B GIO DC V O TO CNG HA X HI CH NGHA VIT NAM TRNG I HC S PHM H NI c lp T do Hnh phc

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THI TUYN SINH VO TRNG TRUNG HC PH THNG CHUYN NM 2011 Mn thi: HA HC (Dng cho th sinh thi vo lp chuyn Ha hc) THI GM Thi gian lm bi: 120 pht 02 TRANG Cu I 1. Ha tan mt oxit st vo dung dch H 2SO4 (long, d), c dung dch X. Dung dch X c kh nng lm mt mu nc brom, lm mt mu dung dch thuc tm v ha tan c bt ng. a. Xc nh cng thc oxit st v vit cc phng trnh phn ng xy ra. b. Vit cc phng trnh phn ng khi cho oxit st tc dng vi dung dch HNO 3 long (to kh NO), vi dung dch H2SO4 c nng. 2. Hn hp Y gm CuO v Fe2O3. Ch dng thm dung dch HCl v bt Al, nu 3 cch tch ly Cu kim loi t hn hp Y (cc iu kin v phng tin cn thit c ). 3. Cho BaO vo dung dch H 2SO4 (long), sau khi phn ng kt thc thu c kt ta A v dung dch cht B (c kh nng to kt ta vi C O2). Cho b Al d vo dung dch B thu t c kh E v dung dch cht D. Ly dung dch D cho tc dng vi dung dch Na 2CO3 thu c kt ta F. Xc nh cng thc A, B, D, E, F. Vit cc phng trnh phn ng xy ra. Cu II 1. Hp cht hu c A (to nn t C, H, O) c mch cacbon khng phn nhnh, ch cha mt loi nhm chc trong phn t v c phn t khi l 144 vC. Cho 14,4 gam A tc dng va vi 100 ml dung dch NaOH 2M, thu c hn hp gm mt mui v mt ru vi c im s nguyn t cacbon trong hai gc hircacbon bng nhau. Xc nh cng thc cu to ca A. t 2. Hn hp kh X ( iu kin thng) gm mt ankan A (CmH2m+2) v m anken B (CnH2n). T khi hi ca anken so vi ankan l 2,625. a. Tm cng thc ca hai hircacbon. b. Vit cc phng trnh phn ng iu ch A t B, c dng thm cc cht v c v iu kin cn thit.

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Cu III 1. Mt hn hp A gm Na v Al. - Cho m gam A vo m lng d H 2O thu c 1,344 lt kh, dung dch B v phn khng t tan C. - Cho 2m gam A tc dng vi dung dch NaOH d thu c 20,832 lt kh. Cc phn ng u xy ra hon ton, cc th tch kh o iu kin tiu chun. a. Tnh khi lng tng kim loi trong m gam A. b. Cho 50 ml dung dch HCl vo dung dch B. Sau khi phn ng kt thc, thu c 0,78 gam kt ta. Xc nh nng mol/lt ca dung dch HCl dng. 2. Trn CuO vi oxit kim loi M (ha tr II khng i) theo t l s mol 1: 2 c hn hp A. Cho mt lung kh CO nng (d) i qua 1,2 gam A n phn ng hon to n, thu c cht rn B. ha tan ht B cn 50ml dung dch HNO 3 1M, thu c dung dch C ch cha mui ca 2 kim loi v V lt kh NO duy nht ( ktc). Xc nh kim loi M v tnh V. Cu IV 1. Cho 728 ml hn hp kh A gm 2 hirocacbon mch h i qua m t lng d dung dch Br2 th c 448 ml kh thot ra;ng Br 2 phn ng l 2 gam. Nu t chy hon ton l 1456 ml h hp A, sau hp th ton b sn phm chy vo 1000 gam dung d n ch Ca(OH)2 x% th thu c 7,5 gam kt ta. Lc tch kt ta, khi un nng phn nc lc th thu c thm ti a 4 gam kt ta na. Bit th tch cc kh o iu kin tiu chun, cc phn ng xy ra hon ton. Tm x v xc nh cng thc phn t ca 2 hirocacbon trong hn hp A. c 2. t chy hon ton 27,4 cm3 hn hp kh B gm CH 4, C3H8 v CO thu 51,4 cm 3 CO2. a. Tnh thnh phn % v th tch ca prpan trong hn hp B. b. Hi 1 lt hn hp B nng hay nh hn 1 lt N2? (Cc kh c o cng iu kin nhit , p sut) ----------------------------------------------------------------------------Cho: H = 1; C = 12; O = 16; Na = 23; Mg = 24; S = 32; Cl = 35,5; Ca = 40; Fe = 56 Cu = 64; Zn = 65; Br = 80; Ba = 137.
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