g bt Zn vo dung dch Y sau phn ng thu c 5,265g cht rn Z v dung dch ch cha 1 mui duy nht. Gi tr ca m
l:
A. 3,17
B. 2,56
C. 1,92
D. 3,2
Cu 40: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CuSO4, NaOH, NaHSO4, K2CO3, Ca(OH)2, H2SO4, HNO3,
MgCl2, HCl, Ca(NO3)2. S trng hp c phn ng xy ra l:
A. 9
B. 6
C. 8
D. 7
II. Phn ring (10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II )
Phn I: Theo chng trnh Chun (t cu 41 n cu 50)
Cu 41: t chy 10,4 gam mt axit cacboxylic no, a chc mch h, khng phn nhnh thu c 0,3 mol CO2 v 0,2
mol H2O. Cng thc cu to ca 2 axit l:
A. HOOC-(CH2)3-COOH.
B. HOOC-CH2-COOH.
C. HOOC-CH2-CH2-COOH.
D. HOOC-(CH2)4-COOH.
Cu 42: Hp cht A1 c CTPT C3H6O2 tho mn s
dd NaOH
dd H 2SO4
dd AgNO 3 / NH 3
A1
A2
A3

A4
Cng thc cu to ca A1 l:
A. HCOOCH2CH3.
B. CH3COCH2OH.
C. CH3CH2COOH.
D. HOCH2CH2CHO.
Cu 43: Dy no sau y gm cc kim loi u c th iu ch c bng phng php nhit luyn:
A. Zn, Mg, Ag
B. Ba, Fe, Cu
C. Al, Cu, Ag
D. Cr, Fe, Cu
Cu 44: Cc ion no sau y khng th cng tn ti trong mt dung dch:

A. K+, Mg2+, NO3 , Cl-.

B. Cu2+, Fe2+, HSO4 , NO3 .

C. Mg2+, Al3+, Cl , HSO4 .

D. Na+, NH4+, SO42 , PO43 .
Cu 45: Ha tan hon ton 30,4 gam cht rn X gm Cu, CuS, Cu 2S v S bng HNO3 d thy thot ra 20,16 lt kh NO
duy nht (ktc) v dung dch Y. Thm dung dch Ba(OH)2 d vo dung dch Y c m gam kt ta.
Gi tr ca m l:
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A. 81,55 gam.
B. 115,85 gam.
C. 110,95 gam.
D. 29,4 gam.
Cu 46: Hn hp kh X gm mt hirocacbon A v H2. T khi ca X so vi H2 bng 6,7. un X vi bt Ni nung nng
n khi phn ng xy ra hon ton thu c hn hp Y gm ankan v H2 d. T khi ca Y so vi H2 bng 16,75. Cng
thc phn t ca A l:
A. C2H2
B. C2H4
C. C3H4
D. C3H6
Cu 47: Mt - aminoaxit no X ch cha 1 nhm -NH 2 v 1 nhm -COOH. Cho 3,56 gam X tc dng va vi HCl
to ra 5,02 gam mui. Tn gi ca X l:
A. Alanin
B. Valin
C. Lysin
D. Glyxin
Cu 48: Oxi ha hon ton m gam mt ancol n chc X bng CuO th thu c hn hp kh v hi c t khi so vi H 2
bng 19. Sau phn ng ngi ta nhn thy khi lng cht rn gim 4,8 g. Gi tr ca m l:
A. 15 g
B. 1,8 g
C. 12 g
D. 18 g
Cu 49: Th nghim no sau y c kt ta sau phn ng?
A. Thi CO2 n d vo dung dch Ca(OH)2.
B. Cho dung dch HCl n d vo dung dch NaCrO2
C. Cho dung dch NaOH n d vo dung dch Cr(NO3)3.
D. Cho dung dch NH3 n d vo dung dch FeCl3.
Cu 50: Pht biu no sau y khng ng?
A. m chy magie c th c dp tt bng ct kh.
B. Pht pho trng c cu trc mng tinh th phn t
C. Trong phng th nghim, N2 c iu ch bng cch un nng dung dch NH4NO2 bo ho.
D. CF2Cl2 b cm s dng do khi thi ra kh quyn th ph hy tng ozon.
Phn II: Theo chng trnh nng cao (t cu 51 n cu 60)
Cu 51: Ch dng 1 ha cht phn bit cc cht sau: lng trng trng, dung dch glucoz, dung dch glixerol, dung
dch metanal, etanol. Ha cht l:
A. Cu(OH)2.
B. KMnO4
C. HNO3 c
D. HCl
Cu 52: Khng th iu ch trc tip axetanehit t:
A. Vinyl axetat
B. Etilen
C. Etanol
D. Etan
Cu 53: Trn 250 ml dung dch HCl 0,08 M v H2SO4 0,01M vi 250 ml dung dch Ba(OH)2 x M. Thu m gam kt ta v
500ml dung dch c pH = 12. Gi tr ca m v x ln lt l:
A. 1,165g v 0,04M
B. 1,165g v 0,04M
C. 0,5825g v 0,03M
D. 0,5825 v 0,06M
Cu 54: Th tch dung dch Br2 0,5M cn dng oxi ha ht 200 ml dung dch CrBr3 1M l:
A. 300 ml
B. 600 ml
C. 450 ml
D. 900 ml
Cu 55: Dung dch no sau y c th ha tan c vng?
A. KNO3
B. HNO3 c nng
C. HCl c
D. HNO3 c + HCl c t l 1:3
Cu 56: Cho cc kim loi: Na, Ca, Al, Fe, Cu. Nu ch dng H2O c th phn bit c bao nhiu kim loi:
A. 0
B. 3
C. 1
D. 5
Cu 57: Anehit X c cha 4 nguyn t C trong phn t. Khi cho 0,1 mol X tc dng vi dung dch AgNO 3/NH3 d thu
c 43,2 gam Ag. Mt khc 0,15 mol X lm mt mu va 200 ml dung dch Br2 1,5M. X l:
A. C2H4(CHO)2
B. C3H7CHO
C. O=HC-C C-CHO
D. O=CH-CH=CH-CHO
Cu 58: C6H12 khi tc dng vi dung dch HBr ch to ra 1 sn phm monobrom duy nht. S cng thc cu to ca
C6H12 tha mn iu kin trn l:
A. 4
B. 2
C. 3
D. 1
Cu 59: Cho sut in ng chun ca cc pin in ho: Mg-Ni l 2,11 V; Ni-Ag l 1,06 V. Bit th in cc chun ca
cp Ag+/Ag bng 0,8V. Th in cc chun ca cp Mg2+/Mg v cp Ni2+/Ni ln lt l:
A. -2,37V v -0,26V.
B. -1,87V v +0,26V.
C. -1,46V v -0,34V.
D. -0,76V v -0,26V.
Cu 60: Cho 27,48 gam axit picric vo bnh kn dung tch 20 lt ri nung nng nhit cao phn ng xy ra hon
ton thu c hn hp kh gm CO2, CO, N2 v H2. Gi bnh 12230C th p sut ca bnh l P atm. Gi tr ca P l:
A. 7,724 atm
B. 6,624 atm
C. 8,32 atm
D. 5,21 atm
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P N M 132 HA L1-2011
(THPT CHUYN NGUYN HU HN):
1C, 2C, 3B, 4B, 5D, 6B, 7D, 8C, 9C, 10B, 11B, 12B, 13C, 14B, 15C, 16D, 17A, 18D, 19A, 20C, 21A, 22A, 23A, 24B, 25D, 26A,
27A, 28D, 29A, 30B, 31B, 32C, 33B, 34C, 35A, 36D, 37C, 38C, 39D, 40C, 41B, 42A, 43D, 44B, 45C, 46C, 47A, 48D, 49D, 50A,
51A, 52D, 53D, 54B, 55D, 56D, 57A, 58C, 59A, 60B.

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