THI TUYN SINH I HC NM 2011 Mn thi : HA HC, khi B- M : 794

Cho bit nguyn t khi (theo vC) ca cc nguyn t : H = 1; He = 4; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52, Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Sr = 88; Ag=108; Sn = 119; Ba = 137. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1 : Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng ca nit trong X l 11,864%. C th iu ch c ti a bao nhiu gam hn hp ba kim loi t 14,16 gam X? A. 10,56 gam B. 7,68 gam C. 3,36 gam D. 6,72 gam %khi lng O: 11,864% x 48/14 =40,677% % khi lng cc kim loi trong mui: 100 40,677 -11,864 = 44,492% Khi lng KL iu ch c ti a: 14,16 x 44,492% = 6,72 gam Cu 2: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l: A. 4 B. 2 C. 5 D. 3 Cu 3: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l: A. 31 gam B. 32,36 gam C. 30 gam D. 31,45 gam gi s mol NaOH l a ch s axit l 7 nn s mol NaOH dng trung ha axit (s mol KOH)l: 200 x 7x 10-3/56 = 0,025mol s mol H2O to ra: 0,025 mol s mol NaOH p trieste: a 0,025 s mol glixerol thu c: (a-0,025)/3 LBTKL: m(cht bo) + m NaOH = m mui + mglixerol + m H2O 200 + 40a = 207,55 + 92 (a-0,025)/3 + 18 x 0,025 a= 0,775 m NaOH = 31 gam Cu 4: Thc hin cc th nghim vi hn hp gm Ag v Cu (hn hp X): (a) Cho X vo bnh cha mt lng d kh O3 ( iu kin thng) (b) Cho X vo mt lng d dung dch HNO3 (c) (c) Cho X vo mt lng d dung dch HCl (khng c mt O2) (d) Cho X vo mt lng d dung dch FeCl3 Th nghim m Cu b oxi ha cn Ag khng b oxi ha l: A. (a) B. (b) C. (d) D. (c) Cu 5: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tha mn cc tnh cht trn l: A. 4 B. 5 C. 6 D. 2 nNaOH :nEste = 2:1 l este to bi axit v phenol (v cho X l n chc) RCOOR` + 2NaOH RCOONa + R`ONa + H2 O 0,15 0,3 0,15 mEste =29,7 + 0,15.18 12 =20,4 gam KLPT ca este l 136 CTPT C8H8O2 Cc ng phn ca E: C-COO -C6H5; HCOO C6H4 CH 3 (c 3 ng phn o,p,m). Tng cng c 4 p. Cu 6: Cho phn ng : 3 C6H5-CH=CH2 + 10 KMnO4 3C6H5-COOK + 3K2CO3 + 10 MnO2 + KOH + 4H2O Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ha hc ca phn ng trn l: A. 27 B. 31 C. 24 D. 34 Cu 7: Cho dy cc oxi sau: SO2, NO2, NO, SO3, CrO3, P2O5, CO, N2O5, N2O. S oxit trong dy tc dng c vi H2O iu kin thng l:

A. 5 B. 6 C. 8 D. 7 Cu 8: luyn c 800 tn gang c hm lng st 95% , cn dng x tn qung manhetit cha 80% Fe3O4 (cn li l tp cht khng cha st). Bit rng lng st b hao ht trong qu trnh sn xut l 1%. Gi tr ca x l: A. 959,59 B. 1311,90 C. 1394,90 D. 1325,16 Khi lng Fe trong gang: 800 x 95% = 760 tn x = (760 x 232 /( 56x3)) x 100/80 x 100/99 = 1325,16 tn Cu 9: Triolein khng tc dng vi cht (hoc dung dch) no sau y? A. H2O (xc tc H2SO4 long, un nng) B. Cu(OH)2 ( iu kin thng) C. Dung dch NaOH (un nng) D. H2 (xc tc Ni, un nng) Cu 10: Cho cc phn ng: (a) Sn + HCl (long) t (b) FeS + H2SO4 (long) t (c) MnO2 + HCl (c) (d) Cu + H2SO4 (c) (e) Al + H2SO4 (long) (g) FeSO4 + KMnO4 + H2SO4 S phn ng m H+ ca axit ng vai tr oxi ha l: A. 3 B. 6 C. 2 D. 5 Cu 11: Choxt,t phn ng : s (1) X + O2 xt,t axit cacboxylic Y1 (2) X + H2 xt,t ancol Y2 (3) Y1 + Y2 Y3 + H2O Bit Y3 c cng thc phn t C6H10O2. Tn gi ca X l: A. anehit acrylic B. anehit propionic C. anehit metacrylic D. andehit axetic Cu 12: Thc hin cc th nghim sau: (a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c) (c) Sc kh Cl2 vo dung dch NaHCO3. (d) Sc kh CO2 vo dung dch Ca(OH)2 (d). (e) Sc kh SO2 vo dung dch KMnO4. (g) Cho dung dch KHSO4 vo dung dch NaHCO3. (h) Cho PbS vo dung dch HCl (long). (i) Cho Na2SO3 vo dung dch H2SO4 (d) , un nng. S th nghim sinh ra cht kh l: A. 2 B. 6 C. 5 D.4 Cu 13: Dung dch X gm 0,1 mol H+, z mol Al3+, t mol NO3- v 0,02 mol SO42-. Cho 120 ml dung dch Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn ng kt thc, thu c 3,732 gam kt a. Gi tr ca z, t ln lt l: A. 0,020 v 0,012 B. 0,020 v 0,120 C. 0,012 v 0,096 D. 0,120 v 0,020 p dng nh lut bo ton in tch ta c : 0,1 + 3z = t + 0,04 2+ 2nBa =0,012 < nSO4 = 0,02 nBaSO4 = 0,012 mol mBaSO4 = 2,796 gam mAl(OH)3 = 3,732 - 2,796 = 0,936 gam nAl(OH)3 = 0,012 mol. + 3+ nOH =0,168, nOH dng trung ha H = 0,1 nOH dng phn ng vi Al = 0,068>0,012.3=0,036 mol mol OH trong kt ta s mol OH trong Al(OH)4 =0,032. 3+ Vy nAl =nAl(OH)3 + nAl(OH)4 = 0,012 + (0,032 : 4) = 0,02 mol = z t=0,12 Cu 14: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l: A. Na, K, Ba B. Mg, Ca, Ba C. Na, K , Ca D. Li , Na, Mg Cu 15: Pht biu no sau y l sai? A. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh. B. nhit thng, tt c kim loi kim th u tc dng c vi nc. C. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v D. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn Cu 16: Pht biu no sau y l sai?
0

A. Tinh th nc , tinh th iot u thuc loi tinh th phn t. B. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht. C. Tt c cc tinh th phn t u kh nng chy v kh bay hi. D. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ha tr. Cu 17: hiro ha hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam, cn 1,12 lt H2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO 3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l: A. OHC-CH2-CHO v OHC-CHO B. H-CHO v OHC-CH2-CHO C. CH2=C(CH3)-CHO v OHC-CHO D. CH2=CH-CHO v OHC-CH2-CHO nH2 : n hai aneh it = 2: 1 Vy hai ane hit u cng hi ro theo t l 1: 2 loi B nAg/ n andehit = 0,08/0,025 = 3,2 loi A v andehit 2 chc c s mol (0,08- 0,025x2)/2 = 0,015 mol ; andehit n chc = 0,01 mol phng n D tha mn Cu 18: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l: A. 5,85 B. 3,39 C. 6,6 D. 7,3 t cng thc chung ca cc cht l CxH4 12x+4 =17 . 2 x = 2,5 Khi lng dung dch Ca(OH)2 tng bng mCO 2 + mH2O = 0,05.2,5.44 + 0,05.2.18=7,3 gam Cu 19: Nhit phn 4,385 gam hn hp X gm KClO3 v KMnO4, thu c O2 v m gam cht rn gm K2MnO4, MnO2 v KCl . Ton b lng O2 tc dng ht vi cacbon nng , thu c 0,896 lt hn hp kh Y (ktc) c t khi so vi H2 l 16. Thnh phn % theo khi lng ca KMnO4 trong X l: A. 62,76% B. 74,92% C. 72,06% D. 27,94% Cu 20: Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm CO, CO 2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ha tan ton b Y bng dung dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l: A. 18,42% B. 28,57% C. 14,28% D. 57,15% H2O + C CO + H2 x x x 2H2O + C CO 2 + 2H2 2y y 2y Theo phng trnh v theo gi thit ta c : 2x + 3y = 0,7 (1) CO +CuO CO 2 + Cu H2 + CuO H2 O + Cu p dng bo ton eletron ta c : 2nCO+ 2nH2=2nCu =3nNO nCO + nH2 = 0,6 mol 2x +2y = 0,6 (2) T cc phng trnh (1), (2) ta c : x = 0,2 ; y = 0,1 Vy %CO = 28,57% Cu 21: Ha tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch cht Y th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l: A. phenol, natri hiroxit, natri phenolat B. natri phenolat, axit clohiric, phenol C. phenylamoni clorua, axit clohiric, anilin D. anilin, axit clohiric, phenylamoni clorua Cu 22: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht ca N+5). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l: A. 1 B. 3 C. 2 D. 4

nCu = 0,02 ; nAg =0,005 Tng s mol e cho ti a = 0,02.2 +0,005.1 = 0,45 + nH = 0,09 mol; nNO3 = 0,06 (d) + 4H +NO3 + 3e NO + 2H2O 0,06 0,045 0,015 Ag, Cu phn ng ht. 2NO + O2 2NO2 0,015 0,0075 0,015 4NO2 + O2 + 2H2O 4HNO3 0,015 0,015 Nng mol HNO3 =0,015:0,15 = 0,1M. Vy pH= 1 Cu 23: Cho cn bng ha hc sau: 2SO2 (k) + O2 (k) 2SO3 (k) ; H < 0 Cho cc bin php : (1) tng nhit , (2) tng p sut chung ca h phn ng, (3) h nhit , (4) dng thm cht xc tc V2O5, (5) gim nng SO3, (6) gim p sut chung ca h phn ng. Nhng bin php no lm cn bng trn chuyn dch theo chiu thun? A. (2), (3), (4), (6) B. (1), (2), (4) C. (1), (2), (4), (5) D. (2), (3), (5) Cu 24: Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y l A. 4 : 3 B. 3 : 4 C. 7 : 4 D. 3 : 2 3+ S mol Al = 0,4x +0,8y; nSO4 = 1,2 y mol 2S mol BaSO4 =0,144 mol = nSO4 =1,2y y= 0,12 nOH =0,612 mol; nAl(OH)3 = 0,108 mol nOH trong kt ta =0,324 < 0,612 s mol OH trong Al(OH)4 =0,288 mol 0,4x +0,8y=0,108 + (0,288:4) x= 0,21 x:y=7:4 Cu 25: Hn hp X gm O2 v O3 c t khi so vi H2 l 22 . Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t chy hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh khi o cng iu kin nhit , p sut). T l V1 : V2 l: A. 3 : 5 B. 5 : 3 C. 2 : 1 D. 1 : 2 t CTPT trung bnh ca 2 amin l CnH2n +3N n =4/3 Quy i O3, O2 thnh O , m(O3, O2) =mO 2CnH2n +3N 2nCO2 + (2n+3)H2O Mol : 1 n (2n+3)/2 nO =2n+(2n+3)/2 =5,5 mol m(O3, O2) =mO=88gam n(O3, O2)= 88:44=2 Vy V1 :V2 = 1:2 Cu 26: Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c 0,784 lt CO 2 (ktc). Tn ca Z l: A. anehit propionic B. anehit butiric C. anehit axetic D. anehit acrylic V cho HCl vo dung dch sau phn ng trng gng c CO 2 chng t trong dung dch c(NH4)2 CO 3 . Vy trong hn hp anehit ban u c HCHO HCHO 4Ag + (NH4)2 CO 3 CO 2 0,035 0,14 0,035 RCHO 2Ag 0,015 0,03
T s phn ng v gi thit ta suy ra : (R+29).0,015 + 0,035.30 = 1,89

R = 27 (C2H3

Cu 27: Cho cc pht biu sau: (a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO 2 bng s mol H2O th X l anken. (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr. (d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau (e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh (g) Hp cht C9H14BrCl c vng benzen trong phn t S pht biu ng l A. 4 B. 3 C. 2 D. 5 Cu 28: Ancol v amin no sau y cng bc? A. (C6H5)2NH v C6H5CH2OH B. C6H5NHCH3 v C6H5CH(OH)CH3 C. (CH3)3COH v (CH3)3CNH2 D. (CH3)2CHOH v (CH3)2CHNH2 37 35 Cu 29: Trong t nhin clo c hai ng v bn: 17 Cl chim 24,23% tng s nguyn t, cn li l 17 Cl . Thnh phn % theo khi lng ca 17 Cl trong HClO4 l: A. 8,92% B. 8,43% C. 8,56%
35
37

D. 8,79%

% Cl = 100-24,23= 75,77% KLNT trung bnh ca Cl gn bng s khi TB = 17 0.7577.35+0,2424.37= 35,4846 Gi s c 1mol HClO4 n 17 =0,2423 mol Cl 37 % v khi lng ca 17 trong HClO4 = 0, 2423.37/ (1 + 35, 4846 + 16.4) 100% = 8, 92% Cl Cu 30: Dy gm cc cht (hoc dung dch) u phn ng c vi dung dch FeCl2 l: A. Bt Mg, dung dch NaNO3, dung dch HCL B. Bt Mg, dung dch BaCl2, dung dch HNO3 C. Kh Cl2, dung dch Na2CO3, dung dch HCL D. Kh Cl2, dung dch Na2S, dung dch HNO3 Cu 31: Chia hn hp gm hai n chc X v Y (phn t khi ca X nh hn ca Y) l ng ng k tip thnh hai phn bng nhau: - t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O. - un nng phn 2 vi H2SO4 c 1400C to thnh 1,25 gam hn hp ba ete. Ha hi hon ton hn hp ba ete trn, thu c th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut). Hiu sut ca phn ng to ete ca X, Y ln lt l: A. 30% v 30% B. 25% v 35% C. 40% v 20% D. 20% v 40% P1 :nCO 2 = 0,25 ; nH2O = 0,35 Hai ancol ban u l no, n chc. nCnH2 n+1OH = 0,1 mol S C TB l 2,5 Hai ancol l C2H5OH v C3H7OH, mi cht c 0,05 mol. P2: nCmH2m+2O (ete) = 0,015 mol =nH2O, n2ancol p = 0,03 n2ancol d = 0,07 m2ancol d = tng m2ancol m2ancol p ete ha = 0,05.46+0,05.60- mete - mH2O =3,78 gam
37

a b 4 6 + 6 0 = 3,7 8 a + b = 0,0 7

a = 0,0 3 b = 0,0 4

Hiu sut este ha ca X v Y l 40% v 20% Cu 32: Thc hin cc phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr 2O3 (trong iu kin khng c O2), sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl (long, nng), sau khi cc phn ng xy ra hon ton, thu c 2,016 lt H 2 (ktc). Cn nu cho ton b X vo mt lng d dung dch NaOH (c, nng), sau khi phn ng kt thc th s mol NaOH phn ng l: A. 0,06 mol B. 0,14 mol C. 0,08 mol D. 0,16 mol Gi s phn ng xy ra va th nCr = 0,06 = nH2 gii phng, nhng nH2 gii phng =0,09

suy ra nhm d. p dng bo ton electron: Khi nhn phn ng vi Cr2O3 : 3.nAl phn ng = 2.3nC r2O3 nAl p = 0,06 mol Khi nhm d v Al2O3 phn ng vi HCl : 3nAl d + 2nCr = 2nH2 nAl d = 0,02 mol Vy tng s mol Al l 0,08 mol. Sau tt c cc phn ng Al chuyn thnh NaAlO2 nn suy ra nNaOH = 0,08 mol. Cu 33: Hp th hon ton 2,24 lt CO2 (ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH x mol/lt , sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl2 (d), thu c 11,82 gam kt ta. Gi tr ca x l: A. 1,0 B 1,4 . C. 1,2 D. 1,6 2 Nhn thy nCO2 + nCO 3 ban u = nHCO 3 + nBaC O3 nHC O 3 = 0,06 mol 2CO 2 +2OH CO3 ; CO2 + OH HCO3 mol: 0,04 0,08 0,06 0,06 0,06 Vy nOH = 0,14 mol. Vy x = 0,14:0,1 = 1,4M Cu 34: Pht biu no sau y l ng? A. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ha hc, ch cn dng thuc th l nc brom. B. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip thc phm, m phm. C. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi thm ca chui chn. D. Trong phn ng este ha gia CH3COOH vi CH3OH, H2O to nn t -OH trong nhm -COOH ca axit v H trong nhm -OH ca ancol. Cu 35: Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 2 B. 1 C. 4 D. 3 Cu 36: Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit (c) Trong dung dch, glucoz v saccaroz u ha tan Cu(OH)2, to phc mu xanh lam. (d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol. S pht biu ng l: A. 6 B. 3 C. 4 D. 5 Cu 37: Cho ba dung dch c cng nng mol : (1) H 2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l: A. (3), (1), (2) B. (1), (2), (3) C. (2) , (3) , (1) D. (2), (1), (3) Cu 38: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l: A. 25% B. 27,92% C. 72,08% D. 75% X + O2 3 H2O s mol X = 1/3 s mol H2O = 0,04 mol gi s mol vinyl axetat l a; tng s mol metyl axetat v etyl fomat ( 2 cht ng phn) l b
-

a + b = 0,0 4 a = 0,01 a b 8 6 + 7 4 = 3,0 8

Cu 39: Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong hn hp M l: A. 20% B. 50% C. 40% D. 30% S C trung bnh = 3x:x = 3 Ankin l C3H4 S H trung bnh = 1,8x.2: x = 3,6 Anehit c s H nh hn 3,6 v v sH trong anehit phi chn nn suy ra anehit co 2H. Vy anehit c CTPT l C3H2O (CH C CHO) p dng s dng cho ta c Cu 40: Cho dy cc cht: SiO2, Cr(OH)3, CrO3, Zn(OH)2, NaHCO3, Al2O3. S cht trong dy tc dng c vi dung dch NaOH( c, nng) l A. 6 B. 3 C. 5 D. 4 PHN RING (10 cu) Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l: A. 8 B. 9 C. 5 D. 7 Ba ng phn xicloankan v 5 ng phn anken Cu 42: X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt H 2 (ktc). Gi tr ln nht ca V l A. 22,4 B. 5,6 C. 11,2 D. 13,44 p dng nh lut bo ton khi lng ta c : mX = mY nX.MX = nY.MY nX : nY = MY:MX=2:1 Vy s mol H2 phn ng = 2-1 =1 mol - CHO + H2 - CH2OH +N a H2 1 mol 0,5 mol Cu 43: Pht biu no sau y l sai? A. Nhm l kim loi dn in tt hn vng. B. Ch (Pb) c ng dng ch to thit b ngn cn tia phng x. C. Trong y hc, ZnO c dng lm thuc gim au dy thn kinh, cha bnh eczema, bnh nga D. Thic c th dng ph ln b mt ca st chng g. Cu 44: Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ha thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l: A. 2,67 B. 4,45 C. 5,34 D. 3,56 T gi thit suy ra mX =100.14/15,73=89 suy ra X l H2NCH 2COOC H3 H2NCH2COOCH 3 CH 3OH HCHO 4Ag Suy ra nH2NCH 2COOC H3= nHCHO = nAg =0,03 m =0,03.89=2,67 gam Cu 45: Cho dy cc cht sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3, K2SO4. C bao nhiu cht trong dy va tc dng c vi dung dch HCl, va tc dng c vi dung dch NaOH? A. 2 B. 3 C. 4 D. 5 Cu 46: Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l A.32,50 B. 20,80 C. 29,25 D. 48,75 3+ 2+ 2+ 2Fe + Zn 2Fe + Zn

0,24 0,12 0,24 0,12 2+ 2+ Fe + Zn Fe + Zn x x x x V trc v sau phn ng tng khi lng khng i nn sau phn ng khi lng dung dch tng 9,6 gam th khi lng kim loi gim 9,6 gam = mZn phn ng - mFe sinh ra = (0,12+x)65 56x = 9,6 x= 0,2 Vy mZn =(0,2 + 0,12)65 = 20,8 gam Cu 47: Nhit phn mt lng AgNO3 c cht rn X v hn hp kh Y. Dn ton b Y vo mt lng d H2O, thu c dung dch Z. Cho ton b X vo Z, X ch tan mt phn v thot ra kh NO (sn phm kh duy nht). Bit cc phn ng xy ra hon ton. Phn trm khi lng ca X phn ng l A.25% B. 60% C. 70% D. 75% 2AgNO3 2Ag + 2NO2 + O2 x x x 0,5x 4NO2 + O2 + 2H2O 4HNO3 x 0,025x x 3Ag + 4HNO3 3AgNO3 + NO + 2H2O 0,75x x Phn trm khi lng Ag phn ng l 0,75x:x = 75% Cu 48: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C 4H10, C4H8, C4H6, H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l A. 0,48 mol B. 0,36 mol C. 0,60 mol D. 0,24 mol mC4H10 = mX nC 4H10.MC4H10 = nX.MX nC 4H10 : nX = MX:MC4H10=0,4:1 nC4H10=0,24. S mol kh tng l 0,6 0,24 = 0,36. Suy ra s mol Br2 tham gia phn ng = s mol kh tng ln = 0,36 mol ( c hnh dung l ch c phn ng t C4H10 thnh C4H8 +H2 d) Cu 49: Trong qu gc chn rt giu hm lng: A.ete ca vitamin A B. este ca vitamin A C. -caroten D. vitamin A Cu 50: Cho cc pht biu sau: (a) Anehit va c tnh oxi ha va c tnh kh (b) Phenol tham gia phn ng th brom kh hn benzen (c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt (d) Dung dch axit axetic tc dng c vi Cu(OH)2 (e) Dung dch phenol trong nc lm qu tm ha (f) Trong cng nghip, axeton c sn xut t cumen S pht biu ng l A. 5 B. 4 C. 3 D. 2 B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51:Pht biu khng ng l A.Etylamin tc dng vi axit nitr nhit thng to ra etanol B.Protein l nhng polopeptit cao phn t c phn t khi t vi chc nghn n vi chc triu C.Metylamin tan trong nc cho dung dch c mi trng baz D.ipeptit glyxylalanin (mch h) c 2 lin kt peptit Cu 52: Thc hin cc th nghim sau: (a) Nhit phn AgNO3

(b) Nung FeS2 trong khng kh

(c) Nhit phn KNO3 (d) Cho dung dch CuSO4 vo dung dch NH3 (d) (e) Cho Fe vo dung dch CuSO4 (g) Cho Zn vo dung dch FeCl3 (d) (h) Nung Ag2S trong khng kh (i) Cho Ba vo dung dch CuSO4 (d) S th nghim thu c kim loi sau khi cc phn ng kt thc l A. 3 B. 5 C. 2 D. 4 Cu 53: Ha tan 25 gam hn hp X gm FeSO4 v Fe2(SO4)3 vo nc, thu c 150 ml dung dch Y. Thm H2SO4 (d) vo 20ml dung dch Y ri chun ton b dung dch ny bng dung dch KMnO 4 0,1M th dng ht 30 ml dung dch chun. Phn trm khi lng FeSO4 trong hn hp X l A.13,68% B. 68,4% C. 9,12% D. 31,6% s mol KMnO4: 0,03 x 0,1 = 0,003 mol Mn+7 + 5 e Mn+2 Fe+2 -1e Fe+3
0,003 0,015 mol 0,015 0,015

s mol FeSO4 trong 150 ml dd Y: 0,015 x 150/20 = 0,1125 mol % m FeSO4 = 0,1125 x 152/25 x100% = 68,4% Cu 54: Cho s phn ng:
+HCN +H2O

(1)CH3CHO (2)C2H5Br
+ Mg ete

X1 Y1

H+ , to + CO2

X2 Y2 Y3
+ HCl

Cc cht hu c X1, X2, Y1, Y2, Y3 l cc sn phm chnh. Hai cht X2, Y3 ln lt l A. axit 3-hirxipropanoic v ancol propylic. B. axit axetic v ancol propylic. C. axit 2-hirxipropanoic v axit propanoic. D. axit axetic v axit propanoic. Cu 55: Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh hn ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H2O. Mt khc, nu a mol X tc dng vi lng d dung dch NaHCO3, th thu c 1,6a mol CO2. Thnh phn % theo khi lng ca Y trong X l A. 46,67% B. 40,00% C. 25,41% D. 74,59% s nguyn t H trong axit l s chn m a mol X khi chy to a mol H 2O chng t trong cc cht Y, Z mi phn t ch c 2 nguyn t H: Y l HCOOH, Z l: HOOC COOH nZ = 1,6a a = 0,6a; nY = 0,4a %mY = (46 x 0,4a)/ ( 46 x 0,4a + 90 x 0,6a) = 25,41% Cu 56: Cho 5,6 gam CO v 5,4 gam H2O vo mt bnh kn dung tch khng i 10 lt. Nung nng bnh mt thi gian 8300C h t n trng thi cn bng: CO (k) + H2O (k) CO2 (k) + H2 (k) (hng s cn bng Kc = 1). Nng cn bng ca CO, H2O ln lt l A. 0,018M v 0,008 M B. 0,012M v 0,024M C. 0,08M v 0,18M D. 0,008M v 0,018M CO (k) + H2O (k) CO2 (k) + H2 (k) ban u 0,2 0,3 p x x cn bng 0,2 x 0,3 x x x [ CO2 ][ H 2 ] = x.x Kc = =1 [ CO][ H 2 O ] (0,2 x).(0,3 x) x = 0,12 nCO = 0,08 CM CO = 0,08/10 = 0,008M n H2O = 0,18 CM H2O = 0,18/10 = 0,018M Cu 57: Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l A.0,090 mol B. 0,095 mol C. 0,12 mol D. 0,06 mol Saccarozo + H2O glucozo + fructozo

0,02 . 75% 0,015 0,015 Mantozo + H2O 2 glucozo 0,01 . 75% 0,015 Glucozo 2 Ag; fructozo 2 Ag; Mantozo 2 Ag 0,03 0,06 0,015 0,03 0,0025 0,005 Cu 58: Cho m gam bt Cu vo 400 ml dung dch AgNO3 0,2M, sau mt thi gian phn ng thu c 7,76 gam hn hp cht rn X v dung dch Y. Lc tch X, ri thm 5,85 gam bt Zn vo Y, sau khi phn ng xy ra hon ton thu c 10,53 gam cht rn Z. Gi tr ca m l A.3,84 B. 6,40 C. 5,12 D. 5,76 Cu 59: Trong qu trnh hot ng ca pin in ha Zn Cu th A. khi lng ca in cc Zn tng B. nng ca ion Cu2+ trong dung dch tng C. nng ca ion Zn2+ trong dung dch tng D. khi lng ca in cc Cu gim Cu 60: Cho cc pht biu sau: (a) C th dng nc brom phn bit glucoz v fructoz (b) Trong mi trng axit, glucoz v fructoz c th chuyn ha ln nhau (c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO3 trong NH3 (d) Trong dung dch, glucoz v fructoz u ha tan Cu(OH)2 nhit thng cho dung dch mu xanh lam
(e)Trong dung dch, fructoz tn ti ch yu dng mch h (f) Trong dung dch, glucoz tn ti ch yu dng mch vng 6 cnh (dng v )

A.5

S pht biu ng l B. 3

C. 2

D. 4