CC DNG BI TP TRC NGHIM ESTE-LIPIT I. NG PHN, DANH PHP, CNG THC TNG QUT. Cu 1: Nhn nh no sau y khng ng?

A. Tn este RCOOR gm: tn gc hirocacbon R + tn anion gc axit (ui at). B. Khi thay nguyn t H nhm COOH ca axit cacboxylic bng gc hirocacbon th c este. C. Phn ng thu phn este trong mi trng kim l phn ng 1 chiu v gi l phn ng x phng ho. D. Este c nhit si thp hn so vi axit v ancol c cng s nguyn t C v este c khi lng phn t nh hn. Cu 2: Trong s mi lin h gia hirocacbon v dn xut cha oxi, ankan c t trung tm v A. ankan tng i tr v mt ho hc. B. ankan c th tch H2 to thnh cc hirocacbon khng no v cng O2 sinh ra dn xut cha oxi. C. ngnh cng nghip ho cht ly du m lm nn tng. T ankan trong du m ngi ta sn xut ra cc hirocacbon khc v cc loi dn xut ca hirocacbon. D. l do khc. Cu 3:Cng thc tng qut ca este to bi axit n chc no mch h v ancol n chc no mch h c dng. A. CnH2n+2O2 ( n 2) B. CnH2nO2 (n 2) C. CnH2nO2 ( n 3) D. CnH2n-2O2 ( n 4) Cu 4: Cho glixerol phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste ti a c to ra l A. 3. B. 4. C. 5. D. 6. Cu 5: Khi un nng glixerol vi hn hp 3 axit bo C17H35COOH, C17H33COOH, C17H31COOH thu c cht bo khc nhau. S CTCT c th c l bao nhiu? A.21 B.18 C.16 D.19 Cu 6:S ng phn este ng vi cng thc phn t C4H8O2 l: A.5 B.2 C.4 D.6 Cu 7: S ng phn este ng vi cng thc phn t C5H10O2 l: A.10 B.9 C.7 D.5 Cu 8. Hy cho bit c bao nhiu cht hu c n chc c cng thc phn t l C3H6O2? A. 4 B. 2 C. 3 D. 5 Cu 9: Glixerol C3H5(OH)3 c kh nng to ra 3 ln este (trieste). Nu un nng glixerol vi hn hp axit R'COOH v R' COOH (c H2SO4 c xc tc) th thu c ti a l bao nhiu este? A. 2 B. 6 C. 4 D. 8 Cu 10. t chy hon ton mt lng hn hp hai este cho sn phm chy qua bnh ng P 2O5 d thy khi lng bnh tng thm 6,21g, sau cho qua dd Ca(OH)2 d thu c 34,5g kt ta. Cc este ni trn thuc loi: A. No n chc B. Khng no n chc C. No a chc D. Khng no a chc. II. TNH CHT. * Tnh cht. Cu 1:Pht biu ng l: A. Phn ng gia axit v ancol c mt H2SO4 c l phn ng mt chiu. B. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ancol. C. Khi thu phn cht bo lun thu c C2H4(OH)2. D. Phn ng thu phn este trong mi trng axit l phn ng thun nghch Cu 2: Nhn nh khng ng l A. CH3CH2COOCH = CH2 cng dy ng ng vi CH2 = CHCOOCH3. B. CH3CH2COOCH = CH2 tc dng vi dung dch NaOH thu c anehit v mui. C. CH3CH2COOCH = CH2 tc dng vi dung dch Br2. D. CH3CH2COOCH = CH2 c th trng hp to polime. Cu 3: Chn sn phm chnh cho phn ng sau: C2H5COOCH3 L iA4 A + B lH A, B l: A. C2H5OH, CH3COOH B. C3H7OH, CH3OH C. C3H7OH, HCOOH D. C2H5OH, CH3COOH Cu 4. Axit Fomic khng tc dng vi cc cht no trong cc cht sau A.CH3OH B.NaCl C.C6H5NH2 D.Cu(OH)2 (xt OH-, to) Cu 5: Cho cc cht: etyl axetat, etanol, axit acrylic, phenol, phenylamoni clorua, phenyl axetat. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 3. B. 4. C. 5. D. 6. Cu 6: Cho cc cht: axit propionic (X); axit axetic (Y); ancol etylic (Z) v metyl axetat (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l A. T, Z, Y, X. B. Z, T, Y, X. C. T, X, Y, Z. D. Y, T, X, Z. Cu 7: Cho tt c cc ng phn n chc, mch h, c cng thc phn t C 2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO 3. S phn ng xy ra l A. 2. B. 3. C. 4. D. 5.

Cu 8: C2H4O2 c 3 ng phn mch h. Cho cc ng phn tc dng vi: NaOH, Na, AgNO 3/NH3 th s phng trnh phn ng xy ra l A. 3. B. 4. C. 5. D. 6. Cu 9:C4H6O2 c bao nhiu ng phn mch h phn ng c vi dung dch NaOH? A. 5 ng phn. B. 6 ng phn. C. 7 ng phn. D. 8 ng phn. Cu 10: S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u tc dng vi dung dch NaOH A. 3 B. 4 C. 5 D. 6 Cu 11: Hp cht X khng no mch h c cng thc phn t C5H8O2 khi tham gia phn ng x phng ha thu c 1 anehit v 1 mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X ( khng k ng phn cis,tran )? A. 2 B. 3 C. 4 D. 5 Cu 12: Este A n chc, mch h, c t khi hi so vi metan bng 6,25 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi A? A. 3. B. 4. C. 2. D. 5. Cu 13: Thy phn 1 mol este cho 2 mui v nc . CTCT ca este c dng: (R l gc hirocacbon trong cacbon mang ha tr l cacbon no) A. RCOOR B. RCOOCH=CHR C. RCOOC6H5 D. C6H5COOR Cu 14. Este X c cng thc phn t l C5H10O2. un nng X vi NaOH thu c mui Y v ancol Z trong MY < MZ. Hy cho bit X c bao nhiu cng thc cu to? A. 6 B. 7 C. 4 D. 5 Cu 15. Trong s cc este mch h c cng thc phn t C 4H6O2 th c my este khi un nng lu vi dung dch AgNO 3/ NH3 cho Ag kt ta? A. 2 B. 3 C. 4 D. 5 Cu 16: Sn phm thu c khi thu phn vinylaxetat trong dd kim l: A. Mt mui v mt ancol B. Mt mui v mt anehit C. Mt axit cacboxylic v mt ancol D. Mt axit cacboxylic v mt xeton Cu 17: Khi trng hp CH2=CH-COOCH3 thu c A. polistiren. B. polivinyl axetat. C. Poli metyl acrylat . D. polietilen. Cu 18: iu ch thy tinh hu c, ngi ta trng hp t : A. CH2= CH-COOCH3 B.CH2= CH-COOH C. CH2= C(CH3)-COOCH3 D. Tt c u sai Cu 19: Cho axit Salixylic (X) (axit o-hiroxibenzoic) phn ng vi metanol c H2SO4 c xc tc thu c metyl Salixylat (Y) dng lm thuc gim au. Cho Y phn ng vi dung dch NaOH d thu c hn hp sn phm trong c mui Z. Cng thc cu to ca Z l A. o NaOC6H4COOCH3. B. o HOC6H4COONa. C. o NaOOCC6H4COONa D. o NaOC6H4COONa. * Nhn bit. Cu 1: C cc cht mt nhn ring bit sau: etyl axetat, fomanehit, axit axetic v etanol. phn bit chng dng b thuc th no sau y? A. AgNO3/NH3, dung dch Br2, NaOH. B. Qu tm, AgNO3/NH3, Na. C. Qu tm, AgNO3/NH3, NaOH. D. Phenolphtalein, AgNO3/NH3, NaOH. Cu 2: C 4 l mt nhn ng cc dung dch ring bit sau: CH 3COOH, HCOOH, C2H5OH, HOCH2CHO, CH2 = CHCOOH. B thuc th theo th t c th dng phn bit tng cht trn l A. phenolphtalein, AgNO3/NH3, dung dch Br2. B. qi tm, dung dch Br2, AgNO3/NH3. C. qi tm, dung dch Br2, Na. D. phenolphtalein, dung dch Br2, Na. Cu 3: : phn bit cc este ring bit: vinyl axetat, vinyl fomiat, metyl acrylat, ta c th tin hnh theo trnh t no sau y? A. Dng dung dch NaOH, un nh, dng dung dch brom, dng dung dch H2SO4 long. B. Dng dung dch NaOH, dng dung dch AgNO3 trong NH3 , dng dung dch brom. C. Dng dung dch AgNO3 trong NH3, dng dung dch brom, dng dung dch H2SO4 long. D. Tt c u sai * iu ch. Cu 1: i vi phn ng este ho, yu t no sau y nh hng n vn tc phn ng? (1) Nhit (2) Bn cht cc cht phn ng (3) Nng cc cht phn ng (4) Cht xc tc A. (1), (2), (3) B. (2), (3), (4) C. (1) (3) (4) D. (1) (2) (3) (4) Cu 2:Trong phn ng este ho gia ancol v mt axit hu c th cn bng s chuyn dch theo chiu to ra este khi ta: A. Cho ancol d hay axit hu c d. B. Gim nng ancol hay axit hu c. C. Dng cht ht nc hay tch nc. Chng ct ngay tch este. D. C 2 bin php A, C Cu 3:Cho phn ng este ha : RCOOH + ROH R-COO-R + H2O . phn ng chuyn di u tin theo chiu thun, cn dng cc gii php sau : A.Tng nng ca axit hoc ancol. B.Dng H2SO4 c xc tc v ht nc. C.Chng ct tch este ra khi hn hp phn ng . D.C a, b, c u dng. Cu 4: Nhng bin php phn ng thu phn este c hiu sut cao v nhanh hn l

A. Tng nhit ; tng nng ancol. B. Dng OH- (xc tc); tng nhit . + C. Dng H (xc tc); tng nng ancol. D. Dng H+ (xc tc); tng nhit . Cu 5: Bin php dng nng cao hiu sut phn ng este ho l A. Thc hin trong mi trng kim. B. Dng H2SO4 c lm xc tc. C. Ly d 1 trong 2 cht u hoc lm gim nng cc sn phm ng thi dng H2SO4 c xc tc. D. Thc hin trong mi trng axit ng thi h thp nhit . * Xc nh cht trong s .
+ Na OH + NaOH Na OH 2 H Cu 1: Cho s sau: X(C 4H 8O 2) Y Z T 0 C 2 6 Ca O,t O ,xt

Cng thc cu to thu gn ca X l A. CH3COOC2H5. B. C2H5COOCH(CH3)2.

+ HCN + 0 H3 O ,t 0 H2 SO4 c, t

C. CH3CH2CH2COOH
CH3 OH / H2 SO4

D. HCOOCH2CH2CH3.

Cu 2: Cho s sau: CH3 COCH3 X Y 4 H6 O2 ) Z(C T Cng thc cu to ca T l A. CH3CH2COOCH3. B. CH3CH(OH)COOCH3. C. CH2 = C(CH3)COOCH3. D. CH2 = CHCOOCH3.
C2H5OH + HCN Cu 3: Cho s sau: CH3CHO X Y c, Z(C 3H 4O2) / H2SO4 T H3O ,t H2SO4 t Cng thc cu to ca T l A. CH3CH2COOC2H5. B. C2H5COOCH3. C. CH2 = CHCOOC2H5. D. C2H5COOCH = CH2. + 0 0

+ H2O + H2 + O2 1500 +X Cu 4: Cho dy chuyn ho: CH4 X Y Z T M Cng thc cu to ca M l A. CH3COOCH3. B. CH2 = CHCOOCH3. C. CH3COOCH = CH2. D. CH3COOC2H5.
C6H5OH KCN Cu 5: Cho s sau (cc ch ci ch sn phm hu c): CH3Cl X Y Z T M + N H3O ,t P2O5 NaOHd Cng thc cu to ca M v N ln lt l A. CH3COONa v C6H5ONa. B. CH3COONa v C6H5CH2OH. C. CH3OH v C6H5COONa. D. CH3COONa v C6H5COONa. + 0

+ H2O / Hg 1500 Cu 6: Cho s sau: CH4 X Y Z T M CH4 + NaOH Cng thc cu to ca Z l A. C2H5OH. B. CH3COOH. C. CH3COOC2H5. D. C A, B, C u ng. Cu 7: Cho s sau: C2H2 C2H4Cl 2 X C2H4O2 CH2 = CHOOCCH3 Cng thc cu to ca X l A. C2H4(OH)2. B. C2H5OH. C. CH3CHO. D. HOCH2CHO. Cu 8: Cho s sau:

2+

C2 H5OH X NaOH T

Z F

CH 4 Poli(metyl metacrylat)

axit metacrylic

Cng thc cu to ca X l A. CH2 = C(CH3) COOC2H5. B. CH2 = CHOOCC2H5. C. CH2 = C(CH3)COOCH3. D. CH2 = CHCOOC2H5 III. TNH TON. * Tnh ton. Cu 1: X phng ho hon ton 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam. Cu 2: Cho lng CO2 thu c khi t chy hon ton 0,1 mol hn hp gm hai este etyl fomiat v metyl axetat qua 1 lt dung dch NaOH 0,4M thu c m gam mui. Gi tr ca m l A. 25,2. B. 42,4. C. 27,4. D. 33,6. Cu 3: Cho hn hp X gm 2 este c cng thc phn t C4H8O2 v C3H6O2 tc dng vi NaOH d thu c 6,14 gam hn hp hai mui v 3,68 gam ru Y duy nht c t khi hi so vi oxi l 1,4375. Khi lng mi este trong X ln lt l A. 4,4 gam v 2,22 gam. B. 3,33 gam v 6,6 gam. C. 4,44 gam v 8,8 gam. D. 5,6 gam v 11,2 gam. Cu 4: X phng ho hon ton 22,2 gam hn hp gm 2 este HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l A. 400 ml B. 300 ml C. 150 ml D. 200 ml Cu 5: Chia hn hp M gm x mol ancol etylic v y mol axit axetic (x > y) thnh hai phn bng nhau. - Phn 1: Cho tc dng vi Na d thu c 5,6 lt H2 ( ktc). - Phn 2: un nng vi H2SO4 c ti phn ng hon ton c 8,8 gam este. Gi tr ca x v y l A. x = 0,4; y = 0,1. B. x = 0,8; y = 0,2. C. x = 0,3; y = 0,2. D. x = 0,5; y = 0,4.

Cu 6: Cho 2,72 gam CH3COOC6H5 vo 500 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng thu c s gam cht rn l A. 1,64g B. 3,96g C. 2,84g D. 4,36g Cu 7: Cho 4,48 gam hn hp gm CH3COOC2H5 v CH3COOC6H5 (c t l mol l 1:1) tc dng vi 800 ml dung dch NaOH 0,1 M thu c dung dch X. C cn dung dch X th khi lng cht rn thu c l A. 5,6 gam B. 3,28 gam C. 6,4 gam D. 4,88 gam Cu 8: Khi thc hin phn ng este ha 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit). Khi tin hnh este ha 1 mol CH 3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 2,115. B. 2,925. C. 2,412. D. 0,456. Cu 9: Hn hp X gm axit fomic v axit axetic (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam ancol etylic (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l A. 10,125. B. 6,48. C. 8,10. D. 16,20. Cu 10: Tnh khi lng este metyl metacrylat thu c khi un nng 215 gam axit metacrylat vi 100 gam ancol metylic. Gi thit phn ng este ho t hiu sut 60%. A. 125 gam B. 175 gam C. 150 gam D. 200 gam Cu 11: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH ( c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l: A. 6,0 gam B. 4,4 gam C. 8,8 gam D. 5,2 Cu 12: Cho bit hng s cn bng ca phn ng este ho: CH3COOH + C2H5OH CH3COOC2H5 + H2O K = 4 Nu cho hn hp cng s mol axit v ancol tc dng vi nhau th khi phn ng t n trng thi cn bng th % ancol v axit b este ho l A. 50%. B. 66,7%. C. 33,3%. D. 65%. Cu 13: Cho cn bng sau: CH3COOH + C2H5OH CH3COOC2H5 + H2O K = 4 Khi cho 1 mol axit tc dng vi 1,6 mol ancol, khi h t n trng thi cn bng th hiu sut ca phn ng l A. 66,67%. B. 33,33%. C. 80%. D. 50%. Cu 14: un nng hn hp X gm 1 mol ancol etylic v 1 mol axit axetic (c 0,1 mol H 2SO4 c lm xc tc), khi phn ng t n trng thi cn bng c hn hp Y trong c 0,667 mol etyl axetat. Hng s cn bng KC ca phn ng l A. KC = 2. B. KC = 3. C. KC = 4. D. KC = 5. Cu 15: un 12 gam axit axetic vi 1 lung d ancol etylic ( c H2SO4 c lm xc tc). n khi phn ng dng li thu c 11 gam este. Hiu sut ca phn ng este ho l bao nhiu? A. 70% B. 75% C. 62,5% D. 50% Cu 16:Khi un nng 25,8 gam hn hp ancol etylic v axit axetic c H2SO4 c lm xc tc thu c 14,08 gam este. Nu t chy hon ton lng hn hp thu c 23,4 ml H2O. Tm thnh phn trm mi cht trong hn hp u v hiu sut ca phn ng este ho. A. 53,5% C2H5OH; 46,5% CH3COOH v hiu sut 80% B. 55,3% C2H5OH; 44,7% CH3COOH v hiu sut 80% C. 60,0% C2H5OH; 40,0% CH3COOH v hiu sut 75% D. 45,0% C2H5OH; 55,0% CH3COOH v hiu sut 60% Cu 17: un 12 gam axit axetic vi 13,8 gam etanol ( c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l: A. 55% B. 50% C. 62,5% D. 75% Cu 18: Bit rng phn ng este ho CH3COOH + C2H5OH CH3COOC2H5 + H2O C hng s cn bng K = 4, tnh % Ancol etylic b este ho nu bt u vi [C2H5OH] = 1 M, [CH3COOH] = 2 M. A. 80% B. 68% C. 75% D. 84,5% IV. XC NH CU TO ESTE KHI BIT CTPT. * Este thng thng. Cu 1:un este E ( C6H12O2) vi dung dch NaOH ta c 1 acol A khng b oxi ho bi CuO.E c tn l: A. isopropyl propionat B. isopropyl axetat C. butyl axetat D. tert-butyl axetat. Cu 2: Este X ( C4H8O2) tho mn cc iu kin: + O2 , xt H O , X + H Y1 + Y2 Y1 Y2 X c tn l: A. Isopropyl fomiat B. propyl fomiat C. Metyl propionat D. Etyl axetat. Cu 3: Hai cht hu c X, Y c cng cng thc phn t C 3H4O2. X phn ng vi NaHCO3 v phn ng trng hp, Y phn ng vi NaOH nhng khng phn ng vi Na. Cng thc cu to ca X, Y ln lt l A. C2H5COOH, CH3COOCH3. B. C2H5COOH, CH2 = CHCOOCH3. C. CH2 = CHCOOH, HCOOCH = CH2. D. CH2 = CH CH2COOH, HCOOCH = CH2. Cu 4: Thu phn este c cng thc phn t C4H8O2 (xc tc H+), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. metanol. B. Etyl axetat. C. Axit axetic. D. Etanol. Cu 5: Thu phn este C4H6O2 (X) bng dung dch NaOH ch thu c 1 mui duy nht. Cng thc cu to ca X l
2 +

C=O C. (CH2 )3

A. CH3COOCH = CH2. B. HCOOCH2 CH = CH2. D. CH3 CH = CH COOH. Cu 6:X c cng thc phn t C3H4O2. Khi cho X phn ng vi dung dch NaOH thu c 1 sn phm duy nht. Xc nh cng thc cu to ca X ?
H H3C C C O

O A.CH2=CH-COOH. B.HCOOCH=CH2. C. . D.tt c u ng. Cu 7: Hp cht X c cng thc phn t C nH2nO2 khng tc dng vi Na, khi un nng X vi axit v c c 2 cht Y 1 v Y2. Bit Y2 b oxi ho cho metanal cn Y1 tham gia phn ng trng gng. Vy gi tr ca n l A. 1. B. 2. C. 3. D. 4. Cu 8: Cht X c cng thc phn t C7H6O3(M = 138). Bit 27,6 gam X tc dng va vi 600 ml dung dch NaOH 1M. Cng thc cu to ca X l A. (HO)2C6H3CHO. B. HOC6H4CHO. C. (HO)3C6H2CH3. D. HCOOC6H4OH. Cu 9: Cho 10,4 gam este X (cng thc phn t: C4H8O3) tc dng va vi 100 ml dung dch NaOH 1M c 9,8 gam mui khan. Cng thc cu to ca X l A. HCOOCH2CH2CHO. B. CH3COOCH2CH2OH. C. HOCH2COOC2H5. D.CH3CH(OH)COOCH3. Cu 10: Khi thu phn mt este c cng thc C4H8O2 ta c axit X v ancol Y. Oxi ho Y vi K2Cr2O7 trong H2SO4 ta c li X. Este c cng thc cu to no sau y? A. CH3COOC2H5 B. HCOOC3H7 C. C2H5COOCH3 D. Khng xc nh c. * Este v sn phm c phn ng trng gng. Cu 1: Thu phn este C2H5COOCH=CH2 trong mi trng axit to thnh nhng sn phm g? A. C2H5COOH, CH2=CH-OH B. C2H5COOH, HCHO C. C2H5COOH, CH3CHO D. C2H5COOH, CH3CH2OH Cu 2. Este X c CTCP C4H6O2.Bit X thu phn trong mi trng kim to ra mui v anhit.. Cng thc cu to ca X l. A. CH3COOCH= CH2 B. HCOOCH2- CH= CH2 C. HCOOCH2- CH= CH2 D. CH3COOCH2CH3 Cu 3: Thu phn este C4H6O2 trong mi trng axit thu c hn hp 2 cht u tham gia phn ng trng gng. Cng thc cu to ca este l A. HCOOCH2CH = CH2 B. HCOOC(CH3) = CH2 C. CH2 = CHCOOCH3 D. HCOOCH = CHCH3 Cu 4: Cho cht X tc dng vi 1 lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3/NH3 c cht hu c T. Cho cht T tc dng vi NaOH li thu c cht Y. Cht X c th l A. HCOOCH = CH2. B. HCOOCH3. C. CH3COOCH = CHCH3. D. CH3COOCH = CH2. Cu 5: Cht X c cng thc phn t C4H6O3, X c cc tnh cht ho hc sau: - Tc dng vi H2 (Ni, t0), Na, AgNO3/NH3. - Tc dng vi NaOH thu c mui v anehit n chc. Cng thc cu to ca X l A. HCOOCH2CH2CHO. B. OHC-CH2CH2-COOH. C. HCOOCH(OH)-CH=CH2. D. CH3-CO-CH2-COOH. Cu 6: Cho cht X c cng thc phn t C4H6O2 bit:

X +NaOH Y +Z Y +H2SO4 Na2SO4 +T

Z v T u c kh nng tham gia phn ng trng bc. Cng thc phn t ca X l A. CH3COOCH = CH2. B. HCOOCH2 CH = CH2. C. HCOOC(CH3) = CH2. D. HCOOCH = CH CH3. Cu 7: Este C4H8O2 tham gia phn ng trng bc c th c tn sau: A. Etyl fomiat B. propyl fomiat C. isopropyl fomiat D. B, C u ng Cu 8: un este E (C4H6O2) vi HCl thu c sn phm c kh nng c phn ng trng gng. E c tn l: A. Vinyl axetat B. propenyl axetat C. Alyl fomiat D. C A, B, C u ng. Cu 9: Mt cht hu c A c CTPT C3H6O2 tha mn: A tc dng c dd NaOH un nng v dd AgNO3/NH3,t0.Vy A c CTCT l: A. C2H5COOH B. CH3-COO- CH3 C. H-COO- C2H5 D. HOC-CH2-CH2OH * Este thm. Cu 1: Cho este X (C8H8O2) tc dng vi dung dch NaOH thu c hn hp mui u c khi lng phn t ln hn 70 vc. Cng thc cu to ca X l A. HCOO C6H4 CH3. B. CH3COOC6H5. C. C6H5COOCH3. D. HCOOCH2C6H5. Cu 2: Hp cht thm X thuc loi este c cng thc phn t C 8H8O2. X khng th iu ch t phn ng ca axit v ancol tng ng v khng tham gia phn ng trng gng. Cng thc cu to ca X l A. C6H5COOCH3. B. CH3COOC6H5. C. HCOOCH2C6H5. D. HCOOC6H4CH3.

Cu 3. Hai este A v B l dn xut ca benzen c CTPT l: C 9H8O2. A v B u cng hp vi Br2 theo t l mol 1:1. A tc dng vi NaOH cho mt mui v mt anehit, B tc dng vi NaOH cho 2 mui v nc . Cc mui c khi lng phn t ln hn khi lng phn t ca CH3COONa . CTCT ca A v B c th l: A. HOOC-C6H4-CH=CH2 v CH2=CH-COO-C6H5 B. C6H5COOCH=CH2 v C6H5-CH=CH-COOH C. HCOO-C6H4-CH=CH2 v HCOO-CH=CH-C6H5 D. C6H5COOCH=CH2 v CH2=CH-COO-C6H5 Cu 4: Hai este A, B l dn xut ca benzen c CTPT l C 9H8O2. A v B u cng hp Br2 theo t l 1:1. A tc dng vi NaOH to 1 mui v 1 anehit. B tc dng vi NaOH cho 2 mui v H2O. A, B c CTCT ln lt l: A. C6H5COOCH=CH2, CH2=CH-COOC6H5 B. CH2=CH-COOC6H5, C6H5COOCH=CH2 C. HCOOCH=CH-C6H5, C6H5COOCH=CH2 D. C6H5COOCH=CH2, HCOOCH=CH-C6H5 Cu 5: Este X l dn xut ca benzen c cng thc C9H8O2. X tc dng c vi dung dch Br2 theo t l 1:1. Khi cho X tc dng vi dung dch NaOH un nng thu c 1 mui v mt anehit. Mui thu c c khi lng phn t ln hn 82. Cng thc cu to thu gn ca X l A. C6H5COOCH=CH2. B. HCOOC6H4CH=CH2. C. HCOOCH=CHC6H5. D. HCOOC(C6H5)=CH2. Cu 6: Este X l dn xut ca benzen c cng thc C 9H8O2. X tc dng c vi dung dch Br 2 theo t l 1:1. Khi cho X tc dng vi dung dch NaOH un nng thu c 1 mui v 1 xeton. Cng thc cu to thu gn ca X l A. C6H5COOCH=CH2. B. HCOOC6H4CH=CH2. C. C6H5COOCH=CHCH3. D. HCOOC(C6H5)=CH2. Cu 7: Este X l dn xut ca benzen c cng thc C 9H8O2. X tc dng c vi dung dch Br 2 theo t l 1:1. Khi cho X tc dng vi dung dch NaOH un nng, d thu c 2 mui v nc . Cc mui u c khi lng phn t ln hn 82. Cng thc cu to thu gn ca X l A. HCOOC6H4CH=CH2. B. CH2=CHCOOC6H5. C. CH2=CHCOOC6H4CH3. D. C2H5COOC6H5. Cu 8: Este X c cng thc C9H8O2 tc dng vi dung dch NaOH to thnh 2 mui v nc . Nung nng 1 trong 2 mui vi vi ti xt thu c etilen. X l A. phenyl axetat. B. phenyl propionat. C. phenyl acrylat. D. benzyl axetat. Cu 9:Mt hn hp X gm 2 este X, Y c cng cng thc phn t C8H8O2 v u cha vng benzen. X phng ho ht 0,2 mol X, ta cn 0,3 lit dung dch NaOH 1M thu c 3 mui.Tnh khi lng mi mui. A. 8,2 gam CH3COONa; 14,4 gam C6H5COONa; 11,6 gam C6H5ONa B. 4,1 gam CH3COONa; 14,4 gam C6H5COONa; 11,6 gam C6H5ONa C. 8,2 gam CH3COONa; 7,2 gam C6H5COONa; 5,8 gam C6H5ONa D. 4,1 gam CH3COONa; 14,4 gam C6H5COONa; 17,4 gam C6H5ONa * Este a chc. Cu 1: Este X c cng thc phn t C7H12O4, khi cho 16 gam X tc dng va vi 200 gam dung dch NaOH 4% th thu c 1 ancol A v 17,8 gam hn hp hai mui. Cng thc cu to ca X l A. CH3COO(CH2)2OOCC2H5. B. HCOO(CH2)3OOCC2H5. C. HCOO(CH2)3OOCCH3. D. CH3COO(CH2)3OOCCH3. Cu 2: Mt hp cht hu c X c cng thc phn t C8H14O4 . Khi X tc dng hon ton vi dd NaOH to ra hai ancol A v B c s nguyn t cacbon gp i nhau . Khi un nng ln lt A , B vi H2SO4 c 1700C th A to ra mt olefin duy nht , B to ra 3 olefin ng phn . X c cng thc cu to l. A. C2H5OOC COOCH2- CH2- CH2- CH3 B. CH3OOC- (CH2)3- COO- CH2- CH3 C. C2H5OOC COOCH(CH3) - CH2- CH3 D. C2H5OOC COOCH2- CH(CH3)- CH3 V. XC NH CTPT, CTCT 1 ESTE. * Este n chc. Cu 1: Mt este n chc no c 48,65 % C trong phn t th s ng phn este l: A. 1 B. 2 C. 3 D. 4 Cu 2: t chy hon ton 7,5 gam este X ta thu c 11 gam CO2 v 4,5 gam H2O.Nu X n chc th X c cng thc phn t l: A. C3H6O2 B. C4H8O2 C. C5H10O2 D. C2H4O2 Cu 3: t chy hon ton 1,46 gam cht hu c A gm C, H, O th thu c 1,344 lit CO 2 (ktc) v 0,9 gam H2O. Cng thc no di y c th l cng thc ng . A. (COOC2H5)2 B. CH3COOH C. CH3COOCH3 D. HOOC-C6H4-COOH Cu 4: Thu phn mt este trong mi trng kim ta c ancol etylic m khi lng ancol bng 62% khi lng phn t este. Cng thc este c th l cng thc no di y? A. HCOOCH3 B. HCOOC2H5 C. CH3COOC2H5 D. C2H5COOC2H5 Cu 5:Thu phn mt este trong mi trng kim thu c mt mui natri c khi lng 41/37 khi lng este.Bit khi lm bay hi 7,4 gam este th th tch hi ca n ng th tch ca 3,2 gam O 2 cng iu kin.Cng thc cu to ca este c th l cng thc no di y? A. HCOOCH3 B. HCOOC2H5 C. CH3COOCH3 D. CH3COOC2H5 Cu 6: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lit CO 2 ( ktc) v 3,6 gam H2O. Nu cho 4,4 gam cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z.Tn ca X l:

A. Etyl propionat B. Metyl propionat C. isopropyl axetat D. etyl axetat Cu 7: Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc ph hp vi X? A. 2 B. 3 C. 4 D. 5 Cu 8: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi dung dch AgNO3 trong NH3 thu c cht hu c T. Cho T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. HCOOCH=CH2 B. CH3COOCH=CH2 C. HCOOCH3 D. CH3COOCH=CH-CH3 Cu 9: X l mt este no n chc, c t khi hi so vi CH 4 l 5,5. Nu em un 2,2 gam este X vi dd NaOH d, thu c 2,05 gam mui. Cng thc cu to thu gn ca X l: A. HCOOCH2CH2CH3 B. HCOOCH(CH3)2 C. C2H5COOCH3 D. CH3COOC2H5 Cu 10: A c cng thc phn t trng vi cng thc n gin. Khi phn tch A thu c kt qu: 50% C, 5,56% H, 44,44%O theo khi lng. Khi thu phn A bng dung dch H2SO4 long thu c 2 sn phm u tham gia phn ng trng bc. Cng thc cu to ca A l A. HCOO-CH=CH-CH3. B. HCOO-CH=CH2. C. (HCOO)2C2H4. D. CH2=CH-CHO. Cu 11: Cho 13,2 g este n chc no E tc dng ht vi 150 ml dung dch NaOH 1M thu c 12,3 g mui . Xc nh E. A. HCOOCH3 B. CH3-COOC2H5 C. HCOOC2H5 D. CH3COOCH3 Cu 12: Thy phn 1 este n chc no E bng dung dch NaOH thu c mui khan c khi lng phn t bng 24/29 khi lng phn t E.T khi hi ca E i vi khng kh bng 4. Cng thc cu to. A. C2H5COOCH3. B. C2H5COOC3H7 C. C3H7COOCH3 D. Kt qu khc Cu 13: X l este ca mt axit hu c n chc v ancol n chc. thu phn hon ton 6,6g cht X, ngi ta dng 34,10ml dung dch NaOH 10% c D = 1,1g/ml. Lng NaOH ny d 25% so vi lng NaOH cn dng cho phn ng. X c cng thc cu to no sau y? A. HCOOC3H7 vCH3COOC2H5 B. HCOOC3H7 C. CH3COOC2H5 D. C2H5COOCH3 Cu 14: x phng ho 17,4g mt este no n chc cn dng 300ml dung dch NaOH 0,5M. Este c cng thc phn t l A. C3H6O2 B. C5H10O2 C. C4H8O2 D. Kt qu khc Cu 15: 12,9g mt este n chc, mch h tc dng ht vi 150ml dung dch KOH 1M. Sau phn ng thu c mt mui v anehit. Cng thc cu to ca este l cng thc no sau y? A. HCOOCH=CH-CH3 B. CH3COOCH=CH2 C. C2H5COOCH=CH2 D. A v B ng. Cu 16: Mt este n chc c thnh phn khi lng mC:mO = 9:8 .Cho este trn tc dng vi mt lng dung dch NaOH va thu c mt mui c khi lng bng 41/37 khi lng este. Cng thc cu to este l: A. HCOOCH=CH2 B. HCOOC=CH-CH3 C. HCOOC2H5 D. CH3COOCH3 Cu 17: t chy 3g mt este Y ta thu c 2,24lt kh CO2 (ktc) v 1,8g H2O. Y c cng thc cu to no sau y? A. HCOOCH3 B. CH3COOCH3 C. CH2=CHCOOCH3 D. A, B, C u sai Cu 18: Este X to bi ancol no n chc v axit cacboxylic khng no (c 1 lin kt i) n chc. t chy m mol X thu c 22,4 lt CO2 (ktc) v 9g H2O .Gi tr ca m l bao nhiu trong cc s cho di y? A. 1 mol B. 2 mol C. 3 mol D. Kt qu khc Cu 19: t chy hon ton 0,1mol este X thu c 0,3mol CO2 v 0,3 mol H2O. Nu cho 0,1mol X tc dng ht vi NaOH th thu c 8,2g mui. X l cng thc cu to no sau y: A. CH3COOCH3 B. HCOOCH3 C. CH3COOC2H5 D. HCOOC2H5 Cu 20: un nng 1,1g este no n chc M vi dung dch KOH d, ngi ta thu c 1,4g mui. T khi ca M so vi kh CO2 l 2. M c cng thc cu to no sau y? A. C2H5COOCH3 B. CH3COOC2H5 C. HCOOC3H7 D. CH3COOC2H5 Cu 21:t chy hon ton 0,2 mol este X ri dn sn phm chy vo dung dch Ca(OH) 2 d thu c 40g kt ta. X c cng thc phn t l: A. HCOOC2H5 B. CH3COOCH3 C. HCOOCH3 D. Khng xc nh c. Cu 22: Khi t chy hon ton este no n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l: A. etyl axetat B. metyl axetat C. metyl fomiat D. propyl axetat Cu 23: Este n chc X c t khi hi so vi CH4 l 6,25.Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M(un nng). C cn dung dch c sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l: A. CH2=CH-CH2COOCH3 B. CH2=CH-COOCH2CH3 C. CH3COOCH=CH-CH3 D. CH3-CH2COOCH=CH2 Cu 24. Cht X l mt hp cht n chc mch h, tc dng c vi dd NaOH c khi lng phn t l 88 dvc. Khi cho 4,4g X tc dng va vi dd NaOH, c cn dung dich sau phn ng c 4,1g cht rn. X l cht no trong cc cht sau: A. Axit Butanoic B. Metyl Propionat C. Etyl Axetat D. Isopropyl Fomiat . Cu 25: Mt cht hu c X mch h c khi lng phn t l 60 vC tha mn iu kin sau: X khng tc dng vi Na, X tc dng vi d2 NaOH, v X phn ng vi Ag2O.NH3. Vy X l cht no trong cc cht sau: A. CH3COOH B. HCOOCH3 C. C3H7OH D. HO CH2 CHO Cu 26. Mt este X c to ra bi mt axit no n chc v ancol no n chc c dX/CO2=2. Cng thc phn t ca X l: A. C2H402 B. C3H602 C. C4H602 D. C4H802

Cu 27. Cho 4,2g este n chc no E tc dng ht vi dd NaOH ta thu c 4,76g mui natri. Vy cng thc cu to ca E c th l: A. CH3 COOCH3 B. C2H5COOCH3 C. CH3COOC2H5 D. HCOOC2H5 Cu 28: Hp cht hu c X n chc cha (C, H, O) khng tc dng vi Na nhng tc dng vi dung dch NaOH theo t l mol 1 : 1 hoc 1 : 2. Khi t chy 1 mol X thu c 7 mol CO2. Cng thc cu to ca X l A. C2H5COOC4H9. B. HCOOC6H5. C. C6H5COOH. D. C3H7COOC3H7. Cu 29: Khi t chy hon ton 4,4 gam hp cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO 2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l D. etyl propionat. B. Metyl propionat. C. Isopropyl axetat. D. Etyl axetat. Cu 30: X l mt este no n chc mch h, t khi hi i vi CH4 l 5,5. Nu un nng 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to ca X l A. HCOOCH2CH2CH3. B. C2H5COOCH3. C. CH3COOC2H5. D. HCOOCH(CH3)2. Cu 31: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c hi ng bng th tch hi ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l A. HCOOC2H5 v CH3COOCH3. B. C2H5COOCH3 v HCOOCH(CH3)2. C. C2H3COOC2H5 v C2H5COOC2H3. D. HCOOCH2CH2CH3 v CH3COOC2H5. Cu 32: t chy 1,6 gam mt este X n chc thu c 3,52 gam CO2 v 1,152 gam H2O. Cho 10 gam X tc dng vi dung dch NaOH (va ), c cn dung dch sau phn ng thu c 14 gam mui khan Y. Cho Y tc dng vi axit v c long thu c Z khng phn nhnh. Cng thc cu to ca Z l A. CH3(CH2)3COOH. B. CH2 = CH(CH2)2COOH. C. HO(CH2)4COOH. D. HO(CH2)4OH. Cu 33: X l mt este khng no (cha 1 lin kt i C = C) n chc, mch h. t chy hon ton 4,3 gam X cn va 7,2 gam O2. X c ti a bao nhiu cng thc cu to? A. 3. B. 4. C. 5. D. 6. Cu 34:Hn hp A gm 2 este n chc no, ng phn. Khi trn 0,1 mol hn hp A vi O2 va ri t chy thu c 0,6 mol sn phm gm CO2 v hi nc. Cng thc phn t 2 este l A. C4H8O2. B. C5H10O2. C. C3H6O2. D. C3H8O2. Cu 35: Mt este to bi axit n chc v ancol n chc c t khi hi so vi CO 2 bng 2. Khi un nng este ny vi dung dch NaOH to ra lng mui c khi lng ln hn lng este phn ng . Este l A. Metyl axetat. B. Propyl axetat. C. Metyl propionat. D. Etyl axetat. Cu 36: Cho 1,76 gam mt este no, n chc phn ng va ht vi 40 ml dung dch NaOH 0,5M thu c cht X v cht Y. t chy hon ton 1,2 gam cht Y c 2,64 gam CO2 v 1,44 gam H2O. Cng thc cu to ca este l A. HCOOCH2CH2CH3. B. CH3COOC2H5. C. C2H5COOCH3. D. CH3COOCH(CH3)2. Cu 37: un nng hp cht X vi H2O (xc tc H+) c axit hu c Y v ancol Z n chc. Cho hi Z i qua ng ng CuO, t0 c hp cht T c kh nng tham gia phn ng trng bc. t chy hon ton 2,8 gam X phi dng ht 3,92 lt oxi ( ktc), c kh CO2 v hi nc theo t l th tch: VCO2 : VH2O = 3 : 2 . Bit d Y N = 2, 57 . Cng thc cu to ca X l
2

A. CH2 = CHCOOC3H7. B. CH2 = CHCOOCH2CH = CH2. C. C2H5COOCH = CH2. D. CH2=CHCH2COOCH=CH2. Cu 38: X l este ca mt axit cacboxylic n chc v ancol etylic. Thy phn hon ton 7,4 gam X ngi ta dng 125 ml dung dch NaOH 1M. Lng NaOH d 25% so vi l thuyt (lng cn thit). Cng thc cu to ca X l A. HCOOC2H5. B. CH3COOC2H5. C. C2H5COOC2H5. D. HCOOCH3. Cu 39: t chy hon ton 0,2 mol este n chc X ri cho sn phm chy ln lt qua bnh 1 ng 100 gam dung dch H2SO4 96,48%; bnh 2 ng dung dch KOH d. Sau th nghim thy nng H2SO4 bnh 1 gim cn 87,08%; bnh 2 c 82,8 gam mui. Cng thc phn t ca X l A. C2H4O2. B. C3H6O2. C. C4H8O2. D. C3H4O2. Cu 40: Cho ancol X tc dng vi axit Y c este E. Lm bay hi 8,6 gam E c th tch hi bng th tch ca 3,2 gam kh oxi (o cng iu kin), bit MY > MX. Cng thc cu to ca E l : A. HCOOCH2CH = CH2. B. CH3COOCH = CH2. C. CH2 = CHCOOCH3. D. HCOOCH = CHCH3. Cu 41: Mt este n chc X c phn t khi l 88 vC. Cho 17,6 gam X tc dng vi 300 ml dung dch NaOH 1M. Khi phn ng xy ra hon ton, c cn dung dch sau phn ng thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. HCOOCH2CH2CH3. B. HCOOC3H7. C. CH3CH2COOCH3. D. CH3COOCH2CH3. Cu 42: t chy hon ton 4,44 gam cht hu c X n chc (cha C, H, O). Cho ton b sn phm chy hp th hon ton vo bnh ng dung dch Ca(OH)2 d thy khi lng bnh tng 11,16 gam ng thi thu c 18 gam kt ta. Ly m1 gam X cho tc dng vi dung dch NaOH (va ), c cn dung dch sau phn ng c m 2 gam cht rn khan. Bit m2 < m1. Cng thc cu to ca X l A. HCOOC2H5. B. CH3COOCH3. C. C2H5COOH. D. CH2 = CHCOOCH3. Cu 43: Hn hp M gm mt axit X n chc, mt ancol Y n chc v mt este to ra t X v Y. Khi cho 25,2 gam hn hp M tc dng va vi 100 ml dung dch NaOH 2M c 13,6 gam mui khan. Nu un nng Y vi H2SO4 c th thu c cht hu c Y1 c t khi hi so vi Y bng 1,7 (coi hiu sut t 100%). Cng thc cu to ca este l

A. HCOOCH2CH2CH3. B. CH3COOC3H7. C. HCOOCH(CH3)2. D. HCOOC2H4CH3 hoc HCOOCH(CH3)2. * Este a chc. Cu 1: Cho 21,8 gam cht hu c X mch h ch cha mt loi nhm chc tc dng vi 1 lt dung dch NaOH 0,5M thu c 24,6 gam mui v 0,1 mol ancol. Lng NaOH d c trung ho va ht bi 0,5 lt dung dch HCl 0,4M. Cng thc cu to ca X l A. (HCOO)3C3H5. B. (CH3COO)2C2H4. C. (CH3COO)3C3H5. D. C3H5(COOCH3)3. Cu 2: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol v hai loi axit bo. Hai loi axit bo l A. C15H31COOH v C17H35COOH. B. C17H33COOH v C15H31COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C17H35COOH. Cu 3: thu phn 0,01 mol este to bi mt ancol a chc v mt axit cacboxylic n chc cn dng 1,2 gam NaOH. Mt khc thy phn 6,35 gam este cn 3 gam NaOH, sau phn ng thu c 7,05 gam mui. Cng thc cu to ca este l A. (CH3COO)3C3H5. B. (CH2 = CHCOO)3C3H5. C. (CH2 = CHCOO)2C2H4. D. (C3H5COO)3C3H5. Cu 4: iu ch mt este X, dng lm thuc chng mui gi tt l DEP ngi ta cho axit Y tc dng vi mt lng d ancol Z. Mun trung ho dung dch cha 1,66 gam Y cn 100 ml dung dch NaOH 0,2M. Trong dung dch ancol Z 94% (theo khi lng) t l s mol n Z : n H 2O = 86 :14 . Bit 100 < MY < 200. Cng thc cu to ca X l A. CH2 = CHCOOCH3. B. C6H5COOC2H5. C. C6H4(COOC2H5)2. D. (C2H5COO)2C6H4. Cu 5. un nng 0,1 mol X vi lng va dd NaOH thu c 13,4g mui ca axit hu c a chc B v 9,2g ancol n chc C. Cho ancol C bay hi 1270C v 600 mmHg s chim th tch 8,32 lt.Cng thc phn t ca cht X l:

COOCH3 HC COOCH3 COOCH3

H2C COOCH3 C COOCH3 H2

OC2H5 OC H

OCH3 OCH

2 5 3 A. B. C. O D. O Cu 6:X l este ca glixerol v axit hu c Y. t chy hon ton 0,1 mol X ri hp th tt c sn phm chy vo dung dch Ca(OH)2 d thu c 60g kt ta. X c cng thc cu to l: A.(HCOO)3C3H5 B. (CH3COO)3C3H5 C. (C17H35COO)3C3H5 D. (C17H33COO)3C3H5 Cu 7:X l este mch h do axit no A v ancol no B to ra. Khi cho 0,2 mol X phn ng vi NaOH thu c 32,8 gam mui. t chy 1 mol B cn dng 2,5 mol O2. Cng thc cu to ca X l A.(CH3COO)2C2H4. B.(HCOO)2C2H4. C.(C2H5COO)2C2H4. D. (CH3COO)3C3H5. VI. XC NH CTPT, CTCT HN HP ESTE. Cu 1: X phng ha hon ton 9,7 gam hn hp hai este n chc X, Y cn 150 ml dung dch KOH 1M. Sau phn ng c cn dung dch thu c hn hp hai ancol ng ng k tip v mt mui duy nht. Cng thc cu to thu gn ca X, Y ln lt l A. HCOOCH3, HCOOC2H5. B. C2H5COOCH3, C2H5COOC2H5. C. CH3COOCH3, CH3COOC2H5 D. C2H3COOCH3, C2H3COOC2H5. Cu 2: Mt hn hp X gm 2 este A, B n chc ng ng lin tip, khi b x phng ho cho ra 2 mui ca axitcacboxylic v 1 ancol. Th tch dung dch NaOH 1M cn dng x phng ho este ny l 0,3 lit. Xc nh CTCT v s mol mi este trong hn hp X. Bit rng khi lng mX=23,6 gam v trong 2 axit A, B khng c axit no cho phn ng trng gng. A. 0,1 mol CH3COOCH3 v 0,2 mol CH3COOC2H5 B. 0,2 mol CH3COOCH3 v 0,1 mol CH3COOC2H5 C. 0,2 mol CH3COOCH3 v 0,1 mol C2H5COOCH3 D. 0,2 mol HCOOCH3 v 0,2 mol CH3COOC2H5 Cu 3: Cho 35,2 gam hn hp gm 2 este no n chc l ng phn ca nhau c t khi hi i vi H 2 bng 44 tc dng vi 2 lit dung dch NaOH 0,4 M, ri c cn dung dch va thu c, ta c 44,6 gam cht rn B. Cng thc ca 2 este l: A. HCOOC2H5 v CH3COOCH3 B. C2H5COOCH3 v CH3COOC2H5 C. HCOOC3H7 v CH3COOC2H5 D. HCOOC3H7 v CH3COOCH3 Cu 4: t chy hon ton 3,7g hn hp 2 este ng phn X v Y ta thu c 3,36 lt kh CO 2 (ktc) v 2,7g H2O. X v Y c cng thc cu to l: A. CH2=CHCOOCH3 v HCOOCH2CH=CH2 B. CH3COOCH3 v HCOOC2H5 C. CH2=CHCOOC2H5 v C2H5COOCH=CH2 D. Kt qu khc. Cu 5: x phng ho hon ton 2,22g hn hp 2 este ng phn X v Y cn dng ht 30ml dung dch KOH 1M. Khi t chy hon ton hn hp 2 este th thu c kh CO2 v hi nc c th tch bng nhau v o cng iu kin. Cng thc phn t ca X, Y l: A. CH3COOCH3 v HCOOC2H5 B. C2H5COOCH3 v CH3COOC2H5 C. C3H7COOCH3 v CH3COOC3H7 D. Kt qu khc. Cu 6: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 ( o cng iu kin). Cng thc cu to thu gn ca X, Y l: A. C2H5COOCH3 v HCOOCH(CH3)2 B. HCOOC2H5 v CH3COOCH3 C. C2H3COOC2H5 v C2H5COOC2H3 D. HCOOCH2CH2CH3 v CH3COOC2H5

Cu 7: Lm bay hi 5,98 gam hn hp 2 este ca axit axetic v 2 ancol ng ng k tip ca ancol metylic. N chim th tch 1,344 lit (ktc). Cng thc cu to ca 2 este l: A. HCOOC2H5 v HCOOC3H7 B. CH3COOCH3 v CH3COOC2H5 C. CH3COOC2H5 v CH3COOC3H7 D. CH3COOCH3 v CH3COOC2H5 Cu 8: X l hn hp 2 este ng phn c to thnh t mt ancol n chc, mch cacbon khng phn nhnh vi axit n chc. T khi hi ca X so vi hiro bng 44. Cng thc phn t ca X l: A. C3H6O2 B. C4H8O2 C. C5H10O2 D. C6H12O2 Cu 9: t chy hon ton mt lng hn hp hai este n chc no, mch h cn 3,976 lt oxi (o diu kin tiu chun) thu c 6,38 g CO2. Cho lng este ny tc dng va vi KOH thu c hn hp hai ru k tip v 3,92 g mui ca mt axit hu c. Cng thc cu to ca hai cht hu c trong hn hp u l: A. HCOOCH3 v C2H5COOCH3 B. CH3COOC2H5 v C3H7OH C. CH3COOCH3 V CH3COOC2H5 D. CH3COOCH3 V CH3COOC2H5 Cu 10: Hn hp Y gm hai este n chc mch h l ng phn ca nhau. Cho m gam hn hp Y tc dng va vi 100ml dung dch NaOH 0,5M, thu c mt mui ca mt axit cacboxylic v hn hp hai ru. Mt khc t chy hon ton m gam hn hp Y cn dng 5,6 lt O2 v thu c 4,48 lt CO2 (cc th tch kh o iu kin tiu chun). Cng thc cu to ca 2 este trong hn hp Y l: A. CH3COOCH3 v HCOOC2H5 B. C2H5COOCH3 v HCOOC3H C. CH3COOCH3 v CH3COOC2H5 D. HCOO-CH(CH3)CH3 VII. ESTE V CC HP CHT KHC. Cu 1: Mt hn hp X gm 2 cht hu c n chc. Cho X phn ng va vi 500ml dung dch KOH 1M. Sau phn ng thu c hn hp Y gm 2 mui ca hai axit cacboxylic v mt ancol. Cho ton b lng ancol thu c trn tc dng vi Na d, sinh ra 3,36 lit H2( ktc). Hn hp X gm: A. mt axit v mt este B. mt este v mt ancol C. hai este D. mt axit v mt ancol

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