Hp cht X c khi lng phn t l 76 v to bi 2 nguyn t A v B.

A,B c s oxi ho cao nht l +a; +b v c s oxi ho m l x;-y, tho mn iu kin: a=x, b=3y. Bit rng trong X th A c s oxi ha l +a. Cu hnh electron lp ngoi cng ca B v cng thc phn t ca X tng ng l A. 2s22p4 v NiO. B. CS2 v 3s23p4. C. 3s23p4 v SO3. D. 3s23p4 v CS2.

=================== Chuyn 2: PHN NG OXI HA KH V CN BNG HA HC

Chia 22,0 gam hn hp X gm Mg, Na v Ca thnh 2 phn bng nhau. Phn 1, tc dng ht vi O2 thu c 15,8 gam hn hp 3 oxit. Phn 2, tc dng vi dung dch HCl d thu c V lt kh H2 (ktc). Gi tr ca V l A. 6,72. B. 3,36. C. 13,44. D. 8,96. Dng cho cu 14, 15: Chia 29,8 gam hn hp X gm Mg, Na, K v Ca thnh 2 phn bng nhau. Phn 1 tc dng hon ton vi dung dch HNO3 long thu c 1,568 lt kh N 2 duy nht (ktc) v dung dch cha x gam mui (khng cha NH 4NO3). Phn 2 tc dng hon ton vi oxi thu c y gam hn hp 4 oxit. Cu 14: Gi tr ca x l A. 73,20. B. 58,30. C. 66,98. D. 81,88. Cu 15: Gi tr ca y l A. 20,5. B. 35,4. C. 26,1. D. 41,0. Dng cho cu 16, 17, 18, 19: Dn hn hp X gm 0,1 mol C2H2, 0,1 mol C3H4 v 0,1 mol H2 qua ng cha Ni nung nng thu c hn hp kh Y gm 7 cht. t cht hon ton Y cn V lt kh O2 (ktc) thu c x gam CO2 v y gam H2O. Nu cho V lt kh O2 (ktc) tc dng ht vi 40 gam hn hp Mg v Ca th thu c a gam hn hp cht rn. Cu 16: Gi tr ca x l A. 13,2. B. 22,0. C. 17,6. D. 8,8. Cu 17: Gi tr ca y l A. 7,2. B. 5,4. C. 9,0. D. 10,8. Cu 18: Gi tr ca V l A. 10,08. B. 31,36. C. 15,68. D. 13,44. Cu 19: Gi tr ca a l A. 62,4. B. 51,2. C. 58,6. D. 73,4. Dng cho cu 20, 21, 22: Chia 47,1 gam hn hp X gm Mg, Al, Zn, Ni thnh 2 phn bng nhau. Phn 1 tc dng hon ton vi dung dch HNO3 va thu c 7,84 lt kh NO duy nht (ktc) v dung dch Y cha x gam mui (khng cha NH 4NO3). Nu cho Y tc dng vi dung dch NaOH th lng kt ta ln nht thu c l y gam. Phn 2 tc dng hon ton vi dung dch HCl thu c V lt kh H2(ktc). Cu 20: Gi tr ca x l A. 110,35. B. 45,25. C. 112,20. D. 88,65. Cu 21: Gi tr ca y l A. 47,35. B. 41,40. C. 29,50. D. 64,95. Cu 22: Gi tr ca V l A. 11,76. B. 23,52. C. 13,44. D. 15,68. Dng cho cu 23, 24: Cho hn hp X gm 0,2 mol Al v 0,2 mol Zn tc dng vi 500 ml dung dch Y gm Cu(NO3)2 v AgNO3 n khi phn ng hon ton thu c 48,45 gam cht rn A gm 3 kim loi v dung dch B cha 2 mui. Cho A tc dng vi dung dch HCl d thu c 3,36 lt kh H2 (ktc). Coi th tch dung dch khng i Cu 23: Nng mol/lt ca Cu(NO3)2 trong Y l A. 0,6. B. 0,5. C. 0,4. D. 0,3. Cu 24: Tng nng mol/lt ca mui trong dung dch B l A. 0,6. B. 0,5. C. 0,4. D. 0,3. Tc phn ng v cn bng ha hc L thuyt

2SO (k); phn ng thun l phn ng ta nhit. Pht biu ng l: Cu 171. Cho cn bng ha hc: 2SO2 (k) + O2 (k) 3
A. Cn bng chuyn dch theo chiu thun khi tng nhit . B. Cn bng chuyn dch theo chiu nghch khi gim nng O2. C. Cn bng chuyn dch theo chiu thun khi gim p sut h phn ng. D. Cn bng chuyn dch theo chiu nghch khi gim nng SO3. Cu 172. Cho cn bng (trong bnh kn) sau: CO (k) + H2O (k)

CO2 (k)

H2 (k)

H < 0.

Trong cc yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H2; (4) tng p sut chung ca h; (5) dng cht xc tc. Dy gm cc yu t u lm thay i cn bng ca h l:

A. (1), (4), (5).

B. (1), (2), (3).

C. (1), (2), (4).

D. (2), (3), (4).

Cu 173. Cho cn bng ho hc: N2 (k) + 3H2 (k) 2NH3 (k); phn ng thun l phn ng to nhit. Cn bng ho hc khng
b chuyn dch khi. A. thay i p sut ca h. B. thay i nhit . Cu 174. Cho cc cn bng ho hc: C. thm cht xc tc Fe. D. thay i nng N2.

N2 (k) + 3H2 (k)

2NH3 (k)(1)

H2 (k) + I2 (k) 2HI (k)(2).

2SO2 (k) + O2 (k) 2SO3 (k)(3) 2NO2 (k) N2O4 (k)(4).

Khi thay i p sut nhng cn bng ha hc b chuyn dch l: A. (1), (2), (4). B. (1), (3), (4). C. (1), (2), (3). Cu 175. Cho cc cn bng sau: (1) 2SO2(k) + D. (2), (3), (4). 3H2 (k)

O2(k) 2SO3(k)

(2) N2 (k) +

2NH3 (k).

(3) CO2(k) + H2(k) CO(k) + H2O(k)

(4) 2HI (k) H2 (k) + I2 (k).

D. (3) v (4).

Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l A. (1) v (3). B. (1) v (2). C. (2) v (4). Cu 176. Cho cn bng sau trong bnh kn: 2NO2

N2O4.

(mu nu ) (khng mu). Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c: A. H < 0, phn ng thu nhit. B. H < 0, phn ng to nhit. C. H > 0, phn ng to nhit. D. H > 0, phn ng thu nhit. Cu 177. Hng s cn bng ca phn ng xc nh ch ph thuc vo. A. nhit . B. nng . C. p sut. D. cht xc tc. Bi tp Cu 10. Cho cht xc tc MnO2 vo 100 ml dung dch H2O2, sau 60 giy thu c 33,6 ml kh O2 ( ktc). Tc trung bnh ca phn ng (tnh theo H2O2) trong 60 giy trn l A. 5,0.104 mol/(l.s). B. 2,5.104 mol/(l.s). C. 5,0.105 mol/(l.s). D. 5,0.103 mol/(l.s).

Cu 11. Cho phng trnh ha hc ca phn ng tng hp amoniac. N 2 (k) + 3H 2 (k) 2NH3 (k) .
xt

to

Khi tng nng ca hiro ln 2 ln, tc phn ng thun: A. tng ln 8 ln. B. tng ln 2 ln. C. gim i 2 ln. D. tng ln 6 ln. Cu 12. Mt bnh phn ng c dung tch khng i, cha hn hp kh N2 v H2 vi nng tng ng l 0,3M v 0,7M. Sau khi phn ng tng hp NH3 t trng thi cn bng t 0 C, H2 chim 50% th tch hn hp thu c. Hng s cn bng KC t oC ca phn ng c gi tr l A. 3,125. B. 0,500. C. 0,609. D. 2,500. Cu 13. Cho cc cn bng sau:

(1) H 2 (k) + I2 (k) 2HI (k) 1 H 2 (k) + 1 I 2 (k) (3) HI (k) 2 2 (5) H 2 (k) + I2 (r) 2HI (k)

1 1 (2) H2 (k) + I2 (k) HI (k) 2 2 (4) 2HI (k) H2 (k) + I2 ( k)

.

nhit xc nh, nu KC ca cn bng (1) bng 64 th KC bng 0,125 l ca cn bng. A. (5). B. (4). C. (3). D. (2). Cu 1: Tc ca mt phn ng c dng:

v = k.Cx .Cy (A, B l 2 cht khc nhau). Nu tng nng A ln 2 ln (nng B A B

khng i) th tc phn ng tng 8 ln. Gi tr ca x l A. 3. B. 4. C. 6. D. 8. Cu 3: Khi tng thm 10OC, tc mt phn ng ho hc tng ln 2 ln. Vy khi tng nhit ca phn ng t 25 OC ln 75OC th tc phn ng tng A. 5 ln. B. 10 ln. C. 16 ln. D. 32 ln. Cu 4: Khi tng thm 10OC, tc mt phn ng ho hc tng ln 3 ln. tc phn ng (ang tin hnh 30OC) tng 81 ln th cn phi tng nhit ln n A. 50OC. B. 60OC. C. 70OC. D. 80OC. Cu 6: Ngi ta cho N2 v H2 vo trong bnh kn dung tch khng i v thc hin phn ng: N2 + 3H2 2NH3. Sau mt thi gian, nng cc cht trong bnh nh sau: [N2] = 2M; [H2] = 3M; [NH3] = 2M. Nng mol/l ca N2 v H2 ban u ln lt l

A. 3 v 6. B. 2 v 3. C. 4 v 8. D. 2 v 4. Cu 7: Xt phn ng sau nhit khng i: 2NO + O2 2NO2. Khi th tch bnh phn ng gim i mt na th tc phn ng A. tng 4 ln. B. gim 4 ln. C. tng 8 ln. D. gim 8 ln. Cu 8: Cho 6 gam, km ht vo cc ng dung dch H 2SO4 2M nhit thng. Bin i no sau y KHNG lm thay i tc phn ng? A. thay 6 gam km ht bng 6 gam km bt. B. tng nhit ln n 50OC. C. thay dung dch H2SO4 2M bng dung dch H2SO4 1M. D. tng th tch dung dch H2SO4 2M ln 2 ln. Cu 9: Cho phn ng: 2KClO3 (r) 2KCl(r) + 3O2 (k). Yu t KHNG nh hng n tc ca phn ng trn l A. kch thc ht KClO3. B. p sut. C. cht xc tc. D. nhit . Cu 10: Khi phn ng thun nghch trng thi cn bng th n A. khng xy ra na. B. vn tip tc xy ra. C. ch xy ra theo chiu thun. D. ch xy ra theo chiu nghch. Cu 11: Gi tr hng s cn bng KC ca phn ng thay i khi A. thay i nng cc cht. B. thay i nhit . C. thay i p sut. D. thm cht xc tc. Cu 12: Cc yu t nh hng n cn bng ho hc l A. nng , nhit v cht xc tc. B. nng , p sut v din tch b mt. C. nng , nhit v p sut. D. p sut, nhit v cht xc tc. Cu 13: Cho phn ng: Fe2O3 (r) + 3CO (k) 2Fe (r) + 3CO2 (k). Khi tng p sut ca phn ng ny th A. cn bng chuyn dch theo chiu thun. B. cn bng khng b chuyn dch. C. cn bng chuyn dch theo chiu nghch. D. phn ng dng li. 2NH3 (k) H < 0. Cu 14: Cho phn ng: N2 (k) + 3H2 (k) Khi gim nhit ca phn ng t 450OC xung n 25 OC th A. cn bng chuyn dch theo chiu thun. B. cn bng khng b chuyn dch. C. cn bng chuyn dch theo chiu nghch. D. phn ng dng li. Cu 15: Phn ng: 2SO2 + O2 2SO3 H < 0. Khi gim nhit v khi gim p sut th cn bng ca phn ng trn chuyn dch tng ng l A. thun v thun. B. thun v nghch. C. nghch v nghch. D.nghch v thun. Cu 16: Trn 1 mol H2 vi 1 mol I2 trong bnh kn dung tch 1 lt. Bit rng 410 O, hng s tc ca phn ng thun l 0,0659 v hng s tc ca phn ng nghch l 0,0017. Khi phn ng t ti trng thi cn bng 410OC th nng ca HI l A. 2,95. B. 1,52. C. 1,47. D. 0,76. Cu 17: Cho phn ng sau mt nhit nht nh: N2 + 3H3 2NH3. Nng (mol/l) lc ban u ca N2 v H2 ln lt l 0,21 v 2,6. Bit KC ca phn ng l 2. Nng cn bng (mol/l) ca N2, H2, NH3 tng ng l A. 0,08; 1 v 0,4. B. 0,01; 2 v 0,4. C. 0,02; 1 v 0,2. D. 0,001; 2 v 0,04. CO2 (k) + H2 (k) Cu 18: Cho phn ng: CO (k) + H2O (k) Bit KC ca phn ng l 1 v nng ban u ca CO v H2O tng ng l 0,1 mol/l v 0,4 mol/l. Nng cn bng (mol/l) ca CO v H2O tng ng l A. 0,08 v 0,08. B. 0,02 v 0,08. C. 0,02 v 0,32. D. 0,05 v 0,35. Cu 19: Mt bnh kn dung tch khng i V lt cha NH3 0OC v 1atm vi nng 1mol/l. Nung bnh n 546OC v NH3 b phn hu theo phn ng: 2NH3 N2 + 3H2. Khi phn ng t ti trng thi cn bng, p sut kh trong bnh l 3,3atm. nhit ny nng cn bng ca NH3 (mol/l) v gi tr ca KC l A. 0,1; 2,01.10-3. B. 0,9; 2,08.10-4. C. 0,15; 3,02.10-4. D. 0,05; 3,27.10-3. Cu 20: Cho phng trnh phn ng: 2A(k) + B (k) 2X (k) + 2Y(k). Ngi ta trn 4 cht, mi cht 1 mol vo bnh kn dung tch 2 lt (khng i). Khi cn bng, lng cht X l 1,6 mol. Hng s cn bng ca phn ng ny l A. 58,51 B. 33,44. C. 29,26 D. 40,96. Cu 21: Cho phn ng: CO + Cl2 COCl2 thc hin trong bnh kn dung tch 1 lt nhit khng i. Khi cn bng [CO] = 0,02; [Cl2] = 0,01; [COCl2] = 0,02. Bm thm vo bnh 1,42gam Cl2. Nng mol/l ca CO; Cl2 v COCl2 trng thi cn bng mi ln lt l A. 0,013; 0,023 v 0,027. B. 0,014; 0,024 v 0,026. C. 0,015; 0,025 v 0,025. D. 0,016; 0,026 v 0,024.

Cu 23: Cho cn bng: N2O4 2NO2. Cho 18,4 gam N2O4 vo bnh chn khng dung tch 5,9 lt 27OC, khi t n trng thi cn bng, p sut l 1 atm. Hng s cn bng KC nhit ny l A. 0,040. B. 0,007. C. 0,500. D. 0,008. + Cu 24: Khi ho tan SO2 vo nc c cn bng sau: SO2 + H2O HSO3 + H . Khi cho thm NaOH v khi cho thm H2SO4 long vo dung dch trn th cn bng s chuyn dch tng ng l A. thun v thun. B. thun v nghch. C. nghch v thun. D. nghch v nghch.

================= CHUYN 3: NGUYN T PHI KIM V HP CHT L thuyt

Cu 201. Trong phng th nghim, ngi ta thng iu ch clo bng cch. A. in phn dung dch NaCl c mng ngn. B. cho dung dch HCl c tc dng vi MnO2, un nng. C. in phn nng chy NaCl.D. cho F2 y Cl2 ra khi dung dch NaCl. Cu 202. Trong phng th nghim, ngi ta iu ch oxi bng cch. A. nhit phn KClO3 c xc tc MnO2. B. nhit phn Cu(NO3)2. C. in phn nc. D. chng ct phn on khng kh lng. Cu 203. ng dng no sau y khng phi ca ozon? A. iu ch oxi trong phng th nghim. B. Ty trng tinh bt, du n. C. St trng nc sinh hot. D. Cha su rng. Cu 204. Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng dung dch amoni nitrit bo ho. Kh X l A. N2O. B. N2. C. NO2. D. NO. Cu 205. Trong phng th nghim, ngi ta thng iu ch HNO3 t. A. NaNO3 v H2SO4 c. B. NaNO2 v H2SO4 c. C. NH3 v O2. D. NaNO3 v HCl c. Cu 206. Cho Cu v dung dch H2SO4 long tc dng vi cht X (mt loi phn bn ha hc), thy thot ra kh khng mu ha nu trong khng kh. Mt khc, khi X tc dng vi dung dch NaOH th c kh mi khai thot ra. Cht X l A. amophot. B. ure. C. natri nitrat. D. amoni nitrat. Cu 207. Phn bn no sau y lm tng chua ca t? A. NaNO3. B. NH4NO3. C. KCl. D. K2CO3. Cu 208. Thnh phn chnh ca qung photphorit l A. Ca(H2PO4)2. B. CaHPO4. C. NH4H2PO4. D. Ca3(PO4)2. Cu 209. Pht biu no sau y l ng? A. Phn ln cung cp nit ho hp cho cy di dng ion nitrat (NO3-) v ion amoni (NH4+). B. Amophot l hn hp cc mui (NH4)2HPO4 v KNO3. C. Phn hn hp cha nit, photpho, kali c gi chung l phn NPK. D. Phn ur c cng thc l (NH4)2CO3. Cu 210. Phn bn nitrophotka (NPK) l hn hp ca. A. (NH4)2HPO4 v KNO3. B. (NH4)2HPO4 v NaNO3. C. (NH4)3PO4 v KNO3. D. NH4H2PO4 v KNO3. Cu 211. Cho cc phn ng sau: (1) Cu(NO3 )2 t
t (4) NH3 + Cl2 . 0

(2) NH4 NO 2 t .
t (5) NH 4 Cl 0

850 (3) NH3 + O 2 C,Pt

t (6) NH3 + CuO . 0

Cc phn ng u to kh N2 l: A. (1), (2), (5). B. (2), (4), (6). Cu 212. Cho cc phn ng sau:
t 4HCl + MnO2 MnCl2 + Cl2 + 2H2O.
o o

C. (1), (3), (4).

D. (3), (5), (6).

2HCl + Fe FeCl2 + H2.

t 14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O. 6HCl + 2Al 2AlCl3 + 3H2. 16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O. S phn ng trong HCl th hin tnh oxi ha l A. 3. B. 1. C. 2. D. 4. Cu 213. Cho cc phn ng sau: (a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O. (b) HCl + NH4HCO3 NH4Cl + CO2 + H2O. (c) 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O. (d) 2HCl + Zn ZnCl2 + H2. S phn ng trong HCl th hin tnh kh l A. 2. B. 3. C. 4. D. 1.

Cu 214. Cho cc phn ng :

(1)O3 + dung dch KI

t (2) F2 + H2O
0

t (3) MnO2 + HCl c

(4) Cl2 + dung dch H2S D. (2), (3), (4).

Cc phn ng to ra n cht l : A. (1), (2), (3). B. (1), (2), (4)

C. (1), (3), (4).

Cu 215. Phn ng nhit phn khng ng l :

t A. 2KNO3 2KNO2 + O2. t C. NH4NO2 N2 + 2H2O. Cu 216. Trng hp khng xy ra phn ng ha hc l
o 0 0

t B. NaHCO3 NaOH + CO2. t D. NH4Cl NH3 + HCl .

0

t A. 3O2 + 2H2S 2SO2 + 2H2O .B. FeCl2 + H2S FeS + 2HCl. C. O3 + 2KI + H2O O2 + 2KOH + I2. D. Cl2 + 2NaOH NaCl + NaClO + H2O. Cu 217. Dy gm cc cht u tc dng c vi dung dch HCl long l: A. AgNO3, (NH4)2CO3, CuS. B. FeS, BaSO4, KOH. C. KNO3, CaCO3, Fe(OH)3. D. Mg(HCO3)2, HCOONa, CuO. Cu 218. Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l A. CaOCl2. B. K2Cr2O7. C. MnO2. D. KMnO4. Cu 219. Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 ln nht l A. KMnO4. B. KNO3. C. KClO3. D. AgNO3. Cu 220. Cht kh X tan trong nc to ra mt dung dch lm chuyn mu qu tm thnh v c th c dng lm cht ty mu. Kh X l A. CO2. B. O3. C. SO2. D. NH3. Cu 221. SO2 lun th hin tnh kh trong cc phn ng vi. A. O2, nc Br2, dung dch KMnO4. B. dung dch NaOH, O2, dung dch KMnO4. C. dung dch KOH, CaO, nc Br2. D. H2S, O2, nc Br2. Cu 222. Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca V l A. 2,80. B. 3,08. C. 3,36. D. 4,48. Cu 223. Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100oC. Sau khi phn ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l A. 0,24M. B. 0,48M. C. 0,2M. D. 0,4M. Cu 224. Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l A. 47,2%. B. 58,2%. C. 52,8%. D. 41,8%.

Axit Nitric v mui Nitrat trong mi trng axit Cu 225. Khi cho Cu tc dng vi dung dch cha H2SO4 long v NaNO3, vai tr ca NaNO3 trong phn ng l A. cht oxi ho. B. mi trng. C. cht kh. D. cht xc tc. Cu 226. Thc hin hai th nghim: 1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. 2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l A. V2 = 2V1. B. V2 = 2,5V1. C. V2 = V1. D. V2 = 1,5V1. Cu 227. Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 1,792. B. 0,448. C. 0,746. D. 0,672. Cu 228. Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 17,8 v 4,48. B. 17,8 v 2,24. C. 10,8 v 4,48. D. 10,8 v 2,24. Cu 229. Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l A. 240. B. 400. C. 120. D. 360. Cu 230. Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung dch Y c pH bng. A. 3. B. 2. C. 1. D. 4. Cu 231. Nhit phn hon ton 34,65 gam hn hp gm KNO3 v Cu(NO3)2, thu c hn hp kh X (t khi ca X so vi kh hiro bng 18,8). Khi lng Cu(NO3)2 trong hn hp ban u l A. 11,28 gam. B. 8,60 gam. C. 20,50 gam. D. 9,40 gam. Cu 232. Ho tan hon ton mt lng bt Zn vo mt dung dch axit X. Sau phn ng thu c dung dch Y v kh Z. Nh t t dung dch NaOH (d) vo Y, un nng thu c kh khng mu T. Axit X l A. HNO3. B. H2SO4 long. C. H2SO4 c. D. H3PO4. Cu 233. Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l A. 6,52 gam. B. 13,92 gam. C. 8,88 gam. D. 13,32 gam.

Cu 234. Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l A. 106,38. B. 38,34. C. 97,98. D. 34,08.

CHUYN 4: S IN LY
Cu 7: Phng trnh phn li ca axt axetic l: CH3COOH CH3COO- + H+ Ka. Bit [CH3COOH] = 0,5M v trng thi cn + -3 bng [H ] = 2,9.10 M. Gi tr ca Ka l A. 1,7.10-5. B. 8,4.10-5. C. 5,95.10-4. D. 3,4.10-5. Cu 10: Thm t t tng git H2SO4 vo dung dch Ba(OH)2 n d th dn in ca h s bin i nh sau: A. tng dn. B. gim dn. C. lc u gim, sau tng. D. lc u tng, sau gim. Cu 11: C 2 dung dch X v Y, mi dung dch ch cha 2 cation v 2 anion trong s cc ion vi s mol nh sau: K + (0,15); Mg2+ (0,10); NH4+ (0,25); H+ (0,20); Cl- (0,10); SO42- (0,075); NO3- (0,25); CO32- (0,15). Cc ion trong X v Y l A. X cha (K+, NH4+, CO32-, SO42-); Y cha (Mg2+, H+, NO3-, Cl-). B. X cha (K+, NH4+, CO32-, NO3-); Y cha (Mg2+, H+, SO42-, Cl-). C. X cha (K+, NH4+, CO32-, Cl-); Y cha (Mg2+, H+, SO42-, NO3-). D. X cha (H+, NH4+, CO32-, Cl-); Y cha (Mg2+, K+, SO42-, NO3-). Cu 12: Mt dung dch cha a mol Na+, b mol Ca2+, c mol HCO3- v d mol NO3-. Biu thc lin h gia a, b, c, d v cng thc tng s gam mui trong dung dch ln lt l A. a + 2b = c + d v 23a + 40b + 61c + 62d. B. a + b = c + d v 23a + 40b + 61c + 62d. C. a + b = c + d v 23a + 40b - 61c - 62d. D. a + 2b = c + d v 23a + 40b - 61c - 62d. Cu 17: Chia dung dch X gm CuSO4 v Al(NO3)3 thnh 2 phn bng nhau. Phn 1 cho tc dng vi dung dch BaCl2 d thu c 6,99 gam kt ta. Phn 2 cho tc dng vi dung dch NaOH d, ri ly kt ta nung n khi lng khng i thu c m gam cht rn. Gi tr ca m l A. 2,4. B. 3,2. C. 4,4. D. 12,6. Cu 20: Ion CO32 khng tc dng vi cc ion thuc dy no sau y? A. NH4+, K+, Na+. B. H+, NH4+, K+, Na+. 2+ 2+ + C. Ca , Mg , Na . D. Ba2+, Cu2+, NH4+, K+. Cu 21: Dy no cho di y gm cc ion cng tn ti trong mt dung dch A. Na+, NH4+, Al3+, SO42-, OH-, Cl-. B. Ca2+, K+, Cu2+, NO3-, OH-, Cl-. C. Ag+, Fe3+, H+, Br-, CO32-, + 2+ + 2NO3 . D. Na , Mg , NH4 , SO4 , Cl , NO3 . Cu 22: Hin tng to thnh nh trong cc hang ng l do phn ng A. CaCO3 + CO2 + H2O Ca(HCO3)2. B. Ca(HCO3)2 CaCO3 + CO2 + H2O. C. CaO + CO2 CaCO3. D. CaCO3 CaO + CO2. Cu 33: Dung dch axit H2SO4 c pH = 4. Nng mol/l ca H2SO4 trong dung dch l A. 2.10-4M. B. 1.10-4M. C. 5.10-5M. D. 2.10-5M. S in li: 2 + 0,5. Cu 180. Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11 (saccaroz), CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l A. 5. B. 4. C. 2. D. 3. Cu 181. Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l A. 3. B. 5. C. 4. D. 2. Cu 182. Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong dyc tnh cht lng tnh l A. 4. B. 5. C. 3. D. 2. Cu 183. Cc hp cht trong dy cht no di y u c tnh lng tnh? A. Cr(OH)3, Fe(OH)2, Mg(OH)2 B. Cr(OH)3, Zn(OH)2, Mg(OH)2 C. Cr(OH)3, Pb(OH)2, Mg(OH)2. D. Cr(OH)3, Zn(OH)2, Pb(OH)2. Cu 184. Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi dung dch HCl, dung dch NaOH l A. 5. B. 7. C. 4. D. 6. Cu 185. Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l: A. NaHCO3, MgO, Ca(HCO3)2. B. NaHCO3, ZnO, Mg(OH)2. C. Mg(OH)2, Al2O3, Ca(HCO3)2. D. NaHCO3, Ca(HCO3)2, Al2O3. Cu 186. Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dung dch c pH > 7 l A. KCl, C6H5ONa, CH3COONa. B. NH4Cl, CH3COONa, NaHSO4. C. Na2CO3, NH4Cl, KCl. D. Na2CO3, C6H5ONa, CH3COONa.

Cu 187. Cho cc dung dch c cng nng : Na2CO3 (1), H2SO4 (2), HCl (3), KNO3 (4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi l: A. (2), (3), (4), (1). B. (1), (2), (3), (4). C. (3), (2), (4), (1). D. (4), (1), (2), (3). - Hn hp axit td hn hp baz. Pt ion thu gn. Bt in tch. Cu 188. Cho 4 phn ng: (1) Fe + 2HCl FeCl2 + H2. (2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O. (3) BaCl2 + Na2CO3 BaCO3 + 2NaCl. (4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4. Cc phn ng thuc loi phn ng axit - baz l A. (2), (4). B. (1), (2). C. (3), (4). D. (2), (3). Cu 189. Cho cc phn ng ha hc sau: (1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2 . (3) Na2SO4 + BaCl2 (4) H2SO4 + BaSO3 (5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2 . Cc phn ng u c cng mt phng trnh ion rt gn l: A. (1), (2), (3), (6). B. (3), (4), (5), (6). C. (1), (3), (5), (6). D. (2), (3), (4), (6).

Cu 194. Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2 gam Ba(OH)2. Sau phn ng thu c m gam kt ta. Gi tr ca m l A. 17,1. B. 19,7. C. 15,5. D. 39,4. Cu 195. Mt dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl- v y mol SO 4 . Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l: A. 0,01 v 0,03. B. 0,03 v 0,02. C. 0,05 v 0,01. D. 0,02 v 0,05.
2-

Cu 197. Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O (d), un nng, dung dch thu c cha. A. NaCl, NaHCO3, NH4Cl, BaCl2. B. NaCl. C. NaCl, NaOH. D. NaCl, NaOH, BaCl2. Cu 198. Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. B. NaCl, Na2SO4, Ca(OH)2. C. HNO3, Ca(OH)2, KHSO4, Na2SO4. D. HNO3, NaCl, Na2SO4.

CHUYN 5: KIM LOI V HP CHT I. CC DNG BI TP KIM LOI

DNG 1: KIM LOI TC DNG VI AXIT Cu 1. Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10 %, thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l: A. 101,68 gam B. 88,20 gam C. 101,48 gam D. 97,80 gam Cu 2: Ho tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt kh H2 ( ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l: A. 2,80 lt B. 1,68 lt C. 4,48 lt D. 3,92 lt Cu 3: Cho 7,68 gam hn hp X gm Mg v Al vo 400 ml dung dch Y gm HCl 1M v H2SO4 0,5M. Sau khi phn ng xy ra hon ton thu c 8,512 lt kh ( ktc). Bit trong dung dch, cc axit phn li hon ton thnh cc ion. Phn trm v khi lng ca Al trong X l: A. 56,25 % B. 49,22 % C. 50,78 % D. 43,75 % Cu 4: Cho 0,10 mol Ba vo dung dch cha 0,10 mol CuSO4 v 0,12 mol HCl. Sau khi cc phn ng xy ra hon ton, lc ly kt ta nung nhit cao n khi lng khng i thu c m gam cht rn. Gi tr ca m l: A. 23,3 gam B. 26,5 gam C. 24,9 gam D. 25,2 gam Cu 5: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton 18 gam hn hp gm Fe v Cu trn theo t l mol 1 : 1 l: (bit phn ng to cht kh duy nht l NO) A. 1,0 lt B. 0,6 lt C. 0,8 lt D. 1,2 lt Cu 6: Ha tan 9,6 gam Cu vo 180 ml dung dch hn hp HNO3 1M v H2SO4 0,5M, kt thc phn ng thu c V lt ( ktc) kh khng mu duy nht thot ra, ha nu ngoi khng kh. Gi tr ca V l: A. 1,344 lt B. 4,032 lt C. 2,016 lt D. 1,008 lt

Cu 7: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l: A. 360 ml B. 240 ml C. 400 ml D. 120 ml Cu 8. Cho 3,87 gam hn hp Al v Mg vo 200 ml dung dch cha 2 axit HCl 1M v H2SO4 0,5M thu c dung dch B v 4,368 lt H2( ktc).Khi lng ca Al v Mg ln lt l : A. 2,43 v 1,44 gam B. 2,12 v 1,75 gam C . 2,45 v 1,42 gam D. 3,12 v 0,75 gam Cu 9: Ha tan hon ton 100 gam hn hp X gm Fe, Cu , Ag trong dung dch HNO3 (d). Kt thc phn ng thu c 13,44 lt hn hp kh Y gm NO2, NO, N2O theo t l s mol tng ng l 3 : 2 : 1 v dung dch Z (khng cha mui NH4NO3). C cn dung dch Z thu c m gam mui khan. Gi tr ca m v s mol HNO3 phn ng ln lt l: A. 205,4 gam v 2,5 mol B. 199,2 gam v 2,4 mol C. 205,4 gam v 2,4 mol D. 199,2 gam v 2,5 mol Cu 10: Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l: A. 1,92 gam B. 3,20 gam C. 0,64 gam D. 3,84 gam Cu 11: Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l: A. 38,34 gam B. 34,08 gam C. 106,38 gam D. 97,98 gam Cu 12. Cho 1,04 gam hn hp hai kim loi tan hon ton trong dung dch H2SO4 long, d thu c 0,672 lt kh H2 (ktc). Khi lng hn hp mui sunfat khan thu c l A. 3,92 gam. B. 1,96 gam. C. 3,52 gam. D. 5,88 gam Cu 13 Ho tan ht 7,8 gam hn hp Al, Mg trong dung dch HCl, thu c V lt kh H2 ( O0C v 2 atm) ng thi dung dch sau phn ng c khi lng tng thm 7 gam. 1.Gi tr ca V l : A. 2,24 lt B. 3,36 lt C. 4,48 lt D. 6,72 lt 2. Khi lng 2 kim loi Al v Mg ln lt l : A. 5,4 v 2,4 gam B. 6,6 v 1,2 gam C. 5, 2 v 2,6 gam D. 6,2 v 1,6 gam Cu 14 Ho tan ht 10,4 gam hn hp Mg, Fe bng 400 gam dung dch HCl 7,3% thu c 6,72 lt H2(ktc).Nng phn trm cc cht trong dung dch sau phn ng l : A. 2,23 % ; 3,2 % ; 4,46 % B. 4,64 % ; 3,1 % ; 1,78 % C. 3,12 % ; 5,13% ; 4,45 % D. 3,1% ; 4,46 % ; 2,13 % Cu 15. Ho tan ht m gam hn hp Mg, MgCO3 trong dung dch HCl 2M, thu c 4,48 lt hn hp kh A (ktc). T khi ca A so vi H2 l 11,5. Gi tr ca m l : A. 10,2 gam B. 10,4 gam C. 10,6 gam D. 10,8 gam Cu 16. Cho 37,2 gam hn hp gm Zn v Fe tc dng vi 2 lt dung dch H2SO40,5M ti phn ng hon ton. Th tch dung dch NaOH 1 M cn cho vo dd sau phn ng c kt ta ln nht l : A. 2 lt B. 3 lt C. 4 lt D. 5 lt Cu 17. Cho 19,2 gam Cu vo 500 ml dung dch NaNO3 1M, sau thm 500ml dung dch HCl 2M thu c kh NO v dung dch A. 1.Th tch kh NO (ktc) l : A. 2,24 lt B. 3,36 lt C. 4,48 lt D. 6,72 lt 2. Th tch dd NaOH 0,2 M kt ta ht Cu 2+ trong dung dch A l : A. 1 lt B. 2 lt C. 3 lt D. 4 lt DNG 2 BI TP V KIM LOI TC DNG VI DUNG DCH MUI Cu 1. Ngm mt inh st sch trong 200ml dung dch CuSO4 . Sau khi phn ng kt thc, ly dinh st ra khi dung dch ra sch nh bng nc ct v sy kh ri em cn thy khi lng inh st tng 0,8 gam so vi ban u. Nng mol ca dung dch CuSO4 dng l gi tr no di y? A. 0,05M. B. 0,0625M C. 0,50M D. 0,625M Cu 2: Ngm mt thanh Zn vo 100ml dung dch AgNO3 0,1M n khi AgNO3 tc dng ht, th khi lng thnh Zn sau phn ng so vi thanh Zn ban u s A. gim 0,755 B. tng 1,08 C. tng 0,755 D. tng 7,55 Cu 3. Cho t t bt Fe vo 50ml dung dch CuSO4 0,2M, khuy nh cho ti khi dung dch mt mu xanh. Khi lng bt Fe tham gia phn ng l: A. 5,6 gam. B. 0,056 gam. C. 0,56 gam. D. 0,28 gam Cu 4. Cho 2,24 gam bt Fe vo 200ml dung dch hn hp AgNO3 0,1M v Cu(NO3)2 0,5M. Khuy u ti phn ng hon ton, thu c cht rn A v dung dch B. 1.Khi lng cht rn A l : A. 4,08 gam B. 6, 16 gam C. 7,12 gam D. 8,23 gam

2. Nng mol ca cc cht trong dung dch B l : A. 0,20 M v 0,3 M B. 0,20M v 0,35 M C. 0,35 M v 0,45 M D. 0,35 M v 0,6 M Cu 5. Ngm mt inh st sch trong 200 ml dung dch CuSO4 . Sau khi phn ng kt thc, ly inh st ra khi dung dch, ra sch v lm kh nhn thy khi lng inh st tng thm 0,8 gam . Nng mol ca dung dch CuSO4 l : A.0,3 M B. 0,4M C. 0,5M D. 0,6M Cu 6. Ngm mt vt bng ng c khi lng 10 gam trong 250 gam dung dch AgNO3 4%. Khi ly vt ra th lng AgNO3 trong dung dch gim 1,7%. Khi lng ca vt sau phn ng l : A. 10,184 gam B. 10,076 gam C. 10 , 123 gam D. 10,546 gam Cu 7. Mt hn hp A gm Fe v Fe2O3. Nu cho lng kh CO d i qua a gam hn hp A un nng ti phn ng hon ton th thu c 11,2 gam Fe. Nu ngm a gam hn hp A trong dung dch CuSO4 d, phn ng xong ngi ta thu c cht rn c khi lng tng thm 0,8 gam . Gi tr ca a l : A. 6,8 gam B. 13,6 gam C. 12,4 gam D. 15,4 gam Cu 8. Ngm mt l km trong dung dch c ho tan 4,16 gam CuSO4 . Phn ng xong, khi lng l km tng 2,35%. Khi lng l km trc khi phn ng l. A. 80 gam.. B. 100 gam. C. 40 gam. D. 60 gam. Cu 9: Nhng mt thanh kim loi M ha tr II nng m gam vo dung dch Fe(NO3)2 th khi lng thanh kim loi gim 6 % so vi ban u. Nu nhng thanh kim loi trn vo dung dch AgNO3 th khi lng thanh kim loi tng 25 % so vi ban u. Bit gim s mol ca Fe(NO3)2 gp i gim s mol ca AgNO3 v kim loi kt ta bm ht ln thanh kim loi M. Kim loi M l: A. Pb B. Ni C. Cd D. Zn Cu 10: Cho m gam hn hp bt cc kim loi Ni v Cu vo dung dch AgNO3 d. Khuy k cho n khi phn ng kt thc thu c 54 gam kim loi. Mt khc cng cho m gam hn hp bt cc kim loi trn vo dung dch CuSO4 d, khuy k cho n khi phn ng kt thc, thu c kim loi c khi lng bng (m + 0,5) gam. Gi tr ca m l: A. 15,5 gam B. 16 gam C. 12,5 gam D. 18,5 gam Cu 11: Ha tan hn hp bt kim loi gm 8,4 gam Fe v 6,4 gam Cu vo 350 ml dung dch AgNO3 2M. Sau khi phn ng xy ra hon ton thu c m gam cht rn. Gi tr ca m l: A. 70,2 gam B. 54 gam C. 75,6 gam D. 64,8 gam Cu 12: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l: A. 2,80 gam B. 4,08 gam C. 2,16 gam D. 0,64 gam Cu 13: Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n khi cc phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi tr no ca x tho mn trng hp trn: A. 1,8 B. 1,5 C. 1,2 D. 2,0 Cu 14: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l: A. 17,8 v 4,48 B. 17,8 v 2,24 C. 10,8 v 4,48 D. 10,8 v 2,24 Bi -15 -Khuy 7,85 g hn hp bt kim loi Zn v Al vo 100 ml dd gm FeCl2 1M v CuCl2 0,75M th thy phn ng va vi nhau . V vy % khi lng ca Al trong hn hp l: (Zn = 65, Al = 27) A.17,2%. B.12,7%. C.27,1%. D.21,7% Bi -16 -Cho 1,1 gam hn hp bt nhm v bt st vi s mol nhm gp i s mol st vo 100 ml dung dch AgNO3 0,85M ri khuy u ti khi phn ng kt thc th thu c dung dch X. Nng mol ca Fe(NO3)2 trong X l: A.0,1M B.0,2M. C.0,05M D.0,025M DNG 3: BI TP IN PHN L thuyt Bi 1 in phn dung dch cha CuSO4 v MgCl2 c cng nng mol vi in cc tr . Hy cho bit nhng cht g ln lt xut hin bn catot v bn anot . A.Catot : Cu , Mg , Anot : Cl2 , O2 B Catot : Cu , H2, Anot : Cl2 , O2 C Catot : Cu , Mg , Anot : Cl2 , H2 D Catot : Cu , Mg , H2,Anot : ch c O2 Bi 2 in phn dung dch vi bnh in phn c in cc tr, mng ngn xp cc dung dch: (X1) KCl, (X2) CuSO4, (X3) KNO3, (X4) AgNO3, (X5) Na2SO4, (X6) ZnSO4, (X7) NaCl, (X8) H2SO4, (X9) NaOH, (X10) CaCl2 Sau khi in phn dung dch thu c qu tm ho l: A Tt c. B (X1), (X3), (X5), (X7). C (X2), (X4), (X6), (X8). D (X2), (X6), (X8). Bi 3 in phn dung dch cha CuSO4 v NaOH vi s mol : nCuSO4<(1/2) nNaOH , dung dch c cha vi git qu.in phn vi in cc tr.Mu ca dung dch s bin i nh th no trong qu trnh in phn ? A Tm sang . B sang xanh. C Xanh sang . D Tm sang xanh. Bi 6 Phng trnh in phn no sau l sai: A 4 AgNO3 + 2 H2O (in phn nng chy) --> 4 Ag + O2 + 4 HNO3 B 2 NaCl + 2 H2O (in phn nng chy) --> H2 + Cl2 + 2 NaOH (c vch ngn). C 2ACln (in phn nng chy) --> 2A + nCl2

D 4MOH (in phn nng chy)--> 4M + 2H2O Bi 7 iu ch Cu tinh khit t CuCO3.Cu(OH)2. a. Ho tan CuCO3.Cu(OH)2 vo axit H2SO4 ri cho dung dch thu c tc dng vi bt Fe. b. Nung CuCO3.Cu(OH)2 ri dng H2 kh nhit cao. c. Ho tan CuCO3.Cu(OH)2 trong axit HCl ri in phn dung dch thu c: A a, b. B b, c. C c. D a, b v c. Bi 8 Khi in phn dung dch KI c ln h tinh bt, hin tng quan st c sau thi gian in phn l: A Dung dch khng mu. B Dung dch chuyn sang mu hng. C Dung dch chuyn sang mu xanh. D Dung dch chuyn sang mu tm. Bi 10 Cho 4 dung dch mui : CuSO4 , ZnCl2 , NaCl , KNO3 . Khi in phn 4 dung dch trn vi in cc tr dung dch no s cho ta mt dung dch baz . A CuSO4 B ZnCl2 C NaCl D KNO3 Bi 15 in phn dung dch cha NaCl v HCl c thm vi git qu tm. Mu ca dung dch s bin i nh th no trong qu trnh in phn . A sang tm. B sang tm ri sang xanh. C sang xanh. D Ch mt mu . Bi 16 Cho dng in mt chiu i qua bnh in phn cha dung dch H2SO4 long xy ra qu trnh sau: A Oxi ho hidro. B Phn hu axit H2SO4. C Kh lu hunh. D Phn hu H2O. Bi 17 in phn dung dch cha H2SO4 trong mt thi gian ngn . pH ca dung dch bin i nh th no trong qu trng in phn ? A Gim mnh. B Tng nh. C Gn nh khng i. D Tng mnh. Bi 19 in phn dung dch H2SO4 (BP c in cc tr) sau mt thi gian thy pH dung dch gim dn so vi trc in phn, l do: A S in phn to ra thm mt lng axit. B Nc b phn tch gii phng nhiu H+. C Nc b phn tch thnh H2 v O2 thot ra. D Mt l do khc A, B v C Bi 20 in phn hon ton mt dung dch cha Ag2SO4, CuSO4, NiSO4, nhn thy kim loi bm catot theo th t ln lt l: A Ni, Cu, Ag. B Ag, Ni, Cu. C Ag, Cu, Ni. D Cu, Ni, Ag. Bi 23 in phn (in cc tr, mng ngn xp) dung dch X thy pH tng, dung dch Y thy pH gim. Vy dung dch X v dung dch Y no sau y ng: A (X) KBr, (Y) Na2SO4. B (X) AgNO3, (Y) BaCl2. C (X) BaCl2, (Y) CuSO4. D (X) NaCl, (Y) HCl. BI TP Cu 1: in phn vi in cc tr dung dch mui clorua ca mt kim loi ho tr (II) vi cng dng in 3A. Sau 1930 giy, thy khi lng ca catt tng 1,92 gam. Kim loi trong mui clorua trn l kim loi no di y? A. Ni . B. Zn . C. Fe . D. Cu Cu 2: in phn dung dch mui CuSO4 d trong thi gian 1930 giy, thu c 1,92 gam Cu catt. Cng dng in trong qu trnh in phn l gi tr no di y? A. 3,0A. B. 4,5A C. 1,5A D. 6,0A Cu 3: C 200 ml dd CuSO4 (d = 1,25) (dd A). Sau khi in phn dd A, khi lng ca dd gim i 8 gam. Mt khc, lm kt ta ht lng CuSO4 d sau phn ng in phn phi dng ht 1,12 lt H2S (ktc). Nng % v nng mol ca dd CuSO4 trc khi in phn l: A. 9,6; 0,75 B. 50; 0,5 C. 20; 0,2 D. 30; 0,55 Cu 4. in phn 200 ml dd CuSO4 vi cc in cc tr bng dng in mt chiu I = 19,3A. Khi th tch cc kh thot ra c hai in cc u bng 1,12 lt (ktc) th ngng in phn. 1. Khi lng kim loi (gam) sinh ra catot l : A. 0,32 B. 0,64 C. 3,2 D. 6,4 2. Thi gian in phn (s) l: A. 1000 B. 2000 C. 100 D. 200 3. Nng (M) ca dd CuSO4 l: A. 0,25 B. 2,5 C. 0,1 D. 1 Cu 5.Thc hin phn ng in phn dd cha m gam hh CuSO4 v NaCl vi in cc tr, bnh in phn c mng ngn, cng dng in I = 5A n khi nc b in phn ti c 2 in cc th ngng in phn. Dung dch sau khi in phn ho tan va 1,6 gam CuO v anot c 448 ml kh (ktc) thot ra. 1. m nhn gi tr l: A. 5,97 B. 3,785 C. 4,8 D. 4,95 2. Khi lng dd gim i trong qu trnh in phn l: A. 1,295 B. 2,45 C. 3,15 D. 3,59 3. Thi gian in phn l A. 196 B. 98 C. 1816 D. 1918 Cu 6 .in phn 200 ml dd A cha Fe2(SO4)3 0,5M v CuSO4 0,5M.Dung dch sau in phn tc dng va vi 10,2 gam Al2O3. 1. Khi lng kim loi thot ra catot l: A. 6,4 B. 5,6 C. 12 D. A khc 2. Th tch (lt) kh thot ra anot l:

A. 2,24 B. 3,36 C. 4,48 D. A khc. Cu 8. in phn (dng in cc tr) dd mui sunfat kim loi ho tr II vi I = 3A. Sau 1930s thy khi lng catot tng 1,92g. 1. Kim loi trong mui sunfat l: A. Cu B. Mg C. Zn D. Fe 2.Th tch (ml) ca lng kh to thnh ti Anot 25oC, 770 mmHg l: A. 252 B. 362 C. 372 D. 400 Cu 10. in phn 400 ml dd CuSO4 0,2M vi cng I = 10A. Sau thi gian t thy c 224 ml kh duy nht thot ra anot. Bit cc in cc tr v hiu sut in phn l 100%. (24, 25) 1. Khi lng (gam) catot tng ln l: A. 1,28 B. 0,32 C. 0,64 D. 3,2 2.Thi gian in phn (s) l: A. 482,5 B. 965 C. 1448 D. 1930 in phn 100 ml dd CuSO4 0,2M vi I = 9,65A, t = 2000s, H = 100%. 1. Khi lng (gam)Cu thu c catot l: A. 0,32 B. 0,96 C. 0,64 D. 0,16 2. Nu in phn ht lng CuSO4 trn th pH ca dd sau in phn l: A. 1 B. 0,7 C. 0,35 D. A khc DNG 4: BI TON V KIM LOI TC DNG VI NC, KIM LOI TC DNG VI DUNG DCH BAZ V MT S HP CHT CA NHM CU 1.Hn hp X gm Na, K, Ba ha tan ht trong nc d to dung dch Y v 5,6 lt kh ( ktc). Tnh V ml dung dch H2SO4 2M ti thiu trung ha Y A. 125 ml B. 100 ml C. 200 ml D. 150 ml Cu 2.Thc hin hai th nghim sau: Th nghim 1: Cho m gam hn hp Ba v Al vo nc d, thu c 0,896 lt kh ( ktc) Th nghim 2: Cng cho m gam hn hp trn cho vo dung dch NaOH d thu c 2,24 lt kh ( ktc) Cc phn ng xy ra hon ton. Gi tr ca m l: A. 2,85 gam B. 2,99 gam C. 2,72 gam D. 2,80 gam Cu 3. Ha tan hon ton 7,3 gam hn hp X gm kim loi Na v kim loi M (ha tr n khng i) trong nc thu c dung dch Y v 5,6 lt kh hiro ( ktc). trung ha dung dch Y cn dng 100 ml dung dch HCl 1M. Phn trm v khi lng ca kim loi M trong hn hp X l: A. 68,4 % B. 36,9 % C. 63,1 % D. 31,6 % Bi -3 -Rt t t 400 ml dung dch HCl 2M vo 200 ml dung dch NaAlO2 1M. Tnh khi lng kt ta thu c? (chn p n ng). A.15,6 gam B.7,8 gam C.11,7 gam D.Khng c kt ta. Bi -4-Cho mt lng bt nhm vo dung dch HCl d thu c 6,72 lit H2 (ktc). Cng lng bt nhm nu cho vo dung dch NaOH d th thu c th tch H2 l bao nhiu? A.2,24 lit. B.4,48 lit. C.6,72 lit. D.5,6 lit Bi -5 -C hn hp 3 cht rn: Mg, Al, Al2O3. Nu cho 9 gam hn hp tc dng vi dung dch NaOH d, sinh ra 3,36 lit kh H2. Nu cng cho mt lng hn hp nh trn tc dng vi dung dch HCl d, sinh ra 7,84 lit H2. Cc th tch kh u o ktc. tnh khi lng mi cht c trong hn hp. (chn p n ng) A.4,8 gam; 4,05 gam; 0,15 gam. B.2,4 gam; 1,35 gam; 5,25 gam C.4,8 gam; 2,7 gam; 1,5 gam. D.3,6 gam; 2,7 gam; 2,7 gam Bi -6 -Cho m gam hn hp X gm Na2O v Al2O3 tc dng hon ton vi H2O thu c 200 ml dung dch A ch cha mt cht tan duy nht c nng 0,5M. Thi kh CO2 d vo A thu c a gam kt ta.Tr s ca m v a ln lt l: A.8,3 gam v 7,2 gam. B.13,2 gam v 6,72 gam C.12,3 gam v 5,6 gam D.8,2 gam v 7,8 gam Bi -7 -Cho 15,6 gam hn hp A gm bt Al v Al2O3 tc dng va vi 200 ml dung dch KOH nng 2M. hy cho bit khi lng ca tng cht trong hn hp A? A.5,4 gam Al v 10,2 gam Al2O3 B.2,7 gam Al v 12,9 gam Al2O3 C.7,1 gam Al v 8,5 gam Al2O3 D.8,1 gam Al v 7,5 gam Al2O3 Bi -8 -Ha tan 12 gam hn hp Al2O3 v Al trong NaOH d thy khi lng dung dch sau phn ng tng thm 11,4 gam. Khi lng Al2O3 v Al trong hn hp ban u l: A.2 gam v 10 gam B.3,4 gam v 8,6 gam C.6,6 gam v 5,4 gam D.4,6 gam v 7,4 gam Bi -9 -Khi cho hn hp gm 3,45 gam Na v 1,35 gam Al vo nc d th th tch kh sinh ra iu kin tiu chun l: A.1,68 lt. B.2,8 lt. C.3,36 lt. D.3,92 lt Bi -10 -Cho 2,7 gam Al vo 100 ml dung dch NaOH 2,0 M thu c dung dch A. Thm dung dch cha 0,45 mol HCl vo dung dch A th lng kt ta thu c l: A.3,90 gam. B.1,30 gam. C.7,80 gam. D.2,34 gam Bi -11 -Cho bt nhm Al d vo 100ml dd hn hp gm NaOH 0,1M v Ba(OH)2 0,05M. Khi phn ng kt thc th tch kh H2 bay ra ktc l: A.0,672 lt. B.0,448 lt. C.0,336 lt. D.0,224 lt

Bi -12 -Hn hp X gm Na v Al v tin hnh hai th nghim sau: TN 1: Nu cho m gam X tc dng vi nc d th thu c V1 lt H2 TN 2: Nu cho m gam X tc dng vi dung dch NaOH d th thu c V2 lt H2 Cc th tch kh o cng iu kin. Quan h gia V1 v V2 l: A.V1 > V2. B.V1 V2. C.V1 < V2 D.V1 V2 Bi -13 -Cho m gam hn hp A gm Na2O v Al2O3 phn ng hon ton vi H2O thu c 200 ml dung dch A1 ch cha mt cht tan duy nht c nng 0,5 M. Thnh phn % theo khi lng ca Na2O v Al2O3 trong A l: A.37,8% v 62,2 % B.27,8% v 26,2 % C.17,8% v 62,6 %. D.38,7% v 32,2% Bi -14 -Mt dung dch hn hp cha a mol NaAlO2 v a mol NaOH tc dng vi mt dung dch cha b mol HCl. iu kin thu c kt ta sau phn ng l: A.a = b .B.a = 2b. C.b = 5a. D.a < b < 5a Bi -15 -Cho 0,54 gam Al vo 40 ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch X. Cho t t dung dch HCl 0,5M vo dung dch X thu c kt ta. thu c lng kt ta ln nht cn th tch dung dch HCl 0,5M l: A.110ml. B.90ml. C.70ml. D.80ml Bi -16 -Cho 31,2 hn hp bt Al v Al2O3 tc dng vi dung dch NaOH d, thu c 13,44 lit H2 (ktc). Hm lng nhm trong hn hp bng: A.17,30% B.34,615 %. C.51,915%. D.69,23% Bi -17 -Cho 31,2 hn hp bt Al v Al2O3 tc dng vi dung dch NaOH d, thu c 13,44 lit H2 (ktc). Phn trm khi lng bt nhm trong hn hp bng: A.85,675. B.65,385 %. C.34,615 %. D.17,31%. Bi -18 -Khi cho 100 ml dung dch HCl 0,2 M vo 200 ml dung dch NaAlO2 0,075 M khi lng kt ta thu c l: A.3,12 gam. B.0,52 gam. C.1,17 gam. D.0 gam Bi -19 -Cho 200 ml dung dch NaOH vo 200 ml dung dch 200 ml dung dch AlCl3 2M, thu c mt kt ta, nung kt ta n khi lng khng i c 5,1 gam cht rn. Nng mol/lt ca dung dch NaOH l: A.1,5 M v 7,5 M B.1,5 M v 3M. C.1M v 1,5 M. D.2M v 4M Bi -20-Cho 2,16 gam Al vo dung dch HNO3 long, va th thu c dung dch A v khng thy c kh thot ra. Thm dung dch NaOH vo dung dch A n khi lng kt ta nh nht th s mol NaOH dng l: A.0,16 mol. B.0,19 mol. C.0,32 mol. D.0,35 mol Bi -21 -M l mt kim loi kim. Hn hp X gm M v Al. Ly 3,72 gam hn hp X cho vo Nc d gii phng 0,16 gam kh v cn li 1,08 gam cht rn. M l A.K. B.Na . C.Rb . D.Cs Bi -22 -Cho m gam Na vo 200 gam dung dch Al2(SO4)3 1,71%. Phn ng kt thc thu c 0,01mol Al(OH)3 kt ta. Tnh m?

A.0,69

B.0,69 hoc 1,61

C.0,69 hoc 1,15

D.1,61

DNG 5: BI TP V XC NH TN KIM LOI Cu 1: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml kh NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l: A. NO v Mg B. NO2 v Al C. N2O v Al D. N2O v Fe Cu 2:Hn hp X gm hai mui cacbonat ca 2 kim loi kim th hai chu k lin tip. Cho 7,65 gam X vo dung dch HCl d. Kt thc phn ng, c cn dung dch th thu c 8,75 gam mui khan. Hai kim loi l: A. Mg v Ca B. Ca v Sr C. Be v Mg D. Sr v Ba Cu 3. Cho 6,45 gam hn hp hai kim loi A v B ( u c ho tr II ) tc dng vi dung dch H2SO4 long d, sau khi phn ng xong thu c 1,12 lt kh ktc v 3,2 gam cht rn. Lng cht rn ny tc dng va vi 200 ml dung dch AgNO3 0,5M. Hai kim loi A v B l :` A. Mg , Cu B. Cu , Zn C. Ca , Cu D. Cu , Ba Cu 4. Cho 2,23 gam hn hp hai kim loi A, B tc dng vi dung dch HCl d, gii phng 0,56 lt kh H2 (ktc). Phn cht rn cn li c khi lng 1,08 gam cho tc dng vi dung dch HNO3 c nng thu c 0,224 lt kh duy nht (ktc) . Hai kim loi A v B l : A. Na, Cu B. Mg , Cu C. Na , Ag D. Ca , Ag Cu 5. Nung nng 1,6 gam kim loi X trong khng kh ti phn ng hon ton thu c 2 gam oxit.Cho 2,8 gam kim loi Y tc dng vi clo thu c 8,125 gam mui clorua. Hai kim loi X v Y l : A. Cu , Mg B. Cu , Zn C. Cu , Na D. Cu, Fe Cu 6. C 5,56 gam hn hp A gm Fe v mt kim loi M ( c ho tr n khng i ). Chia A lm hai phn bng nhau: Phn mt ho tan ht trong dung dch HCl c 1,568 lt(ktc) kh H2. Phn hai ho tan ht trong dung dch HNO3 long thu c 1,344 lt (ktc) kh NO duy nht v khng to ra NH4NO3 trong dung dch . Kim loi M l : A. Mg B. Al C. Cu D. Zn Cu 7. Cho 25,9 gam hn hp X gm bt S v mt kim loi M ho tr 2 vo bnh kn khng c khng kh, t nng bnh cho n khi phn ng hon ton thu c cht rn A. Bit A tan hon ton trong dung dch HCl d thu c 6,72 lt kh B (ktc). T khi ca B so vi hiro l

35 . Kim loi M cn tm l : 3

A. Mg

B. Zn

C. Fe

D. Al

Cu 8. Chia 7,22 gam hn hp X gm Fe v kim loi M c ho tr khng i thnh hai phn bng nhau.Phn 1 ho tan ht trong dung dch HCl thu c 2,128 lt kh hiro(ktc) .Phn 2 ho tan ht trong dung dch HNO3 thu c 1,792 lt (ktc) kh NO duy nht .Kim loi M cn tm l : A. Mg .B. Al C. Zn D. Cu Cu 9. Ho tan hon ton 62,1 gam kim loi M trong dung dch HNO3 long thu c 16,8 lt hn hp kh X (ktc) gm hai kh khng mu, khng ho nu trong khng kh .T khi ca X xo vi H2 l 17,2. Kim loi M l : A. Cu . B. Mg .C. Al .D. Zn Cu 10.Hn hp X gm Mg v kim loi M. Ha tan hon ton 8 gam hn hp X cn va 200 gam dung dch HCl 7,3 %. Mt khc cho 8 gam hn hp X tc dng hon ton vi kh Cl2 cn dng 5,6 lt Cl2 ( ktc) to ra hai mui clorua. Kim loi M v phn trm v khi lng ca n trong hn hp X l: A. Al v 75 % B. Fe v 25 % C. Al v 30 % D. Fe v 70 % Cu 11.Ha tan hon ton 6 gam hn hp X gm Fe v mt kim loi M (ha tr II) vo dung dch HCl d, thu c 3,36 lt kh H2 ( ktc). Nu ch ha tan 1,0 gam M th dng khng n 0,09 mol HCl trong dung dch. Kim loi M l: A. Mg B. Zn C. Ca D. Ni Cu 12. ha tan hon ton 6,834 gam mt oxit ca kim loi M cn dng ti thiu 201 ml dung dch HCl 2M. Kim loi M l: A. Mg B. Cu C. Al D. Fe Cu 13. Ngm mt l km nh trong mt dung dch c cha 1,12 g ion kim loi c in tch 2+. Phn ng xong, khi lng l km gim i 0,18 g. Ion kim loi trong dung dch l ion ca nguyn t: A.Cu. B.Fe. C.Ni. D.Pb DNG 6 OXITAXIT V AXIT NHIU NC TC DNG VI DUNG DCH KIM, CC HP CHT CA NHM Cu 1. Dung dch c cha a mol NaOH tc dng vi dd c cha b mol H3PO4 sinh ra mui axit. T l a/b l: a a a a A. 1 < <2 B. 3 C. 2 < <3 D. 1 b b b b Cu 2. Cho 44 gam dung dch NaOH 10% vo 10 gam dung dch H3PO4 39,2 %. Sau phn ng trong dung dch c mui: A. Na2HPO4 C. Na3PO4 v Na2HPO4 B. NaH2PO4 D. Na2HPO4 v NaH2PO4 Cu 3.t chy 6,2 gam photpho ri ho tan sn phm vo 200 gam dung dch H3PO4 10% th thu c dung dch A. Nng % ca dung dch A l: A. 18,5 % B. 19,8 % C. 19,2 % D.14,9 % Cu 4.Sc 8,96 lit CO2 (ktc) vo 400 ml dung dch NaOH 1,25 M. Dung dch thu c cha cc cht: A.NaHCO3 B.Na2CO3 C.NaHCO3, Na2CO3 D.Na2CO3, NaOH Cu 5.Cho 12 gam dung dch NaOH 10% tc dng vi 5,88 gam dung dch H3PO4 20% thu c dung dch X. dung dch X cha cc mui sau: A.Na3PO4 B.Na2HPO4 C.NaH2PO4, Na2HPO4. D.Na2HPO4, Na3PO4 Cu 6.Ho tan 174 gam hn hp mui cacbonat v mui sunfit ca 1 kim loi kim vo dung dch HCl d. Ton b kh thot ra (gm CO2 v SO2) c hp th bi mt lng ti thiu l 500 ml dung dich KOH 3M. Xc nh kim loi kim? A.Na. B.Li. C.Cs. D.K Cu 7-Cho V lt kh CO2 (ktc) hp th ht vo 100 ml dung dch Ca(OH)2 0,7M, kt thc th nghim thu c 4g kt ta. Gi tr ca V l: A.1,568 lt.B.1,568 lt hoc 0,896 lt.C.0,896 lt.D.0,896 lt hoc 2,240 lt Cu 8.Cho 6,72 lt CO2 (ktc) tc dng vi 400ml dd NaOH 1M thu c: A.10,6 g Na2CO3 v 16,8 g NaHCO3.. B.21,2 g Na2CO3 v 8,4 gNaHCO3. C.31,8 g Na2CO3 v 4,0 g NaOH d. D.34,8 g NaHCO3 v 4,4 g CO2 d Cu 9.Hp th hon ton 2,24 lt kh CO2 ( ktc) vo dung dch cha 8 gam NaOH, thu c dung dch X. Khi lng mui tan c trong dung dch X l (Cho C = 12, O = 16, Na = 23) A. 10,6 gam. B. 5,3 gam. C. 21,2 gam. D. 15,9 gam. Cu 10: Hp th hon ton 4,48 lt kh SO2 ( ktc) vo dung dch cha 16 gam NaOH thu c dung dch X. Khi lng mui tan thu c trong dung dch X l (Cho H = 1, O = 16, Na = 23, S = 32) A. 20,8 gam. B. 23,0 gam. C. 25,2 gam. D. 18,9 gam. Cu 11: Cho 100 gam CaCO3 tc dng vi axit HCl d. Kh thot ra hp th bng 200 gam dung dch NaOH 30%. Lng mui Natri trong dung dch thu c l A. 10,6 gam Na2CO3 B. 53 gam Na2CO3 v 42 gam NaHCO3 C. 16,8 gam NaHCO3 D. 79,5 gam Na2CO3 v 21 gam NaHCO3 Cu 12: Dn kh CO2 iu ch c bng cch cho 10 gam CaCO3 tc dng vi dung dch HCl d i vo dung dch c cha 8 gam NaOH. Khi lng mui Natri iu ch c A. 5,3 gam. B. 9,5 gam. C. 10,6 gam. D. 8,4 gam. Cu 13: Nung 13,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht rn v kh X. Lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng l A. 5,8 gam. B. 6,5 gam. C. 4,2 gam. D. 6,3 gam. Cu 14: Cho 10 lt hn hp kh (ktc) gm CO2 v 68,64% CO v th tch i qua 100 gam dung dch Ca(OH)2 7,4% thy tch ra m gam kt ta. Tr s ca m bng

A. 10 gam. B. 8 gam. C. 6 gam. D. 12 gam. Cu 15: Thi V lt (ktc) kh CO2 vo 300 ml dung dch Ca(OH)2 0,02M th thu c 0,2 gam kt ta. Gi tr ca V l: A. 44,8 ml hoc 89,6 ml B. 224 ml C. 44,8 ml hoc 224 ml D. 44,8 ml Cu 16: Dn V lit CO2 (ktc) vo dung dch Ca(OH)2 thu c 25 gam kt ta v dung dch X, un nng dung dch li thu thm c 5 gam kt ta na. Gi tr ca V l A. 7,84 lit B. 11,2 lit C. 6,72 lit D. 5,6 lit Cu 17: Hp th hon ton 2,688 lt kh CO2 ( ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l, thu c 15,76 gam kt ta. Gi tr ca a l (cho C = 12, O = 16, Ba = 137) A. 0,032. B. 0,04. C. 0,048. D. 0,06. DNG 7: PHN NG NHIT LUYN Cu 1: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l A. 0,448. B. 0,112. C. 0,224. D. 0,560. Cu 2: Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l A. 1,120. B. 0,896. C. 0,448. D. 0,224. Cu 3: Cho kh CO kh hon ton n Fe mt hn hp gm: FeO, Fe 2O3, Fe3O4 thy c 4,48 lt CO2 (ktc) thot ra. Th tch CO (ktc) tham gia phn ng l A. 1,12 lt. B. 2,24 lt. C. 3,36 lt. D. 4,48 lt. Cu 4: Thi mt lung kh CO i qua ng s ng m gam hn hp Fe3O4 v CuO nung nng thu c 2,32 gam hn hp rn. Ton b kh thot ra cho hp th ht vo bnh ng dung dch Ca(OH)2 d thu c 5 gam kt ta. Gi tr ca m l: A. 3,22 gam. B. 3,12 gam. C. 4,0 gam. D. 4,2 gam. Cu 5: kh hon ton 30 gam hn hp CuO, FeO, Fe2O3, Fe3O4, MgO cn dng 5,6 lt kh CO ( ktc). Khi lng cht rn sau phn ng l A. 28 gam. B. 26 gam. C. 22 gam. D. 24 gam. Cu 6: Kh hon ton 17,6 gam hn hp X gm Fe, FeO, Fe2O3 cn 2,24 lt CO ( ktc). Khi lng st thu c l A. 5,6 gam. B. 6,72 gam. C. 16,0 gam. D. 8,0 gam. Cu 7: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al 2O3 nung nng n khi phn ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l A. 0,8 gam. B. 8,3 gam. C. 2,0 gam. D. 4,0 gam. Cu 8. Cho dng kh CO d i qua hn hp (X) cha 31,9 gam gm Al2O3, ZnO, FeO v CaO th thu c 28,7 gam hn hp cht rn (Y). Cho ton b hn hp cht rn (Y) tc dng vi dung dch HCl d thu c V lt H2 (kc). Gi tr V l A. 5,60 lt. B. 4,48 lt. C. 6,72 lt. D. 2,24 lt. Cu 9. kh hon ton 45 gam hn hp gm CuO, FeO, Fe 3O4, Fe v MgO cn dng va 8,4 lt CO (ktc). Khi lng cht rn thu c sau phn ng l: A. 39g B. 38g C. 24g D. 42g Bi -10 -Tnh khi lng bt nhm cn dng c th iu ch c 78 gam crom bng phng php nhit nhm. A.20,250 gam B.35,695 gam C.81,000 gam .D.40,500 gam Bi -11 - Phng php nhit nhm l phng php rt thng dng iu ch nhiu kim loi. T Cr2O3 iu ch c 78 gam crom vi hiu sut 80 %, cn dng khi lng nhm bng: A.36 gam B.45 gam C.50,625 gam D.81 gam Bi -12 -Nung hn hp bt gm 15,2 gam Cr2O3 v Al nhit cao. Sau khi phn ng xy ra hon ton thu c 23,3 gam hn hp cht rn X. Cho ton b X phn ng vi dung dch HCl d thy thot ra V lt kh H2 ( ktc). Gi tr ca V l: A.7,84 lt.B.5,60 lt.C.10,08 lt.D.8,96 lt Bi -13 -Cho hh kim loi gm( 2,7 gam Al ) v (30,4 gam FeO, Fe3O4). Tin hnh nhit nhm hon ton c hh A. Cho A t/d vi HNO3 d thu c 0,5 mol NO2. Tm thnh phn phn trm ca mi oxit st trong hh 30,4 gam. A.%FeO = 26,32%,%Fe3O4 = 73,68%.B.%Fe3O4 = 26,32%,%FeO = 73,68% C.%Fe3O4 = 23,68%,%FeO = 76,32%.D.%FeO = 23,68%,%Fe3O4 = 76,32% DNG 8: DNG BI TP S TNG TC GIA CC ION TRONG DUNG DCH Bi -1 -Cho V ml dd HCl 1M vo 100ml dd NaAlO2 1,5 M th thy to thnh 7,02g kt ta. Gi tr V l: (H=1, Al=27, O=16):. A.90ml hoc 330ml B.Ch 240ml C.Ch 420ml D.270ml hoc 510ml Bi -2 -Mt dung dch A c cha 5 iom gm (Mg2+; Ba2+; Ca2+ v 0,15 mol Cl-; 0,25 mol NO3-). Khi cho V ml dung dch K2CO3 1M vo dung dch A ti khi thu c kt ta ln nht. Gi tr ca V l: A.150 ml. B.200ml. C.250 ml. D.300 ml Bi -2 -Khi cho rt t t 300 ml dung dch HCl 1M vo 500 ml dung dch Na2CO3 0,4M n khi kt thc phn ng, thu c dung dch X v kh Y. Khi cho thm dung dch Ba(OH)2 d vo X, th thu c m gam kt ta. Gi tr ca m l: A.1,97 gam. B.19,7 gam. C.9,85 gam. D.4,93 gam

Bi -3 -Cho dung dch X cha 0,1 mol Al3+, 0,2 mol Mg2+, 0,2 mol NO3-, x mol Cl-, y mol Cu2+ - Nu cho dung dch X tc dng vi dung dch AgNO3 d th thu c 86,1 gam kt ta - Nu cho 850 ml dung dch NaOH 1M vo dung dch X th khi lng kt ta thu c l: A.26,4 gam. B.25,3 gam. C.20,4 gam. D.21,05 gam Bi -4 -Cho 11,1 gam hn hp hai mui sunft trung ho ca 2 kim loi kim hai chu k lin tip tan hon ton trong dung dch HCl d thu c 2,24 lt kh SO2(ktc). Hai kim loi l: A.Li,Na B.Na,K.C.K,Cs. D.Na, Cs Bi -5 -Thm 23,7 gam NH4Al(SO4)2 vo 225 ml dung dch Ba(OH)2 1M, ri un si dung dch. Sau khi cc phn ng xy ra hon ton, khi lng kt ta thu c l A.78,0 gam B.46,6 gam C. 50,5 gam D.64,0 gam Bi -6 -Ha tan hon ton 5,94g hn hp hai mui clorua ca hai kim loi A, B u thuc nhm IIA vo nc c dung dch X. kt ta ht ion Cl- c trong dung dch X ngi ta cho ton b lng dung dch X trn tc dng va vi dung dch AgNO3. Kt thc th nghim, thu c dung dch Y v 17,22g kt ta. C cn dung dch Y, khi lng mui khan thu c l: A.4,68g B.7,02g. C.9,12g. D.2,76g Bi -7 -Cho x mol Na vo dung dch cha y mol Cu(NO3)2 v z mol AgNO3 (vi x = 2y + z) cho n khi cc phn ng xong, th thu c A.x/4 mol Cu v x/2 mol Ag B.y/2 mol Cu v z/2 mol Ag2O C. x/2 mol kh H2, y mol Cu(OH)2 v z/2 mol Ag2O D.x/2 mol kh H2 v (x + y + z)mol mui Bi -8 -Trong mt cc nc cha a mol Ca2+, b mol Mg 2+, c mol Cl- v d mol HCO3-.Nu ch dng nc vi trong nng p mol/l lm gim cng trong cc, th ngi ta thy khi cho V lt nc vi trong vo, cng bnh l b nht, bit c = 0. Biu thc lin h gia a, b v p l : A.V = (b + a) / p. B.V = (2a + b) / p. C.V = (3a + 2b) / 2p. D.V = (2b + a) / p Bi -9 - Ho tan 12,5 g hai mui KCl v KBr vo nc ri cho tc dng va vi dung dch AgNO3, thu c 20,78 g hn hp 2 mui mi. Hm lng % mui KCl bng: A.11,92. B.23,84. C.38,08 D.76,16 DNG 8: CC NGUYN T PHI KIM V HP CHT CA CHNG Cu 1. Trong phng th nghim, ngi ta thng iu ch clo bng cch. A. in phn dung dch NaCl c mng ngn. B. cho dung dch HCl c tc dng vi MnO2, un nng. C. in phn nng chy NaCl. D. cho F2 y Cl2 ra khi dung dch NaCl. Cu 2. Trong phng th nghim, ngi ta iu ch oxi bng cch. A. nhit phn KClO3 c xc tc MnO2 B. nhit phn Cu(NO3)2. C. in phn nc. D. chng ct phn on khng kh lng. Cu 3. ng dng no sau y khng phi ca ozon? A. iu ch oxi trong phng th nghim. B. Ty trng tinh bt, du n. C. St trng nc sinh hot. D. Cha su rng. Cu 4. Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng dung dch amoni nitrit bo ho. Kh X l A. N2O. B. N2. C. NO2. D. NO. Cu 5. Trong phng th nghim, ngi ta thng iu ch HNO3 t. A. NaNO3 v H2SO4 c. B. NaNO2 v H2SO4 c. C. NH3 v O2. D. NaNO3 v HCl c. Cu 6. Cho Cu v dung dch H2SO4 long tc dng vi cht X (mt loi phn bn ha hc), thy thot ra kh khng mu ha nu trong khng kh. Mt khc, khi X tc dng vi dung dch NaOH th c kh mi khai thot ra. Cht X l A. amophot. B. ure. C. natri nitrat. D. Amoni nitrat Cu 7. Phn bn no sau y lm tng chua ca t? A. NaNO3. B. NH4NO3 C. KCl. D. K2CO3. Cu 8. Thnh phn chnh ca qung photphorit l A. Ca(H2PO4)2. B. CaHPO4. C. NH4H2PO4. D. Ca3(PO4)2 Cu 9. Pht biu no sau y l ng? A. Phn ln cung cp nit ho hp cho cy di dng ion nitrat (NO3-) v ion amoni (NH4+). B. Amophot l hn hp cc mui (NH4)2HPO4 v KNO3. C. Phn hn hp cha nit, photpho, kali c gi chung l NPK. D. Phn ur c cng thc l (NH4)2CO3. Cu 10. Phn bn nitrophotka (NPK) l hn hp ca. A. (NH4)2HPO4 v KNO3. B. (NH4)2HPO4 v NaNO3. C. (NH4)3PO4 v KNO3. D. NH4H2PO4 v KNO3. \ Cu 12. Cho cc phn ng sau:

t 4HCl + MnO2 MnCl2 + Cl2 + 2H2O.

o

2HCl + Fe FeCl2 + H2.

t 14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O. 6HCl + 2Al 2AlCl3 + 3H2. 16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O. S phn ng trong HCl th hin tnh oxi ha l A. 3. B. 1. C. 2. D. 4. Cu 13. Cho cc phn ng sau: (a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O. (b) HCl + NH4HCO3 NH4Cl + CO2 + H2O. (c) 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O. (d) 2HCl + Zn ZnCl2 + H2. S phn ng trong HCl th hin tnh kh l A. 2. B. 3. C. 4. D. 1. Cu 14. Cho cc phn ng : t t (1) O3 + dung dch KI (2) F2 + H2O . t (3) MnO2 + HCl c Cc phn ng to ra n cht l : A. (1), (2), (3) B. (1), (2), (4) Cu 15. Phn ng nhit phn khng ng l : t A. 2KNO3 2KNO2 + O2. t C. NH4NO2 N2 + 2H2O. Cu 16. Trng hp khng xy ra phn ng ha hc l
o 0 0 0 0 0

t (4) Cl2 + dung dch H2S

C. (1), (3), (4).

0

D. (2), (3), (4).

t B.NaHCO3 NaOH + CO2 t D. NH4Cl NH3 + HCl

0

t A. 3O2 + 2H2S 2SO2 + 2H2O .B. FeCl2 + H2S FeS + 2HCl C. O3 + 2KI + H2O O2 + 2KOH + I2. D. Cl2 + 2NaOH NaCl + NaClO + H2O. Cu 17. Dy gm cc cht u tc dng c vi dung dch HCl long l: A. AgNO3, (NH4)2CO3, CuS.B. FeS, BaSO4, KOH. C. KNO3, CaCO3, Fe(OH)3. D. Mg(HCO3)2, HCOONa, CuO. Cu 18. Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l A. CaOCl2. B. K2Cr2O7 C. MnO2. D. KMnO4.

Cu 20. Cht kh X tan trong nc to ra mt dung dch lm chuyn mu qu tm thnh v c th c dng lm cht ty mu. Kh X l A. CO2. B. O3. C. SO2 D. NH3. Cu 21. SO2 lun th hin tnh kh trong cc phn ng vi. A. O2, nc Br2, dung dch KMnO4 B. dung dch NaOH, O2, dung dch KMnO4. C. dung dch KOH, CaO, nc Br2. D. H2S, O2, nc Br2. Cu 22. Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca V l A. 2,80/ B. 3,08. C. 3,36. D. 4,48. Cu 23. Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100oC. Sau khi phn ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l A. 0,24M. B. 0,48M. C. 0,2M. D. 0,4M. Cu 24. Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l A. 47,2%. B. 58,2%. C. 52,8%. D. 41,8%. =========================================== 9. CU TO NGUYN T BNG TUN HON LIN KT HA HC Cu 5: Cc pht biu sau, pht biu no ng: a/ Trong 1 nguyn t lun lun s proton bng s electron bng in tch ht nhn. b/ Tng s proton v s electron trong 1 ht nhn c gi l s khi. c/ S khi A l khi lng tuyt i ca nguyn t. d/ ng v l cc nguyn t c cng s proton nhng khc s ntron. Cu 6: Mnh no say y ng ? a/ Nguyn t ca cc nguyn t trong cng mt nhm bao gi cng c s electron lp ngoi cng bng nhau. b/ S th t nhm A bng s electron lp ngoi cng ca nguyn t nguyn t trong nhm . c/ Cc nguyn t trong cng mt nhm c tnh cht ha hc tng t nhau

d/ Trong mt nhm,nguyn t ca hai nguyn t thuc hai chu k lin tip hn km nhau 1 lp e Cu 7. Chn pht biu sai sau y v bng HTTH cc nguyn t ho hc: A. Cc nguyn t cng mt PNC c tnh cht tng t nhau B. Cc nguyn t trong cng chu k c tnh cht tng t nhau C. Cc nguyn t cng PNC c tnh kh tng dn t trn xung. D. Cc nguyn t trong bng HTTH c sp xp theo chiu tng dn thn cc nguyn t Cu 8. Nguyn t A c cu hnh electron phn lp cui cng l 4p3. A phi A. thuc phn nh IIIA, c s oxyho dng cao nht +3 v khng c s oxyho m B. thuc phn nhm IIIB, c s oxyho dng cao nht +3 v c s oxyho m thp nht -3 C. thuc phn nhm VB, c s oxyho dng cao nht +5 v c s oxyho m thp nht -3 D. thuc phn nhm VA, c s oxyho dng cao nht +5 v c s oxyho m thp nht -3 Cu 98: Nhng cu no sau y khng ng? A. Nguyn t ca cc nguyn t trong cng nhm c s electron ngoi cng bng nhau. B.Nguyn t ca cc nguyn t trong cng phn nhm c s electron ngoi cng bng nhau. C. Tnh cht ho hc ca cc nguyn t trong cng nhm bao gi cng ging nhau. D.Tnh cht ho hc ca cc nguyn t trong cng phn nhm bao gi cng ging nhau. Cu 10: Cho nguyn t cc nguyn t A, B, C, D, E, F ln lt c cu hnh e nh sau : A : 1s22s22p63s1 B : 1s22s22p63s23p64s2 C : 1s22s22p63s23p64s1 2 2 6 2 5 2 2 6 2 6 6 2 D : 1s 2s 2p 3s 3p E : 1s 2s 2p 3s 3p 3d 4s F : 1s22s22p6 Cc nguyn t no thuc cng mt phn nhm chnh? a) A, C b) B, E c) C, D d) A, B, C, E Cu 11 : Cho nguyn t cc nguyn t A, B, C, D, E, F ln lt c cu hnh e nh sau : A : 1s22s22p63s1 B : 1s22s22p63s23p64s2 C : 1s22s22p63s23p64s1 2 2 6 2 5 2 2 6 2 6 6 2 D : 1s 2s 2p 3s 3p E : 1s 2s 2p 3s 3p 3d 4s F : 1s22s22p6 Cc nguyn t kim loi gm :a) A, D, F b) B, C, E c) C, E d) A, B, C, E Cu 12: Cho nguyn t cc nguyn t X1, X2, X3, X4, X5, X6 ln lt c cu hnh e nh sau : X1 : 1s22s22p63s2 X2 : 1s22s22p63s23p64s1 X3 : 1s22s22p63s23p64s2 2 2 6 2 5 2 2 6 2 6 6 2 X4 : 1s 2s 2p 3s 3p X5 : 1s 2s 2p 3s 3p 3d 4s X6 : 1s22s22p63s23p4 Cc nguyn t cng mt phn nhm chnh l : a) X1, X2, X6 b) X1, X2 c) X1, X3 d)X1, X3, X5 Cu 13 : Cho nguyn t cc nguyn t X1, X2, X3, X4, X5, X6 ln lt c cu hnh e nh sau : X1 : 1s22s22p63s2 X2 : 1s22s22p63s23p64s1 X3 : 1s22s22p63s23p64s2 X4 : 1s22s22p63s23p5 X5 : 1s22s22p63s23p63d64s2 X6 : 1s22s22p63s23p4 Cc nguyn t cng mt chu k l : a) X1, X3, X6 b) X2, X3, X5 c) X1, X2, X6 d) X3, X4 Cu 14 : Nguyn t ca nguyn t kim loi X c 2 electron ho tr. Nguyn t ca nguyn t phi kim Y c 5 electron ho tr. Cng thc hp cht to bi X, Y c th l : a) X2Y5 b) X5Y2 c ) X2Y3 d) X5Y3 10 11 Cu 15:Bo c 2 ng v 5B v 5B ; B =10,812 .C c 94 nguyn t 105B th c bao nhiu nguyn t 115B A/ 406 B/ 460 C/ 19 D/ 81 Cu 16: C cc ng v : 11H; 21H; 31H; 3517Cl; 3717Cl .Hi c th to ra bao nhiu loi phn t HCl khc nhau? A/ 8 B/ 12 C/ 6 D/ 9 Cu 17:Trong nguyn t ca 1 nguyn t c cu to bi 115 ht trong s ht mang in nhiu hn ht khng mang in l 25 ht. S khi ca nguyn t l: A/ 45 B/ 40 C/ 42 D/ tt c sai. Cu 18: Cho bit trong cc nguyn t ca cc nguyn t X, Y, Z c electron mc nng lng cao nht c xp vo cc phn lp c cu hnh electron l: 2p3(X); 4s1(Y); 3d1(Z). V tr cc nguyn t trn trong HTTH cc nguyn t ha hc l: a) X chu k 2, nhm IIIA; Y chu k 4, nhm IA ; Z chu k 4, nhm IIIB. b) X chu k 2, nhm VA; Y chu k 4, nhm IA; Z chu k 3, nhm IIIA. c) X chu k 2, nhm VA; Y chu k 4, nhm IA; Z chu k 4 , nhm IIIB. d) Tt c u sai. Cu 19 : Hp cht kh vi hiro ca R c dng RH2n . Oxit cao nht ca R c dng : a) RO4-n b) RO2n c) RO8-n d) RO8-2n Cu 20: Oxit cao nht ca R c dng R2On, hp cht kh vi hiro ca R c dng : a) RHn b) RH2n c) RH8-n d) RH8-2n Cu 21: Xt 3 nguyn t c cu hnh electron ln lt l: (X): 1s2 2s2 2p6 3s1 ; (Y): 1s2 2s2 2p6 3s2; (Z): 1s2 2s2 2p6 3s2 3p1 Hiroxit ca X, Y, Z xp theo th t tnh baz tng dn l A. XOH < Y(OH)2 < Z(OH)3 B. Y(OH)2 < Z(OH)3 < XOH C. Z(OH)3 < Y(OH)2 < XOH D. Z(OH)2 < Y(OH)3 < XOH Cu 22 : A, B l 2 nguyn t ca 2 nguyn t. Tng s ht c bn ca A v B l 191, hiu s ht c bn ca A v B l 153. Bit s ht khng mang in trong A gp 10 ln s ht khng mang in trong B. S khi ca A, B ln lt l :

a) 121, 13 b) 22, 30 c) 23, 34 d) 39, 16 Cu 23: C 2 kim loi: X ho tr II, Y ho tr III. Bit tng s proton, notron v electron ca nguyn t X l 36, ca nguyn t Y l 40. Xc nh tn nguyn t X v Y A. Mg, Al B. Ca, Mg C. Mg, K D. Cu, Al 12 13 Cu 24: trng thi t nhin cacbon cha hai ng v 6 C v 6 C . Bit khi lng nguyn t trung bnh ca cacbon M =12,011.Xc nh thnh phn % cc ng v: A. 98% v 12% B. 50% v 50% C. 98,9% v 1,1% D. 0,98% v 99,2% E. 25% v 75% Cu 25: Khi lng nguyn t trung bnh ca nguyn t R l 79,91. R c 2 ng v . Bit 79R chim 54,5%. Tm khi lng nguyn t ( s khi) ca ng v th 2. a) 80 b) 81 c) 82 d) p s khc 63 65 Cu 26. Trong t nhin, nguyn t Cu c 2 ng v l Cu (72,7%) v Cu (27,3%). Nguyn t khi trung bnh ca Cu l A. 63,54 B. 63,456 C. 63,465 D. 63,546 Cu 27. Nguyn t bc c 2 ng v 109Ag v 107Ag. Bit 107Ag chim 44%. Vy khi lng nguyn t trung bnh ca nguyn t Ag l: a. 106,8 b. 107,88 c. 108 d. 109,5 Cu 28: Magie trong thin nhin gm 2 loi ng v l X, Y. ng v X c khi lng nguyn t l 24. ng v Y hn X mt ntron. Bit s nguyn t ca hai ng v c t l X/Y = 3/2. Khi lng nguyn t trung bnh ca Mg l: a) 24 b) 24,4 c) 24,2 d) 24,3 Cu 29: Cho cc phn t sau: N2 , AgCl , HBr , NH3 , H2O2 , NH4NO2 . Phn t no c lin kt cho nhn: a) NH4NO2 b) NH4NO2 v N2 c) NH4NO2 v H2O2 d) N2 v AgCl Cu 30: Hy cho bit trong cc phn t sau y, phn t no c phn cc ca lin kt cao nht : CaO, MgO, CH4 , AlN, N2 , NaBr , BCl3 , AlCl3. Cho bit m in : O(3,5); Cl(3,0); Br(2,8); Na(0,9); Mg(1,2); Ca(1,0); C(2,5); H(2,1); Al(1,5); N(3,0); B(2,0). a) CaO b) NaBr c) AlCl3 d) MgO =================================================== 10 PHN NG OXI HO KH Cu 1.Cn bng hai phng trnh phn ng sau bng phng php in t : KClO3 + HCl -> Cl2 + KCl + H2O Cc h s theo th t cc cht ln lt l: A. 2,3,3,1,3 B. 1,3,3,1,3 C. 2,6,3,1,3 D. 1,6,3,1,3 Cu 2.Cn bng phng trnh phn ng sau bng phng php thng bng electron: FeS2 + HNO3 +HCl -> FeCl3 +H2SO4 + NO + H2O Cc h s theo th t cc cht ln lt l: A. 2,5,2,2,5,2,2 B. 2,5,3,2,3,5,2 C. 3,5,3,3,4,4,3 D. 1,5,3,1,2,5,2 Cu 3.Cho cc phn ng ha hc sau: Cu + HCl +NaNO3 -> CuCl2+ NO + NaCl + H2O H s cn bng A. 3,4,2,3,3,2,4 B. 2,6,2,6,4,2,4 C. 3,4,2,3,4,2,4 D. 3,8,2,3,2,2,4 Cu 4.Cho cc phn ng ha hc sau: CrCl3 + NaOCl + NaOH -> Na2CrO4 + NaCl + H2O H s cn bng A. 2,6,4,2,3,4 B. 4,6,8,4,3,4 C. 2,3,10,2,9,5 D. 2,4,8,2,9,8 Cu 5.Cho cc phn ng ha hc sau: Mg + HNO3 -> Mg(NO3)2 + NH4NO3 + H2O H s cn bng A. 4,5,4,1,3 B. 4,8,4,2,4 C. 4,10,4,1,3 D. A ng E. 2,5,4,1,6 Cu 6.Cho cc phn ng ha hc sau: CuS2 + HNO3 -> Cu(NO3) 2 + H2SO4 + N2O + H2O H s cn bng A. 4,22,4,8,7,3 B. 4,12,4,4,7,3 C. 3,12,4,8,7,6 D. 4,22,4,4,7,4 + Cu 7Cho phn ng ha hc sau: MnO2 + H + Cl -> Cl2 + H2O + Mn2+ A. 3,4,2,1,1,1 B. 2,4,2,1,2,1 C. 1,6,1,1,1,2 D. 1,4,2,1,2,1 Cu 8.Cho phn ng ha hc sau: As2S3 + KNO3 -> H3AsO4 + H2SO4 + NO + H2O A. 3, 28, 16, 6, 9, 28 B. 6, 14, 18, 12, 18, 14 C. 6, 28, 36, 12, 18, 28 D. 6, 14, 36, 12, 18, 14 Cu 9.Cho phn ng ha hc sau: Cu2S + HNO3 -> Cu(NO3)2 + CuSO4 +NO + H2O A. 3, 8, 3, 4, 5, 4 B. 2, 8, 2, 3, 4, 4 C. 3, 8, 3, 3, 10, 4 D. 3, 1, 3, 2, 2, 1, 3 Cu 10.Cho cc phn ng ha hc sau: HNO3 + H2S -> NO + S + H2O H s cn bng ln lt l: A. 2,3,2,3,4 B. 2,6,2,2,4 C. 2,2,3,2,4 D. 3,2,3,2,4 Cu 11.Trong iu kin th nghim c th, Al tc dng vi HNO3 to hn hp kh X gm : NO, NO2 theo phng trnh phn ng:Al + HNO3 -> Al(NO3)3 + NO2 + NO + H2O Nu dx/40 =1,122 th h s cn bng phn ng ln lt l: A. 16, 30, 16, 2, 29, 44 B. 16, 90, 16, 3, 39, 45 C. 17, 15, 8, 3, 19, 44 D. 16, 30, 16, 3, 39, 90 Cu 12.Cn bng hai phng trnh phn ng sau bng phng php thng bng ion-electron: C2H2 + KMnO4 + H2O -> H2C2O2 + MnO2 + KOH Cc h s theo th t cc cht ln lt l: A. 2,4,3,2,5,8 B. 1,4,2,3,4,4 C. 3,8,4,3,4,4 D. 2,8,3,3,8,8 Cu 13.Hon thnh v cn bng cc phng trnh phn ng theo phng php ion in t: CH2=CH2 + KMnO4 + H2SO4 -> Cc cht sinh ra sau phn ng l: A. C2H4(OH) 2, MnSO4 , K2SO4, H2O B. CH3CHO, MnSO4 , K2SO4, H2O C. CH3COOH, MnO, K2SO4, H2O D. CH3COOH, MnSO4 , K2SO4, H2O Cu 14.Hon thnh cc phng trnh phn ng ha hc sau:

Kl + MnO2 + H2SO4 -> I2 + cc cht l: A. MnSO4, KlO3, HI B. MnSO4, KlO3, K C. MnSO4, K2SO4,H2O D. MnSO4, KlO3, Cu 15.Hon thnh cc phng trnh phn ng ha hc sau: NO + K2Cr2O7 + H2SO4 -> cc cht l A. HNO3, H2O B. K2SO4, Cr2(SO4)3 C. K2SO4, Cr2(SO4)3, HNO3 D. K2SO4, Cr2(SO4)3, HNO3, H2O Cu 16.Hon thnh cc phng trnh phn ng ha hc sau: SO2 + KMnO4 +H2O -> cc cht l : A. K2SO4, MnSO4 B. MnSO4, KHSO4 C. MnSO4, KHSO4, H2SO4 D. MnSO4, K2SO4, H2SO4 Cu 17.Cho phn ng ha hc sau: M2Ox + HNO3 -> M(NO3)3 + NO + H2O Vi gi tr no ca x phn ng trn s l phn ng oxi ho- kh hoc phn ng trao i ? Cu 18. Cho cc cht, ion sau: Cl-, NaS2 , NO2, Fe2+, SO2, Fe3+, N2O5, SO42-, SO2-3, MnO, Na, Cu. Cc cht ion no va c tnh kh, va c tnh oxi ha: A. Cl-, NaS2 , NO2, Fe2+ B. NO2, Fe2+, SO2, MnO, SO323+ C. NaS2 , Fe , N2O5 , MnO D. MnO, Na, Cu Cu 19. Phn ng gia dung dch kali pemanganat trong mi trng axit vi ion iodua c biu din bng phng trnh no di y ? A. 2MnO4 + 5I- + 16H+ -> 2Mn2+ + 8H2O + 5I2 B. MnO4 + 10I- + 2H+ -> Mn2+ + H2O + 5I2 + 11e + 2+ C. 2MnO4 + 10I + 16H -> 2Mn + 8H2O + 5I2 D. MnO4 + 2I- + 8H+ -> Mn2+ + 4H2O + I2 Cu 20.Cho cc dung dch X1: dung dch HCl; dung dch X2: dung dch KNO3; X3: dung dch HCl +KNO3; X4: dung dch Fe2(SO4) 3. Dung dch no c th ho tan c bt Cu: A. X1, X4, X2 B. X3,X4 C. X1, X2, X3,X4 D. X3, X2 Cu 21.Cho phng trnh phn ng: Al + HNO3 -> Al(NO3)3 + NO + N2O + H2O Nu t l mol gia N2O v N2 l 2:3 th sau khi cn bng ta c t l mol nAl: nn2o: n2 l: A. 23:4:6 B. 46:6:9 C. 46:2:3 D. 20:2:3 . DNG 11 : BI TP NHN BIT TCH BIT TINH CH Cu 1/ Dung hoa cht nao sau y nhn 4 dd:NaAlO2, AgNO3, Na2S, NaNO3? a dd HNO3 b dd HCl. c CO2 va nc. d BaCl2. Cu 2/ Chi dung duy nht mt dd nao sau y tach ring ly Al ra khoi hh Al, MgO, CuO,FeO va Fe3O4 ma khi lng Al khng thay i? a NaOH. bH2SO4c, ngui. c H2SO4 loang. dHNO3 loang. Cu 3/ Dung thuc th nao sau y nhn ra 3 goi bt ring bit: Al, Fe, Al2O3? a H2SO4 loang. b dd HCl. c HNO3 loang. d dd KOH. Cu 4/ Co 5 dd ring bit: FeCl3, FeCl2, AlCl3, NH4NO3, NaCl. Dung thuc th nao sau y nhn 5 dd trn? a NaOH. b HCl. c BaCl2. d NH3. Cu 5/ Co 3 cht bt: Al, Al2O3, Cr.Nhn 3 cht trn chi dung 1 thuc th: a dd NaOH. b dd HCl. c dd FeCl2. d H2O. Cu 6/ Co th dung 1 thuc th nhn bit 3 dd: natri sunfat, kali sunfit, nhm sunfat? a dd HCl. b dd BaCl2. c dd NaOH. d quy tim. Cu 7/ Dung 2 hoa cht nao sau y nhn 4 dd: HCl, HNO3, KCl, KNO3? a quy tim, dd AgNO3. b quy tim, dd Ba(OH)2. c dd Ba(OH)2, dd AgNO3. d dd phenolphtalein, dd AgNO3. Cu 8/ loai bo tap cht Fe, Cu co trong mu Ag, ngi ta ngm mu bac nay vao dd d dd(ma khng lam tng lng Ag); a H2SO4c, ngui. b FeCl3. cAgNO3. d HNO3. Cu 9/ Dung 1 thuc th phn bit 4 cht rn: NaOH, Al, Mg, Al2O3 la: a dd HCl. b nc. c dd H2SO4. d dd HNO3 c. Cu 10/ Co th dung H2SO4 c lam kh cac cht: a NH3, O2, N2, CH4, H2. bCaO, CO2, CH4, H2. cSO2, NO2, CO2, CH4, H2. dNa2O, Cl2, O2, CO2, H2. Cu 11/ nhn 4 dd: NH4NO3, (NH4)2SO4, K2SO4, KOH, chi cn dung dd: a quy tim. b AgNO3. c NaOH. d Ba(OH)2. Cu 12/ Co th dung thuc th nao sau y nhn bit 4 dd ring bit: NH4Cl, NaCl, BaCl2, Na2CO3? a NaOH. b H2SO4. c quy tim. d HCl. Cu 13/ lam kh khi H2S co th dung: a ng sunfat khan. bP2O5. cCa(OH)2. d vi sng. Cu 14/ C cc dd : glucoz, glyxerol, etanol, etylfomat. Co th dung thuc th nao sau y nhn c ca 4 dd trn? a Cu(OH)2 b dd NaOH c dd AgNO3/NH3 d dd HCl Cu 15/ C 3 dd: saccaroz, glucoz, h tinh bt.Dng thuc th no sau y nhn 3 dd trn? a I2 b dd AgNO3/NH3 c Cu(OH)2 d dd Br2 Cu 16/ Chi dung nc brom khng th phn bit c 2 cht nao sau y? a Anilin va xiclohexylamin. b dd anilin va dd amoniac.

c Anilin va benzen. d Anilin va phenol. Cu 17/ Thuc th n gian nhn 3 dd kali clorua, kem sunfat, kali sunfit la: a dd HCl. b dd BaCl2. c quy tim. d dd H2SO4. Cu 18/ loai c H2SO4 ra khoi hn hp vi HNO3, ta dung: a dd Ca(NO3)2 va u. b dd AgNO3 va u. c dd CaSO4 va u. d dd Ba(OH)2 va u. Cu 19/ Chi dung nc co th phn bit c cac cht trong day: a Na, Ba, NH4Cl, NH4NO3. b Na, Ba, NH4Cl, (NH4)2SO4. c Na, K, NH4NO3, (NH4)2SO4. d Na, K, NH4Cl, (NH4)2SO4. Cu 20/ Chi co giy mau m, la, va giy tm dd mui X. Ngi ta phn bit 4 lo khi ring bit:O2, N2, H2S va Cl2 do co hin tng: khi(1) lam tan la chay bung ln, khi (2) lam mau cua giy mau bi nhat, khi (3) lam giy tm dd X co mau en.Kt lun sai la: a Khi (1) la O2, X la mui CuSO4. b Khi (1) la O2, khi (2) la Cl2. c X la mui CuSO4, khi (3) la Cl2. d X la mui Pb(NO3)2, khi (2) la Cl2. Cu 21/ Cho 5dd: FeCl3, FeCl2, AgNO3 , NH3 , hn hp NaNO3 va KHSO4. S dd hoa tan c Cu kim loai la: a 5 b 2 c 3 d 4 Cu 22/ t chay st trong clo d c cht X, nung st vi lu huynh thu c cht y. xac inh thanh phn phn t va hoa tri cua cac ng.t trong X, Y co th dung hoa cht nao sau y? a dd H2SO4 , dd BaCl2. b dd HNO3, dd Ba(OH)2. c dd H2SO4 va dd AgNO3 . d dd HCl, NaOH, oxy. Cu 23/ phn bit 3 dd: glucoz, caccaroz, andehytaxetic c th dng: a Cu(OH)2 b Na c dd Br2 ddd AgNO3/NH3 Cu 24/ Nhn bit 4 dd(khoang 0,1 M)Na2SO4, Na2CO3, BaCl2, LiNO3 chi cn dung: a axit sunfuric. b quy tim. c phenolphtalein. d bari hydroxyt. Cu 25/ Thuc th duy nht nhn cac dd: NH4NO3, NaNO3, Al(NO3)3, Mg(NO3)2,Fe(NO3)2,Fe(NO3)3, Cu(NO3)2 la: a NaCl. b NaOH. c Na2CO3. d NaAlO2. Cu 26/ Co cac binh khi: N2 NH3, Cl2, CO2, O2 khng nhan. xac inh binh NH3 Cn dung:(1)giy quy m, (2)bng tm nc, (3)bng tm dd HCl c, (4)Cu(OH)2, (5)AgCl. Cach lam ung la: a (1), (2), (3), (5). b (1), (2), (3). c(1), (3), (4). d(1),(3). Cu 27/ Chi dung Na2CO3 co th nhn c tng dd trong day nao sau y? a KNO3, MgCl2, BaCl2. b CaCl2, Fe(NO3)2, MgSO4. c NaCl, MgCl2, Fe(NO3)3. d Ca(NO3)2, MgCl2, Al(NO3)3. Cu 28/ lam kh khi amoniac ngi ta dung: a P2O5. b axit sunfuric khan. c ng sunfat khan. d vi sng. Cu 29/ Co cac binh khi: N2 NH3, Cl2, CO2, O2 khng nhan. xac inh binh NH3 va Cl2 chi cn dung: a giy quy tim m. bdd HCl. cdd BaCl2. d dd Ca(OH)2. Cu 30/ Phn bit 3 dd NaOH, HCl, H2SO4 chi dung: a quy tim. b Na2CO3. c BaCO3. d Zn. Cu 31/ Thuc th phn bit 4 dd Al(NO3)3, NaNO3, Mg(NO3)2, H2SO4 la: a quy tim. bdd NaOH. cdd CH3COONa. d dd BaCl2. Cu 32/ nhn bit trong thanh phn khng khi co nhim tap cht hydro clorua, ta co th dn khng khi qua:(1)dd AgNO3 , (2)dd NaOH, (3)nc ct co va giot quy tim, (4)nc vi trong. Phng phap ung la: a (1), (2), (3). b(1),(3). c(1). d (1), (2), (3), (4). Cu 33/ Co cac dd AgNO3, ddH2SO4loang,dd HNO3c, ngui, ddHCl. phn bit 2 kim loai:Al va Ag hoc Zn va Ag cn phai dung: a 1 trong 4 dd. b 2 trong 4 dd. c 3 trong 4 dd. d ca 4 dd. Cu 34/ thu c Ag tinh khit t hn hp bt Ag-Fe, ngi ta dung d dd: a FeCl3. bAgNO3 cCuSO4. d HNO3c, ngui, Cu 35/ Phn bit 4 cht ring bit: axit fomic, axit axetic, etyl fomiat, metyl axetat. Dng thuc th ng nht: a qu tm, dd Na2CO3 b qu tm,dd NaOH cqu tm,dd NaOH, Ag2O/ddNH3 dqu tm, Na Cu 36/ lam sach qung boxit co ln Fe2O3, SiO2 dung cho san xut nhm, ngi ta dung: a dd NaOH c, nong, CO2. b dd NaOH c, nong, dd HCl. c dd NaOH loang, dd HCl. d dd NaOH loang, CO2. Cu 37/ Thuc th duy nht nhn cac dd: NH4NO3, (NH4)2SO4, NaNO3, Al(NO3)3, Mg(NO3)2,Fe(NO3)2,Fe(NO3)3, Cu(NO3)2 la: a NaOH. b dd HCl. c AgNO3. d Ba(OH)2. Cu 38/ C th dng NaOH ( th rn) lm kh cc cht kh a.NH3, SO2, CO, Cl2. bN2, NO2, CO2, CH4, H2. c N2. Cl2, O2, CO2, H2. dNH3, O2, N2, CH4, H2. DANG TNG HP V C 1. Cho mt lng hn hp CuO v Fe2O3 tan ht trong dung dch HCl thu c hai mui c t l mol l 1:1. Phn trm khi lng CuO v Fe2O3 trong hn hp l: A. 50% v 50% B. 40% v 60% C. 30% v 70% D. Kt qu khc.

2. Khi c cn 400g dung dch mui c nng 20% th khi lng gim: A. 120g B. 320g C. 380g D. Kt qu khc 3. Hn hp X gm hai kim loi A, B c ho tr khng i, khng tan trong nc , ng trc Cu trong dy in ho. Khi ly m gam X cho vo dung dch CuSO4 d, ton b lng Cu thu c cho phn ng vi dung dch HNO 3 d nhn c 1,12 lt NO duy nht (ktc). Cng ly m gam X ho tan vo dung dch HNO3 d thu c V lt N2 duy nht (ktc). Xc nh V? A. 2,24 lt B. 3,36 lt C. 0,336 lt D. Kt qu khc. 6. Ho tan hoan ton 11,2 gam CaO vo nc thu c dung dch A. Xc V lt CO2 vo dung dch A thu c 2,5 gam kt ta. Tnh V(ktc). A. 0,56 lt B. 8,4 lt C. 8,96 lt D. A hoc B 7. Ho tan 0,9 gam kim loi X vo dung dich HNO3 thu c 0,28 lt kh N2O duy nht (ktc). Xc nh kim loi X. A. Mg B. Al C. Zn D.Cu 8. Ho tan hon ton 10 gam hn hp hai mui cacbonat kim loi ho tr II v III bng dung dch HCl thu c dung dch A v 672 ml kh bay ra (ktc). Hi c cn dung dch A thu c bao nhiu gam mui khan? A. 10,33 g B. 20,66 g C. 30,99 g D. Kt qu khc 9. Ho tan hn hp X gm CuSO4 v AlCl3 vo nc thu c dung dch A. Chia A lm hai phn bng nhau: - Phn 1 cho phn ng vi dung dch BaCl2 d thu c 6,99 g kt ta. - Phn 2 cho phn ng vi dung dch NaOH d thu c kt ta, lc kt ta, lung n khi lng khng i thu c m gam cht rn. Gi tr ca m l: A. 2,4 g B. 3,2 g C. 4,4 g D. Kt qu khc. 10. Cho hn hp X gm 0,08 mol mi kim loi Mg, Al, Zn vo dung dch H 2SO4 c, nng, d thu c 0,07 mol mt sn phm kh duy nht cha lu hunh. Xc nh sn phm kh. A. SO2 B. S C. H2S D. Khng xc nh c 11. Cho s chuyn ho sau:
+ H2 xt,t tr ng h p X Y Z Cao su Buna H O Ni / to
2 o

Cng thc cu to hp l ca X l: A. HO CH2 C C CH2 OH C.

B. CH2OH CH CH CHO D. C A, B, C u ng

H C CH = CH = C H O
||

||

12.

Cho 4,2 g hn hp gm Mg v Zn tc dng ht vi dung dch HCl, thy thot ra 2,24 lt H2 (ktc). Khi lng mui khan to ra trong dung dch l:A. 7,1 g B. 7,75g C. 11,3 g D. Kt qu khc 13. Cho 2,98 g hn hp X gm hai kim loi Zn v Fe vo 200 ml dung dch HCl, sau khi phn ng hon ton ta c cn (trong iu kin khng c Oxi) th c 5,82 g cht rn. Tnh th tch H2 bay ra (ktc)? A. 0,224 lt B. 0,448 lt C. 0,896 lt D. Kt qu khc. 14. Ho tan 9,14 g hn hp Cu, Mg, Al bng dung dch HCl d thu c 7,84 lt kh A (ktc) v 2,54 g cht rn B v dung dch C. Tnh khi lng mui c trong dung dch C? A. 3,99 g B. 33,25 g C. 31,45 g D. Kt qu khc. 15. Dung dch NaOH c phn ng vi tt c cc cht trong dy no sau y? A. FeCl3, MgCl2, CuO, HNO3, NH3, Br2 B. H2SO4, CO2, SO2, FeCl2, FeCl3, NO2, Cl2 C. HNO3, HCl, CuSO4, KNO3, ZnO, Zn(OH)2 D. Al, Al2O3, MgO, H3PO4, MgSO4, MgCl2 16. Dung dch H2SO4 long phn ng c vi tt c cc cht trong dy no sau y? A. FeCl3, MgO, Cu, Ca(OH)2, BaCl2 B. Ba(NO3)2, Na2CO3, (NH4)2SO4, NaOH C. Zn, Fe, (NH4)2CO3, CH3COONa, Ba(OH)2 D. Al, Fe, BaO, BaCl2, NaCl, KOH 17. C bn dung dch ng bn l mt nhn: NH4Cl, (NH4)2SO4, Na2SO4, NaOH. Nu ch c dng mt thuc th nhn bit bn cht lng trn, ta c th dng dung dch no sau y? A. AgNO3 B. BaCl2 C. Ba(OH)2 D. KOH 18. Cho 16,2 g kim loi M(ho tr n khng i) tc dng vi 0,15 mol O2. Ho tan cht rn sau phn ng bng dung dch HCl d thy bay ra 13,44 lt H2(ktc). Xc nh kim loi M? A. Ca B. Mg C. Fe D.Al 19. Mt lng cht thi dng dung dch c cha cc ion Cu 2+, Fe3+, Hg2+, Zn2+, Pb2+. Dng cht no sau y loi b cc ion trn?A. Gim n B. Nc mui n C. Nc vi d D. Axit Nitric 20. Ha tan hon ton 19,2 g Cu vo dung dch HNO3 long. Kh NO thu c em oxi ha thnh NO2 ri sc vo nc cng vi dng kh O2 chuyn ht thnh HNO3. Tnh th tch kh O2(ktc) tham gia vo qu trnh trn? A. 2,24 lit B. 3,36 lt C. 4,48 lt D. 6,72 lt 21. Mui CuSO4 khan dng lm kh kh no sau y? A. NH3 B. H2S C. SO2 D. C A, B, C 22. Khi ly 14,25 g mui clorua ca mt kim loi M ch c ho tr II v mt lng mui nitrat ca M vi s mol nh nhau, th thy khi lng khc nhau l 7,95 g. Cng thc ca hai mui l: A. MgCl2, Mg(NO3)2 B. CaCl2, Ca(NO3)2 C. ZnCl2, Zn(NO3)2 D. CuCl2, Cu(NO3)2 23. Ly 224 th tch kh HCl (ktc) ha tan vo mt th tch nc . Tnh nng C% dung dch axit HCl to thnh?

A. 2,67% B. 26,7% C. 34,2% D. Khng xc nh c 24. Thi mt lung kh CO qua ng s ng m gam hn hp gm Al2O3, MgO, Fe2O3, FeO, CuO nung nng. Kh thot ra c sc vo nc vi trong d thu c 15 g kt ta trng. Sau phn ng cht rn trong ng s c khi lng 200 g. Tnh m?A. 202,4 g B. 217,4 g C. 219,8 g D. Kt qu khc. 25. Ho tan 4,59 g Al bng dung dch HNO3 long thu c hn hp kh gm NO v N2O c t khi hi so vi hiro bng 16,75. T l th tch N2O/NO l: A.

1 3

B.

2 3

C.

3 1

D.

3 2

E. Kt qu khc

26.

C hai ming kim loi A c cng khi lng, mi ming tan hon ton trong dung dch HCl v dung dch H 2SO4 c nng ,5.VH2 cng iu kin). Khi lng mui clorua bng 63,5% khi lng mui sunfat. Kim thu c kh H2 v SO2 ( VSO2 = 1 loi A l. A. Fe B. Mg C. Al D. Zn. 27. C hai ng nghim ng mi ng 2 ml dung dch HCl 1M v 2 ml dung dch H2SO4 1M. Cho Zn tc dng vi hai axit trn, lng kh hiro thu c trong hai trng hp tng ng l V1 v V2 ml (ktc). So snh V1 v V2 ta c: A. V1 > V2 B. V1 = V2 C. V1 < V2 D. Khng so snh c 28. Cht no sau y va phn ng c vi dung dch HCl, va phn ng c vi dng dch NaOH? A. NH4NO3 B. (NH4)2CO3 C. Na2CO3 D. Na2SO4 29. Hn hp A gm Cu, Fe c t l khi lng mCu : mFe = 7 : 3. Ly m gam A cho phn ng hon ton vi 44,1 g HNO 3 trong dung dch thu c 0,75.m gam cht rn, dung dch B v 5,6 lt kh C gm NO v NO2 (ktc). Tnh m? A. 40,5 g B. 50 g C. 50,2 g D. 50,4 g. 30. Cho 12,9 g hn hp gm Al v Mg phn ng ht vi 100 ml dung dch hn hp hai axit HNO 3 4M v H2SO4 7M (m c) thu c 0,1 mol mi kh SO2, NO, N2O. Tnh s mol tng kim loi trong hn hp ban u? A. 0,2 mol Al v 0,3 mol Mg. B. 0,2 mol Mg v 0,3 mol Al. C. 0,1 mol Al v 0,2 mol Mg. D. 0,2 mol Al v 0,1 mol Mg. 31. Thuc th no sau y c th phn bit c bn dung dch: AlCl3, FeCl3, CuCl2, ZnSO4 ? A. dd NaOH B. dd Ba(OH)2 C. dd Ba(NO3)2 D. Qu tm 32. Khng dng thm mt ho cht no khc, c th phn bit c bao nhiu dung dch trong 5 dung dch ring bit sau: NaOH, KCl, MgCl2, CuCl2, AlCl3? A. 2 B. 3 C. 4 D. 5 33. Hn hp A gm Al2O3, MgO, Fe3O4 , CuO. Cho kh CO d qua A nung nng c cht rn B. Ho tan B vo dung dch NaOH d c dd C v cht rn D. Cht rn D gm: A. MgO, Fe, Cu B. MgO, Fe, CuO C. MgO, Fe3O4 , Cu D. Al2O3, MgO, Fe3O4 34. Hn hp A gm BaO, FeO, Al2O3. Ho tan A trong lng d H2O c dd D v phn khng tan B. Sc kh CO2 d vo D to kt ta. Cho kh CO d qua B un nng c cht rn E. Cho E tc dng vi NaOH d thy tan 1 phn cn li l cht rn G. Cht rn G l: A. Ba B. Fe C. Al D. Kt qu khc 35. Cho dy bin ho sau: +X +Z t0 pnc Al D E Al. NaOH C +Y+ Z Cc cht B, C, D, E ln lt l: A. AlCl3, NaAlO2, Al2O3, Al(OH)3 B. Al(OH)3, AlCl3, NaAlO2, Al2O3 C NaAlO2,. AlCl3, Al(OH)3, Al2O3 D. AlCl3, NaAlO2, Al(OH)3, Al2O3 36. Nung 6,58g Cu(NO3)2 trong bnh kn sau 1 thi gian thu c 4,96g cht rn v hn hp kh X . Hp th hon ton hn hp X vo nc c 300ml dung dch Y. Tnh pH ca dung dch Y. A. pH= 1 B. pH= 2 C. pH= 12 D. pH=13 37. Khi nung hn hp FeS2 v FeCO3 trong khng kh thu c 1 oxit v kh B1, B2 . T l khi lng phn t ca B1 v B2 l 11:16 . 2 kh B1 v B2 ln lt l: A. SO2 v CO2 B. CO2 v SO2 C. CO v SO2 D. Kt qu khc. 38. Nhit phn 1 lng CaCO3 sau 1 thi gian c cht rn A v kh B , cho B hp th hon ton vo dd KOH thu c dd D . D tc dng c vi dung dch BaCl2 v vi dd NaOH. dung dch D cha: A. KHCO3 B. K2CO3 C. K2CO3 v KHCO3 D. Kt qu khc 39. Cho cc s phn ng sau: p dd, Mn xt a ) X1 + H2O X2 + X3 + H2 b ) X2 + X4 BaCO3 + K2CO3 + H2O c ) X2 + X3 X1 + KClO3 + H2O d ) X4 + X5 BaSO4 + CO2 + H2O HCl B X1, X2 , X3 , X4 , X5 ln lt l:

A. KOH, KCl, Cl2, Ba(HCO3)2, H2SO4 B. KCl, KOH, Cl2, Ba(HCO3)2, H2SO4 C. KCl, KOH, Cl2, H2SO4, Ba(HCO3)2 D. KCl, Cl2, Ba(HCO3)2, H2SO4, KOH 40. Hn hp gm Na v Al. Cho m g X vo mt lng d nc th thot ra Vlit kh. Nu cng cho m gam X vo dd NaOH(d) th c 1,75V lit kh. Thnh phn % khi lng ca Na trong X l: A. 39,87% B. 77,31% C. 49,87% D. 29,87% 41.nung 13,4 gam hn hp 2 mui cacbonat ca hai kim loi ho tr 2, thu c 6,8 gam cht rn v kh X. lng kh X sinh ra cho hp th vo 75 ml dd naOH 1M, khi lng mui khan thu c sau phn ng l: A. 5,8 g B. 6,5 g C. 4,2 g D. 6,3 g 42. Khi cho Cu tc dng vi dung dch H2SO4 long v NaNO3, vai tr ca NaNO3 trong phn ng l: A. Cht xc tc B. Cht Oxi ho C. Mi trng D. Cht kh. 43. Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O(d), un nng, dung dch thu c cha: A. NaCl, NaOH, BaCl2 B. NaCl, NaOH C. NaCl, NaHCO3, NH4Cl, BaCl2 D. NaCl. 44. Thc hin hai th nghim: 1. Cho 3,84 g Cu phn ng vi 80ml dd HNO3 1M thot ra V1 lit kh NO. 2. Cho 3, 84 g Cu phn ng vi 80ml dd HNO3 1M v H2SO4 0,5 M thot ra V2 lit NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l: A. V2=V1 B. V2=2V1 C. V2=2,5V1 D. V2=1,5V1 45. trong cc dd: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, NaCl, Na2SO4 B. HNO3, Na2SO4, Ca(OH)2, KHSO4 C. NaCl, Na2SO4, Ca(OH)2 D. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2 46. C th phn bit ba dd: KOH, HCl, H2SO4 long bng mt thuc th l: A. Giy qu tm B. Zn C. Al D. BaCO3 47. nhn bit ba axit c ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l mt nhn ta dng thuc th l: A. Fe B. CuO C. Al D. Cu 49. Cho mg hh bt Zn v Fe vo lng d dd CuSO4. Sau khi kt thc cc p, lc b phn dd thu c mg bt rn. Thnh phn % theo khi lng ca Zn trong hh ban u l: A. 90,27% B. 85,30% C. 82,20% D. 12,67% 50. t mt kim loi trong bnh kn ng kh clo, thu c 32,5g mui clorua v nhn thy th tch kh clo trong bnh gim 6,72 lt ( ktc). Hy xc nh tn ca kim loi dng. a. ng b. Nhm c. Canxi d. St 51. X l 10 g hp kim nhm bng dung dch NaOH c nng (d), ngi ta thu c 11,2 lt kh H 2 (ktc). Hy cho bit thnh phn % ca nhm trong hp kim a. 85% b. 90% c. 95% d. Kt qu khc 52. Hai kim loi A v B c ho tr khng i l II.Cho 0,64 g hn hp A v B tan hon ton trong dung dch HCl ta thy thot ra 448 ml kh (ktc). S mol ca hai kim loi trong hn hp l bng nhau. Hai kim loi l: a. Zn, Cu b. Zn, Mg c. Zn, Ba d. Mg, Ca 53. Ho tan hon ton 1,45 g hn hp 3 kim loi Zn, Mg, Fe vo dung dch HCl d, thy thot ra 0,896 lt H2 (ktc). un khan dung dch ta thu c m gam mui khan th gi tr ca m l: a. 4,29 g b.2,87 g c. 3,19 g d. 3,87 g 54. Ho tan hon ton 4,68 g hn hp mui cacbonat ca hai kim loi A, B k tip nhau trong nhm IIA vo dung dch HCl thu c 1,12 lt kh CO2 ( ktc). Hai kim loi A, B ln lt l: a. Mg v Ca b. Be v Mg c. Ca v Sr d. Sr v Ba 55. Khi cho 17,4 g hp kim gm st, ng, nhm phn ng vi H2SO4 long d ta thu c dung dch A; 6,4 g cht rn; 9,856 lt kh B ( 27,30C v 1 atm). Phn trm khi lng mi kim lai trong hp kim Y l: a. Al: 30%; Fe: 50% v Cu: 20% b. Al: 30%; Fe: 32% v Cu 38% c. Al: 31,03%; Fe: 32,18% v Cu: 36,79% d. Al: 25%; Fe: 50% v Cu: 25% 56Khi ly 14,25 gam mui clorua ca 1 kim loi ch c ha tr II v mt lng mui nitrat ca kim loi vi smol nh nhau thy khi lng khc nhau 7,95gam. Cng thc ca 2 mui l: A.SrCl2 v Sr(NO3)2 B.CaCl2 v Ca(NO3)2 C.MgCl2 v Mg(NO3)2 D.BaCl2 v Ba(NO3)2 57 -Nhit phn 67,525 g hn hp hai mui rn bari cacbonat v bari sunfit sau phn ng xy ra hon ton phn cht rn cn li c khi lng 49,725 gam. Phn cht kh thu c c t khi so vi H2 l: A.26,615. B.29,735. C.27,385. D.27,000 58Ha tan 115,3 gam hn hp gm MgCO3 v XCO3 bng dung dch H2SO4 long thu c dung dch Y, cht rn Z v 4,48 lt CO2 ( ktc). C cn dung dch Y thu c 12 gam mui khan. Vy cht rn Z c khi lng l: A.108,5 gam. B.104,5 gam. C.102,5 gam. D.110,5 gam

IV. ST, NG , CROM, CC KIM LOI KHC

TI LIU N THI : CHUYN ST PHN 1: L THUYT

Cu 1: Nguyn t X c in tch ht nhn l 26. Cu hnh electron ca X, chu k v nhm trong h thng tun hon ln lt l: A.1s2 2s22p63s23p63d6 , chu k 3 nhm VIB . B. 1s2 2s22p63s23p63d6 4s2 , chu k 4 nhm IIA . 2 2 6 2 6 5 C.1s 2s 2p 3s 3p 3d , chu k 3 nhm VB . D. 1s2 2s22p63s23p63d6 4s2 , chu k 4 nhm VIIIB Cu 2.H s ng trc FeCl2; FeCl3 phn ng FexOy + HCl FeCl2 + FeCl3 + H2O cn bng s nguyn t cc nguyn t l: A.(y-x); (3x-2y) B.(2x-3y); (2x-2y) C.3x-y); (2y-2x) D.(3x-2y); (2y-2x) Cu 3.Xem phn ng: FeS2 + H2SO4(, nng) Fe2(SO4)3 + SO2 + H2O A.FeS2 b oxi ha to Fe2(SO4)3 B.FeS2 b oxi ha to Fe2(SO4)3 v SO2 C.H2SO4 b oxi ha to SO2 D.H2SO4 oxi ha FeS2 to Fe3+ v SO42Cu 4.C bao nhiu phn ng xy ra khi cho cc cht sau tc dng vi nhau: FeCl2 + Cu, FeCl2 + Br2, FeCl2 + NaOH, FeCl2 + Na2S, FeCl2 + H2S, Fe(NO3)2 + AgNO3, FeCl3 + Fe, FeCl3 + Cu, FeCl3 + H2S, FeCl3 + AgNO3. A.8 B.7 C.6 D.5 Cu 5.Cu hnh electron no sau y l ca ion Fe3+ (Z = 26) : A.1s22s22p63s23p63d6 B.1s22s22p63s23p63d5 C.1s22s22p63s23p63d64s2 D.1s22s22p63s23p63d64s1 Cu 6.Cho hn hp Fe v Cu vo dd HNO3 khuy k phn ng xy ra hon ton. thu c dd ch cha mui st II cn ly: A.d Fe B.HNO3 long C.d Cu D.d HNO3 Cu 7.Cho hn hp Fe v Cu vo dd HNO3 long, sau khi phn ng xy ra hon ton thy dd ch cha 1 cht tan. Cht tan l? A.Fe(NO3)3 B.HNO3 C.Fe(NO3)2 D.Cu(NO3)2 Cu 8.Hy cho bit phn ng no sau y l mt trong nhng phn ng xy ra trong qu trnh luyn thp? A.CO + 3Fe2O3 (to cao) 2Fe3O4 + CO2 B.Mn + FeO (to cao) MnO + Fe o C.CO + Fe3O4 (t cao) 3FeO + CO2 D.CO + FeO(to cao) Fe + CO2 Cu 9.Trong cc cp kim loi sau: (1) Mg, Fe (2) Fe, Cu (3) Fe, Ag . Cp kim loi khi tc dng vi dung dch HNO3 c th to ra dung dch cha ti a 3 mui ( khng k trng hp to NH4NO3) l: A.(1) B.(1) v (2) C.(2) v (3) D.(1) v (2) v (3) Cu 10.Khi cho hn hp Fe2O3 v Cu vo dung dch H2SO4 long d thu c cht rn X v dung dch Y. Dy no di y gm cc cht u tc dng c vi dung dch Y? A.Br2, NaNO3, KMnO4 B.KI, NH3, NH4Cl C.NaOH, Na2SO4, Cl2 D.BaCl2, HCl, Cl2 Cu 11.Cho bit hin tng xy ra khi trn ln cc dung dch FeCl3 v Na2CO3. A.Kt ta trng v si bt kh B.Kt ta trng xanh sau chuyn dn sang kt ta nu v si bt kh C.Kt ta nu, sau tan D.Kt ta nu v si bt kh Cu 12.Cho bit cc phn ng xy ra sau : 2FeBr2+Br2 2FeBr3 2NaBr+Cl2 2NaCl+Br2 Pht biu ng l : A.Tnh oxi ha ca Cl2 mnh hn ca Fe3+ B.Tnh kh ca Br mnh hn ca Fe2+ C.Tnh oxi ho ca Br2 mnh hn ca Cl2 D.Tnh kh ca Cl- mnh hn ca Br 2+ Cu 13.Mui Fe lm mt mu dung dch KMnO4 mi trng axit cho ra ion Fe3+ cn ion Fe3+ tc dng vi I cho ra I2 v Fe2+. Sp xp cc cht oxi ha Fe3+, I2, MnO4 theo th t mnh tng dn : A.I2 < MnO4 < Fe3+ B.MnO4 < Fe3+ < I2 C.Fe3+ < I2 < MnO4 D.I2 < Fe3+ < MnO4 Cu 14.Cho hn hp Al v Fe tc dng vi dung dch cha ng thi AgNO3 v Cu(NO3)2 thu c dung dch B v cht rn D gm 3 kim loi. Thnh phn cht rn D gm: A.Fe, Cu v Ag B.Al, Fe v Ag. C.Al, Fe v Cu. D.Al, Cu v Ag. Cu 15.Phn ng no sau y KHNG phi phn ng oxi ho - kh : A.Fe + H2SO4 B.2FeO + 4H2SO4 , nong C.6FeCl2 + 3Br2 D.Fe3O4 + 4H2SO4 loang Cu 16.Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, FeCO3, FeSO4, FeS, ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l A.6 B.5 C.8 D.7 Cu 17.Cho mt t bt Fe vo dd HNO3 long, khi phn ng xy ra hon ton thu c dd A. Kt lun no sau y l khng ng v dd A? A.dd A c th cha ion Fe3+, H+ v NO3-. B.dd A c th cha ion Fe2+, H+ v NO3-. 2+ 3C.dd A c th cha ion Fe v NO . D.dd A c th cha ion Fe2+, Fe3+ v NO3-. Cu 18.Loi phn ng no sau y khng xy ra trong qu trnh luyn gang? A.Phn ng to x. B.phn ng to cht kh kh. C.phn ng oxi ho Mn, Si, P, S. D.Phn ng kh oxit st thnh st. Cu 19.Nhn xt v kh nng phn ng ca dd mui st (III) vi cc kim loi trong dy in ho th iu khng ng l: A.ion Fe3+ b cc kim loi t Fe n Cu kh thnh Fe2+. B.ion Fe3+ khng oxihoa c cc kim loi Ag tr i. C.cc kim loi t Mg n Zn kh c Fe3+ thnh Fe2+ hoc Fe. D.ion Fe3+oxihoa c tt c cc kim loi t K n Cu. Cu 20.Cho dy bin ha sau: Mi mi tn l mt phng trnh phn ng. Trong cc p n sau y A, B, C, D theo th t l cc cht tng ng. Hy chn p n sai. A.Fe3O4; FeCl2; FeCl3; Fe(NO3)3 B.FeO; Fe2(SO4)3; FeSO4; Fe(NO3)3 C.Fe3O4; Fe(NO3)2; Fe(NO3)3; Fe(OH)3 D.FeO; FeSO4; Fe2(SO4)3; Fe(OH)3 Cu 21.Trong cc phn ng sau, phn ng no sai? A.Fe + Cl2 --> FeCl2 B.Fe + 2HCl --> FeCl2 + H2 C.Cu + Fe2(SO4)3 --> 2FeSO4 + CuSO4 D.Fe + Fe2(SO4)3 --> 3FeSO4 Cu 22.Cho Cu vo dung dch Fe2(SO4)3 ta thu c dung dch c mu xanh lam nht. l do xy ra phn ng:

A.Cu + Fe2(SO4)3 CuSO4 + Fe. B.Cu + Fe2(SO4)3 CuSO4 + FeSO4. C.Cu + 1/2 O2 + H2O Cu(OH)2 D.Cu(OH)2 + Fe2(SO4)3 CuSO4 + 2FeSO4 + H2O2 Cu 23.Trong hai cht FeSO4 , Fe2(SO4)3 cht no phn ng c vi dung dch KI , dung dch KMnO4 trong mi trng axit ? A.FeSO4 vi dung dch KMnO4; Fe2(SO4)3 vi KI . B.FeSO4 v Fe2(SO4)3 u tc dng vi KMnO4 . C.FeSO4 v Fe2(SO4)3 u tc dng vi KI . D.FeSO4 vi dung dch KI ; Fe2(SO4)3 vi KMnO4 . Cu 24.Cho cc cht v hn hp sau:(I)Cl2, (II)I2, (III)HNO3, (IV)H2SO4 c, ngui, (V) hn hp axit HCl v mui NaNO3. Khi cho Fe tc dng vi cht no trong s cc cht trn th to c cht trong st c ho tr III. A.(I), (II). B.(I), (III), (V). C.(I), (II), (III). D.(I), (III), (IV). Cu 25.Cho oxit st FexOy tc dng vi dung dch axit H2SO4 c, nng thu c mt sn phm kh c th lm mt mu cnh hoa hng. Cng thc ho hc no khng th l ca loi oxit st ni trn ? A.Fe2O3 B.Fe3O4 C.FeO D.B v C ng. Cu 26.Mt loi qung cha st trong t nhin c loi b tp cht. Ho tan qung ny trong dung dch axit nitric thy c kh mu nu bay ra,dung dch thu c cho tc dng vi bari clorua thy c kt ta trng ( khng tan trong axit).Hy cho bit tn, thnh phn ho hc ca qung ? A.Xierit FeCO3 B.Manhetit Fe3O4. C.Hematit Fe2O3 D.Pirit FeS2 Cu 27.Mt loi qung st loi tp cht ha tan trong dung dch H2SO4 long d thu c mt dung dch va lm mt mu thuc tm va ha tan bt Cu.Tn ca qung l: A.Pirit FeS2 B.Manhetit Fe3O4 C.Xiderit FeCO3 D.Hematit Fe2O3 Cu 28.Cho Fe tan ht trong HNO3 long thnh dung dch A. Chia dung dch A thnh hai phn bng nhau: cho bt Cu vo phn 1, Cu tan dn. Cho dung dch AgNO3 vo phn 2 th thy c kt ta xut hin. Vy dung dch A gm cc cht: A.HNO3 v Fe(NO3)3 B.HNO3, Fe(NO3)2 v Fe(NO3)3 C.Fe(NO3)2 v Fe(NO3)3 D.HNO3 v Fe(NO3)2 Cu 29. phn bit Fe2O3 v Fe3O4 ta dng dung dch: A.H2SO4 long B.HNO3 C.HCl D.NaOH Cu 30.Dng thuc th no sau y c th phn bit c dung dch Fe2(SO4)3 v dung dch Fe2(SO4)3 c ln FeSO4? A.Dung dch Ba(OH)2 B.Dung dch NH3 C.Dung dch NaOH D.Dung dch KMnO4/H2SO4 Phn 2: Bi tp Bi 1 Cho m gam st phn ng va ht vi axit sunfuric thu c kh A duy nht v 10,56 gam mui. S mol st bng 40,0 % s mol axit sunfuric dng. Vy gi tr ca m l: A.2,52 gam B.3,92 gam C.3,36 gam D.2,80 gam Bi 2 m gam bt Fe trong khng kh sau mt thi gian thu c 19,2 gam hn hp B gm Fe, FeO, Fe2O3, Fe3O4. Cho B vo dd HNO3 long khuy k phn ng hon ton thy B tan ht thu c dd X cha 1 mui v 2,24 lit NO (ktc). Hi m c gi tr no sau y? A.11,2 g B.15,4 g C .16,8 g D.8,4 g Bi 3 t m gam st trong bnh cha 3,36 lit kh clo (ktc), sau khi phn ng kt thc cho nc vo bnh lc k thy cht rn tan hon ton. Thm tip dd NaOH d vo thu c cht kt ta, tch kt ta ngoi khng kh nhn thy khi lng kt ta tng thm 1,02 gam. Tnh m? A.10,08 g B.2,8 g C.4,2 g D.6,72 g Bi 4 T 1 tn qung hematit A iu ch c 420 kg Fe. T 1 tn qung manhetit B iu ch c 504 kg Fe. Vy phi trn hai qung trn vi t l khi lng (mA : mB) l bao nhiu c 1 tn qung hn hp m t 1 tn qung hn hp ny iu ch c 480 kg Fe: A.1 : 3 B.2 : 5 C.2 : 3 D.3 : 5 Bi 5 Cn bao nhiu tn qung manhetit cha 80% Fe3O4 luyn c 800 tn gang c cha 5% C v tp cht. Bit lng Fe b hao ht khi sn xut l 1% A.1235,16 tn B.1325,16 tn C.1253,16 tn D.1316,25 tn Bi 6 Ngm 8,4g Fe trong 400 ml dung dch HNO3 1M kt thc phn ng thu c dung dch A v kh NO. Khi lng cht tan c trong dung dch A l: A.24,2 g B.27,0 g C.23,5 g D.37,5 g Bi 7 kh hon ton 3,04 gam hn hp Y (gm FeO, Fe3O4, Fe2O3) th cn 0,05 mol H2. Mt khc ho tan hon ton 3,04 gam hn hp Y trong dung dch H2SO4 c th thu c th tch kh SO2 (sn phm kh duy nht) iu kin tiu chun l: A.224 ml B.448 ml C.336 ml D.112 ml Bi 8 Gi s gang cng nh thp ch l hp kim ca St vi Cacbon v St ph liu ch gm St, Cacbon v Fe2O3. Coi phn ng xy ra trong l luyn thp Martin l: Fe2O3 + 3C2 Fe + 3CO . Khi lng St ph liu (cha 40% Fe2O3, 1%C) cn dng khi luyn vi 4 tn gang 5%C trong l luyn thp Martin, nhm thu c loi thp 1%C, l: A.1,50 tn B.2,93 tn C.2,15 tn D.1,82 tn Bi 9 Cho 2,236 gam hn hp A dng bt gm Fe v Fe3O4 ha tan hon ton trong 100ml dung dch HNO3 c nng C (mol/l), c 246,4 l kh NO (ktc) thot ra. Sau phn ng cn li 0,448 gam kim loi. Tr s ca C l: A.0,68M B.0,5M C.0,4M D.0,72M Bi 10 Ha tan 0,784 gam bt st trong 100 ml dung dch AgNO3 0,3M. Khuy u phn ng xy ra hon ton, thu c 100 ml dung dch A. Nng mol/l cht tan trong dung dch A l: A.Fe(NO3)2 0,12M; Fe(NO3)3 0,02M B.Fe(NO3)3 0,1M C.Fe(NO3)2 0,14M D.Fe(NO3)2 0,14M; AgNO3 0,02M Bi 11 Hn hp A gm ba oxit st (FeO, Fe3O4, Fe2O3) c s mol bng nhau. Ha tan ht m gam hn hp A ny bng dung dch HNO3 th thu c hn hp K gm hai kh NO2 v NO c th tch 1,12 lt (ktc) v t khi hn hp K so vi hiro bng 19,8. Tr s ca m l: A.20,88 gam B.46,4 gam C.23,2 gam D.16,24 gam Bi 12 Ha tan ht 17,84 gam hn hp A gm ba kim loi l st, bc v ng bng 203,4 ml dung dch HNO3 20% (c khi lng ring 1,115 gam/ml) va . C 4,032 lt kh NO duy nht thot ra (ktc) v cn li dung dch B. em c cn dung dch B, thu c m gam hn hp ba mui khan. Tr s ca m l:

A.51,32 gam B.60,27 gam C.45,64 gam D.54,28 gam Bi 13 Hn hp X gm Fe, FeO, Fe3O4 v Fe2O3. kh hon ton 20,8 gam hn hp X cn 0,25 mol CO. Mt khc, ha tan ht 20,8 gam hn hp X trong dung dch HNO3 m c nng, va , thu c a mol kh NO2. Gi tr ca a l: A.0,2 B.0,3 C.0,4 D.0,5 Bi 14 Cho dung dch HNO3 long vo mt cc thy tinh c ng 5,6 gam Fe v 9,6 gam Cu. Khuy u phn ng xy ra hon ton, c 3,136 lt kh NO thot ra (ktc), cn li m gam kim loi. Tr s ca m l: A.7,04 gam B.1,92 gam C.2,56 gam D.3,2 gam Bi 15 Hn hp A gm ba oxit st FeO, Fe3O4, Fe2O3 c s mol bng nhau. Ha tan ht m gam hn hp A ny bng dung dch HNO3 d th thu c 1,12 lt (ktc) hn hp K gm hai kh NO2 v NO c t khi so vi hiro bng 19,8. Tr s ca m l: A.20,88 gam B.46,4 gam C.23,2 gam D.16,24 gam Bi 16 Cho 18,5g hn hp gm Fe, Fe3O4 vo dung dch HNO3 long, un nng. Khuy k phn ng xy ra hon ton, thu c 0,1 mol kh NO (sn phm kh duy nht), dung dch X v 1,46g kim loi. Khi lng mui nitrat trong dung dch X l: A.27 g B.57,4 g C.48,6 g D.32,6 g Bi 17. Cho m gam Fe vo dung dch cha 1,38 mol HNO3, un nng n kt thc phn ng cn li 0,75m gam rn khng tan v c 0,38 mol hn hp kh NO, NO2 thot ra. Khi lng Fe ban u l A. 70 gam B. 84 gam C. 56 gam D. 112 gam Bi 18 Ha tan ht 5,6 gam Fe trong dung dch H2SO4 long (d), thu c dung dch X. Dung dch X phn ng va vi V ml dung dch KMnO4 0,5 M. Gi tr ca V l A.80 B.40 C.20 D.60 Bi 19 Ha tan hon ton 13,92 gam Fe3O4 bng dung dch HNO3 thu c 448 ml kh NxOy (ktc). NxOy l: A.NO B.N2O C.NO2 D.N2O5 Bi 20 Ha tan hon ton 14,8 gam hn hp Fe v Cu vo lng d dung dch cha HNO3 v H2SO4 c, nng. Sau phn ng thu c 10,08 lt kh NO2 v 2,24 lt kh SO2 (cc kh o ktc). Khi lng ca Fe trong hn hp ban u l: A.5,6 gam B.8,4 gam C.4,2 gam D.11,2 gam Bi 21 Nung x mol Fe trong khng kh mt thi gian thu c 16,08 gam hn hp H gm 4 cht rn, l Fe v 3 oxit ca n. Ha tan ht lng hn hp H trn bng dung dch HNO3 long, thu c 672 ml kh NO duy nht (ktc). Tr s ca x l: A.0,15 B.0,21 C.0,24 D.Khng th xc nh c v khng d kin Bi 22 Hn hp A gm Fe v ba oxit ca n. Ha tan ht m gam hn hp A bng dung dch HNO3 long, c 672 ml NO thot ra (ktc) v dung d ch D. em c cn dung dch D,thu c 50,82 gam mt mui khan. Tr s ca m l: A.16,08 gam B.11,76 gam C.18,90 gam D.15,12 gam Bi 23 Cho mt hn hp di dng bt gm 0,15 mol Fe v 0,15 mol Cu vo dung dch HNO3 ri khuy u cho phn ng xy ra hon ton, thu c 2,24 lt kh NO (ktc) v phn khng tan c khi lng m gam. Gi tr ca m l: A.3,2 g B.6,4 g C. 9,6 g D.12,4 g Bi 24 11,45 g hn hp X gm Fe v M (c ha tr khng i) c chia lm 2 phn bng nhau. Phn (1) cho tan ht trong dung dch HCl thu c 2,128 lt H2 (ktc). Phn 2 cho tc dng hon ton vi HNO3 thu c 1,792 lt NO (ktc). Kim loi M trong hn hp X l: A.Al B.Mg C.Zn D.Mn Bi 25 Thc hin phn ng nhit nhm vi 25 gam hn hp A gm Al v Fe2O3 thu c hn hp B. Cho B tc dng vi dung dch NaOH d c 14,8 gam hn hp C, khng thy kh thot ra. Phn trm khi lng Fe2O3 trong hn hp A l: A.86,4 % B.84,6 % C.78,4 % D.74,8% Bi 26 Cho ming st nng m gam vo dung dch HNO3, sau phn ng thy c 6,72 lt kh NO2 (ktc) thot ra v cn li 2,4 gam cht rn khng tan. Gi tr ca m l: A.8,0 B.5,6 C.10,8 D.8,4 Bi 27 Nung x mol Fe trong khng kh mt thi gian thu c 16,08 gam hn hp H gm 4 cht rn, l Fe v 3 oxit ca n. Ha tan ht lng hn hp H trn bng dung dch HNO3 long, thu c 672 ml kh NO duy nht (ktc). Tr s ca x l: A.0,15 B.0,21 C.0,24 D.Khng th xc nh c v khng d kin Bi 29 Thm dung dch NaOH d vo dung dch cha 0,3 mol Fe(NO3)3. Lc kt ta, em nung n khi lng khng i th khi lng cht rn thu c bng: A.24,0 gam B.96,0 gam C.32,1 gam D.48,0 gam Bi 30 Tnh lng I2 hnh thnh khi cho dung dch cha 0,2 mol FeCl3 phn ng hon ton vi dung dch cha 0,3 mol KI. A.0,10 mol B.0,40 mol C.0,20 mol D.0,15 mol TI LIU N THI : CHUYN Cu PHN 1: L THUYT Cu 1. Cu hnh electron ca Cu trng thi c bn l A. [Ar]4s13d10 B. [Ar]4s23d9 C. [Ar]3d94s2 D. [Ar]3d104s1 Cu 2. phn bit 4 dung dch AlCl3, FeCl3, ZnCl2 v CuCl2 c th dng dung dch A. NaOH B. NH3 C. Ba(OH)2 D. AgNO3 Cu 3. Trong PTN, iu ch CuSO4 ngi ta cho Cu tc dng vi A. H2SO4 m c B. H2SO4 long C. Fe2(SO4)3 long D. FeSO4 Cu 4. C cc dung dch: HCl, HNO3, NaOH, AgNO3, NaNO3. Ch dng thm cht no sau y nhn bit cc dung dch trn? A. Cu B. Dung dch Al2(SO4)3 C. Dung dch BaCl2 D. Dung dch Ca(OH)2 Cu 5.T dung dch NaCl, AlCl3, CuCl2 iu ch Cu, ta c th cho tc dng vi dung dch A. NaOH d, lc ly kt ta, nhit phn ri in phn B. NH3 d, lc ly kt ta, nhit phn ri in phn C. Na2CO3 d, lc ly kt ta, nhit phn ri in phn D. Na2S d, lc ly kt ta, nhit phn ri in phn Cu 6. tch ri Cu ra khi hn hp c ln Al v Zn c th dng dung dch

A. NH3 B. KOH C. HNO3 long D. H2SO4 c ngui Cu 7. Dung dch no di y khng ho tan c Cu? A. dung dch FeCl3 B. Dung dch NaHSO4 C. Dung dch hn hp NaNO3 + HNO3 D. dd HNO3 c ngui Cu 8. Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch A. NaOH (d). B. HCl (d). C. AgNO3 (d). D. NH3(d). Cu 9. Tin hnh bn th nghim sau: - Th nghim 1: Nhng thanh Fe vo dung dch FeCl3; - Th nghim 2: Nhng thanh Fe vo dung dch CuSO4; - Th nghim 3: Nhng thanh Cu vo dung dch FeCl3; - Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl. S trng hp xut hin n mn in ho l A. 1. B. 2. C. 4. D. 3. Cu 10. Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l A. 1. B. 3. C. 2. D. 4. Cu 11. Cho Cu v dung dch H2SO4 long tc dng vi cht X (mt loi phn bn ha hc), thy thot ra kh khng mu ha nu trong khng kh. Mt khc, khi X tc dng vi dung dch NaOH th c kh mi khai thot ra. Cht X l : A. ure. B. amoni nitrat. C. amophot. D. natri nitrat. Cu 12. X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi dung dch Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe3+/Fe2+ ng trc Ag+/Ag) A. Mg, Ag. B. Fe, Cu. C. Cu, Fe. D. Ag, Mg. Cu 14. C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l A. 4. B. 1. C. 3. D. 2. Cu 15. Mnh khng ng l: A. Fe2+ oxi ho c Cu. B. Fe kh c Cu2+ trong dung dch. 3+ 2+ C. Fe c tnh oxi ha mnh hn Cu . D. Tnh oxi ha ca cc ion tng theo th t: Fe2+, H+, Cu2+, Ag+. Cu 16. C 4 dung dch ring bit: a) HCl, b) CuCl2, c) FeCl3, d) HCl c ln CuCl2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l A. 1. B. 0. C. 3. D. 2. Cu 17. Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s A. nhng 12 electron. B. nhn 13 electron. C. nhn 12 electron. D. nhng 13 electron. Cu 18. in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn xp). dung dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l (bit ion SO42- khng b in phn trong dung dch) A. 2b = a. B. b > 2a. C. b < 2a. D. b = 2a. Cu 19. Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu c dung dch ch cha mt cht tan v kim loi d. Cht tan l A. Cu(NO3)2. B. Fe(NO3)3. C. HNO3. D. Fe(NO3)2. Cu 20. Cho cc phn ng: (1) Cu2O + Cu2S (2) Cu(NO3)2 (3) CuO + CO (4) CuO + NH3 S phn ng to ra kim loi Cu l A. 2. B. 1. C. 3. D. 4 Phn 2: Bi tp Bi 1. Cho 1,12 gam Fe v 0,24 gam Mg vo 250ml dung dch CuSO4 aM. Phn ng xong, thu c 1,88g cht rn X. a c gi tr bng A. 0,04M B. 0,10M C. 0,16M D. 0,12M Bi 2. Cho V lt H2 (ktc) i qua bt CuO (d) un nng, thu c 32 gam Cu. Nu cho V lt H2 (ktc) i qua bt FeO (d) un nng th khi lng Fe thu c l bao nhiu? Gi s hiu sut ca cc phn ng l 100%? A. 24g B. 26g C. 28g D. 30g Bi 3. Cho hn hp gm 0,1 mol Ag2O v 0,2 mol Cu tc dng ht vi dung dch HNO3 long, d. C cn dung dch thu c sau phn ng c hn hp mui khan A. Nung A n khi lng khng i thu c cht rn B c khi lng l A. 26,8g B. 13,4g C. 37,6g D. 34,4g Bi 4. Ho tan hon ton 19,2 gam Cu vo dung dch HNO3 long. Kh NO thu c em oxi ho thnh NO2 ri sc vo nc cng vi dng kh O2 chuyn ht thnh HNO3. Th tch O2 (ktc) tham gia vo qu trnh trn l A. 2,24 lt B. 3,36 lt C. 4,48 lt D. 6,72 lt Bi 5. Nhng thanh Cu vo 200ml dung dch AgNO3 0,5M. Khi phn ng kt thc, ly thanh Cu ra sch, sy kh em cn li th khi lng thanh kim loi s A. tng 4,4 gam B, gim 4,4 gam C. tng 7,6 gam D. gim 7,6 gam Bi 6. Cho 1,92 gam Cu tc dng vi 100ml dung dch hn hp KNO3 0,1M v H2SO4 0,16M. Th tch X (tir khi hi so vi H2 l 15) sinh ra ktc l: A. 448ml B. 672ml C. 179,2ml D. 358,4ml Bi 7. Cho 19,2 gam kim loi M tc dng vi dung dch HNO3 long d, thu c 4,48 lt kh duy nht NO (ktc). Kim loi M l A. Mg B. Cu C. Fe D. Zn Bi 8. Ho tan 58 gam CuSO4.5H2O vo nc c 500ml dung dch A. Cho dn dn bt Fe vo dung dch A, khuy nh cho ti khi dung dch ht mu xanh. Tnh lng Fe tham gia phn ng? A. 1,12g B. 11,2g C. 5,6g D. 0,56g Bi 9. Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 1,0 lt. B. 0,6 lt. C. 0,8 lt. D. 1,2 lt.

Bi 10. Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l A. 11,5. B. 10,5. C. 12,3. D. 15,6. Bi 11. Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 0,746. B. 0,448. C. 0,672. D. 1,792. Bi 12. Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn ng ht vi Y l A. 90 ml. B. 57 ml. C. 75 ml. D. 50 ml. Bi 13. Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l A. 0,04. B. 0,075. C. 0,12. D. 0,06. Bi 14. in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catt v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH l (cho Cu = 64) A. 0,15M. B. 0,2M. C. 0,1M. D. 0,05M. Bi 15. Thc hin hai th nghim: 1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. 2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l (cho Cu = 64) A. V2 = 2,5V1. B. V2 = 1,5V1. C. V2 = V1. D. V2 = 2V1. Bi 16 . Ho tan hon ton m gam hn hp Al, Fe, Cu, Zn, Mg trong V lt HNO3 0,1M (va ) thu c 0,1 NO v 0,2 mol NO2. Dung dch thu c. Tnh V? A. 0,8 lt B. 8 lt C. 11,2 lt D. 22,4 lt CHUYN : CRM + CC KIM LOI KHC Cu 1.Cho cn bng ha hc: 2CrO4- + 2H+ Cr2O72- + H2O. Cn bng s chuyn dch theo chiu no trong hai trng hp: (1) pha long v (2) thm BaCl2 vo: A.(1) Nghch ; (2) Nghch B.(1) Khng chuyn dch ; (2) Thun C.(1) Khng chuyn dch ; (2) Nghch D.(1) Thun ; (2) Thun Cu 2.Cho th in cc chun (Eo) ca cp Cr2O72-/2Cr3+ ln hn cp Fe3+/Fe2+. Phn ng xy ra ti pH = 0. Vy phng trnh ion thu gn nht ca phn ng: K2Cr2O7 + FeSO4 + H2SO4 Fe2(SO4)3 + Cr2(SO4)3 + K2SO4 + H2O c tng cc h s l: A.35 B.36 C.37 D.38 Cu 3.Cho cc phng trnh phn ng sau: (1) 2Cr + 3Cl2 2CrCl3 (2) Cr + 2H2O (hi) Cr(OH)2 + H2 (3) CrO3 + H2O H2CrO4 2NiCl3 (4) 2CrO3 + H2O H2Cr2O7 (5) 2Ni + 3Cl2 (6) CuO + Cu Cu2O (7) 2Ag + H2S Ag2S + H2 (8) Sn + H2SO4 (long) SnSO4 + H2 S phng trnh phn ng c vit ng l: A.5 B.7 C.4 D.6 Cu 4.Cho phn ng ho hc sau: CrCl3 + NaOCl + NaOH Na2CrO4 + NaCl + H2O H s cn bng ca H2O trong phn ng trn l: A.3 B.5 C.6 D.4 Cu 5.Hin tng xy ra khi cho vi git dung dch H2SO4 vo dung dch mui Na2CrO4 l: A.dung dch c mu da cam m hn B.dung dch chuyn sang mu vng C.dung dch c mu vng m hn D.dung dch chuyn sang mu da cam Cu 6.Khi cho dung dch HCl c, d vo K2CrO4 th dung dch chuyn thnh: A.Mu vng B.Mu da cam C.Khng mu D.Mu xanh Cu 7.Cht rn mu lc , tan trong dung dch HCl c dung dch A. Cho A tc dng vi NaOH v brom c dung dch mu vng, cho dung dch H2SO4 vo li thnh mu da cam. Cht rn l: A.Cr B.CrO C.Cr2O D.Cr2O3 Cu 8.Ha tan Cr2O3 vo lng d dung dch NaOH, sau thm brom vo dung dch phn ng ht vi hp cht ca crom. Sau phn ng thu c dung dch A. Vy dung dch A c mu: A.Vng B.Da cam C.Xanh tm D.Khng mu Cu 9.Khi nung mt cht bt mu lc X vi potat n da v c mt khng kh chuyn thnh cht Y c mu vng v d tan trong nc, cht Y tc dng vi axit to thnh cht Z c mu da cam. Cht Z b lu hunh kh thnh cht X v oxi ho axit clohiric thnh clo. Cng thc phn t ca cc cht X, Y, Z ln lt l: A.Cr2O3, K2CrO4, K2Cr2O7 B.Cr2O3, K2Cr2O7, K2CrO4 C.Cr2O3, Na2CrO4, Na2Cr2O7 D.Cr2O3, Na2Cr2O7, Na2CrO4 Cu 10.Hin tng no di y m t khng ng? A.Thm dung dch axit vo dung dch K2CrO4 th dung dch chuyn t mu vng sang mu da cam B.Thm t t dung dch NaOH vo dung dch CrCl3 thy xut hin kt ta mu vng sau kt ta tan dn C.Thm dung dch kim vo dung dch mui icromat thy mui ny chuyn t mu da cam sang mu vng D.Thm t t dung dch HCl vo dung dch Na[Cr(OH)4] thy xut hin kt ta mu lc xm sau kt ta tan Cu 11.Pht biu no sau y khng ng? A.BaSO4 v BaCrO4 u l nhng cht khng tan trong nc

B.H2SO4 v H2CrO4 u l axit c tnh oxi ha mnh C.Fe(OH)2 v Cr(OH)2 u l baz v l cht kh D.Al(OH)3 v Cr(OH)3 u l cht lng tnh v va c tnh oxi ha va c tnh kh Cu 12.Thm mt t tinh th K2Cr2O7 (lng bng ht u xanh) vo ng nghim, thm khong 1ml nc ct. Lc ng nghim cho tinh th tan ht, thu c dung dch X. Thm vi git dung dch KOH vo dung dch X thu c dung dch Y. Mu sc ca dung dch X v Y ln lt l: A.Mu vng chanh v mu nu B.Mu vng chanh v mu da cam C.Mu da cam v mu vng chanh D.Mu nu v mu vng chanh Cu 13.Hin tng no di y miu t khng ng? A.Thm lng d NaOH v Cl2 vo dung dch CrCl2 th dung dch mu xanh chuyn sang mu vng B.Thi kh NH3 qua CrO3 t nng thy cht rn chuyn t mu sang mu lc thm C.Thm lng d NaOH vo sung dch K2Cr2O7 th dung dch chuyn t mu da cam sang mu vng D.Nung Cr(OH)2 trong khng kh thy cht rn chuyn t mu lc xm sang mu lc thm

CHUYN 7: ANCOL PHENOL

Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. phenol. B. axit acrylic. C. metyl axetat. D. anilin. Cu 460. Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l A. 1. B. 2. C. 3. D. 4. Cu 461. Dy gm cc cht u tc dng vi ancol etylic l: A. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH. B. HBr (to), Na, CuO (to), CH3COOH (xc tc). C. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O. D. NaOH, K, MgO, HCOOH (xc tc). Cu 463. Dy gm cc cht u phn ng vi phenol l: A. nc brom, anehit axetic, dung dch NaOH. B. nc brom, axit axetic, dung dch NaOH. C. dung dch NaCl, dung dch NaOH, kim loi Na. D. nc brom, anhirit axetic, dung dch NaOH. Cu 464. nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. nc Br2.. B. dung dch NaOH. C. H2 (Ni, nung nng). D. Na kim loi. Cu 466. Cho cc phn ng :
t HBr + C2H5OH S phn ng to ra C2H5Br l : A. 2.
0

t C2H4 + Br2 .

C2H4 + HBr C. 1

askt (1:1mol) C2H6 + Br2 .

B. 4

D. 3.

Cu 469. t chy hon ton mt ancol a chc, mch h X, thu c H2O v CO2 vi t l s mol tng ng l 3:2. Cng thc phn t ca X l A. C2H6O. B. C3H8O2. C. C2H6O2. D. C4H10O2. Cu 470. Khi thc hin phn ng tch nc i vi ancol X, ch thu c mt anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu cng thc cu to ph hp vi X? A. 4. B. 3. C. 2. D. 5. Cu 471. t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l: A. C2H6O2, C3H8O2. B. C3H6OvC4H8O. C. C2H6OvC3H8O. D. C2H6O v CH4O. Cu 472. t chy hon ton mt ru (ancol) X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l A. C3H8O3. B. C3H4O. C. C3H8O. D. C3H8O2. Cu 473. t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 4,9 v propan-1,2-iol. B. 4,9 v propan-1,3-iol. C. 4,9 v glixerol. D. 9,8 v propan-1,2-iol. Cu 474. X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l A. C3H7OH. B. C2H4(OH)2. C. C3H6(OH)2. D. C3H5(OH)3.

Cu 475. Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l: A. m = 2a + V/11,2 B. m = a + V/5,6 . C. m = 2a - V/22,4 . D. m = a - V/5,6 Cu 476. Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l A. C2H4(OH)2 v C3H6(OH)2. B. C3H5(OH)3 v C4H7(OH)3. C. C2H4(OH)2 v C4H8(OH)2. D. C2H5OH v C4H9OH. Cu 477. Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (th tch dung dch thay i khng ng k). A. C3H7OH v C4H9OH. B. C2H5OH v C3H7OH. C. C2H5OH v C4H9OH. D. C4H9OH v C5H11OH. Cu 478. Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l A. C2H5C6H4OH. B. C6H4 (OH)2. C. HOCH2C6H4COOH. D. HO C6H4CH2OH. Cu 479. S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 2. B. 4. C. 3. D. 1. Cu 481. Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. CH3OC6H4OH. B. CH3C6H3(OH)2. C. HOC6H4CH2OH. D. C6H5CH(OH)2. Cu 482. Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. CH3-C6H3(OH)2. B. HO-CH2-C6H4-OH. C. HO-C6H4-COOH. D. HO-C6H4-COOCH3. Cu 486. un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ancol trn l A. CH3OH v C2H5OH. B. C3H5OH v C4H7OH. C. C3H7OH v C4H9OH. D. C2H5OH v C3H7OH. Cu 487. X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 140 oC, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 18,00. B. 16,20. C. 8,10. D. 4,05. Cu 488. un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l A. C2H6O. B. C3H8O. C. CH4O. D. C4H8O. Cu 489. un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l A. C2H5OH v CH2=CH-CH2-OH. B. CH3OH v C3H7OH. C. C2H5OH v CH3OH. D. CH3OH v CH2=CH-CH2-OH. Cu 490. Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l A. CH3-CO-CH3. B. CH3-CHOH-CH3. C. CH3-CH2-CH2-OH. D. CH3-CH2-CHOH-CH3. Cu 491. Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hpsn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 13,5. B. 15,3. C. 8,5. D. 8,1. Cu 492. Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l A. 0,64. B. 0,92. C. 0,46. D. 0,32. Cu 493. Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 9,2. B. 7,4. C. 8,8. D. 7,8. Cu 494. Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l A. 1,15 gam. B. 5,75 gam. C. 4,60 gam. D. 2,30 gam. Cu 495. Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l

A. 80,0%.

B. 70,4%.

C. 76,6%.

D. 65,5%.

CHUYN 8: ANEHIT XETON

Cu 496. Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi (CH3)2CO l A. 4. B. 1. C. 2. D. 3. Cu 497. Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l: A. CH3COOH, C2H2, C2H4. B. C2H5OH, C2H4, C2H2. C. HCOOC2H3, C2H2, CH3COOH. D. C2H5OH, C2H2, CH3COOC2H5. Cu 499. Qu trnh no sau y khng to ra anehit axetic? A. CH3COOCH=CH2 + dung dch NaOH (to). B. CH2=CH2 + O2 (to, xc tc). C. CH2=CH2 + H2O (to, xc tc HgSO4). D. CH3CH2OH + CuO (to). Cu 500. Trong cng nghip, axeton c iu ch t. A. propan-1-ol. B. propan-2-ol. C. xiclopropan. D. cumen. Cu 501. S ng phn xeton ng vi cng thc phn t C5H10O l A. 6. B. 4. C. 5. D. 3. Cu 503. Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l A. 60%. B. 70%. C. 50%. D. 80%. Cu 504. un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc. B. no, hai chc. C. khng no (cha mt ni i C=C), n chc. D. no, n chc. Cu 506. Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HCOOCH3 v HCOOCH2-CH3. B. HO-CH(CH3)-CHO v HOOC-CH2-CHO. C. HO-CH2-CH2-CHO v HO-CH2-CH2-CH2-CHO. D. HO-CH2-CHO v HO-CH2-CH2-CHO. Cu 507. Cho cc hp cht hu c: (1) ankan;(2) ancol no, n chc, mch h; (3) xicloankan;(4) ete no, n chc, mch h;. (5) anken;(6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h;(9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (2), (3), (5), (7), (9). B. (3), (4), (6), (7), (10). C. (3), (5), (6), (8), (9). D. (1), (3), (5), (6), (8). Cu 508. t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit. A. no, hai chc. B. no, n chc. C. khng no c hai ni i, n chc. D. khng no c mt ni i, n chc. Cu 509. t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HO-CH2-CH2-CH=CH-CHO. B. HOOC-CH=CH-COOH. C. HO-CH2-CH2-CH2-CHO. D. HO-CH2-CH=CH-CHO. Cu 511. t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l A. CH2=CH-CH2-OH. B. C2H5CHO. C. CH3COCH3. D. O=CH-CH=O. Cu 512. Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l A. HCHO v 32,44%. B. CH3CHO v 49,44%. C. CH3CHO v 67,16%. D. HCHO v 50,56%. Cu 513. Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 10,5. B. 8,8. C. 24,8. D. 17,8. Cu 514. Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 35,00%. B. 65,00%. C. 53,85%. D. 46,15%. Cu 515. Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 5. B. 4. C. 6. D. 3.

Cu 517. t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu cho X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, sinh ra s mol Ag gp bn ln s mol X phn ng. Cng thc ca X l A. (CHO)2. B. C2H5CHO. C. CH3CHO. D. HCHO. Cu 518. Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l A. CH3CH(OH)CHO. B. OHC-CHO. C. HCHO. D. CH3CHO. Cu 519. Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l A. CnH2n+1CHO (n 0). B. CnH2n-1CHO (n 2). C. CnH2n-3CHO (n 2). D. CnH2n(CHO)2 (n 0). Cu 520. Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l A. HCHO. B. CH2=CH-CHO. C. OHC-CHO. D. CH3CHO. Cu 521. Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l A. HCHO. B. CH3CHO. C. CH2 = CHCHO. D. CH3CH2CHO. Cu 522. Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. C2H5CHO. C. C4H9CHO. D. HCHO. Cu 523. Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l A. HCHO v C2H5CHO. B. CH3CHO v C2H5CHO. C. C2H3CHO v C3H5CHO. D. HCHO v CH3CHO. Cu 524. Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l A. HCHO. B. CH3CHO. C. C2H3CHO. D. C2H5CHO.

CHUYN 9: AXIT CACBOXYLIC

Cu 498. Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. CH3CHO, C6H12O6 (glucoz), CH3OH. B. C2H4(OH)2, CH3OH, CH3CHO. C. CH3CHO, C2H5OH, C2H5COOCH3. D. CH3OH, C2H5OH, CH3CHO. Cu 502. Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l A. C9H12O9. B. C3H4O3. C. C6H8O6. D. C12H16O12. Cu 505. Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. HCOOC2H5 v HOCH2COCH3. B. HCOOC2H5 v HOCH2CH2CHO. C. C2H5COOH v HCOOC2H5. D. C2H5COOH v CH3CH(OH)CHO. Cu 510. t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l A. 6,72. B. 4,48. C. 8,96. D. 11,2. Cu 516. Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 64,8 gam. B. 43,2 gam. C. 21,6 gam. D. 10,8 gam. Cu 525. Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. axit aipic. B. ancol o-hiroxibenzylic. C. axit 3-hiroxipropanoic. D. etylen glicol. Cu 526. t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l A. CH3-COOH. B. HOOC-COOH. C. C2H5-COOH. D. HOOC-CH2-CH2-COOH. Cu 527. Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung dch NaOH 1M. Hai axit l: A. HCOOH, HOOC-CH2-COOH. B. HCOOH, C2H5COOH. C. HCOOH, CH3COOH. D. HCOOH, HOOC-COOH. Cu 528. Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l A. 6,84 gam. B. 4,90 gam. C. 6,80 gam. D. 8,64 gam. Cu 529. trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l A. C2H5COOH. B. HCOOH. C. C3H7COOH. D. CH3COOH. Cu 530. Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l A. CH3COOH. B. CH2=CH-COOH. C. CH3-CH2-COOH. D. HC COOH. C-

Cu 531. Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. HCOOH. B. C3H7COOH. C. CH3COOH. D. C2H5COOH. Cu 532. Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l A. 1,44 gam. B. 0,56 gam. C. 0,72 gam. D. 2,88 gam. Cu 533. Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3, un nng th thu c 21,6 gam Ag. Tn gi ca X l A. axit metacrylic. B. axit propanoic. C. axit acrylic. D. axit etanoic. Cu 534. Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc).t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOC-CH2-COOH v 54,88%. B. HOOC-COOH v 42,86%. C. HOOC-COOH v 60,00%. D. HOOC-CH2-COOH v 70,87%.

HUYN 12: AMIN AMINOAXIT

Cu 326. Pht biu khng ng l: A. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). B. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2-COO-. C. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. D. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. Cu 327. C cc dung dch ring bit sau: C6H5NH3Cl (phenylamoni clorua), NH2 - CH2 - CH2 - CH(NH2) - COOH, ClNH3 CH2 - COOH, HOOC - CH2 - CH2 - CH(NH2) - COOH, NH2 - CH2 - COONa. S lng cc dung dch c pH < 7 l A. 3. B. 5. C. 4. D. 2. Cu 329. S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 2. B. 4. C. 5. D. 3. Cu 332. Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. amoni acrylat. B. axit aminopropionic. C. axit -aminopropionic. D. metyl aminoaxetat. Cu 333. Cht X c cng thc phn t C4H9O2N. Bit: X + NaOH Y + CH4O. Y + HCl (d) Z + NaCl. Cng thc cu to ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH. B. H2NCH2COOC2H5 v ClH3NCH2COOH. C. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH. D. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH. Cu 335. Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l A. C3H9N. B. C4H9N. C. C3H7N. D. C2H7N. Cu 336. t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l A. H2N-CH2-CH2-COOH. B. H2N-CH2-COO-CH3. C. H2N-CH2-COO-C2H5.D. H2N-CH2-COO-C3H7. Cu 337. Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este caaminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z. B. Y, Z, T. C. X, Y, Z, T. D. X, Y, T. Cu 338. -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. CH3CH2CH(NH2)COOH. B. H2NCH2COOH. C. CH3CH(NH2)COOH. D. H2NCH2CH2COOH. Cu 339. Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 5. B. 7. C. 8. D. 4. Cu 340. Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l

A. 2. B. 3. C. 5. D. 4. Cu 341. Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C4H8O4N2. B. C4H10O2N2. C. C5H11O2N. D. C5H9O4N. Cu 342. trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H7N. B. CH5N. C. C3H7N. D. C3H5N. Cu 343. Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC3H6COOH. B. H2NC2H4COOH. C. H2NCH2COOH. D. H2NC4H8COOH. Cu 344. Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC3H5(COOH)2. B. H2NC2H3(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH. Cu 345. Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCH2COO-CH3. B. H2NC2H4COOH. C. CH2=CHCOONH4. D. H2NCOO-CH2CH3. Cu 346. Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. H2NCH2COOCH3. B. HCOOH3NCH=CH2. C. H2NCH2CH2COOH. D. CH2=CHCOONH4. Cu 347. Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. HCOONH2(CH3)2. B. HCOONH3CH2CH3. C. CH3COONH3CH3. D. CH3CH2COONH4. Cu 348. Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 16,5 gam. B. 8,9 gam. C. 14,3 gam. D. 15,7 gam. Cu 349. Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 9,6. B. 9,4. C. 8,2. D. 10,8. Cu 351. Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3NH2 v NH3. B. CH3OH v CH3NH2. C. CH3OH v NH3. D. C2H5OH v N2.

CHUYN 13: POLIME

Cu 374. Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. buta-1,3-ien; cumen; etilen; trans-but-2-en. B. stiren; clobenzen; isopren; but-1-en. C. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. Cu 375. Pht biu no sau y l ng? A. Trng hp stiren thu c poli(phenol-fomanehit). B. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng. C. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N. D. T visco l t tng hp. Cu 376. Nilon-6,6 l mt loi. A. t axetat. B. t visco. C. t poliamit. D. polieste. Cu 377. Dy gm cc cht c dng tng hp cao su Buna-S l: A. CH2=CH-CH=CH2, lu hunh. B. CH2=C(CH3)-CH=CH2, C6H5CH=CH2. C. CH2=CH-CH=CH2, C6H5CH=CH2. D. CH2=CH-CH=CH2, CH3-CH=CH2. Cu 378. Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp. A. CH3COO-CH=CH2. B. C2H5COO-CH=CH2. C. CH2=CH-COO-C2H5. D. CH2=CH-COO-CH3. Cu 379. Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp. A. CH3COOCH=CH2. B. CH2=C(CH3)COOCH3. C. C6H5CH=CH2. D. CH2 =CHCOOCH3. Cu 380. Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang, nhng loi t no thuc loi t nhn to? A. T visco v t axetat. B. T tm v t enang. C. T visco v t nilon-6,6. D. T nilon-6,6 v t capron. Cu 381. Polime c cu trc mng khng gian (mng li) l A. PVC. B. PE. C. nha bakelit. D. amilopectin.

Cu 382. Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l A. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH. B. CH2=CH-COOCH3 v H2N-[CH2]6-COOH. C. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH. D. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH. Cu 383. T nilon - 6,6 c iu ch bng phn ng trng ngng. A. HOOC-(CH2)2-CH(NH2)-COOH. B. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. C. H2N-(CH2)5-COOH. D. HOOC-(CH2)4-COOH v HO-(CH2)2-OH. Cu 384. Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 328. B. 382. C. 453. D. 479. Cu 385. Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l A. 4. B. 6. C. 5. D. 3. Cu 386. Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 121 v 114. B. 113 v 114. C. 113 v 152. D. 121 v 152.

Bi 1: Ho tan hon ton 23,8 gam hn hp gm mt mui cacbonat ca kim loi ho tr I v mui cacbonat ca kim loi ho tr II trong dung dch HCl. Sau phn ng thu c 4,48 lt kh (ktc). em c cn dung dch thu c th thu c bao nhiu gam mui khan. Bi 2: Hn hp A gm KClO3, Ca(ClO3)2, Ca(ClO2)2, CaCl2 v KCl nng 83,68 gam. Nhit phn hon ton A ta thu c cht rn B gm CaCl2 v KCl v mt th tch O2 va oxi ho SO2 thnh SO3 iu ch 191,1 gam dung dch H2SO4 80%. Cho cht rn B tc dng vi 360ml dung dch K2CO3 0,5 M (va ) thu c kt ta C v dung dch D. Lng KCl trong dung dch D nhiu gp 22/3 ln lng KCl c trong A. a. Tnh khi lng kt ta C. b. Tnh % khi lng KClO3 c trong A. Bi 3: Hn hp X gm Fe, FeO, Fe2O3, cho lung kh CO i qua ng ng m gam X un nng. Sau khi kt thc th nghim thu c 64 gam cht rn trong ng s v 11,2 lt hn hp kh B (ktc) c t khi so H2 l 20,4. Tm m. Bi 4: Cho 0,1 mol este to bi axit 2 ln axit v ru mt ln ru tc dng hon ton vi NaOH thu c 6,4 gam ru v mt lng mui c khi lng nhiu hn lng este l 13,56% (so vi lng este). Tnh khi lng mui v xc nh cng thc cu to ca este Bi 5: Cho mt lung CO i qua ng s ng 0,04 mol hn hp A gm FeO v Fe 2O3 t nng. Sau khi kt thc th nghim thu c cht rn B gm 4 cht nng 4,784 gam. Kh i ra khi ng s cho hp th vo dung dch Ba(OH) 2 d th thu c 9,062 gam kt ta. Mt khc ho tan cht rn B bng dung dch HCl d thy thot ra 0,6272 lt H2 (ktc). a. Tnh % khi lng cc oxit trong A. b. Tnh % khi lng cc cht trong B, bit rng trong B s mol st t oxit bng 1/3 tng s mol ca st (II) v st (III) oxit. Bi 6. Ha tan hon ton 3,34 gam hn hp hai mui cacbonat kim loi ha tr II v ha tr III bng dung dch HCl d ta thu c dung dch A v 0,896 lt kh bay ra (ktc). Tnh khi lng mui c trong dung dch A. Bi 7. Kh m gam hn hp A gm cc oxit CuO, FeO, Fe 3O4 v Fe2O3 bng kh CO nhit cao, ngi ta thu c 40 gam hn hp cht rn X v 13,2 gam kh CO2. Tm gi tr ca m PHN BI TP TRC NGHIM Cu 1: Hn hp X gm Fe, FeO v Fe2O3. Cho mt lung CO i qua ng s ng m gam hn hp X nung nng. Sau khi kt thc th nghim thu c 64 gam cht rn A trong ng s v 11,2 lt kh B (ktc) c t khi so vi H2 l 20,4. Tnh gi tr m. A. 105,6 gam. B. 35,2 gam. C. 70,4 gam. D. 140,8 gam Cu 2: Kh 4,64g hn hp X gm FeO, Fe3O4, Fe2O3 c s mol bng nhau bng CO thu c cht rn Y. Kh tht ra sau phn ng c dn vo dung dch Ba(OH)2 d thu c 1,79g kt ta. Khi lng ca cht rn Y l: A. 4,48g B. 4,84g C. 4,40g D. 4,68g Cu 3: Ha tan 9,14 gam hp kim Cu, Mg, Al bng mt lng va dung dch HCl thu c 7,84 lt kh X (ktc) v 2,54 gam cht rn Y v dung dch Z. Lc b cht rn Y, c cn cn thn dung dch Z thu c lng mui khan l A. 31,45 gam. B. 33,99 gam. C. 19,025 gam. D. 56,3 gam. Cu 4: Cho 15 gam hn hp 3 amin n chc, bc mt tc dng va vi dung dch HCl 1,2 M th thu c 18,504 gam mui. Th tch dung dch HCl phi dng l A. 0,8 lt. B. 0,08 lt. C. 0,4 lt. D. 0,04 lt. Cu 5: Trn 8,1 gam bt Al vi 48 gam bt Fe2O3 ri cho tin hnh phn ng nhit nhm trong iu kin khng c khng kh, kt thc th nghim lng cht rn thu c l A. 61,5 gam. B. 56,1 gam. C. 65,1 gam. D. 51,6 gam. Cu 6: Nung 13,4g hn hp 2 mui cacbonat ca 2 kim loi ca ha tr II, thu c 6,8g cht rn v kh X. Lng kh X sinh ra cho hp th vo 75ml dd NaOH 1M, khi lng mui khan thu c sau phn ng l A. 5,8g B. 6,5g C. 4,2g D. 6,3g Cu 7: Ha tan hon ton 10,0 gam hn hp X gm hai kim loi (ng trc H trong dy in ha) bng dung dch HCl d thu c 2,24 lt kh H2 (ktc). C cn dung dch sau phn ng thu c lng mui khan l

A. 1,71 gam. B. 17,1 gam. C. 13,55 gam. D. 34,2 gam. Cu 8: Nhit phn hon ton m gam hn hp X gm CaCO3 v Na2CO3 thu c 11,6 gam cht rn v 2,24 lt kh (ktc). Hm lng % CaCO3 trong X l A. 6,25%. B. 8,62%. C. 50,2%. D. 62,5%. Cu 9: Cho 4,4 gam hn hp hai kim loi nhm IA hai chu k lin tip tc dng vi dung dch HCl d thu c 4,48 lt H2 (ktc) v dung dch cha m gam mui tan. Tn hai kim loi v khi lng m l A. 11 gam; Li v Na. B. 18,6 gam; Li v Na. C. 18,6 gam; Na v K. D. 12,7 gam; Na v K. Cu 10: t chy hon ton 18 gam FeS2 v cho ton b lng SO2 vo 2 lt dung dch Ba(OH)2 0,125M. Khi lng mui to thnh l A. 57,40 gam. B. 56,35 gam. C. 59,17 gam. D.58,35 gam. Cu 11: Ha tan 33,75 gam mt kim loi M trong dung dch HNO 3 long, d thu c 16,8 lt kh X (ktc) gm hai kh khng mu ha nu trong khng kh c t khi hi so vi hiro bng 17,8. a) Kim loi l A. Cu. B. Zn. C. Fe. D. Al. b) Nu dng dung dch HNO3 2M v ly d 25% th th tch dung dch cn ly l A. 3,15 lt. B. 3,00 lt. C. 3,35 lt. D. 3,45 lt Cu 12: Ho tan hon ton 15,9 gam hn hp gm 3 kim loi Al, Mg v Cu bng dung dch HNO3 thu c 6,72 lt kh NO v dung dch X. em c cn dung dch X thu c bao nhiu gam mui khan? A. 77,1 gam. B. 71,7 gam. C. 17,7 gam. D. 53,1 gam. Cu 13: Ha tan hon ton 2,81 gam hn hp gm Fe 2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l A. 6,81 gam. B. 4,81 gam. C. 3,81 gam. D. 5,81 gam. Cu 14: Cho 115g hn hp gm ACO3, B2CO3, R2CO3 tc dng ht vi dd HCl thy tht ra 0,448l CO2 (ktc). Khi lng mui clorua to ra trong dung dch l: A. 115,22g B.151,22g C. 116,22g D. 161,22g Cu 15: Cho kh CO qua ng ng a (g) hn hp gm CuO, Fe3O4, FeO, Al2O3 nung nng. Kh tht ra c cho vo nc vi trong d thy c 30g kt ta trng. Sau phn ng, cht rn trong ng s c khi lng 202g. Khi lng a (g) ca hn hp cc oxit ban u l: A. 200,8g B. 216,8g C. 206,8g D. 103,4g Cu 16: Ha tan 5g hn hp 2 mui cacbonat kim loi ha tr I v ha tr II bng dung dch HCl thu c dung dch M v 1,12l kh CO2 (ktc). Khi c cn dung dich M thu c khi lng mui khan bng: A. 11,1g B. 5,55g C. 16,5g D. 22,2g Cu 17: Cho 50g hn hp bt oxit kim loi gm ZnO, FeO, Fe2O3, Fe3O4, MgO tc dng ht vi 200ml dung dch HCl 4M (ly va ) thu c dung dch X. Lng mui c trong dung dch X bng: A. 79,2g B. 78,4g C. 72g D. 72,9g Cu 18: Ha tan 5,94g hn hp hai mui clorua ca hai kim loi A, B (A v B l 2 kim loi thuc PNC nhm II) vo nc c 100ml dung dch X. lm kt ta ht ion Cl- c trong dung dch X, Ngi ta cho dung dch X tc dng vi dd AgNO3 thu c 17,22g kt ta. Lc b kt ta, thu c dung dch Y. C cn Y c m (g) hn hp mui khan, m c gi tr l: A. 6,36g B. 63,6g C. 9,12g D. 91,2g Cu 19: Kh hn tn 11,6g oxit st bng C nhit cao. Sn phm kh dn vo nc vi trong d, to ra 10g kt ta. Cng thc phn t oxit st l cng thc no sau y: A. FeO B. Fe2O3 C. Fe3O4 D. FeO2 Cu 20: Ha tan hn tn 5g hn hp ba kim loi Zn, Fe,Mg vo dung dch H2SO4 thy tht ra 0,672l kh H2 (ktc). Khi c cn dung dch ta thu c bao nhiu gam mui khan? A. 4,66g B. 6,46g C. 9,7g D. 7,9g Cu 21: Cho 19,5g hn hp Cu, Fe, Zn tc dng vi O2 d, nung nng thu c m (g) hn hp X. Cho hn hp X ny tc dng va vi dung dch HCl cn 325ml dung dch 2M (khng c kh tht ra). Tnh khi lng mui clorua thu c: A. 28,525g B. 42,025g C. 65,1g D. 56,1g Cu 22:Cho 2,81gam hn hp gm Fe2O3 , ZnO , MgO tc dng va vi 500ml dd H2SO4 0,1M . Khi lng mui sunfat to ra trong dd l : A. 5,81gam B . 5,18gam C . 6,18gam D . 6,81gam Cu 23 : Cho 2,81gam hn hp gm Fe2O3 , ZnO , MgO tc dng va vi 300ml dd H2SO4 0,1M . Khi lng mui sunfat to ra trong dd l : A. 3,81gam B . 4,81gam C . 5,21gam D . 4,8gam Cu 24 : Cho 29 gam hn hp gm 3 kim loi Mg , Zn , Fe tc dng ht vi dd H2SO4 long thy sinh ra b lt H2 (KTC) , c cn dung dch sau phn ng thu c 86,6gam mui khan . Ga tr ca b l : A. 6,72 lt B . 8,96lt C . 3,36lt D . 13,44lt Cu 25 : Ho tan hon ton 17,5gam hn hp Mg , Zn , Cu vo 400ml dung dch HCl 1M va c dd A . Cho dn dn NaOH vo A thu c kt ta ti a , lc kt ta un nng n khi lng khng i c m gam cht rn . m c gi tr l : A. 20,7 B. 24 C . 23,8 D. 23,9 Cu 26. Cho 24,4g hn hp Na2CO3, K2CO3 tc dng va vi dung dch BaCl 2 . Sau phn ng thu c 39,4g kt ta. Lc

tch kt ta, c cn dung dch thu c m(g) mui clorua. Vy m c gi tr l: A. 2,66g B. 22,6g C. 26,6g D. 6,26g Bi 27.Cho t t mt lung kh CO i qua ng s ng m gam hn hp gm Fe, FeO, Fe3O4, Fe2O3 un nng thu c 64g st, kh i ra sau phn ng cho i qua dd Ca(OH)2 d c 40g kt ta. Tnh m. A.m = 70,4g B.m = 74g C.m = 65,4g D.m = 73g ==================================== PHNG PHP TNG GIM KHI LNG Nguyn tc ca phng php l xem khi chuyn t cht A thnh cht B (khng nht thit trc tip, c th b qua nhiu giai on trung gian) khi lng tng hay gim bao nhiu gam thng tnh theo 1 mol) v da vo khi lng thay i ta d dng tnh c s mol cht tham gia phn ng hoc ngc li PHN BI TP T LUN Bi 1: Nung mt lng Cu(NO3)2 sau mt thi gian dng li, ngui, em cn thy khi lng gim 27 gam. a) Tnh khi lng Cu(NO3)2 b phn hu. b) Tnh th tch cc kh thot ra iu kin tiu chun. Bi 2: Ho tan hon ton 23,8 gam hn hp gm mt mui cacbonat ca kim loi ho tr I v mui cacbonat ca kim loi ho tr II trong dung dch HCl. Sau phn ng thu c dung dch A v kh B. Dn ton b lng kh B i qua dung dich Ca(OH) 2 d thu c 20 gam kt ta. Hi em c cn dung dich A th thu c bao nhiu gam mui khan. Bi 3: Ho tan 14,2 gam hn hp mui cacbonat ca 2 kim loi A, B thuc phn nhm chnh nhm II bng dung dch HCl d thu c 3,36 lt kh CO2 (ktc) v dung dch D. a) Tnh tng s gam ca 2 mui c trong dung dich D. b) Xc nh 2 kim loi A v B, bit chng thuc 2 chu k lin tip trong bng HTTH. c) Tnh thnh phn % theo khi lng mi mui trong hn hp u. d) Cho ton b lng kh CO2 thu c trn hp th vo 250ml dung dch NaOH 1M. Tnh khi lng mui thu c? Bi 4: Nhng mt thanh Al nng 50 gam vo 400ml dung dch CuSO 4 0,5M. Sau mt thi gian ly thanh nhm ra, cn nng 51,38 gam. Tnh khi lng Cu thot ra v nng cc cht trong dung dch sau phn ng, gi s tt c Cu thot ra bm vo thanh Al v th tch dung dch thay i khng ng k. Bi 6: Hn hp NaI v NaBr ho tan vo nc c dung dch A cho thm Brom va vo dung dch A c mui X c khi lng nh hn khi lng ca hn hp mui ban u l a gam. Ho tan X vo nc c dung dch B, sc kh clo va vo dung dch B, thu c mui Y c khi lng nh hn khi lng ca mui X l a gam. Hy tnh % v khi lng ca cc cht trong hn hp mui ban u (Coi Cl2, Br2 , I2 khng phn ng vi nc). PHN BI TP TRC NGHIM Bi 1: Ha tan 9,875g mt mui hirocacbonat vo nc, cho tc dng vi dung dch H2SO4 va ri em c cn thu c 8,25g mt mui sunfat trung ha khan. Cng thc phn t ca mui l: A. NH4HCO3 B. NaHCO3 C. Ca( HCO3 )2 D. KHCO3 Bi 2:C 1 lt dung dch hn hp Na2CO3 0,1 mol/l v (NH4)2CO3 0,25 mol/l. Cho 43 gam hn hp BaCl2 v CaCl2 vo dung dch . Sau khi cc phn ng kt thc ta thu c 39,7 gam kt ta A v dung dch B. Tnh % khi lng cc cht trong A. A. %mBaCO3 = 50%, %mCaCO3 = 50%. B. %mBaCO3 = 50,38%, %mCaCO3 = 49,62%. C. %mBaCO3 = 49,62%, %mCaCO3 = 50,38%. D. Khng xc nh c. Bi 3:Ho tan hon ton 23,8 gam hn hp mt mui cacbonat ca kim loi ho tr (I) v mt mui cacbonat ca kim loi ho tr (II) bng dung dch HCl thy thot ra 4,48 lt kh CO2 (ktc). C cn dung dch thu c sau phn ng th khi lng mui khan thu c l bao nhiu? A. 26,0 gam. B. 28,0 gam. C. 26,8 gam. D. 28,6 gam. Bi 4:Cho dung dch AgNO3 d tc dng vi dung dch hn hp c ha tan 6,25 gam hai mui KCl v KBr thu c 10,39 gam hn hp AgCl v AgBr. Hy xc nh s mol hn hp u. A. 0,08 mol. B. 0,06 mol. C. 0,03 mol. D. 0,055 mol. Bi 5:Nhng mt thanh graphit c ph mt lp kim loi ha tr (II) vo dung dch CuSO4 d. Sau phn ng khi lng ca thanh graphit gim i 0,24 gam. Cng thanh graphit ny nu c nhng vo dung dch AgNO3 th khi phn ng xong thy khi lng thanh graphit tng ln 0,52 gam. Kim loi ha tr (II) l kim loi no sau y? A. Pb. B. Cd. C. Al. D. Sn. Bi 6:Ho tan hon ton 104,25 gam hn hp X gm NaCl v NaI vo nc c dung dch A. Sc kh Cl 2 d vo dung dch A. Kt thc th nghim, c cn dung dch thu c 58,5 gam mui khan. Khi lng NaCl c trong hn hp X l A. 29,25 gam. B. 58,5 gam. C. 17,55 gam. D. 23,4 gam. Bi 7:Ngm mt vt bng ng c khi lng 15 gam trong 340 gam dung dch AgNO 3 6%. Sau mt thi gian ly vt ra thy khi lng AgNO3 trong dung dch gim 25%. Khi lng ca vt sau phn ng l A. 3,24 gam. B. 2,28 gam. C. 17,28 gam. D. 24,12 gam. Bi 8:Nhng thanh km vo dung dch cha 8,32 gam CdSO4. Sau khi kh hon ton ion Cd2+ khi lng thanh km tng 2,35% so vi ban u. Hi khi lng thanh km ban u. A. 60 gam. B. 70 gam. C. 80 gam. D. 90 gam.

Bi 9:Nhng thanh kim loi M ho tr 2 vo dung dch CuSO4, sau mt thi gian ly thanh kim loi ra thy khi lng gim 0,05%. Mt khc nhng thanh kim loi trn vo dung dch Pb(NO 3)2, sau mt thi gian thy khi lng tng 7,1%. Xc nh M, bit rng s mol CuSO4 v Pb(NO3)2 tham gia 2 trng hp nh nhau. A. Al. B. Zn. C. Mg. D. Fe. Bi 10:Nung 100 gam hn hp gm Na2CO3 v NaHCO3 cho n khi khi lng hn hp khng i c 69 gam cht rn. Xc nh phn trm khi lng ca mi cht tng ng trong hn hp ban u. A. 15,4% v 84,6%. B. 22,4% v 77,6%. C. 16% v 84%. D. 24% v 76%. Bi 11:Ha tan 3,28 gam hn hp mui CuCl2 v Cu(NO3)2 vo nc c dung dch A. Nhng Mg vo dung dch A cho n khi mt mu xanh ca dung dch. Ly thanh Mg ra cn li thy tng thm 0,8 gam. C cn dung dch sau phn ng thu c m gam mui khan. Tnh m? A. 1.28 gam. B. 2,48 gam. C. 3,1 gam. D. 0,48 gam. Bi 12:Ha tan 3,28 gam hn hp mui MgCl2 v Cu(NO3)2 vo nc c dung dch A. Nhng vo dung dch A mt thanh st. Sau mt khong thi gian ly thanh st ra cn li thy tng thm 0,8 gam. C cn dung dch sau phn ng thu c m gam mui khan. Gi tr m l A. 4,24 gam. B. 2,48 gam. C. 4,13 gam. D. 1,49 gam. Bi 13:Cho 115 gam hn hp gm ACO3, B2CO3, R2CO3 tc dng ht vi dung dch HCl thy thot ra 22,4 lt CO2 (ktc). Khi lng mui clorua to ra trong dung dch l A. 142 gam. B. 126 gam. C. 141 gam. D. 132 gam. Bi 14: Ngm mt l st trong dung dch CuSO 4. Nu bit khi lng ng bm trn l st l 9,6 gam th khi lng l st sau ngm tng thm bao nhiu gam so vi ban u? A. 5,6 gam. B. 2,8 gam. C. 2,4 gam. D. 1,2 gam. Bi 15:Cho hai thanh st c khi lng bng nhau. - Thanh 1 nhng vo dung dch c cha a mol AgNO3. - Thanh 2 nhng vo dung dch c cha a mol Cu(NO3)2. Sau phn ng, ly thanh st ra, sy kh v cn li thy s cho kt qu no sau y? A. Khi lng hai thanh sau nhng vn bng nhau nhng khc ban u. B. Khi lng thanh 2 sau nhng nh hn khi lng thanh 1 sau nhng. C. Khi lng thanh 1 sau nhng nh hn khi lng thanh 2 sau nhng. D. Khi lng hai thanh khng i vn nh trc khi nhng. Bi 16: Cho V lt dung dch A cha ng thi FeCl3 1M v Fe2(SO4)3 0,5M tc dng vi dung dch Na2CO3 c d, phn ng kt thc thy khi lng dung dch sau phn ng gim 69,2 gam so vi tng khi lng ca cc dung dch ban u. Gi tr ca V l: A. 0,2 lt. B. 0,24 lt. C. 0,237 lt. D.0,336 lt. Bi 17: Cho lung kh CO i qua 16 gam oxit st nguyn cht c nung nng trong mt ci ng. Khi phn ng thc hin hon ton v kt thc, thy khi lng ng gim 4,8 gam. Xc nh cng thc v tn oxit st em dng. --------------------------------------------------------------------------------------PHNG PHP BO TON IN TCH I. Nguyn tc ca phng php: [6] [14] Phng php BTT da trn nh lut: in tch ca mt h c lp lun khng i tc l c bo ton. Ngha l tng in tch dng lun bng tng in tch m v gi tr tuyt i. Do dung dch lun trung ha v in ( q+ = q- ) II. Vn dng phng php bo ton in tch vo gii ton: - Thng dng gii quyt cc dng ton trong dung dch vi vic tnh ton khi lng mui khan, nng dung dch... MT S BI TP VN DNG Bi 1:Cho 100ml dung dch A cha Na2SO4 0,1M v Na2CO3 0,2M tc dng va vi 100ml dung dch B cha Ba(NO3)2 v Pb(NO3)2 0,05M to kt ta. Tnh nng mol ca Ba(NO3)2 v khi lng chung ca cc kt ta? A. 0,25M v 66,2g B. 0,15M v 6,62g C. 0,25M v 6,62g D. 0,15M v 66,2g
Bi 2:100ml dung dch X cha cc ion Ca2+: 0,1mol; NO3 : 0,05mol; Br : 0,15mol; HCO3 : 0,1mol v mt ion ca kim loi M. C cn dung dch thu c 29,1g mui khan. Ion kim loi M l ion no v tnh nng ca n trong dung dch. A. Na+ v 0,15M B. K+ v 0,1M 2+ C. Ca v 0,15M D. K+ v 1M Bi 3:Dung dch A cha Mg2+, Ba2+, Ca2+ v 0,2mol Cl , 0,3 mol NO3 . Thm dn dn dung dch Na2CO3 1M vo dung dch Acho n khi thu c lng kt ta ln nht th ngng li. Hi th tch dung dch A thm l bao nhiu? A. 150ml B. 200ml C. 250ml D. 300ml

2 Bi 4:Mt dung dch cha hai cation Fe2+ (0,1mol) v Al3+ (0,2mol) v hai anion Cl (x mol) v SO4 (y mol). Bit rng khi c cn dung dch thu c 46,9g cht rn khan. x v y c gi tr l: A. 0,2 v 0,3mol B. 0,15 v 0,3mol C. 0,2 v 0,35mol D. 0,15 v 0,2mol + Bi 5:C dung dch X, dung dich ny ch cha hai cation v hai anion trong s cc ion sau: K+ (0,15mol) ; NH 4 (0,25mol); H+ 2 2 (0,2mol); Cl (0,1mol); SO4 (0,075 mol); CO3 (0,15mol). Dung dch gm cc ion no? + 2 A. NH 4 , K+, CO3 , Cl + 2 B. NH 4 , K+, SO4 , Cl + 2 + 2 2 C. NH 4 , H+, SO4 , Cl D. NH 4 , K+, CO3 , SO4 Bi 6:100ml dung dch A cha AgNO3 0,06M v Pb(NO3)2 0,05M tc dng va vi 100ml dung dch B cha NaCl 0,08M v KBr. Tnh nng mol ca KBr trong dung dch B v lng kt ta to ra trong phn ng gia hai dung dch A v B. A. 0,08M v 2,458g B. 0,016M v 2,185g C. 0,008M v 2,297g D. 0,08M v 2,607g 2 Bi 7:Dung dch A cha x mol Al3+, y mol Cu2+, z mol SO4 v 0,4 mol Cl - C cn dung dch A c 45,2g mui khan. - Cho dung dch A tc dng vi dung dch NH3 ly d thu c 15,6g kt ta. Tm x,y,z. A. 0,2; 0,04; 0,24mol B. 0,1; 0,1; 0,05mol C. 0,2; 0,2; 0,3mol .D. 0,1; 0,15; 0,1mol Bi 8: Cho 3,75g hn hp A gm Mg v Al vo 250ml dung dch X cha HCl 1M v H2SO4 0,5M, c ung dch B v 3,92l H2 (ktc). C cn ddB thu c m(g) mui khan. Tm m? A. 19,3g B. 17,425g< m <19,3g C. 17,425g D. 17, 425g m 19,3g

==================================== PHNG PHP BO TON NGUYN T I. Nguyn tc ca phng php: Da vo nh lut bo tn nguyn t: Trong cc phn ng ha hc, cc nguyn t lun lun c bo tn. C th hiu nh lut nh sau: tng s mol nguyn t ca mt nguyn t A trc phn ng ha hc lun bng tng s mol nguyn t ca mt nguyn t A sau phn ng. Ch : nh lut c xem nh nguyn nhn ca nh lut bo tn khi lng. II. Vn dng phng php bo tn nguyn t trong gii tn: Cc dng tn thng s dng bo tn nguyn t: - Nguyn t ca nguyn t tn ti trong nhiu hp cht trong cng mt hn hp hoc dung dch... th khi lng ca nguyn t (hay ion) bng tng khi lng ca nguyn t ca nguyn t trong cc dng tn ti. - Tnh tn khi lng sn phm sau mt qu trnh phn ng th ch cn cn c vo cht u v cht cui, b qua cc phn ng trung gian v cc nguyn t lun c bo tn. Bi 1: kh hon ton 3,04 gam hn hp X gm FeO, Fe3O4, Fe2O3 cn 0,05 mol H2. Mt khc ha tan hon ton 3,04 gam hn hp X trong dung dch H2SO4 c thu c th tch kh SO2 (sn phm kh duy nht) iu kin tiu chun l A. 448 ml. B. 224 ml. C. 336 ml. D. 112 ml. Bi 2: Thi t t V lt hn hp kh (ktc) gm CO v H2 i qua mt ng ng 16,8 gam hn hp 3 oxit: CuO, Fe3O4, Al2O3 nung nng, phn ng hon ton. Sau phn ng thu c m gam cht rn v mt hn hp kh v hi nng hn khi lng ca hn hp V l 0,32 gam. Tnh V v m. A. 0,224 lt v 14,48 gam. B. 0,448 lt v 18,46 gam. C. 0,112 lt v 12,28 gam. D. 0,448 lt v 16,48 gam. Bi 3: Thi rt chm 2,24 lt (ktc) mt hn hp kh gm CO v H2 qua mt ng s ng hn hp Al2O3, CuO, Fe3O4, Fe2O3 c khi lng l 24 gam d ang c un nng. Sau khi kt thc phn ng khi lng cht rn cn li trong ng s l A. 22,4 gam. B. 11,2 gam. C. 20,8 gam. D. 16,8 gam. Bi 4: t chy hon ton 4,04 gam mt hn hp bt kim loi gm Al, Fe, Cu trong khng kh thu c 5,96 gam hn hp 3 oxit. Ha tan ht hn hp 3 oxit bng dung dch HCl 2M. Tnh th tch dung dch HCl cn dng. A. 0,5 lt. B. 0,7 lt. C. 0,12 lt. D. 1 lt. Bi 5: (Cu 46 - M 231 - TSC Khi A 2007) Cho 4,48 lt CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l

A. FeO; 75%. B. Fe2O3; 75%. C. Fe2O3; 65%. D. Fe3O4; 65%. Bi 6: Cho hn hp A gm Al, Zn, Mg. em oxi ho hon ton 28,6 gam A bng oxi d thu c 44,6 gam hn hp oxit B. Ho tan ht B trong dung dch HCl thu c dung dch D. C cn dung dch D c hn hp mui khan l A. 99,6 gam. B. 49,8 gam. C. 74,7 gam..D. 100,8 gam. Bi 7: Kh hon ton 24 gam hn hp CuO v FexOy bng H2 d nhit cao thu c 17,6 gam hn hp 2 kim loi. Khi lng H2O to thnh l A. 1,8 gam. B. 5,4 gam. C. 7,2 gam. D. 3,6 gam. Bi 8: Kh ht m gam Fe3O4 bng CO thu c hn hp A gm FeO v Fe. A tan va trong 0,3 lt dung dch H2SO4 1M cho ra 4,48 lt kh (ktc). Tnh m? A. 23,2 gam. B. 46,4 gam. C. 11,2 gam. D. 16,04 gam. Bi 9. Ha tan hon ton hn hp X gm 0,4 mol FeO v 0,1mol Fe2O3 vo dung dch HNO3 long, d thu c dung dch A v kh B khng mu, ha nu trong khng kh. Dung dch A cho tc dng vi dung dch NaOH d thu c kt ta. Ly ton b kt ta nung trong khng kh n khi lng khng i thu c cht rn c khi lng l A. 23,0 gam. B. 32,0 gam. C. 16,0 gam. D. 48,0 gam. Bi 10. Cho kh CO i qua ng s cha 16 gam Fe2O3 un nng, sau phn ng thu c hn hp rn X gm Fe, FeO, Fe3O4, Fe2O3. Ha tan hon ton X bng H2SO4 c, nng thu c dung dch Y. C cn dung dch Y, lng mui khan thu c l A. 20 gam. B. 32 gam. C. 40 gam. D. 48 gam. Bi 11. Kh hon ton 17,6 gam hn hp X gm Fe, FeO, Fe2O3 cn 2,24 lt CO ( ktc). Khi lng st thu c l A. 5,6 gam. B. 6,72 gam. C. 16,0 gam. D. 11,2 gam. Bi 12. t chy hn hp hirocacbon X thu c 2,24 lt CO2 (ktc) v 2,7 gam H2O. Th tch O2 tham gia phn ng chy (ktc) l A. 5,6 lt. B. 2,8 lt. C. 4,48 lt. D. 3,92 lt. Bi 13. Ho tan hon ton a gam hn hp X gm Fe v Fe2O3 trong dung dch HCl thu c 2,24 lt kh H2 ktc v dung dch B. Cho dung dch B tc dng dung dch NaOH d, lc ly kt ta, nung trong khng kh n khi lng khng i thu c 24 gam cht rn. Gi tr ca a l A. 13,6 gam. B. 17,6 gam. C. 21,6 gam. D. 29,6 gam. Bi 14 . Hn hp X gm Mg v Al2O3. Cho 3 gam X tc dng vi dung dch HCl d gii phng V lt kh (ktc). Dung dch thu c cho tc dng vi dung dch NH3 d, lc v nung kt ta c 4,12 gam bt oxit. V c gi tr l: A. 1,12 lt. B. 1,344 lt. C. 1,568 lt. D. 2,016 lt. Bi 15. Hn hp A gm Mg, Al, Fe, Zn. Cho 2 gam A tc dng vi dung dch HCl d gii phng 0,1 gam kh. Cho 2 gam A tc dng vi kh clo d thu c 5,763 gam hn hp mui. Phn trm khi lng ca Fe trong A l A. 8,4%. B. 16,8%. C. 19,2%. D. 22,4%. Bi 16. (Cu 2 - M 231 - TSC - Khi A 2007) t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh Oxi chim 20% th tch), thu c 7,84 lt kh CO2 (ktc) v 9,9 gam H2O. Th tch khng kh (ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l A. 70,0 lt. B. 78,4 lt. C. 84,0 lt. D. 56,0 lt. Bi 17. Ho tan hon ton 5 gam hn hp 2 kim loi X v Y bng dung dch HCl thu c dung dch A v kh H2. C cn dung dch A thu c 5,71 gam mui khan. Hy tnh th tch kh H2 thu c ktc. A. 0,56 lt. B. 0,112 lt. C. 0,224 lt D. 0,448 lt Bi 18. t chy hon ton m gam hn hp Y gm C2H6, C3H4 v C4H8 th thu c 12,98 gam CO2 v 5,76 gam H2O. Vy m c gi tr l A. 1,48 gam. B. 8,14 gam. C. 4,18 gam. D. 16,04 gam. Bi 19. Kh ht m (g) Fe3O4 bng kh CO thu c hn hp A gm FeO v Fe. A tan va trong 300ml dung dch H2SO4 1M to dung dch B. Tnh m v khi lng mui sunfat thu c khi c cn B. A. 23,2g v 45,6g B. 23,2g v 54,6g C. 2,32g v 4,56g D. 69,6g v 45,6g Bi 20. Ha tan hn tn hn hp A gm 0,1 mol Fe v 0,2 mol Cu vo mt lng va dung dch H2SO4 98% (c , nng) thu c kh SO2 (ktc) v dung dch B.Cho ddB tc dng vi NaOH d, c kt ta C, nung C n khi lng khng i c hn hp cht rn E. Cho E tc dng vi lng d CO, un nng thu c hn hp cht rn F. Khi lng ca hn hp cht rn F l: A. 24g B. 18,4g C. 15,6g D. 16,5g Bi 21. Ha tan a gam hh gm FeO v Fe3O4 ht 300ml ddHCl 2M c ddX. Cho X tc dng vi mt lng ddNH3 d c kt ta. Nung kt ta trong khng kh n khi lng khng i c a +1,2 g cht rn. Phn trm khi lng ca FeO trong hh trn l: A. 28,4% B. 24,6% C. 38,3% D. 40,2% ============================================== PHNG PHP NG CHO

Phng php ng cho thng p dng gii cc bi tn trn ln cc cht vi nhau, c th l ng th: lng - lng, kh - kh, rn - rn hoc d th lng - rn, lng - kh, nhng hn hp cui cng phi l ng th. Phng php ny c ngha thc t l trng hp pha ch dung dch. Tuy nhin, phng php ny ch p dng cho trng hp trn ln cc dung dch ca cng mt cht (hoc cht khc nhng do phn ng vi nc li cho cng mt cht) ; khng p dng cho trng hp trn ln cc cht khc nhau hoc xy ra phn ng ha hc. II.1. Nguyn tc ca phng php: trn ln 2 dung dch: - Dung dch 1: c khi lng m1, th tch V1, nng C1 (C% hoc CM), khi lng ring d1 - Dung dch 2: c khi lng m2, th tch V2, nng C2 (C2 > C1), khi lng ring d2. - Dung dch thu c c m = m1+ m2, V= V1+ V2, nng C (C1<C <C2), khi lng ring d. MT S BI TP VN DNG Bi 1:: thu c dung dch HCl 25% cn ly m1 gam dung dch HCl 45% pha vi m2 gam dung dch HCl 15%. T l m1/m2 l A. 1:2. B. 1:3. C. 2:1. D. 3:1. Bi 1:: pha c 500 ml dung dch nc mui sinh l (C = 0,9%) cn ly V ml dung dch NaCl 3% pha vi nc ct. Gi tr ca V l A. 150 ml. B. 214,3 ml. C. 285,7 ml. D. 350 ml. Bi 3: Ha tan 200 gam SO3 vo m2 gam dung dch H2SO4 49% ta c dung dch H2SO4 78,4%. Gi tr ca m2 l A. 133,3 gam. B. 146,9 gam. C. 272,2 gam. D. 300 gam. 79 81 Bi 4: Nguyn t khi trung bnh ca brom l 79,319. Brom c hai ng v bn: 35 Br v 35 Br . Thnh phn % s nguyn t ca
81 35

Br l

A. 84,05. B. 81,02. C. 18,98. D. 15,95. Bi 5: Mt hn hp gm O2, O3 iu kin tiu chun c t khi hi vi hiro l 18. Thnh phn % v th tch ca O 3 trong hn hp l A. 15%. B. 25%. C. 35%. D. 45%. Bi 6: Cn trn hai th tch metan vi mt th tch ng ng X ca metan thu c hn hp kh c t khi hi so vi hiro bng 15. X l A. C3H8. B. C4H10. C. C5H12. D. C6H14. Bi 7: Thm 250 ml dung dch NaOH 2M vo 200 ml dung dch H3PO4 1,5M. Mui to thnh v khi lng tng ng l A. 14,2 gam Na2HPO4 ; 32,8 gam Na3PO4. B. 28,4 gam Na2HPO4 ; 16,4 gam Na3PO4. C. 12 gam NaH2PO4 ; 28,4 gam Na2HPO4. D. 24 gam NaH2PO4 ; 14,2 gam Na2HPO4. Bi 8: Ha tan 3,164 gam hn hp 2 mui CaCO 3 v BaCO3 bng dung dch HCl d, thu c 448 ml kh CO 2 (ktc). Thnh phn % s mol ca BaCO3 trong hn hp l A. 50%. B. 55%. C. 60%. D. 65%. Bi 9: Cn ly bao nhiu gam tinh th CuSO4.5H2O v bao nhiu gam dung dch CuSO4 8% pha thnh 280 gam dung dch CuSO4 16%? A. 180 gam v 100 gam. B. 330 gam v 250 gam. C. 60 gam v 220 gam. D. 40 gam v 240 gam. Bi 11: Cn bao nhiu lt axit H2SO4 (D = 1,84) v bao nhiu lt nc ct pha thnh 9 lt dung dch H2SO4 c D = 1,28 gam/ml? A. 2 lt v 7 lt. B. 3 lt v 6 lt. C. 4 lt v 5 lt. D. 6 lt v 3 lt. Bi 12. Ha tan hon ton m gam Na2O nguyn cht vo 40 gam dung dch NaOH 12% thu c dung dch NaOH 51%. Gi tr ca m (gam) l A. 11,3. B. 20,0. C. 31,8. D. 40,0. Bi 13:Th tch nc nguyn cht cn thm vo 1 lt dung dch H 2SO4 98% (d = 1,84 g/ml) c dung dch mi c nng 10% l A. 14,192 ml. B. 15,192 ml. C. 16,192 ml. D. 17,192 ml. 63 65 Bi 14:Nguyn t khi trung bnh ca ng 63,54. ng c hai ng v bn: 29 Cu v 29 Cu Thnh phn % s nguyn t ca
65 29

Cu l

A. 73,0%. B. 34,2%. C.32,3%. D. 27,0%. Bi 15:Cn ly V1 lt CO2 v V2 lt CO c c 24 lt hn hp CO 2 v CO c t khi hi i vi metan bng 2. Gi tr ca V 1 (lt) l A. 2. B. 4. C. 6. D. 8. Bi 16: Thm 150 ml dung dch KOH 2M vo 120 ml dung dch H3PO4 1M. Khi lng cc mui thu c trong dung dch l A. 10,44 gam KH2PO4 ; 8,5 gam K3PO4. B. 10,44 gam K2HPO4 ; 12,72 gam K3PO4. C. 10,44 gam K2HPO4 ; 13,5 gam KH2PO4. D. 13,5 gam KH2PO4 ; 14,2 gam K3PO4.

Bi 17:Ha tan 2,84 gam hn hp 2 mui CaCO3 v MgCO3 bng dung dch HCl (d) thu c 0,672 lt kh iu kin tiu chun. Thnh phn % s mol ca MgCO3 trong hn hp l A. 33,33%. B. 45,55%. C. 54,45%. D. 66,67%. Bi 18: Lng SO3 cn thm vo dung dch H2SO4 10% c 100 gam dung dch H2SO4 20% l A. 2,5 gam. B. 8,88 gam. C. 6,66 gam. D. 24,5 gam. o l Bi 19: Dung dch ru etylic 13,8 c d (g/ml) =?. Bit dC2H5OH(ng.cht) =0,8 g/m ; d H 2O = 1 g ml . A. 0,805. B. 0,8 55. C. 0,972. D. 0,915. Bi 20:Ha tan m gam Al bng dung dch HNO3 long thu c hn hp kh NO v N2O c t khi so vi H2 bng 16,75. T l th tch kh trong hn hp l A. 2 : 3. B. 1 : 2. C. 1 : 3. D. 3 : 1. Bi 21: T 1 tn qung hematit A iu ch c 420 kg Fe. T 1 tn qung manhetit B iu ch c 504 kg Fe. Hi phi trn hai qung trn vi t l khi lng (mA : mB) l bao nhiu c 1 tn qung hn hp m t 1 tn qung hn hp ny iu ch c 480 kg Fe. A. 1 : 3. B. 2 : 5. C. 2 : 3. D. 1 : 1.
========================================================

TNH THEO PHNG TRNH ION Cu 1: Cho t t 500 ml dung dch HCl 1M vo 300 ml dung dch Na2CO3 1M thu c V lt kh (ktc). V l: A. 5,6 lt B. 3,36 lt C. 6,72 lt D. 4,48 lt Cu 2: Mt dung dch cha 0,02 mol Cu2+ , 0,03 mol K+ , x mol Cl- v y mol SO42- . Tng khi lng cc mui tan trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l : A. 0,03 v 0,02 B. 0,05 v 0,01 C. 0,01 v 0,03 D. 0,02 v 0,05 Cu 3: Cho t t 2 lt dung dch hn hp gm: HCl 1M v CH3COOH 0,1M vo 500 ml dung dch hn hp gm: Na2CO3 0,4M v K2CO3 2M thu c V lt kh (ktc). V l: A. 22,4 lt B. 33,6 lt C. 11,2 lt D. 44,8 lt Cu 4: Cho 2 mol kh CO2 phn ng hon ton vi 1,5 lt dung dch hn hp NaOH 1M v Ba(OH) 2 0,2M. Sau phn ng thu c khi lng kt ta l: A. 19,7 gam B. 39,4 gam C. 59,1 gam D. 78,8 gam 2+ + 2Cu 5: Dung dch A gm: a mol Mg , b mol Cl , c mol NH4 , d mol SO4 . Biu thc no sau y l ng: A. 2a + b = c + 2d B. 2a + c = b + d C. 2a - d = b c D. 2a - 2d = b c Cu 6: Dung dch A gm 4 ion: a mol Na+ , b mol Ca2+ , 1 mol NO3- v 2 mol Cl- . Thm 2 lt lt dung dch Na2CO3 1M vo dung dch A n khi phn ng hon ton kt thc th thu c 100 gam kt ta. a bng: A. 1 B. 0,5 C. 1,5 D. 2 Cu 7: Dung dch A c cha 5 ion : Mg 2+, Ba2+ , Ca2+, 0,1 mol Cl- v 0,2 mol NO-3 . Thm dn V lt dung dch K2CO3 1M vo A n khi c lng kt ta ln nht. V c gi tr l A. 150 ml B. 300 ml C. 200 ml D. 250 ml Cu 8: Cho 500 ml dung dch A Cha hn hp Ba(OH) 2 0,5M v KOH 0,5M trung ho va 400 ml dung dch B cha hn hp HCl C1 (M) v H2SO4 C2 (M). Sau phn ng thu c 46,6 gam kt ta. Gi tr C1 v C2 ln lt l: A. 0,5 M v 0,6 M. B. 0,875 M v 0,5 M. C. 0,6M v 0,75 M. D. 0,5 M v 1 M Cu 9: Cho 100ml dung dch A cha Na 2SO4 0,1M , K2SO4 0,2M phn ng va vi 100ml dung dch B cha Pb(NO 3)2 0,1M v Ba(NO3)2 . Tnh nng mol ca Ba(NO3)2 trong dung dch v khi lng cht kt ta thu c sau phn ng gia 2 dung dch A v B. A. 0,1M, 6,32g B. 0,2M, 7,69g C. 0,2M, 8,35g D. 0,1M, 7,69g Cu 10: Mt dung dch X c V= 200ml c cha H2SO4 1M v HCl 2M. Thm vo dung dch X 300 ml dung dch Ba(OH)2 0,8 M. Tnh nng mol cc ion cha trong dung dch Y thu c sau phn ng (V dung dchY = 500ml): A. CBa2+ =0,08M ,CH+ =0,24 mol ,CCl- = 0,8M B. CBa2+ =0,16M ,CH+ =0,12 mol ,CCl- = 1,6M C. CBa2+ =0,08M ,CH+ =0,64 mol ,CCl- = 0,8M D. CBa2+ =0,24M ,CH+ =0,64 mol ,CCl- = 0,8M Cu 11: Cho 2 mol kh CO2 phn ng hon ton vi 1,5 lt dung dch hn hp NaOH 1M v Ba(OH) 2 0,2M. Sau phn ng thu c m gam kt ta. m bng? A. 19,7 gam B. 39,4 gam C. 54,1 gam D. 78,8 gam Cu 12: Cho 500 ml dung dch NaOH 1M vo 250 ml dung dch NH4Cl 2M c cha qu tm, un nng dung dch n khi phn ng hon ton. Mu dung dch s: A. Chuyn t mu xanh sang mu B. Chuyn t mu sang mu xanh C. Chuyn t mu tm sang mu D. Chuyn t mu sang mu tm

Cu 13: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l : A. 1. B. 6. C. 7. D. 2. Cu 14: Cho mt mu hp kim Na-Ba tc dng vi nc (d) thu c dung dch X v 3,36 lt H2 ( ktc). Th tch dung dch axit H2SO4 2M cn dng trung ho dung dch X l : A. 150ml B. 75ml C. 60ml D. 30ml Cu 16: Cho m gam mt hn hp Na2CO3 v Na2SO3 tc dng ht vi dung dch H2SO4 2M d th thu c 2,24 lit hn hp kh (ktc) c t khi i vi hiro l 27. Gi tr ca m l: A. 1,16 gam. B. 11,6 gam. C. 6,11 gam. D. 61,1 gam. Cu 17: Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 500 ml dung dch hn hp gm NaOH 0,1M v Ba(OH) 2 0,2M, sinh ra m gam kt ta. Gi tr ca m l: A. 19,70 B. 17,73 C. 9,85 D. 11,82 Cu 18: Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO 3 0,8M v H2SO4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l: A. 0,746 B. 0,448 C. 1,792 D. 0,672 Cu 19: Cho 3,87 gam hn hp A gm Mg v Al vo dung dch cha: 0,25mol HCl v 0,125 mol H 2SO4 ta thu c dung dch B v 4,368 lit H2 (ktc). Thnh phn phn trm khi lng ca Mg trong A l: A. 21,30% B. 37,21% C. 65,78% D. 62,79% Cu 20: Ngi ta tin hnh 2 th nghim sau: - TN1: Cho 2,02 gam hn hp Mg, Zn vo cc ng 200ml dung dch HCl. Sau phn ng un nng cho nc bay hi ht thu c 4,86 gam cht rn. - TN2: Cho 2,02 gam hn hp trn vo cc ng 400ml dung dch HCl trn. Sau khi c cn thu c 5,57 gam cht rn. Khi lng kim loi Zn trong hn hp ban u l: A. 0,13 gam B. 1,3 gam C. 0,65 gam D. 0,325 gam Cu 21: Cho a gam Fe ho tan trong dung dch HCl (TN1) sau khi c cn dung dch thu c 3,1 gam cht rn. Nu cho a gam Fe v b gam Mg ( TN2) vo dung dch HCl cng vi lng trn sau khi c cn dung dch thu thu c 3,34 gam cht rn . Bit th tch H2 thot ra c 2 TN u l 448 ml. Gi tr ca a, b ln lt l (bit rng TN2 Mg hot ng mnh hn Fe, ch khi Mg phn ng xong th Fe mi phn ng). A. 1,68g v 0,48g B. 1,12g v 0,24g C. 1,68g v 0,24g D. Kt qu khc Cu 22: Trn 100ml dung dch Ba(OH)2 0,5M v 100ml dung dch KOH 0,5M thu dung dchX. Cho X tc dng vi 100ml dung dch H2SO4 1M. Khi lng kt ta v gi tr pH ca dung dch thu c sau phn ng: A. 11,65g ;13,22. B. 23,3g;13,22. C. 11,65g; 0,78. D. 23,3g; 0,78. Cu 23: Cho 100 ml dung dch A cha Na2SO4 0,1M v Na2CO3 0,1M tc dng va vi 100 ml dung dch B cha Ba(NO3)2 0,05M v Pb(NO3)2 aM to kt ta . Tnh nng mol/l ca Pb(NO3)2 v khi lng chung ca cc kt ta. A. 0,15M; 5,35g B. 0,15M; 5,53g C. 0,2M; 3,55g D. Kt qu khc Cu 24: Thc hin hai th nghim: +. Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO 3 1M thot ra V1 lt NO.Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l: (cho Cu = 64) A. V2 = V1 B. V2 = 2V1 C. V2 = 2,5V1 D. V2 = 1,5V1 PHNG PHP QUI I Mt s bi ton ha hc c th gii nhanh bng cc phng php bo ton electron, bo ton nguyn t, bo ton khi lng song phng php quy i cng tm ra p s rt nhanh v l phng php tng i u vit, c th vn dng vo cc bi tp trc nghim phn loi hc sinh. Cc ch khi p dng phng php quy i: 1. Khi quy i hn hp nhiu cht (hn hp X) (t ba cht tr ln) thnh hn hp hai cht hay ch cn mt cht ta phi bo ton s mol nguyn t v bo ton khi lng hn hp. 2. C th quy i hn hp X v bt k cp cht no, thm ch quy i v mt cht. Tuy nhin ta nn chn cp cht no n gin c t phn ng oxi ha kh nht n gin vic tnh ton. 3. Trong qu trnh tnh ton theo phng php quy i i khi ta gp s m l do s b tr khi lng ca cc cht trong hn hp. Trong trng hp ny ta vn tnh ton bnh thng v kt qu cui cng vn tha mn. 4. Khi quy i hn hp X v mt cht l FexOy th oxit FexOy tm c ch l oxit gi nh khng c thc. Bi1: Nung 8,4 gam Fe trong khng kh, sau phn ng thu c m gam cht rn X gm Fe, Fe 2O3, Fe3O4, FeO. Ha tan m gam hn hp X vo dung dch HNO3 d thu c 2,24 lt kh NO2 (ktc) l sn phm kh duy nht. Gi tr ca m l A. 11,2 gam. B. 10,2 gam. C. 7,2 gam. D. 6,9 gam. Bi2: Ha tan ht m gam hn hp X gm FeO, Fe 2O3, Fe3O4 bng HNO3 c nng thu c 4,48 lt kh NO 2 (ktc). C cn dung dch sau phn ng thu c 145,2 gam mui khan gi tr ca m l A. 35,7 gam. B. 46,4 gam. C. 15,8 gam. D. 77,7 gam. Bi3: Ha tan hon ton 49,6 gam hn hp X gm Fe, FeO, Fe2O3, Fe3O4 bng H2SO4 c nng thu c dung dch Y v 8,96 lt kh SO2 (ktc). a) Tnh phn trm khi lng oxi trong hn hp X. A. 40,24%. B. 30,7%. C. 20,97%. D. 37,5%.

b) Tnh khi lng mui trong dung dch Y. A. 160 gam. B.140 gam. C. 120 gam. D. 100 gam. Bi4: kh hon ton 3,04 gam hn hp X gm FeO, Fe2O3, Fe3O4 th cn 0,05 mol H2. Mt khc ha tan hon ton 3,04 gam hn hp X trong dung dch H2SO4 c nng th thu c th tch kh SO2 (sn phm kh duy nht ktc) l. A. 224 ml. B. 448 ml. C. 336 ml. D. 112 ml. Bi5: Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong dung dch HNO3 (d) thot ra 0,56 lt NO ( ktc) (l sn phm kh duy nht). Gi tr ca m l A. 2,52 gam. B. 2,22 gam. C. 2,62 gam. D. 2,32 gam. Bi6: Hn hp X gm (Fe, Fe2O3, Fe3O4, FeO) vi s mol mi cht l 0,1 mol, ha tan ht vo dung dch Y gm (HCl v H 2SO4 long) d thu c dung dch Z. Nh t t dung dch Cu(NO3)2 1M vo dung dch Z cho ti khi ngng thot kh NO. Th tch dung dch Cu(NO3)2 cn dng v th tch kh thot ra ktc thuc phng n no? A. 25 ml; 1,12 lt. B. 0,5 lt; 22,4 lt. C. 50 ml; 2,24 lt. D. 50 ml; 1,12 lt. Bi7: Nung 8,96 gam Fe trong khng kh c hn hp A gm FeO, Fe 3O4, Fe2O3. A ha tan va vn trong dung dch cha 0,5 mol HNO3, bay ra kh NO l sn phm kh duy nht. S mol NO bay ra l. A. 0,01. B. 0,04. C. 0,03. D. 0,02. Bi -1 -: Ha tan hon ton 2,84 gam hn hp hai mui cacbonat ca hai kim loi phn nhm II A v thuc hai chu k lin tip trong bng tun hon bng dung dch HCl ta thu c dung dch X v 672 ml CO2 ( ktc). 1. Hy xc nh tn cc kim loi. A. Be, Mg. B. Mg, Ca. C. Ca, Ba. D. Ca, Sr. 2. C cn dung dch X th thu c bao nhiu gam mui khan? A. 2 gam. B. 2,54 gam. C. 3,17 gam. D. 2,95 gam. 63 65 Bi -2 -: Trong t nhin, ng (Cu) tn ti di hai dng ng v 29 Cu v 29Cu . KLNT (xp x khi lng trung bnh) ca Cu l 63,55. Tnh % v khi lng ca mi loi ng v. A. 65Cu: 27,5% ; 63Cu: 72,5%. B. 65Cu: 70% ; 63Cu: 30%. C. 65Cu: 72,5% ; 63Cu: 27,5%. D. 65Cu: 30% ; 63Cu: 70%. Bi -3 -Ho tan 18,4 gam hn hp hai mui ccbonnat ca hai kim loi ng lin tip trong phn nhm chnh nhm II ca bng tun hon vo dung dch HCl d thu c 4,48 lit kh ktc. Hy xc nh tn hai kim loi. (chn p n ng). A.Be, Mg B.Mg, Ca C.Ca, Sr D.Sr, Ba Bi -4-Hai kim loi A v B c ho tr khng i l II.Cho 0,64 g hn hp A v B tan hon ton trong dung dch HCl ta thy thot ra 448 ml kh (ktc). S mol ca hai kim loi trong hn hp l bng nhau. Hai kim loi l: a. Zn, Cu b. Zn, Mg c. Zn, Ba d. Mg, Ca Bi -5-H tan ht 7,6g hn hp 2 kim loi X v Y nhm IIA thuc 2 chu k lin tip bng dd HCl d th thu c 5,6 lit kh (ktc). X v Y l nhng kim loi no sau y? A. Mg v Ca B. Be v Mg C. Ca v Sr D. Sr v Ba Bi -6-Cho 500ml dd X cha 2 mui NaA v NaB vi A v B l halogen (nhm VIIA thuc 2 chu k k tip ca bng HTTH) tc dng vi 100ml ddAgNO3 0,1M (lng va , cho ra 1,5685g kt ta). Xc nh A, B v nng mol ca NaA v NaB trong dd X. A. F v Cl; CNaF = 0,015M; CNaCl = 0,005M B. Br v I; CNaBr = 0,014M; CNaI = 0,006M C. Cl v Br; CNaCl = 0,012M; CNaBr = 0,008M D. Cl v Br; CNaCl = 0,014M; CNaBr = 0,006M Bi -7-Hn hp A gm cc kh N2, H2, NH3 (v mt t cht xc tc) c t khi so vi H2 bng 6,05. Nung nng A mt thi gian thy t khi hn hp so vi H2 tng 0,348. Vy, hiu sut to kh NH3 l: A. 10% b. 18,75% C. 34% D. 27% Bi -8-Hn hp A gm 2 kim loi X,Y c ha tr khng i v khng c kim loi no ha tr I. Ly 7,68g hn hp A chia thnh 2 phn bng nhau: - Phn 1: nung trong kh O2 d oxi ha hn tn, thu c 6g hn hp rn B gm 2 oxit - Phn 2: ha tan hn tn trong dd cha HCl v H2SO4 lng, thu c V lit kh H2 (ktc) v ddC. Tnh V. A. 2,352lit B. 4,704lit C. 3,024lit D. 1,176lit Bi -9-0,1 mol hn hp A c khi lng 3,84g gm 2 kim loi X,Y c ha tr khng i v khng c kim loi no ha tr I. Nung hn hp A trong O2 d oxi ha hn tn, thu c 6g hn hp rn B gm 2 oxit. Bit khi lng nguyn t ca X, Y u ln hn 20vC. X, Y l nhng kim loi no? A. Mg v Fe B. Mg v Zn C. Al v Zn D. Al v Fe Bi -10-Mt hn hp 2 kim loi kim 2 chu k k tip ca bng HTTH c khi lng l 8,5g. Hn hp ny tan ht trong nc d cho ra 3,36lit kh H2 (ktc). Xc nh A, B v khi lng mi kim loi. A. Na, K; 4,6g Na; 3,9g K B. Na, K; 2,3g Na; 6,1g K C. Li, Na; 1,4g Li; 7,1g Na A. Li, Na; 2,8g Li; 5,7g Na Bi -11-2,56g mt hn hpX gm 2 halogen A2, B2 (thuc 2 chu k k tip ca bng HTTH) tc dng ht vi Ag cho ra hn hp 2 mui c khi lng l 133,6g. Xc nh A, B v A2, B2 trong hn hp X.

A. Cl, Br; mCl2 = 14 ,2 g; m Br2 = 11,4 g

B. F, Cl; m Br2 = 5 ,7 g;mCl 2 = 19,9 g

C. F, Cl; m F2 = 11,4 g; mCl 2 = 14 ,2 g D. Cl, Br; mCl 2 = 7 ,1g ; m Br2 = 18,5 g Bi -12-Hn hp X nng 5,28g gm Cu v mt kim loi ch c ha tr 2, 2 kim loi ny c cng s mol. X tan ht trong HNO3 sinh ra 3,584 lit hn hp NO2 v NO (ktc) c t khi vi H2 l 21. Kim loi cha bit l: A. Ca B. Mg C. Ba D. Zn PHNG PHP T CHN LNG CHT Trong mt s cu hi v bi tp trc nghim chng ta c th gp mt s trng hp c bit sau: - C mt s bi ton tng nh thiu d kin gy b tc cho vic tnh ton. - C mt s bi ton ngi ta cho di dng gi tr tng qut nh a gam, V lt, n mol hoc cho t l th tch hoc t l s mol cc cht... Nh vy kt qu gii bi ton khng ph thuc vo cht cho. Trong cc trng hp trn tt nht ta t chn mt gi tr nh th no cho vic gii bi ton tr thnh n gin nht. Cch 1: Chn mt mol nguyn t, phn t hoc mt mol hn hp cc cht phn ng. Cch 2: Chn ng t l lng cht trong u bi cho. Cch 3: Chn cho thng s mt gi tr ph hp chuyn phn s phc tp v s n gin tnh ton. Cch 1: CHN 1 MOL CHT HOC HN HP CHT PHN NG Bi 1: Ho tan mt mui cacbonat kim loi M ha tr n bng mt lng va dung dch H 2SO4 9,8% ta thu c dung dch mui sunfat 14,18%. M l kim loi g? A. Cu. B. Fe. C. Al. D. Zn. Bi 2: Cho dung dch axit axetic c nng x% tc dng va vi dung dch NaOH 10% th thu c dung dch mui c nng 10,25%. Vy x c gi tr no sau y? A. 20%. B. 16%. C. 15%. D.13%. Bi 3: (Khi A - TSC 2007)Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch mui trung ho c nng 27,21%. Kim loi M l A. Cu. B. Zn. C. Fe. D. Mg. Bi4: Hn hp X gm N2 v c H2 c t khi hi so vi H2 bng 3,6. Sau khi tin hnh phn ng tng hp c hn hp Y c t khi hi so vi H2 bng 4. Hiu sut phn ng tng hp l A. 10%. B. 15%. C. 20%. D. 25%.

Bi5: Hn hp X gm N2 v H2 c M X = 12,4 . Dn X i qua bnh ng bt Fe ri nung nng bit rng hiu sut tng hp NH 3 t 40% th thu c hn hp Y. M Y c gi tr l A. 15,12. B. 18,23. C. 14,76. D. 13,48.

Bi6: Phng in qua O2 c hn hp kh O2, O3 c M = 33 gam. Hiu sut phn ng l A. 7,09%. B. 9,09%. C. 11,09%. D.13,09%. Bi7: Ho tan hon ton mt lng kim loi R ha tr n bng dung dch H 2SO4 long ri c cn dung dch sau phn ng thu c mt lng mui khan c khi lng gp 5 ln khi lng kim loi R ban u em ho tan. Kim loi R l A. Al. B. Ba. C. Zn. D. Mg. Cch 2: CHN NG T L LNG CHT TRONG U BI CHO Bi8: (khi A - TSH 2007)Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H 2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l A. C3H8. B. C3H6. C. C4H8. D. C3H4. Cch 3: CHN GI TR CHO THNG S Bi9: X l hp kim gm (Fe, C, Fe3C), trong hm lng tng cng ca Fe l 96%, hm lng C n cht l 3,1%, hm lng Fe3C l a%. Gi tr a l A. 10,5. B. 13,5. C. 14,5. D. 16.

Bi10: Nung m gam X cha 80% khi lng gam CaCO3 (phn cn li l tp cht tr) mt thi gian thu c cht rn Y cha 45,65 % CaO. Tnh hiu sut phn hy CaCO3. A. 50%. B. 75%. C. 80%. D. 70%.

PHNG PHP PHN TCH H S Bi Sau khi ozon ha, th tch ca O2 gim i 5ml. Hi c bao nhiu ml O3 c to thnh. A 7,5 ml B 10 ml C 5ml D 15ml Li gii ca: 220thanhxinh284 p dng phng php phn tch h s trong trng hp c s tng gim s mol kh vi phn ng ozone ha: 3O2 2O3 Th tch kh gim bng 1/2 th tch kh O3 sinh ra. Do , p n ng l B. p dng phng php phn tch h s trong trng hp c s tng gim s mol kh vi phn ng ozone ha: 3O2 2O3 Th tch kh gim bng 1/2 th tch kh O3 sinh ra. ===> B. Bi a mt hn hp kh N2 v H2 c t l 1:3 vo thp tng hp, sau phn ng thy th tch kh i ra gim 10% so vi ban u. Tnh thnh phn phn trm v th tch ca hn hp kh sau phn ng. A 20%, 60%, 20% B 22,22%, 66,67%, 11,11% C 30%, 60%, 10% D 33,33%, 50%, 16,67% Li gii ca: Moon.vn gii nhanh bi ton ny, ta da vo 2 kt qu quan trng: - Trong phn ng c hiu sut nh hn 100%, nu t l cc cht tham gia phn ng bng ng h s cn bng trong phng trnh phn ng, th sau phn ng, phn cht d cng c t l ng vi h s cn bng ca phn ng. C th trng hp ny l 1:3. Do A v B c kh nng l p n ng, C v D b loi. - Trong phn ng tng hp amoniac, th tch kh gim sau phn ng (2 mol) ng bng th tch kh NH3 sinh ra (2 mol). Trong trng hp ny, %NH3 = 1/10 hn hp u hay l 1/9 = 11,11% hn hp sau. Vy p n ng l B. 22,22%, 66,67%, 11,11% Bi Trn ln 250 ml dung dch NaOH 2M vo 200 ml dung dch H3PO4 1,5M, ri c cn dung dch sau phn ng. % khi lng ca Na2HPO4 trong hn hp cht rn thu c l: A 29,7% B 70,3% C 28,4% D 56,8% T khi ca hn hp gm H2, CH4, CO so vi Hiro bng 7,8. t chy hon ton mt th tch hn hp ny cn 1,4 th tch oxi. Thnh phn phn trm v th tch ca mi kh trong hn hp u l: A 20%, 50%, 30% B 33,33%, 50%, 16,67% C 20%, 60%, 20% D 10%, 80%, 10% Hn hp X gm 2 cht hu c k tip nhau trong cng dy ng ng, phn t ca chng ch c mt nhm chc. Chia X lm 2 phn bng nhau: - Phn 1: em t chy hon ton ri cho ton b sn phm chy (ch c CO2 v H2O) ln lt qua bnh (1) ng dung dch H2SO4 c, bnh (2) ng dung dch Ca(OH)2 d, thy khi lng bnh (1) tng 2,16 gam v bnh (2) c 7 gam kt ta. - Phn 2: cho tc dng ht vi Na d th th tch kh H2 (ktc) thu c l bao nhiu. A 0,224 lt B 2,24 lt C 0,56 lt D 1,12 lt

Li gii ca: Moon.vn Ta c: nH2O = 0,12 mol > nCO2 = 0,07 mol => cc cht trong X l hp cht no. Mt khc chng ch c mt nhm chc, tc dng vi Na gii phng H2 => hn hp X gm 2 ru no, n chc vi s mol mi phn l: nX = nH2O - nCO2 = 0,05 mol. Do , th tch kh H2 sinh ra bng 1/2 th tch X. p n ng l C.