CV.

NCUEN 1AN 1kUNC

(1rung 1om Luyen 1h| Chot Lucng Coc V|NH V|EN|
EU KEN.
Fhan unz tranz zuonz
hop chat huu co pha| co nhom
0
0
H
0ac hchc co nhom
0
0
H
Andehyt
HC00H
Este hcoc Muc|
cuo HC00H
C|ux|t:
C|ucczc, Montczc
PHAN UNC
Coch :
k(CH0|
n
+ Ag
2
0 k(C00H|
n
+ Ag
Fhan unz tranz zuonz
EU KEN.
hop chat huu co pha| co nhom
0
0
H
2n
n
CH
3
CH0 + Ag
2
0
CH
3
C00H + Ag
2
V| du:
CH0
CH0 C00H
C00H
CH0
CH0
C00H
C00H
PHAN UNC
Coch :
k(CH0|
n
+ Ag
2
0 k(C00H|
n
+ Ag
Fhan unz tranz zuonz
EU KEN.
hop chat huu co pha| co nhom
0
0
H
2n
n
k(CH0|
n
+ AgN0
3
+ NH
3
+ H
2
0
k(C00NH
4
|
n
+ NH
4
N0
3
+ Ag 2n
Coch 2:
2n
2n
3n n
CH0
CH0
C00NH
C00NH
4
4
Coch :
k(CH0|
n
+ Ag
2
0 k(C00H|
n
+ Ag
Fhan unz tranz zuonz
2n
n
k(CH0|
n
+ AgN0
3
+ NH
3
+ H
2
0
k(C00NH
4
|
n
+ NH
4
N0
3
+ Ag 2n
Coch 2:
2n
2n
3n n
CH0
CH0
C00NH
C00NH
4
4
0an nho:
0
0
H
+ Ag
2
0 0
0
0H
AgN0
3
NH
3
,H
2
0
0
0
0-NH
4
+ NH
3
+
+
Ag
Ag
2
2
0
0 0
0
0H
AgN0
AgN0
3
3
NH
NH
3
3
,
,
H
H
2
2
0
0
0
0
0-NH
4
+ NH
+ NH
3 3
0
0
H
+
+
Ag
Ag
2
2
0
0 0
0
0H
AgN0
AgN0
3
3
NH
NH
3
3
,
,
H
H
2
2
0
0
0
0
0-NH
4
+ NH
+ NH
3 3
Fhan unz tranz zuonz
V| du 4: V|et coc pu
o. HCH0 + Ag
2
0
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
b. HC00H + Ag
2
0
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
c. 0|ucozo + 4z
2
0
V| du 4: V|et coc pu
o. HCH0 + Ag
2
0
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
0
0
H
H
+ Ag
2
0
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
0H
0
0
H0
0
0
H 0
0
0H
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
+Ag
2
0
+ Ag 4
2
C0
2
+H
2
0+4Ag 2
C0
2
+H
2
0
V| du 4: V|et coc pu
b. HC00H +Ag
2
0
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
0
0
0H
H
+Ag
2
0
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
0
0
H0
0
0
H 0
0
0H
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
+Ag
2
0
+ Ag 2
C0
2
+H
2
0+2Ag
0H
0H
C0
2
+H
2
0
0H
0H
V| du 4: V|et coc pu
c. C|ucc +Ag
2
0
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
0
0
H0
0
0
H 0
0
0H
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
+Ag
2
0
0H
0H
4
CH CH
2
0
0
CH CH
2
H
0H
4
0H
0H
0H
4
CH CH
2
Coch :
k(CH0|
n
+ Ag
2
0 k(C00H|
n
+ Ag
Fhan unz tranz zuonz
2n
n
k(CH0|
n
+ AgN0
3
+ NH
3
+ H
2
0
k(C00NH
4
|
n
+ NH
4
N0
3
+ Ag 2n
Coch 2:
2n
2n
3n n
CH0
CH0
C00NH
C00NH
4
4
0an nho 2:
n
Ag
n
hchc(pu|
=2n = 2.
5c
nhcm
-CH0
n
Ag
n
hchc(pu|
=2n = 2.
5c
nhcm
(-CH0|
Fhan unz tranz zuonz
V| du :
Chc 0, mc| A phon ung het
vc| ddAgN0
3
/NH
3
, thu ducc
0,4 mc| Ag. Hc| A cc moy
nhcm - CH0
1hoy:
n
Ag
n
A(pu|
=4
= 2.
2
Voy A cc 2 nhcm (-CH0|
0, mc| A
0, mc| A
0,4 mc| Ag
0,4 mc| Ag
n
Ag
n
hchc(pu|
=2n = 2.
5c
nhcm
(-CH0|
Fhan unz tranz zuonz
Con nhc:
- HCH0 ducc xem nhu ondehyt
2
2
ch
ch
u
u
c
c v| :
HCH0 cc C1C1:
0
0
H
H
mc|
mc| HCH0
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
4mc|
4mc| Ag
Fhan unz tranz zuonz
mc|
mc| X(C,H,0|
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
4 mc| Ag
8a| toan co 2 truonz hop
1H X: cc 2 nhcm (-CH0|
n
Ag
n
hchc(pu|
=2n = 2.
5c
nhcm
(-CH0|
0
0
H
H
1H2 X: H-CH0
mc|
mc| X(C,H,0|
ddAgN0
ddAgN0
3
3
NH
NH
3
3
(d
(d
u
u
|
|
4 mc|
4 mc| Ag
8a| toan co 2 truonz hop
1H X: cc 2 nhcm (-CH0|
1H2 X: H-CH0
Fhan unz tranz zuonz
V| du 3: (H 1HU 5AN 7|
Chot huu cc A chuo C,H,0 trcng dc
X0 = 37,2. Ach| chuo |co| chuc.
Kh| chc mc| A pu vc| ddAgN0
3
/NH
3
(du| to thu ducc 4 mc| Ag. 1|m A7
mc| A
mc| A
p
p
u
u
vc
vc

|
|
ddAgN0
ddAgN0
3 3
/NH
/NH
3 3
(
(
d
d
u
u
|
|
to
to
thu
thu
du
du
c
c

c
c
4 mc| Ag
4 mc| Ag
X0 = 37,2
X0 = 37,2
V| du 4: (HQC1P.HCM |
-Chot huu cc A chuo C,H,0. ct choy het
A con the t|ch cx| bong the t|ch C0
2
s|nh
ro c cung d|eu k|en. Hc| A thucc |co| chot
g|7 Loy 2,6 g A phon ung het ddAgN0
3
trcng NH
3
du thu ducc 25,2 g Ag. 1|m A7
-8|et:Kh| chc mc| A pu vc| ddAgN0
3
/NH
3
(du| to thu ducc 2 mc| Ag.
mc| A
mc| A
p
p
u
u
vc
vc

|
|
ddAgN0
ddAgN0
3 3
/NH
/NH
3 3
(
(
d
d
u
u
|
|
to
to
thu
thu
du
du
c
c

c
c
2 mc| Ag
2 mc| Ag
cx|
cx|
bo
bo

ng
ng
the
the

t
t
|
|
ch
ch
C0
C0
2 2
Hc
Hc

|
|
A
A
thuc
thuc

c
c
|co
|co

|
|
cho
cho

t
t
g
g
|
|
7
7
2,6 g A
2,6 g A
25,2 g Ag
25,2 g Ag
V| du 5: (H8K 1P.HCM 6|
Chc 3 hcp chot huu cc X,,Z (cc
khc| |ucng phon tu tong don|. Loy cung
sc mc| mc| chot chc toc dung het vc| dd
AgN0
3
/NH
3
th| d|eu thu ducc Ag vo 2
muc| A,8, |ucng Ag dc X s|nh ro gop 2
|on |ucng Ag dc s|nh ro hcoc Z. 8|et A
toc dung vc| No0H th| s|nh ro kh| vc cc
vo 8 toc dung vc| No0H hoy H
2
50
4
cung
d|eu toc thonh kh| vc cc. Xoc d|nh coc
C1C1 cuo X,,Z vo v|et coc P1PU.
3
3
hc
hc

p
p
cho
cho

t
t
h
h
u
u
u
u
cc
cc
X,,Z
X,,Z
dd
AgN0
3
/NH
3
Lo
Lo

y
y
cu
cu

ng
ng
sc
sc

mc|
mc|
No0H
No0H
th
th
|
|
s|nh
s|nh
ro
ro
kh
kh
|
|
vc
vc
cc
cc
No0H
No0H
hoy H
hoy H
2
2
50
50
4
4
thonh kh| vc cc
Ag dc X s|nh ro gop 2
|on |ucng Ag dc s|nh ro hcoc Z
CV. NCUEN 1AN 1kUNC
(1rung 1om Luyen 1h| Chot Lucng Coc V|NH V|EN|