Bi tp v ph

GV. Khnh Ton

Bi 1. H Y Thi Bnh 1999 a. : Tnh pH ca dung dch sau 250C: Dung dch NaCl 0,1M ; dung dch H2SO4 0,005M ; dung dch Ba(OH)2 0,05M b. Tnh pH ca dung dch NaOH, bit 1 lt dung dch c cha 4 gam NaOH c. Ho tan 0,56 lt kh HCl (ktc) vo H2O thu -c 250 ml dung dch. Tnh pH ca dung dch thu -c? d. H Th-ng Mi 2001 Ho tan m gam Ba vo n-c thu -c 1,5 lt dung dch X c pH = 13. Tnh m ? Bi 2: Cho 1,44 gam Mg vo 5 lt dung dch axit HCl c pH =2 a. Mg c tan ht trong dung dch axit hay khng ? b. Tnh tht tch kh H2 bay ra (ktc)? c. tnh nng mol/ lt ca dung dch sau phn ng (coi Vdd khng i)? Bi 3: a. (C Cng ng Tin Giang 2005). Trn 1 lt dung dch H2SO4 0,15M vi 2 lt dung dch KOH 0,165M thu -c dung dch E. Tnh pH ca dung dch E? b.Trn 50 ml dung dch HCl 0,12M vi 50 ml dung dch NaOH 0,1M. Tnh pH ca dung dch thu -c ? Bi 4: Cho dung dch A gm HCl v H2SO4. Trung ho 2 lt dd A cn 400ml dung dch NaOH 0,5M . C cn dung dch to thnh th thu -c 12,95 gam mui khan. a. Tnh nng mol/lt ca cc axit trong dung dch A? b. Tnh pH ca dung dch A? Bi 5: H Y H Ni 1999: in li ca axit axetic (CH3COOH ) trong dung dch CH3COOH 0,1M l 1%. Tnh pH ca dung dch axit ny Bi 6: thi H khi B 2002 Cho hai dung dch H2SO4 c pH = 1 v pH = 2. thm 100 ml dung dch KOH 0,1M vo 100 ml mi dung dch trn. Tnh nng mol / lt ca dung dch thu -c? Bi 7 : H Y D-c TP HCM 2000 Tnh in li ca axit focmic HCOOH. Nu dung dch HCOOH 0,46% (d = 1g/ml) ca axit c pH = 3 Bi 8: H S- Phm H Ni 1 2000 Tnh in li ca axit focmic HCOOH trong dung dch HCOOH 0,007M c pH = 3 Bi 9: Cho dung dch CH3COOH c pH = 4, bit in li = 1%. Xc nh nng mol /lt ca dung dch axit ny Bi 10: a. ( 19, H D-c 1997, C L-ng Thc- Thc Phm 2004) Cho dung dch HCl c pH = 3. Cn pha long dung dch axit ny (bng n-c) bao nhiu ln thu -c dung dch HCl c pH = 4. b. ( H S- Phm TP HCM 2000) Cho dung dch HCl c pH = 4. Hi phi thm mt l-ng n-c gp bao nhiu ln th tch dung dch ban u thu -c dung dch HCl c pH = 5. Bi 11: 8, H D-c 1998, Cho dung dch NaOH c pH = 12 (dung dch A). Cn pha long bao nhiu ln thu -c dung dch NaOH c pH = 11. Bi 12: H Kinh T Quc Dn 1999. Pha long 10 ml dung dch HCl vi n-c thnh 250 ml dung dch. Dung dch thu -c c pH = 3. hy tnh nng ca HCl tr-c khi pha long v pH ca dung dch . Bi 13: H Th-ng Mi 2000. Pha long 200 ml dung dch Ba(OH)2 vi 1,3 lt H2O thu -c dung dch c pH = 12. Tnh nng mol/l ca dung dch Ba(OH)2 ban u, bit rng Ba(OH)2 phn li hon ton Bi 14: H Thu li 1997. Dung dch Ba(OH)2 c pH = 13 (dd A), dung dch HCl c pH = 1 (dd B). em trn 2,75 lt dung dch A vi 2,25 lt dung dch B a. xc nh nng mol/l ca cc cht trong dung dch to thnh?

GV. Khnh Ton

Trng C CN Nam nh

b. tnh pH ca dung dch ny Bi 15: H Quc Gia H Ni 2000 a. (Ban B). Trn 250 ml dung dch hn hp gm HCl 0,08 M v H2SO4 0,01M vi 250 ml dung dch NaOH amol/lt thu -c 500ml dung dch c pH = 12. Tnh a b. (CPB). Trn 300 ml dung dch HCl 0,05 M vi 200 ml dung dch Ba(OH)2 amol/lt thu -c 500ml dung dch c pH = 12 Tnh a c. (Ban A, thi H khi B 2003). Trn 250 ml dung dch hn hp gm HCl 0,08 M v H2SO4 0,01M vi 250 ml dung dch Ba(OH)2 amol/lt thu -c m gam kt ta v 500ml dung dch c pH = 12 Tnh m v a Bi 16: Hc Vin Qun Y 2001 A l dung dch H2SO4 0,5M. B l dung dch NaOH 0,6M. Cn trn VA v VB theo t l no -c dung dch c pH = 1 v dung dch c pH = 13 (gi thit cc cht phn ly hon ton ). Bi 17: H S- Phm H Ni I 2001 Tnh th tch dung dch Ba(OH)2 0,025M cn cho vo 100ml dung dch gm HNO3 v HCl c pH = 1 pH ca dung dch thu -c bng 2. Bi 18: H kinh t TP HCM 2001 Trn 3 dung dch H2SO4 0,1M; HNO3 0,2 M; HCl 0,3M vi nhng th tich bng nhau -c dung dch A. Ly 300 ml dung dch A cho tc dng vi mt dung dch B gm NaOH 0,2M v KOH 0,29M. Tnh th tch dung dch B cn dng sau khi tc dng vi 300ml dung dch A -c dung dch c pH = 2. Bi 19: C 2004 Ho tan m gam BaO vo n-c -c 200ml dung dch A c pH = 13. Tnh m (gam). Bi 20 ; C SP Qung Ninh 2005 Cho m gam Ba vo 500 ml dung dch Ba(OH)2 0,04M th -c mt dung dch c pH = 13 . tnh m ( Coi th tch dung dch khng i ) Bi 21: thi H Khi A 2006 Nung 6,58 gam Cu(NO3)2 trong bnh kn, sau mt thi gian thu -c 4,96 gam cht rn v hn hp kh X. Hp th hon ton hn hp X vo n-c, -c 300 ml dung dch Y. vit ph-ng trnh phn ng xy ra v tnh pH ca dung dch Y. Bi 22: thi H khi A 2004 Cho 40 ml dung dch HCl 0,75M vo 160 ml dung dch cha ng thi Ba(OH) 2 0,08M v KOH 0,04M. Tnh pH ca dung dch thu -c. Cho [H+]. [OH-] = 10-14. Bi 23: C SP H Ni 2005 Cho dung dch NaOH c pH = 13 (dung dch A). a. Cn pha long dung dch A bao nhiu ln thu -c dung dch B c pH = 12? b. Cho 2,14 gam NH4Cl vo mt cc cha300 ml dung dch B. un si sau ngui ri thm mt t qu tm vo cc. Qu tm c mu g? ti sao? Bi 24: thi H khi B 2008 Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l (bit trong mi dung dch [H+][OH-] = 10-14) A. 0,15. B. 0,30. C. 0,03. D. 0,12.

GV. Khnh Ton

Trng C CN Nam nh