S GIO DC V O TO H NI

THI TH I HC LN II NM 2011
TRNG THPT AMSTERDAM
Mn thi: HO HC
Thi gian lm bi: 90 pht, khng k thi gian pht .

thi gm 5 trang
I. PHN CHUNG CHO TT C TH SINH (40 cu t cu 1 n cu 40)
Cu 1: Chia m gam hn hp M gm hai ancol n chc k tip trong dy ng ng thnh 2 phn bng
nhau. Cho phn mt tc dng vi Na (d), c 3,36 lt kh hiro (ktc). Cho phn hai phn ng hon
ton vi CuO nhit cao, c hn hp M1 cha hai anehit (ancol ch bin thnh anehit). Ton b
lng M1 phn ng ht vi AgNO3 trong NH3, thu c 86,4 gam Ag. Gi tr ca m l
A. 24,8 gam
B. 30,4 gam
C. 15,2 gam
D. 45,6 gam
*ap an. nH2= 0,15. nancol = 0,3 = n andehyt , t= n Ag/Andehyt =2,67, suy ra co HCHO, ma ng
ng lin tip CH3CHO. D co nHCHO =0,1, CH3CHO =0,2, vy mancol =(32.0,1 +46.0,2)*2 =A
Cu 2: Chia 156,8 gam hn hp L gm FeO, Fe3O4, Fe2O3 thnh hai phn bng nhau. Cho phn th nht
tc dng ht vi dung dch HCl d c 155,4 gam mui khan. Phn th hai tc dng va vi dung
dch M l hn hp HCl, H2SO4 long thu c 167,9 gam mui khan. S mol ca HCl trong dung dch M
l
A. 1,75 mol
B. 1,50 mol
C. 1,80 mol
D. 1,00 mol
D thy mt 1O thay 2 Cl, M =2.35,5- 16=55, m= 155,4-156,8/2 , vy s mol HCl =nH+= (m/M )
*2 =2,8 mol.Ta co m mui 2 = mOxit mO +x,35,5+y.96 =167,9 x +2y =2,8, vy x=1,8
Cu 3: Hn hp bt X gm BaCO3, Fe(OH)2, Al(OH)3, CuO, MgCO3. Nung X trong khng kh n khi
lng khng i c hn hp rn A1. Cho A1 vo nc d khuy u c dung dch B cha 2 cht tan
v phn khng tan C1. Cho kh CO d qua bnh cha C1 nung nng c hn hp rn E (Cho cc phn
ng xy ra hon ton). E cha ti a:
A. 1 n cht v 2 hp cht.
B. 3 n cht.
C. 2 n cht v 2 hp cht.
D. 2 n cht v 1 hp cht.
ap an> Rn A1= BaO, Fe2O3, Al2O3,CuO, MgO. Dd B = Ba(AlO2)2va Ba(OH)2, Rn E =Fe, Cu, MgO.
Cu 4: Cho a gam Na vo 160 ml dung dch gm Fe2(SO4)3 0,125M v Al2(SO4)3 0,25M. Tch kt ta ri
nung n khi lng khng i th thu c 5,24 gam cht rn. Gi tr a no sau y l ph hp?
A. 9,43.
B. 11,5.
C. 9,2.
D. 10,35.
ap an> mFe2O3= 0,02*160=3,2 m Al2O3=2,04 nAl2O3 =0,02. Ma Al3+ ban u =0,08 vy
OH- =3Fe3++ 4.0,08- 0,02.2 =nNa =0,4. Vy =mNa= 9,2
Cu 5: Cho hn hp Na, Al, Fe, FeCO3, Fe3O4 tc dng vi dung dch NaOH d, lc ly kt ta ri chia
lm 2 phn. Phn 1 em tc dng vi dung dch HNO3 long d. Phn 2 em tc dng vi dung dch HCl
d. S phn ng oxi ha kh xy ra l:
A. 5.
B. 6.
C. 8.
D. 7.
ap an>NaOH co 2 OXH K, HNO3 co 3 OXH-K, HCl co 1 OXH-K vy =B
Cu 6: Cho s dng: X Y Z. Cho cc cht sau y: etilen, etyl clorua, ancol etylic. S s
nhiu nht th hin mi quan h gia cc cht trn l
A. 3
B. 4
C. 5
D. 6
aps an 3! =6
Cu 7: Cho cc cht sau: propyl clorua, anlyl clorua, phenyl clorua, natri phenolat, anilin, mui natri ca
axit amino axetic, ancol benzylic. S cht tc dng c vi dung dch NaOH long khi un nng l
A. 3.
B. 4.
C. 2.
D. 1.
ap an> Propyl C l, Anlyl Cl,
Cu 9: Oxi ho 25,6 gam CH3OH (c xc tc) thu c hn hp sn phm X. Chia X thnh hai phn
bng nhau Phn 1 tc dng vi AgNO3 d trong NH3 un nng thu c m gam Ag. Phn 2 tc dng va
vi 100ml dung dch KOH 1M. Hiu sut qu trnh oxi ho CH3OH l 75%. Gi tr ca m l
A. 64,8.
B. 32,4.
C. 129,6.
D. 108.
ap an > nCH3OH =0,8, n p/ =0,75*0,8=0,6 ! mi phn 0,3 mol p/ trong o axit =0,1 =nKOH, vy
mAg=( 0,2*4 +0,1*2)*108 =D
Cu 10: t chy 0,2 mol hp cht A thuc loi tp chc thu c 26,4 gam kh CO2, 12,6 gam hi H2O,
2,24 lt kh nit (ktc) v lng O2 cn dng l 0,75 mol. S ng phn ca A tc dng c vi dung
dch NaOH v HCl l
A. 2.
B. 4.
C. 3.
D. 5.
Trang 1/7 - M thi 135

ap an>nCO2 =0,6 , C=3, nH2O =0,7, H= 0,7*2/0,2=7, nN=0,2, N =1, O=0,6*2+0,7-0,75*2=0,4, O=

2. Vy C3H7NO2, ng phn aa = 2. ng phn RCOONRRR =2
Cu 11: S ng phn l hp cht thm c cng thc phn t C8H10O tc dng c vi NaOH l
A. 9.
B. 6.
C. 7.
D. 8.
ap an>Tac dung NaOH, hp cht thm, o la phenol, vy .CH3-CH2-C6H4(OH) co 3 p, (o, m, p) .
CH3-C6H3(OH)-CH3 co p 4 (2,3,4,5 ofC vong benzen).
Cu 12: Cho cc phn ng: (I) Fe + HCl ; (II) Fe3O4 + H2SO4 (c) ;
(III)KMnO4 + HCl ; (IV) FeS2 + H2SO4 (long) ; (V) Al + H2SO4 (long) ;
S phn ng m H+ ng vai tr l cht oxi ho l:
A. 3
B. 2
C. 4
D. 1
a p a n ( I . V ) t c p h a i s i n h r a H 2
I.sinh H2, II sinh SO2,III sinh Cl2,IV sinh raH2S,V sinh ra H2
Cu 13: Hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t
chy m gam hn hp X thu c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X
thc hin phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p l
A. 9,72.
B. 8,64.
C. 10,8.
D. 2,16.
ap an. nAncol= x= nH2O-nCO2 =0,17-0,14= 0,03, C2H5COOH (y) +CH3CHO (z)= 0,03.
nCO2=nC= 2x+3y+2z=0,14. x=0,03, y=0,02,z=0,01. m= 0,03*46+0,02*74 +0,01*44=3,3 g. Vy trong
13,2g co CH3CHO= (13,2/3,3)*0,01 =0,04. mAg=( 0,04*108)*2 =8,64
Cu 14: Cc nhn nh sau: 1)Axit hu c l axit axetic. 2)Gim n l dung dch axit axetic c nng
t 2% - 5%. 3)Khi cho 1 mol axit hu c (X) tc dng vi Na d, s mol H2 sinh ra bng s mol X v
khi t chy axit X th thu c n(H2O) : nCO2 =1. Vy X l axit no n chc no. 4)Khi t chy
hirocacbon no th ta c n(H2O) : nCO2 >1. Cc nhn nh sai l:
A. 1, 2, 3, 4.
B. 2, 3, 4.
C. 1, 2, 3.
D. 1, 3, 4.
ap an sai 1.sai vi axit acetic la axit HC, ngc lai khng ung. 4 sai vi ankan(hydrocacbon no mach
h) con hydrocacbon no mach vong (xycloankan) khng ung.
Cu 15: Cho phn ng sau X + H2SO4 (c, nng)
Fe2(SO4)3 + SO2 + H2O
S cht X c th thc hin phn ng trn l
A. 4.
B. 6.
C. 5.
D. 7.
ap an.X = Fe, FeO, Fe3O4, FeS,FeS2,Fe(OH)2, FeSO3 nn nh Fe2(SO3)3 khng tn tai, (nguyn tc
Fe co s OXH <3) vi y la p/ OXH K va khng c sinh cht khac( theo phng trinh)
Cu 16: C 4 dung dch long ca cc mui: BaCl2, ZnCl2, FeCl2, FeCl3. Khi sc kh H2S d vo cc
dung dch mui trn th s trng hp c phn ng to kt ta l
A. 3.
B. 2.
C. 1.
D. 4.
2+
23+
2ap an> Ba va S tan, va Fe +S FeS+S
Cu 17: Cho V lt hn hp kh A gm clo v oxi tc dng va ht vi hn hp B gm 0,2 mol Al v 0,1
mol Mg th thu c 25,2 gam hn hp mui clorua v oxit ca 2 kim loi. S mol ca Cl 2 c trong V lt
hn hp kh A l
A. 0,15.
B. 0,3.
C. 0,2.
D. 0,25.
mO +mCl = 25,2-0,2*27 +0,1*24 =17,4 =16x +35,5y, x*2 +y*1 =0,2*3 +0,1*2 ! y =0,4, nCl2 =0,2
Cu 18: Cho tng cht: Fe, FeO, Fe(OH) 2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3,
FeCO3 ln lt phn ng vi HNO3 c, nng, d. S phn ng thuc loi phn ng oxi ha kh l
A. 7
B. 8
C. 10
D. 9

Cu 19: Cho bt Fe vo dung dch NaNO3 v H2SO4. n phn ng hon thu c dung dch A, hn hp
kh X gm NO v H2 c v cht rn khng tan. Bit dung dch A khng cha mui amoni. Trong dung
dch A cha cc mui:
A. FeSO4, Fe(NO3)2, Na2SO4, NaNO3.
B. FeSO4, Fe2(SO4)3, NaNO3, Na2SO4.
C. FeSO4, Na2SO4.
D. FeSO4, Fe(NO3)2, Na2SO4.
ap an> rn ko tan Fe d, ddA chi thu c Fe2+, do sinh ra H2 nn NO3 ht
Cu 20: Hn hp X c 2 hirocacbon ng ng lin tip, c t khi hi so vi H2 bng 15,8. Ly 6,32
gam X li vo 200 gam dung dch cha xc tc thch hp th thu c dung dch Z v thy thot ra 2,688
lt kh kh Y iu kin tiu chun c t khi hi so vi H 2 bng 16,5. Bit rng dung dch Z cha anehit
vi nng C%. Gi tr ca C% l:
Trang 2/7 - M thi 135

A. 1,305%
B. 1,407%
C. 1,043%
D. 1,208%
ap an . M=15,8*2=31,6. nX=0,2. MY=33, nY=0,12, mY =3,96, mdd Z= 200+(6,32-3,96)=202,36.
Theo bai ra d thy X la an kin, co andehytco axetilen, ankin kia la C3H4, dung ng cheo trong X
va Y, suy ra s mol C2H 2 (phan ng) =CH3HCO =(nC2Hbd nC2H2 d) =0,12-0,12/2 =0,06, C
%=(0,06*44/202,36)*100% =A
Cu 21: C cc nhn nh sau y:
1)Nguyn tc sn xut gang l kh st bng CO nhit cao.
2)Nguyn tc sn xut thp l kh cc tp cht trong gang.
3)Tnh cht ha hc ca Fe2+ l tnh kh.
4)Nc cng l nc c cha ion Ca2+, Mg2+ di dng mui Cl-, HCO3-, SO42-.
S nhn nh ng l
A. 2.
B. 3.
C. 0.
D. 1.
ap an 1 sai, 2 ung, 3 ung (nn hoi la tinh cht hoa hoc c trng chun hn vi ngoai tinh kh c
trng Fe2+ con co tinh OXH, va tinh axit). 4 ung
Cu 22: C cc nhn nh sau:
1)Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon cc nguyn t ho hc,
nguyn t X thuc chu k 4, nhm VIIIB.
2)Cc ion v nguyn t: Ne , Na+ , F c im chung l c cng s electron.
3)Khi t chy ancol no th ta c n(H2O) : n(CO2)>1.
4)Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l K,
Mg, Si, N.
5)Tnh baz ca dy cc hiroxit: NaOH, Mg(OH)2, Al(OH)3 gim dn.
Cho: N (Z = 7), F (Z=9), Ne (Z=10), Na (Z=11), Mg (Z=12), Al (Z=13), K (Z = 19), Si (Z = 14).
S nhn nh ng:
A. 3.
B. 5.
C. 4.
D. 2.
ap an> 1.Fe. ung, 2 ung Vi u co 10e, 3sai( ancol no mach h mi ung) 4.ung (r cung nhom
tng dn, cung chu ky giam dn) 5. ung
Cu 23: Hn hp X gm 3 ancol n chc A, B, C trong B, C l 2 ancol ng phn. t chy hon
ton 0,08 mol X thu c 3,96 gam H 2O v 3,136 lt kh CO2 (ktc). S mol ancol A bng 5/3 tng s mol
2 ancol (B + C). Khi lng ca B, C trong hn hp l:
A. 3,6 gam
B. 0,9 gam
C. 1,8 gam
D. 2,22 gam
AP AN .nH2O =0,22, nCO2=0,14, do 0,08=0,22-0,14 khng inh cung day ng ng. CTRUNG
BINH=0,14/0,08=1,75. Co CH3OH,n=0,05 mol, CB=CC =(1,75*8-1C*5)/3=3, MB,C= C3H7OH*0,03=1,8
Cu 24: Cho m in ca cc nguyn t nh sau: O(3,44), Cl(3,16), Mg(1,31), C(2,55), H(2,2)
Trong cc phn t: MgO, CO2, CH4, Cl2O. S cht c kiu lin kt cng ha tr c cc l
A. 2.
B. 3.
C. 1.
D. 4.
DA vao hiu m in ta co MgO =2,13 (LK ion) CO2 =0,89 (tuy nhin da vao cu tao) lin kt
cng ht khng phn cc, 2 cht con lai chon .
Cu 25: t chy hon ton 0,1 mol ancol no, mch h X cn va 5,6 lt oxi (ktc). X cng vi axit
HOOCC6H4COOH l 2 monome c dng iu ch polime, lm nguyn liu sn xut t:
A. Nilon-6,6.
B. Lapsan.
C. Capron.
D. Enang
AP AN .d thy ancolX =etilenglicol,
Cu 26: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch
O2 v 80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh
phn th tch: N2 = 84,77%; SO2 = 10,6% cn li l O2. Thnh phn % theo khi lng ca FeS trong X
l
A. 68,75%
B. 59,46%
C. 26,83%
D. 42,3%
FeS(x) FeS2(y). x+2y=10,6 . Oban u 84,77/4=21,1925. O2d =4,63, Otrong Fe2O3=Obd-OdO(SO2)=11,925mol nguyn t.x+y=(11,925/3)*2=7,95 .x= 5,3.y=2,65
Cu 27: Cho 32,8 gam hn hp gm axit glutamic v tyrosin (t l mol 1:1) tc dng vi 500ml dung
dch NaOH 1M, phn ng hon ton thu c dung dch Y. C cn cn thn dung dch Y thu c m
gam cht rn khan. Gi tr ca m l
A. 49,2
B. 52,8
C. 43,8
D. 45,6
Trang 3/7 - M thi 135

Cu nay rt d hs t lam (tuy nhin khng hay, ma thi cung khong ra vi hoc sinh khng nh c
tyrosin=p(OH)-C6H4-CH2-CH(NH2)-COOH.
Cu 28: Cho cc cht v ion sau y: NO2-, Br2, SO2, N2, H2O2, HCl, S. S cht v ion c c tnh oxi ha
v tnh kh l
A. 7.
B. 4.
C. 6.
D. 5.
Cu 29: Cho qu tm vo ln lt cc dung dch: CH 3COOK, FeCl3, NH4NO3, K2S, Zn(NO3)2, Na2CO3.
S dung dch lm i mu giy qu l
A. 4
B. 6
C. 5
D. 3
Cu 30: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang. Nhng loi
t no thuc loi t nhn to l:
A. T nilon 6,6 v t capron.
B. T tm v t enang.
C. T visco v t nilon-6,6.
D. T visco v t axetat.

Cu 31: Cho phn ng sau: 2SO2(k) + O2(k)

2SO3(k) ; H < 0
cn bng trn chuyn dch theo chiu thun th: (1): tng tng nhit , (2): tng p sut, (3): h
nhit , (4): dng xc tc l V2O5, (5): Gim nng SO3. Bin php ng l:
A. 1, 2, 5.
B. 2, 3, 5.
C. 1, 2, 3, 4, 5.
D. 2, 3, 4, 5.
Cu 32: T etilen v benzen, cht v c v iu kin phn ng c . Tng s phn ng t nht c th
iu ch c polibutaien, polistiren, poli (butaien - stiren), poli (vinyl clorua) l
A. 11.
B. 12.
C. 9.
D. 10.
Etilen etanol-buta-1,3dien- polibutadien (4pt)
Benzen- etylbenzen-styren-PS (3 pt)
Buta1,3dien cao subuna S (1pt)
Etilen- dicloetan-vinylclorua- PVC(3pt)
Cu 33: X phng ha hon ton 100gam cht bo c ch s axit bng 7 cn a gam dung dch Na0H 25%,
thu c 9,43gam glyxerol v b gam mui natri. Gi tr ca a, b ln lt l:
A. 49,2 v 103,37
B. 51,2 v 103,145
C. 51,2 v 103,37
D. 49,2 v 103,145
nGlyxerol=0,1025, nNaOH=0,1025*3 +(7*100/1000/56)=0,32. a =51,2. B=100+12,8-9,43(0,7/56)*18=103,145
Cu 34: Tch s ion ca nc mt s nhit nh sau: 20 0C l 7,00.10-15, 250C l 1,00.10-14,
300C l 1,50.10-14. S in ly ca nc l
A. thu nhit
B. ta nhit hay thu nhit ty theo iu kin phn ng
C. ta nhit
D. khng xc nh ta nhit hay thu nhit
Cu 35: t chy hon ton mt lng hn hp hai este n chc no, mch h cn 3,976 lt oxi (ktc)
thu c 6,38 gam CO2. Cho lng este ny tc dng va vi KOH thu c hn hp hai ancol k tip
v 3,92 gam mui ca mt axit hu c. Cng thc ca hai cht hu c trong hn hp u l:
A. HCOOC3H7 v HCOOC2H5
B. CH3COOCH3 v CH3COOC2H5
C. C2H5COOC2H5 v C2H5COOCH3
D. CH3COOC2H5 v CH3COOC3H7
*3-(3,976/22,4)*2=0,08.mE=3,31.
Ctb=3,68. Tim R=15 (CH3)
nCO2=0,145=nH2O, O(E) =0,145
Cu 36: Xt cc cht: imetylete (1), ancol metylic (2), ancol etylic (3), axit axetic (4), axeton (5).
Cc cht trn c xp theo nhit si tng dn (t tri sang phi) l:
A. 1, 5, 2, 3, 4
B. 2, 3, 4, 5, 1
C. 5, 1, 2, 3, 4
D. 1, 2, 3, 4, 5
Cu 37: Cho lung kh CO d i qua hn hp BaO, Al2O3 v FeO t nng thu c cht rn X1. Ho tan
cht rn X1 vo nc thu c dung dch Y1 v cht rn E1. Sc kh CO2 d vo dung dch Y1 thu c
kt ta F1. Ho tan E1 vo dung dch NaOH d thy b tan mt phn v cn cht rn G1. Cho G1 vo dung
dch AgNO3 d (Coi CO2 khng phn ng vi nc). Tng s phn ng xy ra l
A. 7.
B. 8.
C. 6.
D. 9.
Rn X1=(BaO.Al2O3,Fe) ,E1(Al2O3d, Fe) G1=Fe, F1(BaCO3, Al(OH)3, Fe +Ag+ Fe2++Ag,Fe2+
+Ag+Fe3+ +Ag.
CO+FeO (1pt)

Trang 4/7 - M thi 135

BaO+H2O (1pt) ,Ba(OH)2+Al2O3 (1pt), Ba (AlO2)2 +CO2 (1pt) (do Al2O3 d,nn
Ba(OH)2ht).NaOH+Al2O3 (1pt)
Cu 38: Cho 25,65 gam mui gm H2NCH2COONa v H2NCH2CH2COONa tc dng va vi 250 ml
dung dch H2SO41M. Sau phn ng c cn dung dch th khi lng mui do H2NCH2COONa to thnh
l:
A. 29,25 gam
B. 18,6 gam
C. 37,9 gam
D. 12,4 gam
a>97x+111y=25,65 , 2x+2y=0,25*2, x=0,15,y=0,1. m= 0,15*97 +0,15*98=A
Cu 39: Nung m gam hn hp X gm KClO3 v KMnO4 thu c cht rn Y v O2. Bit KClO3 phn hy
hon ton, cn KMnO4 ch b phn hy mt phn. Trong Y c 0,894 gam KCl chim 8,132% theo khi
lng. Trn lng O2 trn vi khng kh theo t l th tch VO2 : V KK =1:3 trong mt bnh kn ta thu
c hn hp kh Z. Cho vo bnh 0,528 gam cacbon ri t chy ht cacbon, phn ng hon ton, thu
c hn hp kh T gm 3 kh O2, N2, CO2, trong CO2 chim 22,92% th tch. Gi tr m (gam) l
A. 12,59
B. 12,53
C. 12,70
D. 12,91
KlO3KCl +3/2 O2, 2 KMnO4K2MnO4 +MnO2+O2. nKCl=KclO3=0,012. nO2(oF KclO3)=0,018.
mY=11g. nCO2=0,044, nhh khi=0,1919=0,2. =nO2 sinhra (x)+3x, x=0,05, vy theo bao toan
mX=mY+mO2(sinh ra ) =11+0,05*32=12,6=A
Cu 40: Cht hu c X mch h, khng cha lin kt (-O-O-) v c cng thc phn t l C3H6On. Bit X
ch cha mt loi nhm chc. S ng phn cu to c th c ca X l
A. 4.
B. 6.
C. 7.
D. 5.

ap an D thy n3 /n=1. C3H6O, ancol =1, te=1 (mach h), andehyt=1, xton =1,
n=2. Axit =1, este =1, O HC-H2C- CH2- OH= 1, n=3 loai
II. PHN RING [10 cu]
Th sinh ch c lm mt trong hai phn (phn A hoc B)
A.Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Dng mt lng dung dch H2SO4 nng 20%, un nng ha tan va a mol CuO. Sau
phn ng lm ngui dung dch n 1000C th khi lng tinh th CuSO4.5H2O tch ra khi dung dch
l 30,7 gam. Bit rng tan ca dung dch CuSO4 1000C l 17,4 gam. Gi tr ca a l
A. 0,1.
B. 0,15.
C. 0,2.
D. 0,25.
mdd=a*80+a*98/20%=570a , mct=a*160 ,theo bai ra c 117,4 gdd bao hoa co 17,4 ganm ctan. mct co
trong dd=570a*17,4/117,4=84,48a, mct tach ra=160a-84,48a=75,52a=30,7*160/250, a=D
Cu 42: C dung dch X gm (KI v mt t h tinh bt). Cho ln lt tng cht sau: O3, Cl2, H2O2, FeCl3,
AgNO3 tc dng vi dung dch X. S cht lm dung dch X chuyn sang mu xanh l
A. 4 cht
B. 5 cht
C. 3 cht
D. 2 cht
o la cac cht OXH manh
Cu 43: Ha tan hon ton 3,76 gam hn hp: S, FeS, FeS2 trong HNO3 d c 0,48 mol NO2 v dung
dch X. Cho dung dch Ba(OH)2 d vo X, lc kt ta nung n khi lng khng i th khi lng cht
rn thu c l:
A. 17,545 gam
B. 18,355 gam
C. 15,145 gam
D. 2,4 gam
AP AN> 56X +32Y= 3,76, 3X +6Y =0,48*1, X=0,03, Y=O,065, m= 0,065*233+0,015*160=A
Cu 44: Ngi ta c th iu ch cao su Buna t g theo s sau:
Xenluloz 3%5 glucoz 8%0 C2H5OH 6%0 Buta-1,3-ien T H Cao su Buna
Khi lng xenluloz cn sn xut 1 tn cao su Buna l
A. 25,625 tn.
B. 37,875 tn.
C. 5,806 tn.
D. 17,857 tn.
M=(1*162/54)/0,35/0,8/0,6/=D
Cu 45: Hn hp A gm 0,1 mol anehit metacrylic v 0,3 mol kh hiro. Nung nng hn hp A mt thi
gian, c mt cht xc tc Ni, thu c hn hp hi B gm hn hp cc ancol, cc anehit v hiro. T
khi hi ca B so vi He bng 95/12. Hiu sut ca phn ng hiro ha anehit metacrylic l:
A. 100%
B. 70%
C. 65%
D. 80%
0,1*(CH2=C(CH3)-CHO)+0,3*2 =MB*nB, nB=0,24= 0,4-2x, x=0,08. H=0,08/0,1=D
Cu 46: Cho 6,0 gam Mg tc dng ht vi dung dch HCl 18,25% (va ). Sau phn ng thu c dung
dch mui A v hiro that ra. Bit phn ng xy ra hon ton. Vy nng phn trm ca dung dch
mui s l:
A. 22,41%
B. 22,51%
C. 42,79%
D. 42,41%
nMg=6/24 =0,25 HCl = 0,5, mHCl=(0,5*36,5)/18,25%=100g, C%=0,25*(24+71)/(100-0,5*1+6)=B
Trang 5/7 - M thi 135

Cu 47: C 5 kh ng ring bit trong 5 l l Cl 2, O2, HCl, O3, SO2. Hy chn trnh t tin hnh no
trong cc trnh t sau phn bit cc kh:
A. Qu tm m, dung dch KI/h tinh bt, Cu un nng.
B. Dung dch AgNO3, dung dch KI/h tinh bt, dng u que m cn tn .
C. Nhn bit mu ca kh, dung dch AgNO3, dung dch KI, dng u que m cn tn .
D. Dung dch H2S, dung dch AgNO3, dung dch KI.
Cu 48: T butan, cht v c v iu kin phn ng c . S phng trnh phn ng ti thiu iu
ch glixerol l
A. 5.
B. 4.
C. 7.
D. 6.
ap an.Butan------ propen------- 1clo propen------1,3 iclo propan-2ol-----glixerol
Cu 49: Tm pht biu sai trong cc pht biu sau :
A. Nhit si ca ankanol cao hn so vi ankanal c phn t khi tng ng.
B. Phenol l cht rn kt tinh iu kin thng.
C. Metylamin l cht lng c mi khai, tng t nh amoniac.
D. Etylamin d tan trong H2O.
Metyl amin la cht khi
Cu 50: Cho cc cht sau: C2H5OH, C6H5OH, C6H5NH2, dung dch C6H5ONa, dung dch NaOH, dung
dch CH3COOH, dung dch HCl. Cho tng cp cht tc dng vi nhau c xc tc, s cp cht c phn ng
xy ra l
A. 12
B. 8
C. 9
D. 10
Etanol =2, phenol =1, anilin=2, phenolat=2, NaOH =2
B.Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Cho NH3 d vo ln lt cc dung dch sau: CrCl3, CuCl2, ZnCl2, AgNO3, NiCl2. S trng hp
kt ta hnh thnh b tan l
A. 4.
B. 3.
C. 1.
D. 5.
Cu 52: Mt bnh kn dung tch 1 lt cha 1,5 mol H2 v 1,0 mol N2 (c xc tc v nhit thch hp).
trng thi cn bng c 0,2 mol NH3 to thnh. Mun hiu sut t 25 % cn phi thm vo bnh bao
nhiu mol N2?
A. 1,5
B. 2,25
C. 0,83
D. 1,71
Cu 53: Cho 12gam hn hp Fe v Cu vo 200ml dung dch HNO 3 2M, thu c mt cht kh (sn phm
kh duy nht) khng mu, ha nu trong khng kh, v c mt kim loi d. Sau cho thm dung dch
H2SO4 2M, thy cht kh trn tip tc thot ra, ho tan ht kim loi cn 33,33ml. Khi lng kim loi
Fe trong hn hp l
A. 8,4 gam
B. 5,6 gam
C. 2,8 gam
D. 1,4 gam
Cu 54: Thy phn hon ton mt lng mantoz, sau cho ton b lng glucoz thu c ln men
thnh ancol etylic th thu c 100 ml ru 460. Khi lng ring ca ancol l 0,8gam/ml. Hp th ton
b kh CO2 vo dung dch NaOH d thu c mui c khi lng l:
A. 84,8 gam.
B. 42,4 gam.
C. 212 gam.
D. 169,6 gam.
Cu 55: Cho cc cht sau y: 1)CH3COOH, 2)C2H5OH, 3)C2H2, 4)CH3COONa, 5)HCOOCH=CH2,
6)CH3COONH4. Dy gm cc cht no sau y u c to ra t CH 3CHO bng mt phng trnh phn
ng l:
A. 1, 2, 3, 4, 5, 6.
B. 1, 2, 6.
C. 1, 2.
D. 1, 2, 4, 6.
2+
Cu 56: Cho bit th in cc chun ca cc cp oxi ho kh: 2H+/H 2; Zn /Zn; Cu2+/Cu; Ag+/Ag ln lt
l 0,00V; -0,76V; +0,34V; +0,80V. Sut in ng ca pin in ho no sau y ln nht?
A. Cu + 2Ag+ Cu2+ + 2Ag.
B. 2Ag + 2H+ 2Ag+ + H2.
2+
2+
C. Zn + Cu
Zn + Cu.
D. Zn + 2H+ Zn2+ + H2.
Cu 57: Cc kh thi cng nghip v ca cc ng c t, xe my...l nguyn nhn ch yu gy ra ma
axit. Nhng thnh phn ha hc ch yu trong cc kh thi trc tip gy ra ma axit l:
A. SO2, CO, NO.
B. SO2, CO, NO2.
C. NO, NO2, SO2.
D. NO2, CO2, CO.
Cu 58: Cho isopren tc dng Br2 theo t l mol 1:1 thu c ti a x dn xut mono brom. un nng
ancol bc 2 C5H12O vi H2SO4 c 1800C thu c ti a y sn phm hu c. Mi lin h gia x, y l :
A. x - y = 1
B. x = y
C. y - x = 1
D. y - x = 2
Cu 59: Cho cc cht sau: axit glutamic; valin, lysin, alanin, trimetylamin, anilin. S cht lm qu tm
chuyn mu hng, mu xanh, khng i mu ln lt l
A. 2, 1,3.
B. 1, 2, 3.
C. 3, 1, 2.
D. 1, 1, 4.
Trang 6/7 - M thi 135

Cu 60: Cho s phn ng sau :

Cng thc cu to ca Y l
A. CH2=C(CH3)-COOC6H5.
B. CH2=CH-COOC6H5.
C. C6H5COOCH=CH2.
D. CH2=C(CH3)-COOCH2-C6H5.
-------------------------------------------------------------------------------------------------------H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40;
Mn = 55; Fe = 56; Cu = 64; Zn = 65; Cl=35,5; Br = 80; Ag = 108; Ba = 137; Pb = 207.
Khng c s dng bng HTTH
HT

Trang 7/7 - M thi 135