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Zn 2+ / Zn
o
Zn 2+ / Zn
Zn 2+ / Zn
2+
= - 0,793 =
Cd 2+ /Cd
o
Cd2+ /Cd
RT
RT
ln a Cd 2+ = -0,403 +
ln a Cd 2+
2F
2F
o
O2 ,H + /H 2O
2+
catot
anot
RT
RT
ln a Sn 2+ = -0,140 +
ln 0,10 = -0,170V
2F
2F
RT
RT
o
ln a H+ + O2 = 1,23 +
ln 0, 01 + 0,5 = 1,612 V
= O2 ,H+ /H 2O +
F
F
Epc =
o
Sn 2+ /Sn
anot
catot
H + / H2
a Sn
2+
RT
ln a H+ -
F
H2
RT
ln 0, 21 - 0,5 =
F
Sn 2+ /Sn
o
Sn 2+ /Sn
RT
ln a Sn 2+
2F
/Sn
Ni 2+ / Ni
H+ / H2
=
=
o
Ni2+ / Ni
RT
RT
ln a Ni2+ = -0,25 +
ln1,10 = -0,249V
2F
2F
RT
ln a H+ -
F
H2
RT
ln107 - 0,42 = -0,833V <
F
Ni 2+ / Ni
Ni2+ b kh trc
anot c th xy ra s oxi ha H2O v Ni (dng lm in cc) cn SO 24 rt kh b
oxi ha (2SO 24 - 2e S2O82- 2,05V)
1
2
2 ,H
Ni 2+ / Ni
/H 2O
= Oo
2 ,H
RT
RT
ln a H2 + a1/2
ln10 7 + 0,1 = 0,917V
O 2 + O 2 = 1, 23 +
2F
2F
RT
RT
ln a Ni 2+ = -0,25 +
ln1,10 = -0,249V< O2 ,H + / H2O
+
2F
2F
/H 2 O
o
Ni2+ / Ni
Ni b oxi ha trc
4. Mun dng in cc Pt in phn dung dch cha CdCl2 1,0m, NiSO4 1,0m th cn
phi t vo hai in cc ca bnh in phn mt hiu in th bng bao nhiu? V lc
hai cc bnh in phn xut hin cht g? (khng tnh n qu th, u bng 1)
E = 1,065, xut hin Ni v O2
2+
2+
+
catot c th xy ra cc phn ng kh Cd , Ni v H :
o
Ni / Ni = Ni / Ni = -0,25V
2+
Cd 2+ /Cd
H+ / H2
2+
=
=
o
Cd2+ /Cd
= -0,402V
RT
RT
ln a H+ =
ln107 = -0,414V
F
F
1
2
2 /Cl
RT
RT
ln aCl = 1,358
ln 2, 0= 1,340V
F
F
RT
RT
= oO ,H O/OH
ln a OH = 0, 401
ln10 7= 0,815V
2
2
F
F
o
= Cl
2 ,H 2 O/OH
2 /Cl
Cd 2+ /Cd
o
Cd 2+ /Cd
2 /Cl
2 ,H
RT
RT
ln
a
ln 0, 06= 1, 430V
= 1,358
Cl
2 /Cl
F
F
RT
RT
= Oo ,H+ /H O +
ln aH + = 1, 229+
ln10 7 = 0,815V < Cl2 /Cl
2
2
F
F
o
= Cl
/H 2O
2 ,H
/H 2O
E = O ,H
2
= Oo
+
/ H 2O
2 ,H
/H 2O
RT
RT
ln aH + = 1, 229+
ln 0, 04= 1,146V
F
F
Cd 2+ /Cd
2+
/Cu
= Cd 2+ /Cd
0,337 +
RT
ln a Cu 2+ = 0, 642
2F
2 ,H
/H 2 O
= Oo
2 ,H
/H 2 O
RT
RT
ln aH+ + O2 = 1, 229+
ln10 7 + 0, 6= 1, 415V < Cl2 /Cl
F
F
vn l s oxi ha to ra O2 xy ra trc
6. 298K, 1atm, in phn dung dch c cha Ag+ (a=0,05), Fe2+ (a=0,01), Cd2+
(a=0,001), Ni2+ (a=0,1) v H+ (a=0,001) v gi thit rng nng H+ khng thay i
trong qu trnh in phn. Bit qu th ca H2 trn Ag, Ni, Fe v Cd ln lt l 0,20,
0,24, 0,18 v 0,30V. t vo hai in cc mt hiu in th tng dn t 0, hi th t cc
cht b kh catot.
Ag, Ni, H2, Cd, Fe
in cc Pt:
RT
RT
ln a Ag+ = -0,7794 +
ln 0, 05 = 0,722V
F
2F
RT
RT
o
ln a Fe2+ = -0,4402+
ln 0, 01 = -0,4994V
Fe2+ /Fe = Fe2+ / Fe +
2F
2F
RT
RT
o
ln a Cd 2+ = -0,403 +
ln 0, 001 = -0,4917V
Cd 2+ /Cd = Cd 2+ /Cd +
2F
2F
RT
RT
o
ln a Ni 2+ = -0,25 +
ln 0,1 = -0,2796V
Ni 2+ / Ni = Ni2+ / Ni +
2F
2F
RT
RT
ln a H+ =
ln 0, 001 = -0,1775V
H+ / H2 =
F
F
Ag + /Ag
o
Ag+ / Ag
cc in cc khc:
RT
ln a H+ -
F
RT
ln a H+ -
Ni: H+ / H2 =
F
RT
ln a H+ -
Fe: H+ /H2 =
F
RT
ln a H+ -
Cd: H+ /H2 =
F
Ag:
H + /H2
H2
H2
H2
H2
2+
2+
Fe2+ /Fe